# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mx8857a_sq
_database_code_depnum_ccdc_archive 'CCDC 2108770'
loop_
_audit_author_name
_audit_author_address
'Zhixun Luo'
;Institute of Chemistry, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2024-01-20 deposited with the CCDC.	2024-03-18 downloaded from the CCDC.
;
_audit_creation_date             2020-11-05
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '1(C150 H114 Ag8 N6 P6), 2(C1 H1 Cl3)'
_chemical_formula_sum            'C152 H116 Ag8 Cl6 N6 P6'
_chemical_formula_weight         3287.92
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           155
_space_group_name_H-M_alt        'R 3 2'
_space_group_name_Hall           'R 3 2"'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'

_cell_length_a                   17.4780(3)
_cell_length_b                   17.4780(3)
_cell_length_c                   39.6944(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     10501.3(4)
_cell_formula_units_Z            3.00006
_cell_measurement_reflns_used    32205
_cell_measurement_temperature    110.01(10)
_cell_measurement_theta_max      30.6480
_cell_measurement_theta_min      1.4180
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.330
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.90394
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.45i (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.560
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4914
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.23
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0182
_diffrn_reflns_av_unetI/netI     0.0126
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       51
_diffrn_reflns_limit_l_min       -51
_diffrn_reflns_number            33066
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.497
_diffrn_reflns_theta_min         1.440
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      110.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -77.00  55.00   0.50    5.00    --  -14.80  45.00  -6.56  264
  2  ω   -104.00  66.00   0.50    5.00    --  -14.80  45.00  30.00  340
  3  ω    -85.00  -2.00   0.50    5.00    --  -14.80  45.00 150.00  166
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC10 (RCD3): fixed-chi single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0251327000
_diffrn_orient_matrix_UB_12      0.0329188000
_diffrn_orient_matrix_UB_13      0.0121546000
_diffrn_orient_matrix_UB_21      0.0383908000
_diffrn_orient_matrix_UB_22      0.0144881000
_diffrn_orient_matrix_UB_23      -0.0100286000
_diffrn_orient_matrix_UB_31      -0.0095549000
_diffrn_orient_matrix_UB_32      0.0300268000
_diffrn_orient_matrix_UB_33      -0.0084077000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.821
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                5338
_reflns_number_total             5395
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.398
_refine_diff_density_min         -1.536
_refine_diff_density_rms         0.083
_refine_ls_abs_structure_details 
;
 Flack x determined using 2395 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.003(5)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     269
_refine_ls_number_reflns         5395
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0198
_refine_ls_R_factor_gt           0.0196
_refine_ls_restrained_S_all      1.089
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0419P)²+10.0672P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0584
_refine_ls_wR_factor_ref         0.0587
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Ternary CH refined with riding coordinates:
 C26(H26)
2.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C10(H10), C11(H11), C12(H12),
 C13(H13), C15(H15), C16(H16), C17(H17), C18(H18), C19(H19), C21(H21), C22(H22),
  C23(H23), C24(H24), C25(H25)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.333333 0.46766(2) 0.666667 0.01814(8) Uani 1 2 d S T P . .
Ag2 Ag 0.18881(2) 0.52215(2) 0.666667 0.01798(8) Uani 1 2 d S T P . .
Ag3 Ag 0.333333 0.666667 0.62888(2) 0.01931(9) Uani 1 3 d S T P . .
P1 P 0.21149(5) 0.32438(5) 0.69035(2) 0.01939(16) Uani 1 1 d . . . . .
N1 N 0.10419(19) 0.38494(19) 0.70659(7) 0.0246(6) Uani 1 1 d . . . . .
C1 C 0.2632(2) 0.5115(2) 0.62547(7) 0.0189(6) Uani 1 1 d . . . . .
C2 C 0.2901(2) 0.5123(2) 0.59728(8) 0.0214(6) Uani 1 1 d . . . . .
C3 C 0.3173(3) 0.5079(2) 0.56345(9) 0.0278(7) Uani 1 1 d . . . . .
C4 C 0.2574(3) 0.4432(3) 0.54131(11) 0.0447(10) Uani 1 1 d . . . . .
H4 H 0.199829 0.404182 0.548165 0.054 Uiso 1 1 calc R . . . .
C5 C 0.2849(4) 0.4382(4) 0.50903(13) 0.0674(18) Uani 1 1 d . . . . .
H5 H 0.245518 0.395159 0.494278 0.081 Uiso 1 1 calc R . . . .
C6 C 0.3690(5) 0.4955(5) 0.49859(13) 0.0730(19) Uani 1 1 d . . . . .
H6 H 0.385801 0.491981 0.476674 0.088 Uiso 1 1 calc R . . . .
C7 C 0.4296(4) 0.5589(4) 0.52044(11) 0.0553(13) Uani 1 1 d . . . . .
H7 H 0.487585 0.595989 0.513508 0.066 Uiso 1 1 calc R . . . .
C8 C 0.4034(3) 0.5667(3) 0.55266(9) 0.0366(9) Uani 1 1 d . . . . .
H8 H 0.442909 0.610787 0.567035 0.044 Uiso 1 1 calc R . . . .
C9 C 0.1306(2) 0.3293(2) 0.71810(8) 0.0215(6) Uani 1 1 d . . . . .
C10 C 0.0972(2) 0.2796(3) 0.74735(9) 0.0293(7) Uani 1 1 d . . . . .
H10 H 0.115693 0.240572 0.754243 0.035 Uiso 1 1 calc R . . . .
C11 C 0.0353(3) 0.2899(3) 0.76614(9) 0.0313(8) Uani 1 1 d . . . . .
H11 H 0.012606 0.258871 0.786107 0.038 Uiso 1 1 calc R . . . .
C12 C 0.0086(2) 0.3471(2) 0.75442(9) 0.0290(7) Uani 1 1 d . . . . .
H12 H -0.032297 0.355402 0.766496 0.035 Uiso 1 1 calc R . . . .
C13 C 0.0429(2) 0.3916(2) 0.72469(10) 0.0287(7) Uani 1 1 d . . . . .
H13 H 0.022598 0.428328 0.716715 0.034 Uiso 1 1 calc R . . . .
C14 C 0.2546(2) 0.2665(2) 0.71491(8) 0.0238(6) Uani 1 1 d . . . . .
C15 C 0.2920(2) 0.3009(2) 0.74657(9) 0.0267(7) Uani 1 1 d . . . . .
H15 H 0.286917 0.346888 0.755958 0.032 Uiso 1 1 calc R . . . .
C16 C 0.3364(3) 0.2660(3) 0.76365(9) 0.0314(8) Uani 1 1 d . . . . .
H16 H 0.361048 0.288909 0.784600 0.038 Uiso 1 1 calc R . . . .
C17 C 0.3448(3) 0.1982(3) 0.75024(10) 0.0349(8) Uani 1 1 d . . . . .
H17 H 0.375653 0.175889 0.761884 0.042 Uiso 1 1 calc R . . . .
C18 C 0.3072(3) 0.1632(3) 0.71933(10) 0.0358(8) Uani 1 1 d . . . . .
H18 H 0.311969 0.116668 0.710261 0.043 Uiso 1 1 calc R . . . .
C19 C 0.2624(3) 0.1974(2) 0.70183(10) 0.0297(8) Uani 1 1 d . . . . .
H19 H 0.237240 0.173627 0.681032 0.036 Uiso 1 1 calc R . . . .
C20 C 0.1398(2) 0.2458(2) 0.65851(9) 0.0228(6) Uani 1 1 d . . . . .
C21 C 0.0543(3) 0.1774(2) 0.66558(10) 0.0322(8) Uani 1 1 d . . . . .
H21 H 0.033082 0.168232 0.687557 0.039 Uiso 1 1 calc R . . . .
C22 C 0.0015(3) 0.1236(3) 0.64006(12) 0.0403(9) Uani 1 1 d . . . . .
H22 H -0.055549 0.078710 0.644890 0.048 Uiso 1 1 calc R . . . .
C23 C 0.0324(3) 0.1354(3) 0.60742(11) 0.0348(8) Uani 1 1 d . . . . .
H23 H -0.004033 0.099064 0.590315 0.042 Uiso 1 1 calc R . . . .
C24 C 0.1171(3) 0.2010(3) 0.60019(10) 0.0310(8) Uani 1 1 d . . . . .
H24 H 0.138539 0.208270 0.578293 0.037 Uiso 1 1 calc R . . . .
C25 C 0.1709(2) 0.2569(2) 0.62586(9) 0.0265(7) Uani 1 1 d . . . . .
H25 H 0.227891 0.301816 0.620907 0.032 Uiso 1 1 calc R . . . .
Cl1 Cl 0.2840(2) 0.56201(17) 0.43148(9) 0.1410(12) Uani 1 1 d . . . . .
C26 C 0.333333 0.666667 0.4543(3) 0.077(3) Uani 1 3 d S T P . .
H26 H 0.333333 0.666667 0.478983 0.092 Uiso 1 3 calc RS T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.1133(2) . ?
Ag1 Ag2 3.1132(2) 2_665 ?
Ag1 P1 2.5213(8) 12_556 ?
Ag1 P1 2.5213(8) . ?
Ag1 C1 2.388(3) . ?
Ag1 C1 2.388(3) 12_556 ?
Ag2 Ag3 2.9376(3) . ?
Ag2 Ag3 2.9376(3) 10_456 ?
Ag2 N1 2.627(3) 10_456 ?
Ag2 N1 2.627(3) . ?
Ag2 C1 2.154(3) 10_456 ?
Ag2 C1 2.154(3) . ?
Ag3 Ag3 2.9995(8) 10_456 ?
Ag3 C1 2.356(3) 3_565 ?
Ag3 C1 2.356(3) . ?
Ag3 C1 2.356(3) 2_665 ?
P1 C9 1.828(3) . ?
P1 C14 1.818(3) . ?
P1 C20 1.826(4) . ?
N1 C9 1.348(4) . ?
N1 C13 1.343(5) . ?
C1 C2 1.211(4) . ?
C2 C3 1.439(4) . ?
C3 C4 1.401(6) . ?
C3 C8 1.399(6) . ?
C4 C5 1.387(6) . ?
C5 C6 1.364(10) . ?
C6 C7 1.389(9) . ?
C7 C8 1.388(5) . ?
C9 C10 1.391(5) . ?
C10 C11 1.399(5) . ?
C11 C12 1.378(6) . ?
C12 C13 1.376(5) . ?
C14 C15 1.405(5) . ?
C14 C19 1.382(5) . ?
C15 C16 1.380(5) . ?
C16 C17 1.374(6) . ?
C17 C18 1.382(6) . ?
C18 C19 1.387(5) . ?
C20 C21 1.398(5) . ?
C20 C25 1.381(5) . ?
C21 C22 1.376(6) . ?
C22 C23 1.379(6) . ?
C23 C24 1.375(6) . ?
C24 C25 1.400(5) . ?
Cl1 C26 1.825(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 89.281(13) 2_665 . ?
P1 Ag1 Ag2 156.954(19) . 2_665 ?
P1 Ag1 Ag2 83.816(19) . . ?
P1 Ag1 Ag2 156.953(19) 12_556 . ?
P1 Ag1 Ag2 83.81(2) 12_556 2_665 ?
P1 Ag1 P1 110.37(4) . 12_556 ?
C1 Ag1 Ag2 43.66(7) 12_556 2_665 ?
C1 Ag1 Ag2 84.35(7) 12_556 . ?
C1 Ag1 Ag2 43.67(7) . . ?
C1 Ag1 Ag2 84.35(8) . 2_665 ?
C1 Ag1 P1 113.56(8) 12_556 . ?
C1 Ag1 P1 105.05(8) . . ?
C1 Ag1 P1 105.05(8) 12_556 12_556 ?
C1 Ag1 P1 113.56(8) . 12_556 ?
C1 Ag1 C1 109.45(14) 12_556 . ?
Ag1 Ag2 Ag1 150.720(14) 3_565 . ?
Ag3 Ag2 Ag1 77.449(6) 10_456 . ?
Ag3 Ag2 Ag1 77.447(6) 10_456 3_565 ?
Ag3 Ag2 Ag1 77.448(6) . . ?
Ag3 Ag2 Ag1 77.449(6) . 3_565 ?
Ag3 Ag2 Ag3 61.398(14) 10_456 . ?
N1 Ag2 Ag1 118.66(6) 10_456 . ?
N1 Ag2 Ag1 118.66(6) . 3_565 ?
N1 Ag2 Ag1 83.88(6) . . ?
N1 Ag2 Ag1 83.88(6) 10_456 3_565 ?
N1 Ag2 Ag3 160.46(7) . . ?
N1 Ag2 Ag3 160.46(7) 10_456 10_456 ?
N1 Ag2 Ag3 109.06(7) . 10_456 ?
N1 Ag2 Ag3 109.06(7) 10_456 . ?
N1 Ag2 N1 84.90(14) . 10_456 ?
C1 Ag2 Ag1 120.84(8) 10_456 . ?
C1 Ag2 Ag1 49.96(8) 10_456 3_565 ?
C1 Ag2 Ag1 49.96(8) . . ?
C1 Ag2 Ag1 120.84(8) . 3_565 ?
C1 Ag2 Ag3 52.42(8) 10_456 10_456 ?
C1 Ag2 Ag3 99.52(8) . 10_456 ?
C1 Ag2 Ag3 52.42(8) . . ?
C1 Ag2 Ag3 99.52(8) 10_456 . ?
C1 Ag2 N1 85.05(10) 10_456 . ?
C1 Ag2 N1 85.05(10) . 10_456 ?
C1 Ag2 N1 117.88(11) . . ?
C1 Ag2 N1 117.88(11) 10_456 10_456 ?
C1 Ag2 C1 150.04(17) 10_456 . ?
Ag2 Ag3 Ag2 96.258(10) . 2_665 ?
Ag2 Ag3 Ag2 96.259(9) 3_565 . ?
Ag2 Ag3 Ag2 96.258(10) 3_565 2_665 ?
Ag2 Ag3 Ag3 59.298(7) 3_565 10_456 ?
Ag2 Ag3 Ag3 59.301(7) . 10_456 ?
Ag2 Ag3 Ag3 59.300(7) 2_665 10_456 ?
C1 Ag3 Ag2 88.97(7) 2_665 3_565 ?
C1 Ag3 Ag2 142.68(7) . 3_565 ?
C1 Ag3 Ag2 142.68(7) 2_665 . ?
C1 Ag3 Ag2 46.42(7) 2_665 2_665 ?
C1 Ag3 Ag2 46.43(7) . . ?
C1 Ag3 Ag2 46.43(7) 3_565 3_565 ?
C1 Ag3 Ag2 88.97(7) . 2_665 ?
C1 Ag3 Ag2 88.97(8) 3_565 . ?
C1 Ag3 Ag2 142.68(8) 3_565 2_665 ?
C1 Ag3 Ag3 93.30(7) . 10_456 ?
C1 Ag3 Ag3 93.29(7) 2_665 10_456 ?
C1 Ag3 Ag3 93.29(7) 3_565 10_456 ?
C1 Ag3 C1 119.673(15) 3_565 2_665 ?
C1 Ag3 C1 119.672(14) 3_565 . ?
C1 Ag3 C1 119.673(14) 2_665 . ?
C9 P1 Ag1 117.86(11) . . ?
C14 P1 Ag1 111.92(11) . . ?
C14 P1 C9 104.40(16) . . ?
C14 P1 C20 105.78(15) . . ?
C20 P1 Ag1 114.22(12) . . ?
C20 P1 C9 101.33(15) . . ?
C9 N1 Ag2 128.6(2) . . ?
C13 N1 Ag2 110.7(2) . . ?
C13 N1 C9 117.2(3) . . ?
Ag2 C1 Ag1 86.37(10) . . ?
Ag2 C1 Ag3 81.15(10) . . ?
Ag3 C1 Ag1 105.94(11) . . ?
C2 C1 Ag1 112.2(2) . . ?
C2 C1 Ag2 161.5(3) . . ?
C2 C1 Ag3 93.7(2) . . ?
C1 C2 C3 176.4(4) . . ?
C4 C3 C2 119.7(4) . . ?
C8 C3 C2 120.6(3) . . ?
C8 C3 C4 119.7(3) . . ?
C5 C4 C3 119.2(5) . . ?
C6 C5 C4 121.0(5) . . ?
C5 C6 C7 120.5(4) . . ?
C8 C7 C6 119.7(5) . . ?
C7 C8 C3 119.8(4) . . ?
N1 C9 P1 112.4(2) . . ?
N1 C9 C10 123.1(3) . . ?
C10 C9 P1 124.5(3) . . ?
C9 C10 C11 118.3(3) . . ?
C12 C11 C10 118.6(3) . . ?
C13 C12 C11 119.3(3) . . ?
N1 C13 C12 123.4(4) . . ?
C15 C14 P1 118.4(3) . . ?
C19 C14 P1 122.3(3) . . ?
C19 C14 C15 118.8(3) . . ?
C16 C15 C14 119.6(3) . . ?
C17 C16 C15 121.2(4) . . ?
C16 C17 C18 119.6(4) . . ?
C17 C18 C19 120.0(4) . . ?
C14 C19 C18 120.8(4) . . ?
C21 C20 P1 122.8(3) . . ?
C25 C20 P1 118.0(3) . . ?
C25 C20 C21 119.1(3) . . ?
C22 C21 C20 120.1(4) . . ?
C21 C22 C23 120.7(4) . . ?
C24 C23 C22 119.9(4) . . ?
C23 C24 C25 119.9(4) . . ?
C20 C25 C24 120.3(3) . . ?
Cl1 C26 Cl1 97.5(5) 2_665 . ?
Cl1 C26 Cl1 97.5(5) 3_565 2_665 ?
Cl1 C26 Cl1 97.5(5) 3_565 . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.141
_oxdiff_exptl_absorpt_empirical_full_min 0.865
