# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_22222222
_database_code_depnum_ccdc_archive 'CCDC 2345924'
loop_
_audit_author_name
_audit_author_address
'Zhixia Gao'
;Xinjiang Normal University
China
;
_audit_update_record             
;
2024-04-05 deposited with the CCDC.	2024-05-02 downloaded from the CCDC.
;
_audit_creation_date             2023-11-22
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        1
_chemical_formula_moiety         'K2 Mg Mo O10 P2'
_chemical_formula_sum            'K2 Mg Mo O10 P2'
_chemical_formula_weight         420.39
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.7629(18)
_cell_length_b                   9.7379(16)
_cell_length_c                   10.6366(19)
_cell_angle_alpha                90
_cell_angle_beta                 92.593(9)
_cell_angle_gamma                90
_cell_volume                     906.7(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3715
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.38
_cell_measurement_theta_min      2.84
_shelx_estimated_absorpt_T_max   0.746
_shelx_estimated_absorpt_T_min   0.630
_exptl_absorpt_coefficient_mu    2.828
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6542
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0900 before and 0.0714 after correction.
The Ratio of minimum to maximum transmission is 0.8774.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.080
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             808
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0831
_diffrn_reflns_av_unetI/netI     0.0481
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            13912
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.544
_diffrn_reflns_theta_min         2.837
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1684
_reflns_number_total             2089
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.641
_refine_diff_density_min         -0.817
_refine_diff_density_rms         0.156
_refine_ls_extinction_coef       0.0008(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     146
_refine_ls_number_reflns         2089
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0477
_refine_ls_R_factor_gt           0.0327
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0103P)²+3.7770P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0620
_refine_ls_wR_factor_ref         0.0671
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K -0.00653(13) 0.69891(11) 0.69549(10) 0.0220(2) Uani 1 1 d . . . . .
K2 K 0.95507(15) 0.28680(13) 0.90080(11) 0.0317(3) Uani 1 1 d . . . . .
Mg1 Mg 0.32094(17) 0.54374(15) 0.86371(13) 0.0105(3) Uani 1 1 d . . . . .
Mo1 Mo 0.24792(4) 0.62611(4) 0.42357(3) 0.01006(12) Uani 1 1 d . . . . .
P1 P 0.70038(13) 0.54526(11) 0.85504(10) 0.0097(2) Uani 1 1 d . . . . .
P2 P 0.16427(13) 0.37746(11) 0.61382(10) 0.0085(2) Uani 1 1 d . . . . .
O1 O 0.2462(4) 0.7076(3) 0.5652(3) 0.0164(7) Uani 1 1 d . . . . .
O2 O 0.4385(4) 0.6241(4) 0.4004(3) 0.0195(7) Uani 1 1 d . . . . .
O3 O 0.2330(3) 0.4380(3) 0.4918(3) 0.0120(6) Uani 1 1 d . . . . .
O4 O 0.1984(4) 0.4695(3) 0.7255(3) 0.0179(7) Uani 1 1 d . . . . .
O5 O -0.0069(4) 0.3696(3) 0.5857(3) 0.0189(7) Uani 1 1 d . . . . .
O6 O 0.2330(4) 0.2361(3) 0.6313(3) 0.0160(7) Uani 1 1 d . . . . .
O7 O 0.5340(4) 0.5041(3) 0.8492(3) 0.0213(8) Uani 1 1 d . . . . .
O8 O 0.7172(4) 0.6998(3) 0.8207(3) 0.0155(7) Uani 1 1 d . . . . .
O9 O 0.7920(4) 0.4679(3) 0.7573(3) 0.0115(6) Uani 1 1 d . . . . .
O10 O 0.7754(4) 0.5169(3) 0.9840(3) 0.0159(7) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
K1 P1 3.4799(16) 1_455 ?
K1 P2 3.5883(16) 3_566 ?
K1 O1 2.667(3) . ?
K1 O2 2.837(3) 4_576 ?
K1 O3 3.054(3) 3_566 ?
K1 O4 2.875(3) . ?
K1 O5 3.413(4) . ?
K1 O5 3.072(3) 3_566 ?
K1 O6 2.978(3) 2_556 ?
K1 O7 3.018(3) 2_556 ?
K1 O8 2.815(3) 1_455 ?
K1 O9 2.952(3) 1_455 ?
K2 Mo1 3.5032(13) 2_646 ?
K2 P1 3.3843(17) . ?
K2 P2 3.7370(17) 1_655 ?
K2 O1 2.737(4) 2_646 ?
K2 O2 2.771(3) 2_646 ?
K2 O3 3.112(3) 4_666 ?
K2 O4 3.398(4) 1_655 ?
K2 O6 3.206(3) 4_666 ?
K2 O8 2.868(3) 2_646 ?
K2 O9 2.699(3) . ?
K2 O10 3.236(4) 3_767 ?
K2 O10 2.899(3) . ?
Mg1 P1 3.1282(18) 3_667 ?
Mg1 O4 1.921(3) . ?
Mg1 O6 1.933(3) 2_556 ?
Mg1 O7 1.919(4) . ?
Mg1 O10 1.952(3) 3_667 ?
Mo1 O1 1.704(3) . ?
Mo1 O2 1.699(3) . ?
Mo1 O3 1.977(3) . ?
Mo1 O5 2.110(3) 3_566 ?
Mo1 O8 2.029(3) 4_575 ?
Mo1 O9 2.145(3) 3_666 ?
P1 O7 1.511(3) . ?
P1 O8 1.558(3) . ?
P1 O9 1.539(3) . ?
P1 O10 1.519(3) . ?
P2 O3 1.570(3) . ?
P2 O4 1.508(3) . ?
P2 O5 1.518(3) . ?
P2 O6 1.511(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 K1 P2 95.50(4) 1_455 3_566 ?
O1 K1 P1 156.32(8) . 1_455 ?
O1 K1 P2 79.91(7) . 3_566 ?
O1 K1 O2 123.63(10) . 4_576 ?
O1 K1 O3 101.86(9) . 3_566 ?
O1 K1 O4 63.45(10) . . ?
O1 K1 O5 55.37(9) . 3_566 ?
O1 K1 O5 80.80(9) . . ?
O1 K1 O6 69.71(10) . 2_556 ?
O1 K1 O7 87.07(9) . 2_556 ?
O1 K1 O8 176.32(10) . 1_455 ?
O1 K1 O9 131.24(9) . 1_455 ?
O2 K1 P1 74.44(7) 4_576 1_455 ?
O2 K1 P2 139.33(8) 4_576 3_566 ?
O2 K1 O3 129.67(10) 4_576 3_566 ?
O2 K1 O4 120.91(10) 4_576 . ?
O2 K1 O5 153.54(10) 4_576 3_566 ?
O2 K1 O5 146.74(9) 4_576 . ?
O2 K1 O6 67.11(9) 4_576 2_556 ?
O2 K1 O7 60.50(9) 4_576 2_556 ?
O2 K1 O9 99.66(9) 4_576 1_455 ?
O3 K1 P1 70.02(6) 3_566 1_455 ?
O3 K1 P2 25.77(6) 3_566 3_566 ?
O3 K1 O5 47.35(8) 3_566 3_566 ?
O3 K1 O5 51.40(8) 3_566 . ?
O4 K1 P1 94.75(7) . 1_455 ?
O4 K1 P2 98.84(7) . 3_566 ?
O4 K1 O3 96.76(9) . 3_566 ?
O4 K1 O5 83.58(9) . 3_566 ?
O4 K1 O5 45.49(8) . . ?
O4 K1 O6 62.90(9) . 2_556 ?
O4 K1 O7 145.85(10) . 2_556 ?
O4 K1 O9 76.12(9) . 1_455 ?
O5 K1 P1 76.91(6) . 1_455 ?
O5 K1 P1 116.30(7) 3_566 1_455 ?
O5 K1 P2 24.83(6) 3_566 3_566 ?
O5 K1 P2 59.81(6) . 3_566 ?
O5 K1 O5 57.47(10) 3_566 . ?
O6 K1 P1 109.98(7) 2_556 1_455 ?
O6 K1 P2 149.11(7) 2_556 3_566 ?
O6 K1 O3 159.65(9) 2_556 3_566 ?
O6 K1 O5 108.31(8) 2_556 . ?
O6 K1 O5 124.29(9) 2_556 3_566 ?
O6 K1 O7 91.94(9) 2_556 2_556 ?
O7 K1 P1 116.43(7) 2_556 1_455 ?
O7 K1 P2 92.01(7) 2_556 3_566 ?
O7 K1 O3 106.40(9) 2_556 3_566 ?
O7 K1 O5 150.77(9) 2_556 . ?
O7 K1 O5 93.83(9) 2_556 3_566 ?
O8 K1 P1 26.01(6) 1_455 1_455 ?
O8 K1 P2 97.49(7) 1_455 3_566 ?
O8 K1 O2 56.99(9) 1_455 4_576 ?
O8 K1 O3 76.26(9) 1_455 3_566 ?
O8 K1 O4 119.74(10) 1_455 . ?
O8 K1 O5 122.20(10) 1_455 3_566 ?
O8 K1 O5 100.21(9) 1_455 . ?
O8 K1 O6 113.10(10) 1_455 2_556 ?
O8 K1 O7 90.42(9) 1_455 2_556 ?
O8 K1 O9 50.30(8) 1_455 1_455 ?
O9 K1 P1 26.06(6) 1_455 1_455 ?
O9 K1 P2 80.61(6) 1_455 3_566 ?
O9 K1 O3 55.61(8) 1_455 3_566 ?
O9 K1 O5 50.86(8) 1_455 . ?
O9 K1 O5 95.80(9) 1_455 3_566 ?
O9 K1 O6 115.31(9) 1_455 2_556 ?
O9 K1 O7 137.85(10) 1_455 2_556 ?
Mo1 K2 P2 99.27(4) 2_646 1_655 ?
P1 K2 Mo1 151.41(4) . 2_646 ?
P1 K2 P2 92.95(4) . 1_655 ?
P1 K2 O4 87.58(7) . 1_655 ?
O1 K2 Mo1 28.45(6) 2_646 2_646 ?
O1 K2 P1 148.10(8) 2_646 . ?
O1 K2 P2 70.90(7) 2_646 1_655 ?
O1 K2 O2 56.71(9) 2_646 2_646 ?
O1 K2 O3 111.62(9) 2_646 4_666 ?
O1 K2 O4 66.41(9) 2_646 1_655 ?
O1 K2 O6 119.30(9) 2_646 4_666 ?
O1 K2 O8 119.34(10) 2_646 2_646 ?
O1 K2 O10 55.90(9) 2_646 3_767 ?
O1 K2 O10 134.96(10) 2_646 . ?
O2 K2 Mo1 28.49(7) 2_646 2_646 ?
O2 K2 P1 137.07(8) 2_646 . ?
O2 K2 P2 126.73(8) 2_646 1_655 ?
O2 K2 O3 63.51(9) 2_646 4_666 ?
O2 K2 O4 121.35(10) 2_646 1_655 ?
O2 K2 O6 64.63(9) 2_646 4_666 ?
O2 K2 O8 127.21(10) 2_646 2_646 ?
O2 K2 O10 112.19(10) 2_646 . ?
O2 K2 O10 80.45(9) 2_646 3_767 ?
O3 K2 Mo1 88.85(6) 4_666 2_646 ?
O3 K2 P1 98.64(7) 4_666 . ?
O3 K2 P2 139.20(7) 4_666 1_655 ?
O3 K2 O4 162.86(8) 4_666 1_655 ?
O3 K2 O6 45.86(8) 4_666 4_666 ?
O3 K2 O10 138.90(8) 4_666 3_767 ?
O4 K2 Mo1 93.26(7) 1_655 2_646 ?
O4 K2 P2 23.79(5) 1_655 1_655 ?
O6 K2 Mo1 91.33(7) 4_666 2_646 ?
O6 K2 P1 75.08(6) 4_666 . ?
O6 K2 P2 168.03(7) 4_666 1_655 ?
O6 K2 O4 150.87(8) 4_666 1_655 ?
O6 K2 O10 102.08(8) 4_666 3_767 ?
O8 K2 Mo1 131.06(7) 2_646 2_646 ?
O8 K2 P1 77.43(7) 2_646 . ?
O8 K2 P2 70.01(7) 2_646 1_655 ?
O8 K2 O3 74.60(9) 2_646 4_666 ?
O8 K2 O4 91.38(9) 2_646 1_655 ?
O8 K2 O6 107.01(10) 2_646 4_666 ?
O8 K2 O10 146.47(9) 2_646 3_767 ?
O8 K2 O10 101.89(10) 2_646 . ?
O9 K2 Mo1 162.74(8) . 2_646 ?
O9 K2 P1 26.35(6) . . ?
O9 K2 P2 69.53(7) . 1_655 ?
O9 K2 O1 137.51(11) . 2_646 ?
O9 K2 O2 163.10(10) . 2_646 ?
O9 K2 O3 108.25(10) . 4_666 ?
O9 K2 O4 71.15(9) . 1_655 ?
O9 K2 O6 98.85(9) . 4_666 ?
O9 K2 O8 58.87(9) . 2_646 ?
O9 K2 O10 52.18(8) . . ?
O9 K2 O10 100.76(9) . 3_767 ?
O10 K2 Mo1 125.66(7) . 2_646 ?
O10 K2 Mo1 63.26(6) 3_767 2_646 ?
O10 K2 P1 26.57(6) . . ?
O10 K2 P1 94.61(7) 3_767 . ?
O10 K2 P2 111.09(7) . 1_655 ?
O10 K2 P2 78.06(6) 3_767 1_655 ?
O10 K2 O3 95.33(9) . 4_666 ?
O10 K2 O4 97.22(9) . 1_655 ?
O10 K2 O4 55.46(8) 3_767 1_655 ?
O10 K2 O6 57.56(8) . 4_666 ?
O10 K2 O10 79.92(10) . 3_767 ?
K1 Mg1 K1 128.29(4) . 2_546 ?
K1 Mg1 K2 99.76(4) 2_546 2_656 ?
K1 Mg1 K2 69.16(4) . 3_667 ?
K1 Mg1 K2 79.56(4) 2_546 1_455 ?
K1 Mg1 K2 79.62(4) . 2_656 ?
K1 Mg1 K2 72.43(4) . 1_455 ?
K1 Mg1 K2 139.38(5) 2_546 3_667 ?
K2 Mg1 K2 120.50(4) 3_667 2_656 ?
K2 Mg1 K2 142.60(4) 1_455 2_656 ?
K2 Mg1 K2 71.82(4) 3_667 1_455 ?
P1 Mg1 K1 87.60(4) 3_667 2_546 ?
P1 Mg1 K1 120.34(5) 3_667 . ?
P1 Mg1 K2 147.27(5) 3_667 2_656 ?
P1 Mg1 K2 56.00(4) 3_667 3_667 ?
P1 Mg1 K2 70.01(4) 3_667 1_455 ?
O4 Mg1 K1 51.65(11) . . ?
O4 Mg1 K1 76.65(11) . 2_546 ?
O4 Mg1 K2 87.81(11) . 2_656 ?
O4 Mg1 K2 55.37(10) . 1_455 ?
O4 Mg1 K2 107.89(12) . 3_667 ?
O4 Mg1 P1 124.87(11) . 3_667 ?
O4 Mg1 O6 104.86(15) . 2_556 ?
O4 Mg1 O7 112.01(16) . . ?
O4 Mg1 O10 105.86(15) . 3_667 ?
O6 Mg1 K1 165.65(11) 2_556 2_546 ?
O6 Mg1 K1 54.76(10) 2_556 . ?
O6 Mg1 K2 54.30(10) 2_556 3_667 ?
O6 Mg1 K2 113.29(11) 2_556 1_455 ?
O6 Mg1 K2 66.24(10) 2_556 2_656 ?
O6 Mg1 P1 102.54(11) 2_556 3_667 ?
O6 Mg1 O10 98.90(14) 2_556 3_667 ?
O7 Mg1 K1 51.92(11) . 2_546 ?
O7 Mg1 K1 142.36(12) . . ?
O7 Mg1 K2 130.75(12) . 1_455 ?
O7 Mg1 K2 64.95(11) . 2_656 ?
O7 Mg1 K2 139.97(12) . 3_667 ?
O7 Mg1 P1 96.97(12) . 3_667 ?
O7 Mg1 O6 115.91(15) . 2_556 ?
O7 Mg1 O10 117.69(16) . 3_667 ?
O10 Mg1 K1 94.29(10) 3_667 2_546 ?
O10 Mg1 K1 99.93(11) 3_667 . ?
O10 Mg1 K2 50.66(10) 3_667 1_455 ?
O10 Mg1 K2 45.17(9) 3_667 3_667 ?
O10 Mg1 K2 162.37(11) 3_667 2_656 ?
O10 Mg1 P1 22.44(10) 3_667 3_667 ?
K1 Mo1 K1 141.861(14) 4_675 . ?
K1 Mo1 K1 118.06(2) 4_675 3_566 ?
K1 Mo1 K1 93.95(2) . 3_566 ?
K1 Mo1 K2 65.08(3) 4_675 3_666 ?
K1 Mo1 K2 111.89(3) . 3_666 ?
K2 Mo1 K1 71.17(3) 3_666 3_566 ?
K2 Mo1 K1 87.60(3) 2_656 . ?
K2 Mo1 K1 72.90(3) 2_656 4_675 ?
K2 Mo1 K1 153.62(3) 2_656 3_566 ?
K2 Mo1 K2 132.24(2) 2_656 3_666 ?
O1 Mo1 K1 128.75(11) . 3_566 ?
O1 Mo1 K1 113.02(11) . 4_675 ?
O1 Mo1 K1 37.88(11) . . ?
O1 Mo1 K2 131.21(11) . 3_666 ?
O1 Mo1 K2 49.93(11) . 2_656 ?
O1 Mo1 O3 95.95(13) . . ?
O1 Mo1 O5 89.06(14) . 3_566 ?
O1 Mo1 O8 94.69(13) . 4_575 ?
O1 Mo1 O9 169.91(14) . 3_666 ?
O2 Mo1 K1 117.13(12) . 3_566 ?
O2 Mo1 K1 46.42(11) . 4_675 ?
O2 Mo1 K1 136.69(11) . . ?
O2 Mo1 K2 106.59(11) . 3_666 ?
O2 Mo1 K2 51.05(11) . 2_656 ?
O2 Mo1 O1 100.48(16) . . ?
O2 Mo1 O3 97.14(15) . . ?
O2 Mo1 O5 168.96(13) . 3_566 ?
O2 Mo1 O8 92.21(15) . 4_575 ?
O2 Mo1 O9 89.21(13) . 3_666 ?
O3 Mo1 K1 80.94(8) . . ?
O3 Mo1 K1 48.49(9) . 3_566 ?
O3 Mo1 K1 135.42(9) . 4_675 ?
O3 Mo1 K2 106.14(9) . 2_656 ?
O3 Mo1 K2 119.40(9) . 3_666 ?
O3 Mo1 O5 87.30(13) . 3_566 ?
O3 Mo1 O8 164.32(13) . 4_575 ?
O3 Mo1 O9 85.57(11) . 3_666 ?
O5 Mo1 K1 124.51(9) 3_566 4_675 ?
O5 Mo1 K1 58.98(9) 3_566 3_566 ?
O5 Mo1 K1 53.92(9) 3_566 . ?
O5 Mo1 K2 137.22(9) 3_566 2_656 ?
O5 Mo1 K2 62.56(9) 3_566 3_666 ?
O5 Mo1 O9 81.03(12) 3_566 3_666 ?
O8 Mo1 K1 48.19(10) 4_575 4_675 ?
O8 Mo1 K1 100.76(9) 4_575 . ?
O8 Mo1 K1 115.90(9) 4_575 3_566 ?
O8 Mo1 K2 89.53(9) 4_575 2_656 ?
O8 Mo1 K2 45.37(9) 4_575 3_666 ?
O8 Mo1 O5 81.38(13) 4_575 3_566 ?
O8 Mo1 O9 81.99(11) 4_575 3_666 ?
O9 Mo1 K1 133.25(9) 3_666 . ?
O9 Mo1 K1 46.57(8) 3_666 3_566 ?
O9 Mo1 K1 71.76(8) 3_666 4_675 ?
O9 Mo1 K2 139.12(9) 3_666 2_656 ?
O9 Mo1 K2 41.46(8) 3_666 3_666 ?
K1 P1 K1 130.32(4) 1_655 2_546 ?
K1 P1 K2 68.49(3) 1_655 2_656 ?
K2 P1 K1 107.71(4) 2_656 2_546 ?
K2 P1 K1 69.41(4) . 2_546 ?
K2 P1 K1 83.88(4) . 1_655 ?
K2 P1 K2 140.85(3) . 2_656 ?
Mg1 P1 K1 131.52(5) 3_667 1_655 ?
Mg1 P1 K1 81.02(4) 3_667 2_546 ?
Mg1 P1 K2 145.17(5) 3_667 2_656 ?
Mg1 P1 K2 73.98(4) 3_667 . ?
O7 P1 K1 145.73(14) . 1_655 ?
O7 P1 K1 48.32(13) . 2_546 ?
O7 P1 K2 79.68(14) . 2_656 ?
O7 P1 K2 115.96(14) . . ?
O7 P1 Mg1 82.32(14) . 3_667 ?
O7 P1 O8 110.36(19) . . ?
O7 P1 O9 112.02(18) . . ?
O7 P1 O10 111.48(19) . . ?
O8 P1 K1 150.47(13) . 2_546 ?
O8 P1 K1 52.42(13) . 1_655 ?
O8 P1 K2 43.01(12) . 2_656 ?
O8 P1 K2 133.13(14) . . ?
O8 P1 Mg1 120.18(12) . 3_667 ?
O9 P1 K1 73.39(12) . 2_546 ?
O9 P1 K1 57.43(12) . 1_655 ?
O9 P1 K2 90.00(12) . 2_656 ?
O9 P1 K2 51.14(11) . . ?
O9 P1 Mg1 124.48(12) . 3_667 ?
O9 P1 O8 104.85(17) . . ?
O10 P1 K1 102.69(14) . 1_655 ?
O10 P1 K1 97.96(13) . 2_546 ?
O10 P1 K2 58.61(12) . . ?
O10 P1 K2 152.26(13) . 2_656 ?
O10 P1 Mg1 29.36(13) . 3_667 ?
O10 P1 O8 110.25(18) . . ?
O10 P1 O9 107.65(17) . . ?
K1 P2 K1 104.76(3) 3_566 . ?
K1 P2 K2 121.14(4) 3_566 1_455 ?
K1 P2 K2 67.08(3) 3_566 4_565 ?
K1 P2 K2 143.26(4) . 4_565 ?
K1 P2 K2 77.48(3) . 1_455 ?
K2 P2 K2 138.39(3) 1_455 4_565 ?
O3 P2 K1 57.74(12) . 3_566 ?
O3 P2 K1 93.00(12) . . ?
O3 P2 K2 51.55(11) . 4_565 ?
O3 P2 K2 169.94(12) . 1_455 ?
O4 P2 K1 154.21(14) . 3_566 ?
O4 P2 K1 50.32(13) . . ?
O4 P2 K2 126.88(14) . 4_565 ?
O4 P2 K2 65.41(13) . 1_455 ?
O4 P2 O3 111.00(18) . . ?
O4 P2 O5 110.14(19) . . ?
O4 P2 O6 112.38(18) . . ?
O5 P2 K1 70.90(13) . . ?
O5 P2 K1 58.19(12) . 3_566 ?
O5 P2 K2 68.41(13) . 1_455 ?
O5 P2 K2 122.66(13) . 4_565 ?
O5 P2 O3 105.59(17) . . ?
O6 P2 K1 93.38(13) . 3_566 ?
O6 P2 K1 158.77(13) . . ?
O6 P2 K2 83.78(13) . 1_455 ?
O6 P2 K2 54.61(12) . 4_565 ?
O6 P2 O3 106.15(17) . . ?
O6 P2 O5 111.30(19) . . ?
K1 O1 K2 138.79(12) . 2_656 ?
Mo1 O1 K1 119.03(16) . . ?
Mo1 O1 K2 101.63(14) . 2_656 ?
K2 O2 K1 100.13(11) 2_656 4_675 ?
Mo1 O2 K1 107.87(15) . 4_675 ?
Mo1 O2 K2 100.46(14) . 2_656 ?
K1 O3 K2 83.52(8) 3_566 4_565 ?
Mo1 O3 K1 102.52(11) . 3_566 ?
Mo1 O3 K2 119.01(12) . 4_565 ?
P2 O3 K1 96.49(14) . 3_566 ?
P2 O3 K2 105.17(14) . 4_565 ?
P2 O3 Mo1 133.27(18) . . ?
K1 O4 K2 93.64(10) . 1_455 ?
Mg1 O4 K1 96.74(13) . . ?
Mg1 O4 K2 96.90(12) . 1_455 ?
P2 O4 K1 105.87(16) . . ?
P2 O4 K2 90.80(14) . 1_455 ?
P2 O4 Mg1 155.6(2) . . ?
K1 O5 K1 122.53(10) 3_566 . ?
Mo1 O5 K1 89.02(11) 3_566 . ?
Mo1 O5 K1 92.36(11) 3_566 3_566 ?
P2 O5 K1 84.24(14) . . ?
P2 O5 K1 96.98(15) . 3_566 ?
P2 O5 Mo1 170.4(2) . 3_566 ?
K1 O6 K2 88.01(9) 2_546 4_565 ?
Mg1 O6 K1 93.23(12) 2_546 2_546 ?
Mg1 O6 K2 96.38(12) 2_546 4_565 ?
P2 O6 K1 119.48(16) . 2_546 ?
P2 O6 K2 102.79(14) . 4_565 ?
P2 O6 Mg1 142.2(2) . 2_546 ?
Mg1 O7 K1 98.04(13) . 2_546 ?
P1 O7 K1 109.72(17) . 2_546 ?
P1 O7 Mg1 152.1(2) . . ?
K1 O8 K2 92.55(10) 1_655 2_656 ?
Mo1 O8 K1 99.31(12) 4_676 1_655 ?
Mo1 O8 K2 104.39(12) 4_676 2_656 ?
P1 O8 K1 101.57(15) . 1_655 ?
P1 O8 K2 115.24(16) . 2_656 ?
P1 O8 Mo1 133.81(18) . 4_676 ?
K2 O9 K1 108.50(11) . 1_655 ?
Mo1 O9 K1 101.57(11) 3_666 1_655 ?
Mo1 O9 K2 106.79(11) 3_666 . ?
P1 O9 K1 96.51(14) . 1_655 ?
P1 O9 K2 102.51(14) . . ?
P1 O9 Mo1 138.24(19) . 3_666 ?
K2 O10 K2 100.08(10) . 3_767 ?
Mg1 O10 K2 101.54(13) 3_667 3_767 ?
Mg1 O10 K2 106.31(13) 3_667 . ?
P1 O10 K2 94.81(14) . . ?
P1 O10 K2 120.86(16) . 3_767 ?
P1 O10 Mg1 128.2(2) . 3_667 ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 2345925'
loop_
_audit_author_name
_audit_author_address
'Zhixia Gao'
;Xinjiang Normal University
China
;
_audit_update_record             
;
2024-04-05 deposited with the CCDC.	2024-05-02 downloaded from the CCDC.
;
_audit_creation_date             2021-04-06
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'K3 Mg2 Mo O14 P3'
_chemical_formula_sum            'K3 Mg2 Mo O14 P3'
_chemical_formula_weight         578.77
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   16.4088(10)
_cell_length_b                   15.8303(10)
_cell_length_c                   5.4483(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1415.23(18)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    1906
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.35
_cell_measurement_theta_min      2.57
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.308
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6150
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1316 before and 0.0921 after correction.
The Ratio of minimum to maximum transmission is 0.8248.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.716
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1120
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1215
_diffrn_reflns_av_unetI/netI     0.0784
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            10032
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.525
_diffrn_reflns_theta_min         2.482
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1255
_reflns_number_total             1684
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.783
_refine_diff_density_min         -1.301
_refine_diff_density_rms         0.182
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     115
_refine_ls_number_reflns         1684
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0711
_refine_ls_R_factor_gt           0.0466
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0407P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1049
_refine_ls_wR_factor_ref         0.1156
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mo1 Mo 0.89552(4) 0.250000 0.68025(13) 0.0158(2) Uani 1 2 d S T P . .
K2 K 0.49379(7) 0.11120(7) 0.2726(2) 0.0219(3) Uani 1 1 d . . . . .
P2 P 0.86164(8) 0.45557(8) 0.7206(3) 0.0147(3) Uani 1 1 d . . . . .
P1 P 0.57151(12) 0.250000 0.7248(4) 0.0175(4) Uani 1 2 d S T P . .
Mg1 Mg 0.65903(10) 0.43825(10) 0.7230(3) 0.0142(4) Uani 1 1 d . . . . .
O1 O 0.4897(3) 0.250000 0.5765(11) 0.0205(12) Uani 1 2 d S T P . .
O8 O 0.8865(2) 0.5152(2) 0.5150(8) 0.0251(9) Uani 1 1 d . . . . .
O9 O 0.8861(2) 0.4934(2) 0.9633(8) 0.0261(9) Uani 1 1 d . . . . .
O7 O 0.7734(2) 0.4329(3) 0.7083(8) 0.0296(10) Uani 1 1 d . . . . .
O6 O 0.9142(2) 0.3740(2) 0.6902(8) 0.0267(10) Uani 1 1 d . . . . .
O3 O 0.6187(2) 0.3283(2) 0.6460(9) 0.0272(10) Uani 1 1 d . . . . .
O4 O 0.8070(3) 0.250000 0.8352(12) 0.0269(14) Uani 1 2 d S T P . .
O2 O 0.5436(5) 0.250000 0.9925(11) 0.0401(17) Uani 1 2 d S T P . .
O5 O 0.8706(4) 0.250000 0.3758(12) 0.0353(15) Uani 1 2 d S T P . .
K1 K 0.71053(18) 0.250000 0.2611(7) 0.0964(13) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mo1 K2 3.6765(14) 6_656 ?
Mo1 K2 4.0391(14) 4_556 ?
Mo1 K2 3.6765(14) 4 ?
Mo1 K2 4.0391(14) 6_657 ?
Mo1 P1 2.934(2) 6_657 ?
Mo1 O1 2.036(5) 6_657 ?
Mo1 O6 1.987(4) 7_565 ?
Mo1 O6 1.987(4) . ?
Mo1 O4 1.679(6) . ?
Mo1 O5 1.708(6) . ?
Mo1 K1 3.799(4) . ?
K2 P2 3.4319(18) 8_755 ?
K2 P1 3.539(2) . ?
K2 O1 2.752(4) . ?
K2 O8 3.092(4) 4_455 ?
K2 O8 2.853(4) 8_755 ?
K2 O9 2.906(4) 8_755 ?
K2 O9 2.816(4) 4_456 ?
K2 O6 3.213(5) 4_456 ?
K2 O6 2.849(5) 4_455 ?
K2 O3 3.042(5) 7_565 ?
K2 O2 2.797(4) 1_554 ?
K2 O5 3.093(5) 6_556 ?
P2 O8 1.520(4) . ?
P2 O9 1.506(4) . ?
P2 O7 1.493(4) . ?
P2 O6 1.562(4) . ?
P1 O1 1.567(5) . ?
P1 O3 1.523(4) . ?
P1 O3 1.523(4) 7_565 ?
P1 O2 1.529(6) . ?
P1 K1 3.707(4) 1_556 ?
P1 K1 3.404(4) . ?
Mg1 O8 1.906(4) 2_665 ?
Mg1 O9 1.929(4) 2_664 ?
Mg1 O7 1.880(4) . ?
Mg1 O3 1.909(4) . ?
Mg1 K1 3.991(3) . ?
Mg1 K1 4.265(3) 1_556 ?
O3 K1 2.865(5) . ?
O4 K1 2.809(7) 1_556 ?
O2 K1 3.105(8) 1_556 ?
O5 K1 2.700(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
K2 Mo1 K2 65.91(4) 4_556 6_657 ?
K2 Mo1 K2 89.72(3) 6_656 6_657 ?
K2 Mo1 K2 73.40(4) 6_656 4 ?
K2 Mo1 K2 89.72(3) 4 4_556 ?
K2 Mo1 K2 130.19(4) 6_656 4_556 ?
K2 Mo1 K2 130.19(4) 4 6_657 ?
K2 Mo1 K1 86.96(5) 6_656 . ?
K2 Mo1 K1 86.96(5) 4 . ?
P1 Mo1 K2 58.46(4) 6_657 6_657 ?
P1 Mo1 K2 71.73(4) 6_657 4 ?
P1 Mo1 K2 71.73(4) 6_657 6_656 ?
P1 Mo1 K2 58.46(4) 6_657 4_556 ?
P1 Mo1 K1 153.20(7) 6_657 . ?
O1 Mo1 K2 38.41(8) 6_657 4_556 ?
O1 Mo1 K2 95.97(13) 6_657 4 ?
O1 Mo1 K2 38.41(8) 6_657 6_657 ?
O1 Mo1 K2 95.97(13) 6_657 6_656 ?
O1 Mo1 P1 30.47(16) 6_657 6_657 ?
O1 Mo1 K1 176.33(16) 6_657 . ?
O6 Mo1 K2 51.75(13) 7_565 6_657 ?
O6 Mo1 K2 117.09(13) . 6_657 ?
O6 Mo1 K2 51.75(13) . 4_556 ?
O6 Mo1 K2 117.09(13) 7_565 4_556 ?
O6 Mo1 K2 50.23(13) 7_565 6_656 ?
O6 Mo1 K2 122.74(12) 7_565 4 ?
O6 Mo1 K2 50.23(13) . 4 ?
O6 Mo1 K2 122.74(12) . 6_656 ?
O6 Mo1 P1 80.97(11) 7_565 6_657 ?
O6 Mo1 P1 80.97(11) . 6_657 ?
O6 Mo1 O1 82.24(12) 7_565 6_657 ?
O6 Mo1 O1 82.23(12) . 6_657 ?
O6 Mo1 O6 161.9(2) . 7_565 ?
O6 Mo1 K1 98.04(12) 7_565 . ?
O6 Mo1 K1 98.05(12) . . ?
O4 Mo1 K2 135.76(11) . 4 ?
O4 Mo1 K2 135.76(11) . 6_656 ?
O4 Mo1 K2 88.53(18) . 6_657 ?
O4 Mo1 K2 88.53(18) . 4_556 ?
O4 Mo1 P1 139.7(2) . 6_657 ?
O4 Mo1 O1 109.2(3) . 6_657 ?
O4 Mo1 O6 96.89(11) . 7_565 ?
O4 Mo1 O6 96.89(11) . . ?
O4 Mo1 O5 106.3(3) . . ?
O4 Mo1 K1 67.1(2) . . ?
O5 Mo1 K2 144.30(8) . 4_556 ?
O5 Mo1 K2 144.30(8) . 6_657 ?
O5 Mo1 K2 56.86(15) . 4 ?
O5 Mo1 K2 56.86(15) . 6_656 ?
O5 Mo1 P1 114.0(2) . 6_657 ?
O5 Mo1 O1 144.5(3) . 6_657 ?
O5 Mo1 O6 93.64(14) . 7_565 ?
O5 Mo1 O6 93.64(14) . . ?
O5 Mo1 K1 39.2(2) . . ?
K1 Mo1 K2 139.71(3) . 4_556 ?
K1 Mo1 K2 139.71(3) . 6_657 ?
P2 K2 P1 104.72(5) 8_755 . ?
O1 K2 P2 129.78(11) . 8_755 ?
O1 K2 P1 25.08(10) . . ?
O1 K2 O8 137.58(14) . 8_755 ?
O1 K2 O8 143.87(13) . 4_455 ?
O1 K2 O9 98.42(13) . 4_456 ?
O1 K2 O9 108.31(14) . 8_755 ?
O1 K2 O6 51.95(12) . 4_456 ?
O1 K2 O6 117.09(13) . 4_455 ?
O1 K2 O3 50.43(12) . 7_565 ?
O1 K2 O2 73.04(14) . 1_554 ?
O1 K2 O5 64.79(15) . 6_556 ?
O8 K2 P2 83.52(8) 4_455 8_755 ?
O8 K2 P2 25.96(8) 8_755 8_755 ?
O8 K2 P1 163.71(9) 4_455 . ?
O8 K2 P1 115.16(10) 8_755 . ?
O8 K2 O8 78.35(12) 8_755 4_455 ?
O8 K2 O9 50.72(11) 8_755 8_755 ?
O8 K2 O6 140.07(11) 8_755 4_456 ?
O8 K2 O6 106.12(11) 4_455 4_456 ?
O8 K2 O3 91.88(12) 8_755 7_565 ?
O8 K2 O5 87.42(12) 4_455 6_556 ?
O8 K2 O5 134.41(15) 8_755 6_556 ?
O9 K2 P2 25.82(8) 8_755 8_755 ?
O9 K2 P2 93.09(9) 4_456 8_755 ?
O9 K2 P1 84.56(9) 8_755 . ?
O9 K2 P1 103.61(10) 4_456 . ?
O9 K2 O8 98.74(11) 8_755 4_455 ?
O9 K2 O8 61.40(11) 4_456 4_455 ?
O9 K2 O8 111.73(11) 4_456 8_755 ?
O9 K2 O9 82.27(12) 4_456 8_755 ?
O9 K2 O6 89.82(11) 8_755 4_456 ?
O9 K2 O6 47.37(10) 4_456 4_456 ?
O9 K2 O6 102.30(12) 4_456 4_455 ?
O9 K2 O3 60.40(10) 8_755 7_565 ?
O9 K2 O3 105.42(12) 4_456 7_565 ?
O9 K2 O5 173.09(14) 8_755 6_556 ?
O9 K2 O5 98.11(13) 4_456 6_556 ?
O6 K2 P2 114.11(8) 4_456 8_755 ?
O6 K2 P2 107.62(9) 4_455 8_755 ?
O6 K2 P1 57.79(7) 4_456 . ?
O6 K2 P1 136.89(9) 4_455 . ?
O6 K2 O8 48.99(10) 4_455 4_455 ?
O6 K2 O8 85.64(12) 4_455 8_755 ?
O6 K2 O9 132.85(12) 4_455 8_755 ?
O6 K2 O6 127.88(14) 4_455 4_456 ?
O6 K2 O3 150.99(11) 4_455 7_565 ?
O6 K2 O5 53.89(14) 4_455 6_556 ?
O3 K2 P2 79.38(8) 7_565 8_755 ?
O3 K2 P1 25.35(7) 7_565 . ?
O3 K2 O8 157.86(11) 7_565 4_455 ?
O3 K2 O6 68.99(11) 7_565 4_456 ?
O3 K2 O5 113.05(12) 7_565 6_556 ?
O2 K2 P2 108.47(14) 1_554 8_755 ?
O2 K2 P1 77.69(12) 1_554 . ?
O2 K2 O8 87.06(14) 1_554 8_755 ?
O2 K2 O8 113.47(16) 1_554 4_455 ?
O2 K2 O9 120.07(17) 1_554 8_755 ?
O2 K2 O9 157.47(17) 1_554 4_456 ?
O2 K2 O6 65.57(16) 1_554 4_455 ?
O2 K2 O6 123.93(13) 1_554 4_456 ?
O2 K2 O3 85.45(17) 1_554 7_565 ?
O2 K2 O5 59.37(17) 1_554 6_556 ?
O5 K2 P2 160.06(13) 6_556 8_755 ?
O5 K2 P1 88.65(11) 6_556 . ?
O5 K2 O6 85.45(14) 6_556 4_456 ?
K2 P2 K2 74.69(4) 8_766 4_556 ?
K2 P2 K2 96.94(4) 4 4_556 ?
K2 P2 K2 81.75(4) 8_766 4 ?
O8 P2 K2 125.10(16) . 4_556 ?
O8 P2 K2 58.17(16) . 4 ?
O8 P2 K2 55.23(16) . 8_766 ?
O8 P2 O6 106.7(2) . . ?
O9 P2 K2 127.56(17) . 4 ?
O9 P2 K2 57.18(16) . 8_766 ?
O9 P2 K2 45.21(15) . 4_556 ?
O9 P2 O8 109.2(2) . . ?
O9 P2 O6 105.9(2) . . ?
O7 P2 K2 147.81(17) . 8_766 ?
O7 P2 K2 122.55(18) . 4_556 ?
O7 P2 K2 118.61(19) . 4 ?
O7 P2 O8 112.1(2) . . ?
O7 P2 O9 113.1(2) . . ?
O7 P2 O6 109.4(2) . . ?
O6 P2 K2 60.97(17) . 4_556 ?
O6 P2 K2 49.27(17) . 4 ?
O6 P2 K2 102.74(15) . 8_766 ?
Mo1 P1 K2 76.59(5) 6_557 . ?
Mo1 P1 K2 76.59(5) 6_557 7_565 ?
Mo1 P1 K1 142.23(9) 6_557 . ?
Mo1 P1 K1 117.83(8) 6_557 1_556 ?
K2 P1 K2 76.76(6) . 7_565 ?
K2 P1 K1 140.40(3) 7_565 1_556 ?
K2 P1 K1 140.40(3) . 1_556 ?
O1 P1 Mo1 41.2(2) . 6_557 ?
O1 P1 K2 48.11(12) . . ?
O1 P1 K2 48.11(12) . 7_565 ?
O1 P1 K1 101.0(2) . . ?
O1 P1 K1 159.0(2) . 1_556 ?
O3 P1 Mo1 123.35(16) . 6_557 ?
O3 P1 Mo1 123.34(16) 7_565 6_557 ?
O3 P1 K2 58.76(17) 7_565 . ?
O3 P1 K2 119.5(2) . . ?
O3 P1 K2 58.76(17) . 7_565 ?
O3 P1 K2 119.5(2) 7_565 7_565 ?
O3 P1 O1 106.8(2) 7_565 . ?
O3 P1 O1 106.8(2) . . ?
O3 P1 O3 109.0(3) . 7_565 ?
O3 P1 O2 114.9(2) 7_565 . ?
O3 P1 O2 114.9(2) . . ?
O3 P1 K1 56.66(17) . . ?
O3 P1 K1 56.66(17) 7_565 . ?
O3 P1 K1 84.82(19) . 1_556 ?
O3 P1 K1 84.82(19) 7_565 1_556 ?
O2 P1 Mo1 62.4(3) . 6_557 ?
O2 P1 K2 123.8(2) . . ?
O2 P1 K2 123.8(2) . 7_565 ?
O2 P1 O1 103.6(4) . . ?
O2 P1 K1 155.3(3) . . ?
O2 P1 K1 55.4(3) . 1_556 ?
K1 P1 K2 74.02(6) . 7_565 ?
K1 P1 K2 74.02(6) . . ?
K1 P1 K1 99.94(9) . 1_556 ?
K2 Mg1 K2 70.66(4) 3_656 7_565 ?
K2 Mg1 K2 71.97(4) 3_656 7_566 ?
K2 Mg1 K2 87.71(4) 7_565 7_566 ?
K2 Mg1 K1 134.24(7) 3_656 . ?
K2 Mg1 K1 130.14(6) 3_656 1_556 ?
K2 Mg1 K1 116.64(6) 7_565 1_556 ?
K2 Mg1 K1 59.83(5) 7_566 1_556 ?
K2 Mg1 K1 65.39(6) 7_565 . ?
O8 Mg1 K2 56.27(13) 2_665 3_656 ?
O8 Mg1 K2 37.61(12) 2_665 7_566 ?
O8 Mg1 K2 110.15(14) 2_665 7_565 ?
O8 Mg1 O9 104.16(19) 2_665 2_664 ?
O8 Mg1 O3 113.6(2) 2_665 . ?
O8 Mg1 K1 76.94(14) 2_665 1_556 ?
O8 Mg1 K1 153.91(15) 2_665 . ?
O9 Mg1 K2 48.06(13) 2_664 3_656 ?
O9 Mg1 K2 112.80(14) 2_664 7_566 ?
O9 Mg1 K2 50.06(13) 2_664 7_565 ?
O9 Mg1 K1 92.17(14) 2_664 . ?
O9 Mg1 K1 166.47(15) 2_664 1_556 ?
O7 Mg1 K2 135.03(15) . 3_656 ?
O7 Mg1 K2 133.35(16) . 7_565 ?
O7 Mg1 K2 132.85(16) . 7_566 ?
O7 Mg1 O8 116.4(2) . 2_665 ?
O7 Mg1 O9 112.2(2) . 2_664 ?
O7 Mg1 O3 107.23(19) . . ?
O7 Mg1 K1 74.24(15) . . ?
O7 Mg1 K1 78.47(14) . 1_556 ?
O3 Mg1 K2 75.99(14) . 7_566 ?
O3 Mg1 K2 54.08(14) . 7_565 ?
O3 Mg1 K2 116.06(14) . 3_656 ?
O3 Mg1 O9 102.6(2) . 2_664 ?
O3 Mg1 K1 65.34(15) . 1_556 ?
O3 Mg1 K1 41.77(13) . . ?
K1 Mg1 K2 117.16(6) . 7_566 ?
K1 Mg1 K1 82.52(3) . 1_556 ?
Mo1 O1 K2 114.23(13) 6_557 7_565 ?
Mo1 O1 K2 114.23(13) 6_557 . ?
K2 O1 K2 106.0(2) . 7_565 ?
P1 O1 Mo1 108.3(3) . 6_557 ?
P1 O1 K2 106.81(16) . . ?
P1 O1 K2 106.81(16) . 7_565 ?
K2 O8 K2 101.65(12) 8_766 4 ?
P2 O8 K2 97.14(18) . 4 ?
P2 O8 K2 98.8(2) . 8_766 ?
P2 O8 Mg1 138.6(3) . 2_664 ?
Mg1 O8 K2 92.88(17) 2_664 4 ?
Mg1 O8 K2 118.33(17) 2_664 8_766 ?
K2 O9 K2 97.73(12) 4_556 8_766 ?
P2 O9 K2 112.5(2) . 4_556 ?
P2 O9 K2 97.0(2) . 8_766 ?
P2 O9 Mg1 139.9(3) . 2_665 ?
Mg1 O9 K2 99.34(16) 2_665 8_766 ?
Mg1 O9 K2 101.31(17) 2_665 4_556 ?
P2 O7 Mg1 162.8(3) . . ?
Mo1 O6 K2 99.20(16) . 4_556 ?
Mo1 O6 K2 97.36(16) . 4 ?
K2 O6 K2 127.88(14) 4 4_556 ?
P2 O6 Mo1 137.2(2) . . ?
P2 O6 K2 93.87(19) . 4_556 ?
P2 O6 K2 106.2(2) . 4 ?
P1 O3 K2 95.9(2) . 7_565 ?
P1 O3 Mg1 148.9(3) . . ?
P1 O3 K1 96.97(19) . . ?
Mg1 O3 K2 95.38(16) . 7_565 ?
Mg1 O3 K1 111.89(17) . . ?
K1 O3 K2 90.06(15) . 7_565 ?
Mo1 O4 K1 154.5(3) . 1_556 ?
K2 O2 K2 103.5(2) 7_566 1_556 ?
K2 O2 K1 90.05(17) 7_566 1_556 ?
K2 O2 K1 90.05(17) 1_556 1_556 ?
P1 O2 K2 127.44(12) . 7_566 ?
P1 O2 K2 127.44(12) . 1_556 ?
P1 O2 K1 100.7(4) . 1_556 ?
Mo1 O5 K2 95.59(18) . 4 ?
Mo1 O5 K2 95.59(18) . 6_656 ?
Mo1 O5 K1 117.2(3) . . ?
K2 O5 K2 90.53(17) 4 6_656 ?
K1 O5 K2 125.11(14) . 6_656 ?
K1 O5 K2 125.11(14) . 4 ?
Mo1 K1 K2 132.12(7) . 7_565 ?
Mo1 K1 K2 132.12(7) . . ?
Mo1 K1 Mg1 77.88(7) . 7_565 ?
Mo1 K1 Mg1 77.88(7) . . ?
K2 K1 K2 63.41(5) . 7_565 ?
P1 K1 Mo1 164.94(10) 1_554 . ?
P1 K1 Mo1 95.12(9) . . ?
P1 K1 K2 59.23(5) 1_554 . ?
P1 K1 K2 59.23(5) 1_554 7_565 ?
P1 K1 K2 54.47(5) . . ?
P1 K1 K2 54.47(5) . 7_565 ?
P1 K1 P1 99.94(9) . 1_554 ?
P1 K1 Mg1 111.51(6) 1_554 7_565 ?
P1 K1 Mg1 52.41(5) . . ?
P1 K1 Mg1 52.41(5) . 7_565 ?
P1 K1 Mg1 111.51(6) 1_554 . ?
Mg1 K1 K2 101.70(7) . . ?
Mg1 K1 K2 54.41(4) 7_565 . ?
Mg1 K1 K2 101.70(7) 7_565 7_565 ?
Mg1 K1 K2 54.41(4) . 7_565 ?
Mg1 K1 Mg1 96.61(9) 7_565 . ?
O3 K1 Mo1 88.87(12) . . ?
O3 K1 Mo1 88.87(12) 7_565 . ?
O3 K1 K2 76.64(10) 7_565 7_565 ?
O3 K1 K2 46.68(10) 7_565 . ?
O3 K1 K2 46.68(10) . 7_565 ?
O3 K1 K2 76.64(10) . . ?
O3 K1 P1 26.37(8) 7_565 . ?
O3 K1 P1 26.37(8) . . ?
O3 K1 P1 104.67(12) . 1_554 ?
O3 K1 P1 104.67(12) 7_565 1_554 ?
O3 K1 Mg1 75.53(11) 7_565 . ?
O3 K1 Mg1 26.34(8) 7_565 7_565 ?
O3 K1 Mg1 75.53(11) . 7_565 ?
O3 K1 Mg1 26.34(8) . . ?
O3 K1 O3 51.29(16) . 7_565 ?
O3 K1 O2 83.16(15) . 1_554 ?
O3 K1 O2 83.16(15) 7_565 1_554 ?
O4 K1 Mo1 92.65(14) 1_554 . ?
O4 K1 K2 119.46(13) 1_554 7_565 ?
O4 K1 K2 119.46(13) 1_554 . ?
O4 K1 P1 172.23(18) 1_554 . ?
O4 K1 P1 72.29(14) 1_554 1_554 ?
O4 K1 Mg1 129.81(5) 1_554 7_565 ?
O4 K1 Mg1 129.81(5) 1_554 . ?
O4 K1 O3 154.32(8) 1_554 . ?
O4 K1 O3 154.32(8) 1_554 7_565 ?
O4 K1 O2 96.2(2) 1_554 1_554 ?
O2 K1 Mo1 171.16(16) 1_554 . ?
O2 K1 K2 42.00(8) 1_554 . ?
O2 K1 K2 42.00(8) 1_554 7_565 ?
O2 K1 P1 76.04(14) 1_554 . ?
O2 K1 P1 23.90(12) 1_554 1_554 ?
O2 K1 Mg1 96.34(10) 1_554 7_565 ?
O2 K1 Mg1 96.34(10) 1_554 . ?
O5 K1 Mo1 23.57(15) . . ?
O5 K1 K2 145.49(8) . 7_565 ?
O5 K1 K2 145.49(8) . . ?
O5 K1 P1 118.69(19) . . ?
O5 K1 P1 141.37(19) . 1_554 ?
O5 K1 Mg1 93.44(13) . . ?
O5 K1 Mg1 93.44(13) . 7_565 ?
O5 K1 O3 110.02(19) . 7_565 ?
O5 K1 O3 110.02(19) . . ?
O5 K1 O4 69.1(2) . 1_554 ?
O5 K1 O2 165.3(2) . 1_554 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Mo1 P1 O1 K2 -123.48(15) 6_557 . . . ?
Mo1 P1 O1 K2 123.48(15) 6_557 . . 7_565 ?
Mo1 P1 O3 K2 -43.6(2) 6_557 . . 7_565 ?
Mo1 P1 O3 Mg1 67.1(6) 6_557 . . . ?
Mo1 P1 O3 K1 -134.41(14) 6_557 . . . ?
Mo1 P1 O2 K2 81.6(4) 6_557 . . 1_556 ?
Mo1 P1 O2 K2 -81.6(4) 6_557 . . 7_566 ?
Mo1 P1 O2 K1 180.000(1) 6_557 . . 1_556 ?
K2 Mo1 O4 K1 -121.05(19) 4 . . 1_556 ?
K2 Mo1 O4 K1 -32.969(18) 4_556 . . 1_556 ?
K2 Mo1 O4 K1 32.969(19) 6_657 . . 1_556 ?
K2 Mo1 O4 K1 121.05(19) 6_656 . . 1_556 ?
K2 Mo1 O5 K2 114.34(19) 4_556 . . 6_656 ?
K2 Mo1 O5 K2 -114.34(19) 6_657 . . 4 ?
K2 Mo1 O5 K2 -23.3(4) 6_657 . . 6_656 ?
K2 Mo1 O5 K2 23.3(4) 4_556 . . 4 ?
K2 Mo1 O5 K2 91.1(2) 4 . . 6_656 ?
K2 Mo1 O5 K2 -91.1(2) 6_656 . . 4 ?
K2 Mo1 O5 K1 134.46(10) 6_656 . . . ?
K2 Mo1 O5 K1 -134.46(10) 4 . . . ?
K2 Mo1 O5 K1 -111.2(3) 4_556 . . . ?
K2 Mo1 O5 K1 111.2(3) 6_657 . . . ?
K2 P2 O8 K2 -103.03(15) 4 . . 8_766 ?
K2 P2 O8 K2 103.03(15) 8_766 . . 4 ?
K2 P2 O8 K2 -28.2(2) 4_556 . . 8_766 ?
K2 P2 O8 K2 74.78(18) 4_556 . . 4 ?
K2 P2 O8 Mg1 177.4(3) 4_556 . . 2_664 ?
K2 P2 O8 Mg1 102.6(4) 4 . . 2_664 ?
K2 P2 O8 Mg1 -154.4(5) 8_766 . . 2_664 ?
K2 P2 O9 K2 44.7(2) 4 . . 8_766 ?
K2 P2 O9 K2 101.4(2) 4_556 . . 8_766 ?
K2 P2 O9 K2 -56.7(3) 4 . . 4_556 ?
K2 P2 O9 K2 -101.4(2) 8_766 . . 4_556 ?
K2 P2 O9 Mg1 -145.1(5) 4_556 . . 2_665 ?
K2 P2 O9 Mg1 158.2(3) 4 . . 2_665 ?
K2 P2 O9 Mg1 113.5(4) 8_766 . . 2_665 ?
K2 P2 O7 Mg1 -135.9(10) 4 . . . ?
K2 P2 O7 Mg1 -11.9(14) 8_766 . . . ?
K2 P2 O7 Mg1 103.3(10) 4_556 . . . ?
K2 P2 O6 Mo1 172.2(3) 8_766 . . . ?
K2 P2 O6 Mo1 108.0(4) 4_556 . . . ?
K2 P2 O6 Mo1 -120.7(5) 4 . . . ?
K2 P2 O6 K2 -131.33(19) 4_556 . . 4 ?
K2 P2 O6 K2 131.33(19) 4 . . 4_556 ?
K2 P2 O6 K2 64.21(12) 8_766 . . 4_556 ?
K2 P2 O6 K2 -67.12(16) 8_766 . . 4 ?
K2 P1 O1 Mo1 -123.48(15) 7_565 . . 6_557 ?
K2 P1 O1 Mo1 123.48(15) . . . 6_557 ?
K2 P1 O1 K2 113.0(3) 7_565 . . . ?
K2 P1 O1 K2 -113.0(3) . . . 7_565 ?
K2 P1 O3 K2 49.42(17) . . . 7_565 ?
K2 P1 O3 Mg1 160.1(4) . . . . ?
K2 P1 O3 Mg1 110.7(5) 7_565 . . . ?
K2 P1 O3 K1 -90.79(18) 7_565 . . . ?
K2 P1 O3 K1 -41.4(2) . . . . ?
K2 P1 O2 K2 33.3(6) . . . 1_556 ?
K2 P1 O2 K2 130.0(3) 7_565 . . 1_556 ?
K2 P1 O2 K2 -130.0(3) . . . 7_566 ?
K2 P1 O2 K2 -33.3(6) 7_565 . . 7_566 ?
K2 P1 O2 K1 131.65(16) . . . 1_556 ?
K2 P1 O2 K1 -131.65(16) 7_565 . . 1_556 ?
K2 Mg1 O7 P2 126.2(10) 7_565 . . . ?
K2 Mg1 O7 P2 18.7(12) 3_656 . . . ?
K2 Mg1 O7 P2 -90.7(11) 7_566 . . . ?
P1 Mo1 O4 K1 0.000(2) 6_657 . . 1_556 ?
P1 Mo1 O5 K2 45.54(10) 6_657 . . 6_656 ?
P1 Mo1 O5 K2 -45.54(10) 6_657 . . 4 ?
P1 Mo1 O5 K1 180.0 6_657 . . . ?
O1 Mo1 O4 K1 0.000(1) 6_657 . . 1_556 ?
O1 Mo1 O5 K2 -45.54(10) 6_657 . . 4 ?
O1 Mo1 O5 K2 45.54(10) 6_657 . . 6_656 ?
O1 Mo1 O5 K1 180.000(0) 6_657 . . . ?
O1 P1 O3 K2 -1.5(2) . . . 7_565 ?
O1 P1 O3 Mg1 109.2(5) . . . . ?
O1 P1 O3 K1 -92.3(2) . . . . ?
O1 P1 O2 K2 -81.6(4) . . . 7_566 ?
O1 P1 O2 K2 81.6(4) . . . 1_556 ?
O1 P1 O2 K1 180.000(1) . . . 1_556 ?
O8 P2 O9 K2 -120.8(2) . . . 4_556 ?
O8 P2 O9 K2 -19.4(2) . . . 8_766 ?
O8 P2 O9 Mg1 94.1(4) . . . 2_665 ?
O8 P2 O7 Mg1 -71.2(11) . . . . ?
O8 P2 O6 Mo1 -130.6(4) . . . . ?
O8 P2 O6 K2 -10.0(3) . . . 4 ?
O8 P2 O6 K2 121.34(19) . . . 4_556 ?
O8 Mg1 O7 P2 -48.9(11) 2_665 . . . ?
O9 P2 O8 K2 122.93(19) . . . 4 ?
O9 P2 O8 K2 19.9(2) . . . 8_766 ?
O9 P2 O8 Mg1 -134.4(4) . . . 2_664 ?
O9 P2 O7 Mg1 52.8(11) . . . . ?
O9 P2 O6 Mo1 113.1(4) . . . . ?
O9 P2 O6 K2 5.1(2) . . . 4_556 ?
O9 P2 O6 K2 -126.2(2) . . . 4 ?
O9 Mg1 O7 P2 70.8(11) 2_664 . . . ?
O7 P2 O8 K2 146.1(2) . . . 8_766 ?
O7 P2 O8 K2 -110.9(2) . . . 4 ?
O7 P2 O8 Mg1 -8.3(5) . . . 2_664 ?
O7 P2 O9 K2 -145.03(19) . . . 8_766 ?
O7 P2 O9 K2 113.6(2) . . . 4_556 ?
O7 P2 O9 Mg1 -31.5(5) . . . 2_665 ?
O7 P2 O6 Mo1 -9.2(5) . . . . ?
O7 P2 O6 K2 -117.2(2) . . . 4_556 ?
O7 P2 O6 K2 111.5(2) . . . 4 ?
O6 Mo1 O4 K1 -84.14(13) . . . 1_556 ?
O6 Mo1 O4 K1 84.14(13) 7_565 . . 1_556 ?
O6 Mo1 O5 K2 36.19(16) . . . 4 ?
O6 Mo1 O5 K2 127.27(14) . . . 6_656 ?
O6 Mo1 O5 K2 -36.19(16) 7_565 . . 6_656 ?
O6 Mo1 O5 K2 -127.27(14) 7_565 . . 4 ?
O6 Mo1 O5 K1 -98.27(11) . . . . ?
O6 Mo1 O5 K1 98.27(11) 7_565 . . . ?
O6 P2 O8 K2 -94.1(2) . . . 8_766 ?
O6 P2 O8 K2 8.9(2) . . . 4 ?
O6 P2 O8 Mg1 111.5(4) . . . 2_664 ?
O6 P2 O9 K2 95.1(2) . . . 8_766 ?
O6 P2 O9 K2 -6.3(3) . . . 4_556 ?
O6 P2 O9 Mg1 -151.4(4) . . . 2_665 ?
O6 P2 O7 Mg1 170.6(10) . . . . ?
O3 P1 O1 Mo1 -121.7(2) . . . 6_557 ?
O3 P1 O1 Mo1 121.7(2) 7_565 . . 6_557 ?
O3 P1 O1 K2 -114.8(2) 7_565 . . 7_565 ?
O3 P1 O1 K2 114.8(2) . . . . ?
O3 P1 O1 K2 1.7(3) . . . 7_565 ?
O3 P1 O1 K2 -1.7(3) 7_565 . . . ?
O3 P1 O3 K2 113.6(2) 7_565 . . 7_565 ?
O3 P1 O3 Mg1 -135.7(4) 7_565 . . . ?
O3 P1 O3 K1 22.8(4) 7_565 . . . ?
O3 P1 O2 K2 -34.6(6) 7_565 . . 1_556 ?
O3 P1 O2 K2 -162.2(3) . . . 1_556 ?
O3 P1 O2 K2 34.6(6) . . . 7_566 ?
O3 P1 O2 K2 162.2(3) 7_565 . . 7_566 ?
O3 P1 O2 K1 -63.8(2) . . . 1_556 ?
O3 P1 O2 K1 63.8(2) 7_565 . . 1_556 ?
O3 Mg1 O7 P2 -177.3(10) . . . . ?
O4 Mo1 O5 K2 -134.46(10) . . . 6_656 ?
O4 Mo1 O5 K2 134.46(10) . . . 4 ?
O4 Mo1 O5 K1 0.000(0) . . . . ?
O2 P1 O1 Mo1 0.000(0) . . . 6_557 ?
O2 P1 O1 K2 123.48(15) . . . 7_565 ?
O2 P1 O1 K2 -123.48(15) . . . . ?
O2 P1 O3 K2 -115.8(3) . . . 7_565 ?
O2 P1 O3 Mg1 -5.1(7) . . . . ?
O2 P1 O3 K1 153.4(3) . . . . ?
O5 Mo1 O4 K1 180.000(1) . . . 1_556 ?
K1 Mo1 O4 K1 180.000(1) . . . 1_556 ?
K1 Mo1 O5 K2 -134.46(10) . . . 6_656 ?
K1 Mo1 O5 K2 134.46(10) . . . 4 ?
K1 P1 O1 Mo1 180.0 . . . 6_557 ?
K1 P1 O1 Mo1 0.000(1) 1_556 . . 6_557 ?
K1 P1 O1 K2 123.48(15) 1_556 . . 7_565 ?
K1 P1 O1 K2 56.52(15) . . . . ?
K1 P1 O1 K2 -56.52(15) . . . 7_565 ?
K1 P1 O1 K2 -123.48(15) 1_556 . . . ?
K1 P1 O3 K2 -163.71(12) 1_556 . . 7_565 ?
K1 P1 O3 K2 90.79(18) . . . 7_565 ?
K1 P1 O3 Mg1 -53.0(5) 1_556 . . . ?
K1 P1 O3 Mg1 -158.5(6) . . . . ?
K1 P1 O3 K1 105.50(14) 1_556 . . . ?
K1 P1 O2 K2 -98.4(4) 1_556 . . 1_556 ?
K1 P1 O2 K2 -98.4(4) . . . 1_556 ?
K1 P1 O2 K2 98.4(4) 1_556 . . 7_566 ?
K1 P1 O2 K2 98.4(4) . . . 7_566 ?
K1 P1 O2 K1 0.000(2) . . . 1_556 ?
K1 Mg1 O7 P2 -117.9(11) 1_556 . . . ?
K1 Mg1 O7 P2 156.7(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
