# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_1155
_database_code_depnum_ccdc_archive 'CCDC 2368666'
loop_
_audit_author_name
_audit_author_address
WQb
;Zhejiang University of Technology
China
;
_audit_update_record             
;
2024-07-08 deposited with the CCDC.	2024-12-09 downloaded from the CCDC.
;
_audit_creation_date             2020-01-16
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C19 H17 N O'
_chemical_formula_sum            'C19 H17 N O'
_chemical_formula_weight         275.33
_chemical_absolute_configuration unk
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'

_cell_length_a                   7.16669(7)
_cell_length_b                   13.97128(11)
_cell_length_c                   14.98548(11)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1500.46(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    23040
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      74.1060
_cell_measurement_theta_min      4.3050
_shelx_estimated_absorpt_T_max   0.867
_shelx_estimated_absorpt_T_min   0.821
_exptl_absorpt_coefficient_mu    0.585
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.29493
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.28b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.219
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_av_unetI/netI     0.0193
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            33187
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        67.059
_diffrn_reflns_theta_max         67.059
_diffrn_reflns_theta_min         4.327
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     63.00  89.00   1.00    1.00    --    0.00  38.00-150.00   26
  2  ω    -18.00   8.00   1.00    1.00    --    0.00  38.00-150.00   26
  3  ω    -87.00  18.00   1.00    1.00    --    0.00 -38.00 -30.00  105
  4  ω    -29.00  35.00   1.00    1.00    --    0.00  82.00  30.00   64
  5  ω    -88.00  -1.00   1.00    1.00    --    0.00 -77.00 120.00   87
  6  ω    -28.00  17.00   1.00    1.00    --    0.00 -38.00  30.00   45
  7  ω     51.00  83.00   1.00    1.00    --    0.00  77.00 120.00   32
  8  ω     49.00  81.00   1.00    1.00    --    0.00  38.00 -90.00   32
  9  ω    -89.00 -63.00   1.00    1.00    --    0.00 -38.00  30.00   26
 10  ω     55.00  82.00   1.00    1.00    --    0.00  82.00  30.00   27
 11  ω    -30.00  34.00   1.00    1.00    --    0.00  77.00 120.00   64
 12  ω    -19.00  12.00   1.00    1.00    --    0.00  38.00 -90.00   31
 13  ω    151.00 181.00   1.00    1.00    --   95.80  82.00  30.00   30
 14  ω     64.00  89.00   1.00    1.00    --   95.80  82.00  30.00   25
 15  ω     70.00 100.00   1.00    1.00    --   95.80  64.00 134.14   30
 16  ω    123.00 175.00   1.00    1.00    --   95.80  77.00 -60.00   52
 17  ω     61.00 127.00   1.00    1.00    --   95.80 -82.00-180.00   66
 18  ω    128.00 169.00   1.00    1.00    --   95.80  76.00 165.89   41
 19  ω     65.00  94.00   1.00    1.00    --   95.80  78.00 -37.94   29
 20  ω     78.00 185.00   1.00    1.00    --   95.80  45.00 -90.00  107
 21  ω    110.00 185.00   1.00    1.00    --   95.80  82.00 -30.00   75
 22  ω    157.00 185.00   1.00    1.00    --   95.80  79.00-112.23   28
 23  ω     65.00  91.00   1.00    1.00    --   95.80  82.00   0.00   26
 24  ω     65.00  92.00   1.00    1.00    --   95.80  77.00 -60.00   27
 25  ω     75.00 122.00   1.00    1.00    --   95.80  45.00  90.00   47
 26  ω     65.00  91.00   1.00    1.00    --   95.80  77.00 150.00   26
 27  ω     43.00  78.00   1.00    1.00    --   95.80 -82.00  90.00   35
 28  ω     83.00 125.00   1.00    1.00    --   95.80 -82.00  90.00   42
 29  ω     74.00 132.00   1.00    1.00    --   95.80  61.00  90.00   58
 30  ω    157.00 185.00   1.00    1.00    --   95.80  61.00  90.00   28
 31  ω     63.00  89.00   1.00    1.00    --   95.80  82.00 -30.00   26
 32  ω     63.00 185.00   1.00    1.00    --   95.80  82.00-180.00  122
 33  ω     64.00  94.00   1.00    1.00    --   95.80  79.00-112.23   30
 34  ω     65.00 114.00   1.00    1.00    --   95.80  76.00 165.89   49
 35  ω     83.00 108.00   1.00    1.00    --   95.80 -82.00-120.00   25
 36  ω     32.00  69.00   1.00    1.00    --   95.80 -82.00-120.00   37
 37  ω    156.00 183.00   1.00    1.00    --   95.80  77.00  60.00   27
 38  ω     65.00  90.00   1.00    1.00    --   95.80  77.00  30.00   25
 39  ω     63.00  88.00   1.00    1.00    --   95.80  82.00 -60.00   25
 40  ω    129.00 155.00   1.00    1.00    --   95.80  77.00   0.00   26
 41  ω     65.00  91.00   1.00    1.00    --   95.80  77.00  60.00   26
 42  ω     66.00  92.00   1.00    1.00    --   95.80  77.00-180.00   26
 43  ω     65.00  91.00   1.00    1.00    --   95.80  77.00-150.00   26
 44  ω     44.00 106.00   1.00    1.00    --   95.80 -82.00 -30.00   62
 45  ω     76.00 108.00   1.00    1.00    --   95.80  45.00   0.00   32
 46  ω     65.00  90.00   1.00    1.00    --   95.80  77.00  90.00   25
 47  ω     67.00  97.00   1.00    1.00    --   95.80  73.00  89.14   30
 48  ω     63.00  89.00   1.00    1.00    --   95.80  82.00  60.00   26
 49  ω     63.00  89.00   1.00    1.00    --   95.80  82.00  90.00   26
 50  ω     75.00 135.00   1.00    1.00    --   95.80  45.00-180.00   60
 51  ω     65.00  90.00   1.00    1.00    --   95.80  77.00   0.00   25
 52  ω    154.00 182.00   1.00    1.00    --   95.80  45.00  90.00   28
 53  ω     73.00  99.00   1.00    1.00    --   95.80  61.00-120.00   26
 54  ω     76.00 114.00   1.00    1.00    --   95.80  30.00-180.00   38
 55  ω     79.00 109.00   1.00    1.00    --   95.80  30.00  90.00   30
 56  ω    128.00 178.00   1.00    1.00    --   95.80  30.00  90.00   50
 57  ω     75.00 101.00   1.00    1.00    --   95.80  45.00  60.00   26
 58  ω    126.00 182.00   1.00    1.00    --   95.80  45.00  60.00   56
 59  ω     72.00  97.00   1.00    1.00    --   95.80  61.00 -60.00   25
 60  ω     71.00  97.00   1.00    1.00    --   95.80  61.00   0.00   26
 61  ω    129.00 182.00   1.00    1.00    --   95.80  61.00   0.00   53
 62  ω     65.00  91.00   1.00    1.00    --   95.80  77.00 -90.00   26
 63  ω     63.00  88.00   1.00    1.00    --   95.80  82.00 -90.00   25
 64  ω    118.00 171.00   1.00    1.00    --   95.80  77.00-120.00   53
 65  ω     65.00  91.00   1.00    1.00    --   95.80  77.00-120.00   26
 66  ω     54.00 124.00   1.00    1.00    --   95.80 -82.00  30.00   70
 67  ω    138.00 164.00   1.00    1.00    --   95.80  64.00 134.14   26
 68  ω     75.00 134.00   1.00    1.00    --   95.80  45.00 -60.00   59
 69  ω     75.00 126.00   1.00    1.00    --   95.80  45.00  30.00   51
 70  ω     75.00 100.00   1.00    1.00    --   95.80  45.00 150.00   25
 71  ω    115.00 168.00   1.00    1.00    --   95.80  78.00 -37.94   53
 72  ω    119.00 163.00   1.00    1.00    --   95.80  45.00-122.88   44
 73  ω     63.00  88.00   1.00    1.00    --   95.80  82.00 120.00   25
 74  ω    130.00 181.00   1.00    1.00    --   95.80  82.00 120.00   51
 75  ω     75.00 101.00   1.00    1.00    --   95.80  45.00-122.88   26
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa dual home/near'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0346524000
_diffrn_orient_matrix_UB_12      -0.0789787000
_diffrn_orient_matrix_UB_13      -0.0696664000
_diffrn_orient_matrix_UB_21      0.0368785000
_diffrn_orient_matrix_UB_22      -0.0768892000
_diffrn_orient_matrix_UB_23      0.0715545000
_diffrn_orient_matrix_UB_31      -0.2090701000
_diffrn_orient_matrix_UB_32      -0.0004511000
_diffrn_orient_matrix_UB_33      0.0242596000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Cu) X-ray Source'
_reflns_Friedel_coverage         0.716
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                2641
_reflns_number_total             2678
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.28b (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.39.28b (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.28b (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.103
_refine_diff_density_min         -0.173
_refine_diff_density_rms         0.038
_refine_ls_abs_structure_details 
;
 Flack x determined using 1096 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.03(11)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     192
_refine_ls_number_reflns         2678
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0277
_refine_ls_R_factor_gt           0.0273
_refine_ls_restrained_S_all      1.075
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0362P)²+0.2671P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0685
_refine_ls_wR_factor_ref         0.0688
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C15(H15), C16(H16), C17(H17), C18(H18)
2.c Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C12(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8457(3) 0.82544(12) 0.51321(11) 0.0260(4) Uani 1 1 d . . . . .
H1 H 0.961069 0.809515 0.488985 0.031 Uiso 1 1 calc R . . . .
C2 C 0.8106(3) 0.80818(13) 0.60291(11) 0.0311(4) Uani 1 1 d . . . . .
H2 H 0.901815 0.779781 0.638240 0.037 Uiso 1 1 calc R . . . .
C3 C 0.6413(3) 0.83295(13) 0.63979(11) 0.0309(4) Uani 1 1 d . . . . .
H3 H 0.617950 0.820730 0.699768 0.037 Uiso 1 1 calc R . . . .
C4 C 0.5056(3) 0.87608(13) 0.58752(11) 0.0286(4) Uani 1 1 d . . . . .
H4 H 0.392230 0.893680 0.612823 0.034 Uiso 1 1 calc R . . . .
C5 C 0.5382(3) 0.89315(12) 0.49750(11) 0.0243(4) Uani 1 1 d . . . . .
H5 H 0.446875 0.922219 0.462748 0.029 Uiso 1 1 calc R . . . .
C6 C 0.7086(2) 0.86659(11) 0.45915(10) 0.0211(4) Uani 1 1 d . . . . .
C7 C 0.7455(2) 0.87772(11) 0.36509(10) 0.0200(3) Uani 1 1 d . . . . .
C8 C 0.7883(2) 0.88191(11) 0.28777(10) 0.0185(3) Uani 1 1 d . . . . .
C9 C 0.8524(2) 0.89086(12) 0.19536(10) 0.0189(3) Uani 1 1 d . . . . .
H9A H 0.982707 0.872239 0.192775 0.023 Uiso 1 1 calc R . . . .
H9B H 0.844936 0.957662 0.178097 0.023 Uiso 1 1 calc R . . . .
C10 C 0.7428(2) 0.83071(11) 0.12648(10) 0.0166(3) Uani 1 1 d . . . . .
C11 C 0.8256(2) 0.84725(12) 0.03378(10) 0.0224(4) Uani 1 1 d . . . . .
H11A H 0.759446 0.809180 -0.009143 0.034 Uiso 1 1 calc GR . . . .
H11B H 0.954905 0.829269 0.033929 0.034 Uiso 1 1 calc GR . . . .
H11C H 0.814553 0.913692 0.018335 0.034 Uiso 1 1 calc GR . . . .
C12 C 0.4690(3) 0.94635(12) 0.10002(11) 0.0250(4) Uani 1 1 d . . . . .
H12A H 0.485540 0.952647 0.036716 0.037 Uiso 1 1 calc GR . . . .
H12B H 0.534368 0.997054 0.129906 0.037 Uiso 1 1 calc GR . . . .
H12C H 0.338574 0.949957 0.114160 0.037 Uiso 1 1 calc GR . . . .
C13 C 0.4312(2) 0.78115(12) 0.15517(10) 0.0183(3) Uani 1 1 d . . . . .
C14 C 0.5553(2) 0.69744(11) 0.16759(10) 0.0171(3) Uani 1 1 d . . . . .
C15 C 0.5103(2) 0.60307(12) 0.18722(10) 0.0216(4) Uani 1 1 d . . . . .
H15 H 0.387734 0.585034 0.198779 0.026 Uiso 1 1 calc R . . . .
C16 C 0.6541(3) 0.53652(12) 0.18905(11) 0.0236(4) Uani 1 1 d . . . . .
H16 H 0.628185 0.472856 0.202247 0.028 Uiso 1 1 calc R . . . .
C17 C 0.8372(3) 0.56446(12) 0.17123(11) 0.0233(4) Uani 1 1 d . . . . .
H17 H 0.931736 0.518884 0.172527 0.028 Uiso 1 1 calc R . . . .
C18 C 0.8813(2) 0.65917(12) 0.15154(10) 0.0199(3) Uani 1 1 d . . . . .
H18 H 1.003683 0.677488 0.139900 0.024 Uiso 1 1 calc R . . . .
C19 C 0.7374(2) 0.72522(11) 0.14983(9) 0.0160(3) Uani 1 1 d . . . . .
N1 N 0.54270(19) 0.85454(9) 0.12922(8) 0.0177(3) Uani 1 1 d . . . . .
O1 O 0.26056(16) 0.78450(9) 0.16391(8) 0.0260(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.389(2) . ?
C1 C6 1.397(2) . ?
C2 C3 1.378(3) . ?
C3 C4 1.386(3) . ?
C4 C5 1.390(2) . ?
C5 C6 1.400(2) . ?
C6 C7 1.442(2) . ?
C7 C8 1.200(2) . ?
C8 C9 1.464(2) . ?
C9 C10 1.546(2) . ?
C10 C11 1.528(2) . ?
C10 C19 1.515(2) . ?
C10 N1 1.473(2) . ?
C12 N1 1.455(2) . ?
C13 C14 1.481(2) . ?
C13 N1 1.357(2) . ?
C13 O1 1.2310(19) . ?
C14 C15 1.389(2) . ?
C14 C19 1.388(2) . ?
C15 C16 1.388(3) . ?
C16 C17 1.395(3) . ?
C17 C18 1.392(2) . ?
C18 C19 1.384(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 120.36(17) . . ?
C3 C2 C1 120.28(18) . . ?
C2 C3 C4 120.01(16) . . ?
C3 C4 C5 120.35(18) . . ?
C4 C5 C6 119.98(18) . . ?
C1 C6 C5 118.98(15) . . ?
C1 C6 C7 118.84(16) . . ?
C5 C6 C7 122.16(16) . . ?
C8 C7 C6 174.58(19) . . ?
C7 C8 C9 175.91(18) . . ?
C8 C9 C10 115.18(14) . . ?
C11 C10 C9 109.10(13) . . ?
C19 C10 C9 112.80(13) . . ?
C19 C10 C11 111.52(13) . . ?
N1 C10 C9 110.70(13) . . ?
N1 C10 C11 111.68(13) . . ?
N1 C10 C19 100.89(12) . . ?
N1 C13 C14 106.22(13) . . ?
O1 C13 C14 127.82(16) . . ?
O1 C13 N1 125.93(16) . . ?
C15 C14 C13 129.57(16) . . ?
C19 C14 C13 108.65(14) . . ?
C19 C14 C15 121.64(15) . . ?
C16 C15 C14 117.87(16) . . ?
C15 C16 C17 120.48(16) . . ?
C18 C17 C16 121.35(16) . . ?
C19 C18 C17 117.93(15) . . ?
C14 C19 C10 109.89(13) . . ?
C18 C19 C10 129.34(15) . . ?
C18 C19 C14 120.72(15) . . ?
C12 N1 C10 122.99(14) . . ?
C13 N1 C10 114.23(13) . . ?
C13 N1 C12 122.62(14) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.172
_oxdiff_exptl_absorpt_empirical_full_min 0.504
