# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aghypro1
_database_code_depnum_ccdc_archive 'CCDC 2331721'
loop_
_audit_author_name
_audit_author_address
'Robert Gyepes'
;Department of Inorganic Chemistry, Charles University, Prague
Czech Republic
;
_audit_update_record             
;
2024-02-08 deposited with the CCDC.	2024-04-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C10 H18 Ag2 N4 O12'
_chemical_formula_sum            'C10 H18 Ag2 N4 O12'
_chemical_formula_weight         602.02

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   5.5261(4)
_cell_length_b                   11.2082(8)
_cell_length_c                   14.0565(12)
_cell_angle_alpha                90
_cell_angle_beta                 97.992(3)
_cell_angle_gamma                90
_cell_volume                     862.17(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    9960
_cell_measurement_theta_min      2.9267
_cell_measurement_theta_max      26.4481

_exptl_crystal_description       fragment
_exptl_crystal_colour            'translucent colourless'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.319
_exptl_crystal_F_000             592
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.171
_exptl_crystal_size_mid          0.162
_exptl_crystal_size_min          0.058
_exptl_absorpt_coefficient_mu    2.346
_shelx_estimated_absorpt_T_min   0.690
_shelx_estimated_absorpt_T_max   0.876
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_process_details   
;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10.
doi:10.1107/S1600576714022985
;
_exptl_absorpt_correction_T_min  0.72
_exptl_absorpt_correction_T_max  0.88
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            31594
_diffrn_reflns_av_unetI/netI     0.0222
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.333
_diffrn_reflns_theta_max         26.489
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             3526
_reflns_number_gt                3461
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.896
_reflns_Friedel_fraction_max     0.990
_reflns_Friedel_fraction_full    0.993

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0797P)²+1.6479P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.06(6)
_chemical_absolute_configuration ad
_refine_ls_number_reflns         3526
_refine_ls_number_parameters     267
_refine_ls_number_restraints     17
_refine_ls_R_factor_all          0.0358
_refine_ls_R_factor_gt           0.0351
_refine_ls_wR_factor_ref         0.1071
_refine_ls_wR_factor_gt          0.1062
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_restrained_S_all      1.108
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.39468(11) 0.40539(5) 0.25357(5) 0.01892(19) Uani 1 1 d . . . . .
Ag2 Ag 0.82196(12) 0.55447(5) 0.26989(5) 0.0207(2) Uani 1 1 d . . . . .
O1 O 0.2529(12) 0.5703(6) 0.3129(5) 0.0184(13) Uani 1 1 d . U . . .
C1 C 0.3863(16) 0.6504(7) 0.3559(6) 0.0114(15) Uani 1 1 d . U . . .
O2 O 0.6107(11) 0.6463(6) 0.3810(5) 0.0155(12) Uani 1 1 d . . . . .
C2 C 0.2559(15) 0.7687(8) 0.3694(6) 0.0135(16) Uani 1 1 d . . . . .
H2 H 0.078973 0.755406 0.373879 0.016 Uiso 1 1 calc R U . . .
C3 C 0.2879(19) 0.8536(8) 0.2879(6) 0.0191(18) Uani 1 1 d . . . . .
H3A H 0.164254 0.838250 0.231227 0.023 Uiso 1 1 calc R U . . .
H3B H 0.453022 0.845911 0.268801 0.023 Uiso 1 1 calc R U . . .
C4 C 0.252(2) 0.9769(8) 0.3303(6) 0.0188(18) Uani 1 1 d . . . . .
H4 H 0.329254 1.040745 0.294894 0.023 Uiso 1 1 calc R U . . .
O3 O -0.0055(13) 0.9953(6) 0.3258(5) 0.0191(13) Uani 1 1 d D . . . .
H3 H -0.03(2) 1.040(10) 0.369(7) 0.029 Uiso 1 1 d D U . . .
C5 C 0.379(2) 0.9652(9) 0.4341(7) 0.023(2) Uani 1 1 d . . . . .
H5A H 0.547622 0.996423 0.440209 0.028 Uiso 1 1 calc R U . . .
H5B H 0.287650 1.009890 0.478481 0.028 Uiso 1 1 calc R U . . .
N1 N 0.3791(15) 0.8337(7) 0.4560(5) 0.0159(15) Uani 1 1 d D . . . .
H1A H 0.535(9) 0.820(11) 0.474(8) 0.019 Uiso 1 1 d D U . . .
H1B H 0.312(19) 0.833(11) 0.507(5) 0.019 Uiso 1 1 d D U . . .
O4 O 0.6088(12) 0.2724(6) 0.1882(5) 0.0184(13) Uani 1 1 d . . . . .
C6 C 0.8294(17) 0.2913(7) 0.1799(6) 0.0145(17) Uani 1 1 d . . . . .
O5 O 0.9433(14) 0.3843(6) 0.1969(5) 0.0232(15) Uani 1 1 d . . . . .
C7 C 0.9734(16) 0.1860(8) 0.1494(6) 0.0146(16) Uani 1 1 d . . . . .
H7 H 1.112999 0.171258 0.201450 0.018 Uiso 1 1 calc R U . . .
C8 C 1.0782(16) 0.1966(7) 0.0546(6) 0.0146(16) Uani 1 1 d . . . . .
H8A H 0.960762 0.235656 0.004632 0.018 Uiso 1 1 calc R U . . .
H8B H 1.233352 0.241983 0.063016 0.018 Uiso 1 1 calc R U . . .
C9 C 1.1198(15) 0.0666(8) 0.0294(6) 0.0145(16) Uani 1 1 d . . . . .
H9 H 1.143073 0.057249 -0.039545 0.017 Uiso 1 1 calc R U . . .
O6 O 1.3263(12) 0.0248(6) 0.0924(5) 0.0184(13) Uani 1 1 d D . . . .
H6 H 1.343(19) -0.048(4) 0.084(7) 0.01(2) Uiso 1 1 d D . . . .
C10 C 0.8857(16) 0.0072(8) 0.0503(6) 0.0160(17) Uani 1 1 d . . . . .
H10A H 0.754440 0.015785 -0.004846 0.019 Uiso 1 1 calc R U . . .
H10B H 0.912540 -0.078652 0.064467 0.019 Uiso 1 1 calc R U . . .
N2 N 0.8210(13) 0.0733(6) 0.1377(5) 0.0135(14) Uani 1 1 d . . . . .
H2A H 0.659109 0.091904 0.129309 0.016 Uiso 1 1 calc R U . . .
H2B H 0.853575 0.026766 0.191006 0.016 Uiso 1 1 calc R U . . .
N3 N 0.5713(15) 0.7257(7) 0.1184(5) 0.0206(17) Uani 1 1 d . . . . .
O7 O 0.4994(16) 0.6207(7) 0.1277(5) 0.0321(17) Uani 1 1 d . . . . .
O8 O 0.7530(14) 0.7640(8) 0.1702(5) 0.0333(17) Uani 1 1 d . . . . .
O9 O 0.4502(13) 0.7911(6) 0.0562(5) 0.0222(14) Uani 1 1 d . . . . .
N4 N 0.0769(15) 0.2740(8) 0.4177(5) 0.0191(15) Uani 1 1 d . . . . .
O10 O 0.0850(15) 0.3664(7) 0.4675(6) 0.0332(17) Uani 1 1 d . . . . .
O11 O 0.2595(12) 0.2422(7) 0.3797(5) 0.0224(14) Uani 1 1 d . . . . .
O12 O -0.1166(13) 0.2132(7) 0.4057(5) 0.0278(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O4 2.184(6) . ?
Ag1 O1 2.215(6) . ?
Ag1 O5 2.522(8) 1_455 ?
Ag1 Ag2 2.8756(9) . ?
Ag2 O5 2.309(7) . ?
Ag2 O2 2.318(6) . ?
Ag2 O1 2.381(6) 1_655 ?
Ag2 O7 2.595(8) . ?
O1 C1 1.262(10) . ?
C1 O2 1.242(11) . ?
C1 C2 1.533(11) . ?
C2 N1 1.498(11) . ?
C2 C3 1.518(12) . ?
C2 H2 1.0000 . ?
C3 C4 1.529(12) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 O3 1.431(13) . ?
C4 C5 1.533(13) . ?
C4 H4 1.0000 . ?
O3 H3 0.81(4) . ?
C5 N1 1.506(12) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
N1 H1A 0.87(4) . ?
N1 H1B 0.86(4) . ?
O4 C6 1.259(12) . ?
C6 O5 1.224(11) . ?
C6 C7 1.518(12) . ?
C7 N2 1.514(11) . ?
C7 C8 1.530(11) . ?
C7 H7 1.0000 . ?
C8 C9 1.525(12) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 O6 1.423(10) . ?
C9 C10 1.520(12) . ?
C9 H9 1.0000 . ?
O6 H6 0.83(4) . ?
C10 N2 1.519(11) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
N2 H2A 0.9100 . ?
N2 H2B 0.9100 . ?
N3 O8 1.232(11) . ?
N3 O7 1.255(11) . ?
N3 O9 1.260(11) . ?
N4 O10 1.248(11) . ?
N4 O11 1.257(11) . ?
N4 O12 1.259(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Ag1 O1 165.6(2) . . ?
O4 Ag1 O5 111.9(2) . 1_455 ?
O1 Ag1 O5 79.1(2) . 1_455 ?
O4 Ag1 Ag2 86.76(18) . . ?
O1 Ag1 Ag2 79.32(17) . . ?
O5 Ag1 Ag2 147.64(16) 1_455 . ?
O5 Ag2 O2 150.6(2) . . ?
O5 Ag2 O1 80.3(2) . 1_655 ?
O2 Ag2 O1 112.1(2) . 1_655 ?
O5 Ag2 O7 96.0(2) . . ?
O2 Ag2 O7 92.1(2) . . ?
O1 Ag2 O7 136.9(2) 1_655 . ?
O5 Ag2 Ag1 76.73(19) . . ?
O2 Ag2 Ag1 80.03(16) . . ?
O1 Ag2 Ag1 147.65(16) 1_655 . ?
O7 Ag2 Ag1 68.66(17) . . ?
C1 O1 Ag1 124.1(5) . . ?
C1 O1 Ag2 132.2(5) . 1_455 ?
Ag1 O1 Ag2 103.7(2) . 1_455 ?
O2 C1 O1 127.1(8) . . ?
O2 C1 C2 117.7(7) . . ?
O1 C1 C2 115.0(7) . . ?
C1 O2 Ag2 113.6(5) . . ?
N1 C2 C3 102.8(7) . . ?
N1 C2 C1 110.7(7) . . ?
C3 C2 C1 110.0(7) . . ?
N1 C2 H2 111.0 . . ?
C3 C2 H2 111.0 . . ?
C1 C2 H2 111.0 . . ?
C2 C3 C4 103.7(7) . . ?
C2 C3 H3A 111.0 . . ?
C4 C3 H3A 111.0 . . ?
C2 C3 H3B 111.0 . . ?
C4 C3 H3B 111.0 . . ?
H3A C3 H3B 109.0 . . ?
O3 C4 C3 107.2(8) . . ?
O3 C4 C5 111.9(8) . . ?
C3 C4 C5 103.1(7) . . ?
O3 C4 H4 111.4 . . ?
C3 C4 H4 111.4 . . ?
C5 C4 H4 111.4 . . ?
C4 O3 H3 110(10) . . ?
N1 C5 C4 105.4(7) . . ?
N1 C5 H5A 110.7 . . ?
C4 C5 H5A 110.7 . . ?
N1 C5 H5B 110.7 . . ?
C4 C5 H5B 110.7 . . ?
H5A C5 H5B 108.8 . . ?
C2 N1 C5 108.8(7) . . ?
C2 N1 H1A 117(8) . . ?
C5 N1 H1A 102(8) . . ?
C2 N1 H1B 119(8) . . ?
C5 N1 H1B 101(8) . . ?
H1A N1 H1B 107(10) . . ?
C6 O4 Ag1 120.8(6) . . ?
O5 C6 O4 127.1(8) . . ?
O5 C6 C7 116.2(8) . . ?
O4 C6 C7 116.6(7) . . ?
C6 O5 Ag2 128.1(7) . . ?
C6 O5 Ag1 126.9(6) . 1_655 ?
Ag2 O5 Ag1 96.8(2) . 1_655 ?
N2 C7 C6 111.9(7) . . ?
N2 C7 C8 104.0(7) . . ?
C6 C7 C8 117.5(7) . . ?
N2 C7 H7 107.6 . . ?
C6 C7 H7 107.6 . . ?
C8 C7 H7 107.6 . . ?
C9 C8 C7 102.5(7) . . ?
C9 C8 H8A 111.3 . . ?
C7 C8 H8A 111.3 . . ?
C9 C8 H8B 111.3 . . ?
C7 C8 H8B 111.3 . . ?
H8A C8 H8B 109.2 . . ?
O6 C9 C10 111.4(7) . . ?
O6 C9 C8 107.6(7) . . ?
C10 C9 C8 102.3(7) . . ?
O6 C9 H9 111.7 . . ?
C10 C9 H9 111.7 . . ?
C8 C9 H9 111.7 . . ?
C9 O6 H6 109(7) . . ?
N2 C10 C9 104.2(7) . . ?
N2 C10 H10A 110.9 . . ?
C9 C10 H10A 110.9 . . ?
N2 C10 H10B 110.9 . . ?
C9 C10 H10B 110.9 . . ?
H10A C10 H10B 108.9 . . ?
C7 N2 C10 107.7(7) . . ?
C7 N2 H2A 110.2 . . ?
C10 N2 H2A 110.2 . . ?
C7 N2 H2B 110.2 . . ?
C10 N2 H2B 110.2 . . ?
H2A N2 H2B 108.5 . . ?
O8 N3 O7 120.6(9) . . ?
O8 N3 O9 121.2(9) . . ?
O7 N3 O9 118.2(8) . . ?
N3 O7 Ag2 98.9(6) . . ?
O10 N4 O11 120.4(8) . . ?
O10 N4 O12 119.1(8) . . ?
O11 N4 O12 120.5(8) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O1 C1 O2 -8.1(12) . . . . ?
Ag2 O1 C1 O2 174.4(6) 1_455 . . . ?
Ag1 O1 C1 C2 166.0(5) . . . . ?
Ag2 O1 C1 C2 -11.5(11) 1_455 . . . ?
O1 C1 O2 Ag2 39.3(10) . . . . ?
C2 C1 O2 Ag2 -134.7(6) . . . . ?
O2 C1 C2 N1 -32.3(10) . . . . ?
O1 C1 C2 N1 152.9(7) . . . . ?
O2 C1 C2 C3 80.5(9) . . . . ?
O1 C1 C2 C3 -94.2(9) . . . . ?
N1 C2 C3 C4 -38.7(9) . . . . ?
C1 C2 C3 C4 -156.5(8) . . . . ?
C2 C3 C4 O3 -79.7(8) . . . . ?
C2 C3 C4 C5 38.5(10) . . . . ?
O3 C4 C5 N1 91.6(10) . . . . ?
C3 C4 C5 N1 -23.3(11) . . . . ?
C3 C2 N1 C5 24.3(10) . . . . ?
C1 C2 N1 C5 141.7(8) . . . . ?
C4 C5 N1 C2 -0.5(11) . . . . ?
Ag1 O4 C6 O5 -7.4(13) . . . . ?
Ag1 O4 C6 C7 170.0(5) . . . . ?
O4 C6 O5 Ag2 9.2(14) . . . . ?
C7 C6 O5 Ag2 -168.2(6) . . . . ?
O4 C6 O5 Ag1 150.0(7) . . . 1_655 ?
C7 C6 O5 Ag1 -27.3(11) . . . 1_655 ?
O5 C6 C7 N2 175.6(7) . . . . ?
O4 C6 C7 N2 -2.0(11) . . . . ?
O5 C6 C7 C8 -64.1(11) . . . . ?
O4 C6 C7 C8 118.3(9) . . . . ?
N2 C7 C8 C9 -35.1(8) . . . . ?
C6 C7 C8 C9 -159.5(7) . . . . ?
C7 C8 C9 O6 -73.4(8) . . . . ?
C7 C8 C9 C10 44.1(8) . . . . ?
O6 C9 C10 N2 78.8(8) . . . . ?
C8 C9 C10 N2 -35.9(8) . . . . ?
C6 C7 N2 C10 140.9(7) . . . . ?
C8 C7 N2 C10 12.9(8) . . . . ?
C9 C10 N2 C7 14.3(9) . . . . ?
O8 N3 O7 Ag2 1.5(10) . . . . ?
O9 N3 O7 Ag2 -177.3(7) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C3 H3A O8 0.99 2.46 3.336(12) 147 1_455 yes
C3 H3B O8 0.99 2.48 3.397(13) 154 . yes
O3 H3 O12 0.81(4) 2.08(9) 2.792(10) 146(13) 1_565 yes
C5 H5B O2 0.99 2.50 3.292(11) 137 2_656 yes
N1 H1A N4 0.87(4) 2.51(6) 3.340(11) 159(10) 2_656 yes
N1 H1A O10 0.87(4) 2.21(7) 3.029(12) 155(11) 2_656 yes
N1 H1A O11 0.87(4) 2.38(9) 3.016(10) 130(9) 2_656 yes
N1 H1B N4 0.86(4) 2.61(8) 3.347(11) 145(10) 2_556 yes
N1 H1B O10 0.86(4) 2.30(9) 2.939(12) 132(10) 2_556 yes
N1 H1B O12 0.86(4) 2.20(8) 2.914(11) 141(10) 2_556 yes
C8 H8A O9 0.99 2.39 3.288(11) 150 2_645 yes
C8 H8B O4 0.99 2.55 3.364(11) 139 1_655 yes
C9 H9 O7 1.00 2.57 3.310(12) 130 2_745 yes
O6 H6 O9 0.83(4) 1.96(5) 2.773(9) 168(10) 1_645 yes
C10 H10A O7 0.99 2.38 3.305(12) 156 2_645 yes
C10 H10B O8 0.99 2.54 3.340(13) 138 1_545 yes
N2 H2A O6 0.91 1.99 2.773(10) 144 1_455 yes
N2 H2B O3 0.91 1.98 2.823(10) 154 1_645 yes

_refine_diff_density_max         2.396
_refine_diff_density_min         -1.008
_refine_diff_density_rms         0.199

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_agprolin
_database_code_depnum_ccdc_archive 'CCDC 2331722'
loop_
_audit_author_name
_audit_author_address
'Robert Gyepes'
;Department of Inorganic Chemistry, Charles University, Prague
Czech Republic
;
_audit_update_record             
;
2024-02-08 deposited with the CCDC.	2024-04-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/3
_shelx_SHELXL_version_number     2019/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C10 H18 Ag2 N4 O10'
_chemical_formula_sum            'C10 H18 Ag2 N4 O10'
_chemical_formula_weight         570.02

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   5.47390(10)
_cell_length_b                   11.0228(3)
_cell_length_c                   13.9383(4)
_cell_angle_alpha                90
_cell_angle_beta                 98.0410(10)
_cell_angle_gamma                90
_cell_volume                     832.74(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    9130
_cell_measurement_theta_min      2.3647
_cell_measurement_theta_max      29.9651

_exptl_crystal_description       block
_exptl_crystal_colour            'translucent colourless'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.273
_exptl_crystal_F_000             560
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.437
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.066
_exptl_absorpt_coefficient_mu    2.414
_shelx_estimated_absorpt_T_min   0.419
_shelx_estimated_absorpt_T_max   0.857
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_process_details   
;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10.
doi:10.1107/S1600576714022985
;
_exptl_absorpt_correction_T_min  0.66
_exptl_absorpt_correction_T_max  0.86
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  'multilayer mirror'
_diffrn_measurement_device       'Bruker D8 VENTURE'
_diffrn_measurement_device_type  'κ-geometry diffractometer'
_diffrn_source                   'INCOATEC microfocus sealed tube'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            21750
_diffrn_reflns_av_unetI/netI     0.0204
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.365
_diffrn_reflns_theta_max         29.980
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             4834
_reflns_number_gt                4771
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.906
_reflns_Friedel_fraction_max     0.997
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0137P)²+0.2912P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 2231 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.015(9)
_chemical_absolute_configuration ad
_refine_ls_number_reflns         4834
_refine_ls_number_parameters     251
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0156
_refine_ls_R_factor_gt           0.0152
_refine_ls_wR_factor_ref         0.0331
_refine_ls_wR_factor_gt          0.0329
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.73468(3) 0.50377(2) 0.22363(2) 0.01366(4) Uani 1 1 d . . . . .
Ag2 Ag 0.34985(3) 0.59643(2) 0.31946(2) 0.01779(5) Uani 1 1 d . . . . .
O1 O 0.1463(3) 0.5022(2) 0.17843(12) 0.0150(4) Uani 1 1 d . . . . .
O2 O 0.4573(3) 0.41716(19) 0.11317(14) 0.0165(4) Uani 1 1 d . . . . .
C1 C 0.2342(5) 0.4301(2) 0.12303(18) 0.0119(5) Uani 1 1 d . . . . .
C2 C 0.0494(5) 0.3471(2) 0.06339(19) 0.0131(5) Uani 1 1 d . . . . .
H2 H -0.103303 0.393626 0.038721 0.016 Uiso 1 1 calc R U . . .
N1 N 0.1574(4) 0.2921(2) -0.02040(17) 0.0157(4) Uani 1 1 d . . . . .
H1NA H 0.031(7) 0.298(3) -0.077(3) 0.018(9) Uiso 1 1 d . . . . .
H1NB H 0.271(8) 0.328(4) -0.032(3) 0.031(11) Uiso 1 1 d . . . . .
C3 C -0.0172(5) 0.2375(3) 0.1242(2) 0.0179(5) Uani 1 1 d . . . . .
H3A H 0.100389 0.230331 0.184676 0.021 Uiso 1 1 calc R U . . .
H3B H -0.186080 0.246181 0.141026 0.021 Uiso 1 1 calc R U . . .
C4 C -0.0001(6) 0.1271(3) 0.0593(2) 0.0221(6) Uani 1 1 d . . . . .
H4A H -0.155716 0.114474 0.014987 0.027 Uiso 1 1 calc R U . . .
H4B H 0.039454 0.052724 0.098236 0.027 Uiso 1 1 calc R U . . .
C5 C 0.2110(6) 0.1618(3) 0.0035(2) 0.0223(6) Uani 1 1 d . . . . .
H5A H 0.373250 0.152206 0.044178 0.027 Uiso 1 1 calc R U . . .
H5B H 0.208087 0.112345 -0.055925 0.027 Uiso 1 1 calc R U . . .
O3 O 0.9384(3) 0.5865(2) 0.35779(13) 0.0131(3) Uani 1 1 d . . . . .
O4 O 0.6411(3) 0.6027(2) 0.45287(13) 0.0160(4) Uani 1 1 d . . . . .
C6 C 0.8600(4) 0.5908(3) 0.43865(17) 0.0118(4) Uani 1 1 d . . . . .
C7 C 1.0588(4) 0.5765(2) 0.52600(18) 0.0124(5) Uani 1 1 d . . . . .
H7 H 1.202263 0.630328 0.518967 0.015 Uiso 1 1 calc R U . . .
N2 N 0.9564(4) 0.6067(2) 0.61772(16) 0.0120(4) Uani 1 1 d . . . . .
H2NA H 0.805(7) 0.624(3) 0.602(3) 0.021(9) Uiso 1 1 d . . . . .
H2NB H 1.024(6) 0.666(3) 0.647(2) 0.012(8) Uiso 1 1 d . . . . .
C8 C 1.1450(5) 0.4442(3) 0.5392(2) 0.0190(6) Uani 1 1 d . . . . .
H8A H 1.116602 0.399564 0.477053 0.023 Uiso 1 1 calc R U . . .
H8B H 1.322362 0.439903 0.565544 0.023 Uiso 1 1 calc R U . . .
C9 C 0.9863(6) 0.3933(3) 0.6111(2) 0.0211(6) Uani 1 1 d . . . . .
H9A H 0.818701 0.372802 0.578763 0.025 Uiso 1 1 calc R U . . .
H9B H 1.062413 0.319994 0.643813 0.025 Uiso 1 1 calc R U . . .
C10 C 0.9788(5) 0.4962(3) 0.68184(19) 0.0180(5) Uani 1 1 d . . . . .
H10A H 0.835131 0.488623 0.717399 0.022 Uiso 1 1 calc R U . . .
H10B H 1.131688 0.498955 0.729046 0.022 Uiso 1 1 calc R U . . .
N3 N 0.4091(4) 0.8042(2) 0.16581(17) 0.0175(5) Uani 1 1 d . . . . .
O5 O 0.6038(4) 0.7607(2) 0.20839(17) 0.0285(5) Uani 1 1 d . . . . .
O6 O 0.2053(4) 0.7791(2) 0.19324(16) 0.0220(4) Uani 1 1 d . . . . .
O7 O 0.4117(4) 0.8729(2) 0.09413(17) 0.0285(5) Uani 1 1 d . . . . .
N4 N 0.5366(4) 0.2676(2) 0.32936(17) 0.0153(4) Uani 1 1 d . . . . .
O8 O 0.7510(4) 0.31369(19) 0.33388(16) 0.0205(4) Uani 1 1 d . . . . .
O9 O 0.3574(4) 0.3318(2) 0.33955(17) 0.0230(4) Uani 1 1 d . . . . .
O10 O 0.5122(4) 0.15569(18) 0.31459(18) 0.0227(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O2 2.2210(18) . ?
Ag1 O3 2.2334(18) . ?
Ag1 O1 2.4230(15) 1_655 ?
Ag1 O8 2.592(2) . ?
Ag1 Ag2 2.8375(3) . ?
Ag2 O4 2.2748(18) . ?
Ag2 O1 2.3605(17) . ?
Ag2 O3 2.3887(17) 1_455 ?
O1 C1 1.251(3) . ?
O2 C1 1.256(3) . ?
C1 C2 1.522(3) . ?
C2 N1 1.508(3) . ?
C2 C3 1.547(4) . ?
C2 H2 1.0000 . ?
N1 C5 1.494(4) . ?
N1 H1NA 0.97(4) . ?
N1 H1NB 0.77(4) . ?
C3 C4 1.526(4) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 C5 1.529(4) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
O3 C6 1.262(3) . ?
O4 C6 1.249(3) . ?
C6 C7 1.523(3) . ?
C7 N2 1.504(3) . ?
C7 C8 1.535(4) . ?
C7 H7 1.0000 . ?
N2 C10 1.506(4) . ?
N2 H2NA 0.85(4) . ?
N2 H2NB 0.83(3) . ?
C8 C9 1.522(4) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.507(4) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
N3 O5 1.241(3) . ?
N3 O7 1.256(3) . ?
N3 O6 1.259(3) . ?
N4 O9 1.234(3) . ?
N4 O10 1.255(3) . ?
N4 O8 1.272(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ag1 O3 165.63(7) . . ?
O2 Ag1 O1 112.77(6) . 1_655 ?
O3 Ag1 O1 81.20(6) . 1_655 ?
O2 Ag1 O8 91.55(7) . . ?
O3 Ag1 O8 82.06(7) . . ?
O1 Ag1 O8 101.08(7) 1_655 . ?
O2 Ag1 Ag2 90.03(5) . . ?
O3 Ag1 Ag2 77.04(5) . . ?
O1 Ag1 Ag2 154.63(5) 1_655 . ?
O8 Ag1 Ag2 88.75(5) . . ?
O4 Ag2 O1 152.80(8) . . ?
O4 Ag2 O3 113.16(6) . 1_455 ?
O1 Ag2 O3 79.40(6) . 1_455 ?
O4 Ag2 Ag1 85.08(5) . . ?
O1 Ag2 Ag1 75.21(4) . . ?
O3 Ag2 Ag1 150.92(5) 1_455 . ?
C1 O1 Ag2 128.04(15) . . ?
C1 O1 Ag1 128.13(16) . 1_455 ?
Ag2 O1 Ag1 97.36(6) . 1_455 ?
C1 O2 Ag1 117.15(16) . . ?
O1 C1 O2 127.1(2) . . ?
O1 C1 C2 115.8(2) . . ?
O2 C1 C2 117.0(2) . . ?
N1 C2 C1 111.2(2) . . ?
N1 C2 C3 105.0(2) . . ?
C1 C2 C3 111.1(2) . . ?
N1 C2 H2 109.8 . . ?
C1 C2 H2 109.8 . . ?
C3 C2 H2 109.8 . . ?
C5 N1 C2 107.4(2) . . ?
C5 N1 H1NA 110(2) . . ?
C2 N1 H1NA 107(2) . . ?
C5 N1 H1NB 113(3) . . ?
C2 N1 H1NB 112(3) . . ?
H1NA N1 H1NB 108(4) . . ?
C4 C3 C2 105.0(2) . . ?
C4 C3 H3A 110.7 . . ?
C2 C3 H3A 110.7 . . ?
C4 C3 H3B 110.7 . . ?
C2 C3 H3B 110.7 . . ?
H3A C3 H3B 108.8 . . ?
C3 C4 C5 102.4(2) . . ?
C3 C4 H4A 111.3 . . ?
C5 C4 H4A 111.3 . . ?
C3 C4 H4B 111.3 . . ?
C5 C4 H4B 111.3 . . ?
H4A C4 H4B 109.2 . . ?
N1 C5 C4 102.4(2) . . ?
N1 C5 H5A 111.3 . . ?
C4 C5 H5A 111.3 . . ?
N1 C5 H5B 111.3 . . ?
C4 C5 H5B 111.3 . . ?
H5A C5 H5B 109.2 . . ?
C6 O3 Ag1 124.81(16) . . ?
C6 O3 Ag2 130.33(15) . 1_655 ?
Ag1 O3 Ag2 101.98(7) . 1_655 ?
C6 O4 Ag2 116.45(16) . . ?
O4 C6 O3 126.8(2) . . ?
O4 C6 C7 118.6(2) . . ?
O3 C6 C7 114.6(2) . . ?
N2 C7 C6 110.30(19) . . ?
N2 C7 C8 104.7(2) . . ?
C6 C7 C8 111.5(2) . . ?
N2 C7 H7 110.1 . . ?
C6 C7 H7 110.1 . . ?
C8 C7 H7 110.1 . . ?
C7 N2 C10 108.4(2) . . ?
C7 N2 H2NA 107(2) . . ?
C10 N2 H2NA 109(2) . . ?
C7 N2 H2NB 114(2) . . ?
C10 N2 H2NB 111(2) . . ?
H2NA N2 H2NB 108(3) . . ?
C9 C8 C7 103.6(2) . . ?
C9 C8 H8A 111.0 . . ?
C7 C8 H8A 111.0 . . ?
C9 C8 H8B 111.0 . . ?
C7 C8 H8B 111.0 . . ?
H8A C8 H8B 109.0 . . ?
C10 C9 C8 102.9(2) . . ?
C10 C9 H9A 111.2 . . ?
C8 C9 H9A 111.2 . . ?
C10 C9 H9B 111.2 . . ?
C8 C9 H9B 111.2 . . ?
H9A C9 H9B 109.1 . . ?
N2 C10 C9 103.2(2) . . ?
N2 C10 H10A 111.1 . . ?
C9 C10 H10A 111.1 . . ?
N2 C10 H10B 111.1 . . ?
C9 C10 H10B 111.1 . . ?
H10A C10 H10B 109.1 . . ?
O5 N3 O7 120.6(2) . . ?
O5 N3 O6 120.5(3) . . ?
O7 N3 O6 118.9(2) . . ?
O9 N4 O10 120.9(2) . . ?
O9 N4 O8 120.6(2) . . ?
O10 N4 O8 118.5(2) . . ?
N4 O8 Ag1 109.77(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag2 O1 C1 O2 -21.5(4) . . . . ?
Ag1 O1 C1 O2 -166.7(2) 1_455 . . . ?
Ag2 O1 C1 C2 156.73(17) . . . . ?
Ag1 O1 C1 C2 11.6(3) 1_455 . . . ?
Ag1 O2 C1 O1 12.7(4) . . . . ?
Ag1 O2 C1 C2 -165.49(17) . . . . ?
O1 C1 C2 N1 163.0(2) . . . . ?
O2 C1 C2 N1 -18.6(3) . . . . ?
O1 C1 C2 C3 -80.5(3) . . . . ?
O2 C1 C2 C3 98.0(3) . . . . ?
C1 C2 N1 C5 106.5(3) . . . . ?
C3 C2 N1 C5 -13.7(3) . . . . ?
N1 C2 C3 C4 -13.0(3) . . . . ?
C1 C2 C3 C4 -133.3(2) . . . . ?
C2 C3 C4 C5 34.0(3) . . . . ?
C2 N1 C5 C4 34.9(3) . . . . ?
C3 C4 C5 N1 -42.2(3) . . . . ?
Ag2 O4 C6 O3 6.9(4) . . . . ?
Ag2 O4 C6 C7 -171.53(18) . . . . ?
Ag1 O3 C6 O4 -34.1(4) . . . . ?
Ag2 O3 C6 O4 168.7(2) 1_655 . . . ?
Ag1 O3 C6 C7 144.36(18) . . . . ?
Ag2 O3 C6 C7 -12.8(4) 1_655 . . . ?
O4 C6 C7 N2 -12.3(4) . . . . ?
O3 C6 C7 N2 169.1(2) . . . . ?
O4 C6 C7 C8 103.5(3) . . . . ?
O3 C6 C7 C8 -75.0(3) . . . . ?
C6 C7 N2 C10 119.5(2) . . . . ?
C8 C7 N2 C10 -0.6(3) . . . . ?
N2 C7 C8 C9 24.9(3) . . . . ?
C6 C7 C8 C9 -94.3(3) . . . . ?
C7 C8 C9 C10 -40.1(3) . . . . ?
C7 N2 C10 C9 -24.2(3) . . . . ?
C8 C9 C10 N2 39.4(3) . . . . ?
O9 N4 O8 Ag1 -49.2(3) . . . . ?
O10 N4 O8 Ag1 130.9(2) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C2 H2 O7 1.00 2.34 3.118(3) 134 2_545 yes
N1 H1NA N3 0.97(4) 2.55(4) 3.462(3) 156(3) 2_545 yes
N1 H1NA O6 0.97(4) 1.94(4) 2.903(3) 170(3) 2_545 yes
N1 H1NA O7 0.97(4) 2.54(4) 3.265(3) 131(3) 2_545 yes
N1 H1NB O7 0.77(4) 2.11(4) 2.845(3) 160(4) 2_645 yes
N2 H2NA O4 0.85(4) 2.16(4) 2.674(3) 119(3) . yes
N2 H2NA O10 0.85(4) 2.24(4) 2.905(3) 135(3) 2_656 yes
N2 H2NB O8 0.83(3) 2.03(3) 2.815(3) 156(3) 2_756 yes
N2 H2NB O10 0.83(3) 2.52(3) 2.979(3) 116(3) 2_756 yes
C8 H8A O9 0.99 2.58 3.397(4) 139 1_655 yes
C9 H9B O3 0.99 2.57 3.427(4) 144 2_746 yes

_refine_diff_density_max         0.544
_refine_diff_density_min         -0.426
_refine_diff_density_rms         0.062

