# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_d-rh(sin)[r-b(s-man)2]
_database_code_depnum_ccdc_archive 'CCDC 2341546'
loop_
_audit_author_name
_audit_author_address
'Pablo Salcedo'
;Universidad de Granada
Spain
;
_audit_update_record             
;
2024-09-02 deposited with the CCDC.	2024-09-11 downloaded from the CCDC.
;
_audit_creation_date             2024-09-02
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C38 H36 B N2 O6 Rh Si2, C H2 Cl2'
_chemical_formula_sum            'C39 H38 B Cl2 N2 O6 Rh Si2'
_chemical_formula_weight         871.51
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   8.5875(7)
_cell_length_b                   22.565(2)
_cell_length_c                   40.397(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7828.0(12)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    3477
_cell_measurement_temperature    150.00
_cell_measurement_theta_max      24.061
_cell_measurement_theta_min      2.755
_shelx_estimated_absorpt_T_max   0.999
_shelx_estimated_absorpt_T_min   0.821
_exptl_absorpt_coefficient_mu    0.683
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5133
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1288 before and 0.0933 after correction.
The Ratio of minimum to maximum transmission is 0.6886.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.479
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             3568
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.002
_exptl_crystal_size_min          0.002
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_av_unetI/netI     0.2058
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       50
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            16076
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.459
_diffrn_reflns_theta_min         2.017
_diffrn_ambient_temperature      150.00
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.801
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.993
_reflns_number_gt                7800
_reflns_number_total             16076
_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.258
_refine_diff_density_min         -1.425
_refine_diff_density_rms         0.140
_refine_ls_abs_structure_details 
;
 Flack x determined using 2265 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.06(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     964
_refine_ls_number_reflns         16076
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1984
_refine_ls_R_factor_gt           0.0658
_refine_ls_restrained_S_all      1.025
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0441P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1151
_refine_ls_wR_factor_ref         0.1665
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 1.0008(15)
 -0.0008(15)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3.a Ternary CH refined with riding coordinates:
 C29A(H29A), C37A(H37A), C29B(H29B), C37B(H37B)
3.b Secondary CH2 refined with riding coordinates:
 C1S(H1SA,H1SB), C2S(H2SA,H2SB)
3.c Aromatic/amide H refined with riding coordinates:
 C1A(H1A), C2A(H2A), C3A(H3A), C5A(H5A), C6A(H6A), C7A(H7A), C12A(H12A),
 C13A(H13A), C14A(H14A), C16A(H16A), C17A(H17A), C18A(H18A), C23A(H23A),
 C24A(H24A), C25A(H25A), C26A(H26A), C27A(H27A), C31A(H31A), C32A(H32A),
 C33A(H33A), C34A(H34A), C35A(H35A), C1B(H1B), C2B(H2B), C3B(H3B), C5B(H5B),
 C6B(H6B), C7B(H7B), C12B(H12B), C13B(H13B), C14B(H14B), C16B(H16B), C17B(H17B),
  C18B(H18B), C23B(H23B), C24B(H24B), C25B(H25B), C26B(H26B), C27B(H27B),
 C31B(H31B), C32B(H32B), C33B(H33B), C34B(H34B), C35B(H35B)
3.d Idealised Me refined as rotating group:
 C10A(H10A,H10B,H10C), C11A(H11A,H11B,H11C), C21A(H21A,H21B,H21C), C22A(H22A,
 H22B,H22C), C10B(H10D,H10E,H10F), C11B(H11D,H11E,H11F), C21B(H21D,H21E,H21F),
 C22B(H22D,H22E,H22F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1A Rh 0.26059(13) 0.52592(5) 0.82427(2) 0.0272(3) Uani 1 1 d . . . . .
Si1A Si 0.1183(5) 0.56402(19) 0.78236(9) 0.0290(10) Uani 1 1 d . . . . .
Si2A Si 0.4046(4) 0.47542(19) 0.78724(9) 0.0287(9) Uani 1 1 d . . . . .
B1A B 0.260(2) 0.5430(6) 0.8970(3) 0.027(3) Uani 1 1 d . . . . .
O1A O 0.3683(11) 0.5046(4) 0.8794(2) 0.028(2) Uani 1 1 d . . . . .
O2A O 0.1464(10) 0.5685(4) 0.8738(2) 0.025(2) Uani 1 1 d . . . . .
O3A O 0.3194(11) 0.6949(5) 0.9090(2) 0.045(3) Uani 1 1 d . . . . .
O4A O 0.3380(11) 0.5949(4) 0.9126(2) 0.032(2) Uani 1 1 d . . . . .
O5A O 0.1852(11) 0.5059(4) 0.9219(2) 0.031(2) Uani 1 1 d . . . . .
O6A O 0.1923(11) 0.4094(5) 0.9363(2) 0.040(3) Uani 1 1 d . . . . .
N1A N 0.4002(13) 0.6007(5) 0.8192(3) 0.028(3) Uani 1 1 d . . . . .
N2A N 0.1258(12) 0.4508(5) 0.8262(3) 0.026(3) Uani 1 1 d . . . . .
C1A C 0.5198(15) 0.6080(6) 0.8392(3) 0.027(3) Uani 1 1 d . . . . .
H1A H 0.538327 0.579537 0.856044 0.033 Uiso 1 1 calc R U . . .
C2A C 0.6208(17) 0.6567(6) 0.8364(3) 0.034(4) Uani 1 1 d . . . . .
H2A H 0.704305 0.661618 0.851544 0.041 Uiso 1 1 calc R U . . .
C3A C 0.5979(16) 0.6970(7) 0.8115(3) 0.037(4) Uani 1 1 d . . . . .
H3A H 0.666397 0.729774 0.809333 0.044 Uiso 1 1 calc R U . . .
C4A C 0.4724(17) 0.6901(6) 0.7890(3) 0.033(4) Uani 1 1 d . . . . .
C5A C 0.4428(18) 0.7297(7) 0.7626(4) 0.044(4) Uani 1 1 d . . . . .
H5A H 0.508571 0.762948 0.758912 0.052 Uiso 1 1 calc R U . . .
C6A C 0.3192(17) 0.7194(7) 0.7427(3) 0.037(4) Uani 1 1 d . . . . .
H6A H 0.299873 0.745807 0.724821 0.044 Uiso 1 1 calc R U . . .
C7A C 0.2175(18) 0.6707(6) 0.7474(3) 0.038(4) Uani 1 1 d . . . . .
H7A H 0.130659 0.665589 0.733111 0.045 Uiso 1 1 calc R U . . .
C8A C 0.2438(19) 0.6306(5) 0.7726(3) 0.029(3) Uani 1 1 d . . . . .
C9A C 0.3725(16) 0.6405(6) 0.7934(3) 0.022(3) Uani 1 1 d . . . . .
C10A C 0.0587(16) 0.5218(7) 0.7443(3) 0.038(4) Uani 1 1 d . . . . .
H10A H 0.151747 0.506441 0.733140 0.057 Uiso 1 1 calc R U . . .
H10B H 0.002215 0.548189 0.729250 0.057 Uiso 1 1 calc R U . . .
H10C H -0.008753 0.488650 0.750648 0.057 Uiso 1 1 calc R U . . .
C11A C -0.0683(17) 0.5908(7) 0.7999(4) 0.044(5) Uani 1 1 d . . . . .
H11A H -0.129253 0.556977 0.807892 0.067 Uiso 1 1 calc R U . . .
H11B H -0.127216 0.611814 0.782774 0.067 Uiso 1 1 calc R U . . .
H11C H -0.047107 0.617800 0.818386 0.067 Uiso 1 1 calc R U . . .
C12A C 0.0119(16) 0.4464(7) 0.8481(3) 0.036(4) Uani 1 1 d . . . . .
H12A H 0.000013 0.477280 0.863860 0.043 Uiso 1 1 calc R U . . .
C13A C -0.0932(16) 0.3982(6) 0.8492(3) 0.032(4) Uani 1 1 d . . . . .
H13A H -0.171770 0.396267 0.865726 0.038 Uiso 1 1 calc R U . . .
C14A C -0.0791(15) 0.3548(6) 0.8261(4) 0.031(3) Uani 1 1 d . . . . .
H14A H -0.149291 0.322237 0.826020 0.037 Uiso 1 1 calc R U . . .
C15A C 0.0409(18) 0.3584(7) 0.8021(3) 0.032(4) Uani 1 1 d . . . . .
C16A C 0.0561(18) 0.3171(7) 0.7765(4) 0.042(4) Uani 1 1 d . . . . .
H16A H -0.014147 0.284619 0.775399 0.051 Uiso 1 1 calc R U . . .
C17A C 0.1674(17) 0.3222(7) 0.7533(4) 0.038(4) Uani 1 1 d . . . . .
H17A H 0.172094 0.294383 0.735698 0.046 Uiso 1 1 calc R U . . .
C18A C 0.2778(17) 0.3688(6) 0.7548(3) 0.033(4) Uani 1 1 d . . . . .
H18A H 0.359295 0.370909 0.738985 0.039 Uiso 1 1 calc R U . . .
C19A C 0.2664(18) 0.4119(6) 0.7800(3) 0.030(3) Uani 1 1 d . . . . .
C20A C 0.1431(16) 0.4065(6) 0.8028(3) 0.027(4) Uani 1 1 d . . . . .
C21A C 0.5805(16) 0.4472(6) 0.8101(3) 0.037(4) Uani 1 1 d . . . . .
H21A H 0.548886 0.432591 0.831927 0.055 Uiso 1 1 calc R U . . .
H21B H 0.655880 0.479439 0.812762 0.055 Uiso 1 1 calc R U . . .
H21C H 0.628264 0.414857 0.797481 0.055 Uiso 1 1 calc R U . . .
C22A C 0.486(2) 0.5077(7) 0.7482(3) 0.037(4) Uani 1 1 d . . . . .
H22A H 0.511477 0.475700 0.732732 0.056 Uiso 1 1 calc R U . . .
H22B H 0.580700 0.530225 0.753352 0.056 Uiso 1 1 calc R U . . .
H22C H 0.408949 0.534127 0.738134 0.056 Uiso 1 1 calc R U . . .
C23A C -0.1007(18) 0.6154(7) 0.9127(4) 0.046(4) Uani 1 1 d . . . . .
H23A H -0.070682 0.575359 0.916224 0.055 Uiso 1 1 calc R U . . .
C24A C -0.2340(19) 0.6372(7) 0.9272(3) 0.046(4) Uani 1 1 d . . . . .
H24A H -0.295620 0.611593 0.940476 0.055 Uiso 1 1 calc R U . . .
C25A C -0.2804(19) 0.6950(6) 0.9230(4) 0.045(4) Uani 1 1 d . . . . .
H25A H -0.371394 0.709368 0.933715 0.053 Uiso 1 1 calc R U . . .
C26A C -0.1941(16) 0.7312(7) 0.9033(4) 0.043(4) Uani 1 1 d . . . . .
H26A H -0.226916 0.770903 0.899753 0.052 Uiso 1 1 calc R U . . .
C27A C -0.0578(17) 0.7108(7) 0.8883(4) 0.039(4) Uani 1 1 d . . . . .
H27A H 0.002355 0.736714 0.874846 0.047 Uiso 1 1 calc R U . . .
C28A C -0.0104(15) 0.6522(6) 0.8930(3) 0.027(3) Uani 1 1 d . . . . .
C29A C 0.1376(17) 0.6319(6) 0.8782(3) 0.032(4) Uani 1 1 d . . . . .
H29A H 0.154483 0.652151 0.856498 0.038 Uiso 1 1 calc R U . . .
C30A C 0.2733(17) 0.6459(7) 0.9017(3) 0.033(4) Uani 1 1 d . . . . .
C31A C 0.6356(16) 0.4721(7) 0.9152(3) 0.031(3) Uani 1 1 d . . . . .
H31A H 0.623019 0.511295 0.907007 0.038 Uiso 1 1 calc R U . . .
C32A C 0.7725(18) 0.4568(6) 0.9322(3) 0.037(4) Uani 1 1 d . . . . .
H32A H 0.853569 0.485068 0.934795 0.045 Uiso 1 1 calc R U . . .
C33A C 0.7889(16) 0.4009(7) 0.9451(3) 0.039(4) Uani 1 1 d . . . . .
H33A H 0.879066 0.390914 0.957531 0.046 Uiso 1 1 calc R U . . .
C34A C 0.6755(17) 0.3598(7) 0.9400(3) 0.040(4) Uani 1 1 d . . . . .
H34A H 0.687582 0.320985 0.948755 0.048 Uiso 1 1 calc R U . . .
C35A C 0.5436(16) 0.3739(6) 0.9224(3) 0.036(4) Uani 1 1 d . . . . .
H35A H 0.467116 0.344354 0.918483 0.043 Uiso 1 1 calc R U . . .
C36A C 0.5205(14) 0.4314(6) 0.9102(3) 0.021(3) Uani 1 1 d . . . . .
C37A C 0.3665(14) 0.4471(6) 0.8939(3) 0.023(3) Uani 1 1 d . . . . .
H37A H 0.339949 0.416797 0.876739 0.028 Uiso 1 1 calc R U . . .
C38A C 0.2373(17) 0.4504(6) 0.9195(3) 0.029(3) Uani 1 1 d . . . . .
Rh1B Rh 0.25236(16) 0.48544(4) 0.57506(2) 0.0272(3) Uani 1 1 d . . . . .
Si1B Si 0.1118(5) 0.53357(19) 0.53629(9) 0.0295(10) Uani 1 1 d . . . . .
Si2B Si 0.3903(5) 0.44191(19) 0.53400(9) 0.0301(10) Uani 1 1 d . . . . .
B1B B 0.251(2) 0.4772(7) 0.6481(3) 0.028(3) Uani 1 1 d . . . . .
O1B O 0.3596(10) 0.4475(4) 0.62633(19) 0.026(2) Uani 1 1 d . . . . .
O2B O 0.1416(10) 0.5134(4) 0.6289(2) 0.027(2) Uani 1 1 d . . . . .
O3B O 0.3216(10) 0.6169(4) 0.6810(2) 0.038(3) Uani 1 1 d . . . . .
O4B O 0.3288(10) 0.5198(4) 0.6710(2) 0.031(2) Uani 1 1 d . . . . .
O5B O 0.1736(10) 0.4298(4) 0.6675(2) 0.032(2) Uani 1 1 d . . . . .
O6B O 0.1968(10) 0.3299(5) 0.6714(2) 0.042(3) Uani 1 1 d . . . . .
N1B N 0.3886(13) 0.5606(5) 0.5751(3) 0.029(3) Uani 1 1 d . . . . .
N2B N 0.1121(12) 0.4123(5) 0.5717(2) 0.024(3) Uani 1 1 d . . . . .
C1B C 0.5091(16) 0.5638(6) 0.5966(3) 0.030(3) Uani 1 1 d . . . . .
H1B H 0.525539 0.532114 0.611686 0.037 Uiso 1 1 calc R U . . .
C2B C 0.6108(17) 0.6127(7) 0.5972(4) 0.037(4) Uani 1 1 d . . . . .
H2B H 0.691468 0.614723 0.613232 0.044 Uiso 1 1 calc R U . . .
C3B C 0.5931(16) 0.6573(7) 0.5746(3) 0.035(4) Uani 1 1 d . . . . .
H3B H 0.662825 0.690026 0.574451 0.043 Uiso 1 1 calc R U . . .
C4B C 0.4698(16) 0.6541(6) 0.5517(4) 0.034(4) Uani 1 1 d . . . . .
C5B C 0.4489(17) 0.6987(6) 0.5272(3) 0.037(4) Uani 1 1 d . . . . .
H5B H 0.517689 0.731614 0.525946 0.044 Uiso 1 1 calc R U . . .
C6B C 0.3254(19) 0.6931(7) 0.5053(4) 0.047(5) Uani 1 1 d . . . . .
H6B H 0.310131 0.722882 0.488981 0.056 Uiso 1 1 calc R U . . .
C7B C 0.2227(18) 0.6449(6) 0.5064(3) 0.033(4) Uani 1 1 d . . . . .
H7B H 0.140192 0.642309 0.490773 0.040 Uiso 1 1 calc R U . . .
C8B C 0.2408(19) 0.6011(5) 0.5301(3) 0.030(3) Uani 1 1 d . . . . .
C9B C 0.3654(15) 0.6055(6) 0.5524(3) 0.025(3) Uani 1 1 d . . . . .
C10B C 0.0465(18) 0.5014(7) 0.4959(3) 0.038(4) Uani 1 1 d . . . . .
H10D H 0.137271 0.487303 0.483524 0.057 Uiso 1 1 calc R U . . .
H10E H -0.007639 0.531886 0.483033 0.057 Uiso 1 1 calc R U . . .
H10F H -0.024387 0.468197 0.500093 0.057 Uiso 1 1 calc R U . . .
C11B C -0.0732(15) 0.5591(7) 0.5569(3) 0.042(4) Uani 1 1 d . . . . .
H11D H -0.136405 0.524556 0.562923 0.062 Uiso 1 1 calc R U . . .
H11E H -0.131913 0.584383 0.541670 0.062 Uiso 1 1 calc R U . . .
H11F H -0.047444 0.581592 0.576948 0.062 Uiso 1 1 calc R U . . .
C12B C -0.0006(17) 0.4037(7) 0.5933(3) 0.033(4) Uani 1 1 d . . . . .
H12B H -0.010245 0.430787 0.611141 0.039 Uiso 1 1 calc R U . . .
C13B C -0.1094(17) 0.3559(7) 0.5914(4) 0.038(4) Uani 1 1 d . . . . .
H13B H -0.185253 0.350237 0.608193 0.046 Uiso 1 1 calc R U . . .
C14B C -0.1021(17) 0.3189(7) 0.5652(3) 0.037(4) Uani 1 1 d . . . . .
H14B H -0.175895 0.287792 0.562843 0.045 Uiso 1 1 calc R U . . .
C15B C 0.0179(16) 0.3269(7) 0.5409(3) 0.031(3) Uani 1 1 d . . . . .
C16B C 0.0264(18) 0.2912(7) 0.5126(3) 0.041(4) Uani 1 1 d . . . . .
H16B H -0.045523 0.259664 0.509580 0.050 Uiso 1 1 calc R U . . .
C17B C 0.1399(18) 0.3020(7) 0.4892(3) 0.042(4) Uani 1 1 d . . . . .
H17B H 0.141126 0.279084 0.469454 0.051 Uiso 1 1 calc R U . . .
C18B C 0.253(2) 0.3457(6) 0.4938(3) 0.035(3) Uani 1 1 d . . . . .
H18B H 0.333217 0.350546 0.477826 0.043 Uiso 1 1 calc R U . . .
C19B C 0.2484(19) 0.3829(6) 0.5220(3) 0.030(3) Uani 1 1 d . . . . .
C20B C 0.1256(17) 0.3736(7) 0.5450(3) 0.035(4) Uani 1 1 d . . . . .
C21B C 0.5610(17) 0.4035(7) 0.5537(4) 0.050(4) Uani 1 1 d . . . . .
H21D H 0.634246 0.433109 0.562130 0.074 Uiso 1 1 calc R U . . .
H21E H 0.613294 0.378672 0.537132 0.074 Uiso 1 1 calc R U . . .
H21F H 0.524419 0.378579 0.571952 0.074 Uiso 1 1 calc R U . . .
C22B C 0.4735(16) 0.4839(7) 0.4983(3) 0.038(4) Uani 1 1 d . . . . .
H22D H 0.394343 0.510774 0.489386 0.057 Uiso 1 1 calc R U . . .
H22E H 0.506371 0.456079 0.481091 0.057 Uiso 1 1 calc R U . . .
H22F H 0.563561 0.506991 0.505846 0.057 Uiso 1 1 calc R U . . .
C23B C -0.1229(16) 0.5496(6) 0.6640(3) 0.030(3) Uani 1 1 d . . . . .
H23B H -0.108951 0.509440 0.657545 0.036 Uiso 1 1 calc R U . . .
C24B C -0.2608(18) 0.5670(6) 0.6810(3) 0.034(3) Uani 1 1 d . . . . .
H24B H -0.339431 0.538748 0.685913 0.040 Uiso 1 1 calc R U . . .
C25B C -0.2789(18) 0.6260(7) 0.6904(3) 0.037(4) Uani 1 1 d . . . . .
H25B H -0.368993 0.638250 0.702147 0.045 Uiso 1 1 calc R U . . .
C26B C -0.1662(18) 0.6660(7) 0.6824(4) 0.045(4) Uani 1 1 d . . . . .
H26B H -0.179522 0.706228 0.688673 0.054 Uiso 1 1 calc R U . . .
C27B C -0.0333(16) 0.6498(7) 0.6656(3) 0.038(4) Uani 1 1 d . . . . .
H27B H 0.042479 0.678685 0.659923 0.045 Uiso 1 1 calc R U . . .
C28B C -0.0111(15) 0.5905(6) 0.6570(3) 0.024(3) Uani 1 1 d . . . . .
C29B C 0.1418(16) 0.5729(6) 0.6415(3) 0.031(4) Uani 1 1 d . . . . .
H29B H 0.166828 0.601018 0.623146 0.037 Uiso 1 1 calc R U . . .
C30B C 0.2723(17) 0.5737(7) 0.6664(3) 0.032(4) Uani 1 1 d . . . . .
C31B C 0.6136(18) 0.4082(7) 0.6675(4) 0.044(4) Uani 1 1 d . . . . .
H31B H 0.581580 0.448308 0.669745 0.052 Uiso 1 1 calc R U . . .
C32B C 0.749(2) 0.3888(7) 0.6817(4) 0.051(4) Uani 1 1 d . . . . .
H32B H 0.810873 0.416655 0.693381 0.062 Uiso 1 1 calc R U . . .
C33B C 0.7979(17) 0.3319(8) 0.6800(4) 0.050(5) Uani 1 1 d . . . . .
H33B H 0.891080 0.319900 0.690788 0.060 Uiso 1 1 calc R U . . .
C34B C 0.7095(17) 0.2916(7) 0.6623(4) 0.046(4) Uani 1 1 d . . . . .
H34B H 0.742481 0.251535 0.660839 0.055 Uiso 1 1 calc R U . . .
C35B C 0.5739(17) 0.3091(6) 0.6466(4) 0.039(4) Uani 1 1 d . . . . .
H35B H 0.515431 0.281499 0.633917 0.046 Uiso 1 1 calc R U . . .
C36B C 0.5237(16) 0.3677(6) 0.6496(3) 0.031(4) Uani 1 1 d . . . . .
C37B C 0.3696(15) 0.3855(6) 0.6351(3) 0.030(3) Uani 1 1 d . . . . .
H37B H 0.347889 0.360757 0.615031 0.036 Uiso 1 1 calc R U . . .
C38B C 0.2382(19) 0.3774(7) 0.6601(3) 0.034(3) Uani 1 1 d . . . . .
C1S C 0.0366(17) 0.2918(7) 0.9131(3) 0.043(4) Uani 1 1 d . . . . .
H1SA H -0.058004 0.309248 0.902994 0.052 Uiso 1 1 calc R U . . .
H1SB H 0.073772 0.319418 0.930393 0.052 Uiso 1 1 calc R U . . .
Cl1S Cl -0.0128(5) 0.2236(2) 0.93169(11) 0.0600(12) Uani 1 1 d . . . . .
Cl2S Cl 0.1795(5) 0.2850(2) 0.88278(10) 0.0560(12) Uani 1 1 d . . . . .
C2S C 0.4727(18) 0.7305(7) 0.6537(4) 0.049(4) Uani 1 1 d . . . . .
H2SA H 0.566281 0.714111 0.642756 0.059 Uiso 1 1 calc R U . . .
H2SB H 0.438270 0.701652 0.670678 0.059 Uiso 1 1 calc R U . . .
Cl3S Cl 0.5225(5) 0.79770(19) 0.67340(11) 0.0590(12) Uani 1 1 d . . . . .
Cl4S Cl 0.3243(5) 0.7392(2) 0.62420(10) 0.0611(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1A Si1A 2.258(4) . ?
Rh1A Si2A 2.251(4) . ?
Rh1A O1A 2.459(8) . ?
Rh1A O2A 2.428(8) . ?
Rh1A N1A 2.080(11) . ?
Rh1A N2A 2.053(11) . ?
Si1A C8A 1.891(15) . ?
Si1A C10A 1.880(14) . ?
Si1A C11A 1.854(15) . ?
Si2A C19A 1.883(15) . ?
Si2A C21A 1.881(14) . ?
Si2A C22A 1.873(14) . ?
B1A O1A 1.460(17) . ?
B1A O2A 1.468(17) . ?
B1A O4A 1.490(17) . ?
B1A O5A 1.455(16) . ?
O1A C37A 1.424(14) . ?
O2A C29A 1.442(16) . ?
O3A C30A 1.211(16) . ?
O4A C30A 1.351(16) . ?
O5A C38A 1.333(15) . ?
O6A C38A 1.212(15) . ?
N1A C1A 1.317(16) . ?
N1A C9A 1.397(16) . ?
N2A C12A 1.322(16) . ?
N2A C20A 1.384(16) . ?
C1A H1A 0.9500 . ?
C1A C2A 1.404(18) . ?
C2A H2A 0.9500 . ?
C2A C3A 1.368(18) . ?
C3A H3A 0.9500 . ?
C3A C4A 1.418(19) . ?
C4A C5A 1.417(19) . ?
C4A C9A 1.420(18) . ?
C5A H5A 0.9500 . ?
C5A C6A 1.352(19) . ?
C6A H6A 0.9500 . ?
C6A C7A 1.417(19) . ?
C7A H7A 0.9500 . ?
C7A C8A 1.382(17) . ?
C8A C9A 1.406(19) . ?
C10A H10A 0.9800 . ?
C10A H10B 0.9800 . ?
C10A H10C 0.9800 . ?
C11A H11A 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11C 0.9800 . ?
C12A H12A 0.9500 . ?
C12A C13A 1.414(18) . ?
C13A H13A 0.9500 . ?
C13A C14A 1.359(18) . ?
C14A H14A 0.9500 . ?
C14A C15A 1.417(19) . ?
C15A C16A 1.399(19) . ?
C15A C20A 1.40(2) . ?
C16A H16A 0.9500 . ?
C16A C17A 1.342(19) . ?
C17A H17A 0.9500 . ?
C17A C18A 1.416(19) . ?
C18A H18A 0.9500 . ?
C18A C19A 1.411(17) . ?
C19A C20A 1.409(19) . ?
C21A H21A 0.9800 . ?
C21A H21B 0.9800 . ?
C21A H21C 0.9800 . ?
C22A H22A 0.9800 . ?
C22A H22B 0.9800 . ?
C22A H22C 0.9800 . ?
C23A H23A 0.9500 . ?
C23A C24A 1.38(2) . ?
C23A C28A 1.387(19) . ?
C24A H24A 0.9500 . ?
C24A C25A 1.373(19) . ?
C25A H25A 0.9500 . ?
C25A C26A 1.361(19) . ?
C26A H26A 0.9500 . ?
C26A C27A 1.396(19) . ?
C27A H27A 0.9500 . ?
C27A C28A 1.398(19) . ?
C28A C29A 1.478(19) . ?
C29A H29A 1.0000 . ?
C29A C30A 1.535(19) . ?
C31A H31A 0.9500 . ?
C31A C32A 1.406(19) . ?
C31A C36A 1.364(18) . ?
C32A H32A 0.9500 . ?
C32A C33A 1.372(18) . ?
C33A H33A 0.9500 . ?
C33A C34A 1.359(19) . ?
C34A H34A 0.9500 . ?
C34A C35A 1.375(19) . ?
C35A H35A 0.9500 . ?
C35A C36A 1.401(18) . ?
C36A C37A 1.520(17) . ?
C37A H37A 1.0000 . ?
C37A C38A 1.519(18) . ?
Rh1B Si1B 2.256(4) . ?
Rh1B Si2B 2.263(4) . ?
Rh1B O1B 2.423(8) . ?
Rh1B O2B 2.456(8) . ?
Rh1B N1B 2.060(12) . ?
Rh1B N2B 2.047(11) . ?
Si1B C8B 1.901(15) . ?
Si1B C10B 1.871(14) . ?
Si1B C11B 1.884(13) . ?
Si2B C19B 1.870(15) . ?
Si2B C21B 1.879(15) . ?
Si2B C22B 1.867(14) . ?
B1B O1B 1.448(17) . ?
B1B O2B 1.465(18) . ?
B1B O4B 1.495(16) . ?
B1B O5B 1.482(17) . ?
O1B C37B 1.446(15) . ?
O2B C29B 1.437(16) . ?
O3B C30B 1.215(15) . ?
O4B C30B 1.321(16) . ?
O5B C38B 1.340(16) . ?
O6B C38B 1.215(15) . ?
N1B C1B 1.352(16) . ?
N1B C9B 1.381(16) . ?
N2B C12B 1.316(16) . ?
N2B C20B 1.395(16) . ?
C1B H1B 0.9500 . ?
C1B C2B 1.409(19) . ?
C2B H2B 0.9500 . ?
C2B C3B 1.366(19) . ?
C3B H3B 0.9500 . ?
C3B C4B 1.410(18) . ?
C4B C5B 1.421(18) . ?
C4B C9B 1.417(18) . ?
C5B H5B 0.9500 . ?
C5B C6B 1.39(2) . ?
C6B H6B 0.9500 . ?
C6B C7B 1.40(2) . ?
C7B H7B 0.9500 . ?
C7B C8B 1.386(16) . ?
C8B C9B 1.403(19) . ?
C10B H10D 0.9800 . ?
C10B H10E 0.9800 . ?
C10B H10F 0.9800 . ?
C11B H11D 0.9800 . ?
C11B H11E 0.9800 . ?
C11B H11F 0.9800 . ?
C12B H12B 0.9500 . ?
C12B C13B 1.429(19) . ?
C13B H13B 0.9500 . ?
C13B C14B 1.348(18) . ?
C14B H14B 0.9500 . ?
C14B C15B 1.435(18) . ?
C15B C16B 1.400(18) . ?
C15B C20B 1.41(2) . ?
C16B H16B 0.9500 . ?
C16B C17B 1.380(19) . ?
C17B H17B 0.9500 . ?
C17B C18B 1.40(2) . ?
C18B H18B 0.9500 . ?
C18B C19B 1.415(16) . ?
C19B C20B 1.421(19) . ?
C21B H21D 0.9800 . ?
C21B H21E 0.9800 . ?
C21B H21F 0.9800 . ?
C22B H22D 0.9800 . ?
C22B H22E 0.9800 . ?
C22B H22F 0.9800 . ?
C23B H23B 0.9500 . ?
C23B C24B 1.424(18) . ?
C23B C28B 1.363(18) . ?
C24B H24B 0.9500 . ?
C24B C25B 1.392(18) . ?
C25B H25B 0.9500 . ?
C25B C26B 1.36(2) . ?
C26B H26B 0.9500 . ?
C26B C27B 1.377(19) . ?
C27B H27B 0.9500 . ?
C27B C28B 1.394(18) . ?
C28B C29B 1.507(18) . ?
C29B H29B 1.0000 . ?
C29B C30B 1.504(19) . ?
C31B H31B 0.9500 . ?
C31B C32B 1.36(2) . ?
C31B C36B 1.398(19) . ?
C32B H32B 0.9500 . ?
C32B C33B 1.354(19) . ?
C33B H33B 0.9500 . ?
C33B C34B 1.38(2) . ?
C34B H34B 0.9500 . ?
C34B C35B 1.383(19) . ?
C35B H35B 0.9500 . ?
C35B C36B 1.396(19) . ?
C36B C37B 1.503(18) . ?
C37B H37B 1.0000 . ?
C37B C38B 1.528(19) . ?
C1S H1SA 0.9900 . ?
C1S H1SB 0.9900 . ?
C1S Cl1S 1.765(15) . ?
C1S Cl2S 1.740(14) . ?
C2S H2SA 0.9900 . ?
C2S H2SB 0.9900 . ?
C2S Cl3S 1.764(15) . ?
C2S Cl4S 1.756(14) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1A Rh1A O1A 163.2(2) . . ?
Si1A Rh1A O2A 104.4(2) . . ?
Si2A Rh1A Si1A 89.52(15) . . ?
Si2A Rh1A O1A 107.2(2) . . ?
Si2A Rh1A O2A 166.1(2) . . ?
O2A Rh1A O1A 58.8(3) . . ?
N1A Rh1A Si1A 85.9(3) . . ?
N1A Rh1A Si2A 91.6(3) . . ?
N1A Rh1A O1A 91.8(4) . . ?
N1A Rh1A O2A 89.6(4) . . ?
N2A Rh1A Si1A 92.1(3) . . ?
N2A Rh1A Si2A 85.2(3) . . ?
N2A Rh1A O1A 91.0(4) . . ?
N2A Rh1A O2A 93.9(4) . . ?
N2A Rh1A N1A 176.3(4) . . ?
C8A Si1A Rh1A 98.6(4) . . ?
C10A Si1A Rh1A 124.6(5) . . ?
C10A Si1A C8A 112.9(6) . . ?
C11A Si1A Rh1A 107.8(5) . . ?
C11A Si1A C8A 108.2(7) . . ?
C11A Si1A C10A 104.1(7) . . ?
C19A Si2A Rh1A 98.2(5) . . ?
C21A Si2A Rh1A 106.6(5) . . ?
C21A Si2A C19A 108.9(6) . . ?
C22A Si2A Rh1A 124.6(5) . . ?
C22A Si2A C19A 113.7(6) . . ?
C22A Si2A C21A 104.1(7) . . ?
O1A B1A O2A 110.2(10) . . ?
O1A B1A O4A 112.5(12) . . ?
O2A B1A O4A 105.1(10) . . ?
O5A B1A O1A 106.0(10) . . ?
O5A B1A O2A 112.1(12) . . ?
O5A B1A O4A 111.1(10) . . ?
B1A O1A Rh1A 94.9(7) . . ?
C37A O1A Rh1A 123.1(7) . . ?
C37A O1A B1A 109.5(9) . . ?
B1A O2A Rh1A 96.0(7) . . ?
C29A O2A Rh1A 121.0(7) . . ?
C29A O2A B1A 110.2(10) . . ?
C30A O4A B1A 110.2(11) . . ?
C38A O5A B1A 110.1(10) . . ?
C1A N1A Rh1A 119.4(9) . . ?
C1A N1A C9A 120.6(12) . . ?
C9A N1A Rh1A 119.9(9) . . ?
C12A N2A Rh1A 120.3(10) . . ?
C12A N2A C20A 118.7(12) . . ?
C20A N2A Rh1A 120.7(9) . . ?
N1A C1A H1A 119.0 . . ?
N1A C1A C2A 122.0(13) . . ?
C2A C1A H1A 119.0 . . ?
C1A C2A H2A 120.3 . . ?
C3A C2A C1A 119.3(14) . . ?
C3A C2A H2A 120.3 . . ?
C2A C3A H3A 119.8 . . ?
C2A C3A C4A 120.5(14) . . ?
C4A C3A H3A 119.8 . . ?
C3A C4A C9A 117.7(13) . . ?
C5A C4A C3A 123.4(14) . . ?
C5A C4A C9A 118.9(14) . . ?
C4A C5A H5A 120.6 . . ?
C6A C5A C4A 118.7(15) . . ?
C6A C5A H5A 120.6 . . ?
C5A C6A H6A 118.7 . . ?
C5A C6A C7A 122.5(14) . . ?
C7A C6A H6A 118.7 . . ?
C6A C7A H7A 119.8 . . ?
C8A C7A C6A 120.4(14) . . ?
C8A C7A H7A 119.8 . . ?
C7A C8A Si1A 125.5(12) . . ?
C7A C8A C9A 117.7(14) . . ?
C9A C8A Si1A 116.8(9) . . ?
N1A C9A C4A 119.8(13) . . ?
N1A C9A C8A 118.4(12) . . ?
C8A C9A C4A 121.7(12) . . ?
Si1A C10A H10A 109.5 . . ?
Si1A C10A H10B 109.5 . . ?
Si1A C10A H10C 109.5 . . ?
H10A C10A H10B 109.5 . . ?
H10A C10A H10C 109.5 . . ?
H10B C10A H10C 109.5 . . ?
Si1A C11A H11A 109.5 . . ?
Si1A C11A H11B 109.5 . . ?
Si1A C11A H11C 109.5 . . ?
H11A C11A H11B 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
N2A C12A H12A 118.2 . . ?
N2A C12A C13A 123.5(14) . . ?
C13A C12A H12A 118.2 . . ?
C12A C13A H13A 120.8 . . ?
C14A C13A C12A 118.4(14) . . ?
C14A C13A H13A 120.8 . . ?
C13A C14A H14A 120.2 . . ?
C13A C14A C15A 119.6(13) . . ?
C15A C14A H14A 120.2 . . ?
C16A C15A C14A 122.4(14) . . ?
C20A C15A C14A 119.1(13) . . ?
C20A C15A C16A 118.4(14) . . ?
C15A C16A H16A 119.2 . . ?
C17A C16A C15A 121.6(15) . . ?
C17A C16A H16A 119.2 . . ?
C16A C17A H17A 119.7 . . ?
C16A C17A C18A 120.7(14) . . ?
C18A C17A H17A 119.7 . . ?
C17A C18A H18A 120.1 . . ?
C19A C18A C17A 119.8(14) . . ?
C19A C18A H18A 120.1 . . ?
C18A C19A Si2A 126.4(12) . . ?
C20A C19A Si2A 116.0(10) . . ?
C20A C19A C18A 117.6(14) . . ?
N2A C20A C15A 120.6(13) . . ?
N2A C20A C19A 117.6(13) . . ?
C15A C20A C19A 121.7(13) . . ?
Si2A C21A H21A 109.5 . . ?
Si2A C21A H21B 109.5 . . ?
Si2A C21A H21C 109.5 . . ?
H21A C21A H21B 109.5 . . ?
H21A C21A H21C 109.5 . . ?
H21B C21A H21C 109.5 . . ?
Si2A C22A H22A 109.5 . . ?
Si2A C22A H22B 109.5 . . ?
Si2A C22A H22C 109.5 . . ?
H22A C22A H22B 109.5 . . ?
H22A C22A H22C 109.5 . . ?
H22B C22A H22C 109.5 . . ?
C24A C23A H23A 120.2 . . ?
C24A C23A C28A 119.6(15) . . ?
C28A C23A H23A 120.2 . . ?
C23A C24A H24A 119.0 . . ?
C25A C24A C23A 121.9(15) . . ?
C25A C24A H24A 119.0 . . ?
C24A C25A H25A 120.5 . . ?
C26A C25A C24A 118.9(16) . . ?
C26A C25A H25A 120.5 . . ?
C25A C26A H26A 119.6 . . ?
C25A C26A C27A 120.9(15) . . ?
C27A C26A H26A 119.6 . . ?
C26A C27A H27A 120.1 . . ?
C26A C27A C28A 119.8(15) . . ?
C28A C27A H27A 120.1 . . ?
C23A C28A C27A 118.8(13) . . ?
C23A C28A C29A 121.8(13) . . ?
C27A C28A C29A 119.3(13) . . ?
O2A C29A C28A 113.7(12) . . ?
O2A C29A H29A 109.7 . . ?
O2A C29A C30A 103.9(11) . . ?
C28A C29A H29A 109.7 . . ?
C28A C29A C30A 109.8(11) . . ?
C30A C29A H29A 109.7 . . ?
O3A C30A O4A 124.2(13) . . ?
O3A C30A C29A 126.0(14) . . ?
O4A C30A C29A 109.8(12) . . ?
C32A C31A H31A 119.6 . . ?
C36A C31A H31A 119.6 . . ?
C36A C31A C32A 120.8(14) . . ?
C31A C32A H32A 120.1 . . ?
C33A C32A C31A 119.8(14) . . ?
C33A C32A H32A 120.1 . . ?
C32A C33A H33A 120.1 . . ?
C34A C33A C32A 119.8(14) . . ?
C34A C33A H33A 120.1 . . ?
C33A C34A H34A 119.7 . . ?
C33A C34A C35A 120.6(15) . . ?
C35A C34A H34A 119.7 . . ?
C34A C35A H35A 119.6 . . ?
C34A C35A C36A 120.9(14) . . ?
C36A C35A H35A 119.6 . . ?
C31A C36A C35A 118.0(13) . . ?
C31A C36A C37A 122.5(13) . . ?
C35A C36A C37A 119.4(12) . . ?
O1A C37A C36A 112.4(11) . . ?
O1A C37A H37A 109.9 . . ?
O1A C37A C38A 104.0(10) . . ?
C36A C37A H37A 109.9 . . ?
C38A C37A C36A 110.6(10) . . ?
C38A C37A H37A 109.9 . . ?
O5A C38A C37A 110.0(11) . . ?
O6A C38A O5A 124.8(13) . . ?
O6A C38A C37A 125.2(13) . . ?
Si1B Rh1B Si2B 88.87(15) . . ?
Si1B Rh1B O1B 165.2(2) . . ?
Si1B Rh1B O2B 106.5(2) . . ?
Si2B Rh1B O1B 105.9(2) . . ?
Si2B Rh1B O2B 164.4(2) . . ?
O1B Rh1B O2B 58.7(3) . . ?
N1B Rh1B Si1B 84.7(3) . . ?
N1B Rh1B Si2B 93.5(3) . . ?
N1B Rh1B O1B 94.2(4) . . ?
N1B Rh1B O2B 90.4(4) . . ?
N2B Rh1B Si1B 91.6(3) . . ?
N2B Rh1B Si2B 84.8(3) . . ?
N2B Rh1B O1B 89.7(4) . . ?
N2B Rh1B O2B 92.2(4) . . ?
N2B Rh1B N1B 176.0(4) . . ?
C8B Si1B Rh1B 99.5(4) . . ?
C10B Si1B Rh1B 125.4(5) . . ?
C10B Si1B C8B 111.8(6) . . ?
C10B Si1B C11B 104.6(7) . . ?
C11B Si1B Rh1B 106.9(5) . . ?
C11B Si1B C8B 107.7(7) . . ?
C19B Si2B Rh1B 99.1(4) . . ?
C19B Si2B C21B 106.8(7) . . ?
C21B Si2B Rh1B 107.4(5) . . ?
C22B Si2B Rh1B 123.1(5) . . ?
C22B Si2B C19B 114.2(6) . . ?
C22B Si2B C21B 105.2(7) . . ?
O1B B1B O2B 110.5(9) . . ?
O1B B1B O4B 112.6(12) . . ?
O1B B1B O5B 106.1(11) . . ?
O2B B1B O4B 104.8(11) . . ?
O2B B1B O5B 113.4(12) . . ?
O5B B1B O4B 109.7(9) . . ?
B1B O1B Rh1B 96.3(7) . . ?
C37B O1B Rh1B 124.9(8) . . ?
C37B O1B B1B 109.7(10) . . ?
B1B O2B Rh1B 94.5(7) . . ?
C29B O2B Rh1B 123.7(8) . . ?
C29B O2B B1B 109.5(10) . . ?
C30B O4B B1B 109.8(11) . . ?
C38B O5B B1B 109.5(11) . . ?
C1B N1B Rh1B 118.6(9) . . ?
C1B N1B C9B 119.8(12) . . ?
C9B N1B Rh1B 121.5(9) . . ?
C12B N2B Rh1B 120.6(9) . . ?
C12B N2B C20B 118.7(12) . . ?
C20B N2B Rh1B 120.5(9) . . ?
N1B C1B H1B 119.1 . . ?
N1B C1B C2B 121.8(14) . . ?
C2B C1B H1B 119.1 . . ?
C1B C2B H2B 120.1 . . ?
C3B C2B C1B 119.8(14) . . ?
C3B C2B H2B 120.1 . . ?
C2B C3B H3B 120.5 . . ?
C2B C3B C4B 119.0(14) . . ?
C4B C3B H3B 120.5 . . ?
C3B C4B C5B 121.1(13) . . ?
C3B C4B C9B 120.0(14) . . ?
C9B C4B C5B 118.9(14) . . ?
C4B C5B H5B 120.8 . . ?
C6B C5B C4B 118.4(14) . . ?
C6B C5B H5B 120.8 . . ?
C5B C6B H6B 118.9 . . ?
C5B C6B C7B 122.2(14) . . ?
C7B C6B H6B 118.9 . . ?
C6B C7B H7B 119.8 . . ?
C8B C7B C6B 120.3(14) . . ?
C8B C7B H7B 119.8 . . ?
C7B C8B Si1B 126.7(12) . . ?
C7B C8B C9B 118.6(14) . . ?
C9B C8B Si1B 114.6(9) . . ?
N1B C9B C4B 119.5(13) . . ?
N1B C9B C8B 119.0(12) . . ?
C8B C9B C4B 121.6(13) . . ?
Si1B C10B H10D 109.5 . . ?
Si1B C10B H10E 109.5 . . ?
Si1B C10B H10F 109.5 . . ?
H10D C10B H10E 109.5 . . ?
H10D C10B H10F 109.5 . . ?
H10E C10B H10F 109.5 . . ?
Si1B C11B H11D 109.5 . . ?
Si1B C11B H11E 109.5 . . ?
Si1B C11B H11F 109.5 . . ?
H11D C11B H11E 109.5 . . ?
H11D C11B H11F 109.5 . . ?
H11E C11B H11F 109.5 . . ?
N2B C12B H12B 118.1 . . ?
N2B C12B C13B 123.8(13) . . ?
C13B C12B H12B 118.1 . . ?
C12B C13B H13B 120.7 . . ?
C14B C13B C12B 118.6(14) . . ?
C14B C13B H13B 120.7 . . ?
C13B C14B H14B 120.3 . . ?
C13B C14B C15B 119.4(14) . . ?
C15B C14B H14B 120.3 . . ?
C16B C15B C14B 121.5(14) . . ?
C16B C15B C20B 119.4(13) . . ?
C20B C15B C14B 119.0(13) . . ?
C15B C16B H16B 120.2 . . ?
C17B C16B C15B 119.7(14) . . ?
C17B C16B H16B 120.2 . . ?
C16B C17B H17B 119.2 . . ?
C16B C17B C18B 121.7(14) . . ?
C18B C17B H17B 119.2 . . ?
C17B C18B H18B 119.8 . . ?
C17B C18B C19B 120.4(15) . . ?
C19B C18B H18B 119.8 . . ?
C18B C19B Si2B 127.9(12) . . ?
C18B C19B C20B 117.3(14) . . ?
C20B C19B Si2B 114.7(9) . . ?
N2B C20B C15B 120.2(13) . . ?
N2B C20B C19B 118.4(13) . . ?
C15B C20B C19B 121.3(13) . . ?
Si2B C21B H21D 109.5 . . ?
Si2B C21B H21E 109.5 . . ?
Si2B C21B H21F 109.5 . . ?
H21D C21B H21E 109.5 . . ?
H21D C21B H21F 109.5 . . ?
H21E C21B H21F 109.5 . . ?
Si2B C22B H22D 109.5 . . ?
Si2B C22B H22E 109.5 . . ?
Si2B C22B H22F 109.5 . . ?
H22D C22B H22E 109.5 . . ?
H22D C22B H22F 109.5 . . ?
H22E C22B H22F 109.5 . . ?
C24B C23B H23B 120.0 . . ?
C28B C23B H23B 120.0 . . ?
C28B C23B C24B 119.9(13) . . ?
C23B C24B H24B 120.4 . . ?
C25B C24B C23B 119.2(14) . . ?
C25B C24B H24B 120.4 . . ?
C24B C25B H25B 120.3 . . ?
C26B C25B C24B 119.4(14) . . ?
C26B C25B H25B 120.3 . . ?
C25B C26B H26B 119.0 . . ?
C25B C26B C27B 122.0(15) . . ?
C27B C26B H26B 119.0 . . ?
C26B C27B H27B 120.3 . . ?
C26B C27B C28B 119.4(14) . . ?
C28B C27B H27B 120.3 . . ?
C23B C28B C27B 120.1(13) . . ?
C23B C28B C29B 121.4(13) . . ?
C27B C28B C29B 118.4(13) . . ?
O2B C29B C28B 113.1(11) . . ?
O2B C29B H29B 109.2 . . ?
O2B C29B C30B 104.3(11) . . ?
C28B C29B H29B 109.2 . . ?
C30B C29B C28B 111.7(11) . . ?
C30B C29B H29B 109.2 . . ?
O3B C30B O4B 122.7(13) . . ?
O3B C30B C29B 126.3(14) . . ?
O4B C30B C29B 111.0(12) . . ?
C32B C31B H31B 120.8 . . ?
C32B C31B C36B 118.5(15) . . ?
C36B C31B H31B 120.8 . . ?
C31B C32B H32B 118.4 . . ?
C33B C32B C31B 123.3(17) . . ?
C33B C32B H32B 118.4 . . ?
C32B C33B H33B 120.8 . . ?
C32B C33B C34B 118.5(16) . . ?
C34B C33B H33B 120.8 . . ?
C33B C34B H34B 119.6 . . ?
C35B C34B C33B 120.8(15) . . ?
C35B C34B H34B 119.6 . . ?
C34B C35B H35B 120.3 . . ?
C34B C35B C36B 119.3(15) . . ?
C36B C35B H35B 120.3 . . ?
C31B C36B C37B 121.0(13) . . ?
C35B C36B C31B 119.6(14) . . ?
C35B C36B C37B 119.4(14) . . ?
O1B C37B C36B 113.9(11) . . ?
O1B C37B H37B 109.4 . . ?
O1B C37B C38B 103.5(11) . . ?
C36B C37B H37B 109.4 . . ?
C36B C37B C38B 111.0(11) . . ?
C38B C37B H37B 109.4 . . ?
O5B C38B C37B 110.3(12) . . ?
O6B C38B O5B 125.0(14) . . ?
O6B C38B C37B 124.7(14) . . ?
H1SA C1S H1SB 107.8 . . ?
Cl1S C1S H1SA 109.0 . . ?
Cl1S C1S H1SB 109.0 . . ?
Cl2S C1S H1SA 109.0 . . ?
Cl2S C1S H1SB 109.0 . . ?
Cl2S C1S Cl1S 113.1(9) . . ?
H2SA C2S H2SB 107.8 . . ?
Cl3S C2S H2SA 109.0 . . ?
Cl3S C2S H2SB 109.0 . . ?
Cl4S C2S H2SA 109.0 . . ?
Cl4S C2S H2SB 109.0 . . ?
Cl4S C2S Cl3S 112.7(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1A Si1A C8A C7A 177.1(11) . . . . ?
Rh1A Si1A C8A C9A -4.2(10) . . . . ?
Rh1A Si2A C19A C18A 168.9(11) . . . . ?
Rh1A Si2A C19A C20A -13.3(10) . . . . ?
Rh1A O1A C37A C36A 136.1(9) . . . . ?
Rh1A O1A C37A C38A -104.2(10) . . . . ?
Rh1A O2A C29A C28A 139.5(9) . . . . ?
Rh1A O2A C29A C30A -101.1(9) . . . . ?
Rh1A N1A C1A C2A 178.2(10) . . . . ?
Rh1A N1A C9A C4A -177.0(10) . . . . ?
Rh1A N1A C9A C8A 3.8(15) . . . . ?
Rh1A N2A C12A C13A 175.0(10) . . . . ?
Rh1A N2A C20A C15A -173.3(10) . . . . ?
Rh1A N2A C20A C19A 6.3(16) . . . . ?
Si1A C8A C9A N1A 0.9(16) . . . . ?
Si1A C8A C9A C4A -178.3(10) . . . . ?
Si2A C19A C20A N2A 6.2(16) . . . . ?
Si2A C19A C20A C15A -174.1(11) . . . . ?
B1A O1A C37A C36A -114.1(12) . . . . ?
B1A O1A C37A C38A 5.6(13) . . . . ?
B1A O2A C29A C28A -110.0(12) . . . . ?
B1A O2A C29A C30A 9.4(13) . . . . ?
B1A O4A C30A O3A -176.2(14) . . . . ?
B1A O4A C30A C29A 2.3(14) . . . . ?
B1A O5A C38A O6A -177.5(13) . . . . ?
B1A O5A C38A C37A 5.3(14) . . . . ?
O1A B1A O2A Rh1A -3.6(11) . . . . ?
O1A B1A O2A C29A -129.7(11) . . . . ?
O1A B1A O4A C30A 123.4(11) . . . . ?
O1A B1A O5A C38A -1.7(14) . . . . ?
O1A C37A C38A O5A -6.8(14) . . . . ?
O1A C37A C38A O6A 176.0(12) . . . . ?
O2A B1A O1A Rh1A 3.5(11) . . . . ?
O2A B1A O1A C37A -124.2(11) . . . . ?
O2A B1A O4A C30A 3.5(14) . . . . ?
O2A B1A O5A C38A 118.5(12) . . . . ?
O2A C29A C30A O3A 171.2(13) . . . . ?
O2A C29A C30A O4A -7.2(14) . . . . ?
O4A B1A O1A Rh1A -113.4(9) . . . . ?
O4A B1A O1A C37A 118.9(11) . . . . ?
O4A B1A O2A Rh1A 117.9(9) . . . . ?
O4A B1A O2A C29A -8.3(14) . . . . ?
O4A B1A O5A C38A -124.3(12) . . . . ?
O5A B1A O1A Rh1A 125.0(9) . . . . ?
O5A B1A O1A C37A -2.8(14) . . . . ?
O5A B1A O2A Rh1A -121.3(9) . . . . ?
O5A B1A O2A C29A 112.5(12) . . . . ?
O5A B1A O4A C30A -117.9(12) . . . . ?
N1A C1A C2A C3A -2(2) . . . . ?
N2A C12A C13A C14A -2(2) . . . . ?
C1A N1A C9A C4A -1.1(19) . . . . ?
C1A N1A C9A C8A 179.7(12) . . . . ?
C1A C2A C3A C4A 1(2) . . . . ?
C2A C3A C4A C5A -179.4(14) . . . . ?
C2A C3A C4A C9A 0(2) . . . . ?
C3A C4A C5A C6A -179.5(14) . . . . ?
C3A C4A C9A N1A 0(2) . . . . ?
C3A C4A C9A C8A 178.9(12) . . . . ?
C4A C5A C6A C7A 1(2) . . . . ?
C5A C4A C9A N1A 179.6(12) . . . . ?
C5A C4A C9A C8A -1(2) . . . . ?
C5A C6A C7A C8A -1(2) . . . . ?
C6A C7A C8A Si1A 179.5(10) . . . . ?
C6A C7A C8A C9A 1(2) . . . . ?
C7A C8A C9A N1A 179.6(12) . . . . ?
C7A C8A C9A C4A 0.5(19) . . . . ?
C9A N1A C1A C2A 2.2(19) . . . . ?
C9A C4A C5A C6A 1(2) . . . . ?
C10A Si1A C8A C7A 43.8(14) . . . . ?
C10A Si1A C8A C9A -137.6(10) . . . . ?
C11A Si1A C8A C7A -70.9(13) . . . . ?
C11A Si1A C8A C9A 107.8(11) . . . . ?
C12A N2A C20A C15A 1.0(19) . . . . ?
C12A N2A C20A C19A -179.4(12) . . . . ?
C12A C13A C14A C15A 1(2) . . . . ?
C13A C14A C15A C16A -176.0(14) . . . . ?
C13A C14A C15A C20A 0(2) . . . . ?
C14A C15A C16A C17A 177.8(14) . . . . ?
C14A C15A C20A N2A -1(2) . . . . ?
C14A C15A C20A C19A 178.9(12) . . . . ?
C15A C16A C17A C18A 2(2) . . . . ?
C16A C15A C20A N2A 175.1(13) . . . . ?
C16A C15A C20A C19A -5(2) . . . . ?
C16A C17A C18A C19A -3(2) . . . . ?
C17A C18A C19A Si2A 177.8(11) . . . . ?
C17A C18A C19A C20A 0.0(19) . . . . ?
C18A C19A C20A N2A -175.8(12) . . . . ?
C18A C19A C20A C15A 4(2) . . . . ?
C20A N2A C12A C13A 1(2) . . . . ?
C20A C15A C16A C17A 1(2) . . . . ?
C21A Si2A C19A C18A -80.3(13) . . . . ?
C21A Si2A C19A C20A 97.5(11) . . . . ?
C22A Si2A C19A C18A 35.3(14) . . . . ?
C22A Si2A C19A C20A -146.9(10) . . . . ?
C23A C24A C25A C26A 2(2) . . . . ?
C23A C28A C29A O2A 24.9(18) . . . . ?
C23A C28A C29A C30A -91.0(16) . . . . ?
C24A C23A C28A C27A 0(2) . . . . ?
C24A C23A C28A C29A 177.0(14) . . . . ?
C24A C25A C26A C27A -2(2) . . . . ?
C25A C26A C27A C28A 1(2) . . . . ?
C26A C27A C28A C23A 0(2) . . . . ?
C26A C27A C28A C29A -177.3(12) . . . . ?
C27A C28A C29A O2A -157.9(11) . . . . ?
C27A C28A C29A C30A 86.2(15) . . . . ?
C28A C23A C24A C25A -1(2) . . . . ?
C28A C29A C30A O3A -66.8(19) . . . . ?
C28A C29A C30A O4A 114.8(12) . . . . ?
C31A C32A C33A C34A 3(2) . . . . ?
C31A C36A C37A O1A 10.6(17) . . . . ?
C31A C36A C37A C38A -105.2(14) . . . . ?
C32A C31A C36A C35A -0.5(19) . . . . ?
C32A C31A C36A C37A 176.0(11) . . . . ?
C32A C33A C34A C35A -1(2) . . . . ?
C33A C34A C35A C36A -2(2) . . . . ?
C34A C35A C36A C31A 3(2) . . . . ?
C34A C35A C36A C37A -173.9(12) . . . . ?
C35A C36A C37A O1A -173.0(11) . . . . ?
C35A C36A C37A C38A 71.2(15) . . . . ?
C36A C31A C32A C33A -2(2) . . . . ?
C36A C37A C38A O5A 114.1(12) . . . . ?
C36A C37A C38A O6A -63.1(18) . . . . ?
Rh1B Si2B C19B C18B 168.7(12) . . . . ?
Rh1B Si2B C19B C20B -14.0(11) . . . . ?
Rh1B O1B C37B C36B 135.2(10) . . . . ?
Rh1B O1B C37B C38B -104.1(10) . . . . ?
Rh1B O2B C29B C28B 136.4(9) . . . . ?
Rh1B O2B C29B C30B -102.0(10) . . . . ?
Rh1B N1B C1B C2B 177.6(10) . . . . ?
Rh1B N1B C9B C4B -174.9(10) . . . . ?
Rh1B N1B C9B C8B 3.5(16) . . . . ?
Rh1B N2B C12B C13B 175.8(11) . . . . ?
Rh1B N2B C20B C15B -173.1(10) . . . . ?
Rh1B N2B C20B C19B 6.0(17) . . . . ?
Si1B C8B C9B N1B 3.3(16) . . . . ?
Si1B C8B C9B C4B -178.3(11) . . . . ?
Si2B C19B C20B N2B 6.9(17) . . . . ?
Si2B C19B C20B C15B -174.0(11) . . . . ?
B1B O1B C37B C36B -111.7(12) . . . . ?
B1B O1B C37B C38B 9.0(13) . . . . ?
B1B O2B C29B C28B -114.1(12) . . . . ?
B1B O2B C29B C30B 7.6(14) . . . . ?
B1B O4B C30B O3B -176.7(13) . . . . ?
B1B O4B C30B C29B 4.0(14) . . . . ?
B1B O5B C38B O6B -177.7(13) . . . . ?
B1B O5B C38B C37B 1.2(14) . . . . ?
O1B B1B O2B Rh1B 1.2(11) . . . . ?
O1B B1B O2B C29B -126.9(11) . . . . ?
O1B B1B O4B C30B 120.9(12) . . . . ?
O1B B1B O5B C38B 4.4(14) . . . . ?
O1B C37B C38B O5B -6.3(14) . . . . ?
O1B C37B C38B O6B 172.6(13) . . . . ?
O2B B1B O1B Rh1B -1.2(11) . . . . ?
O2B B1B O1B C37B -131.9(11) . . . . ?
O2B B1B O4B C30B 0.8(13) . . . . ?
O2B B1B O5B C38B 125.9(11) . . . . ?
O2B C29B C30B O3B 173.4(13) . . . . ?
O2B C29B C30B O4B -7.3(14) . . . . ?
O4B B1B O1B Rh1B -118.0(9) . . . . ?
O4B B1B O1B C37B 111.4(12) . . . . ?
O4B B1B O2B Rh1B 122.7(9) . . . . ?
O4B B1B O2B C29B -5.5(13) . . . . ?
O4B B1B O5B C38B -117.4(12) . . . . ?
O5B B1B O1B Rh1B 122.1(9) . . . . ?
O5B B1B O1B C37B -8.6(14) . . . . ?
O5B B1B O2B Rh1B -117.7(9) . . . . ?
O5B B1B O2B C29B 114.1(11) . . . . ?
O5B B1B O4B C30B -121.3(12) . . . . ?
N1B C1B C2B C3B -3(2) . . . . ?
N2B C12B C13B C14B -3(2) . . . . ?
C1B N1B C9B C4B 0.9(18) . . . . ?
C1B N1B C9B C8B 179.3(12) . . . . ?
C1B C2B C3B C4B 2(2) . . . . ?
C2B C3B C4B C5B -178.5(13) . . . . ?
C2B C3B C4B C9B 1(2) . . . . ?
C3B C4B C5B C6B 179.9(14) . . . . ?
C3B C4B C9B N1B -2(2) . . . . ?
C3B C4B C9B C8B 179.5(12) . . . . ?
C4B C5B C6B C7B 0(2) . . . . ?
C5B C4B C9B N1B 177.1(12) . . . . ?
C5B C4B C9B C8B -1(2) . . . . ?
C5B C6B C7B C8B 1(2) . . . . ?
C6B C7B C8B Si1B 178.5(11) . . . . ?
C6B C7B C8B C9B -1(2) . . . . ?
C7B C8B C9B N1B -176.9(12) . . . . ?
C7B C8B C9B C4B 1(2) . . . . ?
C9B N1B C1B C2B 1.6(19) . . . . ?
C9B C4B C5B C6B 1(2) . . . . ?
C12B N2B C20B C15B 1.4(19) . . . . ?
C12B N2B C20B C19B -179.5(12) . . . . ?
C12B C13B C14B C15B 3(2) . . . . ?
C13B C14B C15B C16B -177.4(14) . . . . ?
C13B C14B C15B C20B 0(2) . . . . ?
C14B C15B C16B C17B 177.3(14) . . . . ?
C14B C15B C20B N2B -2(2) . . . . ?
C14B C15B C20B C19B 178.9(13) . . . . ?
C15B C16B C17B C18B 4(2) . . . . ?
C16B C15B C20B N2B 175.3(13) . . . . ?
C16B C15B C20B C19B -4(2) . . . . ?
C16B C17B C18B C19B -4(2) . . . . ?
C17B C18B C19B Si2B 177.4(11) . . . . ?
C17B C18B C19B C20B 0(2) . . . . ?
C18B C19B C20B N2B -175.5(12) . . . . ?
C18B C19B C20B C15B 4(2) . . . . ?
C20B N2B C12B C13B 1(2) . . . . ?
C20B C15B C16B C17B 0(2) . . . . ?
C21B Si2B C19B C18B -79.9(13) . . . . ?
C21B Si2B C19B C20B 97.4(12) . . . . ?
C22B Si2B C19B C18B 36.0(15) . . . . ?
C22B Si2B C19B C20B -146.7(10) . . . . ?
C23B C24B C25B C26B 1(2) . . . . ?
C23B C28B C29B O2B 12.7(18) . . . . ?
C23B C28B C29B C30B -104.7(15) . . . . ?
C24B C23B C28B C27B -1.8(19) . . . . ?
C24B C23B C28B C29B 175.0(12) . . . . ?
C24B C25B C26B C27B -1(2) . . . . ?
C25B C26B C27B C28B -1(2) . . . . ?
C26B C27B C28B C23B 3(2) . . . . ?
C26B C27B C28B C29B -174.2(13) . . . . ?
C27B C28B C29B O2B -170.5(11) . . . . ?
C27B C28B C29B C30B 72.1(16) . . . . ?
C28B C23B C24B C25B -0.2(19) . . . . ?
C28B C29B C30B O3B -64.0(19) . . . . ?
C28B C29B C30B O4B 115.3(13) . . . . ?
C31B C32B C33B C34B 2(2) . . . . ?
C31B C36B C37B O1B 29.4(18) . . . . ?
C31B C36B C37B C38B -87.1(16) . . . . ?
C32B C31B C36B C35B 0(2) . . . . ?
C32B C31B C36B C37B 176.5(13) . . . . ?
C32B C33B C34B C35B 0(2) . . . . ?
C33B C34B C35B C36B -2(2) . . . . ?
C34B C35B C36B C31B 2(2) . . . . ?
C34B C35B C36B C37B -174.9(13) . . . . ?
C35B C36B C37B O1B -153.8(12) . . . . ?
C35B C36B C37B C38B 89.8(16) . . . . ?
C36B C31B C32B C33B -2(2) . . . . ?
C36B C37B C38B O5B 116.3(13) . . . . ?
C36B C37B C38B O6B -64.8(19) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 1.0008(15)
2 -0.0008(15)

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_l-rh(sin)[s-b(r-man)2]
_database_code_depnum_ccdc_archive 'CCDC 2341547'
loop_
_audit_author_name
_audit_author_address
'Pablo Salcedo'
;Universidad de Granada
Spain
;
_audit_update_record             
;
2024-09-02 deposited with the CCDC.	2024-09-11 downloaded from the CCDC.
;
_audit_creation_date             2024-09-02
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C38 H36 B N2 O6 Rh Si2'
_chemical_formula_sum            'C38 H36 B N2 O6 Rh Si2'
_chemical_formula_weight         786.59
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   10.2080(8)
_cell_length_b                   8.5609(7)
_cell_length_c                   21.3464(16)
_cell_angle_alpha                90
_cell_angle_beta                 101.940(2)
_cell_angle_gamma                90
_cell_volume                     1825.1(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3488
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      20.18
_cell_measurement_theta_min      2.44
_shelx_estimated_absorpt_T_max   0.999
_shelx_estimated_absorpt_T_min   0.868
_exptl_absorpt_coefficient_mu    0.582
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.6183
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1094 before and 0.0895 after correction.
The Ratio of minimum to maximum transmission is 0.8295.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.431
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             808
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.0022
_exptl_crystal_size_min          0.0018
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1593
_diffrn_reflns_av_unetI/netI     0.1425
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            37156
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.615
_diffrn_reflns_theta_min         2.039
_diffrn_ambient_temperature      150.00
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.863
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.986
_reflns_number_gt                4478
_reflns_number_total             7581
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.939
_refine_diff_density_min         -1.685
_refine_diff_density_rms         0.140
_refine_ls_abs_structure_details 
;
 Flack x determined using 1521 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.02(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     455
_refine_ls_number_reflns         7581
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.1609
_refine_ls_R_factor_gt           0.0583
_refine_ls_restrained_S_all      1.096
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0452P)²+2.7028P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1091
_refine_ls_wR_factor_ref         0.1538
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C29(H29), C37(H37)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C12(H12), C13(H13), C14(H14),
 C16(H16), C17(H17), C18(H18), C23(H23), C24(H24), C25(H25), C26(H26), C27(H27),
  C31(H31), C32(H32), C33(H33), C34(H34), C35(H35)
2.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C21(H21A,H21B,H21C), C22(H22A,H22B,
 H22C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.31936(9) 0.48789(12) 0.25106(5) 0.0317(3) Uani 1 1 d . . . . .
Si1 Si 0.4641(3) 0.6244(4) 0.20492(17) 0.0320(8) Uani 1 1 d . . . . .
Si2 Si 0.4945(3) 0.3430(4) 0.30184(18) 0.0347(9) Uani 1 1 d . . . . .
B1 B 0.0253(10) 0.495(2) 0.2416(5) 0.018(2) Uani 1 1 d . . . . .
O1 O 0.1138(7) 0.3845(9) 0.2804(4) 0.0295(19) Uani 1 1 d . . . . .
O2 O 0.1010(7) 0.6034(9) 0.2089(4) 0.0294(19) Uani 1 1 d . . . . .
O3 O -0.1182(9) 0.4311(9) 0.0802(4) 0.044(2) Uani 1 1 d . . . . .
O4 O -0.0719(7) 0.4197(10) 0.1885(4) 0.037(2) Uani 1 1 d . . . . .
O5 O -0.0461(8) 0.5767(10) 0.2848(4) 0.033(2) Uani 1 1 d . . . . .
O6 O -0.0339(9) 0.5831(10) 0.3914(4) 0.047(2) Uani 1 1 d . . . . .
N1 N 0.2950(9) 0.3484(12) 0.1713(5) 0.029(2) Uani 1 1 d . . . . .
N2 N 0.3558(9) 0.6238(13) 0.3325(5) 0.031(2) Uani 1 1 d . . . . .
C1 C 0.2048(12) 0.2353(15) 0.1626(6) 0.035(3) Uani 1 1 d . . . . .
H1 H 0.149612 0.223537 0.193114 0.042 Uiso 1 1 calc R U . . .
C2 C 0.1866(12) 0.1308(16) 0.1101(6) 0.038(3) Uani 1 1 d . . . . .
H2 H 0.116725 0.055573 0.104531 0.046 Uiso 1 1 calc R U . . .
C3 C 0.2690(12) 0.1379(16) 0.0676(7) 0.041(3) Uani 1 1 d . . . . .
H3 H 0.259051 0.066690 0.032853 0.049 Uiso 1 1 calc R U . . .
C4 C 0.3723(12) 0.2566(15) 0.0766(6) 0.034(3) Uani 1 1 d . . . . .
C5 C 0.4679(13) 0.2676(16) 0.0374(6) 0.042(3) Uani 1 1 d . . . . .
H5 H 0.463199 0.198081 0.002328 0.050 Uiso 1 1 calc R U . . .
C6 C 0.5665(13) 0.3771(16) 0.0496(7) 0.044(4) Uani 1 1 d . . . . .
H6 H 0.632592 0.381254 0.024166 0.053 Uiso 1 1 calc R U . . .
C7 C 0.5703(10) 0.484(2) 0.1000(5) 0.041(3) Uani 1 1 d . . . . .
H7 H 0.639063 0.561037 0.107189 0.049 Uiso 1 1 calc R U . . .
C8 C 0.4783(9) 0.483(2) 0.1395(5) 0.031(2) Uani 1 1 d . . . . .
C9 C 0.3811(11) 0.3610(15) 0.1283(6) 0.031(3) Uani 1 1 d . . . . .
C10 C 0.6293(14) 0.6999(19) 0.2486(7) 0.045(4) Uani 1 1 d . . . . .
H10A H 0.684656 0.612481 0.268576 0.067 Uiso 1 1 calc R U . . .
H10B H 0.615436 0.773439 0.281845 0.067 Uiso 1 1 calc R U . . .
H10C H 0.674589 0.753286 0.218493 0.067 Uiso 1 1 calc R U . . .
C11 C 0.3725(13) 0.8009(16) 0.1663(7) 0.045(4) Uani 1 1 d . . . . .
H11A H 0.426378 0.852654 0.139382 0.067 Uiso 1 1 calc R U . . .
H11B H 0.356912 0.873379 0.199555 0.067 Uiso 1 1 calc R U . . .
H11C H 0.286474 0.768835 0.139893 0.067 Uiso 1 1 calc R U . . .
C12 C 0.2694(12) 0.7398(16) 0.3402(6) 0.038(3) Uani 1 1 d . . . . .
H12 H 0.190891 0.756617 0.308197 0.046 Uiso 1 1 calc R U . . .
C13 C 0.2955(13) 0.8353(16) 0.3953(7) 0.045(4) Uani 1 1 d . . . . .
H13 H 0.230864 0.910522 0.401421 0.053 Uiso 1 1 calc R U . . .
C14 C 0.4112(14) 0.8216(16) 0.4397(7) 0.044(4) Uani 1 1 d . . . . .
H14 H 0.428008 0.887776 0.476238 0.053 Uiso 1 1 calc R U . . .
C15 C 0.5052(12) 0.7095(16) 0.4312(6) 0.037(3) Uani 1 1 d . . . . .
C16 C 0.6307(15) 0.6932(18) 0.4723(7) 0.050(4) Uani 1 1 d . . . . .
H16 H 0.655823 0.763739 0.507073 0.060 Uiso 1 1 calc R U . . .
C17 C 0.7174(13) 0.5778(19) 0.4634(6) 0.048(4) Uani 1 1 d . . . . .
H17 H 0.802670 0.570998 0.491363 0.058 Uiso 1 1 calc R U . . .
C18 C 0.6825(10) 0.469(2) 0.4136(5) 0.040(3) Uani 1 1 d . . . . .
H18 H 0.743822 0.389061 0.408831 0.048 Uiso 1 1 calc R U . . .
C19 C 0.5590(10) 0.477(2) 0.3708(5) 0.032(3) Uani 1 1 d . . . . .
C20 C 0.4731(11) 0.6042(14) 0.3789(6) 0.032(3) Uani 1 1 d . . . . .
C21 C 0.6338(15) 0.268(2) 0.2651(8) 0.051(5) Uani 1 1 d . . . . .
H21A H 0.675073 0.356008 0.246745 0.077 Uiso 1 1 calc R U . . .
H21B H 0.597979 0.193324 0.231198 0.077 Uiso 1 1 calc R U . . .
H21C H 0.701152 0.217064 0.297972 0.077 Uiso 1 1 calc R U . . .
C22 C 0.4235(14) 0.1661(17) 0.3350(7) 0.050(4) Uani 1 1 d . . . . .
H22A H 0.495448 0.109942 0.363714 0.075 Uiso 1 1 calc R U . . .
H22B H 0.382254 0.097251 0.299696 0.075 Uiso 1 1 calc R U . . .
H22C H 0.355764 0.198821 0.358780 0.075 Uiso 1 1 calc R U . . .
C23 C -0.0741(13) 0.8573(16) 0.1629(7) 0.043(4) Uani 1 1 d . . . . .
H23 H -0.059905 0.830899 0.207026 0.052 Uiso 1 1 calc R U . . .
C24 C -0.1451(11) 0.993(2) 0.1404(6) 0.048(3) Uani 1 1 d . . . . .
H24 H -0.179306 1.058293 0.169247 0.058 Uiso 1 1 calc R U . . .
C25 C -0.1655(13) 1.0314(16) 0.0764(8) 0.056(5) Uani 1 1 d . . . . .
H25 H -0.213418 1.123726 0.061358 0.068 Uiso 1 1 calc R U . . .
C26 C -0.1163(14) 0.9359(17) 0.0336(8) 0.053(4) Uani 1 1 d . . . . .
H26 H -0.131513 0.961393 -0.010630 0.063 Uiso 1 1 calc R U . . .
C27 C -0.0448(13) 0.8030(15) 0.0568(7) 0.042(3) Uani 1 1 d . . . . .
H27 H -0.008984 0.739093 0.028030 0.050 Uiso 1 1 calc R U . . .
C28 C -0.0242(11) 0.7610(14) 0.1207(6) 0.029(3) Uani 1 1 d . . . . .
C29 C 0.0462(11) 0.6086(14) 0.1430(6) 0.028(3) Uani 1 1 d . . . . .
H29 H 0.117635 0.587679 0.118294 0.034 Uiso 1 1 calc R U . . .
C30 C -0.0579(10) 0.4738(19) 0.1321(6) 0.032(3) Uani 1 1 d . . . . .
C31 C -0.0042(12) 0.1136(16) 0.3208(7) 0.042(3) Uani 1 1 d . . . . .
H31 H 0.015811 0.119333 0.279324 0.051 Uiso 1 1 calc R U . . .
C32 C -0.0661(10) -0.022(2) 0.3388(6) 0.042(3) Uani 1 1 d . . . . .
H32 H -0.087261 -0.106931 0.309951 0.050 Uiso 1 1 calc R U . . .
C33 C -0.0954(11) -0.028(2) 0.3991(6) 0.043(3) Uani 1 1 d . . . . .
H33 H -0.138024 -0.117931 0.411490 0.052 Uiso 1 1 calc R U . . .
C34 C -0.0639(12) 0.0936(15) 0.4413(6) 0.038(3) Uani 1 1 d . . . . .
H34 H -0.083512 0.086516 0.482777 0.045 Uiso 1 1 calc R U . . .
C35 C -0.0028(12) 0.2285(15) 0.4233(6) 0.034(3) Uani 1 1 d . . . . .
H35 H 0.017605 0.313224 0.452412 0.041 Uiso 1 1 calc R U . . .
C36 C 0.0280(11) 0.2385(15) 0.3626(6) 0.031(3) Uani 1 1 d . . . . .
C37 C 0.0905(12) 0.3879(14) 0.3436(6) 0.032(3) Uani 1 1 d . . . . .
H37 H 0.177016 0.407774 0.374392 0.039 Uiso 1 1 calc R U . . .
C38 C -0.0029(12) 0.5277(14) 0.3440(7) 0.039(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Si1 2.263(3) . ?
Rh1 Si2 2.261(4) . ?
Rh1 O1 2.474(7) . ?
Rh1 O2 2.435(8) . ?
Rh1 N1 2.053(10) . ?
Rh1 N2 2.061(10) . ?
Si1 C8 1.877(14) . ?
Si1 C10 1.866(15) . ?
Si1 C11 1.875(13) . ?
Si2 C19 1.877(14) . ?
Si2 C21 1.872(16) . ?
Si2 C22 1.879(14) . ?
B1 O1 1.442(16) . ?
B1 O2 1.475(16) . ?
B1 O4 1.489(15) . ?
B1 O5 1.468(15) . ?
O1 C37 1.419(14) . ?
O2 C29 1.403(13) . ?
O3 C30 1.207(13) . ?
O4 C30 1.324(14) . ?
O5 C38 1.317(15) . ?
O6 C38 1.216(14) . ?
N1 C1 1.322(15) . ?
N1 C9 1.401(14) . ?
N2 C12 1.360(16) . ?
N2 C20 1.398(15) . ?
C1 H1 0.9500 . ?
C1 C2 1.416(17) . ?
C2 H2 0.9500 . ?
C2 C3 1.360(17) . ?
C3 H3 0.9500 . ?
C3 C4 1.448(18) . ?
C4 C5 1.414(17) . ?
C4 C9 1.407(17) . ?
C5 H5 0.9500 . ?
C5 C6 1.361(18) . ?
C6 H6 0.9500 . ?
C6 C7 1.408(19) . ?
C7 H7 0.9500 . ?
C7 C8 1.387(13) . ?
C8 C9 1.426(18) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12 0.9500 . ?
C12 C13 1.413(18) . ?
C13 H13 0.9500 . ?
C13 C14 1.358(18) . ?
C14 H14 0.9500 . ?
C14 C15 1.396(18) . ?
C15 C16 1.402(19) . ?
C15 C20 1.418(17) . ?
C16 H16 0.9500 . ?
C16 C17 1.37(2) . ?
C17 H17 0.9500 . ?
C17 C18 1.40(2) . ?
C18 H18 0.9500 . ?
C18 C19 1.397(14) . ?
C19 C20 1.429(18) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23 0.9500 . ?
C23 C24 1.40(2) . ?
C23 C28 1.392(17) . ?
C24 H24 0.9500 . ?
C24 C25 1.379(18) . ?
C25 H25 0.9500 . ?
C25 C26 1.395(19) . ?
C26 H26 0.9500 . ?
C26 C27 1.386(18) . ?
C27 H27 0.9500 . ?
C27 C28 1.386(17) . ?
C28 C29 1.517(16) . ?
C29 H29 1.0000 . ?
C29 C30 1.553(17) . ?
C31 H31 0.9500 . ?
C31 C32 1.41(2) . ?
C31 C36 1.389(17) . ?
C32 H32 0.9500 . ?
C32 C33 1.382(15) . ?
C33 H33 0.9500 . ?
C33 C34 1.370(19) . ?
C34 H34 0.9500 . ?
C34 C35 1.403(17) . ?
C35 H35 0.9500 . ?
C35 C36 1.396(16) . ?
C36 C37 1.521(17) . ?
C37 H37 1.0000 . ?
C37 C38 1.531(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Rh1 O1 163.5(2) . . ?
Si1 Rh1 O2 105.0(2) . . ?
Si2 Rh1 Si1 88.25(13) . . ?
Si2 Rh1 O1 108.1(2) . . ?
Si2 Rh1 O2 166.7(2) . . ?
O2 Rh1 O1 58.6(2) . . ?
N1 Rh1 Si1 85.3(3) . . ?
N1 Rh1 Si2 91.5(3) . . ?
N1 Rh1 O1 92.2(3) . . ?
N1 Rh1 O2 89.1(3) . . ?
N1 Rh1 N2 176.5(4) . . ?
N2 Rh1 Si1 93.2(3) . . ?
N2 Rh1 Si2 85.3(3) . . ?
N2 Rh1 O1 90.2(3) . . ?
N2 Rh1 O2 94.3(3) . . ?
C8 Si1 Rh1 98.5(4) . . ?
C10 Si1 Rh1 124.4(5) . . ?
C10 Si1 C8 113.2(6) . . ?
C10 Si1 C11 104.9(7) . . ?
C11 Si1 Rh1 107.3(4) . . ?
C11 Si1 C8 107.5(6) . . ?
C19 Si2 Rh1 98.8(4) . . ?
C19 Si2 C22 107.4(7) . . ?
C21 Si2 Rh1 125.4(5) . . ?
C21 Si2 C19 111.4(6) . . ?
C21 Si2 C22 105.6(7) . . ?
C22 Si2 Rh1 107.1(5) . . ?
O1 B1 O2 111.0(7) . . ?
O1 B1 O4 113.3(13) . . ?
O1 B1 O5 106.6(8) . . ?
O2 B1 O4 104.0(8) . . ?
O5 B1 O2 111.8(13) . . ?
O5 B1 O4 110.2(8) . . ?
B1 O1 Rh1 94.8(6) . . ?
C37 O1 Rh1 123.4(7) . . ?
C37 O1 B1 108.9(8) . . ?
B1 O2 Rh1 95.6(6) . . ?
C29 O2 Rh1 121.9(6) . . ?
C29 O2 B1 110.9(8) . . ?
C30 O4 B1 111.2(9) . . ?
C38 O5 B1 109.8(9) . . ?
C1 N1 Rh1 120.2(8) . . ?
C1 N1 C9 118.6(11) . . ?
C9 N1 Rh1 121.0(8) . . ?
C12 N2 Rh1 120.3(8) . . ?
C12 N2 C20 118.9(11) . . ?
C20 N2 Rh1 120.6(8) . . ?
N1 C1 H1 118.4 . . ?
N1 C1 C2 123.1(11) . . ?
C2 C1 H1 118.4 . . ?
C1 C2 H2 119.9 . . ?
C3 C2 C1 120.1(12) . . ?
C3 C2 H2 119.9 . . ?
C2 C3 H3 120.7 . . ?
C2 C3 C4 118.5(13) . . ?
C4 C3 H3 120.7 . . ?
C5 C4 C3 122.8(12) . . ?
C9 C4 C3 118.4(11) . . ?
C9 C4 C5 118.7(12) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 C4 120.4(13) . . ?
C6 C5 H5 119.8 . . ?
C5 C6 H6 120.1 . . ?
C5 C6 C7 119.8(12) . . ?
C7 C6 H6 120.1 . . ?
C6 C7 H7 118.5 . . ?
C8 C7 C6 122.9(14) . . ?
C8 C7 H7 118.5 . . ?
C7 C8 Si1 127.9(13) . . ?
C7 C8 C9 116.0(14) . . ?
C9 C8 Si1 116.1(8) . . ?
N1 C9 C4 121.2(11) . . ?
N1 C9 C8 117.1(11) . . ?
C4 C9 C8 121.8(10) . . ?
Si1 C10 H10A 109.5 . . ?
Si1 C10 H10B 109.5 . . ?
Si1 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si1 C11 H11A 109.5 . . ?
Si1 C11 H11B 109.5 . . ?
Si1 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C12 H12 119.7 . . ?
N2 C12 C13 120.5(12) . . ?
C13 C12 H12 119.7 . . ?
C12 C13 H13 119.4 . . ?
C14 C13 C12 121.2(13) . . ?
C14 C13 H13 119.4 . . ?
C13 C14 H14 120.3 . . ?
C13 C14 C15 119.3(13) . . ?
C15 C14 H14 120.3 . . ?
C14 C15 C16 123.4(13) . . ?
C14 C15 C20 119.1(12) . . ?
C16 C15 C20 117.5(13) . . ?
C15 C16 H16 119.4 . . ?
C17 C16 C15 121.3(14) . . ?
C17 C16 H16 119.4 . . ?
C16 C17 H17 119.5 . . ?
C16 C17 C18 120.9(13) . . ?
C18 C17 H17 119.5 . . ?
C17 C18 H18 119.4 . . ?
C19 C18 C17 121.2(15) . . ?
C19 C18 H18 119.4 . . ?
C18 C19 Si2 127.3(12) . . ?
C18 C19 C20 116.8(13) . . ?
C20 C19 Si2 115.9(8) . . ?
N2 C20 C15 120.4(11) . . ?
N2 C20 C19 117.5(11) . . ?
C15 C20 C19 122.1(11) . . ?
Si2 C21 H21A 109.5 . . ?
Si2 C21 H21B 109.5 . . ?
Si2 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si2 C22 H22A 109.5 . . ?
Si2 C22 H22B 109.5 . . ?
Si2 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 H23 119.9 . . ?
C28 C23 H23 119.9 . . ?
C28 C23 C24 120.2(13) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 C23 119.9(14) . . ?
C25 C24 H24 120.0 . . ?
C24 C25 H25 119.7 . . ?
C24 C25 C26 120.5(14) . . ?
C26 C25 H25 119.7 . . ?
C25 C26 H26 120.6 . . ?
C27 C26 C25 118.8(14) . . ?
C27 C26 H26 120.6 . . ?
C26 C27 H27 119.1 . . ?
C28 C27 C26 121.8(14) . . ?
C28 C27 H27 119.1 . . ?
C23 C28 C29 121.3(11) . . ?
C27 C28 C23 118.8(12) . . ?
C27 C28 C29 119.8(11) . . ?
O2 C29 C28 113.9(10) . . ?
O2 C29 H29 109.8 . . ?
O2 C29 C30 104.1(9) . . ?
C28 C29 H29 109.8 . . ?
C28 C29 C30 109.1(9) . . ?
C30 C29 H29 109.8 . . ?
O3 C30 O4 126.7(12) . . ?
O3 C30 C29 124.4(12) . . ?
O4 C30 C29 108.9(10) . . ?
C32 C31 H31 119.4 . . ?
C36 C31 H31 119.4 . . ?
C36 C31 C32 121.2(12) . . ?
C31 C32 H32 120.6 . . ?
C33 C32 C31 118.7(15) . . ?
C33 C32 H32 120.6 . . ?
C32 C33 H33 119.4 . . ?
C34 C33 C32 121.2(15) . . ?
C34 C33 H33 119.4 . . ?
C33 C34 H34 119.9 . . ?
C33 C34 C35 120.1(12) . . ?
C35 C34 H34 119.9 . . ?
C34 C35 H35 119.9 . . ?
C36 C35 C34 120.2(12) . . ?
C36 C35 H35 119.9 . . ?
C31 C36 C35 118.7(12) . . ?
C31 C36 C37 122.2(11) . . ?
C35 C36 C37 119.1(11) . . ?
O1 C37 C36 113.5(10) . . ?
O1 C37 H37 109.3 . . ?
O1 C37 C38 104.3(10) . . ?
C36 C37 H37 109.3 . . ?
C36 C37 C38 111.1(9) . . ?
C38 C37 H37 109.3 . . ?
O5 C38 C37 109.2(11) . . ?
O6 C38 O5 125.4(12) . . ?
O6 C38 C37 125.3(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 Si1 C8 C7 -168.0(11) . . . . ?
Rh1 Si1 C8 C9 13.3(10) . . . . ?
Rh1 Si2 C19 C18 -166.5(12) . . . . ?
Rh1 Si2 C19 C20 11.7(9) . . . . ?
Rh1 O1 C37 C36 -138.5(8) . . . . ?
Rh1 O1 C37 C38 100.5(9) . . . . ?
Rh1 O2 C29 C28 -139.3(8) . . . . ?
Rh1 O2 C29 C30 101.9(8) . . . . ?
Rh1 N1 C1 C2 -177.3(9) . . . . ?
Rh1 N1 C9 C4 174.4(9) . . . . ?
Rh1 N1 C9 C8 -5.2(15) . . . . ?
Rh1 N2 C12 C13 -178.7(9) . . . . ?
Rh1 N2 C20 C15 172.7(8) . . . . ?
Rh1 N2 C20 C19 -6.0(14) . . . . ?
Si1 C8 C9 N1 -6.9(15) . . . . ?
Si1 C8 C9 C4 173.6(9) . . . . ?
Si2 C19 C20 N2 -5.2(14) . . . . ?
Si2 C19 C20 C15 176.1(9) . . . . ?
B1 O1 C37 C36 112.1(11) . . . . ?
B1 O1 C37 C38 -9.0(12) . . . . ?
B1 O2 C29 C28 109.6(11) . . . . ?
B1 O2 C29 C30 -9.2(12) . . . . ?
B1 O4 C30 O3 176.7(13) . . . . ?
B1 O4 C30 C29 -5.7(14) . . . . ?
B1 O5 C38 O6 173.1(12) . . . . ?
B1 O5 C38 C37 -8.0(13) . . . . ?
O1 B1 O2 Rh1 1.1(10) . . . . ?
O1 B1 O2 C29 128.3(10) . . . . ?
O1 B1 O4 C30 -120.5(11) . . . . ?
O1 B1 O5 C38 2.3(14) . . . . ?
O1 C37 C38 O5 10.7(12) . . . . ?
O1 C37 C38 O6 -170.4(11) . . . . ?
O2 B1 O1 Rh1 -1.0(10) . . . . ?
O2 B1 O1 C37 126.8(10) . . . . ?
O2 B1 O4 C30 0.1(14) . . . . ?
O2 B1 O5 C38 -119.2(10) . . . . ?
O2 C29 C30 O3 -173.1(12) . . . . ?
O2 C29 C30 O4 9.3(12) . . . . ?
O4 B1 O1 Rh1 115.5(7) . . . . ?
O4 B1 O1 C37 -116.6(9) . . . . ?
O4 B1 O2 Rh1 -121.1(8) . . . . ?
O4 B1 O2 C29 6.2(13) . . . . ?
O4 B1 O5 C38 125.6(11) . . . . ?
O5 B1 O1 Rh1 -123.1(9) . . . . ?
O5 B1 O1 C37 4.8(13) . . . . ?
O5 B1 O2 Rh1 120.0(7) . . . . ?
O5 B1 O2 C29 -112.8(10) . . . . ?
O5 B1 O4 C30 120.2(12) . . . . ?
N1 C1 C2 C3 4(2) . . . . ?
N2 C12 C13 C14 5(2) . . . . ?
C1 N1 C9 C4 0.3(17) . . . . ?
C1 N1 C9 C8 -179.2(11) . . . . ?
C1 C2 C3 C4 -1.6(19) . . . . ?
C2 C3 C4 C5 176.1(12) . . . . ?
C2 C3 C4 C9 -1.1(19) . . . . ?
C3 C4 C5 C6 -177.1(13) . . . . ?
C3 C4 C9 N1 1.8(18) . . . . ?
C3 C4 C9 C8 -178.7(12) . . . . ?
C4 C5 C6 C7 -3(2) . . . . ?
C5 C4 C9 N1 -175.5(11) . . . . ?
C5 C4 C9 C8 4.0(19) . . . . ?
C5 C6 C7 C8 1(2) . . . . ?
C6 C7 C8 Si1 -176.0(10) . . . . ?
C6 C7 C8 C9 3(2) . . . . ?
C7 C8 C9 N1 174.3(11) . . . . ?
C7 C8 C9 C4 -5.2(18) . . . . ?
C9 N1 C1 C2 -3.2(18) . . . . ?
C9 C4 C5 C6 0(2) . . . . ?
C10 Si1 C8 C7 -34.7(14) . . . . ?
C10 Si1 C8 C9 146.7(9) . . . . ?
C11 Si1 C8 C7 80.8(12) . . . . ?
C11 Si1 C8 C9 -97.9(10) . . . . ?
C12 N2 C20 C15 -3.8(16) . . . . ?
C12 N2 C20 C19 177.5(11) . . . . ?
C12 C13 C14 C15 -1(2) . . . . ?
C13 C14 C15 C16 176.0(13) . . . . ?
C13 C14 C15 C20 -4.9(19) . . . . ?
C14 C15 C16 C17 177.5(13) . . . . ?
C14 C15 C20 N2 7.4(17) . . . . ?
C14 C15 C20 C19 -174.0(12) . . . . ?
C15 C16 C17 C18 -2(2) . . . . ?
C16 C15 C20 N2 -173.5(11) . . . . ?
C16 C15 C20 C19 5.2(18) . . . . ?
C16 C17 C18 C19 1(2) . . . . ?
C17 C18 C19 Si2 -179.6(10) . . . . ?
C17 C18 C19 C20 2.2(19) . . . . ?
C18 C19 C20 N2 173.2(11) . . . . ?
C18 C19 C20 C15 -5.5(18) . . . . ?
C20 N2 C12 C13 -2.2(17) . . . . ?
C20 C15 C16 C17 -1.6(19) . . . . ?
C21 Si2 C19 C18 -32.8(14) . . . . ?
C21 Si2 C19 C20 145.4(9) . . . . ?
C22 Si2 C19 C18 82.4(13) . . . . ?
C22 Si2 C19 C20 -99.4(10) . . . . ?
C23 C24 C25 C26 0(2) . . . . ?
C23 C28 C29 O2 -23.4(15) . . . . ?
C23 C28 C29 C30 92.5(13) . . . . ?
C24 C23 C28 C27 0.8(18) . . . . ?
C24 C23 C28 C29 -176.4(11) . . . . ?
C24 C25 C26 C27 -1(2) . . . . ?
C25 C26 C27 C28 1.7(19) . . . . ?
C26 C27 C28 C23 -1.6(19) . . . . ?
C26 C27 C28 C29 175.7(11) . . . . ?
C27 C28 C29 O2 159.5(10) . . . . ?
C27 C28 C29 C30 -84.7(13) . . . . ?
C28 C23 C24 C25 0(2) . . . . ?
C28 C29 C30 O3 64.9(16) . . . . ?
C28 C29 C30 O4 -112.7(12) . . . . ?
C31 C32 C33 C34 -0.7(19) . . . . ?
C31 C36 C37 O1 -1.0(16) . . . . ?
C31 C36 C37 C38 116.2(13) . . . . ?
C32 C31 C36 C35 -0.4(18) . . . . ?
C32 C31 C36 C37 -177.9(11) . . . . ?
C32 C33 C34 C35 1.0(19) . . . . ?
C33 C34 C35 C36 -1.0(18) . . . . ?
C34 C35 C36 C31 0.6(17) . . . . ?
C34 C35 C36 C37 178.2(11) . . . . ?
C35 C36 C37 O1 -178.5(10) . . . . ?
C35 C36 C37 C38 -61.3(15) . . . . ?
C36 C31 C32 C33 0.4(18) . . . . ?
C36 C37 C38 O5 -112.0(11) . . . . ?
C36 C37 C38 O6 67.0(16) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
