# Supplementary Information (SI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Ag4Si16Me32
_database_code_depnum_ccdc_archive 'CCDC 2400625'
loop_
_audit_author_name
_audit_author_address
'Yoshimasa Wada'
;The University of Tokyo
Japan
;
_audit_update_record             
;
2025-02-15 deposited with the CCDC.	2025-02-18 downloaded from the CCDC.
;

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C32 H96 Ag4 Si16'
_chemical_formula_moiety         'C32 H96 Ag4 Si16'
_chemical_formula_weight         1361.95
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      orthorhombic
_space_group_name_H-M_alt        'F d d d'
_space_group_name_Hall           '-F 2uv 2vw'
_space_group_IT_number           70
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y+1/4, -z+1/4'
'-x+1/4, y, -z+1/4'
'-x+1/4, -y+1/4, z'
'x, y+1/2, z+1/2'
'x, -y+3/4, -z+3/4'
'-x+1/4, y+1/2, -z+3/4'
'-x+1/4, -y+3/4, z+1/2'
'x+1/2, y, z+1/2'
'x+1/2, -y+1/4, -z+3/4'
'-x+3/4, y, -z+3/4'
'-x+3/4, -y+1/4, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+3/4, -z+1/4'
'-x+3/4, y+1/2, -z+1/4'
'-x+3/4, -y+3/4, z'
'-x, -y, -z'
'-x, y-1/4, z-1/4'
'x-1/4, -y, z-1/4'
'x-1/4, y-1/4, -z'
'-x, -y+1/2, -z+1/2'
'-x, y+1/4, z+1/4'
'x-1/4, -y+1/2, z+1/4'
'x-1/4, y+1/4, -z+1/2'
'-x+1/2, -y, -z+1/2'
'-x+1/2, y-1/4, z+1/4'
'x+1/4, -y, z+1/4'
'x+1/4, y-1/4, -z+1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, y+1/4, z-1/4'
'x+1/4, -y+1/2, z-1/4'
'x+1/4, y+1/4, -z'
#------------------------------------------------------------------------------
_cell_length_a                   26.7344(2)
_cell_length_b                   33.5536(3)
_cell_length_c                   43.8428(4)
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_volume                     39328.5(6)
_cell_formula_units_Z            24
_cell_measurement_reflns_used    59834
_cell_measurement_theta_min      1.79
_cell_measurement_theta_max      31.29
_cell_measurement_temperature    113
#------------------------------------------------------------------------------
_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_crystal_density_diffrn    1.380
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             16800.00
_exptl_absorpt_coefficient_mu    1.487
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_correction_T_min  0.573
_exptl_absorpt_correction_T_max  0.743

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      113
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 28.626
_diffrn_reflns_number            91861
_diffrn_reflns_av_unetI/netI     ?
_diffrn_reflns_av_R_equivalents  0.0252
_diffrn_reflns_theta_max         31.180
_diffrn_reflns_theta_min         1.784
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.939
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.939
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.939
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_k_min       -45
_diffrn_reflns_limit_k_max       48
_diffrn_reflns_limit_l_min       -63
_diffrn_reflns_limit_l_max       59
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             14970
_reflns_number_gt                12857
_reflns_threshold_expression     F²>2.0σ(F²)
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0268
_refine_ls_wR_factor_ref         0.0649
_refine_ls_wR_factor_gt          0.0618
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         14970
_refine_ls_number_parameters     378
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0267P)²+124.9861P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.007
_refine_diff_density_max         2.75
_refine_diff_density_min         -1.02
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Si Si 0.0817 0.0704
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.43575(2) 0.38216(2) 0.55469(2) 0.02522(3) Uani 1 1 d . . . . .
Ag2 Ag 0.375000 0.375000 0.50557(2) 0.02540(4) Uani 1 2 d S T P . .
Ag3 Ag 0.375000 0.375000 0.60354(2) 0.02219(4) Uani 1 2 d S T P . .
Ag4 Ag 0.81334(2) 0.375000 0.375000 0.02673(4) Uani 1 2 d S T P . .
Ag5 Ag 0.875000 0.375000 0.42362(2) 0.02393(4) Uani 1 2 d S T P . .
Si1 Si 0.46984(2) 0.36383(2) 0.50228(2) 0.02875(11) Uani 1 1 d . . . . .
Si2 Si 0.53398(2) 0.40116(2) 0.52709(2) 0.03317(12) Uani 1 1 d . . . . .
Si3 Si 0.53349(2) 0.40899(2) 0.58101(2) 0.03026(11) Uani 1 1 d . . . . .
Si4 Si 0.45534(2) 0.41564(2) 0.60585(2) 0.02225(9) Uani 1 1 d . . . . .
Si5 Si 0.47473(2) 0.38461(2) 0.45108(2) 0.03697(13) Uani 1 1 d . . . . .
Si6 Si 0.48790(3) 0.29548(2) 0.50476(2) 0.03995(14) Uani 1 1 d . . . . .
Si7 Si 0.42110(2) 0.47944(2) 0.60124(2) 0.02726(10) Uani 1 1 d . . . . .
Si8 Si 0.47151(2) 0.40468(2) 0.65765(2) 0.03008(11) Uani 1 1 d . . . . .
Si9 Si 0.78601(2) 0.34706(2) 0.42603(2) 0.02119(9) Uani 1 1 d . . . . .
Si10 Si 0.79352(2) 0.27769(2) 0.42252(2) 0.03117(11) Uani 1 1 d . . . . .
Si11 Si 0.71079(2) 0.36930(2) 0.40194(2) 0.02538(10) Uani 1 1 d . . . . .
Si12 Si 0.77555(2) 0.36290(2) 0.47757(2) 0.03078(11) Uani 1 1 d . . . . .
C1 C 0.44184(12) 0.34838(8) 0.42559(5) 0.0550(7) Uani 1 1 d . . . . .
H1A H 0.458165 0.322941 0.426721 0.066 Uiso 1 1 calc R U . . .
H1B H 0.442801 0.357935 0.404960 0.066 Uiso 1 1 calc R U . . .
H1C H 0.407680 0.345680 0.432015 0.066 Uiso 1 1 calc R U . . .
C2 C 0.54120(10) 0.38611(8) 0.43741(6) 0.0547(7) Uani 1 1 d . . . . .
H2A H 0.541797 0.392284 0.416038 0.066 Uiso 1 1 calc R U . . .
H2B H 0.556576 0.360618 0.440736 0.066 Uiso 1 1 calc R U . . .
H2C H 0.559241 0.406183 0.448477 0.066 Uiso 1 1 calc R U . . .
C3 C 0.44700(10) 0.43534(7) 0.44561(6) 0.0465(5) Uani 1 1 d . . . . .
H3A H 0.414301 0.436138 0.454644 0.056 Uiso 1 1 calc R U . . .
H3B H 0.444462 0.441006 0.424207 0.056 Uiso 1 1 calc R U . . .
H3C H 0.468008 0.454880 0.455185 0.056 Uiso 1 1 calc R U . . .
C4 C 0.50074(12) 0.28126(7) 0.54531(6) 0.0578(7) Uani 1 1 d . . . . .
H4A H 0.529836 0.295199 0.552438 0.069 Uiso 1 1 calc R U . . .
H4B H 0.506454 0.253054 0.546531 0.069 Uiso 1 1 calc R U . . .
H4C H 0.472515 0.288219 0.557754 0.069 Uiso 1 1 calc R U . . .
C5 C 0.54320(12) 0.28132(8) 0.48094(7) 0.0613(8) Uani 1 1 d . . . . .
H5A H 0.549262 0.253230 0.482881 0.074 Uiso 1 1 calc R U . . .
H5B H 0.572085 0.295793 0.487756 0.074 Uiso 1 1 calc R U . . .
H5C H 0.536619 0.287656 0.459970 0.074 Uiso 1 1 calc R U . . .
C6 C 0.43323(11) 0.26583(7) 0.49053(6) 0.0573(7) Uani 1 1 d . . . . .
H6A H 0.440216 0.237908 0.492701 0.069 Uiso 1 1 calc R U . . .
H6B H 0.427481 0.271886 0.469418 0.069 Uiso 1 1 calc R U . . .
H6C H 0.404010 0.272509 0.502182 0.069 Uiso 1 1 calc R U . . .
C7 C 0.59729(9) 0.37895(10) 0.51874(7) 0.0630(8) Uani 1 1 d . . . . .
H7A H 0.598731 0.352327 0.526703 0.076 Uiso 1 1 calc R U . . .
H7B H 0.622773 0.394897 0.528181 0.076 Uiso 1 1 calc R U . . .
H7C H 0.602601 0.378334 0.497092 0.076 Uiso 1 1 calc R U . . .
C8 C 0.53377(10) 0.45319(7) 0.51110(5) 0.0461(5) Uani 1 1 d . . . . .
H8A H 0.541659 0.452291 0.489750 0.055 Uiso 1 1 calc R U . . .
H8B H 0.558278 0.469020 0.521561 0.055 Uiso 1 1 calc R U . . .
H8C H 0.501268 0.464822 0.513832 0.055 Uiso 1 1 calc R U . . .
C9 C 0.56695(8) 0.36460(8) 0.59764(6) 0.0457(5) Uani 1 1 d . . . . .
H9A H 0.597690 0.360318 0.586809 0.055 Uiso 1 1 calc R U . . .
H9B H 0.546143 0.341406 0.595814 0.055 Uiso 1 1 calc R U . . .
H9C H 0.574071 0.369466 0.618779 0.055 Uiso 1 1 calc R U . . .
C10 C 0.57300(8) 0.45461(7) 0.58822(6) 0.0447(5) Uani 1 1 d . . . . .
H10A H 0.556371 0.477679 0.580171 0.054 Uiso 1 1 calc R U . . .
H10B H 0.604852 0.451500 0.578389 0.054 Uiso 1 1 calc R U . . .
H10C H 0.577897 0.457856 0.609769 0.054 Uiso 1 1 calc R U . . .
C11 C 0.35494(8) 0.47817(6) 0.61540(5) 0.0359(4) Uani 1 1 d . . . . .
H11A H 0.337111 0.457086 0.605349 0.043 Uiso 1 1 calc R U . . .
H11B H 0.339010 0.503180 0.611077 0.043 Uiso 1 1 calc R U . . .
H11C H 0.354831 0.473585 0.637009 0.043 Uiso 1 1 calc R U . . .
C12 C 0.41920(10) 0.49421(7) 0.56018(5) 0.0463(6) Uani 1 1 d . . . . .
H12A H 0.452672 0.498185 0.552868 0.056 Uiso 1 1 calc R U . . .
H12B H 0.400554 0.518500 0.558047 0.056 Uiso 1 1 calc R U . . .
H12C H 0.403381 0.473522 0.548524 0.056 Uiso 1 1 calc R U . . .
C13 C 0.45580(9) 0.51849(6) 0.62335(6) 0.0450(5) Uani 1 1 d . . . . .
H13A H 0.440940 0.544083 0.619665 0.054 Uiso 1 1 calc R U . . .
H13B H 0.490149 0.518917 0.616982 0.054 Uiso 1 1 calc R U . . .
H13C H 0.454065 0.512443 0.644728 0.054 Uiso 1 1 calc R U . . .
C14 C 0.48301(9) 0.35079(7) 0.66572(5) 0.0429(5) Uani 1 1 d . . . . .
H14A H 0.453656 0.335674 0.660689 0.051 Uiso 1 1 calc R U . . .
H14B H 0.490608 0.347396 0.686964 0.051 Uiso 1 1 calc R U . . .
H14C H 0.510668 0.341595 0.653659 0.051 Uiso 1 1 calc R U . . .
C15 C 0.41722(9) 0.42294(7) 0.68069(5) 0.0385(5) Uani 1 1 d . . . . .
H15A H 0.415282 0.451448 0.679290 0.046 Uiso 1 1 calc R U . . .
H15B H 0.421642 0.415317 0.701627 0.046 Uiso 1 1 calc R U . . .
H15C H 0.386880 0.411411 0.672986 0.046 Uiso 1 1 calc R U . . .
C16 C 0.52818(9) 0.43285(8) 0.67071(5) 0.0488(6) Uani 1 1 d . . . . .
H16A H 0.557231 0.422877 0.660345 0.059 Uiso 1 1 calc R U . . .
H16B H 0.532275 0.429440 0.692309 0.059 Uiso 1 1 calc R U . . .
H16C H 0.524053 0.460641 0.666171 0.059 Uiso 1 1 calc R U . . .
C17 C 0.85698(11) 0.26164(8) 0.43564(7) 0.0569(7) Uani 1 1 d . . . . .
H17A H 0.860578 0.233435 0.432690 0.068 Uiso 1 1 calc R U . . .
H17B H 0.860833 0.267837 0.456883 0.068 Uiso 1 1 calc R U . . .
H17C H 0.882093 0.275413 0.424068 0.068 Uiso 1 1 calc R U . . .
C18 C 0.78501(11) 0.26119(7) 0.38212(5) 0.0488(6) Uani 1 1 d . . . . .
H18A H 0.792105 0.233217 0.380547 0.059 Uiso 1 1 calc R U . . .
H18B H 0.807412 0.275795 0.369163 0.059 Uiso 1 1 calc R U . . .
H18C H 0.751128 0.266080 0.375897 0.059 Uiso 1 1 calc R U . . .
C19 C 0.74667(12) 0.25169(7) 0.44723(6) 0.0554(7) Uani 1 1 d . . . . .
H19A H 0.751434 0.259594 0.468068 0.067 Uiso 1 1 calc R U . . .
H19B H 0.751045 0.223383 0.445474 0.067 Uiso 1 1 calc R U . . .
H19C H 0.713505 0.258753 0.440806 0.067 Uiso 1 1 calc R U . . .
C20 C 0.82381(8) 0.33584(7) 0.50085(5) 0.0362(4) Uani 1 1 d . . . . .
H20A H 0.817567 0.307689 0.499935 0.043 Uiso 1 1 calc R U . . .
H20B H 0.822016 0.344631 0.521658 0.043 Uiso 1 1 calc R U . . .
H20C H 0.856511 0.341369 0.492851 0.043 Uiso 1 1 calc R U . . .
C21 C 0.71324(9) 0.34586(9) 0.49183(5) 0.0512(6) Uani 1 1 d . . . . .
H21A H 0.687254 0.357834 0.479814 0.061 Uiso 1 1 calc R U . . .
H21B H 0.709361 0.353622 0.512775 0.061 Uiso 1 1 calc R U . . .
H21C H 0.711095 0.317379 0.490236 0.061 Uiso 1 1 calc R U . . .
C22 C 0.78018(11) 0.41796(7) 0.48401(6) 0.0511(6) Uani 1 1 d . . . . .
H22A H 0.776394 0.423567 0.505354 0.061 Uiso 1 1 calc R U . . .
H22B H 0.754275 0.431255 0.472765 0.061 Uiso 1 1 calc R U . . .
H22C H 0.812246 0.427275 0.477202 0.061 Uiso 1 1 calc R U . . .
C23 C 0.65959(7) 0.33189(7) 0.40867(5) 0.0363(4) Uani 1 1 d . . . . .
H23A H 0.654767 0.328414 0.430207 0.044 Uiso 1 1 calc R U . . .
H23B H 0.668759 0.306870 0.399647 0.044 Uiso 1 1 calc R U . . .
H23C H 0.629116 0.341297 0.399602 0.044 Uiso 1 1 calc R U . . .
C24 C 0.68979(8) 0.41735(6) 0.42013(5) 0.0358(4) Uani 1 1 d . . . . .
H24A H 0.683773 0.413039 0.441466 0.043 Uiso 1 1 calc R U . . .
H24B H 0.659533 0.426308 0.410531 0.043 Uiso 1 1 calc R U . . .
H24C H 0.715347 0.437186 0.417668 0.043 Uiso 1 1 calc R U . . .


#==============================================================================
_computing_data_collection       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT Version 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL Version 2017/1 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2019)'
_computing_molecular_graphics    'CrystalStructure 4.3'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Si1 2.5473(5) . ?
Ag1 Si4 2.5628(5) . ?
Ag1 Ag3 2.69896(19) . ?
Ag1 Ag2 2.7077(2) . ?
Ag1 Si2 2.9607(5) . ?
Ag1 Si3 2.9948(5) . ?
Ag1 Ag1 3.2838(3) 16 ?
Ag2 Si1 2.5672(5) . ?
Ag2 Si1 2.5672(5) 16 ?
Ag3 Si4 2.5462(5) 16 ?
Ag3 Si4 2.5462(5) . ?
Ag4 Si9 2.5334(5) . ?
Ag4 Si9 2.5335(5) 6 ?
Ag4 Ag5 2.69447(19) . ?
Ag4 Ag5 2.69454(19) 6 ?
Ag4 Si11 2.9913(5) 6 ?
Ag4 Si11 2.9914(5) . ?
Ag4 Ag4 3.2968(4) 11_655 ?
Ag5 Si9 2.5594(5) 16_655 ?
Ag5 Si9 2.5595(5) . ?
Si1 Si6 2.3462(8) . ?
Si1 Si5 2.3540(8) . ?
Si1 Si2 2.3857(8) . ?
Si2 C8 1.881(2) . ?
Si2 C7 1.885(2) . ?
Si2 Si3 2.3787(8) . ?
Si3 C9 1.884(2) . ?
Si3 C10 1.887(2) . ?
Si3 Si4 2.3665(7) . ?
Si4 Si7 2.3369(7) . ?
Si4 Si8 2.3409(7) . ?
Si5 C1 1.871(3) . ?
Si5 C3 1.872(2) . ?
Si5 C2 1.876(3) . ?
Si6 C5 1.871(2) . ?
Si6 C4 1.873(3) . ?
Si6 C6 1.875(3) . ?
Si7 C12 1.868(2) . ?
Si7 C11 1.875(2) . ?
Si7 C13 1.875(2) . ?
Si8 C14 1.868(2) . ?
Si8 C15 1.872(2) . ?
Si8 C16 1.875(2) . ?
Si9 Si12 2.3381(7) . ?
Si9 Si10 2.3412(7) . ?
Si9 Si11 2.3908(7) . ?
Si10 C18 1.870(2) . ?
Si10 C17 1.871(3) . ?
Si10 C19 1.872(2) . ?
Si11 C23 1.881(2) . ?
Si11 C24 1.884(2) . ?
Si11 Si11 2.3930(10) 6 ?
Si12 C21 1.869(2) . ?
Si12 C22 1.873(2) . ?
Si12 C20 1.879(2) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Ag1 Si4 145.312(18) . . ?
Si1 Ag1 Ag3 155.470(14) . . ?
Si4 Ag1 Ag3 57.813(11) . . ?
Si1 Ag1 Ag2 58.392(13) . . ?
Si4 Ag1 Ag2 149.036(12) . . ?
Ag3 Ag1 Ag2 105.203(6) . . ?
Si1 Ag1 Si2 50.654(18) . . ?
Si4 Ag1 Si2 94.710(16) . . ?
Ag3 Ag1 Si2 151.314(13) . . ?
Ag2 Ag1 Si2 103.071(13) . . ?
Si1 Ag1 Si3 96.202(17) . . ?
Si4 Ag1 Si3 49.660(15) . . ?
Ag3 Ag1 Si3 104.236(12) . . ?
Ag2 Ag1 Si3 148.921(12) . . ?
Si2 Ag1 Si3 47.078(16) . . ?
Si1 Ag1 Ag1 108.577(13) . 16 ?
Si4 Ag1 Ag1 105.445(11) . 16 ?
Ag3 Ag1 Ag1 52.532(4) . 16 ?
Ag2 Ag1 Ag1 52.671(4) . 16 ?
Si2 Ag1 Ag1 155.350(12) . 16 ?
Si3 Ag1 Ag1 155.101(11) . 16 ?
Si1 Ag2 Si1 173.54(3) . 16 ?
Si1 Ag2 Ag1 128.633(14) . 16 ?
Si1 Ag2 Ag1 57.672(13) 16 16 ?
Si1 Ag2 Ag1 57.677(12) . . ?
Si1 Ag2 Ag1 128.628(14) 16 . ?
Ag1 Ag2 Ag1 74.657(7) 16 . ?
Si4 Ag3 Si4 175.45(2) 16 . ?
Si4 Ag3 Ag1 125.932(12) 16 . ?
Si4 Ag3 Ag1 58.410(11) . . ?
Si4 Ag3 Ag1 58.412(11) 16 16 ?
Si4 Ag3 Ag1 125.931(12) . 16 ?
Ag1 Ag3 Ag1 74.939(7) . 16 ?
Si9 Ag4 Si9 146.47(2) . 6 ?
Si9 Ag4 Ag5 58.528(11) . . ?
Si9 Ag4 Ag5 151.048(12) 6 . ?
Si9 Ag4 Ag5 151.048(12) . 6 ?
Si9 Ag4 Ag5 58.526(11) 6 6 ?
Ag5 Ag4 Ag5 104.567(8) . 6 ?
Si9 Ag4 Si11 96.197(16) . 6 ?
Si9 Ag4 Si11 50.453(15) 6 6 ?
Ag5 Ag4 Si11 150.814(11) . 6 ?
Ag5 Ag4 Si11 104.378(10) 6 6 ?
Si9 Ag4 Si11 50.452(15) . . ?
Si9 Ag4 Si11 96.199(16) 6 . ?
Ag5 Ag4 Si11 104.379(10) . . ?
Ag5 Ag4 Si11 150.813(11) 6 . ?
Si11 Ag4 Si11 47.16(2) 6 . ?
Si9 Ag4 Ag4 106.766(11) . 11_655 ?
Si9 Ag4 Ag4 106.765(11) 6 11_655 ?
Ag5 Ag4 Ag4 52.283(4) . 11_655 ?
Ag5 Ag4 Ag4 52.284(4) 6 11_655 ?
Si11 Ag4 Ag4 156.422(10) 6 11_655 ?
Si11 Ag4 Ag4 156.422(10) . 11_655 ?
Si9 Ag5 Si9 175.26(2) 16_655 . ?
Si9 Ag5 Ag4 126.970(12) 16_655 . ?
Si9 Ag5 Ag4 57.589(11) . . ?
Si9 Ag5 Ag4 57.592(11) 16_655 11_655 ?
Si9 Ag5 Ag4 126.968(12) . 11_655 ?
Ag4 Ag5 Ag4 75.434(8) . 11_655 ?
Si6 Si1 Si5 108.80(3) . . ?
Si6 Si1 Si2 110.13(3) . . ?
Si5 Si1 Si2 103.85(3) . . ?
Si6 Si1 Ag1 105.53(2) . . ?
Si5 Si1 Ag1 143.95(3) . . ?
Si2 Si1 Ag1 73.69(2) . . ?
Si6 Si1 Ag2 110.07(3) . . ?
Si5 Si1 Ag2 93.75(3) . . ?
Si2 Si1 Ag2 127.41(2) . . ?
Ag1 Si1 Ag2 63.932(13) . . ?
C8 Si2 C7 107.28(13) . . ?
C8 Si2 Si3 105.53(8) . . ?
C7 Si2 Si3 103.97(10) . . ?
C8 Si2 Si1 108.37(9) . . ?
C7 Si2 Si1 110.44(10) . . ?
Si3 Si2 Si1 120.48(3) . . ?
C8 Si2 Ag1 110.45(8) . . ?
C7 Si2 Ag1 142.24(11) . . ?
Si3 Si2 Ag1 67.214(18) . . ?
Si1 Si2 Ag1 55.661(16) . . ?
C9 Si3 C10 108.09(11) . . ?
C9 Si3 Si4 108.40(8) . . ?
C10 Si3 Si4 109.92(8) . . ?
C9 Si3 Si2 107.14(8) . . ?
C10 Si3 Si2 104.66(8) . . ?
Si4 Si3 Si2 118.21(3) . . ?
C9 Si3 Ag1 109.02(8) . . ?
C10 Si3 Ag1 142.84(8) . . ?
Si4 Si3 Ag1 55.633(16) . . ?
Si2 Si3 Ag1 65.708(19) . . ?
Si7 Si4 Si8 107.47(3) . . ?
Si7 Si4 Si3 113.11(3) . . ?
Si8 Si4 Si3 105.58(3) . . ?
Si7 Si4 Ag3 99.02(2) . . ?
Si8 Si4 Ag3 96.32(2) . . ?
Si3 Si4 Ag3 132.52(3) . . ?
Si7 Si4 Ag1 104.23(2) . . ?
Si8 Si4 Ag1 144.89(3) . . ?
Si3 Si4 Ag1 74.71(2) . . ?
Ag3 Si4 Ag1 63.777(12) . . ?
C1 Si5 C3 109.16(13) . . ?
C1 Si5 C2 105.77(13) . . ?
C3 Si5 C2 108.06(12) . . ?
C1 Si5 Si1 110.55(8) . . ?
C3 Si5 Si1 111.68(8) . . ?
C2 Si5 Si1 111.41(9) . . ?
C5 Si6 C4 108.67(14) . . ?
C5 Si6 C6 107.18(14) . . ?
C4 Si6 C6 108.88(14) . . ?
C5 Si6 Si1 112.64(9) . . ?
C4 Si6 Si1 109.33(8) . . ?
C6 Si6 Si1 110.06(9) . . ?
C12 Si7 C11 107.42(11) . . ?
C12 Si7 C13 109.05(12) . . ?
C11 Si7 C13 108.14(10) . . ?
C12 Si7 Si4 109.70(8) . . ?
C11 Si7 Si4 108.66(7) . . ?
C13 Si7 Si4 113.67(8) . . ?
C14 Si8 C15 110.01(11) . . ?
C14 Si8 C16 107.28(11) . . ?
C15 Si8 C16 107.26(11) . . ?
C14 Si8 Si4 111.49(8) . . ?
C15 Si8 Si4 109.21(7) . . ?
C16 Si8 Si4 111.49(8) . . ?
Si12 Si9 Si10 107.45(3) . . ?
Si12 Si9 Si11 104.79(2) . . ?
Si10 Si9 Si11 110.70(3) . . ?
Si12 Si9 Ag4 143.49(3) . . ?
Si10 Si9 Ag4 106.57(2) . . ?
Si11 Si9 Ag4 74.752(18) . . ?
Si12 Si9 Ag5 93.88(2) . . ?
Si10 Si9 Ag5 106.36(2) . . ?
Si11 Si9 Ag5 130.48(2) . . ?
Ag4 Si9 Ag5 63.882(12) . . ?
C18 Si10 C17 108.45(13) . . ?
C18 Si10 C19 109.20(12) . . ?
C17 Si10 C19 107.15(14) . . ?
C18 Si10 Si9 110.25(8) . . ?
C17 Si10 Si9 110.11(9) . . ?
C19 Si10 Si9 111.59(8) . . ?
C23 Si11 C24 106.72(10) . . ?
C23 Si11 Si9 109.54(7) . . ?
C24 Si11 Si9 109.32(7) . . ?
C23 Si11 Si11 105.16(7) . 6 ?
C24 Si11 Si11 106.33(7) . 6 ?
Si9 Si11 Si11 119.070(18) . 6 ?
C23 Si11 Ag4 140.51(7) . . ?
C24 Si11 Ag4 112.68(7) . . ?
Si9 Si11 Ag4 54.796(15) . . ?
Si11 Si11 Ag4 66.420(10) 6 . ?
C21 Si12 C22 108.07(13) . . ?
C21 Si12 C20 106.40(11) . . ?
C22 Si12 C20 110.45(10) . . ?
C21 Si12 Si9 111.12(8) . . ?
C22 Si12 Si9 111.23(8) . . ?
C20 Si12 Si9 109.45(7) . . ?
Si5 C1 H1A 109.5 . . ?
Si5 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si5 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si5 C2 H2A 109.5 . . ?
Si5 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si5 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si5 C3 H3A 109.5 . . ?
Si5 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si5 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si6 C4 H4A 109.5 . . ?
Si6 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si6 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si6 C5 H5A 109.5 . . ?
Si6 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si6 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si6 C6 H6A 109.5 . . ?
Si6 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si6 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si2 C7 H7A 109.5 . . ?
Si2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si2 C8 H8A 109.5 . . ?
Si2 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si2 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si3 C9 H9A 109.5 . . ?
Si3 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si3 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si3 C10 H10A 109.5 . . ?
Si3 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si3 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si7 C11 H11A 109.5 . . ?
Si7 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si7 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si7 C12 H12A 109.5 . . ?
Si7 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si7 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si7 C13 H13A 109.5 . . ?
Si7 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si7 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si8 C14 H14A 109.5 . . ?
Si8 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si8 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si8 C15 H15A 109.5 . . ?
Si8 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si8 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si8 C16 H16A 109.5 . . ?
Si8 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si8 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si10 C17 H17A 109.5 . . ?
Si10 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si10 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si10 C18 H18A 109.5 . . ?
Si10 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si10 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si10 C19 H19A 109.5 . . ?
Si10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si12 C20 H20A 109.5 . . ?
Si12 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si12 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si12 C21 H21A 109.5 . . ?
Si12 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si12 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si12 C22 H22A 109.5 . . ?
Si12 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si12 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si11 C23 H23A 109.5 . . ?
Si11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si11 C24 H24A 109.5 . . ?
Si11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?


#==============================================================================
# Additional structures and associated data_? identifiers
# should be added at this point if there is more than one 
# structure analysis in the CIF.





#==============================================================================
#     End of CIF
#==============================================================================
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Ag4Ge4Si12Me32
_database_code_depnum_ccdc_archive 'CCDC 2400626'
loop_
_audit_author_name
_audit_author_address
'Yoshimasa Wada'
;The University of Tokyo
Japan
;
_audit_update_record             
;
2024-11-05 deposited with the CCDC.	2025-02-18 downloaded from the CCDC.
;

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C32 H96 Ag4 Ge4 Si12'
_chemical_formula_moiety         'C32 H96 Ag4 Ge4 Si12'
_chemical_formula_weight         1539.97
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      orthorhombic
_space_group_name_H-M_alt        'F d d d'
_space_group_name_Hall           '-F 2uv 2vw'
_space_group_IT_number           70
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y+1/4, -z+1/4'
'-x+1/4, y, -z+1/4'
'-x+1/4, -y+1/4, z'
'x, y+1/2, z+1/2'
'x, -y+3/4, -z+3/4'
'-x+1/4, y+1/2, -z+3/4'
'-x+1/4, -y+3/4, z+1/2'
'x+1/2, y, z+1/2'
'x+1/2, -y+1/4, -z+3/4'
'-x+3/4, y, -z+3/4'
'-x+3/4, -y+1/4, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+3/4, -z+1/4'
'-x+3/4, y+1/2, -z+1/4'
'-x+3/4, -y+3/4, z'
'-x, -y, -z'
'-x, y-1/4, z-1/4'
'x-1/4, -y, z-1/4'
'x-1/4, y-1/4, -z'
'-x, -y+1/2, -z+1/2'
'-x, y+1/4, z+1/4'
'x-1/4, -y+1/2, z+1/4'
'x-1/4, y+1/4, -z+1/2'
'-x+1/2, -y, -z+1/2'
'-x+1/2, y-1/4, z+1/4'
'x+1/4, -y, z+1/4'
'x+1/4, y-1/4, -z+1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, y+1/4, z-1/4'
'x+1/4, -y+1/2, z-1/4'
'x+1/4, y+1/4, -z'
#------------------------------------------------------------------------------
_cell_length_a                   26.89331(19)
_cell_length_b                   33.7727(2)
_cell_length_c                   43.9810(3)
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_volume                     39946.2(5)
_cell_formula_units_Z            24
_cell_measurement_reflns_used    172148
_cell_measurement_theta_min      1.85
_cell_measurement_theta_max      31.28
_cell_measurement_temperature    113
#------------------------------------------------------------------------------
_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             18528.00
_exptl_absorpt_coefficient_mu    3.162
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_correction_T_min  0.461
_exptl_absorpt_correction_T_max  0.729

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      113
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 28.626
_diffrn_reflns_number            93261
_diffrn_reflns_av_unetI/netI     ?
_diffrn_reflns_av_R_equivalents  0.0307
_diffrn_reflns_theta_max         31.137
_diffrn_reflns_theta_min         1.520
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.944
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.944
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.944
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -48
_diffrn_reflns_limit_k_max       48
_diffrn_reflns_limit_l_min       -60
_diffrn_reflns_limit_l_max       58
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             15219
_reflns_number_gt                12613
_reflns_threshold_expression     F²>2.0σ(F²)
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0256
_refine_ls_wR_factor_ref         0.0577
_refine_ls_wR_factor_gt          0.0542
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         15219
_refine_ls_number_parameters     378
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0256P)²+79.5922P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.007
_refine_diff_density_max         1.41
_refine_diff_density_min         -0.36
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ge Ge 0.1547 1.8001
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Si Si 0.0817 0.0704
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.43448(2) 0.38174(2) 0.55438(2) 0.02777(4) Uani 1 1 d . . . . .
Ag2 Ag 0.375000 0.375000 0.60377(2) 0.02439(4) Uani 1 2 d S T P . .
Ag3 Ag 0.375000 0.375000 0.50474(2) 0.02837(5) Uani 1 2 d S T P . .
Ag4 Ag 0.875000 0.375000 0.42432(2) 0.02569(4) Uani 1 2 d S T P . .
Ag5 Ag 0.81496(2) 0.375000 0.375000 0.02862(5) Uani 1 2 d S T P . .
Ge1 Ge 0.45588(2) 0.41634(2) 0.60565(2) 0.02424(4) Uani 1 1 d . . . . .
Ge2 Ge 0.47068(2) 0.36328(2) 0.50173(2) 0.03193(5) Uani 1 1 d . . . . .
Ge3 Ge 0.78539(2) 0.34632(2) 0.42618(2) 0.02271(4) Uani 1 1 d . . . . .
Si1 Si 0.42050(2) 0.48050(2) 0.60093(2) 0.03098(11) Uani 1 1 d . . . . .
Si2 Si 0.47189(2) 0.40498(2) 0.65807(2) 0.03391(12) Uani 1 1 d . . . . .
Si3 Si 0.53464(2) 0.40919(2) 0.58046(2) 0.03415(12) Uani 1 1 d . . . . .
Si4 Si 0.53484(2) 0.40176(2) 0.52681(2) 0.03732(13) Uani 1 1 d . . . . .
Si5 Si 0.47504(3) 0.38446(2) 0.44996(2) 0.04182(15) Uani 1 1 d . . . . .
Si6 Si 0.48893(3) 0.29430(2) 0.50451(2) 0.04457(16) Uani 1 1 d . . . . .
Si7 Si 0.77507(2) 0.36219(2) 0.47841(2) 0.03407(12) Uani 1 1 d . . . . .
Si8 Si 0.70992(2) 0.36932(2) 0.40179(2) 0.02726(11) Uani 1 1 d . . . . .
Si9 Si 0.79303(2) 0.27634(2) 0.42229(2) 0.03520(12) Uani 1 1 d . . . . .
C1 C 0.45502(10) 0.51920(7) 0.62308(6) 0.0500(6) Uani 1 1 d . . . . .
H1A H 0.489742 0.519996 0.616341 0.060 Uiso 1 1 calc R U . . .
H1B H 0.453781 0.512718 0.644788 0.060 Uiso 1 1 calc R U . . .
H1C H 0.439581 0.545113 0.619692 0.060 Uiso 1 1 calc R U . . .
C2 C 0.35494(8) 0.47852(6) 0.61528(5) 0.0409(5) Uani 1 1 d . . . . .
H2A H 0.355133 0.473726 0.637259 0.049 Uiso 1 1 calc R U . . .
H2B H 0.337059 0.457037 0.605047 0.049 Uiso 1 1 calc R U . . .
H2C H 0.338354 0.503761 0.611053 0.049 Uiso 1 1 calc R U . . .
C3 C 0.41827(10) 0.49494(8) 0.55990(5) 0.0530(6) Uani 1 1 d . . . . .
H3A H 0.452156 0.499339 0.552430 0.064 Uiso 1 1 calc R U . . .
H3B H 0.398893 0.519340 0.557663 0.064 Uiso 1 1 calc R U . . .
H3C H 0.402604 0.473711 0.548115 0.064 Uiso 1 1 calc R U . . .
C4 C 0.48301(10) 0.35122(7) 0.66569(5) 0.0488(6) Uani 1 1 d . . . . .
H4A H 0.452898 0.336144 0.660857 0.059 Uiso 1 1 calc R U . . .
H4B H 0.491393 0.347528 0.687192 0.059 Uiso 1 1 calc R U . . .
H4C H 0.510569 0.341828 0.653025 0.059 Uiso 1 1 calc R U . . .
C5 C 0.41745(9) 0.42314(7) 0.68068(5) 0.0435(5) Uani 1 1 d . . . . .
H5A H 0.386853 0.411195 0.672783 0.052 Uiso 1 1 calc R U . . .
H5B H 0.415274 0.452024 0.679031 0.052 Uiso 1 1 calc R U . . .
H5C H 0.421741 0.415697 0.702057 0.052 Uiso 1 1 calc R U . . .
C6 C 0.52853(10) 0.43290(8) 0.67096(6) 0.0540(7) Uani 1 1 d . . . . .
H6A H 0.533033 0.429216 0.692887 0.065 Uiso 1 1 calc R U . . .
H6B H 0.524247 0.461138 0.666538 0.065 Uiso 1 1 calc R U . . .
H6C H 0.557841 0.422915 0.660168 0.065 Uiso 1 1 calc R U . . .
C7 C 0.57397(8) 0.45448(8) 0.58785(6) 0.0508(6) Uani 1 1 d . . . . .
H7A H 0.557060 0.477951 0.579804 0.061 Uiso 1 1 calc R U . . .
H7B H 0.606254 0.451418 0.577788 0.061 Uiso 1 1 calc R U . . .
H7C H 0.579001 0.457569 0.609788 0.061 Uiso 1 1 calc R U . . .
C8 C 0.56729(9) 0.36488(8) 0.59726(6) 0.0517(6) Uani 1 1 d . . . . .
H8A H 0.598226 0.359978 0.586105 0.062 Uiso 1 1 calc R U . . .
H8B H 0.545676 0.341607 0.595723 0.062 Uiso 1 1 calc R U . . .
H8C H 0.574930 0.370045 0.618683 0.062 Uiso 1 1 calc R U . . .
C9 C 0.53294(10) 0.45355(8) 0.51092(6) 0.0522(6) Uani 1 1 d . . . . .
H9A H 0.540367 0.452791 0.489116 0.063 Uiso 1 1 calc R U . . .
H9B H 0.557708 0.469957 0.521331 0.063 Uiso 1 1 calc R U . . .
H9C H 0.499760 0.464824 0.514058 0.063 Uiso 1 1 calc R U . . .
C10 C 0.59785(10) 0.38054(10) 0.51796(7) 0.0683(8) Uani 1 1 d . . . . .
H10A H 0.623578 0.396704 0.527702 0.082 Uiso 1 1 calc R U . . .
H10B H 0.603023 0.380513 0.495899 0.082 Uiso 1 1 calc R U . . .
H10C H 0.599784 0.353354 0.525650 0.082 Uiso 1 1 calc R U . . .
C11 C 0.54104(11) 0.38621(9) 0.43636(6) 0.0611(8) Uani 1 1 d . . . . .
H11A H 0.541650 0.393264 0.414745 0.073 Uiso 1 1 calc R U . . .
H11B H 0.556497 0.360187 0.439168 0.073 Uiso 1 1 calc R U . . .
H11C H 0.559476 0.406082 0.448037 0.073 Uiso 1 1 calc R U . . .
C12 C 0.44690(10) 0.43473(7) 0.44490(6) 0.0514(6) Uani 1 1 d . . . . .
H12A H 0.467590 0.454500 0.455200 0.062 Uiso 1 1 calc R U . . .
H12B H 0.413409 0.435007 0.453682 0.062 Uiso 1 1 calc R U . . .
H12C H 0.444970 0.441004 0.423180 0.062 Uiso 1 1 calc R U . . .
C13 C 0.44218(12) 0.34803(8) 0.42471(6) 0.0623(8) Uani 1 1 d . . . . .
H13A H 0.458858 0.322277 0.425938 0.075 Uiso 1 1 calc R U . . .
H13B H 0.442962 0.357547 0.403667 0.075 Uiso 1 1 calc R U . . .
H13C H 0.407570 0.345248 0.431352 0.075 Uiso 1 1 calc R U . . .
C14 C 0.54443(12) 0.28071(8) 0.48076(7) 0.0693(9) Uani 1 1 d . . . . .
H14A H 0.538612 0.288672 0.459628 0.083 Uiso 1 1 calc R U . . .
H14B H 0.549686 0.252017 0.481671 0.083 Uiso 1 1 calc R U . . .
H14C H 0.573947 0.294339 0.488580 0.083 Uiso 1 1 calc R U . . .
C15 C 0.43464(12) 0.26506(8) 0.49027(7) 0.0648(8) Uani 1 1 d . . . . .
H15A H 0.429424 0.270724 0.468654 0.078 Uiso 1 1 calc R U . . .
H15B H 0.404791 0.272394 0.501753 0.078 Uiso 1 1 calc R U . . .
H15C H 0.441247 0.236736 0.492957 0.078 Uiso 1 1 calc R U . . .
C16 C 0.50162(12) 0.28057(8) 0.54476(6) 0.0636(8) Uani 1 1 d . . . . .
H16A H 0.507084 0.251934 0.546167 0.076 Uiso 1 1 calc R U . . .
H16B H 0.473112 0.287972 0.557423 0.076 Uiso 1 1 calc R U . . .
H16C H 0.531342 0.294558 0.551887 0.076 Uiso 1 1 calc R U . . .
C17 C 0.82379(9) 0.33567(7) 0.50108(5) 0.0404(5) Uani 1 1 d . . . . .
H17A H 0.856742 0.341884 0.492856 0.049 Uiso 1 1 calc R U . . .
H17B H 0.818074 0.307050 0.499889 0.049 Uiso 1 1 calc R U . . .
H17C H 0.822013 0.344198 0.522350 0.049 Uiso 1 1 calc R U . . .
C18 C 0.71322(9) 0.34472(9) 0.49241(5) 0.0565(7) Uani 1 1 d . . . . .
H18A H 0.686759 0.357398 0.480587 0.068 Uiso 1 1 calc R U . . .
H18B H 0.709499 0.351684 0.513925 0.068 Uiso 1 1 calc R U . . .
H18C H 0.710985 0.315918 0.490073 0.068 Uiso 1 1 calc R U . . .
C19 C 0.77921(12) 0.41696(8) 0.48468(6) 0.0591(8) Uani 1 1 d . . . . .
H19A H 0.775470 0.422724 0.506395 0.071 Uiso 1 1 calc R U . . .
H19B H 0.752723 0.430245 0.473271 0.071 Uiso 1 1 calc R U . . .
H19C H 0.811618 0.426572 0.477643 0.071 Uiso 1 1 calc R U . . .
C20 C 0.68965(9) 0.41702(7) 0.42019(5) 0.0396(5) Uani 1 1 d . . . . .
H20A H 0.658616 0.426094 0.410816 0.048 Uiso 1 1 calc R U . . .
H20B H 0.715486 0.437145 0.417352 0.048 Uiso 1 1 calc R U . . .
H20C H 0.684298 0.412634 0.441970 0.048 Uiso 1 1 calc R U . . .
C21 C 0.65868(8) 0.33217(7) 0.40864(5) 0.0401(5) Uani 1 1 d . . . . .
H21A H 0.667899 0.306710 0.399549 0.048 Uiso 1 1 calc R U . . .
H21B H 0.627797 0.341719 0.399367 0.048 Uiso 1 1 calc R U . . .
H21C H 0.653755 0.328779 0.430566 0.048 Uiso 1 1 calc R U . . .
C22 C 0.85614(11) 0.26061(8) 0.43557(7) 0.0639(8) Uani 1 1 d . . . . .
H22A H 0.881642 0.274632 0.423852 0.077 Uiso 1 1 calc R U . . .
H22B H 0.859950 0.232011 0.432622 0.077 Uiso 1 1 calc R U . . .
H22C H 0.859856 0.266958 0.457196 0.077 Uiso 1 1 calc R U . . .
C23 C 0.78480(11) 0.26038(8) 0.38199(6) 0.0546(6) Uani 1 1 d . . . . .
H23A H 0.809151 0.274003 0.369128 0.065 Uiso 1 1 calc R U . . .
H23B H 0.751129 0.267039 0.375181 0.065 Uiso 1 1 calc R U . . .
H23C H 0.789813 0.231701 0.380486 0.065 Uiso 1 1 calc R U . . .
C24 C 0.74622(12) 0.25082(7) 0.44697(6) 0.0638(8) Uani 1 1 d . . . . .
H24A H 0.750673 0.259293 0.468109 0.077 Uiso 1 1 calc R U . . .
H24B H 0.750877 0.222094 0.445569 0.077 Uiso 1 1 calc R U . . .
H24C H 0.712622 0.257700 0.440160 0.077 Uiso 1 1 calc R U . . .


#==============================================================================
_computing_data_collection       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_structure_solution    'SHELXT Version 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL Version 2017/1 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2019)'
_computing_molecular_graphics    'CrystalStructure 4.3'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ge2 2.5883(2) . ?
Ag1 Ge1 2.6040(2) . ?
Ag1 Ag2 2.7070(2) . ?
Ag1 Ag3 2.7160(2) . ?
Ag1 Si4 3.0352(6) . ?
Ag1 Si3 3.0708(6) . ?
Ag1 Ag1 3.2313(3) 16 ?
Ag2 Ge1 2.58579(19) 16 ?
Ag2 Ge1 2.58588(19) . ?
Ag3 Ge2 2.6068(2) 16 ?
Ag3 Ge2 2.6068(2) . ?
Ag4 Ge3 2.59853(18) 16_655 ?
Ag4 Ge3 2.59861(18) . ?
Ag4 Ag5 2.70415(19) . ?
Ag4 Ag5 2.70421(19) 11_655 ?
Ag5 Ge3 2.57641(19) 6 ?
Ag5 Ge3 2.57652(19) . ?
Ag5 Si8 3.0667(5) 6 ?
Ag5 Si8 3.0668(5) . ?
Ag5 Ag5 3.2292(4) 11_655 ?
Ge1 Si1 2.3755(6) . ?
Ge1 Si2 2.3765(6) . ?
Ge1 Si3 2.4027(6) . ?
Ge2 Si6 2.3837(6) . ?
Ge2 Si5 2.3894(6) . ?
Ge2 Si4 2.4256(7) . ?
Ge3 Si7 2.3747(6) . ?
Ge3 Si9 2.3785(6) . ?
Ge3 Si8 2.4236(6) . ?
Si1 C3 1.870(2) . ?
Si1 C2 1.874(2) . ?
Si1 C1 1.876(2) . ?
Si2 C4 1.870(2) . ?
Si2 C5 1.873(2) . ?
Si2 C6 1.879(2) . ?
Si3 C8 1.886(2) . ?
Si3 C7 1.888(2) . ?
Si3 Si4 2.3726(9) . ?
Si4 C10 1.881(3) . ?
Si4 C9 1.884(3) . ?
Si5 C12 1.872(2) . ?
Si5 C11 1.874(3) . ?
Si5 C13 1.879(3) . ?
Si6 C16 1.862(3) . ?
Si6 C15 1.871(3) . ?
Si6 C14 1.879(3) . ?
Si7 C18 1.869(3) . ?
Si7 C19 1.874(3) . ?
Si7 C17 1.874(2) . ?
Si8 C20 1.883(2) . ?
Si8 C21 1.888(2) . ?
Si8 Si8 2.3872(10) 6 ?
Si9 C23 1.866(2) . ?
Si9 C22 1.872(3) . ?
Si9 C24 1.872(3) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge2 Ag1 Ge1 143.101(9) . . ?
Ge2 Ag1 Ag2 156.905(8) . . ?
Ge1 Ag1 Ag2 58.234(5) . . ?
Ge2 Ag1 Ag3 58.813(6) . . ?
Ge1 Ag1 Ag3 149.748(7) . . ?
Ag2 Ag1 Ag3 106.853(6) . . ?
Ge2 Ag1 Si4 50.338(14) . . ?
Ge1 Ag1 Si4 92.835(14) . . ?
Ag2 Ag1 Si4 149.851(14) . . ?
Ag3 Ag1 Si4 102.783(13) . . ?
Ge2 Ag1 Si3 94.409(13) . . ?
Ge1 Ag1 Si3 49.257(12) . . ?
Ag2 Ag1 Si3 104.127(12) . . ?
Ag3 Ag1 Si3 147.359(13) . . ?
Si4 Ag1 Si3 45.726(17) . . ?
Ge2 Ag1 Ag1 109.785(7) . 16 ?
Ge1 Ag1 Ag1 106.379(6) . 16 ?
Ag2 Ag1 Ag1 53.354(4) . 16 ?
Ag3 Ag1 Ag1 53.499(4) . 16 ?
Si4 Ag1 Ag1 155.755(13) . 16 ?
Si3 Ag1 Ag1 155.635(12) . 16 ?
Ge1 Ag2 Ge1 176.322(12) 16 . ?
Ge1 Ag2 Ag1 58.892(6) 16 16 ?
Ge1 Ag2 Ag1 124.621(8) . 16 ?
Ge1 Ag2 Ag1 124.624(8) 16 . ?
Ge1 Ag2 Ag1 58.890(6) . . ?
Ag1 Ag2 Ag1 73.289(8) 16 . ?
Ge2 Ag3 Ge2 174.175(12) 16 . ?
Ge2 Ag3 Ag1 127.548(8) 16 . ?
Ge2 Ag3 Ag1 58.148(6) . . ?
Ge2 Ag3 Ag1 58.147(6) 16 16 ?
Ge2 Ag3 Ag1 127.548(8) . 16 ?
Ag1 Ag3 Ag1 73.003(7) . 16 ?
Ge3 Ag4 Ge3 176.389(11) 16_655 . ?
Ge3 Ag4 Ag5 125.380(8) 16_655 . ?
Ge3 Ag4 Ag5 58.100(5) . . ?
Ge3 Ag4 Ag5 58.097(5) 16_655 11_655 ?
Ge3 Ag4 Ag5 125.383(8) . 11_655 ?
Ag5 Ag4 Ag5 73.322(8) . 11_655 ?
Ge3 Ag5 Ge3 144.037(12) 6 . ?
Ge3 Ag5 Ag4 58.899(5) 6 6 ?
Ge3 Ag5 Ag4 152.277(7) . 6 ?
Ge3 Ag5 Ag4 152.278(7) 6 . ?
Ge3 Ag5 Ag4 58.898(5) . . ?
Ag4 Ag5 Ag4 106.677(8) 6 . ?
Ge3 Ag5 Si8 49.948(11) 6 6 ?
Ge3 Ag5 Si8 94.286(12) . 6 ?
Ag4 Ag5 Si8 103.997(10) 6 6 ?
Ag4 Ag5 Si8 149.109(11) . 6 ?
Ge3 Ag5 Si8 94.290(12) 6 . ?
Ge3 Ag5 Si8 49.944(11) . . ?
Ag4 Ag5 Si8 149.113(11) 6 . ?
Ag4 Ag5 Si8 103.993(10) . . ?
Si8 Ag5 Si8 45.81(2) 6 . ?
Ge3 Ag5 Ag5 107.981(6) 6 11_655 ?
Ge3 Ag5 Ag5 107.982(6) . 11_655 ?
Ag4 Ag5 Ag5 53.338(4) 6 11_655 ?
Ag4 Ag5 Ag5 53.340(4) . 11_655 ?
Si8 Ag5 Ag5 157.096(10) 6 11_655 ?
Si8 Ag5 Ag5 157.094(10) . 11_655 ?
Si1 Ge1 Si2 107.74(2) . . ?
Si1 Ge1 Si3 113.85(2) . . ?
Si2 Ge1 Si3 105.75(2) . . ?
Si1 Ge1 Ag2 98.790(15) . . ?
Si2 Ge1 Ag2 95.528(16) . . ?
Si3 Ge1 Ag2 132.257(17) . . ?
Si1 Ge1 Ag1 104.182(16) . . ?
Si2 Ge1 Ag1 143.865(17) . . ?
Si3 Ge1 Ag1 75.543(16) . . ?
Ag2 Ge1 Ag1 62.876(6) . . ?
Si6 Ge2 Si5 109.36(2) . . ?
Si6 Ge2 Si4 110.72(3) . . ?
Si5 Ge2 Si4 103.77(2) . . ?
Si6 Ge2 Ag1 105.483(17) . . ?
Si5 Ge2 Ag1 143.016(18) . . ?
Si4 Ge2 Ag1 74.430(15) . . ?
Si6 Ge2 Ag3 110.43(2) . . ?
Si5 Ge2 Ag3 92.947(19) . . ?
Si4 Ge2 Ag3 126.703(16) . . ?
Ag1 Ge2 Ag3 63.039(7) . . ?
Si7 Ge3 Si9 107.70(2) . . ?
Si7 Ge3 Si8 104.95(2) . . ?
Si9 Ge3 Si8 111.03(2) . . ?
Si7 Ge3 Ag5 142.775(18) . . ?
Si9 Ge3 Ag5 106.494(16) . . ?
Si8 Ge3 Ag5 75.595(14) . . ?
Si7 Ge3 Ag4 93.136(17) . . ?
Si9 Ge3 Ag4 106.735(17) . . ?
Si8 Ge3 Ag4 130.032(15) . . ?
Ag5 Ge3 Ag4 63.002(7) . . ?
C3 Si1 C2 107.72(12) . . ?
C3 Si1 C1 109.59(13) . . ?
C2 Si1 C1 108.38(11) . . ?
C3 Si1 Ge1 109.58(8) . . ?
C2 Si1 Ge1 108.35(7) . . ?
C1 Si1 Ge1 113.07(9) . . ?
C4 Si2 C5 110.35(11) . . ?
C4 Si2 C6 107.66(12) . . ?
C5 Si2 C6 108.01(12) . . ?
C4 Si2 Ge1 111.08(8) . . ?
C5 Si2 Ge1 108.70(7) . . ?
C6 Si2 Ge1 111.00(9) . . ?
C8 Si3 C7 108.33(12) . . ?
C8 Si3 Si4 107.74(9) . . ?
C7 Si3 Si4 104.81(9) . . ?
C8 Si3 Ge1 108.03(8) . . ?
C7 Si3 Ge1 109.46(8) . . ?
Si4 Si3 Ge1 118.12(3) . . ?
C8 Si3 Ag1 108.38(9) . . ?
C7 Si3 Ag1 143.16(8) . . ?
Si4 Si3 Ag1 66.35(2) . . ?
Ge1 Si3 Ag1 55.200(12) . . ?
C10 Si4 C9 107.54(14) . . ?
C10 Si4 Si3 104.38(10) . . ?
C9 Si4 Si3 105.70(9) . . ?
C10 Si4 Ge2 110.03(11) . . ?
C9 Si4 Ge2 108.02(9) . . ?
Si3 Si4 Ge2 120.48(3) . . ?
C10 Si4 Ag1 143.05(11) . . ?
C9 Si4 Ag1 109.32(8) . . ?
Si3 Si4 Ag1 67.929(19) . . ?
Ge2 Si4 Ag1 55.232(13) . . ?
C12 Si5 C11 108.45(13) . . ?
C12 Si5 C13 109.48(13) . . ?
C11 Si5 C13 106.10(14) . . ?
C12 Si5 Ge2 111.41(8) . . ?
C11 Si5 Ge2 111.11(10) . . ?
C13 Si5 Ge2 110.13(9) . . ?
C16 Si6 C15 109.26(14) . . ?
C16 Si6 C14 108.80(15) . . ?
C15 Si6 C14 107.75(15) . . ?
C16 Si6 Ge2 109.28(9) . . ?
C15 Si6 Ge2 109.75(9) . . ?
C14 Si6 Ge2 111.95(9) . . ?
C18 Si7 C19 108.43(14) . . ?
C18 Si7 C17 107.20(11) . . ?
C19 Si7 C17 110.61(11) . . ?
C18 Si7 Ge3 110.58(9) . . ?
C19 Si7 Ge3 110.99(9) . . ?
C17 Si7 Ge3 108.97(7) . . ?
C20 Si8 C21 106.78(11) . . ?
C20 Si8 Si8 106.67(8) . 6 ?
C21 Si8 Si8 105.33(7) . 6 ?
C20 Si8 Ge3 109.05(7) . . ?
C21 Si8 Ge3 109.12(8) . . ?
Si8 Si8 Ge3 119.237(15) 6 . ?
C20 Si8 Ag5 112.23(8) . . ?
C21 Si8 Ag5 140.82(7) . . ?
Si8 Si8 Ag5 67.092(10) 6 . ?
Ge3 Si8 Ag5 54.461(11) . . ?
C23 Si9 C22 108.78(13) . . ?
C23 Si9 C24 109.76(13) . . ?
C22 Si9 C24 107.33(15) . . ?
C23 Si9 Ge3 110.20(9) . . ?
C22 Si9 Ge3 109.75(10) . . ?
C24 Si9 Ge3 110.96(9) . . ?
Si1 C1 H1A 109.5 . . ?
Si1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si1 C2 H2A 109.5 . . ?
Si1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si2 C4 H4A 109.5 . . ?
Si2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si2 C5 H5A 109.5 . . ?
Si2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si2 C6 H6A 109.5 . . ?
Si2 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si2 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si3 C7 H7A 109.5 . . ?
Si3 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si3 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si3 C8 H8A 109.5 . . ?
Si3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
Si3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4 C9 H9A 109.5 . . ?
Si4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si4 C10 H10A 109.5 . . ?
Si4 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Si4 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si5 C11 H11A 109.5 . . ?
Si5 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si5 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si5 C12 H12A 109.5 . . ?
Si5 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si5 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si5 C13 H13A 109.5 . . ?
Si5 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si5 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si6 C14 H14A 109.5 . . ?
Si6 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si6 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si6 C15 H15A 109.5 . . ?
Si6 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si6 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si6 C16 H16A 109.5 . . ?
Si6 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si6 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si7 C17 H17A 109.5 . . ?
Si7 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si7 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si7 C18 H18A 109.5 . . ?
Si7 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si7 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si7 C19 H19A 109.5 . . ?
Si7 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si7 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si8 C20 H20A 109.5 . . ?
Si8 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si8 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si8 C21 H21A 109.5 . . ?
Si8 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si8 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si9 C22 H22A 109.5 . . ?
Si9 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si9 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si9 C23 H23A 109.5 . . ?
Si9 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si9 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si9 C24 H24A 109.5 . . ?
Si9 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Si9 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?


#==============================================================================
# Additional structures and associated data_? identifiers
# should be added at this point if there is more than one 
# structure analysis in the CIF.





#==============================================================================
#     End of CIF
#==============================================================================
