# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_x
_database_code_depnum_ccdc_archive 'CCDC 2291212'
loop_
_audit_author_name
_audit_author_address
'Yingchen Peng'
; Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2024-08-21 deposited with the CCDC.	2024-08-28 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C29 H26 Cl Eu3 N4 O25'
_chemical_formula_weight         1321.87

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.8426(9)
_cell_length_b                   14.2179(11)
_cell_length_c                   24.756(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.899(3)
_cell_angle_gamma                90
_cell_volume                     4118.2(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.132
_exptl_crystal_F_000             2536
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    4.674
_shelx_estimated_absorpt_T_min   0.335
_shelx_estimated_absorpt_T_max   0.455
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            63493
_diffrn_reflns_av_unetI/netI     0.0538
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.495
_diffrn_reflns_theta_max         28.510
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             10301
_reflns_number_gt                7719
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0224P)²+7.3898P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.00021(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         10301
_refine_ls_number_parameters     662
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.0608
_refine_ls_R_factor_gt           0.0339
_refine_ls_wR_factor_ref         0.0672
_refine_ls_wR_factor_gt          0.0607
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.18726(2) 0.29425(2) 0.25435(2) 0.01919(6) Uani 1 1 d . . . . .
Eu2 Eu -0.04934(2) 0.05974(2) 0.16517(2) 0.01723(6) Uani 1 1 d . . . . .
Eu3 Eu 0.26641(2) 0.24133(2) 0.01303(2) 0.02225(7) Uani 1 1 d D . . . .
O1 O 0.0128(3) 0.2164(2) 0.19967(13) 0.0236(7) Uani 1 1 d . . . . .
O2 O 0.0206(3) 0.3702(2) 0.19164(15) 0.0352(9) Uani 1 1 d . . . . .
O3 O -0.1961(3) 0.0265(2) 0.08733(13) 0.0252(7) Uani 1 1 d . . . . .
O4 O -0.3675(3) 0.0608(3) 0.04039(15) 0.0380(9) Uani 1 1 d . . . . .
O5 O 0.3197(3) 0.3039(3) 0.33864(13) 0.0297(8) Uani 1 1 d . . . . .
O6 O 0.4949(3) 0.2962(3) 0.38729(14) 0.0443(10) Uani 1 1 d . . . . .
O7 O 0.2327(3) 0.2678(3) 0.16409(14) 0.0345(9) Uani 1 1 d . . . . .
O8 O 0.3535(3) 0.2421(3) 0.10487(14) 0.0378(9) Uani 1 1 d . . . . .
O9 O -0.0796(3) -0.1065(2) 0.18633(13) 0.0234(7) Uani 1 1 d . . . . .
O10 O -0.0674(3) -0.2592(2) 0.17247(14) 0.0308(8) Uani 1 1 d . . . . .
O11 O 0.0423(3) 0.1198(2) 0.08983(14) 0.0295(8) Uani 1 1 d . . . . .
O12 O 0.1684(3) 0.1022(2) 0.03240(14) 0.0365(9) Uani 1 1 d . . . . .
O13 O 0.2120(3) 0.1312(2) 0.26283(14) 0.0269(8) Uani 1 1 d . . . . .
O14 O 0.1562(3) 0.0334(2) 0.19310(14) 0.0304(8) Uani 1 1 d . . . . .
O16 O 0.7616(3) 0.0600(2) 0.19304(14) 0.0321(8) Uani 1 1 d . . . . .
O15 O 0.7612(3) -0.0498(2) 0.25741(13) 0.0255(7) Uani 1 1 d . . . . .
O1W O -0.0196(3) 0.0580(3) 0.26555(14) 0.0328(8) Uani 1 1 d D . . . .
H1C H 0.035(3) 0.093(3) 0.275(2) 0.049 Uiso 1 1 d D U . . .
H1D H -0.016(4) 0.0061(17) 0.280(2) 0.049 Uiso 1 1 d D U . . .
O2W O 0.4033(3) 0.1090(3) 0.02193(17) 0.0364(9) Uani 1 1 d D . . . .
H2C H 0.468(2) 0.109(4) 0.0391(19) 0.055 Uiso 1 1 d D U . . .
H2D H 0.391(4) 0.072(3) -0.0036(16) 0.055 Uiso 1 1 d D U . . .
O3W O 0.1652(5) 0.3413(3) -0.06121(19) 0.0665(14) Uani 1 1 d D . . . .
H3C H 0.147(7) 0.319(4) -0.0918(14) 0.100 Uiso 1 1 d D U . . .
H3D H 0.138(6) 0.393(3) -0.056(3) 0.100 Uiso 1 1 d D U . . .
O4W O 0.2314(3) 0.1573(2) -0.07035(13) 0.0278(8) Uani 1 1 d D . . . .
H4C H 0.225(4) 0.1004(10) -0.0656(19) 0.042 Uiso 1 1 d D U . . .
H4D H 0.264(4) 0.171(3) -0.0962(15) 0.042 Uiso 1 1 d D U . . .
O5W O 0.2911(4) 0.4064(3) 0.0387(2) 0.0603(13) Uani 1 1 d D . . . .
H5C H 0.354(3) 0.422(5) 0.032(2) 0.090 Uiso 1 1 d D U . . .
H5D H 0.280(5) 0.422(5) 0.0696(13) 0.090 Uiso 1 1 d D U . . .
O6W O 0.4270(3) 0.2925(3) -0.02714(16) 0.0374(9) Uani 1 1 d D . . . .
H6C H 0.454(5) 0.262(3) -0.0502(18) 0.056 Uiso 1 1 d D U . . .
H6D H 0.434(5) 0.3494(8) -0.028(2) 0.056 Uiso 1 1 d D U . . .
O7W O 0.0918(4) 0.2896(3) 0.0446(2) 0.0587(13) Uani 1 1 d D . . . .
H7C H 0.047(3) 0.289(5) 0.0160(11) 0.088 Uiso 1 1 d D U . . .
H7D H 0.083(4) 0.248(3) 0.0665(19) 0.088 Uiso 1 1 d D U . . .
N1 N -0.1621(3) 0.1994(3) 0.12198(15) 0.0198(8) Uani 1 1 d . . . . .
N2 N 0.3968(3) 0.2829(3) 0.24637(15) 0.0211(8) Uani 1 1 d . . . . .
C1 C -0.0256(4) 0.2937(3) 0.17815(19) 0.0219(10) Uani 1 1 d . . . . .
C2 C -0.1299(4) 0.2881(3) 0.1350(2) 0.0245(10) Uani 1 1 d . . . . .
C3 C -0.1880(5) 0.3644(4) 0.1108(3) 0.0454(16) Uani 1 1 d . . . . .
H3A H -0.163518 0.425250 0.120137 0.054 Uiso 1 1 calc R U . . .
C4 C -0.2833(5) 0.3491(4) 0.0723(3) 0.0539(18) Uani 1 1 d . . . . .
H4A H -0.324623 0.399847 0.055776 0.065 Uiso 1 1 calc R U . . .
C5 C -0.3173(5) 0.2587(4) 0.0584(2) 0.0382(13) Uani 1 1 d . . . . .
H5A H -0.382119 0.247297 0.032879 0.046 Uiso 1 1 calc R U . . .
C6 C -0.2529(4) 0.1850(3) 0.08338(19) 0.0234(10) Uani 1 1 d . . . . .
C7 C -0.2762(4) 0.0827(4) 0.06969(19) 0.0250(11) Uani 1 1 d . . . . .
C8 C 0.4289(4) 0.2985(4) 0.34409(19) 0.0276(11) Uani 1 1 d . . . . .
C9 C 0.4761(4) 0.2909(3) 0.29075(19) 0.0217(10) Uani 1 1 d . . . . .
N3 N 0.0363(3) -0.0631(3) 0.10818(15) 0.0212(8) Uani 1 1 d . . . . .
C10 C 0.5922(4) 0.2930(4) 0.2871(2) 0.0331(12) Uani 1 1 d . . . . .
H10A H 0.646445 0.300480 0.318281 0.040 Uiso 1 1 calc R U . . .
C11 C 0.6250(4) 0.2837(4) 0.2366(2) 0.0400(14) Uani 1 1 d . . . . .
H11A H 0.702109 0.283507 0.233225 0.048 Uiso 1 1 calc R U . . .
C12 C 0.5434(4) 0.2746(4) 0.1909(2) 0.0358(13) Uani 1 1 d . . . . .
H12A H 0.564515 0.268924 0.156438 0.043 Uiso 1 1 calc R U . . .
C13 C 0.4296(4) 0.2739(3) 0.19718(19) 0.0234(10) Uani 1 1 d . . . . .
C14 C 0.3314(4) 0.2610(3) 0.1515(2) 0.0281(11) Uani 1 1 d . . . . .
C15 C -0.0419(4) -0.1763(3) 0.16263(18) 0.0194(10) Uani 1 1 d . . . . .
C16 C 0.0348(4) -0.1546(3) 0.12081(19) 0.0233(10) Uani 1 1 d . . . . .
C17 C 0.1005(5) -0.2198(4) 0.1000(3) 0.0454(16) Uani 1 1 d . . . . .
H17A H 0.095489 -0.283077 0.108740 0.055 Uiso 1 1 calc R U . . .
C18 C 0.1744(6) -0.1901(4) 0.0657(3) 0.066(2) Uani 1 1 d . . . . .
H18A H 0.222007 -0.232756 0.051799 0.079 Uiso 1 1 calc R U . . .
C19 C 0.1767(5) -0.0962(4) 0.0524(3) 0.0505(17) Uani 1 1 d . . . . .
H19A H 0.225349 -0.074850 0.028948 0.061 Uiso 1 1 calc R U . . .
C20 C 0.1060(4) -0.0335(3) 0.0741(2) 0.0267(11) Uani 1 1 d . . . . .
C21 C 0.1050(4) 0.0705(4) 0.0642(2) 0.0268(11) Uani 1 1 d . . . . .
C22 C 0.2306(4) 0.0715(3) 0.22762(19) 0.0219(10) Uani 1 1 d . . . . .
C23 C 0.3542(4) 0.0478(3) 0.2263(2) 0.0217(10) Uani 1 1 d . . . . .
C24 C 0.3948(4) 0.0370(3) 0.1773(2) 0.0261(11) Uani 1 1 d . . . . .
H24A H 0.344240 0.035319 0.144628 0.031 Uiso 1 1 calc R U . . .
C25 C 0.5121(4) 0.0287(3) 0.1771(2) 0.0266(11) Uani 1 1 d . . . . .
H25A H 0.539317 0.023995 0.143889 0.032 Uiso 1 1 calc R U . . .
C26 C 0.5884(4) 0.0273(3) 0.22508(19) 0.0211(10) Uani 1 1 d . . . . .
C27 C 0.5460(4) 0.0334(4) 0.2741(2) 0.0328(13) Uani 1 1 d D . . . .
H27A H 0.595540 0.029260 0.306997 0.039 Uiso 0.5 1 calc R U P A 2
O17 O 0.7098(7) 0.0984(6) 0.3272(3) 0.059(3) Uani 0.5 1 d D . P B 1
O18 O 0.5938(9) 0.0159(11) 0.3652(4) 0.123(5) Uani 0.5 1 d D U P B 1
N4 N 0.6212(7) 0.0545(8) 0.3253(3) 0.053(3) Uani 0.5 1 d D . P B 1
C28 C 0.4308(4) 0.0454(4) 0.2741(2) 0.0304(12) Uani 1 1 d D . . . .
H28A H 0.404039 0.052148 0.307307 0.036 Uiso 0.5 1 calc R U P C 1
O17B O 0.3089(7) -0.0104(7) 0.3316(4) 0.063(3) Uani 0.5 1 d D . P D 2
O18B O 0.4433(8) 0.0865(8) 0.3625(4) 0.082(3) Uani 0.5 1 d D . P D 2
N4B N 0.3906(7) 0.0383(7) 0.3265(3) 0.044(3) Uani 0.5 1 d D . P D 2
C29 C 0.7147(4) 0.0120(3) 0.22502(19) 0.0212(10) Uani 1 1 d . . . . .
Cl1 Cl 0.500000 0.000000 0.500000 0.0646(7) Uani 1 2 d S . P . .
Cl2 Cl 0.9748(17) 0.0112(13) 0.5216(8) 0.103(5) Uani 0.165 1 d . U P E 1
Cl2D Cl 0.963(2) 0.046(2) 0.4749(14) 0.086(7) Uani 0.085 1 d . U P E 1
Cl2B Cl 0.8135(15) -0.0084(10) 0.3832(5) 0.107(6) Uani 0.165 1 d . . P F 2
Cl2C Cl 1.003(3) 0.006(2) 0.4337(16) 0.122(15) Uani 0.085 1 d . . P F 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O15 2.330(3) 2_655 ?
Eu1 O13 2.342(3) . ?
Eu1 O7 2.407(3) . ?
Eu1 O5 2.413(3) . ?
Eu1 O9 2.520(3) 2 ?
Eu1 N2 2.524(4) . ?
Eu1 O1 2.542(3) . ?
Eu1 O2 2.554(3) . ?
Eu1 O10 2.583(3) 2 ?
Eu1 C1 2.905(4) . ?
Eu1 C15 2.909(4) 2 ?
Eu2 O3 2.434(3) . ?
Eu2 O16 2.443(3) 1_455 ?
Eu2 O11 2.452(3) . ?
Eu2 O14 2.454(3) . ?
Eu2 O1W 2.456(4) . ?
Eu2 O1 2.457(3) . ?
Eu2 O9 2.459(3) . ?
Eu2 N1 2.535(4) . ?
Eu2 N3 2.552(4) . ?
Eu2 H1C 2.80(5) . ?
Eu3 O8 2.347(3) . ?
Eu3 O4W 2.366(3) . ?
Eu3 O12 2.380(3) . ?
Eu3 O6W 2.391(3) . ?
Eu3 O7W 2.420(4) . ?
Eu3 O5W 2.438(4) . ?
Eu3 O2W 2.471(3) . ?
Eu3 O3W 2.481(4) . ?
Eu3 H4C 2.78(4) . ?
Eu3 H5C 2.78(6) . ?
Eu3 H7C 2.70(5) . ?
Eu3 H7D 2.72(5) . ?
O1 C1 1.274(5) . ?
O2 C1 1.240(5) . ?
O3 C7 1.266(6) . ?
O4 C7 1.244(5) . ?
O5 C8 1.282(6) . ?
O6 C8 1.223(6) . ?
O7 C14 1.260(6) . ?
O8 C14 1.252(5) . ?
O9 C15 1.270(5) . ?
O10 C15 1.249(5) . ?
O11 C21 1.262(6) . ?
O12 C21 1.253(5) . ?
O13 C22 1.260(5) . ?
O14 C22 1.252(5) . ?
O16 C29 1.240(5) . ?
O15 C29 1.257(5) . ?
O1W H1C 0.819(10) . ?
O1W H1D 0.817(10) . ?
O2W H2C 0.817(10) . ?
O2W H2D 0.817(10) . ?
O3W H3C 0.821(10) . ?
O3W H3D 0.817(10) . ?
O4W H4C 0.823(10) . ?
O4W H4D 0.825(10) . ?
O5W H5C 0.827(10) . ?
O5W H5D 0.827(10) . ?
O6W H6C 0.817(10) . ?
O6W H6D 0.815(10) . ?
O7W H7C 0.820(10) . ?
O7W H7D 0.820(10) . ?
N1 C6 1.339(6) . ?
N1 C2 1.342(6) . ?
N2 C9 1.336(6) . ?
N2 C13 1.340(6) . ?
C1 C2 1.505(6) . ?
C2 C3 1.372(7) . ?
C3 C4 1.376(7) . ?
C3 H3A 0.9300 . ?
C4 C5 1.375(8) . ?
C4 H4A 0.9300 . ?
C5 C6 1.384(7) . ?
C5 H5A 0.9300 . ?
C6 C7 1.509(7) . ?
C8 C9 1.515(6) . ?
C9 C10 1.392(6) . ?
N3 C20 1.336(6) . ?
N3 C16 1.338(6) . ?
C10 C11 1.373(7) . ?
C10 H10A 0.9300 . ?
C11 C12 1.374(7) . ?
C11 H11A 0.9300 . ?
C12 C13 1.380(6) . ?
C12 H12A 0.9300 . ?
C13 C14 1.502(7) . ?
C15 C16 1.510(6) . ?
C16 C17 1.362(7) . ?
C17 C18 1.376(7) . ?
C17 H17A 0.9300 . ?
C18 C19 1.377(8) . ?
C18 H18A 0.9300 . ?
C19 C20 1.387(7) . ?
C19 H19A 0.9300 . ?
C20 C21 1.499(7) . ?
C22 C23 1.508(6) . ?
C23 C28 1.377(6) . ?
C23 C24 1.379(6) . ?
C24 C25 1.395(6) . ?
C24 H24A 0.9300 . ?
C25 C26 1.377(6) . ?
C25 H25A 0.9300 . ?
C26 C27 1.385(6) . ?
C26 C29 1.512(6) . ?
C27 C28 1.375(6) . ?
C27 N4 1.464(8) . ?
C27 H27A 0.9300 . ?
O17 N4 1.216(10) . ?
O18 N4 1.218(10) . ?
C28 N4B 1.452(8) . ?
C28 H28A 0.9300 . ?
O17B N4B 1.213(9) . ?
O18B N4B 1.217(10) . ?
Cl2 Cl2D 1.09(3) 3_756 ?
Cl2 Cl2 1.34(4) 3_756 ?
Cl2 Cl2D 1.24(3) . ?
Cl2D Cl2D 1.92(6) 3_756 ?
Cl2B Cl2C 2.40(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Eu1 O13 157.17(11) 2_655 . ?
O15 Eu1 O7 86.12(12) 2_655 . ?
O13 Eu1 O7 83.44(12) . . ?
O15 Eu1 O5 84.60(12) 2_655 . ?
O13 Eu1 O5 85.61(12) . . ?
O7 Eu1 O5 127.10(11) . . ?
O15 Eu1 O9 72.89(10) 2_655 2 ?
O13 Eu1 O9 124.71(11) . 2 ?
O7 Eu1 O9 146.52(11) . 2 ?
O5 Eu1 O9 77.51(10) . 2 ?
O15 Eu1 N2 76.79(11) 2_655 . ?
O13 Eu1 N2 80.39(11) . . ?
O7 Eu1 N2 63.52(12) . . ?
O5 Eu1 N2 63.64(11) . . ?
O9 Eu1 N2 132.31(11) 2 . ?
O15 Eu1 O1 123.71(10) 2_655 . ?
O13 Eu1 O1 72.35(10) . . ?
O7 Eu1 O1 73.58(11) . . ?
O5 Eu1 O1 148.39(11) . . ?
O9 Eu1 O1 96.41(10) 2 . ?
N2 Eu1 O1 131.16(11) . . ?
O15 Eu1 O2 73.41(11) 2_655 . ?
O13 Eu1 O2 123.17(11) . . ?
O7 Eu1 O2 76.38(12) . . ?
O5 Eu1 O2 147.07(11) . . ?
O9 Eu1 O2 72.81(11) 2 . ?
N2 Eu1 O2 131.00(12) . . ?
O1 Eu1 O2 51.13(10) . . ?
O15 Eu1 O10 123.41(10) 2_655 2 ?
O13 Eu1 O10 73.77(11) . 2 ?
O7 Eu1 O10 146.21(11) . 2 ?
O5 Eu1 O10 76.37(11) . 2 ?
O9 Eu1 O10 51.21(10) 2 2 ?
N2 Eu1 O10 133.60(12) . 2 ?
O1 Eu1 O10 75.87(11) . 2 ?
O2 Eu1 O10 95.38(11) . 2 ?
O15 Eu1 C1 98.01(12) 2_655 . ?
O13 Eu1 C1 98.01(12) . . ?
O7 Eu1 C1 72.10(12) . . ?
O5 Eu1 C1 160.80(12) . . ?
O9 Eu1 C1 85.06(11) 2 . ?
N2 Eu1 C1 135.52(12) . . ?
O1 Eu1 C1 25.96(11) . . ?
O2 Eu1 C1 25.22(11) . . ?
O10 Eu1 C1 86.50(12) 2 . ?
O15 Eu1 C15 98.43(12) 2_655 2 ?
O13 Eu1 C15 99.12(12) . 2 ?
O7 Eu1 C15 156.93(12) . 2 ?
O5 Eu1 C15 75.95(11) . 2 ?
O9 Eu1 C15 25.80(11) 2 2 ?
N2 Eu1 C15 139.55(12) . 2 ?
O1 Eu1 C15 85.28(11) . 2 ?
O2 Eu1 C15 83.24(12) . 2 ?
O10 Eu1 C15 25.42(11) 2 2 ?
C1 Eu1 C15 84.85(12) . 2 ?
O3 Eu2 O16 69.52(11) . 1_455 ?
O3 Eu2 O11 79.13(11) . . ?
O16 Eu2 O11 138.34(11) 1_455 . ?
O3 Eu2 O14 138.53(11) . . ?
O16 Eu2 O14 146.41(12) 1_455 . ?
O11 Eu2 O14 74.42(11) . . ?
O3 Eu2 O1W 140.57(11) . . ?
O16 Eu2 O1W 73.05(12) 1_455 . ?
O11 Eu2 O1W 139.67(11) . . ?
O14 Eu2 O1W 74.48(12) . . ?
O3 Eu2 O1 126.18(10) . . ?
O16 Eu2 O1 97.98(11) 1_455 . ?
O11 Eu2 O1 78.73(11) . . ?
O14 Eu2 O1 79.04(11) . . ?
O1W Eu2 O1 70.68(11) . . ?
O3 Eu2 O9 82.64(11) . . ?
O16 Eu2 O9 76.75(11) 1_455 . ?
O11 Eu2 O9 126.39(11) . . ?
O14 Eu2 O9 87.95(11) . . ?
O1W Eu2 O9 77.13(11) . . ?
O1 Eu2 O9 147.45(11) . . ?
O3 Eu2 N1 63.47(11) . . ?
O16 Eu2 N1 70.86(11) 1_455 . ?
O11 Eu2 N1 70.88(11) . . ?
O14 Eu2 N1 132.32(12) . . ?
O1W Eu2 N1 114.74(12) . . ?
O1 Eu2 N1 63.03(11) . . ?
O9 Eu2 N1 139.28(11) . . ?
O3 Eu2 N3 74.06(11) . . ?
O16 Eu2 N3 128.09(12) 1_455 . ?
O11 Eu2 N3 63.75(11) . . ?
O14 Eu2 N3 65.78(11) . . ?
O1W Eu2 N3 123.05(12) . . ?
O1 Eu2 N3 133.59(11) . . ?
O9 Eu2 N3 62.83(11) . . ?
N1 Eu2 N3 122.10(12) . . ?
O3 Eu2 H1C 155.2(9) . . ?
O16 Eu2 H1C 85.8(9) 1_455 . ?
O11 Eu2 H1C 123.4(6) . . ?
O14 Eu2 H1C 64.1(10) . . ?
O1W Eu2 H1C 16.3(6) . . ?
O1 Eu2 H1C 57.7(7) . . ?
O9 Eu2 H1C 89.8(7) . . ?
N1 Eu2 H1C 111.3(10) . . ?
N3 Eu2 H1C 122.9(10) . . ?
O8 Eu3 O4W 147.06(13) . . ?
O8 Eu3 O12 87.92(13) . . ?
O4W Eu3 O12 74.37(12) . . ?
O8 Eu3 O6W 98.21(13) . . ?
O4W Eu3 O6W 80.46(12) . . ?
O12 Eu3 O6W 141.31(13) . . ?
O8 Eu3 O7W 87.43(15) . . ?
O4W Eu3 O7W 112.44(15) . . ?
O12 Eu3 O7W 72.73(13) . . ?
O6W Eu3 O7W 145.29(14) . . ?
O8 Eu3 O5W 74.09(16) . . ?
O4W Eu3 O5W 135.38(14) . . ?
O12 Eu3 O5W 142.24(14) . . ?
O6W Eu3 O5W 75.20(14) . . ?
O7W Eu3 O5W 73.53(16) . . ?
O8 Eu3 O2W 74.53(13) . . ?
O4W Eu3 O2W 73.57(12) . . ?
O12 Eu3 O2W 71.51(13) . . ?
O6W Eu3 O2W 73.48(14) . . ?
O7W Eu3 O2W 140.24(14) . . ?
O5W Eu3 O2W 131.26(15) . . ?
O8 Eu3 O3W 143.57(14) . . ?
O4W Eu3 O3W 69.12(14) . . ?
O12 Eu3 O3W 115.53(16) . . ?
O6W Eu3 O3W 80.88(18) . . ?
O7W Eu3 O3W 74.80(18) . . ?
O5W Eu3 O3W 70.49(17) . . ?
O2W Eu3 O3W 137.51(16) . . ?
O8 Eu3 H4C 133.2(8) . . ?
O4W Eu3 H4C 15.9(6) . . ?
O12 Eu3 H4C 60.2(6) . . ?
O6W Eu3 H4C 89.7(8) . . ?
O7W Eu3 H4C 111.3(10) . . ?
O5W Eu3 H4C 151.2(6) . . ?
O2W Eu3 H4C 63.7(10) . . ?
O3W Eu3 H4C 83.2(8) . . ?
O8 Eu3 H5C 74.9(14) . . ?
O4W Eu3 H5C 128.4(11) . . ?
O12 Eu3 H5C 156.3(9) . . ?
O6W Eu3 H5C 59.1(7) . . ?
O7W Eu3 H5C 90.1(8) . . ?
O5W Eu3 H5C 16.6(8) . . ?
O2W Eu3 H5C 117.7(12) . . ?
O3W Eu3 H5C 73.7(14) . . ?
H4C Eu3 H5C 143.2(12) . . ?
O8 Eu3 H7C 104.7(6) . . ?
O4W Eu3 H7C 96.4(8) . . ?
O12 Eu3 H7C 72.7(13) . . ?
O6W Eu3 H7C 139.9(11) . . ?
O7W Eu3 H7C 17.3(6) . . ?
O5W Eu3 H7C 80.0(13) . . ?
O2W Eu3 H7C 144.2(13) . . ?
O3W Eu3 H7C 61.2(8) . . ?
H4C Eu3 H7C 97.7(15) . . ?
H5C Eu3 H7C 95.7(17) . . ?
O8 Eu3 H7D 78.0(11) . . ?
O4W Eu3 H7D 113.4(13) . . ?
O12 Eu3 H7D 58.6(10) . . ?
O6W Eu3 H7D 160.0(11) . . ?
O7W Eu3 H7D 17.1(6) . . ?
O5W Eu3 H7D 84.9(11) . . ?
O2W Eu3 H7D 123.2(6) . . ?
O3W Eu3 H7D 90.5(6) . . ?
H4C Eu3 H7D 107.3(16) . . ?
H5C Eu3 H7D 101.2(14) . . ?
H7C Eu3 H7D 29.7(6) . . ?
C1 O1 Eu2 124.6(3) . . ?
C1 O1 Eu1 93.2(3) . . ?
Eu2 O1 Eu1 139.01(13) . . ?
C1 O2 Eu1 93.4(3) . . ?
C7 O3 Eu2 123.8(3) . . ?
C8 O5 Eu1 126.7(3) . . ?
C14 O7 Eu1 126.2(3) . . ?
C14 O8 Eu3 140.5(3) . . ?
C15 O9 Eu2 125.4(3) . . ?
C15 O9 Eu1 94.4(3) . 2_545 ?
Eu2 O9 Eu1 140.00(13) . 2_545 ?
C15 O10 Eu1 92.0(3) . 2_545 ?
C21 O11 Eu2 123.6(3) . . ?
C21 O12 Eu3 141.6(3) . . ?
C22 O13 Eu1 129.6(3) . . ?
C22 O14 Eu2 133.5(3) . . ?
C29 O16 Eu2 134.4(3) . 1_655 ?
C29 O15 Eu1 133.0(3) . 2_645 ?
Eu2 O1W H1C 106(4) . . ?
Eu2 O1W H1D 116(4) . . ?
H1C O1W H1D 116(2) . . ?
Eu3 O2W H2C 127(4) . . ?
Eu3 O2W H2D 112(3) . . ?
H2C O2W H2D 116(2) . . ?
Eu3 O3W H3C 119(5) . . ?
Eu3 O3W H3D 124(5) . . ?
H3C O3W H3D 116(2) . . ?
Eu3 O4W H4C 112(3) . . ?
Eu3 O4W H4D 121(3) . . ?
H4C O4W H4D 114.5(19) . . ?
Eu3 O5W H5C 106(5) . . ?
Eu3 O5W H5D 118(5) . . ?
H5C O5W H5D 114(2) . . ?
Eu3 O6W H6C 123(4) . . ?
Eu3 O6W H6D 114(4) . . ?
H6C O6W H6D 117(2) . . ?
Eu3 O7W H7C 101(4) . . ?
Eu3 O7W H7D 102(4) . . ?
H7C O7W H7D 116(2) . . ?
C6 N1 C2 118.8(4) . . ?
C6 N1 Eu2 119.6(3) . . ?
C2 N1 Eu2 121.6(3) . . ?
C9 N2 C13 119.3(4) . . ?
C9 N2 Eu1 120.4(3) . . ?
C13 N2 Eu1 120.3(3) . . ?
O2 C1 O1 122.0(4) . . ?
O2 C1 C2 121.1(4) . . ?
O1 C1 C2 116.9(4) . . ?
O2 C1 Eu1 61.4(2) . . ?
O1 C1 Eu1 60.9(2) . . ?
C2 C1 Eu1 174.5(3) . . ?
N1 C2 C3 122.2(4) . . ?
N1 C2 C1 113.0(4) . . ?
C3 C2 C1 124.7(5) . . ?
C2 C3 C4 118.6(5) . . ?
C2 C3 H3A 120.7 . . ?
C4 C3 H3A 120.7 . . ?
C5 C4 C3 119.8(5) . . ?
C5 C4 H4A 120.1 . . ?
C3 C4 H4A 120.1 . . ?
C4 C5 C6 118.4(5) . . ?
C4 C5 H5A 120.8 . . ?
C6 C5 H5A 120.8 . . ?
N1 C6 C5 121.9(5) . . ?
N1 C6 C7 114.0(4) . . ?
C5 C6 C7 124.0(4) . . ?
O4 C7 O3 125.4(5) . . ?
O4 C7 C6 119.0(4) . . ?
O3 C7 C6 115.5(4) . . ?
O6 C8 O5 126.2(4) . . ?
O6 C8 C9 119.2(4) . . ?
O5 C8 C9 114.5(4) . . ?
N2 C9 C10 121.7(4) . . ?
N2 C9 C8 114.5(4) . . ?
C10 C9 C8 123.8(4) . . ?
C20 N3 C16 119.1(4) . . ?
C20 N3 Eu2 118.0(3) . . ?
C16 N3 Eu2 121.0(3) . . ?
C11 C10 C9 118.5(5) . . ?
C11 C10 H10A 120.7 . . ?
C9 C10 H10A 120.7 . . ?
C10 C11 C12 119.8(5) . . ?
C10 C11 H11A 120.1 . . ?
C12 C11 H11A 120.1 . . ?
C11 C12 C13 118.9(5) . . ?
C11 C12 H12A 120.6 . . ?
C13 C12 H12A 120.6 . . ?
N2 C13 C12 121.8(4) . . ?
N2 C13 C14 113.3(4) . . ?
C12 C13 C14 124.9(4) . . ?
O8 C14 O7 125.4(5) . . ?
O8 C14 C13 118.2(4) . . ?
O7 C14 C13 116.4(4) . . ?
O10 C15 O9 122.3(4) . . ?
O10 C15 C16 121.1(4) . . ?
O9 C15 C16 116.7(4) . . ?
O10 C15 Eu1 62.5(2) . 2_545 ?
O9 C15 Eu1 59.8(2) . 2_545 ?
C16 C15 Eu1 176.3(3) . 2_545 ?
N3 C16 C17 122.9(4) . . ?
N3 C16 C15 113.0(4) . . ?
C17 C16 C15 124.0(4) . . ?
C16 C17 C18 118.7(5) . . ?
C16 C17 H17A 120.7 . . ?
C18 C17 H17A 120.7 . . ?
C17 C18 C19 118.9(5) . . ?
C17 C18 H18A 120.6 . . ?
C19 C18 H18A 120.6 . . ?
C18 C19 C20 119.7(5) . . ?
C18 C19 H19A 120.2 . . ?
C20 C19 H19A 120.2 . . ?
N3 C20 C19 120.7(5) . . ?
N3 C20 C21 115.1(4) . . ?
C19 C20 C21 124.1(4) . . ?
O12 C21 O11 125.0(5) . . ?
O12 C21 C20 117.9(4) . . ?
O11 C21 C20 117.1(4) . . ?
O14 C22 O13 125.7(4) . . ?
O14 C22 C23 118.1(4) . . ?
O13 C22 C23 116.1(4) . . ?
C28 C23 C24 118.7(4) . . ?
C28 C23 C22 119.9(4) . . ?
C24 C23 C22 121.1(4) . . ?
C23 C24 C25 119.8(4) . . ?
C23 C24 H24A 120.1 . . ?
C25 C24 H24A 120.1 . . ?
C26 C25 C24 121.2(4) . . ?
C26 C25 H25A 119.4 . . ?
C24 C25 H25A 119.4 . . ?
C25 C26 C27 118.4(4) . . ?
C25 C26 C29 121.2(4) . . ?
C27 C26 C29 120.2(4) . . ?
C28 C27 C26 120.2(4) . . ?
C28 C27 N4 116.4(5) . . ?
C26 C27 N4 121.1(5) . . ?
C28 C27 H27A 119.9 . . ?
C26 C27 H27A 119.9 . . ?
O17 N4 O18 122.5(10) . . ?
O17 N4 C27 123.0(8) . . ?
O18 N4 C27 114.1(9) . . ?
C27 C28 C23 121.6(4) . . ?
C27 C28 N4B 117.1(5) . . ?
C23 C28 N4B 120.4(5) . . ?
C27 C28 H28A 119.2 . . ?
C23 C28 H28A 119.2 . . ?
O17B N4B O18B 124.9(9) . . ?
O17B N4B C28 120.6(8) . . ?
O18B N4B C28 114.4(8) . . ?
O16 C29 O15 126.7(4) . . ?
O16 C29 C26 117.5(4) . . ?
O15 C29 C26 115.8(4) . . ?
Cl2D Cl2 Cl2 60(2) 3_756 3_756 ?
Cl2D Cl2 Cl2D 110(3) 3_756 . ?
Cl2 Cl2 Cl2D 49.8(17) 3_756 . ?
Cl2 Cl2D Cl2 70(3) 3_756 . ?
Cl2 Cl2D Cl2D 37.5(17) 3_756 3_756 ?
Cl2 Cl2D Cl2D 32.3(16) . 3_756 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O2 C1 O1 5.3(5) . . . . ?
Eu1 O2 C1 C2 -174.4(4) . . . . ?
Eu2 O1 C1 O2 -168.5(3) . . . . ?
Eu1 O1 C1 O2 -5.3(5) . . . . ?
Eu2 O1 C1 C2 11.2(6) . . . . ?
Eu1 O1 C1 C2 174.4(4) . . . . ?
Eu2 O1 C1 Eu1 -163.1(3) . . . . ?
C6 N1 C2 C3 1.1(7) . . . . ?
Eu2 N1 C2 C3 178.0(4) . . . . ?
C6 N1 C2 C1 -178.9(4) . . . . ?
Eu2 N1 C2 C1 -2.0(5) . . . . ?
O2 C1 C2 N1 174.2(4) . . . . ?
O1 C1 C2 N1 -5.5(6) . . . . ?
O2 C1 C2 C3 -5.8(8) . . . . ?
O1 C1 C2 C3 174.5(5) . . . . ?
N1 C2 C3 C4 0.9(9) . . . . ?
C1 C2 C3 C4 -179.1(6) . . . . ?
C2 C3 C4 C5 -0.9(10) . . . . ?
C3 C4 C5 C6 -0.9(10) . . . . ?
C2 N1 C6 C5 -3.0(7) . . . . ?
Eu2 N1 C6 C5 -179.9(4) . . . . ?
C2 N1 C6 C7 176.3(4) . . . . ?
Eu2 N1 C6 C7 -0.7(5) . . . . ?
C4 C5 C6 N1 2.9(8) . . . . ?
C4 C5 C6 C7 -176.3(5) . . . . ?
Eu2 O3 C7 O4 -160.3(4) . . . . ?
Eu2 O3 C7 C6 23.6(5) . . . . ?
N1 C6 C7 O4 169.7(4) . . . . ?
C5 C6 C7 O4 -11.1(7) . . . . ?
N1 C6 C7 O3 -13.9(6) . . . . ?
C5 C6 C7 O3 165.3(5) . . . . ?
Eu1 O5 C8 O6 -173.9(4) . . . . ?
Eu1 O5 C8 C9 3.7(6) . . . . ?
C13 N2 C9 C10 1.9(7) . . . . ?
Eu1 N2 C9 C10 -174.4(4) . . . . ?
C13 N2 C9 C8 -178.8(4) . . . . ?
Eu1 N2 C9 C8 4.9(5) . . . . ?
O6 C8 C9 N2 172.4(5) . . . . ?
O5 C8 C9 N2 -5.4(6) . . . . ?
O6 C8 C9 C10 -8.4(8) . . . . ?
O5 C8 C9 C10 173.9(5) . . . . ?
N2 C9 C10 C11 -2.0(8) . . . . ?
C8 C9 C10 C11 178.8(5) . . . . ?
C9 C10 C11 C12 1.3(9) . . . . ?
C10 C11 C12 C13 -0.7(9) . . . . ?
C9 N2 C13 C12 -1.3(7) . . . . ?
Eu1 N2 C13 C12 175.1(4) . . . . ?
C9 N2 C13 C14 177.2(4) . . . . ?
Eu1 N2 C13 C14 -6.4(5) . . . . ?
C11 C12 C13 N2 0.7(8) . . . . ?
C11 C12 C13 C14 -177.7(5) . . . . ?
Eu3 O8 C14 O7 18.4(9) . . . . ?
Eu3 O8 C14 C13 -163.6(4) . . . . ?
Eu1 O7 C14 O8 175.9(4) . . . . ?
Eu1 O7 C14 C13 -2.1(6) . . . . ?
N2 C13 C14 O8 -172.6(4) . . . . ?
C12 C13 C14 O8 5.9(8) . . . . ?
N2 C13 C14 O7 5.5(6) . . . . ?
C12 C13 C14 O7 -176.0(5) . . . . ?
Eu1 O10 C15 O9 -2.0(4) 2_545 . . . ?
Eu1 O10 C15 C16 179.0(4) 2_545 . . . ?
Eu2 O9 C15 O10 -174.5(3) . . . . ?
Eu1 O9 C15 O10 2.1(5) 2_545 . . . ?
Eu2 O9 C15 C16 4.5(5) . . . . ?
Eu1 O9 C15 C16 -178.9(3) 2_545 . . . ?
Eu2 O9 C15 Eu1 -176.6(3) . . . 2_545 ?
C20 N3 C16 C17 -0.8(7) . . . . ?
Eu2 N3 C16 C17 -164.8(4) . . . . ?
C20 N3 C16 C15 176.0(4) . . . . ?
Eu2 N3 C16 C15 12.0(5) . . . . ?
O10 C15 C16 N3 168.4(4) . . . . ?
O9 C15 C16 N3 -10.6(6) . . . . ?
O10 C15 C16 C17 -14.8(8) . . . . ?
O9 C15 C16 C17 166.1(5) . . . . ?
N3 C16 C17 C18 2.1(9) . . . . ?
C15 C16 C17 C18 -174.4(6) . . . . ?
C16 C17 C18 C19 -2.0(11) . . . . ?
C17 C18 C19 C20 0.8(11) . . . . ?
C16 N3 C20 C19 -0.5(7) . . . . ?
Eu2 N3 C20 C19 164.0(4) . . . . ?
C16 N3 C20 C21 -177.7(4) . . . . ?
Eu2 N3 C20 C21 -13.2(5) . . . . ?
C18 C19 C20 N3 0.5(10) . . . . ?
C18 C19 C20 C21 177.5(6) . . . . ?
Eu3 O12 C21 O11 23.4(9) . . . . ?
Eu3 O12 C21 C20 -154.4(4) . . . . ?
Eu2 O11 C21 O12 -166.9(4) . . . . ?
Eu2 O11 C21 C20 10.9(6) . . . . ?
N3 C20 C21 O12 -179.7(4) . . . . ?
C19 C20 C21 O12 3.1(8) . . . . ?
N3 C20 C21 O11 2.3(7) . . . . ?
C19 C20 C21 O11 -174.9(5) . . . . ?
Eu2 O14 C22 O13 8.6(8) . . . . ?
Eu2 O14 C22 C23 -168.9(3) . . . . ?
Eu1 O13 C22 O14 -83.6(6) . . . . ?
Eu1 O13 C22 C23 93.9(5) . . . . ?
O14 C22 C23 C28 -147.1(5) . . . . ?
O13 C22 C23 C28 35.1(6) . . . . ?
O14 C22 C23 C24 39.1(7) . . . . ?
O13 C22 C23 C24 -138.6(5) . . . . ?
C28 C23 C24 C25 -3.1(7) . . . . ?
C22 C23 C24 C25 170.7(4) . . . . ?
C23 C24 C25 C26 2.6(7) . . . . ?
C24 C25 C26 C27 0.7(7) . . . . ?
C24 C25 C26 C29 176.0(4) . . . . ?
C25 C26 C27 C28 -3.4(8) . . . . ?
C29 C26 C27 C28 -178.7(5) . . . . ?
C25 C26 C27 N4 -165.5(7) . . . . ?
C29 C26 C27 N4 19.2(9) . . . . ?
C28 C27 N4 O17 -136.4(10) . . . . ?
C26 C27 N4 O17 26.4(14) . . . . ?
C28 C27 N4 O18 50.9(13) . . . . ?
C26 C27 N4 O18 -146.3(10) . . . . ?
C26 C27 C28 C23 2.8(8) . . . . ?
N4 C27 C28 C23 165.7(7) . . . . ?
C26 C27 C28 N4B 171.8(6) . . . . ?
C24 C23 C28 C27 0.5(8) . . . . ?
C22 C23 C28 C27 -173.4(5) . . . . ?
C24 C23 C28 N4B -168.1(6) . . . . ?
C22 C23 C28 N4B 17.9(8) . . . . ?
C27 C28 N4B O17B -131.2(9) . . . . ?
C23 C28 N4B O17B 37.9(12) . . . . ?
C27 C28 N4B O18B 50.8(12) . . . . ?
C23 C28 N4B O18B -140.1(9) . . . . ?
Eu2 O16 C29 O15 7.0(8) 1_655 . . . ?
Eu2 O16 C29 C26 -172.1(3) 1_655 . . . ?
Eu1 O15 C29 O16 -78.7(6) 2_645 . . . ?
Eu1 O15 C29 C26 100.4(4) 2_645 . . . ?
C25 C26 C29 O16 48.8(6) . . . . ?
C27 C26 C29 O16 -136.0(5) . . . . ?
C25 C26 C29 O15 -130.4(5) . . . . ?
C27 C26 C29 O15 44.8(6) . . . . ?
Cl2D Cl2 Cl2D Cl2 0.001(7) 3_756 . . 3_756 ?
Cl2 Cl2 Cl2D Cl2D -0.001(12) 3_756 . . 3_756 ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O1W H1D O2 0.817(10) 2.060(11) 2.873(5) 174(5) 2_545 yes
O2W H2C O4 0.817(10) 2.06(3) 2.768(5) 145(4) 1_655 yes
O2W H2D O4 0.817(10) 2.10(3) 2.861(5) 156(6) 3 yes
O3W H3C O10 0.821(10) 2.239(19) 3.051(6) 170(8) 3 yes
O3W H3D Cl2 0.817(10) 2.39(3) 3.170(16) 160(8) 2_655 yes
O3W H3D Cl2D 0.817(10) 2.49(6) 3.13(3) 136(8) 4_465 yes
O3W H3D Cl2C 0.817(10) 2.14(4) 2.89(3) 153(7) 4_465 yes
O4W H4D O5 0.825(10) 1.865(14) 2.684(4) 171(5) 4_565 yes
O5W H5D O18 0.827(10) 2.42(5) 2.989(12) 127(5) 2_655 yes
O5W H5D Cl2B 0.827(10) 1.99(4) 2.735(12) 149(7) 2_655 yes
O6W H6C O6 0.817(10) 1.885(16) 2.692(5) 169(6) 4_565 yes
O6W H6D Cl1 0.815(10) 2.34(2) 3.119(4) 159(6) 2_655 yes
C3 H3A Cl2C 0.93 2.73 3.28(3) 118.7 2_655 yes
C5 H5A O6W 0.93 2.59 3.450(7) 154.6 1_455 yes
C19 H19A O4 0.93 2.59 3.499(6) 165.4 3 yes

_refine_diff_density_max         0.911
_refine_diff_density_min         -0.691
_refine_diff_density_rms         0.160



