# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2_a
_database_code_depnum_ccdc_archive 'CCDC 2387787'
loop_
_audit_author_name
_audit_author_address
xwja
;henan normal university
China
;
_audit_update_record             
;
2024-09-30 deposited with the CCDC.	2024-10-29 downloaded from the CCDC.
;
_audit_creation_date             2024-09-30
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C34 H26 Si'
_chemical_formula_sum            'C34 H26 Si'
_chemical_formula_weight         462.64
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   14.5996(2)
_cell_length_b                   9.42640(10)
_cell_length_c                   18.8989(2)
_cell_angle_alpha                90
_cell_angle_beta                 94.4420(10)
_cell_angle_gamma                90
_cell_volume                     2593.09(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    22415
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      71.3350
_cell_measurement_theta_min      3.6700
_shelx_estimated_absorpt_T_max   0.946
_shelx_estimated_absorpt_T_min   0.767
_exptl_absorpt_coefficient_mu    0.932
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.185
_exptl_crystal_density_meas      none
_exptl_crystal_density_method    none
_exptl_crystal_description       plate
_exptl_crystal_F_000             976
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   1.00000
_exptl_transmission_factor_min   0.66094
_diffrn_reflns_av_R_equivalents  0.1162
_diffrn_reflns_av_unetI/netI     0.0603
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            43685
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        66.588
_diffrn_reflns_theta_max         66.588
_diffrn_reflns_theta_min         3.691
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.870
_reflns_Friedel_fraction_full    0.993
_reflns_Friedel_fraction_max     0.993
_reflns_number_gt                8453
_reflns_number_total             9145
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.531
_refine_diff_density_min         -0.244
_refine_diff_density_rms         0.045
_refine_ls_abs_structure_details 
;
 Flack x determined using 3559 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.03(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         9145
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0631
_refine_ls_R_factor_gt           0.0583
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1079P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1551
_refine_ls_wR_factor_ref         0.1596
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C16(H16), C17(H17), C50(H50), C8(H8), C51(H51), C26(H26), C9(H9), C36(H36),
 C37(H37), C42(H42), C10(H10), C19(H19), C12(H12), C2(H2), C33(H33), C13(H13),
 C56(H56), C67(H67), C53(H53), C61(H61), C62(H62), C6(H6), C40(H40), C3(H3),
 C60(H60), C38(H38), C64(H64), C47(H47), C46(H46), C22(H22), C66(H66), C5(H5),
 C20(H20), C55(H55), C43(H43), C44(H44), C11(H11), C4(H4), C45(H45), C21(H21),
 C27(H27), C39(H39), C54(H54), C28(H28), C65(H65), C32(H32), C31(H31), C30(H30)
2.b X=CH2 refined with riding coordinates:
 C14(H14A,H14B), C48(H48A,H48B)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.21995(7) 0.52757(9) 0.82686(5) 0.0464(2) Uani 1 1 d . . . . .
C15 C 0.1882(3) 0.4121(4) 0.90292(18) 0.0476(7) Uani 1 1 d . . . . .
C1 C 0.1601(3) 0.7019(4) 0.8385(2) 0.0525(8) Uani 1 1 d . . . . .
C18 C 0.1290(3) 0.2658(4) 1.0216(2) 0.0573(9) Uani 1 1 d . . . . .
C7 C 0.1796(3) 0.4423(4) 0.74010(18) 0.0494(8) Uani 1 1 d . . . . .
C16 C 0.1018(3) 0.4384(4) 0.9296(2) 0.0587(9) Uani 1 1 d . . . . .
H16 H 0.063987 0.507869 0.908059 0.070 Uiso 1 1 calc R U . . .
C24 C 0.2436(3) 0.3058(4) 0.93475(18) 0.0470(7) Uani 1 1 d . . . . .
C34 C 0.4179(3) 0.2881(4) 0.9308(3) 0.0623(10) Uani 1 1 d . . . . .
C25 C 0.3274(3) 0.2582(4) 0.9009(2) 0.0514(8) Uani 1 1 d . . . . .
C23 C 0.2157(3) 0.2350(4) 0.99699(19) 0.0511(8) Uani 1 1 d . . . . .
C17 C 0.0721(3) 0.3657(5) 0.9858(2) 0.0637(10) Uani 1 1 d . . . . .
H17 H 0.013722 0.382818 1.000410 0.076 Uiso 1 1 calc R U . . .
C8 C 0.2173(3) 0.4823(4) 0.6778(2) 0.0588(9) Uani 1 1 d . . . . .
H8 H 0.260999 0.554202 0.679085 0.071 Uiso 1 1 calc R U . . .
C26 C 0.3153(4) 0.1804(5) 0.8394(2) 0.0653(10) Uani 1 1 d . . . . .
H26 H 0.256193 0.158184 0.820957 0.078 Uiso 1 1 calc R U . . .
C9 C 0.1909(4) 0.4168(5) 0.6135(2) 0.0693(11) Uani 1 1 d . . . . .
H9 H 0.216811 0.444900 0.572368 0.083 Uiso 1 1 calc R U . . .
C10 C 0.1264(4) 0.3105(5) 0.6109(2) 0.0748(13) Uani 1 1 d . . . . .
H10 H 0.109414 0.265708 0.568072 0.090 Uiso 1 1 calc R U . . .
C19 C 0.1020(4) 0.1945(5) 1.0831(3) 0.0737(13) Uani 1 1 d . . . . .
H19 H 0.044771 0.213304 1.099510 0.088 Uiso 1 1 calc R U . . .
C12 C 0.1137(3) 0.3350(5) 0.7360(2) 0.0625(10) Uani 1 1 d . . . . .
H12 H 0.087372 0.306298 0.776936 0.075 Uiso 1 1 calc R U . . .
C2 C 0.1756(3) 0.7746(5) 0.9030(2) 0.0641(10) Uani 1 1 d . . . . .
H2 H 0.213089 0.733111 0.939257 0.077 Uiso 1 1 calc R U . . .
C33 C 0.4349(4) 0.3675(5) 0.9934(3) 0.0800(14) Uani 1 1 d . . . . .
H33 H 0.385608 0.405128 1.015458 0.096 Uiso 1 1 calc R U . . .
C13 C 0.3456(3) 0.5673(5) 0.8254(2) 0.0595(9) Uani 1 1 d . . . . .
H13 H 0.386453 0.491476 0.826592 0.071 Uiso 1 1 calc R U . . .
C6 C 0.1027(4) 0.7663(5) 0.7864(2) 0.0680(11) Uani 1 1 d . . . . .
H6 H 0.090198 0.720958 0.743016 0.082 Uiso 1 1 calc R U . . .
C3 C 0.1377(4) 0.9039(5) 0.9143(3) 0.0744(13) Uani 1 1 d . . . . .
H3 H 0.149291 0.949528 0.957740 0.089 Uiso 1 1 calc R U . . .
C22 C 0.2734(4) 0.1350(5) 1.0347(2) 0.0663(11) Uani 1 1 d . . . . .
H22 H 0.330629 0.113126 1.019215 0.080 Uiso 1 1 calc R U . . .
C5 C 0.0635(4) 0.8977(6) 0.7979(3) 0.0868(16) Uani 1 1 d . . . . .
H5 H 0.024528 0.939020 0.762484 0.104 Uiso 1 1 calc R U . . .
C20 C 0.1586(5) 0.0997(5) 1.1180(3) 0.0859(16) Uani 1 1 d . . . . .
H20 H 0.139932 0.053789 1.158072 0.103 Uiso 1 1 calc R U . . .
C11 C 0.0868(4) 0.2702(5) 0.6716(3) 0.0740(12) Uani 1 1 d . . . . .
H11 H 0.042154 0.199643 0.669470 0.089 Uiso 1 1 calc R U . . .
C4 C 0.0821(4) 0.9665(5) 0.8612(3) 0.0851(16) Uani 1 1 d . . . . .
H4 H 0.057029 1.055700 0.868160 0.102 Uiso 1 1 calc R U . . .
C29 C 0.4927(3) 0.2381(6) 0.8942(4) 0.0845(16) Uani 1 1 d . . . . .
C21 C 0.2442(5) 0.0706(5) 1.0944(3) 0.0837(15) Uani 1 1 d . . . . .
H21 H 0.282750 0.006218 1.119309 0.100 Uiso 1 1 calc R U . . .
C27 C 0.3910(5) 0.1338(7) 0.8040(3) 0.0950(18) Uani 1 1 d . . . . .
H27 H 0.381635 0.083095 0.761891 0.114 Uiso 1 1 calc R U . . .
C14 C 0.3786(5) 0.6937(8) 0.8228(4) 0.105(2) Uani 1 1 d . . . . .
H14A H 0.339416 0.771581 0.821582 0.126 Uiso 1 1 calc R U . . .
H14B H 0.441666 0.707154 0.822215 0.126 Uiso 1 1 calc R U . . .
C28 C 0.4766(5) 0.1624(7) 0.8309(4) 0.103(2) Uani 1 1 d . . . . .
H28 H 0.526248 0.131373 0.806974 0.124 Uiso 1 1 calc R U . . .
C32 C 0.5217(5) 0.3905(7) 1.0223(5) 0.110(2) Uani 1 1 d . . . . .
H32 H 0.531820 0.441513 1.064343 0.132 Uiso 1 1 calc R U . . .
C31 C 0.5950(5) 0.3365(8) 0.9882(6) 0.135(4) Uani 1 1 d . . . . .
H31 H 0.654477 0.350684 1.008281 0.162 Uiso 1 1 calc R U . . .
C30 C 0.5823(5) 0.2640(8) 0.9264(6) 0.125(3) Uani 1 1 d . . . . .
H30 H 0.633055 0.230451 0.904688 0.150 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C15 1.889(4) . ?
Si1 C1 1.882(4) . ?
Si1 C7 1.879(3) . ?
Si1 C13 1.875(4) . ?
C15 C16 1.416(5) . ?
C15 C24 1.395(5) . ?
C1 C2 1.400(6) . ?
C1 C6 1.383(6) . ?
C18 C23 1.413(6) . ?
C18 C17 1.395(7) . ?
C18 C19 1.425(6) . ?
C7 C8 1.390(5) . ?
C7 C12 1.394(6) . ?
C16 H16 0.9300 . ?
C16 C17 1.363(6) . ?
C24 C25 1.492(5) . ?
C24 C23 1.438(5) . ?
C34 C25 1.425(6) . ?
C34 C33 1.405(7) . ?
C34 C29 1.417(7) . ?
C25 C26 1.374(6) . ?
C23 C22 1.419(6) . ?
C17 H17 0.9300 . ?
C8 H8 0.9300 . ?
C8 C9 1.390(6) . ?
C26 H26 0.9300 . ?
C26 C27 1.406(7) . ?
C9 H9 0.9300 . ?
C9 C10 1.373(8) . ?
C10 H10 0.9300 . ?
C10 C11 1.376(8) . ?
C19 H19 0.9300 . ?
C19 C20 1.354(8) . ?
C12 H12 0.9300 . ?
C12 C11 1.392(6) . ?
C2 H2 0.9300 . ?
C2 C3 1.364(7) . ?
C33 H33 0.9300 . ?
C33 C32 1.358(8) . ?
C13 H13 0.9300 . ?
C13 C14 1.287(8) . ?
C6 H6 0.9300 . ?
C6 C5 1.388(7) . ?
C3 H3 0.9300 . ?
C3 C4 1.375(8) . ?
C22 H22 0.9300 . ?
C22 C21 1.377(7) . ?
C5 H5 0.9300 . ?
C5 C4 1.369(9) . ?
C20 H20 0.9300 . ?
C20 C21 1.388(9) . ?
C11 H11 0.9300 . ?
C4 H4 0.9300 . ?
C29 C28 1.398(10) . ?
C29 C30 1.420(11) . ?
C21 H21 0.9300 . ?
C27 H27 0.9300 . ?
C27 C28 1.340(11) . ?
C14 H14A 0.9300 . ?
C14 H14B 0.9300 . ?
C28 H28 0.9300 . ?
C32 H32 0.9300 . ?
C32 C31 1.389(14) . ?
C31 H31 0.9300 . ?
C31 C30 1.353(14) . ?
C30 H30 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Si1 C15 105.67(17) . . ?
C7 Si1 C15 109.80(16) . . ?
C7 Si1 C1 110.99(16) . . ?
C13 Si1 C15 115.12(18) . . ?
C13 Si1 C1 106.93(19) . . ?
C13 Si1 C7 108.29(18) . . ?
C16 C15 Si1 116.6(3) . . ?
C24 C15 Si1 125.0(3) . . ?
C24 C15 C16 118.3(3) . . ?
C2 C1 Si1 118.9(3) . . ?
C6 C1 Si1 124.1(3) . . ?
C6 C1 C2 116.9(4) . . ?
C23 C18 C19 118.9(4) . . ?
C17 C18 C23 119.6(4) . . ?
C17 C18 C19 121.5(4) . . ?
C8 C7 Si1 120.3(3) . . ?
C8 C7 C12 117.8(3) . . ?
C12 C7 Si1 121.8(3) . . ?
C15 C16 H16 118.8 . . ?
C17 C16 C15 122.4(4) . . ?
C17 C16 H16 118.8 . . ?
C15 C24 C25 119.9(3) . . ?
C15 C24 C23 119.6(3) . . ?
C23 C24 C25 120.3(3) . . ?
C33 C34 C25 122.5(4) . . ?
C33 C34 C29 119.7(5) . . ?
C29 C34 C25 117.8(5) . . ?
C34 C25 C24 122.4(4) . . ?
C26 C25 C24 117.9(4) . . ?
C26 C25 C34 119.7(4) . . ?
C18 C23 C24 119.5(4) . . ?
C18 C23 C22 118.9(4) . . ?
C22 C23 C24 121.6(4) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 C18 120.3(4) . . ?
C16 C17 H17 119.9 . . ?
C7 C8 H8 119.4 . . ?
C9 C8 C7 121.2(4) . . ?
C9 C8 H8 119.4 . . ?
C25 C26 H26 119.5 . . ?
C25 C26 C27 121.0(5) . . ?
C27 C26 H26 119.5 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 119.9(4) . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 119.9 . . ?
C9 C10 C11 120.2(4) . . ?
C11 C10 H10 119.9 . . ?
C18 C19 H19 119.6 . . ?
C20 C19 C18 120.8(5) . . ?
C20 C19 H19 119.6 . . ?
C7 C12 H12 119.5 . . ?
C11 C12 C7 120.9(4) . . ?
C11 C12 H12 119.5 . . ?
C1 C2 H2 118.8 . . ?
C3 C2 C1 122.3(5) . . ?
C3 C2 H2 118.8 . . ?
C34 C33 H33 119.2 . . ?
C32 C33 C34 121.5(7) . . ?
C32 C33 H33 119.2 . . ?
Si1 C13 H13 118.1 . . ?
C14 C13 Si1 123.7(5) . . ?
C14 C13 H13 118.1 . . ?
C1 C6 H6 119.5 . . ?
C1 C6 C5 121.0(5) . . ?
C5 C6 H6 119.5 . . ?
C2 C3 H3 120.2 . . ?
C2 C3 C4 119.5(5) . . ?
C4 C3 H3 120.2 . . ?
C23 C22 H22 120.1 . . ?
C21 C22 C23 119.7(5) . . ?
C21 C22 H22 120.1 . . ?
C6 C5 H5 119.9 . . ?
C4 C5 C6 120.3(5) . . ?
C4 C5 H5 119.9 . . ?
C19 C20 H20 119.9 . . ?
C19 C20 C21 120.3(4) . . ?
C21 C20 H20 119.9 . . ?
C10 C11 C12 119.9(5) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 120.0(4) . . ?
C5 C4 H4 120.0 . . ?
C34 C29 C30 116.9(7) . . ?
C28 C29 C34 120.2(5) . . ?
C28 C29 C30 122.8(7) . . ?
C22 C21 C20 121.3(5) . . ?
C22 C21 H21 119.3 . . ?
C20 C21 H21 119.3 . . ?
C26 C27 H27 119.9 . . ?
C28 C27 C26 120.1(6) . . ?
C28 C27 H27 119.9 . . ?
C13 C14 H14A 120.0 . . ?
C13 C14 H14B 120.0 . . ?
H14A C14 H14B 120.0 . . ?
C29 C28 H28 119.4 . . ?
C27 C28 C29 121.1(5) . . ?
C27 C28 H28 119.4 . . ?
C33 C32 H32 120.6 . . ?
C33 C32 C31 118.9(8) . . ?
C31 C32 H32 120.6 . . ?
C32 C31 H31 119.1 . . ?
C30 C31 C32 121.8(7) . . ?
C30 C31 H31 119.1 . . ?
C29 C30 H30 119.5 . . ?
C31 C30 C29 121.1(8) . . ?
C31 C30 H30 119.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Si1 C15 C16 C17 -177.8(3) . . . . ?
Si1 C15 C24 C25 -11.2(5) . . . . ?
Si1 C15 C24 C23 173.6(3) . . . . ?
Si1 C1 C2 C3 177.3(4) . . . . ?
Si1 C1 C6 C5 -177.6(4) . . . . ?
Si1 C7 C8 C9 177.5(3) . . . . ?
Si1 C7 C12 C11 -178.0(4) . . . . ?
C15 Si1 C1 C2 55.5(4) . . . . ?
C15 Si1 C1 C6 -126.4(4) . . . . ?
C15 Si1 C7 C8 -160.7(3) . . . . ?
C15 Si1 C7 C12 17.3(4) . . . . ?
C15 Si1 C13 C14 -125.8(6) . . . . ?
C15 C16 C17 C18 3.1(7) . . . . ?
C15 C24 C25 C34 110.0(4) . . . . ?
C15 C24 C25 C26 -71.3(5) . . . . ?
C15 C24 C23 C18 5.3(5) . . . . ?
C15 C24 C23 C22 -174.5(3) . . . . ?
C1 Si1 C15 C16 29.3(3) . . . . ?
C1 Si1 C15 C24 -149.7(3) . . . . ?
C1 Si1 C7 C8 82.8(3) . . . . ?
C1 Si1 C7 C12 -99.2(3) . . . . ?
C1 Si1 C13 C14 -8.8(6) . . . . ?
C1 C2 C3 C4 0.0(8) . . . . ?
C1 C6 C5 C4 0.7(8) . . . . ?
C18 C23 C22 C21 -0.2(6) . . . . ?
C18 C19 C20 C21 0.1(8) . . . . ?
C7 Si1 C15 C16 -90.4(3) . . . . ?
C7 Si1 C15 C24 90.5(3) . . . . ?
C7 Si1 C1 C2 174.4(3) . . . . ?
C7 Si1 C1 C6 -7.4(4) . . . . ?
C7 Si1 C13 C14 110.9(6) . . . . ?
C7 C8 C9 C10 0.0(7) . . . . ?
C7 C12 C11 C10 0.9(8) . . . . ?
C16 C15 C24 C25 169.7(4) . . . . ?
C16 C15 C24 C23 -5.4(5) . . . . ?
C24 C15 C16 C17 1.3(6) . . . . ?
C24 C25 C26 C27 179.0(5) . . . . ?
C24 C23 C22 C21 179.5(4) . . . . ?
C34 C25 C26 C27 -2.3(7) . . . . ?
C34 C33 C32 C31 1.4(9) . . . . ?
C34 C29 C28 C27 -1.0(9) . . . . ?
C34 C29 C30 C31 -1.8(9) . . . . ?
C25 C24 C23 C18 -169.9(3) . . . . ?
C25 C24 C23 C22 10.4(5) . . . . ?
C25 C34 C33 C32 177.6(5) . . . . ?
C25 C34 C29 C28 0.1(7) . . . . ?
C25 C34 C29 C30 -177.5(5) . . . . ?
C25 C26 C27 C28 1.5(9) . . . . ?
C23 C18 C17 C16 -3.3(6) . . . . ?
C23 C18 C19 C20 0.6(7) . . . . ?
C23 C24 C25 C34 -74.9(5) . . . . ?
C23 C24 C25 C26 103.8(4) . . . . ?
C23 C22 C21 C20 1.0(8) . . . . ?
C17 C18 C23 C24 -0.9(5) . . . . ?
C17 C18 C23 C22 178.9(4) . . . . ?
C17 C18 C19 C20 -178.8(4) . . . . ?
C8 C7 C12 C11 0.0(6) . . . . ?
C8 C9 C10 C11 1.0(7) . . . . ?
C26 C27 C28 C29 0.2(10) . . . . ?
C9 C10 C11 C12 -1.5(8) . . . . ?
C19 C18 C23 C24 179.7(4) . . . . ?
C19 C18 C23 C22 -0.6(6) . . . . ?
C19 C18 C17 C16 176.1(4) . . . . ?
C19 C20 C21 C22 -1.0(8) . . . . ?
C12 C7 C8 C9 -0.5(6) . . . . ?
C2 C1 C6 C5 0.6(7) . . . . ?
C2 C3 C4 C5 1.4(8) . . . . ?
C33 C34 C25 C24 -1.6(6) . . . . ?
C33 C34 C25 C26 179.8(4) . . . . ?
C33 C34 C29 C28 -178.2(5) . . . . ?
C33 C34 C29 C30 4.2(7) . . . . ?
C33 C32 C31 C30 1.1(11) . . . . ?
C13 Si1 C15 C16 147.1(3) . . . . ?
C13 Si1 C15 C24 -32.0(4) . . . . ?
C13 Si1 C1 C2 -67.7(4) . . . . ?
C13 Si1 C1 C6 110.5(4) . . . . ?
C13 Si1 C7 C8 -34.2(4) . . . . ?
C13 Si1 C7 C12 143.7(3) . . . . ?
C6 C1 C2 C3 -1.0(7) . . . . ?
C6 C5 C4 C3 -1.8(9) . . . . ?
C29 C34 C25 C24 -179.9(4) . . . . ?
C29 C34 C25 C26 1.4(6) . . . . ?
C29 C34 C33 C32 -4.1(8) . . . . ?
C28 C29 C30 C31 -179.3(6) . . . . ?
C32 C31 C30 C29 -0.9(11) . . . . ?
C30 C29 C28 C27 176.5(7) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
