# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_12712
_database_code_depnum_ccdc_archive 'CCDC 2336662'
loop_
_audit_author_name
_audit_author_address
'deyun ma'
;zhaoqing university
China
;
_audit_update_record             
;
2024-03-01 deposited with the CCDC.	2024-06-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C10 H20 Eu2 N2 O21'
_chemical_formula_weight         808.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.5241(4)
_cell_length_b                   13.6671(3)
_cell_length_c                   12.3015(4)
_cell_angle_alpha                90
_cell_angle_beta                 113.557(3)
_cell_angle_gamma                90
_cell_volume                     2238.38(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3392
_cell_measurement_theta_min      3.2640
_cell_measurement_theta_max      71.0140

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            WHITE
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.398
_exptl_crystal_F_000             1552
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    40.680
_shelx_estimated_absorpt_T_min   0.139
_shelx_estimated_absorpt_T_max   0.163
_exptl_absorpt_correction_T_min  0.76764
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8084
_diffrn_reflns_av_unetI/netI     0.0588
_diffrn_reflns_av_R_equivalents  0.0463
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         3.320
_diffrn_reflns_theta_max         67.250
_diffrn_reflns_theta_full        67.250
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             4007
_reflns_number_gt                3079
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_structure_solution    'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0596P)²+1.2607P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4007
_refine_ls_number_parameters     316
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0607
_refine_ls_R_factor_gt           0.0441
_refine_ls_wR_factor_ref         0.1186
_refine_ls_wR_factor_gt          0.1082
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.046
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.53415(3) 0.77322(4) 0.54230(4) 0.01746(15) Uani 1 1 d . . . . .
Eu2 Eu -0.02725(3) 0.72345(3) 0.04402(4) 0.01547(14) Uani 1 1 d . . . . .
N1 N 0.3503(5) 0.7229(6) 0.3893(7) 0.0294(17) Uani 1 1 d . . . . .
N2 N 0.1605(5) 0.7260(5) 0.2063(6) 0.0240(15) Uani 1 1 d . . . . .
O1 O -0.0026(4) 0.7339(5) 0.2503(5) 0.0262(13) Uani 1 1 d . . . . .
O2 O 0.0212(5) 0.8928(5) 0.0708(7) 0.0487(19) Uani 1 1 d . . . . .
H2B H 0.054189 0.904141 0.144144 0.073 Uiso 1 1 d R U . . .
H2C H 0.057788 0.905241 0.033074 0.073 Uiso 1 1 d R U . . .
O3 O -0.1397(4) 0.7897(5) -0.1555(5) 0.0303(14) Uani 1 1 d . . . . .
H3A H -0.147539 0.850800 -0.149607 0.045 Uiso 1 1 d R U . . .
H3B H -0.112949 0.779690 -0.204617 0.045 Uiso 1 1 d R U . . .
O4 O 0.0366(5) 0.5643(5) 0.1314(5) 0.0327(14) Uani 1 1 d . . . . .
O5 O 0.0551(5) 0.4066(5) 0.1009(5) 0.0333(14) Uani 1 1 d . . . . .
O6 O 0.0859(4) 0.7483(5) 0.4443(5) 0.0297(15) Uani 1 1 d . . . . .
O7 O 0.5148(4) 0.7203(5) 0.3446(5) 0.0275(13) Uani 1 1 d . . . . .
O8 O 0.4248(4) 0.7227(5) 0.1503(5) 0.0296(14) Uani 1 1 d . . . . .
O9 O 0.4534(5) 1.0632(5) 0.3665(5) 0.0356(15) Uani 1 1 d . . . . .
O10 O 0.4502(5) 0.9029(5) 0.4026(6) 0.0399(16) Uani 1 1 d . . . . .
O11 O 0.5129(5) 0.6035(5) 0.5815(7) 0.0450(17) Uani 1 1 d . . . . .
H11A H 0.455084 0.595524 0.582117 0.068 Uiso 1 1 d R U . . .
H11C H 0.557675 0.587573 0.648557 0.068 Uiso 1 1 d R U . . .
O12 O 0.6499(4) 0.7547(5) 0.7483(5) 0.0330(15) Uani 1 1 d . . . . .
H12A H 0.617538 0.737718 0.789516 0.049 Uiso 1 1 d R U . . .
H12C H 0.679238 0.808948 0.773786 0.049 Uiso 1 1 d R U . . .
O13 O 0.6690(4) 0.8672(5) 0.5242(6) 0.0374(15) Uani 1 1 d . . . . .
O14 O 0.6806(4) 0.6736(5) 0.5527(5) 0.0288(13) Uani 1 1 d . . . . .
O15 O 0.8255(4) 0.8697(5) 0.5319(6) 0.0374(16) Uani 1 1 d . . . . .
O16 O 0.8355(4) 0.6762(4) 0.5556(5) 0.0261(12) Uani 1 1 d . . . . .
O17 O 0.8065(7) 0.9894(7) 0.8298(10) 0.084(3) Uani 1 1 d . . . . .
H17A H 0.774013 1.005147 0.757624 0.101 Uiso 1 1 d R U . . .
H17B H 0.768583 0.998726 0.866593 0.101 Uiso 1 1 d R U . . .
O18 O 0.6918(12) 0.5175(10) 0.7582(17) 0.199(9) Uani 1 1 d . . . . .
H18B H 0.685708 0.485325 0.814113 0.238 Uiso 1 1 d R U . . .
H18D H 0.705068 0.576645 0.780303 0.238 Uiso 1 1 d R U . . .
O19 O 0.3702(6) 0.4930(6) 0.6200(8) 0.059(2) Uani 1 1 d . . . . .
H19C H 0.394211 0.476567 0.692649 0.071 Uiso 1 1 d R U . . .
H19B H 0.356611 0.442276 0.576398 0.071 Uiso 1 1 d R U . . .
O20 O 0.7890(16) 0.0574(11) 0.605(2) 0.207(10) Uani 1 1 d . . . . .
H20C H 0.799290 0.004532 0.575204 0.248 Uiso 1 1 d R U . . .
H20B H 0.833830 0.099032 0.609464 0.248 Uiso 1 1 d R U . . .
O21 O 0.8977(7) 0.0191(7) 0.1265(8) 0.072(3) Uani 1 1 d . . . . .
H21D H 0.920659 0.031012 0.200396 0.086 Uiso 1 1 d R U . . .
H21A H 0.839830 -0.006898 0.103776 0.086 Uiso 1 1 d R U . . .
C1 C 0.0772(6) 0.7378(6) 0.3403(7) 0.0211(17) Uani 1 1 d . . . . .
C2 C 0.1727(6) 0.7281(7) 0.3198(8) 0.0266(19) Uani 1 1 d . . . . .
C3 C 0.2670(6) 0.7228(8) 0.4100(8) 0.035(2) Uani 1 1 d . . . . .
H3 H 0.272698 0.719004 0.487895 0.042 Uiso 1 1 calc R U . . .
C4 C 0.3386(6) 0.7213(6) 0.2773(7) 0.0221(17) Uani 1 1 d . . . . .
C5 C 0.2454(6) 0.7179(7) 0.1876(7) 0.029(2) Uani 1 1 d . . . . .
H5 H 0.240203 0.709782 0.110307 0.035 Uiso 1 1 calc R U . . .
C6 C 0.4335(5) 0.7207(6) 0.2544(7) 0.0210(17) Uani 1 1 d . . . . .
C7 C 0.0263(6) 0.4912(7) 0.0685(7) 0.0249(18) Uani 1 1 d . . . . .
C8 C 0.4727(6) 0.9909(7) 0.4337(7) 0.0276(19) Uani 1 1 d . . . . .
C9 C 0.7506(5) 0.8275(7) 0.5341(7) 0.0229(17) Uani 1 1 d . . . . .
C10 C 0.7553(5) 0.7159(6) 0.5489(6) 0.0177(16) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O11 2.414(7) . ?
Eu1 O13 2.426(6) . ?
Eu1 O12 2.430(6) . ?
Eu1 O10 2.430(7) . ?
Eu1 O7 2.443(6) . ?
Eu1 O8 2.445(5) 4_576 ?
Eu1 O9 2.475(7) 3_676 ?
Eu1 O14 2.486(5) . ?
Eu1 N1 2.670(7) . ?
Eu1 C8 3.237(9) . ?
Eu1 C8 3.243(9) 3_676 ?
Eu1 C9 3.271(7) . ?
Eu1 H11A 2.8118 . ?
Eu1 H11C 2.8118 . ?
Eu2 O2 2.403(7) . ?
Eu2 O1 2.421(6) . ?
Eu2 O5 2.434(6) 3_565 ?
Eu2 O4 2.440(6) . ?
Eu2 O15 2.441(6) 4_475 ?
Eu2 O6 2.441(6) 4_575 ?
Eu2 O16 2.470(5) 4_475 ?
Eu2 O3 2.511(6) . ?
Eu2 N2 2.659(6) . ?
Eu2 C7 3.246(9) 3_565 ?
Eu2 C9 3.255(7) 4_475 ?
Eu2 C7 3.253(9) . ?
Eu2 H2B 2.8018 . ?
Eu2 H2C 2.8017 . ?
N1 C4 1.320(11) . ?
N1 C3 1.331(11) . ?
N2 C2 1.336(11) . ?
N2 C5 1.346(10) . ?
O1 C1 1.243(10) . ?
O2 H2B 0.8500 . ?
O2 H2C 0.8500 . ?
O3 H3A 0.8499 . ?
O3 H3B 0.8499 . ?
O4 C7 1.235(10) . ?
O5 C7 1.240(10) . ?
O6 C1 1.244(10) . ?
O7 C6 1.256(10) . ?
O8 C6 1.236(10) . ?
O9 C8 1.247(11) . ?
O10 C8 1.264(11) . ?
O11 H11A 0.8499 . ?
O11 H11C 0.8499 . ?
O12 H12A 0.8501 . ?
O12 H12C 0.8501 . ?
O13 C9 1.264(9) . ?
O14 C10 1.247(9) . ?
O15 C9 1.241(9) . ?
O16 C10 1.258(9) . ?
O17 H17A 0.8500 . ?
O17 H17B 0.8500 . ?
O18 H18B 0.8499 . ?
O18 H18D 0.8499 . ?
O19 H19C 0.8500 . ?
O19 H19B 0.8500 . ?
O20 H20C 0.8500 . ?
O20 H20B 0.8500 . ?
O21 H21D 0.8500 . ?
O21 H21A 0.8500 . ?
C1 C2 1.510(11) . ?
C2 C3 1.377(12) . ?
C3 H3 0.9300 . ?
C4 C5 1.364(11) . ?
C4 C6 1.513(10) . ?
C5 H5 0.9300 . ?
C7 C7 1.566(16) 3_565 ?
C8 C8 1.522(17) 3_676 ?
C9 C10 1.535(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Eu1 O13 134.4(2) . . ?
O11 Eu1 O12 77.4(2) . . ?
O13 Eu1 O12 84.5(2) . . ?
O11 Eu1 O10 140.7(2) . . ?
O13 Eu1 O10 75.2(2) . . ?
O12 Eu1 O10 139.1(2) . . ?
O11 Eu1 O7 86.6(2) . . ?
O13 Eu1 O7 80.9(2) . . ?
O12 Eu1 O7 139.78(19) . . ?
O10 Eu1 O7 71.7(2) . . ?
O11 Eu1 O8 75.6(2) . 4_576 ?
O13 Eu1 O8 139.6(2) . 4_576 ?
O12 Eu1 O8 76.39(19) . 4_576 ?
O10 Eu1 O8 96.7(2) . 4_576 ?
O7 Eu1 O8 134.93(19) . 4_576 ?
O11 Eu1 O9 140.3(2) . 3_676 ?
O13 Eu1 O9 69.4(2) . 3_676 ?
O12 Eu1 O9 74.1(2) . 3_676 ?
O10 Eu1 O9 65.6(2) . 3_676 ?
O7 Eu1 O9 132.6(2) . 3_676 ?
O8 Eu1 O9 71.3(2) 4_576 3_676 ?
O11 Eu1 O14 68.8(2) . . ?
O13 Eu1 O14 65.7(2) . . ?
O12 Eu1 O14 70.6(2) . . ?
O10 Eu1 O14 127.8(2) . . ?
O7 Eu1 O14 69.19(19) . . ?
O8 Eu1 O14 135.5(2) 4_576 . ?
O9 Eu1 O14 124.4(2) 3_676 . ?
O11 Eu1 N1 73.8(2) . . ?
O13 Eu1 N1 133.5(2) . . ?
O12 Eu1 N1 142.0(2) . . ?
O10 Eu1 N1 67.1(2) . . ?
O7 Eu1 N1 62.5(2) . . ?
O8 Eu1 N1 72.8(2) 4_576 . ?
O9 Eu1 N1 115.0(2) 3_676 . ?
O14 Eu1 N1 119.3(2) . . ?
O11 Eu1 C8 158.3(2) . . ?
O13 Eu1 C8 64.9(2) . . ?
O12 Eu1 C8 119.2(2) . . ?
O10 Eu1 C8 20.0(2) . . ?
O7 Eu1 C8 87.6(2) . . ?
O8 Eu1 C8 94.1(2) 4_576 . ?
O9 Eu1 C8 46.8(2) 3_676 . ?
O14 Eu1 C8 127.9(2) . . ?
N1 Eu1 C8 85.0(2) . . ?
O11 Eu1 C8 157.9(2) . 3_676 ?
O13 Eu1 C8 62.4(2) . 3_676 ?
O12 Eu1 C8 92.4(2) . 3_676 ?
O10 Eu1 C8 46.7(2) . 3_676 ?
O7 Eu1 C8 112.9(2) . 3_676 ?
O8 Eu1 C8 83.0(2) 4_576 3_676 ?
O9 Eu1 C8 20.0(2) 3_676 3_676 ?
O14 Eu1 C8 126.6(2) . 3_676 ?
N1 Eu1 C8 105.2(2) . 3_676 ?
C8 Eu1 C8 27.2(3) . 3_676 ?
O11 Eu1 C9 115.2(2) . . ?
O13 Eu1 C9 19.2(2) . . ?
O12 Eu1 C9 77.5(2) . . ?
O10 Eu1 C9 91.7(2) . . ?
O7 Eu1 C9 76.47(19) . . ?
O8 Eu1 C9 148.52(19) 4_576 . ?
O9 Eu1 C9 85.0(2) 3_676 . ?
O14 Eu1 C9 46.6(2) . . ?
N1 Eu1 C9 137.7(2) . . ?
C8 Eu1 C9 83.6(2) . . ?
C8 Eu1 C9 80.9(2) 3_676 . ?
O11 Eu1 H11A 16.6 . . ?
O13 Eu1 H11A 150.9 . . ?
O12 Eu1 H11A 83.6 . . ?
O10 Eu1 H11A 128.9 . . ?
O7 Eu1 H11A 91.4 . . ?
O8 Eu1 H11A 61.7 4_576 . ?
O9 Eu1 H11A 131.5 3_676 . ?
O14 Eu1 H11A 85.3 . . ?
N1 Eu1 H11A 62.4 . . ?
C8 Eu1 H11A 143.2 . . ?
C8 Eu1 H11A 144.4 3_676 . ?
C9 Eu1 H11A 131.7 . . ?
O11 Eu1 H11C 16.6 . . ?
O13 Eu1 H11C 124.6 . . ?
O12 Eu1 H11C 61.1 . . ?
O10 Eu1 H11C 157.0 . . ?
O7 Eu1 H11C 98.0 . . ?
O8 Eu1 H11C 75.7 4_576 . ?
O9 Eu1 H11C 129.1 3_676 . ?
O14 Eu1 H11C 62.6 . . ?
N1 Eu1 H11C 89.8 . . ?
C8 Eu1 H11C 169.5 . . ?
C8 Eu1 H11C 149.0 3_676 . ?
C9 Eu1 H11C 106.2 . . ?
H11A Eu1 H11C 28.6 . . ?
O2 Eu2 O1 83.5(2) . . ?
O2 Eu2 O5 139.2(2) . 3_565 ?
O1 Eu2 O5 136.3(2) . 3_565 ?
O2 Eu2 O4 139.4(2) . . ?
O1 Eu2 O4 73.8(2) . . ?
O5 Eu2 O4 66.0(2) 3_565 . ?
O2 Eu2 O15 135.4(2) . 4_475 ?
O1 Eu2 O15 81.6(2) . 4_475 ?
O5 Eu2 O15 71.9(2) 3_565 4_475 ?
O4 Eu2 O15 74.4(2) . 4_475 ?
O2 Eu2 O6 72.4(2) . 4_575 ?
O1 Eu2 O6 132.03(18) . 4_575 ?
O5 Eu2 O6 72.3(2) 3_565 4_575 ?
O4 Eu2 O6 98.5(2) . 4_575 ?
O15 Eu2 O6 143.2(2) 4_475 4_575 ?
O2 Eu2 O16 69.9(2) . 4_475 ?
O1 Eu2 O16 72.04(18) . 4_475 ?
O5 Eu2 O16 123.1(2) 3_565 4_475 ?
O4 Eu2 O16 130.1(2) . 4_475 ?
O15 Eu2 O16 65.5(2) 4_475 4_475 ?
O6 Eu2 O16 131.4(2) 4_575 4_475 ?
O2 Eu2 O3 80.0(2) . . ?
O1 Eu2 O3 140.27(18) . . ?
O5 Eu2 O3 72.2(2) 3_565 . ?
O4 Eu2 O3 137.4(2) . . ?
O15 Eu2 O3 85.2(2) 4_475 . ?
O6 Eu2 O3 75.96(18) 4_575 . ?
O16 Eu2 O3 68.38(19) 4_475 . ?
O2 Eu2 N2 74.2(2) . . ?
O1 Eu2 N2 62.25(19) . . ?
O5 Eu2 N2 112.3(2) 3_565 . ?
O4 Eu2 N2 65.5(2) . . ?
O15 Eu2 N2 131.5(2) 4_475 . ?
O6 Eu2 N2 71.4(2) 4_575 . ?
O16 Eu2 N2 123.9(2) 4_475 . ?
O3 Eu2 N2 143.2(2) . . ?
O2 Eu2 C7 151.4(2) . 3_565 ?
O1 Eu2 C7 118.4(2) . 3_565 ?
O5 Eu2 C7 19.2(2) 3_565 3_565 ?
O4 Eu2 C7 46.9(2) . 3_565 ?
O15 Eu2 C7 69.9(2) 4_475 3_565 ?
O6 Eu2 C7 79.1(2) 4_575 3_565 ?
O16 Eu2 C7 131.89(19) 4_475 3_565 ?
O3 Eu2 C7 91.2(2) . 3_565 ?
N2 Eu2 C7 98.9(2) . 3_565 ?
O2 Eu2 C9 116.3(2) . 4_475 ?
O1 Eu2 C9 77.38(18) . 4_475 ?
O5 Eu2 C9 86.8(2) 3_565 4_475 ?
O4 Eu2 C9 91.3(2) . 4_475 ?
O15 Eu2 C9 19.1(2) 4_475 4_475 ?
O6 Eu2 C9 150.54(19) 4_575 4_475 ?
O16 Eu2 C9 46.4(2) 4_475 4_475 ?
O3 Eu2 C9 78.04(19) . 4_475 ?
N2 Eu2 C9 137.3(2) . 4_475 ?
C7 Eu2 C9 87.9(2) 3_565 4_475 ?
O2 Eu2 C7 151.7(2) . . ?
O1 Eu2 C7 91.8(2) . . ?
O5 Eu2 C7 47.1(2) 3_565 . ?
O4 Eu2 C7 18.98(19) . . ?
O15 Eu2 C7 70.6(2) 4_475 . ?
O6 Eu2 C7 91.0(2) 4_575 . ?
O16 Eu2 C7 134.85(19) 4_475 . ?
O3 Eu2 C7 118.7(2) . . ?
N2 Eu2 C7 78.9(2) . . ?
C7 Eu2 C7 27.9(3) 3_565 . ?
C9 Eu2 C7 89.5(2) 4_475 . ?
O2 Eu2 H2B 16.6 . . ?
O1 Eu2 H2B 68.1 . . ?
O5 Eu2 H2B 152.0 3_565 . ?
O4 Eu2 H2B 125.0 . . ?
O15 Eu2 H2B 133.8 4_475 . ?
O6 Eu2 H2B 80.3 4_575 . ?
O16 Eu2 H2B 72.2 4_475 . ?
O3 Eu2 H2B 96.2 . . ?
N2 Eu2 H2B 62.1 . . ?
C7 Eu2 H2B 155.6 3_565 . ?
C9 Eu2 H2B 116.3 4_475 . ?
C7 Eu2 H2B 140.9 . . ?
O2 Eu2 H2C 16.6 . . ?
O1 Eu2 H2C 96.6 . . ?
O5 Eu2 H2C 124.0 3_565 . ?
O4 Eu2 H2C 135.6 . . ?
O15 Eu2 H2C 148.4 4_475 . ?
O6 Eu2 H2C 55.8 4_575 . ?
O16 Eu2 H2C 83.8 4_475 . ?
O3 Eu2 H2C 76.1 . . ?
N2 Eu2 H2C 71.6 . . ?
C7 Eu2 H2C 134.7 3_565 . ?
C9 Eu2 H2C 129.6 4_475 . ?
C7 Eu2 H2C 140.9 . . ?
H2B Eu2 H2C 28.7 . . ?
C4 N1 C3 116.9(7) . . ?
C4 N1 Eu1 114.5(5) . . ?
C3 N1 Eu1 126.5(6) . . ?
C2 N2 C5 115.7(7) . . ?
C2 N2 Eu2 116.9(5) . . ?
C5 N2 Eu2 127.2(5) . . ?
C1 O1 Eu2 129.1(5) . . ?
Eu2 O2 H2B 109.3 . . ?
Eu2 O2 H2C 109.3 . . ?
H2B O2 H2C 109.5 . . ?
Eu2 O3 H3A 109.2 . . ?
Eu2 O3 H3B 109.5 . . ?
H3A O3 H3B 109.5 . . ?
C7 O4 Eu2 121.0(5) . . ?
C7 O5 Eu2 120.6(5) . 3_565 ?
C1 O6 Eu2 136.4(5) . 4_576 ?
C6 O7 Eu1 124.9(5) . . ?
C6 O8 Eu1 138.1(5) . 4_575 ?
C8 O9 Eu1 117.3(5) . 3_676 ?
C8 O10 Eu1 118.9(6) . . ?
Eu1 O11 H11A 109.3 . . ?
Eu1 O11 H11C 109.3 . . ?
H11A O11 H11C 109.5 . . ?
Eu1 O12 H12A 109.5 . . ?
Eu1 O12 H12C 109.3 . . ?
H12A O12 H12C 109.5 . . ?
C9 O13 Eu1 121.6(6) . . ?
C10 O14 Eu1 118.9(5) . . ?
C9 O15 Eu2 120.7(6) . 4_676 ?
C10 O16 Eu2 120.2(5) . 4_676 ?
H17A O17 H17B 108.2 . . ?
H18B O18 H18D 108.5 . . ?
H19C O19 H19B 110.0 . . ?
H20C O20 H20B 109.5 . . ?
H21D O21 H21A 110.2 . . ?
O6 C1 O1 126.6(8) . . ?
O6 C1 C2 117.4(7) . . ?
O1 C1 C2 116.1(7) . . ?
N2 C2 C3 120.9(8) . . ?
N2 C2 C1 115.4(7) . . ?
C3 C2 C1 123.7(8) . . ?
N1 C3 C2 122.3(8) . . ?
N1 C3 H3 118.9 . . ?
C2 C3 H3 118.9 . . ?
N1 C4 C5 121.2(7) . . ?
N1 C4 C6 116.6(7) . . ?
C5 C4 C6 122.2(7) . . ?
N2 C5 C4 122.7(7) . . ?
N2 C5 H5 118.7 . . ?
C4 C5 H5 118.7 . . ?
O8 C6 O7 125.9(7) . . ?
O8 C6 C4 118.0(7) . . ?
O7 C6 C4 116.1(7) . . ?
O5 C7 O4 127.7(8) . . ?
O5 C7 C7 116.5(9) . 3_565 ?
O4 C7 C7 115.8(9) . 3_565 ?
O5 C7 Eu2 40.2(4) . 3_565 ?
O4 C7 Eu2 167.9(6) . 3_565 ?
C7 C7 Eu2 76.3(6) 3_565 3_565 ?
O5 C7 Eu2 167.7(6) . . ?
O4 C7 Eu2 40.0(4) . . ?
C7 C7 Eu2 75.8(6) 3_565 . ?
Eu2 C7 Eu2 152.1(3) 3_565 . ?
O9 C8 O10 126.2(8) . . ?
O9 C8 C8 117.6(10) . 3_676 ?
O10 C8 C8 116.2(10) . 3_676 ?
O9 C8 Eu1 162.6(6) . . ?
O10 C8 Eu1 41.1(4) . . ?
C8 C8 Eu1 76.6(7) 3_676 . ?
O9 C8 Eu1 42.7(4) . 3_676 ?
O10 C8 Eu1 163.6(6) . 3_676 ?
C8 C8 Eu1 76.2(7) 3_676 3_676 ?
Eu1 C8 Eu1 152.8(3) . 3_676 ?
O15 C9 O13 126.6(9) . . ?
O15 C9 C10 117.8(7) . . ?
O13 C9 C10 115.7(7) . . ?
O15 C9 Eu2 40.1(4) . 4_676 ?
O13 C9 Eu2 166.5(6) . 4_676 ?
C10 C9 Eu2 77.7(4) . 4_676 ?
O15 C9 Eu1 165.5(6) . . ?
O13 C9 Eu1 39.1(4) . . ?
C10 C9 Eu1 76.6(4) . . ?
Eu2 C9 Eu1 154.3(3) 4_676 . ?
O14 C10 O16 126.4(8) . . ?
O14 C10 C9 117.9(6) . . ?
O16 C10 C9 115.7(6) . . ?

_refine_diff_density_max         1.538
_refine_diff_density_min         -1.109
_refine_diff_density_rms         0.173



