File Name : figs1.tif

Caption : fig. s1 theoretical powder diffraction patterns generated from single-crystal x-ray diffraction data for cbz(ii) (1, ccdc number 1121423) [m. m. j. lowes, m. r. caira, a. p. lötter and j. g. van der watt, j pharm sci, 1987, 76, 744–752], cbz : 0.33h2o hydrate (2, ccdc number 905203) [r. prohens, m. font-bardia and r. barbas, crystengcomm, 2013, 15, 845–847], cbz : 0.17h2o hydrate (3, ccdc number 1494538) [p. p. nievergelt and b. spingler, crystengcomm, 2017, 19, 142–147]  and solvate cbz with thf (4, ccdc number 641710) [f. p. a. fabbiani, l. t. byrne, j. j. mckinnon and m. a. spackman, crystengcomm, 2007, 9, 728-731].

File Name : figs2.tiff

Caption : fig. s2 rietveld refinement plot for experiment on dissolution of cbz (iii) in palmitic acid and its recrystallization into cbz (ii) (fig. 3a, exp. 1 in the main text). r=4.21%, wr=6.43%. qualitative composition (weight fraction): palmitic acid – 48%, cbz (iii) – 37% cbz (ii) – 15%.

File Name : figs3.tiff

Caption : fig. s3 rietveld refinement plot for experiment on dissolution of cbz (iii) in palmitic acid and its recrystallization into cbz (ii) (fig. 3b, exp. 2 in the main text). r=4.30%, wr=6.11%. qualitative composition (weight fraction): palmitic acid – 96%, cbz (ii) – 4%.

File Name : figs4.tiff

Caption : fig. s4 rietveld refinement plot for experiment on dissolution of cbz (iii) in palmitic acid and its recrystallization into cbz (ii) (exp. 3 in the main text). r=5.06%, wr=7.72%. qualitative composition (weight fraction): palmitic acid – 88%, cbz (ii) – 12%.