# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1b
_database_code_depnum_ccdc_archive 'CCDC 2348909'
loop_
_audit_author_name
_audit_author_address
'Zhong-Ning Chen'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2024-04-17 deposited with the CCDC.	2024-05-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C119.50 H109 Au2 Cl6 N2 O12 P6 Pt'
_chemical_formula_weight         2752.62

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2543 0.3332 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3281 0.5435 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -5.3886 5.5592 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -5.1040 5.8603 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_H-M_alt        'P 1'
_space_group_name_Hall           'P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'

_cell_length_a                   15.27880(10)
_cell_length_b                   15.84130(10)
_cell_length_c                   25.2877(2)
_cell_angle_alpha                80.2140(10)
_cell_angle_beta                 88.8280(10)
_cell_angle_gamma                77.0780(10)
_cell_volume                     5877.75(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    112750
_cell_measurement_theta_min      2.7190
_cell_measurement_theta_max      60.1510

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.555
_exptl_crystal_F_000             2728
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    6.313
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.3405
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'ROD, Synergy Custom system, HyPix'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            153609
_diffrn_reflns_av_unetI/netI     0.0404
_diffrn_reflns_av_R_equivalents  0.0472
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.726
_diffrn_reflns_theta_max         60.210
_diffrn_reflns_theta_full        53.543
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             49558
_reflns_number_gt                44597
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         1.000
_reflns_Friedel_fraction_max     0.980
_reflns_Friedel_fraction_full    0.997

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           fullcycle
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1313P)²+14.9077P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.142(13)
_chemical_absolute_configuration rm
_refine_ls_number_reflns         49558
_refine_ls_number_parameters     2703
_refine_ls_number_restraints     7027
_refine_ls_R_factor_all          0.0735
_refine_ls_R_factor_gt           0.0683
_refine_ls_wR_factor_ref         0.1950
_refine_ls_wR_factor_gt          0.1884
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_restrained_S_all      1.096
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.73780(7) 0.70268(8) 0.25838(6) 0.03658(14) Uani 1 1 d . . . . .
Au2 Au 0.50679(7) 0.97499(8) 0.10749(6) 0.03516(14) Uani 1 1 d . . . . .
Au3 Au -0.36294(7) 1.93885(8) 0.57719(6) 0.03921(15) Uani 1 1 d . . . . .
Au4 Au -0.37656(7) 1.72972(8) 0.78962(6) 0.03712(14) Uani 1 1 d . . . . .
Pt1 Pt 0.62238(7) 0.83848(9) 0.18257(6) 0.02794(10) Uani 1 1 d . . . . .
Pt2 Pt -0.37112(8) 1.83594(9) 0.68360(6) 0.02988(10) Uani 1 1 d . . . . .
Cl1 Cl 0.3539(3) 0.5708(3) 0.1526(2) 0.0617(12) Uani 1 1 d . U . . .
Cl2 Cl 0.4525(7) 0.5452(4) 0.5858(3) 0.114(3) Uani 1 1 d D U . . .
Cl3 Cl -0.1087(3) 1.1072(3) 1.2133(2) 0.0610(12) Uani 1 1 d D U . . .
P1 P 0.8425(3) 0.7904(3) 0.25773(18) 0.0455(9) Uani 1 1 d . . . . .
P2 P 0.7364(2) 0.9105(2) 0.16085(16) 0.0302(7) Uani 1 1 d . . . . .
P3 P 0.5990(2) 1.0749(2) 0.10058(18) 0.0361(8) Uani 1 1 d . . . . .
P4 P 0.6456(3) 0.6033(3) 0.26403(18) 0.0393(8) Uani 1 1 d . . . . .
P5 P 0.5076(2) 0.7666(2) 0.20476(17) 0.0322(7) Uani 1 1 d . . . . .
P6 P 0.3998(2) 0.8929(3) 0.10948(18) 0.0432(9) Uani 1 1 d . . . . .
P7 P -0.2608(3) 2.0115(3) 0.60607(18) 0.0432(9) Uani 1 1 d . . . . .
P8 P -0.2502(2) 1.8838(3) 0.71195(16) 0.0337(7) Uani 1 1 d . . . . .
P9 P -0.2763(2) 1.7956(3) 0.82643(16) 0.0335(7) Uani 1 1 d . . . . .
P10 P -0.4652(2) 1.8747(3) 0.54082(16) 0.0358(8) Uani 1 1 d . . . . .
P11 P -0.4921(2) 1.7881(3) 0.65544(16) 0.0335(7) Uani 1 1 d . . . . .
P12 P -0.4780(3) 1.6563(3) 0.76125(18) 0.0426(9) Uani 1 1 d . . . . .
O1 O 0.6838(9) 0.3716(7) -0.0211(5) 0.058(3) Uani 1 1 d . . . . .
O2 O 0.9653(9) 0.4052(9) -0.0510(6) 0.072(4) Uani 1 1 d . . . . .
O3 O 0.2648(13) 1.2286(15) 0.3987(10) 0.134(7) Uani 1 1 d D U . . .
O4 O 0.5204(14) 1.3403(12) 0.4020(8) 0.134(6) Uani 1 1 d D U . . .
O5 O -0.6963(7) 2.2104(9) 0.9122(6) 0.068(3) Uani 1 1 d . U . . .
O6 O -0.7080(12) 2.4400(11) 0.7676(10) 0.136(7) Uani 1 1 d . U . . .
O7 O -0.0515(11) 1.4683(16) 0.4501(8) 0.127(7) Uani 1 1 d D U . . .
O8 O -0.0552(13) 1.2362(13) 0.5777(10) 0.148(8) Uani 1 1 d D U . . .
O9 O 0.4412(9) 0.5473(12) 0.1425(8) 0.094(4) Uani 1 1 d . U . . .
O10 O 0.3186(11) 0.6371(11) 0.1802(10) 0.109(5) Uani 1 1 d . U . . .
O11 O 0.341(2) 0.6424(14) 0.0991(11) 0.141(6) Uani 1 1 d . U . . .
O12 O 0.2974(9) 0.5145(10) 0.1432(7) 0.078(4) Uani 1 1 d . U . . .
N1 N 0.8246(9) 0.3839(7) -0.0340(6) 0.051(3) Uani 1 1 d D . . . .
N2 N 0.3914(10) 1.2797(11) 0.4007(8) 0.095(4) Uani 1 1 d D U . . .
N3 N -0.7032(8) 2.3275(10) 0.8427(7) 0.071(3) Uani 1 1 d D U . . .
N4 N -0.0531(10) 1.3596(14) 0.5094(8) 0.096(4) Uani 1 1 d D U . . .
C1 C 0.8015(9) 0.9011(11) 0.2196(6) 0.042(2) Uani 1 1 d . U . . .
H1A H 0.765145 0.937491 0.243799 0.050 Uiso 1 1 calc R U . . .
H1B H 0.854157 0.926647 0.209218 0.050 Uiso 1 1 calc R U . . .
C2 C 0.6982(10) 1.0306(10) 0.1443(7) 0.042(2) Uani 1 1 d . U . . .
H2A H 0.685929 1.053617 0.178392 0.051 Uiso 1 1 calc R U . . .
H2B H 0.748487 1.054386 0.127194 0.051 Uiso 1 1 calc R U . . .
C3 C 0.9463(10) 0.7411(10) 0.2246(7) 0.062(2) Uani 1 1 d D U . . .
C4 C 1.0282(9) 0.7638(10) 0.2324(6) 0.064(3) Uani 1 1 d D U . . .
C5 C 1.1000(11) 0.7228(10) 0.2048(6) 0.070(3) Uani 1 1 d D U . . .
H5 H 1.157011 0.735836 0.208661 0.084 Uiso 1 1 calc R U . . .
C6 C 1.0918(10) 0.6639(11) 0.1719(7) 0.072(3) Uani 1 1 d D U . . .
H6 H 1.143401 0.637881 0.153861 0.086 Uiso 1 1 calc R U . . .
C7 C 1.0111(9) 0.6411(11) 0.1640(7) 0.068(3) Uani 1 1 d D U . . .
H7 H 1.005769 0.600413 0.141342 0.082 Uiso 1 1 calc R U . . .
C8 C 0.9392(10) 0.6814(10) 0.1913(6) 0.062(3) Uani 1 1 d D U . . .
H8 H 0.882392 0.667950 0.187178 0.074 Uiso 1 1 calc R U . . .
C9 C 1.0485(11) 0.8262(14) 0.2663(8) 0.070(4) Uani 1 1 d . U . . .
H9A H 0.993724 0.851629 0.284090 0.105 Uiso 1 1 calc R U . . .
H9B H 1.094402 0.794480 0.293460 0.105 Uiso 1 1 calc R U . . .
H9C H 1.070678 0.873240 0.243570 0.105 Uiso 1 1 calc R U . . .
C10 C 0.8648(10) 0.8167(11) 0.3242(5) 0.078(3) Uani 1 1 d D U . . .
C11 C 0.9037(8) 0.7563(11) 0.3663(7) 0.093(3) Uani 1 1 d D U . . .
C12 C 0.9191(11) 0.7736(11) 0.4156(6) 0.098(4) Uani 1 1 d D U . . .
H12 H 0.947249 0.725413 0.441875 0.118 Uiso 1 1 calc R U . . .
C13 C 0.8972(13) 0.8562(13) 0.4308(6) 0.102(4) Uani 1 1 d D U . . .
H13 H 0.907945 0.867326 0.465572 0.123 Uiso 1 1 calc R U . . .
C14 C 0.8550(11) 0.9240(10) 0.3857(6) 0.094(4) Uani 1 1 d D U . . .
H14 H 0.835604 0.984553 0.388129 0.113 Uiso 1 1 calc R U . . .
C15 C 0.8467(10) 0.8911(10) 0.3407(5) 0.080(3) Uani 1 1 d D U . . .
H15 H 0.819256 0.936636 0.312642 0.096 Uiso 1 1 calc R U . . .
C16 C 0.9299(13) 0.6642(12) 0.3536(9) 0.091(4) Uani 1 1 d D U . . .
H16A H 0.957628 0.623532 0.385490 0.136 Uiso 1 1 calc R U . . .
H16B H 0.876261 0.646644 0.342816 0.136 Uiso 1 1 calc R U . . .
H16C H 0.972813 0.662746 0.324244 0.136 Uiso 1 1 calc R U . . .
C17 C 0.8107(8) 0.8853(11) 0.1059(6) 0.043(2) Uani 1 1 d D U . . .
C18 C 0.7731(9) 0.8679(10) 0.0607(5) 0.042(2) Uani 1 1 d D U . . .
H18 H 0.712277 0.862734 0.061479 0.051 Uiso 1 1 calc R U . . .
C19 C 0.8218(9) 0.8578(12) 0.0144(6) 0.049(2) Uani 1 1 d D U . . .
H19 H 0.797090 0.845758 -0.016963 0.059 Uiso 1 1 calc R U . . .
C20 C 0.9109(9) 0.8670(13) 0.0178(5) 0.054(3) Uani 1 1 d D U . . .
H20 H 0.948394 0.855309 -0.011751 0.065 Uiso 1 1 calc DR U . . .
C21 C 0.9484(10) 0.8912(13) 0.0597(6) 0.058(3) Uani 1 1 d D U . . .
H21 H 1.006198 0.904344 0.057497 0.070 Uiso 1 1 calc R U . . .
C22 C 0.8982(8) 0.8957(12) 0.1055(7) 0.051(2) Uani 1 1 d D U . . .
H22 H 0.923971 0.906004 0.137070 0.061 Uiso 1 1 calc R U . . .
C23 C 0.6354(12) 1.1068(10) 0.0333(8) 0.050(2) Uani 1 1 d . U . . .
C24 C 0.5680(13) 1.1513(11) -0.0047(8) 0.060(3) Uani 1 1 d . U . . .
C25 C 0.5963(15) 1.1741(12) -0.0554(9) 0.066(3) Uani 1 1 d . U . . .
H25 H 0.551516 1.206172 -0.081259 0.079 Uiso 1 1 calc R U . . .
C26 C 0.6799(14) 1.1562(12) -0.0725(9) 0.064(3) Uani 1 1 d . U . . .
H26 H 0.693923 1.175082 -0.108756 0.076 Uiso 1 1 calc R U . . .
C27 C 0.7469(13) 1.1083(11) -0.0350(8) 0.058(3) Uani 1 1 d . U . . .
H27 H 0.807318 1.090926 -0.045690 0.070 Uiso 1 1 calc R U . . .
C28 C 0.7230(12) 1.0870(11) 0.0180(8) 0.053(2) Uani 1 1 d . U . . .
H28 H 0.768400 1.058011 0.044214 0.064 Uiso 1 1 calc R U . . .
C29 C 0.4735(14) 1.1684(13) 0.0041(9) 0.070(4) Uani 1 1 d . U . . .
H29A H 0.462568 1.148932 0.042104 0.105 Uiso 1 1 calc R U . . .
H29B H 0.447887 1.231558 -0.005586 0.105 Uiso 1 1 calc R U . . .
H29C H 0.445341 1.136375 -0.017995 0.105 Uiso 1 1 calc R U . . .
C30 C 0.5431(12) 1.1739(11) 0.1271(7) 0.053(3) Uani 1 1 d . U . . .
C31 C 0.5784(12) 1.2452(10) 0.1258(7) 0.052(3) Uani 1 1 d . U . . .
C32 C 0.5295(13) 1.3169(12) 0.1494(8) 0.059(3) Uani 1 1 d . U . . .
H32 H 0.553642 1.367173 0.149359 0.071 Uiso 1 1 calc R U . . .
C33 C 0.4471(14) 1.3135(13) 0.1722(9) 0.066(3) Uani 1 1 d . U . . .
H33 H 0.412766 1.363140 0.185359 0.079 Uiso 1 1 calc R U . . .
C34 C 0.4147(14) 1.2381(12) 0.1759(8) 0.064(3) Uani 1 1 d . U . . .
H34 H 0.362081 1.231412 0.195314 0.077 Uiso 1 1 calc R U . . .
C35 C 0.4620(13) 1.1738(12) 0.1504(8) 0.060(3) Uani 1 1 d . U . . .
H35 H 0.436309 1.124933 0.148750 0.072 Uiso 1 1 calc R U . . .
C36 C 0.6670(13) 1.2549(11) 0.1004(8) 0.057(3) Uani 1 1 d . U . . .
H36A H 0.678531 1.311942 0.104445 0.085 Uiso 1 1 calc R U . . .
H36B H 0.715511 1.207725 0.118106 0.085 Uiso 1 1 calc R U . . .
H36C H 0.664363 1.251388 0.062166 0.085 Uiso 1 1 calc R U . . .
C37 C 0.5448(11) 0.6460(11) 0.2208(6) 0.043(2) Uani 1 1 d . U . . .
H37A H 0.494858 0.622279 0.238530 0.052 Uiso 1 1 calc R U . . .
H37B H 0.556241 0.622922 0.186718 0.052 Uiso 1 1 calc R U . . .
C38 C 0.4382(10) 0.7801(11) 0.1434(6) 0.043(2) Uani 1 1 d . U . . .
H38A H 0.473650 0.745589 0.117871 0.052 Uiso 1 1 calc R U . . .
H38B H 0.385108 0.755027 0.153084 0.052 Uiso 1 1 calc R U . . .
C39 C 0.7016(9) 0.5059(9) 0.2359(5) 0.052(2) Uani 1 1 d D U . . .
C40 C 0.6653(9) 0.4313(8) 0.2384(4) 0.052(2) Uani 1 1 d D U . . .
C41 C 0.7134(10) 0.3634(10) 0.2152(5) 0.057(3) Uani 1 1 d D U . . .
H41 H 0.690198 0.312228 0.216467 0.068 Uiso 1 1 calc R U . . .
C42 C 0.7944(10) 0.3662(10) 0.1899(6) 0.059(3) Uani 1 1 d D U . . .
H42 H 0.825529 0.317894 0.174225 0.071 Uiso 1 1 calc R U . . .
C43 C 0.8293(11) 0.4401(9) 0.1878(6) 0.062(3) Uani 1 1 d D U . . .
H43 H 0.884808 0.443289 0.170836 0.074 Uiso 1 1 calc R U . . .
C44 C 0.7822(10) 0.5085(10) 0.2107(6) 0.056(3) Uani 1 1 d D U . . .
H44 H 0.805765 0.559529 0.209225 0.067 Uiso 1 1 calc R U . . .
C45 C 0.5770(10) 0.4213(10) 0.2648(6) 0.060(4) Uani 1 1 d D U . . .
H45A H 0.550220 0.474360 0.279542 0.090 Uiso 1 1 calc R U . . .
H45B H 0.535733 0.412773 0.237964 0.090 Uiso 1 1 calc R U . . .
H45C H 0.587980 0.370297 0.293718 0.090 Uiso 1 1 calc R U . . .
C46 C 0.6113(10) 0.5687(8) 0.3326(7) 0.053(2) Uani 1 1 d D U . . .
C47 C 0.6736(11) 0.5192(7) 0.3719(6) 0.063(3) Uani 1 1 d D U . . .
C48 C 0.6415(12) 0.4947(9) 0.4233(7) 0.069(3) Uani 1 1 d D U . . .
H48 H 0.682660 0.460988 0.450675 0.083 Uiso 1 1 calc R U . . .
C49 C 0.5509(11) 0.5185(9) 0.4353(8) 0.068(3) Uani 1 1 d D U . . .
H49 H 0.531743 0.500756 0.470561 0.082 Uiso 1 1 calc R U . . .
C50 C 0.4886(13) 0.5674(9) 0.3970(6) 0.070(3) Uani 1 1 d D U . . .
H50 H 0.426617 0.583905 0.404668 0.084 Uiso 1 1 calc R U . . .
C51 C 0.5218(11) 0.5910(10) 0.3466(6) 0.058(3) Uani 1 1 d D U . . .
H51 H 0.480211 0.624979 0.319508 0.070 Uiso 1 1 calc R U . . .
C52 C 0.7731(11) 0.4922(12) 0.3597(8) 0.085(5) Uani 1 1 d D U . . .
H52A H 0.805692 0.457933 0.392188 0.128 Uiso 1 1 calc R U . . .
H52B H 0.780798 0.456382 0.331249 0.128 Uiso 1 1 calc R U . . .
H52C H 0.796673 0.544851 0.348018 0.128 Uiso 1 1 calc R U . . .
C53 C 0.4374(10) 0.7933(11) 0.2603(7) 0.043(2) Uani 1 1 d . U . . .
C54 C 0.3470(10) 0.7855(12) 0.2624(7) 0.049(2) Uani 1 1 d . U . . .
H54 H 0.319738 0.771952 0.232381 0.059 Uiso 1 1 calc R U . . .
C55 C 0.2978(11) 0.7977(13) 0.3087(7) 0.055(3) Uani 1 1 d . U . . .
H55 H 0.235495 0.798222 0.309034 0.066 Uiso 1 1 calc R U . . .
C56 C 0.3398(11) 0.8092(13) 0.3542(7) 0.053(3) Uani 1 1 d . U . . .
H56 H 0.308614 0.811832 0.387001 0.063 Uiso 1 1 calc R U . . .
C57 C 0.4261(11) 0.8165(12) 0.3507(7) 0.049(3) Uani 1 1 d . U . . .
H57 H 0.453018 0.829721 0.380935 0.059 Uiso 1 1 calc R U . . .
C58 C 0.4759(11) 0.8063(11) 0.3072(6) 0.045(2) Uani 1 1 d . U . . .
H58 H 0.537627 0.807794 0.308096 0.054 Uiso 1 1 calc R U . . .
C59 C 0.3007(10) 0.9327(12) 0.1436(7) 0.052(2) Uani 1 1 d . U . . .
C60 C 0.2157(11) 0.9155(13) 0.1363(8) 0.058(3) Uani 1 1 d . U . . .
C61 C 0.1424(11) 0.9591(13) 0.1621(8) 0.061(3) Uani 1 1 d . U . . .
H61 H 0.084733 0.948505 0.156640 0.073 Uiso 1 1 calc R U . . .
C62 C 0.1508(12) 1.0157(14) 0.1943(9) 0.066(3) Uani 1 1 d . U . . .
H62 H 0.098846 1.047173 0.209510 0.079 Uiso 1 1 calc R U . . .
C63 C 0.2363(12) 1.0292(14) 0.2061(9) 0.066(3) Uani 1 1 d . U . . .
H63 H 0.243970 1.063816 0.232131 0.079 Uiso 1 1 calc R U . . .
C64 C 0.3095(11) 0.9890(13) 0.1775(8) 0.057(2) Uani 1 1 d . U . . .
H64 H 0.366699 1.001481 0.181858 0.069 Uiso 1 1 calc R U . . .
C65 C 0.2005(11) 0.8509(14) 0.1032(8) 0.061(4) Uani 1 1 d . U . . .
H65A H 0.257338 0.825222 0.087455 0.092 Uiso 1 1 calc R U . . .
H65B H 0.177471 0.804324 0.125778 0.092 Uiso 1 1 calc R U . . .
H65C H 0.156740 0.880671 0.074424 0.092 Uiso 1 1 calc R U . . .
C66 C 0.3666(7) 0.8962(8) 0.0406(4) 0.059(2) Uani 1 1 d D U . . .
C67 C 0.3199(6) 0.9723(8) 0.0091(5) 0.067(3) Uani 1 1 d D U . . .
C68 C 0.2954(8) 0.9692(9) -0.0433(4) 0.076(3) Uani 1 1 d D U . . .
H68 H 0.263237 1.020970 -0.065421 0.091 Uiso 1 1 calc R U . . .
C69 C 0.3173(10) 0.8917(10) -0.0631(5) 0.077(3) Uani 1 1 d D U . . .
H69 H 0.300117 0.890342 -0.098744 0.093 Uiso 1 1 calc R U . . .
C70 C 0.3641(9) 0.8158(9) -0.0316(5) 0.074(3) Uani 1 1 d D U . . .
H70 H 0.379627 0.762413 -0.045428 0.089 Uiso 1 1 calc R U . . .
C71 C 0.3882(8) 0.8187(8) 0.0209(5) 0.069(3) Uani 1 1 d D U . . .
H71 H 0.419860 0.766784 0.043108 0.083 Uiso 1 1 calc R U . . .
C72 C 0.2942(10) 1.0593(9) 0.0300(6) 0.069(3) Uani 1 1 d D U . . .
H72A H 0.261617 1.105094 0.001808 0.103 Uiso 1 1 calc R U . . .
H72B H 0.255908 1.052787 0.061306 0.103 Uiso 1 1 calc R U . . .
H72C H 0.348754 1.075814 0.040356 0.103 Uiso 1 1 calc R U . . .
C73 C 0.6646(9) 0.7448(9) 0.1359(6) 0.037(2) Uani 1 1 d . U . . .
C74 C 0.6789(10) 0.6856(10) 0.1118(6) 0.044(2) Uani 1 1 d . U . . .
C75 C 0.6971(10) 0.6122(9) 0.0835(6) 0.044(2) Uani 1 1 d . U . . .
C76 C 0.6261(10) 0.5663(9) 0.0772(6) 0.042(2) Uani 1 1 d . U . . .
H76 H 0.568952 0.581421 0.092970 0.050 Uiso 1 1 calc R U . . .
C77 C 0.6472(10) 0.4975(9) 0.0461(6) 0.044(2) Uani 1 1 d . U . . .
H77 H 0.603975 0.464168 0.042158 0.053 Uiso 1 1 calc R U . . .
C78 C 0.7284(10) 0.4786(10) 0.0220(6) 0.047(2) Uani 1 1 d . U . . .
C79 C 0.7970(11) 0.5208(10) 0.0272(6) 0.048(2) Uani 1 1 d . U . . .
C80 C 0.8779(11) 0.4998(10) 0.0020(7) 0.052(2) Uani 1 1 d . U . . .
C81 C 0.9419(11) 0.5487(10) 0.0048(7) 0.053(2) Uani 1 1 d . U . . .
H81 H 0.996522 0.534866 -0.013799 0.064 Uiso 1 1 calc R U . . .
C82 C 0.9286(11) 0.6181(11) 0.0340(7) 0.055(2) Uani 1 1 d . U . . .
H82 H 0.972986 0.650982 0.035889 0.066 Uiso 1 1 calc R U . . .
C83 C 0.8458(10) 0.6367(10) 0.0607(6) 0.046(2) Uani 1 1 d . U . . .
H83 H 0.835643 0.681508 0.082225 0.055 Uiso 1 1 calc R U . . .
C84 C 0.7804(10) 0.5923(9) 0.0564(6) 0.0440(19) Uani 1 1 d . U . . .
C85 C 0.7406(12) 0.4067(10) -0.0132(7) 0.054(2) Uani 1 1 d . U . . .
C86 C 0.8968(12) 0.4259(11) -0.0285(7) 0.059(2) Uani 1 1 d . U . . .
C87 C 0.8490(11) 0.3105(8) -0.0639(6) 0.063(3) Uani 1 1 d D U . . .
H87 H 0.794055 0.285863 -0.063190 0.075 Uiso 1 1 calc R U . . .
C88 C 0.8605(17) 0.3459(13) -0.1232(7) 0.080(5) Uani 1 1 d D U . . .
H88A H 0.876777 0.296766 -0.142980 0.119 Uiso 1 1 calc R U . . .
H88B H 0.804040 0.384854 -0.137855 0.119 Uiso 1 1 calc R U . . .
H88C H 0.908135 0.378831 -0.126596 0.119 Uiso 1 1 calc R U . . .
C89 C 0.9207(8) 0.2358(6) -0.0372(5) 0.070(3) Uani 1 1 d D U . . .
C90 C 0.9073(9) 0.1964(8) 0.0148(6) 0.071(3) Uani 1 1 d D U . . .
H90 H 0.853321 0.217051 0.032533 0.085 Uiso 1 1 calc R U . . .
C91 C 0.9719(10) 0.1276(9) 0.0406(5) 0.078(3) Uani 1 1 d D U . . .
H91 H 0.962533 0.101242 0.076333 0.093 Uiso 1 1 calc R U . . .
C92 C 1.0504(10) 0.0966(9) 0.0150(6) 0.085(4) Uani 1 1 d D U . . .
H92 H 1.094534 0.048570 0.032804 0.102 Uiso 1 1 calc R U . . .
C93 C 1.0641(10) 0.1361(10) -0.0367(6) 0.086(3) Uani 1 1 d D U . . .
H93 H 1.118170 0.115436 -0.054378 0.103 Uiso 1 1 calc R U . . .
C94 C 0.9992(10) 0.2058(9) -0.0629(5) 0.082(3) Uani 1 1 d D U . . .
H94 H 1.008774 0.232750 -0.098417 0.099 Uiso 1 1 calc R U . . .
C95 C 0.5793(10) 0.9319(10) 0.2282(6) 0.042(2) Uani 1 1 d . U . . .
C96 C 0.5492(12) 0.9870(12) 0.2543(7) 0.058(2) Uani 1 1 d . U . . .
C97 C 0.4918(8) 1.0449(8) 0.2870(4) 0.064(2) Uani 1 1 d D U . . .
C98 C 0.4040(8) 1.0427(8) 0.3005(5) 0.062(2) Uani 1 1 d D U . . .
H98 H 0.376168 1.001776 0.287900 0.075 Uiso 1 1 calc R U . . .
C99 C 0.3561(8) 1.0997(8) 0.3324(5) 0.076(3) Uani 1 1 d D U . . .
H99 H 0.295903 1.097836 0.341694 0.091 Uiso 1 1 calc R U . . .
C100 C 0.3972(9) 1.1596(8) 0.3506(5) 0.080(2) Uani 1 1 d D U . . .
C101 C 0.4840(7) 1.1619(7) 0.3373(4) 0.073(2) Uani 1 1 d D U . . .
C102 C 0.5225(9) 1.2209(8) 0.3559(5) 0.078(3) Uani 1 1 d D U . . .
C103 C 0.6106(9) 1.2267(8) 0.3441(5) 0.076(3) Uani 1 1 d D U . . .
H103 H 0.636563 1.268338 0.357420 0.091 Uiso 1 1 calc R U . . .
C104 C 0.6597(9) 1.1701(9) 0.3122(5) 0.072(3) Uani 1 1 d D U . . .
H104 H 0.720057 1.172488 0.303738 0.087 Uiso 1 1 calc R U . . .
C105 C 0.6207(8) 1.1105(8) 0.2929(5) 0.063(2) Uani 1 1 d D U . . .
H105 H 0.654448 1.072642 0.270763 0.075 Uiso 1 1 calc R U . . .
C106 C 0.5334(7) 1.1049(7) 0.3052(4) 0.068(2) Uani 1 1 d D U . . .
C107 C 0.3427(14) 1.2247(13) 0.3824(9) 0.093(3) Uani 1 1 d D U . . .
C108 C 0.4816(13) 1.2829(12) 0.3896(9) 0.090(3) Uani 1 1 d D U . . .
C109 C 0.3408(12) 1.3475(10) 0.4292(7) 0.107(3) Uani 1 1 d D U . . .
H109 H 0.285737 1.324112 0.438107 0.129 Uiso 1 1 calc R U . . .
C110 C 0.378(2) 1.341(2) 0.4851(9) 0.112(6) Uani 1 1 d D U . . .
H11A H 0.342170 1.387724 0.502440 0.168 Uiso 1 1 calc R U . . .
H11B H 0.376180 1.283661 0.506335 0.168 Uiso 1 1 calc R U . . .
H11C H 0.440584 1.347503 0.482837 0.168 Uiso 1 1 calc R U . . .
C111 C 0.2998(9) 1.4345(9) 0.3959(6) 0.113(4) Uani 1 1 d D U . . .
C112 C 0.2352(13) 1.4947(11) 0.4181(7) 0.124(4) Uani 1 1 d D U . . .
H112 H 0.217249 1.480514 0.454155 0.149 Uiso 1 1 calc R U . . .
C113 C 0.1970(15) 1.5755(12) 0.3875(9) 0.129(4) Uani 1 1 d D U . . .
H113 H 0.152941 1.616691 0.402670 0.155 Uiso 1 1 calc R U . . .
C114 C 0.2228(15) 1.5964(11) 0.3349(9) 0.124(4) Uani 1 1 d D U . . .
H114 H 0.196353 1.651751 0.314095 0.149 Uiso 1 1 calc R U . . .
C115 C 0.2872(16) 1.5368(13) 0.3128(7) 0.121(4) Uani 1 1 d D U . . .
H115 H 0.305024 1.551062 0.276755 0.145 Uiso 1 1 calc R U . . .
C116 C 0.3255(13) 1.4559(11) 0.3434(6) 0.117(4) Uani 1 1 d D U . . .
H116 H 0.369709 1.414889 0.328200 0.141 Uiso 1 1 calc R U . . .
C201 C -0.2586(12) 1.9969(10) 0.6784(7) 0.048(2) Uani 1 1 d . U . . .
H20A H -0.313986 2.034160 0.690252 0.058 Uiso 1 1 calc R U . . .
H20B H -0.206950 2.017821 0.690054 0.058 Uiso 1 1 calc R U . . .
C202 C -0.2647(10) 1.8944(11) 0.7795(6) 0.045(2) Uani 1 1 d . U . . .
H20C H -0.318912 1.941212 0.782043 0.054 Uiso 1 1 calc R U . . .
H20D H -0.212725 1.914399 0.791531 0.054 Uiso 1 1 calc R U . . .
C203 C -0.2958(11) 2.1280(13) 0.5835(7) 0.066(3) Uani 1 1 d D U . . .
C204 C -0.2977(8) 2.1601(12) 0.5287(7) 0.072(3) Uani 1 1 d D U . . .
C205 C -0.3268(11) 2.2482(11) 0.5092(8) 0.081(3) Uani 1 1 d D U . . .
H205 H -0.328037 2.269713 0.471697 0.098 Uiso 1 1 calc R U . . .
C206 C -0.3541(13) 2.3044(13) 0.5450(7) 0.084(3) Uani 1 1 d D U . . .
H206 H -0.374533 2.365604 0.532458 0.101 Uiso 1 1 calc R U . . .
C207 C -0.3519(12) 2.2718(11) 0.5991(7) 0.083(3) Uani 1 1 d D U . . .
H207 H -0.371058 2.311926 0.623165 0.100 Uiso 1 1 calc R U . . .
C208 C -0.3233(12) 2.1842(10) 0.6201(8) 0.076(3) Uani 1 1 d D U . . .
H208 H -0.322333 2.163234 0.657589 0.091 Uiso 1 1 calc R U . . .
C209 C -0.2686(12) 2.1050(12) 0.4866(7) 0.069(4) Uani 1 1 d . U . . .
H20F H -0.248839 2.043275 0.503558 0.104 Uiso 1 1 calc R U . . .
H20G H -0.319009 2.111079 0.461862 0.104 Uiso 1 1 calc R U . . .
H20H H -0.218817 2.124224 0.466748 0.104 Uiso 1 1 calc R U . . .
C210 C -0.1457(13) 1.9836(10) 0.5871(6) 0.070(3) Uani 1 1 d D U . . .
C211 C -0.1054(11) 1.9064(11) 0.5700(5) 0.078(3) Uani 1 1 d D U . . .
C212 C -0.0159(11) 1.8788(14) 0.5568(7) 0.086(3) Uani 1 1 d D U . . .
H212 H 0.007709 1.824342 0.545141 0.104 Uiso 1 1 calc R U . . .
C213 C 0.0347(15) 1.9385(12) 0.5622(8) 0.087(3) Uani 1 1 d D U . . .
H213 H 0.096794 1.925063 0.554119 0.104 Uiso 1 1 calc R U . . .
C214 C -0.0013(13) 2.0173(13) 0.5790(7) 0.083(3) Uani 1 1 d D U . . .
H214 H 0.036972 2.056125 0.581801 0.099 Uiso 1 1 calc R U . . .
C215 C -0.0908(12) 2.0421(14) 0.5919(7) 0.076(3) Uani 1 1 d D U . . .
H215 H -0.114167 2.096601 0.603507 0.091 Uiso 1 1 calc R U . . .
C216 C -0.1630(14) 1.8446(13) 0.5650(8) 0.091(4) Uani 1 1 d D U . . .
H21A H -0.127031 1.792379 0.552660 0.137 Uiso 1 1 calc R U . . .
H21B H -0.188310 1.827087 0.600022 0.137 Uiso 1 1 calc R U . . .
H21C H -0.211784 1.873192 0.539063 0.137 Uiso 1 1 calc R U . . .
C217 C -0.1333(11) 1.8257(12) 0.7090(7) 0.052(2) Uani 1 1 d . U . . .
C218 C -0.0658(12) 1.8619(14) 0.7200(8) 0.063(2) Uani 1 1 d . U . . .
H218 H -0.079887 1.918889 0.729418 0.075 Uiso 1 1 calc R U . . .
C219 C 0.0225(13) 1.8198(15) 0.7183(9) 0.070(3) Uani 1 1 d . U . . .
H219 H 0.069068 1.849158 0.722552 0.084 Uiso 1 1 calc R U . . .
C220 C 0.0424(13) 1.7323(15) 0.7100(9) 0.070(3) Uani 1 1 d . U . . .
H220 H 0.103360 1.701038 0.711752 0.084 Uiso 1 1 calc R U . . .
C221 C -0.0208(13) 1.6915(16) 0.6997(10) 0.073(3) Uani 1 1 d . U . . .
H221 H -0.006499 1.634016 0.691073 0.088 Uiso 1 1 calc R U . . .
C222 C -0.1132(12) 1.7400(14) 0.7024(9) 0.064(3) Uani 1 1 d . U . . .
H222 H -0.160628 1.711138 0.699522 0.077 Uiso 1 1 calc R U . . .
C223 C -0.3255(10) 1.8367(11) 0.8884(7) 0.042(2) Uani 1 1 d . U . . .
C224 C -0.3425(10) 1.7722(11) 0.9304(7) 0.043(2) Uani 1 1 d . U . . .
C225 C -0.3883(10) 1.7989(10) 0.9740(7) 0.043(2) Uani 1 1 d . U . . .
H225 H -0.401267 1.757555 1.003286 0.052 Uiso 1 1 calc R U . . .
C226 C -0.4166(11) 1.8947(12) 0.9738(7) 0.048(3) Uani 1 1 d . U . . .
H226 H -0.454117 1.915760 1.001336 0.058 Uiso 1 1 calc R U . . .
C227 C -0.3903(11) 1.9509(12) 0.9356(8) 0.049(3) Uani 1 1 d . U . . .
H227 H -0.400290 2.011129 0.938903 0.058 Uiso 1 1 calc R U . . .
C228 C -0.3476(11) 1.9219(11) 0.8902(6) 0.045(2) Uani 1 1 d . U . . .
H228 H -0.334755 1.963182 0.860868 0.054 Uiso 1 1 calc R U . . .
C229 C -0.3156(13) 1.6746(12) 0.9311(7) 0.055(4) Uani 1 1 d . U . . .
H22C H -0.283502 1.663202 0.898205 0.083 Uiso 1 1 calc R U . . .
H22D H -0.276320 1.646793 0.962339 0.083 Uiso 1 1 calc R U . . .
H22E H -0.369421 1.650313 0.933249 0.083 Uiso 1 1 calc R U . . .
C230 C -0.1640(8) 1.7303(9) 0.8421(6) 0.058(2) Uani 1 1 d D U . . .
C231 C -0.1017(9) 1.7676(8) 0.8642(4) 0.069(3) Uani 1 1 d D U . . .
C232 C -0.0176(9) 1.7170(10) 0.8799(6) 0.080(3) Uani 1 1 d D U . . .
H232 H 0.024869 1.742258 0.894847 0.095 Uiso 1 1 calc R U . . .
C233 C 0.0051(9) 1.6295(9) 0.8738(7) 0.081(3) Uani 1 1 d D U . . .
H233 H 0.062875 1.594750 0.884986 0.097 Uiso 1 1 calc R U . . .
C234 C -0.0561(10) 1.5929(8) 0.8517(6) 0.079(3) Uani 1 1 d D U . . .
H234 H -0.040242 1.533057 0.847220 0.095 Uiso 1 1 calc R U . . .
C235 C -0.1411(9) 1.6436(9) 0.8360(6) 0.069(3) Uani 1 1 d D U . . .
H235 H -0.183417 1.618271 0.820928 0.083 Uiso 1 1 calc R U . . .
C236 C -0.1093(14) 1.8587(11) 0.8744(6) 0.087(4) Uani 1 1 d D U . . .
H23A H -0.169188 1.894202 0.863147 0.131 Uiso 1 1 calc R U . . .
H23B H -0.099990 1.857457 0.912754 0.131 Uiso 1 1 calc R U . . .
H23C H -0.063719 1.884510 0.853905 0.131 Uiso 1 1 calc R U . . .
C237 C -0.4802(10) 1.7753(11) 0.5839(6) 0.041(2) Uani 1 1 d . U . . .
H23D H -0.427975 1.726890 0.580402 0.049 Uiso 1 1 calc R U . . .
H23E H -0.534480 1.759019 0.571817 0.049 Uiso 1 1 calc R U . . .
C238 C -0.4836(12) 1.6753(11) 0.6875(7) 0.049(2) Uani 1 1 d . U . . .
H23F H -0.429294 1.638355 0.674330 0.059 Uiso 1 1 calc R U . . .
H23G H -0.536258 1.655462 0.676173 0.059 Uiso 1 1 calc R U . . .
C239 C -0.4222(10) 1.8388(12) 0.4804(6) 0.042(2) Uani 1 1 d . U . . .
C240 C -0.4038(11) 1.8999(13) 0.4362(7) 0.047(3) Uani 1 1 d . U . . .
C241 C -0.3595(12) 1.8628(13) 0.3946(7) 0.056(3) Uani 1 1 d . U . . .
H241 H -0.341082 1.902589 0.366406 0.067 Uiso 1 1 calc R U . . .
C242 C -0.3404(12) 1.7840(14) 0.3891(7) 0.056(3) Uani 1 1 d . U . . .
H242 H -0.314738 1.767235 0.356878 0.067 Uiso 1 1 calc R U . . .
C243 C -0.3576(13) 1.7206(14) 0.4317(8) 0.055(3) Uani 1 1 d . U . . .
H243 H -0.339763 1.659920 0.429514 0.066 Uiso 1 1 calc R U . . .
C244 C -0.3997(11) 1.7466(13) 0.4759(6) 0.049(2) Uani 1 1 d . U . . .
H244 H -0.414523 1.704259 0.503834 0.059 Uiso 1 1 calc R U . . .
C245 C -0.4318(12) 1.9959(12) 0.4366(7) 0.055(4) Uani 1 1 d . U . . .
H24A H -0.461890 2.005722 0.470326 0.082 Uiso 1 1 calc R U . . .
H24B H -0.378689 2.021388 0.433451 0.082 Uiso 1 1 calc R U . . .
H24C H -0.473133 2.023746 0.406346 0.082 Uiso 1 1 calc R U . . .
C246 C -0.5797(10) 1.9419(10) 0.5233(5) 0.057(2) Uani 1 1 d D U . . .
C247 C -0.6121(10) 2.0253(10) 0.5353(5) 0.068(3) Uani 1 1 d D U . . .
C248 C -0.7021(10) 2.0660(12) 0.5206(6) 0.072(3) Uani 1 1 d D U . . .
H248 H -0.727125 2.123284 0.527987 0.086 Uiso 1 1 calc R U . . .
C249 C -0.7542(12) 2.0230(11) 0.4955(7) 0.073(3) Uani 1 1 d D U . . .
H249 H -0.814613 2.052349 0.486448 0.087 Uiso 1 1 calc R U . . .
C250 C -0.7240(10) 1.9395(11) 0.4827(6) 0.073(3) Uani 1 1 d D U . . .
H250 H -0.760893 1.911241 0.465270 0.088 Uiso 1 1 calc R U . . .
C251 C -0.6351(10) 1.9009(11) 0.4977(6) 0.064(3) Uani 1 1 d D U . . .
H251 H -0.610479 1.843687 0.490109 0.077 Uiso 1 1 calc R U . . .
C252 C -0.5605(14) 2.0745(13) 0.5620(7) 0.075(4) Uani 1 1 d . U . . .
H25A H -0.598594 2.131719 0.565767 0.112 Uiso 1 1 calc R U . . .
H25B H -0.540118 2.041291 0.597524 0.112 Uiso 1 1 calc R U . . .
H25C H -0.508298 2.083419 0.540340 0.112 Uiso 1 1 calc R U . . .
C253 C -0.6097(10) 1.8427(10) 0.6600(6) 0.051(2) Uani 1 1 d D U . . .
C254 C -0.6758(9) 1.7976(11) 0.6520(6) 0.061(2) Uani 1 1 d D U . . .
H254 H -0.659572 1.738281 0.646543 0.073 Uiso 1 1 calc R U . . .
C255 C -0.7656(11) 1.8404(11) 0.6522(6) 0.068(3) Uani 1 1 d D U . . .
H255 H -0.810825 1.810151 0.646765 0.082 Uiso 1 1 calc R U . . .
C256 C -0.7897(11) 1.9262(11) 0.6603(7) 0.067(3) Uani 1 1 d D U . . .
H256 H -0.851426 1.954689 0.660505 0.080 Uiso 1 1 calc R U . . .
C257 C -0.7240(9) 1.9716(12) 0.6681(7) 0.067(3) Uani 1 1 d D U . . .
H257 H -0.740453 2.030966 0.673476 0.080 Uiso 1 1 calc R U . . .
C258 C -0.6350(10) 1.9292(10) 0.6678(7) 0.061(2) Uani 1 1 d D U . . .
H258 H -0.589963 1.959854 0.673042 0.074 Uiso 1 1 calc R U . . .
C259 C -0.5965(12) 1.6860(11) 0.7800(8) 0.063(2) Uani 1 1 d D U . . .
C260 C -0.6324(11) 1.7644(11) 0.7981(7) 0.070(3) Uani 1 1 d D U . . .
C261 C -0.7241(11) 1.7797(14) 0.8079(9) 0.079(3) Uani 1 1 d D U . . .
H26B H -0.753308 1.832536 0.819717 0.095 Uiso 1 1 calc R U . . .
C262 C -0.7731(15) 1.7191(13) 0.8005(10) 0.080(3) Uani 1 1 d D U . . .
H262 H -0.835029 1.732344 0.809007 0.096 Uiso 1 1 calc R U . . .
C263 C -0.7407(12) 1.6415(13) 0.7822(9) 0.076(3) Uani 1 1 d D U . . .
H263 H -0.776358 1.601450 0.776970 0.092 Uiso 1 1 calc R U . . .
C264 C -0.6502(11) 1.6288(13) 0.7722(8) 0.066(3) Uani 1 1 d D U . . .
H264 H -0.622223 1.576905 0.758910 0.079 Uiso 1 1 calc R U . . .
C265 C -0.5891(15) 1.8354(14) 0.8097(9) 0.079(4) Uani 1 1 d D U . . .
H26E H -0.634630 1.881902 0.821955 0.119 Uiso 1 1 calc R U . . .
H26F H -0.542761 1.810831 0.837788 0.119 Uiso 1 1 calc R U . . .
H26G H -0.561666 1.860075 0.777050 0.119 Uiso 1 1 calc R U . . .
C266 C -0.4445(10) 1.5375(12) 0.7810(6) 0.061(3) Uani 1 1 d D U . . .
C267 C -0.4398(8) 1.5030(11) 0.8355(7) 0.066(3) Uani 1 1 d D U . . .
C268 C -0.4136(10) 1.4115(11) 0.8448(8) 0.073(3) Uani 1 1 d D U . . .
H268 H -0.408941 1.383672 0.881320 0.088 Uiso 1 1 calc R U . . .
C269 C -0.3936(11) 1.3561(13) 0.8069(6) 0.076(3) Uani 1 1 d D U . . .
H269 H -0.376452 1.294189 0.818010 0.091 Uiso 1 1 calc R U . . .
C270 C -0.3989(11) 1.3919(11) 0.7528(7) 0.077(3) Uani 1 1 d D U . . .
H270 H -0.386001 1.357527 0.725153 0.092 Uiso 1 1 calc R U . . .
C271 C -0.4247(11) 1.4829(10) 0.7430(8) 0.071(3) Uani 1 1 d D U . . .
H271 H -0.429256 1.510603 0.706488 0.085 Uiso 1 1 calc R U . . .
C272 C -0.4587(12) 1.5488(13) 0.8781(7) 0.069(4) Uani 1 1 d . U . . .
H27A H -0.449559 1.507301 0.912012 0.103 Uiso 1 1 calc R U . . .
H27B H -0.418560 1.589431 0.877205 0.103 Uiso 1 1 calc R U . . .
H27C H -0.521174 1.582133 0.875054 0.103 Uiso 1 1 calc R U . . .
C273 C -0.4429(10) 1.9378(12) 0.7166(7) 0.048(2) Uani 1 1 d . U . . .
C274 C -0.4765(12) 1.9978(12) 0.7378(8) 0.054(2) Uani 1 1 d . U . . .
C275 C -0.5208(7) 2.0626(9) 0.7707(5) 0.058(2) Uani 1 1 d D U . . .
C276 C -0.5425(6) 2.0317(9) 0.8238(5) 0.057(2) Uani 1 1 d D U . . .
H276 H -0.522707 1.971345 0.838925 0.068 Uiso 1 1 calc R U . . .
C277 C -0.5935(6) 2.0908(8) 0.8544(7) 0.060(2) Uani 1 1 d D U . . .
H277 H -0.608739 2.070592 0.890184 0.072 Uiso 1 1 calc R U . . .
C278 C -0.6218(7) 2.1798(8) 0.8316(6) 0.062(2) Uani 1 1 d D U . . .
C279 C -0.6000(7) 2.2105(9) 0.7784(5) 0.065(2) Uani 1 1 d D U . . .
C280 C -0.6306(9) 2.3011(10) 0.7568(7) 0.072(3) Uani 1 1 d D U . . .
C281 C -0.6094(10) 2.3322(12) 0.7033(6) 0.079(3) Uani 1 1 d D U . . .
H281 H -0.630621 2.392810 0.689242 0.095 Uiso 1 1 calc R U . . .
C282 C -0.5582(10) 2.2778(10) 0.6697(8) 0.082(3) Uani 1 1 d D U . . .
H282 H -0.543873 2.299799 0.634043 0.098 Uiso 1 1 calc R U . . .
C283 C -0.5298(10) 2.1881(11) 0.6929(7) 0.074(3) Uani 1 1 d D U . . .
H283 H -0.495429 2.149204 0.671662 0.088 Uiso 1 1 calc R U . . .
C284 C -0.5496(7) 2.1527(8) 0.7463(6) 0.064(2) Uani 1 1 d D U . . .
C285 C -0.6767(8) 2.2382(12) 0.8675(8) 0.068(2) Uani 1 1 d D U . . .
C286 C -0.6836(10) 2.3626(13) 0.7882(9) 0.076(3) Uani 1 1 d . U . . .
C287 C -0.7495(11) 2.3877(10) 0.8774(7) 0.076(3) Uani 1 1 d D U . . .
H287 H -0.757356 2.448499 0.856363 0.091 Uiso 1 1 calc R U . . .
C288 C -0.8437(11) 2.3706(16) 0.8873(9) 0.092(5) Uani 1 1 d D U . . .
H28A H -0.876250 2.410244 0.910501 0.139 Uiso 1 1 calc R U . . .
H28B H -0.876247 2.380945 0.852975 0.139 Uiso 1 1 calc R U . . .
H28C H -0.838858 2.309509 0.904787 0.139 Uiso 1 1 calc R U . . .
C289 C -0.7023(9) 2.3868(6) 0.9290(7) 0.079(3) Uani 1 1 d D U . . .
C290 C -0.6137(11) 2.3951(9) 0.9278(9) 0.080(3) Uani 1 1 d D U . . .
H290 H -0.585397 2.401239 0.894006 0.096 Uiso 1 1 calc R U . . .
C291 C -0.5642(15) 2.3949(11) 0.9733(8) 0.087(3) Uani 1 1 d D U . . .
H291 H -0.503515 2.400521 0.971268 0.104 Uiso 1 1 calc R U . . .
C292 C -0.6079(14) 2.3862(10) 1.0216(9) 0.088(4) Uani 1 1 d D U . . .
H292 H -0.575202 2.386192 1.053138 0.106 Uiso 1 1 calc R U . . .
C293 C -0.6958(13) 2.3774(12) 1.0275(9) 0.089(4) Uani 1 1 d D U . . .
H293 H -0.724004 2.371493 1.061309 0.107 Uiso 1 1 calc R U . . .
C294 C -0.7394(14) 2.3778(10) 0.9798(7) 0.083(3) Uani 1 1 d D U . . .
H294 H -0.799765 2.371403 0.982002 0.100 Uiso 1 1 calc R U . . .
C295 C -0.3023(11) 1.7376(13) 0.6496(8) 0.054(2) Uani 1 1 d . U . . .
C296 C -0.2616(14) 1.6809(15) 0.6255(9) 0.067(3) Uani 1 1 d . U . . .
C297 C -0.2194(9) 1.6106(12) 0.5969(7) 0.081(3) Uani 1 1 d D U . . .
C298 C -0.1946(7) 1.6427(13) 0.5465(6) 0.080(3) Uani 1 1 d D U . . .
H298 H -0.210543 1.704458 0.534647 0.096 Uiso 1 1 calc R U . . .
C299 C -0.1485(7) 1.5916(12) 0.5122(8) 0.090(3) Uani 1 1 d D U . . .
H299 H -0.132329 1.616367 0.477493 0.108 Uiso 1 1 calc R U . . .
C300 C -0.1264(9) 1.5019(12) 0.5304(7) 0.089(3) Uani 1 1 d D U . . .
C301 C -0.1483(9) 1.4644(12) 0.5801(7) 0.090(3) Uani 1 1 d D U . . .
C302 C -0.1250(10) 1.3746(12) 0.5970(8) 0.094(3) Uani 1 1 d D U . . .
C303 C -0.1470(11) 1.3368(16) 0.6472(8) 0.098(3) Uani 1 1 d D U . . .
H303 H -0.130222 1.274983 0.658423 0.118 Uiso 1 1 calc R U . . .
C304 C -0.1940(12) 1.3903(13) 0.6811(9) 0.096(3) Uani 1 1 d D U . . .
H304 H -0.210559 1.365682 0.715799 0.115 Uiso 1 1 calc R U . . .
C305 C -0.2165(12) 1.4801(14) 0.6636(8) 0.089(3) Uani 1 1 d D U . . .
H305 H -0.248407 1.516423 0.687193 0.107 Uiso 1 1 calc R U . . .
C306 C -0.1947(9) 1.5201(12) 0.6133(7) 0.087(3) Uani 1 1 d D U . . .
C307 C -0.0777(10) 1.4458(17) 0.4960(8) 0.097(3) Uani 1 1 d D U . . .
C308 C -0.0772(11) 1.3180(13) 0.5633(9) 0.101(3) Uani 1 1 d D U . . .
C309 C 0.0020(13) 1.3093(15) 0.4717(7) 0.111(3) Uani 1 1 d D U . . .
H309 H 0.028875 1.357737 0.452462 0.134 Uiso 1 1 calc R U . . .
C310 C 0.0891(17) 1.247(2) 0.4937(12) 0.123(6) Uani 1 1 d D U . . .
H31A H 0.119484 1.217414 0.465130 0.184 Uiso 1 1 calc R U . . .
H31B H 0.128113 1.280067 0.507259 0.184 Uiso 1 1 calc R U . . .
H31C H 0.075677 1.202748 0.523051 0.184 Uiso 1 1 calc R U . . .
C311 C -0.0486(10) 1.2956(9) 0.4245(6) 0.111(3) Uani 1 1 d D U . . .
C312 C -0.1294(11) 1.2683(13) 0.4321(7) 0.112(3) Uani 1 1 d D U . . .
H312 H -0.152771 1.258248 0.467094 0.134 Uiso 1 1 calc R U . . .
C313 C -0.1754(12) 1.2559(14) 0.3884(9) 0.116(4) Uani 1 1 d D U . . .
H313 H -0.230393 1.237411 0.393681 0.139 Uiso 1 1 calc R U . . .
C314 C -0.1419(14) 1.2704(14) 0.3372(8) 0.117(4) Uani 1 1 d D U . . .
H314 H -0.173761 1.261761 0.307394 0.141 Uiso 1 1 calc R U . . .
C315 C -0.0613(14) 1.2975(16) 0.3296(7) 0.117(4) Uani 1 1 d D U . . .
H315 H -0.037932 1.307391 0.294512 0.141 Uiso 1 1 calc R U . . .
C316 C -0.0152(12) 1.3101(13) 0.3731(7) 0.114(4) Uani 1 1 d D U . . .
H316 H 0.039747 1.328799 0.367743 0.137 Uiso 1 1 calc R U . . .
O13 O 0.4367(15) 0.4726(9) 0.5656(7) 0.151(6) Uani 0.88(2) 1 d D U P A 1
O14 O 0.5443(9) 0.5320(13) 0.5995(8) 0.137(4) Uani 0.88(2) 1 d D U P A 1
O15 O 0.4305(16) 0.6208(9) 0.5442(6) 0.131(6) Uani 0.88(2) 1 d D U P A 1
O16 O 0.3987(13) 0.5609(12) 0.6301(6) 0.119(5) Uani 0.88(2) 1 d D U P A 1
O13' O 0.4367(15) 0.4726(9) 0.5656(7) 0.151(4) Uani 0.12(2) 1 d D U P A 2
O14' O 0.512(6) 0.585(5) 0.553(3) 0.122(9) Uani 0.12(2) 1 d D U P A 2
O15' O 0.371(2) 0.607(4) 0.588(4) 0.122(10) Uani 0.12(2) 1 d D U P A 2
O16' O 0.491(7) 0.517(2) 0.6383(19) 0.129(9) Uani 0.12(2) 1 d D U P A 2
O17 O -0.0535(7) 1.1646(8) 1.2131(7) 0.093(5) Uani 1 1 d D U . . .
O18 O -0.0787(10) 1.0444(9) 1.1811(7) 0.114(6) Uani 1 1 d D U . . .
O19 O -0.1981(7) 1.1498(9) 1.2019(8) 0.112(5) Uani 1 1 d D U . . .
O20 O -0.1076(14) 1.0590(11) 1.2683(5) 0.145(7) Uani 1 1 d D U . . .
Cl4 Cl 0.7968(5) 1.1254(4) 0.7819(3) 0.0814(16) Uani 1 1 d D U . . .
O21 O 0.7181(10) 1.0967(11) 0.7967(8) 0.139(6) Uani 1 1 d D U . . .
O22 O 0.8621(10) 1.0591(11) 0.7656(8) 0.138(7) Uani 1 1 d D U . . .
O23 O 0.7720(14) 1.1946(11) 0.7353(6) 0.147(7) Uani 1 1 d D U . . .
O24 O 0.8275(13) 1.1622(12) 0.8218(7) 0.146(7) Uani 1 1 d D U . . .
Cl5 Cl 0.0665(7) 1.4120(6) 1.1045(4) 0.143(3) Uani 1 1 d D U . . .
Cl6 Cl 0.2075(9) 1.2218(6) 1.1069(5) 0.170(4) Uani 1 1 d D U . . .
C01 C 0.029(2) 1.3157(14) 1.1008(18) 0.159(7) Uani 1 1 d D U . . .
H01A H -0.025510 1.316755 1.123157 0.191 Uiso 1 1 calc R U . . .
H01B H 0.009234 1.319159 1.063246 0.191 Uiso 1 1 calc R U . . .
C02 C 0.0926(12) 1.227(2) 1.1177(18) 0.155(7) Uani 1 1 d D U . . .
H02A H 0.074395 1.184143 1.098296 0.186 Uiso 1 1 calc R U . . .
H02B H 0.084639 1.207366 1.156459 0.186 Uiso 1 1 calc R U . . .
Cl7 Cl 1.2500(7) 0.6432(7) -0.0786(3) 0.120(3) Uani 1 1 d D U . . .
Cl8 Cl 1.1299(8) 0.7173(8) 0.0143(6) 0.170(4) Uani 1 1 d D U . . .
C03 C 1.2662(15) 0.608(2) -0.0084(6) 0.105(5) Uani 1 1 d D U . . .
H03A H 1.307517 0.548948 -0.000920 0.126 Uiso 1 1 calc R U . . .
H03B H 1.292248 0.649445 0.007667 0.126 Uiso 1 1 calc R U . . .
C04 C 1.1741(14) 0.6034(11) 0.0147(11) 0.096(4) Uani 1 1 d D U . . .
H04A H 1.178641 0.569013 0.051476 0.116 Uiso 1 1 calc R U . . .
H04B H 1.138214 0.578968 -0.008470 0.116 Uiso 1 1 calc R U . . .
Cl9 Cl 0.1543(7) 1.7625(8) 0.4573(6) 0.171(4) Uani 1 1 d D U . . .
C05 C 0.202(3) 1.676(2) 0.5094(14) 0.177(7) Uani 1 1 d D U . . .
H05A H 0.224129 1.624737 0.491012 0.212 Uiso 1 1 calc R U . . .
H05B H 0.255609 1.692111 0.521519 0.212 Uiso 1 1 calc R U . . .
C06 C 0.161(2) 1.637(4) 0.5610(17) 0.199(8) Uani 1 1 d D U . . .
H06A H 0.142832 1.682388 0.584153 0.238 Uiso 1 1 calc R U . . .
H06B H 0.205043 1.587269 0.580977 0.238 Uiso 1 1 calc R U . . .
Cl10 Cl 0.0644(12) 1.6005(15) 0.5436(9) 0.269(8) Uani 1 1 d D U . . .
Cl11 Cl 0.1609(8) 0.9925(7) 0.3461(4) 0.153(3) Uani 1 1 d D U . . .
Cl12 Cl 0.0253(13) 1.0269(13) 0.4353(7) 0.237(7) Uani 1 1 d D U . . .
C07 C 0.068(3) 1.061(2) 0.3712(13) 0.202(11) Uani 1 1 d D U . . .
H07A H 0.018015 1.072534 0.344730 0.242 Uiso 1 1 calc R U . . .
H07B H 0.083997 1.118036 0.371915 0.242 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P4 2.322(4) . ?
Au1 P1 2.341(4) . ?
Au1 Pt1 2.9073(8) . ?
Au2 P6 2.300(4) . ?
Au2 P3 2.328(4) . ?
Au2 Pt1 2.9042(8) . ?
Au3 P10 2.325(4) . ?
Au3 P7 2.330(4) . ?
Au3 Pt2 2.9154(10) . ?
Au4 P12 2.324(4) . ?
Au4 P9 2.325(4) . ?
Au4 Pt2 2.9234(9) . ?
Pt1 C95 2.016(15) . ?
Pt1 C73 2.036(14) . ?
Pt1 P2 2.296(3) . ?
Pt1 P5 2.306(3) . ?
Pt2 C295 1.988(17) . ?
Pt2 C273 2.032(17) . ?
Pt2 P11 2.315(3) . ?
Pt2 P8 2.317(4) . ?
Cl1 O9 1.334(13) . ?
Cl1 O10 1.366(15) . ?
Cl1 O12 1.422(13) . ?
Cl1 O11 1.59(2) . ?
Cl2 O16 1.398(11) . ?
Cl2 O13' 1.405(8) . ?
Cl2 O13 1.405(8) . ?
Cl2 O14' 1.411(13) . ?
Cl2 O14 1.412(11) . ?
Cl2 O15' 1.413(13) . ?
Cl2 O16' 1.420(13) . ?
Cl2 O15 1.435(11) . ?
Cl3 O17 1.371(9) . ?
Cl3 O18 1.384(10) . ?
Cl3 O19 1.394(10) . ?
Cl3 O20 1.466(11) . ?
P1 C1 1.831(17) . ?
P1 C10 1.854(14) . ?
P1 C3 1.856(18) . ?
P2 C1 1.771(14) . ?
P2 C17 1.817(14) . ?
P2 C2 1.839(16) . ?
P3 C23 1.803(19) . ?
P3 C2 1.827(17) . ?
P3 C30 1.836(16) . ?
P4 C46 1.831(18) . ?
P4 C39 1.836(15) . ?
P4 C37 1.837(17) . ?
P5 C53 1.800(16) . ?
P5 C37 1.844(17) . ?
P5 C38 1.853(14) . ?
P6 C59 1.772(17) . ?
P6 C66 1.813(11) . ?
P6 C38 1.817(17) . ?
P7 C210 1.79(2) . ?
P7 C203 1.80(2) . ?
P7 C201 1.805(18) . ?
P8 C202 1.749(14) . ?
P8 C217 1.824(18) . ?
P8 C201 1.824(16) . ?
P9 C230 1.808(12) . ?
P9 C202 1.837(17) . ?
P9 C223 1.877(17) . ?
P10 C239 1.782(15) . ?
P10 C237 1.812(18) . ?
P10 C246 1.852(16) . ?
P11 C238 1.810(17) . ?
P11 C253 1.822(16) . ?
P11 C237 1.855(13) . ?
P12 C266 1.821(19) . ?
P12 C238 1.839(18) . ?
P12 C259 1.840(19) . ?
O1 C85 1.17(2) . ?
O2 C86 1.19(2) . ?
O3 C107 1.243(13) . ?
O4 C108 1.275(13) . ?
O5 C285 1.20(2) . ?
O6 C286 1.22(2) . ?
O7 C307 1.242(13) . ?
O8 C308 1.255(13) . ?
N1 C85 1.37(2) . ?
N1 C86 1.43(2) . ?
N1 C87 1.469(11) . ?
N2 C107 1.402(19) . ?
N2 C108 1.411(18) . ?
N2 C109 1.462(13) . ?
N3 C285 1.42(2) . ?
N3 C286 1.45(3) . ?
N3 C287 1.461(12) . ?
N4 C307 1.32(3) . ?
N4 C309 1.477(13) . ?
N4 C308 1.49(3) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C8 1.390(13) . ?
C3 C4 1.403(13) . ?
C4 C5 1.384(13) . ?
C4 C9 1.50(3) . ?
C5 C6 1.379(13) . ?
C5 H5 0.9500 . ?
C6 C7 1.387(13) . ?
C6 H6 0.9500 . ?
C7 C8 1.376(13) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C15 1.286(12) . ?
C10 C11 1.352(13) . ?
C11 C12 1.356(11) . ?
C11 C16 1.512(13) . ?
C12 C13 1.394(13) . ?
C12 H12 0.9500 . ?
C13 C14 1.474(12) . ?
C13 H13 0.9500 . ?
C14 C15 1.351(11) . ?
C14 H14 0.9500 . ?
C15 H15 0.9500 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C22 1.384(12) . ?
C17 C18 1.384(12) . ?
C18 C19 1.389(12) . ?
C18 H18 0.9500 . ?
C19 C20 1.408(12) . ?
C19 H19 0.9500 . ?
C20 C21 1.364(12) . ?
C20 H20 0.9500 . ?
C21 C22 1.379(12) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C28 1.37(2) . ?
C23 C24 1.40(3) . ?
C24 C25 1.36(3) . ?
C24 C29 1.43(3) . ?
C25 C26 1.32(3) . ?
C25 H25 0.9500 . ?
C26 C27 1.40(3) . ?
C26 H26 0.9500 . ?
C27 C28 1.39(2) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 C31 1.35(2) . ?
C30 C35 1.36(3) . ?
C31 C32 1.43(2) . ?
C31 C36 1.51(2) . ?
C32 C33 1.38(3) . ?
C32 H32 0.9500 . ?
C33 C34 1.38(3) . ?
C33 H33 0.9500 . ?
C34 C35 1.36(2) . ?
C34 H34 0.9500 . ?
C35 H35 0.9500 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C44 1.381(13) . ?
C39 C40 1.404(12) . ?
C40 C41 1.374(12) . ?
C40 C45 1.521(13) . ?
C41 C42 1.386(13) . ?
C41 H41 0.9500 . ?
C42 C43 1.384(13) . ?
C42 H42 0.9500 . ?
C43 C44 1.370(12) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C51 1.387(13) . ?
C46 C47 1.395(13) . ?
C47 C48 1.404(13) . ?
C47 C52 1.524(13) . ?
C48 C49 1.391(13) . ?
C48 H48 0.9500 . ?
C49 C50 1.377(13) . ?
C49 H49 0.9500 . ?
C50 C51 1.385(13) . ?
C50 H50 0.9500 . ?
C51 H51 0.9500 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 C58 1.40(2) . ?
C53 C54 1.41(2) . ?
C54 C55 1.40(2) . ?
C54 H54 0.9500 . ?
C55 C56 1.39(2) . ?
C55 H55 0.9500 . ?
C56 C57 1.35(2) . ?
C56 H56 0.9500 . ?
C57 C58 1.34(2) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C64 1.37(3) . ?
C59 C60 1.41(2) . ?
C60 C61 1.39(2) . ?
C60 C65 1.48(3) . ?
C61 C62 1.34(3) . ?
C61 H61 0.9500 . ?
C62 C63 1.41(3) . ?
C62 H62 0.9500 . ?
C63 C64 1.41(2) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 C71 1.372(11) . ?
C66 C67 1.383(11) . ?
C67 C68 1.395(11) . ?
C67 C72 1.526(13) . ?
C68 C69 1.373(11) . ?
C68 H68 0.9500 . ?
C69 C70 1.379(12) . ?
C69 H69 0.9500 . ?
C70 C71 1.396(11) . ?
C70 H70 0.9500 . ?
C71 H71 0.9500 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 C74 1.18(2) . ?
C74 C75 1.439(19) . ?
C75 C84 1.430(19) . ?
C75 C76 1.46(2) . ?
C76 C77 1.426(18) . ?
C76 H76 0.9500 . ?
C77 C78 1.366(19) . ?
C77 H77 0.9500 . ?
C78 C79 1.38(2) . ?
C78 C85 1.54(2) . ?
C79 C80 1.38(2) . ?
C79 C84 1.431(19) . ?
C80 C81 1.39(2) . ?
C80 C86 1.48(2) . ?
C81 C82 1.40(2) . ?
C81 H81 0.9500 . ?
C82 C83 1.42(2) . ?
C82 H82 0.9500 . ?
C83 C84 1.36(2) . ?
C83 H83 0.9500 . ?
C87 C89 1.495(12) . ?
C87 C88 1.529(13) . ?
C87 H87 1.0000 . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C89 C94 1.379(11) . ?
C89 C90 1.388(11) . ?
C90 C91 1.376(11) . ?
C90 H90 0.9500 . ?
C91 C92 1.382(11) . ?
C91 H91 0.9500 . ?
C92 C93 1.384(12) . ?
C92 H92 0.9500 . ?
C93 C94 1.390(11) . ?
C93 H93 0.9500 . ?
C94 H94 0.9500 . ?
C95 C96 1.19(2) . ?
C96 C97 1.47(2) . ?
C97 C98 1.385(11) . ?
C97 C106 1.396(14) . ?
C98 C99 1.389(11) . ?
C98 H98 0.9500 . ?
C99 C100 1.389(11) . ?
C99 H99 0.9500 . ?
C100 C101 1.370(10) . ?
C100 C107 1.508(12) . ?
C101 C102 1.360(10) . ?
C101 C106 1.401(10) . ?
C102 C103 1.393(11) . ?
C102 C108 1.44(2) . ?
C103 C104 1.392(11) . ?
C103 H103 0.9500 . ?
C104 C105 1.381(11) . ?
C104 H104 0.9500 . ?
C105 C106 1.382(10) . ?
C105 H105 0.9500 . ?
C109 C111 1.498(13) . ?
C109 C110 1.516(13) . ?
C109 H109 1.0000 . ?
C110 H11A 0.9800 . ?
C110 H11B 0.9800 . ?
C110 H11C 0.9800 . ?
C111 C116 1.385(12) . ?
C111 C112 1.393(12) . ?
C112 C113 1.388(12) . ?
C112 H112 0.9500 . ?
C113 C114 1.386(12) . ?
C113 H113 0.9500 . ?
C114 C115 1.384(12) . ?
C114 H114 0.9500 . ?
C115 C116 1.390(12) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C201 H20A 0.9900 . ?
C201 H20B 0.9900 . ?
C202 H20C 0.9900 . ?
C202 H20D 0.9900 . ?
C203 C208 1.386(13) . ?
C203 C204 1.390(13) . ?
C204 C205 1.374(13) . ?
C204 C209 1.49(3) . ?
C205 C206 1.370(13) . ?
C205 H205 0.9500 . ?
C206 C207 1.377(13) . ?
C206 H206 0.9500 . ?
C207 C208 1.373(13) . ?
C207 H207 0.9500 . ?
C208 H208 0.9500 . ?
C209 H20F 0.9800 . ?
C209 H20G 0.9800 . ?
C209 H20H 0.9800 . ?
C210 C211 1.376(13) . ?
C210 C215 1.402(13) . ?
C211 C212 1.392(13) . ?
C211 C216 1.477(13) . ?
C212 C213 1.374(13) . ?
C212 H212 0.9500 . ?
C213 C214 1.380(13) . ?
C213 H213 0.9500 . ?
C214 C215 1.385(13) . ?
C214 H214 0.9500 . ?
C215 H215 0.9500 . ?
C216 H21A 0.9800 . ?
C216 H21B 0.9800 . ?
C216 H21C 0.9800 . ?
C217 C218 1.34(2) . ?
C217 C222 1.36(3) . ?
C218 C219 1.37(3) . ?
C218 H218 0.9500 . ?
C219 C220 1.40(3) . ?
C219 H219 0.9500 . ?
C220 C221 1.33(3) . ?
C220 H220 0.9500 . ?
C221 C222 1.45(3) . ?
C221 H221 0.9500 . ?
C222 H222 0.9500 . ?
C223 C228 1.32(2) . ?
C223 C224 1.41(2) . ?
C224 C225 1.37(2) . ?
C224 C229 1.50(2) . ?
C225 C226 1.48(2) . ?
C225 H225 0.9500 . ?
C226 C227 1.32(2) . ?
C226 H226 0.9500 . ?
C227 C228 1.40(2) . ?
C227 H227 0.9500 . ?
C228 H228 0.9500 . ?
C229 H22C 0.9800 . ?
C229 H22D 0.9800 . ?
C229 H22E 0.9800 . ?
C230 C235 1.373(11) . ?
C230 C231 1.398(11) . ?
C231 C232 1.378(11) . ?
C231 C236 1.488(13) . ?
C232 C233 1.386(12) . ?
C232 H232 0.9500 . ?
C233 C234 1.377(12) . ?
C233 H233 0.9500 . ?
C234 C235 1.392(11) . ?
C234 H234 0.9500 . ?
C235 H235 0.9500 . ?
C236 H23A 0.9800 . ?
C236 H23B 0.9800 . ?
C236 H23C 0.9800 . ?
C237 H23D 0.9900 . ?
C237 H23E 0.9900 . ?
C238 H23F 0.9900 . ?
C238 H23G 0.9900 . ?
C239 C240 1.42(2) . ?
C239 C244 1.45(2) . ?
C240 C241 1.38(2) . ?
C240 C245 1.49(3) . ?
C241 C242 1.25(3) . ?
C241 H241 0.9500 . ?
C242 C243 1.40(3) . ?
C242 H242 0.9500 . ?
C243 C244 1.36(2) . ?
C243 H243 0.9500 . ?
C244 H244 0.9500 . ?
C245 H24A 0.9800 . ?
C245 H24B 0.9800 . ?
C245 H24C 0.9800 . ?
C246 C247 1.386(13) . ?
C246 C251 1.404(13) . ?
C247 C248 1.410(13) . ?
C247 C252 1.47(3) . ?
C248 C249 1.382(13) . ?
C248 H248 0.9500 . ?
C249 C250 1.391(13) . ?
C249 H249 0.9500 . ?
C250 C251 1.390(13) . ?
C250 H250 0.9500 . ?
C251 H251 0.9500 . ?
C252 H25A 0.9800 . ?
C252 H25B 0.9800 . ?
C252 H25C 0.9800 . ?
C253 C258 1.385(13) . ?
C253 C254 1.397(13) . ?
C254 C255 1.387(13) . ?
C254 H254 0.9500 . ?
C255 C256 1.375(13) . ?
C255 H255 0.9500 . ?
C256 C257 1.393(13) . ?
C256 H256 0.9500 . ?
C257 C258 1.377(13) . ?
C257 H257 0.9500 . ?
C258 H258 0.9500 . ?
C259 C260 1.388(13) . ?
C259 C264 1.391(13) . ?
C260 C261 1.391(13) . ?
C260 C265 1.499(13) . ?
C261 C262 1.379(13) . ?
C261 H26B 0.9500 . ?
C262 C263 1.374(13) . ?
C262 H262 0.9500 . ?
C263 C264 1.376(13) . ?
C263 H263 0.9500 . ?
C264 H264 0.9500 . ?
C265 H26E 0.9800 . ?
C265 H26F 0.9800 . ?
C265 H26G 0.9800 . ?
C266 C271 1.385(13) . ?
C266 C267 1.391(13) . ?
C267 C272 1.39(3) . ?
C267 C268 1.394(13) . ?
C268 C269 1.392(13) . ?
C268 H268 0.9500 . ?
C269 C270 1.385(13) . ?
C269 H269 0.9500 . ?
C270 C271 1.386(13) . ?
C270 H270 0.9500 . ?
C271 H271 0.9500 . ?
C272 H27A 0.9800 . ?
C272 H27B 0.9800 . ?
C272 H27C 0.9800 . ?
C273 C274 1.18(2) . ?
C274 C275 1.47(2) . ?
C275 C276 1.410(10) . ?
C275 C284 1.428(10) . ?
C276 C277 1.405(10) . ?
C276 H276 0.9500 . ?
C277 C278 1.403(10) . ?
C277 H277 0.9500 . ?
C278 C279 1.411(10) . ?
C278 C285 1.513(13) . ?
C279 C284 1.415(10) . ?
C279 C280 1.421(10) . ?
C280 C281 1.417(11) . ?
C280 C286 1.46(3) . ?
C281 C282 1.413(11) . ?
C281 H281 0.9500 . ?
C282 C283 1.414(10) . ?
C282 H282 0.9500 . ?
C283 C284 1.425(10) . ?
C283 H283 0.9500 . ?
C287 C289 1.500(13) . ?
C287 C288 1.532(13) . ?
C287 H287 1.0000 . ?
C288 H28A 0.9800 . ?
C288 H28B 0.9800 . ?
C288 H28C 0.9800 . ?
C289 C290 1.389(13) . ?
C289 C294 1.390(13) . ?
C290 C291 1.389(13) . ?
C290 H290 0.9500 . ?
C291 C292 1.382(13) . ?
C291 H291 0.9500 . ?
C292 C293 1.383(13) . ?
C292 H292 0.9500 . ?
C293 C294 1.388(13) . ?
C293 H293 0.9500 . ?
C294 H294 0.9500 . ?
C295 C296 1.22(3) . ?
C296 C297 1.45(3) . ?
C297 C298 1.369(13) . ?
C297 C306 1.390(13) . ?
C298 C299 1.366(13) . ?
C298 H298 0.9500 . ?
C299 C300 1.383(13) . ?
C299 H299 0.9500 . ?
C300 C301 1.365(13) . ?
C300 C307 1.428(13) . ?
C301 C302 1.380(13) . ?
C301 C306 1.391(13) . ?
C302 C303 1.377(13) . ?
C302 C308 1.416(13) . ?
C303 C304 1.385(13) . ?
C303 H303 0.9500 . ?
C304 C305 1.383(13) . ?
C304 H304 0.9500 . ?
C305 C306 1.390(13) . ?
C305 H305 0.9500 . ?
C309 C311 1.505(13) . ?
C309 C310 1.522(12) . ?
C309 H309 1.0000 . ?
C310 H31A 0.9800 . ?
C310 H31B 0.9800 . ?
C310 H31C 0.9800 . ?
C311 C316 1.388(12) . ?
C311 C312 1.396(12) . ?
C312 C313 1.385(12) . ?
C312 H312 0.9500 . ?
C313 C314 1.385(12) . ?
C313 H313 0.9500 . ?
C314 C315 1.392(12) . ?
C314 H314 0.9500 . ?
C315 C316 1.385(12) . ?
C315 H315 0.9500 . ?
C316 H316 0.9500 . ?
Cl4 O24 1.385(10) . ?
Cl4 O22 1.391(11) . ?
Cl4 O21 1.400(11) . ?
Cl4 O23 1.458(11) . ?
Cl5 C01 1.765(14) . ?
Cl6 C02 1.757(14) . ?
C01 C02 1.522(14) . ?
C01 H01A 0.9900 . ?
C01 H01B 0.9900 . ?
C02 H02A 0.9900 . ?
C02 H02B 0.9900 . ?
Cl7 C03 1.772(13) . ?
Cl8 C04 1.777(13) . ?
C03 C04 1.524(14) . ?
C03 H03A 0.9900 . ?
C03 H03B 0.9900 . ?
C04 H04A 0.9900 . ?
C04 H04B 0.9900 . ?
Cl9 C05 1.768(14) . ?
C05 C06 1.528(14) . ?
C05 H05A 0.9900 . ?
C05 H05B 0.9900 . ?
C06 Cl10 1.784(14) . ?
C06 H06A 0.9900 . ?
C06 H06B 0.9900 . ?
Cl11 C07 1.762(14) . ?
Cl12 C07 1.778(14) . ?
C07 H07A 0.9900 . ?
C07 H07B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P4 Au1 P1 173.79(14) . . ?
P4 Au1 Pt1 95.26(10) . . ?
P1 Au1 Pt1 90.84(11) . . ?
P6 Au2 P3 171.94(14) . . ?
P6 Au2 Pt1 91.72(10) . . ?
P3 Au2 Pt1 95.93(9) . . ?
P10 Au3 P7 174.76(15) . . ?
P10 Au3 Pt2 92.69(10) . . ?
P7 Au3 Pt2 92.53(11) . . ?
P12 Au4 P9 174.37(15) . . ?
P12 Au4 Pt2 93.02(11) . . ?
P9 Au4 Pt2 92.60(10) . . ?
C95 Pt1 C73 179.3(8) . . ?
C95 Pt1 P2 84.4(4) . . ?
C73 Pt1 P2 95.8(4) . . ?
C95 Pt1 P5 95.3(4) . . ?
C73 Pt1 P5 84.5(4) . . ?
P2 Pt1 P5 179.68(17) . . ?
C95 Pt1 Au2 78.2(5) . . ?
C73 Pt1 Au2 101.2(4) . . ?
P2 Pt1 Au2 88.22(9) . . ?
P5 Pt1 Au2 91.77(10) . . ?
C95 Pt1 Au1 101.4(5) . . ?
C73 Pt1 Au1 79.2(4) . . ?
P2 Pt1 Au1 91.74(9) . . ?
P5 Pt1 Au1 88.28(10) . . ?
Au2 Pt1 Au1 179.55(3) . . ?
C295 Pt2 C273 178.6(9) . . ?
C295 Pt2 P11 82.1(5) . . ?
C273 Pt2 P11 97.2(4) . . ?
C295 Pt2 P8 98.0(5) . . ?
C273 Pt2 P8 82.7(4) . . ?
P11 Pt2 P8 179.88(18) . . ?
C295 Pt2 Au3 83.5(6) . . ?
C273 Pt2 Au3 95.3(5) . . ?
P11 Pt2 Au3 89.97(10) . . ?
P8 Pt2 Au3 90.12(10) . . ?
C295 Pt2 Au4 95.3(6) . . ?
C273 Pt2 Au4 85.8(5) . . ?
P11 Pt2 Au4 90.11(10) . . ?
P8 Pt2 Au4 89.80(10) . . ?
Au3 Pt2 Au4 178.80(3) . . ?
O9 Cl1 O10 123.3(10) . . ?
O9 Cl1 O12 118.4(9) . . ?
O10 Cl1 O12 117.3(9) . . ?
O9 Cl1 O11 89.6(15) . . ?
O10 Cl1 O11 88.0(14) . . ?
O12 Cl1 O11 103.1(11) . . ?
O16 Cl2 O13 110.8(8) . . ?
O13' Cl2 O14' 110.1(10) . . ?
O16 Cl2 O14 110.8(7) . . ?
O13 Cl2 O14 110.3(8) . . ?
O13' Cl2 O15' 109.9(10) . . ?
O14' Cl2 O15' 109.5(10) . . ?
O13' Cl2 O16' 109.3(10) . . ?
O14' Cl2 O16' 109.1(10) . . ?
O15' Cl2 O16' 108.9(10) . . ?
O16 Cl2 O15 108.9(8) . . ?
O13 Cl2 O15 108.1(8) . . ?
O14 Cl2 O15 107.8(8) . . ?
O17 Cl3 O18 113.2(7) . . ?
O17 Cl3 O19 112.7(7) . . ?
O18 Cl3 O19 111.8(8) . . ?
O17 Cl3 O20 107.0(8) . . ?
O18 Cl3 O20 106.1(7) . . ?
O19 Cl3 O20 105.4(8) . . ?
C1 P1 C10 100.6(7) . . ?
C1 P1 C3 106.5(7) . . ?
C10 P1 C3 113.0(7) . . ?
C1 P1 Au1 112.2(5) . . ?
C10 P1 Au1 114.5(5) . . ?
C3 P1 Au1 109.6(5) . . ?
C1 P2 C17 109.2(6) . . ?
C1 P2 C2 100.2(7) . . ?
C17 P2 C2 102.4(8) . . ?
C1 P2 Pt1 108.5(6) . . ?
C17 P2 Pt1 120.6(5) . . ?
C2 P2 Pt1 113.9(5) . . ?
C23 P3 C2 108.6(8) . . ?
C23 P3 C30 109.1(8) . . ?
C2 P3 C30 103.3(8) . . ?
C23 P3 Au2 114.1(5) . . ?
C2 P3 Au2 110.5(5) . . ?
C30 P3 Au2 110.7(6) . . ?
C46 P4 C39 109.3(6) . . ?
C46 P4 C37 108.9(7) . . ?
C39 P4 C37 102.2(6) . . ?
C46 P4 Au1 113.2(4) . . ?
C39 P4 Au1 110.4(5) . . ?
C37 P4 Au1 112.2(5) . . ?
C53 P5 C37 103.1(8) . . ?
C53 P5 C38 110.3(7) . . ?
C37 P5 C38 101.3(7) . . ?
C53 P5 Pt1 118.8(5) . . ?
C37 P5 Pt1 114.2(5) . . ?
C38 P5 Pt1 107.6(5) . . ?
C59 P6 C66 106.7(7) . . ?
C59 P6 C38 103.9(7) . . ?
C66 P6 C38 110.8(6) . . ?
C59 P6 Au2 114.5(6) . . ?
C66 P6 Au2 107.4(4) . . ?
C38 P6 Au2 113.4(5) . . ?
C210 P7 C203 104.9(7) . . ?
C210 P7 C201 105.5(8) . . ?
C203 P7 C201 105.7(8) . . ?
C210 P7 Au3 119.3(5) . . ?
C203 P7 Au3 110.5(6) . . ?
C201 P7 Au3 110.0(5) . . ?
C202 P8 C217 104.0(8) . . ?
C202 P8 C201 103.0(8) . . ?
C217 P8 C201 107.4(8) . . ?
C202 P8 Pt2 108.3(5) . . ?
C217 P8 Pt2 124.1(6) . . ?
C201 P8 Pt2 108.0(6) . . ?
C230 P9 C202 106.7(7) . . ?
C230 P9 C223 108.9(7) . . ?
C202 P9 C223 105.2(7) . . ?
C230 P9 Au4 117.1(5) . . ?
C202 P9 Au4 108.9(5) . . ?
C223 P9 Au4 109.4(5) . . ?
C239 P10 C237 104.3(7) . . ?
C239 P10 C246 105.6(7) . . ?
C237 P10 C246 105.8(7) . . ?
C239 P10 Au3 109.7(5) . . ?
C237 P10 Au3 112.1(5) . . ?
C246 P10 Au3 118.3(5) . . ?
C238 P11 C253 105.6(8) . . ?
C238 P11 C237 101.0(8) . . ?
C253 P11 C237 103.6(7) . . ?
C238 P11 Pt2 108.6(6) . . ?
C253 P11 Pt2 125.2(5) . . ?
C237 P11 Pt2 110.2(5) . . ?
C266 P12 C238 105.1(7) . . ?
C266 P12 C259 105.3(7) . . ?
C238 P12 C259 103.2(9) . . ?
C266 P12 Au4 113.2(5) . . ?
C238 P12 Au4 109.6(5) . . ?
C259 P12 Au4 119.2(5) . . ?
C85 N1 C86 125.1(12) . . ?
C85 N1 C87 121.7(13) . . ?
C86 N1 C87 113.2(13) . . ?
C107 N2 C108 126.9(14) . . ?
C107 N2 C109 116.6(10) . . ?
C108 N2 C109 116.1(9) . . ?
C285 N3 C286 125.5(14) . . ?
C285 N3 C287 115.4(15) . . ?
C286 N3 C287 119.0(15) . . ?
C307 N4 C309 119(2) . . ?
C307 N4 C308 118.5(15) . . ?
C309 N4 C308 122.8(19) . . ?
P2 C1 P1 117.1(8) . . ?
P2 C1 H1A 108.0 . . ?
P1 C1 H1A 108.0 . . ?
P2 C1 H1B 108.0 . . ?
P1 C1 H1B 108.0 . . ?
H1A C1 H1B 107.3 . . ?
P3 C2 P2 117.8(8) . . ?
P3 C2 H2A 107.9 . . ?
P2 C2 H2A 107.9 . . ?
P3 C2 H2B 107.9 . . ?
P2 C2 H2B 107.9 . . ?
H2A C2 H2B 107.2 . . ?
C8 C3 C4 121.6(16) . . ?
C8 C3 P1 117.1(11) . . ?
C4 C3 P1 121.3(13) . . ?
C5 C4 C3 115.2(17) . . ?
C5 C4 C9 115.7(14) . . ?
C3 C4 C9 129.1(15) . . ?
C6 C5 C4 122.5(17) . . ?
C6 C5 H5 118.8 . . ?
C4 C5 H5 118.8 . . ?
C5 C6 C7 122.5(18) . . ?
C5 C6 H6 118.8 . . ?
C7 C6 H6 118.8 . . ?
C8 C7 C6 115.6(17) . . ?
C8 C7 H7 122.2 . . ?
C6 C7 H7 122.2 . . ?
C7 C8 C3 122.6(16) . . ?
C7 C8 H8 118.7 . . ?
C3 C8 H8 118.7 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C15 C10 C11 106.2(9) . . ?
C15 C10 P1 129.6(10) . . ?
C11 C10 P1 124.1(11) . . ?
C10 C11 C12 125.3(11) . . ?
C10 C11 C16 113.2(14) . . ?
C12 C11 C16 121.5(15) . . ?
C11 C12 C13 125.4(8) . . ?
C11 C12 H12 117.3 . . ?
C13 C12 H12 117.3 . . ?
C12 C13 C14 110.9(7) . . ?
C12 C13 H13 124.5 . . ?
C14 C13 H13 124.5 . . ?
C15 C14 C13 112.9(7) . . ?
C15 C14 H14 123.5 . . ?
C13 C14 H14 123.5 . . ?
C10 C15 C14 139.3(8) . . ?
C10 C15 H15 110.4 . . ?
C14 C15 H15 110.4 . . ?
C11 C16 H16A 109.5 . . ?
C11 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C11 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C22 C17 C18 120.5(14) . . ?
C22 C17 P2 121.5(11) . . ?
C18 C17 P2 117.4(9) . . ?
C17 C18 C19 121.8(13) . . ?
C17 C18 H18 119.1 . . ?
C19 C18 H18 119.1 . . ?
C18 C19 C20 114.2(13) . . ?
C18 C19 H19 122.9 . . ?
C20 C19 H19 122.9 . . ?
C21 C20 C19 125.9(14) . . ?
C21 C20 H20 117.1 . . ?
C19 C20 H20 117.1 . . ?
C20 C21 C22 116.7(14) . . ?
C20 C21 H21 121.6 . . ?
C22 C21 H21 121.6 . . ?
C21 C22 C17 120.4(15) . . ?
C21 C22 H22 119.8 . . ?
C17 C22 H22 119.8 . . ?
C28 C23 C24 119.9(19) . . ?
C28 C23 P3 123.5(15) . . ?
C24 C23 P3 116.5(14) . . ?
C25 C24 C23 115.9(19) . . ?
C25 C24 C29 117.9(19) . . ?
C23 C24 C29 126.0(19) . . ?
C26 C25 C24 127(2) . . ?
C26 C25 H25 116.6 . . ?
C24 C25 H25 116.6 . . ?
C25 C26 C27 117(2) . . ?
C25 C26 H26 121.3 . . ?
C27 C26 H26 121.3 . . ?
C28 C27 C26 118.6(18) . . ?
C28 C27 H27 120.7 . . ?
C26 C27 H27 120.7 . . ?
C23 C28 C27 121.3(19) . . ?
C23 C28 H28 119.4 . . ?
C27 C28 H28 119.4 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C31 C30 C35 118.6(16) . . ?
C31 C30 P3 124.0(14) . . ?
C35 C30 P3 117.4(13) . . ?
C30 C31 C32 118.6(17) . . ?
C30 C31 C36 124.2(14) . . ?
C32 C31 C36 117.1(15) . . ?
C33 C32 C31 120.3(18) . . ?
C33 C32 H32 119.8 . . ?
C31 C32 H32 119.8 . . ?
C34 C33 C32 120.1(17) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C35 C34 C33 117(2) . . ?
C35 C34 H34 121.7 . . ?
C33 C34 H34 121.7 . . ?
C34 C35 C30 125(2) . . ?
C34 C35 H35 117.4 . . ?
C30 C35 H35 117.4 . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
P4 C37 P5 116.1(8) . . ?
P4 C37 H37A 108.3 . . ?
P5 C37 H37A 108.3 . . ?
P4 C37 H37B 108.3 . . ?
P5 C37 H37B 108.3 . . ?
H37A C37 H37B 107.4 . . ?
P6 C38 P5 114.9(8) . . ?
P6 C38 H38A 108.6 . . ?
P5 C38 H38A 108.6 . . ?
P6 C38 H38B 108.6 . . ?
P5 C38 H38B 108.6 . . ?
H38A C38 H38B 107.5 . . ?
C44 C39 C40 119.8(14) . . ?
C44 C39 P4 117.1(10) . . ?
C40 C39 P4 123.0(11) . . ?
C41 C40 C39 117.2(14) . . ?
C41 C40 C45 118.4(13) . . ?
C39 C40 C45 124.4(12) . . ?
C40 C41 C42 122.9(15) . . ?
C40 C41 H41 118.6 . . ?
C42 C41 H41 118.6 . . ?
C43 C42 C41 119.3(16) . . ?
C43 C42 H42 120.3 . . ?
C41 C42 H42 120.3 . . ?
C44 C43 C42 118.6(17) . . ?
C44 C43 H43 120.7 . . ?
C42 C43 H43 120.7 . . ?
C43 C44 C39 122.2(16) . . ?
C43 C44 H44 118.9 . . ?
C39 C44 H44 118.9 . . ?
C40 C45 H45A 109.5 . . ?
C40 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C40 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C51 C46 C47 118.4(16) . . ?
C51 C46 P4 120.3(12) . . ?
C47 C46 P4 121.3(12) . . ?
C46 C47 C48 117.6(16) . . ?
C46 C47 C52 121.6(14) . . ?
C48 C47 C52 120.7(15) . . ?
C49 C48 C47 121.8(18) . . ?
C49 C48 H48 119.1 . . ?
C47 C48 H48 119.1 . . ?
C50 C49 C48 121.3(19) . . ?
C50 C49 H49 119.3 . . ?
C48 C49 H49 119.3 . . ?
C49 C50 C51 115.9(19) . . ?
C49 C50 H50 122.0 . . ?
C51 C50 H50 122.0 . . ?
C50 C51 C46 125.0(18) . . ?
C50 C51 H51 117.5 . . ?
C46 C51 H51 117.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C58 C53 C54 117.4(14) . . ?
C58 C53 P5 119.8(11) . . ?
C54 C53 P5 121.7(12) . . ?
C55 C54 C53 119.8(16) . . ?
C55 C54 H54 120.1 . . ?
C53 C54 H54 120.1 . . ?
C56 C55 C54 120.1(16) . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C57 C56 C55 118.2(15) . . ?
C57 C56 H56 120.9 . . ?
C55 C56 H56 120.9 . . ?
C58 C57 C56 123.8(16) . . ?
C58 C57 H57 118.1 . . ?
C56 C57 H57 118.1 . . ?
C57 C58 C53 120.3(15) . . ?
C57 C58 H58 119.9 . . ?
C53 C58 H58 119.9 . . ?
C64 C59 C60 119.1(16) . . ?
C64 C59 P6 114.7(12) . . ?
C60 C59 P6 126.0(15) . . ?
C61 C60 C59 118.9(19) . . ?
C61 C60 C65 118.0(15) . . ?
C59 C60 C65 123.1(16) . . ?
C62 C61 C60 121.8(17) . . ?
C62 C61 H61 119.1 . . ?
C60 C61 H61 119.1 . . ?
C61 C62 C63 120.8(18) . . ?
C61 C62 H62 119.6 . . ?
C63 C62 H62 119.6 . . ?
C64 C63 C62 117(2) . . ?
C64 C63 H63 121.5 . . ?
C62 C63 H63 121.5 . . ?
C59 C64 C63 121.9(17) . . ?
C59 C64 H64 119.1 . . ?
C63 C64 H64 119.1 . . ?
C60 C65 H65A 109.5 . . ?
C60 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C60 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C71 C66 C67 120.7(7) . . ?
C71 C66 P6 117.0(7) . . ?
C67 C66 P6 122.3(8) . . ?
C66 C67 C68 118.8(8) . . ?
C66 C67 C72 121.8(8) . . ?
C68 C67 C72 119.3(8) . . ?
C69 C68 C67 120.5(8) . . ?
C69 C68 H68 119.8 . . ?
C67 C68 H68 119.8 . . ?
C68 C69 C70 120.6(8) . . ?
C68 C69 H69 119.7 . . ?
C70 C69 H69 119.7 . . ?
C69 C70 C71 119.0(8) . . ?
C69 C70 H70 120.5 . . ?
C71 C70 H70 120.5 . . ?
C66 C71 C70 120.4(8) . . ?
C66 C71 H71 119.8 . . ?
C70 C71 H71 119.8 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C74 C73 Pt1 170.5(13) . . ?
C73 C74 C75 178.7(18) . . ?
C84 C75 C74 119.4(13) . . ?
C84 C75 C76 120.9(12) . . ?
C74 C75 C76 119.3(12) . . ?
C77 C76 C75 116.3(12) . . ?
C77 C76 H76 121.9 . . ?
C75 C76 H76 121.9 . . ?
C78 C77 C76 121.3(13) . . ?
C78 C77 H77 119.3 . . ?
C76 C77 H77 119.3 . . ?
C77 C78 C79 123.7(13) . . ?
C77 C78 C85 116.2(14) . . ?
C79 C78 C85 120.1(13) . . ?
C80 C79 C78 121.9(14) . . ?
C80 C79 C84 119.5(14) . . ?
C78 C79 C84 118.4(13) . . ?
C79 C80 C81 119.8(14) . . ?
C79 C80 C86 120.6(15) . . ?
C81 C80 C86 119.6(14) . . ?
C80 C81 C82 122.1(14) . . ?
C80 C81 H81 118.9 . . ?
C82 C81 H81 118.9 . . ?
C81 C82 C83 116.9(15) . . ?
C81 C82 H82 121.6 . . ?
C83 C82 H82 121.6 . . ?
C84 C83 C82 121.9(14) . . ?
C84 C83 H83 119.0 . . ?
C82 C83 H83 119.0 . . ?
C83 C84 C75 121.2(13) . . ?
C83 C84 C79 119.6(13) . . ?
C75 C84 C79 119.0(13) . . ?
O1 C85 N1 121.2(15) . . ?
O1 C85 C78 123.3(15) . . ?
N1 C85 C78 115.5(14) . . ?
O2 C86 N1 120.0(15) . . ?
O2 C86 C80 123.3(17) . . ?
N1 C86 C80 116.4(14) . . ?
N1 C87 C89 114.1(10) . . ?
N1 C87 C88 109.7(12) . . ?
C89 C87 C88 117.5(13) . . ?
N1 C87 H87 104.7 . . ?
C89 C87 H87 104.7 . . ?
C88 C87 H87 104.7 . . ?
C87 C88 H88A 109.5 . . ?
C87 C88 H88B 109.5 . . ?
H88A C88 H88B 109.5 . . ?
C87 C88 H88C 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
C94 C89 C90 119.8(7) . . ?
C94 C89 C87 121.7(12) . . ?
C90 C89 C87 118.6(11) . . ?
C91 C90 C89 120.2(8) . . ?
C91 C90 H90 119.9 . . ?
C89 C90 H90 119.9 . . ?
C90 C91 C92 120.4(8) . . ?
C90 C91 H91 119.8 . . ?
C92 C91 H91 119.8 . . ?
C91 C92 C93 119.5(8) . . ?
C91 C92 H92 120.3 . . ?
C93 C92 H92 120.3 . . ?
C92 C93 C94 120.3(8) . . ?
C92 C93 H93 119.9 . . ?
C94 C93 H93 119.9 . . ?
C89 C94 C93 119.9(8) . . ?
C89 C94 H94 120.1 . . ?
C93 C94 H94 120.1 . . ?
C96 C95 Pt1 176.4(15) . . ?
C95 C96 C97 165.2(19) . . ?
C98 C97 C106 120.2(8) . . ?
C98 C97 C96 125.4(13) . . ?
C106 C97 C96 114.4(12) . . ?
C97 C98 C99 120.7(8) . . ?
C97 C98 H98 119.6 . . ?
C99 C98 H98 119.6 . . ?
C98 C99 C100 119.3(8) . . ?
C98 C99 H99 120.4 . . ?
C100 C99 H99 120.4 . . ?
C101 C100 C99 120.2(7) . . ?
C101 C100 C107 121.0(13) . . ?
C99 C100 C107 118.7(13) . . ?
C102 C101 C100 118.8(10) . . ?
C102 C101 C106 119.9(7) . . ?
C100 C101 C106 121.4(8) . . ?
C101 C102 C103 121.9(8) . . ?
C101 C102 C108 126.7(13) . . ?
C103 C102 C108 111.5(11) . . ?
C104 C103 C102 118.3(7) . . ?
C104 C103 H103 120.8 . . ?
C102 C103 H103 120.8 . . ?
C105 C104 C103 120.0(8) . . ?
C105 C104 H104 120.0 . . ?
C103 C104 H104 120.0 . . ?
C104 C105 C106 121.2(8) . . ?
C104 C105 H105 119.4 . . ?
C106 C105 H105 119.4 . . ?
C105 C106 C97 123.0(9) . . ?
C105 C106 C101 118.8(7) . . ?
C97 C106 C101 118.3(7) . . ?
O3 C107 N2 117.3(18) . . ?
O3 C107 C100 128(2) . . ?
N2 C107 C100 114.1(15) . . ?
O4 C108 N2 124.9(17) . . ?
O4 C108 C102 122.4(17) . . ?
N2 C108 C102 112.2(13) . . ?
N2 C109 C111 116.9(13) . . ?
N2 C109 C110 112.7(17) . . ?
C111 C109 C110 121.3(14) . . ?
N2 C109 H109 100.1 . . ?
C111 C109 H109 100.1 . . ?
C110 C109 H109 100.1 . . ?
C109 C110 H11A 109.5 . . ?
C109 C110 H11B 109.5 . . ?
H11A C110 H11B 109.5 . . ?
C109 C110 H11C 109.5 . . ?
H11A C110 H11C 109.5 . . ?
H11B C110 H11C 109.5 . . ?
C116 C111 C112 119.7(8) . . ?
C116 C111 C109 120.8(9) . . ?
C112 C111 C109 119.6(9) . . ?
C113 C112 C111 119.8(8) . . ?
C113 C112 H112 120.1 . . ?
C111 C112 H112 120.1 . . ?
C114 C113 C112 120.3(8) . . ?
C114 C113 H113 119.9 . . ?
C112 C113 H113 119.9 . . ?
C115 C114 C113 120.1(8) . . ?
C115 C114 H114 120.0 . . ?
C113 C114 H114 120.0 . . ?
C114 C115 C116 119.7(8) . . ?
C114 C115 H115 120.1 . . ?
C116 C115 H115 120.1 . . ?
C111 C116 C115 120.5(8) . . ?
C111 C116 H116 119.8 . . ?
C115 C116 H116 119.8 . . ?
P7 C201 P8 114.5(9) . . ?
P7 C201 H20A 108.6 . . ?
P8 C201 H20A 108.6 . . ?
P7 C201 H20B 108.6 . . ?
P8 C201 H20B 108.6 . . ?
H20A C201 H20B 107.6 . . ?
P8 C202 P9 116.7(9) . . ?
P8 C202 H20C 108.1 . . ?
P9 C202 H20C 108.1 . . ?
P8 C202 H20D 108.1 . . ?
P9 C202 H20D 108.1 . . ?
H20C C202 H20D 107.3 . . ?
C208 C203 C204 120.8(19) . . ?
C208 C203 P7 120.3(13) . . ?
C204 C203 P7 118.8(14) . . ?
C205 C204 C203 121.2(19) . . ?
C205 C204 C209 114.2(16) . . ?
C203 C204 C209 124.6(16) . . ?
C206 C205 C204 118.5(19) . . ?
C206 C205 H205 120.8 . . ?
C204 C205 H205 120.8 . . ?
C205 C206 C207 119.8(19) . . ?
C205 C206 H206 120.1 . . ?
C207 C206 H206 120.1 . . ?
C208 C207 C206 123(2) . . ?
C208 C207 H207 118.3 . . ?
C206 C207 H207 118.3 . . ?
C207 C208 C203 116.4(19) . . ?
C207 C208 H208 121.8 . . ?
C203 C208 H208 121.8 . . ?
C204 C209 H20F 109.5 . . ?
C204 C209 H20G 109.5 . . ?
H20F C209 H20G 109.5 . . ?
C204 C209 H20H 109.5 . . ?
H20F C209 H20H 109.5 . . ?
H20G C209 H20H 109.5 . . ?
C211 C210 C215 116.8(19) . . ?
C211 C210 P7 124.6(13) . . ?
C215 C210 P7 118.5(13) . . ?
C210 C211 C212 127.8(19) . . ?
C210 C211 C216 116.9(12) . . ?
C212 C211 C216 115.3(13) . . ?
C213 C212 C211 113(2) . . ?
C213 C212 H212 123.5 . . ?
C211 C212 H212 123.5 . . ?
C212 C213 C214 122(2) . . ?
C212 C213 H213 118.8 . . ?
C214 C213 H213 118.8 . . ?
C213 C214 C215 123(2) . . ?
C213 C214 H214 118.6 . . ?
C215 C214 H214 118.6 . . ?
C214 C215 C210 117(2) . . ?
C214 C215 H215 121.3 . . ?
C210 C215 H215 121.3 . . ?
C211 C216 H21A 109.5 . . ?
C211 C216 H21B 109.5 . . ?
H21A C216 H21B 109.5 . . ?
C211 C216 H21C 109.5 . . ?
H21A C216 H21C 109.5 . . ?
H21B C216 H21C 109.5 . . ?
C218 C217 C222 118.2(17) . . ?
C218 C217 P8 121.2(15) . . ?
C222 C217 P8 120.1(13) . . ?
C217 C218 C219 123(2) . . ?
C217 C218 H218 118.7 . . ?
C219 C218 H218 118.7 . . ?
C218 C219 C220 118.3(19) . . ?
C218 C219 H219 120.9 . . ?
C220 C219 H219 120.9 . . ?
C221 C220 C219 122.4(19) . . ?
C221 C220 H220 118.8 . . ?
C219 C220 H220 118.8 . . ?
C220 C221 C222 116(2) . . ?
C220 C221 H221 121.9 . . ?
C222 C221 H221 121.9 . . ?
C217 C222 C221 121.7(18) . . ?
C217 C222 H222 119.2 . . ?
C221 C222 H222 119.2 . . ?
C228 C223 C224 123.0(16) . . ?
C228 C223 P9 121.0(13) . . ?
C224 C223 P9 115.8(12) . . ?
C225 C224 C223 118.5(16) . . ?
C225 C224 C229 116.5(15) . . ?
C223 C224 C229 125.0(16) . . ?
C224 C225 C226 117.4(15) . . ?
C224 C225 H225 121.3 . . ?
C226 C225 H225 121.3 . . ?
C227 C226 C225 120.6(16) . . ?
C227 C226 H226 119.7 . . ?
C225 C226 H226 119.7 . . ?
C226 C227 C228 120.2(17) . . ?
C226 C227 H227 119.9 . . ?
C228 C227 H227 119.9 . . ?
C223 C228 C227 119.6(17) . . ?
C223 C228 H228 120.2 . . ?
C227 C228 H228 120.2 . . ?
C224 C229 H22C 109.5 . . ?
C224 C229 H22D 109.5 . . ?
H22C C229 H22D 109.5 . . ?
C224 C229 H22E 109.5 . . ?
H22C C229 H22E 109.5 . . ?
H22D C229 H22E 109.5 . . ?
C235 C230 C231 119.9(8) . . ?
C235 C230 P9 121.1(9) . . ?
C231 C230 P9 118.8(9) . . ?
C232 C231 C230 119.7(8) . . ?
C232 C231 C236 110.0(12) . . ?
C230 C231 C236 130.3(12) . . ?
C231 C232 C233 120.2(8) . . ?
C231 C232 H232 119.9 . . ?
C233 C232 H232 119.9 . . ?
C234 C233 C232 120.1(8) . . ?
C234 C233 H233 120.0 . . ?
C232 C233 H233 120.0 . . ?
C233 C234 C235 119.9(8) . . ?
C233 C234 H234 120.1 . . ?
C235 C234 H234 120.1 . . ?
C230 C235 C234 120.2(8) . . ?
C230 C235 H235 119.9 . . ?
C234 C235 H235 119.9 . . ?
C231 C236 H23A 109.5 . . ?
C231 C236 H23B 109.5 . . ?
H23A C236 H23B 109.5 . . ?
C231 C236 H23C 109.5 . . ?
H23A C236 H23C 109.5 . . ?
H23B C236 H23C 109.5 . . ?
P10 C237 P11 112.5(8) . . ?
P10 C237 H23D 109.1 . . ?
P11 C237 H23D 109.1 . . ?
P10 C237 H23E 109.1 . . ?
P11 C237 H23E 109.1 . . ?
H23D C237 H23E 107.8 . . ?
P11 C238 P12 115.2(9) . . ?
P11 C238 H23F 108.5 . . ?
P12 C238 H23F 108.5 . . ?
P11 C238 H23G 108.5 . . ?
P12 C238 H23G 108.5 . . ?
H23F C238 H23G 107.5 . . ?
C240 C239 C244 117.7(14) . . ?
C240 C239 P10 120.5(13) . . ?
C244 C239 P10 121.6(13) . . ?
C241 C240 C239 114.8(17) . . ?
C241 C240 C245 124.8(17) . . ?
C239 C240 C245 120.4(15) . . ?
C242 C241 C240 129(2) . . ?
C242 C241 H241 115.7 . . ?
C240 C241 H241 115.7 . . ?
C241 C242 C243 118.6(17) . . ?
C241 C242 H242 120.7 . . ?
C243 C242 H242 120.7 . . ?
C244 C243 C242 119.6(19) . . ?
C244 C243 H243 120.2 . . ?
C242 C243 H243 120.2 . . ?
C243 C244 C239 120.1(18) . . ?
C243 C244 H244 119.9 . . ?
C239 C244 H244 119.9 . . ?
C240 C245 H24A 109.5 . . ?
C240 C245 H24B 109.5 . . ?
H24A C245 H24B 109.5 . . ?
C240 C245 H24C 109.5 . . ?
H24A C245 H24C 109.5 . . ?
H24B C245 H24C 109.5 . . ?
C247 C246 C251 120.7(15) . . ?
C247 C246 P10 124.5(11) . . ?
C251 C246 P10 114.8(11) . . ?
C246 C247 C248 117.0(16) . . ?
C246 C247 C252 125.4(15) . . ?
C248 C247 C252 117.6(15) . . ?
C249 C248 C247 120.2(17) . . ?
C249 C248 H248 119.9 . . ?
C247 C248 H248 119.9 . . ?
C248 C249 C250 124.4(17) . . ?
C248 C249 H249 117.8 . . ?
C250 C249 H249 117.8 . . ?
C251 C250 C249 114.1(17) . . ?
C251 C250 H250 122.9 . . ?
C249 C250 H250 122.9 . . ?
C250 C251 C246 123.5(16) . . ?
C250 C251 H251 118.2 . . ?
C246 C251 H251 118.2 . . ?
C247 C252 H25A 109.5 . . ?
C247 C252 H25B 109.5 . . ?
H25A C252 H25B 109.5 . . ?
C247 C252 H25C 109.5 . . ?
H25A C252 H25C 109.5 . . ?
H25B C252 H25C 109.5 . . ?
C258 C253 C254 119.4(15) . . ?
C258 C253 P11 121.7(11) . . ?
C254 C253 P11 118.9(11) . . ?
C255 C254 C253 119.2(16) . . ?
C255 C254 H254 120.4 . . ?
C253 C254 H254 120.4 . . ?
C256 C255 C254 120.8(17) . . ?
C256 C255 H255 119.6 . . ?
C254 C255 H255 119.6 . . ?
C255 C256 C257 120.2(17) . . ?
C255 C256 H256 119.9 . . ?
C257 C256 H256 119.9 . . ?
C258 C257 C256 119.0(16) . . ?
C258 C257 H257 120.5 . . ?
C256 C257 H257 120.5 . . ?
C257 C258 C253 121.4(16) . . ?
C257 C258 H258 119.3 . . ?
C253 C258 H258 119.3 . . ?
C260 C259 C264 121.1(17) . . ?
C260 C259 P12 121.9(12) . . ?
C264 C259 P12 116.9(12) . . ?
C259 C260 C261 115.1(16) . . ?
C259 C260 C265 131.0(16) . . ?
C261 C260 C265 113.8(15) . . ?
C262 C261 C260 120.8(19) . . ?
C262 C261 H26B 119.6 . . ?
C260 C261 H26B 119.6 . . ?
C263 C262 C261 126(2) . . ?
C263 C262 H262 117.0 . . ?
C261 C262 H262 117.0 . . ?
C262 C263 C264 111.7(19) . . ?
C262 C263 H263 124.1 . . ?
C264 C263 H263 124.1 . . ?
C263 C264 C259 125.1(19) . . ?
C263 C264 H264 117.4 . . ?
C259 C264 H264 117.4 . . ?
C260 C265 H26E 109.5 . . ?
C260 C265 H26F 109.5 . . ?
H26E C265 H26F 109.5 . . ?
C260 C265 H26G 109.5 . . ?
H26E C265 H26G 109.5 . . ?
H26F C265 H26G 109.5 . . ?
C271 C266 C267 120.9(18) . . ?
C271 C266 P12 121.1(13) . . ?
C267 C266 P12 118.1(13) . . ?
C272 C267 C266 127.5(17) . . ?
C272 C267 C268 120.7(16) . . ?
C266 C267 C268 111.9(17) . . ?
C269 C268 C267 127.7(18) . . ?
C269 C268 H268 116.1 . . ?
C267 C268 H268 116.1 . . ?
C270 C269 C268 119.4(19) . . ?
C270 C269 H269 120.3 . . ?
C268 C269 H269 120.3 . . ?
C269 C270 C271 113.5(19) . . ?
C269 C270 H270 123.2 . . ?
C271 C270 H270 123.2 . . ?
C266 C271 C270 126.6(19) . . ?
C266 C271 H271 116.7 . . ?
C270 C271 H271 116.7 . . ?
C267 C272 H27A 109.5 . . ?
C267 C272 H27B 109.5 . . ?
H27A C272 H27B 109.5 . . ?
C267 C272 H27C 109.5 . . ?
H27A C272 H27C 109.5 . . ?
H27B C272 H27C 109.5 . . ?
C274 C273 Pt2 173.3(14) . . ?
C273 C274 C275 172(2) . . ?
C276 C275 C284 122.1(14) . . ?
C276 C275 C274 118.1(13) . . ?
C284 C275 C274 119.4(14) . . ?
C277 C276 C275 119.5(14) . . ?
C277 C276 H276 120.2 . . ?
C275 C276 H276 120.2 . . ?
C278 C277 C276 119.6(15) . . ?
C278 C277 H277 120.2 . . ?
C276 C277 H277 120.2 . . ?
C277 C278 C279 120.7(14) . . ?
C277 C278 C285 115.7(13) . . ?
C279 C278 C285 123.6(14) . . ?
C278 C279 C284 121.2(13) . . ?
C278 C279 C280 118.9(13) . . ?
C284 C279 C280 119.9(14) . . ?
C281 C280 C279 119.2(16) . . ?
C281 C280 C286 119.2(15) . . ?
C279 C280 C286 121.6(15) . . ?
C282 C281 C280 123.4(18) . . ?
C282 C281 H281 118.3 . . ?
C280 C281 H281 118.3 . . ?
C281 C282 C283 115.3(18) . . ?
C281 C282 H282 122.4 . . ?
C283 C282 H282 122.4 . . ?
C282 C283 C284 124.0(16) . . ?
C282 C283 H283 118.0 . . ?
C284 C283 H283 118.0 . . ?
C279 C284 C283 118.2(13) . . ?
C279 C284 C275 116.9(13) . . ?
C283 C284 C275 124.9(13) . . ?
O5 C285 N3 124.1(15) . . ?
O5 C285 C278 122.5(17) . . ?
N3 C285 C278 113.4(16) . . ?
O6 C286 N3 124(2) . . ?
O6 C286 C280 119(2) . . ?
N3 C286 C280 117.0(16) . . ?
N3 C287 C289 116.5(12) . . ?
N3 C287 C288 107.8(14) . . ?
C289 C287 C288 111.4(11) . . ?
N3 C287 H287 106.9 . . ?
C289 C287 H287 106.9 . . ?
C288 C287 H287 106.9 . . ?
C287 C288 H28A 109.5 . . ?
C287 C288 H28B 109.5 . . ?
H28A C288 H28B 109.5 . . ?
C287 C288 H28C 109.5 . . ?
H28A C288 H28C 109.5 . . ?
H28B C288 H28C 109.5 . . ?
C290 C289 C294 115.1(17) . . ?
C290 C289 C287 119.2(16) . . ?
C294 C289 C287 125.8(13) . . ?
C291 C290 C289 124(2) . . ?
C291 C290 H290 118.2 . . ?
C289 C290 H290 118.2 . . ?
C292 C291 C290 116(2) . . ?
C292 C291 H291 121.8 . . ?
C290 C291 H291 121.8 . . ?
C291 C292 C293 125(2) . . ?
C291 C292 H292 117.6 . . ?
C293 C292 H292 117.6 . . ?
C292 C293 C294 114(2) . . ?
C292 C293 H293 122.8 . . ?
C294 C293 H293 122.8 . . ?
C293 C294 C289 125.7(19) . . ?
C293 C294 H294 117.2 . . ?
C289 C294 H294 117.2 . . ?
C296 C295 Pt2 175.6(19) . . ?
C295 C296 C297 176(2) . . ?
C298 C297 C306 116.7(18) . . ?
C298 C297 C296 111.7(17) . . ?
C306 C297 C296 131.5(18) . . ?
C299 C298 C297 124(2) . . ?
C299 C298 H298 118.0 . . ?
C297 C298 H298 118.0 . . ?
C298 C299 C300 117(2) . . ?
C298 C299 H299 121.6 . . ?
C300 C299 H299 121.6 . . ?
C301 C300 C299 123.0(18) . . ?
C301 C300 C307 118.2(18) . . ?
C299 C300 C307 118.7(19) . . ?
C300 C301 C302 121.5(17) . . ?
C300 C301 C306 117.5(17) . . ?
C302 C301 C306 121.1(18) . . ?
C303 C302 C301 121.3(19) . . ?
C303 C302 C308 117.6(19) . . ?
C301 C302 C308 121.0(18) . . ?
C302 C303 C304 119(2) . . ?
C302 C303 H303 120.4 . . ?
C304 C303 H303 120.4 . . ?
C305 C304 C303 119(2) . . ?
C305 C304 H304 120.6 . . ?
C303 C304 H304 120.6 . . ?
C304 C305 C306 123(2) . . ?
C304 C305 H305 118.3 . . ?
C306 C305 H305 118.3 . . ?
C297 C306 C305 121.6(17) . . ?
C297 C306 C301 122.0(18) . . ?
C305 C306 C301 116.3(18) . . ?
O7 C307 N4 109(2) . . ?
O7 C307 C300 127(2) . . ?
N4 C307 C300 124(2) . . ?
O8 C308 C302 122(2) . . ?
O8 C308 N4 121(2) . . ?
C302 C308 N4 117.1(18) . . ?
N4 C309 C311 115.3(12) . . ?
N4 C309 C310 117.0(17) . . ?
C311 C309 C310 122.6(16) . . ?
N4 C309 H309 97.5 . . ?
C311 C309 H309 97.5 . . ?
C310 C309 H309 97.5 . . ?
C309 C310 H31A 109.5 . . ?
C309 C310 H31B 109.5 . . ?
H31A C310 H31B 109.5 . . ?
C309 C310 H31C 109.5 . . ?
H31A C310 H31C 109.5 . . ?
H31B C310 H31C 109.5 . . ?
C316 C311 C312 119.5(8) . . ?
C316 C311 C309 120.2(9) . . ?
C312 C311 C309 120.3(9) . . ?
C313 C312 C311 119.9(8) . . ?
C313 C312 H312 120.1 . . ?
C311 C312 H312 120.1 . . ?
C312 C313 C314 120.5(8) . . ?
C312 C313 H313 119.7 . . ?
C314 C313 H313 119.7 . . ?
C313 C314 C315 119.6(8) . . ?
C313 C314 H314 120.2 . . ?
C315 C314 H314 120.2 . . ?
C316 C315 C314 120.0(8) . . ?
C316 C315 H315 120.0 . . ?
C314 C315 H315 120.0 . . ?
C315 C316 C311 120.5(8) . . ?
C315 C316 H316 119.8 . . ?
C311 C316 H316 119.8 . . ?
O24 Cl4 O22 112.8(8) . . ?
O24 Cl4 O21 111.8(8) . . ?
O22 Cl4 O21 111.5(7) . . ?
O24 Cl4 O23 107.6(8) . . ?
O22 Cl4 O23 107.1(8) . . ?
O21 Cl4 O23 105.7(8) . . ?
C02 C01 Cl5 119(2) . . ?
C02 C01 H01A 107.6 . . ?
Cl5 C01 H01A 107.6 . . ?
C02 C01 H01B 107.6 . . ?
Cl5 C01 H01B 107.6 . . ?
H01A C01 H01B 107.1 . . ?
C01 C02 Cl6 117(2) . . ?
C01 C02 H02A 108.0 . . ?
Cl6 C02 H02A 108.0 . . ?
C01 C02 H02B 108.0 . . ?
Cl6 C02 H02B 108.0 . . ?
H02A C02 H02B 107.3 . . ?
C04 C03 Cl7 106.7(16) . . ?
C04 C03 H03A 110.4 . . ?
Cl7 C03 H03A 110.4 . . ?
C04 C03 H03B 110.4 . . ?
Cl7 C03 H03B 110.4 . . ?
H03A C03 H03B 108.6 . . ?
C03 C04 Cl8 99.3(17) . . ?
C03 C04 H04A 111.9 . . ?
Cl8 C04 H04A 111.9 . . ?
C03 C04 H04B 111.9 . . ?
Cl8 C04 H04B 111.9 . . ?
H04A C04 H04B 109.6 . . ?
C06 C05 Cl9 131(4) . . ?
C06 C05 H05A 104.6 . . ?
Cl9 C05 H05A 104.6 . . ?
C06 C05 H05B 104.6 . . ?
Cl9 C05 H05B 104.6 . . ?
H05A C05 H05B 105.7 . . ?
C05 C06 Cl10 108(3) . . ?
C05 C06 H06A 110.0 . . ?
Cl10 C06 H06A 110.0 . . ?
C05 C06 H06B 110.0 . . ?
Cl10 C06 H06B 110.0 . . ?
H06A C06 H06B 108.4 . . ?
Cl11 C07 Cl12 120.0(13) . . ?
Cl11 C07 H07A 107.3 . . ?
Cl12 C07 H07A 107.3 . . ?
Cl11 C07 H07B 107.3 . . ?
Cl12 C07 H07B 107.3 . . ?
H07A C07 H07B 106.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 P2 C1 P1 -81.4(10) . . . . ?
C2 P2 C1 P1 171.5(8) . . . . ?
Pt1 P2 C1 P1 51.9(9) . . . . ?
C10 P1 C1 P2 -159.1(8) . . . . ?
C3 P1 C1 P2 82.9(9) . . . . ?
Au1 P1 C1 P2 -37.0(10) . . . . ?
C23 P3 C2 P2 -99.4(10) . . . . ?
C30 P3 C2 P2 144.8(10) . . . . ?
Au2 P3 C2 P2 26.4(10) . . . . ?
C1 P2 C2 P3 -159.7(9) . . . . ?
C17 P2 C2 P3 87.8(10) . . . . ?
Pt1 P2 C2 P3 -44.1(11) . . . . ?
C1 P1 C3 C8 -101.7(8) . . . . ?
C10 P1 C3 C8 148.8(8) . . . . ?
Au1 P1 C3 C8 19.9(8) . . . . ?
C1 P1 C3 C4 77.7(10) . . . . ?
C10 P1 C3 C4 -31.8(12) . . . . ?
Au1 P1 C3 C4 -160.8(7) . . . . ?
C8 C3 C4 C5 0.0(4) . . . . ?
P1 C3 C4 C5 -179.3(11) . . . . ?
C8 C3 C4 C9 179.9(6) . . . . ?
P1 C3 C4 C9 0.6(12) . . . . ?
C3 C4 C5 C6 0.1(4) . . . . ?
C9 C4 C5 C6 -179.9(5) . . . . ?
C4 C5 C6 C7 -0.1(9) . . . . ?
C5 C6 C7 C8 0.1(11) . . . . ?
C6 C7 C8 C3 0.0(11) . . . . ?
C4 C3 C8 C7 0.0(9) . . . . ?
P1 C3 C8 C7 179.3(12) . . . . ?
C1 P1 C10 C15 7.1(11) . . . . ?
C3 P1 C10 C15 120.3(10) . . . . ?
Au1 P1 C10 C15 -113.4(9) . . . . ?
C1 P1 C10 C11 -174.3(10) . . . . ?
C3 P1 C10 C11 -61.2(12) . . . . ?
Au1 P1 C10 C11 65.2(10) . . . . ?
C15 C10 C11 C12 0.2(4) . . . . ?
P1 C10 C11 C12 -178.7(11) . . . . ?
C15 C10 C11 C16 -179.7(6) . . . . ?
P1 C10 C11 C16 1.5(12) . . . . ?
C10 C11 C12 C13 0.2(5) . . . . ?
C16 C11 C12 C13 -179.9(6) . . . . ?
C11 C12 C13 C14 -0.5(9) . . . . ?
C12 C13 C14 C15 0.4(11) . . . . ?
C11 C10 C15 C14 -0.2(13) . . . . ?
P1 C10 C15 C14 178.5(14) . . . . ?
C13 C14 C15 C10 -0.1(16) . . . . ?
C1 P2 C17 C22 -25.0(17) . . . . ?
C2 P2 C17 C22 80.6(16) . . . . ?
Pt1 P2 C17 C22 -151.6(13) . . . . ?
C1 P2 C17 C18 164.4(13) . . . . ?
C2 P2 C17 C18 -90.0(14) . . . . ?
Pt1 P2 C17 C18 37.8(15) . . . . ?
C22 C17 C18 C19 2(3) . . . . ?
P2 C17 C18 C19 172.6(13) . . . . ?
C17 C18 C19 C20 0(2) . . . . ?
C18 C19 C20 C21 -6(3) . . . . ?
C19 C20 C21 C22 9(3) . . . . ?
C20 C21 C22 C17 -7(3) . . . . ?
C18 C17 C22 C21 2(3) . . . . ?
P2 C17 C22 C21 -168.6(15) . . . . ?
C2 P3 C23 C28 9.3(15) . . . . ?
C30 P3 C23 C28 121.2(13) . . . . ?
Au2 P3 C23 C28 -114.5(12) . . . . ?
C2 P3 C23 C24 -173.2(11) . . . . ?
C30 P3 C23 C24 -61.2(13) . . . . ?
Au2 P3 C23 C24 63.1(12) . . . . ?
C28 C23 C24 C25 -2(2) . . . . ?
P3 C23 C24 C25 -179.3(13) . . . . ?
C28 C23 C24 C29 173.3(17) . . . . ?
P3 C23 C24 C29 -4(2) . . . . ?
C23 C24 C25 C26 2(3) . . . . ?
C29 C24 C25 C26 -173.1(19) . . . . ?
C24 C25 C26 C27 0(3) . . . . ?
C25 C26 C27 C28 -4(2) . . . . ?
C24 C23 C28 C27 -1(2) . . . . ?
P3 C23 C28 C27 176.0(12) . . . . ?
C26 C27 C28 C23 4(2) . . . . ?
C23 P3 C30 C31 -50.1(18) . . . . ?
C2 P3 C30 C31 65.3(17) . . . . ?
Au2 P3 C30 C31 -176.4(14) . . . . ?
C23 P3 C30 C35 131.4(15) . . . . ?
C2 P3 C30 C35 -113.2(15) . . . . ?
Au2 P3 C30 C35 5.1(16) . . . . ?
C35 C30 C31 C32 0(3) . . . . ?
P3 C30 C31 C32 -178.0(14) . . . . ?
C35 C30 C31 C36 -178.9(17) . . . . ?
P3 C30 C31 C36 3(3) . . . . ?
C30 C31 C32 C33 -1(3) . . . . ?
C36 C31 C32 C33 178.5(17) . . . . ?
C31 C32 C33 C34 5(3) . . . . ?
C32 C33 C34 C35 -8(3) . . . . ?
C33 C34 C35 C30 8(3) . . . . ?
C31 C30 C35 C34 -4(3) . . . . ?
P3 C30 C35 C34 174.4(16) . . . . ?
C46 P4 C37 P5 100.8(9) . . . . ?
C39 P4 C37 P5 -143.5(8) . . . . ?
Au1 P4 C37 P5 -25.3(10) . . . . ?
C53 P5 C37 P4 -86.6(10) . . . . ?
C38 P5 C37 P4 159.1(8) . . . . ?
Pt1 P5 C37 P4 43.8(10) . . . . ?
C59 P6 C38 P5 -84.9(10) . . . . ?
C66 P6 C38 P5 160.9(7) . . . . ?
Au2 P6 C38 P5 40.1(9) . . . . ?
C53 P5 C38 P6 78.7(10) . . . . ?
C37 P5 C38 P6 -172.5(8) . . . . ?
Pt1 P5 C38 P6 -52.4(9) . . . . ?
C46 P4 C39 C44 -132.2(7) . . . . ?
C37 P4 C39 C44 112.5(8) . . . . ?
Au1 P4 C39 C44 -7.1(7) . . . . ?
C46 P4 C39 C40 48.8(9) . . . . ?
C37 P4 C39 C40 -66.5(9) . . . . ?
Au1 P4 C39 C40 173.9(6) . . . . ?
C44 C39 C40 C41 0.1(4) . . . . ?
P4 C39 C40 C41 179.1(9) . . . . ?
C44 C39 C40 C45 -179.6(5) . . . . ?
P4 C39 C40 C45 -0.6(10) . . . . ?
C39 C40 C41 C42 -0.1(4) . . . . ?
C45 C40 C41 C42 179.6(5) . . . . ?
C40 C41 C42 C43 0.2(9) . . . . ?
C41 C42 C43 C44 -0.3(11) . . . . ?
C42 C43 C44 C39 0.3(11) . . . . ?
C40 C39 C44 C43 -0.2(9) . . . . ?
P4 C39 C44 C43 -179.3(10) . . . . ?
C39 P4 C46 C51 -122.3(7) . . . . ?
C37 P4 C46 C51 -11.3(9) . . . . ?
Au1 P4 C46 C51 114.3(6) . . . . ?
C39 P4 C46 C47 57.2(9) . . . . ?
C37 P4 C46 C47 168.1(8) . . . . ?
Au1 P4 C46 C47 -66.3(7) . . . . ?
C51 C46 C47 C48 0.1(4) . . . . ?
P4 C46 C47 C48 -179.4(9) . . . . ?
C51 C46 C47 C52 -179.9(5) . . . . ?
P4 C46 C47 C52 0.6(9) . . . . ?
C46 C47 C48 C49 0.0(4) . . . . ?
C52 C47 C48 C49 -179.9(5) . . . . ?
C47 C48 C49 C50 0.0(9) . . . . ?
C48 C49 C50 C51 -0.2(11) . . . . ?
C49 C50 C51 C46 0.3(11) . . . . ?
C47 C46 C51 C50 -0.3(9) . . . . ?
P4 C46 C51 C50 179.2(10) . . . . ?
C37 P5 C53 C58 86.4(15) . . . . ?
C38 P5 C53 C58 -166.1(13) . . . . ?
Pt1 P5 C53 C58 -41.1(16) . . . . ?
C37 P5 C53 C54 -81.4(16) . . . . ?
C38 P5 C53 C54 26.1(17) . . . . ?
Pt1 P5 C53 C54 151.1(13) . . . . ?
C58 C53 C54 C55 5(3) . . . . ?
P5 C53 C54 C55 173.1(14) . . . . ?
C53 C54 C55 C56 -6(3) . . . . ?
C54 C55 C56 C57 6(3) . . . . ?
C55 C56 C57 C58 -6(3) . . . . ?
C56 C57 C58 C53 5(3) . . . . ?
C54 C53 C58 C57 -4(3) . . . . ?
P5 C53 C58 C57 -172.6(14) . . . . ?
C66 P6 C59 C64 -137.4(12) . . . . ?
C38 P6 C59 C64 105.5(13) . . . . ?
Au2 P6 C59 C64 -18.7(14) . . . . ?
C66 P6 C59 C60 38.8(17) . . . . ?
C38 P6 C59 C60 -78.3(16) . . . . ?
Au2 P6 C59 C60 157.4(13) . . . . ?
C64 C59 C60 C61 3(2) . . . . ?
P6 C59 C60 C61 -173.3(14) . . . . ?
C64 C59 C60 C65 -175.9(16) . . . . ?
P6 C59 C60 C65 8(2) . . . . ?
C59 C60 C61 C62 -1(3) . . . . ?
C65 C60 C61 C62 177.4(17) . . . . ?
C60 C61 C62 C63 -4(3) . . . . ?
C61 C62 C63 C64 7(3) . . . . ?
C60 C59 C64 C63 1(3) . . . . ?
P6 C59 C64 C63 177.6(15) . . . . ?
C62 C63 C64 C59 -6(3) . . . . ?
C59 P6 C66 C71 -123.2(8) . . . . ?
C38 P6 C66 C71 -10.7(8) . . . . ?
Au2 P6 C66 C71 113.5(6) . . . . ?
C59 P6 C66 C67 55.4(10) . . . . ?
C38 P6 C66 C67 167.9(8) . . . . ?
Au2 P6 C66 C67 -67.8(7) . . . . ?
C71 C66 C67 C68 -0.3(4) . . . . ?
P6 C66 C67 C68 -178.9(9) . . . . ?
C71 C66 C67 C72 179.5(5) . . . . ?
P6 C66 C67 C72 0.9(9) . . . . ?
C66 C67 C68 C69 0.0(4) . . . . ?
C72 C67 C68 C69 -179.8(5) . . . . ?
C67 C68 C69 C70 -0.1(9) . . . . ?
C68 C69 C70 C71 0.5(11) . . . . ?
C67 C66 C71 C70 0.6(9) . . . . ?
P6 C66 C71 C70 179.3(9) . . . . ?
C69 C70 C71 C66 -0.7(11) . . . . ?
C84 C75 C76 C77 4(2) . . . . ?
C74 C75 C76 C77 176.5(14) . . . . ?
C75 C76 C77 C78 -3(2) . . . . ?
C76 C77 C78 C79 3(2) . . . . ?
C76 C77 C78 C85 -176.4(14) . . . . ?
C77 C78 C79 C80 -179.9(16) . . . . ?
C85 C78 C79 C80 -1(2) . . . . ?
C77 C78 C79 C84 -4(2) . . . . ?
C85 C78 C79 C84 174.7(14) . . . . ?
C78 C79 C80 C81 174.6(16) . . . . ?
C84 C79 C80 C81 -1(2) . . . . ?
C78 C79 C80 C86 -5(3) . . . . ?
C84 C79 C80 C86 179.9(15) . . . . ?
C79 C80 C81 C82 2(3) . . . . ?
C86 C80 C81 C82 -178.5(17) . . . . ?
C80 C81 C82 C83 0(3) . . . . ?
C81 C82 C83 C84 -3(3) . . . . ?
C82 C83 C84 C75 -179.8(16) . . . . ?
C82 C83 C84 C79 4(2) . . . . ?
C74 C75 C84 C83 6(2) . . . . ?
C76 C75 C84 C83 177.9(15) . . . . ?
C74 C75 C84 C79 -178.3(14) . . . . ?
C76 C75 C84 C79 -6(2) . . . . ?
C80 C79 C84 C83 -2(2) . . . . ?
C78 C79 C84 C83 -177.9(15) . . . . ?
C80 C79 C84 C75 -178.5(15) . . . . ?
C78 C79 C84 C75 6(2) . . . . ?
C86 N1 C85 O1 176.8(16) . . . . ?
C87 N1 C85 O1 -4(3) . . . . ?
C86 N1 C85 C78 -5(2) . . . . ?
C87 N1 C85 C78 174.0(13) . . . . ?
C77 C78 C85 O1 3(2) . . . . ?
C79 C78 C85 O1 -176.4(16) . . . . ?
C77 C78 C85 N1 -175.4(15) . . . . ?
C79 C78 C85 N1 5(2) . . . . ?
C85 N1 C86 O2 -174.9(18) . . . . ?
C87 N1 C86 O2 6(2) . . . . ?
C85 N1 C86 C80 0(2) . . . . ?
C87 N1 C86 C80 -179.1(14) . . . . ?
C79 C80 C86 O2 179.8(18) . . . . ?
C81 C80 C86 O2 0(3) . . . . ?
C79 C80 C86 N1 5(2) . . . . ?
C81 C80 C86 N1 -174.1(16) . . . . ?
C85 N1 C87 C89 -115.3(16) . . . . ?
C86 N1 C87 C89 63.6(17) . . . . ?
C85 N1 C87 C88 110.4(19) . . . . ?
C86 N1 C87 C88 -70.6(19) . . . . ?
N1 C87 C89 C94 -123.6(14) . . . . ?
C88 C87 C89 C94 6.9(14) . . . . ?
N1 C87 C89 C90 56.2(13) . . . . ?
C88 C87 C89 C90 -173.3(14) . . . . ?
C94 C89 C90 C91 -0.1(5) . . . . ?
C87 C89 C90 C91 -179.9(4) . . . . ?
C89 C90 C91 C92 -0.5(8) . . . . ?
C90 C91 C92 C93 0.9(11) . . . . ?
C91 C92 C93 C94 -0.6(12) . . . . ?
C90 C89 C94 C93 0.3(8) . . . . ?
C87 C89 C94 C93 -179.9(5) . . . . ?
C92 C93 C94 C89 0.0(11) . . . . ?
C95 C96 C97 C98 -4(8) . . . . ?
C95 C96 C97 C106 176(7) . . . . ?
C106 C97 C98 C99 -0.2(4) . . . . ?
C96 C97 C98 C99 179.0(13) . . . . ?
C97 C98 C99 C100 0.2(4) . . . . ?
C98 C99 C100 C101 -0.3(9) . . . . ?
C98 C99 C100 C107 176.4(15) . . . . ?
C99 C100 C101 C102 -179.7(7) . . . . ?
C107 C100 C101 C102 3.8(18) . . . . ?
C99 C100 C101 C106 0.3(12) . . . . ?
C107 C100 C101 C106 -176.2(16) . . . . ?
C100 C101 C102 C103 179.9(8) . . . . ?
C106 C101 C102 C103 -0.1(13) . . . . ?
C100 C101 C102 C108 0.7(19) . . . . ?
C106 C101 C102 C108 -179.3(16) . . . . ?
C101 C102 C103 C104 0.0(12) . . . . ?
C108 C102 C103 C104 179.3(14) . . . . ?
C102 C103 C104 C105 0.4(12) . . . . ?
C103 C104 C105 C106 -0.8(12) . . . . ?
C104 C105 C106 C97 -179.3(7) . . . . ?
C104 C105 C106 C101 0.8(12) . . . . ?
C98 C97 C106 C105 -179.8(6) . . . . ?
C96 C97 C106 C105 0.9(15) . . . . ?
C98 C97 C106 C101 0.2(8) . . . . ?
C96 C97 C106 C101 -179.1(13) . . . . ?
C102 C101 C106 C105 -0.3(12) . . . . ?
C100 C101 C106 C105 179.7(8) . . . . ?
C102 C101 C106 C97 179.7(7) . . . . ?
C100 C101 C106 C97 -0.3(12) . . . . ?
C108 N2 C107 O3 177(2) . . . . ?
C109 N2 C107 O3 -11(3) . . . . ?
C108 N2 C107 C100 4(3) . . . . ?
C109 N2 C107 C100 176.7(17) . . . . ?
C101 C100 C107 O3 -177(2) . . . . ?
C99 C100 C107 O3 6(3) . . . . ?
C101 C100 C107 N2 -6(3) . . . . ?
C99 C100 C107 N2 177.5(15) . . . . ?
C107 N2 C108 O4 172(2) . . . . ?
C109 N2 C108 O4 -1(3) . . . . ?
C107 N2 C108 C102 0(3) . . . . ?
C109 N2 C108 C102 -172.8(16) . . . . ?
C101 C102 C108 O4 -174.7(18) . . . . ?
C103 C102 C108 O4 6(3) . . . . ?
C101 C102 C108 N2 -3(3) . . . . ?
C103 C102 C108 N2 178.2(15) . . . . ?
C107 N2 C109 C111 -90(2) . . . . ?
C108 N2 C109 C111 83.6(19) . . . . ?
C107 N2 C109 C110 123(2) . . . . ?
C108 N2 C109 C110 -64(3) . . . . ?
N2 C109 C111 C116 -14.3(13) . . . . ?
C110 C109 C111 C116 130(2) . . . . ?
N2 C109 C111 C112 165.8(13) . . . . ?
C110 C109 C111 C112 -50(2) . . . . ?
C116 C111 C112 C113 0.0(5) . . . . ?
C109 C111 C112 C113 180.0(4) . . . . ?
C111 C112 C113 C114 0.1(8) . . . . ?
C112 C113 C114 C115 -0.2(11) . . . . ?
C113 C114 C115 C116 0.1(12) . . . . ?
C112 C111 C116 C115 -0.1(8) . . . . ?
C109 C111 C116 C115 180.0(5) . . . . ?
C114 C115 C116 C111 0.0(11) . . . . ?
C210 P7 C201 P8 -82.6(10) . . . . ?
C203 P7 C201 P8 166.6(9) . . . . ?
Au3 P7 C201 P8 47.3(11) . . . . ?
C202 P8 C201 P7 -172.4(9) . . . . ?
C217 P8 C201 P7 78.1(11) . . . . ?
Pt2 P8 C201 P7 -57.9(10) . . . . ?
C217 P8 C202 P9 -76.2(10) . . . . ?
C201 P8 C202 P9 171.8(9) . . . . ?
Pt2 P8 C202 P9 57.5(9) . . . . ?
C230 P9 C202 P8 81.5(10) . . . . ?
C223 P9 C202 P8 -162.9(8) . . . . ?
Au4 P9 C202 P8 -45.7(10) . . . . ?
C210 P7 C203 C208 -117.8(8) . . . . ?
C201 P7 C203 C208 -6.6(10) . . . . ?
Au3 P7 C203 C208 112.4(7) . . . . ?
C210 P7 C203 C204 64.3(11) . . . . ?
C201 P7 C203 C204 175.5(9) . . . . ?
Au3 P7 C203 C204 -65.6(10) . . . . ?
C208 C203 C204 C205 -0.2(4) . . . . ?
P7 C203 C204 C205 177.7(11) . . . . ?
C208 C203 C204 C209 179.3(6) . . . . ?
P7 C203 C204 C209 -2.8(12) . . . . ?
C203 C204 C205 C206 0.2(4) . . . . ?
C209 C204 C205 C206 -179.3(5) . . . . ?
C204 C205 C206 C207 0.0(9) . . . . ?
C205 C206 C207 C208 0.0(13) . . . . ?
C206 C207 C208 C203 0.0(12) . . . . ?
C204 C203 C208 C207 0.1(9) . . . . ?
P7 C203 C208 C207 -177.8(12) . . . . ?
C203 P7 C210 C211 -144.3(10) . . . . ?
C201 P7 C210 C211 104.4(11) . . . . ?
Au3 P7 C210 C211 -19.8(12) . . . . ?
C203 P7 C210 C215 38.6(10) . . . . ?
C201 P7 C210 C215 -72.8(10) . . . . ?
Au3 P7 C210 C215 163.0(7) . . . . ?
C215 C210 C211 C212 0.0(4) . . . . ?
P7 C210 C211 C212 -177.2(12) . . . . ?
C215 C210 C211 C216 179.9(6) . . . . ?
P7 C210 C211 C216 2.7(12) . . . . ?
C210 C211 C212 C213 0.1(4) . . . . ?
C216 C211 C212 C213 -179.9(6) . . . . ?
C211 C212 C213 C214 -0.2(10) . . . . ?
C212 C213 C214 C215 0.3(14) . . . . ?
C213 C214 C215 C210 -0.3(13) . . . . ?
C211 C210 C215 C214 0.1(9) . . . . ?
P7 C210 C215 C214 177.5(12) . . . . ?
C202 P8 C217 C218 -64.0(18) . . . . ?
C201 P8 C217 C218 44.8(18) . . . . ?
Pt2 P8 C217 C218 172.0(13) . . . . ?
C202 P8 C217 C222 107.5(16) . . . . ?
C201 P8 C217 C222 -143.8(16) . . . . ?
Pt2 P8 C217 C222 -16.6(19) . . . . ?
C222 C217 C218 C219 8(3) . . . . ?
P8 C217 C218 C219 179.9(17) . . . . ?
C217 C218 C219 C220 -7(3) . . . . ?
C218 C219 C220 C221 5(3) . . . . ?
C219 C220 C221 C222 -6(3) . . . . ?
C218 C217 C222 C221 -9(3) . . . . ?
P8 C217 C222 C221 179.8(16) . . . . ?
C220 C221 C222 C217 7(3) . . . . ?
C230 P9 C223 C228 117.0(14) . . . . ?
C202 P9 C223 C228 3.0(15) . . . . ?
Au4 P9 C223 C228 -113.8(13) . . . . ?
C230 P9 C223 C224 -67.2(13) . . . . ?
C202 P9 C223 C224 178.8(11) . . . . ?
Au4 P9 C223 C224 62.0(12) . . . . ?
C228 C223 C224 C225 3(2) . . . . ?
P9 C223 C224 C225 -172.2(12) . . . . ?
C228 C223 C224 C229 -177.7(16) . . . . ?
P9 C223 C224 C229 7(2) . . . . ?
C223 C224 C225 C226 0(2) . . . . ?
C229 C224 C225 C226 -179.0(14) . . . . ?
C224 C225 C226 C227 -7(2) . . . . ?
C225 C226 C227 C228 10(3) . . . . ?
C224 C223 C228 C227 0(2) . . . . ?
P9 C223 C228 C227 175.3(12) . . . . ?
C226 C227 C228 C223 -7(3) . . . . ?
C202 P9 C230 C235 -126.6(8) . . . . ?
C223 P9 C230 C235 120.4(9) . . . . ?
Au4 P9 C230 C235 -4.4(9) . . . . ?
C202 P9 C230 C231 57.7(10) . . . . ?
C223 P9 C230 C231 -55.3(10) . . . . ?
Au4 P9 C230 C231 179.9(6) . . . . ?
C235 C230 C231 C232 -0.2(4) . . . . ?
P9 C230 C231 C232 175.6(10) . . . . ?
C235 C230 C231 C236 179.2(6) . . . . ?
P9 C230 C231 C236 -5.1(11) . . . . ?
C230 C231 C232 C233 -0.1(4) . . . . ?
C236 C231 C232 C233 -179.6(5) . . . . ?
C231 C232 C233 C234 0.6(9) . . . . ?
C232 C233 C234 C235 -0.7(12) . . . . ?
C231 C230 C235 C234 0.1(9) . . . . ?
P9 C230 C235 C234 -175.6(11) . . . . ?
C233 C234 C235 C230 0.4(12) . . . . ?
C239 P10 C237 P11 163.0(8) . . . . ?
C246 P10 C237 P11 -85.9(8) . . . . ?
Au3 P10 C237 P11 44.4(9) . . . . ?
C238 P11 C237 P10 -169.4(8) . . . . ?
C253 P11 C237 P10 81.4(9) . . . . ?
Pt2 P11 C237 P10 -54.8(9) . . . . ?
C253 P11 C238 P12 -79.8(10) . . . . ?
C237 P11 C238 P12 172.6(9) . . . . ?
Pt2 P11 C238 P12 56.7(10) . . . . ?
C266 P12 C238 P11 -167.4(9) . . . . ?
C259 P12 C238 P11 82.4(10) . . . . ?
Au4 P12 C238 P11 -45.5(11) . . . . ?
C237 P10 C239 C240 178.5(13) . . . . ?
C246 P10 C239 C240 67.2(14) . . . . ?
Au3 P10 C239 C240 -61.3(14) . . . . ?
C237 P10 C239 C244 -5.3(14) . . . . ?
C246 P10 C239 C244 -116.6(13) . . . . ?
Au3 P10 C239 C244 115.0(12) . . . . ?
C244 C239 C240 C241 -5(2) . . . . ?
P10 C239 C240 C241 171.6(13) . . . . ?
C244 C239 C240 C245 175.2(15) . . . . ?
P10 C239 C240 C245 -8(2) . . . . ?
C239 C240 C241 C242 6(3) . . . . ?
C245 C240 C241 C242 -173.5(19) . . . . ?
C240 C241 C242 C243 -6(3) . . . . ?
C241 C242 C243 C244 4(3) . . . . ?
C242 C243 C244 C239 -4(3) . . . . ?
C240 C239 C244 C243 4(2) . . . . ?
P10 C239 C244 C243 -172.4(14) . . . . ?
C239 P10 C246 C247 -130.0(9) . . . . ?
C237 P10 C246 C247 119.8(8) . . . . ?
Au3 P10 C246 C247 -6.8(10) . . . . ?
C239 P10 C246 C251 52.0(9) . . . . ?
C237 P10 C246 C251 -58.2(8) . . . . ?
Au3 P10 C246 C251 175.1(5) . . . . ?
C251 C246 C247 C248 0.0(4) . . . . ?
P10 C246 C247 C248 -177.9(10) . . . . ?
C251 C246 C247 C252 -180.0(5) . . . . ?
P10 C246 C247 C252 2.1(11) . . . . ?
C246 C247 C248 C249 0.1(4) . . . . ?
C252 C247 C248 C249 -179.9(5) . . . . ?
C247 C248 C249 C250 -0.4(9) . . . . ?
C248 C249 C250 C251 0.4(11) . . . . ?
C249 C250 C251 C246 -0.2(11) . . . . ?
C247 C246 C251 C250 0.0(9) . . . . ?
P10 C246 C251 C250 178.1(10) . . . . ?
C238 P11 C253 C258 144.3(10) . . . . ?
C237 P11 C253 C258 -110.0(10) . . . . ?
Pt2 P11 C253 C258 17.2(11) . . . . ?
C238 P11 C253 C254 -39.8(10) . . . . ?
C237 P11 C253 C254 66.0(10) . . . . ?
Pt2 P11 C253 C254 -166.8(6) . . . . ?
C258 C253 C254 C255 -0.1(4) . . . . ?
P11 C253 C254 C255 -176.2(10) . . . . ?
C253 C254 C255 C256 -0.2(4) . . . . ?
C254 C255 C256 C257 0.3(9) . . . . ?
C255 C256 C257 C258 -0.2(12) . . . . ?
C256 C257 C258 C253 0.0(12) . . . . ?
C254 C253 C258 C257 0.2(9) . . . . ?
P11 C253 C258 C257 176.2(11) . . . . ?
C266 P12 C259 C260 145.4(13) . . . . ?
C238 P12 C259 C260 -104.6(14) . . . . ?
Au4 P12 C259 C260 17.1(16) . . . . ?
C266 P12 C259 C264 -38.4(17) . . . . ?
C238 P12 C259 C264 71.6(16) . . . . ?
Au4 P12 C259 C264 -166.7(12) . . . . ?
C264 C259 C260 C261 0.6(18) . . . . ?
P12 C259 C260 C261 176.6(16) . . . . ?
C264 C259 C260 C265 180(2) . . . . ?
P12 C259 C260 C265 -4(2) . . . . ?
C259 C260 C261 C262 1(2) . . . . ?
C265 C260 C261 C262 -178(2) . . . . ?
C260 C261 C262 C263 -2(3) . . . . ?
C261 C262 C263 C264 1(3) . . . . ?
C262 C263 C264 C259 1(3) . . . . ?
C260 C259 C264 C263 -2(3) . . . . ?
P12 C259 C264 C263 -177.8(19) . . . . ?
C238 P12 C266 C271 3.4(9) . . . . ?
C259 P12 C266 C271 112.0(9) . . . . ?
Au4 P12 C266 C271 -116.1(7) . . . . ?
C238 P12 C266 C267 -176.2(9) . . . . ?
C259 P12 C266 C267 -67.6(10) . . . . ?
Au4 P12 C266 C267 64.2(9) . . . . ?
C271 C266 C267 C272 -179.1(6) . . . . ?
P12 C266 C267 C272 0.6(11) . . . . ?
C271 C266 C267 C268 0.2(4) . . . . ?
P12 C266 C267 C268 179.8(10) . . . . ?
C272 C267 C268 C269 179.1(6) . . . . ?
C266 C267 C268 C269 -0.2(4) . . . . ?
C267 C268 C269 C270 0.1(9) . . . . ?
C268 C269 C270 C271 0.0(10) . . . . ?
C267 C266 C271 C270 -0.1(9) . . . . ?
P12 C266 C271 C270 -179.8(12) . . . . ?
C269 C270 C271 C266 0.0(11) . . . . ?
C284 C275 C276 C277 -0.4(4) . . . . ?
C274 C275 C276 C277 -173.0(10) . . . . ?
C275 C276 C277 C278 -0.3(4) . . . . ?
C276 C277 C278 C279 0.4(8) . . . . ?
C276 C277 C278 C285 179.8(4) . . . . ?
C277 C278 C279 C284 0.4(11) . . . . ?
C285 C278 C279 C284 -179.0(7) . . . . ?
C277 C278 C279 C280 179.6(6) . . . . ?
C285 C278 C279 C280 0.2(12) . . . . ?
C278 C279 C280 C281 -179.7(7) . . . . ?
C284 C279 C280 C281 -0.5(12) . . . . ?
C278 C279 C280 C286 0.0(12) . . . . ?
C284 C279 C280 C286 179.3(7) . . . . ?
C279 C280 C281 C282 -0.5(12) . . . . ?
C286 C280 C281 C282 179.8(8) . . . . ?
C280 C281 C282 C283 0.8(12) . . . . ?
C281 C282 C283 C284 -0.2(12) . . . . ?
C278 C279 C284 C283 -179.8(7) . . . . ?
C280 C279 C284 C283 1.0(11) . . . . ?
C278 C279 C284 C275 -1.1(11) . . . . ?
C280 C279 C284 C275 179.7(6) . . . . ?
C282 C283 C284 C279 -0.7(12) . . . . ?
C282 C283 C284 C275 -179.3(7) . . . . ?
C276 C275 C284 C279 1.1(8) . . . . ?
C274 C275 C284 C279 173.6(11) . . . . ?
C276 C275 C284 C283 179.8(6) . . . . ?
C274 C275 C284 C283 -7.7(13) . . . . ?
C286 N3 C285 O5 -177.6(8) . . . . ?
C287 N3 C285 O5 6.2(14) . . . . ?
C286 N3 C285 C278 1.4(11) . . . . ?
C287 N3 C285 C278 -174.8(11) . . . . ?
C277 C278 C285 O5 -1.2(11) . . . . ?
C279 C278 C285 O5 178.1(8) . . . . ?
C277 C278 C285 N3 179.7(6) . . . . ?
C279 C278 C285 N3 -0.9(11) . . . . ?
C285 N3 C286 O6 179.3(8) . . . . ?
C287 N3 C286 O6 -4.6(15) . . . . ?
C285 N3 C286 C280 -1.2(12) . . . . ?
C287 N3 C286 C280 174.8(11) . . . . ?
C281 C280 C286 O6 -0.4(12) . . . . ?
C279 C280 C286 O6 179.9(8) . . . . ?
C281 C280 C286 N3 -179.9(7) . . . . ?
C279 C280 C286 N3 0.4(11) . . . . ?
C285 N3 C287 C289 53.8(15) . . . . ?
C286 N3 C287 C289 -122.6(11) . . . . ?
C285 N3 C287 C288 -72.3(15) . . . . ?
C286 N3 C287 C288 111.3(13) . . . . ?
N3 C287 C289 C290 51.2(13) . . . . ?
C288 C287 C289 C290 175.5(14) . . . . ?
N3 C287 C289 C294 -128.5(13) . . . . ?
C288 C287 C289 C294 -4.2(14) . . . . ?
C294 C289 C290 C291 -0.2(5) . . . . ?
C287 C289 C290 C291 -180.0(4) . . . . ?
C289 C290 C291 C292 -0.2(8) . . . . ?
C290 C291 C292 C293 0.3(11) . . . . ?
C291 C292 C293 C294 0.0(11) . . . . ?
C292 C293 C294 C289 -0.5(11) . . . . ?
C290 C289 C294 C293 0.6(9) . . . . ?
C287 C289 C294 C293 -179.7(5) . . . . ?
C306 C297 C298 C299 0.4(4) . . . . ?
C296 C297 C298 C299 175.7(11) . . . . ?
C297 C298 C299 C300 0.2(4) . . . . ?
C298 C299 C300 C301 -0.3(10) . . . . ?
C298 C299 C300 C307 -179.7(6) . . . . ?
C299 C300 C301 C302 -179.8(8) . . . . ?
C307 C300 C301 C302 -0.4(13) . . . . ?
C299 C300 C301 C306 -0.3(13) . . . . ?
C307 C300 C301 C306 179.2(8) . . . . ?
C300 C301 C302 C303 179.9(9) . . . . ?
C306 C301 C302 C303 0.3(14) . . . . ?
C300 C301 C302 C308 0.0(14) . . . . ?
C306 C301 C302 C308 -179.5(9) . . . . ?
C301 C302 C303 C304 0.4(14) . . . . ?
C308 C302 C303 C304 -179.8(8) . . . . ?
C302 C303 C304 C305 -0.7(13) . . . . ?
C303 C304 C305 C306 0.4(14) . . . . ?
C298 C297 C306 C305 -179.8(6) . . . . ?
C296 C297 C306 C305 6.0(18) . . . . ?
C298 C297 C306 C301 -0.9(10) . . . . ?
C296 C297 C306 C301 -175.1(15) . . . . ?
C304 C305 C306 C297 179.2(8) . . . . ?
C304 C305 C306 C301 0.3(13) . . . . ?
C300 C301 C306 C297 0.9(13) . . . . ?
C302 C301 C306 C297 -179.6(8) . . . . ?
C300 C301 C306 C305 179.8(8) . . . . ?
C302 C301 C306 C305 -0.6(13) . . . . ?
C309 N4 C307 O7 3.5(16) . . . . ?
C308 N4 C307 O7 179.7(8) . . . . ?
C309 N4 C307 C300 -176.2(14) . . . . ?
C308 N4 C307 C300 0.0(14) . . . . ?
C301 C300 C307 O7 -179.3(10) . . . . ?
C299 C300 C307 O7 0.2(14) . . . . ?
C301 C300 C307 N4 0.4(14) . . . . ?
C299 C300 C307 N4 179.8(8) . . . . ?
C303 C302 C308 O8 0.2(14) . . . . ?
C301 C302 C308 O8 -180.0(9) . . . . ?
C303 C302 C308 N4 -179.5(8) . . . . ?
C301 C302 C308 N4 0.4(13) . . . . ?
C307 N4 C308 O8 180.0(9) . . . . ?
C309 N4 C308 O8 -4.0(18) . . . . ?
C307 N4 C308 C302 -0.4(13) . . . . ?
C309 N4 C308 C302 175.6(14) . . . . ?
C307 N4 C309 C311 -77.7(17) . . . . ?
C308 N4 C309 C311 106.3(13) . . . . ?
C307 N4 C309 C310 127(2) . . . . ?
C308 N4 C309 C310 -49(3) . . . . ?
N4 C309 C311 C316 133.7(19) . . . . ?
C310 C309 C311 C316 -72(2) . . . . ?
N4 C309 C311 C312 -46.3(19) . . . . ?
C310 C309 C311 C312 108(2) . . . . ?
C316 C311 C312 C313 0.0(5) . . . . ?
C309 C311 C312 C313 180.0(4) . . . . ?
C311 C312 C313 C314 0.0(8) . . . . ?
C312 C313 C314 C315 0.0(11) . . . . ?
C313 C314 C315 C316 -0.1(12) . . . . ?
C314 C315 C316 C311 0.2(11) . . . . ?
C312 C311 C316 C315 -0.1(8) . . . . ?
C309 C311 C316 C315 179.9(5) . . . . ?
Cl5 C01 C02 Cl6 -32(5) . . . . ?
Cl7 C03 C04 Cl8 -77.5(19) . . . . ?
Cl9 C05 C06 Cl10 58(6) . . . . ?

_refine_diff_density_max         3.522
_refine_diff_density_min         -1.909
_refine_diff_density_rms         0.160




####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1a
_database_code_depnum_ccdc_archive 'CCDC 2348910'
loop_
_audit_author_name
_audit_author_address
'Zhong-Ning Chen'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2024-04-17 deposited with the CCDC.	2024-05-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C118 H104 Au2 Cl8 N2 O12 P6 Pt'
_chemical_formula_weight         2800.47

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   15.0171(2)
_cell_length_b                   19.1160(2)
_cell_length_c                   24.6819(3)
_cell_angle_alpha                90
_cell_angle_beta                 106.2340(10)
_cell_angle_gamma                90
_cell_volume                     6802.85(15)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    86652
_cell_measurement_theta_min      2.1220
_cell_measurement_theta_max      30.9270

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.367
_exptl_crystal_F_000             2768
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    3.455
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            197142
_diffrn_reflns_av_unetI/netI     0.0445
_diffrn_reflns_av_R_equivalents  0.0579
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         2.131
_diffrn_reflns_theta_max         31.002
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.879
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.879
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.879
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             35893
_reflns_number_gt                29818
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.946
_reflns_Friedel_fraction_max     0.878
_reflns_Friedel_fraction_full    0.998

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0838P)²+7.5460P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.058(7)
_chemical_absolute_configuration rm
_refine_ls_number_reflns         35893
_refine_ls_number_parameters     1352
_refine_ls_number_restraints     1262
_refine_ls_R_factor_all          0.0697
_refine_ls_R_factor_gt           0.0548
_refine_ls_wR_factor_ref         0.1395
_refine_ls_wR_factor_gt          0.1320
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_restrained_S_all      1.343
_refine_ls_shift/su_max          0.029
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.75855(2) 0.34734(2) 0.24495(2) 0.03461(10) Uani 1 1 d . . . . .
Au2 Au 0.72292(2) 0.65224(2) 0.25731(2) 0.03471(10) Uani 1 1 d . . . . .
Pt1 Pt 0.74155(3) 0.50003(3) 0.25080(2) 0.02822(8) Uani 1 1 d . . . . .
Cl1 Cl 0.4189(2) 0.50515(16) 0.01045(12) 0.0568(7) Uani 1 1 d . . . . .
Cl2 Cl 0.0718(2) 0.49387(15) 0.48727(12) 0.0541(7) Uani 1 1 d . . . . .
Cl3 Cl 0.6050(4) 0.6058(2) 0.9170(3) 0.130(3) Uani 1 1 d . . . . .
Cl4 Cl 0.6520(3) 0.4621(2) 0.9347(2) 0.0960(13) Uani 1 1 d . . . . .
Cl5 Cl 0.5235(4) 0.5082(3) 0.8312(2) 0.1124(17) Uani 1 1 d . . . . .
O1 O 0.9439(11) 0.4871(7) -0.0788(6) 0.111(4) Uani 1 1 d . . . . .
O2 O 0.8682(8) 0.7132(6) -0.1034(5) 0.083(3) Uani 1 1 d . . . . .
O3 O 0.6653(8) 0.2771(6) 0.5891(5) 0.114(4) Uani 1 1 d . U . . .
O4 O 0.5761(7) 0.4956(7) 0.6241(5) 0.108(4) Uani 1 1 d . U . . .
O5 O 0.3979(8) 0.4417(5) 0.0374(5) 0.077(3) Uani 1 1 d . . . . .
O6 O 0.5164(7) 0.5148(6) 0.0242(4) 0.077(3) Uani 1 1 d . . . . .
O7 O 0.3814(7) 0.4995(5) -0.0517(3) 0.064(2) Uani 1 1 d . . . . .
O8 O 0.3791(7) 0.5620(5) 0.0313(4) 0.068(3) Uani 1 1 d . . . . .
O9 O 0.1066(7) 0.4326(5) 0.4661(4) 0.066(2) Uani 1 1 d . . . . .
O10 O 0.0949(6) 0.5541(4) 0.4594(4) 0.063(2) Uani 1 1 d . . . . .
O11 O -0.0274(7) 0.4906(5) 0.4751(4) 0.064(2) Uani 1 1 d . . . . .
O12 O 0.1155(8) 0.4998(5) 0.5461(4) 0.072(3) Uani 1 1 d . . . . .
P1 P 0.62014(18) 0.33922(14) 0.17366(11) 0.0345(5) Uani 1 1 d . . . . .
P2 P 0.58817(18) 0.49280(15) 0.19727(12) 0.0336(6) Uani 1 1 d . . . . .
P3 P 0.57676(16) 0.65341(16) 0.19236(10) 0.0319(5) Uani 1 1 d . . . . .
P4 P 0.90548(17) 0.34672(16) 0.30869(11) 0.0345(5) Uani 1 1 d . . . . .
P5 P 0.89572(18) 0.50739(14) 0.30334(11) 0.0314(5) Uani 1 1 d . . . . .
P6 P 0.86186(17) 0.66037(13) 0.32784(12) 0.0348(5) Uani 1 1 d . . . . .
N1 N 0.9106(8) 0.6009(7) -0.0902(5) 0.072(3) Uani 1 1 d D . . . .
N2 N 0.6203(7) 0.3866(7) 0.6061(5) 0.084(3) Uani 1 1 d D U . . .
C1 C 0.5824(7) 0.4250(6) 0.1431(4) 0.036(2) Uani 1 1 d . . . . .
H1A H 0.517757 0.421487 0.118838 0.043 Uiso 1 1 calc R U . . .
H1B H 0.621927 0.439357 0.119008 0.043 Uiso 1 1 calc R U . . .
C2 C 0.5543(7) 0.5713(5) 0.1523(4) 0.031(2) Uani 1 1 d . . . . .
H2A H 0.588840 0.571699 0.123515 0.038 Uiso 1 1 calc R U . . .
H2B H 0.487315 0.568400 0.132244 0.038 Uiso 1 1 calc R U . . .
C3 C 0.9294(7) 0.4308(6) 0.3456(4) 0.035(2) Uani 1 1 d . . . . .
H3A H 0.897343 0.431344 0.375656 0.041 Uiso 1 1 calc R U . . .
H3B H 0.996791 0.433699 0.364306 0.041 Uiso 1 1 calc R U . . .
C4 C 0.9013(7) 0.5737(6) 0.3557(4) 0.035(2) Uani 1 1 d . . . . .
H4A H 0.966314 0.577509 0.379426 0.042 Uiso 1 1 calc R U . . .
H4B H 0.863302 0.558402 0.380507 0.042 Uiso 1 1 calc R U . . .
C5 C 0.5172(6) 0.3015(4) 0.1859(4) 0.055(2) Uani 1 1 d D U . . .
C6 C 0.5067(7) 0.2859(3) 0.2383(4) 0.065(3) Uani 1 1 d D U . . .
C7 C 0.4221(8) 0.2596(4) 0.2427(5) 0.073(3) Uani 1 1 d D U . . .
H7 H 0.414308 0.248837 0.278624 0.088 Uiso 1 1 calc R U . . .
C8 C 0.3499(7) 0.2493(5) 0.1945(5) 0.076(3) Uani 1 1 d D U . . .
H8 H 0.292645 0.231154 0.197605 0.091 Uiso 1 1 calc R U . . .
C9 C 0.3598(7) 0.2651(5) 0.1419(5) 0.076(3) Uani 1 1 d D U . . .
H9 H 0.309569 0.258179 0.108987 0.092 Uiso 1 1 calc R U . . .
C10 C 0.4429(7) 0.2910(5) 0.1375(4) 0.071(3) Uani 1 1 d D U . . .
H10 H 0.450060 0.301909 0.101372 0.085 Uiso 1 1 calc R U . . .
C11 C 0.5820(10) 0.2961(5) 0.2902(6) 0.072(3) Uani 1 1 d . U . . .
H11A H 0.560894 0.282094 0.322789 0.108 Uiso 1 1 calc R U . . .
H11B H 0.635458 0.267583 0.288777 0.108 Uiso 1 1 calc R U . . .
H11C H 0.599916 0.345584 0.293839 0.108 Uiso 1 1 calc R U . . .
C12 C 0.6440(7) 0.2913(5) 0.1160(4) 0.0395(19) Uani 1 1 d . U . . .
C13 C 0.6570(8) 0.2172(5) 0.1211(5) 0.046(2) Uani 1 1 d . U . . .
C14 C 0.6818(9) 0.1819(6) 0.0769(6) 0.057(2) Uani 1 1 d . U . . .
H14 H 0.690511 0.132691 0.079531 0.068 Uiso 1 1 calc R U . . .
C15 C 0.6935(10) 0.2153(6) 0.0310(6) 0.061(3) Uani 1 1 d . U . . .
H15 H 0.712384 0.189702 0.003103 0.074 Uiso 1 1 calc R U . . .
C16 C 0.6776(9) 0.2891(7) 0.0242(6) 0.060(3) Uani 1 1 d . U . . .
H16 H 0.683768 0.313305 -0.008180 0.072 Uiso 1 1 calc R U . . .
C17 C 0.6523(8) 0.3239(6) 0.0683(5) 0.049(2) Uani 1 1 d . U . . .
H17 H 0.640453 0.372750 0.064536 0.058 Uiso 1 1 calc R U . . .
C18 C 0.6445(10) 0.1756(5) 0.1696(5) 0.055(3) Uani 1 1 d . U . . .
H18A H 0.581622 0.182803 0.172885 0.083 Uiso 1 1 calc R U . . .
H18B H 0.689784 0.190927 0.204402 0.083 Uiso 1 1 calc R U . . .
H18C H 0.653877 0.125911 0.163245 0.083 Uiso 1 1 calc R U . . .
C19 C 0.4906(7) 0.4771(5) 0.2263(5) 0.044(2) Uani 1 1 d . U . . .
C20 C 0.4996(8) 0.4910(7) 0.2837(6) 0.055(2) Uani 1 1 d . U . . .
H20 H 0.556908 0.506774 0.307978 0.067 Uiso 1 1 calc R U . . .
C21 C 0.4226(10) 0.4812(8) 0.3044(7) 0.069(3) Uani 1 1 d . U . . .
H21 H 0.426213 0.492411 0.342471 0.083 Uiso 1 1 calc R U . . .
C22 C 0.3429(10) 0.4555(8) 0.2694(8) 0.075(3) Uani 1 1 d . U . . .
H22 H 0.293085 0.444090 0.284584 0.091 Uiso 1 1 calc R U . . .
C23 C 0.3322(10) 0.4457(7) 0.2147(8) 0.074(3) Uani 1 1 d . U . . .
H23 H 0.273461 0.432032 0.190927 0.089 Uiso 1 1 calc R U . . .
C24 C 0.4068(8) 0.4554(6) 0.1916(6) 0.059(3) Uani 1 1 d . U . . .
H24 H 0.399377 0.447141 0.152614 0.071 Uiso 1 1 calc R U . . .
C25 C 0.4860(6) 0.6648(4) 0.2283(4) 0.049(2) Uani 1 1 d D U . . .
C26 C 0.3916(7) 0.6695(4) 0.2014(4) 0.068(3) Uani 1 1 d D U . . .
C27 C 0.3295(7) 0.6764(5) 0.2337(5) 0.081(3) Uani 1 1 d D U . . .
H27 H 0.264913 0.679757 0.215565 0.097 Uiso 1 1 calc R U . . .
C28 C 0.3611(8) 0.6786(6) 0.2915(5) 0.087(3) Uani 1 1 d D U . . .
H28 H 0.318168 0.683209 0.313231 0.104 Uiso 1 1 calc R U . . .
C29 C 0.4545(8) 0.6740(5) 0.3182(4) 0.079(3) Uani 1 1 d D U . . .
H29 H 0.476194 0.675434 0.358206 0.094 Uiso 1 1 calc R U . . .
C30 C 0.5163(7) 0.6672(5) 0.2865(4) 0.064(3) Uani 1 1 d D U . . .
H30 H 0.580818 0.664181 0.304931 0.077 Uiso 1 1 calc R U . . .
C31 C 0.3538(11) 0.6674(7) 0.1380(5) 0.099(5) Uani 1 1 d D U . . .
H31A H 0.400061 0.686353 0.120777 0.148 Uiso 1 1 calc R U . . .
H31B H 0.297118 0.695669 0.126411 0.148 Uiso 1 1 calc R U . . .
H31C H 0.339512 0.618985 0.125663 0.148 Uiso 1 1 calc R U . . .
C32 C 0.5658(8) 0.7179(5) 0.1379(5) 0.040(2) Uani 1 1 d . U . . .
C33 C 0.5749(8) 0.7905(6) 0.1516(5) 0.049(2) Uani 1 1 d . U . . .
C34 C 0.5718(9) 0.8379(6) 0.1103(5) 0.057(3) Uani 1 1 d . U . . .
H34 H 0.580781 0.886097 0.119731 0.068 Uiso 1 1 calc R U . . .
C35 C 0.5557(10) 0.8172(6) 0.0537(6) 0.059(3) Uani 1 1 d . U . . .
H35 H 0.553572 0.851111 0.025230 0.071 Uiso 1 1 calc R U . . .
C36 C 0.5430(9) 0.7480(6) 0.0401(5) 0.054(2) Uani 1 1 d . U . . .
H36 H 0.530295 0.734127 0.001704 0.065 Uiso 1 1 calc R U . . .
C37 C 0.5483(7) 0.6988(5) 0.0804(5) 0.044(2) Uani 1 1 d . U . . .
H37 H 0.540217 0.650842 0.069994 0.053 Uiso 1 1 calc R U . . .
C38 C 0.5910(12) 0.8126(6) 0.2108(5) 0.066(4) Uani 1 1 d . U . . .
H38A H 0.612595 0.861233 0.214962 0.099 Uiso 1 1 calc R U . . .
H38B H 0.638090 0.782433 0.235347 0.099 Uiso 1 1 calc R U . . .
H38C H 0.533017 0.808914 0.221454 0.099 Uiso 1 1 calc R U . . .
C39 C 0.9193(6) 0.2815(5) 0.3647(5) 0.040(2) Uani 1 1 d . U . . .
C40 C 0.9025(5) 0.2102(5) 0.3497(6) 0.053(2) Uani 1 1 d . U . . .
C41 C 0.9059(6) 0.1627(6) 0.3950(6) 0.065(3) Uani 1 1 d . U . . .
H41 H 0.895065 0.114381 0.386778 0.078 Uiso 1 1 calc R U . . .
C42 C 0.9243(8) 0.1846(7) 0.4506(6) 0.069(3) Uani 1 1 d . U . . .
H42 H 0.925764 0.151586 0.479600 0.082 Uiso 1 1 calc R U . . .
C43 C 0.9404(7) 0.2532(7) 0.4636(6) 0.060(3) Uani 1 1 d . U . . .
H43 H 0.953119 0.268305 0.501726 0.072 Uiso 1 1 calc R U . . .
C44 C 0.9381(6) 0.3017(6) 0.4208(5) 0.047(2) Uani 1 1 d . U . . .
H44 H 0.949664 0.349674 0.430392 0.056 Uiso 1 1 calc R U . . .
C45 C 0.8826(8) 0.1820(6) 0.2908(7) 0.070(4) Uani 1 1 d . U . . .
H45A H 0.830024 0.149603 0.283720 0.105 Uiso 1 1 calc R U . . .
H45B H 0.937316 0.157261 0.286460 0.105 Uiso 1 1 calc R U . . .
H45C H 0.867382 0.220771 0.263814 0.105 Uiso 1 1 calc R U . . .
C46 C 0.9944(7) 0.3347(5) 0.2724(4) 0.058(3) Uani 1 1 d D U . . .
C47 C 1.0873(7) 0.3279(4) 0.2992(5) 0.078(3) Uani 1 1 d D U . . .
C48 C 1.1517(8) 0.3227(5) 0.2684(7) 0.092(4) Uani 1 1 d D U . . .
H48 H 1.215894 0.318019 0.287171 0.110 Uiso 1 1 calc R U . . .
C49 C 1.1212(9) 0.3245(6) 0.2102(7) 0.102(4) Uani 1 1 d D U . . .
H49 H 1.164755 0.321004 0.188810 0.122 Uiso 1 1 calc R U . . .
C50 C 1.0285(10) 0.3313(7) 0.1829(5) 0.099(4) Uani 1 1 d D U . . .
H50 H 1.008300 0.332796 0.142829 0.119 Uiso 1 1 calc R U . . .
C51 C 0.9645(8) 0.3360(6) 0.2134(5) 0.083(3) Uani 1 1 d D U . . .
H51 H 0.900341 0.340138 0.194441 0.099 Uiso 1 1 calc R U . . .
C52 C 1.1286(11) 0.3249(8) 0.3609(6) 0.105(5) Uani 1 1 d D U . . .
H52A H 1.105381 0.283476 0.376049 0.157 Uiso 1 1 calc R U . . .
H52B H 1.111489 0.367052 0.378270 0.157 Uiso 1 1 calc R U . . .
H52C H 1.196261 0.322148 0.369404 0.157 Uiso 1 1 calc R U . . .
C53 C 0.9908(6) 0.5228(4) 0.2725(4) 0.042(2) Uani 1 1 d D U . . .
C54 C 0.9833(7) 0.5057(5) 0.2166(4) 0.054(2) Uani 1 1 d D U . . .
H54 H 0.927079 0.485693 0.194268 0.064 Uiso 1 1 calc R U . . .
C55 C 1.0550(7) 0.5167(5) 0.1926(6) 0.065(3) Uani 1 1 d D U . . .
H55 H 1.048732 0.504373 0.154409 0.079 Uiso 1 1 calc R U . . .
C56 C 1.1358(8) 0.5462(6) 0.2255(5) 0.071(3) Uani 1 1 d D U . . .
H56 H 1.185577 0.555059 0.209710 0.085 Uiso 1 1 calc R U . . .
C57 C 1.1453(8) 0.5631(5) 0.2814(6) 0.067(3) Uani 1 1 d D U . . .
H57 H 1.201351 0.582907 0.304109 0.081 Uiso 1 1 calc R U . . .
C58 C 1.0718(6) 0.5507(5) 0.3035(6) 0.059(3) Uani 1 1 d D U . . .
H58 H 1.078438 0.562275 0.341874 0.071 Uiso 1 1 calc R U . . .
C59 C 0.8460(7) 0.7109(5) 0.3884(5) 0.0424(17) Uani 1 1 d . U . . .
C60 C 0.8292(7) 0.7837(5) 0.3824(5) 0.0462(18) Uani 1 1 d . U . . .
C61 C 0.8108(8) 0.8184(6) 0.4270(6) 0.053(2) Uani 1 1 d . U . . .
H61 H 0.798196 0.867196 0.423759 0.064 Uiso 1 1 calc R U . . .
C62 C 0.8103(9) 0.7841(6) 0.4764(6) 0.056(2) Uani 1 1 d . U . . .
H62 H 0.798853 0.809231 0.506944 0.067 Uiso 1 1 calc R U . . .
C63 C 0.8266(8) 0.7126(6) 0.4806(6) 0.053(2) Uani 1 1 d . U . . .
H63 H 0.826586 0.688888 0.514473 0.064 Uiso 1 1 calc R U . . .
C64 C 0.8424(8) 0.6762(6) 0.4373(5) 0.0481(19) Uani 1 1 d . U . . .
H64 H 0.851148 0.626989 0.440285 0.058 Uiso 1 1 calc R U . . .
C65 C 0.8314(9) 0.8232(6) 0.3298(6) 0.056(3) Uani 1 1 d . U . . .
H65A H 0.808057 0.793034 0.296756 0.085 Uiso 1 1 calc R U . . .
H65B H 0.895259 0.837181 0.332565 0.085 Uiso 1 1 calc R U . . .
H65C H 0.792224 0.864922 0.325977 0.085 Uiso 1 1 calc R U . . .
C66 C 0.9538(9) 0.6967(5) 0.2993(6) 0.094(4) Uani 1 1 d D U . . .
C67 C 1.0403(10) 0.7191(4) 0.3283(5) 0.108(4) Uani 1 1 d D U . . .
C68 C 1.1028(9) 0.7449(5) 0.3012(7) 0.107(4) Uani 1 1 d D U . . .
H68 H 1.162614 0.760130 0.322328 0.129 Uiso 1 1 calc R U . . .
C69 C 1.0767(10) 0.7482(6) 0.2429(7) 0.120(5) Uani 1 1 d D U . . .
H69 H 1.118607 0.765958 0.223725 0.144 Uiso 1 1 calc R U . . .
C70 C 0.9893(11) 0.7254(7) 0.2124(6) 0.125(5) Uani 1 1 d D U . . .
H70 H 0.972031 0.727298 0.172361 0.150 Uiso 1 1 calc R U . . .
C71 C 0.9285(9) 0.7006(6) 0.2391(6) 0.112(4) Uani 1 1 d D U . . .
H71 H 0.868690 0.685649 0.217676 0.134 Uiso 1 1 calc R U . . .
C72 C 1.0604(12) 0.7133(7) 0.3897(7) 0.104(5) Uani 1 1 d D U . . .
H72A H 1.007689 0.691406 0.399215 0.157 Uiso 1 1 calc R U . . .
H72B H 1.071079 0.759989 0.406632 0.157 Uiso 1 1 calc R U . . .
H72C H 1.115953 0.684490 0.404381 0.157 Uiso 1 1 calc R U . . .
C73 C 0.7642(7) 0.5217(5) 0.1764(4) 0.041(2) Uani 1 1 d . . . . .
C74 C 0.7784(8) 0.5307(7) 0.1326(5) 0.057(3) Uani 1 1 d . . . . .
C75 C 0.8093(5) 0.5310(5) 0.0819(3) 0.061(3) Uani 1 1 d D U . . .
C76 C 0.8430(5) 0.4705(5) 0.0619(4) 0.065(3) Uani 1 1 d D U . . .
H76 H 0.843592 0.427017 0.080532 0.078 Uiso 1 1 calc R U . . .
C77 C 0.8756(6) 0.4751(5) 0.0142(4) 0.072(3) Uani 1 1 d D U . . .
H77 H 0.898383 0.434537 0.000291 0.086 Uiso 1 1 calc R U . . .
C78 C 0.8747(6) 0.5393(5) -0.0132(4) 0.063(3) Uani 1 1 d D U . . .
C79 C 0.8411(6) 0.5995(4) 0.0064(4) 0.057(2) Uani 1 1 d D U . . .
C80 C 0.8399(6) 0.6623(5) -0.0201(3) 0.063(3) Uani 1 1 d D U . . .
C81 C 0.8089(6) 0.7251(5) -0.0052(4) 0.062(3) Uani 1 1 d D U . . .
H81 H 0.809267 0.767197 -0.025642 0.074 Uiso 1 1 calc R U . . .
C82 C 0.7754(6) 0.7213(5) 0.0448(4) 0.065(3) Uani 1 1 d D U . . .
H82 H 0.752926 0.760691 0.060384 0.078 Uiso 1 1 calc R U . . .
C83 C 0.7796(6) 0.6558(5) 0.0669(4) 0.062(2) Uani 1 1 d D U . . .
H83 H 0.756308 0.653851 0.098924 0.075 Uiso 1 1 calc R U . . .
C84 C 0.8081(5) 0.5950(4) 0.0545(3) 0.054(2) Uani 1 1 d D U . . .
C85 C 0.9152(10) 0.5399(8) -0.0615(6) 0.072(4) Uani 1 1 d . . . . .
C86 C 0.8707(9) 0.6626(9) -0.0745(5) 0.069(4) Uani 1 1 d D . . . .
C87 C 0.9376(9) 0.6062(7) -0.1431(5) 0.096(4) Uani 1 1 d D U . . .
H87 H 0.961810 0.558034 -0.145900 0.116 Uiso 1 1 calc R U . . .
C88 C 0.8594(9) 0.6101(5) -0.1972(4) 0.094(3) Uani 1 1 d D U . . .
C89 C 0.8726(10) 0.6442(7) -0.2434(6) 0.119(4) Uani 1 1 d D U . . .
H89 H 0.930650 0.665392 -0.241475 0.142 Uiso 1 1 calc R U . . .
C90 C 0.8010(12) 0.6475(8) -0.2925(5) 0.131(5) Uani 1 1 d D U . . .
H90 H 0.810139 0.671324 -0.324347 0.157 Uiso 1 1 calc R U . . .
C91 C 0.7173(11) 0.6171(8) -0.2962(5) 0.127(5) Uani 1 1 d D U . . .
H91 H 0.668662 0.619414 -0.330374 0.153 Uiso 1 1 calc R U . . .
C92 C 0.7037(9) 0.5828(7) -0.2497(6) 0.108(4) Uani 1 1 d D U . . .
H92 H 0.645756 0.561496 -0.251725 0.129 Uiso 1 1 calc R U . . .
C93 C 0.7751(10) 0.5799(6) -0.2006(5) 0.096(4) Uani 1 1 d D U . . .
H93 H 0.765901 0.556670 -0.168539 0.115 Uiso 1 1 calc R U . . .
C94 C 1.0251(11) 0.6493(11) -0.1348(8) 0.108(6) Uani 1 1 d D . . . .
H94A H 1.054791 0.637703 -0.164359 0.162 Uiso 1 1 calc R U . . .
H94B H 1.067887 0.638971 -0.097753 0.162 Uiso 1 1 calc R U . . .
H94C H 1.009321 0.699190 -0.137011 0.162 Uiso 1 1 calc R U . . .
C96 C 0.7214(7) 0.4737(7) 0.3241(5) 0.049(3) Uani 1 1 d . . . . .
C97 C 0.7131(9) 0.4471(8) 0.3675(5) 0.062(3) Uani 1 1 d . . . . .
C98 C 0.6997(5) 0.4198(6) 0.4219(5) 0.063(3) Uani 1 1 d D U . . .
C99 C 0.7173(5) 0.3496(6) 0.4332(4) 0.059(2) Uani 1 1 d D U . . .
H99 H 0.738948 0.319841 0.408825 0.071 Uiso 1 1 calc R U . . .
C100 C 0.7008(5) 0.3250(7) 0.4835(4) 0.071(3) Uani 1 1 d D U . . .
H100 H 0.711523 0.277166 0.493710 0.085 Uiso 1 1 calc R U . . .
C101 C 0.6690(6) 0.3700(6) 0.5181(5) 0.077(3) Uani 1 1 d D U . . .
C102 C 0.6516(6) 0.4404(6) 0.5061(5) 0.080(3) Uani 1 1 d D U . . .
C103 C 0.6202(7) 0.4854(7) 0.5409(5) 0.085(3) Uani 1 1 d D U . . .
C104 C 0.6028(8) 0.5557(7) 0.5285(6) 0.094(4) Uani 1 1 d D U . . .
H104 H 0.580612 0.585447 0.552652 0.113 Uiso 1 1 calc R U . . .
C105 C 0.6193(8) 0.5810(8) 0.4790(5) 0.090(4) Uani 1 1 d D U . . .
H105 H 0.608762 0.628878 0.468951 0.108 Uiso 1 1 calc R U . . .
C106 C 0.6511(7) 0.5359(6) 0.4447(6) 0.071(3) Uani 1 1 d D U . . .
H106 H 0.662205 0.554264 0.411401 0.085 Uiso 1 1 calc R U . . .
C107 C 0.6676(6) 0.4658(5) 0.4561(5) 0.070(3) Uani 1 1 d D U . . .
C108 C 0.6526(7) 0.3386(10) 0.5726(6) 0.089(3) Uani 1 1 d . U . . .
C109 C 0.6030(8) 0.4585(10) 0.5939(7) 0.090(3) Uani 1 1 d . U . . .
C110 C 0.6008(13) 0.3644(8) 0.6589(6) 0.153(5) Uani 1 1 d D U . . .
H110 H 0.603659 0.312199 0.656909 0.183 Uiso 1 1 calc R U . . .
C111 C 0.5003(15) 0.3779(12) 0.6581(9) 0.156(5) Uani 1 1 d D U . . .
H11D H 0.495902 0.423095 0.675828 0.234 Uiso 1 1 calc R U . . .
H11E H 0.479276 0.340676 0.678913 0.234 Uiso 1 1 calc R U . . .
H11F H 0.461161 0.378469 0.618952 0.234 Uiso 1 1 calc R U . . .
C112 C 0.6806(13) 0.3815(6) 0.7091(6) 0.156(5) Uani 1 1 d D U . . .
C113 C 0.6684(13) 0.3734(7) 0.7624(8) 0.159(5) Uani 1 1 d D U . . .
H113 H 0.610560 0.357455 0.766290 0.191 Uiso 1 1 calc R U . . .
C114 C 0.7402(16) 0.3885(8) 0.8100(6) 0.162(5) Uani 1 1 d D U . . .
H114 H 0.731585 0.382849 0.846407 0.195 Uiso 1 1 calc R U . . .
C115 C 0.8244(14) 0.4118(8) 0.8045(6) 0.163(5) Uani 1 1 d D U . . .
H115 H 0.873793 0.422016 0.837153 0.196 Uiso 1 1 calc R U . . .
C116 C 0.8367(13) 0.4202(9) 0.7512(8) 0.162(5) Uani 1 1 d D U . . .
H116 H 0.894367 0.436432 0.747365 0.195 Uiso 1 1 calc R U . . .
C117 C 0.7650(15) 0.4050(8) 0.7038(6) 0.158(5) Uani 1 1 d D U . . .
H117 H 0.773639 0.410679 0.667345 0.189 Uiso 1 1 calc R U . . .
C120 C 0.5675(9) 0.5205(7) 0.9033(6) 0.065(3) Uani 1 1 d . . . . .
H12A H 0.515096 0.513557 0.920370 0.078 Uiso 1 1 calc R U . . .
C121 C 0.9509(9) 0.4860(5) 0.6037(6) 0.105(5) Uani 1 1 d D U . . .
H121 H 0.989844 0.497134 0.577963 0.126 Uiso 1 1 calc R U . . .
Cl6 Cl 1.0217(5) 0.4930(3) 0.6731(2) 0.132(2) Uani 1 1 d D U . . .
Cl7 Cl 0.9095(4) 0.3994(2) 0.5889(3) 0.1103(17) Uani 1 1 d D U . . .
Cl8 Cl 0.8571(5) 0.5449(3) 0.5885(4) 0.156(3) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.323(3) . ?
Au1 P4 2.324(3) . ?
Au1 Pt1 2.9370(5) . ?
Au2 P6 2.319(3) . ?
Au2 P3 2.328(2) . ?
Au2 Pt1 2.9318(6) . ?
Pt1 C96 1.981(11) . ?
Pt1 C73 2.001(11) . ?
Pt1 P2 2.317(3) . ?
Pt1 P5 2.320(3) . ?
Cl1 O8 1.405(9) . ?
Cl1 O6 1.420(11) . ?
Cl1 O5 1.459(10) . ?
Cl1 O7 1.483(8) . ?
Cl2 O12 1.422(9) . ?
Cl2 O10 1.433(10) . ?
Cl2 O11 1.436(10) . ?
Cl2 O9 1.439(9) . ?
Cl3 C120 1.726(14) . ?
Cl4 C120 1.705(15) . ?
Cl5 C120 1.734(15) . ?
O1 C85 1.220(18) . ?
O2 C86 1.196(17) . ?
O3 C108 1.24(2) . ?
O4 C109 1.18(2) . ?
P1 C5 1.806(9) . ?
P1 C12 1.810(11) . ?
P1 C1 1.828(11) . ?
P2 C19 1.827(10) . ?
P2 C1 1.846(11) . ?
P2 C2 1.851(10) . ?
P3 C32 1.797(11) . ?
P3 C25 1.835(8) . ?
P3 C2 1.836(10) . ?
P4 C46 1.819(9) . ?
P4 C39 1.829(11) . ?
P4 C3 1.834(12) . ?
P5 C3 1.786(10) . ?
P5 C4 1.796(11) . ?
P5 C53 1.820(9) . ?
P6 C4 1.829(11) . ?
P6 C59 1.850(11) . ?
P6 C66 1.853(10) . ?
N1 C85 1.357(18) . ?
N1 C86 1.426(19) . ?
N1 C87 1.475(10) . ?
N2 C108 1.41(2) . ?
N2 C109 1.41(2) . ?
N2 C110 1.475(12) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.380(10) . ?
C5 C10 1.402(10) . ?
C6 C7 1.398(10) . ?
C6 C11 1.465(17) . ?
C7 C8 1.381(10) . ?
C7 H7 0.9500 . ?
C8 C9 1.382(11) . ?
C8 H8 0.9500 . ?
C9 C10 1.375(10) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C17 1.368(15) . ?
C12 C13 1.432(13) . ?
C13 C14 1.419(17) . ?
C13 C18 1.489(17) . ?
C14 C15 1.354(19) . ?
C14 H14 0.9500 . ?
C15 C16 1.431(17) . ?
C15 H15 0.9500 . ?
C16 C17 1.416(17) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C24 1.374(16) . ?
C19 C20 1.411(17) . ?
C20 C21 1.400(16) . ?
C20 H20 0.9500 . ?
C21 C22 1.36(2) . ?
C21 H21 0.9500 . ?
C22 C23 1.33(2) . ?
C22 H22 0.9500 . ?
C23 C24 1.404(18) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.380(10) . ?
C25 C26 1.390(10) . ?
C26 C27 1.392(10) . ?
C26 C31 1.508(11) . ?
C27 C28 1.374(10) . ?
C27 H27 0.9500 . ?
C28 C29 1.376(11) . ?
C28 H28 0.9500 . ?
C29 C30 1.378(10) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 C37 1.417(16) . ?
C32 C33 1.426(14) . ?
C33 C34 1.356(16) . ?
C33 C38 1.475(16) . ?
C34 C35 1.405(18) . ?
C34 H34 0.9500 . ?
C35 C36 1.366(17) . ?
C35 H35 0.9500 . ?
C36 C37 1.356(16) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C44 1.390(16) . ?
C39 C40 1.417(15) . ?
C40 C41 1.432(17) . ?
C40 C45 1.498(19) . ?
C41 C42 1.386(19) . ?
C41 H41 0.9500 . ?
C42 C43 1.355(19) . ?
C42 H42 0.9500 . ?
C43 C44 1.399(16) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C47 1.373(10) . ?
C46 C51 1.398(11) . ?
C47 C48 1.390(11) . ?
C47 C52 1.478(12) . ?
C48 C49 1.382(17) . ?
C48 H48 0.9500 . ?
C49 C50 1.373(11) . ?
C49 H49 0.9500 . ?
C50 C51 1.380(11) . ?
C50 H50 0.9500 . ?
C51 H51 0.9500 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 C58 1.354(10) . ?
C53 C54 1.390(10) . ?
C54 C55 1.384(11) . ?
C54 H54 0.9500 . ?
C55 C56 1.378(11) . ?
C55 H55 0.9500 . ?
C56 C57 1.384(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.381(11) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C64 1.391(16) . ?
C59 C60 1.415(14) . ?
C60 C61 1.376(16) . ?
C60 C65 1.511(18) . ?
C61 C62 1.387(18) . ?
C61 H61 0.9500 . ?
C62 C63 1.387(16) . ?
C62 H62 0.9500 . ?
C63 C64 1.351(16) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 C67 1.364(11) . ?
C66 C71 1.430(11) . ?
C67 C68 1.387(11) . ?
C67 C72 1.465(12) . ?
C68 C69 1.382(11) . ?
C68 H68 0.9500 . ?
C69 C70 1.387(11) . ?
C69 H69 0.9500 . ?
C70 C71 1.352(11) . ?
C70 H70 0.9500 . ?
C71 H71 0.9500 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 C74 1.173(15) . ?
C74 C75 1.452(14) . ?
C75 C84 1.396(9) . ?
C75 C76 1.405(10) . ?
C76 C77 1.399(10) . ?
C76 H76 0.9500 . ?
C77 C78 1.399(10) . ?
C77 H77 0.9500 . ?
C78 C79 1.397(9) . ?
C78 C85 1.481(16) . ?
C79 C80 1.365(9) . ?
C79 C84 1.411(9) . ?
C80 C81 1.374(10) . ?
C80 C86 1.537(10) . ?
C81 C82 1.459(10) . ?
C81 H81 0.9500 . ?
C82 C83 1.361(9) . ?
C82 H82 0.9500 . ?
C83 C84 1.303(10) . ?
C83 H83 0.9500 . ?
C87 C88 1.514(12) . ?
C87 C94 1.516(12) . ?
C87 H87 1.0000 . ?
C88 C93 1.373(11) . ?
C88 C89 1.375(11) . ?
C89 C90 1.379(11) . ?
C89 H89 0.9500 . ?
C90 C91 1.366(11) . ?
C90 H90 0.9500 . ?
C91 C92 1.384(11) . ?
C91 H91 0.9500 . ?
C92 C93 1.377(11) . ?
C92 H92 0.9500 . ?
C93 H93 0.9500 . ?
C94 H94A 0.9800 . ?
C94 H94B 0.9800 . ?
C94 H94C 0.9800 . ?
C96 C97 1.224(16) . ?
C97 C98 1.505(17) . ?
C98 C99 1.382(11) . ?
C98 C107 1.395(11) . ?
C99 C100 1.411(11) . ?
C99 H99 0.9500 . ?
C100 C101 1.389(11) . ?
C100 H100 0.9500 . ?
C101 C102 1.387(12) . ?
C101 C108 1.55(2) . ?
C102 C103 1.387(11) . ?
C102 C107 1.407(11) . ?
C103 C104 1.385(12) . ?
C103 C109 1.50(2) . ?
C104 C105 1.400(12) . ?
C104 H104 0.9500 . ?
C105 C106 1.383(11) . ?
C105 H105 0.9500 . ?
C106 C107 1.376(11) . ?
C106 H106 0.9500 . ?
C110 C112 1.500(13) . ?
C110 C111 1.526(13) . ?
C110 H110 1.0000 . ?
C111 H11D 0.9800 . ?
C111 H11E 0.9800 . ?
C111 H11F 0.9800 . ?
C112 C117 1.384(12) . ?
C112 C113 1.387(11) . ?
C113 C114 1.384(12) . ?
C113 H113 0.9500 . ?
C114 C115 1.383(12) . ?
C114 H114 0.9500 . ?
C115 C116 1.387(11) . ?
C115 H115 0.9500 . ?
C116 C117 1.382(12) . ?
C116 H116 0.9500 . ?
C117 H117 0.9500 . ?
C120 H12A 1.0000 . ?
C121 Cl6 1.750(11) . ?
C121 Cl8 1.761(11) . ?
C121 Cl7 1.770(11) . ?
C121 H121 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P4 172.50(10) . . ?
P1 Au1 Pt1 91.83(7) . . ?
P4 Au1 Pt1 92.92(8) . . ?
P6 Au2 P3 173.45(10) . . ?
P6 Au2 Pt1 91.61(6) . . ?
P3 Au2 Pt1 93.31(7) . . ?
C96 Pt1 C73 177.1(5) . . ?
C96 Pt1 P2 97.1(3) . . ?
C73 Pt1 P2 83.5(3) . . ?
C96 Pt1 P5 83.6(3) . . ?
C73 Pt1 P5 95.8(3) . . ?
P2 Pt1 P5 179.26(11) . . ?
C96 Pt1 Au2 99.3(4) . . ?
C73 Pt1 Au2 83.6(3) . . ?
P2 Pt1 Au2 89.75(7) . . ?
P5 Pt1 Au2 90.27(7) . . ?
C96 Pt1 Au1 80.2(4) . . ?
C73 Pt1 Au1 97.0(3) . . ?
P2 Pt1 Au1 89.94(7) . . ?
P5 Pt1 Au1 90.05(7) . . ?
Au2 Pt1 Au1 179.339(18) . . ?
O8 Cl1 O6 109.1(6) . . ?
O8 Cl1 O5 107.9(7) . . ?
O6 Cl1 O5 109.7(7) . . ?
O8 Cl1 O7 111.0(6) . . ?
O6 Cl1 O7 109.0(6) . . ?
O5 Cl1 O7 110.1(6) . . ?
O12 Cl2 O10 108.7(6) . . ?
O12 Cl2 O11 111.8(7) . . ?
O10 Cl2 O11 108.1(6) . . ?
O12 Cl2 O9 109.0(6) . . ?
O10 Cl2 O9 108.6(6) . . ?
O11 Cl2 O9 110.4(6) . . ?
C5 P1 C12 107.2(4) . . ?
C5 P1 C1 104.2(4) . . ?
C12 P1 C1 103.7(5) . . ?
C5 P1 Au1 121.8(3) . . ?
C12 P1 Au1 107.3(3) . . ?
C1 P1 Au1 111.2(3) . . ?
C19 P2 C1 106.8(5) . . ?
C19 P2 C2 104.6(5) . . ?
C1 P2 C2 100.7(4) . . ?
C19 P2 Pt1 124.4(4) . . ?
C1 P2 Pt1 107.0(3) . . ?
C2 P2 Pt1 110.9(3) . . ?
C32 P3 C25 110.8(5) . . ?
C32 P3 C2 102.6(5) . . ?
C25 P3 C2 108.2(4) . . ?
C32 P3 Au2 113.2(4) . . ?
C25 P3 Au2 110.7(3) . . ?
C2 P3 Au2 111.0(3) . . ?
C46 P4 C39 110.0(5) . . ?
C46 P4 C3 106.7(5) . . ?
C39 P4 C3 104.9(5) . . ?
C46 P4 Au1 110.8(4) . . ?
C39 P4 Au1 113.6(3) . . ?
C3 P4 Au1 110.4(3) . . ?
C3 P5 C4 102.0(5) . . ?
C3 P5 C53 104.5(5) . . ?
C4 P5 C53 107.6(5) . . ?
C3 P5 Pt1 110.6(4) . . ?
C4 P5 Pt1 106.5(3) . . ?
C53 P5 Pt1 123.6(3) . . ?
C4 P6 C59 105.7(5) . . ?
C4 P6 C66 106.6(5) . . ?
C59 P6 C66 112.9(5) . . ?
C4 P6 Au2 110.5(3) . . ?
C59 P6 Au2 110.4(3) . . ?
C66 P6 Au2 110.5(5) . . ?
C85 N1 C86 122.2(11) . . ?
C85 N1 C87 122.4(12) . . ?
C86 N1 C87 115.1(11) . . ?
C108 N2 C109 125.6(13) . . ?
C108 N2 C110 121.0(13) . . ?
C109 N2 C110 113.4(13) . . ?
P1 C1 P2 112.6(5) . . ?
P1 C1 H1A 109.1 . . ?
P2 C1 H1A 109.1 . . ?
P1 C1 H1B 109.1 . . ?
P2 C1 H1B 109.1 . . ?
H1A C1 H1B 107.8 . . ?
P3 C2 P2 113.0(5) . . ?
P3 C2 H2A 109.0 . . ?
P2 C2 H2A 109.0 . . ?
P3 C2 H2B 109.0 . . ?
P2 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?
P5 C3 P4 116.4(6) . . ?
P5 C3 H3A 108.2 . . ?
P4 C3 H3A 108.2 . . ?
P5 C3 H3B 108.2 . . ?
P4 C3 H3B 108.2 . . ?
H3A C3 H3B 107.4 . . ?
P5 C4 P6 115.0(5) . . ?
P5 C4 H4A 108.5 . . ?
P6 C4 H4A 108.5 . . ?
P5 C4 H4B 108.5 . . ?
P6 C4 H4B 108.5 . . ?
H4A C4 H4B 107.5 . . ?
C6 C5 C10 119.7(7) . . ?
C6 C5 P1 124.8(7) . . ?
C10 C5 P1 115.4(7) . . ?
C5 C6 C7 119.6(7) . . ?
C5 C6 C11 121.9(9) . . ?
C7 C6 C11 118.5(9) . . ?
C8 C7 C6 119.8(7) . . ?
C8 C7 H7 120.1 . . ?
C6 C7 H7 120.1 . . ?
C7 C8 C9 120.9(7) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C10 C9 C8 119.4(7) . . ?
C10 C9 H9 120.3 . . ?
C8 C9 H9 120.3 . . ?
C9 C10 C5 120.5(7) . . ?
C9 C10 H10 119.7 . . ?
C5 C10 H10 119.7 . . ?
C6 C11 H11A 109.5 . . ?
C6 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C6 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C17 C12 C13 118.9(10) . . ?
C17 C12 P1 122.2(8) . . ?
C13 C12 P1 118.9(8) . . ?
C14 C13 C12 117.4(11) . . ?
C14 C13 C18 119.0(10) . . ?
C12 C13 C18 123.6(10) . . ?
C15 C14 C13 122.9(11) . . ?
C15 C14 H14 118.5 . . ?
C13 C14 H14 118.5 . . ?
C14 C15 C16 120.4(12) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C17 C16 C15 116.4(12) . . ?
C17 C16 H16 121.8 . . ?
C15 C16 H16 121.8 . . ?
C12 C17 C16 123.8(11) . . ?
C12 C17 H17 118.1 . . ?
C16 C17 H17 118.1 . . ?
C13 C18 H18A 109.5 . . ?
C13 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C13 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C24 C19 C20 119.8(11) . . ?
C24 C19 P2 120.0(9) . . ?
C20 C19 P2 120.1(8) . . ?
C21 C20 C19 119.0(13) . . ?
C21 C20 H20 120.5 . . ?
C19 C20 H20 120.5 . . ?
C22 C21 C20 119.2(14) . . ?
C22 C21 H21 120.4 . . ?
C20 C21 H21 120.4 . . ?
C23 C22 C21 122.1(13) . . ?
C23 C22 H22 119.0 . . ?
C21 C22 H22 119.0 . . ?
C22 C23 C24 120.8(14) . . ?
C22 C23 H23 119.6 . . ?
C24 C23 H23 119.6 . . ?
C19 C24 C23 118.8(14) . . ?
C19 C24 H24 120.6 . . ?
C23 C24 H24 120.6 . . ?
C30 C25 C26 119.4(6) . . ?
C30 C25 P3 115.7(7) . . ?
C26 C25 P3 124.9(7) . . ?
C25 C26 C27 119.3(7) . . ?
C25 C26 C31 122.2(10) . . ?
C27 C26 C31 118.5(10) . . ?
C28 C27 C26 120.4(7) . . ?
C28 C27 H27 119.8 . . ?
C26 C27 H27 119.8 . . ?
C27 C28 C29 120.3(7) . . ?
C27 C28 H28 119.9 . . ?
C29 C28 H28 119.9 . . ?
C28 C29 C30 119.6(7) . . ?
C28 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C29 C30 C25 121.0(7) . . ?
C29 C30 H30 119.5 . . ?
C25 C30 H30 119.5 . . ?
C26 C31 H31A 109.5 . . ?
C26 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C26 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C37 C32 C33 117.9(10) . . ?
C37 C32 P3 121.6(8) . . ?
C33 C32 P3 120.5(9) . . ?
C34 C33 C32 119.5(12) . . ?
C34 C33 C38 121.0(11) . . ?
C32 C33 C38 119.5(11) . . ?
C33 C34 C35 121.3(11) . . ?
C33 C34 H34 119.4 . . ?
C35 C34 H34 119.4 . . ?
C36 C35 C34 119.4(12) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C37 C36 C35 121.1(12) . . ?
C37 C36 H36 119.5 . . ?
C35 C36 H36 119.5 . . ?
C36 C37 C32 120.8(10) . . ?
C36 C37 H37 119.6 . . ?
C32 C37 H37 119.6 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C44 C39 C40 120.0(10) . . ?
C44 C39 P4 120.8(8) . . ?
C40 C39 P4 119.0(9) . . ?
C39 C40 C41 116.1(12) . . ?
C39 C40 C45 124.9(11) . . ?
C41 C40 C45 119.0(11) . . ?
C42 C41 C40 122.4(11) . . ?
C42 C41 H41 118.8 . . ?
C40 C41 H41 118.8 . . ?
C43 C42 C41 120.0(12) . . ?
C43 C42 H42 120.0 . . ?
C41 C42 H42 120.0 . . ?
C42 C43 C44 119.8(13) . . ?
C42 C43 H43 120.1 . . ?
C44 C43 H43 120.1 . . ?
C39 C44 C43 121.6(11) . . ?
C39 C44 H44 119.2 . . ?
C43 C44 H44 119.2 . . ?
C40 C45 H45A 109.5 . . ?
C40 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C40 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C47 C46 C51 119.3(7) . . ?
C47 C46 P4 124.2(8) . . ?
C51 C46 P4 116.4(7) . . ?
C46 C47 C48 120.8(8) . . ?
C46 C47 C52 125.2(11) . . ?
C48 C47 C52 113.9(11) . . ?
C49 C48 C47 119.2(8) . . ?
C49 C48 H48 120.4 . . ?
C47 C48 H48 120.4 . . ?
C50 C49 C48 120.6(8) . . ?
C50 C49 H49 119.7 . . ?
C48 C49 H49 119.7 . . ?
C49 C50 C51 120.2(8) . . ?
C49 C50 H50 119.9 . . ?
C51 C50 H50 119.9 . . ?
C50 C51 C46 119.8(7) . . ?
C50 C51 H51 120.1 . . ?
C46 C51 H51 120.1 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C58 C53 C54 117.7(10) . . ?
C58 C53 P5 120.9(8) . . ?
C54 C53 P5 121.4(7) . . ?
C55 C54 C53 122.2(11) . . ?
C55 C54 H54 118.9 . . ?
C53 C54 H54 118.9 . . ?
C56 C55 C54 118.1(12) . . ?
C56 C55 H55 120.9 . . ?
C54 C55 H55 120.9 . . ?
C55 C56 C57 120.8(12) . . ?
C55 C56 H56 119.6 . . ?
C57 C56 H56 119.6 . . ?
C58 C57 C56 118.9(12) . . ?
C58 C57 H57 120.6 . . ?
C56 C57 H57 120.6 . . ?
C53 C58 C57 122.4(12) . . ?
C53 C58 H58 118.8 . . ?
C57 C58 H58 118.8 . . ?
C64 C59 C60 120.6(10) . . ?
C64 C59 P6 119.9(8) . . ?
C60 C59 P6 119.3(9) . . ?
C61 C60 C59 117.5(11) . . ?
C61 C60 C65 120.1(10) . . ?
C59 C60 C65 122.3(10) . . ?
C60 C61 C62 121.6(11) . . ?
C60 C61 H61 119.2 . . ?
C62 C61 H61 119.2 . . ?
C61 C62 C63 119.3(12) . . ?
C61 C62 H62 120.4 . . ?
C63 C62 H62 120.4 . . ?
C64 C63 C62 120.9(13) . . ?
C64 C63 H63 119.6 . . ?
C62 C63 H63 119.6 . . ?
C63 C64 C59 120.0(11) . . ?
C63 C64 H64 120.0 . . ?
C59 C64 H64 120.0 . . ?
C60 C65 H65A 109.5 . . ?
C60 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C60 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C67 C66 C71 117.8(7) . . ?
C67 C66 P6 128.3(10) . . ?
C71 C66 P6 113.9(9) . . ?
C66 C67 C68 122.1(8) . . ?
C66 C67 C72 114.2(12) . . ?
C68 C67 C72 123.7(12) . . ?
C69 C68 C67 119.0(8) . . ?
C69 C68 H68 120.5 . . ?
C67 C68 H68 120.5 . . ?
C68 C69 C70 120.0(8) . . ?
C68 C69 H69 120.0 . . ?
C70 C69 H69 120.0 . . ?
C71 C70 C69 120.7(8) . . ?
C71 C70 H70 119.6 . . ?
C69 C70 H70 119.6 . . ?
C70 C71 C66 120.3(8) . . ?
C70 C71 H71 119.8 . . ?
C66 C71 H71 119.8 . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C74 C73 Pt1 176.4(11) . . ?
C73 C74 C75 168.8(14) . . ?
C84 C75 C76 120.5(6) . . ?
C84 C75 C74 117.2(9) . . ?
C76 C75 C74 122.2(9) . . ?
C77 C76 C75 119.3(7) . . ?
C77 C76 H76 120.3 . . ?
C75 C76 H76 120.3 . . ?
C78 C77 C76 120.2(7) . . ?
C78 C77 H77 119.9 . . ?
C76 C77 H77 119.9 . . ?
C79 C78 C77 120.7(7) . . ?
C79 C78 C85 122.8(10) . . ?
C77 C78 C85 116.4(9) . . ?
C80 C79 C78 121.1(8) . . ?
C80 C79 C84 119.8(7) . . ?
C78 C79 C84 119.2(6) . . ?
C79 C80 C81 126.8(6) . . ?
C79 C80 C86 117.1(10) . . ?
C81 C80 C86 115.9(9) . . ?
C80 C81 C82 113.9(6) . . ?
C80 C81 H81 123.0 . . ?
C82 C81 H81 123.0 . . ?
C83 C82 C81 113.4(6) . . ?
C83 C82 H82 123.3 . . ?
C81 C82 H82 123.3 . . ?
C84 C83 C82 135.0(7) . . ?
C84 C83 H83 112.5 . . ?
C82 C83 H83 112.5 . . ?
C83 C84 C75 128.9(7) . . ?
C83 C84 C79 111.1(6) . . ?
C75 C84 C79 120.0(6) . . ?
O1 C85 N1 120.0(13) . . ?
O1 C85 C78 122.6(13) . . ?
N1 C85 C78 117.1(12) . . ?
O2 C86 N1 116.9(10) . . ?
O2 C86 C80 123.8(14) . . ?
N1 C86 C80 119.1(12) . . ?
N1 C87 C88 116.6(10) . . ?
N1 C87 C94 111.1(11) . . ?
C88 C87 C94 121.5(13) . . ?
N1 C87 H87 101.1 . . ?
C88 C87 H87 101.1 . . ?
C94 C87 H87 101.1 . . ?
C93 C88 C89 119.6(7) . . ?
C93 C88 C87 120.5(10) . . ?
C89 C88 C87 119.9(11) . . ?
C88 C89 C90 119.5(8) . . ?
C88 C89 H89 120.2 . . ?
C90 C89 H89 120.2 . . ?
C91 C90 C89 121.1(8) . . ?
C91 C90 H90 119.5 . . ?
C89 C90 H90 119.5 . . ?
C90 C91 C92 119.5(8) . . ?
C90 C91 H91 120.2 . . ?
C92 C91 H91 120.2 . . ?
C93 C92 C91 119.4(8) . . ?
C93 C92 H92 120.3 . . ?
C91 C92 H92 120.3 . . ?
C88 C93 C92 120.9(7) . . ?
C88 C93 H93 119.6 . . ?
C92 C93 H93 119.6 . . ?
C87 C94 H94A 109.5 . . ?
C87 C94 H94B 109.5 . . ?
H94A C94 H94B 109.5 . . ?
C87 C94 H94C 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
C97 C96 Pt1 169.9(12) . . ?
C96 C97 C98 175.5(15) . . ?
C99 C98 C107 124.7(11) . . ?
C99 C98 C97 116.8(11) . . ?
C107 C98 C97 118.5(11) . . ?
C98 C99 C100 115.5(11) . . ?
C98 C99 H99 122.2 . . ?
C100 C99 H99 122.2 . . ?
C101 C100 C99 120.6(12) . . ?
C101 C100 H100 119.7 . . ?
C99 C100 H100 119.7 . . ?
C102 C101 C100 123.1(13) . . ?
C102 C101 C108 119.7(12) . . ?
C100 C101 C108 117.2(12) . . ?
C101 C102 C103 123.0(12) . . ?
C101 C102 C107 117.0(11) . . ?
C103 C102 C107 119.9(12) . . ?
C104 C103 C102 122.7(14) . . ?
C104 C103 C109 117.3(13) . . ?
C102 C103 C109 120.0(13) . . ?
C103 C104 C105 117.3(14) . . ?
C103 C104 H104 121.3 . . ?
C105 C104 H104 121.3 . . ?
C106 C105 C104 119.6(14) . . ?
C106 C105 H105 120.2 . . ?
C104 C105 H105 120.2 . . ?
C107 C106 C105 123.6(13) . . ?
C107 C106 H106 118.2 . . ?
C105 C106 H106 118.2 . . ?
C106 C107 C98 124.2(11) . . ?
C106 C107 C102 116.8(11) . . ?
C98 C107 C102 119.0(10) . . ?
O3 C108 N2 118.1(16) . . ?
O3 C108 C101 127.1(16) . . ?
N2 C108 C101 114.8(14) . . ?
O4 C109 N2 121.8(16) . . ?
O4 C109 C103 121.2(16) . . ?
N2 C109 C103 117.0(15) . . ?
N2 C110 C112 110.9(14) . . ?
N2 C110 C111 112.3(13) . . ?
C112 C110 C111 122.2(14) . . ?
N2 C110 H110 102.9 . . ?
C112 C110 H110 102.9 . . ?
C111 C110 H110 102.9 . . ?
C110 C111 H11D 109.5 . . ?
C110 C111 H11E 109.5 . . ?
H11D C111 H11E 109.5 . . ?
C110 C111 H11F 109.5 . . ?
H11D C111 H11F 109.5 . . ?
H11E C111 H11F 109.5 . . ?
C117 C112 C113 119.6(8) . . ?
C117 C112 C110 122.2(15) . . ?
C113 C112 C110 118.2(15) . . ?
C114 C113 C112 120.1(8) . . ?
C114 C113 H113 119.9 . . ?
C112 C113 H113 119.9 . . ?
C115 C114 C113 120.1(8) . . ?
C115 C114 H114 119.9 . . ?
C113 C114 H114 119.9 . . ?
C114 C115 C116 119.8(8) . . ?
C114 C115 H115 120.1 . . ?
C116 C115 H115 120.1 . . ?
C117 C116 C115 120.1(8) . . ?
C117 C116 H116 120.0 . . ?
C115 C116 H116 120.0 . . ?
C116 C117 C112 120.3(8) . . ?
C116 C117 H117 119.9 . . ?
C112 C117 H117 119.9 . . ?
Cl4 C120 Cl3 111.6(8) . . ?
Cl4 C120 Cl5 113.6(9) . . ?
Cl3 C120 Cl5 109.8(8) . . ?
Cl4 C120 H12A 107.2 . . ?
Cl3 C120 H12A 107.2 . . ?
Cl5 C120 H12A 107.2 . . ?
Cl6 C121 Cl8 113.0(9) . . ?
Cl6 C121 Cl7 110.9(7) . . ?
Cl8 C121 Cl7 109.9(7) . . ?
Cl6 C121 H121 107.6 . . ?
Cl8 C121 H121 107.6 . . ?
Cl7 C121 H121 107.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 P1 C1 P2 85.8(6) . . . . ?
C12 P1 C1 P2 -162.1(5) . . . . ?
Au1 P1 C1 P2 -47.1(6) . . . . ?
C19 P2 C1 P1 -75.0(7) . . . . ?
C2 P2 C1 P1 176.1(5) . . . . ?
Pt1 P2 C1 P1 60.2(6) . . . . ?
C32 P3 C2 P2 166.0(6) . . . . ?
C25 P3 C2 P2 -76.8(6) . . . . ?
Au2 P3 C2 P2 44.8(6) . . . . ?
C19 P2 C2 P3 82.1(6) . . . . ?
C1 P2 C2 P3 -167.3(5) . . . . ?
Pt1 P2 C2 P3 -54.3(6) . . . . ?
C4 P5 C3 P4 165.3(6) . . . . ?
C53 P5 C3 P4 -82.7(7) . . . . ?
Pt1 P5 C3 P4 52.3(7) . . . . ?
C46 P4 C3 P5 77.5(7) . . . . ?
C39 P4 C3 P5 -165.8(5) . . . . ?
Au1 P4 C3 P5 -43.0(7) . . . . ?
C3 P5 C4 P6 -175.3(6) . . . . ?
C53 P5 C4 P6 75.1(6) . . . . ?
Pt1 P5 C4 P6 -59.3(6) . . . . ?
C59 P6 C4 P5 165.7(6) . . . . ?
C66 P6 C4 P5 -73.9(7) . . . . ?
Au2 P6 C4 P5 46.1(7) . . . . ?
C12 P1 C5 C6 135.4(6) . . . . ?
C1 P1 C5 C6 -115.0(6) . . . . ?
Au1 P1 C5 C6 11.5(6) . . . . ?
C12 P1 C5 C10 -47.4(6) . . . . ?
C1 P1 C5 C10 62.1(6) . . . . ?
Au1 P1 C5 C10 -171.4(4) . . . . ?
C10 C5 C6 C7 0.2(4) . . . . ?
P1 C5 C6 C7 177.2(6) . . . . ?
C10 C5 C6 C11 -179.8(5) . . . . ?
P1 C5 C6 C11 -2.7(7) . . . . ?
C5 C6 C7 C8 0.1(4) . . . . ?
C11 C6 C7 C8 -179.9(5) . . . . ?
C6 C7 C8 C9 -0.4(8) . . . . ?
C7 C8 C9 C10 0.4(10) . . . . ?
C8 C9 C10 C5 -0.1(10) . . . . ?
C6 C5 C10 C9 -0.2(8) . . . . ?
P1 C5 C10 C9 -177.5(7) . . . . ?
C5 P1 C12 C17 124.3(9) . . . . ?
C1 P1 C12 C17 14.4(10) . . . . ?
Au1 P1 C12 C17 -103.3(9) . . . . ?
C5 P1 C12 C13 -57.3(9) . . . . ?
C1 P1 C12 C13 -167.2(8) . . . . ?
Au1 P1 C12 C13 75.1(9) . . . . ?
C17 C12 C13 C14 2.6(16) . . . . ?
P1 C12 C13 C14 -175.9(8) . . . . ?
C17 C12 C13 C18 -176.5(11) . . . . ?
P1 C12 C13 C18 5.1(15) . . . . ?
C12 C13 C14 C15 0.1(18) . . . . ?
C18 C13 C14 C15 179.2(12) . . . . ?
C13 C14 C15 C16 -2(2) . . . . ?
C14 C15 C16 C17 2(2) . . . . ?
C13 C12 C17 C16 -3.2(18) . . . . ?
P1 C12 C17 C16 175.2(10) . . . . ?
C15 C16 C17 C12 1.0(19) . . . . ?
C1 P2 C19 C24 -37.6(10) . . . . ?
C2 P2 C19 C24 68.6(10) . . . . ?
Pt1 P2 C19 C24 -162.8(8) . . . . ?
C1 P2 C19 C20 146.0(9) . . . . ?
C2 P2 C19 C20 -107.9(9) . . . . ?
Pt1 P2 C19 C20 20.8(10) . . . . ?
C24 C19 C20 C21 1.0(17) . . . . ?
P2 C19 C20 C21 177.5(9) . . . . ?
C19 C20 C21 C22 3.1(19) . . . . ?
C20 C21 C22 C23 -7(2) . . . . ?
C21 C22 C23 C24 6(2) . . . . ?
C20 C19 C24 C23 -1.7(17) . . . . ?
P2 C19 C24 C23 -178.2(10) . . . . ?
C22 C23 C24 C19 -2(2) . . . . ?
C32 P3 C25 C30 -129.5(6) . . . . ?
C2 P3 C25 C30 118.7(6) . . . . ?
Au2 P3 C25 C30 -3.1(6) . . . . ?
C32 P3 C25 C26 51.8(7) . . . . ?
C2 P3 C25 C26 -60.0(6) . . . . ?
Au2 P3 C25 C26 178.2(4) . . . . ?
C30 C25 C26 C27 -0.2(4) . . . . ?
P3 C25 C26 C27 178.5(7) . . . . ?
C30 C25 C26 C31 179.8(5) . . . . ?
P3 C25 C26 C31 -1.6(7) . . . . ?
C25 C26 C27 C28 -0.1(4) . . . . ?
C31 C26 C27 C28 -180.0(5) . . . . ?
C26 C27 C28 C29 0.1(8) . . . . ?
C27 C28 C29 C30 0.0(10) . . . . ?
C28 C29 C30 C25 -0.2(10) . . . . ?
C26 C25 C30 C29 0.3(8) . . . . ?
P3 C25 C30 C29 -178.5(7) . . . . ?
C25 P3 C32 C37 -118.0(9) . . . . ?
C2 P3 C32 C37 -2.7(10) . . . . ?
Au2 P3 C32 C37 117.0(9) . . . . ?
C25 P3 C32 C33 62.3(11) . . . . ?
C2 P3 C32 C33 177.6(9) . . . . ?
Au2 P3 C32 C33 -62.7(10) . . . . ?
C37 C32 C33 C34 -3.6(17) . . . . ?
P3 C32 C33 C34 176.1(10) . . . . ?
C37 C32 C33 C38 178.6(12) . . . . ?
P3 C32 C33 C38 -1.7(17) . . . . ?
C32 C33 C34 C35 3(2) . . . . ?
C38 C33 C34 C35 -179.4(13) . . . . ?
C33 C34 C35 C36 0(2) . . . . ?
C34 C35 C36 C37 -2(2) . . . . ?
C35 C36 C37 C32 1.0(19) . . . . ?
C33 C32 C37 C36 1.7(17) . . . . ?
P3 C32 C37 C36 -178.0(10) . . . . ?
C46 P4 C39 C44 118.0(6) . . . . ?
C3 P4 C39 C44 3.6(6) . . . . ?
Au1 P4 C39 C44 -117.0(5) . . . . ?
C46 P4 C39 C40 -67.5(6) . . . . ?
C3 P4 C39 C40 178.1(5) . . . . ?
Au1 P4 C39 C40 57.4(5) . . . . ?
C44 C39 C40 C41 0.3(3) . . . . ?
P4 C39 C40 C41 -174.2(6) . . . . ?
C44 C39 C40 C45 -179.3(5) . . . . ?
P4 C39 C40 C45 6.2(7) . . . . ?
C39 C40 C41 C42 0.0(4) . . . . ?
C45 C40 C41 C42 179.7(5) . . . . ?
C40 C41 C42 C43 -0.2(8) . . . . ?
C41 C42 C43 C44 0.1(10) . . . . ?
C40 C39 C44 C43 -0.4(7) . . . . ?
P4 C39 C44 C43 174.0(7) . . . . ?
C42 C43 C44 C39 0.2(10) . . . . ?
C39 P4 C46 C47 -49.4(8) . . . . ?
C3 P4 C46 C47 63.9(7) . . . . ?
Au1 P4 C46 C47 -175.9(5) . . . . ?
C39 P4 C46 C51 133.7(6) . . . . ?
C3 P4 C46 C51 -113.0(6) . . . . ?
Au1 P4 C46 C51 7.2(6) . . . . ?
C51 C46 C47 C48 0.4(4) . . . . ?
P4 C46 C47 C48 -176.4(8) . . . . ?
C51 C46 C47 C52 -179.2(5) . . . . ?
P4 C46 C47 C52 4.0(8) . . . . ?
C46 C47 C48 C49 0.0(4) . . . . ?
C52 C47 C48 C49 179.7(5) . . . . ?
C47 C48 C49 C50 0.0(8) . . . . ?
C48 C49 C50 C51 -0.4(11) . . . . ?
C49 C50 C51 C46 0.8(11) . . . . ?
C47 C46 C51 C50 -0.8(8) . . . . ?
P4 C46 C51 C50 176.3(8) . . . . ?
C3 P5 C53 C58 -76.2(7) . . . . ?
C4 P5 C53 C58 31.7(7) . . . . ?
Pt1 P5 C53 C58 156.4(5) . . . . ?
C3 P5 C53 C54 103.1(6) . . . . ?
C4 P5 C53 C54 -148.9(5) . . . . ?
Pt1 P5 C53 C54 -24.3(6) . . . . ?
C58 C53 C54 C55 -0.4(4) . . . . ?
P5 C53 C54 C55 -179.7(6) . . . . ?
C53 C54 C55 C56 -0.5(4) . . . . ?
C54 C55 C56 C57 1.1(8) . . . . ?
C55 C56 C57 C58 -0.8(10) . . . . ?
C54 C53 C58 C57 0.7(8) . . . . ?
P5 C53 C58 C57 -180.0(7) . . . . ?
C56 C57 C58 C53 -0.1(11) . . . . ?
C4 P6 C59 C64 -15.2(10) . . . . ?
C66 P6 C59 C64 -131.4(9) . . . . ?
Au2 P6 C59 C64 104.3(9) . . . . ?
C4 P6 C59 C60 170.4(8) . . . . ?
C66 P6 C59 C60 54.3(10) . . . . ?
Au2 P6 C59 C60 -70.0(9) . . . . ?
C64 C59 C60 C61 1.0(16) . . . . ?
P6 C59 C60 C61 175.2(8) . . . . ?
C64 C59 C60 C65 -179.4(11) . . . . ?
P6 C59 C60 C65 -5.1(14) . . . . ?
C59 C60 C61 C62 1.1(17) . . . . ?
C65 C60 C61 C62 -178.6(11) . . . . ?
C60 C61 C62 C63 -1.5(18) . . . . ?
C61 C62 C63 C64 -0.3(19) . . . . ?
C62 C63 C64 C59 2.4(18) . . . . ?
C60 C59 C64 C63 -2.7(17) . . . . ?
P6 C59 C64 C63 -177.0(9) . . . . ?
C4 P6 C66 C67 -70.5(8) . . . . ?
C59 P6 C66 C67 45.1(9) . . . . ?
Au2 P6 C66 C67 169.4(6) . . . . ?
C4 P6 C66 C71 109.1(6) . . . . ?
C59 P6 C66 C71 -135.3(6) . . . . ?
Au2 P6 C66 C71 -11.0(6) . . . . ?
C71 C66 C67 C68 -0.1(4) . . . . ?
P6 C66 C67 C68 179.5(8) . . . . ?
C71 C66 C67 C72 -180.0(5) . . . . ?
P6 C66 C67 C72 -0.4(9) . . . . ?
C66 C67 C68 C69 0.1(4) . . . . ?
C72 C67 C68 C69 180.0(5) . . . . ?
C67 C68 C69 C70 -0.4(9) . . . . ?
C68 C69 C70 C71 0.7(12) . . . . ?
C69 C70 C71 C66 -0.7(12) . . . . ?
C67 C66 C71 C70 0.3(9) . . . . ?
P6 C66 C71 C70 -179.3(8) . . . . ?
C73 C74 C75 C84 -147(6) . . . . ?
C73 C74 C75 C76 30(7) . . . . ?
C84 C75 C76 C77 0.1(3) . . . . ?
C74 C75 C76 C77 -177.1(8) . . . . ?
C75 C76 C77 C78 0.1(4) . . . . ?
C76 C77 C78 C79 -0.3(8) . . . . ?
C76 C77 C78 C85 176.9(9) . . . . ?
C77 C78 C79 C80 -179.9(6) . . . . ?
C85 C78 C79 C80 3.1(14) . . . . ?
C77 C78 C79 C84 0.2(10) . . . . ?
C85 C78 C79 C84 -176.7(10) . . . . ?
C78 C79 C80 C81 -180.0(7) . . . . ?
C84 C79 C80 C81 -0.1(11) . . . . ?
C78 C79 C80 C86 4.2(12) . . . . ?
C84 C79 C80 C86 -176.0(9) . . . . ?
C79 C80 C81 C82 0.7(11) . . . . ?
C86 C80 C81 C82 176.6(8) . . . . ?
C80 C81 C82 C83 -1.1(9) . . . . ?
C81 C82 C83 C84 1.3(12) . . . . ?
C82 C83 C84 C75 179.1(7) . . . . ?
C82 C83 C84 C79 -0.7(12) . . . . ?
C76 C75 C84 C83 180.0(6) . . . . ?
C74 C75 C84 C83 -2.6(12) . . . . ?
C76 C75 C84 C79 -0.2(7) . . . . ?
C74 C75 C84 C79 177.2(9) . . . . ?
C80 C79 C84 C83 0.0(10) . . . . ?
C78 C79 C84 C83 179.9(7) . . . . ?
C80 C79 C84 C75 -179.8(6) . . . . ?
C78 C79 C84 C75 0.0(10) . . . . ?
C86 N1 C85 O1 174.7(16) . . . . ?
C87 N1 C85 O1 1(2) . . . . ?
C86 N1 C85 C78 1(2) . . . . ?
C87 N1 C85 C78 -172.2(11) . . . . ?
C79 C78 C85 O1 -179.4(14) . . . . ?
C77 C78 C85 O1 4(2) . . . . ?
C79 C78 C85 N1 -6.2(19) . . . . ?
C77 C78 C85 N1 176.8(11) . . . . ?
C85 N1 C86 O2 -178.4(15) . . . . ?
C87 N1 C86 O2 -4.4(19) . . . . ?
C85 N1 C86 C80 6(2) . . . . ?
C87 N1 C86 C80 179.8(11) . . . . ?
C79 C80 C86 O2 175.8(12) . . . . ?
C81 C80 C86 O2 -0.5(17) . . . . ?
C79 C80 C86 N1 -8.7(15) . . . . ?
C81 C80 C86 N1 175.0(10) . . . . ?
C85 N1 C87 C88 103.5(14) . . . . ?
C86 N1 C87 C88 -70.4(14) . . . . ?
C85 N1 C87 C94 -111.5(17) . . . . ?
C86 N1 C87 C94 74.6(16) . . . . ?
N1 C87 C88 C93 -28.1(11) . . . . ?
C94 C87 C88 C93 -169.2(13) . . . . ?
N1 C87 C88 C89 151.7(11) . . . . ?
C94 C87 C88 C89 10.6(12) . . . . ?
C93 C88 C89 C90 -0.2(5) . . . . ?
C87 C88 C89 C90 -180.0(4) . . . . ?
C88 C89 C90 C91 -0.3(8) . . . . ?
C89 C90 C91 C92 0.5(11) . . . . ?
C90 C91 C92 C93 -0.1(11) . . . . ?
C89 C88 C93 C92 0.6(8) . . . . ?
C87 C88 C93 C92 -179.7(5) . . . . ?
C91 C92 C93 C88 -0.4(10) . . . . ?
C107 C98 C99 C100 -0.2(4) . . . . ?
C97 C98 C99 C100 -177.7(7) . . . . ?
C98 C99 C100 C101 0.1(4) . . . . ?
C99 C100 C101 C102 0.0(8) . . . . ?
C99 C100 C101 C108 180.0(4) . . . . ?
C100 C101 C102 C103 -179.7(6) . . . . ?
C108 C101 C102 C103 0.4(11) . . . . ?
C100 C101 C102 C107 0.0(10) . . . . ?
C108 C101 C102 C107 -179.9(6) . . . . ?
C101 C102 C103 C104 -179.9(7) . . . . ?
C107 C102 C103 C104 0.5(11) . . . . ?
C101 C102 C103 C109 -0.4(11) . . . . ?
C107 C102 C103 C109 179.9(7) . . . . ?
C102 C103 C104 C105 -0.8(11) . . . . ?
C109 C103 C104 C105 179.7(7) . . . . ?
C103 C104 C105 C106 0.4(11) . . . . ?
C104 C105 C106 C107 0.4(11) . . . . ?
C105 C106 C107 C98 -179.9(6) . . . . ?
C105 C106 C107 C102 -0.7(11) . . . . ?
C99 C98 C107 C106 179.4(5) . . . . ?
C97 C98 C107 C106 -3.1(11) . . . . ?
C99 C98 C107 C102 0.2(8) . . . . ?
C97 C98 C107 C102 177.7(8) . . . . ?
C101 C102 C107 C106 -179.4(7) . . . . ?
C103 C102 C107 C106 0.3(11) . . . . ?
C101 C102 C107 C98 -0.1(10) . . . . ?
C103 C102 C107 C98 179.6(6) . . . . ?
C109 N2 C108 O3 179.4(8) . . . . ?
C110 N2 C108 O3 -0.8(14) . . . . ?
C109 N2 C108 C101 -0.3(11) . . . . ?
C110 N2 C108 C101 179.5(11) . . . . ?
C102 C101 C108 O3 -179.6(8) . . . . ?
C100 C101 C108 O3 0.4(11) . . . . ?
C102 C101 C108 N2 0.0(10) . . . . ?
C100 C101 C108 N2 -180.0(6) . . . . ?
C108 N2 C109 O4 -179.8(8) . . . . ?
C110 N2 C109 O4 0.3(14) . . . . ?
C108 N2 C109 C103 0.3(11) . . . . ?
C110 N2 C109 C103 -179.5(10) . . . . ?
C104 C103 C109 O4 -0.3(11) . . . . ?
C102 C103 C109 O4 -179.8(8) . . . . ?
C104 C103 C109 N2 179.6(7) . . . . ?
C102 C103 C109 N2 0.1(10) . . . . ?
C108 N2 C110 C112 98.4(10) . . . . ?
C109 N2 C110 C112 -81.8(10) . . . . ?
C108 N2 C110 C111 -121.0(14) . . . . ?
C109 N2 C110 C111 58.8(17) . . . . ?
N2 C110 C112 C117 -9.1(11) . . . . ?
C111 C110 C112 C117 -145.2(16) . . . . ?
N2 C110 C112 C113 170.8(11) . . . . ?
C111 C110 C112 C113 34.7(15) . . . . ?
C117 C112 C113 C114 -0.2(5) . . . . ?
C110 C112 C113 C114 179.9(4) . . . . ?
C112 C113 C114 C115 0.1(8) . . . . ?
C113 C114 C115 C116 0.2(11) . . . . ?
C114 C115 C116 C117 -0.3(11) . . . . ?
C115 C116 C117 C112 0.2(10) . . . . ?
C113 C112 C117 C116 0.1(8) . . . . ?
C110 C112 C117 C116 180.0(5) . . . . ?

_refine_diff_density_max         6.078
_refine_diff_density_min         -1.654
_refine_diff_density_rms         0.184




