# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_4801
_database_code_depnum_ccdc_archive 'CCDC 2289391'
loop_
_audit_author_name
_audit_author_address
'Ru-Ling Tang'
;YangZhou University
China
;
_audit_update_record             
;
2023-08-18 deposited with the CCDC.	2024-07-02 downloaded from the CCDC.
;
_audit_creation_date             2023-06-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        Ag7B9H2O18
_chemical_formula_moiety         'Ag7 B9 H2 O18'
_chemical_formula_sum            'Ag7 H2 B9 O18'
_chemical_formula_weight         1142.40
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 1 2/c 1'
_space_group_name_Hall           '-I 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, -y+1/2, z'

_cell_length_a                   8.826(4)
_cell_length_b                   8.825(3)
_cell_length_c                   20.483(9)
_cell_angle_alpha                90
_cell_angle_beta                 100.22(2)
_cell_angle_gamma                90
_cell_volume                     1570.1(11)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4286
_cell_measurement_temperature    296
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      3.28
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    8.653
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5720
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0800 before and 0.0398 after correction.
The Ratio of minimum to maximum transmission is 0.7672.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    4.833
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       'rect. Prism'
_exptl_crystal_F_000             2080
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.0
_exptl_crystal_size_min          0.0
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0322
_diffrn_reflns_av_unetI/netI     0.0300
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            7797
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.501
_diffrn_reflns_theta_min         2.519
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1535
_reflns_number_total             1794
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         2.166
_refine_diff_density_min         -1.530
_refine_diff_density_rms         0.186
_refine_ls_extinction_coef       0.00021(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     161
_refine_ls_number_reflns         1794
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0384
_refine_ls_R_factor_gt           0.0280
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0210P)²+19.5866P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0556
_refine_ls_wR_factor_ref         0.0592
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag3 Ag 0.16430(5) 0.37956(5) 0.26364(2) 0.02395(14) Uani 1 1 d . . . . .
Ag2 Ag 0.34101(6) 0.01016(5) 0.09995(2) 0.02939(14) Uani 1 1 d . . . . .
Ag4 Ag 0.16914(5) 0.70634(5) 0.08893(3) 0.03010(15) Uani 1 1 d . . . . .
Ag1 Ag 0.0000 0.0000 0.0000 0.0446(2) Uani 1 2 d S . P . .
O4 O 0.1392(4) 0.3382(4) 0.15473(15) 0.0098(7) Uani 1 1 d . . . . .
O5 O 0.3847(3) 0.2567(4) 0.13476(16) 0.0093(7) Uani 1 1 d . . . . .
O3 O 0.2220(4) 0.4181(4) 0.05375(16) 0.0129(7) Uani 1 1 d . . . . .
O8 O 0.5650(4) 0.6689(4) 0.20206(17) 0.0127(7) Uani 1 1 d . . . . .
O6 O 0.3402(4) 0.5204(4) 0.15864(17) 0.0122(7) Uani 1 1 d . . . . .
O2 O 0.0478(4) 0.2104(4) 0.05139(16) 0.0142(7) Uani 1 1 d . . . . .
O7 O 0.5953(4) 0.4349(4) 0.15192(17) 0.0126(7) Uani 1 1 d . . . . .
O9 O 0.6221(4) 0.8637(4) 0.28453(18) 0.0148(8) Uani 1 1 d . . . . .
O1 O 0.0972(4) 0.3082(4) -0.04989(17) 0.0161(7) Uani 1 1 d . . . . .
B4 B 0.4976(6) 0.5431(6) 0.1710(3) 0.0107(11) Uani 1 1 d . . . . .
B1 B 0.1238(6) 0.3155(6) 0.0172(3) 0.0114(11) Uani 1 1 d . . . . .
B3 B 0.2719(6) 0.3827(6) 0.1255(3) 0.0094(10) Uani 1 1 d . . . . .
B2 B 0.0409(6) 0.2161(6) 0.1241(3) 0.0088(10) Uani 1 1 d . . . . .
B5 B 0.5000 0.7664(8) 0.2500 0.0090(14) Uani 1 2 d S T P . .
H9 H 0.703(7) 0.838(7) 0.288(3) 0.019(17) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag3 Ag3 2.8546(16) 2 ?
Ag3 Ag3 2.8512(11) 7 ?
Ag3 Ag2 2.9669(13) 7 ?
Ag3 O4 2.232(3) . ?
Ag3 O5 2.507(3) 7 ?
Ag3 O7 2.536(3) 2_655 ?
Ag3 O9 2.348(4) 8_465 ?
Ag2 Ag3 2.9669(13) 7 ?
Ag2 Ag4 3.0691(11) 1_545 ?
Ag2 O5 2.300(3) . ?
Ag2 O1 2.174(4) 4_544 ?
Ag4 Ag2 3.0691(11) 1_565 ?
Ag4 Ag1 3.3612(10) 1_565 ?
Ag4 O6 2.499(3) . ?
Ag4 O1 2.507(4) 4_554 ?
Ag4 O1 2.349(4) 5_565 ?
Ag1 Ag4 3.3612(10) 1_545 ?
Ag1 Ag4 3.3612(10) 5_565 ?
Ag1 O2 2.139(3) . ?
Ag1 O2 2.139(3) 5 ?
O4 B3 1.461(6) . ?
O4 B2 1.454(6) . ?
O5 Ag3 2.507(3) 7 ?
O5 B3 1.482(6) . ?
O5 B2 1.454(6) 8 ?
O3 B1 1.380(6) . ?
O3 B3 1.491(6) . ?
O8 B4 1.363(6) . ?
O8 B5 1.495(5) . ?
O6 B4 1.382(6) . ?
O6 B3 1.468(6) . ?
O2 B1 1.403(6) . ?
O2 B2 1.501(6) . ?
O7 Ag3 2.536(3) 2_655 ?
O7 B4 1.388(6) . ?
O7 B2 1.495(6) 8 ?
O9 Ag3 2.348(4) 8_565 ?
O9 B5 1.459(6) . ?
O9 H9 0.75(6) . ?
O1 Ag2 2.174(4) 4_554 ?
O1 Ag4 2.349(4) 5_565 ?
O1 Ag4 2.507(4) 4_544 ?
O1 B1 1.353(6) . ?
B2 O5 1.454(6) 8_455 ?
B2 O7 1.495(6) 8_455 ?
B5 O8 1.495(5) 2_655 ?
B5 O9 1.459(5) 2_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag3 Ag3 Ag3 121.17(2) 7 2 ?
Ag3 Ag3 Ag2 123.04(3) 7 7 ?
Ag3 Ag3 Ag2 89.95(3) 2 7 ?
O4 Ag3 Ag3 68.61(8) . 7 ?
O4 Ag3 Ag3 83.51(8) . 2 ?
O4 Ag3 Ag2 168.33(8) . 7 ?
O4 Ag3 O5 138.60(11) . 7 ?
O4 Ag3 O7 129.48(11) . 2_655 ?
O4 Ag3 O9 110.42(12) . 8_465 ?
O5 Ag3 Ag3 87.35(8) 7 7 ?
O5 Ag3 Ag3 80.99(7) 7 2 ?
O5 Ag3 Ag2 48.82(8) 7 7 ?
O5 Ag3 O7 76.87(11) 7 2_655 ?
O7 Ag3 Ag3 146.27(8) 2_655 2 ?
O7 Ag3 Ag3 83.06(8) 2_655 7 ?
O7 Ag3 Ag2 56.33(8) 2_655 7 ?
O9 Ag3 Ag3 156.44(9) 8_465 7 ?
O9 Ag3 Ag3 81.20(9) 8_465 2 ?
O9 Ag3 Ag2 58.82(9) 8_465 7 ?
O9 Ag3 O5 104.78(12) 8_465 7 ?
O9 Ag3 O7 80.25(12) 8_465 2_655 ?
Ag3 Ag2 Ag4 105.41(2) 7 1_545 ?
O5 Ag2 Ag3 55.09(8) . 7 ?
O5 Ag2 Ag4 154.49(8) . 1_545 ?
O1 Ag2 Ag3 139.51(9) 4_544 7 ?
O1 Ag2 Ag4 53.90(10) 4_544 1_545 ?
O1 Ag2 O5 151.57(12) 4_544 . ?
Ag2 Ag4 Ag1 62.13(3) 1_565 1_565 ?
O6 Ag4 Ag2 106.91(8) . 1_565 ?
O6 Ag4 Ag1 168.83(8) . 1_565 ?
O6 Ag4 O1 88.28(11) . 4_554 ?
O1 Ag4 Ag2 121.64(9) 5_565 1_565 ?
O1 Ag4 Ag2 44.48(8) 4_554 1_565 ?
O1 Ag4 Ag1 82.07(8) 4_554 1_565 ?
O1 Ag4 Ag1 62.36(9) 5_565 1_565 ?
O1 Ag4 O6 128.72(11) 5_565 . ?
O1 Ag4 O1 137.84(14) 5_565 4_554 ?
Ag4 Ag1 Ag4 180.000(16) 1_545 5_565 ?
O2 Ag1 Ag4 111.89(10) . 1_545 ?
O2 Ag1 Ag4 111.89(10) 5 5_565 ?
O2 Ag1 Ag4 68.11(10) 5 1_545 ?
O2 Ag1 Ag4 68.11(10) . 5_565 ?
O2 Ag1 O2 180.0 . 5 ?
B3 O4 Ag3 114.9(3) . . ?
B2 O4 Ag3 119.9(3) . . ?
B2 O4 B3 118.9(4) . . ?
Ag2 O5 Ag3 76.09(10) . 7 ?
B3 O5 Ag3 104.8(3) . 7 ?
B3 O5 Ag2 126.7(3) . . ?
B2 O5 Ag3 120.8(3) 8 7 ?
B2 O5 Ag2 102.8(3) 8 . ?
B2 O5 B3 119.4(4) 8 . ?
B1 O3 B3 116.4(4) . . ?
B4 O8 B5 126.1(4) . . ?
B4 O6 Ag4 119.7(3) . . ?
B4 O6 B3 121.4(4) . . ?
B3 O6 Ag4 97.1(3) . . ?
B1 O2 Ag1 113.4(3) . . ?
B1 O2 B2 125.5(4) . . ?
B2 O2 Ag1 118.5(3) . . ?
B4 O7 Ag3 115.3(3) . 2_655 ?
B4 O7 B2 123.2(4) . 8 ?
B2 O7 Ag3 105.2(3) 8 2_655 ?
Ag3 O9 H9 98(5) 8_565 . ?
B5 O9 Ag3 127.4(3) . 8_565 ?
B5 O9 H9 119(5) . . ?
Ag2 O1 Ag4 81.62(11) 4_554 4_544 ?
Ag2 O1 Ag4 101.76(14) 4_554 5_565 ?
Ag4 O1 Ag4 134.61(15) 5_565 4_544 ?
B1 O1 Ag2 115.3(3) . 4_554 ?
B1 O1 Ag4 109.7(3) . 4_544 ?
B1 O1 Ag4 109.3(3) . 5_565 ?
O8 B4 O6 123.0(4) . . ?
O8 B4 O7 116.8(4) . . ?
O6 B4 O7 120.2(4) . . ?
O3 B1 O2 118.2(4) . . ?
O1 B1 O3 124.2(5) . . ?
O1 B1 O2 117.6(4) . . ?
O4 B3 O5 108.4(4) . . ?
O4 B3 O3 110.0(4) . . ?
O4 B3 O6 109.1(4) . . ?
O5 B3 O3 110.9(4) . . ?
O6 B3 O5 110.6(4) . . ?
O6 B3 O3 107.9(4) . . ?
O4 B2 O2 109.1(4) . . ?
O4 B2 O7 111.7(4) . 8_455 ?
O5 B2 O4 108.7(4) 8_455 . ?
O5 B2 O2 111.2(4) 8_455 . ?
O5 B2 O7 109.8(4) 8_455 8_455 ?
O7 B2 O2 106.4(4) 8_455 . ?
O8 B5 O8 109.7(5) . 2_655 ?
O9 B5 O8 110.9(2) 2_655 . ?
O9 B5 O8 108.71(19) 2_655 2_655 ?
O9 B5 O8 110.9(2) . 2_655 ?
O9 B5 O8 108.71(19) . . ?
O9 B5 O9 107.8(6) . 2_655 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag3 O4 B3 O5 84.5(4) . . . . ?
Ag3 O4 B3 O3 -154.1(3) . . . . ?
Ag3 O4 B3 O6 -36.0(4) . . . . ?
Ag3 O4 B2 O5 60.1(4) . . . 8_455 ?
Ag3 O4 B2 O2 -178.5(2) . . . . ?
Ag3 O4 B2 O7 -61.2(4) . . . 8_455 ?
Ag3 O5 B3 O4 -26.9(4) 7 . . . ?
Ag3 O5 B3 O3 -147.7(3) 7 . . . ?
Ag3 O5 B3 O6 92.6(3) 7 . . . ?
Ag3 O7 B4 O8 42.3(5) 2_655 . . . ?
Ag3 O7 B4 O6 -137.3(4) 2_655 . . . ?
Ag3 O9 B5 O8 -137.9(3) 8_565 . . 2_655 ?
Ag3 O9 B5 O8 101.4(4) 8_565 . . . ?
Ag3 O9 B5 O9 -18.92(14) 8_565 . . 2_655 ?
Ag2 O5 B3 O4 56.6(5) . . . . ?
Ag2 O5 B3 O3 -64.3(5) . . . . ?
Ag2 O5 B3 O6 176.1(2) . . . . ?
Ag2 O1 B1 O3 -18.8(6) 4_554 . . . ?
Ag2 O1 B1 O2 162.0(3) 4_554 . . . ?
Ag4 O6 B4 O8 59.6(6) . . . . ?
Ag4 O6 B4 O7 -120.8(4) . . . . ?
Ag4 O6 B3 O4 -85.3(3) . . . . ?
Ag4 O6 B3 O5 155.6(3) . . . . ?
Ag4 O6 B3 O3 34.1(3) . . . . ?
Ag4 O1 B1 O3 -132.7(4) 5_565 . . . ?
Ag4 O1 B1 O3 71.0(5) 4_544 . . . ?
Ag4 O1 B1 O2 -108.2(4) 4_544 . . . ?
Ag4 O1 B1 O2 48.1(5) 5_565 . . . ?
Ag1 O2 B1 O3 -149.9(3) . . . . ?
Ag1 O2 B1 O1 29.4(5) . . . . ?
Ag1 O2 B2 O4 154.6(3) . . . . ?
Ag1 O2 B2 O5 -85.5(4) . . . 8_455 ?
Ag1 O2 B2 O7 34.0(4) . . . 8_455 ?
B4 O8 B5 O8 44.0(4) . . . 2_655 ?
B4 O8 B5 O9 -76.1(6) . . . 2_655 ?
B4 O8 B5 O9 165.4(4) . . . . ?
B4 O6 B3 O4 143.4(4) . . . . ?
B4 O6 B3 O5 24.3(6) . . . . ?
B4 O6 B3 O3 -97.2(5) . . . . ?
B1 O3 B3 O4 -46.6(5) . . . . ?
B1 O3 B3 O5 73.4(5) . . . . ?
B1 O3 B3 O6 -165.4(4) . . . . ?
B1 O2 B2 O4 -6.0(6) . . . . ?
B1 O2 B2 O5 113.9(5) . . . 8_455 ?
B1 O2 B2 O7 -126.7(4) . . . 8_455 ?
B3 O4 B2 O5 -149.3(4) . . . 8_455 ?
B3 O4 B2 O2 -27.9(5) . . . . ?
B3 O4 B2 O7 89.4(5) . . . 8_455 ?
B3 O3 B1 O2 16.2(6) . . . . ?
B3 O3 B1 O1 -163.0(4) . . . . ?
B3 O6 B4 O8 -179.5(4) . . . . ?
B3 O6 B4 O7 0.2(7) . . . . ?
B2 O4 B3 O5 -67.5(5) . . . . ?
B2 O4 B3 O3 53.9(5) . . . . ?
B2 O4 B3 O6 172.1(4) . . . . ?
B2 O5 B3 O4 -166.0(4) 8 . . . ?
B2 O5 B3 O3 73.1(5) 8 . . . ?
B2 O5 B3 O6 -46.5(5) 8 . . . ?
B2 O2 B1 O3 11.6(7) . . . . ?
B2 O2 B1 O1 -169.1(4) . . . . ?
B2 O7 B4 O8 173.2(4) 8 . . . ?
B2 O7 B4 O6 -6.4(7) 8 . . . ?
B5 O8 B4 O6 26.2(7) . . . . ?
B5 O8 B4 O7 -153.5(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4711
_database_code_depnum_ccdc_archive 'CCDC 2289392'
loop_
_audit_author_name
_audit_author_address
'Ru-Ling Tang'
;YangZhou University
China
;
_audit_update_record             
;
2023-08-18 deposited with the CCDC.	2024-07-02 downloaded from the CCDC.
;
_audit_creation_date             2023-06-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        1
_chemical_formula_moiety         'Ag8 B8 Cl2 O15'
_chemical_formula_sum            'Ag8 B8 Cl2 O15'
_chemical_formula_weight         1260.34
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   13.7794(8)
_cell_length_b                   10.7272(6)
_cell_length_c                   21.5856(12)
_cell_angle_alpha                90
_cell_angle_beta                 95.604(2)
_cell_angle_gamma                90
_cell_volume                     3175.4(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    4717
_cell_measurement_temperature    296
_cell_measurement_theta_max      27.11
_cell_measurement_theta_min      2.41
_shelx_estimated_absorpt_T_max   0.432
_shelx_estimated_absorpt_T_min   0.187
_exptl_absorpt_coefficient_mu    10.071
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6157
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0734 before and 0.0505 after correction.
The Ratio of minimum to maximum transmission is 0.8258.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear grayish gray'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   grayish
_exptl_crystal_colour_primary    gray
_exptl_crystal_density_diffrn    5.273
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4560
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0718
_diffrn_reflns_av_unetI/netI     0.0803
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            15737
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.531
_diffrn_reflns_theta_min         1.896
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2507
_reflns_number_total             3660
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.101
_refine_diff_density_min         -1.573
_refine_diff_density_rms         0.304
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     299
_refine_ls_number_reflns         3660
_refine_ls_number_restraints     216
_refine_ls_R_factor_all          0.0890
_refine_ls_R_factor_gt           0.0442
_refine_ls_restrained_S_all      1.002
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0152P)²+15.1549P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0528
_refine_ls_wR_factor_ref         0.0596
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
B2 \\sim Ag8 \\sim O11 \\sim Cl2 \\sim B8 \\sim B4 \\sim O10 \\sim O5 \\sim O7
\\sim O8 \\sim Ag2 \\sim B9 \\sim B5 \\sim Ag6 \\sim Ag4 \\sim B3 \\sim O9
\\sim O6 \\sim O3 \\sim O4 \\sim O12 \\sim Cl1 \\sim O14 \\sim Ag3 \\sim Ag1
\\sim Ag7 \\sim B6 \\sim B7 \\sim Ag5 \\sim B1 \\sim O2 \\sim O1 \\sim O13
\\sim O15: within 2A with sigma of 0.1 and sigma for terminal atoms of 0.2
within 2A
Uanis(B7) \\sim Ueq, Uanis(B3) \\sim Ueq, Uanis(B9) \\sim Ueq, Uanis(B8) \\sim
Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(B6) \\sim Ueq, Uanis(O14) \\sim Ueq, Uanis(O9) \\sim Ueq: with sigma of
0.001 and sigma for terminal atoms of 0.002
Uanis(O3) \\sim Ueq, Uanis(O2) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag8 Ag 0.11895(4) 0.57187(6) 0.25778(3) 0.01791(16) Uani 1 1 d . . . . .
Ag7 Ag 0.61573(4) 0.56422(6) 0.30602(3) 0.01793(16) Uani 1 1 d . . . . .
Ag5 Ag 0.56866(4) 0.26261(6) 0.51745(3) 0.01980(16) Uani 1 1 d . . . . .
Ag2 Ag 0.09778(5) 0.43238(6) 0.54419(3) 0.02673(18) Uani 1 1 d . . . . .
Ag3 Ag 0.45243(5) 0.48127(6) 0.56044(3) 0.02822(19) Uani 1 1 d . . . . .
Ag6 Ag 0.23739(5) 0.32614(6) 0.26215(3) 0.0343(2) Uani 1 1 d . . . . .
Ag1 Ag 0.24824(5) 0.66167(6) 0.61838(3) 0.02858(18) Uani 1 1 d . . . . .
Ag4 Ag 0.26939(6) 0.30518(6) 0.41110(3) 0.0373(2) Uani 1 1 d . . . . .
Cl1 Cl 0.36839(15) 0.28004(19) 0.52100(10) 0.0246(5) Uani 1 1 d . . . . .
O11 O 0.1688(3) 0.5616(4) 0.3630(2) 0.0091(11) Uani 1 1 d . U . . .
O6 O 0.4592(3) 0.5718(4) 0.3368(2) 0.0090(11) Uani 1 1 d . U . . .
O14 O 0.4648(3) 0.3647(4) 0.3766(2) 0.0105(12) Uani 1 1 d . U . . .
O5 O 0.3043(3) 0.6759(4) 0.3327(2) 0.0080(11) Uani 1 1 d . U . . .
O3 O 0.4161(3) 0.7424(4) 0.2641(2) 0.0079(11) Uani 1 1 d . U . . .
O2 O 0.5312(3) 0.8993(4) 0.3024(2) 0.0117(12) Uani 1 1 d . U . . .
O4 O 0.4502(3) 0.7818(4) 0.3745(2) 0.0078(11) Uani 1 1 d . U . . .
O1 O 0.5342(3) 0.9643(4) 0.4084(2) 0.0097(12) Uani 1 1 d . U . . .
O7 O 0.3100(3) 0.4531(4) 0.3396(2) 0.0083(11) Uani 1 1 d . U . . .
O13 O 0.5328(4) 0.2369(4) 0.3025(2) 0.0147(12) Uani 1 1 d . U . . .
O15 O 0.5462(3) 0.1841(4) 0.4105(2) 0.0098(12) Uani 1 1 d . U . . .
O12 O 0.4169(3) 0.3965(4) 0.2657(2) 0.0090(11) Uani 1 1 d . U . . .
O10 O 0.1604(3) 0.5651(4) 0.4737(2) 0.0092(11) Uani 1 1 d . U . . .
O8 O 0.3151(3) 0.5760(5) 0.4334(2) 0.0170(13) Uani 1 1 d . U . . .
O9 O 0.3086(4) 0.5917(4) 0.5395(2) 0.0166(13) Uani 1 1 d . U . . .
B9 B 0.2613(6) 0.5772(8) 0.4831(4) 0.012(2) Uani 1 1 d . U . . .
B7 B 0.5067(6) 0.8820(8) 0.3609(4) 0.0076(19) Uani 1 1 d . U . . .
B1 B 0.5151(6) 0.2606(8) 0.3625(4) 0.009(2) Uani 1 1 d . U . . .
B3 B 0.4126(6) 0.4483(8) 0.3279(4) 0.0060(18) Uani 1 1 d . U . . .
B8 B 0.1051(6) 0.5672(7) 0.4101(4) 0.0045(18) Uani 1 1 d . U . . .
B5 B 0.4082(6) 0.6902(8) 0.3268(4) 0.0086(19) Uani 1 1 d . U . . .
B6 B 0.5000 0.8157(11) 0.2500 0.011(3) Uani 1 2 d S TU P . .
B2 B 0.5000 0.3225(11) 0.2500 0.014(3) Uani 1 2 d S TU P . .
B4 B 0.2732(6) 0.5670(8) 0.3672(4) 0.010(2) Uani 1 1 d . U . . .
Cl2 Cl 0.20331(14) 0.58942(18) 0.15973(9) 0.0174(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag8 Ag8 3.2624(12) 2 ?
Ag8 O11 2.311(5) . ?
Ag8 O2 2.458(5) 3_445 ?
Ag8 O13 2.388(5) 3_455 ?
Ag8 Cl2 2.519(2) . ?
Ag7 Ag3 3.1556(9) 5_666 ?
Ag7 O6 2.320(4) . ?
Ag7 O3 2.451(4) 2_655 ?
Ag7 O12 2.388(5) 2_655 ?
Ag7 Cl2 2.5450(19) 2_655 ?
Ag5 Ag2 3.2877(9) 7_556 ?
Ag5 Ag3 3.2194(9) 5_666 ?
Ag5 Ag1 3.3149(9) 3_545 ?
Ag5 Cl1 2.774(2) . ?
Ag5 O4 2.420(5) 5_666 ?
Ag5 O15 2.448(5) . ?
Ag5 O8 2.521(5) 5_666 ?
Ag2 Ag5 3.2877(9) 7_556 ?
Ag2 Ag4 3.2296(10) 7_556 ?
Ag2 Cl1 2.742(2) 7_556 ?
Ag2 O1 2.439(5) 7_566 ?
Ag2 O10 2.311(5) . ?
Ag2 Cl2 2.772(2) 6_566 ?
Ag3 Ag7 3.1555(9) 5_666 ?
Ag3 Ag5 3.2194(9) 5_666 ?
Ag3 Ag3 3.0590(14) 5_666 ?
Ag3 Cl1 2.556(2) . ?
Ag3 O6 2.489(5) 5_666 ?
Ag3 O14 2.361(5) 5_666 ?
Ag3 O9 2.316(5) . ?
Ag6 Ag1 3.1243(10) 6_565 ?
Ag6 O3 2.317(4) 4_545 ?
Ag6 O7 2.306(5) . ?
Ag6 O12 2.580(5) . ?
Ag1 Ag5 3.3149(9) 3_455 ?
Ag1 Ag6 3.1242(10) 6_566 ?
Ag1 O5 2.196(5) 7_566 ?
Ag1 O9 2.104(5) . ?
Ag1 Cl2 2.923(2) 6_566 ?
Ag4 Ag2 3.2297(10) 7_556 ?
Ag4 Cl1 2.670(2) 7_556 ?
Ag4 Cl1 2.632(2) . ?
Ag4 O7 2.320(5) . ?
Ag4 Cl2 2.819(2) 4_545 ?
Cl1 Ag2 2.742(2) 7_556 ?
Cl1 Ag4 2.670(2) 7_556 ?
O11 B8 1.407(9) . ?
O11 B4 1.434(9) . ?
O6 Ag3 2.489(5) 5_666 ?
O6 B3 1.477(9) . ?
O6 B5 1.458(9) . ?
O14 Ag3 2.361(5) 5_666 ?
O14 B1 1.365(9) . ?
O14 B3 1.509(9) . ?
O5 Ag1 2.196(4) 7_566 ?
O5 B5 1.458(9) . ?
O5 B4 1.472(9) . ?
O3 Ag7 2.451(4) 2_655 ?
O3 Ag6 2.317(4) 4 ?
O3 B5 1.478(9) . ?
O3 B6 1.455(8) . ?
O2 Ag8 2.458(5) 3 ?
O2 B7 1.351(9) . ?
O2 B6 1.475(8) . ?
O4 Ag5 2.420(5) 5_666 ?
O4 B7 1.375(9) . ?
O4 B5 1.497(9) . ?
O1 Ag2 2.439(5) 7_566 ?
O1 B7 1.379(9) . ?
O1 B8 1.472(9) 3 ?
O7 B3 1.462(9) . ?
O7 B4 1.472(9) . ?
O13 Ag8 2.388(5) 3_545 ?
O13 B1 1.365(9) . ?
O13 B2 1.494(9) . ?
O15 B1 1.358(10) . ?
O15 B8 1.494(9) 3_545 ?
O12 Ag7 2.388(5) 2_655 ?
O12 B3 1.459(9) . ?
O12 B2 1.461(8) . ?
O10 B9 1.392(9) . ?
O10 B8 1.504(9) . ?
O8 Ag5 2.521(5) 5_666 ?
O8 B9 1.362(10) . ?
O8 B4 1.491(9) . ?
O9 B9 1.333(9) . ?
B8 O1 1.472(9) 3_445 ?
B8 O15 1.494(9) 3_455 ?
B6 O3 1.455(8) 2_655 ?
B6 O2 1.475(8) 2_655 ?
B2 O13 1.494(9) 2_655 ?
B2 O12 1.461(8) 2_655 ?
Cl2 Ag7 2.5449(19) 2_655 ?
Cl2 Ag2 2.772(2) 6_565 ?
Cl2 Ag1 2.923(2) 6_565 ?
Cl2 Ag4 2.819(2) 4 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Ag8 Ag8 107.47(11) . 2 ?
O11 Ag8 O2 71.89(16) . 3_445 ?
O11 Ag8 O13 75.48(16) . 3_455 ?
O11 Ag8 Cl2 135.43(12) . . ?
O2 Ag8 Ag8 60.84(11) 3_445 2 ?
O2 Ag8 Cl2 132.09(12) 3_445 . ?
O13 Ag8 Ag8 60.48(12) 3_455 2 ?
O13 Ag8 O2 96.71(16) 3_455 3_445 ?
O13 Ag8 Cl2 124.95(12) 3_455 . ?
Cl2 Ag8 Ag8 117.06(5) . 2 ?
O6 Ag7 Ag3 51.35(11) . 5_666 ?
O6 Ag7 O3 91.97(16) . 2_655 ?
O6 Ag7 O12 95.24(16) . 2_655 ?
O6 Ag7 Cl2 145.58(12) . 2_655 ?
O3 Ag7 Ag3 129.31(11) 2_655 5_666 ?
O3 Ag7 Cl2 101.99(11) 2_655 2_655 ?
O12 Ag7 Ag3 114.96(11) 2_655 5_666 ?
O12 Ag7 O3 100.14(15) 2_655 2_655 ?
O12 Ag7 Cl2 112.67(12) 2_655 2_655 ?
Cl2 Ag7 Ag3 96.99(5) 2_655 5_666 ?
Ag2 Ag5 Ag1 120.30(3) 7_556 3_545 ?
Ag3 Ag5 Ag2 107.92(2) 5_666 7_556 ?
Ag3 Ag5 Ag1 130.21(3) 5_666 3_545 ?
Cl1 Ag5 Ag2 52.96(5) . 7_556 ?
Cl1 Ag5 Ag3 85.27(5) . 5_666 ?
Cl1 Ag5 Ag1 133.20(5) . 3_545 ?
O4 Ag5 Ag2 97.39(11) 5_666 7_556 ?
O4 Ag5 Ag3 131.21(11) 5_666 5_666 ?
O4 Ag5 Ag1 56.33(11) 5_666 3_545 ?
O4 Ag5 Cl1 77.64(12) 5_666 . ?
O4 Ag5 O15 145.65(16) 5_666 . ?
O4 Ag5 O8 81.55(15) 5_666 5_666 ?
O15 Ag5 Ag2 51.72(11) . 7_556 ?
O15 Ag5 Ag3 78.74(11) . 5_666 ?
O15 Ag5 Ag1 121.64(11) . 3_545 ?
O15 Ag5 Cl1 90.85(12) . . ?
O15 Ag5 O8 130.51(16) . 5_666 ?
O8 Ag5 Ag2 175.25(11) 5_666 7_556 ?
O8 Ag5 Ag3 69.82(11) 5_666 5_666 ?
O8 Ag5 Ag1 62.93(11) 5_666 3_545 ?
O8 Ag5 Cl1 122.34(12) 5_666 . ?
Ag4 Ag2 Ag5 88.37(2) 7_556 7_556 ?
Cl1 Ag2 Ag5 53.87(4) 7_556 7_556 ?
Cl1 Ag2 Ag4 51.52(5) 7_556 7_556 ?
Cl1 Ag2 Cl2 106.93(6) 7_556 6_566 ?
O1 Ag2 Ag5 86.53(11) 7_566 7_556 ?
O1 Ag2 Ag4 131.10(11) 7_566 7_556 ?
O1 Ag2 Cl1 139.83(12) 7_566 7_556 ?
O1 Ag2 Cl2 90.47(12) 7_566 6_566 ?
O10 Ag2 Ag5 114.58(11) . 7_556 ?
O10 Ag2 Ag4 116.47(12) . 7_556 ?
O10 Ag2 Cl1 94.65(12) . 7_556 ?
O10 Ag2 O1 109.74(16) . 7_566 ?
O10 Ag2 Cl2 116.59(12) . 6_566 ?
Cl2 Ag2 Ag5 126.47(5) 6_566 7_556 ?
Cl2 Ag2 Ag4 55.41(4) 6_566 7_556 ?
Ag7 Ag3 Ag5 126.11(3) 5_666 5_666 ?
Ag3 Ag3 Ag7 171.94(4) 5_666 5_666 ?
Ag3 Ag3 Ag5 57.77(2) 5_666 5_666 ?
Cl1 Ag3 Ag7 90.46(5) . 5_666 ?
Cl1 Ag3 Ag5 122.14(5) . 5_666 ?
Cl1 Ag3 Ag3 92.57(6) . 5_666 ?
O6 Ag3 Ag7 46.71(10) 5_666 5_666 ?
O6 Ag3 Ag5 132.21(11) 5_666 5_666 ?
O6 Ag3 Ag3 125.22(11) 5_666 5_666 ?
O6 Ag3 Cl1 105.65(12) 5_666 . ?
O14 Ag3 Ag7 75.67(12) 5_666 5_666 ?
O14 Ag3 Ag5 73.59(11) 5_666 5_666 ?
O14 Ag3 Ag3 100.13(12) 5_666 5_666 ?
O14 Ag3 Cl1 163.81(13) 5_666 . ?
O14 Ag3 O6 58.71(15) 5_666 5_666 ?
O9 Ag3 Ag7 86.10(13) . 5_666 ?
O9 Ag3 Ag5 55.22(13) . 5_666 ?
O9 Ag3 Ag3 101.32(13) . 5_666 ?
O9 Ag3 Cl1 90.90(13) . . ?
O9 Ag3 O6 128.75(17) . 5_666 ?
O9 Ag3 O14 96.35(17) . 5_666 ?
O3 Ag6 Ag1 84.51(12) 4_545 6_565 ?
O3 Ag6 O12 166.03(16) 4_545 . ?
O7 Ag6 Ag1 129.46(12) . 6_565 ?
O7 Ag6 O3 136.64(16) . 4_545 ?
O7 Ag6 O12 57.25(15) . . ?
O12 Ag6 Ag1 83.05(11) . 6_565 ?
Ag6 Ag1 Ag5 122.28(3) 6_566 3_455 ?
O5 Ag1 Ag5 78.29(12) 7_566 3_455 ?
O5 Ag1 Ag6 55.89(12) 7_566 6_566 ?
O5 Ag1 Cl2 119.65(13) 7_566 6_566 ?
O9 Ag1 Ag5 85.02(13) . 3_455 ?
O9 Ag1 Ag6 151.58(14) . 6_566 ?
O9 Ag1 O5 147.83(18) . 7_566 ?
O9 Ag1 Cl2 91.76(14) . 6_566 ?
Cl2 Ag1 Ag5 109.57(4) 6_566 3_455 ?
Cl2 Ag1 Ag6 72.73(4) 6_566 6_566 ?
Cl1 Ag4 Ag2 54.63(5) . 7_556 ?
Cl1 Ag4 Ag2 88.76(5) 7_556 7_556 ?
Cl1 Ag4 Cl1 78.70(7) . 7_556 ?
Cl1 Ag4 Cl2 98.99(6) 7_556 4_545 ?
Cl1 Ag4 Cl2 108.65(7) . 4_545 ?
O7 Ag4 Ag2 124.89(11) . 7_556 ?
O7 Ag4 Cl1 146.08(12) . 7_556 ?
O7 Ag4 Cl1 122.18(12) . . ?
O7 Ag4 Cl2 98.44(12) . 4_545 ?
Cl2 Ag4 Ag2 54.03(4) 4_545 7_556 ?
Ag2 Cl1 Ag5 73.17(5) 7_556 . ?
Ag3 Cl1 Ag5 69.31(5) . . ?
Ag3 Cl1 Ag2 141.13(9) . 7_556 ?
Ag3 Cl1 Ag4 115.44(8) . 7_556 ?
Ag3 Cl1 Ag4 113.06(8) . . ?
Ag4 Cl1 Ag5 114.29(8) . . ?
Ag4 Cl1 Ag5 138.98(8) 7_556 . ?
Ag4 Cl1 Ag2 73.84(6) . 7_556 ?
Ag4 Cl1 Ag2 99.37(7) 7_556 7_556 ?
Ag4 Cl1 Ag4 101.30(7) . 7_556 ?
B8 O11 Ag8 124.2(4) . . ?
B8 O11 B4 130.2(6) . . ?
B4 O11 Ag8 105.1(4) . . ?
Ag7 O6 Ag3 81.94(14) . 5_666 ?
B3 O6 Ag7 109.6(4) . . ?
B3 O6 Ag3 94.6(4) . 5_666 ?
B5 O6 Ag7 115.9(4) . . ?
B5 O6 Ag3 121.3(4) . 5_666 ?
B5 O6 B3 124.4(5) . . ?
B1 O14 Ag3 118.2(4) . 5_666 ?
B1 O14 B3 123.3(6) . . ?
B3 O14 Ag3 98.9(4) . 5_666 ?
B5 O5 Ag1 109.3(4) . 7_566 ?
B5 O5 B4 117.7(6) . . ?
B4 O5 Ag1 105.1(4) . 7_566 ?
Ag6 O3 Ag7 92.71(16) 4 2_655 ?
B5 O3 Ag7 104.2(4) . 2_655 ?
B5 O3 Ag6 102.9(4) . 4 ?
B6 O3 Ag7 113.0(4) . 2_655 ?
B6 O3 Ag6 117.7(4) . 4 ?
B6 O3 B5 121.8(5) . . ?
B7 O2 Ag8 130.3(5) . 3 ?
B7 O2 B6 123.5(6) . . ?
B6 O2 Ag8 106.0(4) . 3 ?
B7 O4 Ag5 118.4(4) . 5_666 ?
B7 O4 B5 123.7(6) . . ?
B5 O4 Ag5 117.6(4) . 5_666 ?
B7 O1 Ag2 116.1(4) . 7_566 ?
B7 O1 B8 129.2(6) . 3 ?
B8 O1 Ag2 99.7(4) 3 7_566 ?
Ag6 O7 Ag4 87.88(15) . . ?
B3 O7 Ag6 102.3(4) . . ?
B3 O7 Ag4 113.0(4) . . ?
B3 O7 B4 118.4(6) . . ?
B4 O7 Ag6 129.9(4) . . ?
B4 O7 Ag4 100.5(4) . . ?
B1 O13 Ag8 131.6(5) . 3_545 ?
B1 O13 B2 122.5(6) . . ?
B2 O13 Ag8 105.9(4) . 3_545 ?
B1 O15 Ag5 120.8(4) . . ?
B1 O15 B8 129.3(6) . 3_545 ?
B8 O15 Ag5 106.0(4) 3_545 . ?
Ag7 O12 Ag6 94.69(15) 2_655 . ?
B3 O12 Ag7 106.7(4) . 2_655 ?
B3 O12 Ag6 90.8(4) . . ?
B3 O12 B2 121.6(4) . . ?
B2 O12 Ag7 111.1(4) . 2_655 ?
B2 O12 Ag6 127.3(4) . . ?
B9 O10 Ag2 113.2(4) . . ?
B9 O10 B8 122.7(6) . . ?
B8 O10 Ag2 115.0(4) . . ?
B9 O8 Ag5 92.0(4) . 5_666 ?
B9 O8 B4 124.4(6) . . ?
B4 O8 Ag5 128.2(4) . 5_666 ?
Ag1 O9 Ag3 115.0(2) . . ?
B9 O9 Ag3 116.8(5) . . ?
B9 O9 Ag1 125.8(5) . . ?
O8 B9 O10 119.8(7) . . ?
O9 B9 O10 122.4(7) . . ?
O9 B9 O8 117.7(7) . . ?
O2 B7 O4 120.3(7) . . ?
O2 B7 O1 122.1(7) . . ?
O4 B7 O1 117.5(7) . . ?
O14 B1 O13 120.3(7) . . ?
O15 B1 O14 117.0(7) . . ?
O15 B1 O13 122.7(7) . . ?
O6 B3 O14 105.7(5) . . ?
O7 B3 O6 111.2(6) . . ?
O7 B3 O14 107.7(6) . . ?
O12 B3 O6 114.0(6) . . ?
O12 B3 O14 110.8(6) . . ?
O12 B3 O7 107.3(6) . . ?
O11 B8 O1 114.1(6) . 3_445 ?
O11 B8 O15 114.7(6) . 3_455 ?
O11 B8 O10 111.3(6) . . ?
O1 B8 O15 105.7(6) 3_445 3_455 ?
O1 B8 O10 106.7(6) 3_445 . ?
O15 B8 O10 103.5(5) 3_455 . ?
O6 B5 O3 112.8(6) . . ?
O6 B5 O4 108.7(6) . . ?
O5 B5 O6 111.0(6) . . ?
O5 B5 O3 106.3(6) . . ?
O5 B5 O4 109.1(6) . . ?
O3 B5 O4 108.8(6) . . ?
O3 B6 O3 114.6(9) . 2_655 ?
O3 B6 O2 110.3(3) 2_655 2_655 ?
O3 B6 O2 108.1(3) 2_655 . ?
O3 B6 O2 110.3(3) . . ?
O3 B6 O2 108.1(3) . 2_655 ?
O2 B6 O2 105.0(8) 2_655 . ?
O13 B2 O13 104.2(8) 2_655 . ?
O12 B2 O13 108.9(3) . 2_655 ?
O12 B2 O13 108.9(3) 2_655 . ?
O12 B2 O13 110.1(3) 2_655 2_655 ?
O12 B2 O13 110.1(3) . . ?
O12 B2 O12 114.2(9) . 2_655 ?
O11 B4 O5 109.9(6) . . ?
O11 B4 O7 108.9(6) . . ?
O11 B4 O8 110.9(6) . . ?
O5 B4 O7 108.9(6) . . ?
O5 B4 O8 109.2(6) . . ?
O7 B4 O8 109.0(6) . . ?
Ag8 Cl2 Ag7 105.51(7) . 2_655 ?
Ag8 Cl2 Ag2 120.34(7) . 6_565 ?
Ag8 Cl2 Ag1 108.46(7) . 6_565 ?
Ag8 Cl2 Ag4 127.87(8) . 4 ?
Ag7 Cl2 Ag2 131.72(8) 2_655 6_565 ?
Ag7 Cl2 Ag1 76.12(5) 2_655 6_565 ?
Ag7 Cl2 Ag4 93.78(6) 2_655 4 ?
Ag2 Cl2 Ag1 75.85(5) 6_565 6_565 ?
Ag2 Cl2 Ag4 70.57(5) 6_565 4 ?
Ag4 Cl2 Ag1 123.19(7) 4 6_565 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag8 O11 B8 O1 62.3(7) . . . 3_445 ?
Ag8 O11 B8 O15 -59.8(7) . . . 3_455 ?
Ag8 O11 B8 O10 -176.9(4) . . . . ?
Ag8 O11 B4 O5 52.7(6) . . . . ?
Ag8 O11 B4 O7 -66.6(6) . . . . ?
Ag8 O11 B4 O8 173.4(5) . . . . ?
Ag8 O2 B7 O4 174.9(4) 3 . . . ?
Ag8 O2 B7 O1 -3.4(11) 3 . . . ?
Ag8 O2 B6 O3 77.9(6) 3 . . 2_655 ?
Ag8 O2 B6 O3 -156.2(5) 3 . . . ?
Ag8 O2 B6 O2 -39.88(13) 3 . . 2_655 ?
Ag8 O13 B1 O14 178.5(4) 3_545 . . . ?
Ag8 O13 B1 O15 -1.2(11) 3_545 . . . ?
Ag8 O13 B2 O13 40.94(14) 3_545 . . 2_655 ?
Ag8 O13 B2 O12 -76.5(6) 3_545 . . 2_655 ?
Ag8 O13 B2 O12 157.6(5) 3_545 . . . ?
Ag7 O6 B3 O14 70.3(5) . . . . ?
Ag7 O6 B3 O7 -173.0(4) . . . . ?
Ag7 O6 B3 O12 -51.5(6) . . . . ?
Ag7 O6 B5 O5 165.6(4) . . . . ?
Ag7 O6 B5 O3 46.3(7) . . . . ?
Ag7 O6 B5 O4 -74.5(6) . . . . ?
Ag7 O3 B5 O6 45.3(6) 2_655 . . . ?
Ag7 O3 B5 O5 -76.6(5) 2_655 . . . ?
Ag7 O3 B5 O4 166.1(4) 2_655 . . . ?
Ag7 O3 B6 O3 -42.75(17) 2_655 . . 2_655 ?
Ag7 O3 B6 O2 -165.0(4) 2_655 . . . ?
Ag7 O3 B6 O2 80.7(6) 2_655 . . 2_655 ?
Ag7 O12 B3 O6 -41.4(6) 2_655 . . . ?
Ag7 O12 B3 O14 -160.5(4) 2_655 . . . ?
Ag7 O12 B3 O7 82.2(5) 2_655 . . . ?
Ag7 O12 B2 O13 167.5(4) 2_655 . . . ?
Ag7 O12 B2 O13 -78.9(6) 2_655 . . 2_655 ?
Ag7 O12 B2 O12 44.60(17) 2_655 . . 2_655 ?
Ag5 O4 B7 O2 170.0(5) 5_666 . . . ?
Ag5 O4 B7 O1 -11.7(9) 5_666 . . . ?
Ag5 O4 B5 O6 -64.0(6) 5_666 . . . ?
Ag5 O4 B5 O5 57.1(7) 5_666 . . . ?
Ag5 O4 B5 O3 172.7(4) 5_666 . . . ?
Ag5 O15 B1 O14 -23.0(9) . . . . ?
Ag5 O15 B1 O13 156.8(5) . . . . ?
Ag5 O8 B9 O10 143.1(7) 5_666 . . . ?
Ag5 O8 B9 O9 -36.1(7) 5_666 . . . ?
Ag5 O8 B4 O11 -125.5(5) 5_666 . . . ?
Ag5 O8 B4 O5 -4.3(8) 5_666 . . . ?
Ag5 O8 B4 O7 114.6(5) 5_666 . . . ?
Ag2 O1 B7 O2 118.3(7) 7_566 . . . ?
Ag2 O1 B7 O4 -60.0(8) 7_566 . . . ?
Ag2 O10 B9 O8 137.0(6) . . . . ?
Ag2 O10 B9 O9 -43.8(9) . . . . ?
Ag2 O10 B8 O11 -134.8(5) . . . . ?
Ag2 O10 B8 O1 -9.7(6) . . . 3_445 ?
Ag2 O10 B8 O15 101.5(5) . . . 3_455 ?
Ag3 O6 B3 O14 -12.7(5) 5_666 . . . ?
Ag3 O6 B3 O7 103.9(5) 5_666 . . . ?
Ag3 O6 B3 O12 -134.6(5) 5_666 . . . ?
Ag3 O6 B5 O5 -98.0(6) 5_666 . . . ?
Ag3 O6 B5 O3 142.8(4) 5_666 . . . ?
Ag3 O6 B5 O4 22.0(7) 5_666 . . . ?
Ag3 O14 B1 O13 -114.6(6) 5_666 . . . ?
Ag3 O14 B1 O15 65.1(8) 5_666 . . . ?
Ag3 O14 B3 O6 13.5(5) 5_666 . . . ?
Ag3 O14 B3 O7 -105.5(5) 5_666 . . . ?
Ag3 O14 B3 O12 137.5(5) 5_666 . . . ?
Ag3 O9 B9 O10 138.3(6) . . . . ?
Ag3 O9 B9 O8 -42.5(9) . . . . ?
Ag6 O3 B5 O6 141.5(5) 4 . . . ?
Ag6 O3 B5 O5 19.6(6) 4 . . . ?
Ag6 O3 B5 O4 -97.7(5) 4 . . . ?
Ag6 O3 B6 O3 -149.0(3) 4 . . 2_655 ?
Ag6 O3 B6 O2 -25.6(7) 4 . . 2_655 ?
Ag6 O3 B6 O2 88.7(5) 4 . . . ?
Ag6 O7 B3 O6 140.1(5) . . . . ?
Ag6 O7 B3 O14 -104.4(5) . . . . ?
Ag6 O7 B3 O12 14.9(6) . . . . ?
Ag6 O7 B4 O11 28.2(8) . . . . ?
Ag6 O7 B4 O5 -91.6(6) . . . . ?
Ag6 O7 B4 O8 149.3(4) . . . . ?
Ag6 O12 B3 O6 -136.6(5) . . . . ?
Ag6 O12 B3 O14 104.4(5) . . . . ?
Ag6 O12 B3 O7 -13.0(5) . . . . ?
Ag6 O12 B2 O13 35.0(7) . . . 2_655 ?
Ag6 O12 B2 O13 -78.7(5) . . . . ?
Ag6 O12 B2 O12 158.4(4) . . . 2_655 ?
Ag1 O5 B5 O6 140.3(5) 7_566 . . . ?
Ag1 O5 B5 O3 -96.6(5) 7_566 . . . ?
Ag1 O5 B5 O4 20.6(7) 7_566 . . . ?
Ag1 O5 B4 O11 63.7(6) 7_566 . . . ?
Ag1 O5 B4 O7 -177.0(4) 7_566 . . . ?
Ag1 O5 B4 O8 -58.0(6) 7_566 . . . ?
Ag1 O9 B9 O10 -23.1(11) . . . . ?
Ag1 O9 B9 O8 156.1(5) . . . . ?
Ag4 O7 B3 O6 -126.9(5) . . . . ?
Ag4 O7 B3 O14 -11.5(6) . . . . ?
Ag4 O7 B3 O12 107.8(5) . . . . ?
Ag4 O7 B4 O11 -67.9(6) . . . . ?
Ag4 O7 B4 O5 172.3(4) . . . . ?
Ag4 O7 B4 O8 53.2(6) . . . . ?
B9 O10 B8 O11 9.9(9) . . . . ?
B9 O10 B8 O1 135.0(6) . . . 3_445 ?
B9 O10 B8 O15 -113.8(7) . . . 3_455 ?
B9 O8 B4 O11 0.8(10) . . . . ?
B9 O8 B4 O5 122.0(7) . . . . ?
B9 O8 B4 O7 -119.1(7) . . . . ?
B7 O2 B6 O3 -106.6(6) . . . 2_655 ?
B7 O2 B6 O3 19.4(9) . . . . ?
B7 O2 B6 O2 135.7(7) . . . 2_655 ?
B7 O4 B5 O6 109.3(7) . . . . ?
B7 O4 B5 O5 -129.6(7) . . . . ?
B7 O4 B5 O3 -14.0(9) . . . . ?
B1 O14 B3 O6 -119.1(7) . . . . ?
B1 O14 B3 O7 121.9(7) . . . . ?
B1 O14 B3 O12 4.9(9) . . . . ?
B1 O13 B2 O13 -140.9(7) . . . 2_655 ?
B1 O13 B2 O12 -24.2(9) . . . . ?
B1 O13 B2 O12 101.7(7) . . . 2_655 ?
B3 O6 B5 O5 23.9(9) . . . . ?
B3 O6 B5 O3 -95.4(7) . . . . ?
B3 O6 B5 O4 143.9(6) . . . . ?
B3 O14 B1 O13 9.8(11) . . . . ?
B3 O14 B1 O15 -170.5(6) . . . . ?
B3 O7 B4 O11 168.6(6) . . . . ?
B3 O7 B4 O5 48.7(8) . . . . ?
B3 O7 B4 O8 -70.4(8) . . . . ?
B3 O12 B2 O13 154.3(5) . . . 2_655 ?
B3 O12 B2 O13 40.6(9) . . . . ?
B3 O12 B2 O12 -82.2(6) . . . 2_655 ?
B8 O11 B4 O5 -118.7(7) . . . . ?
B8 O11 B4 O7 122.0(7) . . . . ?
B8 O11 B4 O8 2.1(10) . . . . ?
B8 O1 B7 O2 -11.8(11) 3 . . . ?
B8 O1 B7 O4 170.0(6) 3 . . . ?
B8 O15 B1 O14 -177.7(6) 3_545 . . . ?
B8 O15 B1 O13 2.0(12) 3_545 . . . ?
B8 O10 B9 O8 -8.2(11) . . . . ?
B8 O10 B9 O9 170.9(7) . . . . ?
B5 O6 B3 O14 -146.0(6) . . . . ?
B5 O6 B3 O7 -29.4(9) . . . . ?
B5 O6 B3 O12 92.1(8) . . . . ?
B5 O5 B4 O11 -174.3(6) . . . . ?
B5 O5 B4 O7 -55.1(8) . . . . ?
B5 O5 B4 O8 63.9(8) . . . . ?
B5 O3 B6 O3 82.5(6) . . . 2_655 ?
B5 O3 B6 O2 -154.1(6) . . . 2_655 ?
B5 O3 B6 O2 -39.8(9) . . . . ?
B5 O4 B7 O2 -3.2(11) . . . . ?
B5 O4 B7 O1 175.1(6) . . . . ?
B6 O3 B5 O6 -83.8(8) . . . . ?
B6 O3 B5 O5 154.3(6) . . . . ?
B6 O3 B5 O4 36.9(9) . . . . ?
B6 O2 B7 O4 0.5(11) . . . . ?
B6 O2 B7 O1 -177.7(6) . . . . ?
B2 O13 B1 O14 0.8(10) . . . . ?
B2 O13 B1 O15 -178.9(6) . . . . ?
B2 O12 B3 O6 87.4(8) . . . . ?
B2 O12 B3 O14 -31.7(9) . . . . ?
B2 O12 B3 O7 -149.0(6) . . . . ?
B4 O11 B8 O1 -127.8(7) . . . 3_445 ?
B4 O11 B8 O15 110.1(8) . . . 3_455 ?
B4 O11 B8 O10 -7.0(10) . . . . ?
B4 O5 B5 O6 20.6(8) . . . . ?
B4 O5 B5 O3 143.7(6) . . . . ?
B4 O5 B5 O4 -99.2(7) . . . . ?
B4 O7 B3 O6 -9.8(8) . . . . ?
B4 O7 B3 O14 105.6(7) . . . . ?
B4 O7 B3 O12 -135.1(6) . . . . ?
B4 O8 B9 O10 2.4(11) . . . . ?
B4 O8 B9 O9 -176.8(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag8b8br(oh)o15
_database_code_depnum_ccdc_archive 'CCDC 2289393'
loop_
_audit_author_name
_audit_author_address
'Ru-Ling Tang'
;YangZhou University
China
;
_audit_update_record             
;
2023-08-18 deposited with the CCDC.	2024-07-02 downloaded from the CCDC.
;
_audit_creation_date             2023-06-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        1282
_chemical_formula_moiety         'Ag8 B8 Br H O16'
_chemical_formula_sum            'Ag8 H B8 Br O16'
_chemical_formula_weight         1286.36
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.7338(3)
_cell_length_b                   8.8080(3)
_cell_length_c                   10.8986(3)
_cell_angle_alpha                79.5730(10)
_cell_angle_beta                 89.3170(10)
_cell_angle_gamma                75.2420(10)
_cell_volume                     796.84(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    8252
_cell_measurement_temperature    296
_cell_measurement_theta_max      30.543
_cell_measurement_theta_min      2.433
_shelx_estimated_absorpt_T_max   0.375
_shelx_estimated_absorpt_T_min   0.300
_exptl_absorpt_coefficient_mu    12.212
_exptl_absorpt_correction_T_max  0.5239
_exptl_absorpt_correction_T_min  0.4320
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0727 before and 0.0430 after correction.
The Ratio of minimum to maximum transmission is 0.8246.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    5.361
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0313
_diffrn_reflns_av_unetI/netI     0.0274
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14111
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.483
_diffrn_reflns_theta_min         2.413
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3195
_reflns_number_total             3653
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         2.099
_refine_diff_density_min         -2.297
_refine_diff_density_rms         0.180
_refine_ls_extinction_coef       0.00359(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     306
_refine_ls_number_reflns         3653
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0307
_refine_ls_R_factor_gt           0.0233
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0156P)²+4.0360P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0454
_refine_ls_wR_factor_ref         0.0479
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.10663(4) 0.37747(4) 0.61475(3) 0.01594(9) Uani 1 1 d . . . . .
Ag3 Ag 0.31195(5) 1.33660(5) 0.97189(3) 0.01880(10) Uani 1 1 d . . . . .
Ag4 Ag 0.37625(4) 0.88295(5) 0.51658(3) 0.01805(9) Uani 1 1 d . . . . .
Ag6 Ag 0.54354(4) 0.45672(5) 0.78201(4) 0.01971(10) Uani 1 1 d . . . . .
Ag9 Ag 1.34486(5) -0.02280(5) 1.07435(4) 0.02113(10) Uani 1 1 d . . . . .
Ag8 Ag 1.0000 0.0000 1.0000 0.02744(14) Uani 1 2 d S . P . .
Ag7 Ag 0.98172(5) 0.41944(6) 0.87921(4) 0.03322(13) Uani 1 1 d . . . . .
Ag5 Ag 0.5000 0.5000 0.5000 0.03352(17) Uani 1 2 d S . P . .
Ag2 Ag 0.05351(5) 1.03813(5) 0.61065(5) 0.03556(13) Uani 1 1 d . . . . .
Br1 Br 0.26140(6) 0.83930(6) 0.31253(4) 0.01789(11) Uani 1 1 d . . . . .
O6 O 0.3313(4) 0.8192(4) 0.7274(3) 0.0074(6) Uani 1 1 d . . . . .
O14 O 0.7298(3) 0.5861(4) 0.4638(3) 0.0075(6) Uani 1 1 d . . . . .
O7 O 0.3204(3) 0.5652(3) 0.6818(3) 0.0078(6) Uani 1 1 d . . . . .
O9 O 0.3888(4) 1.0258(4) 0.8264(3) 0.0102(6) Uani 1 1 d . . . . .
O3 O 0.0878(4) 0.7806(3) 0.6684(3) 0.0098(6) Uani 1 1 d . . . . .
O8 O 0.3201(4) 1.1308(4) 0.6108(3) 0.0125(7) Uani 1 1 d . . . . .
O1 O 0.0613(3) 0.5145(3) 0.6753(3) 0.0075(6) Uani 1 1 d . . . . .
O2 O -0.0962(3) 0.7404(4) 0.5257(3) 0.0080(6) Uani 1 1 d . . . . .
O11 O 0.5962(4) 0.7946(4) 0.8141(3) 0.0112(7) Uani 1 1 d . . . . .
O5 O 0.3865(4) 0.7752(4) 0.9491(3) 0.0088(6) Uani 1 1 d . . . . .
O16 O 1.1042(4) 0.1844(4) 1.0199(4) 0.0204(8) Uani 1 1 d . . . . .
O12 O 0.6378(4) 0.7718(4) 0.5997(3) 0.0106(6) Uani 1 1 d . . . . .
O15 O 0.7258(4) 0.4117(4) 0.9175(3) 0.0185(8) Uani 1 1 d . . . . .
O13 O 0.8535(4) 0.7072(4) 0.7470(3) 0.0107(6) Uani 1 1 d . . . . .
O10 O 0.2869(4) 1.3024(4) 0.7592(3) 0.0096(6) Uani 1 1 d . . . . .
O4 O 0.2096(4) 0.6445(4) 0.8697(3) 0.0138(7) Uani 1 1 d . . . . .
B5 B 0.3326(6) 1.1524(6) 0.7313(4) 0.0079(9) Uani 1 1 d . . . . .
B7 B 0.6950(6) 0.7584(6) 0.7196(4) 0.0065(9) Uani 1 1 d . . . . .
B4 B 0.4216(6) 0.8519(6) 0.8227(4) 0.0060(9) Uani 1 1 d . . . . .
B2 B 0.2360(6) 0.7059(6) 0.7384(4) 0.0077(9) Uani 1 1 d . . . . .
B1 B -0.0228(6) 0.6883(6) 0.6528(4) 0.0075(9) Uani 1 1 d . . . . .
B6 B 0.2318(6) 1.4506(6) 0.6615(4) 0.0064(9) Uani 1 1 d . . . . .
B8 B 0.7416(6) 0.7373(6) 0.4953(5) 0.0079(10) Uani 1 1 d . . . . .
B3 B 0.2892(6) 0.6707(6) 0.9684(5) 0.0084(10) Uani 1 1 d . . . . .
H16 H 1.092(7) 0.194(7) 1.087(6) 0.021(17) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag7 3.1021(6) 1_455 ?
Ag1 Ag2 2.9679(6) 1_545 ?
Ag1 Br1 2.6158(6) 2_566 ?
Ag1 O14 2.397(3) 1_455 ?
Ag1 O1 2.292(3) . ?
Ag1 O2 2.476(3) 2_566 ?
Ag3 Ag6 3.1130(6) 1_565 ?
Ag3 Ag9 3.1007(6) 1_465 ?
Ag3 Ag7 2.9329(6) 1_465 ?
Ag3 O11 2.453(3) 2_677 ?
Ag3 O16 2.515(4) 1_465 ?
Ag3 O10 2.410(3) . ?
Ag4 Br1 2.5805(6) . ?
Ag4 O6 2.318(3) . ?
Ag4 O8 2.513(3) . ?
Ag4 O12 2.364(3) . ?
Ag6 Br1 3.0708(7) 2_666 ?
Ag6 O7 2.151(3) . ?
Ag6 O15 2.096(3) . ?
Ag9 Br1 2.8302(6) 1_646 ?
Ag9 O9 2.569(3) 2_767 ?
Ag9 O5 2.387(3) 1_645 ?
Ag9 O16 2.405(4) . ?
Ag8 O16 2.097(4) . ?
Ag8 O16 2.097(4) 2_757 ?
Ag7 O1 2.389(3) 1_655 ?
Ag7 O16 2.354(4) . ?
Ag7 O15 2.285(3) . ?
Ag5 O14 2.326(3) . ?
Ag5 O14 2.326(3) 2_666 ?
Ag5 O7 2.568(3) 2_666 ?
Ag5 O7 2.568(3) . ?
Ag2 Br1 2.8619(7) 2_576 ?
Ag2 O3 2.185(3) . ?
Ag2 O2 2.337(3) 2_576 ?
Br1 Ag1 2.6158(6) 2_566 ?
Br1 Ag6 3.0707(7) 2_666 ?
Br1 Ag9 2.8302(6) 1_464 ?
Br1 Ag2 2.8619(7) 2_576 ?
O6 B4 1.424(5) . ?
O6 B2 1.443(6) . ?
O14 Ag1 2.398(3) 1_655 ?
O14 B6 1.475(5) 2_676 ?
O14 B8 1.463(6) . ?
O7 B2 1.503(6) . ?
O7 B6 1.466(6) 1_545 ?
O9 Ag9 2.569(3) 2_767 ?
O9 B5 1.369(6) . ?
O9 B4 1.493(5) . ?
O3 B2 1.448(6) . ?
O3 B1 1.441(6) . ?
O8 B5 1.369(6) . ?
O8 B8 1.479(6) 2_676 ?
O1 Ag7 2.389(3) 1_455 ?
O1 B1 1.496(6) . ?
O1 B6 1.468(6) 1_545 ?
O2 Ag1 2.476(3) 2_566 ?
O2 Ag2 2.337(3) 2_576 ?
O2 B1 1.478(5) . ?
O2 B8 1.467(6) 1_455 ?
O11 Ag3 2.453(3) 2_677 ?
O11 B7 1.366(6) . ?
O11 B4 1.487(6) . ?
O5 Ag9 2.387(3) 1_465 ?
O5 B4 1.485(6) . ?
O5 B3 1.392(6) . ?
O16 Ag3 2.515(4) 1_645 ?
O16 H16 0.76(6) . ?
O12 B7 1.378(6) . ?
O12 B8 1.473(6) . ?
O15 B3 1.345(6) 2_667 ?
O13 B7 1.360(6) . ?
O13 B1 1.481(6) 1_655 ?
O10 B5 1.368(6) . ?
O10 B6 1.503(5) . ?
O4 B2 1.473(6) . ?
O4 B3 1.372(6) . ?
B1 O13 1.480(6) 1_455 ?
B6 O14 1.475(5) 2_676 ?
B6 O7 1.466(6) 1_565 ?
B6 O1 1.468(6) 1_565 ?
B8 O8 1.479(6) 2_676 ?
B8 O2 1.467(6) 1_655 ?
B3 O15 1.345(6) 2_667 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag7 103.343(18) 1_545 1_455 ?
Br1 Ag1 Ag7 96.717(18) 2_566 1_455 ?
Br1 Ag1 Ag2 61.283(16) 2_566 1_545 ?
O14 Ag1 Ag7 123.95(7) 1_455 1_455 ?
O14 Ag1 Ag2 132.70(7) 1_455 1_545 ?
O14 Ag1 Br1 108.36(7) 1_455 2_566 ?
O14 Ag1 O2 98.93(10) 1_455 2_566 ?
O1 Ag1 Ag7 49.86(7) . 1_455 ?
O1 Ag1 Ag2 112.72(7) . 1_545 ?
O1 Ag1 Br1 145.54(8) . 2_566 ?
O1 Ag1 O14 99.37(10) . 1_455 ?
O1 Ag1 O2 89.79(10) . 2_566 ?
O2 Ag1 Ag7 121.93(7) 2_566 1_455 ?
O2 Ag1 Ag2 49.83(7) 2_566 1_545 ?
O2 Ag1 Br1 105.29(7) 2_566 2_566 ?
Ag9 Ag3 Ag6 122.687(17) 1_465 1_565 ?
Ag7 Ag3 Ag6 114.545(15) 1_465 1_565 ?
Ag7 Ag3 Ag9 97.602(17) 1_465 1_465 ?
O11 Ag3 Ag6 120.62(7) 2_677 1_565 ?
O11 Ag3 Ag9 56.39(8) 2_677 1_465 ?
O11 Ag3 Ag7 124.61(7) 2_677 1_465 ?
O11 Ag3 O16 82.06(12) 2_677 1_465 ?
O16 Ag3 Ag6 148.72(9) 1_465 1_565 ?
O16 Ag3 Ag9 49.38(8) 1_465 1_465 ?
O16 Ag3 Ag7 50.49(8) 1_465 1_465 ?
O10 Ag3 Ag6 62.72(8) . 1_565 ?
O10 Ag3 Ag9 92.20(7) . 1_465 ?
O10 Ag3 Ag7 66.97(8) . 1_465 ?
O10 Ag3 O11 146.01(10) . 2_677 ?
O10 Ag3 O16 86.36(12) . 1_465 ?
O6 Ag4 Br1 135.54(8) . . ?
O6 Ag4 O8 70.29(10) . . ?
O6 Ag4 O12 78.79(10) . . ?
O8 Ag4 Br1 129.11(7) . . ?
O12 Ag4 Br1 126.69(7) . . ?
O12 Ag4 O8 97.11(11) . . ?
O7 Ag6 Br1 113.53(8) . 2_666 ?
O15 Ag6 Br1 86.60(11) . 2_666 ?
O15 Ag6 O7 159.75(13) . . ?
O9 Ag9 Br1 88.10(7) 2_767 1_646 ?
O5 Ag9 Br1 106.70(7) 1_645 1_646 ?
O5 Ag9 O9 109.18(10) 1_645 2_767 ?
O5 Ag9 O16 113.70(12) 1_645 . ?
O16 Ag9 Br1 98.33(9) . 1_646 ?
O16 Ag9 O9 132.42(12) . 2_767 ?
O16 Ag8 O16 180.0 . 2_757 ?
O16 Ag7 O1 128.30(12) . 1_655 ?
O15 Ag7 O1 121.75(11) . 1_655 ?
O15 Ag7 O16 97.06(13) . . ?
O14 Ag5 O14 180.0 . 2_666 ?
O14 Ag5 O7 122.61(10) 2_666 2_666 ?
O14 Ag5 O7 57.39(10) 2_666 . ?
O14 Ag5 O7 122.61(10) . . ?
O14 Ag5 O7 57.39(10) . 2_666 ?
O7 Ag5 O7 180.0 2_666 . ?
O3 Ag2 Br1 102.11(8) . 2_576 ?
O3 Ag2 O2 151.48(11) . 2_576 ?
O2 Ag2 Br1 101.82(7) 2_576 2_576 ?
Ag1 Br1 Ag6 76.006(17) 2_566 2_666 ?
Ag1 Br1 Ag9 132.64(2) 2_566 1_464 ?
Ag1 Br1 Ag2 65.435(16) 2_566 2_576 ?
Ag4 Br1 Ag1 104.47(2) . 2_566 ?
Ag4 Br1 Ag6 113.60(2) . 2_666 ?
Ag4 Br1 Ag9 122.24(2) . 1_464 ?
Ag4 Br1 Ag2 90.35(2) . 2_576 ?
Ag9 Br1 Ag6 78.525(16) 1_464 2_666 ?
Ag9 Br1 Ag2 117.57(2) 1_464 2_576 ?
Ag2 Br1 Ag6 138.81(2) 2_576 2_666 ?
B4 O6 Ag4 123.2(3) . . ?
B4 O6 B2 128.2(3) . . ?
B2 O6 Ag4 106.2(2) . . ?
Ag5 O14 Ag1 95.66(11) . 1_655 ?
B6 O14 Ag1 108.3(2) 2_676 1_655 ?
B6 O14 Ag5 101.2(2) 2_676 . ?
B8 O14 Ag1 106.7(2) . 1_655 ?
B8 O14 Ag5 120.8(3) . . ?
B8 O14 B6 121.0(3) . 2_676 ?
Ag6 O7 Ag5 79.81(9) . . ?
B2 O7 Ag6 108.2(2) . . ?
B2 O7 Ag5 140.2(3) . . ?
B6 O7 Ag6 113.8(2) 1_545 . ?
B6 O7 Ag5 91.3(2) 1_545 . ?
B6 O7 B2 118.0(3) 1_545 . ?
B5 O9 Ag9 114.2(3) . 2_767 ?
B5 O9 B4 128.0(3) . . ?
B4 O9 Ag9 98.1(2) . 2_767 ?
B2 O3 Ag2 112.0(3) . . ?
B1 O3 Ag2 127.4(3) . . ?
B1 O3 B2 120.3(3) . . ?
B5 O8 Ag4 131.8(3) . . ?
B5 O8 B8 123.7(4) . 2_676 ?
B8 O8 Ag4 104.4(2) 2_676 . ?
Ag1 O1 Ag7 82.97(10) . 1_455 ?
B1 O1 Ag1 108.3(2) . . ?
B1 O1 Ag7 102.8(2) . 1_455 ?
B6 O1 Ag1 117.7(3) 1_545 . ?
B6 O1 Ag7 111.4(2) 1_545 1_455 ?
B6 O1 B1 124.7(3) 1_545 . ?
Ag2 O2 Ag1 76.09(9) 2_576 2_566 ?
B1 O2 Ag1 105.9(2) . 2_566 ?
B1 O2 Ag2 122.1(3) . 2_576 ?
B8 O2 Ag1 114.8(2) 1_455 2_566 ?
B8 O2 Ag2 104.9(2) 1_455 2_576 ?
B8 O2 B1 123.5(3) 1_455 . ?
B7 O11 Ag3 117.9(3) . 2_677 ?
B7 O11 B4 134.3(4) . . ?
B4 O11 Ag3 104.0(2) . 2_677 ?
B4 O5 Ag9 106.0(2) . 1_465 ?
B3 O5 Ag9 117.2(3) . 1_465 ?
B3 O5 B4 122.8(3) . . ?
Ag3 O16 H16 98(5) 1_645 . ?
Ag9 O16 Ag3 78.10(11) . 1_645 ?
Ag9 O16 H16 92(5) . . ?
Ag8 O16 Ag3 152.39(19) . 1_645 ?
Ag8 O16 Ag9 85.88(13) . . ?
Ag8 O16 Ag7 110.20(16) . . ?
Ag8 O16 H16 105(5) . . ?
Ag7 O16 Ag3 73.99(11) . 1_645 ?
Ag7 O16 Ag9 145.17(18) . . ?
Ag7 O16 H16 112(5) . . ?
B7 O12 Ag4 128.7(3) . . ?
B7 O12 B8 122.9(4) . . ?
B8 O12 Ag4 107.8(2) . . ?
Ag6 O15 Ag7 125.73(15) . . ?
B3 O15 Ag6 119.2(3) 2_667 . ?
B3 O15 Ag7 112.4(3) 2_667 . ?
B7 O13 B1 124.6(3) . 1_655 ?
B5 O10 Ag3 119.4(3) . . ?
B5 O10 B6 123.0(3) . . ?
B6 O10 Ag3 117.5(2) . . ?
B3 O4 B2 123.2(4) . . ?
O9 B5 O8 121.4(4) . . ?
O10 B5 O9 118.4(4) . . ?
O10 B5 O8 120.3(4) . . ?
O11 B7 O12 121.7(4) . . ?
O13 B7 O11 118.0(4) . . ?
O13 B7 O12 120.3(4) . . ?
O6 B4 O9 113.0(3) . . ?
O6 B4 O11 114.8(4) . . ?
O6 B4 O5 111.9(4) . . ?
O11 B4 O9 106.0(4) . . ?
O5 B4 O9 105.4(3) . . ?
O5 B4 O11 104.9(3) . . ?
O6 B2 O7 109.3(4) . . ?
O6 B2 O3 108.9(3) . . ?
O6 B2 O4 111.9(4) . . ?
O3 B2 O7 107.8(3) . . ?
O3 B2 O4 111.6(4) . . ?
O4 B2 O7 107.3(3) . . ?
O3 B1 O1 109.6(3) . . ?
O3 B1 O2 109.4(4) . . ?
O3 B1 O13 110.6(4) . 1_455 ?
O2 B1 O1 110.8(4) . . ?
O2 B1 O13 110.1(3) . 1_455 ?
O13 B1 O1 106.2(3) 1_455 . ?
O14 B6 O10 110.2(3) 2_676 . ?
O7 B6 O14 106.7(3) 1_565 2_676 ?
O7 B6 O1 111.2(3) 1_565 1_565 ?
O7 B6 O10 108.3(3) 1_565 . ?
O1 B6 O14 112.7(3) 1_565 2_676 ?
O1 B6 O10 107.7(3) 1_565 . ?
O14 B8 O8 109.8(4) . 2_676 ?
O14 B8 O2 113.8(4) . 1_655 ?
O14 B8 O12 108.8(4) . . ?
O2 B8 O8 107.6(4) 1_655 2_676 ?
O2 B8 O12 110.5(4) 1_655 . ?
O12 B8 O8 106.1(3) . 2_676 ?
O15 B3 O5 121.6(4) 2_667 . ?
O15 B3 O4 117.8(4) 2_667 . ?
O4 B3 O5 120.5(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O14 B8 O8 165.0(3) 1_655 . . 2_676 ?
Ag1 O14 B8 O2 44.4(4) 1_655 . . 1_655 ?
Ag1 O14 B8 O12 -79.3(3) 1_655 . . . ?
Ag1 O1 B1 O3 -169.7(3) . . . . ?
Ag1 O1 B1 O2 -48.8(4) . . . . ?
Ag1 O1 B1 O13 70.8(3) . . . 1_455 ?
Ag1 O2 B1 O3 76.2(3) 2_566 . . . ?
Ag1 O2 B1 O1 -44.8(4) 2_566 . . . ?
Ag1 O2 B1 O13 -162.0(3) 2_566 . . 1_455 ?
Ag3 O11 B7 O12 154.0(3) 2_677 . . . ?
Ag3 O11 B7 O13 -25.6(5) 2_677 . . . ?
Ag3 O11 B4 O6 -133.8(3) 2_677 . . . ?
Ag3 O11 B4 O9 100.7(3) 2_677 . . . ?
Ag3 O11 B4 O5 -10.6(3) 2_677 . . . ?
Ag3 O10 B5 O9 1.1(6) . . . . ?
Ag3 O10 B5 O8 -179.6(3) . . . . ?
Ag3 O10 B6 O14 162.3(2) . . . 2_676 ?
Ag3 O10 B6 O7 46.0(4) . . . 1_565 ?
Ag3 O10 B6 O1 -74.3(4) . . . 1_565 ?
Ag4 O6 B4 O9 70.7(4) . . . . ?
Ag4 O6 B4 O11 -51.0(5) . . . . ?
Ag4 O6 B4 O5 -170.4(2) . . . . ?
Ag4 O6 B2 O7 56.5(3) . . . . ?
Ag4 O6 B2 O3 -61.0(4) . . . . ?
Ag4 O6 B2 O4 175.2(3) . . . . ?
Ag4 O8 B5 O9 2.2(7) . . . . ?
Ag4 O8 B5 O10 -177.0(3) . . . . ?
Ag4 O12 B7 O11 8.0(6) . . . . ?
Ag4 O12 B7 O13 -172.4(3) . . . . ?
Ag4 O12 B8 O14 -80.8(3) . . . . ?
Ag4 O12 B8 O8 37.3(4) . . . 2_676 ?
Ag4 O12 B8 O2 153.7(3) . . . 1_655 ?
Ag6 O7 B2 O6 60.4(4) . . . . ?
Ag6 O7 B2 O3 178.6(3) . . . . ?
Ag6 O7 B2 O4 -61.1(4) . . . . ?
Ag9 O9 B5 O8 113.6(4) 2_767 . . . ?
Ag9 O9 B5 O10 -67.1(5) 2_767 . . . ?
Ag9 O9 B4 O6 -154.3(3) 2_767 . . . ?
Ag9 O9 B4 O11 -27.7(3) 2_767 . . . ?
Ag9 O9 B4 O5 83.2(3) 2_767 . . . ?
Ag9 O5 B4 O6 -132.3(3) 1_465 . . . ?
Ag9 O5 B4 O9 -9.0(3) 1_465 . . . ?
Ag9 O5 B4 O11 102.6(3) 1_465 . . . ?
Ag9 O5 B3 O15 -53.7(5) 1_465 . . 2_667 ?
Ag9 O5 B3 O4 128.7(4) 1_465 . . . ?
Ag7 O1 B1 O3 103.6(3) 1_455 . . . ?
Ag7 O1 B1 O2 -135.5(3) 1_455 . . . ?
Ag7 O1 B1 O13 -16.0(3) 1_455 . . 1_455 ?
Ag5 O14 B8 O8 -87.6(4) . . . 2_676 ?
Ag5 O14 B8 O2 151.8(3) . . . 1_655 ?
Ag5 O14 B8 O12 28.1(4) . . . . ?
Ag5 O7 B2 O6 -35.6(6) . . . . ?
Ag5 O7 B2 O3 82.6(5) . . . . ?
Ag5 O7 B2 O4 -157.1(3) . . . . ?
Ag2 O3 B2 O6 -11.5(4) . . . . ?
Ag2 O3 B2 O7 -129.9(3) . . . . ?
Ag2 O3 B2 O4 112.5(3) . . . . ?
Ag2 O3 B1 O1 165.7(2) . . . . ?
Ag2 O3 B1 O2 43.9(5) . . . . ?
Ag2 O3 B1 O13 -77.6(4) . . . 1_455 ?
Ag2 O2 B1 O3 -7.1(5) 2_576 . . . ?
Ag2 O2 B1 O1 -128.1(3) 2_576 . . . ?
Ag2 O2 B1 O13 114.7(3) 2_576 . . 1_455 ?
B5 O9 B4 O6 -24.8(6) . . . . ?
B5 O9 B4 O11 101.8(5) . . . . ?
B5 O9 B4 O5 -147.3(4) . . . . ?
B5 O10 B6 O14 -13.2(6) . . . 2_676 ?
B5 O10 B6 O7 -129.5(4) . . . 1_565 ?
B5 O10 B6 O1 110.1(4) . . . 1_565 ?
B7 O11 B4 O6 22.8(7) . . . . ?
B7 O11 B4 O9 -102.7(5) . . . . ?
B7 O11 B4 O5 146.0(4) . . . . ?
B7 O12 B8 O14 107.0(4) . . . . ?
B7 O12 B8 O8 -135.0(4) . . . 2_676 ?
B7 O12 B8 O2 -18.6(6) . . . 1_655 ?
B4 O6 B2 O7 -105.9(4) . . . . ?
B4 O6 B2 O3 136.5(4) . . . . ?
B4 O6 B2 O4 12.8(6) . . . . ?
B4 O9 B5 O8 -9.5(7) . . . . ?
B4 O9 B5 O10 169.7(4) . . . . ?
B4 O11 B7 O12 -0.2(8) . . . . ?
B4 O11 B7 O13 -179.7(4) . . . . ?
B4 O5 B3 O15 172.0(4) . . . 2_667 ?
B4 O5 B3 O4 -5.7(6) . . . . ?
B2 O6 B4 O9 -129.5(4) . . . . ?
B2 O6 B4 O11 108.7(5) . . . . ?
B2 O6 B4 O5 -10.7(6) . . . . ?
B2 O3 B1 O1 -20.1(5) . . . . ?
B2 O3 B1 O2 -141.8(4) . . . . ?
B2 O3 B1 O13 96.7(4) . . . 1_455 ?
B2 O4 B3 O5 8.1(6) . . . . ?
B2 O4 B3 O15 -169.6(4) . . . 2_667 ?
B1 O3 B2 O6 173.5(3) . . . . ?
B1 O3 B2 O7 55.0(5) . . . . ?
B1 O3 B2 O4 -62.6(5) . . . . ?
B1 O13 B7 O11 -169.7(4) 1_655 . . . ?
B1 O13 B7 O12 10.7(7) 1_655 . . . ?
B6 O14 B8 O8 40.8(5) 2_676 . . 2_676 ?
B6 O14 B8 O2 -79.8(5) 2_676 . . 1_655 ?
B6 O14 B8 O12 156.5(3) 2_676 . . . ?
B6 O7 B2 O6 -168.6(3) 1_545 . . . ?
B6 O7 B2 O3 -50.3(5) 1_545 . . . ?
B6 O7 B2 O4 69.9(4) 1_545 . . . ?
B6 O1 B1 O3 -24.2(5) 1_545 . . . ?
B6 O1 B1 O2 96.7(4) 1_545 . . . ?
B6 O1 B1 O13 -143.7(4) 1_545 . . 1_455 ?
B6 O10 B5 O9 176.6(4) . . . . ?
B6 O10 B5 O8 -4.2(7) . . . . ?
B8 O8 B5 O9 179.2(4) 2_676 . . . ?
B8 O8 B5 O10 0.0(7) 2_676 . . . ?
B8 O2 B1 O3 -148.4(4) 1_455 . . . ?
B8 O2 B1 O1 90.6(5) 1_455 . . . ?
B8 O2 B1 O13 -26.6(5) 1_455 . . 1_455 ?
B8 O12 B7 O11 178.5(4) . . . . ?
B8 O12 B7 O13 -1.9(6) . . . . ?
B3 O5 B4 O6 6.3(5) . . . . ?
B3 O5 B4 O9 129.6(4) . . . . ?
B3 O5 B4 O11 -118.8(4) . . . . ?
B3 O4 B2 O6 -10.8(6) . . . . ?
B3 O4 B2 O7 109.1(4) . . . . ?
B3 O4 B2 O3 -133.0(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_9771
_database_code_depnum_ccdc_archive 'CCDC 2289394'
loop_
_audit_author_name
_audit_author_address
'Ru-Ling Tang'
;YangZhou University
China
;
_audit_update_record             
;
2023-08-18 deposited with the CCDC.	2024-07-02 downloaded from the CCDC.
;
_audit_creation_date             2023-06-26
_audit_creation_method           
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        4
_chemical_formula_moiety         'Ag11 B8 I3 O16'
_chemical_formula_sum            'Ag11 B8 I3 O16'
_chemical_formula_weight         1909.75
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   13.4121(5)
_cell_length_b                   12.5734(4)
_cell_length_c                   25.1948(9)
_cell_angle_alpha                90
_cell_angle_beta                 93.0620(10)
_cell_angle_gamma                90
_cell_volume                     4242.7(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9873
_cell_measurement_temperature    296
_cell_measurement_theta_max      27.53
_cell_measurement_theta_min      2.34
_shelx_estimated_absorpt_T_max   0.328
_shelx_estimated_absorpt_T_min   0.222
_exptl_absorpt_coefficient_mu    14.354
_exptl_absorpt_correction_T_max  0.5208
_exptl_absorpt_correction_T_min  0.3473
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0574 before and 0.0422 after correction.
The Ratio of minimum to maximum transmission is 0.6669.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light green'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    5.980
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             6752
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0275
_diffrn_reflns_av_unetI/netI     0.0182
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            32864
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.534
_diffrn_reflns_theta_min         1.619
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4403
_reflns_number_total             4866
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.799
_refine_diff_density_min         -1.877
_refine_diff_density_rms         0.166
_refine_ls_extinction_coef       0.000192(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     354
_refine_ls_number_reflns         4866
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0272
_refine_ls_R_factor_gt           0.0219
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0084P)²+61.4357P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0398
_refine_ls_wR_factor_ref         0.0413
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 Ag12-O16 \\sim Ag11-O16
 with sigma of 0.02
2. Others
 Sof(Ag11)=1-FVAR(1)
 Sof(Ag12)=FVAR(1)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
I3 I 0.62553(2) 0.27502(2) 0.69628(2) 0.01664(7) Uani 1 1 d . . . . .
I2 I 0.79572(2) 0.40825(3) 0.44359(2) 0.02245(8) Uani 1 1 d . . . . .
I1 I 0.65475(2) 0.66050(3) 0.35383(2) 0.02306(8) Uani 1 1 d . . . . .
Ag10 Ag 0.30999(3) 0.73311(3) 0.79719(2) 0.01999(9) Uani 1 1 d . . . . .
Ag5 Ag 0.80313(3) 0.39217(3) 0.71375(2) 0.01820(8) Uani 1 1 d . . . . .
Ag1 Ag 0.81621(3) 0.70068(3) 0.41914(2) 0.02347(9) Uani 1 1 d . . . . .
Ag9 Ag 0.59740(3) 0.48069(3) 0.72057(2) 0.02466(9) Uani 1 1 d . . . . .
Ag7 Ag 0.60734(3) 0.34888(4) 0.46869(2) 0.03020(11) Uani 1 1 d . . . . .
Ag8 Ag 0.35936(3) 0.37163(3) 0.51684(2) 0.02885(10) Uani 1 1 d . . . . .
Ag3 Ag 1.02760(3) 0.71478(3) 0.59752(2) 0.03113(11) Uani 1 1 d . . . . .
Ag4 Ag 1.10378(4) 0.64138(3) 0.78437(2) 0.03419(11) Uani 1 1 d . . . . .
Ag2 Ag 1.03172(3) 0.62492(4) 0.48423(2) 0.03544(12) Uani 1 1 d . . . . .
Ag6 Ag 0.75930(3) 0.29870(3) 0.58310(3) 0.04353(14) Uani 1 1 d . . . . .
Ag12 Ag 0.2420(3) 0.5446(4) 0.6690(2) 0.0378(8) Uani 0.66(2) 1 d D . P A 1
O13 O 0.4900(2) 0.5964(2) 0.67091(12) 0.0144(7) Uani 1 1 d . . . . .
O8 O 0.6493(2) 0.6095(2) 0.63343(12) 0.0136(6) Uani 1 1 d . . . . .
O4 O 0.8043(2) 0.5146(2) 0.63865(12) 0.0107(6) Uani 1 1 d . . . . .
O9 O 0.6641(2) 0.4463(2) 0.58526(13) 0.0130(6) Uani 1 1 d . . . . .
O14 O 0.4179(2) 0.8841(2) 0.60117(12) 0.0101(6) Uani 1 1 d . . . . .
O5 O 1.0231(2) 0.5210(2) 0.83634(12) 0.0126(6) Uani 1 1 d . . . . .
O3 O 0.7496(2) 0.6015(3) 0.55584(12) 0.0133(6) Uani 1 1 d . . . . .
O1 O 0.8752(2) 0.6713(3) 0.50145(13) 0.0177(7) Uani 1 1 d . . . . .
O7 O 0.8835(2) 0.4914(3) 0.77682(13) 0.0171(7) Uani 1 1 d . . . . .
O2 O 0.9229(2) 0.5663(2) 0.57482(12) 0.0123(6) Uani 1 1 d . . . . .
O12 O 0.5113(2) 0.7224(2) 0.59953(12) 0.0112(6) Uani 1 1 d . . . . .
O10 O 0.5215(2) 0.3658(2) 0.54278(13) 0.0149(7) Uani 1 1 d . . . . .
O11 O 0.5088(2) 0.5369(2) 0.58145(13) 0.0149(7) Uani 1 1 d . . . . .
O15 O 0.4021(2) 0.7594(2) 0.67073(13) 0.0168(7) Uani 1 1 d . . . . .
O6 O 0.9433(2) 0.3532(2) 0.83447(14) 0.0174(7) Uani 1 1 d . . . . .
O16 O 0.3602(2) 0.6238(3) 0.73033(13) 0.0159(7) Uani 1 1 d D . . . .
B1 B 0.8475(4) 0.6134(4) 0.5430(2) 0.0109(9) Uani 1 1 d . . . . .
B5 B 0.5635(4) 0.4487(4) 0.5696(2) 0.0109(9) Uani 1 1 d . . . . .
B6 B 0.5422(4) 0.6172(4) 0.6215(2) 0.0106(9) Uani 1 1 d . . . . .
B7 B 0.4728(4) 0.8040(4) 0.6339(2) 0.0105(9) Uani 1 1 d . . . . .
B8 B 0.4180(4) 0.6591(4) 0.69155(19) 0.0114(10) Uani 1 1 d . . . . .
B3 B 0.7177(3) 0.5436(4) 0.60497(19) 0.0094(9) Uani 1 1 d . . . . .
B4 B 0.9492(4) 0.4548(4) 0.8151(2) 0.0120(10) Uani 1 1 d . . . . .
B2 B 0.9038(3) 0.4946(4) 0.61941(19) 0.0086(9) Uani 1 1 d . . . . .
Ag11 Ag 0.2577(6) 0.5143(11) 0.6853(6) 0.047(2) Uani 0.34(2) 1 d D . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
I3 Ag9 2.6886(5) . ?
I3 Ag3 2.8532(5) 3_445 ?
I3 Ag4 2.8113(5) 3_445 ?
I2 Ag7 2.7408(6) . ?
I2 Ag3 3.0566(6) 5_766 ?
I2 Ag2 2.8962(6) 5_766 ?
I2 Ag6 2.7775(5) 7_656 ?
I2 Ag12 2.916(7) 5_666 ?
I1 Ag10 2.9118(5) 8_565 ?
I1 Ag1 2.6965(5) . ?
I1 Ag3 3.2036(6) 7_666 ?
I1 Ag4 3.0997(6) 8_465 ?
I1 Ag12 2.997(5) 5_666 ?
I1 Ag11 2.703(9) 5_666 ?
Ag10 I1 2.9118(5) 8_466 ?
Ag10 Ag5 2.8995(5) 3_455 ?
Ag10 Ag1 3.1800(5) 8_466 ?
Ag10 Ag4 2.9980(6) 1_455 ?
Ag10 O8 2.381(3) 2_656 ?
Ag10 O6 2.486(3) 3_455 ?
Ag10 O16 2.303(3) . ?
Ag5 Ag10 2.8995(5) 3_545 ?
Ag5 Ag4 3.3724(6) 2_756 ?
Ag5 O4 2.440(3) . ?
Ag5 O7 2.249(3) . ?
Ag5 O15 2.424(3) 3_545 ?
Ag5 Ag11 3.117(17) 2_656 ?
Ag1 Ag10 3.1800(5) 8_565 ?
Ag1 Ag8 3.2957(6) 3 ?
Ag1 Ag8 3.0626(6) 5_666 ?
Ag1 O1 2.211(3) . ?
Ag1 O12 2.575(3) 7_666 ?
Ag9 Ag9 3.0724(8) 2_656 ?
Ag9 O13 2.359(3) . ?
Ag9 O16 2.240(3) 2_656 ?
Ag9 Ag11 3.014(17) 2_656 ?
Ag7 Ag2 3.0255(7) 3_445 ?
Ag7 Ag6 2.9316(6) 7_656 ?
Ag7 O12 2.449(3) 5_666 ?
Ag7 O10 2.255(3) . ?
Ag7 O11 2.424(3) 5_666 ?
Ag8 Ag1 3.2957(6) 3_445 ?
Ag8 Ag1 3.0625(6) 5_666 ?
Ag8 O3 2.306(3) 5_666 ?
Ag8 O1 2.559(3) 3_445 ?
Ag8 O10 2.239(3) . ?
Ag3 I3 2.8532(5) 3 ?
Ag3 I2 3.0565(6) 5_766 ?
Ag3 I1 3.2036(6) 7_666 ?
Ag3 Ag6 3.3201(7) 3 ?
Ag3 O2 2.387(3) . ?
Ag3 O10 2.346(3) 3 ?
Ag4 I3 2.8112(5) 3 ?
Ag4 I1 3.0997(6) 8_566 ?
Ag4 Ag10 2.9980(6) 1_655 ?
Ag4 Ag5 3.3724(6) 2_756 ?
Ag4 Ag4 3.1991(10) 2_756 ?
Ag4 O5 2.308(3) . ?
Ag4 O7 2.447(3) 2_756 ?
Ag2 I2 2.8962(6) 5_766 ?
Ag2 Ag7 3.0255(7) 3 ?
Ag2 Ag2 3.3609(10) 5_766 ?
Ag2 O14 2.292(3) 7_666 ?
Ag2 O1 2.243(3) . ?
Ag6 I2 2.7774(5) 7_656 ?
Ag6 Ag7 2.9316(6) 7_656 ?
Ag6 Ag3 3.3200(7) 3_445 ?
Ag6 O9 2.255(3) . ?
Ag6 O14 2.404(3) 3_545 ?
Ag12 I2 2.916(7) 5_666 ?
Ag12 I1 2.997(5) 5_666 ?
Ag12 O7 2.321(4) 2_656 ?
Ag12 O16 2.372(5) . ?
O13 B6 1.483(6) . ?
O13 B8 1.371(6) . ?
O8 Ag10 2.381(3) 2_656 ?
O8 B6 1.455(6) . ?
O8 B3 1.453(6) . ?
O4 B3 1.449(5) . ?
O4 B2 1.465(5) . ?
O9 B5 1.386(6) . ?
O9 B3 1.489(6) . ?
O14 Ag2 2.292(3) 7_666 ?
O14 Ag6 2.404(3) 3_455 ?
O14 B7 1.473(6) . ?
O14 B2 1.479(5) 3_455 ?
O5 B4 1.380(6) . ?
O5 B2 1.482(5) 2_756 ?
O3 Ag8 2.306(3) 5_666 ?
O3 B1 1.377(6) . ?
O3 B3 1.517(6) . ?
O1 Ag8 2.559(3) 3 ?
O1 B1 1.343(6) . ?
O7 Ag4 2.447(3) 2_756 ?
O7 Ag12 2.321(4) 2_656 ?
O7 B4 1.353(6) . ?
O7 Ag11 2.184(6) 2_656 ?
O2 B1 1.390(6) . ?
O2 B2 1.473(6) . ?
O12 Ag1 2.575(3) 7_666 ?
O12 Ag7 2.449(3) 5_666 ?
O12 B6 1.485(6) . ?
O12 B7 1.454(6) . ?
O10 Ag3 2.346(3) 3_445 ?
O10 B5 1.349(6) . ?
O11 Ag7 2.424(3) 5_666 ?
O11 B5 1.371(6) . ?
O11 B6 1.480(6) . ?
O15 Ag5 2.424(3) 3_455 ?
O15 B7 1.473(6) . ?
O15 B8 1.378(6) . ?
O6 Ag10 2.486(3) 3_545 ?
O6 B7 1.480(6) 4_646 ?
O6 B4 1.371(6) . ?
O16 Ag9 2.239(3) 2_656 ?
O16 B8 1.355(6) . ?
O16 Ag11 2.214(5) . ?
B7 O6 1.480(6) 4_656 ?
B2 O14 1.479(5) 3_545 ?
B2 O5 1.482(5) 2_756 ?
Ag11 I1 2.703(9) 5_666 ?
Ag11 Ag5 3.117(17) 2_656 ?
Ag11 Ag9 3.014(17) 2_656 ?
Ag11 O7 2.184(6) 2_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag9 I3 Ag3 112.962(16) . 3_445 ?
Ag9 I3 Ag4 111.931(17) . 3_445 ?
Ag4 I3 Ag3 117.872(16) 3_445 3_445 ?
Ag7 I2 Ag3 132.942(17) . 5_766 ?
Ag7 I2 Ag2 122.104(18) . 5_766 ?
Ag7 I2 Ag6 64.177(16) . 7_656 ?
Ag7 I2 Ag12 99.54(4) . 5_666 ?
Ag2 I2 Ag3 62.095(13) 5_766 5_766 ?
Ag2 I2 Ag12 137.02(6) 5_766 5_666 ?
Ag6 I2 Ag3 69.182(14) 7_656 5_766 ?
Ag6 I2 Ag2 102.135(18) 7_656 5_766 ?
Ag6 I2 Ag12 85.70(8) 7_656 5_666 ?
Ag12 I2 Ag3 82.57(9) 5_666 5_766 ?
Ag10 I1 Ag3 122.896(16) 8_565 7_666 ?
Ag10 I1 Ag4 59.732(14) 8_565 8_465 ?
Ag10 I1 Ag12 87.21(7) 8_565 5_666 ?
Ag1 I1 Ag10 68.963(14) . 8_565 ?
Ag1 I1 Ag3 106.230(16) . 7_666 ?
Ag1 I1 Ag4 109.855(17) . 8_465 ?
Ag1 I1 Ag12 85.08(8) . 5_666 ?
Ag1 I1 Ag11 91.4(2) . 5_666 ?
Ag4 I1 Ag3 70.900(13) 8_465 7_666 ?
Ag12 I1 Ag3 149.84(6) 5_666 7_666 ?
Ag12 I1 Ag4 132.31(12) 5_666 8_465 ?
Ag11 I1 Ag10 81.9(2) 5_666 8_565 ?
Ag11 I1 Ag3 153.25(11) 5_666 7_666 ?
Ag11 I1 Ag4 122.3(4) 5_666 8_465 ?
I1 Ag10 Ag1 52.321(11) 8_466 8_466 ?
I1 Ag10 Ag4 63.249(14) 8_466 1_455 ?
Ag5 Ag10 I1 92.442(14) 3_455 8_466 ?
Ag5 Ag10 Ag1 121.209(16) 3_455 8_466 ?
Ag5 Ag10 Ag4 101.176(16) 3_455 1_455 ?
Ag4 Ag10 Ag1 100.443(16) 1_455 8_466 ?
O8 Ag10 I1 94.71(8) 2_656 8_466 ?
O8 Ag10 Ag5 168.49(7) 2_656 3_455 ?
O8 Ag10 Ag1 57.89(8) 2_656 8_466 ?
O8 Ag10 Ag4 90.11(7) 2_656 1_455 ?
O8 Ag10 O6 89.27(11) 2_656 3_455 ?
O6 Ag10 I1 93.12(8) 3_455 8_466 ?
O6 Ag10 Ag5 81.33(8) 3_455 3_455 ?
O6 Ag10 Ag1 59.65(8) 3_455 8_466 ?
O6 Ag10 Ag4 156.23(8) 3_455 1_455 ?
O16 Ag10 I1 151.33(8) . 8_466 ?
O16 Ag10 Ag5 83.14(8) . 3_455 ?
O16 Ag10 Ag1 150.41(8) . 8_466 ?
O16 Ag10 Ag4 89.74(8) . 1_455 ?
O16 Ag10 O8 94.74(11) . 2_656 ?
O16 Ag10 O6 114.00(12) . 3_455 ?
Ag10 Ag5 Ag4 129.293(16) 3_545 2_756 ?
Ag10 Ag5 Ag11 75.39(8) 3_545 2_656 ?
O4 Ag5 Ag10 174.98(7) . 3_545 ?
O4 Ag5 Ag4 53.63(7) . 2_756 ?
O4 Ag5 Ag11 109.56(11) . 2_656 ?
O7 Ag5 Ag10 82.82(9) . 3_545 ?
O7 Ag5 Ag4 46.50(8) . 2_756 ?
O7 Ag5 O4 100.09(11) . . ?
O7 Ag5 O15 116.40(12) . 3_545 ?
O7 Ag5 Ag11 44.5(2) . 2_656 ?
O15 Ag5 Ag10 81.51(7) 3_545 3_545 ?
O15 Ag5 Ag4 115.77(8) 3_545 2_756 ?
O15 Ag5 O4 93.51(10) 3_545 . ?
O15 Ag5 Ag11 151.35(14) 3_545 2_656 ?
Ag11 Ag5 Ag4 69.12(18) 2_656 2_756 ?
I1 Ag1 Ag10 58.719(12) . 8_565 ?
I1 Ag1 Ag8 132.938(18) . 3 ?
I1 Ag1 Ag8 69.559(14) . 5_666 ?
Ag10 Ag1 Ag8 123.050(16) 8_565 3 ?
Ag8 Ag1 Ag10 127.257(16) 5_666 8_565 ?
Ag8 Ag1 Ag8 84.808(15) 5_666 3 ?
O1 Ag1 I1 140.94(8) . . ?
O1 Ag1 Ag10 159.99(8) . 8_565 ?
O1 Ag1 Ag8 72.72(8) . 5_666 ?
O1 Ag1 Ag8 50.85(9) . 3 ?
O1 Ag1 O12 87.37(11) . 7_666 ?
O12 Ag1 I1 131.24(7) 7_666 . ?
O12 Ag1 Ag10 72.69(7) 7_666 8_565 ?
O12 Ag1 Ag8 76.57(7) 7_666 3 ?
O12 Ag1 Ag8 158.70(7) 7_666 5_666 ?
I3 Ag9 Ag9 104.071(11) . 2_656 ?
I3 Ag9 Ag11 102.8(2) . 2_656 ?
O13 Ag9 I3 124.17(8) . . ?
O13 Ag9 Ag9 75.22(8) . 2_656 ?
O13 Ag9 Ag11 132.9(2) . 2_656 ?
O16 Ag9 I3 149.74(9) 2_656 . ?
O16 Ag9 Ag9 86.04(8) 2_656 2_656 ?
O16 Ag9 O13 85.84(12) 2_656 . ?
O16 Ag9 Ag11 47.1(2) 2_656 2_656 ?
Ag11 Ag9 Ag9 98.59(11) 2_656 2_656 ?
I2 Ag7 Ag2 127.074(18) . 3_445 ?
I2 Ag7 Ag6 58.518(14) . 7_656 ?
Ag6 Ag7 Ag2 71.649(17) 7_656 3_445 ?
O12 Ag7 I2 120.66(7) 5_666 . ?
O12 Ag7 Ag2 62.65(7) 5_666 3_445 ?
O12 Ag7 Ag6 81.07(7) 5_666 7_656 ?
O10 Ag7 I2 133.08(8) . . ?
O10 Ag7 Ag2 77.95(8) . 3_445 ?
O10 Ag7 Ag6 141.14(8) . 7_656 ?
O10 Ag7 O12 105.94(11) . 5_666 ?
O10 Ag7 O11 91.90(11) . 5_666 ?
O11 Ag7 I2 107.05(8) 5_666 . ?
O11 Ag7 Ag2 114.10(8) 5_666 3_445 ?
O11 Ag7 Ag6 122.25(8) 5_666 7_656 ?
O11 Ag7 O12 58.38(10) 5_666 5_666 ?
Ag1 Ag8 Ag1 95.188(15) 5_666 3_445 ?
O3 Ag8 Ag1 89.37(8) 5_666 5_666 ?
O3 Ag8 Ag1 54.83(8) 5_666 3_445 ?
O3 Ag8 O1 94.48(11) 5_666 3_445 ?
O1 Ag8 Ag1 42.06(7) 3_445 3_445 ?
O1 Ag8 Ag1 81.95(7) 3_445 5_666 ?
O10 Ag8 Ag1 109.02(8) . 3_445 ?
O10 Ag8 Ag1 126.79(8) . 5_666 ?
O10 Ag8 O3 143.27(11) . 5_666 ?
O10 Ag8 O1 85.69(11) . 3_445 ?
I3 Ag3 I2 95.782(16) 3 5_766 ?
I3 Ag3 I1 82.052(15) 3 7_666 ?
I3 Ag3 Ag6 67.736(15) 3 3 ?
I2 Ag3 I1 177.269(18) 5_766 7_666 ?
I2 Ag3 Ag6 51.440(12) 5_766 3 ?
I1 Ag3 Ag6 128.644(16) 7_666 3 ?
O2 Ag3 I3 130.85(7) . 3 ?
O2 Ag3 I2 88.84(7) . 5_766 ?
O2 Ag3 I1 91.32(7) . 7_666 ?
O2 Ag3 Ag6 139.85(7) . 3 ?
O10 Ag3 I3 107.33(8) 3 3 ?
O10 Ag3 I2 102.34(8) 3 5_766 ?
O10 Ag3 I1 79.95(8) 3 7_666 ?
O10 Ag3 Ag6 71.44(8) 3 3 ?
O10 Ag3 O2 119.38(11) 3 . ?
I3 Ag4 I1 86.349(14) 3 8_566 ?
I3 Ag4 Ag10 73.805(14) 3 1_655 ?
I3 Ag4 Ag5 120.829(17) 3 2_756 ?
I3 Ag4 Ag4 72.340(15) 3 2_756 ?
I1 Ag4 Ag5 131.950(19) 8_566 2_756 ?
I1 Ag4 Ag4 117.706(14) 8_566 2_756 ?
Ag10 Ag4 I1 57.018(12) 1_655 8_566 ?
Ag10 Ag4 Ag5 90.987(16) 1_655 2_756 ?
Ag10 Ag4 Ag4 146.040(19) 1_655 2_756 ?
Ag4 Ag4 Ag5 108.567(11) 2_756 2_756 ?
O5 Ag4 I3 155.70(8) . 3 ?
O5 Ag4 I1 107.62(8) . 8_566 ?
O5 Ag4 Ag10 130.44(8) . 1_655 ?
O5 Ag4 Ag5 64.34(8) . 2_756 ?
O5 Ag4 Ag4 83.48(8) . 2_756 ?
O5 Ag4 O7 84.42(11) . 2_756 ?
O7 Ag4 I3 87.11(8) 2_756 3 ?
O7 Ag4 I1 162.58(8) 2_756 8_566 ?
O7 Ag4 Ag10 105.61(8) 2_756 1_655 ?
O7 Ag4 Ag5 41.81(7) 2_756 2_756 ?
O7 Ag4 Ag4 75.35(7) 2_756 2_756 ?
I2 Ag2 Ag7 87.313(17) 5_766 3 ?
I2 Ag2 Ag2 85.459(19) 5_766 5_766 ?
Ag7 Ag2 Ag2 172.46(3) 3 5_766 ?
O14 Ag2 I2 108.45(7) 7_666 5_766 ?
O14 Ag2 Ag7 78.85(7) 7_666 3 ?
O14 Ag2 Ag2 105.49(8) 7_666 5_766 ?
O1 Ag2 I2 129.84(8) . 5_766 ?
O1 Ag2 Ag7 96.12(9) . 3 ?
O1 Ag2 Ag2 86.90(9) . 5_766 ?
O1 Ag2 O14 121.35(11) . 7_666 ?
I2 Ag6 Ag7 57.306(14) 7_656 7_656 ?
I2 Ag6 Ag3 59.377(13) 7_656 3_445 ?
Ag7 Ag6 Ag3 116.390(18) 7_656 3_445 ?
O9 Ag6 I2 129.31(8) . 7_656 ?
O9 Ag6 Ag7 153.04(9) . 7_656 ?
O9 Ag6 Ag3 74.02(8) . 3_445 ?
O9 Ag6 O14 97.13(10) . 3_545 ?
O14 Ag6 I2 133.24(7) 3_545 7_656 ?
O14 Ag6 Ag7 79.18(7) 3_545 7_656 ?
O14 Ag6 Ag3 160.90(7) 3_545 3_445 ?
I2 Ag12 I1 92.64(6) 5_666 5_666 ?
O7 Ag12 I2 122.5(2) 2_656 5_666 ?
O7 Ag12 I1 102.8(2) 2_656 5_666 ?
O7 Ag12 O16 102.6(2) 2_656 . ?
O16 Ag12 I2 128.6(2) . 5_666 ?
O16 Ag12 I1 100.8(2) . 5_666 ?
B6 O13 Ag9 104.5(2) . . ?
B8 O13 Ag9 125.2(3) . . ?
B8 O13 B6 126.2(4) . . ?
B6 O8 Ag10 107.0(2) . 2_656 ?
B3 O8 Ag10 127.5(3) . 2_656 ?
B3 O8 B6 125.3(3) . . ?
B3 O4 Ag5 125.1(3) . . ?
B3 O4 B2 124.4(3) . . ?
B2 O4 Ag5 101.1(2) . . ?
B5 O9 Ag6 123.7(3) . . ?
B5 O9 B3 121.5(3) . . ?
B3 O9 Ag6 114.9(2) . . ?
Ag2 O14 Ag6 95.89(11) 7_666 3_455 ?
B7 O14 Ag2 109.1(2) . 7_666 ?
B7 O14 Ag6 102.2(2) . 3_455 ?
B7 O14 B2 122.5(3) . 3_455 ?
B2 O14 Ag2 112.8(2) 3_455 7_666 ?
B2 O14 Ag6 110.6(2) 3_455 3_455 ?
B4 O5 Ag4 121.6(3) . . ?
B4 O5 B2 126.1(3) . 2_756 ?
B2 O5 Ag4 105.2(2) 2_756 . ?
B1 O3 Ag8 111.6(3) . 5_666 ?
B1 O3 B3 124.0(3) . . ?
B3 O3 Ag8 121.5(2) . 5_666 ?
Ag1 O1 Ag8 87.09(11) . 3 ?
Ag1 O1 Ag2 98.84(13) . . ?
Ag2 O1 Ag8 111.79(13) . 3 ?
B1 O1 Ag1 136.1(3) . . ?
B1 O1 Ag8 112.8(3) . 3 ?
B1 O1 Ag2 108.1(3) . . ?
Ag5 O7 Ag4 91.68(11) . 2_756 ?
Ag5 O7 Ag12 103.9(2) . 2_656 ?
Ag12 O7 Ag4 103.05(14) 2_656 2_756 ?
B4 O7 Ag5 125.8(3) . . ?
B4 O7 Ag4 130.3(3) . 2_756 ?
B4 O7 Ag12 98.3(3) . 2_656 ?
B4 O7 Ag11 106.3(4) . 2_656 ?
Ag11 O7 Ag5 89.3(6) 2_656 . ?
Ag11 O7 Ag4 105.38(17) 2_656 2_756 ?
B1 O2 Ag3 101.9(3) . . ?
B1 O2 B2 123.4(3) . . ?
B2 O2 Ag3 114.8(2) . . ?
Ag7 O12 Ag1 124.45(12) 5_666 7_666 ?
B6 O12 Ag1 99.6(2) . 7_666 ?
B6 O12 Ag7 95.4(2) . 5_666 ?
B7 O12 Ag1 101.2(2) . 7_666 ?
B7 O12 Ag7 116.0(2) . 5_666 ?
B7 O12 B6 120.5(3) . . ?
Ag7 O10 Ag3 114.03(13) . 3_445 ?
Ag8 O10 Ag7 107.00(13) . . ?
Ag8 O10 Ag3 101.59(12) . 3_445 ?
B5 O10 Ag7 105.7(3) . . ?
B5 O10 Ag8 119.6(3) . . ?
B5 O10 Ag3 109.3(3) . 3_445 ?
B5 O11 Ag7 134.6(3) . 5_666 ?
B5 O11 B6 123.7(3) . . ?
B6 O11 Ag7 96.5(2) . 5_666 ?
B7 O15 Ag5 114.0(3) . 3_455 ?
B8 O15 Ag5 122.5(3) . 3_455 ?
B8 O15 B7 119.8(4) . . ?
B7 O6 Ag10 117.4(3) 4_646 3_545 ?
B4 O6 Ag10 119.1(3) . 3_545 ?
B4 O6 B7 121.6(4) . 4_646 ?
Ag10 O16 Ag12 121.06(15) . . ?
Ag9 O16 Ag10 98.69(12) 2_656 . ?
Ag9 O16 Ag12 99.4(2) 2_656 . ?
B8 O16 Ag10 122.2(3) . . ?
B8 O16 Ag9 121.6(3) . 2_656 ?
B8 O16 Ag12 93.2(3) . . ?
B8 O16 Ag11 101.4(4) . . ?
Ag11 O16 Ag10 123.26(17) . . ?
Ag11 O16 Ag9 85.2(5) . 2_656 ?
O3 B1 O2 119.4(4) . . ?
O1 B1 O3 123.3(4) . . ?
O1 B1 O2 117.2(4) . . ?
O10 B5 O9 120.0(4) . . ?
O10 B5 O11 121.3(4) . . ?
O11 B5 O9 118.6(4) . . ?
O13 B6 O12 109.5(3) . . ?
O8 B6 O13 108.7(4) . . ?
O8 B6 O12 112.9(4) . . ?
O8 B6 O11 110.8(3) . . ?
O11 B6 O13 108.3(4) . . ?
O11 B6 O12 106.6(4) . . ?
O14 B7 O6 111.0(4) . 4_656 ?
O12 B7 O14 109.4(4) . . ?
O12 B7 O15 111.6(4) . . ?
O12 B7 O6 109.4(4) . 4_656 ?
O15 B7 O14 107.0(3) . . ?
O15 B7 O6 108.4(4) . 4_656 ?
O13 B8 O15 118.7(4) . . ?
O16 B8 O13 121.8(4) . . ?
O16 B8 O15 119.5(4) . . ?
O8 B3 O9 109.1(3) . . ?
O8 B3 O3 110.0(4) . . ?
O4 B3 O8 111.2(4) . . ?
O4 B3 O9 110.2(4) . . ?
O4 B3 O3 110.2(3) . . ?
O9 B3 O3 105.9(3) . . ?
O7 B4 O5 119.9(4) . . ?
O7 B4 O6 121.5(4) . . ?
O6 B4 O5 118.6(4) . . ?
O4 B2 O14 113.4(4) . 3_545 ?
O4 B2 O5 106.9(3) . 2_756 ?
O4 B2 O2 110.2(3) . . ?
O14 B2 O5 110.7(3) 3_545 2_756 ?
O2 B2 O14 107.9(3) . 3_545 ?
O2 B2 O5 107.5(3) . 2_756 ?
I1 Ag11 Ag5 92.0(5) 5_666 2_656 ?
I1 Ag11 Ag9 84.2(5) 5_666 2_656 ?
Ag9 Ag11 Ag5 58.3(4) 2_656 2_656 ?
O7 Ag11 I1 117.1(5) 2_656 5_666 ?
O7 Ag11 Ag5 46.2(3) 2_656 2_656 ?
O7 Ag11 Ag9 100.1(6) 2_656 2_656 ?
O7 Ag11 O16 112.7(3) 2_656 . ?
O16 Ag11 I1 115.0(4) . 5_666 ?
O16 Ag11 Ag5 94.0(5) . 2_656 ?
O16 Ag11 Ag9 47.8(3) . 2_656 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag10 O8 B6 O13 -56.9(4) 2_656 . . . ?
Ag10 O8 B6 O12 64.9(4) 2_656 . . . ?
Ag10 O8 B6 O11 -175.7(3) 2_656 . . . ?
Ag10 O8 B3 O4 31.4(5) 2_656 . . . ?
Ag10 O8 B3 O9 153.2(3) 2_656 . . . ?
Ag10 O8 B3 O3 -91.0(4) 2_656 . . . ?
Ag10 O6 B4 O5 179.6(3) 3_545 . . . ?
Ag10 O6 B4 O7 1.0(6) 3_545 . . . ?
Ag10 O16 B8 O13 143.7(3) . . . . ?
Ag10 O16 B8 O15 -38.7(5) . . . . ?
Ag5 O4 B3 O8 69.9(4) . . . . ?
Ag5 O4 B3 O9 -51.2(4) . . . . ?
Ag5 O4 B3 O3 -167.7(2) . . . . ?
Ag5 O4 B2 O14 62.0(3) . . . 3_545 ?
Ag5 O4 B2 O5 -60.2(3) . . . 2_756 ?
Ag5 O4 B2 O2 -176.8(3) . . . . ?
Ag5 O7 B4 O5 152.5(3) . . . . ?
Ag5 O7 B4 O6 -28.9(6) . . . . ?
Ag5 O15 B7 O14 -45.8(4) 3_455 . . . ?
Ag5 O15 B7 O12 -165.4(3) 3_455 . . . ?
Ag5 O15 B7 O6 74.0(4) 3_455 . . 4_656 ?
Ag5 O15 B8 O13 -167.3(3) 3_455 . . . ?
Ag5 O15 B8 O16 15.0(6) 3_455 . . . ?
Ag1 O1 B1 O3 -38.2(7) . . . . ?
Ag1 O1 B1 O2 143.6(3) . . . . ?
Ag1 O12 B6 O13 132.9(3) 7_666 . . . ?
Ag1 O12 B6 O8 11.6(4) 7_666 . . . ?
Ag1 O12 B6 O11 -110.2(3) 7_666 . . . ?
Ag1 O12 B7 O14 90.3(3) 7_666 . . . ?
Ag1 O12 B7 O15 -151.5(3) 7_666 . . . ?
Ag1 O12 B7 O6 -31.6(4) 7_666 . . 4_656 ?
Ag9 O13 B6 O8 -29.4(4) . . . . ?
Ag9 O13 B6 O12 -153.2(3) . . . . ?
Ag9 O13 B6 O11 91.0(3) . . . . ?
Ag9 O13 B8 O15 142.3(3) . . . . ?
Ag9 O13 B8 O16 -40.1(6) . . . . ?
Ag9 O16 B8 O13 17.1(6) 2_656 . . . ?
Ag9 O16 B8 O15 -165.3(3) 2_656 . . . ?
Ag7 O12 B6 O13 -100.8(3) 5_666 . . . ?
Ag7 O12 B6 O8 138.0(3) 5_666 . . . ?
Ag7 O12 B6 O11 16.1(3) 5_666 . . . ?
Ag7 O12 B7 O14 -47.3(4) 5_666 . . . ?
Ag7 O12 B7 O15 70.9(4) 5_666 . . . ?
Ag7 O12 B7 O6 -169.2(2) 5_666 . . 4_656 ?
Ag7 O10 B5 O9 -58.6(5) . . . . ?
Ag7 O10 B5 O11 120.6(4) . . . . ?
Ag7 O11 B5 O9 131.4(4) 5_666 . . . ?
Ag7 O11 B5 O10 -47.8(6) 5_666 . . . ?
Ag7 O11 B6 O13 101.4(3) 5_666 . . . ?
Ag7 O11 B6 O8 -139.5(3) 5_666 . . . ?
Ag7 O11 B6 O12 -16.4(3) 5_666 . . . ?
Ag8 O3 B1 O1 23.8(5) 5_666 . . . ?
Ag8 O3 B1 O2 -158.0(3) 5_666 . . . ?
Ag8 O3 B3 O8 -71.0(4) 5_666 . . . ?
Ag8 O3 B3 O4 166.0(2) 5_666 . . . ?
Ag8 O3 B3 O9 46.8(4) 5_666 . . . ?
Ag8 O1 B1 O3 72.7(5) 3 . . . ?
Ag8 O1 B1 O2 -105.4(4) 3 . . . ?
Ag8 O10 B5 O9 -179.2(3) . . . . ?
Ag8 O10 B5 O11 0.0(6) . . . . ?
Ag3 O2 B1 O3 -124.5(4) . . . . ?
Ag3 O2 B1 O1 53.7(4) . . . . ?
Ag3 O2 B2 O4 101.9(3) . . . . ?
Ag3 O2 B2 O14 -133.7(3) . . . 3_545 ?
Ag3 O2 B2 O5 -14.2(4) . . . 2_756 ?
Ag3 O10 B5 O9 64.5(5) 3_445 . . . ?
Ag3 O10 B5 O11 -116.3(4) 3_445 . . . ?
Ag4 O5 B4 O7 -38.0(5) . . . . ?
Ag4 O5 B4 O6 143.4(3) . . . . ?
Ag4 O7 B4 O5 21.4(6) 2_756 . . . ?
Ag4 O7 B4 O6 -160.0(3) 2_756 . . . ?
Ag2 O14 B7 O12 -20.7(4) 7_666 . . . ?
Ag2 O14 B7 O15 -141.7(3) 7_666 . . . ?
Ag2 O14 B7 O6 100.1(3) 7_666 . . 4_656 ?
Ag2 O1 B1 O3 -163.2(4) . . . . ?
Ag2 O1 B1 O2 18.6(5) . . . . ?
Ag6 O9 B5 O10 -12.5(6) . . . . ?
Ag6 O9 B5 O11 168.3(3) . . . . ?
Ag6 O9 B3 O8 -146.7(3) . . . . ?
Ag6 O9 B3 O4 -24.3(4) . . . . ?
Ag6 O9 B3 O3 94.9(3) . . . . ?
Ag6 O14 B7 O12 80.0(3) 3_455 . . . ?
Ag6 O14 B7 O15 -41.0(3) 3_455 . . . ?
Ag6 O14 B7 O6 -159.1(3) 3_455 . . 4_656 ?
Ag12 O7 B4 O5 -93.7(4) 2_656 . . . ?
Ag12 O7 B4 O6 84.9(5) 2_656 . . . ?
Ag12 O16 B8 O13 -86.0(4) . . . . ?
Ag12 O16 B8 O15 91.6(4) . . . . ?
B1 O3 B3 O8 129.7(4) . . . . ?
B1 O3 B3 O4 6.7(6) . . . . ?
B1 O3 B3 O9 -112.6(4) . . . . ?
B1 O2 B2 O4 -23.3(5) . . . . ?
B1 O2 B2 O14 101.1(4) . . . 3_545 ?
B1 O2 B2 O5 -139.4(4) . . . 2_756 ?
B5 O9 B3 O8 33.4(5) . . . . ?
B5 O9 B3 O4 155.8(4) . . . . ?
B5 O9 B3 O3 -85.0(4) . . . . ?
B5 O11 B6 O13 -100.8(5) . . . . ?
B5 O11 B6 O8 18.3(6) . . . . ?
B5 O11 B6 O12 141.4(4) . . . . ?
B6 O13 B8 O15 -11.5(7) . . . . ?
B6 O13 B8 O16 166.1(4) . . . . ?
B6 O8 B3 O4 -153.5(4) . . . . ?
B6 O8 B3 O9 -31.7(6) . . . . ?
B6 O8 B3 O3 84.1(5) . . . . ?
B6 O12 B7 O14 -161.4(3) . . . . ?
B6 O12 B7 O15 -43.2(5) . . . . ?
B6 O12 B7 O6 76.7(5) . . . 4_656 ?
B6 O11 B5 O9 -16.8(6) . . . . ?
B6 O11 B5 O10 164.1(4) . . . . ?
B7 O12 B6 O13 23.7(5) . . . . ?
B7 O12 B6 O8 -97.5(4) . . . . ?
B7 O12 B6 O11 140.6(4) . . . . ?
B7 O15 B8 O13 -10.5(6) . . . . ?
B7 O15 B8 O16 171.8(4) . . . . ?
B7 O6 B4 O5 -16.5(6) 4_646 . . . ?
B7 O6 B4 O7 164.9(4) 4_646 . . . ?
B8 O13 B6 O8 128.8(4) . . . . ?
B8 O13 B6 O12 5.0(6) . . . . ?
B8 O13 B6 O11 -110.9(4) . . . . ?
B8 O15 B7 O14 155.5(4) . . . . ?
B8 O15 B7 O12 35.9(5) . . . . ?
B8 O15 B7 O6 -84.6(5) . . . 4_656 ?
B3 O8 B6 O13 127.2(4) . . . . ?
B3 O8 B6 O12 -111.0(4) . . . . ?
B3 O8 B6 O11 8.4(6) . . . . ?
B3 O4 B2 O14 -85.6(5) . . . 3_545 ?
B3 O4 B2 O5 152.2(4) . . . 2_756 ?
B3 O4 B2 O2 35.6(5) . . . . ?
B3 O9 B5 O10 167.5(4) . . . . ?
B3 O9 B5 O11 -11.7(6) . . . . ?
B3 O3 B1 O1 -175.0(4) . . . . ?
B3 O3 B1 O2 3.1(6) . . . . ?
B2 O4 B3 O8 -150.0(4) . . . . ?
B2 O4 B3 O9 88.8(5) . . . . ?
B2 O4 B3 O3 -27.7(5) . . . . ?
B2 O14 B7 O12 -155.6(4) 3_455 . . . ?
B2 O14 B7 O15 83.4(5) 3_455 . . . ?
B2 O14 B7 O6 -34.7(5) 3_455 . . 4_656 ?
B2 O5 B4 O7 175.9(4) 2_756 . . . ?
B2 O5 B4 O6 -2.7(7) 2_756 . . . ?
B2 O2 B1 O3 6.2(6) . . . . ?
B2 O2 B1 O1 -175.6(4) . . . . ?
Ag11 O7 B4 O5 -106.2(6) 2_656 . . . ?
Ag11 O7 B4 O6 72.4(7) 2_656 . . . ?
Ag11 O16 B8 O13 -74.3(6) . . . . ?
Ag11 O16 B8 O15 103.4(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
