# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_23_a
_database_code_depnum_ccdc_archive 'CCDC 2326041'
loop_
_audit_author_name
_audit_author_address
jiang
;zhejiang normal university
China
;
_audit_update_record             
;
2024-01-17 deposited with the CCDC.	2024-02-26 downloaded from the CCDC.
;
_audit_creation_date             2023-10-04
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'2(C54 H52 Ag2 P4), 2(C2 H3 N), 2(C3 H7 N O), Mo8 O26'
_chemical_formula_sum            'C118 H124 Ag4 Mo8 N4 O28 P8'
_chemical_formula_weight         3492.96
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.2663(4)
_cell_length_b                   20.3743(6)
_cell_length_c                   22.7754(5)
_cell_angle_alpha                90
_cell_angle_beta                 97.1750(10)
_cell_angle_gamma                90
_cell_volume                     6568.2(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9889
_cell_measurement_temperature    293.00
_cell_measurement_theta_max      26.38
_cell_measurement_theta_min      2.46
_shelx_estimated_absorpt_T_max   0.890
_shelx_estimated_absorpt_T_min   0.866
_exptl_absorpt_coefficient_mu    1.484
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.766
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3456
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0411
_diffrn_reflns_av_unetI/netI     0.0393
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            44774
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.402
_diffrn_reflns_theta_min         2.193
_diffrn_ambient_temperature      293.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'BRUKER D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10669
_reflns_number_total             13449
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.494
_refine_diff_density_min         -0.582
_refine_diff_density_rms         0.082
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     799
_refine_ls_number_reflns         13449
_refine_ls_number_restraints     97
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0295
_refine_ls_restrained_S_all      1.046
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0299P)²+2.8903P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0695
_refine_ls_wR_factor_ref         0.0762
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C2_4-N1_4
 1.5 with sigma of 0.02
3. Rigid bond restraints
 N1_3, C1_3, C2_3
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Uiso/Uaniso restraints and constraints
C2'_4 \\sim C3_4 \\sim C3'_4 \\sim C1_4 \\sim C1'_4 \\sim C2_4: within 2A with
sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C1_3 \\sim N1_3 \\sim C2_3: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02 within 2A
5. Rigid body (RIGU) restrains
 O1_4, N1_4, C1_4, C2_4, C3_4, C1'_4, C2'_4, C3'_4
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
6. Others
 Sof(C1')=Sof(H1')=Sof(C2')=Sof(H2'A)=Sof(H2'B)=Sof(H2'C)=Sof(C3')=Sof(H3'A)=
 Sof(H3'B)=Sof(H3'C)=1-FVAR(1)
 Sof(C1)=Sof(H1)=Sof(C2)=Sof(H2A)=Sof(H2B)=Sof(H2C)=Sof(C3)=Sof(H3A)=Sof(H3B)=
 Sof(H3C)=FVAR(1)
7.a Secondary CH2 refined with riding coordinates:
 C25(H25A,H25B), C26(H26A,H26B), C27(H27A,H27B), C25(H25A,H25B), C26(H26A,
 H26B), C27(H27A,H27B)
7.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C18(H18), C19(H19), C20(H20),
  C21(H21), C23(H23), C24(H24), C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7),
 C8(H8), C9(H9), C11(H11), C12(H12), C13(H13), C14(H14), C15(H15), C17(H17),
 C18(H18), C19(H19), C20(H20), C21(H21), C23(H23), C24(H24), C1(H1), C1'(H1')
7.c Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C2'(H2'A,H2'B,H2'C),
 C3'(H3'A,H3'B,H3'C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.55188(2) 0.77422(2) 0.52259(2) 0.05578(9) Uani 1 1 d . . . . .
Ag2 Ag 0.36346(2) 0.62877(2) 0.69607(2) 0.05104(8) Uani 1 1 d . . . . .
P1_1 P 0.51468(6) 0.63844(4) 0.75688(3) 0.03621(18) Uani 1 1 d . . . . .
P2_1 P 0.69476(6) 0.76352(4) 0.59048(4) 0.04028(19) Uani 1 1 d . . . . .
C1_1 C 0.9476(4) 0.7650(3) 0.4845(2) 0.0916(18) Uani 1 1 d . . . . .
H1_1 H 0.995742 0.765293 0.460513 0.110 Uiso 1 1 calc R U . . .
C2_1 C 0.9016(4) 0.8225(3) 0.4947(2) 0.0930(18) Uani 1 1 d . . . . .
H2_1 H 0.919940 0.861629 0.478490 0.112 Uiso 1 1 calc R U . . .
C3_1 C 0.8279(3) 0.8220(2) 0.52912(18) 0.0708(12) Uani 1 1 d . . . . .
H3_1 H 0.796100 0.860747 0.535482 0.085 Uiso 1 1 calc R U . . .
C4_1 C 0.8014(2) 0.76335(18) 0.55417(14) 0.0461(8) Uani 1 1 d . . . . .
C5_1 C 0.8496(3) 0.7070(2) 0.54487(18) 0.0587(10) Uani 1 1 d . . . . .
H5_1 H 0.833347 0.667952 0.562180 0.070 Uiso 1 1 calc R U . . .
C6_1 C 0.9230(3) 0.7077(3) 0.5095(2) 0.0777(14) Uani 1 1 d . . . . .
H6_1 H 0.955066 0.669106 0.503052 0.093 Uiso 1 1 calc R U . . .
C7_1 C 0.7300(4) 0.9142(3) 0.7413(2) 0.0828(15) Uani 1 1 d . . . . .
H7_1 H 0.735384 0.943595 0.772802 0.099 Uiso 1 1 calc R U . . .
C8_1 C 0.6528(4) 0.9157(3) 0.7006(2) 0.0931(17) Uani 1 1 d . . . . .
H8_1 H 0.605071 0.945951 0.704268 0.112 Uiso 1 1 calc R U . . .
C9_1 C 0.6439(3) 0.8719(2) 0.6528(2) 0.0741(13) Uani 1 1 d . . . . .
H9_1 H 0.590825 0.873492 0.624649 0.089 Uiso 1 1 calc R U . . .
C10_1 C 0.7132(3) 0.82671(18) 0.64748(14) 0.0470(8) Uani 1 1 d . . . . .
C11_1 C 0.7914(3) 0.8260(2) 0.69003(17) 0.0630(11) Uani 1 1 d . . . . .
H11_1 H 0.839195 0.795480 0.687426 0.076 Uiso 1 1 calc R U . . .
C12_1 C 0.7993(4) 0.8704(2) 0.73649(19) 0.0800(15) Uani 1 1 d . . . . .
H12_1 H 0.852627 0.869904 0.764488 0.096 Uiso 1 1 calc R U . . .
C13_1 C 0.5717(6) 0.8360(3) 0.8511(3) 0.108(2) Uani 1 1 d . . . . .
H13_1 H 0.583244 0.876625 0.869234 0.130 Uiso 1 1 calc R U . . .
C14_1 C 0.4834(5) 0.8207(3) 0.8265(3) 0.129(3) Uani 1 1 d . . . . .
H14_1 H 0.434312 0.850361 0.828318 0.154 Uiso 1 1 calc R U . . .
C15_1 C 0.4658(3) 0.7604(2) 0.7984(2) 0.0854(15) Uani 1 1 d . . . . .
H15_1 H 0.404854 0.750104 0.781556 0.103 Uiso 1 1 calc R U . . .
C16_1 C 0.5369(2) 0.71653(17) 0.79521(14) 0.0426(8) Uani 1 1 d . . . . .
C17_1 C 0.6267(3) 0.7329(2) 0.82221(18) 0.0647(11) Uani 1 1 d . . . . .
H17_1 H 0.676005 0.703151 0.821701 0.078 Uiso 1 1 calc R U . . .
C18_1 C 0.6436(4) 0.7929(3) 0.8498(2) 0.0810(15) Uani 1 1 d . . . . .
H18_1 H 0.704049 0.803675 0.867281 0.097 Uiso 1 1 calc R U . . .
C19_1 C 0.5699(4) 0.4901(2) 0.90893(19) 0.0889(17) Uani 1 1 d . . . . .
H19_1 H 0.581388 0.460929 0.940427 0.107 Uiso 1 1 calc R U . . .
C20_1 C 0.5063(6) 0.5377(3) 0.9099(3) 0.136(3) Uani 1 1 d . . . . .
H20_1 H 0.471665 0.540716 0.941787 0.163 Uiso 1 1 calc R U . . .
C21_1 C 0.4907(5) 0.5830(3) 0.8640(2) 0.112(2) Uani 1 1 d . . . . .
H21_1 H 0.446732 0.616383 0.865921 0.134 Uiso 1 1 calc R U . . .
C22_1 C 0.5394(2) 0.57886(16) 0.81636(14) 0.0399(7) Uani 1 1 d . . . . .
C23_1 C 0.6000(3) 0.5279(2) 0.8148(2) 0.0759(14) Uani 1 1 d . . . . .
H23_1 H 0.630596 0.521647 0.781459 0.091 Uiso 1 1 calc R U . . .
C24_1 C 0.6171(4) 0.4848(3) 0.8621(2) 0.0944(18) Uani 1 1 d . . . . .
H24_1 H 0.661966 0.451828 0.861210 0.113 Uiso 1 1 calc R U . . .
C25_1 C 0.6136(2) 0.63143(16) 0.71300(13) 0.0382(7) Uani 1 1 d . . . . .
H25A_1 H 0.672790 0.632109 0.739047 0.046 Uiso 1 1 calc R U . . .
H25B_1 H 0.609404 0.590059 0.691760 0.046 Uiso 1 1 calc R U . . .
C26_1 C 0.6112(2) 0.68828(17) 0.66899(14) 0.0428(8) Uani 1 1 d . . . . .
H26A_1 H 0.554178 0.685081 0.641067 0.051 Uiso 1 1 calc R U . . .
H26B_1 H 0.608810 0.729406 0.690213 0.051 Uiso 1 1 calc R U . . .
C27_1 C 0.6969(2) 0.68880(17) 0.63498(14) 0.0417(8) Uani 1 1 d . . . . .
H27A_1 H 0.695436 0.650578 0.609500 0.050 Uiso 1 1 calc R U . . .
H27B_1 H 0.754491 0.687261 0.662510 0.050 Uiso 1 1 calc R U . . .
P3_2 P 0.39812(7) 0.81342(5) 0.48058(4) 0.0483(2) Uani 1 1 d . . . . .
P4_2 P 0.21814(6) 0.66030(5) 0.63626(4) 0.0420(2) Uani 1 1 d . . . . .
C1_2 C 0.0847(4) 0.8484(3) 0.7002(3) 0.0951(17) Uani 1 1 d . . . . .
H1_2 H 0.058816 0.886927 0.713068 0.114 Uiso 1 1 calc R U . . .
C2_2 C 0.0585(3) 0.8259(3) 0.6459(2) 0.0844(15) Uani 1 1 d . . . . .
H2_2 H 0.012563 0.848222 0.621048 0.101 Uiso 1 1 calc R U . . .
C3_2 C 0.0984(3) 0.7700(2) 0.6261(2) 0.0766(14) Uani 1 1 d . . . . .
H3_2 H 0.080685 0.756471 0.587322 0.092 Uiso 1 1 calc R U . . .
C4_2 C 0.1637(2) 0.73356(19) 0.66178(15) 0.0478(9) Uani 1 1 d . . . . .
C5_2 C 0.1893(4) 0.7570(3) 0.7172(2) 0.100(2) Uani 1 1 d . . . . .
H5_2 H 0.234039 0.734580 0.742913 0.120 Uiso 1 1 calc R U . . .
C6_2 C 0.1491(5) 0.8146(4) 0.7360(3) 0.136(3) Uani 1 1 d . . . . .
H6_2 H 0.167432 0.829840 0.774222 0.163 Uiso 1 1 calc R U . . .
C7_2 C -0.0196(3) 0.5098(2) 0.5963(2) 0.0775(13) Uani 1 1 d . . . . .
H7_2 H -0.068249 0.479966 0.586208 0.093 Uiso 1 1 calc R U . . .
C8_2 C -0.0355(3) 0.5636(2) 0.6271(2) 0.0743(13) Uani 1 1 d . . . . .
H8_2 H -0.094516 0.570006 0.639469 0.089 Uiso 1 1 calc R U . . .
C9_2 C 0.0348(3) 0.6099(2) 0.6407(2) 0.0646(11) Uani 1 1 d . . . . .
H9_2 H 0.021783 0.648023 0.660569 0.078 Uiso 1 1 calc R U . . .
C10_2 C 0.1239(2) 0.59988(18) 0.62505(15) 0.0450(8) Uani 1 1 d . . . . .
C11_2 C 0.1400(3) 0.5435(2) 0.5948(3) 0.0860(16) Uani 1 1 d . . . . .
H11_2 H 0.199902 0.535326 0.584461 0.103 Uiso 1 1 calc R U . . .
C12_2 C 0.0676(4) 0.4983(3) 0.5794(3) 0.1023(19) Uani 1 1 d . . . . .
H12_2 H 0.078573 0.460790 0.557891 0.123 Uiso 1 1 calc R U . . .
C13_2 C 0.3020(9) 1.0081(4) 0.5566(4) 0.152(4) Uani 1 1 d . . . . .
H13_2 H 0.283228 1.047420 0.572332 0.182 Uiso 1 1 calc R U . . .
C14_2 C 0.2383(7) 0.9634(4) 0.5363(4) 0.157(4) Uani 1 1 d . . . . .
H14_2 H 0.174646 0.971856 0.538029 0.189 Uiso 1 1 calc R U . . .
C15_2 C 0.2648(5) 0.9033(3) 0.5123(3) 0.119(2) Uani 1 1 d . . . . .
H15_2 H 0.218961 0.872708 0.498314 0.142 Uiso 1 1 calc R U . . .
C16_2 C 0.3585(4) 0.8903(2) 0.50988(18) 0.0687(12) Uani 1 1 d . . . . .
C17_2 C 0.4241(5) 0.9357(3) 0.5313(2) 0.0969(17) Uani 1 1 d . . . . .
H17_2 H 0.488121 0.927146 0.531055 0.116 Uiso 1 1 calc R U . . .
C18_2 C 0.3946(7) 0.9957(3) 0.5538(3) 0.139(3) Uani 1 1 d . . . . .
H18_2 H 0.439507 1.027275 0.567042 0.166 Uiso 1 1 calc R U . . .
C19_2 C 0.3939(4) 0.8368(3) 0.2799(2) 0.0865(17) Uani 1 1 d . . . . .
H19_2 H 0.395962 0.840676 0.239433 0.104 Uiso 1 1 calc R U . . .
C20_2 C 0.3592(4) 0.8875(3) 0.3109(2) 0.0882(17) Uani 1 1 d . . . . .
H20_2 H 0.337074 0.925485 0.291133 0.106 Uiso 1 1 calc R U . . .
C21_2 C 0.3572(3) 0.8819(2) 0.3722(2) 0.0698(12) Uani 1 1 d . . . . .
H21_2 H 0.334336 0.916193 0.393395 0.084 Uiso 1 1 calc R U . . .
C22_2 C 0.3897(3) 0.82506(19) 0.40070(16) 0.0525(9) Uani 1 1 d . . . . .
C23_2 C 0.4238(3) 0.7750(2) 0.36805(18) 0.0630(11) Uani 1 1 d . . . . .
H23_2 H 0.446192 0.736570 0.386889 0.076 Uiso 1 1 calc R U . . .
C24_2 C 0.4247(4) 0.7815(3) 0.30837(19) 0.0781(14) Uani 1 1 d . . . . .
H24_2 H 0.446980 0.747183 0.287082 0.094 Uiso 1 1 calc R U . . .
C25_2 C 0.3053(2) 0.75431(18) 0.48955(15) 0.0465(8) Uani 1 1 d . . . . .
H25A_2 H 0.245043 0.771996 0.472082 0.056 Uiso 1 1 calc R U . . .
H25B_2 H 0.316914 0.714340 0.468483 0.056 Uiso 1 1 calc R U . . .
C26_2 C 0.2997(2) 0.73789(19) 0.55440(15) 0.0484(9) Uani 1 1 d . . . . .
H26A_2 H 0.276774 0.775829 0.574047 0.058 Uiso 1 1 calc R U . . .
H26B_2 H 0.362278 0.727359 0.573815 0.058 Uiso 1 1 calc R U . . .
C27_2 C 0.2336(2) 0.67978(18) 0.55990(15) 0.0464(8) Uani 1 1 d . . . . .
H27A_2 H 0.258738 0.641527 0.541871 0.056 Uiso 1 1 calc R U . . .
H27B_2 H 0.172410 0.689546 0.538105 0.056 Uiso 1 1 calc R U . . .
N1_3 N 0.6328(5) 0.8313(4) 0.4329(3) 0.147(3) Uani 1 1 d . U . . .
C1_3 C 0.6712(6) 0.7928(5) 0.4088(3) 0.125(3) Uani 1 1 d . U . . .
C2_3 C 0.7240(6) 0.7456(4) 0.3804(3) 0.156(3) Uani 1 1 d . U . . .
H2A_3 H 0.681508 0.718621 0.354789 0.235 Uiso 1 1 calc R U . . .
H2B_3 H 0.759378 0.718572 0.409827 0.235 Uiso 1 1 calc R U . . .
H2C_3 H 0.766530 0.767746 0.357634 0.235 Uiso 1 1 calc R U . . .
O1_4 O 0.2613(5) 0.6125(4) 0.8001(3) 0.185(3) Uani 1 1 d . . . . .
N1_4 N 0.1707(6) 0.5251(5) 0.7853(3) 0.148(2) Uani 1 1 d D . . . .
C1_4 C 0.1802(15) 0.5935(12) 0.7956(8) 0.141(4) Uani 0.478(9) 1 d . U P A 1
H1_4 H 0.129137 0.621188 0.798586 0.169 Uiso 0.478(9) 1 calc R U P A 1
C2_4 C 0.2295(16) 0.4795(11) 0.7622(11) 0.184(6) Uani 0.478(9) 1 d D U P A 1
H2A_4 H 0.193614 0.454846 0.731283 0.276 Uiso 0.478(9) 1 calc R U P A 1
H2B_4 H 0.255499 0.450201 0.793057 0.276 Uiso 0.478(9) 1 calc R U P A 1
H2C_4 H 0.279901 0.502144 0.746503 0.276 Uiso 0.478(9) 1 calc R U P A 1
C3_4 C 0.0706(13) 0.4966(12) 0.7761(10) 0.167(6) Uani 0.478(9) 1 d . U P A 1
H3A_4 H 0.066314 0.460801 0.803021 0.251 Uiso 0.478(9) 1 calc R U P A 1
H3B_4 H 0.056759 0.481059 0.736136 0.251 Uiso 0.478(9) 1 calc R U P A 1
H3C_4 H 0.026025 0.530029 0.783269 0.251 Uiso 0.478(9) 1 calc R U P A 1
C1'_4 C 0.2611(13) 0.5491(12) 0.7925(8) 0.145(4) Uani 0.522(9) 1 d . U P A 2
H1'_4 H 0.315088 0.523621 0.792077 0.174 Uiso 0.522(9) 1 calc R U P A 2
C2'_4 C 0.1792(18) 0.4507(12) 0.7849(12) 0.209(7) Uani 0.522(9) 1 d . U P A 2
H2'A_4 H 0.174454 0.435382 0.744715 0.313 Uiso 0.522(9) 1 calc R U P A 2
H2'B_4 H 0.129372 0.431706 0.803973 0.313 Uiso 0.522(9) 1 calc R U P A 2
H2'C_4 H 0.239193 0.437905 0.805583 0.313 Uiso 0.522(9) 1 calc R U P A 2
C3'_4 C 0.0867(12) 0.5588(11) 0.7934(8) 0.155(6) Uani 0.522(9) 1 d . U P A 2
H3'A_4 H 0.102210 0.599888 0.812856 0.233 Uiso 0.522(9) 1 calc R U P A 2
H3'B_4 H 0.050238 0.532617 0.817338 0.233 Uiso 0.522(9) 1 calc R U P A 2
H3'C_4 H 0.050568 0.566699 0.755653 0.233 Uiso 0.522(9) 1 calc R U P A 2
Mo1_5 Mo 0.55052(2) 0.54463(2) 0.35222(2) 0.03683(7) Uani 1 1 d . . . . .
Mo2_5 Mo 0.35238(2) 0.54318(2) 0.41006(2) 0.03276(7) Uani 1 1 d . . . . .
Mo3_5 Mo 0.47050(2) 0.57112(2) 0.53843(2) 0.02853(6) Uani 1 1 d . . . . .
Mo4_5 Mo 0.66598(2) 0.57271(2) 0.48274(2) 0.03562(7) Uani 1 1 d . . . . .
O1_5 O 0.64821(18) 0.65518(12) 0.47668(10) 0.0497(6) Uani 1 1 d . . . . .
O2_5 O 0.78091(16) 0.56419(13) 0.51001(11) 0.0516(6) Uani 1 1 d . . . . .
O3_5 O 0.66777(15) 0.54617(12) 0.40339(9) 0.0424(5) Uani 1 1 d . . . . .
O4_5 O 0.53688(18) 0.62625(12) 0.34014(11) 0.0536(6) Uani 1 1 d . . . . .
O5_5 O 0.58399(18) 0.51339(14) 0.28880(10) 0.0548(6) Uani 1 1 d . . . . .
O6_5 O 0.41986(15) 0.52037(11) 0.34627(8) 0.0359(5) Uani 1 1 d . . . . .
O7_5 O 0.34702(17) 0.62599(11) 0.40304(10) 0.0478(6) Uani 1 1 d . . . . .
O8_5 O 0.24285(16) 0.51652(13) 0.38394(10) 0.0526(6) Uani 1 1 d . . . . .
O9_5 O 0.35091(13) 0.54094(10) 0.49769(8) 0.0325(4) Uani 1 1 d . . . . .
O10_5 O 0.44185(15) 0.56264(11) 0.61049(9) 0.0376(5) Uani 1 1 d . . . . .
O11_5 O 0.46513(16) 0.65313(11) 0.52521(10) 0.0435(5) Uani 1 1 d . . . . .
O12_5 O 0.60670(14) 0.56152(9) 0.55742(8) 0.0304(4) Uani 1 1 d . . . . .
O13_5 O 0.51165(13) 0.54238(9) 0.45372(8) 0.0290(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P2_1 2.4097(9) . ?
Ag1 P3_2 2.4167(10) . ?
Ag2 P1_1 2.4217(9) . ?
Ag2 P4_2 2.4209(9) . ?
P1_1 C16_1 1.823(3) . ?
P1_1 C22_1 1.820(3) . ?
P1_1 C25_1 1.833(3) . ?
P2_1 C4_1 1.821(4) . ?
P2_1 C10_1 1.824(3) . ?
P2_1 C27_1 1.827(3) . ?
C1_1 H1_1 0.9300 . ?
C1_1 C2_1 1.375(8) . ?
C1_1 C6_1 1.365(7) . ?
C2_1 H2_1 0.9300 . ?
C2_1 C3_1 1.389(6) . ?
C3_1 H3_1 0.9300 . ?
C3_1 C4_1 1.397(5) . ?
C4_1 C5_1 1.368(5) . ?
C5_1 H5_1 0.9300 . ?
C5_1 C6_1 1.399(6) . ?
C6_1 H6_1 0.9300 . ?
C7_1 H7_1 0.9300 . ?
C7_1 C8_1 1.348(7) . ?
C7_1 C12_1 1.347(7) . ?
C8_1 H8_1 0.9300 . ?
C8_1 C9_1 1.401(6) . ?
C9_1 H9_1 0.9300 . ?
C9_1 C10_1 1.367(6) . ?
C10_1 C11_1 1.384(5) . ?
C11_1 H11_1 0.9300 . ?
C11_1 C12_1 1.386(6) . ?
C12_1 H12_1 0.9300 . ?
C13_1 H13_1 0.9300 . ?
C13_1 C14_1 1.350(8) . ?
C13_1 C18_1 1.353(8) . ?
C14_1 H14_1 0.9300 . ?
C14_1 C15_1 1.393(7) . ?
C15_1 H15_1 0.9300 . ?
C15_1 C16_1 1.361(5) . ?
C16_1 C17_1 1.391(5) . ?
C17_1 H17_1 0.9300 . ?
C17_1 C18_1 1.382(6) . ?
C18_1 H18_1 0.9300 . ?
C19_1 H19_1 0.9300 . ?
C19_1 C20_1 1.331(7) . ?
C19_1 C24_1 1.334(6) . ?
C20_1 H20_1 0.9300 . ?
C20_1 C21_1 1.391(7) . ?
C21_1 H21_1 0.9300 . ?
C21_1 C22_1 1.363(5) . ?
C22_1 C23_1 1.354(5) . ?
C23_1 H23_1 0.9300 . ?
C23_1 C24_1 1.389(6) . ?
C24_1 H24_1 0.9300 . ?
C25_1 H25A_1 0.9700 . ?
C25_1 H25B_1 0.9700 . ?
C25_1 C26_1 1.529(4) . ?
C26_1 H26A_1 0.9700 . ?
C26_1 H26B_1 0.9700 . ?
C26_1 C27_1 1.527(4) . ?
C27_1 H27A_1 0.9700 . ?
C27_1 H27B_1 0.9700 . ?
P3_2 C16_2 1.821(4) . ?
P3_2 C22_2 1.824(4) . ?
P3_2 C25_2 1.821(4) . ?
P4_2 C4_2 1.812(4) . ?
P4_2 C10_2 1.817(4) . ?
P4_2 C27_2 1.824(3) . ?
C1_2 H1_2 0.9300 . ?
C1_2 C2_2 1.326(7) . ?
C1_2 C6_2 1.342(8) . ?
C2_2 H2_2 0.9300 . ?
C2_2 C3_2 1.374(6) . ?
C3_2 H3_2 0.9300 . ?
C3_2 C4_2 1.375(6) . ?
C4_2 C5_2 1.357(5) . ?
C5_2 H5_2 0.9300 . ?
C5_2 C6_2 1.396(7) . ?
C6_2 H6_2 0.9300 . ?
C7_2 H7_2 0.9300 . ?
C7_2 C8_2 1.336(7) . ?
C7_2 C12_2 1.368(6) . ?
C8_2 H8_2 0.9300 . ?
C8_2 C9_2 1.383(6) . ?
C9_2 H9_2 0.9300 . ?
C9_2 C10_2 1.378(5) . ?
C10_2 C11_2 1.373(6) . ?
C11_2 H11_2 0.9300 . ?
C11_2 C12_2 1.395(6) . ?
C12_2 H12_2 0.9300 . ?
C13_2 H13_2 0.9300 . ?
C13_2 C14_2 1.328(12) . ?
C13_2 C18_2 1.355(11) . ?
C14_2 H14_2 0.9300 . ?
C14_2 C15_2 1.411(9) . ?
C15_2 H15_2 0.9300 . ?
C15_2 C16_2 1.371(7) . ?
C16_2 C17_2 1.362(7) . ?
C17_2 H17_2 0.9300 . ?
C17_2 C18_2 1.411(9) . ?
C18_2 H18_2 0.9300 . ?
C19_2 H19_2 0.9300 . ?
C19_2 C20_2 1.377(8) . ?
C19_2 C24_2 1.344(7) . ?
C20_2 H20_2 0.9300 . ?
C20_2 C21_2 1.407(7) . ?
C21_2 H21_2 0.9300 . ?
C21_2 C22_2 1.379(5) . ?
C22_2 C23_2 1.386(6) . ?
C23_2 H23_2 0.9300 . ?
C23_2 C24_2 1.367(6) . ?
C24_2 H24_2 0.9300 . ?
C25_2 H25A_2 0.9700 . ?
C25_2 H25B_2 0.9700 . ?
C25_2 C26_2 1.526(5) . ?
C26_2 H26A_2 0.9700 . ?
C26_2 H26B_2 0.9700 . ?
C26_2 C27_2 1.528(5) . ?
C27_2 H27A_2 0.9700 . ?
C27_2 H27B_2 0.9700 . ?
N1_3 C1_3 1.138(11) . ?
C1_3 C2_3 1.424(11) . ?
C2_3 H2A_3 0.9600 . ?
C2_3 H2B_3 0.9600 . ?
C2_3 H2C_3 0.9600 . ?
O1_4 C1_4 1.21(2) . ?
O1_4 C1'_4 1.30(2) . ?
N1_4 C1_4 1.42(2) . ?
N1_4 C2_4 1.398(15) . ?
N1_4 C3_4 1.53(2) . ?
N1_4 C1'_4 1.37(2) . ?
N1_4 C2'_4 1.52(2) . ?
N1_4 C3'_4 1.413(16) . ?
C1_4 H1_4 0.9300 . ?
C2_4 H2A_4 0.9600 . ?
C2_4 H2B_4 0.9600 . ?
C2_4 H2C_4 0.9600 . ?
C3_4 H3A_4 0.9600 . ?
C3_4 H3B_4 0.9600 . ?
C3_4 H3C_4 0.9600 . ?
C1'_4 H1'_4 0.9300 . ?
C2'_4 H2'A_4 0.9600 . ?
C2'_4 H2'B_4 0.9600 . ?
C2'_4 H2'C_4 0.9600 . ?
C3'_4 H3'A_4 0.9600 . ?
C3'_4 H3'B_4 0.9600 . ?
C3'_4 H3'C_4 0.9600 . ?
Mo1_5 O3_5 1.916(2) . ?
Mo1_5 O4_5 1.693(2) . ?
Mo1_5 O5_5 1.701(2) . ?
Mo1_5 O6_5 1.917(2) . ?
Mo1_5 O10_5 2.342(2) 3_666 ?
Mo1_5 O13_5 2.4442(18) . ?
Mo2_5 O6_5 1.898(2) . ?
Mo2_5 O7_5 1.696(2) . ?
Mo2_5 O8_5 1.691(2) . ?
Mo2_5 O9_5 1.9991(19) . ?
Mo2_5 O12_5 2.309(2) 3_666 ?
Mo2_5 O13_5 2.3638(19) . ?
Mo3_5 Mo4_5 3.2049(4) . ?
Mo3_5 O9_5 1.938(2) . ?
Mo3_5 O10_5 1.7487(19) . ?
Mo3_5 O11_5 1.698(2) . ?
Mo3_5 O12_5 1.947(2) . ?
Mo3_5 O13_5 2.1661(18) . ?
Mo3_5 O13_5 2.3309(19) 3_666 ?
Mo4_5 O1_5 1.702(2) . ?
Mo4_5 O2_5 1.688(2) . ?
Mo4_5 O3_5 1.890(2) . ?
Mo4_5 O9_5 2.376(2) 3_666 ?
Mo4_5 O12_5 2.0049(19) . ?
Mo4_5 O13_5 2.3028(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2_1 Ag1 P3_2 159.58(3) . . ?
P4_2 Ag2 P1_1 159.94(3) . . ?
C16_1 P1_1 Ag2 115.72(12) . . ?
C16_1 P1_1 C25_1 103.26(15) . . ?
C22_1 P1_1 Ag2 116.58(11) . . ?
C22_1 P1_1 C16_1 102.69(15) . . ?
C22_1 P1_1 C25_1 105.23(15) . . ?
C25_1 P1_1 Ag2 111.90(10) . . ?
C4_1 P2_1 Ag1 113.37(11) . . ?
C4_1 P2_1 C10_1 105.67(16) . . ?
C4_1 P2_1 C27_1 107.07(16) . . ?
C10_1 P2_1 Ag1 115.36(13) . . ?
C10_1 P2_1 C27_1 101.68(15) . . ?
C27_1 P2_1 Ag1 112.67(11) . . ?
C2_1 C1_1 H1_1 119.8 . . ?
C6_1 C1_1 H1_1 119.8 . . ?
C6_1 C1_1 C2_1 120.4(5) . . ?
C1_1 C2_1 H2_1 120.0 . . ?
C1_1 C2_1 C3_1 120.0(5) . . ?
C3_1 C2_1 H2_1 120.0 . . ?
C2_1 C3_1 H3_1 120.1 . . ?
C2_1 C3_1 C4_1 119.9(5) . . ?
C4_1 C3_1 H3_1 120.1 . . ?
C3_1 C4_1 P2_1 117.9(3) . . ?
C5_1 C4_1 P2_1 122.4(3) . . ?
C5_1 C4_1 C3_1 119.3(4) . . ?
C4_1 C5_1 H5_1 119.8 . . ?
C4_1 C5_1 C6_1 120.5(4) . . ?
C6_1 C5_1 H5_1 119.8 . . ?
C1_1 C6_1 C5_1 119.9(5) . . ?
C1_1 C6_1 H6_1 120.1 . . ?
C5_1 C6_1 H6_1 120.1 . . ?
C8_1 C7_1 H7_1 119.9 . . ?
C12_1 C7_1 H7_1 119.9 . . ?
C12_1 C7_1 C8_1 120.2(4) . . ?
C7_1 C8_1 H8_1 119.8 . . ?
C7_1 C8_1 C9_1 120.4(5) . . ?
C9_1 C8_1 H8_1 119.8 . . ?
C8_1 C9_1 H9_1 119.9 . . ?
C10_1 C9_1 C8_1 120.1(4) . . ?
C10_1 C9_1 H9_1 119.9 . . ?
C9_1 C10_1 P2_1 119.8(3) . . ?
C9_1 C10_1 C11_1 118.3(4) . . ?
C11_1 C10_1 P2_1 121.6(3) . . ?
C10_1 C11_1 H11_1 119.7 . . ?
C10_1 C11_1 C12_1 120.6(4) . . ?
C12_1 C11_1 H11_1 119.7 . . ?
C7_1 C12_1 C11_1 120.3(4) . . ?
C7_1 C12_1 H12_1 119.8 . . ?
C11_1 C12_1 H12_1 119.8 . . ?
C14_1 C13_1 H13_1 119.6 . . ?
C14_1 C13_1 C18_1 120.7(5) . . ?
C18_1 C13_1 H13_1 119.6 . . ?
C13_1 C14_1 H14_1 120.0 . . ?
C13_1 C14_1 C15_1 120.0(5) . . ?
C15_1 C14_1 H14_1 120.0 . . ?
C14_1 C15_1 H15_1 119.6 . . ?
C16_1 C15_1 C14_1 120.8(5) . . ?
C16_1 C15_1 H15_1 119.6 . . ?
C15_1 C16_1 P1_1 120.9(3) . . ?
C15_1 C16_1 C17_1 118.0(4) . . ?
C17_1 C16_1 P1_1 121.1(3) . . ?
C16_1 C17_1 H17_1 119.6 . . ?
C18_1 C17_1 C16_1 120.8(4) . . ?
C18_1 C17_1 H17_1 119.6 . . ?
C13_1 C18_1 C17_1 119.7(5) . . ?
C13_1 C18_1 H18_1 120.2 . . ?
C17_1 C18_1 H18_1 120.2 . . ?
C20_1 C19_1 H19_1 120.5 . . ?
C20_1 C19_1 C24_1 119.0(4) . . ?
C24_1 C19_1 H19_1 120.5 . . ?
C19_1 C20_1 H20_1 119.4 . . ?
C19_1 C20_1 C21_1 121.1(5) . . ?
C21_1 C20_1 H20_1 119.4 . . ?
C20_1 C21_1 H21_1 119.8 . . ?
C22_1 C21_1 C20_1 120.5(5) . . ?
C22_1 C21_1 H21_1 119.8 . . ?
C21_1 C22_1 P1_1 118.7(3) . . ?
C23_1 C22_1 P1_1 123.8(3) . . ?
C23_1 C22_1 C21_1 117.3(4) . . ?
C22_1 C23_1 H23_1 119.5 . . ?
C22_1 C23_1 C24_1 121.0(4) . . ?
C24_1 C23_1 H23_1 119.5 . . ?
C19_1 C24_1 C23_1 120.8(5) . . ?
C19_1 C24_1 H24_1 119.6 . . ?
C23_1 C24_1 H24_1 119.6 . . ?
P1_1 C25_1 H25A_1 109.7 . . ?
P1_1 C25_1 H25B_1 109.7 . . ?
H25A_1 C25_1 H25B_1 108.2 . . ?
C26_1 C25_1 P1_1 110.0(2) . . ?
C26_1 C25_1 H25A_1 109.7 . . ?
C26_1 C25_1 H25B_1 109.7 . . ?
C25_1 C26_1 H26A_1 109.1 . . ?
C25_1 C26_1 H26B_1 109.1 . . ?
H26A_1 C26_1 H26B_1 107.8 . . ?
C27_1 C26_1 C25_1 112.6(3) . . ?
C27_1 C26_1 H26A_1 109.1 . . ?
C27_1 C26_1 H26B_1 109.1 . . ?
P2_1 C27_1 H27A_1 109.8 . . ?
P2_1 C27_1 H27B_1 109.8 . . ?
C26_1 C27_1 P2_1 109.2(2) . . ?
C26_1 C27_1 H27A_1 109.8 . . ?
C26_1 C27_1 H27B_1 109.8 . . ?
H27A_1 C27_1 H27B_1 108.3 . . ?
C16_2 P3_2 Ag1 116.58(16) . . ?
C16_2 P3_2 C22_2 105.60(19) . . ?
C16_2 P3_2 C25_2 105.3(2) . . ?
C22_2 P3_2 Ag1 112.40(13) . . ?
C25_2 P3_2 Ag1 111.97(12) . . ?
C25_2 P3_2 C22_2 103.89(16) . . ?
C4_2 P4_2 Ag2 114.17(12) . . ?
C4_2 P4_2 C10_2 105.31(16) . . ?
C4_2 P4_2 C27_2 103.57(17) . . ?
C10_2 P4_2 Ag2 117.76(12) . . ?
C10_2 P4_2 C27_2 100.90(16) . . ?
C27_2 P4_2 Ag2 113.39(11) . . ?
C2_2 C1_2 H1_2 120.6 . . ?
C2_2 C1_2 C6_2 118.7(5) . . ?
C6_2 C1_2 H1_2 120.6 . . ?
C1_2 C2_2 H2_2 119.6 . . ?
C1_2 C2_2 C3_2 120.8(5) . . ?
C3_2 C2_2 H2_2 119.6 . . ?
C2_2 C3_2 H3_2 119.0 . . ?
C2_2 C3_2 C4_2 122.1(4) . . ?
C4_2 C3_2 H3_2 119.0 . . ?
C3_2 C4_2 P4_2 122.8(3) . . ?
C5_2 C4_2 P4_2 120.8(3) . . ?
C5_2 C4_2 C3_2 116.3(4) . . ?
C4_2 C5_2 H5_2 119.7 . . ?
C4_2 C5_2 C6_2 120.5(5) . . ?
C6_2 C5_2 H5_2 119.7 . . ?
C1_2 C6_2 C5_2 121.4(5) . . ?
C1_2 C6_2 H6_2 119.3 . . ?
C5_2 C6_2 H6_2 119.3 . . ?
C8_2 C7_2 H7_2 119.7 . . ?
C8_2 C7_2 C12_2 120.6(4) . . ?
C12_2 C7_2 H7_2 119.7 . . ?
C7_2 C8_2 H8_2 119.6 . . ?
C7_2 C8_2 C9_2 120.7(4) . . ?
C9_2 C8_2 H8_2 119.6 . . ?
C8_2 C9_2 H9_2 119.7 . . ?
C10_2 C9_2 C8_2 120.5(4) . . ?
C10_2 C9_2 H9_2 119.7 . . ?
C9_2 C10_2 P4_2 123.6(3) . . ?
C11_2 C10_2 P4_2 118.1(3) . . ?
C11_2 C10_2 C9_2 118.0(4) . . ?
C10_2 C11_2 H11_2 119.5 . . ?
C10_2 C11_2 C12_2 121.0(4) . . ?
C12_2 C11_2 H11_2 119.5 . . ?
C7_2 C12_2 C11_2 119.0(5) . . ?
C7_2 C12_2 H12_2 120.5 . . ?
C11_2 C12_2 H12_2 120.5 . . ?
C14_2 C13_2 H13_2 120.5 . . ?
C14_2 C13_2 C18_2 119.0(8) . . ?
C18_2 C13_2 H13_2 120.5 . . ?
C13_2 C14_2 H14_2 119.1 . . ?
C13_2 C14_2 C15_2 121.7(8) . . ?
C15_2 C14_2 H14_2 119.1 . . ?
C14_2 C15_2 H15_2 120.3 . . ?
C16_2 C15_2 C14_2 119.5(7) . . ?
C16_2 C15_2 H15_2 120.3 . . ?
C15_2 C16_2 P3_2 122.0(4) . . ?
C17_2 C16_2 P3_2 119.0(4) . . ?
C17_2 C16_2 C15_2 119.0(5) . . ?
C16_2 C17_2 H17_2 120.1 . . ?
C16_2 C17_2 C18_2 119.7(7) . . ?
C18_2 C17_2 H17_2 120.1 . . ?
C13_2 C18_2 C17_2 121.0(8) . . ?
C13_2 C18_2 H18_2 119.5 . . ?
C17_2 C18_2 H18_2 119.5 . . ?
C20_2 C19_2 H19_2 120.1 . . ?
C24_2 C19_2 H19_2 120.1 . . ?
C24_2 C19_2 C20_2 119.9(5) . . ?
C19_2 C20_2 H20_2 120.0 . . ?
C19_2 C20_2 C21_2 120.1(5) . . ?
C21_2 C20_2 H20_2 120.0 . . ?
C20_2 C21_2 H21_2 120.4 . . ?
C22_2 C21_2 C20_2 119.2(5) . . ?
C22_2 C21_2 H21_2 120.4 . . ?
C21_2 C22_2 P3_2 123.7(3) . . ?
C21_2 C22_2 C23_2 119.1(4) . . ?
C23_2 C22_2 P3_2 117.1(3) . . ?
C22_2 C23_2 H23_2 119.7 . . ?
C24_2 C23_2 C22_2 120.6(4) . . ?
C24_2 C23_2 H23_2 119.7 . . ?
C19_2 C24_2 C23_2 121.2(5) . . ?
C19_2 C24_2 H24_2 119.4 . . ?
C23_2 C24_2 H24_2 119.4 . . ?
P3_2 C25_2 H25A_2 109.1 . . ?
P3_2 C25_2 H25B_2 109.1 . . ?
H25A_2 C25_2 H25B_2 107.9 . . ?
C26_2 C25_2 P3_2 112.4(2) . . ?
C26_2 C25_2 H25A_2 109.1 . . ?
C26_2 C25_2 H25B_2 109.1 . . ?
C25_2 C26_2 H26A_2 109.5 . . ?
C25_2 C26_2 H26B_2 109.5 . . ?
C25_2 C26_2 C27_2 110.9(3) . . ?
H26A_2 C26_2 H26B_2 108.0 . . ?
C27_2 C26_2 H26A_2 109.5 . . ?
C27_2 C26_2 H26B_2 109.5 . . ?
P4_2 C27_2 H27A_2 108.9 . . ?
P4_2 C27_2 H27B_2 108.9 . . ?
C26_2 C27_2 P4_2 113.3(2) . . ?
C26_2 C27_2 H27A_2 108.9 . . ?
C26_2 C27_2 H27B_2 108.9 . . ?
H27A_2 C27_2 H27B_2 107.7 . . ?
N1_3 C1_3 C2_3 176.9(10) . . ?
C1_3 C2_3 H2A_3 109.5 . . ?
C1_3 C2_3 H2B_3 109.5 . . ?
C1_3 C2_3 H2C_3 109.5 . . ?
H2A_3 C2_3 H2B_3 109.5 . . ?
H2A_3 C2_3 H2C_3 109.5 . . ?
H2B_3 C2_3 H2C_3 109.5 . . ?
C1_4 N1_4 C3_4 117.7(14) . . ?
C2_4 N1_4 C1_4 131.8(15) . . ?
C2_4 N1_4 C3_4 106.8(15) . . ?
C1'_4 N1_4 C2'_4 106.4(15) . . ?
C1'_4 N1_4 C3'_4 127.8(15) . . ?
C3'_4 N1_4 C2'_4 123.7(14) . . ?
O1_4 C1_4 N1_4 113.4(15) . . ?
O1_4 C1_4 H1_4 123.3 . . ?
N1_4 C1_4 H1_4 123.3 . . ?
N1_4 C2_4 H2A_4 109.5 . . ?
N1_4 C2_4 H2B_4 109.5 . . ?
N1_4 C2_4 H2C_4 109.5 . . ?
H2A_4 C2_4 H2B_4 109.5 . . ?
H2A_4 C2_4 H2C_4 109.5 . . ?
H2B_4 C2_4 H2C_4 109.5 . . ?
N1_4 C3_4 H3A_4 109.5 . . ?
N1_4 C3_4 H3B_4 109.5 . . ?
N1_4 C3_4 H3C_4 109.5 . . ?
H3A_4 C3_4 H3B_4 109.5 . . ?
H3A_4 C3_4 H3C_4 109.5 . . ?
H3B_4 C3_4 H3C_4 109.5 . . ?
O1_4 C1'_4 N1_4 110.9(14) . . ?
O1_4 C1'_4 H1'_4 124.6 . . ?
N1_4 C1'_4 H1'_4 124.6 . . ?
N1_4 C2'_4 H2'A_4 109.5 . . ?
N1_4 C2'_4 H2'B_4 109.5 . . ?
N1_4 C2'_4 H2'C_4 109.5 . . ?
H2'A_4 C2'_4 H2'B_4 109.5 . . ?
H2'A_4 C2'_4 H2'C_4 109.5 . . ?
H2'B_4 C2'_4 H2'C_4 109.5 . . ?
N1_4 C3'_4 H3'A_4 109.5 . . ?
N1_4 C3'_4 H3'B_4 109.5 . . ?
N1_4 C3'_4 H3'C_4 109.5 . . ?
H3'A_4 C3'_4 H3'B_4 109.5 . . ?
H3'A_4 C3'_4 H3'C_4 109.5 . . ?
H3'B_4 C3'_4 H3'C_4 109.5 . . ?
O3_5 Mo1_5 O6_5 144.57(8) . . ?
O3_5 Mo1_5 O10_5 78.30(9) . 3_666 ?
O3_5 Mo1_5 O13_5 73.08(7) . . ?
O4_5 Mo1_5 O3_5 99.01(11) . . ?
O4_5 Mo1_5 O5_5 105.57(12) . . ?
O4_5 Mo1_5 O6_5 98.67(11) . . ?
O4_5 Mo1_5 O10_5 167.09(10) . 3_666 ?
O4_5 Mo1_5 O13_5 97.87(9) . . ?
O5_5 Mo1_5 O3_5 101.91(11) . . ?
O5_5 Mo1_5 O6_5 102.55(11) . . ?
O5_5 Mo1_5 O10_5 87.34(10) . 3_666 ?
O5_5 Mo1_5 O13_5 156.54(10) . . ?
O6_5 Mo1_5 O10_5 77.63(8) . 3_666 ?
O6_5 Mo1_5 O13_5 74.25(7) . . ?
O10_5 Mo1_5 O13_5 69.23(7) 3_666 . ?
O6_5 Mo2_5 O9_5 145.92(8) . . ?
O6_5 Mo2_5 O12_5 83.53(8) . 3_666 ?
O6_5 Mo2_5 O13_5 76.56(8) . . ?
O7_5 Mo2_5 O6_5 101.11(10) . . ?
O7_5 Mo2_5 O9_5 96.36(10) . . ?
O7_5 Mo2_5 O12_5 162.96(9) . 3_666 ?
O7_5 Mo2_5 O13_5 94.36(10) . . ?
O8_5 Mo2_5 O6_5 100.77(11) . . ?
O8_5 Mo2_5 O7_5 104.93(12) . . ?
O8_5 Mo2_5 O9_5 102.67(10) . . ?
O8_5 Mo2_5 O12_5 90.09(10) . 3_666 ?
O8_5 Mo2_5 O13_5 160.64(10) . . ?
O9_5 Mo2_5 O12_5 72.09(7) . 3_666 ?
O9_5 Mo2_5 O13_5 73.10(7) . . ?
O12_5 Mo2_5 O13_5 70.58(7) 3_666 . ?
O9_5 Mo3_5 Mo4_5 124.85(6) . . ?
O9_5 Mo3_5 O12_5 150.36(8) . . ?
O9_5 Mo3_5 O13_5 78.94(8) . . ?
O9_5 Mo3_5 O13_5 78.65(8) . 3_666 ?
O10_5 Mo3_5 Mo4_5 133.58(7) . . ?
O10_5 Mo3_5 O9_5 97.07(9) . . ?
O10_5 Mo3_5 O12_5 97.20(9) . . ?
O10_5 Mo3_5 O13_5 82.31(8) . 3_666 ?
O10_5 Mo3_5 O13_5 158.48(9) . . ?
O11_5 Mo3_5 Mo4_5 86.68(8) . . ?
O11_5 Mo3_5 O9_5 102.11(10) . . ?
O11_5 Mo3_5 O10_5 104.65(10) . . ?
O11_5 Mo3_5 O12_5 99.20(10) . . ?
O11_5 Mo3_5 O13_5 96.85(9) . . ?
O11_5 Mo3_5 O13_5 172.76(9) . 3_666 ?
O12_5 Mo3_5 Mo4_5 36.42(5) . . ?
O12_5 Mo3_5 O13_5 77.70(7) . 3_666 ?
O12_5 Mo3_5 O13_5 78.27(7) . . ?
O13_5 Mo3_5 Mo4_5 45.91(5) . . ?
O13_5 Mo3_5 Mo4_5 87.03(5) 3_666 . ?
O13_5 Mo3_5 O13_5 76.17(7) . 3_666 ?
O1_5 Mo4_5 Mo3_5 85.06(8) . . ?
O1_5 Mo4_5 O3_5 102.98(11) . . ?
O1_5 Mo4_5 O9_5 163.65(9) . 3_666 ?
O1_5 Mo4_5 O12_5 96.12(10) . . ?
O1_5 Mo4_5 O13_5 96.55(10) . . ?
O2_5 Mo4_5 Mo3_5 134.95(8) . . ?
O2_5 Mo4_5 O1_5 105.04(12) . . ?
O2_5 Mo4_5 O3_5 101.18(11) . . ?
O2_5 Mo4_5 O9_5 86.98(10) . 3_666 ?
O2_5 Mo4_5 O12_5 99.75(10) . . ?
O2_5 Mo4_5 O13_5 158.10(10) . . ?
O3_5 Mo4_5 Mo3_5 119.47(7) . . ?
O3_5 Mo4_5 O9_5 85.08(9) . 3_666 ?
O3_5 Mo4_5 O12_5 146.75(9) . . ?
O3_5 Mo4_5 O13_5 77.02(8) . . ?
O9_5 Mo4_5 Mo3_5 78.59(5) 3_666 . ?
O12_5 Mo4_5 Mo3_5 35.21(6) . . ?
O12_5 Mo4_5 O9_5 70.53(7) . 3_666 ?
O12_5 Mo4_5 O13_5 73.94(7) . . ?
O13_5 Mo4_5 Mo3_5 42.50(5) . . ?
O13_5 Mo4_5 O9_5 71.13(7) . 3_666 ?
Mo4_5 O3_5 Mo1_5 118.12(11) . . ?
Mo2_5 O6_5 Mo1_5 117.68(10) . . ?
Mo2_5 O9_5 Mo4_5 102.91(8) . 3_666 ?
Mo3_5 O9_5 Mo2_5 110.63(9) . . ?
Mo3_5 O9_5 Mo4_5 108.86(9) . 3_666 ?
Mo3_5 O10_5 Mo1_5 115.26(10) . 3_666 ?
Mo3_5 O12_5 Mo2_5 111.67(9) . 3_666 ?
Mo3_5 O12_5 Mo4_5 108.37(9) . . ?
Mo4_5 O12_5 Mo2_5 105.11(8) . 3_666 ?
Mo2_5 O13_5 Mo1_5 85.51(6) . . ?
Mo3_5 O13_5 Mo1_5 162.95(10) . . ?
Mo3_5 O13_5 Mo1_5 93.18(7) 3_666 . ?
Mo3_5 O13_5 Mo2_5 97.42(7) 3_666 . ?
Mo3_5 O13_5 Mo2_5 91.13(7) . . ?
Mo3_5 O13_5 Mo3_5 103.83(7) . 3_666 ?
Mo3_5 O13_5 Mo4_5 91.59(7) . . ?
Mo4_5 O13_5 Mo1_5 86.83(6) . . ?
Mo4_5 O13_5 Mo2_5 162.41(9) . . ?
Mo4_5 O13_5 Mo3_5 98.79(7) . 3_666 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P2_1 C4_1 C3_1 70.2(3) . . . . ?
Ag1 P2_1 C4_1 C5_1 -102.3(3) . . . . ?
Ag1 P2_1 C10_1 C9_1 6.2(4) . . . . ?
Ag1 P2_1 C10_1 C11_1 178.9(3) . . . . ?
Ag1 P2_1 C27_1 C26_1 -57.6(2) . . . . ?
Ag1 P3_2 C16_2 C15_2 -149.3(4) . . . . ?
Ag1 P3_2 C16_2 C17_2 29.1(5) . . . . ?
Ag1 P3_2 C22_2 C21_2 -129.3(3) . . . . ?
Ag1 P3_2 C22_2 C23_2 46.5(3) . . . . ?
Ag1 P3_2 C25_2 C26_2 58.9(3) . . . . ?
Ag2 P1_1 C16_1 C15_1 12.5(4) . . . . ?
Ag2 P1_1 C16_1 C17_1 -167.7(3) . . . . ?
Ag2 P1_1 C22_1 C21_1 -70.6(4) . . . . ?
Ag2 P1_1 C22_1 C23_1 105.5(4) . . . . ?
Ag2 P1_1 C25_1 C26_1 63.7(2) . . . . ?
Ag2 P4_2 C4_2 C3_2 160.6(3) . . . . ?
Ag2 P4_2 C4_2 C5_2 -16.2(4) . . . . ?
Ag2 P4_2 C10_2 C9_2 121.9(3) . . . . ?
Ag2 P4_2 C10_2 C11_2 -63.9(4) . . . . ?
Ag2 P4_2 C27_2 C26_2 -61.7(3) . . . . ?
P1_1 C16_1 C17_1 C18_1 178.2(3) . . . . ?
P1_1 C22_1 C23_1 C24_1 178.8(4) . . . . ?
P1_1 C25_1 C26_1 C27_1 174.7(2) . . . . ?
P2_1 C4_1 C5_1 C6_1 170.8(3) . . . . ?
P2_1 C10_1 C11_1 C12_1 -173.2(3) . . . . ?
C1_1 C2_1 C3_1 C4_1 1.0(8) . . . . ?
C2_1 C1_1 C6_1 C5_1 1.1(8) . . . . ?
C2_1 C3_1 C4_1 P2_1 -172.0(4) . . . . ?
C2_1 C3_1 C4_1 C5_1 0.7(6) . . . . ?
C3_1 C4_1 C5_1 C6_1 -1.5(6) . . . . ?
C4_1 P2_1 C10_1 C9_1 132.3(3) . . . . ?
C4_1 P2_1 C10_1 C11_1 -55.1(4) . . . . ?
C4_1 P2_1 C27_1 C26_1 177.1(2) . . . . ?
C4_1 C5_1 C6_1 C1_1 0.6(6) . . . . ?
C6_1 C1_1 C2_1 C3_1 -1.9(8) . . . . ?
C7_1 C8_1 C9_1 C10_1 0.8(9) . . . . ?
C8_1 C7_1 C12_1 C11_1 -0.6(8) . . . . ?
C8_1 C9_1 C10_1 P2_1 172.5(4) . . . . ?
C8_1 C9_1 C10_1 C11_1 -0.4(7) . . . . ?
C9_1 C10_1 C11_1 C12_1 -0.5(6) . . . . ?
C10_1 P2_1 C4_1 C3_1 -57.1(3) . . . . ?
C10_1 P2_1 C4_1 C5_1 130.4(3) . . . . ?
C10_1 P2_1 C27_1 C26_1 66.5(3) . . . . ?
C10_1 C11_1 C12_1 C7_1 1.0(7) . . . . ?
C12_1 C7_1 C8_1 C9_1 -0.3(9) . . . . ?
C13_1 C14_1 C15_1 C16_1 -0.1(11) . . . . ?
C14_1 C13_1 C18_1 C17_1 0.8(10) . . . . ?
C14_1 C15_1 C16_1 P1_1 -178.5(5) . . . . ?
C14_1 C15_1 C16_1 C17_1 1.7(8) . . . . ?
C15_1 C16_1 C17_1 C18_1 -2.0(6) . . . . ?
C16_1 P1_1 C22_1 C21_1 57.0(4) . . . . ?
C16_1 P1_1 C22_1 C23_1 -126.9(4) . . . . ?
C16_1 P1_1 C25_1 C26_1 -61.4(3) . . . . ?
C16_1 C17_1 C18_1 C13_1 0.8(8) . . . . ?
C18_1 C13_1 C14_1 C15_1 -1.1(11) . . . . ?
C19_1 C20_1 C21_1 C22_1 1.2(12) . . . . ?
C20_1 C19_1 C24_1 C23_1 -0.4(10) . . . . ?
C20_1 C21_1 C22_1 P1_1 178.8(6) . . . . ?
C20_1 C21_1 C22_1 C23_1 2.5(9) . . . . ?
C21_1 C22_1 C23_1 C24_1 -5.0(8) . . . . ?
C22_1 P1_1 C16_1 C15_1 -115.7(4) . . . . ?
C22_1 P1_1 C16_1 C17_1 64.1(3) . . . . ?
C22_1 P1_1 C25_1 C26_1 -168.8(2) . . . . ?
C22_1 C23_1 C24_1 C19_1 4.2(9) . . . . ?
C24_1 C19_1 C20_1 C21_1 -2.2(12) . . . . ?
C25_1 P1_1 C16_1 C15_1 135.1(4) . . . . ?
C25_1 P1_1 C16_1 C17_1 -45.1(3) . . . . ?
C25_1 P1_1 C22_1 C21_1 164.8(4) . . . . ?
C25_1 P1_1 C22_1 C23_1 -19.1(4) . . . . ?
C25_1 C26_1 C27_1 P2_1 -173.2(2) . . . . ?
C27_1 P2_1 C4_1 C3_1 -164.9(3) . . . . ?
C27_1 P2_1 C4_1 C5_1 22.6(3) . . . . ?
C27_1 P2_1 C10_1 C9_1 -116.0(4) . . . . ?
C27_1 P2_1 C10_1 C11_1 56.6(3) . . . . ?
P3_2 C16_2 C17_2 C18_2 179.6(5) . . . . ?
P3_2 C22_2 C23_2 C24_2 -176.4(3) . . . . ?
P3_2 C25_2 C26_2 C27_2 -170.0(2) . . . . ?
P4_2 C4_2 C5_2 C6_2 178.1(5) . . . . ?
P4_2 C10_2 C11_2 C12_2 -173.4(5) . . . . ?
C1_2 C2_2 C3_2 C4_2 2.8(9) . . . . ?
C2_2 C1_2 C6_2 C5_2 0.6(12) . . . . ?
C2_2 C3_2 C4_2 P4_2 -179.3(4) . . . . ?
C2_2 C3_2 C4_2 C5_2 -2.3(7) . . . . ?
C3_2 C4_2 C5_2 C6_2 1.0(9) . . . . ?
C4_2 P4_2 C10_2 C9_2 -6.7(4) . . . . ?
C4_2 P4_2 C10_2 C11_2 167.5(4) . . . . ?
C4_2 P4_2 C27_2 C26_2 62.5(3) . . . . ?
C4_2 C5_2 C6_2 C1_2 -0.2(12) . . . . ?
C6_2 C1_2 C2_2 C3_2 -1.8(10) . . . . ?
C7_2 C8_2 C9_2 C10_2 -3.0(8) . . . . ?
C8_2 C7_2 C12_2 C11_2 0.0(9) . . . . ?
C8_2 C9_2 C10_2 P4_2 175.4(4) . . . . ?
C8_2 C9_2 C10_2 C11_2 1.1(7) . . . . ?
C9_2 C10_2 C11_2 C12_2 1.2(8) . . . . ?
C10_2 P4_2 C4_2 C3_2 -68.7(4) . . . . ?
C10_2 P4_2 C4_2 C5_2 114.5(4) . . . . ?
C10_2 P4_2 C27_2 C26_2 171.4(3) . . . . ?
C10_2 C11_2 C12_2 C7_2 -1.8(10) . . . . ?
C12_2 C7_2 C8_2 C9_2 2.3(8) . . . . ?
C13_2 C14_2 C15_2 C16_2 0.2(13) . . . . ?
C14_2 C13_2 C18_2 C17_2 -1.5(14) . . . . ?
C14_2 C15_2 C16_2 P3_2 179.1(6) . . . . ?
C14_2 C15_2 C16_2 C17_2 0.7(10) . . . . ?
C15_2 C16_2 C17_2 C18_2 -1.9(9) . . . . ?
C16_2 P3_2 C22_2 C21_2 -1.2(4) . . . . ?
C16_2 P3_2 C22_2 C23_2 174.7(3) . . . . ?
C16_2 P3_2 C25_2 C26_2 -68.8(3) . . . . ?
C16_2 C17_2 C18_2 C13_2 2.4(11) . . . . ?
C18_2 C13_2 C14_2 C15_2 0.2(15) . . . . ?
C19_2 C20_2 C21_2 C22_2 -0.5(7) . . . . ?
C20_2 C19_2 C24_2 C23_2 -1.1(8) . . . . ?
C20_2 C21_2 C22_2 P3_2 176.0(3) . . . . ?
C20_2 C21_2 C22_2 C23_2 0.2(6) . . . . ?
C21_2 C22_2 C23_2 C24_2 -0.4(6) . . . . ?
C22_2 P3_2 C16_2 C15_2 85.1(5) . . . . ?
C22_2 P3_2 C16_2 C17_2 -96.5(4) . . . . ?
C22_2 P3_2 C25_2 C26_2 -179.6(3) . . . . ?
C22_2 C23_2 C24_2 C19_2 0.9(7) . . . . ?
C24_2 C19_2 C20_2 C21_2 0.9(8) . . . . ?
C25_2 P3_2 C16_2 C15_2 -24.5(5) . . . . ?
C25_2 P3_2 C16_2 C17_2 153.9(4) . . . . ?
C25_2 P3_2 C22_2 C21_2 109.4(4) . . . . ?
C25_2 P3_2 C22_2 C23_2 -74.7(3) . . . . ?
C25_2 C26_2 C27_2 P4_2 -176.7(2) . . . . ?
C27_2 P4_2 C4_2 C3_2 36.8(4) . . . . ?
C27_2 P4_2 C4_2 C5_2 -140.0(4) . . . . ?
C27_2 P4_2 C10_2 C9_2 -114.2(4) . . . . ?
C27_2 P4_2 C10_2 C11_2 60.0(4) . . . . ?
C2_4 N1_4 C1_4 O1_4 -22(3) . . . . ?
C3_4 N1_4 C1_4 O1_4 -177.2(13) . . . . ?
C2'_4 N1_4 C1'_4 O1_4 -172.9(14) . . . . ?
C3'_4 N1_4 C1'_4 O1_4 -9(2) . . . . ?
Mo3_5 Mo4_5 O3_5 Mo1_5 18.49(16) . . . . ?
Mo4_5 Mo3_5 O10_5 Mo1_5 -77.26(13) . . . 3_666 ?
O1_5 Mo4_5 O3_5 Mo1_5 -73.16(15) . . . . ?
O2_5 Mo4_5 O3_5 Mo1_5 178.36(14) . . . . ?
O7_5 Mo2_5 O6_5 Mo1_5 69.29(14) . . . . ?
O8_5 Mo2_5 O6_5 Mo1_5 177.03(13) . . . . ?
O9_5 Mo2_5 O6_5 Mo1_5 -50.2(2) . . . . ?
O9_5 Mo3_5 O10_5 Mo1_5 78.65(11) . . . 3_666 ?
O9_5 Mo4_5 O3_5 Mo1_5 92.43(13) 3_666 . . . ?
O11_5 Mo3_5 O10_5 Mo1_5 -176.82(11) . . . 3_666 ?
O12_5 Mo2_5 O6_5 Mo1_5 -94.11(11) 3_666 . . . ?
O12_5 Mo3_5 O10_5 Mo1_5 -75.31(11) . . . 3_666 ?
O12_5 Mo4_5 O3_5 Mo1_5 50.3(2) . . . . ?
O13_5 Mo2_5 O6_5 Mo1_5 -22.59(10) . . . . ?
O13_5 Mo3_5 O10_5 Mo1_5 1.17(9) 3_666 . . 3_666 ?
O13_5 Mo3_5 O10_5 Mo1_5 0.9(3) . . . 3_666 ?
O13_5 Mo4_5 O3_5 Mo1_5 20.69(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4567_a
_database_code_depnum_ccdc_archive 'CCDC 2326046'
loop_
_audit_author_name
_audit_author_address
jiang
;zhejiang normal university
China
;
_audit_update_record             
;
2024-01-17 deposited with the CCDC.	2024-02-26 downloaded from the CCDC.
;
_audit_creation_date             2023-10-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C58 H58 Ag2 N2 P4, Mo6 O19'
_chemical_formula_sum            'C58 H58 Ag2 Mo6 N2 O19 P4'
_chemical_formula_weight         2002.32
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.6266(10)
_cell_length_b                   12.7787(12)
_cell_length_c                   13.6690(13)
_cell_angle_alpha                109.407(3)
_cell_angle_beta                 96.054(3)
_cell_angle_gamma                115.217(3)
_cell_volume                     1658.7(3)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9862
_cell_measurement_temperature    293.0
_cell_measurement_theta_max      26.39
_cell_measurement_theta_min      3.03
_shelx_estimated_absorpt_T_max   0.867
_shelx_estimated_absorpt_T_min   0.710
_exptl_absorpt_coefficient_mu    1.840
_exptl_absorpt_correction_T_max  0.7449
_exptl_absorpt_correction_T_min  0.6366
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0787 before and 0.0445 after correction.
The Ratio of minimum to maximum transmission is 0.8546.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    2.005
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             978
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_unetI/netI     0.0271
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            26690
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.401
_diffrn_reflns_theta_min         2.210
_diffrn_ambient_temperature      293.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'BRUKER D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6106
_reflns_number_total             6723
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.102
_refine_diff_density_min         -0.906
_refine_diff_density_rms         0.165
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.165
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     413
_refine_ls_number_reflns         6723
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0280
_refine_ls_R_factor_gt           0.0238
_refine_ls_restrained_S_all      1.165
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0382P)²+0.6242P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0668
_refine_ls_wR_factor_ref         0.0762
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C25(H25A,H25B), C26(H26A,H26B), C27(H27A,H27B)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C18(H18), C19(H19), C20(H20),
  C21(H21), C23(H23), C24(H24)
2.c Idealised Me refined as rotating group:
 C28(H28A,H28B,H28C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48390(2) 0.99486(2) 0.71237(2) 0.04338(8) Uani 1 1 d . . . . .
P1 P 0.24801(6) 0.88110(6) 0.62978(5) 0.02878(14) Uani 1 1 d . . . . .
P2 P 0.29810(7) 0.82065(6) 0.21433(5) 0.02982(14) Uani 1 1 d . . . . .
N1 N 0.4827(5) 0.9031(6) 0.8551(5) 0.1172(19) Uani 1 1 d . . . . .
C1 C -0.0029(3) 0.6360(4) 0.7888(3) 0.0520(8) Uani 1 1 d . . . . .
H1 H -0.054864 0.587141 0.820911 0.062 Uiso 1 1 calc R U . . .
C2 C 0.0278(4) 0.5799(3) 0.6995(3) 0.0586(9) Uani 1 1 d . . . . .
H2 H -0.002088 0.492815 0.671695 0.070 Uiso 1 1 calc R U . . .
C3 C 0.1039(3) 0.6521(3) 0.6493(3) 0.0468(7) Uani 1 1 d . . . . .
H3 H 0.124181 0.613029 0.588295 0.056 Uiso 1 1 calc R U . . .
C4 C 0.1485(2) 0.7805(2) 0.6903(2) 0.0301(5) Uani 1 1 d . . . . .
C5 C 0.1171(4) 0.8353(3) 0.7812(3) 0.0549(9) Uani 1 1 d . . . . .
H5 H 0.146701 0.922331 0.809909 0.066 Uiso 1 1 calc R U . . .
C6 C 0.0425(4) 0.7631(4) 0.8305(3) 0.0633(10) Uani 1 1 d . . . . .
H6 H 0.023560 0.801868 0.892445 0.076 Uiso 1 1 calc R U . . .
C7 C 0.0803(5) 1.1529(4) 0.6581(3) 0.0624(10) Uani 1 1 d . . . . .
H7 H 0.046736 1.208456 0.665197 0.075 Uiso 1 1 calc R U . . .
C8 C -0.0047(4) 1.0258(4) 0.6254(3) 0.0562(9) Uani 1 1 d . . . . .
H8 H -0.095762 0.995334 0.610209 0.067 Uiso 1 1 calc R U . . .
C9 C 0.0445(3) 0.9426(3) 0.6147(2) 0.0421(6) Uani 1 1 d . . . . .
H9 H -0.013912 0.856224 0.591908 0.050 Uiso 1 1 calc R U . . .
C10 C 0.1800(3) 0.9870(3) 0.6378(2) 0.0332(5) Uani 1 1 d . . . . .
C11 C 0.2657(4) 1.1159(3) 0.6706(3) 0.0491(7) Uani 1 1 d . . . . .
H11 H 0.356896 1.147183 0.685859 0.059 Uiso 1 1 calc R U . . .
C12 C 0.2143(5) 1.1987(3) 0.6806(3) 0.0648(11) Uani 1 1 d . . . . .
H12 H 0.271470 1.285185 0.702518 0.078 Uiso 1 1 calc R U . . .
C13 C -0.0252(4) 0.9009(4) 0.0912(3) 0.0578(9) Uani 1 1 d . . . . .
H13 H -0.089955 0.918365 0.067148 0.069 Uiso 1 1 calc R U . . .
C14 C 0.1004(4) 0.9983(4) 0.1478(3) 0.0545(8) Uani 1 1 d . . . . .
H14 H 0.121583 1.081754 0.161976 0.065 Uiso 1 1 calc R U . . .
C15 C 0.1971(3) 0.9719(3) 0.1843(2) 0.0415(6) Uani 1 1 d . . . . .
H15 H 0.282793 1.038373 0.223298 0.050 Uiso 1 1 calc R U . . .
C16 C 0.1674(3) 0.8479(3) 0.1633(2) 0.0328(5) Uani 1 1 d . . . . .
C17 C 0.0384(3) 0.7491(3) 0.1057(2) 0.0448(7) Uani 1 1 d . . . . .
H17 H 0.015930 0.665321 0.091396 0.054 Uiso 1 1 calc R U . . .
C18 C -0.0571(3) 0.7780(4) 0.0695(3) 0.0553(9) Uani 1 1 d . . . . .
H18 H -0.143279 0.712625 0.030212 0.066 Uiso 1 1 calc R U . . .
C19 C 0.3252(5) 0.5232(4) -0.0696(4) 0.0794(13) Uani 1 1 d . . . . .
H19 H 0.335346 0.466008 -0.126345 0.095 Uiso 1 1 calc R U . . .
C20 C 0.3650(5) 0.5378(4) 0.0345(4) 0.0673(10) Uani 1 1 d . . . . .
H20 H 0.400969 0.489659 0.047953 0.081 Uiso 1 1 calc R U . . .
C21 C 0.3519(3) 0.6240(3) 0.1197(3) 0.0479(7) Uani 1 1 d . . . . .
H21 H 0.379921 0.634083 0.190152 0.057 Uiso 1 1 calc R U . . .
C22 C 0.2970(3) 0.6952(3) 0.1003(2) 0.0371(6) Uani 1 1 d . . . . .
C23 C 0.2569(4) 0.6792(4) -0.0055(3) 0.0613(10) Uani 1 1 d . . . . .
H23 H 0.220633 0.726713 -0.019726 0.074 Uiso 1 1 calc R U . . .
C24 C 0.2707(5) 0.5925(5) -0.0900(3) 0.0812(14) Uani 1 1 d . . . . .
H24 H 0.242831 0.581515 -0.160768 0.097 Uiso 1 1 calc R U . . .
C25 C 0.2358(3) 0.7455(3) 0.3049(2) 0.0369(6) Uani 1 1 d . . . . .
H25A H 0.141258 0.686513 0.273131 0.044 Uiso 1 1 calc R U . . .
H25B H 0.279179 0.696957 0.311482 0.044 Uiso 1 1 calc R U . . .
C26 C 0.2598(3) 0.8421(2) 0.4174(2) 0.0321(5) Uani 1 1 d . . . . .
H26A H 0.222745 0.895479 0.411020 0.039 Uiso 1 1 calc R U . . .
H26B H 0.354537 0.896352 0.452356 0.039 Uiso 1 1 calc R U . . .
C27 C 0.1956(3) 0.7744(2) 0.4866(2) 0.0303(5) Uani 1 1 d . . . . .
H27A H 0.217882 0.707707 0.479426 0.036 Uiso 1 1 calc R U . . .
H27B H 0.099832 0.734284 0.459185 0.036 Uiso 1 1 calc R U . . .
C28 C 0.5993(6) 0.8472(7) 0.9846(7) 0.135(3) Uani 1 1 d . . . . .
H28A H 0.573233 0.865055 1.049888 0.203 Uiso 1 1 calc R U . . .
H28B H 0.693933 0.897735 1.001639 0.203 Uiso 1 1 calc R U . . .
H28C H 0.573731 0.758482 0.951376 0.203 Uiso 1 1 calc R U . . .
C29 C 0.5315(5) 0.8793(6) 0.9069(5) 0.0906(16) Uani 1 1 d . . . . .
Mo1 Mo 0.38889(3) 0.42313(2) 0.31921(2) 0.04373(8) Uani 1 1 d . . . . .
Mo2 Mo 0.29994(2) 0.44449(2) 0.54160(2) 0.04081(8) Uani 1 1 d . . . . .
Mo3 Mo 0.52695(2) 0.69936(2) 0.52892(2) 0.03614(7) Uani 1 1 d . . . . .
O1 O 0.3127(3) 0.3670(3) 0.1871(2) 0.0742(8) Uani 1 1 d . . . . .
O2 O 0.4004(2) 0.28050(19) 0.32905(17) 0.0447(5) Uani 1 1 d . . . . .
O3 O 0.2503(2) 0.3874(2) 0.38384(19) 0.0504(5) Uani 1 1 d . . . . .
O4 O 0.1525(2) 0.3975(2) 0.5681(3) 0.0649(7) Uani 1 1 d . . . . .
O5 O 0.4221(2) 0.5096(2) 0.67653(18) 0.0468(5) Uani 1 1 d . . . . .
O6 O 0.3530(2) 0.6096(2) 0.55211(19) 0.0449(5) Uani 1 1 d . . . . .
O7 O 0.5409(3) 0.8432(2) 0.5522(2) 0.0542(6) Uani 1 1 d . . . . .
O8 O 0.6826(2) 0.71042(18) 0.49664(18) 0.0422(5) Uani 1 1 d . . . . .
O9 O 0.4319(2) 0.5994(2) 0.37684(18) 0.0458(5) Uani 1 1 d . . . . .
O10 O 0.500000 0.500000 0.500000 0.0274(5) Uani 1 2 d S . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4018(7) . ?
Ag1 P2 2.4061(7) 2_676 ?
Ag1 N1 2.587(5) . ?
P1 C4 1.821(3) . ?
P1 C10 1.816(3) . ?
P1 C27 1.824(3) . ?
P2 C16 1.819(3) . ?
P2 C22 1.822(3) . ?
P2 C25 1.835(3) . ?
N1 C29 1.059(6) . ?
C1 H1 0.9300 . ?
C1 C2 1.364(5) . ?
C1 C6 1.353(5) . ?
C2 H2 0.9300 . ?
C2 C3 1.399(4) . ?
C3 H3 0.9300 . ?
C3 C4 1.371(4) . ?
C4 C5 1.379(4) . ?
C5 H5 0.9300 . ?
C5 C6 1.383(5) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C7 C8 1.367(6) . ?
C7 C12 1.366(6) . ?
C8 H8 0.9300 . ?
C8 C9 1.382(4) . ?
C9 H9 0.9300 . ?
C9 C10 1.386(4) . ?
C10 C11 1.387(4) . ?
C11 H11 0.9300 . ?
C11 C12 1.398(5) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C13 C14 1.361(5) . ?
C13 C18 1.365(5) . ?
C14 H14 0.9300 . ?
C14 C15 1.394(4) . ?
C15 H15 0.9300 . ?
C15 C16 1.386(4) . ?
C16 C17 1.393(4) . ?
C17 H17 0.9300 . ?
C17 C18 1.404(5) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C19 C20 1.373(6) . ?
C19 C24 1.367(7) . ?
C20 H20 0.9300 . ?
C20 C21 1.386(5) . ?
C21 H21 0.9300 . ?
C21 C22 1.387(4) . ?
C22 C23 1.389(4) . ?
C23 H23 0.9300 . ?
C23 C24 1.389(5) . ?
C24 H24 0.9300 . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C25 C26 1.523(4) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C26 C27 1.531(3) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C28 C29 1.519(9) . ?
Mo1 O1 1.680(2) . ?
Mo1 O2 1.930(2) . ?
Mo1 O3 1.878(2) . ?
Mo1 O5 1.975(2) 2_666 ?
Mo1 O9 1.929(2) . ?
Mo1 O10 2.3179(3) . ?
Mo2 O3 1.962(2) . ?
Mo2 O4 1.682(2) . ?
Mo2 O5 1.879(2) . ?
Mo2 O6 1.877(2) . ?
Mo2 O8 1.977(2) 2_666 ?
Mo2 O10 2.3190(3) . ?
Mo3 O2 1.920(2) 2_666 ?
Mo3 O6 1.977(2) . ?
Mo3 O7 1.689(2) . ?
Mo3 O8 1.866(2) . ?
Mo3 O9 1.929(2) . ?
Mo3 O10 2.3171(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 P2 154.72(3) . 2_676 ?
P1 Ag1 N1 97.15(12) . . ?
P2 Ag1 N1 101.33(13) 2_676 . ?
C4 P1 Ag1 115.87(9) . . ?
C4 P1 C27 104.19(12) . . ?
C10 P1 Ag1 112.46(9) . . ?
C10 P1 C4 102.97(12) . . ?
C10 P1 C27 105.98(12) . . ?
C27 P1 Ag1 114.21(9) . . ?
C16 P2 Ag1 114.32(9) . 2_676 ?
C16 P2 C22 106.30(13) . . ?
C16 P2 C25 104.46(13) . . ?
C22 P2 Ag1 109.40(9) . 2_676 ?
C22 P2 C25 104.49(13) . . ?
C25 P2 Ag1 116.93(10) . 2_676 ?
C29 N1 Ag1 149.8(5) . . ?
C2 C1 H1 120.1 . . ?
C6 C1 H1 120.1 . . ?
C6 C1 C2 119.8(3) . . ?
C1 C2 H2 119.7 . . ?
C1 C2 C3 120.6(3) . . ?
C3 C2 H2 119.7 . . ?
C2 C3 H3 120.1 . . ?
C4 C3 C2 119.8(3) . . ?
C4 C3 H3 120.1 . . ?
C3 C4 P1 122.5(2) . . ?
C3 C4 C5 118.5(3) . . ?
C5 C4 P1 119.0(2) . . ?
C4 C5 H5 119.4 . . ?
C4 C5 C6 121.2(3) . . ?
C6 C5 H5 119.4 . . ?
C1 C6 C5 120.1(3) . . ?
C1 C6 H6 119.9 . . ?
C5 C6 H6 119.9 . . ?
C8 C7 H7 119.8 . . ?
C12 C7 H7 119.8 . . ?
C12 C7 C8 120.4(3) . . ?
C7 C8 H8 119.9 . . ?
C7 C8 C9 120.2(4) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 119.8 . . ?
C8 C9 C10 120.5(3) . . ?
C10 C9 H9 119.8 . . ?
C9 C10 P1 121.5(2) . . ?
C9 C10 C11 119.0(3) . . ?
C11 C10 P1 119.4(2) . . ?
C10 C11 H11 120.1 . . ?
C10 C11 C12 119.7(4) . . ?
C12 C11 H11 120.1 . . ?
C7 C12 C11 120.2(4) . . ?
C7 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C14 C13 H13 119.6 . . ?
C14 C13 C18 120.8(3) . . ?
C18 C13 H13 119.6 . . ?
C13 C14 H14 120.3 . . ?
C13 C14 C15 119.5(3) . . ?
C15 C14 H14 120.3 . . ?
C14 C15 H15 119.5 . . ?
C16 C15 C14 121.0(3) . . ?
C16 C15 H15 119.5 . . ?
C15 C16 P2 118.6(2) . . ?
C15 C16 C17 119.1(3) . . ?
C17 C16 P2 122.4(2) . . ?
C16 C17 H17 120.5 . . ?
C16 C17 C18 118.9(3) . . ?
C18 C17 H17 120.5 . . ?
C13 C18 C17 120.8(3) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C20 C19 H19 119.9 . . ?
C24 C19 H19 119.9 . . ?
C24 C19 C20 120.1(4) . . ?
C19 C20 H20 119.8 . . ?
C19 C20 C21 120.3(4) . . ?
C21 C20 H20 119.8 . . ?
C20 C21 H21 119.9 . . ?
C20 C21 C22 120.2(3) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 P2 119.5(2) . . ?
C21 C22 C23 118.8(3) . . ?
C23 C22 P2 121.3(3) . . ?
C22 C23 H23 119.8 . . ?
C22 C23 C24 120.3(4) . . ?
C24 C23 H23 119.8 . . ?
C19 C24 C23 120.2(4) . . ?
C19 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
P2 C25 H25A 109.1 . . ?
P2 C25 H25B 109.1 . . ?
H25A C25 H25B 107.8 . . ?
C26 C25 P2 112.62(19) . . ?
C26 C25 H25A 109.1 . . ?
C26 C25 H25B 109.1 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
C25 C26 C27 110.6(2) . . ?
H26A C26 H26B 108.1 . . ?
C27 C26 H26A 109.5 . . ?
C27 C26 H26B 109.5 . . ?
P1 C27 H27A 108.9 . . ?
P1 C27 H27B 108.9 . . ?
C26 C27 P1 113.27(18) . . ?
C26 C27 H27A 108.9 . . ?
C26 C27 H27B 108.9 . . ?
H27A C27 H27B 107.7 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C29 C28 H28A 109.5 . . ?
C29 C28 H28B 109.5 . . ?
C29 C28 H28C 109.5 . . ?
N1 C29 C28 177.7(7) . . ?
O1 Mo1 O2 102.93(12) . . ?
O1 Mo1 O3 104.58(14) . . ?
O1 Mo1 O5 102.50(13) . 2_666 ?
O1 Mo1 O9 103.74(12) . . ?
O1 Mo1 O10 178.08(12) . . ?
O2 Mo1 O5 84.59(10) . 2_666 ?
O2 Mo1 O10 76.27(6) . . ?
O3 Mo1 O2 88.81(10) . . ?
O3 Mo1 O5 152.91(9) . 2_666 ?
O3 Mo1 O9 89.20(10) . . ?
O3 Mo1 O10 77.19(7) . . ?
O5 Mo1 O10 75.72(6) 2_666 . ?
O9 Mo1 O2 152.88(9) . . ?
O9 Mo1 O5 84.97(9) . 2_666 ?
O9 Mo1 O10 76.92(6) . . ?
O3 Mo2 O8 82.59(10) . 2_666 ?
O3 Mo2 O10 75.63(6) . . ?
O4 Mo2 O3 103.03(13) . . ?
O4 Mo2 O5 103.70(13) . . ?
O4 Mo2 O6 104.58(11) . . ?
O4 Mo2 O8 102.35(10) . 2_666 ?
O4 Mo2 O10 177.48(9) . . ?
O5 Mo2 O3 152.81(9) . . ?
O5 Mo2 O8 86.94(9) . 2_666 ?
O5 Mo2 O10 77.46(7) . . ?
O6 Mo2 O3 86.87(10) . . ?
O6 Mo2 O5 91.18(10) . . ?
O6 Mo2 O8 152.66(9) . 2_666 ?
O6 Mo2 O10 77.56(6) . . ?
O8 Mo2 O10 75.41(6) 2_666 . ?
O2 Mo3 O6 84.77(10) 2_666 . ?
O2 Mo3 O9 153.13(9) 2_666 . ?
O2 Mo3 O10 76.49(6) 2_666 . ?
O6 Mo3 O10 75.78(6) . . ?
O7 Mo3 O2 102.94(11) . 2_666 ?
O7 Mo3 O6 101.79(10) . . ?
O7 Mo3 O8 104.94(10) . . ?
O7 Mo3 O9 103.44(11) . . ?
O7 Mo3 O10 177.51(8) . . ?
O8 Mo3 O2 88.83(10) . 2_666 ?
O8 Mo3 O6 153.27(8) . . ?
O8 Mo3 O9 89.30(10) . . ?
O8 Mo3 O10 77.49(6) . . ?
O9 Mo3 O6 84.94(10) . . ?
O9 Mo3 O10 76.94(6) . . ?
Mo3 O2 Mo1 116.81(10) 2_666 . ?
Mo1 O3 Mo2 117.15(10) . . ?
Mo2 O5 Mo1 116.65(11) . 2_666 ?
Mo2 O6 Mo3 116.56(10) . . ?
Mo3 O8 Mo2 117.01(10) . 2_666 ?
Mo3 O9 Mo1 116.19(10) . . ?
Mo1 O10 Mo1 180.0 2_666 . ?
Mo1 O10 Mo2 90.076(12) 2_666 . ?
Mo1 O10 Mo2 90.075(12) . 2_666 ?
Mo1 O10 Mo2 89.925(12) 2_666 2_666 ?
Mo1 O10 Mo2 89.924(12) . . ?
Mo2 O10 Mo2 180.0 2_666 . ?
Mo3 O10 Mo1 90.055(10) . 2_666 ?
Mo3 O10 Mo1 89.943(10) . . ?
Mo3 O10 Mo1 89.946(10) 2_666 2_666 ?
Mo3 O10 Mo1 90.056(10) 2_666 . ?
Mo3 O10 Mo2 90.018(9) . . ?
Mo3 O10 Mo2 89.983(9) 2_666 . ?
Mo3 O10 Mo2 90.018(9) 2_666 2_666 ?
Mo3 O10 Mo2 89.981(9) . 2_666 ?
Mo3 O10 Mo3 180.0 2_666 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P1 C4 C3 -97.3(3) . . . . ?
Ag1 P1 C4 C5 82.3(3) . . . . ?
Ag1 P1 C10 C9 -167.1(2) . . . . ?
Ag1 P1 C10 C11 11.1(3) . . . . ?
Ag1 P1 C27 C26 -57.0(2) . . . . ?
Ag1 P2 C16 C15 -9.5(2) 2_676 . . . ?
Ag1 P2 C16 C17 171.6(2) 2_676 . . . ?
Ag1 P2 C22 C21 77.8(3) 2_676 . . . ?
Ag1 P2 C22 C23 -94.5(3) 2_676 . . . ?
Ag1 P2 C25 C26 45.2(2) 2_676 . . . ?
P1 C4 C5 C6 -179.6(3) . . . . ?
P1 C10 C11 C12 -177.8(2) . . . . ?
P2 C16 C17 C18 179.6(2) . . . . ?
P2 C22 C23 C24 172.8(3) . . . . ?
P2 C25 C26 C27 175.07(18) . . . . ?
C1 C2 C3 C4 0.2(6) . . . . ?
C2 C1 C6 C5 1.6(6) . . . . ?
C2 C3 C4 P1 180.0(3) . . . . ?
C2 C3 C4 C5 0.4(5) . . . . ?
C3 C4 C5 C6 0.0(5) . . . . ?
C4 P1 C10 C9 -41.7(3) . . . . ?
C4 P1 C10 C11 136.5(2) . . . . ?
C4 P1 C27 C26 175.58(19) . . . . ?
C4 C5 C6 C1 -1.0(6) . . . . ?
C6 C1 C2 C3 -1.2(6) . . . . ?
C7 C8 C9 C10 0.5(5) . . . . ?
C8 C7 C12 C11 -0.3(5) . . . . ?
C8 C9 C10 P1 177.5(2) . . . . ?
C8 C9 C10 C11 -0.7(4) . . . . ?
C9 C10 C11 C12 0.5(5) . . . . ?
C10 P1 C4 C3 139.5(3) . . . . ?
C10 P1 C4 C5 -40.9(3) . . . . ?
C10 P1 C27 C26 67.3(2) . . . . ?
C10 C11 C12 C7 0.0(5) . . . . ?
C12 C7 C8 C9 0.0(5) . . . . ?
C13 C14 C15 C16 0.4(5) . . . . ?
C14 C13 C18 C17 0.5(5) . . . . ?
C14 C15 C16 P2 -179.5(2) . . . . ?
C14 C15 C16 C17 -0.6(4) . . . . ?
C15 C16 C17 C18 0.8(4) . . . . ?
C16 P2 C22 C21 -158.3(2) . . . . ?
C16 P2 C22 C23 29.4(3) . . . . ?
C16 P2 C25 C26 -82.3(2) . . . . ?
C16 C17 C18 C13 -0.8(5) . . . . ?
C18 C13 C14 C15 -0.3(5) . . . . ?
C19 C20 C21 C22 0.7(6) . . . . ?
C20 C19 C24 C23 0.8(8) . . . . ?
C20 C21 C22 P2 -173.0(3) . . . . ?
C20 C21 C22 C23 -0.5(5) . . . . ?
C21 C22 C23 C24 0.5(6) . . . . ?
C22 P2 C16 C15 -130.3(2) . . . . ?
C22 P2 C16 C17 50.8(3) . . . . ?
C22 P2 C25 C26 166.2(2) . . . . ?
C22 C23 C24 C19 -0.7(7) . . . . ?
C24 C19 C20 C21 -0.8(7) . . . . ?
C25 P2 C16 C15 119.5(2) . . . . ?
C25 P2 C16 C17 -59.3(3) . . . . ?
C25 P2 C22 C21 -48.2(3) . . . . ?
C25 P2 C22 C23 139.6(3) . . . . ?
C25 C26 C27 P1 168.03(19) . . . . ?
C27 P1 C4 C3 29.0(3) . . . . ?
C27 P1 C4 C5 -151.4(3) . . . . ?
C27 P1 C10 C9 67.4(2) . . . . ?
C27 P1 C10 C11 -114.3(2) . . . . ?
O1 Mo1 O3 Mo2 -177.95(14) . . . . ?
O2 Mo1 O3 Mo2 79.00(13) . . . . ?
O2 Mo3 O8 Mo2 79.29(12) 2_666 . . 2_666 ?
O3 Mo2 O5 Mo1 11.0(3) . . . 2_666 ?
O3 Mo2 O6 Mo3 -78.65(13) . . . . ?
O4 Mo2 O5 Mo1 -179.74(12) . . . 2_666 ?
O4 Mo2 O6 Mo3 178.69(15) . . . . ?
O5 Mo1 O3 Mo2 3.3(3) 2_666 . . . ?
O5 Mo2 O6 Mo3 74.20(13) . . . . ?
O6 Mo2 O5 Mo1 -74.42(12) . . . 2_666 ?
O6 Mo3 O8 Mo2 3.4(3) . . . 2_666 ?
O7 Mo3 O8 Mo2 -177.63(13) . . . 2_666 ?
O8 Mo2 O5 Mo1 78.29(12) 2_666 . . 2_666 ?
O8 Mo2 O6 Mo3 -11.4(3) 2_666 . . . ?
O9 Mo1 O3 Mo2 -73.96(13) . . . . ?
O9 Mo3 O8 Mo2 -73.90(12) . . . 2_666 ?
O10 Mo1 O3 Mo2 2.81(10) . . . . ?
O10 Mo2 O5 Mo1 2.56(9) . . . 2_666 ?
O10 Mo2 O6 Mo3 -2.68(10) . . . . ?
O10 Mo3 O8 Mo2 2.88(9) . . . 2_666 ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1234_a
_database_code_depnum_ccdc_archive 'CCDC 2326044'
loop_
_audit_author_name
_audit_author_address
jiang
;zhejiang normal university
China
;
_audit_update_record             
;
2024-01-17 deposited with the CCDC.	2024-02-26 downloaded from the CCDC.
;
_audit_creation_date             2023-10-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'O40 P W12, 2(C54 H52 Ag2 P4)'
_chemical_formula_sum            'C108 H104 Ag4 O40 P9 W12'
_chemical_formula_weight         4958.32
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   15.7042(10)
_cell_length_b                   22.4607(16)
_cell_length_c                   20.2442(15)
_cell_angle_alpha                90
_cell_angle_beta                 102.668(2)
_cell_angle_gamma                90
_cell_volume                     6966.9(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9955
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      26.24
_cell_measurement_theta_min      2.25
_shelx_estimated_absorpt_T_max   0.418
_shelx_estimated_absorpt_T_min   0.363
_exptl_absorpt_coefficient_mu    10.580
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5034
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1151 before and 0.0804 after correction.
The Ratio of minimum to maximum transmission is 0.6753.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.364
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4566
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1065
_diffrn_reflns_av_unetI/netI     0.0586
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            92378
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.682
_diffrn_reflns_theta_min         2.248
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'BRUKER D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8949
_reflns_number_total             13212
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.852
_refine_diff_density_min         -3.256
_refine_diff_density_rms         0.369
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     703
_refine_ls_number_reflns         13212
_refine_ls_number_restraints     1014
_refine_ls_R_factor_all          0.0984
_refine_ls_R_factor_gt           0.0656
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1177P)²+94.1975P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1911
_refine_ls_wR_factor_ref         0.2166
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Uiso/Uaniso restraints and constraints
: within 3.8A with sigma of 0.01 and sigma for terminal atoms of 0.02 within
3.8A
3. Others
 Fixed Sof: O22(0.5) O19(0.5) O20(0.5) O21(0.5)
4.a Secondary CH2 refined with riding coordinates:
 C27(H27A,H27B), C26(H26A,H26B), C25(H25A,H25B), C27(H27A,H27B), C26(H26A,
 H26B), C25(H25A,H25B)
4.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C18(H18), C19(H19), C20(H20),
  C21(H21), C23(H23), C24(H24), C2(H2), C3(H3), C5(H5), C6(H6), C1(H1), C7(H7),
 C8(H8), C9(H9), C11(H11), C12(H12), C18(H18), C17(H17), C15(H15), C14(H14),
 C13(H13), C19(H19), C20(H20), C21(H21), C23(H23), C24(H24)
4.c Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6), C7(C8,C9,C10,C11,C12), C13(C14,C15,C16,C17,C18), C19(C20,
 C21,C22,C23,C24), C2(C3,C4,C5,C6,C1), C7(C8,C9,C10,C11,C12), C18(C17,C16,C15,
 C14,C13), C19(C20,C21,C22,C23,C24)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W4 W 0.41407(4) 0.45162(3) 0.33116(3) 0.04158(18) Uani 1 1 d . . . . .
W2 W 0.43887(5) 0.36366(3) 0.56408(3) 0.04516(19) Uani 1 1 d . . . . .
W5 W 0.27911(4) 0.45003(3) 0.45234(4) 0.0483(2) Uani 1 1 d . . . . .
W1 W 0.57002(5) 0.36232(3) 0.44235(4) 0.0518(2) Uani 1 1 d . . . . .
W3 W 0.65909(5) 0.41221(4) 0.61064(4) 0.0526(2) Uani 1 1 d . . . . .
W6 W 0.63526(5) 0.49943(4) 0.37898(4) 0.0576(2) Uani 1 1 d . . . . .
Ag1 Ag 0.31038(8) 0.29660(8) 0.68347(7) 0.0619(4) Uani 1 1 d . . . . .
Ag2 Ag 0.46813(10) 0.19800(8) 0.52519(7) 0.0676(5) Uani 1 1 d . . . . .
P5 P 0.500000 0.500000 0.500000 0.0223(9) Uani 1 2 d S . P . .
O4 O 0.4075(9) 0.2984(6) 0.5929(7) 0.066(4) Uani 1 1 d . . . . .
O10 O 0.4753(9) 0.3833(7) 0.3683(7) 0.072(4) Uani 1 1 d . . . . .
O9 O 0.3728(10) 0.4296(6) 0.2514(6) 0.067(4) Uani 1 1 d . . . . .
O5 O 0.5517(9) 0.3734(8) 0.6164(6) 0.082(5) Uani 1 1 d . . . . .
O8 O 0.5245(8) 0.4835(7) 0.3228(8) 0.072(4) Uani 1 1 d . . . . .
O1 O 0.6037(11) 0.2978(7) 0.4146(10) 0.091(5) Uani 1 1 d . . . . .
O2 O 0.4871(9) 0.3355(8) 0.4913(7) 0.082(5) Uani 1 1 d . . . . .
O11 O 0.3284(9) 0.4267(6) 0.3766(8) 0.068(4) Uani 1 1 d . . . . .
O12 O 0.1754(8) 0.4245(7) 0.4301(8) 0.072(4) Uani 1 1 d . . . . .
O7 O 0.3720(10) 0.5294(6) 0.3295(9) 0.082(5) Uani 1 1 d . . . . .
O14 O 0.2723(10) 0.5295(6) 0.4192(9) 0.080(5) Uani 1 1 d . . . . .
O18 O 0.6382(9) 0.4187(7) 0.4080(8) 0.078(4) Uani 1 1 d . . . . .
O16 O 0.3991(12) 0.4171(8) 0.6229(8) 0.101(6) Uani 1 1 d . . . . .
O6 O 0.7321(11) 0.3708(7) 0.6644(8) 0.083(5) Uani 1 1 d . . . . .
O22 O 0.5730(11) 0.5320(8) 0.4749(9) 0.027(4) Uani 0.5 1 d . . P A -1
O13 O 0.3353(12) 0.3826(7) 0.4967(7) 0.093(6) Uani 1 1 d . . . . .
O17 O 0.6943(10) 0.4999(7) 0.3198(9) 0.087(5) Uani 1 1 d . . . . .
O15 O 0.2805(13) 0.4839(7) 0.5377(9) 0.100(6) Uani 1 1 d . . . . .
O19 O 0.4185(12) 0.4977(8) 0.4391(9) 0.029(4) Uani 0.5 1 d . . P A -1
O20 O 0.4837(11) 0.5315(9) 0.5587(10) 0.032(4) Uani 0.5 1 d . . P A -1
O21 O 0.5328(12) 0.4366(9) 0.5190(9) 0.033(4) Uani 0.5 1 d . . P A -1
O3 O 0.6522(9) 0.3728(7) 0.5265(7) 0.076(4) Uani 1 1 d . . . . .
P2_1 P 0.1653(3) 0.2912(2) 0.6135(2) 0.0399(9) Uani 1 1 d . . . . .
C27_1 C 0.1644(14) 0.2825(10) 0.5244(10) 0.068(3) Uani 1 1 d . U . . .
H27A_1 H 0.105246 0.273161 0.500801 0.082 Uiso 1 1 calc R U . . .
H27B_1 H 0.179548 0.320484 0.507313 0.082 Uiso 1 1 calc R U . . .
C26_1 C 0.2228(15) 0.2369(10) 0.5066(11) 0.070(3) Uani 1 1 d . U . . .
H26A_1 H 0.192216 0.199084 0.501691 0.084 Uiso 1 1 calc R U . . .
H26B_1 H 0.272870 0.232972 0.544080 0.084 Uiso 1 1 calc R U . . .
C25_1 C 0.2558(14) 0.2480(10) 0.4427(10) 0.066(2) Uani 1 1 d . U . . .
H25A_1 H 0.277679 0.288488 0.443640 0.080 Uiso 1 1 calc R U . . .
H25B_1 H 0.207478 0.244386 0.403858 0.080 Uiso 1 1 calc R U . . .
P1_1 P 0.3426(3) 0.1965(2) 0.4326(2) 0.0479(11) Uani 1 1 d . . . . .
C1_1 C -0.0207(9) 0.4496(6) 0.6085(8) 0.085(3) Uani 1 1 d G U . . .
H1_1 H -0.057935 0.482142 0.606212 0.102 Uiso 1 1 calc R U . . .
C2_1 C -0.0549(7) 0.3924(7) 0.5985(8) 0.081(3) Uani 1 1 d G U . . .
H2_1 H -0.114952 0.386661 0.589529 0.098 Uiso 1 1 calc R U . . .
C3_1 C 0.0008(9) 0.3439(5) 0.6018(8) 0.078(3) Uani 1 1 d G U . . .
H3_1 H -0.022094 0.305593 0.595124 0.093 Uiso 1 1 calc R U . . .
C4_1 C 0.0906(9) 0.3525(6) 0.6152(8) 0.076(3) Uani 1 1 d G U . . .
C5_1 C 0.1247(7) 0.4097(7) 0.6252(8) 0.081(3) Uani 1 1 d G U . . .
H5_1 H 0.184799 0.415487 0.634086 0.098 Uiso 1 1 calc R U . . .
C6_1 C 0.0691(10) 0.4583(5) 0.6218(9) 0.087(3) Uani 1 1 d G U . . .
H6_1 H 0.091942 0.496555 0.628492 0.104 Uiso 1 1 calc R U . . .
C7_1 C 0.0520(11) 0.1236(6) 0.6932(8) 0.087(3) Uani 1 1 d G U . . .
H7_1 H 0.031386 0.089492 0.710525 0.105 Uiso 1 1 calc R U . . .
C8_1 C 0.0870(11) 0.1698(7) 0.7364(6) 0.086(3) Uani 1 1 d G U . . .
H8_1 H 0.089783 0.166589 0.782613 0.103 Uiso 1 1 calc R U . . .
C9_1 C 0.1179(11) 0.2208(6) 0.7105(7) 0.084(3) Uani 1 1 d G U . . .
H9_1 H 0.141266 0.251680 0.739387 0.101 Uiso 1 1 calc R U . . .
C10_1 C 0.1137(11) 0.2256(6) 0.6414(7) 0.075(2) Uani 1 1 d G U . . .
C11_1 C 0.0787(11) 0.1794(7) 0.5982(6) 0.084(3) Uani 1 1 d G U . . .
H11_1 H 0.075955 0.182577 0.551986 0.101 Uiso 1 1 calc R U . . .
C12_1 C 0.0479(11) 0.1284(6) 0.6241(7) 0.093(3) Uani 1 1 d G U . . .
H12_1 H 0.024472 0.097486 0.595210 0.111 Uiso 1 1 calc R U . . .
C13_1 C 0.4027(10) 0.2390(6) 0.2252(6) 0.074(3) Uani 1 1 d G U . . .
H13_1 H 0.414819 0.246846 0.183093 0.089 Uiso 1 1 calc R U . . .
C14_1 C 0.3628(10) 0.2821(5) 0.2573(7) 0.074(3) Uani 1 1 d G U . . .
H14_1 H 0.348282 0.318846 0.236704 0.088 Uiso 1 1 calc R U . . .
C15_1 C 0.3446(10) 0.2703(6) 0.3202(7) 0.070(3) Uani 1 1 d G U . . .
H15_1 H 0.317964 0.299206 0.341691 0.084 Uiso 1 1 calc R U . . .
C16_1 C 0.3663(10) 0.2154(6) 0.3510(6) 0.070(2) Uani 1 1 d G U . . .
C17_1 C 0.4062(10) 0.1723(5) 0.3189(7) 0.077(3) Uani 1 1 d G U . . .
H17_1 H 0.420719 0.135565 0.339457 0.093 Uiso 1 1 calc R U . . .
C18_1 C 0.4244(10) 0.1841(6) 0.2560(7) 0.076(3) Uani 1 1 d G U . . .
H18_1 H 0.451038 0.155204 0.234470 0.092 Uiso 1 1 calc R U . . .
C19_1 C 0.1901(10) 0.0216(6) 0.3944(8) 0.087(3) Uani 1 1 d G U . . .
H19_1 H 0.158440 -0.013677 0.386662 0.104 Uiso 1 1 calc R U . . .
C20_1 C 0.1836(10) 0.0634(7) 0.3429(6) 0.086(3) Uani 1 1 d G U . . .
H20_1 H 0.147639 0.056105 0.300727 0.103 Uiso 1 1 calc R U . . .
C21_1 C 0.2310(11) 0.1161(6) 0.3546(7) 0.079(3) Uani 1 1 d G U . . .
H21_1 H 0.226636 0.144062 0.320111 0.095 Uiso 1 1 calc R U . . .
C22_1 C 0.2848(10) 0.1270(5) 0.4177(8) 0.076(2) Uani 1 1 d G U . . .
C23_1 C 0.2912(10) 0.0852(7) 0.4691(6) 0.080(3) Uani 1 1 d G U . . .
H23_1 H 0.327236 0.092457 0.511364 0.096 Uiso 1 1 calc R U . . .
C24_1 C 0.2439(11) 0.0325(6) 0.4575(7) 0.087(3) Uani 1 1 d G U . . .
H24_1 H 0.248240 0.004500 0.491982 0.104 Uiso 1 1 calc R U . . .
P2_2 P 0.4290(3) 0.2894(2) 0.7819(2) 0.0429(10) Uani 1 1 d . . . . .
C27_2 C 0.5340(14) 0.2810(10) 0.7588(11) 0.067(3) Uani 1 1 d . U . . .
H27A_2 H 0.546384 0.316817 0.735853 0.080 Uiso 1 1 calc R U . . .
H27B_2 H 0.579200 0.276766 0.799752 0.080 Uiso 1 1 calc R U . . .
C26_2 C 0.5374(14) 0.2290(10) 0.7144(12) 0.072(3) Uani 1 1 d . U . . .
H26A_2 H 0.484036 0.227645 0.679510 0.086 Uiso 1 1 calc R U . . .
H26B_2 H 0.540310 0.192831 0.740953 0.086 Uiso 1 1 calc R U . . .
C25_2 C 0.6134(15) 0.2309(11) 0.6816(12) 0.076(3) Uani 1 1 d . U . . .
H25A_2 H 0.666303 0.221300 0.714714 0.091 Uiso 1 1 calc R U . . .
H25B_2 H 0.619654 0.270793 0.664855 0.091 Uiso 1 1 calc R U . . .
C2_2 C 0.3194(7) 0.1643(6) 0.8815(7) 0.073(3) Uani 1 1 d G U . . .
H2_2 H 0.263168 0.155133 0.885942 0.088 Uiso 1 1 calc R U . . .
C3_2 C 0.3333(8) 0.2128(6) 0.8425(7) 0.073(3) Uani 1 1 d G U . . .
H3_2 H 0.286437 0.236044 0.820875 0.087 Uiso 1 1 calc R U . . .
C4_2 C 0.4173(9) 0.2266(5) 0.8359(7) 0.069(2) Uani 1 1 d G U . . .
C5_2 C 0.4874(7) 0.1918(6) 0.8682(7) 0.072(2) Uani 1 1 d G U . . .
H5_2 H 0.543620 0.201015 0.863745 0.086 Uiso 1 1 calc R U . . .
C6_2 C 0.4735(8) 0.1433(6) 0.9072(7) 0.072(3) Uani 1 1 d G U . . .
H6_2 H 0.520352 0.120104 0.928813 0.087 Uiso 1 1 calc R U . . .
C1_2 C 0.3895(9) 0.1296(5) 0.9138(7) 0.072(3) Uani 1 1 d G U . . .
H1_2 H 0.380127 0.097162 0.939912 0.087 Uiso 1 1 calc R U . . .
P1_2 P 0.5982(3) 0.1765(2) 0.6096(2) 0.0509(11) Uani 1 1 d . . . . .
C7_2 C 0.4560(12) 0.4565(6) 0.9146(8) 0.089(3) Uani 1 1 d G U . . .
H7_2 H 0.461380 0.490905 0.940656 0.107 Uiso 1 1 calc R U . . .
C8_2 C 0.5006(10) 0.4052(7) 0.9404(6) 0.089(3) Uani 1 1 d G U . . .
H8_2 H 0.535901 0.405280 0.983783 0.107 Uiso 1 1 calc R U . . .
C9_2 C 0.4925(10) 0.3537(6) 0.9014(8) 0.081(3) Uani 1 1 d G U . . .
H9_2 H 0.522412 0.319372 0.918685 0.098 Uiso 1 1 calc R U . . .
C10_2 C 0.4398(11) 0.3535(6) 0.8366(7) 0.076(3) Uani 1 1 d G U . . .
C11_2 C 0.3952(11) 0.4048(7) 0.8107(6) 0.089(3) Uani 1 1 d G U . . .
H11_2 H 0.359880 0.404712 0.767332 0.107 Uiso 1 1 calc R U . . .
C12_2 C 0.4032(11) 0.4563(6) 0.8497(8) 0.090(3) Uani 1 1 d G U . . .
H12_2 H 0.373368 0.490621 0.832429 0.108 Uiso 1 1 calc R U . . .
C18_2 C 0.5394(11) 0.0053(7) 0.6428(9) 0.099(3) Uani 1 1 d G U . . .
H18_2 H 0.502312 -0.023878 0.619978 0.118 Uiso 1 1 calc R U . . .
C17_2 C 0.5425(11) 0.0610(8) 0.6136(7) 0.096(3) Uani 1 1 d G U . . .
H17_2 H 0.507503 0.069162 0.571242 0.115 Uiso 1 1 calc R U . . .
C16_2 C 0.5980(12) 0.1047(6) 0.6478(9) 0.087(3) Uani 1 1 d G U . . .
C15_2 C 0.6504(10) 0.0925(7) 0.7111(9) 0.091(3) Uani 1 1 d G U . . .
H15_2 H 0.687462 0.121719 0.733949 0.109 Uiso 1 1 calc R U . . .
C14_2 C 0.6472(11) 0.0368(8) 0.7403(7) 0.096(3) Uani 1 1 d G U . . .
H14_2 H 0.682273 0.028680 0.782686 0.115 Uiso 1 1 calc R U . . .
C13_2 C 0.5918(12) -0.0068(6) 0.7062(9) 0.097(3) Uani 1 1 d G U . . .
H13_2 H 0.589698 -0.044119 0.725701 0.116 Uiso 1 1 calc R U . . .
C19_2 C 0.8490(9) 0.1935(8) 0.5286(10) 0.099(3) Uani 1 1 d G U . . .
H19_2 H 0.899080 0.197087 0.511446 0.119 Uiso 1 1 calc R U . . .
C20_2 C 0.7974(11) 0.2432(6) 0.5320(9) 0.098(3) Uani 1 1 d G U . . .
H20_2 H 0.812886 0.279995 0.517183 0.117 Uiso 1 1 calc R U . . .
C21_2 C 0.7225(10) 0.2379(6) 0.5576(9) 0.092(3) Uani 1 1 d G U . . .
H21_2 H 0.687938 0.271102 0.559901 0.110 Uiso 1 1 calc R U . . .
C22_2 C 0.6993(9) 0.1829(8) 0.5798(9) 0.089(3) Uani 1 1 d G U . . .
C23_2 C 0.7509(11) 0.1332(6) 0.5763(9) 0.097(3) Uani 1 1 d G U . . .
H23_2 H 0.735373 0.096391 0.591146 0.117 Uiso 1 1 calc R U . . .
C24_2 C 0.8258(10) 0.1385(7) 0.5507(10) 0.102(3) Uani 1 1 d G U . . .
H24_2 H 0.860323 0.105284 0.548428 0.123 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W4 O10 1.878(14) . ?
W4 O9 1.678(11) . ?
W4 O8 1.918(13) . ?
W4 O11 1.874(12) . ?
W4 O7 1.866(13) . ?
W4 O19 2.404(19) . ?
W2 O4 1.690(12) . ?
W2 O5 1.868(13) . ?
W2 O2 1.907(15) . ?
W2 O16 1.891(16) . ?
W2 O13 1.927(14) . ?
W2 O21 2.506(17) . ?
W5 O11 1.936(12) . ?
W5 O12 1.692(12) . ?
W5 O14 1.902(14) . ?
W5 O13 1.879(14) . ?
W5 O15 1.884(17) . ?
W5 O19 2.504(17) . ?
W1 O10 1.924(13) . ?
W1 O1 1.680(15) . ?
W1 O2 1.898(14) . ?
W1 O18 1.888(14) . ?
W1 O21 2.44(2) . ?
W1 O3 1.912(14) . ?
W3 O5 1.924(14) . ?
W3 O7 1.920(13) 3_666 ?
W3 O14 1.877(13) 3_666 ?
W3 O6 1.678(14) . ?
W3 O21 2.462(19) . ?
W3 O3 1.902(14) . ?
W6 O8 1.892(13) . ?
W6 O18 1.903(15) . ?
W6 O16 1.949(16) 3_666 ?
W6 O22 2.468(18) . ?
W6 O17 1.668(15) . ?
W6 O15 1.938(16) 3_666 ?
Ag1 P2_1 2.408(4) . ?
Ag1 P2_2 2.417(4) . ?
Ag2 P1_1 2.404(5) . ?
Ag2 P1_2 2.407(5) . ?
P5 O22 1.532(18) . ?
P5 O19 1.571(19) . ?
P5 O20 1.45(2) . ?
P5 O21 1.53(2) . ?
P2_1 C27_1 1.81(2) . ?
P2_1 C4_1 1.814(11) . ?
P2_1 C10_1 1.830(11) . ?
C27_1 H27A_1 0.9700 . ?
C27_1 H27B_1 0.9700 . ?
C27_1 C26_1 1.47(3) . ?
C26_1 H26A_1 0.9700 . ?
C26_1 H26B_1 0.9700 . ?
C26_1 C25_1 1.51(3) . ?
C25_1 H25A_1 0.9700 . ?
C25_1 H25B_1 0.9700 . ?
C25_1 P1_1 1.83(2) . ?
P1_1 C16_1 1.823(10) . ?
P1_1 C22_1 1.799(12) . ?
C1_1 H1_1 0.9300 . ?
C1_1 C2_1 1.3900 . ?
C1_1 C6_1 1.3900 . ?
C2_1 H2_1 0.9300 . ?
C2_1 C3_1 1.3900 . ?
C3_1 H3_1 0.9300 . ?
C3_1 C4_1 1.3900 . ?
C4_1 C5_1 1.3900 . ?
C5_1 H5_1 0.9300 . ?
C5_1 C6_1 1.3900 . ?
C6_1 H6_1 0.9300 . ?
C7_1 H7_1 0.9300 . ?
C7_1 C8_1 1.3900 . ?
C7_1 C12_1 1.3900 . ?
C8_1 H8_1 0.9300 . ?
C8_1 C9_1 1.3900 . ?
C9_1 H9_1 0.9300 . ?
C9_1 C10_1 1.3900 . ?
C10_1 C11_1 1.3900 . ?
C11_1 H11_1 0.9300 . ?
C11_1 C12_1 1.3900 . ?
C12_1 H12_1 0.9300 . ?
C13_1 H13_1 0.9300 . ?
C13_1 C14_1 1.3900 . ?
C13_1 C18_1 1.3900 . ?
C14_1 H14_1 0.9300 . ?
C14_1 C15_1 1.3900 . ?
C15_1 H15_1 0.9300 . ?
C15_1 C16_1 1.3900 . ?
C16_1 C17_1 1.3900 . ?
C17_1 H17_1 0.9300 . ?
C17_1 C18_1 1.3900 . ?
C18_1 H18_1 0.9300 . ?
C19_1 H19_1 0.9300 . ?
C19_1 C20_1 1.3900 . ?
C19_1 C24_1 1.3900 . ?
C20_1 H20_1 0.9300 . ?
C20_1 C21_1 1.3900 . ?
C21_1 H21_1 0.9300 . ?
C21_1 C22_1 1.3900 . ?
C22_1 C23_1 1.3900 . ?
C23_1 H23_1 0.9300 . ?
C23_1 C24_1 1.3900 . ?
C24_1 H24_1 0.9300 . ?
P2_2 C27_2 1.82(2) . ?
P2_2 C4_2 1.819(11) . ?
P2_2 C10_2 1.800(11) . ?
C27_2 H27A_2 0.9700 . ?
C27_2 H27B_2 0.9700 . ?
C27_2 C26_2 1.48(3) . ?
C26_2 H26A_2 0.9700 . ?
C26_2 H26B_2 0.9700 . ?
C26_2 C25_2 1.49(3) . ?
C25_2 H25A_2 0.9700 . ?
C25_2 H25B_2 0.9700 . ?
C25_2 P1_2 1.88(2) . ?
C2_2 H2_2 0.9300 . ?
C2_2 C3_2 1.3900 . ?
C2_2 C1_2 1.3900 . ?
C3_2 H3_2 0.9300 . ?
C3_2 C4_2 1.3900 . ?
C4_2 C5_2 1.3900 . ?
C5_2 H5_2 0.9300 . ?
C5_2 C6_2 1.3900 . ?
C6_2 H6_2 0.9300 . ?
C6_2 C1_2 1.3900 . ?
C1_2 H1_2 0.9300 . ?
P1_2 C16_2 1.789(13) . ?
P1_2 C22_2 1.824(12) . ?
C7_2 H7_2 0.9300 . ?
C7_2 C8_2 1.3900 . ?
C7_2 C12_2 1.3900 . ?
C8_2 H8_2 0.9300 . ?
C8_2 C9_2 1.3900 . ?
C9_2 H9_2 0.9300 . ?
C9_2 C10_2 1.3900 . ?
C10_2 C11_2 1.3900 . ?
C11_2 H11_2 0.9300 . ?
C11_2 C12_2 1.3900 . ?
C12_2 H12_2 0.9300 . ?
C18_2 H18_2 0.9300 . ?
C18_2 C17_2 1.3900 . ?
C18_2 C13_2 1.3900 . ?
C17_2 H17_2 0.9300 . ?
C17_2 C16_2 1.3900 . ?
C16_2 C15_2 1.3900 . ?
C15_2 H15_2 0.9300 . ?
C15_2 C14_2 1.3900 . ?
C14_2 H14_2 0.9300 . ?
C14_2 C13_2 1.3900 . ?
C13_2 H13_2 0.9300 . ?
C19_2 H19_2 0.9300 . ?
C19_2 C20_2 1.3900 . ?
C19_2 C24_2 1.3900 . ?
C20_2 H20_2 0.9300 . ?
C20_2 C21_2 1.3900 . ?
C21_2 H21_2 0.9300 . ?
C21_2 C22_2 1.3900 . ?
C22_2 C23_2 1.3900 . ?
C23_2 H23_2 0.9300 . ?
C23_2 C24_2 1.3900 . ?
C24_2 H24_2 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10 W4 O8 87.0(6) . . ?
O10 W4 O19 94.4(7) . . ?
O9 W4 O10 101.6(7) . . ?
O9 W4 O8 101.0(7) . . ?
O9 W4 O11 102.5(7) . . ?
O9 W4 O7 101.4(7) . . ?
O9 W4 O19 158.4(7) . . ?
O8 W4 O19 94.2(6) . . ?
O11 W4 O10 85.3(6) . . ?
O11 W4 O8 156.3(7) . . ?
O11 W4 O19 64.1(6) . . ?
O7 W4 O10 157.0(8) . . ?
O7 W4 O8 88.4(6) . . ?
O7 W4 O11 90.0(6) . . ?
O7 W4 O19 63.5(7) . . ?
O4 W2 O5 102.6(7) . . ?
O4 W2 O2 100.1(7) . . ?
O4 W2 O16 99.9(8) . . ?
O4 W2 O13 99.9(8) . . ?
O4 W2 O21 158.7(7) . . ?
O5 W2 O2 89.4(6) . . ?
O5 W2 O16 88.4(7) . . ?
O5 W2 O13 157.5(8) . . ?
O5 W2 O21 64.5(6) . . ?
O2 W2 O13 86.7(7) . . ?
O2 W2 O21 64.5(7) . . ?
O16 W2 O2 159.9(9) . . ?
O16 W2 O13 87.8(6) . . ?
O16 W2 O21 96.7(8) . . ?
O13 W2 O21 94.0(8) . . ?
O11 W5 O19 61.3(6) . . ?
O12 W5 O11 103.1(7) . . ?
O12 W5 O14 104.4(7) . . ?
O12 W5 O13 100.3(8) . . ?
O12 W5 O15 101.4(8) . . ?
O12 W5 O19 158.4(7) . . ?
O14 W5 O11 88.6(6) . . ?
O14 W5 O19 62.8(6) . . ?
O13 W5 O11 86.1(7) . . ?
O13 W5 O14 155.4(8) . . ?
O13 W5 O15 88.7(6) . . ?
O13 W5 O19 93.7(8) . . ?
O15 W5 O11 155.5(8) . . ?
O15 W5 O14 86.2(7) . . ?
O15 W5 O19 95.2(8) . . ?
O10 W1 O21 94.3(7) . . ?
O1 W1 O10 101.4(8) . . ?
O1 W1 O2 101.7(8) . . ?
O1 W1 O18 102.1(8) . . ?
O1 W1 O21 160.2(8) . . ?
O1 W1 O3 101.8(8) . . ?
O2 W1 O10 89.0(6) . . ?
O2 W1 O21 66.2(7) . . ?
O2 W1 O3 88.9(6) . . ?
O18 W1 O10 87.3(6) . . ?
O18 W1 O2 156.2(8) . . ?
O18 W1 O21 90.6(7) . . ?
O18 W1 O3 85.4(6) . . ?
O3 W1 O10 156.7(7) . . ?
O3 W1 O21 63.7(7) . . ?
O5 W3 O21 64.8(6) . . ?
O7 W3 O5 85.6(6) 3_666 . ?
O7 W3 O21 92.8(7) 3_666 . ?
O14 W3 O5 155.2(7) 3_666 . ?
O14 W3 O7 88.3(6) 3_666 3_666 ?
O14 W3 O21 91.5(7) 3_666 . ?
O14 W3 O3 87.7(7) 3_666 . ?
O6 W3 O5 101.1(8) . . ?
O6 W3 O7 101.6(8) . 3_666 ?
O6 W3 O14 103.7(8) . 3_666 ?
O6 W3 O21 159.1(8) . . ?
O6 W3 O3 102.7(8) . . ?
O3 W3 O5 88.0(6) . . ?
O3 W3 O7 155.6(7) . 3_666 ?
O3 W3 O21 63.3(7) . . ?
O8 W6 O18 87.8(6) . . ?
O8 W6 O16 87.5(7) . 3_666 ?
O8 W6 O22 93.4(6) . . ?
O8 W6 O15 157.2(8) . 3_666 ?
O18 W6 O16 155.6(8) . 3_666 ?
O18 W6 O22 91.6(7) . . ?
O18 W6 O15 87.1(7) . 3_666 ?
O16 W6 O22 64.8(7) 3_666 . ?
O17 W6 O8 98.7(8) . . ?
O17 W6 O18 104.3(7) . . ?
O17 W6 O16 100.1(8) . 3_666 ?
O17 W6 O22 160.3(7) . . ?
O17 W6 O15 104.0(9) . 3_666 ?
O15 W6 O16 88.0(6) 3_666 3_666 ?
O15 W6 O22 64.6(7) 3_666 . ?
P2_1 Ag1 P2_2 160.15(16) . . ?
P1_1 Ag2 P1_2 166.84(18) . . ?
O22 P5 O19 107.1(9) . . ?
O22 P5 O21 106.6(9) . . ?
O20 P5 O22 108.8(10) . . ?
O20 P5 O19 113.5(9) . . ?
O20 P5 O21 110.9(10) . . ?
O21 P5 O19 109.7(10) . . ?
W4 O10 W1 138.8(9) . . ?
W2 O5 W3 138.9(8) . . ?
W6 O8 W4 138.3(8) . . ?
W1 O2 W2 137.1(9) . . ?
W4 O11 W5 139.7(7) . . ?
W4 O7 W3 140.0(10) . 3_666 ?
W3 O14 W5 141.0(8) 3_666 . ?
W1 O18 W6 140.8(9) . . ?
W2 O16 W6 136.6(11) . 3_666 ?
P5 O22 W6 125.2(10) . . ?
W5 O13 W2 138.7(9) . . ?
W5 O15 W6 138.1(11) . 3_666 ?
W4 O19 W5 93.5(6) . . ?
P5 O19 W4 125.7(10) . . ?
P5 O19 W5 120.7(9) . . ?
W1 O21 W2 91.6(7) . . ?
W1 O21 W3 93.5(7) . . ?
W3 O21 W2 91.2(6) . . ?
P5 O21 W2 120.4(9) . . ?
P5 O21 W1 126.2(10) . . ?
P5 O21 W3 124.4(11) . . ?
W3 O3 W1 138.6(9) . . ?
C27_1 P2_1 Ag1 113.0(7) . . ?
C27_1 P2_1 C10_1 108.2(9) . . ?
C4_1 P2_1 Ag1 118.9(6) . . ?
C4_1 P2_1 C27_1 103.7(9) . . ?
C4_1 P2_1 C10_1 105.9(7) . . ?
C10_1 P2_1 Ag1 106.5(6) . . ?
P2_1 C27_1 H27A_1 108.1 . . ?
P2_1 C27_1 H27B_1 108.1 . . ?
H27A_1 C27_1 H27B_1 107.3 . . ?
C26_1 C27_1 P2_1 116.8(16) . . ?
C26_1 C27_1 H27A_1 108.1 . . ?
C26_1 C27_1 H27B_1 108.1 . . ?
C27_1 C26_1 H26A_1 108.2 . . ?
C27_1 C26_1 H26B_1 108.2 . . ?
C27_1 C26_1 C25_1 116.3(18) . . ?
H26A_1 C26_1 H26B_1 107.4 . . ?
C25_1 C26_1 H26A_1 108.2 . . ?
C25_1 C26_1 H26B_1 108.2 . . ?
C26_1 C25_1 H25A_1 109.0 . . ?
C26_1 C25_1 H25B_1 109.0 . . ?
C26_1 C25_1 P1_1 113.1(15) . . ?
H25A_1 C25_1 H25B_1 107.8 . . ?
P1_1 C25_1 H25A_1 109.0 . . ?
P1_1 C25_1 H25B_1 109.0 . . ?
C25_1 P1_1 Ag2 114.0(7) . . ?
C16_1 P1_1 Ag2 114.1(6) . . ?
C16_1 P1_1 C25_1 105.0(8) . . ?
C22_1 P1_1 Ag2 116.1(6) . . ?
C22_1 P1_1 C25_1 101.9(9) . . ?
C22_1 P1_1 C16_1 104.2(7) . . ?
C2_1 C1_1 H1_1 120.0 . . ?
C2_1 C1_1 C6_1 120.0 . . ?
C6_1 C1_1 H1_1 120.0 . . ?
C1_1 C2_1 H2_1 120.0 . . ?
C3_1 C2_1 C1_1 120.0 . . ?
C3_1 C2_1 H2_1 120.0 . . ?
C2_1 C3_1 H3_1 120.0 . . ?
C2_1 C3_1 C4_1 120.0 . . ?
C4_1 C3_1 H3_1 120.0 . . ?
C3_1 C4_1 P2_1 121.6(9) . . ?
C5_1 C4_1 P2_1 118.3(9) . . ?
C5_1 C4_1 C3_1 120.0 . . ?
C4_1 C5_1 H5_1 120.0 . . ?
C4_1 C5_1 C6_1 120.0 . . ?
C6_1 C5_1 H5_1 120.0 . . ?
C1_1 C6_1 H6_1 120.0 . . ?
C5_1 C6_1 C1_1 120.0 . . ?
C5_1 C6_1 H6_1 120.0 . . ?
C8_1 C7_1 H7_1 120.0 . . ?
C8_1 C7_1 C12_1 120.0 . . ?
C12_1 C7_1 H7_1 120.0 . . ?
C7_1 C8_1 H8_1 120.0 . . ?
C9_1 C8_1 C7_1 120.0 . . ?
C9_1 C8_1 H8_1 120.0 . . ?
C8_1 C9_1 H9_1 120.0 . . ?
C8_1 C9_1 C10_1 120.0 . . ?
C10_1 C9_1 H9_1 120.0 . . ?
C9_1 C10_1 P2_1 116.5(9) . . ?
C9_1 C10_1 C11_1 120.0 . . ?
C11_1 C10_1 P2_1 123.2(9) . . ?
C10_1 C11_1 H11_1 120.0 . . ?
C12_1 C11_1 C10_1 120.0 . . ?
C12_1 C11_1 H11_1 120.0 . . ?
C7_1 C12_1 H12_1 120.0 . . ?
C11_1 C12_1 C7_1 120.0 . . ?
C11_1 C12_1 H12_1 120.0 . . ?
C14_1 C13_1 H13_1 120.0 . . ?
C14_1 C13_1 C18_1 120.0 . . ?
C18_1 C13_1 H13_1 120.0 . . ?
C13_1 C14_1 H14_1 120.0 . . ?
C13_1 C14_1 C15_1 120.0 . . ?
C15_1 C14_1 H14_1 120.0 . . ?
C14_1 C15_1 H15_1 120.0 . . ?
C14_1 C15_1 C16_1 120.0 . . ?
C16_1 C15_1 H15_1 120.0 . . ?
C15_1 C16_1 P1_1 122.3(8) . . ?
C17_1 C16_1 P1_1 117.7(8) . . ?
C17_1 C16_1 C15_1 120.0 . . ?
C16_1 C17_1 H17_1 120.0 . . ?
C16_1 C17_1 C18_1 120.0 . . ?
C18_1 C17_1 H17_1 120.0 . . ?
C13_1 C18_1 H18_1 120.0 . . ?
C17_1 C18_1 C13_1 120.0 . . ?
C17_1 C18_1 H18_1 120.0 . . ?
C20_1 C19_1 H19_1 120.0 . . ?
C20_1 C19_1 C24_1 120.0 . . ?
C24_1 C19_1 H19_1 120.0 . . ?
C19_1 C20_1 H20_1 120.0 . . ?
C19_1 C20_1 C21_1 120.0 . . ?
C21_1 C20_1 H20_1 120.0 . . ?
C20_1 C21_1 H21_1 120.0 . . ?
C22_1 C21_1 C20_1 120.0 . . ?
C22_1 C21_1 H21_1 120.0 . . ?
C21_1 C22_1 P1_1 119.4(9) . . ?
C21_1 C22_1 C23_1 120.0 . . ?
C23_1 C22_1 P1_1 120.6(9) . . ?
C22_1 C23_1 H23_1 120.0 . . ?
C22_1 C23_1 C24_1 120.0 . . ?
C24_1 C23_1 H23_1 120.0 . . ?
C19_1 C24_1 H24_1 120.0 . . ?
C23_1 C24_1 C19_1 120.0 . . ?
C23_1 C24_1 H24_1 120.0 . . ?
C27_2 P2_2 Ag1 111.9(7) . . ?
C4_2 P2_2 Ag1 112.7(5) . . ?
C4_2 P2_2 C27_2 106.8(9) . . ?
C10_2 P2_2 Ag1 113.9(5) . . ?
C10_2 P2_2 C27_2 105.8(9) . . ?
C10_2 P2_2 C4_2 105.1(7) . . ?
P2_2 C27_2 H27A_2 109.0 . . ?
P2_2 C27_2 H27B_2 109.0 . . ?
H27A_2 C27_2 H27B_2 107.8 . . ?
C26_2 C27_2 P2_2 113.1(15) . . ?
C26_2 C27_2 H27A_2 109.0 . . ?
C26_2 C27_2 H27B_2 109.0 . . ?
C27_2 C26_2 H26A_2 109.0 . . ?
C27_2 C26_2 H26B_2 109.0 . . ?
C27_2 C26_2 C25_2 112.7(19) . . ?
H26A_2 C26_2 H26B_2 107.8 . . ?
C25_2 C26_2 H26A_2 109.0 . . ?
C25_2 C26_2 H26B_2 109.0 . . ?
C26_2 C25_2 H25A_2 109.6 . . ?
C26_2 C25_2 H25B_2 109.6 . . ?
C26_2 C25_2 P1_2 110.4(16) . . ?
H25A_2 C25_2 H25B_2 108.1 . . ?
P1_2 C25_2 H25A_2 109.6 . . ?
P1_2 C25_2 H25B_2 109.6 . . ?
C3_2 C2_2 H2_2 120.0 . . ?
C3_2 C2_2 C1_2 120.0 . . ?
C1_2 C2_2 H2_2 120.0 . . ?
C2_2 C3_2 H3_2 120.0 . . ?
C2_2 C3_2 C4_2 120.0 . . ?
C4_2 C3_2 H3_2 120.0 . . ?
C3_2 C4_2 P2_2 117.0(8) . . ?
C5_2 C4_2 P2_2 123.0(8) . . ?
C5_2 C4_2 C3_2 120.0 . . ?
C4_2 C5_2 H5_2 120.0 . . ?
C4_2 C5_2 C6_2 120.0 . . ?
C6_2 C5_2 H5_2 120.0 . . ?
C5_2 C6_2 H6_2 120.0 . . ?
C5_2 C6_2 C1_2 120.0 . . ?
C1_2 C6_2 H6_2 120.0 . . ?
C2_2 C1_2 H1_2 120.0 . . ?
C6_2 C1_2 C2_2 120.0 . . ?
C6_2 C1_2 H1_2 120.0 . . ?
C25_2 P1_2 Ag2 111.4(8) . . ?
C16_2 P1_2 Ag2 114.0(6) . . ?
C16_2 P1_2 C25_2 105.3(10) . . ?
C16_2 P1_2 C22_2 107.3(8) . . ?
C22_2 P1_2 Ag2 114.4(6) . . ?
C22_2 P1_2 C25_2 103.5(9) . . ?
C8_2 C7_2 H7_2 120.0 . . ?
C8_2 C7_2 C12_2 120.0 . . ?
C12_2 C7_2 H7_2 120.0 . . ?
C7_2 C8_2 H8_2 120.0 . . ?
C9_2 C8_2 C7_2 120.0 . . ?
C9_2 C8_2 H8_2 120.0 . . ?
C8_2 C9_2 H9_2 120.0 . . ?
C8_2 C9_2 C10_2 120.0 . . ?
C10_2 C9_2 H9_2 120.0 . . ?
C9_2 C10_2 P2_2 122.6(9) . . ?
C9_2 C10_2 C11_2 120.0 . . ?
C11_2 C10_2 P2_2 117.4(9) . . ?
C10_2 C11_2 H11_2 120.0 . . ?
C12_2 C11_2 C10_2 120.0 . . ?
C12_2 C11_2 H11_2 120.0 . . ?
C7_2 C12_2 H12_2 120.0 . . ?
C11_2 C12_2 C7_2 120.0 . . ?
C11_2 C12_2 H12_2 120.0 . . ?
C17_2 C18_2 H18_2 120.0 . . ?
C17_2 C18_2 C13_2 120.0 . . ?
C13_2 C18_2 H18_2 120.0 . . ?
C18_2 C17_2 H17_2 120.0 . . ?
C18_2 C17_2 C16_2 120.0 . . ?
C16_2 C17_2 H17_2 120.0 . . ?
C17_2 C16_2 P1_2 118.8(11) . . ?
C15_2 C16_2 P1_2 121.2(11) . . ?
C15_2 C16_2 C17_2 120.0 . . ?
C16_2 C15_2 H15_2 120.0 . . ?
C16_2 C15_2 C14_2 120.0 . . ?
C14_2 C15_2 H15_2 120.0 . . ?
C15_2 C14_2 H14_2 120.0 . . ?
C15_2 C14_2 C13_2 120.0 . . ?
C13_2 C14_2 H14_2 120.0 . . ?
C18_2 C13_2 H13_2 120.0 . . ?
C14_2 C13_2 C18_2 120.0 . . ?
C14_2 C13_2 H13_2 120.0 . . ?
C20_2 C19_2 H19_2 120.0 . . ?
C20_2 C19_2 C24_2 120.0 . . ?
C24_2 C19_2 H19_2 120.0 . . ?
C19_2 C20_2 H20_2 120.0 . . ?
C21_2 C20_2 C19_2 120.0 . . ?
C21_2 C20_2 H20_2 120.0 . . ?
C20_2 C21_2 H21_2 120.0 . . ?
C22_2 C21_2 C20_2 120.0 . . ?
C22_2 C21_2 H21_2 120.0 . . ?
C21_2 C22_2 P1_2 119.1(10) . . ?
C21_2 C22_2 C23_2 120.0 . . ?
C23_2 C22_2 P1_2 120.9(10) . . ?
C22_2 C23_2 H23_2 120.0 . . ?
C24_2 C23_2 C22_2 120.0 . . ?
C24_2 C23_2 H23_2 120.0 . . ?
C19_2 C24_2 H24_2 120.0 . . ?
C23_2 C24_2 C19_2 120.0 . . ?
C23_2 C24_2 H24_2 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P2_1 C27_1 C26_1 47.3(19) . . . . ?
Ag1 P2_1 C4_1 C3_1 -151.8(7) . . . . ?
Ag1 P2_1 C4_1 C5_1 33.0(10) . . . . ?
Ag1 P2_1 C10_1 C9_1 50.6(9) . . . . ?
Ag1 P2_1 C10_1 C11_1 -123.6(9) . . . . ?
Ag1 P2_2 C27_2 C26_2 -56.5(18) . . . . ?
Ag1 P2_2 C4_2 C3_2 -37.0(9) . . . . ?
Ag1 P2_2 C4_2 C5_2 141.2(7) . . . . ?
Ag1 P2_2 C10_2 C9_2 167.6(8) . . . . ?
Ag1 P2_2 C10_2 C11_2 -14.5(10) . . . . ?
Ag2 P1_1 C16_1 C15_1 -104.9(9) . . . . ?
Ag2 P1_1 C16_1 C17_1 76.3(9) . . . . ?
Ag2 P1_1 C22_1 C21_1 -159.3(7) . . . . ?
Ag2 P1_1 C22_1 C23_1 22.8(10) . . . . ?
Ag2 P1_2 C16_2 C17_2 20.9(11) . . . . ?
Ag2 P1_2 C16_2 C15_2 -157.5(8) . . . . ?
Ag2 P1_2 C22_2 C21_2 62.6(11) . . . . ?
Ag2 P1_2 C22_2 C23_2 -114.7(9) . . . . ?
O4 W2 O5 W3 153.7(14) . . . . ?
O4 W2 O16 W6 -155.5(14) . . . 3_666 ?
O10 W4 O11 W5 110.4(14) . . . . ?
O10 W4 O7 W3 -28(2) . . . 3_666 ?
O10 W1 O2 W2 -103.8(14) . . . . ?
O10 W1 O18 W6 50.7(15) . . . . ?
O9 W4 O10 W1 157.4(12) . . . . ?
O9 W4 O11 W5 -148.7(13) . . . . ?
O9 W4 O7 W3 152.6(13) . . . 3_666 ?
O5 W2 O16 W6 102.0(15) . . . 3_666 ?
O8 W4 O10 W1 56.8(12) . . . . ?
O8 W4 O11 W5 39(2) . . . . ?
O8 W4 O7 W3 -106.5(14) . . . 3_666 ?
O1 W1 O2 W2 154.7(14) . . . . ?
O1 W1 O18 W6 151.8(15) . . . . ?
O2 W2 O5 W3 53.5(15) . . . . ?
O2 W2 O16 W6 18(3) . . . 3_666 ?
O2 W1 O18 W6 -31(3) . . . . ?
O11 W4 O10 W1 -100.7(12) . . . . ?
O11 W4 O7 W3 49.8(14) . . . 3_666 ?
O11 W5 O13 W2 101.3(16) . . . . ?
O11 W5 O15 W6 -25(3) . . . 3_666 ?
O12 W5 O13 W2 -156.1(16) . . . . ?
O12 W5 O15 W6 153.1(15) . . . 3_666 ?
O7 W4 O10 W1 -22(2) . . . . ?
O7 W4 O11 W5 -47.0(14) . . . . ?
O14 W5 O13 W2 23(3) . . . . ?
O14 W5 O15 W6 -103.0(16) . . . 3_666 ?
O18 W1 O2 W2 -23(3) . . . . ?
O18 W6 O8 W4 53.7(14) . . . . ?
O16 W2 O5 W3 -106.6(16) . . . . ?
O16 W6 O8 W4 -102.3(14) 3_666 . . . ?
O22 W6 O8 W4 -37.7(14) . . . . ?
O22 P5 O19 W4 59.2(13) . . . . ?
O22 P5 O19 W5 -179.8(10) . . . . ?
O22 P5 O21 W2 179.8(10) . . . . ?
O22 P5 O21 W1 -62.3(14) . . . . ?
O22 P5 O21 W3 64.2(12) . . . . ?
O13 W2 O5 W3 -26(3) . . . . ?
O13 W2 O16 W6 -55.9(15) . . . 3_666 ?
O13 W5 O15 W6 52.9(16) . . . 3_666 ?
O17 W6 O8 W4 157.9(14) . . . . ?
O15 W5 O13 W2 -54.7(17) . . . . ?
O15 W6 O8 W4 -24(3) 3_666 . . . ?
O19 W4 O10 W1 -37.2(12) . . . . ?
O19 W4 O11 W5 13.2(12) . . . . ?
O19 W4 O7 W3 -11.0(12) . . . 3_666 ?
O19 W5 O13 W2 40.5(16) . . . . ?
O19 W5 O15 W6 -40.8(16) . . . 3_666 ?
O19 P5 O22 W6 -59.0(13) . . . . ?
O19 P5 O21 W2 -64.5(12) . . . . ?
O19 P5 O21 W1 53.4(13) . . . . ?
O19 P5 O21 W3 179.8(9) . . . . ?
O20 P5 O22 W6 177.9(10) . . . . ?
O20 P5 O19 W4 179.3(11) . . . . ?
O20 P5 O19 W5 -59.6(14) . . . . ?
O20 P5 O21 W2 61.5(13) . . . . ?
O20 P5 O21 W1 179.5(10) . . . . ?
O20 P5 O21 W3 -54.1(13) . . . . ?
O21 W2 O5 W3 -8.4(13) . . . . ?
O21 W2 O16 W6 37.9(15) . . . 3_666 ?
O21 W1 O2 W2 -8.7(12) . . . . ?
O21 W1 O18 W6 -43.6(15) . . . . ?
O21 P5 O22 W6 58.3(13) . . . . ?
O21 P5 O19 W4 -56.1(13) . . . . ?
O21 P5 O19 W5 65.0(12) . . . . ?
O3 W1 O2 W2 53.0(14) . . . . ?
O3 W1 O18 W6 -107.2(15) . . . . ?
P2_1 C27_1 C26_1 C25_1 -151.4(17) . . . . ?
P2_1 C4_1 C5_1 C6_1 175.3(11) . . . . ?
P2_1 C10_1 C11_1 C12_1 174.0(13) . . . . ?
C27_1 P2_1 C4_1 C3_1 81.8(11) . . . . ?
C27_1 P2_1 C4_1 C5_1 -93.4(11) . . . . ?
C27_1 P2_1 C10_1 C9_1 172.4(10) . . . . ?
C27_1 P2_1 C10_1 C11_1 -1.9(13) . . . . ?
C27_1 C26_1 C25_1 P1_1 169.7(17) . . . . ?
C26_1 C25_1 P1_1 Ag2 -57.9(18) . . . . ?
C26_1 C25_1 P1_1 C16_1 176.6(16) . . . . ?
C26_1 C25_1 P1_1 C22_1 68.1(17) . . . . ?
C25_1 P1_1 C16_1 C15_1 20.7(13) . . . . ?
C25_1 P1_1 C16_1 C17_1 -158.2(10) . . . . ?
C25_1 P1_1 C22_1 C21_1 76.1(11) . . . . ?
C25_1 P1_1 C22_1 C23_1 -101.7(10) . . . . ?
P1_1 C16_1 C17_1 C18_1 178.9(12) . . . . ?
P1_1 C22_1 C23_1 C24_1 177.8(12) . . . . ?
C1_1 C2_1 C3_1 C4_1 0.0 . . . . ?
C2_1 C1_1 C6_1 C5_1 0.0 . . . . ?
C2_1 C3_1 C4_1 P2_1 -175.1(12) . . . . ?
C2_1 C3_1 C4_1 C5_1 0.0 . . . . ?
C3_1 C4_1 C5_1 C6_1 0.0 . . . . ?
C4_1 P2_1 C27_1 C26_1 177.4(16) . . . . ?
C4_1 P2_1 C10_1 C9_1 -77.0(10) . . . . ?
C4_1 P2_1 C10_1 C11_1 108.8(10) . . . . ?
C4_1 C5_1 C6_1 C1_1 0.0 . . . . ?
C6_1 C1_1 C2_1 C3_1 0.0 . . . . ?
C7_1 C8_1 C9_1 C10_1 0.0 . . . . ?
C8_1 C7_1 C12_1 C11_1 0.0 . . . . ?
C8_1 C9_1 C10_1 P2_1 -174.4(12) . . . . ?
C8_1 C9_1 C10_1 C11_1 0.0 . . . . ?
C9_1 C10_1 C11_1 C12_1 0.0 . . . . ?
C10_1 P2_1 C27_1 C26_1 -70.4(18) . . . . ?
C10_1 P2_1 C4_1 C3_1 -32.0(11) . . . . ?
C10_1 P2_1 C4_1 C5_1 152.7(9) . . . . ?
C10_1 C11_1 C12_1 C7_1 0.0 . . . . ?
C12_1 C7_1 C8_1 C9_1 0.0 . . . . ?
C13_1 C14_1 C15_1 C16_1 0.0 . . . . ?
C14_1 C13_1 C18_1 C17_1 0.0 . . . . ?
C14_1 C15_1 C16_1 P1_1 -178.8(12) . . . . ?
C14_1 C15_1 C16_1 C17_1 0.0 . . . . ?
C15_1 C16_1 C17_1 C18_1 0.0 . . . . ?
C16_1 P1_1 C22_1 C21_1 -33.0(10) . . . . ?
C16_1 P1_1 C22_1 C23_1 149.2(9) . . . . ?
C16_1 C17_1 C18_1 C13_1 0.0 . . . . ?
C18_1 C13_1 C14_1 C15_1 0.0 . . . . ?
C19_1 C20_1 C21_1 C22_1 0.0 . . . . ?
C20_1 C19_1 C24_1 C23_1 0.0 . . . . ?
C20_1 C21_1 C22_1 P1_1 -177.9(11) . . . . ?
C20_1 C21_1 C22_1 C23_1 0.0 . . . . ?
C21_1 C22_1 C23_1 C24_1 0.0 . . . . ?
C22_1 P1_1 C16_1 C15_1 127.5(10) . . . . ?
C22_1 P1_1 C16_1 C17_1 -51.4(10) . . . . ?
C22_1 C23_1 C24_1 C19_1 0.0 . . . . ?
C24_1 C19_1 C20_1 C21_1 0.0 . . . . ?
P2_2 C27_2 C26_2 C25_2 165.3(17) . . . . ?
P2_2 C4_2 C5_2 C6_2 -178.2(11) . . . . ?
P2_2 C10_2 C11_2 C12_2 -177.9(13) . . . . ?
C27_2 P2_2 C4_2 C3_2 -160.3(10) . . . . ?
C27_2 P2_2 C4_2 C5_2 17.9(12) . . . . ?
C27_2 P2_2 C10_2 C9_2 -69.1(13) . . . . ?
C27_2 P2_2 C10_2 C11_2 108.8(11) . . . . ?
C27_2 C26_2 C25_2 P1_2 -164.9(16) . . . . ?
C26_2 C25_2 P1_2 Ag2 59.4(18) . . . . ?
C26_2 C25_2 P1_2 C16_2 -64.6(18) . . . . ?
C26_2 C25_2 P1_2 C22_2 -177.1(16) . . . . ?
C25_2 P1_2 C16_2 C17_2 143.2(11) . . . . ?
C25_2 P1_2 C16_2 C15_2 -35.1(13) . . . . ?
C25_2 P1_2 C22_2 C21_2 -58.8(13) . . . . ?
C25_2 P1_2 C22_2 C23_2 123.9(12) . . . . ?
C2_2 C3_2 C4_2 P2_2 178.3(11) . . . . ?
C2_2 C3_2 C4_2 C5_2 0.0 . . . . ?
C3_2 C2_2 C1_2 C6_2 0.0 . . . . ?
C3_2 C4_2 C5_2 C6_2 0.0 . . . . ?
C4_2 P2_2 C27_2 C26_2 67.3(18) . . . . ?
C4_2 P2_2 C10_2 C9_2 43.8(12) . . . . ?
C4_2 P2_2 C10_2 C11_2 -138.4(9) . . . . ?
C4_2 C5_2 C6_2 C1_2 0.0 . . . . ?
C5_2 C6_2 C1_2 C2_2 0.0 . . . . ?
C1_2 C2_2 C3_2 C4_2 0.0 . . . . ?
P1_2 C16_2 C15_2 C14_2 178.4(14) . . . . ?
P1_2 C22_2 C23_2 C24_2 177.3(14) . . . . ?
C7_2 C8_2 C9_2 C10_2 0.0 . . . . ?
C8_2 C7_2 C12_2 C11_2 0.0 . . . . ?
C8_2 C9_2 C10_2 P2_2 177.8(13) . . . . ?
C8_2 C9_2 C10_2 C11_2 0.0 . . . . ?
C9_2 C10_2 C11_2 C12_2 0.0 . . . . ?
C10_2 P2_2 C27_2 C26_2 179.0(15) . . . . ?
C10_2 P2_2 C4_2 C3_2 87.6(9) . . . . ?
C10_2 P2_2 C4_2 C5_2 -94.2(10) . . . . ?
C10_2 C11_2 C12_2 C7_2 0.0 . . . . ?
C12_2 C7_2 C8_2 C9_2 0.0 . . . . ?
C18_2 C17_2 C16_2 P1_2 -178.4(13) . . . . ?
C18_2 C17_2 C16_2 C15_2 0.0 . . . . ?
C17_2 C18_2 C13_2 C14_2 0.0 . . . . ?
C17_2 C16_2 C15_2 C14_2 0.0 . . . . ?
C16_2 P1_2 C22_2 C21_2 -169.9(10) . . . . ?
C16_2 P1_2 C22_2 C23_2 12.8(13) . . . . ?
C16_2 C15_2 C14_2 C13_2 0.0 . . . . ?
C15_2 C14_2 C13_2 C18_2 0.0 . . . . ?
C13_2 C18_2 C17_2 C16_2 0.0 . . . . ?
C19_2 C20_2 C21_2 C22_2 0.0 . . . . ?
C20_2 C19_2 C24_2 C23_2 0.0 . . . . ?
C20_2 C21_2 C22_2 P1_2 -177.3(14) . . . . ?
C20_2 C21_2 C22_2 C23_2 0.0 . . . . ?
C21_2 C22_2 C23_2 C24_2 0.0 . . . . ?
C22_2 P1_2 C16_2 C17_2 -106.9(11) . . . . ?
C22_2 P1_2 C16_2 C15_2 74.7(12) . . . . ?
C22_2 C23_2 C24_2 C19_2 0.0 . . . . ?
C24_2 C19_2 C20_2 C21_2 0.0 . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.159 0.482 0.839 245.3 38.9 ?
2 -0.159 0.518 0.161 245.3 29.1 ?
3 0.175 0.333 0.340 7.2 1.2 ?
4 0.341 -0.018 0.661 245.3 26.6 ?
5 0.325 0.833 0.160 7.2 1.2 ?
6 0.659 0.018 0.339 245.3 41.3 ?
7 0.675 0.167 0.840 7.2 1.2 ?
8 0.825 0.667 0.660 7.2 1.2 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1021_a
_database_code_depnum_ccdc_archive 'CCDC 2326045'
loop_
_audit_author_name
_audit_author_address
jiang
;zhejiang normal university
China
;
_audit_update_record             
;
2024-01-17 deposited with the CCDC.	2024-02-26 downloaded from the CCDC.
;
_audit_creation_date             2023-10-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '3(C54 H52 Ag2 P4), 2(Mo12 O40 P)'
_chemical_formula_sum            'C162 H156 Ag6 Mo24 O80 P14'
_chemical_formula_weight         6766.22
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -0.0483 2.7339 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.0626(4)
_cell_length_b                   14.8889(3)
_cell_length_c                   27.6698(7)
_cell_angle_alpha                100.6530(10)
_cell_angle_beta                 93.370(2)
_cell_angle_gamma                109.7070(10)
_cell_volume                     5314.0(2)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9433
_cell_measurement_temperature    297.00
_cell_measurement_theta_max      76.00
_cell_measurement_theta_min      3.23
_shelx_estimated_absorpt_T_max   0.340
_shelx_estimated_absorpt_T_min   0.183
_exptl_absorpt_coefficient_mu    17.179
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5034
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1151 before and 0.0804 after correction.
The Ratio of minimum to maximum transmission is 0.6753.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    2.114
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             3268
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0792
_diffrn_reflns_av_unetI/netI     0.0707
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            77753
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         80.156
_diffrn_reflns_theta_min         3.230
_diffrn_ambient_temperature      297.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'BRUKER D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14594
_reflns_number_total             22600
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.393
_refine_diff_density_min         -1.859
_refine_diff_density_rms         0.133
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1315
_refine_ls_number_reflns         22600
_refine_ls_number_restraints     468
_refine_ls_R_factor_all          0.1021
_refine_ls_R_factor_gt           0.0666
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0533P)²+26.1338P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1547
_refine_ls_wR_factor_ref         0.1778
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Uiso/Uaniso restraints and constraints
: within 2A with sigma of 0.02 and sigma for terminal atoms of 3.8 within 2A
O5_3 \\sim O21_3 \\sim O16_3 \\sim O20_3 \\sim O22_3 \\sim O6_3 \\sim O18_3
\\sim O8_3 \\sim O9_3 \\sim O17_3 \\sim O19_3 \\sim O14_3 \\sim O10_3 \\sim
O12_3 \\sim O7_3 \\sim O13_3 \\sim O11_3 \\sim O15_3: within 2A with sigma of
0.001 and sigma for terminal atoms of 0.002 within 2A
3. Others
 Fixed Sof: O1(0.5) O2(0.5) O3(0.5) O4(0.5) O1(0.5) O2(0.5) O3(0.5) O4(0.5)
4.a Secondary CH2 refined with riding coordinates:
 C25(H25A,H25B), C26(H26A,H26B), C27(H27A,H27B), C52(H52A,H52B), C53(H53A,
 H53B), C54(H54A,H54B), C25(H25A,H25B), C26(H26A,H26B), C27(H27A,H27B)
4.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C18(H18), C19(H19), C20(H20),
  C21(H21), C23(H23), C24(H24), C28(H28), C29(H29), C30(H30), C32(H32),
 C33(H33), C34(H34), C35(H35), C36(H36), C38(H38), C39(H39), C40(H40), C41(H41),
  C42(H42), C44(H44), C45(H45), C46(H46), C47(H47), C48(H48), C50(H50),
 C51(H51), C1(H1), C2(H2), C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9),
 C11(H11), C12(H12), C13(H13), C14(H14), C15(H15), C17(H17), C18(H18), C19(H19),
  C20(H20), C21(H21), C23(H23), C24(H24)
4.c Fitted hexagon refined as free rotating group:
 C13(C14,C15,C16,C17,C18)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1_1 Ag 1.06254(7) 0.82502(8) 0.79159(3) 0.0924(3) Uani 1 1 d . . . . .
Ag2_1 Ag 0.73944(6) 0.67171(5) 0.87314(3) 0.06686(19) Uani 1 1 d . . . . .
P1_1 P 0.9847(2) 0.7009(2) 0.71897(10) 0.0720(7) Uani 1 1 d . . . . .
P2_1 P 0.6638(3) 0.5336(2) 0.80343(11) 0.0769(8) Uani 1 1 d . . . . .
P3_1 P 1.1562(2) 0.9493(2) 0.86222(10) 0.0676(7) Uani 1 1 d . . . . .
P4_1 P 0.77310(19) 0.84107(18) 0.90819(9) 0.0568(5) Uani 1 1 d . . . . .
C1_1 C 1.026(2) 0.4158(18) 0.7243(9) 0.157(6) Uani 1 1 d . U . . .
H1_1 H 1.032148 0.356088 0.725848 0.188 Uiso 1 1 calc R U . . .
C2_1 C 1.0788(18) 0.4923(16) 0.7605(7) 0.138(5) Uani 1 1 d . U . . .
H2_1 H 1.122236 0.486845 0.785564 0.166 Uiso 1 1 calc R U . . .
C3_1 C 1.0659(14) 0.5831(13) 0.7594(5) 0.113(4) Uani 1 1 d . U . . .
H3_1 H 1.099917 0.638517 0.784198 0.135 Uiso 1 1 calc R U . . .
C4_1 C 1.0021(14) 0.5865(11) 0.7208(5) 0.101(4) Uani 1 1 d . U . . .
C5_1 C 0.9497(17) 0.5057(13) 0.6832(6) 0.130(5) Uani 1 1 d . U . . .
H5_1 H 0.906642 0.509554 0.657436 0.156 Uiso 1 1 calc R U . . .
C6_1 C 0.964(2) 0.4181(18) 0.6855(9) 0.164(6) Uani 1 1 d . U . . .
H6_1 H 0.932159 0.362186 0.660799 0.197 Uiso 1 1 calc R U . . .
C7_1 C 1.0979(12) 0.7931(12) 0.5785(6) 0.111(4) Uani 1 1 d . U . . .
H7_1 H 1.116640 0.809497 0.548735 0.133 Uiso 1 1 calc R U . . .
C8_1 C 1.1327(10) 0.7308(12) 0.5968(6) 0.098(4) Uani 1 1 d . U . . .
H8_1 H 1.180211 0.708728 0.581434 0.117 Uiso 1 1 calc R U . . .
C9_1 C 1.0970(9) 0.6996(10) 0.6387(5) 0.083(3) Uani 1 1 d . U . . .
H9_1 H 1.117193 0.653035 0.650108 0.100 Uiso 1 1 calc R U . . .
C10_1 C 1.0327(8) 0.7365(8) 0.6634(4) 0.071(3) Uani 1 1 d . U . . .
C11_1 C 1.0042(12) 0.8044(10) 0.6456(6) 0.099(4) Uani 1 1 d . U . . .
H11_1 H 0.962300 0.832322 0.662546 0.119 Uiso 1 1 calc R U . . .
C12_1 C 1.0364(14) 0.8320(11) 0.6029(7) 0.116(4) Uani 1 1 d . U . . .
H12_1 H 1.015621 0.877649 0.590949 0.139 Uiso 1 1 calc R U . . .
C13_1 C 0.5903(11) 0.2141(6) 0.8130(5) 0.155(6) Uani 1 1 d G U . . .
H13_1 H 0.574171 0.149088 0.815088 0.186 Uiso 1 1 calc R U . . .
C14_1 C 0.6673(10) 0.2561(8) 0.7860(5) 0.149(6) Uani 1 1 d G U . . .
H14_1 H 0.702631 0.219195 0.770020 0.179 Uiso 1 1 calc R U . . .
C15_1 C 0.6913(8) 0.3532(8) 0.7829(4) 0.132(5) Uani 1 1 d G U . . .
H15_1 H 0.742835 0.381290 0.764830 0.158 Uiso 1 1 calc R U . . .
C16_1 C 0.6385(8) 0.4083(5) 0.8068(4) 0.094(4) Uani 1 1 d G U . . .
C17_1 C 0.5615(9) 0.3663(8) 0.8338(4) 0.137(5) Uani 1 1 d G U . . .
H17_1 H 0.526120 0.403175 0.849775 0.164 Uiso 1 1 calc R U . . .
C18_1 C 0.5374(10) 0.2692(8) 0.8369(5) 0.158(6) Uani 1 1 d G U . . .
H18_1 H 0.485914 0.241079 0.854966 0.189 Uiso 1 1 calc R U . . .
C19_1 C 0.3616(14) 0.5413(14) 0.7367(6) 0.119(5) Uani 1 1 d . U . . .
H19_1 H 0.301262 0.544022 0.722626 0.142 Uiso 1 1 calc R U . . .
C20_1 C 0.4071(14) 0.4859(14) 0.7101(6) 0.117(5) Uani 1 1 d . U . . .
H20_1 H 0.378351 0.451438 0.678039 0.140 Uiso 1 1 calc R U . . .
C21_1 C 0.4975(12) 0.4804(11) 0.7308(5) 0.098(4) Uani 1 1 d . U . . .
H21_1 H 0.527491 0.440223 0.712965 0.118 Uiso 1 1 calc R U . . .
C22_1 C 0.5420(11) 0.5343(10) 0.7774(4) 0.088(3) Uani 1 1 d . U . . .
C23_1 C 0.4942(12) 0.5898(12) 0.8043(6) 0.106(4) Uani 1 1 d . U . . .
H23_1 H 0.523277 0.625032 0.836219 0.127 Uiso 1 1 calc R U . . .
C24_1 C 0.4022(14) 0.5938(14) 0.7841(7) 0.123(5) Uani 1 1 d . U . . .
H24_1 H 0.369571 0.631017 0.802286 0.148 Uiso 1 1 calc R U . . .
C25_1 C 0.7492(12) 0.5515(10) 0.7560(5) 0.096(4) Uani 1 1 d . U . . .
H25A_1 H 0.808564 0.536691 0.765958 0.115 Uiso 1 1 calc R U . . .
H25B_1 H 0.714627 0.506033 0.725135 0.115 Uiso 1 1 calc R U . . .
C26_1 C 0.7825(10) 0.6510(10) 0.7477(5) 0.088(3) Uani 1 1 d . U . . .
H26A_1 H 0.821691 0.695132 0.778136 0.105 Uiso 1 1 calc R U . . .
H26B_1 H 0.722434 0.667347 0.741376 0.105 Uiso 1 1 calc R U . . .
C27_1 C 0.8466(9) 0.6704(10) 0.7053(4) 0.082(3) Uani 1 1 d . U . . .
H27A_1 H 0.835637 0.723587 0.693079 0.098 Uiso 1 1 calc R U . . .
H27B_1 H 0.820613 0.612777 0.678465 0.098 Uiso 1 1 calc R U . . .
C28_1 C 1.4537(10) 0.8919(11) 0.8833(5) 0.096(4) Uani 1 1 d . U . . .
H28_1 H 1.513297 0.878160 0.886469 0.115 Uiso 1 1 calc R U . . .
C29_1 C 1.4552(10) 0.9747(12) 0.8693(5) 0.096(4) Uani 1 1 d . U . . .
H29_1 H 1.515766 1.017107 0.862211 0.116 Uiso 1 1 calc R U . . .
C30_1 C 1.3680(10) 0.9969(10) 0.8654(5) 0.087(3) Uani 1 1 d . U . . .
H30_1 H 1.370300 1.054790 0.856438 0.105 Uiso 1 1 calc R U . . .
C31_1 C 1.2775(8) 0.9337(8) 0.8747(4) 0.069(2) Uani 1 1 d . U . . .
C32_1 C 1.2760(9) 0.8497(9) 0.8890(6) 0.089(3) Uani 1 1 d . U . . .
H32_1 H 1.215604 0.807305 0.896197 0.107 Uiso 1 1 calc R U . . .
C33_1 C 1.3637(10) 0.8281(10) 0.8928(6) 0.094(4) Uani 1 1 d . U . . .
H33_1 H 1.362001 0.770497 0.901786 0.113 Uiso 1 1 calc R U . . .
C34_1 C 1.221(2) 1.2697(17) 0.8605(10) 0.163(6) Uani 1 1 d . U . . .
H34_1 H 1.238861 1.335609 0.860180 0.196 Uiso 1 1 calc R U . . .
C35_1 C 1.2590(17) 1.2462(14) 0.8988(8) 0.134(5) Uani 1 1 d . U . . .
H35_1 H 1.298329 1.294784 0.925638 0.161 Uiso 1 1 calc R U . . .
C36_1 C 1.2404(14) 1.1503(11) 0.8991(6) 0.107(4) Uani 1 1 d . U . . .
H36_1 H 1.265275 1.133975 0.926874 0.128 Uiso 1 1 calc R U . . .
C37_1 C 1.1850(12) 1.0768(12) 0.8589(5) 0.096(4) Uani 1 1 d . U . . .
C38_1 C 1.1427(19) 1.1009(17) 0.8200(8) 0.152(6) Uani 1 1 d . U . . .
H38_1 H 1.104137 1.052853 0.792782 0.182 Uiso 1 1 calc R U . . .
C39_1 C 1.159(2) 1.2036(19) 0.8219(10) 0.174(7) Uani 1 1 d . U . . .
H39_1 H 1.127652 1.222562 0.797239 0.209 Uiso 1 1 calc R U . . .
C40_1 C 0.7034(13) 0.9952(10) 0.7898(5) 0.098(4) Uani 1 1 d . U . . .
H40_1 H 0.689323 1.026232 0.765511 0.117 Uiso 1 1 calc R U . . .
C41_1 C 0.6649(12) 0.8967(10) 0.7808(5) 0.093(3) Uani 1 1 d . U . . .
H41_1 H 0.624123 0.860150 0.751220 0.112 Uiso 1 1 calc R U . . .
C42_1 C 0.6884(9) 0.8515(8) 0.8174(4) 0.073(3) Uani 1 1 d . U . . .
H42_1 H 0.662673 0.783612 0.811892 0.087 Uiso 1 1 calc R U . . .
C43_1 C 0.7485(7) 0.9047(7) 0.8614(4) 0.058(2) Uani 1 1 d . U . . .
C44_1 C 0.7865(10) 1.0068(8) 0.8686(4) 0.079(3) Uani 1 1 d . U . . .
H44_1 H 0.828638 1.044496 0.897644 0.095 Uiso 1 1 calc R U . . .
C45_1 C 0.7622(12) 1.0514(10) 0.8332(5) 0.097(4) Uani 1 1 d . U . . .
H45_1 H 0.785384 1.119261 0.838557 0.116 Uiso 1 1 calc R U . . .
C46_1 C 0.5409(12) 0.8713(14) 1.0129(5) 0.112(4) Uani 1 1 d . U . . .
H46_1 H 0.492115 0.876211 1.033497 0.134 Uiso 1 1 calc R U . . .
C47_1 C 0.6094(11) 0.9540(12) 1.0036(5) 0.098(4) Uani 1 1 d . U . . .
H47_1 H 0.606159 1.014840 1.016954 0.118 Uiso 1 1 calc R U . . .
C48_1 C 0.6840(9) 0.9468(9) 0.9743(4) 0.076(3) Uani 1 1 d . U . . .
H48_1 H 0.732370 1.002999 0.968609 0.091 Uiso 1 1 calc R U . . .
C49_1 C 0.6865(8) 0.8546(9) 0.9531(4) 0.069(2) Uani 1 1 d . U . . .
C50_1 C 0.6176(9) 0.7739(11) 0.9627(5) 0.086(3) Uani 1 1 d . U . . .
H50_1 H 0.620254 0.712855 0.949327 0.103 Uiso 1 1 calc R U . . .
C51_1 C 0.5427(11) 0.7807(14) 0.9922(6) 0.109(4) Uani 1 1 d . U . . .
H51_1 H 0.494329 0.724556 0.997978 0.131 Uiso 1 1 calc R U . . .
C52_1 C 0.9046(8) 0.9120(7) 0.9375(4) 0.061(2) Uani 1 1 d . U . . .
H52A_1 H 0.909713 0.977214 0.953915 0.074 Uiso 1 1 calc R U . . .
H52B_1 H 0.924003 0.880574 0.962162 0.074 Uiso 1 1 calc R U . . .
C53_1 C 0.9748(8) 0.9178(8) 0.8978(4) 0.070(3) Uani 1 1 d . U . . .
H53A_1 H 0.972778 0.969735 0.881584 0.084 Uiso 1 1 calc R U . . .
H53B_1 H 0.948296 0.857004 0.872976 0.084 Uiso 1 1 calc R U . . .
C54_1 C 1.0861(7) 0.9361(8) 0.9156(4) 0.068(2) Uani 1 1 d . U . . .
H54A_1 H 1.091159 0.881714 0.928864 0.081 Uiso 1 1 calc R U . . .
H54B_1 H 1.113849 0.995094 0.941546 0.081 Uiso 1 1 calc R U . . .
Ag1_2 Ag 0.31215(9) 0.95636(10) 0.53173(4) 0.1081(4) Uani 1 1 d . . . . .
P1_2 P 0.6342(2) 0.9609(3) 0.38233(13) 0.0832(8) Uani 1 1 d . . . . .
P2_2 P 0.2520(2) 0.8762(2) 0.44662(11) 0.0689(7) Uani 1 1 d . . . . .
C1_2 C 0.834(2) 0.806(2) 0.3197(12) 0.188(8) Uani 1 1 d . U . . .
H1_2 H 0.876896 0.773255 0.308009 0.226 Uiso 1 1 calc R U . . .
C2_2 C 0.881(2) 0.886(2) 0.3532(11) 0.179(7) Uani 1 1 d . U . . .
H2_2 H 0.950196 0.911495 0.364045 0.215 Uiso 1 1 calc R U . . .
C3_2 C 0.8116(15) 0.9296(17) 0.3705(9) 0.151(6) Uani 1 1 d . U . . .
H3_2 H 0.837210 0.987142 0.394725 0.181 Uiso 1 1 calc R U . . .
C4_2 C 0.7089(14) 0.8938(13) 0.3546(8) 0.124(5) Uani 1 1 d . U . . .
C5_2 C 0.6712(17) 0.8095(16) 0.3208(10) 0.173(7) Uani 1 1 d . U . . .
H5_2 H 0.601061 0.781260 0.311535 0.208 Uiso 1 1 calc R U . . .
C6_2 C 0.735(2) 0.7617(19) 0.2986(12) 0.198(8) Uani 1 1 d . U . . .
H6_2 H 0.711709 0.706577 0.272803 0.238 Uiso 1 1 calc R U . . .
C7_2 C 0.6250(18) 1.1687(17) 0.2789(8) 0.146(6) Uani 1 1 d . U . . .
H7_2 H 0.618818 1.208953 0.257890 0.175 Uiso 1 1 calc R U . . .
C8_2 C 0.6788(19) 1.1089(18) 0.2669(7) 0.158(6) Uani 1 1 d . U . . .
H8_2 H 0.715032 1.112752 0.239868 0.189 Uiso 1 1 calc R U . . .
C9_2 C 0.6785(16) 1.0399(16) 0.2969(6) 0.133(5) Uani 1 1 d . U . . .
H9_2 H 0.711787 0.995933 0.288498 0.160 Uiso 1 1 calc R U . . .
C10_2 C 0.6271(12) 1.0391(11) 0.3394(5) 0.095(4) Uani 1 1 d . U . . .
C11_2 C 0.5907(15) 1.1074(12) 0.3508(6) 0.118(4) Uani 1 1 d . U . . .
H11_2 H 0.568713 1.115911 0.381792 0.142 Uiso 1 1 calc R U . . .
C12_2 C 0.5812(16) 1.1706(13) 0.3201(7) 0.129(5) Uani 1 1 d . U . . .
H12_2 H 0.545365 1.212301 0.328489 0.154 Uiso 1 1 calc R U . . .
C13_2 C -0.0189(11) 0.5987(12) 0.4453(6) 0.107(4) Uani 1 1 d . U . . .
H13_2 H -0.073688 0.542145 0.445348 0.128 Uiso 1 1 calc R U . . .
C14_2 C 0.0761(11) 0.6031(10) 0.4565(6) 0.100(4) Uani 1 1 d . U . . .
H14_2 H 0.087060 0.549129 0.464634 0.121 Uiso 1 1 calc R U . . .
C15_2 C 0.1592(9) 0.6861(9) 0.4564(5) 0.083(3) Uani 1 1 d . U . . .
H15_2 H 0.224899 0.688152 0.465105 0.100 Uiso 1 1 calc R U . . .
C16_2 C 0.1435(8) 0.7667(8) 0.4432(4) 0.070(3) Uani 1 1 d . U . . .
C17_2 C 0.0460(9) 0.7636(10) 0.4324(5) 0.083(3) Uani 1 1 d . U . . .
H17_2 H 0.034128 0.817233 0.424493 0.099 Uiso 1 1 calc R U . . .
C18_2 C -0.0353(10) 0.6788(12) 0.4335(6) 0.103(4) Uani 1 1 d . U . . .
H18_2 H -0.101636 0.676333 0.426247 0.123 Uiso 1 1 calc R U . . .
C19_2 C 0.1725(15) 1.0496(15) 0.3408(9) 0.135(5) Uani 1 1 d . U . . .
H19_2 H 0.166519 1.088274 0.318836 0.162 Uiso 1 1 calc R U . . .
C20_2 C 0.1973(15) 1.0897(13) 0.3894(10) 0.140(6) Uani 1 1 d . U . . .
H20_2 H 0.198763 1.152772 0.401570 0.168 Uiso 1 1 calc R U . . .
C21_2 C 0.2207(11) 1.0367(10) 0.4214(8) 0.114(4) Uani 1 1 d . U . . .
H21_2 H 0.241196 1.066175 0.454873 0.136 Uiso 1 1 calc R U . . .
C22_2 C 0.2145(10) 0.9445(10) 0.4055(6) 0.093(4) Uani 1 1 d . U . . .
C23_2 C 0.1784(12) 0.9014(14) 0.3562(7) 0.115(4) Uani 1 1 d . U . . .
H23_2 H 0.169123 0.835747 0.345106 0.138 Uiso 1 1 calc R U . . .
C24_2 C 0.1555(14) 0.9518(16) 0.3227(8) 0.133(5) Uani 1 1 d . U . . .
H24_2 H 0.130064 0.921489 0.289700 0.160 Uiso 1 1 calc R U . . .
C25_2 C 0.3399(8) 0.8313(8) 0.4120(5) 0.078(3) Uani 1 1 d . U . . .
H25A_2 H 0.355169 0.783730 0.427723 0.093 Uiso 1 1 calc R U . . .
H25B_2 H 0.306703 0.798204 0.378623 0.093 Uiso 1 1 calc R U . . .
C26_2 C 0.4385(9) 0.9112(9) 0.4092(5) 0.084(3) Uani 1 1 d . U . . .
H26A_2 H 0.474242 0.941480 0.442438 0.101 Uiso 1 1 calc R U . . .
H26B_2 H 0.423389 0.960942 0.395389 0.101 Uiso 1 1 calc R U . . .
C27_2 C 0.5070(10) 0.8727(9) 0.3775(5) 0.088(3) Uani 1 1 d . U . . .
H27A_2 H 0.476387 0.853458 0.343132 0.105 Uiso 1 1 calc R U . . .
H27B_2 H 0.511314 0.814934 0.387478 0.105 Uiso 1 1 calc R U . . .
Mo1_3 Mo 0.51862(9) 0.26305(7) 0.47663(4) 0.0892(4) Uani 1 1 d . . . . .
Mo2_3 Mo 0.32363(7) 0.30727(7) 0.54312(4) 0.0729(2) Uani 1 1 d . . . . .
Mo3_3 Mo 0.23707(7) 0.42096(7) 0.45614(3) 0.0665(2) Uani 1 1 d . . . . .
Mo4_3 Mo 0.32907(7) 0.55188(6) 0.58078(3) 0.0677(2) Uani 1 1 d . . . . .
Mo5_3 Mo 0.40254(9) 0.33884(6) 0.38168(3) 0.0807(3) Uani 1 1 d . . . . .
Mo6_3 Mo 0.41670(10) 0.58636(8) 0.40063(3) 0.0856(3) Uani 1 1 d . . . . .
P1_3 P 0.500000 0.500000 0.500000 0.0596(9) Uani 1 2 d S . P . .
O1_3 O 0.5976(9) 0.5338(8) 0.4888(4) 0.049(3) Uani 0.5 1 d . . P . .
O2_3 O 0.4755(8) 0.4037(8) 0.5232(4) 0.044(2) Uani 0.5 1 d . . P . .
O3_3 O 0.4111(9) 0.4698(8) 0.4572(4) 0.053(3) Uani 0.5 1 d . . P . .
O4_3 O 0.4733(9) 0.5736(8) 0.5410(4) 0.049(3) Uani 0.5 1 d . . P . .
O5_3 O 0.2870(11) 0.3381(7) 0.4063(4) 0.131(5) Uani 1 1 d . . . . .
O6_3 O 0.3619(6) 0.2685(6) 0.3255(3) 0.083(2) Uani 1 1 d . . . . .
O7_3 O 0.4290(8) 0.2563(7) 0.4170(4) 0.135(5) Uani 1 1 d . . . . .
O8_3 O 0.5489(8) 0.3938(7) 0.3790(5) 0.140(5) Uani 1 1 d . . . . .
O9_3 O 0.6272(8) 0.3299(7) 0.4479(5) 0.140(5) Uani 1 1 d . . . . .
O10_3 O 0.2475(9) 0.5771(9) 0.6166(3) 0.117(4) Uani 1 1 d . . . . .
O11_3 O 0.2442(5) 0.5026(5) 0.5155(3) 0.0691(18) Uani 1 1 d . . . . .
O12_3 O 0.1147(9) 0.3806(8) 0.4364(5) 0.137(5) Uani 1 1 d . . . . .
O13_3 O 0.2440(6) 0.3206(5) 0.4930(3) 0.0711(18) Uani 1 1 d . . . . .
O14_3 O 0.2414(10) 0.2226(7) 0.5642(4) 0.131(5) Uani 1 1 d . . . . .
O15_3 O 0.3080(5) 0.4250(5) 0.5833(2) 0.0656(17) Uani 1 1 d . . . . .
O16_3 O 0.3876(9) 0.2414(11) 0.5035(4) 0.166(7) Uani 1 1 d . . . . .
O17_3 O 0.5207(7) 0.1505(5) 0.4669(3) 0.080(2) Uani 1 1 d . . . . .
O18_3 O 0.5537(8) 0.6484(10) 0.4062(4) 0.144(5) Uani 1 1 d . . . . .
O19_3 O 0.5814(8) 0.3138(10) 0.5398(4) 0.148(6) Uani 1 1 d . . . . .
O20_3 O 0.3742(6) 0.6295(6) 0.3561(3) 0.078(2) Uani 1 1 d . . . . .
O21_3 O 0.2903(12) 0.5193(7) 0.4235(4) 0.137(5) Uani 1 1 d . . . . .
O22_3 O 0.4135(10) 0.4689(7) 0.3679(4) 0.119(4) Uani 1 1 d . . . . .
Mo1_4 Mo 0.97782(7) 0.61973(6) 0.90219(3) 0.0649(2) Uani 1 1 d . . . . .
Mo2_4 Mo 0.95804(8) 0.37028(7) 0.87427(3) 0.0691(2) Uani 1 1 d . . . . .
Mo3_4 Mo 0.98224(7) 0.73605(6) 1.02800(3) 0.0629(2) Uani 1 1 d . . . . .
Mo4_4 Mo 0.76490(7) 0.52958(7) 0.96778(4) 0.0705(2) Uani 1 1 d . . . . .
Mo5_4 Mo 0.77525(7) 0.29011(6) 0.95655(3) 0.0692(2) Uani 1 1 d . . . . .
Mo6_4 Mo 0.80193(7) 0.44290(7) 1.07551(4) 0.0715(2) Uani 1 1 d . . . . .
P1_4 P 1.000000 0.500000 1.000000 0.0491(7) Uani 1 2 d S . P . .
O1_4 O 0.8849(9) 0.4589(8) 0.9994(4) 0.048(2) Uani 0.5 1 d . . P . .
O2_4 O 1.0468(9) 0.4324(8) 1.0173(4) 0.053(3) Uani 0.5 1 d . . P . .
O3_4 O 1.0425(9) 0.6009(8) 1.0333(4) 0.053(3) Uani 0.5 1 d . . P . .
O4_4 O 1.0216(8) 0.5081(8) 0.9465(4) 0.048(2) Uani 0.5 1 d . . P . .
O5_4 O 0.9991(7) 0.7185(7) 0.9555(3) 0.098(3) Uani 1 1 d . . . . .
O6_4 O 0.9610(8) 0.6725(6) 0.8563(3) 0.093(3) Uani 1 1 d . . . . .
O7_4 O 0.8903(7) 0.3735(6) 1.0971(5) 0.112(4) Uani 1 1 d . . . . .
O8_4 O 0.9393(7) 0.4811(7) 0.8667(5) 0.116(4) Uani 1 1 d . . . . .
O9_4 O 0.8365(7) 0.3163(8) 0.8950(4) 0.106(3) Uani 1 1 d . . . . .
O10_4 O 0.9438(8) 0.3076(6) 0.8173(3) 0.093(3) Uani 1 1 d . . . . .
O11_4 O 0.8938(7) 0.5529(6) 1.1148(5) 0.124(4) Uani 1 1 d . . . . .
O12_4 O 0.9919(7) 0.7115(8) 1.0899(3) 0.105(3) Uani 1 1 d . . . . .
O13_4 O 0.9809(8) 0.8482(5) 1.0392(3) 0.091(2) Uani 1 1 d . . . . .
O14_4 O 0.8510(7) 0.6611(7) 1.0081(3) 0.105(3) Uani 1 1 d . . . . .
O15_4 O 0.6593(7) 0.5498(8) 0.9541(4) 0.106(3) Uani 1 1 d . . . . .
O16_4 O 0.7525(10) 0.5042(7) 1.0353(3) 0.112(3) Uani 1 1 d . . . . .
O17_4 O 0.7302(10) 0.3996(7) 0.9440(3) 0.110(3) Uani 1 1 d . . . . .
O18_4 O 0.6725(7) 0.1955(6) 0.9328(4) 0.099(3) Uani 1 1 d . . . . .
O19_4 O 0.8686(7) 0.2346(8) 0.9679(3) 0.106(3) Uani 1 1 d . . . . .
O20_4 O 0.7572(10) 0.3256(6) 1.0213(3) 0.110(3) Uani 1 1 d . . . . .
O21_4 O 0.7122(7) 0.4100(7) 1.1105(4) 0.097(3) Uani 1 1 d . . . . .
O22_4 O 0.8356(7) 0.5667(7) 0.9172(3) 0.103(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1_1 P1_1 2.378(3) . ?
Ag1_1 P3_1 2.386(3) . ?
Ag2_1 P2_1 2.429(3) . ?
Ag2_1 P4_1 2.400(3) . ?
P1_1 C4_1 1.810(14) . ?
P1_1 C10_1 1.812(12) . ?
P1_1 C27_1 1.837(12) . ?
P2_1 C16_1 1.799(8) . ?
P2_1 C22_1 1.823(15) . ?
P2_1 C25_1 1.825(14) . ?
P3_1 C31_1 1.818(10) . ?
P3_1 C37_1 1.824(15) . ?
P3_1 C54_1 1.829(11) . ?
P4_1 C43_1 1.821(10) . ?
P4_1 C49_1 1.821(11) . ?
P4_1 C52_1 1.839(10) . ?
C1_1 H1_1 0.9300 . ?
C1_1 C2_1 1.33(3) . ?
C1_1 C6_1 1.35(3) . ?
C2_1 H2_1 0.9300 . ?
C2_1 C3_1 1.43(2) . ?
C3_1 H3_1 0.9300 . ?
C3_1 C4_1 1.37(2) . ?
C4_1 C5_1 1.39(2) . ?
C5_1 H5_1 0.9300 . ?
C5_1 C6_1 1.40(3) . ?
C6_1 H6_1 0.9300 . ?
C7_1 H7_1 0.9300 . ?
C7_1 C8_1 1.34(2) . ?
C7_1 C12_1 1.34(2) . ?
C8_1 H8_1 0.9300 . ?
C8_1 C9_1 1.387(18) . ?
C9_1 H9_1 0.9300 . ?
C9_1 C10_1 1.361(16) . ?
C10_1 C11_1 1.363(17) . ?
C11_1 H11_1 0.9300 . ?
C11_1 C12_1 1.37(2) . ?
C12_1 H12_1 0.9300 . ?
C13_1 H13_1 0.9300 . ?
C13_1 C14_1 1.3900 . ?
C13_1 C18_1 1.3900 . ?
C14_1 H14_1 0.9300 . ?
C14_1 C15_1 1.3900 . ?
C15_1 H15_1 0.9300 . ?
C15_1 C16_1 1.3900 . ?
C16_1 C17_1 1.3900 . ?
C17_1 H17_1 0.9300 . ?
C17_1 C18_1 1.3900 . ?
C18_1 H18_1 0.9300 . ?
C19_1 H19_1 0.9300 . ?
C19_1 C20_1 1.35(2) . ?
C19_1 C24_1 1.37(2) . ?
C20_1 H20_1 0.9300 . ?
C20_1 C21_1 1.40(2) . ?
C21_1 H21_1 0.9300 . ?
C21_1 C22_1 1.371(17) . ?
C22_1 C23_1 1.38(2) . ?
C23_1 H23_1 0.9300 . ?
C23_1 C24_1 1.40(2) . ?
C24_1 H24_1 0.9300 . ?
C25_1 H25A_1 0.9700 . ?
C25_1 H25B_1 0.9700 . ?
C25_1 C26_1 1.461(18) . ?
C26_1 H26A_1 0.9700 . ?
C26_1 H26B_1 0.9700 . ?
C26_1 C27_1 1.533(16) . ?
C27_1 H27A_1 0.9700 . ?
C27_1 H27B_1 0.9700 . ?
C28_1 H28_1 0.9300 . ?
C28_1 C29_1 1.35(2) . ?
C28_1 C33_1 1.38(2) . ?
C29_1 H29_1 0.9300 . ?
C29_1 C30_1 1.377(18) . ?
C30_1 H30_1 0.9300 . ?
C30_1 C31_1 1.375(17) . ?
C31_1 C32_1 1.374(17) . ?
C32_1 H32_1 0.9300 . ?
C32_1 C33_1 1.378(17) . ?
C33_1 H33_1 0.9300 . ?
C34_1 H34_1 0.9300 . ?
C34_1 C35_1 1.31(3) . ?
C34_1 C39_1 1.34(3) . ?
C35_1 H35_1 0.9300 . ?
C35_1 C36_1 1.36(2) . ?
C36_1 H36_1 0.9300 . ?
C36_1 C37_1 1.38(2) . ?
C37_1 C38_1 1.36(2) . ?
C38_1 H38_1 0.9300 . ?
C38_1 C39_1 1.46(3) . ?
C39_1 H39_1 0.9300 . ?
C40_1 H40_1 0.9300 . ?
C40_1 C41_1 1.349(19) . ?
C40_1 C45_1 1.367(19) . ?
C41_1 H41_1 0.9300 . ?
C41_1 C42_1 1.396(16) . ?
C42_1 H42_1 0.9300 . ?
C42_1 C43_1 1.377(14) . ?
C43_1 C44_1 1.402(15) . ?
C44_1 H44_1 0.9300 . ?
C44_1 C45_1 1.369(16) . ?
C45_1 H45_1 0.9300 . ?
C46_1 H46_1 0.9300 . ?
C46_1 C47_1 1.36(2) . ?
C46_1 C51_1 1.37(2) . ?
C47_1 H47_1 0.9300 . ?
C47_1 C48_1 1.384(17) . ?
C48_1 H48_1 0.9300 . ?
C48_1 C49_1 1.402(16) . ?
C49_1 C50_1 1.348(17) . ?
C50_1 H50_1 0.9300 . ?
C50_1 C51_1 1.391(19) . ?
C51_1 H51_1 0.9300 . ?
C52_1 H52A_1 0.9700 . ?
C52_1 H52B_1 0.9700 . ?
C52_1 C53_1 1.516(15) . ?
C53_1 H53A_1 0.9700 . ?
C53_1 H53B_1 0.9700 . ?
C53_1 C54_1 1.529(14) . ?
C54_1 H54A_1 0.9700 . ?
C54_1 H54B_1 0.9700 . ?
Ag1_2 P1_2 2.413(4) 2_676 ?
Ag1_2 P2_2 2.394(3) . ?
P1_2 C4_2 1.791(16) . ?
P1_2 C10_2 1.830(14) . ?
P1_2 C27_2 1.807(13) . ?
P2_2 C16_2 1.802(12) . ?
P2_2 C22_2 1.823(14) . ?
P2_2 C25_2 1.831(12) . ?
C1_2 H1_2 0.9300 . ?
C1_2 C2_2 1.31(3) . ?
C1_2 C6_2 1.37(4) . ?
C2_2 H2_2 0.9300 . ?
C2_2 C3_2 1.39(3) . ?
C3_2 H3_2 0.9300 . ?
C3_2 C4_2 1.37(3) . ?
C4_2 C5_2 1.34(3) . ?
C5_2 H5_2 0.9300 . ?
C5_2 C6_2 1.42(3) . ?
C6_2 H6_2 0.9300 . ?
C7_2 H7_2 0.9300 . ?
C7_2 C8_2 1.36(3) . ?
C7_2 C12_2 1.33(3) . ?
C8_2 H8_2 0.9300 . ?
C8_2 C9_2 1.43(3) . ?
C9_2 H9_2 0.9300 . ?
C9_2 C10_2 1.42(2) . ?
C10_2 C11_2 1.28(2) . ?
C11_2 H11_2 0.9300 . ?
C11_2 C12_2 1.41(2) . ?
C12_2 H12_2 0.9300 . ?
C13_2 H13_2 0.9300 . ?
C13_2 C14_2 1.33(2) . ?
C13_2 C18_2 1.38(2) . ?
C14_2 H14_2 0.9300 . ?
C14_2 C15_2 1.385(18) . ?
C15_2 H15_2 0.9300 . ?
C15_2 C16_2 1.398(15) . ?
C16_2 C17_2 1.369(15) . ?
C17_2 H17_2 0.9300 . ?
C17_2 C18_2 1.394(18) . ?
C18_2 H18_2 0.9300 . ?
C19_2 H19_2 0.9300 . ?
C19_2 C20_2 1.34(3) . ?
C19_2 C24_2 1.38(3) . ?
C20_2 H20_2 0.9300 . ?
C20_2 C21_2 1.38(2) . ?
C21_2 H21_2 0.9300 . ?
C21_2 C22_2 1.333(19) . ?
C22_2 C23_2 1.38(2) . ?
C23_2 H23_2 0.9300 . ?
C23_2 C24_2 1.38(2) . ?
C24_2 H24_2 0.9300 . ?
C25_2 H25A_2 0.9700 . ?
C25_2 H25B_2 0.9700 . ?
C25_2 C26_2 1.509(16) . ?
C26_2 H26A_2 0.9700 . ?
C26_2 H26B_2 0.9700 . ?
C26_2 C27_2 1.520(16) . ?
C27_2 H27A_2 0.9700 . ?
C27_2 H27B_2 0.9700 . ?
Mo1_3 O7_3 1.983(8) . ?
Mo1_3 O9_3 1.834(13) . ?
Mo1_3 O16_3 1.975(14) . ?
Mo1_3 O17_3 1.657(7) . ?
Mo1_3 O19_3 1.812(9) . ?
Mo2_3 O2_3 2.300(11) . ?
Mo2_3 O13_3 1.813(7) . ?
Mo2_3 O14_3 1.624(10) . ?
Mo2_3 O15_3 1.981(7) . ?
Mo2_3 O16_3 1.812(10) . ?
Mo2_3 O18_3 1.997(8) 2_666 ?
Mo3_3 O1_3 2.515(11) 2_666 ?
Mo3_3 O3_3 2.303(12) . ?
Mo3_3 O5_3 1.996(8) . ?
Mo3_3 O11_3 1.828(7) . ?
Mo3_3 O12_3 1.641(10) . ?
Mo3_3 O13_3 1.983(7) . ?
Mo3_3 O21_3 1.831(10) . ?
Mo4_3 O4_3 2.320(12) . ?
Mo4_3 O8_3 1.828(8) 2_666 ?
Mo4_3 O9_3 1.987(9) 2_666 ?
Mo4_3 O10_3 1.651(9) . ?
Mo4_3 O11_3 1.973(6) . ?
Mo4_3 O15_3 1.827(7) . ?
Mo5_3 O4_3 2.513(11) 2_666 ?
Mo5_3 O5_3 1.796(12) . ?
Mo5_3 O6_3 1.653(7) . ?
Mo5_3 O7_3 1.819(8) . ?
Mo5_3 O8_3 1.954(12) . ?
Mo5_3 O22_3 2.000(8) . ?
Mo6_3 O2_3 2.472(10) 2_666 ?
Mo6_3 O18_3 1.816(12) . ?
Mo6_3 O19_3 1.998(8) 2_666 ?
Mo6_3 O20_3 1.658(7) . ?
Mo6_3 O21_3 1.930(13) . ?
Mo6_3 O22_3 1.799(9) . ?
P1_3 O1_3 1.370(12) . ?
P1_3 O1_3 1.370(12) 2_666 ?
P1_3 O2_3 1.620(10) . ?
P1_3 O2_3 1.620(10) 2_666 ?
P1_3 O3_3 1.554(11) 2_666 ?
P1_3 O3_3 1.554(11) . ?
P1_3 O4_3 1.580(11) . ?
P1_3 O4_3 1.580(11) 2_666 ?
O1_3 O2_3 1.661(14) 2_666 ?
O1_3 O3_3 1.515(17) 2_666 ?
O1_3 O4_3 1.604(16) 2_666 ?
Mo1_4 O2_4 2.495(12) 2_767 ?
Mo1_4 O4_4 2.449(11) . ?
Mo1_4 O5_4 1.811(9) . ?
Mo1_4 O6_4 1.657(7) . ?
Mo1_4 O7_4 1.822(9) 2_767 ?
Mo1_4 O8_4 1.989(9) . ?
Mo1_4 O22_4 1.987(10) . ?
Mo2_4 O3_4 2.514(12) 2_767 ?
Mo2_4 O4_4 2.457(11) . ?
Mo2_4 O8_4 1.802(9) . ?
Mo2_4 O9_4 1.804(10) . ?
Mo2_4 O10_4 1.641(8) . ?
Mo2_4 O11_4 1.983(10) 2_767 ?
Mo2_4 O12_4 1.976(8) 2_767 ?
Mo3_4 O2_4 2.474(12) 2_767 ?
Mo3_4 O3_4 2.456(11) . ?
Mo3_4 O5_4 2.013(8) . ?
Mo3_4 O12_4 1.822(8) . ?
Mo3_4 O13_4 1.648(7) . ?
Mo3_4 O14_4 1.794(9) . ?
Mo3_4 O19_4 1.985(10) 2_767 ?
Mo4_4 O1_4 2.467(11) . ?
Mo4_4 O2_4 2.506(12) 2_767 ?
Mo4_4 O14_4 1.995(9) . ?
Mo4_4 O15_4 1.648(8) . ?
Mo4_4 O16_4 1.980(9) . ?
Mo4_4 O17_4 1.809(9) . ?
Mo4_4 O22_4 1.826(9) . ?
Mo5_4 O1_4 2.483(11) . ?
Mo5_4 O3_4 2.495(12) 2_767 ?
Mo5_4 O9_4 1.996(9) . ?
Mo5_4 O17_4 2.015(9) . ?
Mo5_4 O18_4 1.636(8) . ?
Mo5_4 O19_4 1.812(9) . ?
Mo5_4 O20_4 1.829(9) . ?
Mo6_4 O1_4 2.477(11) . ?
Mo6_4 O4_4 2.486(11) 2_767 ?
Mo6_4 O7_4 1.994(9) . ?
Mo6_4 O11_4 1.812(10) . ?
Mo6_4 O16_4 1.807(10) . ?
Mo6_4 O20_4 1.969(9) . ?
Mo6_4 O21_4 1.635(8) . ?
P1_4 O1_4 1.524(12) 2_767 ?
P1_4 O1_4 1.524(12) . ?
P1_4 O2_4 1.504(12) 2_767 ?
P1_4 O2_4 1.504(12) . ?
P1_4 O3_4 1.511(12) . ?
P1_4 O3_4 1.511(12) 2_767 ?
P1_4 O4_4 1.548(11) . ?
P1_4 O4_4 1.548(11) 2_767 ?
O1_4 O2_4 1.744(16) 2_767 ?
O1_4 O3_4 1.755(17) 2_767 ?
O1_4 O4_4 1.809(15) 2_767 ?
O2_4 O3_4 1.704(16) 2_767 ?
O2_4 O4_4 1.753(17) 2_767 ?
O3_4 O4_4 1.779(16) 2_767 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1_1 Ag1_1 P3_1 174.41(11) . . ?
P4_1 Ag2_1 P2_1 148.04(10) . . ?
C4_1 P1_1 Ag1_1 113.5(5) . . ?
C4_1 P1_1 C10_1 106.7(6) . . ?
C4_1 P1_1 C27_1 105.7(8) . . ?
C10_1 P1_1 Ag1_1 112.4(4) . . ?
C10_1 P1_1 C27_1 103.4(5) . . ?
C27_1 P1_1 Ag1_1 114.3(4) . . ?
C16_1 P2_1 Ag2_1 124.2(4) . . ?
C16_1 P2_1 C22_1 104.2(6) . . ?
C16_1 P2_1 C25_1 103.2(6) . . ?
C22_1 P2_1 Ag2_1 109.8(5) . . ?
C22_1 P2_1 C25_1 107.5(6) . . ?
C25_1 P2_1 Ag2_1 106.8(5) . . ?
C31_1 P3_1 Ag1_1 107.1(4) . . ?
C31_1 P3_1 C37_1 106.9(6) . . ?
C31_1 P3_1 C54_1 110.2(5) . . ?
C37_1 P3_1 Ag1_1 118.5(5) . . ?
C37_1 P3_1 C54_1 104.1(6) . . ?
C54_1 P3_1 Ag1_1 110.0(4) . . ?
C43_1 P4_1 Ag2_1 111.5(3) . . ?
C43_1 P4_1 C49_1 104.3(5) . . ?
C43_1 P4_1 C52_1 105.4(5) . . ?
C49_1 P4_1 Ag2_1 110.9(4) . . ?
C49_1 P4_1 C52_1 108.7(5) . . ?
C52_1 P4_1 Ag2_1 115.3(3) . . ?
C2_1 C1_1 H1_1 117.4 . . ?
C2_1 C1_1 C6_1 125(2) . . ?
C6_1 C1_1 H1_1 117.4 . . ?
C1_1 C2_1 H2_1 121.3 . . ?
C1_1 C2_1 C3_1 117(2) . . ?
C3_1 C2_1 H2_1 121.3 . . ?
C2_1 C3_1 H3_1 120.9 . . ?
C4_1 C3_1 C2_1 118.2(18) . . ?
C4_1 C3_1 H3_1 120.9 . . ?
C3_1 C4_1 P1_1 118.8(12) . . ?
C3_1 C4_1 C5_1 122.9(15) . . ?
C5_1 C4_1 P1_1 118.3(12) . . ?
C4_1 C5_1 H5_1 121.4 . . ?
C4_1 C5_1 C6_1 117.2(19) . . ?
C6_1 C5_1 H5_1 121.4 . . ?
C1_1 C6_1 C5_1 119(2) . . ?
C1_1 C6_1 H6_1 120.5 . . ?
C5_1 C6_1 H6_1 120.5 . . ?
C8_1 C7_1 H7_1 119.7 . . ?
C12_1 C7_1 H7_1 119.7 . . ?
C12_1 C7_1 C8_1 120.5(15) . . ?
C7_1 C8_1 H8_1 120.3 . . ?
C7_1 C8_1 C9_1 119.4(13) . . ?
C9_1 C8_1 H8_1 120.3 . . ?
C8_1 C9_1 H9_1 119.6 . . ?
C10_1 C9_1 C8_1 120.7(13) . . ?
C10_1 C9_1 H9_1 119.6 . . ?
C9_1 C10_1 P1_1 123.2(10) . . ?
C9_1 C10_1 C11_1 118.2(12) . . ?
C11_1 C10_1 P1_1 118.6(10) . . ?
C10_1 C11_1 H11_1 119.6 . . ?
C10_1 C11_1 C12_1 120.8(14) . . ?
C12_1 C11_1 H11_1 119.6 . . ?
C7_1 C12_1 C11_1 120.1(15) . . ?
C7_1 C12_1 H12_1 119.9 . . ?
C11_1 C12_1 H12_1 119.9 . . ?
C14_1 C13_1 H13_1 120.0 . . ?
C14_1 C13_1 C18_1 120.0 . . ?
C18_1 C13_1 H13_1 120.0 . . ?
C13_1 C14_1 H14_1 120.0 . . ?
C15_1 C14_1 C13_1 120.0 . . ?
C15_1 C14_1 H14_1 120.0 . . ?
C14_1 C15_1 H15_1 120.0 . . ?
C16_1 C15_1 C14_1 120.0 . . ?
C16_1 C15_1 H15_1 120.0 . . ?
C15_1 C16_1 P2_1 122.5(6) . . ?
C15_1 C16_1 C17_1 120.0 . . ?
C17_1 C16_1 P2_1 117.5(6) . . ?
C16_1 C17_1 H17_1 120.0 . . ?
C18_1 C17_1 C16_1 120.0 . . ?
C18_1 C17_1 H17_1 120.0 . . ?
C13_1 C18_1 H18_1 120.0 . . ?
C17_1 C18_1 C13_1 120.0 . . ?
C17_1 C18_1 H18_1 120.0 . . ?
C20_1 C19_1 H19_1 119.1 . . ?
C20_1 C19_1 C24_1 121.7(17) . . ?
C24_1 C19_1 H19_1 119.1 . . ?
C19_1 C20_1 H20_1 120.0 . . ?
C19_1 C20_1 C21_1 120.0(15) . . ?
C21_1 C20_1 H20_1 120.0 . . ?
C20_1 C21_1 H21_1 120.0 . . ?
C22_1 C21_1 C20_1 120.0(16) . . ?
C22_1 C21_1 H21_1 120.0 . . ?
C21_1 C22_1 P2_1 120.6(12) . . ?
C21_1 C22_1 C23_1 119.4(15) . . ?
C23_1 C22_1 P2_1 120.1(10) . . ?
C22_1 C23_1 H23_1 119.6 . . ?
C22_1 C23_1 C24_1 120.8(15) . . ?
C24_1 C23_1 H23_1 119.6 . . ?
C19_1 C24_1 C23_1 118.1(18) . . ?
C19_1 C24_1 H24_1 121.0 . . ?
C23_1 C24_1 H24_1 121.0 . . ?
P2_1 C25_1 H25A_1 109.0 . . ?
P2_1 C25_1 H25B_1 109.0 . . ?
H25A_1 C25_1 H25B_1 107.8 . . ?
C26_1 C25_1 P2_1 112.9(10) . . ?
C26_1 C25_1 H25A_1 109.0 . . ?
C26_1 C25_1 H25B_1 109.0 . . ?
C25_1 C26_1 H26A_1 108.1 . . ?
C25_1 C26_1 H26B_1 108.1 . . ?
C25_1 C26_1 C27_1 116.6(12) . . ?
H26A_1 C26_1 H26B_1 107.3 . . ?
C27_1 C26_1 H26A_1 108.1 . . ?
C27_1 C26_1 H26B_1 108.1 . . ?
P1_1 C27_1 H27A_1 107.9 . . ?
P1_1 C27_1 H27B_1 107.9 . . ?
C26_1 C27_1 P1_1 117.5(9) . . ?
C26_1 C27_1 H27A_1 107.9 . . ?
C26_1 C27_1 H27B_1 107.9 . . ?
H27A_1 C27_1 H27B_1 107.2 . . ?
C29_1 C28_1 H28_1 120.2 . . ?
C29_1 C28_1 C33_1 119.7(12) . . ?
C33_1 C28_1 H28_1 120.2 . . ?
C28_1 C29_1 H29_1 119.6 . . ?
C28_1 C29_1 C30_1 120.8(13) . . ?
C30_1 C29_1 H29_1 119.6 . . ?
C29_1 C30_1 H30_1 119.9 . . ?
C31_1 C30_1 C29_1 120.1(13) . . ?
C31_1 C30_1 H30_1 119.9 . . ?
C30_1 C31_1 P3_1 122.7(10) . . ?
C32_1 C31_1 P3_1 117.8(9) . . ?
C32_1 C31_1 C30_1 119.2(11) . . ?
C31_1 C32_1 H32_1 119.9 . . ?
C31_1 C32_1 C33_1 120.3(13) . . ?
C33_1 C32_1 H32_1 119.9 . . ?
C28_1 C33_1 C32_1 120.0(13) . . ?
C28_1 C33_1 H33_1 120.0 . . ?
C32_1 C33_1 H33_1 120.0 . . ?
C35_1 C34_1 H34_1 118.4 . . ?
C35_1 C34_1 C39_1 123(2) . . ?
C39_1 C34_1 H34_1 118.4 . . ?
C34_1 C35_1 H35_1 120.0 . . ?
C34_1 C35_1 C36_1 120(2) . . ?
C36_1 C35_1 H35_1 120.0 . . ?
C35_1 C36_1 H36_1 119.5 . . ?
C35_1 C36_1 C37_1 121.1(17) . . ?
C37_1 C36_1 H36_1 119.5 . . ?
C36_1 C37_1 P3_1 119.6(10) . . ?
C38_1 C37_1 P3_1 121.0(15) . . ?
C38_1 C37_1 C36_1 118.9(16) . . ?
C37_1 C38_1 H38_1 120.7 . . ?
C37_1 C38_1 C39_1 119(2) . . ?
C39_1 C38_1 H38_1 120.7 . . ?
C34_1 C39_1 C38_1 118(2) . . ?
C34_1 C39_1 H39_1 121.1 . . ?
C38_1 C39_1 H39_1 121.1 . . ?
C41_1 C40_1 H40_1 118.6 . . ?
C41_1 C40_1 C45_1 122.8(12) . . ?
C45_1 C40_1 H40_1 118.6 . . ?
C40_1 C41_1 H41_1 121.1 . . ?
C40_1 C41_1 C42_1 117.8(12) . . ?
C42_1 C41_1 H41_1 121.1 . . ?
C41_1 C42_1 H42_1 119.1 . . ?
C43_1 C42_1 C41_1 121.7(11) . . ?
C43_1 C42_1 H42_1 119.1 . . ?
C42_1 C43_1 P4_1 119.4(8) . . ?
C42_1 C43_1 C44_1 117.9(10) . . ?
C44_1 C43_1 P4_1 122.6(8) . . ?
C43_1 C44_1 H44_1 119.8 . . ?
C45_1 C44_1 C43_1 120.5(11) . . ?
C45_1 C44_1 H44_1 119.8 . . ?
C40_1 C45_1 C44_1 119.3(12) . . ?
C40_1 C45_1 H45_1 120.4 . . ?
C44_1 C45_1 H45_1 120.4 . . ?
C47_1 C46_1 H46_1 119.5 . . ?
C47_1 C46_1 C51_1 121.0(15) . . ?
C51_1 C46_1 H46_1 119.5 . . ?
C46_1 C47_1 H47_1 120.3 . . ?
C46_1 C47_1 C48_1 119.5(14) . . ?
C48_1 C47_1 H47_1 120.3 . . ?
C47_1 C48_1 H48_1 120.0 . . ?
C47_1 C48_1 C49_1 119.9(13) . . ?
C49_1 C48_1 H48_1 120.0 . . ?
C48_1 C49_1 P4_1 121.2(9) . . ?
C50_1 C49_1 P4_1 119.1(9) . . ?
C50_1 C49_1 C48_1 119.4(11) . . ?
C49_1 C50_1 H50_1 119.5 . . ?
C49_1 C50_1 C51_1 120.9(14) . . ?
C51_1 C50_1 H50_1 119.5 . . ?
C46_1 C51_1 C50_1 119.2(16) . . ?
C46_1 C51_1 H51_1 120.4 . . ?
C50_1 C51_1 H51_1 120.4 . . ?
P4_1 C52_1 H52A_1 109.9 . . ?
P4_1 C52_1 H52B_1 109.9 . . ?
H52A_1 C52_1 H52B_1 108.3 . . ?
C53_1 C52_1 P4_1 108.7(7) . . ?
C53_1 C52_1 H52A_1 109.9 . . ?
C53_1 C52_1 H52B_1 109.9 . . ?
C52_1 C53_1 H53A_1 108.3 . . ?
C52_1 C53_1 H53B_1 108.3 . . ?
C52_1 C53_1 C54_1 115.8(9) . . ?
H53A_1 C53_1 H53B_1 107.4 . . ?
C54_1 C53_1 H53A_1 108.3 . . ?
C54_1 C53_1 H53B_1 108.3 . . ?
P3_1 C54_1 H54A_1 110.2 . . ?
P3_1 C54_1 H54B_1 110.2 . . ?
C53_1 C54_1 P3_1 107.4(7) . . ?
C53_1 C54_1 H54A_1 110.2 . . ?
C53_1 C54_1 H54B_1 110.2 . . ?
H54A_1 C54_1 H54B_1 108.5 . . ?
P2_2 Ag1_2 P1_2 177.36(13) . 2_676 ?
C4_2 P1_2 Ag1_2 116.7(8) . 2_676 ?
C4_2 P1_2 C10_2 103.9(8) . . ?
C4_2 P1_2 C27_2 105.9(7) . . ?
C10_2 P1_2 Ag1_2 115.4(5) . 2_676 ?
C27_2 P1_2 Ag1_2 107.9(5) . 2_676 ?
C27_2 P1_2 C10_2 106.1(7) . . ?
C16_2 P2_2 Ag1_2 109.4(4) . . ?
C16_2 P2_2 C22_2 106.7(6) . . ?
C16_2 P2_2 C25_2 103.1(5) . . ?
C22_2 P2_2 Ag1_2 118.0(5) . . ?
C22_2 P2_2 C25_2 102.0(7) . . ?
C25_2 P2_2 Ag1_2 116.2(4) . . ?
C2_2 C1_2 H1_2 114.1 . . ?
C2_2 C1_2 C6_2 132(3) . . ?
C6_2 C1_2 H1_2 114.1 . . ?
C1_2 C2_2 H2_2 124.6 . . ?
C1_2 C2_2 C3_2 111(3) . . ?
C3_2 C2_2 H2_2 124.6 . . ?
C2_2 C3_2 H3_2 117.4 . . ?
C4_2 C3_2 C2_2 125(2) . . ?
C4_2 C3_2 H3_2 117.4 . . ?
C3_2 C4_2 P1_2 117.7(17) . . ?
C5_2 C4_2 P1_2 124.7(16) . . ?
C5_2 C4_2 C3_2 117.6(18) . . ?
C4_2 C5_2 H5_2 119.0 . . ?
C4_2 C5_2 C6_2 122(2) . . ?
C6_2 C5_2 H5_2 119.0 . . ?
C1_2 C6_2 C5_2 112(3) . . ?
C1_2 C6_2 H6_2 124.0 . . ?
C5_2 C6_2 H6_2 124.0 . . ?
C8_2 C7_2 H7_2 119.4 . . ?
C12_2 C7_2 H7_2 119.4 . . ?
C12_2 C7_2 C8_2 121(2) . . ?
C7_2 C8_2 H8_2 120.7 . . ?
C7_2 C8_2 C9_2 119(2) . . ?
C9_2 C8_2 H8_2 120.7 . . ?
C8_2 C9_2 H9_2 120.2 . . ?
C10_2 C9_2 C8_2 119.5(18) . . ?
C10_2 C9_2 H9_2 120.2 . . ?
C9_2 C10_2 P1_2 121.5(13) . . ?
C11_2 C10_2 P1_2 121.2(12) . . ?
C11_2 C10_2 C9_2 116.2(15) . . ?
C10_2 C11_2 H11_2 117.3 . . ?
C10_2 C11_2 C12_2 125.4(16) . . ?
C12_2 C11_2 H11_2 117.3 . . ?
C7_2 C12_2 C11_2 117.9(18) . . ?
C7_2 C12_2 H12_2 121.0 . . ?
C11_2 C12_2 H12_2 121.0 . . ?
C14_2 C13_2 H13_2 120.4 . . ?
C14_2 C13_2 C18_2 119.3(14) . . ?
C18_2 C13_2 H13_2 120.4 . . ?
C13_2 C14_2 H14_2 119.2 . . ?
C13_2 C14_2 C15_2 121.6(14) . . ?
C15_2 C14_2 H14_2 119.2 . . ?
C14_2 C15_2 H15_2 120.2 . . ?
C14_2 C15_2 C16_2 119.5(12) . . ?
C16_2 C15_2 H15_2 120.2 . . ?
C15_2 C16_2 P2_2 118.8(8) . . ?
C17_2 C16_2 P2_2 121.6(9) . . ?
C17_2 C16_2 C15_2 119.3(11) . . ?
C16_2 C17_2 H17_2 120.5 . . ?
C16_2 C17_2 C18_2 119.1(12) . . ?
C18_2 C17_2 H17_2 120.5 . . ?
C13_2 C18_2 C17_2 121.1(13) . . ?
C13_2 C18_2 H18_2 119.4 . . ?
C17_2 C18_2 H18_2 119.4 . . ?
C20_2 C19_2 H19_2 119.4 . . ?
C20_2 C19_2 C24_2 121.3(18) . . ?
C24_2 C19_2 H19_2 119.4 . . ?
C19_2 C20_2 H20_2 120.2 . . ?
C19_2 C20_2 C21_2 119.6(19) . . ?
C21_2 C20_2 H20_2 120.2 . . ?
C20_2 C21_2 H21_2 119.2 . . ?
C22_2 C21_2 C20_2 121.6(19) . . ?
C22_2 C21_2 H21_2 119.2 . . ?
C21_2 C22_2 P2_2 122.0(14) . . ?
C21_2 C22_2 C23_2 117.7(15) . . ?
C23_2 C22_2 P2_2 120.3(11) . . ?
C22_2 C23_2 H23_2 118.7 . . ?
C22_2 C23_2 C24_2 122.7(18) . . ?
C24_2 C23_2 H23_2 118.7 . . ?
C19_2 C24_2 C23_2 116(2) . . ?
C19_2 C24_2 H24_2 121.8 . . ?
C23_2 C24_2 H24_2 121.8 . . ?
P2_2 C25_2 H25A_2 108.9 . . ?
P2_2 C25_2 H25B_2 108.9 . . ?
H25A_2 C25_2 H25B_2 107.7 . . ?
C26_2 C25_2 P2_2 113.3(8) . . ?
C26_2 C25_2 H25A_2 108.9 . . ?
C26_2 C25_2 H25B_2 108.9 . . ?
C25_2 C26_2 H26A_2 109.2 . . ?
C25_2 C26_2 H26B_2 109.2 . . ?
C25_2 C26_2 C27_2 112.1(10) . . ?
H26A_2 C26_2 H26B_2 107.9 . . ?
C27_2 C26_2 H26A_2 109.2 . . ?
C27_2 C26_2 H26B_2 109.2 . . ?
P1_2 C27_2 H27A_2 108.9 . . ?
P1_2 C27_2 H27B_2 108.9 . . ?
C26_2 C27_2 P1_2 113.3(9) . . ?
C26_2 C27_2 H27A_2 108.9 . . ?
C26_2 C27_2 H27B_2 108.9 . . ?
H27A_2 C27_2 H27B_2 107.7 . . ?
O9_3 Mo1_3 O7_3 87.8(4) . . ?
O9_3 Mo1_3 O16_3 154.8(6) . . ?
O16_3 Mo1_3 O7_3 79.4(5) . . ?
O17_3 Mo1_3 O7_3 101.7(4) . . ?
O17_3 Mo1_3 O9_3 103.8(5) . . ?
O17_3 Mo1_3 O16_3 100.0(5) . . ?
O17_3 Mo1_3 O19_3 102.1(5) . . ?
O19_3 Mo1_3 O7_3 154.5(5) . . ?
O19_3 Mo1_3 O9_3 95.2(6) . . ?
O19_3 Mo1_3 O16_3 87.7(5) . . ?
O13_3 Mo2_3 O2_3 95.8(4) . . ?
O13_3 Mo2_3 O15_3 87.0(3) . . ?
O13_3 Mo2_3 O18_3 154.4(5) . 2_666 ?
O14_3 Mo2_3 O2_3 160.8(5) . . ?
O14_3 Mo2_3 O13_3 101.1(5) . . ?
O14_3 Mo2_3 O15_3 100.1(5) . . ?
O14_3 Mo2_3 O16_3 103.7(7) . . ?
O14_3 Mo2_3 O18_3 102.9(6) . 2_666 ?
O15_3 Mo2_3 O2_3 89.8(3) . . ?
O15_3 Mo2_3 O18_3 80.1(3) . 2_666 ?
O16_3 Mo2_3 O2_3 65.2(6) . . ?
O16_3 Mo2_3 O13_3 95.6(4) . . ?
O16_3 Mo2_3 O15_3 155.1(6) . . ?
O16_3 Mo2_3 O18_3 87.4(4) . 2_666 ?
O18_3 Mo2_3 O2_3 62.4(5) 2_666 . ?
O3_3 Mo3_3 O1_3 36.3(4) . 2_666 ?
O5_3 Mo3_3 O1_3 88.3(5) . 2_666 ?
O5_3 Mo3_3 O3_3 64.0(5) . . ?
O11_3 Mo3_3 O1_3 67.0(3) . 2_666 ?
O11_3 Mo3_3 O3_3 94.2(4) . . ?
O11_3 Mo3_3 O5_3 155.2(5) . . ?
O11_3 Mo3_3 O13_3 88.6(3) . . ?
O11_3 Mo3_3 O21_3 95.0(4) . . ?
O12_3 Mo3_3 O1_3 161.4(6) . 2_666 ?
O12_3 Mo3_3 O3_3 161.8(6) . . ?
O12_3 Mo3_3 O5_3 102.0(6) . . ?
O12_3 Mo3_3 O11_3 101.5(5) . . ?
O12_3 Mo3_3 O13_3 100.8(5) . . ?
O12_3 Mo3_3 O21_3 103.3(7) . . ?
O13_3 Mo3_3 O1_3 65.5(3) . 2_666 ?
O13_3 Mo3_3 O3_3 88.6(4) . . ?
O13_3 Mo3_3 O5_3 79.5(3) . . ?
O21_3 Mo3_3 O1_3 92.7(6) . 2_666 ?
O21_3 Mo3_3 O3_3 65.9(5) . . ?
O21_3 Mo3_3 O5_3 86.9(4) . . ?
O21_3 Mo3_3 O13_3 154.4(5) . . ?
O8_3 Mo4_3 O4_3 64.1(6) 2_666 . ?
O8_3 Mo4_3 O9_3 86.7(4) 2_666 2_666 ?
O8_3 Mo4_3 O11_3 153.2(5) 2_666 . ?
O9_3 Mo4_3 O4_3 64.9(5) 2_666 . ?
O10_3 Mo4_3 O4_3 160.2(5) . . ?
O10_3 Mo4_3 O8_3 103.7(6) . 2_666 ?
O10_3 Mo4_3 O9_3 100.3(6) . 2_666 ?
O10_3 Mo4_3 O11_3 101.0(4) . . ?
O10_3 Mo4_3 O15_3 102.1(5) . . ?
O11_3 Mo4_3 O4_3 89.3(4) . . ?
O11_3 Mo4_3 O9_3 78.9(3) . 2_666 ?
O15_3 Mo4_3 O4_3 95.1(4) . . ?
O15_3 Mo4_3 O8_3 96.8(4) . 2_666 ?
O15_3 Mo4_3 O9_3 155.8(5) . 2_666 ?
O15_3 Mo4_3 O11_3 87.9(3) . . ?
O5_3 Mo5_3 O4_3 98.9(5) . 2_666 ?
O5_3 Mo5_3 O7_3 96.3(5) . . ?
O5_3 Mo5_3 O8_3 153.5(6) . . ?
O5_3 Mo5_3 O22_3 86.1(4) . . ?
O6_3 Mo5_3 O4_3 156.2(4) . 2_666 ?
O6_3 Mo5_3 O5_3 103.5(5) . . ?
O6_3 Mo5_3 O7_3 102.4(5) . . ?
O6_3 Mo5_3 O8_3 101.2(5) . . ?
O6_3 Mo5_3 O22_3 100.6(4) . . ?
O7_3 Mo5_3 O4_3 66.9(4) . 2_666 ?
O7_3 Mo5_3 O8_3 87.5(4) . . ?
O7_3 Mo5_3 O22_3 155.5(5) . . ?
O8_3 Mo5_3 O4_3 58.6(5) . 2_666 ?
O8_3 Mo5_3 O22_3 80.1(5) . . ?
O22_3 Mo5_3 O4_3 88.7(5) . 2_666 ?
O18_3 Mo6_3 O2_3 60.8(5) . 2_666 ?
O18_3 Mo6_3 O19_3 86.9(4) . 2_666 ?
O18_3 Mo6_3 O21_3 155.2(5) . . ?
O19_3 Mo6_3 O2_3 63.5(4) 2_666 2_666 ?
O20_3 Mo6_3 O2_3 155.6(4) . 2_666 ?
O20_3 Mo6_3 O18_3 102.3(5) . . ?
O20_3 Mo6_3 O19_3 100.3(4) . 2_666 ?
O20_3 Mo6_3 O21_3 100.4(5) . . ?
O20_3 Mo6_3 O22_3 102.6(4) . . ?
O21_3 Mo6_3 O2_3 94.5(5) . 2_666 ?
O21_3 Mo6_3 O19_3 79.4(5) . 2_666 ?
O22_3 Mo6_3 O2_3 97.1(5) . 2_666 ?
O22_3 Mo6_3 O18_3 96.8(5) . . ?
O22_3 Mo6_3 O19_3 155.4(5) . 2_666 ?
O22_3 Mo6_3 O21_3 87.8(4) . . ?
O1_3 P1_3 O1_3 180.0 2_666 . ?
O1_3 P1_3 O2_3 66.9(6) . 2_666 ?
O1_3 P1_3 O2_3 66.9(6) 2_666 . ?
O1_3 P1_3 O2_3 113.1(6) . . ?
O1_3 P1_3 O2_3 113.1(6) 2_666 2_666 ?
O1_3 P1_3 O3_3 62.0(7) 2_666 . ?
O1_3 P1_3 O3_3 118.0(7) 2_666 2_666 ?
O1_3 P1_3 O3_3 62.0(7) . 2_666 ?
O1_3 P1_3 O3_3 118.0(7) . . ?
O1_3 P1_3 O4_3 65.4(6) 2_666 . ?
O1_3 P1_3 O4_3 65.4(6) . 2_666 ?
O1_3 P1_3 O4_3 114.6(6) 2_666 2_666 ?
O1_3 P1_3 O4_3 114.6(6) . . ?
O2_3 P1_3 O2_3 180.0 . 2_666 ?
O3_3 P1_3 O2_3 103.3(6) 2_666 2_666 ?
O3_3 P1_3 O2_3 76.7(6) 2_666 . ?
O3_3 P1_3 O2_3 103.3(6) . . ?
O3_3 P1_3 O2_3 76.7(6) . 2_666 ?
O3_3 P1_3 O3_3 180.0 . 2_666 ?
O3_3 P1_3 O4_3 76.6(6) . 2_666 ?
O3_3 P1_3 O4_3 103.4(6) . . ?
O3_3 P1_3 O4_3 76.6(6) 2_666 . ?
O3_3 P1_3 O4_3 103.4(6) 2_666 2_666 ?
O4_3 P1_3 O2_3 102.6(6) 2_666 2_666 ?
O4_3 P1_3 O2_3 77.4(6) . 2_666 ?
O4_3 P1_3 O2_3 77.4(6) 2_666 . ?
O4_3 P1_3 O2_3 102.6(6) . . ?
O4_3 P1_3 O4_3 180.0 . 2_666 ?
P1_3 O1_3 Mo3_3 129.0(7) . 2_666 ?
P1_3 O1_3 O2_3 63.8(6) . 2_666 ?
P1_3 O1_3 O3_3 65.0(7) . 2_666 ?
P1_3 O1_3 O4_3 63.6(6) . 2_666 ?
O2_3 O1_3 Mo3_3 133.1(7) 2_666 2_666 ?
O3_3 O1_3 Mo3_3 64.2(6) 2_666 2_666 ?
O3_3 O1_3 O2_3 103.2(9) 2_666 2_666 ?
O3_3 O1_3 O4_3 104.1(9) 2_666 2_666 ?
O4_3 O1_3 Mo3_3 126.8(7) 2_666 2_666 ?
O4_3 O1_3 O2_3 99.8(8) 2_666 2_666 ?
Mo2_3 O2_3 Mo6_3 97.0(4) . 2_666 ?
P1_3 O2_3 Mo2_3 129.2(5) . . ?
P1_3 O2_3 Mo6_3 118.3(5) . 2_666 ?
P1_3 O2_3 O1_3 49.3(5) . 2_666 ?
O1_3 O2_3 Mo2_3 80.0(6) 2_666 . ?
O1_3 O2_3 Mo6_3 131.9(7) 2_666 2_666 ?
P1_3 O3_3 Mo3_3 132.3(7) . . ?
O1_3 O3_3 Mo3_3 79.5(7) 2_666 . ?
O1_3 O3_3 P1_3 53.0(6) 2_666 . ?
Mo4_3 O4_3 Mo5_3 95.1(4) . 2_666 ?
P1_3 O4_3 Mo4_3 130.3(6) . . ?
P1_3 O4_3 Mo5_3 119.4(6) . 2_666 ?
P1_3 O4_3 O1_3 51.0(6) . 2_666 ?
O1_3 O4_3 Mo4_3 79.6(6) 2_666 . ?
O1_3 O4_3 Mo5_3 141.9(7) 2_666 2_666 ?
Mo5_3 O5_3 Mo3_3 140.0(8) . . ?
Mo5_3 O7_3 Mo1_3 138.8(5) . . ?
Mo4_3 O8_3 Mo5_3 141.4(8) 2_666 . ?
Mo1_3 O9_3 Mo4_3 138.1(7) . 2_666 ?
Mo3_3 O11_3 Mo4_3 138.7(4) . . ?
Mo2_3 O13_3 Mo3_3 139.5(4) . . ?
Mo4_3 O15_3 Mo2_3 139.4(4) . . ?
Mo2_3 O16_3 Mo1_3 140.3(8) . . ?
Mo6_3 O18_3 Mo2_3 139.3(8) . 2_666 ?
Mo1_3 O19_3 Mo6_3 140.2(5) . 2_666 ?
Mo3_3 O21_3 Mo6_3 139.7(7) . . ?
Mo6_3 O22_3 Mo5_3 139.1(5) . . ?
O4_4 Mo1_4 O2_4 41.5(4) . 2_767 ?
O5_4 Mo1_4 O2_4 65.3(4) . 2_767 ?
O5_4 Mo1_4 O4_4 97.1(4) . . ?
O5_4 Mo1_4 O7_4 96.8(5) . 2_767 ?
O5_4 Mo1_4 O8_4 155.5(5) . . ?
O5_4 Mo1_4 O22_4 87.0(4) . . ?
O6_4 Mo1_4 O2_4 157.7(5) . 2_767 ?
O6_4 Mo1_4 O4_4 159.8(4) . . ?
O6_4 Mo1_4 O5_4 101.1(4) . . ?
O6_4 Mo1_4 O7_4 103.5(5) . 2_767 ?
O6_4 Mo1_4 O8_4 101.6(5) . . ?
O6_4 Mo1_4 O22_4 100.4(5) . . ?
O7_4 Mo1_4 O2_4 95.8(5) 2_767 2_767 ?
O7_4 Mo1_4 O4_4 65.3(4) 2_767 . ?
O7_4 Mo1_4 O8_4 86.6(4) 2_767 . ?
O7_4 Mo1_4 O22_4 154.5(5) 2_767 . ?
O8_4 Mo1_4 O2_4 90.2(5) . 2_767 ?
O8_4 Mo1_4 O4_4 62.3(4) . . ?
O22_4 Mo1_4 O2_4 62.8(4) . 2_767 ?
O22_4 Mo1_4 O4_4 89.2(4) . . ?
O22_4 Mo1_4 O8_4 80.1(4) . . ?
O4_4 Mo2_4 O3_4 41.9(4) . 2_767 ?
O8_4 Mo2_4 O3_4 96.4(5) . 2_767 ?
O8_4 Mo2_4 O4_4 64.2(5) . . ?
O8_4 Mo2_4 O9_4 95.9(5) . . ?
O8_4 Mo2_4 O11_4 86.8(4) . 2_767 ?
O8_4 Mo2_4 O12_4 155.0(5) . 2_767 ?
O9_4 Mo2_4 O3_4 64.2(4) . 2_767 ?
O9_4 Mo2_4 O4_4 94.6(5) . . ?
O9_4 Mo2_4 O11_4 153.4(5) . 2_767 ?
O9_4 Mo2_4 O12_4 87.0(4) . 2_767 ?
O10_4 Mo2_4 O3_4 157.5(4) . 2_767 ?
O10_4 Mo2_4 O4_4 159.5(5) . . ?
O10_4 Mo2_4 O8_4 103.9(5) . . ?
O10_4 Mo2_4 O9_4 103.5(5) . . ?
O10_4 Mo2_4 O11_4 101.5(5) . 2_767 ?
O10_4 Mo2_4 O12_4 99.5(4) . 2_767 ?
O11_4 Mo2_4 O3_4 89.2(5) 2_767 2_767 ?
O11_4 Mo2_4 O4_4 62.7(4) 2_767 . ?
O12_4 Mo2_4 O3_4 62.5(4) 2_767 2_767 ?
O12_4 Mo2_4 O4_4 90.8(4) 2_767 . ?
O12_4 Mo2_4 O11_4 80.0(4) 2_767 2_767 ?
O3_4 Mo3_4 O2_4 40.4(4) . 2_767 ?
O5_4 Mo3_4 O2_4 63.6(4) . 2_767 ?
O5_4 Mo3_4 O3_4 89.7(4) . . ?
O12_4 Mo3_4 O2_4 95.9(5) . 2_767 ?
O12_4 Mo3_4 O3_4 65.4(4) . . ?
O12_4 Mo3_4 O5_4 155.0(5) . . ?
O12_4 Mo3_4 O19_4 86.6(4) . 2_767 ?
O13_4 Mo3_4 O2_4 159.5(4) . 2_767 ?
O13_4 Mo3_4 O3_4 158.5(4) . . ?
O13_4 Mo3_4 O5_4 99.9(4) . . ?
O13_4 Mo3_4 O12_4 102.9(5) . . ?
O13_4 Mo3_4 O14_4 103.7(5) . . ?
O13_4 Mo3_4 O19_4 99.7(5) . 2_767 ?
O14_4 Mo3_4 O2_4 65.2(4) . 2_767 ?
O14_4 Mo3_4 O3_4 96.1(5) . . ?
O14_4 Mo3_4 O5_4 86.3(4) . . ?
O14_4 Mo3_4 O12_4 98.0(4) . . ?
O14_4 Mo3_4 O19_4 154.4(5) . 2_767 ?
O19_4 Mo3_4 O2_4 89.4(4) 2_767 2_767 ?
O19_4 Mo3_4 O3_4 62.9(4) 2_767 . ?
O19_4 Mo3_4 O5_4 79.6(4) 2_767 . ?
O1_4 Mo4_4 O2_4 41.0(4) . 2_767 ?
O14_4 Mo4_4 O1_4 90.0(4) . . ?
O14_4 Mo4_4 O2_4 62.3(4) . 2_767 ?
O15_4 Mo4_4 O1_4 161.7(5) . . ?
O15_4 Mo4_4 O2_4 156.7(5) . 2_767 ?
O15_4 Mo4_4 O14_4 100.0(5) . . ?
O15_4 Mo4_4 O16_4 102.5(5) . . ?
O15_4 Mo4_4 O17_4 103.5(5) . . ?
O15_4 Mo4_4 O22_4 101.3(5) . . ?
O16_4 Mo4_4 O1_4 64.0(4) . . ?
O16_4 Mo4_4 O2_4 89.9(5) . 2_767 ?
O16_4 Mo4_4 O14_4 80.1(4) . . ?
O17_4 Mo4_4 O1_4 65.7(4) . . ?
O17_4 Mo4_4 O2_4 96.4(5) . 2_767 ?
O17_4 Mo4_4 O14_4 155.7(5) . . ?
O17_4 Mo4_4 O16_4 88.8(4) . . ?
O17_4 Mo4_4 O22_4 95.7(5) . . ?
O22_4 Mo4_4 O1_4 94.7(4) . . ?
O22_4 Mo4_4 O2_4 64.3(4) . 2_767 ?
O22_4 Mo4_4 O14_4 85.7(4) . . ?
O22_4 Mo4_4 O16_4 154.1(5) . . ?
O1_4 Mo5_4 O3_4 41.3(4) . 2_767 ?
O9_4 Mo5_4 O1_4 88.2(4) . . ?
O9_4 Mo5_4 O3_4 62.6(4) . 2_767 ?
O9_4 Mo5_4 O17_4 78.8(4) . . ?
O17_4 Mo5_4 O1_4 63.0(4) . . ?
O17_4 Mo5_4 O3_4 90.6(4) . 2_767 ?
O18_4 Mo5_4 O1_4 159.9(5) . . ?
O18_4 Mo5_4 O3_4 157.5(5) . 2_767 ?
O18_4 Mo5_4 O9_4 100.2(5) . . ?
O18_4 Mo5_4 O17_4 100.5(5) . . ?
O18_4 Mo5_4 O19_4 102.9(5) . . ?
O18_4 Mo5_4 O20_4 104.5(5) . . ?
O19_4 Mo5_4 O1_4 95.7(5) . . ?
O19_4 Mo5_4 O3_4 63.9(4) . 2_767 ?
O19_4 Mo5_4 O9_4 87.2(4) . . ?
O19_4 Mo5_4 O17_4 154.5(5) . . ?
O19_4 Mo5_4 O20_4 97.0(4) . . ?
O20_4 Mo5_4 O1_4 65.2(4) . . ?
O20_4 Mo5_4 O3_4 95.5(5) . 2_767 ?
O20_4 Mo5_4 O9_4 153.3(5) . . ?
O20_4 Mo5_4 O17_4 86.8(4) . . ?
O1_4 Mo6_4 O4_4 42.8(4) . 2_767 ?
O7_4 Mo6_4 O1_4 90.8(5) . . ?
O7_4 Mo6_4 O4_4 62.6(4) . 2_767 ?
O11_4 Mo6_4 O1_4 96.0(5) . . ?
O11_4 Mo6_4 O4_4 64.0(5) . 2_767 ?
O11_4 Mo6_4 O7_4 86.4(4) . . ?
O11_4 Mo6_4 O20_4 155.1(5) . . ?
O16_4 Mo6_4 O1_4 65.7(4) . . ?
O16_4 Mo6_4 O4_4 97.5(5) . 2_767 ?
O16_4 Mo6_4 O7_4 156.5(5) . . ?
O16_4 Mo6_4 O11_4 96.0(5) . . ?
O16_4 Mo6_4 O20_4 88.6(4) . . ?
O20_4 Mo6_4 O1_4 63.7(4) . . ?
O20_4 Mo6_4 O4_4 91.2(4) . 2_767 ?
O20_4 Mo6_4 O7_4 80.1(4) . . ?
O21_4 Mo6_4 O1_4 159.4(5) . . ?
O21_4 Mo6_4 O4_4 156.6(5) . 2_767 ?
O21_4 Mo6_4 O7_4 98.9(5) . . ?
O21_4 Mo6_4 O11_4 102.8(6) . . ?
O21_4 Mo6_4 O16_4 103.3(5) . . ?
O21_4 Mo6_4 O20_4 99.9(5) . . ?
O1_4 P1_4 O1_4 180.0 2_767 . ?
O1_4 P1_4 O4_4 107.8(6) . . ?
O1_4 P1_4 O4_4 107.8(6) 2_767 2_767 ?
O1_4 P1_4 O4_4 72.2(6) 2_767 . ?
O1_4 P1_4 O4_4 72.2(6) . 2_767 ?
O2_4 P1_4 O1_4 109.7(6) 2_767 2_767 ?
O2_4 P1_4 O1_4 70.3(6) 2_767 . ?
O2_4 P1_4 O1_4 109.7(6) . . ?
O2_4 P1_4 O1_4 70.3(6) . 2_767 ?
O2_4 P1_4 O2_4 179.999(11) . 2_767 ?
O2_4 P1_4 O3_4 111.2(6) . . ?
O2_4 P1_4 O3_4 111.2(6) 2_767 2_767 ?
O2_4 P1_4 O3_4 68.8(6) . 2_767 ?
O2_4 P1_4 O3_4 68.8(6) 2_767 . ?
O2_4 P1_4 O4_4 70.1(6) 2_767 . ?
O2_4 P1_4 O4_4 70.1(6) . 2_767 ?
O2_4 P1_4 O4_4 109.9(6) 2_767 2_767 ?
O2_4 P1_4 O4_4 109.9(6) . . ?
O3_4 P1_4 O1_4 70.7(6) . 2_767 ?
O3_4 P1_4 O1_4 109.3(6) . . ?
O3_4 P1_4 O1_4 109.3(6) 2_767 2_767 ?
O3_4 P1_4 O1_4 70.7(6) 2_767 . ?
O3_4 P1_4 O3_4 180.0 . 2_767 ?
O3_4 P1_4 O4_4 108.9(6) . . ?
O3_4 P1_4 O4_4 71.1(6) 2_767 . ?
O3_4 P1_4 O4_4 71.1(6) . 2_767 ?
O3_4 P1_4 O4_4 108.9(6) 2_767 2_767 ?
O4_4 P1_4 O4_4 180.0 . 2_767 ?
Mo4_4 O1_4 Mo5_4 92.4(4) . . ?
Mo4_4 O1_4 Mo6_4 91.4(4) . . ?
Mo6_4 O1_4 Mo5_4 91.7(4) . . ?
P1_4 O1_4 Mo4_4 124.8(6) . . ?
P1_4 O1_4 Mo5_4 123.9(6) . . ?
P1_4 O1_4 Mo6_4 123.2(6) . . ?
P1_4 O1_4 O2_4 54.3(5) . 2_767 ?
P1_4 O1_4 O3_4 54.3(5) . 2_767 ?
P1_4 O1_4 O4_4 54.5(5) . 2_767 ?
O2_4 O1_4 Mo4_4 70.7(5) 2_767 . ?
O2_4 O1_4 Mo5_4 137.2(7) 2_767 . ?
O2_4 O1_4 Mo6_4 126.5(7) 2_767 . ?
O2_4 O1_4 O3_4 90.6(8) 2_767 2_767 ?
O2_4 O1_4 O4_4 89.4(7) 2_767 2_767 ?
O3_4 O1_4 Mo4_4 129.3(6) 2_767 . ?
O3_4 O1_4 Mo5_4 69.7(5) 2_767 . ?
O3_4 O1_4 Mo6_4 134.3(7) 2_767 . ?
O3_4 O1_4 O4_4 88.5(7) 2_767 2_767 ?
O4_4 O1_4 Mo4_4 135.7(7) 2_767 . ?
O4_4 O1_4 Mo5_4 126.0(6) 2_767 . ?
O4_4 O1_4 Mo6_4 68.9(5) 2_767 . ?
Mo1_4 O2_4 Mo4_4 91.8(4) 2_767 2_767 ?
Mo3_4 O2_4 Mo1_4 92.1(4) 2_767 2_767 ?
Mo3_4 O2_4 Mo4_4 91.6(4) 2_767 2_767 ?
P1_4 O2_4 Mo1_4 123.7(7) . 2_767 ?
P1_4 O2_4 Mo3_4 124.7(6) . 2_767 ?
P1_4 O2_4 Mo4_4 123.5(6) . 2_767 ?
P1_4 O2_4 O1_4 55.4(5) . 2_767 ?
P1_4 O2_4 O3_4 55.8(6) . 2_767 ?
P1_4 O2_4 O4_4 56.1(6) . 2_767 ?
O1_4 O2_4 Mo1_4 134.5(7) 2_767 2_767 ?
O1_4 O2_4 Mo3_4 127.3(7) 2_767 2_767 ?
O1_4 O2_4 Mo4_4 68.3(5) 2_767 2_767 ?
O1_4 O2_4 O4_4 90.4(8) 2_767 2_767 ?
O3_4 O2_4 Mo1_4 126.9(7) 2_767 2_767 ?
O3_4 O2_4 Mo3_4 69.2(6) 2_767 2_767 ?
O3_4 O2_4 Mo4_4 135.9(8) 2_767 2_767 ?
O3_4 O2_4 O1_4 91.8(8) 2_767 2_767 ?
O3_4 O2_4 O4_4 92.1(8) 2_767 2_767 ?
O4_4 O2_4 Mo1_4 67.8(5) 2_767 2_767 ?
O4_4 O2_4 Mo3_4 136.7(7) 2_767 2_767 ?
O4_4 O2_4 Mo4_4 125.4(7) 2_767 2_767 ?
Mo3_4 O3_4 Mo2_4 91.8(4) . 2_767 ?
Mo3_4 O3_4 Mo5_4 92.3(4) . 2_767 ?
Mo5_4 O3_4 Mo2_4 91.3(4) 2_767 2_767 ?
P1_4 O3_4 Mo2_4 122.5(6) . 2_767 ?
P1_4 O3_4 Mo3_4 125.5(6) . . ?
P1_4 O3_4 Mo5_4 123.8(7) . 2_767 ?
P1_4 O3_4 O1_4 55.0(6) . 2_767 ?
P1_4 O3_4 O2_4 55.4(6) . 2_767 ?
P1_4 O3_4 O4_4 55.4(5) . 2_767 ?
O1_4 O3_4 Mo2_4 124.8(6) 2_767 2_767 ?
O1_4 O3_4 Mo3_4 137.8(7) 2_767 . ?
O1_4 O3_4 Mo5_4 69.0(5) 2_767 2_767 ?
O1_4 O3_4 O4_4 89.2(7) 2_767 2_767 ?
O2_4 O3_4 Mo2_4 135.9(8) 2_767 2_767 ?
O2_4 O3_4 Mo3_4 70.3(6) 2_767 . ?
O2_4 O3_4 Mo5_4 128.1(7) 2_767 2_767 ?
O2_4 O3_4 O1_4 91.4(8) 2_767 2_767 ?
O2_4 O3_4 O4_4 91.7(7) 2_767 2_767 ?
O4_4 O3_4 Mo2_4 67.3(5) 2_767 2_767 ?
O4_4 O3_4 Mo3_4 127.6(7) 2_767 . ?
O4_4 O3_4 Mo5_4 133.3(7) 2_767 2_767 ?
Mo1_4 O4_4 Mo2_4 93.1(4) . . ?
Mo1_4 O4_4 Mo6_4 92.8(4) . 2_767 ?
Mo2_4 O4_4 Mo6_4 92.5(4) . 2_767 ?
P1_4 O4_4 Mo1_4 124.2(6) . . ?
P1_4 O4_4 Mo2_4 124.0(6) . . ?
P1_4 O4_4 Mo6_4 121.5(6) . 2_767 ?
P1_4 O4_4 O1_4 53.3(5) . 2_767 ?
P1_4 O4_4 O2_4 53.8(5) . 2_767 ?
P1_4 O4_4 O3_4 53.5(5) . 2_767 ?
O1_4 O4_4 Mo1_4 126.9(7) 2_767 . ?
O1_4 O4_4 Mo2_4 134.9(7) 2_767 . ?
O1_4 O4_4 Mo6_4 68.4(5) 2_767 2_767 ?
O2_4 O4_4 Mo1_4 70.6(5) 2_767 . ?
O2_4 O4_4 Mo2_4 129.0(7) 2_767 . ?
O2_4 O4_4 Mo6_4 134.8(7) 2_767 2_767 ?
O2_4 O4_4 O1_4 88.0(7) 2_767 2_767 ?
O2_4 O4_4 O3_4 89.5(8) 2_767 2_767 ?
O3_4 O4_4 Mo1_4 138.1(7) 2_767 . ?
O3_4 O4_4 Mo2_4 70.8(5) 2_767 . ?
O3_4 O4_4 Mo6_4 125.3(7) 2_767 2_767 ?
O3_4 O4_4 O1_4 87.2(7) 2_767 2_767 ?
Mo1_4 O5_4 Mo3_4 138.5(5) . . ?
Mo1_4 O7_4 Mo6_4 139.0(6) 2_767 . ?
Mo2_4 O8_4 Mo1_4 139.9(7) . . ?
Mo2_4 O9_4 Mo5_4 141.0(6) . . ?
Mo6_4 O11_4 Mo2_4 140.4(7) . 2_767 ?
Mo3_4 O12_4 Mo2_4 139.9(6) . 2_767 ?
Mo3_4 O14_4 Mo4_4 140.7(6) . . ?
Mo6_4 O16_4 Mo4_4 138.1(6) . . ?
Mo4_4 O17_4 Mo5_4 138.3(6) . . ?
Mo5_4 O19_4 Mo3_4 140.2(6) . 2_767 ?
Mo5_4 O20_4 Mo6_4 139.0(6) . . ?
Mo4_4 O22_4 Mo1_4 140.6(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1_1 P1_1 C4_1 C3_1 -7.3(15) . . . . ?
Ag1_1 P1_1 C4_1 C5_1 172.3(13) . . . . ?
Ag1_1 P1_1 C10_1 C9_1 106.5(10) . . . . ?
Ag1_1 P1_1 C10_1 C11_1 -72.8(11) . . . . ?
Ag1_1 P1_1 C27_1 C26_1 -48.9(12) . . . . ?
Ag1_1 P3_1 C31_1 C30_1 107.7(10) . . . . ?
Ag1_1 P3_1 C31_1 C32_1 -65.3(11) . . . . ?
Ag1_1 P3_1 C37_1 C36_1 -179.2(11) . . . . ?
Ag1_1 P3_1 C37_1 C38_1 8.9(17) . . . . ?
Ag1_1 P3_1 C54_1 C53_1 -44.8(8) . . . . ?
Ag2_1 P2_1 C16_1 C15_1 -111.8(7) . . . . ?
Ag2_1 P2_1 C16_1 C17_1 69.4(7) . . . . ?
Ag2_1 P2_1 C22_1 C21_1 162.9(10) . . . . ?
Ag2_1 P2_1 C22_1 C23_1 -16.6(13) . . . . ?
Ag2_1 P2_1 C25_1 C26_1 -46.2(12) . . . . ?
Ag2_1 P4_1 C43_1 C42_1 18.8(10) . . . . ?
Ag2_1 P4_1 C43_1 C44_1 -162.7(9) . . . . ?
Ag2_1 P4_1 C49_1 C48_1 -172.7(8) . . . . ?
Ag2_1 P4_1 C49_1 C50_1 1.3(10) . . . . ?
Ag2_1 P4_1 C52_1 C53_1 66.1(7) . . . . ?
P1_1 C4_1 C5_1 C6_1 -179.9(16) . . . . ?
P1_1 C10_1 C11_1 C12_1 -178.4(13) . . . . ?
P2_1 C16_1 C17_1 C18_1 178.9(9) . . . . ?
P2_1 C22_1 C23_1 C24_1 177.7(13) . . . . ?
P2_1 C25_1 C26_1 C27_1 -174.6(9) . . . . ?
P3_1 C31_1 C32_1 C33_1 171.7(11) . . . . ?
P3_1 C37_1 C38_1 C39_1 173.2(18) . . . . ?
P4_1 C43_1 C44_1 C45_1 -177.1(11) . . . . ?
P4_1 C49_1 C50_1 C51_1 -172.5(10) . . . . ?
P4_1 C52_1 C53_1 C54_1 -156.4(8) . . . . ?
C1_1 C2_1 C3_1 C4_1 -1(3) . . . . ?
C2_1 C1_1 C6_1 C5_1 -3(4) . . . . ?
C2_1 C3_1 C4_1 P1_1 179.8(13) . . . . ?
C2_1 C3_1 C4_1 C5_1 0(3) . . . . ?
C3_1 C4_1 C5_1 C6_1 0(3) . . . . ?
C4_1 P1_1 C10_1 C9_1 -18.6(12) . . . . ?
C4_1 P1_1 C10_1 C11_1 162.2(11) . . . . ?
C4_1 P1_1 C27_1 C26_1 76.7(11) . . . . ?
C4_1 C5_1 C6_1 C1_1 1(3) . . . . ?
C6_1 C1_1 C2_1 C3_1 3(4) . . . . ?
C7_1 C8_1 C9_1 C10_1 -4(2) . . . . ?
C8_1 C7_1 C12_1 C11_1 -3(3) . . . . ?
C8_1 C9_1 C10_1 P1_1 -178.9(10) . . . . ?
C8_1 C9_1 C10_1 C11_1 0(2) . . . . ?
C9_1 C10_1 C11_1 C12_1 2(2) . . . . ?
C10_1 P1_1 C4_1 C3_1 117.0(13) . . . . ?
C10_1 P1_1 C4_1 C5_1 -63.4(16) . . . . ?
C10_1 P1_1 C27_1 C26_1 -171.3(10) . . . . ?
C10_1 C11_1 C12_1 C7_1 -1(3) . . . . ?
C12_1 C7_1 C8_1 C9_1 6(3) . . . . ?
C13_1 C14_1 C15_1 C16_1 0.0 . . . . ?
C14_1 C13_1 C18_1 C17_1 0.0 . . . . ?
C14_1 C15_1 C16_1 P2_1 -178.8(9) . . . . ?
C14_1 C15_1 C16_1 C17_1 0.0 . . . . ?
C15_1 C16_1 C17_1 C18_1 0.0 . . . . ?
C16_1 P2_1 C22_1 C21_1 -62.1(12) . . . . ?
C16_1 P2_1 C22_1 C23_1 118.5(12) . . . . ?
C16_1 P2_1 C25_1 C26_1 -178.6(11) . . . . ?
C16_1 C17_1 C18_1 C13_1 0.0 . . . . ?
C18_1 C13_1 C14_1 C15_1 0.0 . . . . ?
C19_1 C20_1 C21_1 C22_1 -3(3) . . . . ?
C20_1 C19_1 C24_1 C23_1 1(3) . . . . ?
C20_1 C21_1 C22_1 P2_1 -176.3(12) . . . . ?
C20_1 C21_1 C22_1 C23_1 3(2) . . . . ?
C21_1 C22_1 C23_1 C24_1 -2(2) . . . . ?
C22_1 P2_1 C16_1 C15_1 121.8(8) . . . . ?
C22_1 P2_1 C16_1 C17_1 -57.1(8) . . . . ?
C22_1 P2_1 C25_1 C26_1 71.6(12) . . . . ?
C22_1 C23_1 C24_1 C19_1 0(3) . . . . ?
C24_1 C19_1 C20_1 C21_1 0(3) . . . . ?
C25_1 P2_1 C16_1 C15_1 9.5(9) . . . . ?
C25_1 P2_1 C16_1 C17_1 -169.3(8) . . . . ?
C25_1 P2_1 C22_1 C21_1 47.0(13) . . . . ?
C25_1 P2_1 C22_1 C23_1 -132.4(12) . . . . ?
C25_1 C26_1 C27_1 P1_1 -85.4(15) . . . . ?
C27_1 P1_1 C4_1 C3_1 -133.4(13) . . . . ?
C27_1 P1_1 C4_1 C5_1 46.3(16) . . . . ?
C27_1 P1_1 C10_1 C9_1 -129.8(11) . . . . ?
C27_1 P1_1 C10_1 C11_1 50.9(12) . . . . ?
C28_1 C29_1 C30_1 C31_1 -1(2) . . . . ?
C29_1 C28_1 C33_1 C32_1 -1(2) . . . . ?
C29_1 C30_1 C31_1 P3_1 -171.4(11) . . . . ?
C29_1 C30_1 C31_1 C32_1 2(2) . . . . ?
C30_1 C31_1 C32_1 C33_1 -2(2) . . . . ?
C31_1 P3_1 C37_1 C36_1 -58.3(14) . . . . ?
C31_1 P3_1 C37_1 C38_1 129.8(15) . . . . ?
C31_1 P3_1 C54_1 C53_1 -162.6(7) . . . . ?
C31_1 C32_1 C33_1 C28_1 1(2) . . . . ?
C33_1 C28_1 C29_1 C30_1 1(2) . . . . ?
C34_1 C35_1 C36_1 C37_1 2(3) . . . . ?
C35_1 C34_1 C39_1 C38_1 -7(5) . . . . ?
C35_1 C36_1 C37_1 P3_1 -176.8(13) . . . . ?
C35_1 C36_1 C37_1 C38_1 -5(3) . . . . ?
C36_1 C37_1 C38_1 C39_1 1(3) . . . . ?
C37_1 P3_1 C31_1 C30_1 -20.2(12) . . . . ?
C37_1 P3_1 C31_1 C32_1 166.7(10) . . . . ?
C37_1 P3_1 C54_1 C53_1 83.1(9) . . . . ?
C37_1 C38_1 C39_1 C34_1 5(4) . . . . ?
C39_1 C34_1 C35_1 C36_1 4(4) . . . . ?
C40_1 C41_1 C42_1 C43_1 0(2) . . . . ?
C41_1 C40_1 C45_1 C44_1 2(3) . . . . ?
C41_1 C42_1 C43_1 P4_1 178.3(10) . . . . ?
C41_1 C42_1 C43_1 C44_1 -0.3(18) . . . . ?
C42_1 C43_1 C44_1 C45_1 1.5(19) . . . . ?
C43_1 P4_1 C49_1 C48_1 -52.6(10) . . . . ?
C43_1 P4_1 C49_1 C50_1 121.5(10) . . . . ?
C43_1 P4_1 C52_1 C53_1 -57.3(8) . . . . ?
C43_1 C44_1 C45_1 C40_1 -2(2) . . . . ?
C45_1 C40_1 C41_1 C42_1 -1(2) . . . . ?
C46_1 C47_1 C48_1 C49_1 2(2) . . . . ?
C47_1 C46_1 C51_1 C50_1 2(2) . . . . ?
C47_1 C48_1 C49_1 P4_1 172.3(9) . . . . ?
C47_1 C48_1 C49_1 C50_1 -1.7(17) . . . . ?
C48_1 C49_1 C50_1 C51_1 1.6(19) . . . . ?
C49_1 P4_1 C43_1 C42_1 -101.0(9) . . . . ?
C49_1 P4_1 C43_1 C44_1 77.5(10) . . . . ?
C49_1 P4_1 C52_1 C53_1 -168.7(7) . . . . ?
C49_1 C50_1 C51_1 C46_1 -2(2) . . . . ?
C51_1 C46_1 C47_1 C48_1 -2(2) . . . . ?
C52_1 P4_1 C43_1 C42_1 144.6(9) . . . . ?
C52_1 P4_1 C43_1 C44_1 -36.9(11) . . . . ?
C52_1 P4_1 C49_1 C48_1 59.5(10) . . . . ?
C52_1 P4_1 C49_1 C50_1 -126.5(9) . . . . ?
C52_1 C53_1 C54_1 P3_1 -175.8(8) . . . . ?
C54_1 P3_1 C31_1 C30_1 -132.7(11) . . . . ?
C54_1 P3_1 C31_1 C32_1 54.2(11) . . . . ?
C54_1 P3_1 C37_1 C36_1 58.3(14) . . . . ?
C54_1 P3_1 C37_1 C38_1 -113.6(15) . . . . ?
Ag1_2 P1_2 C4_2 C3_2 -33.3(18) 2_676 . . . ?
Ag1_2 P1_2 C4_2 C5_2 144.3(19) 2_676 . . . ?
Ag1_2 P1_2 C10_2 C9_2 126.4(14) 2_676 . . . ?
Ag1_2 P1_2 C10_2 C11_2 -41.3(18) 2_676 . . . ?
Ag1_2 P1_2 C27_2 C26_2 41.3(11) 2_676 . . . ?
Ag1_2 P2_2 C16_2 C15_2 -73.2(11) . . . . ?
Ag1_2 P2_2 C16_2 C17_2 100.8(11) . . . . ?
Ag1_2 P2_2 C22_2 C21_2 0.6(15) . . . . ?
Ag1_2 P2_2 C22_2 C23_2 -179.4(11) . . . . ?
Ag1_2 P2_2 C25_2 C26_2 -60.8(10) . . . . ?
P1_2 C4_2 C5_2 C6_2 177(2) . . . . ?
P1_2 C10_2 C11_2 C12_2 -179.4(16) . . . . ?
P2_2 C16_2 C17_2 C18_2 -175.8(11) . . . . ?
P2_2 C22_2 C23_2 C24_2 -175.5(14) . . . . ?
P2_2 C25_2 C26_2 C27_2 -176.3(10) . . . . ?
C1_2 C2_2 C3_2 C4_2 0(4) . . . . ?
C2_2 C1_2 C6_2 C5_2 -5(5) . . . . ?
C2_2 C3_2 C4_2 P1_2 180(2) . . . . ?
C2_2 C3_2 C4_2 C5_2 2(4) . . . . ?
C3_2 C4_2 C5_2 C6_2 -5(4) . . . . ?
C4_2 P1_2 C10_2 C9_2 -2.7(18) . . . . ?
C4_2 P1_2 C10_2 C11_2 -170.4(17) . . . . ?
C4_2 P1_2 C27_2 C26_2 166.9(12) . . . . ?
C4_2 C5_2 C6_2 C1_2 6(4) . . . . ?
C6_2 C1_2 C2_2 C3_2 3(5) . . . . ?
C7_2 C8_2 C9_2 C10_2 -3(3) . . . . ?
C8_2 C7_2 C12_2 C11_2 -1(4) . . . . ?
C8_2 C9_2 C10_2 P1_2 -174.1(16) . . . . ?
C8_2 C9_2 C10_2 C11_2 -6(3) . . . . ?
C9_2 C10_2 C11_2 C12_2 12(3) . . . . ?
C10_2 P1_2 C4_2 C3_2 95.0(17) . . . . ?
C10_2 P1_2 C4_2 C5_2 -87(2) . . . . ?
C10_2 P1_2 C27_2 C26_2 -83.0(12) . . . . ?
C10_2 C11_2 C12_2 C7_2 -9(3) . . . . ?
C12_2 C7_2 C8_2 C9_2 7(4) . . . . ?
C13_2 C14_2 C15_2 C16_2 -1(2) . . . . ?
C14_2 C13_2 C18_2 C17_2 1(3) . . . . ?
C14_2 C15_2 C16_2 P2_2 176.7(11) . . . . ?
C14_2 C15_2 C16_2 C17_2 3(2) . . . . ?
C15_2 C16_2 C17_2 C18_2 -2(2) . . . . ?
C16_2 P2_2 C22_2 C21_2 124.2(13) . . . . ?
C16_2 P2_2 C22_2 C23_2 -55.9(14) . . . . ?
C16_2 P2_2 C25_2 C26_2 179.6(10) . . . . ?
C16_2 C17_2 C18_2 C13_2 0(2) . . . . ?
C18_2 C13_2 C14_2 C15_2 0(3) . . . . ?
C19_2 C20_2 C21_2 C22_2 -3(3) . . . . ?
C20_2 C19_2 C24_2 C23_2 -8(3) . . . . ?
C20_2 C21_2 C22_2 P2_2 176.5(14) . . . . ?
C20_2 C21_2 C22_2 C23_2 -4(2) . . . . ?
C21_2 C22_2 C23_2 C24_2 4(3) . . . . ?
C22_2 P2_2 C16_2 C15_2 158.0(11) . . . . ?
C22_2 P2_2 C16_2 C17_2 -28.0(13) . . . . ?
C22_2 P2_2 C25_2 C26_2 69.0(11) . . . . ?
C22_2 C23_2 C24_2 C19_2 1(3) . . . . ?
C24_2 C19_2 C20_2 C21_2 9(3) . . . . ?
C25_2 P2_2 C16_2 C15_2 51.0(12) . . . . ?
C25_2 P2_2 C16_2 C17_2 -135.0(11) . . . . ?
C25_2 P2_2 C22_2 C21_2 -128.0(13) . . . . ?
C25_2 P2_2 C22_2 C23_2 52.0(14) . . . . ?
C25_2 C26_2 C27_2 P1_2 -169.4(10) . . . . ?
C27_2 P1_2 C4_2 C3_2 -153.4(16) . . . . ?
C27_2 P1_2 C4_2 C5_2 24(2) . . . . ?
C27_2 P1_2 C10_2 C9_2 -114.1(16) . . . . ?
C27_2 P1_2 C10_2 C11_2 78.2(17) . . . . ?
O1_3 Mo3_3 O11_3 Mo4_3 -13.5(6) 2_666 . . . ?
O1_3 Mo3_3 O21_3 Mo6_3 35.6(9) 2_666 . . . ?
O1_3 P1_3 O2_3 Mo2_3 -174.4(7) . . . . ?
O1_3 P1_3 O2_3 Mo2_3 5.6(7) 2_666 . . . ?
O1_3 P1_3 O2_3 Mo6_3 57.4(8) . . . 2_666 ?
O1_3 P1_3 O2_3 Mo6_3 -122.6(8) 2_666 . . 2_666 ?
O1_3 P1_3 O2_3 O1_3 180.003(6) . . . 2_666 ?
O1_3 P1_3 O3_3 Mo3_3 -174.5(7) . . . . ?
O1_3 P1_3 O3_3 Mo3_3 5.5(7) 2_666 . . . ?
O1_3 P1_3 O3_3 O1_3 179.999(6) . . . 2_666 ?
O1_3 P1_3 O4_3 Mo4_3 -172.8(7) . . . . ?
O1_3 P1_3 O4_3 Mo4_3 7.2(7) 2_666 . . . ?
O1_3 P1_3 O4_3 Mo5_3 -45.1(8) . . . 2_666 ?
O1_3 P1_3 O4_3 Mo5_3 134.9(8) 2_666 . . 2_666 ?
O1_3 P1_3 O4_3 O1_3 179.998(1) . . . 2_666 ?
O2_3 Mo2_3 O13_3 Mo3_3 -36.6(7) . . . . ?
O2_3 Mo2_3 O16_3 Mo1_3 8.6(10) . . . . ?
O2_3 Mo6_3 O18_3 Mo2_3 -7.9(7) 2_666 . . 2_666 ?
O2_3 Mo6_3 O22_3 Mo5_3 39.8(11) 2_666 . . . ?
O2_3 P1_3 O1_3 Mo3_3 -54.5(9) . . . 2_666 ?
O2_3 P1_3 O1_3 Mo3_3 125.5(9) 2_666 . . 2_666 ?
O2_3 P1_3 O1_3 O2_3 180.001(5) . . . 2_666 ?
O2_3 P1_3 O1_3 O3_3 120.7(8) 2_666 . . 2_666 ?
O2_3 P1_3 O1_3 O3_3 -59.3(8) . . . 2_666 ?
O2_3 P1_3 O1_3 O4_3 -117.1(7) 2_666 . . 2_666 ?
O2_3 P1_3 O1_3 O4_3 62.9(7) . . . 2_666 ?
O2_3 P1_3 O3_3 Mo3_3 59.8(9) . . . . ?
O2_3 P1_3 O3_3 Mo3_3 -120.1(9) 2_666 . . . ?
O2_3 P1_3 O3_3 O1_3 -125.7(7) 2_666 . . 2_666 ?
O2_3 P1_3 O3_3 O1_3 54.3(7) . . . 2_666 ?
O2_3 P1_3 O4_3 Mo4_3 130.3(8) 2_666 . . . ?
O2_3 P1_3 O4_3 Mo4_3 -49.7(8) . . . . ?
O2_3 P1_3 O4_3 Mo5_3 77.9(7) . . . 2_666 ?
O2_3 P1_3 O4_3 Mo5_3 -102.1(7) 2_666 . . 2_666 ?
O2_3 P1_3 O4_3 O1_3 123.0(6) 2_666 . . 2_666 ?
O2_3 P1_3 O4_3 O1_3 -57.0(6) . . . 2_666 ?
O3_3 Mo3_3 O11_3 Mo4_3 -38.1(7) . . . . ?
O3_3 Mo3_3 O21_3 Mo6_3 10.3(8) . . . . ?
O3_3 P1_3 O1_3 Mo3_3 -175.2(6) . . . 2_666 ?
O3_3 P1_3 O1_3 Mo3_3 4.8(6) 2_666 . . 2_666 ?
O3_3 P1_3 O1_3 O2_3 -120.7(8) 2_666 . . 2_666 ?
O3_3 P1_3 O1_3 O2_3 59.3(8) . . . 2_666 ?
O3_3 P1_3 O1_3 O3_3 180.002(6) . . . 2_666 ?
O3_3 P1_3 O1_3 O4_3 -57.9(8) . . . 2_666 ?
O3_3 P1_3 O1_3 O4_3 122.1(8) 2_666 . . 2_666 ?
O3_3 P1_3 O2_3 Mo2_3 -45.7(9) . . . . ?
O3_3 P1_3 O2_3 Mo2_3 134.3(9) 2_666 . . . ?
O3_3 P1_3 O2_3 Mo6_3 6.1(6) 2_666 . . 2_666 ?
O3_3 P1_3 O2_3 Mo6_3 -173.9(6) . . . 2_666 ?
O3_3 P1_3 O2_3 O1_3 -51.3(7) . . . 2_666 ?
O3_3 P1_3 O2_3 O1_3 128.7(7) 2_666 . . 2_666 ?
O3_3 P1_3 O4_3 Mo4_3 -122.5(9) 2_666 . . . ?
O3_3 P1_3 O4_3 Mo4_3 57.5(9) . . . . ?
O3_3 P1_3 O4_3 Mo5_3 -174.8(6) . . . 2_666 ?
O3_3 P1_3 O4_3 Mo5_3 5.2(6) 2_666 . . 2_666 ?
O3_3 P1_3 O4_3 O1_3 -129.7(7) 2_666 . . 2_666 ?
O3_3 P1_3 O4_3 O1_3 50.3(7) . . . 2_666 ?
O4_3 Mo4_3 O15_3 Mo2_3 -34.8(6) . . . . ?
O4_3 Mo5_3 O5_3 Mo3_3 34.1(8) 2_666 . . . ?
O4_3 Mo5_3 O7_3 Mo1_3 -4.7(10) 2_666 . . . ?
O4_3 P1_3 O1_3 Mo3_3 62.6(9) . . . 2_666 ?
O4_3 P1_3 O1_3 Mo3_3 -117.4(9) 2_666 . . 2_666 ?
O4_3 P1_3 O1_3 O2_3 -62.8(7) . . . 2_666 ?
O4_3 P1_3 O1_3 O2_3 117.1(7) 2_666 . . 2_666 ?
O4_3 P1_3 O1_3 O3_3 -122.1(8) 2_666 . . 2_666 ?
O4_3 P1_3 O1_3 O3_3 57.9(8) . . . 2_666 ?
O4_3 P1_3 O1_3 O4_3 180.003(1) . . . 2_666 ?
O4_3 P1_3 O2_3 Mo2_3 61.6(8) . . . . ?
O4_3 P1_3 O2_3 Mo2_3 -118.4(8) 2_666 . . . ?
O4_3 P1_3 O2_3 Mo6_3 113.5(7) 2_666 . . 2_666 ?
O4_3 P1_3 O2_3 Mo6_3 -66.5(7) . . . 2_666 ?
O4_3 P1_3 O2_3 O1_3 -124.0(7) 2_666 . . 2_666 ?
O4_3 P1_3 O2_3 O1_3 56.0(7) . . . 2_666 ?
O4_3 P1_3 O3_3 Mo3_3 133.2(9) 2_666 . . . ?
O4_3 P1_3 O3_3 Mo3_3 -46.8(9) . . . . ?
O4_3 P1_3 O3_3 O1_3 127.7(7) 2_666 . . 2_666 ?
O4_3 P1_3 O3_3 O1_3 -52.3(7) . . . 2_666 ?
O5_3 Mo3_3 O11_3 Mo4_3 -10.6(13) . . . . ?
O5_3 Mo3_3 O21_3 Mo6_3 -52.5(10) . . . . ?
O5_3 Mo5_3 O7_3 Mo1_3 -101.7(12) . . . . ?
O6_3 Mo5_3 O5_3 Mo3_3 -153.9(8) . . . . ?
O6_3 Mo5_3 O7_3 Mo1_3 153.0(12) . . . . ?
O7_3 Mo1_3 O9_3 Mo4_3 54.3(9) . . . 2_666 ?
O7_3 Mo1_3 O19_3 Mo6_3 8(2) . . . 2_666 ?
O7_3 Mo5_3 O5_3 Mo3_3 101.6(8) . . . . ?
O8_3 Mo4_3 O15_3 Mo2_3 -99.3(7) 2_666 . . . ?
O8_3 Mo5_3 O5_3 Mo3_3 4.5(15) . . . . ?
O8_3 Mo5_3 O7_3 Mo1_3 52.1(13) . . . . ?
O9_3 Mo1_3 O19_3 Mo6_3 103.4(14) . . . 2_666 ?
O9_3 Mo4_3 O15_3 Mo2_3 -2.1(12) 2_666 . . . ?
O10_3 Mo4_3 O15_3 Mo2_3 155.1(6) . . . . ?
O11_3 Mo3_3 O21_3 Mo6_3 102.7(9) . . . . ?
O11_3 Mo4_3 O15_3 Mo2_3 54.3(6) . . . . ?
O12_3 Mo3_3 O11_3 Mo4_3 151.1(7) . . . . ?
O12_3 Mo3_3 O21_3 Mo6_3 -154.2(9) . . . . ?
O13_3 Mo2_3 O16_3 Mo1_3 102.4(11) . . . . ?
O13_3 Mo3_3 O11_3 Mo4_3 50.4(6) . . . . ?
O13_3 Mo3_3 O21_3 Mo6_3 5.3(16) . . . . ?
O14_3 Mo2_3 O13_3 Mo3_3 152.7(7) . . . . ?
O14_3 Mo2_3 O16_3 Mo1_3 -154.7(11) . . . . ?
O15_3 Mo2_3 O13_3 Mo3_3 53.0(6) . . . . ?
O15_3 Mo2_3 O16_3 Mo1_3 7.5(19) . . . . ?
O16_3 Mo1_3 O9_3 Mo4_3 -4.8(17) . . . 2_666 ?
O16_3 Mo1_3 O19_3 Mo6_3 -51.5(14) . . . 2_666 ?
O16_3 Mo2_3 O13_3 Mo3_3 -102.2(8) . . . . ?
O17_3 Mo1_3 O9_3 Mo4_3 155.8(8) . . . 2_666 ?
O17_3 Mo1_3 O19_3 Mo6_3 -151.2(13) . . . 2_666 ?
O18_3 Mo2_3 O13_3 Mo3_3 -6.4(13) 2_666 . . . ?
O18_3 Mo2_3 O16_3 Mo1_3 -52.1(12) 2_666 . . . ?
O18_3 Mo6_3 O22_3 Mo5_3 101.0(11) . . . . ?
O19_3 Mo1_3 O9_3 Mo4_3 -100.4(9) . . . 2_666 ?
O19_3 Mo6_3 O18_3 Mo2_3 53.3(9) 2_666 . . 2_666 ?
O19_3 Mo6_3 O22_3 Mo5_3 4(2) 2_666 . . . ?
O20_3 Mo6_3 O18_3 Mo2_3 153.2(9) . . . 2_666 ?
O20_3 Mo6_3 O22_3 Mo5_3 -154.8(10) . . . . ?
O21_3 Mo3_3 O11_3 Mo4_3 -104.2(8) . . . . ?
O21_3 Mo6_3 O18_3 Mo2_3 -2.8(17) . . . 2_666 ?
O21_3 Mo6_3 O22_3 Mo5_3 -54.6(11) . . . . ?
O22_3 Mo5_3 O5_3 Mo3_3 -53.9(8) . . . . ?
O22_3 Mo5_3 O7_3 Mo1_3 -7(2) . . . . ?
O22_3 Mo6_3 O18_3 Mo2_3 -102.3(9) . . . 2_666 ?
O1_4 Mo4_4 O17_4 Mo5_4 8.9(8) . . . . ?
O1_4 Mo4_4 O22_4 Mo1_4 -36.9(9) . . . . ?
O1_4 Mo5_4 O19_4 Mo3_4 -36.2(9) . . . 2_767 ?
O1_4 Mo5_4 O20_4 Mo6_4 7.2(8) . . . . ?
O1_4 Mo6_4 O11_4 Mo2_4 -36.3(10) . . . 2_767 ?
O1_4 Mo6_4 O16_4 Mo4_4 9.5(8) . . . . ?
O1_4 P1_4 O2_4 Mo1_4 124.3(8) 2_767 . . 2_767 ?
O1_4 P1_4 O2_4 Mo1_4 -55.7(8) . . . 2_767 ?
O1_4 P1_4 O2_4 Mo3_4 -114.7(9) 2_767 . . 2_767 ?
O1_4 P1_4 O2_4 Mo3_4 65.3(9) . . . 2_767 ?
O1_4 P1_4 O2_4 Mo4_4 5.2(6) 2_767 . . 2_767 ?
O1_4 P1_4 O2_4 Mo4_4 -174.8(6) . . . 2_767 ?
O1_4 P1_4 O2_4 O1_4 179.997(6) . . . 2_767 ?
O1_4 P1_4 O2_4 O3_4 59.0(7) . . . 2_767 ?
O1_4 P1_4 O2_4 O3_4 -121.0(7) 2_767 . . 2_767 ?
O1_4 P1_4 O2_4 O4_4 -61.6(7) . . . 2_767 ?
O1_4 P1_4 O2_4 O4_4 118.4(7) 2_767 . . 2_767 ?
O1_4 P1_4 O3_4 Mo2_4 -112.3(8) 2_767 . . 2_767 ?
O1_4 P1_4 O3_4 Mo2_4 67.7(8) . . . 2_767 ?
O1_4 P1_4 O3_4 Mo3_4 -52.3(9) . . . . ?
O1_4 P1_4 O3_4 Mo3_4 127.7(9) 2_767 . . . ?
O1_4 P1_4 O3_4 Mo5_4 -174.8(6) . . . 2_767 ?
O1_4 P1_4 O3_4 Mo5_4 5.2(6) 2_767 . . 2_767 ?
O1_4 P1_4 O3_4 O1_4 180.002(3) . . . 2_767 ?
O1_4 P1_4 O3_4 O2_4 121.2(7) 2_767 . . 2_767 ?
O1_4 P1_4 O3_4 O2_4 -58.8(7) . . . 2_767 ?
O1_4 P1_4 O3_4 O4_4 -117.5(7) 2_767 . . 2_767 ?
O1_4 P1_4 O3_4 O4_4 62.5(7) . . . 2_767 ?
O1_4 P1_4 O4_4 Mo1_4 -113.5(8) 2_767 . . . ?
O1_4 P1_4 O4_4 Mo1_4 66.5(8) . . . . ?
O1_4 P1_4 O4_4 Mo2_4 -56.0(8) . . . . ?
O1_4 P1_4 O4_4 Mo2_4 124.0(8) 2_767 . . . ?
O1_4 P1_4 O4_4 Mo6_4 5.6(6) 2_767 . . 2_767 ?
O1_4 P1_4 O4_4 Mo6_4 -174.4(6) . . . 2_767 ?
O1_4 P1_4 O4_4 O1_4 180.001(8) . . . 2_767 ?
O1_4 P1_4 O4_4 O2_4 60.5(7) . . . 2_767 ?
O1_4 P1_4 O4_4 O2_4 -119.5(7) 2_767 . . 2_767 ?
O1_4 P1_4 O4_4 O3_4 118.5(7) 2_767 . . 2_767 ?
O1_4 P1_4 O4_4 O3_4 -61.5(7) . . . 2_767 ?
O2_4 Mo1_4 O5_4 Mo3_4 -7.8(7) 2_767 . . . ?
O2_4 Mo3_4 O12_4 Mo2_4 34.3(9) 2_767 . . 2_767 ?
O2_4 Mo3_4 O14_4 Mo4_4 -6.0(7) 2_767 . . . ?
O2_4 Mo4_4 O17_4 Mo5_4 36.8(10) 2_767 . . . ?
O2_4 Mo4_4 O22_4 Mo1_4 -8.5(8) 2_767 . . . ?
O2_4 P1_4 O1_4 Mo4_4 -174.6(7) . . . . ?
O2_4 P1_4 O1_4 Mo4_4 5.4(7) 2_767 . . . ?
O2_4 P1_4 O1_4 Mo5_4 -52.6(8) . . . . ?
O2_4 P1_4 O1_4 Mo5_4 127.4(8) 2_767 . . . ?
O2_4 P1_4 O1_4 Mo6_4 66.1(8) . . . . ?
O2_4 P1_4 O1_4 Mo6_4 -113.9(8) 2_767 . . . ?
O2_4 P1_4 O1_4 O2_4 180.001(6) . . . 2_767 ?
O2_4 P1_4 O1_4 O3_4 122.1(7) 2_767 . . 2_767 ?
O2_4 P1_4 O1_4 O3_4 -57.9(7) . . . 2_767 ?
O2_4 P1_4 O1_4 O4_4 60.3(7) . . . 2_767 ?
O2_4 P1_4 O1_4 O4_4 -119.7(7) 2_767 . . 2_767 ?
O2_4 P1_4 O3_4 Mo2_4 126.5(9) 2_767 . . 2_767 ?
O2_4 P1_4 O3_4 Mo2_4 -53.5(9) . . . 2_767 ?
O2_4 P1_4 O3_4 Mo3_4 -173.6(7) . . . . ?
O2_4 P1_4 O3_4 Mo3_4 6.4(7) 2_767 . . . ?
O2_4 P1_4 O3_4 Mo5_4 63.9(9) . . . 2_767 ?
O2_4 P1_4 O3_4 Mo5_4 -116.1(9) 2_767 . . 2_767 ?
O2_4 P1_4 O3_4 O1_4 58.8(7) . . . 2_767 ?
O2_4 P1_4 O3_4 O1_4 -121.2(7) 2_767 . . 2_767 ?
O2_4 P1_4 O3_4 O2_4 179.999(11) . . . 2_767 ?
O2_4 P1_4 O3_4 O4_4 121.2(7) 2_767 . . 2_767 ?
O2_4 P1_4 O3_4 O4_4 -58.8(7) . . . 2_767 ?
O2_4 P1_4 O4_4 Mo1_4 6.0(6) 2_767 . . . ?
O2_4 P1_4 O4_4 Mo1_4 -174.0(6) . . . . ?
O2_4 P1_4 O4_4 Mo2_4 -116.5(8) 2_767 . . . ?
O2_4 P1_4 O4_4 Mo2_4 63.5(8) . . . . ?
O2_4 P1_4 O4_4 Mo6_4 125.1(8) 2_767 . . 2_767 ?
O2_4 P1_4 O4_4 Mo6_4 -54.9(8) . . . 2_767 ?
O2_4 P1_4 O4_4 O1_4 -60.5(7) . . . 2_767 ?
O2_4 P1_4 O4_4 O1_4 119.5(7) 2_767 . . 2_767 ?
O2_4 P1_4 O4_4 O2_4 180.000(19) . . . 2_767 ?
O2_4 P1_4 O4_4 O3_4 58.0(7) . . . 2_767 ?
O2_4 P1_4 O4_4 O3_4 -122.0(7) 2_767 . . 2_767 ?
O3_4 Mo2_4 O8_4 Mo1_4 35.2(10) 2_767 . . . ?
O3_4 Mo2_4 O9_4 Mo5_4 -10.0(8) 2_767 . . . ?
O3_4 Mo3_4 O12_4 Mo2_4 6.9(8) . . . 2_767 ?
O3_4 Mo3_4 O14_4 Mo4_4 -32.8(9) . . . . ?
O3_4 Mo5_4 O19_4 Mo3_4 -9.0(8) 2_767 . . 2_767 ?
O3_4 Mo5_4 O20_4 Mo6_4 36.0(10) 2_767 . . . ?
O3_4 P1_4 O1_4 Mo4_4 63.2(8) . . . . ?
O3_4 P1_4 O1_4 Mo4_4 -116.7(8) 2_767 . . . ?
O3_4 P1_4 O1_4 Mo5_4 5.2(6) 2_767 . . . ?
O3_4 P1_4 O1_4 Mo5_4 -174.8(6) . . . . ?
O3_4 P1_4 O1_4 Mo6_4 -56.1(8) . . . . ?
O3_4 P1_4 O1_4 Mo6_4 123.9(8) 2_767 . . . ?
O3_4 P1_4 O1_4 O2_4 -122.1(7) 2_767 . . 2_767 ?
O3_4 P1_4 O1_4 O2_4 57.9(7) . . . 2_767 ?
O3_4 P1_4 O1_4 O3_4 179.997(3) . . . 2_767 ?
O3_4 P1_4 O1_4 O4_4 -61.8(7) . . . 2_767 ?
O3_4 P1_4 O1_4 O4_4 118.2(7) 2_767 . . 2_767 ?
O3_4 P1_4 O2_4 Mo1_4 65.3(9) . . . 2_767 ?
O3_4 P1_4 O2_4 Mo1_4 -114.7(9) 2_767 . . 2_767 ?
O3_4 P1_4 O2_4 Mo3_4 -173.7(7) . . . 2_767 ?
O3_4 P1_4 O2_4 Mo3_4 6.3(7) 2_767 . . 2_767 ?
O3_4 P1_4 O2_4 Mo4_4 126.2(9) 2_767 . . 2_767 ?
O3_4 P1_4 O2_4 Mo4_4 -53.7(9) . . . 2_767 ?
O3_4 P1_4 O2_4 O1_4 121.0(7) 2_767 . . 2_767 ?
O3_4 P1_4 O2_4 O1_4 -59.0(7) . . . 2_767 ?
O3_4 P1_4 O2_4 O3_4 180.003(10) . . . 2_767 ?
O3_4 P1_4 O2_4 O4_4 59.4(7) . . . 2_767 ?
O3_4 P1_4 O2_4 O4_4 -120.6(7) 2_767 . . 2_767 ?
O3_4 P1_4 O4_4 Mo1_4 -52.0(8) . . . . ?
O3_4 P1_4 O4_4 Mo1_4 128.0(8) 2_767 . . . ?
O3_4 P1_4 O4_4 Mo2_4 -174.5(6) . . . . ?
O3_4 P1_4 O4_4 Mo2_4 5.5(6) 2_767 . . . ?
O3_4 P1_4 O4_4 Mo6_4 67.1(8) . . . 2_767 ?
O3_4 P1_4 O4_4 Mo6_4 -112.9(8) 2_767 . . 2_767 ?
O3_4 P1_4 O4_4 O1_4 -118.5(7) 2_767 . . 2_767 ?
O3_4 P1_4 O4_4 O1_4 61.5(7) . . . 2_767 ?
O3_4 P1_4 O4_4 O2_4 122.0(7) 2_767 . . 2_767 ?
O3_4 P1_4 O4_4 O2_4 -58.0(7) . . . 2_767 ?
O3_4 P1_4 O4_4 O3_4 180.000(7) . . . 2_767 ?
O4_4 Mo1_4 O5_4 Mo3_4 -35.2(9) . . . . ?
O4_4 Mo2_4 O8_4 Mo1_4 7.6(8) . . . . ?
O4_4 Mo2_4 O9_4 Mo5_4 -39.8(10) . . . . ?
O4_4 Mo6_4 O11_4 Mo2_4 -7.1(9) 2_767 . . 2_767 ?
O4_4 Mo6_4 O16_4 Mo4_4 38.9(10) 2_767 . . . ?
O4_4 P1_4 O1_4 Mo4_4 125.0(8) 2_767 . . . ?
O4_4 P1_4 O1_4 Mo4_4 -55.0(8) . . . . ?
O4_4 P1_4 O1_4 Mo5_4 -113.0(8) 2_767 . . . ?
O4_4 P1_4 O1_4 Mo5_4 67.0(8) . . . . ?
O4_4 P1_4 O1_4 Mo6_4 -174.3(6) . . . . ?
O4_4 P1_4 O1_4 Mo6_4 5.7(6) 2_767 . . . ?
O4_4 P1_4 O1_4 O2_4 119.7(7) 2_767 . . 2_767 ?
O4_4 P1_4 O1_4 O2_4 -60.3(7) . . . 2_767 ?
O4_4 P1_4 O1_4 O3_4 61.8(7) . . . 2_767 ?
O4_4 P1_4 O1_4 O3_4 -118.2(7) 2_767 . . 2_767 ?
O4_4 P1_4 O1_4 O4_4 180.001(9) . . . 2_767 ?
O4_4 P1_4 O2_4 Mo1_4 -174.1(6) . . . 2_767 ?
O4_4 P1_4 O2_4 Mo1_4 5.9(6) 2_767 . . 2_767 ?
O4_4 P1_4 O2_4 Mo3_4 126.9(9) 2_767 . . 2_767 ?
O4_4 P1_4 O2_4 Mo3_4 -53.1(9) . . . 2_767 ?
O4_4 P1_4 O2_4 Mo4_4 66.9(8) . . . 2_767 ?
O4_4 P1_4 O2_4 Mo4_4 -113.1(8) 2_767 . . 2_767 ?
O4_4 P1_4 O2_4 O1_4 61.6(7) . . . 2_767 ?
O4_4 P1_4 O2_4 O1_4 -118.4(7) 2_767 . . 2_767 ?
O4_4 P1_4 O2_4 O3_4 120.6(7) 2_767 . . 2_767 ?
O4_4 P1_4 O2_4 O3_4 -59.4(7) . . . 2_767 ?
O4_4 P1_4 O2_4 O4_4 179.998(18) . . . 2_767 ?
O4_4 P1_4 O3_4 Mo2_4 5.3(6) 2_767 . . 2_767 ?
O4_4 P1_4 O3_4 Mo2_4 -174.7(6) . . . 2_767 ?
O4_4 P1_4 O3_4 Mo3_4 -114.8(9) 2_767 . . . ?
O4_4 P1_4 O3_4 Mo3_4 65.2(9) . . . . ?
O4_4 P1_4 O3_4 Mo5_4 -57.3(8) . . . 2_767 ?
O4_4 P1_4 O3_4 Mo5_4 122.7(8) 2_767 . . 2_767 ?
O4_4 P1_4 O3_4 O1_4 117.5(6) 2_767 . . 2_767 ?
O4_4 P1_4 O3_4 O1_4 -62.4(6) . . . 2_767 ?
O4_4 P1_4 O3_4 O2_4 58.8(7) . . . 2_767 ?
O4_4 P1_4 O3_4 O2_4 -121.2(7) 2_767 . . 2_767 ?
O4_4 P1_4 O3_4 O4_4 180.001(7) . . . 2_767 ?
O5_4 Mo3_4 O12_4 Mo2_4 1.4(17) . . . 2_767 ?
O5_4 Mo3_4 O14_4 Mo4_4 56.5(9) . . . . ?
O6_4 Mo1_4 O5_4 Mo3_4 153.6(8) . . . . ?
O7_4 Mo1_4 O5_4 Mo3_4 -101.1(9) 2_767 . . . ?
O7_4 Mo6_4 O11_4 Mo2_4 54.1(10) . . . 2_767 ?
O7_4 Mo6_4 O16_4 Mo4_4 8.6(18) . . . . ?
O8_4 Mo1_4 O5_4 Mo3_4 -4.1(16) . . . . ?
O8_4 Mo2_4 O9_4 Mo5_4 -104.3(10) . . . . ?
O9_4 Mo2_4 O8_4 Mo1_4 99.8(10) . . . . ?
O9_4 Mo5_4 O19_4 Mo3_4 51.8(9) . . . 2_767 ?
O9_4 Mo5_4 O20_4 Mo6_4 2.6(17) . . . . ?
O10_4 Mo2_4 O8_4 Mo1_4 -154.6(10) . . . . ?
O10_4 Mo2_4 O9_4 Mo5_4 149.8(9) . . . . ?
O11_4 Mo2_4 O8_4 Mo1_4 -53.6(10) 2_767 . . . ?
O11_4 Mo2_4 O9_4 Mo5_4 -9.6(17) 2_767 . . . ?
O11_4 Mo6_4 O16_4 Mo4_4 103.3(10) . . . . ?
O12_4 Mo2_4 O8_4 Mo1_4 4.3(18) 2_767 . . . ?
O12_4 Mo2_4 O9_4 Mo5_4 50.7(10) 2_767 . . . ?
O12_4 Mo3_4 O14_4 Mo4_4 -98.8(9) . . . . ?
O13_4 Mo3_4 O12_4 Mo2_4 -153.9(9) . . . 2_767 ?
O13_4 Mo3_4 O14_4 Mo4_4 155.8(8) . . . . ?
O14_4 Mo3_4 O12_4 Mo2_4 99.9(9) . . . 2_767 ?
O14_4 Mo4_4 O17_4 Mo5_4 9.2(17) . . . . ?
O14_4 Mo4_4 O22_4 Mo1_4 52.7(9) . . . . ?
O15_4 Mo4_4 O17_4 Mo5_4 -155.5(9) . . . . ?
O15_4 Mo4_4 O22_4 Mo1_4 152.1(9) . . . . ?
O16_4 Mo4_4 O17_4 Mo5_4 -53.0(10) . . . . ?
O16_4 Mo4_4 O22_4 Mo1_4 -3.9(17) . . . . ?
O16_4 Mo6_4 O11_4 Mo2_4 -102.5(10) . . . 2_767 ?
O17_4 Mo4_4 O22_4 Mo1_4 -102.9(9) . . . . ?
O17_4 Mo5_4 O19_4 Mo3_4 -4.5(16) . . . 2_767 ?
O17_4 Mo5_4 O20_4 Mo6_4 -54.4(10) . . . . ?
O18_4 Mo5_4 O19_4 Mo3_4 151.6(9) . . . 2_767 ?
O18_4 Mo5_4 O20_4 Mo6_4 -154.4(9) . . . . ?
O19_4 Mo3_4 O12_4 Mo2_4 -54.8(9) 2_767 . . 2_767 ?
O19_4 Mo3_4 O14_4 Mo4_4 0.2(16) 2_767 . . . ?
O19_4 Mo5_4 O20_4 Mo6_4 100.3(10) . . . . ?
O20_4 Mo5_4 O19_4 Mo3_4 -101.8(9) . . . 2_767 ?
O20_4 Mo6_4 O11_4 Mo2_4 -2.7(18) . . . 2_767 ?
O20_4 Mo6_4 O16_4 Mo4_4 -52.2(10) . . . . ?
O21_4 Mo6_4 O11_4 Mo2_4 152.4(10) . . . 2_767 ?
O21_4 Mo6_4 O16_4 Mo4_4 -152.0(9) . . . . ?
O22_4 Mo1_4 O5_4 Mo3_4 53.6(8) . . . . ?
O22_4 Mo4_4 O17_4 Mo5_4 101.4(9) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
