# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_giobbio2_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2380164'
loop_
_audit_author_name
_audit_author_address
'Jean-Francois Lohier'
;CRISMAT ENSICAEN
France
;
_audit_update_record             
;
2024-08-27 deposited with the CCDC.	2024-10-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        
;
(1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene) (3,3â\/E?-dimethyl-2,2â\/E?-dipyridylamine) silver hexafluorophosphate
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C39 H49 Ag F6 N5 P'
_chemical_formula_sum            'C39 H49 Ag F6 N5 P'
_chemical_formula_weight         840.67

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   15.8119(5)
_cell_length_b                   17.8148(5)
_cell_length_c                   28.1724(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7935.8(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9813
_cell_measurement_theta_min      2.71
_cell_measurement_theta_max      30.03

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.407
_exptl_crystal_F_000             3472
_exptl_transmission_factor_min   0.6144
_exptl_transmission_factor_max   0.7464
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    0.611
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'Sadabs 2016/2'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            77541
_diffrn_reflns_av_unetI/netI     0.0341
_diffrn_reflns_av_R_equivalents  0.0501
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         2.249
_diffrn_reflns_theta_max         30.101
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             11620
_reflns_number_gt                9118
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0256P)²+4.8990P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11620
_refine_ls_number_parameters     483
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0481
_refine_ls_R_factor_gt           0.0315
_refine_ls_wR_factor_ref         0.0725
_refine_ls_wR_factor_gt          0.0656
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.019
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.20104(2) 0.55021(2) 0.39231(2) 0.01867(4) Uani 1 1 d . . . . .
P1 P 0.28751(3) 0.77708(3) 0.14774(2) 0.02742(11) Uani 1 1 d . . . . .
F1 F 0.32030(9) 0.69519(7) 0.16094(5) 0.0519(4) Uani 1 1 d . . . . .
F6 F 0.32958(9) 0.80741(7) 0.19556(4) 0.0487(3) Uani 1 1 d . . . . .
F4 F 0.20216(8) 0.75951(9) 0.17560(5) 0.0525(4) Uani 1 1 d . . . . .
N3 N 0.10085(9) 0.45840(7) 0.38460(5) 0.0202(3) Uani 1 1 d . . . . .
N2 N 0.25409(8) 0.63944(7) 0.30221(5) 0.0161(3) Uani 1 1 d . . . . .
F2 F 0.37288(9) 0.79389(10) 0.12019(5) 0.0618(4) Uani 1 1 d . . . . .
F3 F 0.25403(10) 0.85920(7) 0.13591(5) 0.0572(4) Uani 1 1 d . . . . .
F5 F 0.24583(10) 0.74687(9) 0.10010(5) 0.0599(4) Uani 1 1 d . . . . .
N1 N 0.32324(9) 0.67737(7) 0.36276(5) 0.0180(3) Uani 1 1 d . . . . .
N4 N 0.06773(10) 0.43933(8) 0.46560(5) 0.0231(3) Uani 1 1 d . . . . .
C1 C 0.26454(10) 0.62602(9) 0.34926(5) 0.0159(3) Uani 1 1 d . . . . .
N5 N 0.18989(9) 0.51620(8) 0.47040(5) 0.0204(3) Uani 1 1 d . . . . .
C3 C 0.30464(11) 0.69795(9) 0.28679(6) 0.0218(3) Uani 1 1 d . . . . .
H3 H 0.308105 0.717268 0.255415 0.026 Uiso 1 1 calc R U . . .
C16 C 0.19483(10) 0.59902(9) 0.27286(5) 0.0175(3) Uani 1 1 d . . . . .
C21 C 0.11234(11) 0.62666(10) 0.26912(6) 0.0216(3) Uani 1 1 d . . . . .
C2 C 0.34798(11) 0.72213(10) 0.32499(6) 0.0231(4) Uani 1 1 d . . . . .
H2 H 0.387743 0.762077 0.325885 0.028 Uiso 1 1 calc R U . . .
C28 C 0.05323(10) 0.42554(9) 0.41761(6) 0.0180(3) Uani 1 1 d . . . . .
C9 C 0.42354(11) 0.65322(10) 0.42692(6) 0.0244(4) Uani 1 1 d . . . . .
C25 C 0.08401(11) 0.69691(10) 0.29519(7) 0.0254(4) Uani 1 1 d . . . . .
H25 H 0.135777 0.723725 0.306513 0.030 Uiso 1 1 calc R U . . .
C29 C -0.01431(11) 0.37659(9) 0.40647(6) 0.0211(3) Uani 1 1 d . . . . .
C32 C 0.08566(11) 0.44111(9) 0.33868(6) 0.0215(3) Uani 1 1 d . . . . .
H32 H 0.120045 0.463644 0.314977 0.026 Uiso 1 1 calc R U . . .
C34 C 0.13462(11) 0.47001(9) 0.49133(6) 0.0194(3) Uani 1 1 d . . . . .
C5 C 0.29775(12) 0.73187(10) 0.44078(6) 0.0244(4) Uani 1 1 d . . . . .
C31 C 0.02320(11) 0.39276(9) 0.32459(6) 0.0229(3) Uani 1 1 d . . . . .
H31 H 0.015140 0.381173 0.291986 0.027 Uiso 1 1 calc R U . . .
C6 C 0.32315(13) 0.73996(11) 0.48790(7) 0.0307(4) Uani 1 1 d . . . . .
H6 H 0.290018 0.769531 0.508916 0.037 Uiso 1 1 calc R U . . .
C4 C 0.34939(11) 0.68810(9) 0.41123(6) 0.0214(3) Uani 1 1 d . . . . .
C30 C -0.02808(11) 0.36111(9) 0.35931(7) 0.0240(4) Uani 1 1 d . . . . .
H30 H -0.072932 0.328562 0.350377 0.029 Uiso 1 1 calc R U . . .
C20 C 0.05569(12) 0.58539(11) 0.24193(7) 0.0287(4) Uani 1 1 d . . . . .
H20 H -0.001136 0.602047 0.238948 0.034 Uiso 1 1 calc R U . . .
C33 C -0.06801(12) 0.34211(10) 0.44472(7) 0.0284(4) Uani 1 1 d . . . . .
H33A H -0.113209 0.312322 0.430172 0.043 Uiso 1 1 calc R U . . .
H33B H -0.092922 0.381926 0.464230 0.043 Uiso 1 1 calc R U . . .
H33C H -0.032904 0.309597 0.464703 0.043 Uiso 1 1 calc R U . . .
C13 C 0.47751(12) 0.60362(11) 0.39524(7) 0.0282(4) Uani 1 1 d . . . . .
H13 H 0.455669 0.608708 0.362083 0.034 Uiso 1 1 calc R U . . .
C10 C 0.21580(12) 0.76740(10) 0.42343(7) 0.0267(4) Uani 1 1 d . . . . .
H10 H 0.207402 0.752726 0.389495 0.032 Uiso 1 1 calc R U . . .
C8 C 0.44521(13) 0.66326(11) 0.47456(7) 0.0303(4) Uani 1 1 d . . . . .
H8 H 0.495090 0.640357 0.486551 0.036 Uiso 1 1 calc R U . . .
C35 C 0.13921(12) 0.45102(10) 0.53996(6) 0.0242(4) Uani 1 1 d . . . . .
C19 C 0.08089(13) 0.52045(12) 0.21918(7) 0.0317(4) Uani 1 1 d . . . . .
H19 H 0.040969 0.492846 0.201001 0.038 Uiso 1 1 calc R U . . .
C7 C 0.39566(14) 0.70571(11) 0.50451(7) 0.0334(5) Uani 1 1 d . . . . .
H7 H 0.411502 0.711458 0.536837 0.040 Uiso 1 1 calc R U . . .
C38 C 0.25315(12) 0.54474(10) 0.49725(6) 0.0259(4) Uani 1 1 d . . . . .
H38 H 0.292943 0.577198 0.482518 0.031 Uiso 1 1 calc R U . . .
C17 C 0.22252(11) 0.53432(10) 0.24968(6) 0.0226(3) Uani 1 1 d . . . . .
C27 C 0.03157(13) 0.67575(13) 0.33868(7) 0.0374(5) Uani 1 1 d . . . . .
H27A H -0.018835 0.648005 0.328582 0.056 Uiso 1 1 calc R U . . .
H27B H 0.014374 0.721430 0.355482 0.056 Uiso 1 1 calc R U . . .
H27C H 0.065513 0.644223 0.359886 0.056 Uiso 1 1 calc R U . . .
C36 C 0.20464(13) 0.48157(12) 0.56572(7) 0.0332(4) Uani 1 1 d . . . . .
H36 H 0.210086 0.469813 0.598472 0.040 Uiso 1 1 calc R U . . .
C39 C 0.07557(14) 0.40010(11) 0.56295(7) 0.0322(4) Uani 1 1 d . . . . .
H39A H 0.091251 0.391861 0.596203 0.048 Uiso 1 1 calc R U . . .
H39B H 0.074486 0.351899 0.546206 0.048 Uiso 1 1 calc R U . . .
H39C H 0.019447 0.423322 0.561462 0.048 Uiso 1 1 calc R U . . .
C22 C 0.31322(12) 0.50743(11) 0.25253(7) 0.0286(4) Uani 1 1 d . . . . .
H22 H 0.344883 0.542626 0.273710 0.034 Uiso 1 1 calc R U . . .
C24 C 0.35378(14) 0.51074(12) 0.20324(8) 0.0383(5) Uani 1 1 d . . . . .
H24A H 0.327386 0.473153 0.182606 0.057 Uiso 1 1 calc R U . . .
H24B H 0.414458 0.500335 0.205911 0.057 Uiso 1 1 calc R U . . .
H24C H 0.345480 0.560833 0.189648 0.057 Uiso 1 1 calc R U . . .
C18 C 0.16312(13) 0.49504(11) 0.22244(6) 0.0290(4) Uani 1 1 d . . . . .
H18 H 0.179517 0.450701 0.206119 0.035 Uiso 1 1 calc R U . . .
C37 C 0.26277(13) 0.52930(12) 0.54452(7) 0.0335(4) Uani 1 1 d . . . . .
H37 H 0.307867 0.550599 0.562267 0.040 Uiso 1 1 calc R U . . .
C11 C 0.14024(14) 0.73894(13) 0.45187(9) 0.0413(5) Uani 1 1 d . . . . .
H11A H 0.137315 0.684109 0.449549 0.062 Uiso 1 1 calc R U . . .
H11B H 0.088145 0.760877 0.439124 0.062 Uiso 1 1 calc R U . . .
H11C H 0.146728 0.753531 0.485212 0.062 Uiso 1 1 calc R U . . .
C26 C 0.03492(13) 0.75047(12) 0.26309(8) 0.0375(5) Uani 1 1 d . . . . .
H26A H 0.069810 0.763798 0.235598 0.056 Uiso 1 1 calc R U . . .
H26B H 0.020522 0.796020 0.280836 0.056 Uiso 1 1 calc R U . . .
H26C H -0.017083 0.725968 0.252215 0.056 Uiso 1 1 calc R U . . .
C12 C 0.21939(17) 0.85303(12) 0.42600(11) 0.0534(7) Uani 1 1 d . . . . .
H12A H 0.227381 0.868656 0.459050 0.080 Uiso 1 1 calc R U . . .
H12B H 0.166356 0.874059 0.413861 0.080 Uiso 1 1 calc R U . . .
H12C H 0.266719 0.871286 0.406737 0.080 Uiso 1 1 calc R U . . .
C15 C 0.4676(2) 0.52171(14) 0.40978(11) 0.0652(8) Uani 1 1 d . . . . .
H15A H 0.484903 0.515640 0.442961 0.098 Uiso 1 1 calc R U . . .
H15B H 0.503189 0.490149 0.389467 0.098 Uiso 1 1 calc R U . . .
H15C H 0.408310 0.506652 0.406266 0.098 Uiso 1 1 calc R U . . .
C14 C 0.56975(15) 0.62744(16) 0.39502(10) 0.0544(7) Uani 1 1 d . . . . .
H14A H 0.573972 0.679980 0.384978 0.082 Uiso 1 1 calc R U . . .
H14B H 0.601513 0.595671 0.372909 0.082 Uiso 1 1 calc R U . . .
H14C H 0.593287 0.622043 0.427015 0.082 Uiso 1 1 calc R U . . .
C23 C 0.31952(16) 0.42890(14) 0.27383(10) 0.0514(6) Uani 1 1 d . . . . .
H23A H 0.293688 0.428718 0.305447 0.077 Uiso 1 1 calc R U . . .
H23B H 0.379138 0.414405 0.276381 0.077 Uiso 1 1 calc R U . . .
H23C H 0.289790 0.393123 0.253337 0.077 Uiso 1 1 calc R U . . .
H4 H 0.0379(14) 0.4158(12) 0.4826(8) 0.031(6) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.0744(15) . ?
Ag1 N3 2.2872(14) . ?
Ag1 N5 2.2889(14) . ?
P1 F2 1.5856(14) . ?
P1 F5 1.5889(14) . ?
P1 F3 1.5913(13) . ?
P1 F1 1.5921(13) . ?
P1 F4 1.5924(13) . ?
P1 F6 1.5967(14) . ?
N3 C28 1.332(2) . ?
N3 C32 1.352(2) . ?
N2 C1 1.357(2) . ?
N2 C3 1.384(2) . ?
N2 C16 1.442(2) . ?
N1 C1 1.357(2) . ?
N1 C2 1.386(2) . ?
N1 C4 1.439(2) . ?
N4 C28 1.393(2) . ?
N4 C34 1.394(2) . ?
N4 H4 0.79(2) . ?
N5 C34 1.337(2) . ?
N5 C38 1.353(2) . ?
C3 C2 1.347(2) . ?
C3 H3 0.9500 . ?
C16 C17 1.395(2) . ?
C16 C21 1.398(2) . ?
C21 C20 1.389(2) . ?
C21 C25 1.519(2) . ?
C2 H2 0.9500 . ?
C28 C29 1.414(2) . ?
C9 C8 1.397(2) . ?
C9 C4 1.399(3) . ?
C9 C13 1.518(3) . ?
C25 C27 1.527(3) . ?
C25 C26 1.527(3) . ?
C25 H25 1.0000 . ?
C29 C30 1.374(3) . ?
C29 C33 1.503(2) . ?
C32 C31 1.369(2) . ?
C32 H32 0.9500 . ?
C34 C35 1.413(2) . ?
C5 C6 1.394(3) . ?
C5 C4 1.403(2) . ?
C5 C10 1.523(3) . ?
C31 C30 1.390(2) . ?
C31 H31 0.9500 . ?
C6 C7 1.381(3) . ?
C6 H6 0.9500 . ?
C30 H30 0.9500 . ?
C20 C19 1.381(3) . ?
C20 H20 0.9500 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C13 C14 1.519(3) . ?
C13 C15 1.524(3) . ?
C13 H13 1.0000 . ?
C10 C11 1.525(3) . ?
C10 C12 1.528(3) . ?
C10 H10 1.0000 . ?
C8 C7 1.378(3) . ?
C8 H8 0.9500 . ?
C35 C36 1.376(3) . ?
C35 C39 1.502(3) . ?
C19 C18 1.380(3) . ?
C19 H19 0.9500 . ?
C7 H7 0.9500 . ?
C38 C37 1.368(3) . ?
C38 H38 0.9500 . ?
C17 C18 1.400(2) . ?
C17 C22 1.514(2) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C36 C37 1.387(3) . ?
C36 H36 0.9500 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C22 C23 1.526(3) . ?
C22 C24 1.531(3) . ?
C22 H22 1.0000 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C18 H18 0.9500 . ?
C37 H37 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 N3 138.19(6) . . ?
C1 Ag1 N5 140.50(6) . . ?
N3 Ag1 N5 81.29(5) . . ?
F2 P1 F5 90.21(9) . . ?
F2 P1 F3 90.40(9) . . ?
F5 P1 F3 89.80(8) . . ?
F2 P1 F1 90.59(8) . . ?
F5 P1 F1 91.26(9) . . ?
F3 P1 F1 178.55(8) . . ?
F2 P1 F4 179.48(9) . . ?
F5 P1 F4 89.90(9) . . ?
F3 P1 F4 90.11(8) . . ?
F1 P1 F4 88.90(8) . . ?
F2 P1 F6 89.68(8) . . ?
F5 P1 F6 179.89(10) . . ?
F3 P1 F6 90.23(8) . . ?
F1 P1 F6 88.71(8) . . ?
F4 P1 F6 90.21(8) . . ?
C28 N3 C32 117.88(14) . . ?
C28 N3 Ag1 129.76(11) . . ?
C32 N3 Ag1 112.14(11) . . ?
C1 N2 C3 111.66(14) . . ?
C1 N2 C16 123.45(13) . . ?
C3 N2 C16 124.84(13) . . ?
C1 N1 C2 111.43(13) . . ?
C1 N1 C4 123.49(13) . . ?
C2 N1 C4 124.80(13) . . ?
C28 N4 C34 134.32(15) . . ?
C28 N4 H4 113.2(16) . . ?
C34 N4 H4 110.2(16) . . ?
N2 C1 N1 103.79(13) . . ?
N2 C1 Ag1 128.81(11) . . ?
N1 C1 Ag1 127.29(11) . . ?
C34 N5 C38 117.89(15) . . ?
C34 N5 Ag1 129.57(11) . . ?
C38 N5 Ag1 112.39(11) . . ?
C2 C3 N2 106.49(14) . . ?
C2 C3 H3 126.8 . . ?
N2 C3 H3 126.8 . . ?
C17 C16 C21 123.26(15) . . ?
C17 C16 N2 118.48(14) . . ?
C21 C16 N2 118.26(15) . . ?
C20 C21 C16 117.18(16) . . ?
C20 C21 C25 120.84(16) . . ?
C16 C21 C25 121.93(15) . . ?
C3 C2 N1 106.62(14) . . ?
C3 C2 H2 126.7 . . ?
N1 C2 H2 126.7 . . ?
N3 C28 N4 120.46(15) . . ?
N3 C28 C29 122.90(15) . . ?
N4 C28 C29 116.64(15) . . ?
C8 C9 C4 116.90(17) . . ?
C8 C9 C13 120.10(17) . . ?
C4 C9 C13 122.95(16) . . ?
C21 C25 C27 110.18(15) . . ?
C21 C25 C26 112.24(16) . . ?
C27 C25 C26 110.71(16) . . ?
C21 C25 H25 107.8 . . ?
C27 C25 H25 107.8 . . ?
C26 C25 H25 107.8 . . ?
C30 C29 C28 117.25(16) . . ?
C30 C29 C33 121.44(15) . . ?
C28 C29 C33 121.30(16) . . ?
N3 C32 C31 123.30(16) . . ?
N3 C32 H32 118.3 . . ?
C31 C32 H32 118.3 . . ?
N5 C34 N4 120.52(15) . . ?
N5 C34 C35 122.77(16) . . ?
N4 C34 C35 116.70(15) . . ?
C6 C5 C4 117.05(18) . . ?
C6 C5 C10 120.51(17) . . ?
C4 C5 C10 122.41(16) . . ?
C32 C31 C30 118.16(16) . . ?
C32 C31 H31 120.9 . . ?
C30 C31 H31 120.9 . . ?
C7 C6 C5 121.08(18) . . ?
C7 C6 H6 119.5 . . ?
C5 C6 H6 119.5 . . ?
C9 C4 C5 123.19(16) . . ?
C9 C4 N1 118.79(15) . . ?
C5 C4 N1 118.00(16) . . ?
C29 C30 C31 120.43(16) . . ?
C29 C30 H30 119.8 . . ?
C31 C30 H30 119.8 . . ?
C19 C20 C21 120.88(17) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 H20 119.6 . . ?
C29 C33 H33A 109.5 . . ?
C29 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C29 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C9 C13 C14 112.30(17) . . ?
C9 C13 C15 109.97(17) . . ?
C14 C13 C15 111.6(2) . . ?
C9 C13 H13 107.6 . . ?
C14 C13 H13 107.6 . . ?
C15 C13 H13 107.6 . . ?
C5 C10 C11 111.09(16) . . ?
C5 C10 C12 111.60(17) . . ?
C11 C10 C12 109.63(18) . . ?
C5 C10 H10 108.1 . . ?
C11 C10 H10 108.1 . . ?
C12 C10 H10 108.1 . . ?
C7 C8 C9 121.29(19) . . ?
C7 C8 H8 119.4 . . ?
C9 C8 H8 119.4 . . ?
C36 C35 C34 117.09(16) . . ?
C36 C35 C39 121.01(17) . . ?
C34 C35 C39 121.90(17) . . ?
C18 C19 C20 121.04(17) . . ?
C18 C19 H19 119.5 . . ?
C20 C19 H19 119.5 . . ?
C8 C7 C6 120.49(18) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
N5 C38 C37 123.41(17) . . ?
N5 C38 H38 118.3 . . ?
C37 C38 H38 118.3 . . ?
C16 C17 C18 117.31(16) . . ?
C16 C17 C22 122.26(15) . . ?
C18 C17 C22 120.41(17) . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C35 C36 C37 120.89(18) . . ?
C35 C36 H36 119.6 . . ?
C37 C36 H36 119.6 . . ?
C35 C39 H39A 109.5 . . ?
C35 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C35 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C17 C22 C23 111.89(17) . . ?
C17 C22 C24 109.68(16) . . ?
C23 C22 C24 111.39(17) . . ?
C17 C22 H22 107.9 . . ?
C23 C22 H22 107.9 . . ?
C24 C22 H22 107.9 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C19 C18 C17 120.30(18) . . ?
C19 C18 H18 119.8 . . ?
C17 C18 H18 119.8 . . ?
C38 C37 C36 117.95(19) . . ?
C38 C37 H37 121.0 . . ?
C36 C37 H37 121.0 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?

_refine_diff_density_max         0.433
_refine_diff_density_min         -0.370
_refine_diff_density_rms         0.065



