# Supplementary Information (SI) for Materials Advances.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_audit_block_doi                 10.5517/ccdc.csd.cc2kp13f
_database_code_depnum_ccdc_archive 'CCDC 2373704'
loop_
_audit_author_name
_audit_author_address
'Bing Liu'
;Shaanxi University of Sciences and Technology
China
;
_audit_update_record             
;
2024-07-26 deposited with the CCDC.	2024-12-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H19 Eu2 N7 O14'
_chemical_formula_weight         933.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.1327(3)
_cell_length_b                   13.4199(14)
_cell_length_c                   16.4494(5)
_cell_angle_alpha                76.483(5)
_cell_angle_beta                 88.538(3)
_cell_angle_gamma                84.360(5)
_cell_volume                     1737.1(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    10450
_cell_measurement_theta_min      2.7450
_cell_measurement_theta_max      76.8630

_exptl_crystal_description       platelet
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.784
_exptl_crystal_F_000             900
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.05
_exptl_absorpt_coefficient_mu    26.209
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.41364
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.63a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            26143
_diffrn_reflns_av_unetI/netI     0.0592
_diffrn_reflns_av_R_equivalents  0.0870
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.763
_diffrn_reflns_theta_max         89.461
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.901
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.901
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.901
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             7172
_reflns_number_gt                5790
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.42.63a (Rigaku OD, 2022)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.63a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.63a (Rigaku OD, 2022)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1592P)²+29.1821P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7172
_refine_ls_number_parameters     424
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.1203
_refine_ls_R_factor_gt           0.1033
_refine_ls_wR_factor_ref         0.2883
_refine_ls_wR_factor_gt          0.2742
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.021
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.48998(9) 0.68416(7) 0.25002(4) 0.0388(3) Uani 1 1 d . . . . .
Eu2 Eu 0.97845(9) 0.69114(7) 0.17861(4) 0.0415(3) Uani 1 1 d . . . . .
O1 O 0.2156(11) 0.7518(10) 0.2294(6) 0.055(3) Uani 1 1 d . . . . .
O11 O 0.8958(14) 0.6893(10) 0.3169(6) 0.057(3) Uani 1 1 d . . . . .
O12 O 0.6543(13) 0.6379(12) 0.3702(6) 0.065(4) Uani 1 1 d . . . . .
O13 O 0.6505(13) 0.4533(10) 0.6711(7) 0.063(3) Uani 1 1 d . . . . .
O14 O 0.8640(14) 0.4562(9) 0.7517(6) 0.053(3) Uani 1 1 d . . . . .
C11 C 0.8774(15) 0.6322(13) 0.4627(7) 0.042(3) Uani 1 1 d . . . . .
C12 C 0.7969(14) 0.5730(11) 0.5312(8) 0.037(3) Uani 1 1 d . . . . .
H12 H 0.6950 0.5504 0.5237 0.044 Uiso 1 1 calc R U . . .
C13 C 0.8670(16) 0.5485(12) 0.6085(8) 0.041(3) Uani 1 1 d . . . . .
C14 C 1.0151(16) 0.5854(14) 0.6218(9) 0.049(4) Uani 1 1 d . . . . .
H14 H 1.0614 0.5701 0.6749 0.059 Uiso 1 1 calc R U . . .
C15 C 1.0926(16) 0.6450(15) 0.5550(9) 0.051(4) Uani 1 1 d . . . . .
C16 C 1.0248(18) 0.6717(14) 0.4755(8) 0.051(4) Uani 1 1 d . . . . .
H16 H 1.0762 0.7148 0.4317 0.061 Uiso 1 1 calc R U . . .
C17 C 0.8056(17) 0.6571(12) 0.3756(8) 0.041(3) Uani 1 1 d . . . . .
C18 C 0.7857(14) 0.4833(13) 0.6824(8) 0.046(4) Uani 1 1 d . . . . .
C1 C 1.381(3) 0.700(2) 0.5223(19) 0.102(8) Uani 1 1 d . U . . .
H1 H 1.3957 0.6804 0.4717 0.123 Uiso 1 1 calc R U . . .
C2 C 1.267(3) 0.726(2) 0.6368(18) 0.101(8) Uani 1 1 d . U . . .
H2 H 1.1915 0.7298 0.6798 0.121 Uiso 1 1 calc R U . . .
N1 N 1.2412(16) 0.6895(14) 0.5706(9) 0.061(4) Uani 1 1 d . . . . .
N2 N 1.490(3) 0.740(2) 0.5577(17) 0.108(7) Uani 1 1 d . U . . .
N3 N 1.424(3) 0.757(2) 0.6308(16) 0.114(8) Uani 1 1 d . U . . .
O21 O 0.8794(14) 0.5605(11) 0.1167(8) 0.063(3) Uani 1 1 d . . . . .
O22 O 0.7010(14) 0.5561(8) 0.2210(6) 0.050(3) Uani 1 1 d . . . . .
O23 O 0.8269(11) 0.3234(10) -0.0737(6) 0.052(3) Uani 1 1 d . . . . .
O24 O 0.5679(12) 0.3226(10) -0.1112(6) 0.053(3) Uani 1 1 d . . . . .
C21 C 0.6545(16) 0.4574(12) 0.1242(8) 0.042(3) Uani 1 1 d . . . . .
C22 C 0.7127(15) 0.4237(12) 0.0507(8) 0.041(3) Uani 1 1 d . . . . .
H22 H 0.8135 0.4419 0.0268 0.049 Uiso 1 1 calc R U . . .
C23 C 0.6189(15) 0.3645(12) 0.0159(8) 0.039(3) Uani 1 1 d . . . . .
C24 C 0.4686(15) 0.3343(13) 0.0519(8) 0.044(3) Uani 1 1 d . . . . .
H24 H 0.4027 0.2972 0.0267 0.053 Uiso 1 1 calc R U . . .
C25 C 0.4207(14) 0.3608(13) 0.1257(8) 0.041(3) Uani 1 1 d . . . . .
C26 C 0.5090(17) 0.4237(13) 0.1623(8) 0.044(3) Uani 1 1 d . . . . .
H26 H 0.4710 0.4424 0.2109 0.053 Uiso 1 1 calc R U . . .
C27 C 0.7493(17) 0.5305(12) 0.1562(9) 0.045(3) Uani 1 1 d . . . . .
C28 C 0.6764(16) 0.3367(12) -0.0643(7) 0.042(3) Uani 1 1 d . . . . .
C3 C 0.123(2) 0.324(2) 0.1271(16) 0.095(8) Uani 1 1 d . . . . .
H3 H 0.1021 0.3520 0.0707 0.114 Uiso 1 1 calc R U . . .
C4 C 0.241(3) 0.286(2) 0.2453(12) 0.083(7) Uani 1 1 d . . . . .
H4 H 0.3147 0.2829 0.2882 0.100 Uiso 1 1 calc R U . . .
N4 N 0.2703(14) 0.3248(13) 0.1644(8) 0.057(4) Uani 1 1 d . . . . .
N5 N 0.016(2) 0.280(2) 0.1774(12) 0.096(7) Uani 1 1 d . . . . .
N6 N 0.094(2) 0.2535(18) 0.2560(12) 0.092(7) Uani 1 1 d . . . . .
O31 O 0.6852(11) 0.7829(8) 0.1639(6) 0.045(2) Uani 1 1 d . . . . .
O32 O 0.8306(13) 0.7880(10) 0.0475(7) 0.055(3) Uani 1 1 d . . . . .
C31 C 0.5992(16) 0.9139(13) 0.0402(8) 0.044(3) Uani 1 1 d . . . . .
C32 C 0.4777(18) 0.9605(13) 0.0832(9) 0.050(4) Uani 1 1 d . . . . .
H32 H 0.4626 0.9313 0.1397 0.060 Uiso 1 1 calc R U . . .
C33 C 0.3781(17) 1.0478(12) 0.0466(9) 0.045(3) Uani 1 1 d . . . . .
C34 C 0.7094(17) 0.8224(11) 0.0849(8) 0.041(3) Uani 1 1 d . . . . .
N31 N 0.269(4) 1.086(2) 0.0941(19) 0.131(9) Uani 1 1 d . U . . .
H31A H 0.2620 1.0572 0.1463 0.157 Uiso 1 1 calc R U . . .
H31B H 0.2056 1.1408 0.0730 0.157 Uiso 1 1 calc R U . . .
O1W O 0.470(2) 0.8300(12) 0.3067(10) 0.083(4) Uani 1 1 d . . . . .
H1WA H 0.3701 0.8701 0.3056 0.100 Uiso 1 1 calc R U . . .
H1WB H 0.5628 0.8476 0.3304 0.100 Uiso 1 1 calc R U . . .
O2W O 0.9850(19) 0.8785(13) 0.1717(10) 0.086(5) Uani 1 1 d . . . . .
H2WA H 1.0639 0.9004 0.2018 0.104 Uiso 1 1 calc R U . . .
H2WB H 0.9085 0.9263 0.1391 0.104 Uiso 1 1 calc R U . . .
O3W O 0.833(5) 1.066(3) 0.162(3) 0.227(16) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.327(10) . ?
Eu1 O12 2.341(9) . ?
Eu1 O1W 2.347(14) . ?
Eu1 O24 2.367(9) 2_665 ?
Eu1 O13 2.368(11) 2_666 ?
Eu1 O31 2.388(9) . ?
Eu1 O22 2.427(11) . ?
Eu1 Eu2 4.1175(10) . ?
Eu1 Eu2 4.3378(10) 1_455 ?
Eu2 O14 2.320(11) 2_766 ?
Eu2 O23 2.341(9) 2_765 ?
Eu2 O11 2.350(9) . ?
Eu2 O1 2.406(10) 1_655 ?
Eu2 O21 2.432(13) . ?
Eu2 O2W 2.496(16) . ?
Eu2 O32 2.510(10) . ?
Eu2 O31 2.564(10) . ?
Eu2 C34 2.900(14) . ?
Eu2 O22 3.000(12) . ?
Eu2 C27 3.074(14) . ?
O1 Eu2 2.406(9) 1_455 ?
O11 C17 1.220(17) . ?
O12 C17 1.291(17) . ?
O13 C18 1.240(17) . ?
O13 Eu1 2.368(11) 2_666 ?
O14 C18 1.279(16) . ?
O14 Eu2 2.320(11) 2_766 ?
C11 C16 1.397(19) . ?
C11 C12 1.406(18) . ?
C11 C17 1.512(17) . ?
C12 C13 1.362(17) . ?
C12 H12 0.9300 . ?
C13 C14 1.39(2) . ?
C13 C18 1.502(17) . ?
C14 C15 1.38(2) . ?
C14 H14 0.9300 . ?
C15 C16 1.386(19) . ?
C15 N1 1.454(18) . ?
C16 H16 0.9300 . ?
C1 N2 1.30(3) . ?
C1 N1 1.37(3) . ?
C1 H1 0.9300 . ?
C2 N1 1.32(3) . ?
C2 N3 1.38(3) . ?
C2 H2 0.9300 . ?
N2 N3 1.36(3) . ?
O21 C27 1.277(18) . ?
O22 C27 1.237(19) . ?
O23 C28 1.230(16) . ?
O23 Eu2 2.341(9) 2_765 ?
O24 C28 1.243(17) . ?
O24 Eu1 2.367(9) 2_665 ?
C21 C26 1.390(19) . ?
C21 C22 1.44(2) . ?
C21 C27 1.50(2) . ?
C22 C23 1.38(2) . ?
C22 H22 0.9300 . ?
C23 C24 1.400(17) . ?
C23 C28 1.503(18) . ?
C24 C25 1.379(19) . ?
C24 H24 0.9300 . ?
C25 C26 1.40(2) . ?
C25 N4 1.438(16) . ?
C26 H26 0.9300 . ?
C3 N5 1.27(3) . ?
C3 N4 1.37(2) . ?
C3 H3 0.9300 . ?
C4 N6 1.31(2) . ?
C4 N4 1.33(2) . ?
C4 H4 0.9300 . ?
N5 N6 1.41(3) . ?
O31 C34 1.302(16) . ?
O32 C34 1.255(18) . ?
C31 C32 1.38(2) . ?
C31 C33 1.414(18) 2_675 ?
C31 C34 1.50(2) . ?
C32 C33 1.38(2) . ?
C32 H32 0.9300 . ?
C33 N31 1.31(3) . ?
C33 C31 1.414(18) 2_675 ?
N31 H31A 0.8600 . ?
N31 H31B 0.8600 . ?
O1W H1WA 0.9300 . ?
O1W H1WB 0.9300 . ?
O2W H2WA 0.9300 . ?
O2W H2WB 0.9300 . ?
O3W O3W 0.0000(2) 1 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O12 131.6(4) . . ?
O1 Eu1 O1W 75.5(5) . . ?
O12 Eu1 O1W 74.4(5) . . ?
O1 Eu1 O24 75.5(4) . 2_665 ?
O12 Eu1 O24 151.8(4) . 2_665 ?
O1W Eu1 O24 127.6(5) . 2_665 ?
O1 Eu1 O13 78.6(4) . 2_666 ?
O12 Eu1 O13 80.1(4) . 2_666 ?
O1W Eu1 O13 113.8(6) . 2_666 ?
O24 Eu1 O13 101.9(4) 2_665 2_666 ?
O1 Eu1 O31 115.0(4) . . ?
O12 Eu1 O31 95.9(4) . . ?
O1W Eu1 O31 79.9(5) . . ?
O24 Eu1 O31 74.2(4) 2_665 . ?
O13 Eu1 O31 163.6(4) 2_666 . ?
O1 Eu1 O22 145.4(4) . . ?
O12 Eu1 O22 75.4(4) . . ?
O1W Eu1 O22 138.7(5) . . ?
O24 Eu1 O22 76.6(4) 2_665 . ?
O13 Eu1 O22 87.7(4) 2_666 . ?
O31 Eu1 O22 75.8(4) . . ?
O1 Eu1 Eu2 149.7(3) . . ?
O12 Eu1 Eu2 71.4(3) . . ?
O1W Eu1 Eu2 97.1(4) . . ?
O24 Eu1 Eu2 86.9(2) 2_665 . ?
O13 Eu1 Eu2 130.0(3) 2_666 . ?
O31 Eu1 Eu2 35.1(2) . . ?
O22 Eu1 Eu2 46.1(3) . . ?
O1 Eu1 Eu2 24.0(3) . 1_455 ?
O12 Eu1 Eu2 139.4(3) . 1_455 ?
O1W Eu1 Eu2 99.4(4) . 1_455 ?
O24 Eu1 Eu2 61.5(2) 2_665 1_455 ?
O13 Eu1 Eu2 65.7(3) 2_666 1_455 ?
O31 Eu1 Eu2 123.0(2) . 1_455 ?
O22 Eu1 Eu2 121.9(2) . 1_455 ?
Eu2 Eu1 Eu2 148.23(3) . 1_455 ?
O14 Eu2 O23 81.1(4) 2_766 2_765 ?
O14 Eu2 O11 80.3(4) 2_766 . ?
O23 Eu2 O11 154.1(4) 2_765 . ?
O14 Eu2 O1 74.8(4) 2_766 1_655 ?
O23 Eu2 O1 78.5(3) 2_765 1_655 ?
O11 Eu2 O1 79.3(4) . 1_655 ?
O14 Eu2 O21 78.3(4) 2_766 . ?
O23 Eu2 O21 76.6(4) 2_765 . ?
O11 Eu2 O21 116.7(4) . . ?
O1 Eu2 O21 145.7(4) 1_655 . ?
O14 Eu2 O2W 133.7(5) 2_766 . ?
O23 Eu2 O2W 98.2(5) 2_765 . ?
O11 Eu2 O2W 82.0(5) . . ?
O1 Eu2 O2W 60.0(5) 1_655 . ?
O21 Eu2 O2W 147.1(5) . . ?
O14 Eu2 O32 148.1(4) 2_766 . ?
O23 Eu2 O32 76.9(3) 2_765 . ?
O11 Eu2 O32 126.9(4) . . ?
O1 Eu2 O32 122.0(4) 1_655 . ?
O21 Eu2 O32 74.4(4) . . ?
O2W Eu2 O32 72.7(5) . . ?
O14 Eu2 O31 143.5(3) 2_766 . ?
O23 Eu2 O31 128.7(3) 2_765 . ?
O11 Eu2 O31 75.9(4) . . ?
O1 Eu2 O31 126.0(4) 1_655 . ?
O21 Eu2 O31 88.2(4) . . ?
O2W Eu2 O31 69.5(4) . . ?
O32 Eu2 O31 51.8(3) . . ?
O14 Eu2 C34 160.3(4) 2_766 . ?
O23 Eu2 C34 102.2(4) 2_765 . ?
O11 Eu2 C34 101.4(4) . . ?
O1 Eu2 C34 124.8(4) 1_655 . ?
O21 Eu2 C34 83.6(4) . . ?
O2W Eu2 C34 65.5(5) . . ?
O32 Eu2 C34 25.5(4) . . ?
O31 Eu2 C34 26.7(3) . . ?
O14 Eu2 O22 83.0(4) 2_766 . ?
O23 Eu2 O22 123.1(4) 2_765 . ?
O11 Eu2 O22 72.1(4) . . ?
O1 Eu2 O22 146.3(3) 1_655 . ?
O21 Eu2 O22 46.6(3) . . ?
O2W Eu2 O22 130.5(4) . . ?
O32 Eu2 O22 90.0(3) . . ?
O31 Eu2 O22 63.7(3) . . ?
C34 Eu2 O22 79.0(3) . . ?
O14 Eu2 C27 81.4(4) 2_766 . ?
O23 Eu2 C27 99.9(4) 2_765 . ?
O11 Eu2 C27 95.0(4) . . ?
O1 Eu2 C27 156.1(4) 1_655 . ?
O21 Eu2 C27 23.3(4) . . ?
O2W Eu2 C27 142.7(5) . . ?
O32 Eu2 C27 80.0(4) . . ?
O31 Eu2 C27 73.7(4) . . ?
C34 Eu2 C27 79.0(4) . . ?
O22 Eu2 C27 23.5(4) . . ?
O14 Eu2 Eu1 111.1(3) 2_766 . ?
O23 Eu2 Eu1 146.4(2) 2_765 . ?
O11 Eu2 Eu1 58.5(3) . . ?
O1 Eu2 Eu1 134.3(3) 1_655 . ?
O21 Eu2 Eu1 75.7(3) . . ?
O2W Eu2 Eu1 94.8(4) . . ?
O32 Eu2 Eu1 77.6(2) . . ?
O31 Eu2 Eu1 32.4(2) . . ?
C34 Eu2 Eu1 56.1(3) . . ?
O22 Eu2 Eu1 35.7(2) . . ?
C27 Eu2 Eu1 54.1(3) . . ?
Eu1 O1 Eu2 132.8(6) . 1_455 ?
C17 O11 Eu2 148.2(11) . . ?
C17 O12 Eu1 126.3(9) . . ?
C18 O13 Eu1 131.0(9) . 2_666 ?
C18 O14 Eu2 135.1(11) . 2_766 ?
C16 C11 C12 119.4(11) . . ?
C16 C11 C17 119.0(12) . . ?
C12 C11 C17 121.6(12) . . ?
C13 C12 C11 120.4(11) . . ?
C13 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
C12 C13 C14 120.7(12) . . ?
C12 C13 C18 121.6(12) . . ?
C14 C13 C18 117.8(12) . . ?
C15 C14 C13 118.9(12) . . ?
C15 C14 H14 120.5 . . ?
C13 C14 H14 120.5 . . ?
C14 C15 C16 122.0(13) . . ?
C14 C15 N1 118.5(13) . . ?
C16 C15 N1 119.2(14) . . ?
C15 C16 C11 118.4(13) . . ?
C15 C16 H16 120.8 . . ?
C11 C16 H16 120.8 . . ?
O11 C17 O12 125.8(12) . . ?
O11 C17 C11 118.0(12) . . ?
O12 C17 C11 116.1(12) . . ?
O13 C18 O14 123.6(13) . . ?
O13 C18 C13 117.7(12) . . ?
O14 C18 C13 118.4(12) . . ?
N2 C1 N1 110(3) . . ?
N2 C1 H1 125.0 . . ?
N1 C1 H1 125.0 . . ?
N1 C2 N3 108(2) . . ?
N1 C2 H2 126.1 . . ?
N3 C2 H2 126.1 . . ?
C2 N1 C1 107.2(19) . . ?
C2 N1 C15 125.2(16) . . ?
C1 N1 C15 127.6(17) . . ?
C1 N2 N3 108(2) . . ?
C2 N3 N2 107(2) . . ?
C27 O21 Eu2 107.9(11) . . ?
C27 O22 Eu1 133.4(9) . . ?
C27 O22 Eu2 81.7(9) . . ?
Eu1 O22 Eu2 98.2(3) . . ?
C28 O23 Eu2 140.0(8) . 2_765 ?
C28 O24 Eu1 144.3(9) . 2_665 ?
C26 C21 C22 119.1(13) . . ?
C26 C21 C27 121.6(13) . . ?
C22 C21 C27 119.3(12) . . ?
C23 C22 C21 120.0(12) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C24 121.0(13) . . ?
C22 C23 C28 118.9(12) . . ?
C24 C23 C28 120.0(13) . . ?
C25 C24 C23 118.3(13) . . ?
C25 C24 H24 120.9 . . ?
C23 C24 H24 120.9 . . ?
C24 C25 C26 122.9(12) . . ?
C24 C25 N4 117.8(12) . . ?
C26 C25 N4 119.3(12) . . ?
C21 C26 C25 118.5(13) . . ?
C21 C26 H26 120.7 . . ?
C25 C26 H26 120.7 . . ?
O22 C27 O21 123.3(14) . . ?
O22 C27 C21 118.5(13) . . ?
O21 C27 C21 118.2(14) . . ?
O22 C27 Eu2 74.9(9) . . ?
O21 C27 Eu2 48.8(8) . . ?
C21 C27 Eu2 166.1(10) . . ?
O23 C28 O24 126.8(13) . . ?
O23 C28 C23 116.1(12) . . ?
O24 C28 C23 116.9(11) . . ?
N5 C3 N4 113(2) . . ?
N5 C3 H3 123.5 . . ?
N4 C3 H3 123.5 . . ?
N6 C4 N4 110.9(19) . . ?
N6 C4 H4 124.6 . . ?
N4 C4 H4 124.6 . . ?
C4 N4 C3 103.5(15) . . ?
C4 N4 C25 128.5(14) . . ?
C3 N4 C25 128.0(15) . . ?
C3 N5 N6 105.1(16) . . ?
C4 N6 N5 107.0(16) . . ?
C34 O31 Eu1 138.4(8) . . ?
C34 O31 Eu2 91.2(8) . . ?
Eu1 O31 Eu2 112.4(4) . . ?
C34 O32 Eu2 94.9(8) . . ?
C32 C31 C33 120.6(13) . 2_675 ?
C32 C31 C34 120.5(12) . . ?
C33 C31 C34 118.9(13) 2_675 . ?
C31 C32 C33 123.3(14) . . ?
C31 C32 H32 118.3 . . ?
C33 C32 H32 118.3 . . ?
N31 C33 C32 118.0(18) . . ?
N31 C33 C31 126.0(18) . 2_675 ?
C32 C33 C31 116.0(14) . 2_675 ?
O32 C34 O31 120.1(13) . . ?
O32 C34 C31 120.0(12) . . ?
O31 C34 C31 119.8(13) . . ?
O32 C34 Eu2 59.6(7) . . ?
O31 C34 Eu2 62.1(7) . . ?
C31 C34 Eu2 163.6(10) . . ?
C33 N31 H31A 120.0 . . ?
C33 N31 H31B 120.0 . . ?
H31A N31 H31B 120.0 . . ?
Eu1 O1W H1WA 120.0 . . ?
Eu1 O1W H1WB 120.0 . . ?
H1WA O1W H1WB 120.0 . . ?
Eu2 O2W H2WA 120.0 . . ?
Eu2 O2W H2WB 120.0 . . ?
H2WA O2W H2WB 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C16 C11 C12 C13 -4(2) . . . . ?
C17 C11 C12 C13 177.6(15) . . . . ?
C11 C12 C13 C14 3(2) . . . . ?
C11 C12 C13 C18 -178.5(15) . . . . ?
C12 C13 C14 C15 -2(3) . . . . ?
C18 C13 C14 C15 179.8(16) . . . . ?
C13 C14 C15 C16 2(3) . . . . ?
C13 C14 C15 N1 175.5(16) . . . . ?
C14 C15 C16 C11 -3(3) . . . . ?
N1 C15 C16 C11 -176.8(16) . . . . ?
C12 C11 C16 C15 4(3) . . . . ?
C17 C11 C16 C15 -177.6(16) . . . . ?
Eu2 O11 C17 O12 -35(3) . . . . ?
Eu2 O11 C17 C11 141.8(16) . . . . ?
Eu1 O12 C17 O11 -11(2) . . . . ?
Eu1 O12 C17 C11 171.9(11) . . . . ?
C16 C11 C17 O11 17(2) . . . . ?
C12 C11 C17 O11 -164.8(15) . . . . ?
C16 C11 C17 O12 -165.7(16) . . . . ?
C12 C11 C17 O12 12(2) . . . . ?
Eu1 O13 C18 O14 -15(3) 2_666 . . . ?
Eu1 O13 C18 C13 159.9(11) 2_666 . . . ?
Eu2 O14 C18 O13 76(2) 2_766 . . . ?
Eu2 O14 C18 C13 -99.1(18) 2_766 . . . ?
C12 C13 C18 O13 -1(2) . . . . ?
C14 C13 C18 O13 177.6(16) . . . . ?
C12 C13 C18 O14 174.5(15) . . . . ?
C14 C13 C18 O14 -7(2) . . . . ?
N3 C2 N1 C1 -1(3) . . . . ?
N3 C2 N1 C15 177(2) . . . . ?
N2 C1 N1 C2 0(3) . . . . ?
N2 C1 N1 C15 -178(2) . . . . ?
C14 C15 N1 C2 -37(3) . . . . ?
C16 C15 N1 C2 137(2) . . . . ?
C14 C15 N1 C1 141(2) . . . . ?
C16 C15 N1 C1 -45(3) . . . . ?
N1 C1 N2 N3 1(4) . . . . ?
N1 C2 N3 N2 2(4) . . . . ?
C1 N2 N3 C2 -1(4) . . . . ?
C26 C21 C22 C23 4(2) . . . . ?
C27 C21 C22 C23 -173.8(13) . . . . ?
C21 C22 C23 C24 -1(2) . . . . ?
C21 C22 C23 C28 175.7(13) . . . . ?
C22 C23 C24 C25 -3(2) . . . . ?
C28 C23 C24 C25 179.6(14) . . . . ?
C23 C24 C25 C26 5(2) . . . . ?
C23 C24 C25 N4 -176.9(14) . . . . ?
C22 C21 C26 C25 -2(2) . . . . ?
C27 C21 C26 C25 175.8(13) . . . . ?
C24 C25 C26 C21 -3(2) . . . . ?
N4 C25 C26 C21 179.7(14) . . . . ?
Eu1 O22 C27 O21 100.1(16) . . . . ?
Eu2 O22 C27 O21 6.7(14) . . . . ?
Eu1 O22 C27 C21 -82.4(18) . . . . ?
Eu2 O22 C27 C21 -175.8(13) . . . . ?
Eu1 O22 C27 Eu2 93.4(11) . . . . ?
Eu2 O21 C27 O22 -8.6(18) . . . . ?
Eu2 O21 C27 C21 173.9(10) . . . . ?
C26 C21 C27 O22 4(2) . . . . ?
C22 C21 C27 O22 -177.6(13) . . . . ?
C26 C21 C27 O21 -178.0(14) . . . . ?
C22 C21 C27 O21 0(2) . . . . ?
C26 C21 C27 Eu2 -159(3) . . . . ?
C22 C21 C27 Eu2 20(5) . . . . ?
Eu2 O23 C28 O24 19(3) 2_765 . . . ?
Eu2 O23 C28 C23 -166.0(11) 2_765 . . . ?
Eu1 O24 C28 O23 -25(3) 2_665 . . . ?
Eu1 O24 C28 C23 160.4(13) 2_665 . . . ?
C22 C23 C28 O23 34(2) . . . . ?
C24 C23 C28 O23 -149.2(15) . . . . ?
C22 C23 C28 O24 -151.2(15) . . . . ?
C24 C23 C28 O24 26(2) . . . . ?
N6 C4 N4 C3 6(3) . . . . ?
N6 C4 N4 C25 -175(2) . . . . ?
N5 C3 N4 C4 -6(3) . . . . ?
N5 C3 N4 C25 175(2) . . . . ?
C24 C25 N4 C4 138(2) . . . . ?
C26 C25 N4 C4 -44(3) . . . . ?
C24 C25 N4 C3 -43(3) . . . . ?
C26 C25 N4 C3 134(2) . . . . ?
N4 C3 N5 N6 3(3) . . . . ?
N4 C4 N6 N5 -5(3) . . . . ?
C3 N5 N6 C4 1(3) . . . . ?
C33 C31 C32 C33 -3(3) 2_675 . . . ?
C34 C31 C32 C33 176.6(15) . . . . ?
C31 C32 C33 N31 -179(2) . . . . ?
C31 C32 C33 C31 3(3) . . . 2_675 ?
Eu2 O32 C34 O31 -14.7(14) . . . . ?
Eu2 O32 C34 C31 161.0(11) . . . . ?
Eu1 O31 C34 O32 -112.5(15) . . . . ?
Eu2 O31 C34 O32 14.3(14) . . . . ?
Eu1 O31 C34 C31 71.8(19) . . . . ?
Eu2 O31 C34 C31 -161.3(11) . . . . ?
Eu1 O31 C34 Eu2 -126.8(14) . . . . ?
C32 C31 C34 O32 -172.0(15) . . . . ?
C33 C31 C34 O32 8(2) 2_675 . . . ?
C32 C31 C34 O31 4(2) . . . . ?
C33 C31 C34 O31 -176.6(13) 2_675 . . . ?
C32 C31 C34 Eu2 -88(3) . . . . ?
C33 C31 C34 Eu2 91(4) 2_675 . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2W H2WB O3W 0.93 2.03 2.66(5) 123.8 1

_refine_diff_density_max         3.504
_refine_diff_density_min         -1.356
_refine_diff_density_rms         0.275

