# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_t50146
_database_code_depnum_ccdc_archive 'CCDC 2351450'
loop_
_audit_author_name
_audit_author_address
'Milan Gembicky'
;University of California San Diego
United States of America
;
_audit_update_record             
;
2024-04-26 deposited with the CCDC.	2024-11-19 downloaded from the CCDC.
;
_audit_creation_date             2022-06-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H72 Ge2 N4 S2 Si8'
_chemical_formula_sum            'C24 H72 Ge2 N4 S2 Si8'
_chemical_formula_weight         850.87
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.0563(16)
_cell_length_b                   41.160(7)
_cell_length_c                   12.510(2)
_cell_angle_alpha                90
_cell_angle_beta                 106.559(2)
_cell_angle_gamma                90
_cell_volume                     4469.8(14)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9832
_cell_measurement_temperature    100.00
_cell_measurement_theta_max      26.38
_cell_measurement_theta_min      2.26
_shelx_estimated_absorpt_T_max   0.967
_shelx_estimated_absorpt_T_min   0.731
_exptl_absorpt_coefficient_mu    1.674
_exptl_absorpt_correction_T_max  0.5624
_exptl_absorpt_correction_T_min  0.4631
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1298 before and 0.0456 after correction.
The Ratio of minimum to maximum transmission is 0.8234.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.264
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plank
_exptl_crystal_F_000             1808
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_unetI/netI     0.0269
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       50
_diffrn_reflns_limit_k_min       -50
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            42528
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.014
_diffrn_reflns_theta_min         1.769
_diffrn_ambient_temperature      100.00
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           50.0
_diffrn_source_power             2.5
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7657
_reflns_number_total             8806
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         0.728
_refine_diff_density_min         -0.295
_refine_diff_density_rms         0.060
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     385
_refine_ls_number_reflns         8806
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0321
_refine_ls_R_factor_gt           0.0257
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0279P)²+3.1437P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0622
_refine_ls_wR_factor_ref         0.0650
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.5 times of:
  All C(H,H,H) groups
2.a Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C5(H5A,
 H5B,H5C), C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C),
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,H13B,
 H13C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C17(H17A,
 H17B,H17C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C),
 C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,H24B,
 H24C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.83135(2) 0.62452(2) 0.56692(2) 0.01214(5) Uani 1 1 d . . . . .
Ge2 Ge 0.60576(2) 0.62555(2) 0.33372(2) 0.01234(6) Uani 1 1 d . . . . .
S1 S 0.57283(5) 0.62309(2) 0.50397(4) 0.01508(10) Uani 1 1 d . . . . .
S2 S 0.86231(6) 0.62476(2) 0.39589(4) 0.01758(10) Uani 1 1 d . . . . .
Si11 Si 0.86381(7) 0.66203(2) 0.78554(5) 0.02009(12) Uani 1 1 d . . . . .
Si12 Si 1.00674(7) 0.69353(2) 0.61938(5) 0.02201(13) Uani 1 1 d . . . . .
Si21 Si 1.10168(6) 0.57702(2) 0.65303(4) 0.01478(11) Uani 1 1 d . . . . .
Si22 Si 0.78609(6) 0.55643(2) 0.66851(4) 0.01542(11) Uani 1 1 d . . . . .
Si31 Si 0.55841(7) 0.66379(2) 0.11872(4) 0.01956(12) Uani 1 1 d . . . . .
Si32 Si 0.47254(7) 0.69919(2) 0.30456(5) 0.02165(13) Uani 1 1 d . . . . .
Si41 Si 0.32001(6) 0.58345(2) 0.24559(4) 0.01539(11) Uani 1 1 d . . . . .
Si42 Si 0.60881(6) 0.55839(2) 0.19722(4) 0.01629(11) Uani 1 1 d . . . . .
N1 N 0.90514(19) 0.66053(4) 0.65467(13) 0.0167(3) Uani 1 1 d . . . . .
N2 N 0.90860(18) 0.58684(4) 0.64249(13) 0.0141(3) Uani 1 1 d . . . . .
N3 N 0.54041(19) 0.66363(4) 0.25564(13) 0.0166(3) Uani 1 1 d . . . . .
N4 N 0.51624(18) 0.58952(3) 0.25099(12) 0.0137(3) Uani 1 1 d . . . . .
C1 C 0.6513(3) 0.66298(6) 0.76486(18) 0.0309(5) Uani 1 1 d . . . . .
H1A H 0.607609 0.682452 0.722456 0.046 Uiso 1 1 calc R U . . .
H1B H 0.630674 0.663417 0.837606 0.046 Uiso 1 1 calc R U . . .
H1C H 0.604118 0.643582 0.723655 0.046 Uiso 1 1 calc R U . . .
C2 C 0.9551(3) 0.62775(5) 0.87845(17) 0.0251(5) Uani 1 1 d . . . . .
H2A H 0.912061 0.607120 0.844334 0.038 Uiso 1 1 calc R U . . .
H2B H 0.934745 0.630143 0.950891 0.038 Uiso 1 1 calc R U . . .
H2C H 1.066575 0.627972 0.888953 0.038 Uiso 1 1 calc R U . . .
C3 C 0.9406(3) 0.69891(6) 0.8712(2) 0.0395(6) Uani 1 1 d . . . . .
H3A H 1.050717 0.701233 0.878378 0.059 Uiso 1 1 calc R U . . .
H3B H 0.925857 0.696556 0.945467 0.059 Uiso 1 1 calc R U . . .
H3C H 0.885474 0.718223 0.834677 0.059 Uiso 1 1 calc R U . . .
C4 C 1.2052(3) 0.69529(6) 0.7203(2) 0.0383(6) Uani 1 1 d . . . . .
H4A H 1.207299 0.711646 0.777660 0.057 Uiso 1 1 calc R U . . .
H4B H 1.279950 0.701135 0.680278 0.057 Uiso 1 1 calc R U . . .
H4C H 1.231803 0.673998 0.755648 0.057 Uiso 1 1 calc R U . . .
C5 C 0.9009(3) 0.73270(5) 0.6210(2) 0.0316(5) Uani 1 1 d . . . . .
H5A H 0.789679 0.728749 0.594938 0.047 Uiso 1 1 calc R U . . .
H5B H 0.929745 0.748460 0.571758 0.047 Uiso 1 1 calc R U . . .
H5C H 0.928138 0.741311 0.697164 0.047 Uiso 1 1 calc R U . . .
C6 C 1.0358(3) 0.69275(5) 0.4778(2) 0.0308(5) Uani 1 1 d . . . . .
H6A H 1.096294 0.673532 0.470796 0.046 Uiso 1 1 calc R U . . .
H6B H 1.091005 0.712388 0.466976 0.046 Uiso 1 1 calc R U . . .
H6C H 0.935534 0.691906 0.421305 0.046 Uiso 1 1 calc R U . . .
C7 C 1.1145(2) 0.53828(5) 0.57810(16) 0.0196(4) Uani 1 1 d . . . . .
H7A H 1.075731 0.520302 0.613876 0.029 Uiso 1 1 calc R U . . .
H7B H 1.222117 0.534122 0.580998 0.029 Uiso 1 1 calc R U . . .
H7C H 1.052341 0.540099 0.500153 0.029 Uiso 1 1 calc R U . . .
C8 C 1.1964(2) 0.60933(5) 0.59119(18) 0.0237(4) Uani 1 1 d . . . . .
H8A H 1.150417 0.609817 0.510171 0.036 Uiso 1 1 calc R U . . .
H8B H 1.306787 0.604704 0.608071 0.036 Uiso 1 1 calc R U . . .
H8C H 1.181659 0.630456 0.622839 0.036 Uiso 1 1 calc R U . . .
C9 C 1.2238(2) 0.57266(5) 0.80014(16) 0.0241(5) Uani 1 1 d . . . . .
H9A H 1.232560 0.593742 0.837822 0.036 Uiso 1 1 calc R U . . .
H9B H 1.326492 0.565015 0.800785 0.036 Uiso 1 1 calc R U . . .
H9C H 1.176322 0.556921 0.839062 0.036 Uiso 1 1 calc R U . . .
C10 C 0.6317(2) 0.57169(5) 0.72844(18) 0.0232(4) Uani 1 1 d . . . . .
H10A H 0.678991 0.583408 0.797986 0.035 Uiso 1 1 calc R U . . .
H10B H 0.572157 0.553277 0.743679 0.035 Uiso 1 1 calc R U . . .
H10C H 0.563241 0.586379 0.675019 0.035 Uiso 1 1 calc R U . . .
C11 C 0.6941(2) 0.53376(5) 0.53762(17) 0.0223(4) Uani 1 1 d . . . . .
H11A H 0.647021 0.549184 0.477969 0.033 Uiso 1 1 calc R U . . .
H11B H 0.614505 0.519261 0.549763 0.033 Uiso 1 1 calc R U . . .
H11C H 0.772207 0.520894 0.516263 0.033 Uiso 1 1 calc R U . . .
C12 C 0.8974(2) 0.52746(5) 0.77736(17) 0.0232(4) Uani 1 1 d . . . . .
H12A H 0.983891 0.518567 0.754292 0.035 Uiso 1 1 calc R U . . .
H12B H 0.829734 0.509711 0.786309 0.035 Uiso 1 1 calc R U . . .
H12C H 0.936647 0.538952 0.848426 0.035 Uiso 1 1 calc R U . . .
C13 C 0.2993(2) 0.55617(5) 0.35961(17) 0.0215(4) Uani 1 1 d . . . . .
H13A H 0.343482 0.534849 0.352164 0.032 Uiso 1 1 calc R U . . .
H13B H 0.189874 0.553690 0.354543 0.032 Uiso 1 1 calc R U . . .
H13C H 0.353608 0.565652 0.431996 0.032 Uiso 1 1 calc R U . . .
C14 C 0.2238(2) 0.62256(5) 0.26137(18) 0.0215(4) Uani 1 1 d . . . . .
H14A H 0.278373 0.632686 0.332580 0.032 Uiso 1 1 calc R U . . .
H14B H 0.116751 0.618329 0.259794 0.032 Uiso 1 1 calc R U . . .
H14C H 0.225929 0.637192 0.200020 0.032 Uiso 1 1 calc R U . . .
C15 C 0.2043(2) 0.56612(5) 0.10876(17) 0.0224(4) Uani 1 1 d . . . . .
H15A H 0.198687 0.581996 0.049352 0.034 Uiso 1 1 calc R U . . .
H15B H 0.100029 0.561099 0.112369 0.034 Uiso 1 1 calc R U . . .
H15C H 0.253622 0.546206 0.093021 0.034 Uiso 1 1 calc R U . . .
C16 C 0.5691(3) 0.56160(5) 0.04219(17) 0.0271(5) Uani 1 1 d . . . . .
H16A H 0.457616 0.561031 0.006938 0.041 Uiso 1 1 calc R U . . .
H16B H 0.617802 0.543354 0.014943 0.041 Uiso 1 1 calc R U . . .
H16C H 0.611073 0.582089 0.023593 0.041 Uiso 1 1 calc R U . . .
C17 C 0.5405(3) 0.51711(5) 0.22585(17) 0.0239(5) Uani 1 1 d . . . . .
H17A H 0.566455 0.513637 0.306584 0.036 Uiso 1 1 calc R U . . .
H17B H 0.590862 0.500453 0.192471 0.036 Uiso 1 1 calc R U . . .
H17C H 0.428649 0.515677 0.193443 0.036 Uiso 1 1 calc R U . . .
C18 C 0.8226(2) 0.55621(5) 0.25601(18) 0.0236(4) Uani 1 1 d . . . . .
H18A H 0.869101 0.576128 0.237226 0.035 Uiso 1 1 calc R U . . .
H18B H 0.861864 0.537431 0.224397 0.035 Uiso 1 1 calc R U . . .
H18C H 0.849189 0.553943 0.337261 0.035 Uiso 1 1 calc R U . . .
C19 C 0.7439(3) 0.64445(6) 0.11665(17) 0.0291(5) Uani 1 1 d . . . . .
H19A H 0.830131 0.657246 0.162420 0.044 Uiso 1 1 calc R U . . .
H19B H 0.750161 0.643588 0.039778 0.044 Uiso 1 1 calc R U . . .
H19C H 0.748789 0.622356 0.146656 0.044 Uiso 1 1 calc R U . . .
C20 C 0.3927(3) 0.64329(5) 0.01867(17) 0.0249(5) Uani 1 1 d . . . . .
H20A H 0.385186 0.620861 0.042852 0.037 Uiso 1 1 calc R U . . .
H20B H 0.408181 0.643264 -0.055734 0.037 Uiso 1 1 calc R U . . .
H20C H 0.297440 0.654956 0.016179 0.037 Uiso 1 1 calc R U . . .
C21 C 0.5659(3) 0.70535(5) 0.05970(19) 0.0364(6) Uani 1 1 d . . . . .
H21A H 0.476456 0.717955 0.065036 0.055 Uiso 1 1 calc R U . . .
H21B H 0.564493 0.703533 -0.018689 0.055 Uiso 1 1 calc R U . . .
H21C H 0.660641 0.716322 0.101861 0.055 Uiso 1 1 calc R U . . .
C22 C 0.2771(3) 0.70962(6) 0.2109(2) 0.0413(6) Uani 1 1 d . . . . .
H22A H 0.277111 0.707442 0.132907 0.062 Uiso 1 1 calc R U . . .
H22B H 0.251419 0.732040 0.225058 0.062 Uiso 1 1 calc R U . . .
H22C H 0.200410 0.694833 0.225761 0.062 Uiso 1 1 calc R U . . .
C23 C 0.6062(3) 0.73425(5) 0.30894(19) 0.0299(5) Uani 1 1 d . . . . .
H23A H 0.712873 0.726484 0.331256 0.045 Uiso 1 1 calc R U . . .
H23B H 0.592376 0.750364 0.362968 0.045 Uiso 1 1 calc R U . . .
H23C H 0.583076 0.744234 0.234890 0.045 Uiso 1 1 calc R U . . .
C24 C 0.4518(3) 0.69749(5) 0.4485(2) 0.0324(5) Uani 1 1 d . . . . .
H24A H 0.383727 0.679430 0.453848 0.049 Uiso 1 1 calc R U . . .
H24B H 0.407450 0.717939 0.465112 0.049 Uiso 1 1 calc R U . . .
H24C H 0.553162 0.694212 0.502077 0.049 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 S1 2.2482(7) . ?
Ge1 S2 2.2358(6) . ?
Ge1 N1 1.8519(15) . ?
Ge1 N2 1.8470(15) . ?
Ge2 S1 2.2355(6) . ?
Ge2 S2 2.2303(7) . ?
Ge2 N3 1.8522(15) . ?
Ge2 N4 1.8573(15) . ?
Si11 N1 1.7815(17) . ?
Si11 C1 1.868(2) . ?
Si11 C2 1.865(2) . ?
Si11 C3 1.874(2) . ?
Si12 N1 1.7657(17) . ?
Si12 C4 1.881(2) . ?
Si12 C5 1.879(2) . ?
Si12 C6 1.863(2) . ?
Si21 N2 1.7627(17) . ?
Si21 C7 1.8701(19) . ?
Si21 C8 1.866(2) . ?
Si21 C9 1.866(2) . ?
Si22 N2 1.7636(16) . ?
Si22 C10 1.873(2) . ?
Si22 C11 1.862(2) . ?
Si22 C12 1.873(2) . ?
Si31 N3 1.7662(17) . ?
Si31 C19 1.866(2) . ?
Si31 C20 1.860(2) . ?
Si31 C21 1.872(2) . ?
Si32 N3 1.7631(16) . ?
Si32 C22 1.873(2) . ?
Si32 C23 1.874(2) . ?
Si32 C24 1.864(2) . ?
Si41 N4 1.7768(17) . ?
Si41 C13 1.8662(19) . ?
Si41 C14 1.867(2) . ?
Si41 C15 1.875(2) . ?
Si42 N4 1.7659(16) . ?
Si42 C16 1.874(2) . ?
Si42 C17 1.877(2) . ?
Si42 C18 1.867(2) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S2 Ge1 S1 93.84(2) . . ?
N1 Ge1 S1 113.11(5) . . ?
N1 Ge1 S2 116.18(5) . . ?
N2 Ge1 S1 111.22(5) . . ?
N2 Ge1 S2 111.16(5) . . ?
N2 Ge1 N1 110.40(7) . . ?
S2 Ge2 S1 94.34(2) . . ?
N3 Ge2 S1 115.56(5) . . ?
N3 Ge2 S2 109.92(5) . . ?
N3 Ge2 N4 111.02(7) . . ?
N4 Ge2 S1 109.82(5) . . ?
N4 Ge2 S2 115.38(5) . . ?
Ge2 S1 Ge1 85.651(18) . . ?
Ge2 S2 Ge1 86.072(19) . . ?
N1 Si11 C1 110.58(9) . . ?
N1 Si11 C2 112.00(8) . . ?
N1 Si11 C3 114.38(10) . . ?
C1 Si11 C3 105.19(11) . . ?
C2 Si11 C1 111.02(11) . . ?
C2 Si11 C3 103.29(11) . . ?
N1 Si12 C4 109.16(10) . . ?
N1 Si12 C5 110.71(10) . . ?
N1 Si12 C6 116.70(9) . . ?
C5 Si12 C4 110.64(11) . . ?
C6 Si12 C4 105.77(12) . . ?
C6 Si12 C5 103.64(11) . . ?
N2 Si21 C7 111.10(9) . . ?
N2 Si21 C8 111.65(8) . . ?
N2 Si21 C9 113.09(8) . . ?
C8 Si21 C7 107.37(9) . . ?
C8 Si21 C9 105.33(10) . . ?
C9 Si21 C7 107.96(9) . . ?
N2 Si22 C10 114.60(8) . . ?
N2 Si22 C11 109.93(8) . . ?
N2 Si22 C12 110.46(9) . . ?
C10 Si22 C12 103.34(9) . . ?
C11 Si22 C10 108.78(10) . . ?
C11 Si22 C12 109.48(9) . . ?
N3 Si31 C19 110.13(9) . . ?
N3 Si31 C20 111.78(9) . . ?
N3 Si31 C21 114.19(9) . . ?
C19 Si31 C21 104.51(11) . . ?
C20 Si31 C19 110.73(10) . . ?
C20 Si31 C21 105.19(11) . . ?
N3 Si32 C22 109.51(10) . . ?
N3 Si32 C23 111.30(9) . . ?
N3 Si32 C24 116.44(9) . . ?
C22 Si32 C23 109.21(11) . . ?
C24 Si32 C22 105.97(13) . . ?
C24 Si32 C23 104.04(10) . . ?
N4 Si41 C13 111.90(9) . . ?
N4 Si41 C14 111.48(8) . . ?
N4 Si41 C15 112.40(8) . . ?
C13 Si41 C14 106.64(9) . . ?
C13 Si41 C15 108.49(9) . . ?
C14 Si41 C15 105.56(10) . . ?
N4 Si42 C16 111.79(9) . . ?
N4 Si42 C17 111.48(9) . . ?
N4 Si42 C18 115.87(8) . . ?
C16 Si42 C17 106.54(10) . . ?
C18 Si42 C16 106.42(10) . . ?
C18 Si42 C17 104.03(10) . . ?
Si11 N1 Ge1 115.95(9) . . ?
Si12 N1 Ge1 126.38(9) . . ?
Si12 N1 Si11 117.65(9) . . ?
Si21 N2 Ge1 116.99(8) . . ?
Si21 N2 Si22 119.09(9) . . ?
Si22 N2 Ge1 121.61(9) . . ?
Si31 N3 Ge2 114.25(8) . . ?
Si32 N3 Ge2 127.58(9) . . ?
Si32 N3 Si31 118.10(9) . . ?
Si41 N4 Ge2 113.99(8) . . ?
Si42 N4 Ge2 127.77(9) . . ?
Si42 N4 Si41 117.49(8) . . ?
Si11 C1 H1A 109.5 . . ?
Si11 C1 H1B 109.5 . . ?
Si11 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si11 C2 H2A 109.5 . . ?
Si11 C2 H2B 109.5 . . ?
Si11 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si11 C3 H3A 109.5 . . ?
Si11 C3 H3B 109.5 . . ?
Si11 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si12 C4 H4A 109.5 . . ?
Si12 C4 H4B 109.5 . . ?
Si12 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si12 C5 H5A 109.5 . . ?
Si12 C5 H5B 109.5 . . ?
Si12 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si12 C6 H6A 109.5 . . ?
Si12 C6 H6B 109.5 . . ?
Si12 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si21 C7 H7A 109.5 . . ?
Si21 C7 H7B 109.5 . . ?
Si21 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si21 C8 H8A 109.5 . . ?
Si21 C8 H8B 109.5 . . ?
Si21 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si21 C9 H9A 109.5 . . ?
Si21 C9 H9B 109.5 . . ?
Si21 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si22 C10 H10A 109.5 . . ?
Si22 C10 H10B 109.5 . . ?
Si22 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si22 C11 H11A 109.5 . . ?
Si22 C11 H11B 109.5 . . ?
Si22 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si22 C12 H12A 109.5 . . ?
Si22 C12 H12B 109.5 . . ?
Si22 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si41 C13 H13A 109.5 . . ?
Si41 C13 H13B 109.5 . . ?
Si41 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si41 C14 H14A 109.5 . . ?
Si41 C14 H14B 109.5 . . ?
Si41 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si41 C15 H15A 109.5 . . ?
Si41 C15 H15B 109.5 . . ?
Si41 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si42 C16 H16A 109.5 . . ?
Si42 C16 H16B 109.5 . . ?
Si42 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si42 C17 H17A 109.5 . . ?
Si42 C17 H17B 109.5 . . ?
Si42 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si42 C18 H18A 109.5 . . ?
Si42 C18 H18B 109.5 . . ?
Si42 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si31 C19 H19A 109.5 . . ?
Si31 C19 H19B 109.5 . . ?
Si31 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si31 C20 H20A 109.5 . . ?
Si31 C20 H20B 109.5 . . ?
Si31 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si31 C21 H21A 109.5 . . ?
Si31 C21 H21B 109.5 . . ?
Si31 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si32 C22 H22A 109.5 . . ?
Si32 C22 H22B 109.5 . . ?
Si32 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si32 C23 H23A 109.5 . . ?
Si32 C23 H23B 109.5 . . ?
Si32 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si32 C24 H24A 109.5 . . ?
Si32 C24 H24B 109.5 . . ?
Si32 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
S1 Ge1 N1 Si11 67.27(10) . . . . ?
S1 Ge1 N1 Si12 -110.94(10) . . . . ?
S1 Ge1 N2 Si21 157.56(7) . . . . ?
S1 Ge1 N2 Si22 -5.02(11) . . . . ?
S1 Ge2 N3 Si31 -176.67(6) . . . . ?
S1 Ge2 N3 Si32 6.36(13) . . . . ?
S1 Ge2 N4 Si41 53.47(9) . . . . ?
S1 Ge2 N4 Si42 -116.26(9) . . . . ?
S2 Ge1 N1 Si11 174.19(6) . . . . ?
S2 Ge1 N1 Si12 -4.03(13) . . . . ?
S2 Ge1 N2 Si21 54.42(9) . . . . ?
S2 Ge1 N2 Si22 -108.16(9) . . . . ?
S2 Ge2 N3 Si31 78.11(9) . . . . ?
S2 Ge2 N3 Si32 -98.87(11) . . . . ?
S2 Ge2 N4 Si41 158.54(6) . . . . ?
S2 Ge2 N4 Si42 -11.18(12) . . . . ?
N1 Ge1 N2 Si21 -76.03(10) . . . . ?
N1 Ge1 N2 Si22 121.39(10) . . . . ?
N2 Ge1 N1 Si11 -58.08(11) . . . . ?
N2 Ge1 N1 Si12 123.71(11) . . . . ?
N3 Ge2 N4 Si41 -75.57(10) . . . . ?
N3 Ge2 N4 Si42 114.71(11) . . . . ?
N4 Ge2 N3 Si31 -50.76(11) . . . . ?
N4 Ge2 N3 Si32 132.26(11) . . . . ?
C1 Si11 N1 Ge1 -61.43(12) . . . . ?
C1 Si11 N1 Si12 116.95(12) . . . . ?
C2 Si11 N1 Ge1 62.97(13) . . . . ?
C2 Si11 N1 Si12 -118.66(11) . . . . ?
C3 Si11 N1 Ge1 -179.95(11) . . . . ?
C3 Si11 N1 Si12 -1.57(15) . . . . ?
C4 Si12 N1 Ge1 -117.28(13) . . . . ?
C4 Si12 N1 Si11 64.53(13) . . . . ?
C5 Si12 N1 Ge1 120.69(12) . . . . ?
C5 Si12 N1 Si11 -57.49(13) . . . . ?
C6 Si12 N1 Ge1 2.50(16) . . . . ?
C6 Si12 N1 Si11 -175.68(11) . . . . ?
C7 Si21 N2 Ge1 -116.02(10) . . . . ?
C7 Si21 N2 Si22 47.02(12) . . . . ?
C8 Si21 N2 Ge1 3.81(13) . . . . ?
C8 Si21 N2 Si22 166.85(10) . . . . ?
C9 Si21 N2 Ge1 122.40(10) . . . . ?
C9 Si21 N2 Si22 -74.56(12) . . . . ?
C10 Si22 N2 Ge1 -48.61(13) . . . . ?
C10 Si22 N2 Si21 149.17(10) . . . . ?
C11 Si22 N2 Ge1 74.25(12) . . . . ?
C11 Si22 N2 Si21 -87.97(12) . . . . ?
C12 Si22 N2 Ge1 -164.82(10) . . . . ?
C12 Si22 N2 Si21 32.95(13) . . . . ?
C13 Si41 N4 Ge2 -91.75(10) . . . . ?
C13 Si41 N4 Si42 79.11(11) . . . . ?
C14 Si41 N4 Ge2 27.58(12) . . . . ?
C14 Si41 N4 Si42 -161.56(10) . . . . ?
C15 Si41 N4 Ge2 145.88(9) . . . . ?
C15 Si41 N4 Si42 -43.26(12) . . . . ?
C16 Si42 N4 Ge2 -107.25(12) . . . . ?
C16 Si42 N4 Si41 83.33(12) . . . . ?
C17 Si42 N4 Ge2 133.61(11) . . . . ?
C17 Si42 N4 Si41 -35.81(13) . . . . ?
C18 Si42 N4 Ge2 14.90(14) . . . . ?
C18 Si42 N4 Si41 -154.52(10) . . . . ?
C19 Si31 N3 Ge2 -40.74(12) . . . . ?
C19 Si31 N3 Si32 136.55(11) . . . . ?
C20 Si31 N3 Ge2 82.80(11) . . . . ?
C20 Si31 N3 Si32 -99.91(12) . . . . ?
C21 Si31 N3 Ge2 -157.94(11) . . . . ?
C21 Si31 N3 Si32 19.35(15) . . . . ?
C22 Si32 N3 Ge2 -124.50(13) . . . . ?
C22 Si32 N3 Si31 58.63(14) . . . . ?
C23 Si32 N3 Ge2 114.65(13) . . . . ?
C23 Si32 N3 Si31 -62.22(13) . . . . ?
C24 Si32 N3 Ge2 -4.35(16) . . . . ?
C24 Si32 N3 Si31 178.78(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
