# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Cu-10
_audit_block_doi                 10.5517/ccdc.csd.cc2jj7cp
_database_code_depnum_ccdc_archive 'CCDC 2339302'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1016/j.molstruc.2024.141098 2025
loop_
_audit_author_name
_audit_author_address
'Hua-Xin Zhang'
;Guangxi University
China
;
_audit_update_record             
;
2024-03-11 deposited with the CCDC.	2025-02-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H30 Cl2 Cu N14 O16'
_chemical_formula_weight         977.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   22.155(3)
_cell_length_b                   12.3764(17)
_cell_length_c                   30.424(4)
_cell_angle_alpha                90
_cell_angle_beta                 102.455(3)
_cell_angle_gamma                90
_cell_volume                     8146(2)
_cell_formula_units_Z            8
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    7784
_cell_measurement_theta_min      1.371
_cell_measurement_theta_max      25.788

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_F_000             3992
_exptl_transmission_factor_min   0.840
_exptl_transmission_factor_max   0.893
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_exptl_absorpt_coefficient_mu    0.756
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'SADABS (Sheldrick,1996)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            38089
_diffrn_reflns_av_unetI/netI     0.0324
_diffrn_reflns_av_R_equivalents  0.0390
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         1.371
_diffrn_reflns_theta_max         25.788
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             7784
_reflns_number_gt                6007
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1486P)²+13.0389P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7784
_refine_ls_number_parameters     568
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0737
_refine_ls_R_factor_gt           0.0549
_refine_ls_wR_factor_ref         0.1967
_refine_ls_wR_factor_gt          0.1707
_refine_ls_goodness_of_fit_ref   0.915
_refine_ls_restrained_S_all      0.915
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.07118(2) 0.81748(3) 0.10199(2) 0.04455(17) Uani 1 1 d . . . . .
Cl1 Cl 0.38336(6) 0.56626(12) 0.18430(4) 0.0779(4) Uani 1 1 d . . . . .
N1 N -0.00604(14) 0.8386(2) 0.05436(9) 0.0414(6) Uani 1 1 d . . . . .
N8 N 0.14370(14) 0.7987(3) 0.15212(10) 0.0475(7) Uani 1 1 d . . . . .
N13 N 0.03926(14) 1.0551(3) 0.12918(10) 0.0500(7) Uani 1 1 d . . . . .
N12 N 0.07365(14) 0.9690(2) 0.13304(9) 0.0460(7) Uani 1 1 d . . . . .
N6 N -0.01287(13) 0.7549(3) 0.17976(10) 0.0508(7) Uani 1 1 d . . . . .
N7 N -0.07303(13) 0.7696(3) 0.17852(10) 0.0484(7) Uani 1 1 d . . . . .
N4 N 0.14225(16) 0.8501(3) -0.02295(10) 0.0525(7) Uani 1 1 d . . . . .
C12 C -0.10383(17) 0.8038(3) 0.13808(12) 0.0501(9) Uani 1 1 d . . . . .
H12A H -0.1457 0.8195 0.1290 0.060 Uiso 1 1 calc R U . . .
C11 C -0.05918(16) 0.8102(3) 0.11304(11) 0.0438(8) Uani 1 1 d . . . . .
N3 N 0.16021(16) 0.8497(3) 0.02223(10) 0.0552(8) Uani 1 1 d . . . . .
N5 N -0.00473(13) 0.7786(3) 0.13959(10) 0.0473(7) Uani 1 1 d . . . . .
N9 N 0.09936(16) 0.6599(3) 0.09000(11) 0.0530(8) Uani 1 1 d . . . . .
C26 C 0.11694(17) 0.9703(3) 0.17267(11) 0.0482(8) Uani 1 1 d . . . . .
C3 C -0.1122(2) 0.8812(3) -0.00914(13) 0.0555(9) Uani 1 1 d . . . . .
H3B H -0.1480 0.8956 -0.0306 0.067 Uiso 1 1 calc R U . . .
C6 C 0.05915(17) 0.8563(3) 0.00223(10) 0.0445(8) Uani 1 1 d . . . . .
C2 C -0.11533(19) 0.8647(3) 0.03533(13) 0.0531(9) Uani 1 1 d . . . . .
H2A H -0.1528 0.8697 0.0442 0.064 Uiso 1 1 calc R U . . .
C5 C -0.00293(18) 0.8579(3) 0.01101(11) 0.0447(8) Uani 1 1 d . . . . .
C1 C -0.06134(17) 0.8404(3) 0.06624(12) 0.0453(8) Uani 1 1 d . . . . .
C4 C -0.0561(2) 0.8766(3) -0.02158(12) 0.0522(9) Uani 1 1 d . . . . .
H4A H -0.0539 0.8858 -0.0515 0.063 Uiso 1 1 calc R U . . .
C7 C 0.08065(18) 0.8541(3) -0.03689(11) 0.0493(8) Uani 1 1 d . . . . .
H7A H 0.0577 0.8552 -0.0663 0.059 Uiso 1 1 calc R U . . .
N2 N 0.10937(15) 0.8543(3) 0.03740(9) 0.0512(7) Uani 1 1 d . . . . .
O7 O 0.03552(16) 1.2865(3) 0.10264(11) 0.0749(9) Uani 1 1 d . . . . .
N14 N 0.06102(16) 1.1141(3) 0.16629(10) 0.0529(8) Uani 1 1 d . . . . .
O2 O 0.21498(16) 0.7152(3) -0.10147(11) 0.0760(9) Uani 1 1 d . . . . .
C20 C 0.17545(19) 0.7046(3) 0.15633(13) 0.0552(9) Uani 1 1 d . . . . .
C21 C 0.15136(18) 0.6297(3) 0.12001(14) 0.0545(9) Uani 1 1 d . . . . .
C16 C 0.15745(18) 0.8772(3) 0.18324(11) 0.0510(9) Uani 1 1 d . . . . .
C29 C 0.02318(19) 1.2964(3) 0.13826(16) 0.0603(10) Uani 1 1 d . . . . .
C27 C 0.10852(19) 1.0649(3) 0.19363(13) 0.0566(10) Uani 1 1 d . . . . .
H27A H 0.1311 1.0899 0.2211 0.068 Uiso 1 1 calc R U . . .
O3 O -0.1008(3) 0.5612(4) 0.1922(2) 0.131(2) Uani 1 1 d . . . . .
N10 N 0.08384(17) 0.5871(3) 0.05902(12) 0.0621(9) Uani 1 1 d . . . . .
C13 C -0.09727(19) 0.7432(4) 0.21819(13) 0.0596(10) Uani 1 1 d . . . . .
H13B H -0.1368 0.7786 0.2163 0.072 Uiso 1 1 calc R U . . .
H13C H -0.0690 0.7689 0.2451 0.072 Uiso 1 1 calc R U . . .
N11 N 0.12700(18) 0.5082(3) 0.06964(14) 0.0685(10) Uani 1 1 d . . . . .
O8 O -0.0001(2) 1.3837(3) 0.15354(16) 0.1029(14) Uani 1 1 d . . . . .
O4 O -0.11959(18) 0.5983(3) 0.25923(13) 0.0923(11) Uani 1 1 d . . . . .
O1 O 0.1635(3) 0.6487(4) -0.05301(18) 0.1241(19) Uani 1 1 d . . . . .
C9 C 0.1859(2) 0.7220(4) -0.06828(15) 0.0685(12) Uani 1 1 d . . . . .
C28 C 0.0315(2) 1.2137(4) 0.17564(16) 0.0692(12) Uani 1 1 d . . . . .
H28A H 0.0560 1.2457 0.2028 0.083 Uiso 1 1 calc R U . . .
H28B H -0.0088 1.1964 0.1815 0.083 Uiso 1 1 calc R U . . .
O10 O 0.3770(2) 0.6678(3) 0.20488(14) 0.0967(12) Uani 1 1 d . . . . .
O6 O 0.1580(2) 0.3763(3) -0.02592(15) 0.0972(12) Uani 1 1 d . . . . .
C8 C 0.1886(2) 0.8348(4) -0.05029(14) 0.0612(10) Uani 1 1 d . . . . .
H8A H 0.2295 0.8488 -0.0321 0.073 Uiso 1 1 calc R U . . .
H8B H 0.1811 0.8857 -0.0751 0.073 Uiso 1 1 calc R U . . .
C17 C 0.2057(2) 0.8635(5) 0.22028(14) 0.0675(12) Uani 1 1 d . . . . .
H17A H 0.2153 0.9171 0.2421 0.081 Uiso 1 1 calc R U . . .
C22 C 0.1695(2) 0.5316(4) 0.10689(16) 0.0650(11) Uani 1 1 d . . . . .
H22A H 0.2035 0.4906 0.1206 0.078 Uiso 1 1 calc R U . . .
O5 O 0.2256(2) 0.4551(4) 0.02905(16) 0.1103(15) Uani 1 1 d . . . . .
C19 C 0.2251(2) 0.6904(4) 0.19237(16) 0.0726(13) Uani 1 1 d . . . . .
H19A H 0.2486 0.6276 0.1949 0.087 Uiso 1 1 calc R U . . .
C23 C 0.1237(3) 0.4158(4) 0.0398(2) 0.0812(15) Uani 1 1 d . . . . .
H23A H 0.0841 0.4155 0.0187 0.097 Uiso 1 1 calc R U . . .
H23B H 0.1270 0.3497 0.0573 0.097 Uiso 1 1 calc R U . . .
C14 C -0.1050(2) 0.6238(5) 0.2210(2) 0.0816(15) Uani 1 1 d . . . . .
C24 C 0.1751(3) 0.4197(4) 0.0142(2) 0.0778(14) Uani 1 1 d . . . . .
C18 C 0.2389(2) 0.7695(5) 0.22411(15) 0.0776(14) Uani 1 1 d . . . . .
H18A H 0.2714 0.7594 0.2488 0.093 Uiso 1 1 calc R U . . .
O9 O 0.3928(3) 0.5828(6) 0.14172(14) 0.149(2) Uani 1 1 d . . . . .
O11 O 0.3322(2) 0.5050(5) 0.1853(3) 0.168(3) Uani 1 1 d . . . . .
O12 O 0.4364(3) 0.5127(5) 0.20790(18) 0.1363(19) Uani 1 1 d . . . . .
C10 C 0.2151(4) 0.6133(5) -0.1231(2) 0.116(2) Uani 1 1 d . . . . .
H10C H 0.2377 0.6189 -0.1466 0.174 Uiso 1 1 calc R U . . .
H10D H 0.2343 0.5604 -0.1015 0.174 Uiso 1 1 calc R U . . .
H10E H 0.1733 0.5918 -0.1358 0.174 Uiso 1 1 calc R U . . .
C25 C 0.2048(4) 0.3710(6) -0.0530(2) 0.119(3) Uani 1 1 d . . . . .
H25A H 0.1874 0.3381 -0.0815 0.179 Uiso 1 1 calc R U . . .
H25B H 0.2185 0.4428 -0.0579 0.179 Uiso 1 1 calc R U . . .
H25C H 0.2392 0.3288 -0.0376 0.179 Uiso 1 1 calc R U . . .
C30 C -0.0156(4) 1.4721(5) 0.1215(3) 0.147(4) Uani 1 1 d . . . . .
H30A H -0.0321 1.5314 0.1355 0.220 Uiso 1 1 calc R U . . .
H30B H 0.0209 1.4951 0.1119 0.220 Uiso 1 1 calc R U . . .
H30C H -0.0459 1.4479 0.0958 0.220 Uiso 1 1 calc R U . . .
Cl2 Cl 0.21434(5) 0.22603(10) 0.14454(4) 0.0655(3) Uani 1 1 d . . . . .
O13 O 0.17486(18) 0.2819(3) 0.16871(13) 0.0911(11) Uani 1 1 d . . . . .
O14 O 0.1787(2) 0.1569(4) 0.11268(14) 0.1106(15) Uani 1 1 d . . . . .
O15 O 0.2567(3) 0.1621(5) 0.1737(2) 0.165(3) Uani 1 1 d . . . . .
O16 O 0.2450(3) 0.3005(4) 0.1226(3) 0.172(3) Uani 1 1 d . . . . .
C15 C -0.1311(5) 0.4804(8) 0.2631(4) 0.175(4) Uani 1 1 d . . . . .
H15B H -0.1416 0.4658 0.2915 0.263 Uiso 1 1 calc R U . . .
H15C H -0.1646 0.4585 0.2391 0.263 Uiso 1 1 calc R U . . .
H15D H -0.0945 0.4408 0.2611 0.263 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 N8 1.976(3) . ?
Cu1 N1 2.006(3) . ?
Cu1 N12 2.095(3) . ?
Cu1 N9 2.104(3) . ?
Cu1 N5 2.280(3) . ?
Cu1 N2 2.346(3) . ?
Cl1 O11 1.370(5) . ?
Cl1 O9 1.372(4) . ?
Cl1 O12 1.404(5) . ?
Cl1 O10 1.425(4) . ?
N1 C1 1.350(5) . ?
N1 C5 1.357(4) . ?
N8 C16 1.345(5) . ?
N8 C20 1.352(5) . ?
N13 N12 1.300(4) . ?
N13 N14 1.344(4) . ?
N12 C26 1.369(5) . ?
N6 N5 1.307(4) . ?
N6 N7 1.338(4) . ?
N7 C12 1.340(5) . ?
N7 C13 1.460(4) . ?
N4 C7 1.340(5) . ?
N4 N3 1.346(4) . ?
N4 C8 1.467(5) . ?
C12 C11 1.375(5) . ?
C11 N5 1.357(5) . ?
C11 C1 1.463(5) . ?
N3 N2 1.307(5) . ?
N9 N10 1.295(5) . ?
N9 C21 1.359(5) . ?
C26 C27 1.365(5) . ?
C26 C16 1.453(6) . ?
C3 C4 1.377(6) . ?
C3 C2 1.385(5) . ?
C6 N2 1.367(5) . ?
C6 C7 1.374(5) . ?
C6 C5 1.457(5) . ?
C2 C1 1.386(5) . ?
C5 C4 1.385(5) . ?
O7 C29 1.180(5) . ?
N14 C27 1.339(5) . ?
N14 C28 1.452(5) . ?
O2 C9 1.313(5) . ?
O2 C10 1.423(7) . ?
C20 C19 1.386(6) . ?
C20 C21 1.453(6) . ?
C21 C22 1.365(6) . ?
C16 C17 1.386(6) . ?
C29 O8 1.324(5) . ?
C29 C28 1.512(7) . ?
O3 C14 1.188(7) . ?
N10 N11 1.356(5) . ?
C13 C14 1.492(8) . ?
N11 C22 1.339(6) . ?
N11 C23 1.453(6) . ?
O8 C30 1.456(8) . ?
O4 C14 1.311(6) . ?
O4 C15 1.490(10) . ?
O1 C9 1.176(6) . ?
C9 C8 1.497(7) . ?
O6 C24 1.313(6) . ?
O6 C25 1.459(7) . ?
C17 C18 1.367(8) . ?
O5 C24 1.195(6) . ?
C19 C18 1.363(8) . ?
C23 C24 1.512(7) . ?
Cl2 O15 1.390(5) . ?
Cl2 O16 1.397(5) . ?
Cl2 O14 1.402(4) . ?
Cl2 O13 1.436(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Cu1 N1 175.94(11) . . ?
N8 Cu1 N12 79.60(12) . . ?
N1 Cu1 N12 98.30(11) . . ?
N8 Cu1 N9 78.61(13) . . ?
N1 Cu1 N9 103.54(12) . . ?
N12 Cu1 N9 158.15(13) . . ?
N8 Cu1 N5 98.79(11) . . ?
N1 Cu1 N5 77.50(11) . . ?
N12 Cu1 N5 85.00(11) . . ?
N9 Cu1 N5 99.79(12) . . ?
N8 Cu1 N2 106.82(11) . . ?
N1 Cu1 N2 77.00(11) . . ?
N12 Cu1 N2 102.99(11) . . ?
N9 Cu1 N2 81.99(12) . . ?
N5 Cu1 N2 154.12(11) . . ?
O11 Cl1 O9 113.6(4) . . ?
O11 Cl1 O12 109.4(4) . . ?
O9 Cl1 O12 105.8(4) . . ?
O11 Cl1 O10 108.5(3) . . ?
O9 Cl1 O10 109.5(3) . . ?
O12 Cl1 O10 110.1(3) . . ?
C1 N1 C5 119.8(3) . . ?
C1 N1 Cu1 119.4(2) . . ?
C5 N1 Cu1 120.7(2) . . ?
C16 N8 C20 121.4(3) . . ?
C16 N8 Cu1 118.8(3) . . ?
C20 N8 Cu1 119.6(3) . . ?
N12 N13 N14 105.8(3) . . ?
N13 N12 C26 110.8(3) . . ?
N13 N12 Cu1 137.3(2) . . ?
C26 N12 Cu1 110.7(2) . . ?
N5 N6 N7 106.3(3) . . ?
N6 N7 C12 112.1(3) . . ?
N6 N7 C13 119.2(3) . . ?
C12 N7 C13 128.6(3) . . ?
C7 N4 N3 112.3(3) . . ?
C7 N4 C8 128.0(3) . . ?
N3 N4 C8 119.3(3) . . ?
N7 C12 C11 104.0(3) . . ?
N5 C11 C12 107.9(3) . . ?
N5 C11 C1 119.4(3) . . ?
C12 C11 C1 132.7(3) . . ?
N2 N3 N4 105.8(3) . . ?
N6 N5 C11 109.7(3) . . ?
N6 N5 Cu1 141.5(2) . . ?
C11 N5 Cu1 107.3(2) . . ?
N10 N9 C21 110.6(3) . . ?
N10 N9 Cu1 136.8(3) . . ?
C21 N9 Cu1 112.2(3) . . ?
C27 C26 N12 106.3(4) . . ?
C27 C26 C16 135.8(4) . . ?
N12 C26 C16 117.9(3) . . ?
C4 C3 C2 120.1(4) . . ?
N2 C6 C7 107.6(3) . . ?
N2 C6 C5 119.9(3) . . ?
C7 C6 C5 132.6(3) . . ?
C3 C2 C1 118.5(4) . . ?
N1 C5 C4 120.8(3) . . ?
N1 C5 C6 115.1(3) . . ?
C4 C5 C6 124.2(3) . . ?
N1 C1 C2 121.5(3) . . ?
N1 C1 C11 114.5(3) . . ?
C2 C1 C11 123.9(3) . . ?
C3 C4 C5 119.3(3) . . ?
N4 C7 C6 104.3(3) . . ?
N3 N2 C6 110.0(3) . . ?
N3 N2 Cu1 141.4(2) . . ?
C6 N2 Cu1 106.2(2) . . ?
C27 N14 N13 111.4(3) . . ?
C27 N14 C28 126.3(3) . . ?
N13 N14 C28 122.1(4) . . ?
C9 O2 C10 117.5(4) . . ?
N8 C20 C19 119.5(4) . . ?
N8 C20 C21 112.3(4) . . ?
C19 C20 C21 128.2(4) . . ?
N9 C21 C22 107.9(4) . . ?
N9 C21 C20 117.0(3) . . ?
C22 C21 C20 135.0(4) . . ?
N8 C16 C17 120.1(4) . . ?
N8 C16 C26 112.4(3) . . ?
C17 C16 C26 127.5(4) . . ?
O7 C29 O8 126.4(5) . . ?
O7 C29 C28 127.3(4) . . ?
O8 C29 C28 106.4(4) . . ?
N14 C27 C26 105.6(3) . . ?
N9 N10 N11 105.3(3) . . ?
N7 C13 C14 109.7(4) . . ?
C22 N11 N10 112.1(4) . . ?
C22 N11 C23 129.1(4) . . ?
N10 N11 C23 118.7(4) . . ?
C29 O8 C30 115.5(5) . . ?
C14 O4 C15 112.6(6) . . ?
O1 C9 O2 125.0(5) . . ?
O1 C9 C8 124.2(4) . . ?
O2 C9 C8 110.7(4) . . ?
N14 C28 C29 114.5(3) . . ?
C24 O6 C25 116.4(5) . . ?
N4 C8 C9 110.5(3) . . ?
C18 C17 C16 118.7(4) . . ?
N11 C22 C21 104.0(4) . . ?
C18 C19 C20 119.2(5) . . ?
N11 C23 C24 110.8(4) . . ?
O3 C14 O4 124.7(6) . . ?
O3 C14 C13 125.1(5) . . ?
O4 C14 C13 110.1(5) . . ?
O5 C24 O6 124.1(5) . . ?
O5 C24 C23 124.4(5) . . ?
O6 C24 C23 111.5(5) . . ?
C19 C18 C17 121.1(4) . . ?
O15 Cl2 O16 110.5(5) . . ?
O15 Cl2 O14 107.2(4) . . ?
O16 Cl2 O14 109.4(4) . . ?
O15 Cl2 O13 110.5(3) . . ?
O16 Cl2 O13 109.8(3) . . ?
O14 Cl2 O13 109.5(2) . . ?

_refine_diff_density_max         0.657
_refine_diff_density_min         -0.708
_refine_diff_density_rms         0.074

