# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_VL_YbRhSn_2_03_cylindrical
_database_code_depnum_ccdc_archive 'CCDC 2383845'
loop_
_audit_author_name
_audit_author_address
'Joerg Wagler'
;Technische Universitaet Bergakademie Freiberg
Germany
;
_audit_update_record             
;
2024-09-13 deposited with the CCDC.	2024-11-11 downloaded from the CCDC.
;




_audit_creation_method           SHELXL-2019/3
_shelx_SHELXL_version_number     2019/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Rh6 Sn18 Yb5'
_chemical_formula_sum            'Rh6 Sn18 Yb5'
_chemical_formula_weight         3619.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           137
_space_group_name_H-M_alt        'P 42/n m c'
_space_group_name_Hall           '-P 4ac 2a'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z+1/2'
'y, -x+1/2, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y, -z'
'y+1/2, x+1/2, -z+1/2'
'-y, -x, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z-1/2'
'-y, x-1/2, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y, z'
'-y-1/2, -x-1/2, z-1/2'
'y, x, z-1/2'

_cell_length_a                   9.7018(5)
_cell_length_b                   9.7018(5)
_cell_length_c                   13.7933(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1298.29(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9396
_cell_measurement_theta_min      3.32
_cell_measurement_theta_max      30.26

_exptl_crystal_description       piece
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    9.258
_exptl_crystal_F_000             3040
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.030
_exptl_crystal_size_mid          0.020
_exptl_crystal_size_min          0.010
_exptl_absorpt_coefficient_mu    38.423
_shelx_estimated_absorpt_T_min   0.392
_shelx_estimated_absorpt_T_max   0.700
_exptl_absorpt_correction_type   cylinder
_exptl_absorpt_process_details   
;
Interpolation using  Int.Tab. Vol. C (1992) p. 523,Tab. 6.3.3.3
for values of muR in the range 0-2.5, and Int.Tab. Vol.II (1959)
p.302; Table 5.3.6 B for muR in the range 2.6-10.0.
The interpolation procedure of C.W.Dwiggins Jr (Acta Cryst.(1975)
A31,146-148) is used with some modification.
;
_exptl_absorpt_correction_T_min  0.0165
_exptl_absorpt_correction_T_max  0.0403
_exptl_absorpt_correction_T_ave  0.0305
_exptl_crystal_size_rad          0.0750
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Stoe IPDS-2T'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14544
_diffrn_reflns_av_unetI/netI     0.0268
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.954
_diffrn_reflns_theta_max         28.981
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             14544
_reflns_number_gt                11550
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;

_computing_data_collection       'STOE X-AREA'
_computing_cell_refinement       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_solution    ShelXT
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          'Refined as a 3-component twin.,Twin'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0757P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ShelXT
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14544
_refine_ls_number_parameters     45
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0569
_refine_ls_R_factor_gt           0.0423
_refine_ls_wR_factor_ref         0.1164
_refine_ls_wR_factor_gt          0.1084
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Yb1 Yb 0.750000 0.250000 0.250000 0.0210(4) Uani 1 8 d S T P . .
Yb2 Yb 0.250000 0.02547(10) 0.38263(8) 0.0194(2) Uani 1 2 d S T P . .
Rh1 Rh 0.750000 0.250000 0.5060(2) 0.0158(6) Uani 1 4 d S T P . .
Rh2 Rh 0.49530(14) 0.50470(14) 0.250000 0.0171(4) Uani 1 2 d S T P . .
Sn1 Sn 0.250000 0.250000 0.03889(18) 0.0275(6) Uani 1 4 d S T P . .
Sn2 Sn 0.250000 0.0999(2) 0.73881(15) 0.0216(4) Uani 1 2 d S T P . .
Sn3 Sn 0.250000 0.57868(16) 0.16335(12) 0.0196(3) Uani 1 2 d S T P . .
Sn4 Sn 0.57583(15) 0.07429(14) 0.07366(11) 0.0229(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Yb1 Sn2 3.398(2) 3_554 ?
Yb1 Sn2 3.398(2) 10_666 ?
Yb1 Sn2 3.398(2) 4_654 ?
Yb1 Sn2 3.398(2) 9_656 ?
Yb1 Sn4 3.4172(14) . ?
Yb1 Sn4 3.4173(14) 8_665 ?
Yb1 Sn4 3.4173(14) 14_755 ?
Yb1 Sn4 3.4173(14) 13_565 ?
Yb1 Sn4 3.4173(14) 12_656 ?
Yb1 Sn4 3.4173(14) 11_666 ?
Yb1 Sn4 3.4173(14) 7_545 ?
Yb1 Sn4 3.4173(14) 2_655 ?
Yb2 Rh2 3.0160(12) 2 ?
Yb2 Rh2 3.0160(12) 12_656 ?
Yb2 Sn1 3.0644(19) 3 ?
Yb2 Rh1 3.083(2) 9_656 ?
Yb2 Sn3 3.189(2) 2 ?
Yb2 Sn3 3.2105(13) 11_556 ?
Yb2 Sn3 3.2105(13) 12_656 ?
Yb2 Sn4 3.2405(15) 7_545 ?
Yb2 Sn4 3.2405(15) 12_556 ?
Yb2 Sn2 3.2867(18) 3_554 ?
Yb2 Sn2 3.2867(18) 4_554 ?
Yb2 Sn4 3.2885(18) 15_666 ?
Rh1 Sn4 2.640(2) 7_545 ?
Rh1 Sn4 2.640(2) 8_665 ?
Rh1 Sn4 2.640(2) 12_656 ?
Rh1 Sn4 2.640(2) 11_666 ?
Rh1 Sn3 2.734(3) 3_655 ?
Rh1 Sn3 2.734(3) 4 ?
Rh2 Sn2 2.6424(11) 3_554 ?
Rh2 Sn2 2.6424(11) 10_666 ?
Rh2 Sn4 2.6672(19) 13_565 ?
Rh2 Sn4 2.6672(19) 11_666 ?
Rh2 Sn3 2.7582(18) . ?
Rh2 Sn3 2.7582(18) 12_666 ?
Sn1 Sn2 3.119(3) 3_554 ?
Sn1 Sn2 3.119(3) 4_554 ?
Sn2 Sn2 2.913(4) 2 ?
Sn4 Sn4 2.893(3) 9_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sn2 Yb1 Sn2 90.118(3) 3_554 10_666 ?
Sn2 Yb1 Sn2 174.79(7) 3_554 4_654 ?
Sn2 Yb1 Sn2 90.118(3) 10_666 4_654 ?
Sn2 Yb1 Sn2 90.118(3) 3_554 9_656 ?
Sn2 Yb1 Sn2 174.79(7) 10_666 9_656 ?
Sn2 Yb1 Sn2 90.118(3) 4_654 9_656 ?
Sn2 Yb1 Sn4 58.24(4) 3_554 . ?
Sn2 Yb1 Sn4 122.05(4) 10_666 . ?
Sn2 Yb1 Sn4 117.49(4) 4_654 . ?
Sn2 Yb1 Sn4 62.23(4) 9_656 . ?
Sn2 Yb1 Sn4 122.05(4) 3_554 8_665 ?
Sn2 Yb1 Sn4 58.24(4) 10_666 8_665 ?
Sn2 Yb1 Sn4 62.23(4) 4_654 8_665 ?
Sn2 Yb1 Sn4 117.49(4) 9_656 8_665 ?
Sn4 Yb1 Sn4 179.65(4) . 8_665 ?
Sn2 Yb1 Sn4 117.49(4) 3_554 14_755 ?
Sn2 Yb1 Sn4 122.05(4) 10_666 14_755 ?
Sn2 Yb1 Sn4 58.24(4) 4_654 14_755 ?
Sn2 Yb1 Sn4 62.23(4) 9_656 14_755 ?
Sn4 Yb1 Sn4 59.27(5) . 14_755 ?
Sn4 Yb1 Sn4 120.44(3) 8_665 14_755 ?
Sn2 Yb1 Sn4 58.24(4) 3_554 13_565 ?
Sn2 Yb1 Sn4 62.23(4) 10_666 13_565 ?
Sn2 Yb1 Sn4 117.49(4) 4_654 13_565 ?
Sn2 Yb1 Sn4 122.05(4) 9_656 13_565 ?
Sn4 Yb1 Sn4 59.85(5) . 13_565 ?
Sn4 Yb1 Sn4 120.44(3) 8_665 13_565 ?
Sn4 Yb1 Sn4 89.24(6) 14_755 13_565 ?
Sn2 Yb1 Sn4 122.05(4) 3_554 12_656 ?
Sn2 Yb1 Sn4 117.49(4) 10_666 12_656 ?
Sn2 Yb1 Sn4 62.23(4) 4_654 12_656 ?
Sn2 Yb1 Sn4 58.24(4) 9_656 12_656 ?
Sn4 Yb1 Sn4 120.44(3) . 12_656 ?
Sn4 Yb1 Sn4 59.27(5) 8_665 12_656 ?
Sn4 Yb1 Sn4 90.76(6) 14_755 12_656 ?
Sn4 Yb1 Sn4 179.65(4) 13_565 12_656 ?
Sn2 Yb1 Sn4 62.23(4) 3_554 11_666 ?
Sn2 Yb1 Sn4 58.24(4) 10_666 11_666 ?
Sn2 Yb1 Sn4 122.05(4) 4_654 11_666 ?
Sn2 Yb1 Sn4 117.49(4) 9_656 11_666 ?
Sn4 Yb1 Sn4 120.44(3) . 11_666 ?
Sn4 Yb1 Sn4 59.85(5) 8_665 11_666 ?
Sn4 Yb1 Sn4 179.65(4) 14_755 11_666 ?
Sn4 Yb1 Sn4 90.76(6) 13_565 11_666 ?
Sn4 Yb1 Sn4 89.24(6) 12_656 11_666 ?
Sn2 Yb1 Sn4 62.23(4) 3_554 7_545 ?
Sn2 Yb1 Sn4 117.49(4) 10_666 7_545 ?
Sn2 Yb1 Sn4 122.05(4) 4_654 7_545 ?
Sn2 Yb1 Sn4 58.24(4) 9_656 7_545 ?
Sn4 Yb1 Sn4 90.76(6) . 7_545 ?
Sn4 Yb1 Sn4 89.24(6) 8_665 7_545 ?
Sn4 Yb1 Sn4 120.44(3) 14_755 7_545 ?
Sn4 Yb1 Sn4 120.44(3) 13_565 7_545 ?
Sn4 Yb1 Sn4 59.85(5) 12_656 7_545 ?
Sn4 Yb1 Sn4 59.27(5) 11_666 7_545 ?
Sn2 Yb1 Sn4 117.49(4) 3_554 2_655 ?
Sn2 Yb1 Sn4 62.23(4) 10_666 2_655 ?
Sn2 Yb1 Sn4 58.24(4) 4_654 2_655 ?
Sn2 Yb1 Sn4 122.05(4) 9_656 2_655 ?
Sn4 Yb1 Sn4 89.24(6) . 2_655 ?
Sn4 Yb1 Sn4 90.76(6) 8_665 2_655 ?
Sn4 Yb1 Sn4 59.85(5) 14_755 2_655 ?
Sn4 Yb1 Sn4 59.27(5) 13_565 2_655 ?
Sn4 Yb1 Sn4 120.44(3) 12_656 2_655 ?
Sn4 Yb1 Sn4 120.44(3) 11_666 2_655 ?
Sn4 Yb1 Sn4 179.65(4) 7_545 2_655 ?
Rh2 Yb2 Rh2 104.20(5) 2 12_656 ?
Rh2 Yb2 Sn1 119.71(4) 2 3 ?
Rh2 Yb2 Sn1 119.71(4) 12_656 3 ?
Rh2 Yb2 Rh1 102.60(4) 2 9_656 ?
Rh2 Yb2 Rh1 102.60(4) 12_656 9_656 ?
Sn1 Yb2 Rh1 105.41(7) 3 9_656 ?
Rh2 Yb2 Sn3 52.69(3) 2 2 ?
Rh2 Yb2 Sn3 52.69(3) 12_656 2 ?
Sn1 Yb2 Sn3 153.17(6) 3 2 ?
Rh1 Yb2 Sn3 101.42(7) 9_656 2 ?
Rh2 Yb2 Sn3 52.48(4) 2 11_556 ?
Rh2 Yb2 Sn3 102.00(5) 12_656 11_556 ?
Sn1 Yb2 Sn3 136.94(4) 3 11_556 ?
Rh1 Yb2 Sn3 51.45(5) 9_656 11_556 ?
Sn3 Yb2 Sn3 63.18(5) 2 11_556 ?
Rh2 Yb2 Sn3 102.00(5) 2 12_656 ?
Rh2 Yb2 Sn3 52.48(4) 12_656 12_656 ?
Sn1 Yb2 Sn3 136.94(4) 3 12_656 ?
Rh1 Yb2 Sn3 51.45(5) 9_656 12_656 ?
Sn3 Yb2 Sn3 63.18(5) 2 12_656 ?
Sn3 Yb2 Sn3 62.36(5) 11_556 12_656 ?
Rh2 Yb2 Sn4 153.33(5) 2 7_545 ?
Rh2 Yb2 Sn4 50.31(4) 12_656 7_545 ?
Sn1 Yb2 Sn4 76.23(3) 3 7_545 ?
Rh1 Yb2 Sn4 92.18(3) 9_656 7_545 ?
Sn3 Yb2 Sn4 102.96(3) 2 7_545 ?
Sn3 Yb2 Sn4 131.67(4) 11_556 7_545 ?
Sn3 Yb2 Sn4 70.10(4) 12_656 7_545 ?
Rh2 Yb2 Sn4 50.31(4) 2 12_556 ?
Rh2 Yb2 Sn4 153.33(5) 12_656 12_556 ?
Sn1 Yb2 Sn4 76.23(3) 3 12_556 ?
Rh1 Yb2 Sn4 92.18(3) 9_656 12_556 ?
Sn3 Yb2 Sn4 102.96(3) 2 12_556 ?
Sn3 Yb2 Sn4 70.10(4) 11_556 12_556 ?
Sn3 Yb2 Sn4 131.67(4) 12_656 12_556 ?
Sn4 Yb2 Sn4 152.29(6) 7_545 12_556 ?
Rh2 Yb2 Sn2 92.75(5) 2 3_554 ?
Rh2 Yb2 Sn2 49.34(4) 12_656 3_554 ?
Sn1 Yb2 Sn2 87.33(5) 3 3_554 ?
Rh1 Yb2 Sn2 151.09(4) 9_656 3_554 ?
Sn3 Yb2 Sn2 68.75(4) 2 3_554 ?
Sn3 Yb2 Sn2 131.45(5) 11_556 3_554 ?
Sn3 Yb2 Sn2 101.72(4) 12_656 3_554 ?
Sn4 Yb2 Sn2 65.30(4) 7_545 3_554 ?
Sn4 Yb2 Sn2 116.27(5) 12_556 3_554 ?
Rh2 Yb2 Sn2 49.34(4) 2 4_554 ?
Rh2 Yb2 Sn2 92.75(5) 12_656 4_554 ?
Sn1 Yb2 Sn2 87.33(5) 3 4_554 ?
Rh1 Yb2 Sn2 151.09(4) 9_656 4_554 ?
Sn3 Yb2 Sn2 68.75(4) 2 4_554 ?
Sn3 Yb2 Sn2 101.72(4) 11_556 4_554 ?
Sn3 Yb2 Sn2 131.45(5) 12_656 4_554 ?
Sn4 Yb2 Sn2 116.27(5) 7_545 4_554 ?
Sn4 Yb2 Sn2 65.30(4) 12_556 4_554 ?
Sn2 Yb2 Sn2 52.61(7) 3_554 4_554 ?
Rh2 Yb2 Sn4 150.00(4) 2 15_666 ?
Rh2 Yb2 Sn4 92.75(3) 12_656 15_666 ?
Sn1 Yb2 Sn4 69.45(4) 3 15_666 ?
Rh1 Yb2 Sn4 48.82(5) 9_656 15_666 ?
Sn3 Yb2 Sn4 131.70(4) 2 15_666 ?
Sn3 Yb2 Sn4 100.25(5) 11_556 15_666 ?
Sn3 Yb2 Sn4 68.97(4) 12_656 15_666 ?
Sn4 Yb2 Sn4 52.60(4) 7_545 15_666 ?
Sn4 Yb2 Sn4 113.53(4) 12_556 15_666 ?
Sn2 Yb2 Sn4 116.87(5) 3_554 15_666 ?
Sn2 Yb2 Sn4 155.70(5) 4_554 15_666 ?
Sn4 Rh1 Sn4 130.82(15) 7_545 8_665 ?
Sn4 Rh1 Sn4 80.45(8) 7_545 12_656 ?
Sn4 Rh1 Sn4 79.61(7) 8_665 12_656 ?
Sn4 Rh1 Sn4 79.61(7) 7_545 11_666 ?
Sn4 Rh1 Sn4 80.45(8) 8_665 11_666 ?
Sn4 Rh1 Sn4 130.82(15) 12_656 11_666 ?
Sn4 Rh1 Sn3 136.30(8) 7_545 3_655 ?
Sn4 Rh1 Sn3 86.43(5) 8_665 3_655 ?
Sn4 Rh1 Sn3 86.43(5) 12_656 3_655 ?
Sn4 Rh1 Sn3 136.30(8) 11_666 3_655 ?
Sn4 Rh1 Sn3 86.43(5) 7_545 4 ?
Sn4 Rh1 Sn3 136.30(8) 8_665 4 ?
Sn4 Rh1 Sn3 136.30(8) 12_656 4 ?
Sn4 Rh1 Sn3 86.43(5) 11_666 4 ?
Sn3 Rh1 Sn3 74.88(11) 3_655 4 ?
Sn4 Rh1 Yb2 139.67(3) 7_545 10_666 ?
Sn4 Rh1 Yb2 69.66(3) 8_665 10_666 ?
Sn4 Rh1 Yb2 139.67(3) 12_656 10_666 ?
Sn4 Rh1 Yb2 69.66(3) 11_666 10_666 ?
Sn3 Rh1 Yb2 66.69(6) 3_655 10_666 ?
Sn3 Rh1 Yb2 66.69(6) 4 10_666 ?
Sn4 Rh1 Yb2 69.66(3) 7_545 9_656 ?
Sn4 Rh1 Yb2 139.67(3) 8_665 9_656 ?
Sn4 Rh1 Yb2 69.66(3) 12_656 9_656 ?
Sn4 Rh1 Yb2 139.67(3) 11_666 9_656 ?
Sn3 Rh1 Yb2 66.69(6) 3_655 9_656 ?
Sn3 Rh1 Yb2 66.69(6) 4 9_656 ?
Yb2 Rh1 Yb2 120.21(12) 10_666 9_656 ?
Sn4 Rh1 Yb1 65.41(7) 7_545 . ?
Sn4 Rh1 Yb1 65.41(7) 8_665 . ?
Sn4 Rh1 Yb1 65.41(7) 12_656 . ?
Sn4 Rh1 Yb1 65.41(7) 11_666 . ?
Sn3 Rh1 Yb1 142.56(5) 3_655 . ?
Sn3 Rh1 Yb1 142.56(5) 4 . ?
Yb2 Rh1 Yb1 119.90(6) 10_666 . ?
Yb2 Rh1 Yb1 119.90(6) 9_656 . ?
Sn2 Rh2 Sn2 131.07(11) 3_554 10_666 ?
Sn2 Rh2 Sn4 77.31(6) 3_554 13_565 ?
Sn2 Rh2 Sn4 83.09(6) 10_666 13_565 ?
Sn2 Rh2 Sn4 83.09(6) 3_554 11_666 ?
Sn2 Rh2 Sn4 77.31(6) 10_666 11_666 ?
Sn4 Rh2 Sn4 131.56(10) 13_565 11_666 ?
Sn2 Rh2 Sn3 85.21(6) 3_554 . ?
Sn2 Rh2 Sn3 137.84(7) 10_666 . ?
Sn4 Rh2 Sn3 86.12(5) 13_565 . ?
Sn4 Rh2 Sn3 136.00(6) 11_666 . ?
Sn2 Rh2 Sn3 137.84(7) 3_554 12_666 ?
Sn2 Rh2 Sn3 85.21(6) 10_666 12_666 ?
Sn4 Rh2 Sn3 136.00(6) 13_565 12_666 ?
Sn4 Rh2 Sn3 86.12(5) 11_666 12_666 ?
Sn3 Rh2 Sn3 74.85(8) . 12_666 ?
Sn2 Rh2 Yb2 70.67(5) 3_554 2 ?
Sn2 Rh2 Yb2 137.42(5) 10_666 2 ?
Sn4 Rh2 Yb2 139.15(3) 13_565 2 ?
Sn4 Rh2 Yb2 69.22(3) 11_666 2 ?
Sn3 Rh2 Yb2 66.87(5) . 2 ?
Sn3 Rh2 Yb2 67.39(5) 12_666 2 ?
Sn2 Rh2 Yb2 137.42(5) 3_554 11_666 ?
Sn2 Rh2 Yb2 70.67(5) 10_666 11_666 ?
Sn4 Rh2 Yb2 69.22(3) 13_565 11_666 ?
Sn4 Rh2 Yb2 139.15(3) 11_666 11_666 ?
Sn3 Rh2 Yb2 67.39(5) . 11_666 ?
Sn3 Rh2 Yb2 66.87(5) 12_666 11_666 ?
Yb2 Rh2 Yb2 121.40(7) 2 11_666 ?
Sn2 Rh2 Yb1 65.53(6) 3_554 . ?
Sn2 Rh2 Yb1 65.53(6) 10_666 . ?
Sn4 Rh2 Yb1 65.78(5) 13_565 . ?
Sn4 Rh2 Yb1 65.78(5) 11_666 . ?
Sn3 Rh2 Yb1 142.57(4) . . ?
Sn3 Rh2 Yb1 142.57(4) 12_666 . ?
Yb2 Rh2 Yb1 119.30(4) 2 . ?
Yb2 Rh2 Yb1 119.30(4) 11_666 . ?
Yb2 Sn1 Yb2 90.61(8) 4_554 3_554 ?
Yb2 Sn1 Sn2 162.54(7) 4_554 3_554 ?
Yb2 Sn1 Sn2 106.85(4) 3_554 3_554 ?
Yb2 Sn1 Sn2 106.85(4) 4_554 4_554 ?
Yb2 Sn1 Sn2 162.54(7) 3_554 4_554 ?
Sn2 Sn1 Sn2 55.69(9) 3_554 4_554 ?
Rh2 Sn2 Rh2 138.50(11) 10_556 4 ?
Rh2 Sn2 Sn2 110.45(6) 10_556 2 ?
Rh2 Sn2 Sn2 110.45(6) 4 2 ?
Rh2 Sn2 Sn1 102.41(5) 10_556 3 ?
Rh2 Sn2 Sn1 102.41(5) 4 3 ?
Sn2 Sn2 Sn1 62.15(4) 2 3 ?
Rh2 Sn2 Yb2 137.68(7) 10_556 3 ?
Rh2 Sn2 Yb2 59.99(4) 4 3 ?
Sn2 Sn2 Yb2 63.69(4) 2 3 ?
Sn1 Sn2 Yb2 109.07(5) 3 3 ?
Rh2 Sn2 Yb2 59.99(4) 10_556 4 ?
Rh2 Sn2 Yb2 137.68(7) 4 4 ?
Sn2 Sn2 Yb2 63.69(4) 2 4 ?
Sn1 Sn2 Yb2 109.07(5) 3 4 ?
Yb2 Sn2 Yb2 83.03(6) 3 4 ?
Rh2 Sn2 Yb1 69.41(6) 10_556 9_656 ?
Rh2 Sn2 Yb1 69.41(6) 4 9_656 ?
Sn2 Sn2 Yb1 177.40(3) 2 9_656 ?
Sn1 Sn2 Yb1 120.45(7) 3 9_656 ?
Yb2 Sn2 Yb1 114.54(5) 3 9_656 ?
Yb2 Sn2 Yb1 114.54(5) 4 9_656 ?
Rh1 Sn3 Rh2 120.15(3) 3_554 . ?
Rh1 Sn3 Rh2 120.15(3) 3_554 11_566 ?
Rh2 Sn3 Rh2 119.28(6) . 11_566 ?
Rh1 Sn3 Yb2 161.03(7) 3_554 2 ?
Rh2 Sn3 Yb2 60.43(3) . 2 ?
Rh2 Sn3 Yb2 60.43(3) 11_566 2 ?
Rh1 Sn3 Yb2 61.86(4) 3_554 11_666 ?
Rh2 Sn3 Yb2 60.14(2) . 11_666 ?
Rh2 Sn3 Yb2 159.82(6) 11_566 11_666 ?
Yb2 Sn3 Yb2 110.57(4) 2 11_666 ?
Rh1 Sn3 Yb2 61.86(4) 3_554 12_566 ?
Rh2 Sn3 Yb2 159.82(6) . 12_566 ?
Rh2 Sn3 Yb2 60.14(2) 11_566 12_566 ?
Yb2 Sn3 Yb2 110.57(4) 2 12_566 ?
Yb2 Sn3 Yb2 112.70(5) 11_666 12_566 ?
Rh1 Sn4 Rh2 138.81(8) 11_666 12_656 ?
Rh1 Sn4 Sn4 110.80(11) 11_666 9_655 ?
Rh2 Sn4 Sn4 110.39(10) 12_656 9_655 ?
Rh1 Sn4 Yb2 143.22(5) 11_666 11_656 ?
Rh2 Sn4 Yb2 60.48(5) 12_656 11_656 ?
Sn4 Sn4 Yb2 64.55(6) 9_655 11_656 ?
Rh1 Sn4 Yb2 61.52(6) 11_666 3_554 ?
Rh2 Sn4 Yb2 142.38(5) 12_656 3_554 ?
Sn4 Sn4 Yb2 62.85(5) 9_655 3_554 ?
Yb2 Sn4 Yb2 127.39(4) 11_656 3_554 ?
Rh1 Sn4 Yb1 69.97(7) 11_666 . ?
Rh2 Sn4 Yb1 68.84(5) 12_656 . ?
Sn4 Sn4 Yb1 179.03(9) 9_655 . ?
Yb2 Sn4 Yb1 115.24(5) 11_656 . ?
Yb2 Sn4 Yb1 117.36(4) 3_554 . ?

_refine_diff_density_max         2.039
_refine_diff_density_min         -2.994
_refine_diff_density_rms         0.494



_exptl_crystal_recrystallization_method 'From the Melt'
