# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_GIOBBIO3_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2347259'
loop_
_audit_author_name
_audit_author_address
'Jean-Francois Lohier'
;CRISMAT ENSICAEN
France
;
_audit_update_record             
;
2024-04-10 deposited with the CCDC.	2024-06-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        
;
(1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene) (2-2'-bipyridine) silver hexafluorophosphate
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C37 H44 Ag F6 N4 P'
_chemical_formula_sum            'C37 H44 Ag F6 N4 P'
_chemical_formula_weight         797.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   15.6677(4)
_cell_length_b                   17.2396(5)
_cell_length_c                   27.1830(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7342.3(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9921
_cell_measurement_theta_min      2.80
_cell_measurement_theta_max      34.05

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_F_000             3280
_exptl_transmission_factor_min   0.6722
_exptl_transmission_factor_max   0.7469
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.06
_exptl_absorpt_coefficient_mu    0.655
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'Sadabs 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            92122
_diffrn_reflns_av_unetI/netI     0.0400
_diffrn_reflns_av_R_equivalents  0.0478
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -43
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         1.909
_diffrn_reflns_theta_max         35.016
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             16143
_reflns_number_gt                11798
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0269P)²+2.7641P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16143
_refine_ls_number_parameters     475
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0597
_refine_ls_R_factor_gt           0.0346
_refine_ls_wR_factor_ref         0.0757
_refine_ls_wR_factor_gt          0.0680
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_restrained_S_all      1.017
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C14A C 1.0697(4) 0.6032(4) 0.3887(2) 0.0603(18) Uani 0.498(2) 1 d . . P A 1
H14A H 1.070828 0.657853 0.378755 0.090 Uiso 0.498(2) 1 calc R U P A 1
H14B H 1.096572 0.571495 0.363065 0.090 Uiso 0.498(2) 1 calc R U P A 1
H14C H 1.100970 0.596920 0.419630 0.090 Uiso 0.498(2) 1 calc R U P A 1
C15A C 1.0715(3) 0.5704(3) 0.40519(18) 0.0359(10) Uani 0.498(2) 1 d . . P A 1
H15A H 1.096453 0.622462 0.406976 0.054 Uiso 0.498(2) 1 calc R U P A 1
H15B H 1.098257 0.541429 0.378273 0.054 Uiso 0.498(2) 1 calc R U P A 1
H15C H 1.081323 0.543171 0.436321 0.054 Uiso 0.498(2) 1 calc R U P A 1
C14B C 0.9674(6) 0.4959(5) 0.4112(3) 0.080(3) Uani 0.502(2) 1 d . . P A 2
H14D H 0.995354 0.488705 0.443112 0.121 Uiso 0.502(2) 1 calc R U P A 2
H14F H 0.994460 0.462211 0.386690 0.121 Uiso 0.502(2) 1 calc R U P A 2
H14E H 0.906820 0.482671 0.414002 0.121 Uiso 0.502(2) 1 calc R U P A 2
C15B C 0.9372(3) 0.4940(4) 0.4003(2) 0.0284(9) Uani 0.502(2) 1 d . . P A 2
H15D H 0.968388 0.458377 0.378709 0.043 Uiso 0.502(2) 1 calc R U P A 2
H15E H 0.876979 0.495236 0.390696 0.043 Uiso 0.502(2) 1 calc R U P A 2
H15F H 0.941970 0.476082 0.434459 0.043 Uiso 0.502(2) 1 calc R U P A 2
Ag1 Ag 0.68688(2) 0.54106(2) 0.40472(2) 0.01852(3) Uani 1 1 d . . . . .
P1 P 0.27137(2) 0.75147(2) 0.35569(2) 0.02284(8) Uani 1 1 d . . . . .
F6 F 0.35777(6) 0.73942(7) 0.38548(3) 0.0394(2) Uani 1 1 d . . . . .
F3 F 0.21988(7) 0.71772(8) 0.40157(3) 0.0447(3) Uani 1 1 d . . . . .
F2 F 0.28072(7) 0.66649(6) 0.33309(3) 0.0398(2) Uani 1 1 d . . . . .
F1 F 0.32369(8) 0.78487(7) 0.30971(4) 0.0457(3) Uani 1 1 d . . . . .
N2 N 0.74385(6) 0.62207(6) 0.30847(3) 0.01409(19) Uani 1 1 d . . . . .
N1 N 0.82161(6) 0.65926(7) 0.36852(4) 0.0153(2) Uani 1 1 d . . . . .
F4 F 0.26202(9) 0.83627(7) 0.37787(4) 0.0578(3) Uani 1 1 d . . . . .
F5 F 0.18498(7) 0.76282(9) 0.32593(4) 0.0599(4) Uani 1 1 d . . . . .
N3 N 0.57657(7) 0.45372(7) 0.40651(4) 0.0208(2) Uani 1 1 d . . . . .
N4 N 0.66430(7) 0.50563(7) 0.48502(4) 0.0193(2) Uani 1 1 d . . . . .
C1 C 0.75666(8) 0.61068(7) 0.35734(4) 0.0145(2) Uani 1 1 d . . . . .
C16 C 0.68011(8) 0.58088(8) 0.28050(4) 0.0166(2) Uani 1 1 d . . . . .
C3 C 0.79981(8) 0.67666(8) 0.28949(4) 0.0183(2) Uani 1 1 d . . . . .
H3 H 0.803195 0.693896 0.256348 0.022 Uiso 1 1 calc R U . . .
C4 C 0.85413(8) 0.66941(8) 0.41785(4) 0.0167(2) Uani 1 1 d . . . . .
C2 C 0.84866(8) 0.70048(8) 0.32767(4) 0.0187(2) Uani 1 1 d . . . . .
H2 H 0.892886 0.738146 0.326644 0.022 Uiso 1 1 calc R U . . .
C5 C 0.80725(8) 0.71580(8) 0.45043(4) 0.0181(2) Uani 1 1 d . . . . .
C28 C 0.55826(8) 0.42062(8) 0.44998(4) 0.0164(2) Uani 1 1 d . . . . .
C6 C 0.83857(9) 0.72303(9) 0.49844(5) 0.0227(3) Uani 1 1 d . . . . .
H6 H 0.808307 0.753658 0.521670 0.027 Uiso 1 1 calc R U . . .
C17 C 0.70106(9) 0.50802(9) 0.26152(5) 0.0209(3) Uani 1 1 d . . . . .
C31 C 0.47732(9) 0.36880(9) 0.36687(5) 0.0261(3) Uani 1 1 d . . . . .
H31 H 0.449994 0.352143 0.337518 0.031 Uiso 1 1 calc R U . . .
C9 C 0.92948(8) 0.63110(8) 0.43087(5) 0.0201(3) Uani 1 1 d . . . . .
C33 C 0.60581(8) 0.45038(7) 0.49359(4) 0.0168(2) Uani 1 1 d . . . . .
C25 C 0.57918(9) 0.69386(9) 0.29680(6) 0.0263(3) Uani 1 1 d . . . . .
H25 H 0.634325 0.721159 0.303399 0.032 Uiso 1 1 calc R U . . .
C21 C 0.59994(8) 0.61561(8) 0.27436(5) 0.0204(3) Uani 1 1 d . . . . .
C10 C 0.72463(8) 0.75597(8) 0.43598(5) 0.0201(2) Uani 1 1 d . . . . .
H10 H 0.712473 0.743285 0.400774 0.024 Uiso 1 1 calc R U . . .
C7 C 0.91309(9) 0.68607(10) 0.51244(5) 0.0263(3) Uani 1 1 d . . . . .
H7 H 0.933563 0.691686 0.545140 0.032 Uiso 1 1 calc R U . . .
C30 C 0.45874(10) 0.33434(10) 0.41135(6) 0.0295(3) Uani 1 1 d . . . . .
H30 H 0.418532 0.293194 0.413170 0.035 Uiso 1 1 calc R U . . .
C35 C 0.64096(12) 0.44947(9) 0.57944(5) 0.0296(3) Uani 1 1 d . . . . .
H35 H 0.632918 0.429827 0.611763 0.036 Uiso 1 1 calc R U . . .
C34 C 0.59244(10) 0.42139(9) 0.54074(5) 0.0252(3) Uani 1 1 d . . . . .
H34 H 0.550404 0.382675 0.546347 0.030 Uiso 1 1 calc R U . . .
C36 C 0.70096(11) 0.50615(9) 0.57059(5) 0.0283(3) Uani 1 1 d . . . . .
H36 H 0.734901 0.526420 0.596545 0.034 Uiso 1 1 calc R U . . .
C8 C 0.95814(9) 0.64093(9) 0.47920(5) 0.0255(3) Uani 1 1 d . . . . .
H8 H 1.009375 0.616240 0.489414 0.031 Uiso 1 1 calc R U . . .
C29 C 0.49961(9) 0.36063(9) 0.45335(5) 0.0246(3) Uani 1 1 d . . . . .
H29 H 0.487490 0.337652 0.484339 0.030 Uiso 1 1 calc R U . . .
C37 C 0.71052(10) 0.53287(9) 0.52276(5) 0.0252(3) Uani 1 1 d . . . . .
H37 H 0.751608 0.572163 0.516475 0.030 Uiso 1 1 calc R U . . .
C13 C 0.97594(9) 0.57688(9) 0.39585(5) 0.0243(3) Uani 1 1 d . . . . .
C32 C 0.53657(9) 0.42809(9) 0.36596(5) 0.0252(3) Uani 1 1 d . . . . .
H32 H 0.549599 0.451767 0.335308 0.030 Uiso 1 1 calc R U . . .
C26 C 0.52640(11) 0.74504(10) 0.26243(7) 0.0361(4) Uani 1 1 d . . . . .
H26A H 0.555314 0.749297 0.230571 0.054 Uiso 1 1 calc R U . . .
H26B H 0.520169 0.796770 0.276931 0.054 Uiso 1 1 calc R U . . .
H26C H 0.469869 0.721862 0.257734 0.054 Uiso 1 1 calc R U . . .
C18 C 0.63748(10) 0.46858(9) 0.23548(5) 0.0268(3) Uani 1 1 d . . . . .
H18 H 0.649475 0.419040 0.221826 0.032 Uiso 1 1 calc R U . . .
C22 C 0.78909(10) 0.47269(9) 0.26787(5) 0.0256(3) Uani 1 1 d . . . . .
H22 H 0.823468 0.508319 0.289086 0.031 Uiso 1 1 calc R U . . .
C20 C 0.53868(9) 0.57342(10) 0.24845(5) 0.0268(3) Uani 1 1 d . . . . .
H20 H 0.483354 0.594738 0.243804 0.032 Uiso 1 1 calc R U . . .
C12 C 0.73143(11) 0.84390(10) 0.44062(7) 0.0357(4) Uani 1 1 d . . . . .
H12A H 0.741770 0.857774 0.475071 0.054 Uiso 1 1 calc R U . . .
H12B H 0.678085 0.867825 0.429487 0.054 Uiso 1 1 calc R U . . .
H12C H 0.778809 0.862598 0.420291 0.054 Uiso 1 1 calc R U . . .
C11 C 0.64973(9) 0.72669(9) 0.46706(6) 0.0276(3) Uani 1 1 d . . . . .
H11A H 0.644772 0.670297 0.463506 0.041 Uiso 1 1 calc R U . . .
H11B H 0.596850 0.751387 0.455874 0.041 Uiso 1 1 calc R U . . .
H11C H 0.659659 0.739634 0.501698 0.041 Uiso 1 1 calc R U . . .
C19 C 0.55746(10) 0.50078(10) 0.22939(5) 0.0299(3) Uani 1 1 d . . . . .
H19 H 0.514825 0.472870 0.211945 0.036 Uiso 1 1 calc R U . . .
C24 C 0.83396(12) 0.46617(12) 0.21795(7) 0.0397(4) Uani 1 1 d . . . . .
H24A H 0.802149 0.430408 0.196760 0.060 Uiso 1 1 calc R U . . .
H24B H 0.892057 0.446515 0.222764 0.060 Uiso 1 1 calc R U . . .
H24C H 0.836378 0.517414 0.202410 0.060 Uiso 1 1 calc R U . . .
C27 C 0.53330(12) 0.68336(12) 0.34591(6) 0.0426(5) Uani 1 1 d . . . . .
H27A H 0.478643 0.657106 0.340434 0.064 Uiso 1 1 calc R U . . .
H27B H 0.523063 0.734246 0.360855 0.064 Uiso 1 1 calc R U . . .
H27C H 0.568757 0.651984 0.367960 0.064 Uiso 1 1 calc R U . . .
C23 C 0.78439(13) 0.39390(11) 0.29352(7) 0.0443(4) Uani 1 1 d . . . . .
H23A H 0.753799 0.399386 0.324776 0.066 Uiso 1 1 calc R U . . .
H23B H 0.842293 0.374839 0.299836 0.066 Uiso 1 1 calc R U . . .
H23C H 0.754077 0.356977 0.272406 0.066 Uiso 1 1 calc R U . . .
H13 H 0.9603(10) 0.5895(10) 0.3632(6) 0.028(4) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C14A C13 1.550(6) . ?
C14A H14A 0.9800 . ?
C14A H14B 0.9800 . ?
C14A H14C 0.9800 . ?
C15A C13 1.523(5) . ?
C15A H15A 0.9800 . ?
C15A H15B 0.9800 . ?
C15A H15C 0.9800 . ?
C14B C13 1.462(8) . ?
C14B H14D 0.9800 . ?
C14B H14F 0.9800 . ?
C14B H14E 0.9800 . ?
C15B C13 1.558(7) . ?
C15B H15D 0.9800 . ?
C15B H15E 0.9800 . ?
C15B H15F 0.9800 . ?
Ag1 C1 2.0723(12) . ?
Ag1 N3 2.2928(11) . ?
Ag1 N4 2.2944(11) . ?
P1 F4 1.5882(11) . ?
P1 F5 1.5890(11) . ?
P1 F6 1.5910(10) . ?
P1 F3 1.5950(10) . ?
P1 F2 1.5953(10) . ?
P1 F1 1.6018(10) . ?
N2 C1 1.3579(14) . ?
N2 C3 1.3859(16) . ?
N2 C16 1.4420(15) . ?
N1 C1 1.3524(16) . ?
N1 C2 1.3849(15) . ?
N1 C4 1.4452(15) . ?
N3 C32 1.3428(17) . ?
N3 C28 1.3433(16) . ?
N4 C37 1.3406(18) . ?
N4 C33 1.3421(17) . ?
C16 C17 1.397(2) . ?
C16 C21 1.4015(18) . ?
C3 C2 1.3534(17) . ?
C3 H3 0.9500 . ?
C4 C9 1.3983(19) . ?
C4 C5 1.4011(18) . ?
C2 H2 0.9500 . ?
C5 C6 1.3997(17) . ?
C5 C10 1.5198(19) . ?
C28 C29 1.3865(19) . ?
C28 C33 1.4911(18) . ?
C6 C7 1.384(2) . ?
C6 H6 0.9500 . ?
C17 C18 1.3984(19) . ?
C17 C22 1.518(2) . ?
C31 C30 1.378(2) . ?
C31 C32 1.381(2) . ?
C31 H31 0.9500 . ?
C9 C8 1.3987(18) . ?
C9 C13 1.520(2) . ?
C33 C34 1.3915(17) . ?
C25 C21 1.516(2) . ?
C25 C27 1.527(2) . ?
C25 C26 1.528(2) . ?
C25 H25 1.0000 . ?
C21 C20 1.3951(19) . ?
C10 C12 1.525(2) . ?
C10 C11 1.5316(19) . ?
C10 H10 1.0000 . ?
C7 C8 1.386(2) . ?
C7 H7 0.9500 . ?
C30 C29 1.385(2) . ?
C30 H30 0.9500 . ?
C35 C36 1.377(2) . ?
C35 C34 1.385(2) . ?
C35 H35 0.9500 . ?
C34 H34 0.9500 . ?
C36 C37 1.388(2) . ?
C36 H36 0.9500 . ?
C8 H8 0.9500 . ?
C29 H29 0.9500 . ?
C37 H37 0.9500 . ?
C13 H13 0.945(17) . ?
C32 H32 0.9500 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C18 C19 1.381(2) . ?
C18 H18 0.9500 . ?
C22 C23 1.529(2) . ?
C22 C24 1.532(2) . ?
C22 H22 1.0000 . ?
C20 C19 1.387(2) . ?
C20 H20 0.9500 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C19 H19 0.9500 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 C14A H14A 109.5 . . ?
C13 C14A H14B 109.5 . . ?
H14A C14A H14B 109.5 . . ?
C13 C14A H14C 109.5 . . ?
H14A C14A H14C 109.5 . . ?
H14B C14A H14C 109.5 . . ?
C13 C15A H15A 109.5 . . ?
C13 C15A H15B 109.5 . . ?
H15A C15A H15B 109.5 . . ?
C13 C15A H15C 109.5 . . ?
H15A C15A H15C 109.5 . . ?
H15B C15A H15C 109.5 . . ?
C13 C14B H14D 109.5 . . ?
C13 C14B H14F 109.5 . . ?
H14D C14B H14F 109.5 . . ?
C13 C14B H14E 109.5 . . ?
H14D C14B H14E 109.5 . . ?
H14F C14B H14E 109.5 . . ?
C13 C15B H15D 109.5 . . ?
C13 C15B H15E 109.5 . . ?
H15D C15B H15E 109.5 . . ?
C13 C15B H15F 109.5 . . ?
H15D C15B H15F 109.5 . . ?
H15E C15B H15F 109.5 . . ?
C1 Ag1 N3 142.31(4) . . ?
C1 Ag1 N4 145.78(4) . . ?
N3 Ag1 N4 71.86(4) . . ?
F4 P1 F5 90.07(7) . . ?
F4 P1 F6 90.31(7) . . ?
F5 P1 F6 179.58(8) . . ?
F4 P1 F3 89.56(7) . . ?
F5 P1 F3 90.70(7) . . ?
F6 P1 F3 89.13(6) . . ?
F4 P1 F2 179.65(6) . . ?
F5 P1 F2 89.73(7) . . ?
F6 P1 F2 89.89(6) . . ?
F3 P1 F2 90.72(6) . . ?
F4 P1 F1 90.72(7) . . ?
F5 P1 F1 89.67(7) . . ?
F6 P1 F1 90.49(6) . . ?
F3 P1 F1 179.54(7) . . ?
F2 P1 F1 89.00(6) . . ?
C1 N2 C3 111.64(10) . . ?
C1 N2 C16 123.16(10) . . ?
C3 N2 C16 125.19(10) . . ?
C1 N1 C2 111.58(10) . . ?
C1 N1 C4 123.28(10) . . ?
C2 N1 C4 125.03(10) . . ?
C32 N3 C28 118.86(12) . . ?
C32 N3 Ag1 123.40(9) . . ?
C28 N3 Ag1 117.30(8) . . ?
C37 N4 C33 118.99(11) . . ?
C37 N4 Ag1 123.47(9) . . ?
C33 N4 Ag1 117.35(8) . . ?
N1 C1 N2 103.98(10) . . ?
N1 C1 Ag1 128.02(8) . . ?
N2 C1 Ag1 127.86(9) . . ?
C17 C16 C21 123.42(12) . . ?
C17 C16 N2 118.35(11) . . ?
C21 C16 N2 118.23(12) . . ?
C2 C3 N2 106.16(10) . . ?
C2 C3 H3 126.9 . . ?
N2 C3 H3 126.9 . . ?
C9 C4 C5 123.51(11) . . ?
C9 C4 N1 118.38(11) . . ?
C5 C4 N1 118.09(11) . . ?
C3 C2 N1 106.63(11) . . ?
C3 C2 H2 126.7 . . ?
N1 C2 H2 126.7 . . ?
C6 C5 C4 117.15(12) . . ?
C6 C5 C10 119.93(12) . . ?
C4 C5 C10 122.90(11) . . ?
N3 C28 C29 121.10(12) . . ?
N3 C28 C33 116.52(11) . . ?
C29 C28 C33 122.36(11) . . ?
C7 C6 C5 120.75(13) . . ?
C7 C6 H6 119.6 . . ?
C5 C6 H6 119.6 . . ?
C16 C17 C18 117.18(13) . . ?
C16 C17 C22 122.17(12) . . ?
C18 C17 C22 120.65(13) . . ?
C30 C31 C32 118.48(13) . . ?
C30 C31 H31 120.8 . . ?
C32 C31 H31 120.8 . . ?
C4 C9 C8 116.85(12) . . ?
C4 C9 C13 122.43(11) . . ?
C8 C9 C13 120.61(13) . . ?
N4 C33 C34 121.16(12) . . ?
N4 C33 C28 116.57(11) . . ?
C34 C33 C28 122.25(12) . . ?
C21 C25 C27 110.32(14) . . ?
C21 C25 C26 112.58(13) . . ?
C27 C25 C26 110.38(13) . . ?
C21 C25 H25 107.8 . . ?
C27 C25 H25 107.8 . . ?
C26 C25 H25 107.8 . . ?
C20 C21 C16 117.00(13) . . ?
C20 C21 C25 121.30(13) . . ?
C16 C21 C25 121.65(12) . . ?
C5 C10 C12 111.85(12) . . ?
C5 C10 C11 111.09(11) . . ?
C12 C10 C11 109.61(12) . . ?
C5 C10 H10 108.1 . . ?
C12 C10 H10 108.1 . . ?
C11 C10 H10 108.1 . . ?
C6 C7 C8 120.61(12) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
C31 C30 C29 118.97(14) . . ?
C31 C30 H30 120.5 . . ?
C29 C30 H30 120.5 . . ?
C36 C35 C34 119.34(13) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C35 C34 C33 119.43(14) . . ?
C35 C34 H34 120.3 . . ?
C33 C34 H34 120.3 . . ?
C35 C36 C37 118.22(13) . . ?
C35 C36 H36 120.9 . . ?
C37 C36 H36 120.9 . . ?
C7 C8 C9 121.12(13) . . ?
C7 C8 H8 119.4 . . ?
C9 C8 H8 119.4 . . ?
C30 C29 C28 119.73(13) . . ?
C30 C29 H29 120.1 . . ?
C28 C29 H29 120.1 . . ?
N4 C37 C36 122.85(14) . . ?
N4 C37 H37 118.6 . . ?
C36 C37 H37 118.6 . . ?
C14B C13 C9 111.4(3) . . ?
C9 C13 C15A 114.3(2) . . ?
C9 C13 C14A 110.7(3) . . ?
C15A C13 C14A 27.2(3) . . ?
C14B C13 C15B 21.0(4) . . ?
C9 C13 C15B 109.2(3) . . ?
C14B C13 H13 117.6(11) . . ?
C9 C13 H13 108.8(11) . . ?
C15A C13 H13 115.3(10) . . ?
C14A C13 H13 93.4(10) . . ?
C15B C13 H13 100.6(11) . . ?
N3 C32 C31 122.85(13) . . ?
N3 C32 H32 118.6 . . ?
C31 C32 H32 118.6 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C19 C18 C17 120.79(14) . . ?
C19 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C17 C22 C23 111.40(14) . . ?
C17 C22 C24 110.22(13) . . ?
C23 C22 C24 111.15(14) . . ?
C17 C22 H22 108.0 . . ?
C23 C22 H22 108.0 . . ?
C24 C22 H22 108.0 . . ?
C19 C20 C21 120.90(14) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 H20 119.6 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C18 C19 C20 120.71(13) . . ?
C18 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?

_refine_diff_density_max         0.469
_refine_diff_density_min         -0.548
_refine_diff_density_rms         0.076




