# Supplementary Information (SI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex-1
_database_code_depnum_ccdc_archive 'CCDC 2381643'
loop_
_audit_author_name
_audit_author_address
'Anangamohan Panja'
;Gokhale Memorial Girls College
India
;
_audit_update_record             
;
2024-11-05 deposited with the CCDC.	2024-11-18 downloaded from the CCDC.
;
_audit_creation_date             2024-10-10
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C35 H42 Co Dy N4 O15'
_chemical_formula_sum            'C35 H42 Co Dy N4 O15'
_chemical_formula_weight         980.15
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1528(4)
_cell_length_b                   12.5134(4)
_cell_length_c                   14.9487(5)
_cell_angle_alpha                67.7210(10)
_cell_angle_beta                 79.1420(10)
_cell_angle_gamma                66.4550(10)
_cell_volume                     1926.63(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    568
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.08
_cell_measurement_theta_min      3.12
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.430
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.6589
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            brown
_exptl_crystal_colour_primary    brown
_exptl_crystal_density_diffrn    1.690
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             986
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_unetI/netI     0.0320
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            30615
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.631
_diffrn_reflns_theta_min         2.950
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8085
_reflns_number_total             8905
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_refine_diff_density_max         0.658
_refine_diff_density_min         -0.833
_refine_diff_density_rms         0.073
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     529
_refine_ls_number_reflns         8905
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0287
_refine_ls_R_factor_gt           0.0241
_refine_ls_restrained_S_all      1.057
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0176P)²+1.4243P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0548
_refine_ls_wR_factor_ref         0.0570
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All H(H) groups, All C(H,H,H) groups, All C(H,H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C34B) \\sim Ueq, Uanis(C34A) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
3. Others
 Fixed Sof: C34A(0.45) H34A(0.45) H34B(0.45) H34C(0.45) C34B(0.55) H34D(0.55)
 H34E(0.55) H34F(0.55)
 Fixed X: H8(0.417399)
 Fixed Y: H8(0.9821)
 Fixed Z: H8(0.1077)
4.a Secondary CH2 refined with riding coordinates:
 C32(H32A,H32B), C16(H16A,H16B)
4.b Aromatic/amide H refined with riding coordinates:
 C25(H25), C20(H20), C9(H9), C23(H23), C7(H7A), C11(H11), C4(H4), C27(H27),
 C12(H12), C30(H30), C28(H28), C29(H29), C14(H14), C13(H13)
4.c Idealised Me refined as rotating group:
 C22(H22A,H22B,H22C), C6(H6A,H6B,H6C), C35(H35A,H35B,H35C), C3(H3A,H3B,H3C),
 C33(H33A,H33B,H33C), C19(H19A,H19B,H19C), C34A(H34A,H34B,H34C), C34B(H34D,H34E,
 H34F)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.58357(2) 0.72097(2) 0.17903(2) 0.02616(4) Uani 1 1 d . . . . .
Co1 Co 0.48261(2) 0.48932(3) 0.25843(2) 0.02133(6) Uani 1 1 d . . . . .
O6 O 0.46250(13) 0.63312(14) 0.28768(11) 0.0258(3) Uani 1 1 d . . . . .
O3 O 0.58763(13) 0.54901(14) 0.15698(11) 0.0256(3) Uani 1 1 d . . . . .
O1 O 0.34788(14) 0.58735(14) 0.17976(11) 0.0274(3) Uani 1 1 d . . . . .
O4 O 0.61764(13) 0.39517(14) 0.33715(11) 0.0283(3) Uani 1 1 d . . . . .
O15 O 0.74444(16) 0.54273(16) 0.27164(13) 0.0353(4) Uani 1 1 d . . . . .
O12 O 0.71460(18) 0.81701(19) 0.20565(14) 0.0474(5) Uani 1 1 d . . . . .
O13 O 0.59831(17) 0.75988(18) 0.32606(13) 0.0404(4) Uani 1 1 d . . . . .
N1 N 0.50759(16) 0.35592(17) 0.21429(13) 0.0248(4) Uani 1 1 d . . . . .
O5 O 0.83881(16) 0.24106(18) 0.36401(15) 0.0493(5) Uani 1 1 d . . . . .
O9 O 0.61765(17) 0.86466(19) 0.01473(14) 0.0493(5) Uani 1 1 d . . . . .
N2 N 0.38330(16) 0.43703(17) 0.36969(13) 0.0256(4) Uani 1 1 d . . . . .
O10 O 0.76399(17) 0.69287(18) 0.06711(15) 0.0466(5) Uani 1 1 d . . . . .
O8 O 0.4464(2) 0.93021(18) 0.17038(16) 0.0554(6) Uani 1 1 d . . . . .
O2 O 0.12881(16) 0.74408(16) 0.13774(15) 0.0429(4) Uani 1 1 d . . . . .
N4 N 0.6786(2) 0.8065(2) 0.29270(17) 0.0427(5) Uani 1 1 d . . . . .
O14 O 0.7211(2) 0.8376(3) 0.34235(18) 0.0728(7) Uani 1 1 d . . . . .
N3 N 0.7281(2) 0.7997(2) 0.00583(16) 0.0399(5) Uani 1 1 d . . . . .
O7 O 0.4066(2) 0.7872(2) 0.0867(2) 0.0675(8) Uani 1 1 d . . . . .
C17 C 0.26967(19) 0.5423(2) 0.17298(16) 0.0248(4) Uani 1 1 d . . . . .
O11 O 0.7936(2) 0.8400(2) -0.05819(17) 0.0693(7) Uani 1 1 d . . . . .
C18 C 0.1493(2) 0.6241(2) 0.14981(17) 0.0299(5) Uani 1 1 d . . . . .
C25 C 0.4221(2) 0.3364(2) 0.19068(17) 0.0285(5) Uani 1 1 d . . . . .
H25 H 0.442254 0.263872 0.177307 0.034 Uiso 1 1 calc R U . . .
C24 C 0.2986(2) 0.4178(2) 0.18347(17) 0.0272(5) Uani 1 1 d . . . . .
C20 C 0.0659(2) 0.5810(2) 0.14045(18) 0.0343(5) Uani 1 1 d . . . . .
H20 H -0.012422 0.635927 0.126546 0.041 Uiso 1 1 calc R U . . .
C32 C 0.6392(2) 0.4911(2) 0.08650(17) 0.0327(5) Uani 1 1 d . . . . .
H32A H 0.699269 0.524125 0.047487 0.039 Uiso 1 1 calc R U . . .
H32B H 0.577344 0.510860 0.044097 0.039 Uiso 1 1 calc R U . . .
C9 C 0.4177(2) 0.3297(2) 0.43660(17) 0.0297(5) Uani 1 1 d . . . . .
H9 H 0.361166 0.309035 0.484293 0.036 Uiso 1 1 calc R U . . .
C1 C 0.6328(2) 0.2809(2) 0.39484(16) 0.0277(5) Uani 1 1 d . . . . .
C21 C 0.0954(2) 0.4560(2) 0.15130(18) 0.0334(5) Uani 1 1 d . . . . .
C10 C 0.2706(2) 0.5304(2) 0.38279(16) 0.0277(5) Uani 1 1 d . . . . .
C23 C 0.2111(2) 0.3772(2) 0.17137(18) 0.0320(5) Uani 1 1 d . . . . .
H23 H 0.232747 0.294742 0.177220 0.038 Uiso 1 1 calc R U . . .
C2 C 0.7523(2) 0.1933(2) 0.41156(18) 0.0346(5) Uani 1 1 d . . . . .
C16 C 0.3996(2) 0.6478(2) 0.37413(18) 0.0330(5) Uani 1 1 d . . . . .
H16A H 0.389814 0.727970 0.375634 0.040 Uiso 1 1 calc R U . . .
H16B H 0.446194 0.584628 0.428802 0.040 Uiso 1 1 calc R U . . .
C26 C 0.62948(19) 0.2845(2) 0.19340(17) 0.0268(5) Uani 1 1 d . . . . .
C15 C 0.2773(2) 0.6386(2) 0.38357(17) 0.0314(5) Uani 1 1 d . . . . .
C31 C 0.6970(2) 0.3524(2) 0.12997(17) 0.0303(5) Uani 1 1 d . . . . .
C7 C 0.5626(2) 0.1155(2) 0.50267(18) 0.0346(5) Uani 1 1 d . . . . .
H7A H 0.498997 0.090688 0.535084 0.042 Uiso 1 1 calc R U . . .
C11 C 0.1617(2) 0.5150(3) 0.39276(18) 0.0367(6) Uani 1 1 d . . . . .
H11 H 0.158902 0.442038 0.392312 0.044 Uiso 1 1 calc R U . . .
C4 C 0.7726(2) 0.0725(2) 0.4688(2) 0.0409(6) Uani 1 1 d . . . . .
H4 H 0.851217 0.016416 0.477465 0.049 Uiso 1 1 calc R U . . .
C5 C 0.6773(3) 0.0308(2) 0.51486(19) 0.0389(6) Uani 1 1 d . . . . .
C22 C 0.0030(2) 0.4124(3) 0.1369(2) 0.0440(7) Uani 1 1 d . . . . .
H22A H 0.042471 0.332517 0.129561 0.066 Uiso 1 1 calc R U . . .
H22B H -0.040067 0.470296 0.079963 0.066 Uiso 1 1 calc R U . . .
H22C H -0.052193 0.406542 0.192164 0.066 Uiso 1 1 calc R U . . .
C8 C 0.5384(2) 0.2401(2) 0.44178(17) 0.0290(5) Uani 1 1 d . . . . .
C27 C 0.6766(2) 0.1566(2) 0.23343(19) 0.0342(5) Uani 1 1 d . . . . .
H27 H 0.629809 0.113325 0.275555 0.041 Uiso 1 1 calc R U . . .
C12 C 0.0568(2) 0.6106(3) 0.4035(2) 0.0455(7) Uani 1 1 d . . . . .
H12 H -0.017000 0.601552 0.410431 0.055 Uiso 1 1 calc R U . . .
C6 C 0.7055(3) -0.1048(3) 0.5748(2) 0.0550(8) Uani 1 1 d . . . . .
H6A H 0.632578 -0.117478 0.605078 0.082 Uiso 1 1 calc R U . . .
H6B H 0.760084 -0.128612 0.623629 0.082 Uiso 1 1 calc R U . . .
H6C H 0.741582 -0.154123 0.533672 0.082 Uiso 1 1 calc R U . . .
C35 C 0.8260(3) 0.5207(3) 0.3389(2) 0.0519(8) Uani 1 1 d . . . . .
H35A H 0.859326 0.584749 0.315525 0.078 Uiso 1 1 calc R U . . .
H35B H 0.889535 0.441871 0.346511 0.078 Uiso 1 1 calc R U . . .
H35C H 0.784348 0.520610 0.400263 0.078 Uiso 1 1 calc R U . . .
C30 C 0.8149(2) 0.2866(3) 0.1072(2) 0.0396(6) Uani 1 1 d . . . . .
H30 H 0.862030 0.329195 0.064799 0.048 Uiso 1 1 calc R U . . .
C28 C 0.7950(2) 0.0941(3) 0.2094(2) 0.0437(7) Uani 1 1 d . . . . .
H28 H 0.828358 0.008227 0.235823 0.052 Uiso 1 1 calc R U . . .
C29 C 0.8631(2) 0.1593(3) 0.1465(2) 0.0474(7) Uani 1 1 d . . . . .
H29 H 0.942158 0.117129 0.130320 0.057 Uiso 1 1 calc R U . . .
C14 C 0.1714(2) 0.7327(3) 0.3939(2) 0.0441(6) Uani 1 1 d . . . . .
H14 H 0.173812 0.805851 0.394358 0.053 Uiso 1 1 calc R U . . .
C13 C 0.0616(2) 0.7183(3) 0.4038(2) 0.0491(7) Uani 1 1 d . . . . .
H13 H -0.009110 0.782012 0.410573 0.059 Uiso 1 1 calc R U . . .
C3 C 0.9596(3) 0.1603(3) 0.3764(3) 0.0731(11) Uani 1 1 d . . . . .
H3A H 0.975561 0.124576 0.444066 0.110 Uiso 1 1 calc R U . . .
H3B H 1.011404 0.205575 0.342544 0.110 Uiso 1 1 calc R U . . .
H3C H 0.974146 0.095589 0.351139 0.110 Uiso 1 1 calc R U . . .
C33 C 0.3543(4) 0.8591(4) 0.0020(3) 0.0884(15) Uani 1 1 d . . . . .
H33A H 0.388482 0.921839 -0.030834 0.133 Uiso 1 1 calc R U . . .
H33B H 0.269607 0.897479 0.013554 0.133 Uiso 1 1 calc R U . . .
H33C H 0.367470 0.809321 -0.037344 0.133 Uiso 1 1 calc R U . . .
C19 C 0.0090(3) 0.8301(3) 0.1196(3) 0.0635(10) Uani 1 1 d . . . . .
H19A H -0.016673 0.830614 0.062494 0.095 Uiso 1 1 calc R U . . .
H19B H 0.006173 0.911405 0.110327 0.095 Uiso 1 1 calc R U . . .
H19C H -0.043187 0.806367 0.173798 0.095 Uiso 1 1 calc R U . . .
C34A C 0.3477(10) 0.9636(10) 0.2334(8) 0.092(3) Uani 0.45 1 d . U P A 1
H34A H 0.287811 0.934441 0.228398 0.138 Uiso 0.45 1 calc R U P A 1
H34B H 0.314314 1.052114 0.216137 0.138 Uiso 0.45 1 calc R U P A 1
H34C H 0.373505 0.927105 0.298627 0.138 Uiso 0.45 1 calc R U P A 1
C34B C 0.4158(9) 1.0038(7) 0.2250(6) 0.082(3) Uani 0.55 1 d . U P A 2
H34D H 0.443852 0.954538 0.289059 0.123 Uiso 0.55 1 calc R U P A 2
H34E H 0.330044 1.043545 0.228135 0.123 Uiso 0.55 1 calc R U P A 2
H34F H 0.451952 1.065526 0.196352 0.123 Uiso 0.55 1 calc R U P A 2
H15 H 0.722(4) 0.485(5) 0.292(4) 0.123 Uiso 1 1 d . U . . .
H7 H 0.383(4) 0.741(5) 0.110(4) 0.107(19) Uiso 1 1 d . . . . .
H8 H 0.417399 0.982100 0.107700 0.160 Uiso 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O6 2.2472(15) . y
Dy1 O3 2.2778(15) . y
Dy1 O15 2.4307(17) . y
Dy1 O12 2.5037(18) . y
Dy1 O13 2.4758(18) . y
Dy1 O9 2.5099(19) . y
Dy1 O10 2.4856(19) . y
Dy1 O8 2.4471(19) . y
Dy1 O7 2.458(2) . y
Co1 O6 1.9219(15) . y
Co1 O3 1.9131(15) . y
Co1 O1 1.8962(15) . y
Co1 O4 1.8967(15) . y
Co1 N1 1.9155(19) . y
Co1 N2 1.9237(19) . y
O6 C16 1.409(3) . ?
O3 C32 1.413(3) . ?
O1 C17 1.319(3) . ?
O4 C1 1.318(3) . ?
O15 C35 1.421(3) . ?
O15 H15 0.80(5) . ?
O12 N4 1.266(3) . ?
O13 N4 1.262(3) . ?
N1 C25 1.292(3) . ?
N1 C26 1.439(3) . ?
O5 C2 1.366(3) . ?
O5 C3 1.409(3) . ?
O9 N3 1.274(3) . ?
N2 C9 1.292(3) . ?
N2 C10 1.440(3) . ?
O10 N3 1.254(3) . ?
O8 C34A 1.404(10) . ?
O8 C34B 1.354(7) . ?
O8 H8 0.951(2) . ?
O2 C18 1.364(3) . ?
O2 C19 1.424(3) . ?
N4 O14 1.222(3) . ?
N3 O11 1.213(3) . ?
O7 C33 1.341(4) . ?
O7 H7 0.70(5) . ?
C17 C18 1.426(3) . ?
C17 C24 1.405(3) . ?
C18 C20 1.374(3) . ?
C25 H25 0.9300 . ?
C25 C24 1.435(3) . ?
C24 C23 1.413(3) . ?
C20 H20 0.9300 . ?
C20 C21 1.407(4) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C32 C31 1.507(3) . ?
C9 H9 0.9300 . ?
C9 C8 1.442(3) . ?
C1 C2 1.424(3) . ?
C1 C8 1.401(3) . ?
C21 C23 1.366(3) . ?
C21 C22 1.508(3) . ?
C10 C15 1.392(3) . ?
C10 C11 1.384(3) . ?
C23 H23 0.9300 . ?
C2 C4 1.371(4) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C15 1.512(3) . ?
C26 C31 1.395(3) . ?
C26 C27 1.386(3) . ?
C15 C14 1.385(4) . ?
C31 C30 1.390(3) . ?
C7 H7A 0.9300 . ?
C7 C5 1.367(4) . ?
C7 C8 1.416(3) . ?
C11 H11 0.9300 . ?
C11 C12 1.390(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.413(4) . ?
C5 C6 1.516(4) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C27 H27 0.9300 . ?
C27 C28 1.389(4) . ?
C12 H12 0.9300 . ?
C12 C13 1.374(4) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C30 H30 0.9300 . ?
C30 C29 1.378(4) . ?
C28 H28 0.9300 . ?
C28 C29 1.379(4) . ?
C29 H29 0.9300 . ?
C14 H14 0.9300 . ?
C14 C13 1.391(4) . ?
C13 H13 0.9300 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C34A H34A 0.9600 . ?
C34A H34B 0.9600 . ?
C34A H34C 0.9600 . ?
C34B H34D 0.9600 . ?
C34B H34E 0.9600 . ?
C34B H34F 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Dy1 O3 67.97(5) . . y
O6 Dy1 O15 84.32(6) . . y
O6 Dy1 O12 128.11(6) . . y
O6 Dy1 O13 77.17(6) . . y
O6 Dy1 O9 149.82(6) . . y
O6 Dy1 O10 147.25(6) . . y
O6 Dy1 O8 92.61(7) . . y
O6 Dy1 O7 76.62(7) . . y
O3 Dy1 O15 71.51(6) . . y
O3 Dy1 O12 142.98(6) . . y
O3 Dy1 O13 131.71(6) . . y
O3 Dy1 O9 106.56(6) . . y
O3 Dy1 O10 82.06(6) . . y
O3 Dy1 O8 140.62(7) . . y
O3 Dy1 O7 73.68(7) . . y
O15 Dy1 O12 77.09(6) . . y
O15 Dy1 O13 72.78(6) . . y
O15 Dy1 O9 123.21(6) . . y
O15 Dy1 O10 73.54(6) . . y
O15 Dy1 O8 142.94(7) . . y
O15 Dy1 O7 144.54(7) . . y
O12 Dy1 O9 74.95(7) . . y
O13 Dy1 O12 51.15(6) . . y
O13 Dy1 O9 119.99(7) . . y
O13 Dy1 O10 117.12(6) . . y
O10 Dy1 O12 70.48(7) . . y
O10 Dy1 O9 50.79(6) . . y
O8 Dy1 O12 76.04(7) . . y
O8 Dy1 O13 70.54(7) . . y
O8 Dy1 O9 72.91(7) . . y
O8 Dy1 O10 119.59(7) . . y
O8 Dy1 O7 68.48(8) . . y
O7 Dy1 O12 137.84(7) . . y
O7 Dy1 O13 129.55(9) . . y
O7 Dy1 O9 73.46(8) . . y
O7 Dy1 O10 108.15(9) . . y
O6 Co1 Dy1 40.84(5) . . y
O6 Co1 N2 91.68(7) . . y
O3 Co1 Dy1 41.72(5) . . y
O3 Co1 O6 82.54(7) . . y
O3 Co1 N1 91.43(7) . . y
O3 Co1 N2 173.05(7) . . y
O1 Co1 Dy1 90.93(5) . . y
O1 Co1 O6 88.16(7) . . y
O1 Co1 O3 91.68(7) . . y
O1 Co1 O4 178.48(7) . . y
O1 Co1 N1 89.28(7) . . y
O1 Co1 N2 91.98(7) . . y
O4 Co1 Dy1 87.70(5) . . y
O4 Co1 O6 90.37(7) . . y
O4 Co1 O3 87.73(7) . . y
O4 Co1 N1 92.14(7) . . y
O4 Co1 N2 88.46(7) . . y
N1 Co1 Dy1 133.14(6) . . y
N1 Co1 O6 173.38(7) . . y
N1 Co1 N2 94.51(8) . . y
N2 Co1 Dy1 132.29(6) . . y
Co1 O6 Dy1 105.15(7) . . ?
C16 O6 Dy1 134.83(14) . . ?
C16 O6 Co1 118.83(14) . . ?
Co1 O3 Dy1 104.30(7) . . ?
C32 O3 Dy1 135.26(13) . . ?
C32 O3 Co1 120.23(13) . . ?
C17 O1 Co1 122.22(13) . . ?
C1 O4 Co1 120.34(13) . . ?
Dy1 O15 H15 107(4) . . ?
C35 O15 Dy1 135.93(17) . . ?
C35 O15 H15 106(4) . . ?
N4 O12 Dy1 95.44(14) . . ?
N4 O13 Dy1 96.91(14) . . ?
C25 N1 Co1 123.95(16) . . ?
C25 N1 C26 118.01(19) . . ?
C26 N1 Co1 117.44(14) . . ?
C2 O5 C3 117.5(2) . . ?
N3 O9 Dy1 95.14(14) . . ?
C9 N2 Co1 123.86(16) . . ?
C9 N2 C10 119.5(2) . . ?
C10 N2 Co1 116.21(14) . . ?
N3 O10 Dy1 96.85(14) . . ?
Dy1 O8 H8 114.06(15) . . ?
C34A O8 Dy1 127.4(5) . . ?
C34A O8 H8 104.1(5) . . ?
C34B O8 Dy1 137.4(3) . . ?
C34B O8 H8 107.0(4) . . ?
C18 O2 C19 117.0(2) . . ?
O12 N4 Dy1 58.89(12) . . ?
O13 N4 Dy1 57.60(12) . . ?
O13 N4 O12 116.5(2) . . ?
O14 N4 Dy1 177.5(2) . . ?
O14 N4 O12 121.8(2) . . ?
O14 N4 O13 121.7(2) . . ?
O9 N3 Dy1 59.06(12) . . ?
O10 N3 Dy1 57.86(12) . . ?
O10 N3 O9 115.9(2) . . ?
O11 N3 Dy1 170.1(2) . . ?
O11 N3 O9 121.4(2) . . ?
O11 N3 O10 122.7(2) . . ?
Dy1 O7 H7 104(4) . . ?
C33 O7 Dy1 144.6(2) . . ?
C33 O7 H7 109(4) . . ?
O1 C17 C18 119.1(2) . . ?
O1 C17 C24 123.83(19) . . ?
C24 C17 C18 117.0(2) . . ?
O2 C18 C17 113.7(2) . . ?
O2 C18 C20 125.5(2) . . ?
C20 C18 C17 120.8(2) . . ?
N1 C25 H25 117.4 . . ?
N1 C25 C24 125.1(2) . . ?
C24 C25 H25 117.4 . . ?
C17 C24 C25 119.2(2) . . ?
C17 C24 C23 120.7(2) . . ?
C23 C24 C25 119.4(2) . . ?
C18 C20 H20 119.0 . . ?
C18 C20 C21 121.9(2) . . ?
C21 C20 H20 119.0 . . ?
O3 C32 H32A 109.0 . . ?
O3 C32 H32B 109.0 . . ?
O3 C32 C31 112.87(19) . . ?
H32A C32 H32B 107.8 . . ?
C31 C32 H32A 109.0 . . ?
C31 C32 H32B 109.0 . . ?
N2 C9 H9 118.0 . . ?
N2 C9 C8 123.9(2) . . ?
C8 C9 H9 118.0 . . ?
O4 C1 C2 118.4(2) . . ?
O4 C1 C8 124.0(2) . . ?
C8 C1 C2 117.7(2) . . ?
C20 C21 C22 120.7(2) . . ?
C23 C21 C20 117.9(2) . . ?
C23 C21 C22 121.3(2) . . ?
C15 C10 N2 115.9(2) . . ?
C11 C10 N2 122.4(2) . . ?
C11 C10 C15 121.7(2) . . ?
C24 C23 H23 119.2 . . ?
C21 C23 C24 121.7(2) . . ?
C21 C23 H23 119.2 . . ?
O5 C2 C1 113.9(2) . . ?
O5 C2 C4 125.6(2) . . ?
C4 C2 C1 120.5(2) . . ?
O6 C16 H16A 109.2 . . ?
O6 C16 H16B 109.2 . . ?
O6 C16 C15 111.89(19) . . ?
H16A C16 H16B 107.9 . . ?
C15 C16 H16A 109.2 . . ?
C15 C16 H16B 109.2 . . ?
C31 C26 N1 115.7(2) . . ?
C27 C26 N1 122.1(2) . . ?
C27 C26 C31 122.2(2) . . ?
C10 C15 C16 118.8(2) . . ?
C14 C15 C10 118.4(2) . . ?
C14 C15 C16 122.8(2) . . ?
C26 C31 C32 119.5(2) . . ?
C30 C31 C32 123.0(2) . . ?
C30 C31 C26 117.4(2) . . ?
C5 C7 H7A 119.3 . . ?
C5 C7 C8 121.5(2) . . ?
C8 C7 H7A 119.3 . . ?
C10 C11 H11 120.6 . . ?
C10 C11 C12 118.8(3) . . ?
C12 C11 H11 120.6 . . ?
C2 C4 H4 119.1 . . ?
C2 C4 C5 121.8(2) . . ?
C5 C4 H4 119.1 . . ?
C7 C5 C4 118.0(2) . . ?
C7 C5 C6 122.7(3) . . ?
C4 C5 C6 119.3(2) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C1 C8 C9 119.0(2) . . ?
C1 C8 C7 120.4(2) . . ?
C7 C8 C9 120.2(2) . . ?
C26 C27 H27 120.6 . . ?
C26 C27 C28 118.7(2) . . ?
C28 C27 H27 120.6 . . ?
C11 C12 H12 119.8 . . ?
C13 C12 C11 120.3(2) . . ?
C13 C12 H12 119.8 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
O15 C35 H35A 109.5 . . ?
O15 C35 H35B 109.5 . . ?
O15 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C31 C30 H30 119.5 . . ?
C29 C30 C31 121.1(3) . . ?
C29 C30 H30 119.5 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 C27 120.0(3) . . ?
C29 C28 H28 120.0 . . ?
C30 C29 C28 120.6(2) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C15 C14 H14 119.8 . . ?
C15 C14 C13 120.4(3) . . ?
C13 C14 H14 119.8 . . ?
C12 C13 C14 120.4(3) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
O5 C3 H3A 109.5 . . ?
O5 C3 H3B 109.5 . . ?
O5 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
O7 C33 H33A 109.5 . . ?
O7 C33 H33B 109.5 . . ?
O7 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
O2 C19 H19A 109.5 . . ?
O2 C19 H19B 109.5 . . ?
O2 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
O8 C34A H34A 109.5 . . ?
O8 C34A H34B 109.5 . . ?
O8 C34A H34C 109.5 . . ?
H34A C34A H34B 109.5 . . ?
H34A C34A H34C 109.5 . . ?
H34B C34A H34C 109.5 . . ?
O8 C34B H34D 109.5 . . ?
O8 C34B H34E 109.5 . . ?
O8 C34B H34F 109.5 . . ?
H34D C34B H34E 109.5 . . ?
H34D C34B H34F 109.5 . . ?
H34E C34B H34F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 Co1 O1 C17 175.25(16) . . . . ?
Dy1 Co1 O4 C1 179.13(17) . . . . ?
Dy1 O6 C16 C15 141.34(16) . . . . ?
Dy1 O3 C32 C31 136.66(17) . . . . ?
Dy1 O12 N4 O13 -1.5(2) . . . . ?
Dy1 O12 N4 O14 177.1(3) . . . . ?
Dy1 O13 N4 O12 1.5(2) . . . . ?
Dy1 O13 N4 O14 -177.1(3) . . . . ?
Dy1 O9 N3 O10 11.5(2) . . . . ?
Dy1 O9 N3 O11 -168.5(2) . . . . ?
Dy1 O10 N3 O9 -11.6(2) . . . . ?
Dy1 O10 N3 O11 168.3(2) . . . . ?
Co1 O6 C16 C15 -53.2(2) . . . . ?
Co1 O3 C32 C31 -49.6(2) . . . . ?
Co1 O1 C17 C18 153.20(17) . . . . ?
Co1 O1 C17 C24 -29.5(3) . . . . ?
Co1 O4 C1 C2 146.76(18) . . . . ?
Co1 O4 C1 C8 -33.9(3) . . . . ?
Co1 N1 C25 C24 7.3(3) . . . . ?
Co1 N1 C26 C31 -52.9(2) . . . . ?
Co1 N1 C26 C27 127.4(2) . . . . ?
Co1 N2 C9 C8 6.5(3) . . . . ?
Co1 N2 C10 C15 -53.6(2) . . . . ?
Co1 N2 C10 C11 125.5(2) . . . . ?
O6 Co1 O1 C17 -144.00(17) . . . . ?
O6 Co1 O4 C1 138.37(17) . . . . ?
O6 C16 C15 C10 58.7(3) . . . . ?
O6 C16 C15 C14 -121.9(3) . . . . ?
O3 Co1 O1 C17 133.53(17) . . . . ?
O3 Co1 O4 C1 -139.12(17) . . . . ?
O3 C32 C31 C26 55.4(3) . . . . ?
O3 C32 C31 C30 -127.1(2) . . . . ?
O1 C17 C18 O2 -0.5(3) . . . . ?
O1 C17 C18 C20 178.9(2) . . . . ?
O1 C17 C24 C25 -7.7(3) . . . . ?
O1 C17 C24 C23 -177.4(2) . . . . ?
O4 C1 C2 O5 0.2(3) . . . . ?
O4 C1 C2 C4 -178.1(2) . . . . ?
O4 C1 C8 C9 -7.4(3) . . . . ?
O4 C1 C8 C7 180.0(2) . . . . ?
N1 Co1 O1 C17 42.12(17) . . . . ?
N1 Co1 O4 C1 -47.77(17) . . . . ?
N1 C25 C24 C17 19.7(4) . . . . ?
N1 C25 C24 C23 -170.5(2) . . . . ?
N1 C26 C31 C32 -1.7(3) . . . . ?
N1 C26 C31 C30 -179.4(2) . . . . ?
N1 C26 C27 C28 179.7(2) . . . . ?
O5 C2 C4 C5 -179.6(3) . . . . ?
N2 Co1 O1 C17 -52.37(17) . . . . ?
N2 Co1 O4 C1 46.69(17) . . . . ?
N2 C9 C8 C1 22.3(3) . . . . ?
N2 C9 C8 C7 -165.1(2) . . . . ?
N2 C10 C15 C16 -1.9(3) . . . . ?
N2 C10 C15 C14 178.7(2) . . . . ?
N2 C10 C11 C12 -178.9(2) . . . . ?
O2 C18 C20 C21 178.0(2) . . . . ?
C17 C18 C20 C21 -1.2(4) . . . . ?
C17 C24 C23 C21 -1.4(4) . . . . ?
C18 C17 C24 C25 169.7(2) . . . . ?
C18 C17 C24 C23 0.0(3) . . . . ?
C18 C20 C21 C23 -0.2(4) . . . . ?
C18 C20 C21 C22 -177.7(2) . . . . ?
C25 N1 C26 C31 118.5(2) . . . . ?
C25 N1 C26 C27 -61.2(3) . . . . ?
C25 C24 C23 C21 -171.2(2) . . . . ?
C24 C17 C18 O2 -178.0(2) . . . . ?
C24 C17 C18 C20 1.3(3) . . . . ?
C20 C21 C23 C24 1.6(4) . . . . ?
C32 C31 C30 C29 -178.0(2) . . . . ?
C9 N2 C10 C15 118.8(2) . . . . ?
C9 N2 C10 C11 -62.0(3) . . . . ?
C1 C2 C4 C5 -1.5(4) . . . . ?
C10 N2 C9 C8 -165.4(2) . . . . ?
C10 C15 C14 C13 0.3(4) . . . . ?
C10 C11 C12 C13 0.2(4) . . . . ?
C2 C1 C8 C9 172.0(2) . . . . ?
C2 C1 C8 C7 -0.6(3) . . . . ?
C2 C4 C5 C7 -1.4(4) . . . . ?
C2 C4 C5 C6 178.2(3) . . . . ?
C16 C15 C14 C13 -179.0(3) . . . . ?
C26 N1 C25 C24 -163.6(2) . . . . ?
C26 C31 C30 C29 -0.4(4) . . . . ?
C26 C27 C28 C29 -0.4(4) . . . . ?
C15 C10 C11 C12 0.2(4) . . . . ?
C15 C14 C13 C12 0.1(5) . . . . ?
C31 C26 C27 C28 0.0(4) . . . . ?
C31 C30 C29 C28 0.1(4) . . . . ?
C11 C10 C15 C16 178.9(2) . . . . ?
C11 C10 C15 C14 -0.5(4) . . . . ?
C11 C12 C13 C14 -0.4(5) . . . . ?
C5 C7 C8 C9 -174.8(2) . . . . ?
C5 C7 C8 C1 -2.3(4) . . . . ?
C22 C21 C23 C24 179.0(2) . . . . ?
C8 C1 C2 O5 -179.3(2) . . . . ?
C8 C1 C2 C4 2.5(4) . . . . ?
C8 C7 C5 C4 3.3(4) . . . . ?
C8 C7 C5 C6 -176.3(3) . . . . ?
C27 C26 C31 C32 178.1(2) . . . . ?
C27 C26 C31 C30 0.4(3) . . . . ?
C27 C28 C29 C30 0.3(4) . . . . ?
C3 O5 C2 C1 -179.8(3) . . . . ?
C3 O5 C2 C4 -1.6(4) . . . . ?
C19 O2 C18 C17 -176.7(3) . . . . ?
C19 O2 C18 C20 4.0(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex-2
_database_code_depnum_ccdc_archive 'CCDC 2381644'
loop_
_audit_author_name
_audit_author_address
'Anangamohan Panja'
;Gokhale Memorial Girls College
India
;
_audit_update_record             
;
2024-11-05 deposited with the CCDC.	2024-11-18 downloaded from the CCDC.
;
_audit_creation_date             2024-10-03
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C47 H57.3 Co Dy N2 O12, H O0.5'
_chemical_formula_sum            'C47 H58.30 Co Dy N2 O12.50'
_chemical_formula_weight         1072.68
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           43
_space_group_name_H-M_alt        'F d d 2'
_space_group_name_Hall           'F 2 -2d'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x+1/4, -y+1/4, z+1/4'
'-x+1/4, y+1/4, z+1/4'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x+1/4, -y+3/4, z+3/4'
'-x+1/4, y+3/4, z+3/4'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'x+3/4, -y+1/4, z+3/4'
'-x+3/4, y+1/4, z+3/4'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+3/4, -y+3/4, z+1/4'
'-x+3/4, y+3/4, z+1/4'

_cell_length_a                   35.215(3)
_cell_length_b                   42.917(4)
_cell_length_c                   12.7391(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     19253(3)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    496
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.92
_cell_measurement_theta_min      2.88
_shelx_estimated_absorpt_T_max   0.944
_shelx_estimated_absorpt_T_min   0.721
_exptl_absorpt_coefficient_mu    1.947
_exptl_absorpt_correction_T_max  0.894
_exptl_absorpt_correction_T_min  0.679
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadbs
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    1.480
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             8757
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0398
_diffrn_reflns_av_unetI/netI     0.0299
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       45
_diffrn_reflns_limit_h_min       -45
_diffrn_reflns_limit_k_max       54
_diffrn_reflns_limit_k_min       -54
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            81576
_diffrn_reflns_point_group_measured_fraction_full 0.979
_diffrn_reflns_point_group_measured_fraction_max 0.969
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.187
_diffrn_reflns_theta_min         2.217
_diffrn_ambient_temperature      150.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.865
_reflns_Friedel_fraction_full    0.960
_reflns_Friedel_fraction_max     0.942
_reflns_number_gt                9687
_reflns_number_total             10399
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.041
_refine_diff_density_min         -0.563
_refine_diff_density_rms         0.068
_refine_ls_abs_structure_details 
;
 Flack x determined using 4291 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.012(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     640
_refine_ls_number_reflns         10399
_refine_ls_number_restraints     88
_refine_ls_R_factor_all          0.0289
_refine_ls_R_factor_gt           0.0248
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0330P)²+42.2866P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0616
_refine_ls_wR_factor_ref         0.0635
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Restrained distances
 O3-H3
 0.85 with sigma of 0.02
 C28-C29 \\sim C28A-C29A
 with sigma of 0.02
 C28-C33 \\sim C28A-C33
 with sigma of 0.02
 C29-C30 \\sim C29A-C30A
 with sigma of 0.02
 C30-C31 \\sim C30A-C31
 with sigma of 0.02
 C28-C30 \\sim C28A-C30A
 with sigma of 0.04
 C29-C31 \\sim C29A-C31
 with sigma of 0.04
 C29-C33 \\sim C29A-C33
 with sigma of 0.04
3. Rigid bond restraints
 C26, O14
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C28 \\sim C28A: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002 within 2A
C30 \\sim C30A: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002 within 2A
C29 \\sim C29A: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002 within 2A
Uanis(C29) \\sim Ueq, Uanis(C30) \\sim Ueq, Uanis(C28) \\sim Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
5. Rigid body (RIGU) restrains
 C28, C29, C30, O14, C26
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 C28A, C26A, C29A, C30A, O14A
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
6. Others
 Fixed Sof: C28(0.7) C29(0.7) H29(0.7) C30(0.7) H30(0.7) H31(0.7) H31A(0.3)
 O14(0.7) C26(0.7) H26A(0.7) H26B(0.7) C28A(0.3) C26A(0.3) H26C(0.3) H26D(0.3)
 C29A(0.3) H29A(0.3) C30A(0.3) H30A(0.3) O14A(0.3) H14A(0.3)
7.a Secondary CH2 refined with riding coordinates:
 C16(H16A,H16B), C26(H26A,H26B), C26A(H26C,H26D)
7.b Aromatic/amide H refined with riding coordinates:
 C3(H3A), C5(H5), C9(H9), C11(H11), C12(H12), C13(H13), C14(H14), C19(H19),
 C21(H21), C29(H29), C30(H30), C31(H31), C31(H31A), C32(H32), C29A(H29A),
 C30A(H30A)
7.c Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C23(H23A,H23B,H23C), C24(H24A,H24B,H24C),
 C36(H36A,H36B,H36C), C37(H37A,H37B,H37C), C38(H38A,H38B,H38C), C41(H41A,H41B,
 H41C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C46(H46A,H46B,H46C), C47(H47A,
 H47B,H47C), C48(H48A,H48B,H48C)
7.d Idealised tetrahedral OH refined as rotating group:
 O14A(H14A)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.47981(2) 0.60231(2) 0.41715(2) 0.02652(6) Uani 1 1 d . . . . .
Co1 Co 0.43751(2) 0.56718(2) 0.62805(5) 0.02282(12) Uani 1 1 d . . . . .
O1 O 0.49243(8) 0.57395(7) 0.5736(2) 0.0245(6) Uani 1 1 d . . . . .
O2 O 0.54482(9) 0.60815(8) 0.4909(3) 0.0327(8) Uani 1 1 d . . . . .
O3 O 0.43625(9) 0.51721(8) 0.5784(3) 0.0281(7) Uani 1 1 d D . . . .
O4 O 0.42687(9) 0.57658(8) 0.4768(2) 0.0277(7) Uani 1 1 d . . . . .
O5 O 0.43607(10) 0.57612(10) 0.2768(3) 0.0403(9) Uani 1 1 d . . . . .
O7 O 0.44218(9) 0.61186(8) 0.6919(3) 0.0322(8) Uani 1 1 d . . . . .
O8 O 0.46877(10) 0.63598(8) 0.5559(3) 0.0341(8) Uani 1 1 d . . . . .
O9 O 0.43472(11) 0.63721(9) 0.3394(3) 0.0445(9) Uani 1 1 d . . . . .
O10 O 0.49383(11) 0.65355(9) 0.3470(3) 0.0443(9) Uani 1 1 d . . . . .
O12 O 0.50922(10) 0.55279(8) 0.3615(3) 0.0332(7) Uani 1 1 d . . . . .
O11 O 0.52045(11) 0.59420(9) 0.2662(3) 0.0416(9) Uani 1 1 d . . . . .
N1 N 0.46202(11) 0.54700(9) 0.7586(3) 0.0271(8) Uani 1 1 d . . . . .
N2 N 0.37841(10) 0.56156(9) 0.6518(3) 0.0271(8) Uani 1 1 d . . . . .
C1 C 0.52000(11) 0.58247(10) 0.6376(4) 0.0259(9) Uani 1 1 d . . . . .
C2 C 0.54997(13) 0.60053(10) 0.5953(4) 0.0291(10) Uani 1 1 d . . . . .
C3 C 0.58090(12) 0.60914(11) 0.6546(5) 0.0355(11) Uani 1 1 d . . . . .
H3A H 0.600702 0.621008 0.623530 0.043 Uiso 1 1 calc R U . . .
C4 C 0.58342(13) 0.60056(11) 0.7602(5) 0.0352(11) Uani 1 1 d . . . . .
C5 C 0.55424(13) 0.58341(12) 0.8031(4) 0.0347(11) Uani 1 1 d . . . . .
H5 H 0.555752 0.577546 0.874874 0.042 Uiso 1 1 calc R U . . .
C6 C 0.52237(12) 0.57429(11) 0.7446(4) 0.0268(9) Uani 1 1 d . . . . .
C7 C 0.57331(16) 0.62724(15) 0.4420(5) 0.0507(15) Uani 1 1 d . . . . .
H7A H 0.572660 0.648170 0.472762 0.076 Uiso 1 1 calc R U . . .
H7B H 0.568294 0.628603 0.366506 0.076 Uiso 1 1 calc R U . . .
H7C H 0.598402 0.617975 0.453527 0.076 Uiso 1 1 calc R U . . .
C8 C 0.61781(16) 0.60924(15) 0.8241(6) 0.0496(15) Uani 1 1 d . . . . .
H8A H 0.613756 0.603257 0.897445 0.074 Uiso 1 1 calc R U . . .
H8B H 0.621929 0.631791 0.819792 0.074 Uiso 1 1 calc R U . . .
H8C H 0.640129 0.598330 0.796496 0.074 Uiso 1 1 calc R U . . .
C9 C 0.49492(13) 0.55436(11) 0.7967(4) 0.0281(9) Uani 1 1 d . . . . .
H9 H 0.501563 0.546115 0.863384 0.034 Uiso 1 1 calc R U . . .
C10 C 0.43856(13) 0.52560(11) 0.8137(4) 0.0292(10) Uani 1 1 d . . . . .
C11 C 0.42806(15) 0.53151(12) 0.9173(5) 0.0396(11) Uani 1 1 d . . . . .
H11 H 0.438459 0.548849 0.953672 0.047 Uiso 1 1 calc R U . . .
C12 C 0.40232(18) 0.51192(14) 0.9671(5) 0.0469(14) Uani 1 1 d . . . . .
H12 H 0.395338 0.515672 1.038038 0.056 Uiso 1 1 calc R U . . .
C13 C 0.38702(15) 0.48718(13) 0.9138(5) 0.0445(12) Uani 1 1 d . . . . .
H13 H 0.369040 0.474018 0.947265 0.053 Uiso 1 1 calc R U . . .
C14 C 0.39781(15) 0.48137(12) 0.8107(4) 0.0364(11) Uani 1 1 d . . . . .
H14 H 0.387330 0.463974 0.774850 0.044 Uiso 1 1 calc R U . . .
C15 C 0.42342(13) 0.50032(11) 0.7595(4) 0.0287(9) Uani 1 1 d . . . . .
C16 C 0.43690(14) 0.49201(11) 0.6510(4) 0.0339(11) Uani 1 1 d . . . . .
H16A H 0.463200 0.483977 0.655881 0.041 Uiso 1 1 calc R U . . .
H16B H 0.420765 0.474988 0.623395 0.041 Uiso 1 1 calc R U . . .
C17 C 0.39873(12) 0.56416(9) 0.4213(4) 0.0277(9) Uani 1 1 d . . . . .
C18 C 0.40249(14) 0.56371(11) 0.3118(4) 0.0321(10) Uani 1 1 d . . . . .
C19 C 0.37444(17) 0.55167(13) 0.2465(4) 0.0407(13) Uani 1 1 d . . . . .
H19 H 0.377540 0.552296 0.172436 0.049 Uiso 1 1 calc R U . . .
C20 C 0.34187(17) 0.53875(14) 0.2900(5) 0.0480(15) Uani 1 1 d . . . . .
C21 C 0.33804(16) 0.53861(14) 0.3963(5) 0.0476(15) Uani 1 1 d . . . . .
H21 H 0.315924 0.529465 0.425837 0.057 Uiso 1 1 calc R U . . .
C22 C 0.36565(14) 0.55154(12) 0.4651(4) 0.0344(11) Uani 1 1 d . . . . .
C23 C 0.43823(19) 0.58392(19) 0.1669(5) 0.0634(18) Uani 1 1 d . . . . .
H23A H 0.437870 0.564769 0.124993 0.095 Uiso 1 1 calc R U . . .
H23B H 0.461824 0.595331 0.153192 0.095 Uiso 1 1 calc R U . . .
H23C H 0.416467 0.596966 0.147693 0.095 Uiso 1 1 calc R U . . .
C24 C 0.3114(2) 0.5256(2) 0.2188(6) 0.073(2) Uani 1 1 d . . . . .
H24A H 0.292046 0.515123 0.261291 0.110 Uiso 1 1 calc R U . . .
H24B H 0.322772 0.510687 0.169946 0.110 Uiso 1 1 calc R U . . .
H24C H 0.299579 0.542639 0.179105 0.110 Uiso 1 1 calc R U . . .
C25 C 0.35714(14) 0.55215(14) 0.5769(5) 0.0399(12) Uani 1 1 d . . . . .
C28 C 0.3296(4) 0.5475(4) 0.7785(9) 0.050(3) Uani 0.7 1 d D U P A 1
C29 C 0.3118(3) 0.5524(3) 0.8731(9) 0.062(3) Uani 0.7 1 d D U P A 1
H29 H 0.290689 0.539832 0.892012 0.074 Uiso 0.7 1 calc R U P A 1
C30 C 0.3243(3) 0.5754(3) 0.9415(9) 0.063(3) Uani 0.7 1 d D U P A 1
H30 H 0.310942 0.579119 1.005042 0.076 Uiso 0.7 1 calc R U P A 1
C31 C 0.35675(19) 0.59333(15) 0.9169(6) 0.0608(16) Uani 1 1 d D . . . .
H31 H 0.366400 0.608252 0.965033 0.073 Uiso 0.7 1 calc R U P A 1
H31A H 0.359974 0.612866 0.950745 0.073 Uiso 0.3 1 calc R U P A 2
C32 C 0.37415(17) 0.58856(14) 0.8205(5) 0.0464(13) Uani 1 1 d . . . . .
H32 H 0.395180 0.601140 0.800946 0.056 Uiso 1 1 calc R U . . .
C33 C 0.36130(15) 0.56575(13) 0.7526(5) 0.0384(12) Uani 1 1 d D . . . .
C34 C 0.45778(12) 0.63504(11) 0.6497(4) 0.0304(10) Uani 1 1 d . . . . .
C35 C 0.46437(14) 0.66432(12) 0.7177(5) 0.0371(12) Uani 1 1 d . . . . .
C36 C 0.4637(2) 0.69338(14) 0.6467(6) 0.066(2) Uani 1 1 d . . . . .
H36A H 0.469980 0.711857 0.688447 0.099 Uiso 1 1 calc R U . . .
H36B H 0.438324 0.695837 0.616260 0.099 Uiso 1 1 calc R U . . .
H36C H 0.482383 0.690931 0.590286 0.099 Uiso 1 1 calc R U . . .
C37 C 0.50342(19) 0.66094(18) 0.7646(7) 0.071(2) Uani 1 1 d . . . . .
H37A H 0.508159 0.678214 0.813205 0.107 Uiso 1 1 calc R U . . .
H37B H 0.522456 0.661274 0.708504 0.107 Uiso 1 1 calc R U . . .
H37C H 0.505058 0.641144 0.802682 0.107 Uiso 1 1 calc R U . . .
C38 C 0.43453(17) 0.66756(16) 0.8018(5) 0.0531(16) Uani 1 1 d . . . . .
H38A H 0.435410 0.649367 0.848180 0.080 Uiso 1 1 calc R U . . .
H38B H 0.409399 0.668949 0.769064 0.080 Uiso 1 1 calc R U . . .
H38C H 0.439385 0.686477 0.842704 0.080 Uiso 1 1 calc R U . . .
C39 C 0.45937(15) 0.65766(13) 0.3227(4) 0.0384(12) Uani 1 1 d . . . . .
C40 C 0.44796(17) 0.68821(15) 0.2685(6) 0.0512(15) Uani 1 1 d . . . . .
C41 C 0.4081(2) 0.69754(17) 0.3047(8) 0.075(2) Uani 1 1 d . . . . .
H41A H 0.400708 0.717123 0.270715 0.113 Uiso 1 1 calc R U . . .
H41B H 0.407978 0.700321 0.381049 0.113 Uiso 1 1 calc R U . . .
H41C H 0.389969 0.681156 0.285477 0.113 Uiso 1 1 calc R U . . .
C42 C 0.4478(3) 0.6818(2) 0.1501(7) 0.095(3) Uani 1 1 d . . . . .
H42A H 0.473281 0.675553 0.127523 0.142 Uiso 1 1 calc R U . . .
H42B H 0.440124 0.700654 0.112391 0.142 Uiso 1 1 calc R U . . .
H42C H 0.429790 0.664946 0.134605 0.142 Uiso 1 1 calc R U . . .
C43 C 0.4757(2) 0.71390(16) 0.2980(8) 0.069(2) Uani 1 1 d . . . . .
H43A H 0.501724 0.706435 0.288441 0.104 Uiso 1 1 calc R U . . .
H43B H 0.471771 0.719765 0.371562 0.104 Uiso 1 1 calc R U . . .
H43C H 0.471330 0.732084 0.252998 0.104 Uiso 1 1 calc R U . . .
C44 C 0.52610(15) 0.56573(12) 0.2859(4) 0.0358(11) Uani 1 1 d . . . . .
C45 C 0.5526(2) 0.54743(15) 0.2151(6) 0.0584(18) Uani 1 1 d . . . . .
C46 C 0.5291(3) 0.5427(2) 0.1080(7) 0.092(3) Uani 1 1 d . . . . .
H46A H 0.543804 0.550866 0.048834 0.137 Uiso 1 1 calc R U . . .
H46B H 0.504859 0.553806 0.112810 0.137 Uiso 1 1 calc R U . . .
H46C H 0.524250 0.520406 0.097095 0.137 Uiso 1 1 calc R U . . .
C47 C 0.5871(3) 0.5655(2) 0.1905(11) 0.123(5) Uani 1 1 d . . . . .
H47A H 0.579977 0.586452 0.167648 0.185 Uiso 1 1 calc R U . . .
H47B H 0.601241 0.555027 0.134213 0.185 Uiso 1 1 calc R U . . .
H47C H 0.603162 0.566870 0.253214 0.185 Uiso 1 1 calc R U . . .
C48 C 0.5599(2) 0.51563(18) 0.2547(7) 0.075(2) Uani 1 1 d . . . . .
H48A H 0.536419 0.503422 0.251423 0.113 Uiso 1 1 calc R U . . .
H48B H 0.568733 0.516732 0.327524 0.113 Uiso 1 1 calc R U . . .
H48C H 0.579396 0.505630 0.211277 0.113 Uiso 1 1 calc R U . . .
O14 O 0.32334(15) 0.53765(16) 0.5961(5) 0.0511(14) Uani 0.7 1 d . U P A 1
C26 C 0.3175(3) 0.5245(3) 0.6992(8) 0.053(2) Uani 0.7 1 d . U P A 1
H26A H 0.332519 0.505112 0.706741 0.064 Uiso 0.7 1 calc R U P A 1
H26B H 0.290358 0.519322 0.709132 0.064 Uiso 0.7 1 calc R U P A 1
H13A H 0.503(2) 0.5155(15) 0.434(6) 0.07(2) Uiso 1 1 d . . . . .
H3 H 0.4536(13) 0.5182(14) 0.536(4) 0.043(18) Uiso 1 1 d D . . . .
O13 O 0.500000 0.500000 0.4726(4) 0.0319(10) Uani 1 2 d S T P . .
C28A C 0.3349(10) 0.5450(9) 0.798(2) 0.050(3) Uani 0.3 1 d D U P A 2
C26A C 0.3183(9) 0.5165(7) 0.743(3) 0.067(7) Uani 0.3 1 d . . P A 2
H26C H 0.337368 0.507803 0.693678 0.080 Uiso 0.3 1 calc R U P A 2
H26D H 0.312164 0.500195 0.795211 0.080 Uiso 0.3 1 calc R U P A 2
C29A C 0.3214(8) 0.5472(6) 0.899(2) 0.062(3) Uani 0.3 1 d D U P A 2
H29A H 0.302886 0.532762 0.923576 0.074 Uiso 0.3 1 calc R U P A 2
C30A C 0.3345(8) 0.5704(6) 0.966(2) 0.063(3) Uani 0.3 1 d D U P A 2
H30A H 0.328996 0.570790 1.039335 0.076 Uiso 0.3 1 calc R U P A 2
O14A O 0.2841(5) 0.5247(5) 0.685(2) 0.089(6) Uani 0.3 1 d . . P A 2
H14A H 0.274620 0.508540 0.658397 0.134 Uiso 0.3 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.376(3) . ?
Dy1 O2 2.487(3) . ?
Dy1 O4 2.296(3) . ?
Dy1 O5 2.614(4) . ?
Dy1 O8 2.316(4) . ?
Dy1 O9 2.397(4) . ?
Dy1 O10 2.424(4) . ?
Dy1 O12 2.468(3) . ?
Dy1 O11 2.422(4) . ?
Co1 O1 2.075(3) . ?
Co1 O3 2.237(3) . ?
Co1 O4 2.004(3) . ?
Co1 O7 2.089(3) . ?
Co1 N1 2.064(4) . ?
Co1 N2 2.117(4) . ?
O1 C1 1.320(5) . ?
O2 C2 1.381(6) . ?
O2 C7 1.437(6) . ?
O3 C16 1.424(6) . ?
O3 H3 0.82(3) . ?
O4 C17 1.329(5) . ?
O5 C18 1.372(6) . ?
O5 C23 1.442(8) . ?
O7 C34 1.257(6) . ?
O8 C34 1.257(6) . ?
O9 C39 1.253(7) . ?
O10 C39 1.265(7) . ?
O12 C44 1.261(6) . ?
O11 C44 1.263(6) . ?
N1 C9 1.295(6) . ?
N1 C10 1.421(6) . ?
N2 C25 1.279(7) . ?
N2 C33 1.430(7) . ?
C1 C2 1.416(6) . ?
C1 C6 1.410(7) . ?
C2 C3 1.376(7) . ?
C3 H3A 0.9500 . ?
C3 C4 1.397(8) . ?
C4 C5 1.377(7) . ?
C4 C8 1.506(7) . ?
C5 H5 0.9500 . ?
C5 C6 1.403(6) . ?
C6 C9 1.451(7) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9 0.9500 . ?
C10 C11 1.393(8) . ?
C10 C15 1.392(7) . ?
C11 H11 0.9500 . ?
C11 C12 1.390(8) . ?
C12 H12 0.9500 . ?
C12 C13 1.371(9) . ?
C13 H13 0.9500 . ?
C13 C14 1.389(9) . ?
C14 H14 0.9500 . ?
C14 C15 1.379(7) . ?
C15 C16 1.505(7) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.400(7) . ?
C17 C22 1.401(7) . ?
C18 C19 1.391(7) . ?
C19 H19 0.9500 . ?
C19 C20 1.389(9) . ?
C20 C21 1.361(9) . ?
C20 C24 1.513(8) . ?
C21 H21 0.9500 . ?
C21 C22 1.422(7) . ?
C22 C25 1.456(8) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 O14 1.365(7) . ?
C28 C29 1.375(13) . ?
C28 C33 1.402(11) . ?
C28 C26 1.477(16) . ?
C29 H29 0.9500 . ?
C29 C30 1.387(13) . ?
C30 H30 0.9500 . ?
C30 C31 1.413(12) . ?
C31 H31 0.9500 . ?
C31 H31A 0.9500 . ?
C31 C32 1.387(9) . ?
C31 C30A 1.41(2) . ?
C32 H32 0.9500 . ?
C32 C33 1.382(8) . ?
C33 C28A 1.42(2) . ?
C34 C35 1.544(7) . ?
C35 C36 1.541(9) . ?
C35 C37 1.507(8) . ?
C35 C38 1.507(8) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.535(8) . ?
C40 C41 1.532(9) . ?
C40 C42 1.534(12) . ?
C40 C43 1.519(10) . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 C45 1.518(7) . ?
C45 C46 1.610(13) . ?
C45 C47 1.474(10) . ?
C45 C48 1.477(10) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
O14 C26 1.444(12) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
O13 H13A 0.83(7) . ?
C28A C26A 1.53(4) . ?
C28A C29A 1.37(2) . ?
C26A H26C 0.9900 . ?
C26A H26D 0.9900 . ?
C26A O14A 1.45(3) . ?
C29A H29A 0.9500 . ?
C29A C30A 1.39(2) . ?
C30A H30A 0.9500 . ?
O14A H14A 0.8400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O2 64.07(11) . . ?
O1 Dy1 O5 117.61(12) . . ?
O1 Dy1 O9 142.20(12) . . ?
O1 Dy1 O10 137.33(13) . . ?
O1 Dy1 O12 73.82(11) . . ?
O1 Dy1 O11 118.79(12) . . ?
O2 Dy1 O5 147.58(12) . . ?
O4 Dy1 O1 68.17(11) . . ?
O4 Dy1 O2 132.13(11) . . ?
O4 Dy1 O5 62.68(11) . . ?
O4 Dy1 O8 84.90(12) . . ?
O4 Dy1 O9 84.22(13) . . ?
O4 Dy1 O10 136.34(12) . . ?
O4 Dy1 O12 91.25(11) . . ?
O4 Dy1 O11 132.33(13) . . ?
O8 Dy1 O1 73.22(12) . . ?
O8 Dy1 O2 78.66(12) . . ?
O8 Dy1 O5 133.73(12) . . ?
O8 Dy1 O9 79.28(14) . . ?
O8 Dy1 O10 75.48(14) . . ?
O8 Dy1 O12 145.79(12) . . ?
O8 Dy1 O11 142.62(13) . . ?
O9 Dy1 O2 134.65(13) . . ?
O9 Dy1 O5 66.15(13) . . ?
O9 Dy1 O10 54.26(13) . . ?
O9 Dy1 O12 134.22(13) . . ?
O9 Dy1 O11 98.81(14) . . ?
O10 Dy1 O2 81.97(12) . . ?
O10 Dy1 O5 104.95(14) . . ?
O10 Dy1 O12 126.14(12) . . ?
O12 Dy1 O2 78.99(12) . . ?
O12 Dy1 O5 71.38(12) . . ?
O11 Dy1 O2 76.74(13) . . ?
O11 Dy1 O5 75.14(13) . . ?
O11 Dy1 O10 73.59(13) . . ?
O11 Dy1 O12 53.16(12) . . ?
O1 Co1 Dy1 43.11(9) . . ?
O1 Co1 O3 93.33(12) . . ?
O1 Co1 O7 85.90(13) . . ?
O1 Co1 N2 168.53(14) . . ?
O3 Co1 Dy1 102.06(9) . . ?
O4 Co1 Dy1 40.35(9) . . ?
O4 Co1 O1 79.89(13) . . ?
O4 Co1 O3 85.25(13) . . ?
O4 Co1 O7 101.81(14) . . ?
O4 Co1 N1 159.61(15) . . ?
O4 Co1 N2 88.66(14) . . ?
O7 Co1 Dy1 82.38(10) . . ?
O7 Co1 O3 172.63(13) . . ?
O7 Co1 N2 97.25(14) . . ?
N1 Co1 Dy1 129.45(11) . . ?
N1 Co1 O1 86.48(14) . . ?
N1 Co1 O3 80.44(14) . . ?
N1 Co1 O7 92.20(15) . . ?
N1 Co1 N2 104.35(15) . . ?
N2 Co1 Dy1 126.20(11) . . ?
N2 Co1 O3 84.93(14) . . ?
Co1 O1 Dy1 100.25(12) . . ?
C1 O1 Dy1 120.9(3) . . ?
C1 O1 Co1 121.2(3) . . ?
C2 O2 Dy1 117.4(3) . . ?
C2 O2 C7 117.4(4) . . ?
C7 O2 Dy1 122.4(3) . . ?
Co1 O3 H3 97(4) . . ?
C16 O3 Co1 123.0(3) . . ?
C16 O3 H3 117(4) . . ?
Co1 O4 Dy1 105.25(13) . . ?
C17 O4 Dy1 128.5(3) . . ?
C17 O4 Co1 124.8(3) . . ?
C18 O5 Dy1 116.9(3) . . ?
C18 O5 C23 116.8(4) . . ?
C23 O5 Dy1 122.2(4) . . ?
C34 O7 Co1 126.4(3) . . ?
C34 O8 Dy1 139.2(3) . . ?
C39 O9 Dy1 92.8(3) . . ?
C39 O10 Dy1 91.2(3) . . ?
C44 O12 Dy1 92.2(3) . . ?
C44 O11 Dy1 94.3(3) . . ?
C9 N1 Co1 125.0(3) . . ?
C9 N1 C10 119.5(4) . . ?
C10 N1 Co1 115.2(3) . . ?
C25 N2 Co1 120.3(4) . . ?
C25 N2 C33 117.6(4) . . ?
C33 N2 Co1 121.9(3) . . ?
O1 C1 C2 117.7(4) . . ?
O1 C1 C6 124.9(4) . . ?
C6 C1 C2 117.4(4) . . ?
O2 C2 C1 113.5(4) . . ?
C3 C2 O2 124.7(4) . . ?
C3 C2 C1 121.8(5) . . ?
C2 C3 H3A 119.7 . . ?
C2 C3 C4 120.5(5) . . ?
C4 C3 H3A 119.7 . . ?
C3 C4 C8 120.4(5) . . ?
C5 C4 C3 118.4(4) . . ?
C5 C4 C8 121.2(5) . . ?
C4 C5 H5 118.8 . . ?
C4 C5 C6 122.4(5) . . ?
C6 C5 H5 118.8 . . ?
C1 C6 C9 123.3(4) . . ?
C5 C6 C1 119.4(4) . . ?
C5 C6 C9 117.1(4) . . ?
O2 C7 H7A 109.5 . . ?
O2 C7 H7B 109.5 . . ?
O2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C4 C8 H8A 109.5 . . ?
C4 C8 H8B 109.5 . . ?
C4 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N1 C9 C6 124.7(4) . . ?
N1 C9 H9 117.7 . . ?
C6 C9 H9 117.7 . . ?
C11 C10 N1 120.3(4) . . ?
C15 C10 N1 118.8(4) . . ?
C15 C10 C11 120.7(5) . . ?
C10 C11 H11 120.2 . . ?
C12 C11 C10 119.7(5) . . ?
C12 C11 H11 120.2 . . ?
C11 C12 H12 120.1 . . ?
C13 C12 C11 119.9(6) . . ?
C13 C12 H12 120.1 . . ?
C12 C13 H13 120.0 . . ?
C12 C13 C14 120.0(5) . . ?
C14 C13 H13 120.0 . . ?
C13 C14 H14 119.3 . . ?
C15 C14 C13 121.3(5) . . ?
C15 C14 H14 119.3 . . ?
C10 C15 C16 121.3(4) . . ?
C14 C15 C10 118.4(5) . . ?
C14 C15 C16 120.1(5) . . ?
O3 C16 C15 114.3(4) . . ?
O3 C16 H16A 108.7 . . ?
O3 C16 H16B 108.7 . . ?
C15 C16 H16A 108.7 . . ?
C15 C16 H16B 108.7 . . ?
H16A C16 H16B 107.6 . . ?
O4 C17 C18 117.7(4) . . ?
O4 C17 C22 124.3(5) . . ?
C18 C17 C22 118.0(4) . . ?
O5 C18 C17 113.6(4) . . ?
O5 C18 C19 124.2(5) . . ?
C19 C18 C17 122.3(5) . . ?
C18 C19 H19 120.1 . . ?
C20 C19 C18 119.7(5) . . ?
C20 C19 H19 120.1 . . ?
C19 C20 C24 119.7(6) . . ?
C21 C20 C19 118.7(5) . . ?
C21 C20 C24 121.6(6) . . ?
C20 C21 H21 118.5 . . ?
C20 C21 C22 123.0(6) . . ?
C22 C21 H21 118.5 . . ?
C17 C22 C21 118.3(5) . . ?
C17 C22 C25 123.7(5) . . ?
C21 C22 C25 118.0(5) . . ?
O5 C23 H23A 109.5 . . ?
O5 C23 H23B 109.5 . . ?
O5 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C20 C24 H24A 109.5 . . ?
C20 C24 H24B 109.5 . . ?
C20 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N2 C25 C22 128.0(5) . . ?
N2 C25 O14 121.4(5) . . ?
O14 C25 C22 110.3(5) . . ?
C29 C28 C33 119.0(10) . . ?
C29 C28 C26 124.8(9) . . ?
C33 C28 C26 116.3(9) . . ?
C28 C29 H29 119.5 . . ?
C28 C29 C30 120.9(10) . . ?
C30 C29 H29 119.5 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.3(10) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 120.9 . . ?
C32 C31 C30 118.3(8) . . ?
C32 C31 H31 120.9 . . ?
C32 C31 H31A 118.7 . . ?
C32 C31 C30A 122.7(13) . . ?
C30A C31 H31A 118.7 . . ?
C31 C32 H32 119.5 . . ?
C33 C32 C31 120.9(6) . . ?
C33 C32 H32 119.5 . . ?
C28 C33 N2 118.4(7) . . ?
C32 C33 N2 120.9(5) . . ?
C32 C33 C28 120.6(7) . . ?
C32 C33 C28A 113.8(12) . . ?
C28A C33 N2 124.6(13) . . ?
O7 C34 C35 118.0(5) . . ?
O8 C34 O7 124.5(5) . . ?
O8 C34 C35 117.4(4) . . ?
C36 C35 C34 109.1(5) . . ?
C37 C35 C34 106.4(4) . . ?
C37 C35 C36 108.9(6) . . ?
C37 C35 C38 111.3(6) . . ?
C38 C35 C34 111.7(4) . . ?
C38 C35 C36 109.4(5) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C35 C37 H37A 109.5 . . ?
C35 C37 H37B 109.5 . . ?
C35 C37 H37C 109.5 . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C35 C38 H38A 109.5 . . ?
C35 C38 H38B 109.5 . . ?
C35 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
O9 C39 Dy1 60.2(3) . . ?
O9 C39 O10 121.7(5) . . ?
O9 C39 C40 119.6(5) . . ?
O10 C39 Dy1 61.5(3) . . ?
O10 C39 C40 118.7(5) . . ?
C40 C39 Dy1 179.1(5) . . ?
C41 C40 C39 109.1(5) . . ?
C41 C40 C42 109.8(7) . . ?
C42 C40 C39 106.8(6) . . ?
C43 C40 C39 109.9(5) . . ?
C43 C40 C41 108.9(6) . . ?
C43 C40 C42 112.2(7) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C40 C42 H42A 109.5 . . ?
C40 C42 H42B 109.5 . . ?
C40 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C40 C43 H43A 109.5 . . ?
C40 C43 H43B 109.5 . . ?
C40 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
O12 C44 Dy1 61.2(3) . . ?
O12 C44 O11 120.2(5) . . ?
O12 C44 C45 121.1(5) . . ?
O11 C44 Dy1 59.1(3) . . ?
O11 C44 C45 118.6(5) . . ?
C45 C44 Dy1 176.9(4) . . ?
C44 C45 C46 104.6(6) . . ?
C47 C45 C44 111.3(6) . . ?
C47 C45 C46 108.1(8) . . ?
C47 C45 C48 114.5(7) . . ?
C48 C45 C44 112.4(5) . . ?
C48 C45 C46 105.1(7) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C45 C48 H48A 109.5 . . ?
C45 C48 H48B 109.5 . . ?
C45 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C25 O14 C26 117.7(6) . . ?
C28 C26 H26A 110.0 . . ?
C28 C26 H26B 110.0 . . ?
O14 C26 C28 108.6(9) . . ?
O14 C26 H26A 110.0 . . ?
O14 C26 H26B 110.0 . . ?
H26A C26 H26B 108.3 . . ?
H13A O13 H13A 108(10) . 2_665 ?
C33 C28A C26A 124(2) . . ?
C29A C28A C33 125(2) . . ?
C29A C28A C26A 111(2) . . ?
C28A C26A H26C 109.5 . . ?
C28A C26A H26D 109.5 . . ?
H26C C26A H26D 108.0 . . ?
O14A C26A C28A 111(3) . . ?
O14A C26A H26C 109.5 . . ?
O14A C26A H26D 109.5 . . ?
C28A C29A H29A 119.7 . . ?
C28A C29A C30A 121(2) . . ?
C30A C29A H29A 119.7 . . ?
C31 C30A H30A 122.9 . . ?
C29A C30A C31 114(2) . . ?
C29A C30A H30A 122.9 . . ?
C26A O14A H14A 109.5 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C7 H7B O11 0.98 2.58 3.239(8) 124.8 . yes
C23 H23B O11 0.98 2.52 3.190(8) 125.7 . yes
C32 H32 O7 0.95 2.21 3.070(7) 150.2 . yes

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C1 C2 -23.1(5) . . . . ?
Dy1 O1 C1 C6 158.6(3) . . . . ?
Dy1 O2 C2 C1 16.5(5) . . . . ?
Dy1 O2 C2 C3 -163.8(4) . . . . ?
Dy1 O4 C17 C18 6.5(6) . . . . ?
Dy1 O4 C17 C22 -173.5(3) . . . . ?
Dy1 O5 C18 C17 -6.5(5) . . . . ?
Dy1 O5 C18 C19 173.6(4) . . . . ?
Dy1 O8 C34 O7 -13.5(8) . . . . ?
Dy1 O8 C34 C35 165.8(3) . . . . ?
Dy1 O9 C39 O10 0.8(6) . . . . ?
Dy1 O9 C39 C40 179.0(5) . . . . ?
Dy1 O10 C39 O9 -0.7(6) . . . . ?
Dy1 O10 C39 C40 -179.0(5) . . . . ?
Dy1 O12 C44 O11 -4.1(6) . . . . ?
Dy1 O12 C44 C45 177.6(6) . . . . ?
Dy1 O11 C44 O12 4.2(6) . . . . ?
Dy1 O11 C44 C45 -177.5(5) . . . . ?
Co1 O1 C1 C2 -150.3(3) . . . . ?
Co1 O1 C1 C6 31.4(6) . . . . ?
Co1 O3 C16 C15 22.7(5) . . . . ?
Co1 O4 C17 C18 -157.4(3) . . . . ?
Co1 O4 C17 C22 22.6(6) . . . . ?
Co1 O7 C34 O8 9.8(6) . . . . ?
Co1 O7 C34 C35 -169.5(3) . . . . ?
Co1 N1 C9 C6 -10.3(7) . . . . ?
Co1 N1 C10 C11 -117.5(4) . . . . ?
Co1 N1 C10 C15 56.5(5) . . . . ?
Co1 N2 C25 C22 -16.8(8) . . . . ?
Co1 N2 C25 O14 155.7(5) . . . . ?
Co1 N2 C33 C28 -147.2(8) . . . . ?
Co1 N2 C33 C32 36.7(7) . . . . ?
Co1 N2 C33 C28A -133(2) . . . . ?
O1 C1 C2 O2 3.2(6) . . . . ?
O1 C1 C2 C3 -176.6(4) . . . . ?
O1 C1 C6 C5 176.5(4) . . . . ?
O1 C1 C6 C9 2.1(7) . . . . ?
O2 C2 C3 C4 179.4(4) . . . . ?
O4 C17 C18 O5 1.0(6) . . . . ?
O4 C17 C18 C19 -179.0(4) . . . . ?
O4 C17 C22 C21 -179.2(4) . . . . ?
O4 C17 C22 C25 3.7(8) . . . . ?
O5 C18 C19 C20 178.1(5) . . . . ?
O7 C34 C35 C36 -151.2(5) . . . . ?
O7 C34 C35 C37 91.4(6) . . . . ?
O7 C34 C35 C38 -30.2(7) . . . . ?
O8 C34 C35 C36 29.4(6) . . . . ?
O8 C34 C35 C37 -88.0(6) . . . . ?
O8 C34 C35 C38 150.4(5) . . . . ?
O9 C39 C40 C41 35.9(9) . . . . ?
O9 C39 C40 C42 -82.8(7) . . . . ?
O9 C39 C40 C43 155.3(6) . . . . ?
O10 C39 C40 C41 -145.8(7) . . . . ?
O10 C39 C40 C42 95.5(8) . . . . ?
O10 C39 C40 C43 -26.3(8) . . . . ?
O12 C44 C45 C46 105.3(7) . . . . ?
O12 C44 C45 C47 -138.2(8) . . . . ?
O12 C44 C45 C48 -8.3(10) . . . . ?
O11 C44 C45 C46 -73.1(8) . . . . ?
O11 C44 C45 C47 43.5(10) . . . . ?
O11 C44 C45 C48 173.4(7) . . . . ?
N1 C10 C11 C12 174.1(5) . . . . ?
N1 C10 C15 C14 -173.9(4) . . . . ?
N1 C10 C15 C16 11.3(7) . . . . ?
N2 C25 O14 C26 -19.1(10) . . . . ?
N2 C33 C28A C26A -6(5) . . . . ?
N2 C33 C28A C29A 173(3) . . . . ?
C1 C2 C3 C4 -0.9(7) . . . . ?
C1 C6 C9 N1 -14.3(7) . . . . ?
C2 C1 C6 C5 -1.8(6) . . . . ?
C2 C1 C6 C9 -176.2(4) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
C2 C3 C4 C8 178.3(5) . . . . ?
C3 C4 C5 C6 0.1(7) . . . . ?
C4 C5 C6 C1 0.9(7) . . . . ?
C4 C5 C6 C9 175.6(5) . . . . ?
C5 C6 C9 N1 171.2(5) . . . . ?
C6 C1 C2 O2 -178.4(4) . . . . ?
C6 C1 C2 C3 1.9(7) . . . . ?
C7 O2 C2 C1 178.2(4) . . . . ?
C7 O2 C2 C3 -2.0(7) . . . . ?
C8 C4 C5 C6 -178.2(5) . . . . ?
C9 N1 C10 C11 56.9(6) . . . . ?
C9 N1 C10 C15 -129.1(5) . . . . ?
C10 N1 C9 C6 175.9(4) . . . . ?
C10 C11 C12 C13 -0.9(9) . . . . ?
C10 C15 C16 O3 -52.2(6) . . . . ?
C11 C10 C15 C14 0.1(7) . . . . ?
C11 C10 C15 C16 -174.7(5) . . . . ?
C11 C12 C13 C14 1.3(9) . . . . ?
C12 C13 C14 C15 -1.0(9) . . . . ?
C13 C14 C15 C10 0.3(8) . . . . ?
C13 C14 C15 C16 175.1(5) . . . . ?
C14 C15 C16 O3 133.1(5) . . . . ?
C15 C10 C11 C12 0.2(8) . . . . ?
C17 C18 C19 C20 -1.9(8) . . . . ?
C17 C22 C25 N2 -5.7(9) . . . . ?
C17 C22 C25 O14 -178.9(5) . . . . ?
C18 C17 C22 C21 0.9(7) . . . . ?
C18 C17 C22 C25 -176.3(5) . . . . ?
C18 C19 C20 C21 0.9(9) . . . . ?
C18 C19 C20 C24 -180.0(6) . . . . ?
C19 C20 C21 C22 1.0(9) . . . . ?
C20 C21 C22 C17 -1.9(9) . . . . ?
C20 C21 C22 C25 175.4(6) . . . . ?
C21 C22 C25 N2 177.1(6) . . . . ?
C21 C22 C25 O14 3.9(8) . . . . ?
C22 C17 C18 O5 -179.0(4) . . . . ?
C22 C17 C18 C19 1.0(7) . . . . ?
C22 C25 O14 C26 154.7(7) . . . . ?
C23 O5 C18 C17 -164.5(5) . . . . ?
C23 O5 C18 C19 15.5(8) . . . . ?
C24 C20 C21 C22 -178.1(6) . . . . ?
C25 N2 C33 C28 28.1(10) . . . . ?
C25 N2 C33 C32 -147.9(6) . . . . ?
C25 N2 C33 C28A 42(2) . . . . ?
C25 O14 C26 C28 46.0(12) . . . . ?
C28 C29 C30 C31 -2.9(19) . . . . ?
C29 C28 C33 N2 -176.9(10) . . . . ?
C29 C28 C33 C32 -0.8(17) . . . . ?
C29 C28 C26 O14 142.8(13) . . . . ?
C29 C30 C31 C32 3.9(15) . . . . ?
C30 C31 C32 C33 -3.3(11) . . . . ?
C31 C32 C33 N2 177.8(6) . . . . ?
C31 C32 C33 C28 1.9(12) . . . . ?
C31 C32 C33 C28A -11(2) . . . . ?
C32 C31 C30A C29A -20(4) . . . . ?
C32 C33 C28A C26A -176(3) . . . . ?
C32 C33 C28A C29A 3(5) . . . . ?
C33 N2 C25 C22 167.8(5) . . . . ?
C33 N2 C25 O14 -19.7(8) . . . . ?
C33 C28 C29 C30 1(2) . . . . ?
C33 C28 C26 O14 -36.1(15) . . . . ?
C33 C28A C26A O14A -89(4) . . . . ?
C33 C28A C29A C30A -2(6) . . . . ?
C26 C28 C29 C30 -177.5(13) . . . . ?
C26 C28 C33 N2 2.1(16) . . . . ?
C26 C28 C33 C32 178.1(9) . . . . ?
C28A C29A C30A C31 10(5) . . . . ?
C26A C28A C29A C30A 176(3) . . . . ?
C29A C28A C26A O14A 93(4) . . . . ?
C30A C31 C32 C33 21(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
