# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_a
_database_code_depnum_ccdc_archive 'CCDC 2326674'
loop_
_audit_author_name
_audit_author_address
'Kunhong Li'
;Henan University
China
;
_audit_update_record             
;
2024-01-19 deposited with the CCDC.	2024-07-25 downloaded from the CCDC.
;
_audit_creation_date             2021-07-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.5(Ge4 Mo40 Na24 O228 Rb4 Ru4), 6(O)'
_chemical_formula_sum            'Ge2 Mo20 Na12 O120 Rb2 Ru2'
_chemical_formula_weight         4632.94
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           58
_space_group_name_H-M_alt        'P n n m'
_space_group_name_Hall           '-P 2 2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x-1/2, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   12.5569(4)
_cell_length_b                   19.0577(5)
_cell_length_c                   24.7605(8)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     5925.3(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7528
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.22
_cell_measurement_theta_min      2.55
_shelx_estimated_absorpt_T_max   0.806
_shelx_estimated_absorpt_T_min   0.584
_exptl_absorpt_coefficient_mu    3.765
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5787
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1252 before and 0.0926 after correction. The Ratio of minimum to maximum transmission is 0.7760. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.597
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             4316
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0951
_diffrn_reflns_av_unetI/netI     0.0623
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            35709
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.095
_diffrn_reflns_theta_max         25.095
_diffrn_reflns_theta_min         2.546
_diffrn_ambient_temperature      150.01
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 VENTURE PHOTON II'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'Helios multilayer optic'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_source            'Incoatc Ius 3.0 '
_diffrn_source_type              Microfocus
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4440
_reflns_number_total             5403
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         1.709
_refine_diff_density_min         -2.162
_refine_diff_density_rms         0.273
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.138
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     369
_refine_ls_number_reflns         5403
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0866
_refine_ls_R_factor_gt           0.0722
_refine_ls_restrained_S_all      1.140
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0286P)²+252.1962P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1602
_refine_ls_wR_factor_ref         0.1677
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(O3W) \\sim Ueq, Uanis(O12W) \\sim Ueq, Uanis(O8W) \\sim Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.53272(14) 1.15514(9) 0.500000 0.0141(4) Uani 1 2 d S T P . .
Mo1 Mo 0.45707(9) 0.84557(6) 0.35824(5) 0.0189(3) Uani 1 1 d . . . . .
Mo2 Mo 0.29594(9) 0.73420(6) 0.42737(5) 0.0208(3) Uani 1 1 d . . . . .
Mo3 Mo 0.60044(10) 0.70491(6) 0.43348(6) 0.0283(3) Uani 1 1 d . . . . .
Mo4 Mo 0.20932(10) 0.81436(7) 0.31598(5) 0.0259(3) Uani 1 1 d . . . . .
Mo5 Mo 0.75472(8) 1.08770(5) 0.42651(4) 0.0132(2) Uani 1 1 d . . . . .
Na1 Na 0.6543(5) 0.3083(4) 0.1204(3) 0.0424(16) Uani 1 1 d . . . . .
Na2 Na 0.6976(5) 0.4142(3) 0.2356(3) 0.0390(15) Uani 1 1 d . . . . .
Na3 Na 0.5057(12) 0.5489(7) 0.3318(5) 0.120(4) Uani 1 1 d . . . . .
O1 O 0.4746(9) 1.0711(6) 0.500000 0.015(3) Uani 1 2 d S T P . .
O1W O 0.5110(10) 0.2850(9) 0.0591(5) 0.066(4) Uani 1 1 d . . . . .
O2 O 0.6560(7) 1.0216(4) 0.4378(3) 0.0144(18) Uani 1 1 d . . . . .
O2W O 0.5719(10) 0.2150(8) 0.1734(6) 0.067(4) Uani 1 1 d . . . . .
O3 O 0.7915(10) 1.1024(6) 0.500000 0.014(3) Uani 1 2 d S T P . .
O3W O 0.7499(7) 0.3808(4) 0.0661(4) 0.026(2) Uani 1 1 d . U . . .
O4 O 0.8066(6) 1.1838(5) 0.4071(4) 0.0180(19) Uani 1 1 d . . . . .
O4W O 0.7692(8) 0.3080(5) 0.1966(5) 0.035(3) Uani 1 1 d . . . . .
O5 O 0.5149(7) 0.9251(5) 0.3829(3) 0.0175(19) Uani 1 1 d . . . . .
O5W O 0.5695(10) 0.3464(6) 0.2872(5) 0.054(3) Uani 1 1 d . . . . .
O6 O 0.6146(6) 1.1621(4) 0.5573(4) 0.0174(19) Uani 1 1 d . . . . .
O6W O 0.5862(8) 0.4152(6) 0.1565(5) 0.043(3) Uani 1 1 d . . . . .
O7 O 0.3504(7) 0.7642(5) 0.3537(4) 0.026(2) Uani 1 1 d . . . . .
O7W O 0.8421(9) 0.4807(6) 0.1974(4) 0.040(3) Uani 1 1 d . . . . .
O8 O 0.3135(7) 0.8932(5) 0.3518(3) 0.0192(19) Uani 1 1 d . . . . .
O8W O 0.8241(16) 0.4060(7) 0.3075(7) 0.086(5) Uani 1 1 d . U . . .
O9 O 0.2512(10) 0.7458(6) 0.500000 0.024(3) Uani 1 2 d S T P . .
O9W O 0.6327(13) 0.5229(8) 0.2709(5) 0.075(5) Uani 1 1 d . . . . .
O10 O 0.8633(7) 1.0397(5) 0.4063(4) 0.021(2) Uani 1 1 d . . . . .
O10W O 0.3788(15) 0.5386(9) 0.3847(8) 0.097(6) Uani 1 1 d . . . . .
O11 O 0.4193(7) 0.6948(5) 0.4415(4) 0.027(2) Uani 1 1 d . . . . .
O11W O 0.423(2) 0.5501(12) 0.500000 0.090(8) Uani 1 2 d S T P . .
O12 O 0.5553(7) 0.7806(5) 0.3880(4) 0.027(2) Uani 1 1 d . . . . .
O12W O 0.805(2) 0.4636(13) 0.3853(12) 0.147(9) Uani 1 1 d . U . . .
O13 O 0.4317(10) 1.2195(6) 0.500000 0.025(3) Uani 1 2 d S T P . .
O14 O 0.5956(10) 0.6517(7) 0.500000 0.030(3) Uani 1 2 d S T P . .
O15 O 0.4970(8) 0.8452(6) 0.2915(4) 0.031(2) Uani 1 1 d . . . . .
O16 O 0.2171(8) 0.6661(5) 0.4098(5) 0.034(3) Uani 1 1 d . . . . .
O17 O 0.2783(8) 0.8152(6) 0.2548(4) 0.033(2) Uani 1 1 d . . . . .
O18 O 0.1098(8) 0.8775(5) 0.3080(4) 0.031(2) Uani 1 1 d . . . . .
O19 O 0.1419(8) 0.7342(5) 0.3139(4) 0.035(3) Uani 1 1 d . . . . .
O20 O 0.5912(9) 0.6343(5) 0.3897(5) 0.042(3) Uani 1 1 d . . . . .
O21 O 0.7345(7) 0.7249(5) 0.4328(5) 0.037(3) Uani 1 1 d . . . . .
Rb1 Rb 0.9550(2) 0.93863(14) 0.500000 0.0461(6) Uani 1 2 d S T P . .
Ru1 Ru 0.500000 1.000000 0.43872(6) 0.0125(3) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 O1 1.761(12) . ?
Ge1 O6 1.757(9) 6_556 ?
Ge1 O6 1.757(9) . ?
Ge1 O13 1.764(13) . ?
Mo1 O5 1.788(8) . ?
Mo1 O6 2.282(9) 5_676 ?
Mo1 O7 2.052(9) . ?
Mo1 O8 2.025(9) . ?
Mo1 O12 1.897(10) . ?
Mo1 O15 1.726(10) . ?
Mo2 O4 2.085(9) 2_675 ?
Mo2 O6 2.305(8) 5_676 ?
Mo2 O7 2.030(10) . ?
Mo2 O9 1.897(4) . ?
Mo2 O11 1.757(9) . ?
Mo2 O16 1.688(9) . ?
Mo3 O11 2.291(9) . ?
Mo3 O12 1.915(10) . ?
Mo3 O13 2.225(8) 5_676 ?
Mo3 O14 1.935(7) . ?
Mo3 O20 1.733(11) . ?
Mo3 O21 1.726(9) . ?
Mo4 O4 2.266(9) 2_675 ?
Mo4 O7 2.219(10) . ?
Mo4 O8 2.181(9) . ?
Mo4 O17 1.745(10) . ?
Mo4 O18 1.746(10) . ?
Mo4 O19 1.748(10) . ?
Mo5 O2 1.788(8) . ?
Mo5 O3 1.898(4) . ?
Mo5 O4 2.002(8) . ?
Mo5 O6 2.295(8) 6_556 ?
Mo5 O8 2.071(9) 2_675 ?
Mo5 O10 1.717(9) . ?
Mo5 Rb1 4.105(2) 5_776 ?
Mo5 Rb1 4.208(3) . ?
Na1 Na2 3.536(10) . ?
Na1 O1W 2.396(15) . ?
Na1 O2W 2.440(15) . ?
Na1 O3W 2.272(12) . ?
Na1 O4W 2.375(13) . ?
Na1 O6W 2.383(13) . ?
Na1 O21 2.492(12) 3_645 ?
Na1 Rb1 4.116(7) 3_645 ?
Na2 Na3 3.562(15) 2_665 ?
Na2 O4W 2.416(12) . ?
Na2 O5W 2.425(13) . ?
Na2 O6W 2.408(14) . ?
Na2 O7W 2.406(12) . ?
Na2 O8W 2.390(18) . ?
Na2 O9W 2.393(14) . ?
Na3 Na3 1.87(3) 2_665 ?
Na3 O5W 2.468(18) 2_665 ?
Na3 O9W 2.68(2) 2_665 ?
Na3 O9W 2.25(2) . ?
Na3 O10W 2.57(2) 2_665 ?
Na3 O10W 2.07(3) . ?
Na3 O20 2.419(17) . ?
O1 Ru1 2.059(8) . ?
O1 Ru1 2.059(8) 5_676 ?
O1W Rb1 3.302(16) 3_645 ?
O2 Ru1 2.003(8) . ?
O3 Rb1 3.279(12) 5_776 ?
O3W Rb1 3.242(10) 3_645 ?
O5 Ru1 1.996(8) . ?
O10 Rb1 3.280(9) 5_776 ?
O10 Rb1 3.227(9) . ?
Rb1 Rb1 2.598(6) 5_776 ?
Ru1 Ru1 3.035(3) 5_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ge1 O13 109.5(6) . . ?
O6 Ge1 O1 108.1(3) . . ?
O6 Ge1 O1 108.1(3) 6_556 . ?
O6 Ge1 O6 107.6(6) 6_556 . ?
O6 Ge1 O13 111.6(3) . . ?
O6 Ge1 O13 111.6(3) 6_556 . ?
O5 Mo1 O6 84.3(3) . 5_676 ?
O5 Mo1 O7 157.5(4) . . ?
O5 Mo1 O8 90.5(4) . . ?
O5 Mo1 O12 99.0(4) . . ?
O7 Mo1 O6 75.2(3) . 5_676 ?
O8 Mo1 O6 75.5(3) . 5_676 ?
O8 Mo1 O7 75.7(4) . . ?
O12 Mo1 O6 81.9(4) . 5_676 ?
O12 Mo1 O7 87.3(4) . . ?
O12 Mo1 O8 154.5(4) . . ?
O15 Mo1 O5 102.2(4) . . ?
O15 Mo1 O6 172.5(4) . 5_676 ?
O15 Mo1 O7 97.7(4) . . ?
O15 Mo1 O8 100.6(4) . . ?
O15 Mo1 O12 100.4(5) . . ?
O4 Mo2 O6 72.4(3) 2_675 5_676 ?
O7 Mo2 O4 77.3(4) . 2_675 ?
O7 Mo2 O6 75.1(3) . 5_676 ?
O9 Mo2 O4 87.6(4) . 2_675 ?
O9 Mo2 O6 83.6(4) . 5_676 ?
O9 Mo2 O7 156.7(4) . . ?
O11 Mo2 O4 155.8(4) . 2_675 ?
O11 Mo2 O6 84.5(4) . 5_676 ?
O11 Mo2 O7 90.1(4) . . ?
O11 Mo2 O9 97.0(5) . . ?
O16 Mo2 O4 98.7(4) . 2_675 ?
O16 Mo2 O6 170.7(4) . 5_676 ?
O16 Mo2 O7 100.5(5) . . ?
O16 Mo2 O9 99.2(5) . . ?
O16 Mo2 O11 103.9(5) . . ?
O12 Mo3 O11 79.7(4) . . ?
O12 Mo3 O13 83.9(4) . 5_676 ?
O12 Mo3 O14 152.3(5) . . ?
O13 Mo3 O11 79.1(4) 5_676 . ?
O14 Mo3 O11 81.4(5) . . ?
O14 Mo3 O13 72.8(4) . 5_676 ?
O20 Mo3 O11 85.5(4) . . ?
O20 Mo3 O12 101.4(5) . . ?
O20 Mo3 O13 162.6(5) . 5_676 ?
O20 Mo3 O14 97.1(5) . . ?
O21 Mo3 O11 170.9(4) . . ?
O21 Mo3 O12 96.7(5) . . ?
O21 Mo3 O13 92.3(5) . 5_676 ?
O21 Mo3 O14 98.9(6) . . ?
O21 Mo3 O20 103.4(5) . . ?
O7 Mo4 O4 70.0(3) . 2_675 ?
O8 Mo4 O4 68.7(3) . 2_675 ?
O8 Mo4 O7 69.3(3) . . ?
O17 Mo4 O4 155.3(4) . 2_675 ?
O17 Mo4 O7 88.5(4) . . ?
O17 Mo4 O8 92.8(4) . . ?
O17 Mo4 O18 104.5(5) . . ?
O17 Mo4 O19 102.9(5) . . ?
O18 Mo4 O4 92.3(4) . 2_675 ?
O18 Mo4 O7 156.3(4) . . ?
O18 Mo4 O8 90.0(4) . . ?
O18 Mo4 O19 104.6(5) . . ?
O19 Mo4 O4 90.0(4) . 2_675 ?
O19 Mo4 O7 91.3(4) . . ?
O19 Mo4 O8 154.8(4) . . ?
O2 Mo5 O3 97.1(4) . . ?
O2 Mo5 O4 155.1(4) . . ?
O2 Mo5 O6 82.9(3) . 6_556 ?
O2 Mo5 O8 88.6(4) . 2_675 ?
O2 Mo5 Rb1 82.6(3) . . ?
O2 Mo5 Rb1 117.4(3) . 5_776 ?
O3 Mo5 O4 90.9(4) . . ?
O3 Mo5 O6 85.8(4) . 6_556 ?
O3 Mo5 O8 158.6(4) . 2_675 ?
O3 Mo5 Rb1 62.6(3) . . ?
O3 Mo5 Rb1 51.5(4) . 5_776 ?
O4 Mo5 O6 74.1(3) . 6_556 ?
O4 Mo5 O8 76.1(4) . 2_675 ?
O4 Mo5 Rb1 121.8(2) . . ?
O4 Mo5 Rb1 85.9(2) . 5_776 ?
O6 Mo5 Rb1 132.7(2) 6_556 5_776 ?
O6 Mo5 Rb1 143.1(2) 6_556 . ?
O8 Mo5 O6 74.4(3) 2_675 6_556 ?
O8 Mo5 Rb1 141.7(2) 2_675 5_776 ?
O8 Mo5 Rb1 138.8(2) 2_675 . ?
O10 Mo5 O2 102.7(4) . . ?
O10 Mo5 O3 99.5(5) . . ?
O10 Mo5 O4 99.2(4) . . ?
O10 Mo5 O6 171.6(4) . 6_556 ?
O10 Mo5 O8 99.3(4) . 2_675 ?
O10 Mo5 Rb1 44.9(3) . . ?
O10 Mo5 Rb1 50.1(3) . 5_776 ?
Rb1 Mo5 Rb1 36.40(7) 5_776 . ?
Na2 Na1 Rb1 106.92(19) . 3_645 ?
O1W Na1 Na2 137.1(4) . . ?
O1W Na1 O2W 83.5(5) . . ?
O1W Na1 O21 88.1(5) . 3_645 ?
O1W Na1 Rb1 53.3(4) . 3_645 ?
O2W Na1 Na2 92.7(4) . . ?
O2W Na1 O21 93.3(5) . 3_645 ?
O2W Na1 Rb1 133.4(4) . 3_645 ?
O3W Na1 Na2 92.8(3) . . ?
O3W Na1 O1W 97.7(5) . . ?
O3W Na1 O2W 170.4(5) . . ?
O3W Na1 O4W 98.7(4) . . ?
O3W Na1 O6W 83.8(4) . . ?
O3W Na1 O21 77.2(4) . 3_645 ?
O3W Na1 Rb1 51.7(3) . 3_645 ?
O4W Na1 Na2 42.9(3) . . ?
O4W Na1 O1W 163.5(5) . . ?
O4W Na1 O2W 80.1(4) . . ?
O4W Na1 O6W 85.6(5) . . ?
O4W Na1 O21 94.5(4) . 3_645 ?
O4W Na1 Rb1 141.2(4) . 3_645 ?
O6W Na1 Na2 42.7(3) . . ?
O6W Na1 O1W 97.2(5) . . ?
O6W Na1 O2W 105.6(5) . . ?
O6W Na1 O21 160.8(5) . 3_645 ?
O6W Na1 Rb1 68.6(3) . 3_645 ?
O21 Na1 Na2 134.8(4) 3_645 . ?
O21 Na1 Rb1 100.8(3) 3_645 3_645 ?
Na1 Na2 Na3 122.8(3) . 2_665 ?
O4W Na2 Na1 42.0(3) . . ?
O4W Na2 Na3 134.4(4) . 2_665 ?
O4W Na2 O5W 90.6(4) . . ?
O5W Na2 Na1 91.1(4) . . ?
O5W Na2 Na3 43.8(4) . 2_665 ?
O6W Na2 Na1 42.2(3) . . ?
O6W Na2 Na3 97.2(4) . 2_665 ?
O6W Na2 O4W 84.1(4) . . ?
O6W Na2 O5W 92.7(5) . . ?
O7W Na2 Na1 95.7(4) . . ?
O7W Na2 Na3 134.3(4) . 2_665 ?
O7W Na2 O4W 90.2(4) . . ?
O7W Na2 O5W 170.7(5) . . ?
O7W Na2 O6W 96.6(4) . . ?
O8W Na2 Na1 131.7(5) . . ?
O8W Na2 Na3 89.5(6) . 2_665 ?
O8W Na2 O4W 89.8(5) . . ?
O8W Na2 O5W 90.8(6) . . ?
O8W Na2 O6W 173.0(6) . . ?
O8W Na2 O7W 80.0(6) . . ?
O8W Na2 O9W 90.6(6) . . ?
O9W Na2 Na1 137.4(4) . . ?
O9W Na2 Na3 48.7(5) . 2_665 ?
O9W Na2 O4W 176.9(5) . . ?
O9W Na2 O5W 92.5(5) . . ?
O9W Na2 O6W 95.3(5) . . ?
O9W Na2 O7W 86.8(5) . . ?
Na3 Na3 Na2 98.1(7) 2_665 2_665 ?
Na3 Na3 O5W 140.9(9) 2_665 2_665 ?
Na3 Na3 O9W 56.0(7) 2_665 2_665 ?
Na3 Na3 O9W 80.5(8) 2_665 . ?
Na3 Na3 O10W 81.1(9) 2_665 . ?
Na3 Na3 O10W 52.9(8) 2_665 2_665 ?
Na3 Na3 O20 134.8(8) 2_665 . ?
O5W Na3 Na2 42.8(4) 2_665 2_665 ?
O5W Na3 O9W 85.0(6) 2_665 2_665 ?
O5W Na3 O10W 165.7(8) 2_665 2_665 ?
O9W Na3 Na2 42.2(3) 2_665 2_665 ?
O9W Na3 Na2 95.9(6) . 2_665 ?
O9W Na3 O5W 98.6(7) . 2_665 ?
O9W Na3 O9W 88.3(8) . 2_665 ?
O9W Na3 O10W 78.4(7) . 2_665 ?
O9W Na3 O20 103.3(8) . . ?
O10W Na3 Na2 83.7(7) . 2_665 ?
O10W Na3 Na2 150.9(7) 2_665 2_665 ?
O10W Na3 O5W 93.7(8) . 2_665 ?
O10W Na3 O9W 78.9(7) . 2_665 ?
O10W Na3 O9W 108.7(7) 2_665 2_665 ?
O10W Na3 O9W 161.4(9) . . ?
O10W Na3 O10W 92.9(9) . 2_665 ?
O10W Na3 O20 91.8(7) . . ?
O20 Na3 Na2 125.5(6) . 2_665 ?
O20 Na3 O5W 83.8(6) . 2_665 ?
O20 Na3 O9W 164.9(7) . 2_665 ?
O20 Na3 O10W 83.4(7) . 2_665 ?
Ge1 O1 Ru1 122.3(4) . 5_676 ?
Ge1 O1 Ru1 122.3(4) . . ?
Ru1 O1 Ru1 95.0(5) 5_676 . ?
Na1 O1W Rb1 91.1(5) . 3_645 ?
Mo5 O2 Ru1 145.6(5) . . ?
Mo5 O3 Mo5 146.9(7) 6_556 . ?
Mo5 O3 Rb1 101.6(4) . 5_776 ?
Mo5 O3 Rb1 101.6(4) 6_556 5_776 ?
Na1 O3W Rb1 95.0(3) . 3_645 ?
Mo2 O4 Mo4 100.0(4) 2_675 2_675 ?
Mo5 O4 Mo2 115.3(4) . 2_675 ?
Mo5 O4 Mo4 102.9(4) . 2_675 ?
Na1 O4W Na2 95.1(4) . . ?
Mo1 O5 Ru1 143.6(5) . . ?
Na2 O5W Na3 93.4(5) . 2_665 ?
Ge1 O6 Mo1 120.3(4) . 5_676 ?
Ge1 O6 Mo2 118.9(4) . 5_676 ?
Ge1 O6 Mo5 122.9(4) . 6_556 ?
Mo1 O6 Mo2 95.5(3) 5_676 5_676 ?
Mo1 O6 Mo5 95.9(3) 5_676 6_556 ?
Mo5 O6 Mo2 97.3(3) 6_556 5_676 ?
Na1 O6W Na2 95.1(4) . . ?
Mo1 O7 Mo4 102.6(4) . . ?
Mo2 O7 Mo1 112.5(5) . . ?
Mo2 O7 Mo4 103.3(4) . . ?
Mo1 O8 Mo4 104.9(4) . . ?
Mo1 O8 Mo5 112.1(4) . 2_675 ?
Mo5 O8 Mo4 103.6(4) 2_675 . ?
Mo2 O9 Mo2 142.9(7) . 6_556 ?
Na2 O9W Na3 89.1(6) . 2_665 ?
Na3 O9W Na2 132.6(8) . . ?
Na3 O9W Na3 43.5(7) . 2_665 ?
Mo5 O10 Rb1 113.1(4) . . ?
Mo5 O10 Rb1 106.2(4) . 5_776 ?
Rb1 O10 Rb1 47.06(16) . 5_776 ?
Na3 O10W Na3 46.0(7) . 2_665 ?
Mo2 O11 Mo3 145.3(5) . . ?
Mo1 O12 Mo3 155.8(6) . . ?
Ge1 O13 Mo3 125.5(4) . 5_676 ?
Ge1 O13 Mo3 125.5(4) . 2_675 ?
Mo3 O13 Mo3 95.5(5) 5_676 2_675 ?
Mo3 O14 Mo3 116.7(6) . 6_556 ?
Mo3 O20 Na3 157.4(7) . . ?
Mo3 O21 Na1 133.8(6) . 3_655 ?
Mo5 Rb1 Mo5 52.63(4) 5_776 2_775 ?
O1W Rb1 Mo5 88.5(2) 8_766 2_775 ?
O1W Rb1 Mo5 65.2(2) 3_655 2_775 ?
O1W Rb1 Mo5 65.2(2) 8_766 5_776 ?
O1W Rb1 Mo5 88.5(2) 3_655 5_776 ?
O1W Rb1 O1W 52.7(5) 3_655 8_766 ?
O3 Rb1 Mo5 26.94(5) 5_776 2_775 ?
O3 Rb1 Mo5 26.94(5) 5_776 5_776 ?
O3 Rb1 O1W 70.3(3) 5_776 8_766 ?
O3 Rb1 O1W 70.3(3) 5_776 3_655 ?
O3 Rb1 O10 49.80(18) 5_776 2_775 ?
O3 Rb1 O10 49.80(18) 5_776 5_776 ?
O3W Rb1 Mo5 152.48(16) 3_655 5_776 ?
O3W Rb1 Mo5 116.07(18) 8_766 5_776 ?
O3W Rb1 Mo5 116.07(18) 3_655 2_775 ?
O3W Rb1 Mo5 152.48(16) 8_766 2_775 ?
O3W Rb1 O1W 65.0(3) 3_655 3_655 ?
O3W Rb1 O1W 65.0(3) 8_766 8_766 ?
O3W Rb1 O1W 91.4(3) 8_766 3_655 ?
O3W Rb1 O1W 91.4(3) 3_655 8_766 ?
O3W Rb1 O3 133.6(2) 3_655 5_776 ?
O3W Rb1 O3 133.6(2) 8_766 5_776 ?
O3W Rb1 O3W 60.6(4) 3_655 8_766 ?
O3W Rb1 O10 103.8(2) 3_655 2_775 ?
O3W Rb1 O10 162.1(2) 8_766 2_775 ?
O3W Rb1 O10 162.1(2) 3_655 5_776 ?
O3W Rb1 O10 103.8(2) 8_766 5_776 ?
O10 Rb1 Mo5 73.21(16) 5_776 2_775 ?
O10 Rb1 Mo5 23.68(16) 2_775 2_775 ?
O10 Rb1 Mo5 94.07(16) 6_556 5_776 ?
O10 Rb1 Mo5 94.07(16) . 2_775 ?
O10 Rb1 Mo5 73.21(16) 2_775 5_776 ?
O10 Rb1 Mo5 135.10(17) . 5_776 ?
O10 Rb1 Mo5 135.10(17) 6_556 2_775 ?
O10 Rb1 Mo5 23.68(16) 5_776 5_776 ?
O10 Rb1 O1W 73.0(3) 2_775 3_655 ?
O10 Rb1 O1W 104.9(3) 6_556 8_766 ?
O10 Rb1 O1W 73.0(3) 5_776 8_766 ?
O10 Rb1 O1W 109.6(3) 2_775 8_766 ?
O10 Rb1 O1W 153.4(3) 6_556 3_655 ?
O10 Rb1 O1W 104.9(3) . 3_655 ?
O10 Rb1 O1W 153.4(3) . 8_766 ?
O10 Rb1 O1W 109.6(3) 5_776 3_655 ?
O10 Rb1 O3 119.3(2) . 5_776 ?
O10 Rb1 O3 119.3(2) 6_556 5_776 ?
O10 Rb1 O3W 106.4(2) . 8_766 ?
O10 Rb1 O3W 106.4(2) 6_556 3_655 ?
O10 Rb1 O3W 63.7(2) . 3_655 ?
O10 Rb1 O3W 63.7(2) 6_556 8_766 ?
O10 Rb1 O10 91.9(3) . 6_556 ?
O10 Rb1 O10 70.4(3) . 2_775 ?
O10 Rb1 O10 70.4(3) 6_556 5_776 ?
O10 Rb1 O10 132.94(16) . 5_776 ?
O10 Rb1 O10 132.94(16) 6_556 2_775 ?
O10 Rb1 O10 90.0(3) 5_776 2_775 ?
Rb1 Rb1 Mo5 73.95(10) 5_776 2_775 ?
Rb1 Rb1 Mo5 73.95(10) 5_776 5_776 ?
Rb1 Rb1 O1W 137.9(3) 5_776 3_655 ?
Rb1 Rb1 O1W 137.9(3) 5_776 8_766 ?
Rb1 Rb1 O3 78.0(2) 5_776 5_776 ?
Rb1 Rb1 O3W 130.65(18) 5_776 3_655 ?
Rb1 Rb1 O3W 130.65(18) 5_776 8_766 ?
Rb1 Rb1 O10 65.40(18) 5_776 5_776 ?
Rb1 Rb1 O10 67.54(17) 5_776 . ?
Rb1 Rb1 O10 65.40(18) 5_776 2_775 ?
Rb1 Rb1 O10 67.54(17) 5_776 6_556 ?
O1 Ru1 O1 85.0(5) . 5_676 ?
O1 Ru1 Ru1 42.5(2) 5_676 5_676 ?
O1 Ru1 Ru1 42.5(2) . 5_676 ?
O2 Ru1 O1 89.6(4) . 5_676 ?
O2 Ru1 O1 89.6(4) 2_675 . ?
O2 Ru1 O1 91.4(4) . . ?
O2 Ru1 O1 91.4(4) 2_675 5_676 ?
O2 Ru1 O2 178.7(5) . 2_675 ?
O2 Ru1 Ru1 90.7(2) 2_675 5_676 ?
O2 Ru1 Ru1 90.7(2) . 5_676 ?
O5 Ru1 O1 174.6(4) . . ?
O5 Ru1 O1 174.6(4) 2_675 5_676 ?
O5 Ru1 O1 91.5(3) . 5_676 ?
O5 Ru1 O1 91.5(3) 2_675 . ?
O5 Ru1 O2 86.3(3) . 2_675 ?
O5 Ru1 O2 92.7(3) . . ?
O5 Ru1 O2 86.3(3) 2_675 . ?
O5 Ru1 O2 92.7(3) 2_675 2_675 ?
O5 Ru1 O5 92.3(5) 2_675 . ?
O5 Ru1 Ru1 133.8(3) . 5_676 ?
O5 Ru1 Ru1 133.8(3) 2_675 5_676 ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 0.500 0.500 391.9 126.8 ?
2 0.500 0.000 0.000 391.9 126.8 ?

_olex2_submission_special_instructions 'No special instructions were received'
