# Supplementary Information (SI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_20210406chen_czpz1280_0m
_database_code_depnum_ccdc_archive 'CCDC 2371317'
loop_
_audit_author_name
_audit_author_address
'Tingting Cao'
; State Key Laboratory of Crystal Materials and school of Crystal Materials, Shandong University
China
;
_audit_update_record             
;
2024-07-16 deposited with the CCDC.	2024-09-24 downloaded from the CCDC.
;
_audit_creation_date             2024-07-16
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Lu2 O6 Te'
_chemical_formula_sum            'Lu2 O6 Te'
_chemical_formula_weight         573.54
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Lu Lu -0.4720 5.8584 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           150
_space_group_name_H-M_alt        'P 3 2 1'
_space_group_name_Hall           'P 3 2"'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'

_cell_length_a                   8.9459(2)
_cell_length_b                   8.9459(2)
_cell_length_c                   5.0618(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     350.82(2)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    5778
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      38.944
_cell_measurement_theta_min      2.629
_shelx_estimated_absorpt_T_max   0.086
_shelx_estimated_absorpt_T_min   0.069
_exptl_absorpt_coefficient_mu    48.020
_exptl_absorpt_correction_T_max  0.0436
_exptl_absorpt_correction_T_min  0.0029
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1702 before and 0.0865 after correction.
The Ratio of minimum to maximum transmission is 0.0665.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    8.144
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             726
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0560
_diffrn_reflns_av_unetI/netI     0.0384
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            5398
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         36.298
_diffrn_reflns_theta_min         2.629
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.737
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.998
_reflns_number_gt                1138
_reflns_number_total             1143
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         6.826
_refine_diff_density_min         -4.529
_refine_diff_density_rms         1.105
_refine_ls_abs_structure_details 
;
 Flack x determined using 480 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.019(12)
_refine_ls_extinction_coef       0.126(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.151
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         1143
_refine_ls_number_restraints     42
_refine_ls_R_factor_all          0.0362
_refine_ls_R_factor_gt           0.0359
_refine_ls_restrained_S_all      1.115
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0817P)²+7.7071P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0912
_refine_ls_wR_factor_ref         0.0917
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(Lu2) \\sim Ueq, Uanis(Lu1) \\sim Ueq, Uanis(Te2) \\sim Ueq, Uanis(Te1)
\\sim Ueq, Uanis(O1) \\sim Ueq, Uanis(O2) \\sim Ueq, Uanis(O3) \\sim Ueq: with
sigma of 0.005 and sigma for terminal atoms of 0.01
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Lu2 Lu 0.000000 0.28395(17) 0.500000 0.0082(4) Uani 1 2 d S TU P . .
Lu1 Lu 0.37918(18) 0.37918(18) 0.000000 0.0078(5) Uani 1 2 d S TU P . .
Te2 Te 0.000000 0.000000 0.000000 0.0073(6) Uani 1 6 d S TU P . .
Te1 Te 0.333333 0.666667 0.4985(5) 0.0069(5) Uani 1 3 d S TU P . .
O1 O 0.238(3) 0.463(3) 0.282(3) 0.011(3) Uani 1 1 d . U . . .
O2 O 0.133(3) 0.543(3) 0.714(3) 0.009(3) Uani 1 1 d . U . . .
O3 O -0.121(3) 0.080(3) 0.212(3) 0.011(3) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Lu2 Lu1 3.9354(18) 3_566 ?
Lu2 Lu1 3.9354(18) 3_565 ?
Lu2 Te2 3.5858(11) . ?
Lu2 Te2 3.5858(11) 1_556 ?
Lu2 Te1 3.2256(9) . ?
Lu2 Te1 3.2256(9) 4_456 ?
Lu2 O1 2.21(2) . ?
Lu2 O1 2.21(2) 6_556 ?
Lu2 O2 2.28(2) . ?
Lu2 O2 2.282(19) 6_556 ?
Lu2 O3 2.16(2) . ?
Lu2 O3 2.158(19) 6_556 ?
Lu1 Te2 3.3921(16) . ?
Lu1 O1 2.27(2) . ?
Lu1 O1 2.27(2) 4 ?
Lu1 O2 2.193(18) 5_666 ?
Lu1 O2 2.193(18) 2_664 ?
Lu1 O3 2.31(2) 3 ?
Lu1 O3 2.31(2) 6 ?
Te2 O3 1.90(2) 2 ?
Te2 O3 1.90(2) 5 ?
Te2 O3 1.90(2) 6 ?
Te2 O3 1.90(2) . ?
Te2 O3 1.90(2) 3 ?
Te2 O3 1.90(2) 4 ?
Te1 O1 1.922(19) 2_665 ?
Te1 O1 1.922(19) 3_565 ?
Te1 O1 1.922(19) . ?
Te1 O2 1.910(19) . ?
Te1 O2 1.910(19) 3_565 ?
Te1 O2 1.910(19) 2_665 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Lu1 Lu2 Lu1 80.05(4) 3_566 3_565 ?
Te2 Lu2 Lu1 175.13(4) 1_556 3_565 ?
Te2 Lu2 Lu1 95.081(15) 1_556 3_566 ?
Te2 Lu2 Lu1 95.081(15) . 3_565 ?
Te2 Lu2 Lu1 175.13(4) . 3_566 ?
Te2 Lu2 Te2 89.79(4) . 1_556 ?
Te1 Lu2 Lu1 62.78(4) . 3_566 ?
Te1 Lu2 Lu1 62.59(4) 4_456 3_566 ?
Te1 Lu2 Lu1 62.78(4) 4_456 3_565 ?
Te1 Lu2 Lu1 62.59(4) . 3_565 ?
Te1 Lu2 Te2 115.22(4) . 1_556 ?
Te1 Lu2 Te2 115.22(4) 4_456 . ?
Te1 Lu2 Te2 115.01(4) . . ?
Te1 Lu2 Te2 115.01(4) 4_456 1_556 ?
Te1 Lu2 Te1 106.38(4) 4_456 . ?
O1 Lu2 Lu1 59.7(6) . 3_565 ?
O1 Lu2 Lu1 97.8(5) . 3_566 ?
O1 Lu2 Lu1 59.7(6) 6_556 3_566 ?
O1 Lu2 Lu1 97.8(5) 6_556 3_565 ?
O1 Lu2 Te2 121.5(6) 6_556 . ?
O1 Lu2 Te2 79.6(5) 6_556 1_556 ?
O1 Lu2 Te2 79.6(5) . . ?
O1 Lu2 Te2 121.5(6) . 1_556 ?
O1 Lu2 Te1 35.6(5) . . ?
O1 Lu2 Te1 121.6(6) 6_556 . ?
O1 Lu2 Te1 35.6(5) 6_556 4_456 ?
O1 Lu2 Te1 121.6(6) . 4_456 ?
O1 Lu2 O1 152.0(12) 6_556 . ?
O1 Lu2 O2 87.5(8) . 6_556 ?
O1 Lu2 O2 87.5(8) 6_556 . ?
O1 Lu2 O2 71.2(6) 6_556 6_556 ?
O1 Lu2 O2 71.2(6) . . ?
O2 Lu2 Lu1 27.8(5) . 3_566 ?
O2 Lu2 Lu1 74.1(5) . 3_565 ?
O2 Lu2 Lu1 27.8(5) 6_556 3_565 ?
O2 Lu2 Lu1 74.1(5) 6_556 3_566 ?
O2 Lu2 Te2 101.6(5) 6_556 . ?
O2 Lu2 Te2 150.5(5) . . ?
O2 Lu2 Te2 101.6(5) . 1_556 ?
O2 Lu2 Te2 150.5(5) 6_556 1_556 ?
O2 Lu2 Te1 84.6(5) . 4_456 ?
O2 Lu2 Te1 35.7(5) . . ?
O2 Lu2 Te1 84.6(5) 6_556 . ?
O2 Lu2 Te1 35.7(5) 6_556 4_456 ?
O2 Lu2 O2 81.7(10) . 6_556 ?
O3 Lu2 Lu1 152.9(6) . 3_566 ?
O3 Lu2 Lu1 91.2(5) . 3_565 ?
O3 Lu2 Lu1 91.2(5) 6_556 3_566 ?
O3 Lu2 Lu1 152.9(6) 6_556 3_565 ?
O3 Lu2 Te2 93.1(5) 6_556 . ?
O3 Lu2 Te2 26.1(6) 6_556 1_556 ?
O3 Lu2 Te2 26.1(6) . . ?
O3 Lu2 Te2 93.1(5) . 1_556 ?
O3 Lu2 Te1 90.5(6) 6_556 . ?
O3 Lu2 Te1 134.8(5) . . ?
O3 Lu2 Te1 134.8(5) 6_556 4_456 ?
O3 Lu2 Te1 90.5(6) . 4_456 ?
O3 Lu2 O1 96.7(8) . 6_556 ?
O3 Lu2 O1 99.9(7) . . ?
O3 Lu2 O1 99.9(7) 6_556 6_556 ?
O3 Lu2 O1 96.7(8) 6_556 . ?
O3 Lu2 O2 165.2(7) . . ?
O3 Lu2 O2 86.2(7) . 6_556 ?
O3 Lu2 O2 86.2(7) 6_556 . ?
O3 Lu2 O2 165.2(7) 6_556 6_556 ?
O3 Lu2 O3 106.9(11) . 6_556 ?
Lu2 Lu1 Lu2 80.05(4) 2_665 2_664 ?
Te2 Lu1 Lu2 139.98(2) . 2_665 ?
Te2 Lu1 Lu2 139.98(2) . 2_664 ?
O1 Lu1 Lu2 71.4(5) . 2_665 ?
O1 Lu1 Lu2 71.4(5) 4 2_664 ?
O1 Lu1 Lu2 119.5(5) . 2_664 ?
O1 Lu1 Lu2 119.5(5) 4 2_665 ?
O1 Lu1 Te2 83.5(5) . . ?
O1 Lu1 Te2 83.5(5) 4 . ?
O1 Lu1 O1 167.0(10) . 4 ?
O1 Lu1 O3 79.4(7) 4 6 ?
O1 Lu1 O3 89.6(7) 4 3 ?
O1 Lu1 O3 79.4(7) . 3 ?
O1 Lu1 O3 89.6(7) . 6 ?
O2 Lu1 Lu2 88.6(5) 5_666 2_664 ?
O2 Lu1 Lu2 29.1(5) 5_666 2_665 ?
O2 Lu1 Lu2 88.6(5) 2_664 2_665 ?
O2 Lu1 Lu2 29.1(5) 2_664 2_664 ?
O2 Lu1 Te2 125.9(5) 5_666 . ?
O2 Lu1 Te2 125.9(5) 2_664 . ?
O2 Lu1 O1 90.6(7) 2_664 4 ?
O2 Lu1 O1 97.1(7) 2_664 . ?
O2 Lu1 O1 97.1(7) 5_666 4 ?
O2 Lu1 O1 90.6(7) 5_666 . ?
O2 Lu1 O2 108.1(10) 5_666 2_664 ?
O2 Lu1 O3 93.6(7) 2_664 6 ?
O2 Lu1 O3 158.1(7) 5_666 6 ?
O2 Lu1 O3 93.6(7) 5_666 3 ?
O2 Lu1 O3 158.1(7) 2_664 3 ?
O3 Lu1 Lu2 110.3(5) 6 2_664 ?
O3 Lu1 Lu2 161.0(5) 6 2_665 ?
O3 Lu1 Lu2 110.3(5) 3 2_665 ?
O3 Lu1 Lu2 161.0(5) 3 2_664 ?
O3 Lu1 Te2 32.4(5) 6 . ?
O3 Lu1 Te2 32.4(5) 3 . ?
O3 Lu1 O3 64.9(10) 6 3 ?
Lu2 Te2 Lu2 138.511(13) . 2_554 ?
Lu2 Te2 Lu2 75.68(3) . 3 ?
Lu2 Te2 Lu2 138.511(13) 2_554 3 ?
Lu1 Te2 Lu2 69.256(7) . . ?
Lu1 Te2 Lu2 69.256(7) 3 2_554 ?
Lu1 Te2 Lu2 69.256(7) . 3 ?
Lu1 Te2 Lu2 135.105(18) 3 . ?
Lu1 Te2 Lu2 69.256(7) 2 2_554 ?
Lu1 Te2 Lu2 69.256(7) 2 . ?
Lu1 Te2 Lu2 69.256(7) 3 3 ?
Lu1 Te2 Lu2 135.105(18) . 2_554 ?
Lu1 Te2 Lu2 135.105(18) 2 3 ?
Lu1 Te2 Lu1 120.0 3 2 ?
Lu1 Te2 Lu1 120.0 . 3 ?
Lu1 Te2 Lu1 120.0 . 2 ?
O3 Te2 Lu2 29.9(6) . . ?
O3 Te2 Lu2 62.1(6) 2 3 ?
O3 Te2 Lu2 29.9(6) 3 3 ?
O3 Te2 Lu2 62.1(6) 3 . ?
O3 Te2 Lu2 86.0(6) 2 2_554 ?
O3 Te2 Lu2 109.2(6) 5 . ?
O3 Te2 Lu2 86.0(6) 4 3 ?
O3 Te2 Lu2 159.4(6) 4 . ?
O3 Te2 Lu2 98.0(6) 6 2_554 ?
O3 Te2 Lu2 86.0(6) 6 . ?
O3 Te2 Lu2 98.0(6) . 3 ?
O3 Te2 Lu2 98.0(6) 2 . ?
O3 Te2 Lu2 159.4(6) 5 3 ?
O3 Te2 Lu2 109.2(6) . 2_554 ?
O3 Te2 Lu2 109.2(6) 6 3 ?
O3 Te2 Lu2 159.4(6) 3 2_554 ?
O3 Te2 Lu2 62.1(6) 4 2_554 ?
O3 Te2 Lu2 29.9(6) 5 2_554 ?
O3 Te2 Lu1 95.6(6) . . ?
O3 Te2 Lu1 95.6(6) 3 3 ?
O3 Te2 Lu1 40.7(6) 3 . ?
O3 Te2 Lu1 131.3(6) 4 2 ?
O3 Te2 Lu1 95.6(6) 2 2 ?
O3 Te2 Lu1 95.6(6) 5 3 ?
O3 Te2 Lu1 131.3(6) 3 2 ?
O3 Te2 Lu1 40.7(6) 4 3 ?
O3 Te2 Lu1 95.6(6) 6 2 ?
O3 Te2 Lu1 131.3(6) 6 3 ?
O3 Te2 Lu1 40.7(6) 5 2 ?
O3 Te2 Lu1 40.7(6) 2 3 ?
O3 Te2 Lu1 131.3(6) 5 . ?
O3 Te2 Lu1 131.3(6) 2 . ?
O3 Te2 Lu1 95.6(6) 4 . ?
O3 Te2 Lu1 131.3(6) . 3 ?
O3 Te2 Lu1 40.7(6) 6 . ?
O3 Te2 Lu1 40.7(6) . 2 ?
O3 Te2 O3 91.2(8) . 2 ?
O3 Te2 O3 97.4(12) 3 4 ?
O3 Te2 O3 91.2(8) 5 6 ?
O3 Te2 O3 91.2(8) 3 2 ?
O3 Te2 O3 97.4(12) . 6 ?
O3 Te2 O3 81.3(12) 4 2 ?
O3 Te2 O3 168.7(12) . 4 ?
O3 Te2 O3 168.7(12) 6 2 ?
O3 Te2 O3 91.2(8) 5 4 ?
O3 Te2 O3 91.2(8) . 3 ?
O3 Te2 O3 81.3(12) 3 6 ?
O3 Te2 O3 81.3(12) . 5 ?
O3 Te2 O3 91.2(8) 4 6 ?
O3 Te2 O3 168.7(12) 3 5 ?
O3 Te2 O3 97.4(12) 5 2 ?
Lu2 Te1 Lu2 120.0 . 2_665 ?
Lu2 Te1 Lu2 120.0 3_565 . ?
Lu2 Te1 Lu2 120.0 3_565 2_665 ?
O1 Te1 Lu2 42.1(6) 3_565 3_565 ?
O1 Te1 Lu2 42.1(6) 2_665 2_665 ?
O1 Te1 Lu2 93.9(7) 2_665 3_565 ?
O1 Te1 Lu2 132.7(7) 3_565 2_665 ?
O1 Te1 Lu2 132.7(7) . 3_565 ?
O1 Te1 Lu2 93.9(7) . 2_665 ?
O1 Te1 Lu2 93.9(7) 3_565 . ?
O1 Te1 Lu2 42.1(6) . . ?
O1 Te1 Lu2 132.7(7) 2_665 . ?
O1 Te1 O1 90.8(8) 3_565 2_665 ?
O1 Te1 O1 90.8(8) 2_665 . ?
O1 Te1 O1 90.8(8) 3_565 . ?
O2 Te1 Lu2 44.1(6) 3_565 3_565 ?
O2 Te1 Lu2 44.1(6) . . ?
O2 Te1 Lu2 90.5(6) 3_565 2_665 ?
O2 Te1 Lu2 90.5(6) . 3_565 ?
O2 Te1 Lu2 90.5(6) 2_665 . ?
O2 Te1 Lu2 134.8(6) 2_665 3_565 ?
O2 Te1 Lu2 44.1(6) 2_665 2_665 ?
O2 Te1 Lu2 134.8(6) 3_565 . ?
O2 Te1 Lu2 134.8(6) . 2_665 ?
O2 Te1 O1 175.5(9) 2_665 3_565 ?
O2 Te1 O1 86.2(8) 3_565 3_565 ?
O2 Te1 O1 86.2(8) . . ?
O2 Te1 O1 92.5(8) 3_565 2_665 ?
O2 Te1 O1 175.5(9) 3_565 . ?
O2 Te1 O1 175.6(9) . 2_665 ?
O2 Te1 O1 92.5(8) . 3_565 ?
O2 Te1 O1 86.2(8) 2_665 2_665 ?
O2 Te1 O1 92.5(8) 2_665 . ?
O2 Te1 O2 90.7(8) . 2_665 ?
O2 Te1 O2 90.7(8) 3_565 2_665 ?
O2 Te1 O2 90.7(8) 3_565 . ?
Lu2 O1 Lu1 124.6(9) . . ?
Te1 O1 Lu2 102.3(8) . . ?
Te1 O1 Lu1 128.0(11) . . ?
Lu1 O2 Lu2 123.1(9) 3_566 . ?
Te1 O2 Lu2 100.2(7) . . ?
Te1 O2 Lu1 134.0(10) . 3_566 ?
Lu2 O3 Lu1 125.3(10) . 2 ?
Te2 O3 Lu2 124.0(10) . . ?
Te2 O3 Lu1 106.9(8) . 2 ?

_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT971_20210406chen_czpz1280_0m 
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PROBLEM: Check Calcd Resid. Dens.  0.62Ang From Lu2             7.01 eA-3  
RESPONSE: Through crystal refinement, R1 has been reduced to a reasonable
 range. This indicates that there are no significant issues with the crystal
 structure. The residual electron density around Lu, Te, and O atoms is to some
 extent caused by the heavy atom effect of Lu and Te.
;
_vrf_PLAT972_20210406chen_czpz1280_0m 
;
PROBLEM: Check Calcd Resid. Dens.  0.70Ang From Lu2            -3.61 eA-3  
RESPONSE: Through crystal refinement, R1 has been reduced to a reasonable
 range. This indicates that there are no significant issues with the crystal
 structure. The residual electron density around Lu, Te, and O atoms is to some
 extent caused by the heavy atom effect of Lu and Te.
;
# end Validation Reply Form
