# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_a
_database_code_depnum_ccdc_archive 'CCDC 2372344'
loop_
_audit_author_name
_audit_author_address
'Alexander Goloveshkin'
;Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS)
Russia
;
_audit_update_record             
;
2024-07-21 deposited with the CCDC.	2024-10-17 downloaded from the CCDC.
;
_audit_creation_date             2024-07-21
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C42 H27 Eu N2 O7, H2 O'
_chemical_formula_sum            'C42 H29 Eu N2 O8'
_chemical_formula_weight         841.63
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.0051(3)
_cell_length_b                   11.6133(3)
_cell_length_c                   17.4351(5)
_cell_angle_alpha                72.3670(10)
_cell_angle_beta                 81.1620(10)
_cell_angle_gamma                82.4180(10)
_cell_volume                     1709.97(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9079
_cell_measurement_temperature    120
_cell_measurement_theta_max      29.38
_cell_measurement_theta_min      2.30
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.895
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6514
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0670 before and 0.0364 after correction.
The Ratio of minimum to maximum transmission is 0.8731.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.635
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             844
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_unetI/netI     0.0574
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.971
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            21560
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.971
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.606
_diffrn_reflns_theta_min         1.234
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8687
_reflns_number_total             10223
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         0.842
_refine_diff_density_min         -0.762
_refine_diff_density_rms         0.116
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     484
_refine_ls_number_reflns         10223
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0373
_refine_ls_R_factor_gt           0.0291
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0223P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0563
_refine_ls_wR_factor_ref         0.0574
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 Eu1-H7A \\sim Eu1-H7B
 with sigma of 0.02
3.a Free rotating group:
 O7(H7A,H7B), O8(H8A,H8B)
3.b Aromatic/amide H refined with riding coordinates:
 C30(H30), C27(H27), C7(H7), C11(H11), C12(H12), C40(H40), C39(H39), C33(H33),
 C1(H1), C36(H36), C2(H2), C42(H42), C34(H34), C8(H8), C28(H28), C18(H18),
 C14(H14), C22(H22), C15(H15), C23(H23), C24(H24), C17(H17), C20(H20), C16(H16),
  C21(H21)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.45639(2) 0.54272(2) 0.85059(2) 0.00942(3) Uani 1 1 d D . . . .
O4 O 0.87430(16) 0.39240(14) 0.95235(9) 0.0141(3) Uani 1 1 d . . . . .
O5 O 0.49108(17) -0.34398(13) 0.93288(9) 0.0149(3) Uani 1 1 d . . . . .
O6 O 0.62651(17) -0.38379(13) 1.03599(9) 0.0142(3) Uani 1 1 d . . . . .
O2 O 0.61049(17) 0.71092(13) 0.75847(9) 0.0150(3) Uani 1 1 d . . . . .
O3 O 0.68114(17) 0.43760(13) 0.87995(9) 0.0145(3) Uani 1 1 d . . . . .
O1 O 0.38315(17) 0.69463(14) 0.73141(9) 0.0173(3) Uani 1 1 d . . . . .
O7 O 0.19804(17) 0.61328(15) 0.88825(9) 0.0164(3) Uani 1 1 d G . . . .
H7A H 0.161779 0.618428 0.935204 0.025 Uiso 1 1 d DG U . . .
H7B H 0.121854 0.626789 0.862403 0.025 Uiso 1 1 d DG U . . .
N2 N 0.5940(2) 0.47089(17) 0.72500(11) 0.0135(4) Uani 1 1 d . . . . .
N1 N 0.3171(2) 0.41062(16) 0.79362(11) 0.0121(4) Uani 1 1 d . . . . .
O8 O -0.08328(19) 0.62661(17) 0.83778(12) 0.0286(4) Uani 1 1 d G . . . .
H8A H -0.166008 0.670002 0.828816 0.043 Uiso 1 1 d G U . . .
H8B H -0.108214 0.563996 0.875708 0.043 Uiso 1 1 d G U . . .
C38 C 0.5742(2) -0.3130(2) 0.97362(13) 0.0119(4) Uani 1 1 d . . . . .
C26 C 0.5229(2) 0.84809(19) 0.63754(13) 0.0138(5) Uani 1 1 d . . . . .
C6 C 0.5263(2) 0.40242(19) 0.69210(13) 0.0118(4) Uani 1 1 d . . . . .
C30 C 0.4206(3) 0.8712(2) 0.58293(13) 0.0153(5) Uani 1 1 d . . . . .
H30 H 0.338905 0.824816 0.594761 0.018 Uiso 1 1 calc R U . . .
C10 C 0.5948(2) 0.3624(2) 0.62469(13) 0.0139(4) Uani 1 1 d . . . . .
C27 C 0.6473(3) 0.9194(2) 0.62050(13) 0.0171(5) Uani 1 1 d . . . . .
H27 H 0.716168 0.903963 0.657832 0.021 Uiso 1 1 calc R U . . .
C7 C 0.7341(2) 0.4971(2) 0.69288(14) 0.0171(5) Uani 1 1 d . . . . .
H7 H 0.783512 0.541395 0.715955 0.021 Uiso 1 1 calc R U . . .
C37 C 0.6079(2) -0.18255(19) 0.94849(13) 0.0117(4) Uani 1 1 d . . . . .
C11 C 0.5166(2) 0.2852(2) 0.59771(14) 0.0172(5) Uani 1 1 d . . . . .
H11 H 0.558331 0.261871 0.551911 0.021 Uiso 1 1 calc R U . . .
C12 C 0.3833(2) 0.2454(2) 0.63727(14) 0.0176(5) Uani 1 1 d . . . . .
H12 H 0.336812 0.193596 0.618895 0.021 Uiso 1 1 calc R U . . .
C4 C 0.3119(2) 0.2814(2) 0.70694(13) 0.0133(4) Uani 1 1 d . . . . .
C35 C 0.7232(2) -0.01984(19) 0.97292(13) 0.0121(4) Uani 1 1 d . . . . .
C40 C 0.5516(2) 0.0253(2) 0.86967(13) 0.0154(5) Uani 1 1 d . . . . .
H40 H 0.501117 0.081348 0.829492 0.019 Uiso 1 1 calc R U . . .
C5 C 0.3795(2) 0.36508(19) 0.73142(13) 0.0116(4) Uani 1 1 d . . . . .
C41 C 0.6458(2) 0.06627(19) 0.91223(13) 0.0123(4) Uani 1 1 d . . . . .
C39 C 0.5338(2) -0.09549(19) 0.88677(13) 0.0140(4) Uani 1 1 d . . . . .
H39 H 0.472648 -0.120647 0.857654 0.017 Uiso 1 1 calc R U . . .
C31 C 0.7702(2) 0.36189(19) 0.92462(13) 0.0115(4) Uani 1 1 d . . . . .
C25 C 0.5047(3) 0.7454(2) 0.71380(13) 0.0142(5) Uani 1 1 d . . . . .
C33 C 0.8284(2) 0.14174(19) 1.00192(13) 0.0148(5) Uani 1 1 d . . . . .
H33 H 0.888915 0.166868 1.031405 0.018 Uiso 1 1 calc R U . . .
C9 C 0.7425(2) 0.3970(2) 0.58995(13) 0.0145(5) Uani 1 1 d . . . . .
C13 C 0.1045(2) 0.1364(2) 0.74207(13) 0.0133(4) Uani 1 1 d . . . . .
C32 C 0.7521(2) 0.22876(19) 0.94142(13) 0.0118(4) Uani 1 1 d . . . . .
C3 C 0.1744(2) 0.2379(2) 0.75230(13) 0.0123(4) Uani 1 1 d . . . . .
C1 C 0.1824(2) 0.3754(2) 0.83126(13) 0.0137(4) Uani 1 1 d . . . . .
H1 H 0.135134 0.409402 0.871662 0.016 Uiso 1 1 calc R U . . .
C29 C 0.5628(2) 1.03506(19) 0.49144(13) 0.0134(4) Uani 1 1 d . . . . .
C36 C 0.7015(2) -0.14475(19) 0.98925(13) 0.0139(4) Uani 1 1 d . . . . .
H36 H 0.752176 -0.202225 1.028687 0.017 Uiso 1 1 calc R U . . .
C2 C 0.1099(2) 0.29040(19) 0.81270(13) 0.0137(4) Uani 1 1 d . . . . .
H2 H 0.016864 0.268449 0.841157 0.016 Uiso 1 1 calc R U . . .
C19 C 0.8240(2) 0.3608(2) 0.51866(13) 0.0150(5) Uani 1 1 d . . . . .
C42 C 0.6635(2) 0.19151(19) 0.89784(13) 0.0130(4) Uani 1 1 d . . . . .
H42 H 0.613774 0.249169 0.858051 0.016 Uiso 1 1 calc R U . . .
C34 C 0.8138(3) 0.0208(2) 1.01734(14) 0.0171(5) Uani 1 1 d . . . . .
H34 H 0.863949 -0.035462 1.057547 0.021 Uiso 1 1 calc R U . . .
C8 C 0.8109(3) 0.4618(2) 0.62650(14) 0.0175(5) Uani 1 1 d . . . . .
H8 H 0.908830 0.482223 0.606969 0.021 Uiso 1 1 calc R U . . .
C28 C 0.6661(3) 1.0105(2) 0.54959(14) 0.0169(5) Uani 1 1 d . . . . .
H28 H 0.747402 1.056922 0.539262 0.020 Uiso 1 1 calc R U . . .
C18 C 0.1890(3) 0.0259(2) 0.74228(14) 0.0194(5) Uani 1 1 d . . . . .
H18 H 0.292888 0.018896 0.742877 0.023 Uiso 1 1 calc R U . . .
C14 C -0.0517(3) 0.1446(2) 0.74046(14) 0.0172(5) Uani 1 1 d . . . . .
H14 H -0.109722 0.216809 0.741025 0.021 Uiso 1 1 calc R U . . .
C22 C 0.9845(3) 0.2951(2) 0.38591(15) 0.0265(6) Uani 1 1 d . . . . .
H22 H 1.037576 0.272512 0.341801 0.032 Uiso 1 1 calc R U . . .
C15 C -0.1202(3) 0.0461(2) 0.73803(15) 0.0232(5) Uani 1 1 d . . . . .
H15 H -0.223442 0.053237 0.735238 0.028 Uiso 1 1 calc R U . . .
C23 C 0.8507(3) 0.3671(2) 0.37744(15) 0.0242(6) Uani 1 1 d . . . . .
H23 H 0.814285 0.394679 0.327298 0.029 Uiso 1 1 calc R U . . .
C24 C 0.7694(3) 0.3990(2) 0.44380(14) 0.0207(5) Uani 1 1 d . . . . .
H24 H 0.677811 0.446259 0.437971 0.025 Uiso 1 1 calc R U . . .
C17 C 0.1189(3) -0.0725(2) 0.74159(15) 0.0249(6) Uani 1 1 d . . . . .
H17 H 0.175849 -0.145662 0.742387 0.030 Uiso 1 1 calc R U . . .
C20 C 0.9604(3) 0.2900(2) 0.52587(15) 0.0249(6) Uani 1 1 d . . . . .
H20 H 0.999119 0.264842 0.575378 0.030 Uiso 1 1 calc R U . . .
C16 C -0.0354(3) -0.0633(2) 0.73974(15) 0.0252(6) Uani 1 1 d . . . . .
H16 H -0.081991 -0.130087 0.739646 0.030 Uiso 1 1 calc R U . . .
C21 C 1.0402(3) 0.2561(2) 0.46014(16) 0.0314(7) Uani 1 1 d . . . . .
H21 H 1.130721 0.207274 0.466005 0.038 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O5 2.2971(15) 1_565 ?
Eu1 O6 2.3608(15) 2_657 ?
Eu1 O2 2.5397(15) . ?
Eu1 O3 2.2663(15) . ?
Eu1 O1 2.3996(15) . ?
Eu1 O7 2.4225(15) . ?
Eu1 N2 2.6506(17) . ?
Eu1 N1 2.5937(18) . ?
O4 C31 1.253(2) . ?
O5 C38 1.258(3) . ?
O6 C38 1.262(3) . ?
O2 C25 1.270(3) . ?
O3 C31 1.270(3) . ?
O1 C25 1.264(3) . ?
O7 H7A 0.8502 . ?
O7 H7B 0.8498 . ?
N2 C6 1.358(3) . ?
N2 C7 1.334(3) . ?
N1 C5 1.361(3) . ?
N1 C1 1.339(3) . ?
O8 H8A 0.8499 . ?
O8 H8B 0.8501 . ?
C38 C37 1.503(3) . ?
C26 C30 1.370(3) . ?
C26 C27 1.422(3) . ?
C26 C25 1.497(3) . ?
C6 C10 1.418(3) . ?
C6 C5 1.448(3) . ?
C30 H30 0.9300 . ?
C30 C29 1.420(3) 2_676 ?
C10 C11 1.430(3) . ?
C10 C9 1.429(3) . ?
C27 H27 0.9300 . ?
C27 C28 1.366(3) . ?
C7 H7 0.9300 . ?
C7 C8 1.397(3) . ?
C37 C39 1.417(3) . ?
C37 C36 1.370(3) . ?
C11 H11 0.9300 . ?
C11 C12 1.352(3) . ?
C12 H12 0.9300 . ?
C12 C4 1.435(3) . ?
C4 C5 1.409(3) . ?
C4 C3 1.427(3) . ?
C35 C41 1.417(3) . ?
C35 C36 1.425(3) . ?
C35 C34 1.416(3) . ?
C40 H40 0.9300 . ?
C40 C41 1.418(3) . ?
C40 C39 1.368(3) . ?
C41 C42 1.425(3) . ?
C39 H39 0.9300 . ?
C31 C32 1.510(3) . ?
C33 H33 0.9300 . ?
C33 C32 1.414(3) . ?
C33 C34 1.368(3) . ?
C9 C19 1.488(3) . ?
C9 C8 1.373(3) . ?
C13 C3 1.475(3) . ?
C13 C18 1.402(3) . ?
C13 C14 1.401(3) . ?
C32 C42 1.371(3) . ?
C3 C2 1.388(3) . ?
C1 H1 0.9300 . ?
C1 C2 1.391(3) . ?
C29 C29 1.422(4) 2_676 ?
C29 C28 1.421(3) . ?
C36 H36 0.9300 . ?
C2 H2 0.9300 . ?
C19 C24 1.389(3) . ?
C19 C20 1.385(3) . ?
C42 H42 0.9300 . ?
C34 H34 0.9300 . ?
C8 H8 0.9300 . ?
C28 H28 0.9300 . ?
C18 H18 0.9300 . ?
C18 C17 1.381(3) . ?
C14 H14 0.9300 . ?
C14 C15 1.384(3) . ?
C22 H22 0.9300 . ?
C22 C23 1.374(4) . ?
C22 C21 1.384(4) . ?
C15 H15 0.9300 . ?
C15 C16 1.388(3) . ?
C23 H23 0.9300 . ?
C23 C24 1.392(3) . ?
C24 H24 0.9300 . ?
C17 H17 0.9300 . ?
C17 C16 1.384(3) . ?
C20 H20 0.9300 . ?
C20 C21 1.389(3) . ?
C16 H16 0.9300 . ?
C21 H21 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu1 O6 91.20(5) 1_565 2_657 ?
O5 Eu1 O2 75.53(5) 1_565 . ?
O5 Eu1 O1 102.73(5) 1_565 . ?
O5 Eu1 O7 79.02(5) 1_565 . ?
O5 Eu1 N2 141.10(6) 1_565 . ?
O5 Eu1 N1 157.46(6) 1_565 . ?
O6 Eu1 O2 161.14(5) 2_657 . ?
O6 Eu1 O1 144.81(5) 2_657 . ?
O6 Eu1 O7 76.34(5) 2_657 . ?
O6 Eu1 N2 114.38(5) 2_657 . ?
O6 Eu1 N1 74.57(5) 2_657 . ?
O2 Eu1 N2 71.73(5) . . ?
O2 Eu1 N1 121.99(5) . . ?
O3 Eu1 O5 87.74(5) . 1_565 ?
O3 Eu1 O6 80.09(5) . 2_657 ?
O3 Eu1 O2 85.95(5) . . ?
O3 Eu1 O1 131.89(5) . . ?
O3 Eu1 O7 152.59(5) . . ?
O3 Eu1 N2 69.75(6) . . ?
O3 Eu1 N1 106.40(5) . . ?
O1 Eu1 O2 53.17(5) . . ?
O1 Eu1 O7 74.90(5) . . ?
O1 Eu1 N2 73.53(5) . . ?
O1 Eu1 N1 81.11(6) . . ?
O7 Eu1 O2 113.24(5) . . ?
O7 Eu1 N2 133.44(5) . . ?
O7 Eu1 N1 80.65(5) . . ?
N1 Eu1 N2 61.41(5) . . ?
C38 O5 Eu1 150.22(14) . 1_545 ?
C38 O6 Eu1 137.58(14) . 2_657 ?
C25 O2 Eu1 89.16(13) . . ?
C31 O3 Eu1 155.13(14) . . ?
C25 O1 Eu1 95.81(13) . . ?
Eu1 O7 H7A 125.0 . . ?
Eu1 O7 H7B 129.8 . . ?
H7A O7 H7B 104.5 . . ?
C6 N2 Eu1 121.29(13) . . ?
C7 N2 Eu1 121.64(15) . . ?
C7 N2 C6 117.04(19) . . ?
C5 N1 Eu1 123.40(14) . . ?
C1 N1 Eu1 119.05(14) . . ?
C1 N1 C5 117.26(19) . . ?
H8A O8 H8B 104.5 . . ?
O5 C38 O6 124.0(2) . . ?
O5 C38 C37 117.93(19) . . ?
O6 C38 C37 118.0(2) . . ?
C30 C26 C27 119.9(2) . . ?
C30 C26 C25 119.5(2) . . ?
C27 C26 C25 120.6(2) . . ?
N2 C6 C10 123.37(19) . . ?
N2 C6 C5 117.01(19) . . ?
C10 C6 C5 119.56(19) . . ?
C26 C30 H30 119.5 . . ?
C26 C30 C29 121.1(2) . 2_676 ?
C29 C30 H30 119.5 2_676 . ?
C6 C10 C11 118.66(19) . . ?
C6 C10 C9 117.7(2) . . ?
C9 C10 C11 123.5(2) . . ?
C26 C27 H27 119.8 . . ?
C28 C27 C26 120.4(2) . . ?
C28 C27 H27 119.8 . . ?
N2 C7 H7 118.2 . . ?
N2 C7 C8 123.7(2) . . ?
C8 C7 H7 118.2 . . ?
C39 C37 C38 120.3(2) . . ?
C36 C37 C38 120.3(2) . . ?
C36 C37 C39 119.2(2) . . ?
C10 C11 H11 119.2 . . ?
C12 C11 C10 121.5(2) . . ?
C12 C11 H11 119.2 . . ?
C11 C12 H12 119.2 . . ?
C11 C12 C4 121.5(2) . . ?
C4 C12 H12 119.2 . . ?
C5 C4 C12 118.56(19) . . ?
C5 C4 C3 118.09(19) . . ?
C3 C4 C12 123.3(2) . . ?
C41 C35 C36 118.2(2) . . ?
C34 C35 C41 119.4(2) . . ?
C34 C35 C36 122.3(2) . . ?
C41 C40 H40 119.5 . . ?
C39 C40 H40 119.5 . . ?
C39 C40 C41 121.0(2) . . ?
N1 C5 C6 116.66(19) . . ?
N1 C5 C4 123.45(19) . . ?
C4 C5 C6 119.82(19) . . ?
C35 C41 C40 119.1(2) . . ?
C35 C41 C42 118.2(2) . . ?
C40 C41 C42 122.6(2) . . ?
C37 C39 H39 119.7 . . ?
C40 C39 C37 120.5(2) . . ?
C40 C39 H39 119.7 . . ?
O4 C31 O3 123.2(2) . . ?
O4 C31 C32 119.17(19) . . ?
O3 C31 C32 117.53(19) . . ?
O2 C25 C26 119.9(2) . . ?
O1 C25 O2 121.8(2) . . ?
O1 C25 C26 118.3(2) . . ?
C32 C33 H33 119.8 . . ?
C34 C33 H33 119.8 . . ?
C34 C33 C32 120.4(2) . . ?
C10 C9 C19 122.1(2) . . ?
C8 C9 C10 117.7(2) . . ?
C8 C9 C19 120.2(2) . . ?
C18 C13 C3 121.1(2) . . ?
C14 C13 C3 120.1(2) . . ?
C14 C13 C18 118.5(2) . . ?
C33 C32 C31 119.84(19) . . ?
C42 C32 C31 120.44(19) . . ?
C42 C32 C33 119.7(2) . . ?
C4 C3 C13 123.80(19) . . ?
C2 C3 C4 116.9(2) . . ?
C2 C3 C13 119.13(19) . . ?
N1 C1 H1 118.5 . . ?
N1 C1 C2 123.0(2) . . ?
C2 C1 H1 118.5 . . ?
C30 C29 C29 118.7(3) 2_676 2_676 ?
C30 C29 C28 122.2(2) 2_676 . ?
C28 C29 C29 119.1(2) . 2_676 ?
C37 C36 C35 121.9(2) . . ?
C37 C36 H36 119.1 . . ?
C35 C36 H36 119.1 . . ?
C3 C2 C1 120.9(2) . . ?
C3 C2 H2 119.5 . . ?
C1 C2 H2 119.5 . . ?
C24 C19 C9 121.8(2) . . ?
C20 C19 C9 119.5(2) . . ?
C20 C19 C24 118.6(2) . . ?
C41 C42 H42 119.3 . . ?
C32 C42 C41 121.4(2) . . ?
C32 C42 H42 119.3 . . ?
C35 C34 H34 119.5 . . ?
C33 C34 C35 120.9(2) . . ?
C33 C34 H34 119.5 . . ?
C7 C8 H8 119.8 . . ?
C9 C8 C7 120.4(2) . . ?
C9 C8 H8 119.8 . . ?
C27 C28 C29 120.8(2) . . ?
C27 C28 H28 119.6 . . ?
C29 C28 H28 119.6 . . ?
C13 C18 H18 119.8 . . ?
C17 C18 C13 120.4(2) . . ?
C17 C18 H18 119.8 . . ?
C13 C14 H14 119.7 . . ?
C15 C14 C13 120.5(2) . . ?
C15 C14 H14 119.7 . . ?
C23 C22 H22 120.0 . . ?
C23 C22 C21 120.0(2) . . ?
C21 C22 H22 120.0 . . ?
C14 C15 H15 119.9 . . ?
C14 C15 C16 120.2(2) . . ?
C16 C15 H15 119.9 . . ?
C22 C23 H23 119.9 . . ?
C22 C23 C24 120.1(2) . . ?
C24 C23 H23 119.9 . . ?
C19 C24 C23 120.6(2) . . ?
C19 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C18 C17 H17 119.7 . . ?
C18 C17 C16 120.6(2) . . ?
C16 C17 H17 119.7 . . ?
C19 C20 H20 119.5 . . ?
C19 C20 C21 120.9(2) . . ?
C21 C20 H20 119.5 . . ?
C15 C16 H16 120.2 . . ?
C17 C16 C15 119.7(2) . . ?
C17 C16 H16 120.2 . . ?
C22 C21 C20 119.8(2) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O5 C38 O6 -65.1(4) 1_545 . . . ?
Eu1 O5 C38 C37 117.6(3) 1_545 . . . ?
Eu1 O6 C38 O5 -38.5(3) 2_657 . . . ?
Eu1 O6 C38 C37 138.75(17) 2_657 . . . ?
Eu1 O2 C25 O1 2.5(2) . . . . ?
Eu1 O2 C25 C26 -176.85(18) . . . . ?
Eu1 O3 C31 O4 -110.2(3) . . . . ?
Eu1 O3 C31 C32 72.5(4) . . . . ?
Eu1 O1 C25 O2 -2.7(2) . . . . ?
Eu1 O1 C25 C26 176.70(16) . . . . ?
Eu1 N2 C6 C10 179.61(15) . . . . ?
Eu1 N2 C6 C5 -3.3(3) . . . . ?
Eu1 N2 C7 C8 -179.67(17) . . . . ?
Eu1 N1 C5 C6 -5.3(3) . . . . ?
Eu1 N1 C5 C4 171.89(16) . . . . ?
Eu1 N1 C1 C2 -170.18(16) . . . . ?
O4 C31 C32 C33 14.1(3) . . . . ?
O4 C31 C32 C42 -165.23(19) . . . . ?
O5 C38 C37 C39 7.1(3) . . . . ?
O5 C38 C37 C36 -178.06(19) . . . . ?
O6 C38 C37 C39 -170.37(19) . . . . ?
O6 C38 C37 C36 4.5(3) . . . . ?
O3 C31 C32 C33 -168.51(19) . . . . ?
O3 C31 C32 C42 12.1(3) . . . . ?
N2 C6 C10 C11 176.7(2) . . . . ?
N2 C6 C10 C9 -0.3(3) . . . . ?
N2 C6 C5 N1 5.4(3) . . . . ?
N2 C6 C5 C4 -171.84(19) . . . . ?
N2 C7 C8 C9 0.5(4) . . . . ?
N1 C1 C2 C3 -0.8(3) . . . . ?
C38 C37 C39 C40 172.9(2) . . . . ?
C38 C37 C36 C35 -173.14(19) . . . . ?
C26 C27 C28 C29 -0.5(3) . . . . ?
C6 N2 C7 C8 2.3(3) . . . . ?
C6 C10 C11 C12 -3.2(3) . . . . ?
C6 C10 C9 C19 -179.5(2) . . . . ?
C6 C10 C9 C8 3.0(3) . . . . ?
C30 C26 C27 C28 -0.5(3) . . . . ?
C30 C26 C25 O2 168.9(2) . . . . ?
C30 C26 C25 O1 -10.5(3) . . . . ?
C30 C29 C28 C27 -179.8(2) 2_676 . . . ?
C10 C6 C5 N1 -177.35(19) . . . . ?
C10 C6 C5 C4 5.4(3) . . . . ?
C10 C11 C12 C4 1.7(4) . . . . ?
C10 C9 C19 C24 62.9(3) . . . . ?
C10 C9 C19 C20 -119.0(3) . . . . ?
C10 C9 C8 C7 -3.1(3) . . . . ?
C27 C26 C30 C29 0.7(3) . . . 2_676 ?
C27 C26 C25 O2 -9.5(3) . . . . ?
C27 C26 C25 O1 171.1(2) . . . . ?
C7 N2 C6 C10 -2.4(3) . . . . ?
C7 N2 C6 C5 174.7(2) . . . . ?
C11 C10 C9 C19 3.8(3) . . . . ?
C11 C10 C9 C8 -173.8(2) . . . . ?
C11 C12 C4 C5 3.4(3) . . . . ?
C11 C12 C4 C3 -177.5(2) . . . . ?
C12 C4 C5 N1 176.1(2) . . . . ?
C12 C4 C5 C6 -6.8(3) . . . . ?
C12 C4 C3 C13 11.1(3) . . . . ?
C12 C4 C3 C2 -173.1(2) . . . . ?
C4 C3 C2 C1 -4.3(3) . . . . ?
C35 C41 C42 C32 -0.3(3) . . . . ?
C40 C41 C42 C32 178.2(2) . . . . ?
C5 N1 C1 C2 3.9(3) . . . . ?
C5 C6 C10 C11 -0.4(3) . . . . ?
C5 C6 C10 C9 -177.3(2) . . . . ?
C5 C4 C3 C13 -169.8(2) . . . . ?
C5 C4 C3 C2 6.0(3) . . . . ?
C41 C35 C36 C37 -0.4(3) . . . . ?
C41 C35 C34 C33 -0.6(3) . . . . ?
C41 C40 C39 C37 0.9(3) . . . . ?
C39 C37 C36 C35 1.8(3) . . . . ?
C39 C40 C41 C35 0.5(3) . . . . ?
C39 C40 C41 C42 -178.0(2) . . . . ?
C31 C32 C42 C41 179.49(18) . . . . ?
C25 C26 C30 C29 -177.66(19) . . . 2_676 ?
C25 C26 C27 C28 177.9(2) . . . . ?
C33 C32 C42 C41 0.1(3) . . . . ?
C9 C10 C11 C12 173.6(2) . . . . ?
C9 C19 C24 C23 177.8(2) . . . . ?
C9 C19 C20 C21 -179.2(2) . . . . ?
C13 C3 C2 C1 171.7(2) . . . . ?
C13 C18 C17 C16 0.8(4) . . . . ?
C13 C14 C15 C16 2.0(4) . . . . ?
C32 C33 C34 C35 0.4(3) . . . . ?
C3 C4 C5 N1 -3.1(3) . . . . ?
C3 C4 C5 C6 174.0(2) . . . . ?
C3 C13 C18 C17 172.9(2) . . . . ?
C3 C13 C14 C15 -174.3(2) . . . . ?
C1 N1 C5 C6 -179.07(19) . . . . ?
C1 N1 C5 C4 -1.9(3) . . . . ?
C29 C29 C28 C27 1.2(4) 2_676 . . . ?
C36 C37 C39 C40 -2.0(3) . . . . ?
C36 C35 C41 C40 -0.7(3) . . . . ?
C36 C35 C41 C42 177.87(19) . . . . ?
C36 C35 C34 C33 -177.9(2) . . . . ?
C19 C9 C8 C7 179.3(2) . . . . ?
C19 C20 C21 C22 1.2(4) . . . . ?
C34 C35 C41 C40 -178.1(2) . . . . ?
C34 C35 C41 C42 0.5(3) . . . . ?
C34 C35 C36 C37 176.9(2) . . . . ?
C34 C33 C32 C31 -179.6(2) . . . . ?
C34 C33 C32 C42 -0.2(3) . . . . ?
C8 C9 C19 C24 -119.6(3) . . . . ?
C8 C9 C19 C20 58.5(3) . . . . ?
C18 C13 C3 C4 49.6(3) . . . . ?
C18 C13 C3 C2 -126.1(2) . . . . ?
C18 C13 C14 C15 -0.9(3) . . . . ?
C18 C17 C16 C15 0.4(4) . . . . ?
C14 C13 C3 C4 -137.1(2) . . . . ?
C14 C13 C3 C2 47.2(3) . . . . ?
C14 C13 C18 C17 -0.5(3) . . . . ?
C14 C15 C16 C17 -1.8(4) . . . . ?
C22 C23 C24 C19 1.5(4) . . . . ?
C23 C22 C21 C20 0.0(4) . . . . ?
C24 C19 C20 C21 -1.0(4) . . . . ?
C20 C19 C24 C23 -0.3(4) . . . . ?
C21 C22 C23 C24 -1.3(4) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
