# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2329237'
loop_
_audit_author_name
_audit_author_address
'Sheng-Ping Guo'
;Yangzhou University
China
;
_audit_update_record             
;
2024-06-28 deposited with the CCDC.	2024-07-04 downloaded from the CCDC.
;
_audit_creation_date             2024-06-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Eu18 Ge9 O5 S31'
_chemical_formula_sum            'Eu18 Ge9 O5 S31'
_chemical_formula_weight         4462.45
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_H-M_alt        'R 3'
_space_group_name_Hall           'R 3'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'

_cell_length_a                   16.8496(4)
_cell_length_b                   16.8496(4)
_cell_length_c                   17.9927(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     4423.9(3)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    9948
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      28.33
_cell_measurement_theta_min      2.41
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    24.431
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.4585
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1184 before and 0.0458 after correction.
The Ratio of minimum to maximum transmission is 0.6149.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    5.025
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5874
_exptl_crystal_size_max          0.02
_exptl_crystal_size_mid          0.015
_exptl_crystal_size_min          0.01
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_av_unetI/netI     0.0363
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            15383
_diffrn_reflns_point_group_measured_fraction_full 0.911
_diffrn_reflns_point_group_measured_fraction_max 0.884
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.353
_diffrn_reflns_theta_min         2.418
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.773
_reflns_Friedel_fraction_full    0.823
_reflns_Friedel_fraction_max     0.771
_reflns_number_gt                4208
_reflns_number_total             4356
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.844
_refine_diff_density_min         -0.895
_refine_diff_density_rms         0.195
_refine_ls_abs_structure_details 
;
 Flack x determined using 1734 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.001(9)
_refine_ls_extinction_coef       0.000081(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   0.974
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     191
_refine_ls_number_reflns         4356
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0207
_refine_ls_R_factor_gt           0.0189
_refine_ls_restrained_S_all      0.974
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0310
_refine_ls_wR_factor_ref         0.0314
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.13413(3) 0.82392(3) 0.67107(2) 0.01168(9) Uani 1 1 d . . . . .
Eu2 Eu 0.32542(3) 0.80553(3) 0.80514(2) 0.01218(9) Uani 1 1 d . . . . .
Eu3 Eu 0.12831(3) 0.99023(3) 0.48547(2) 0.01029(9) Uani 1 1 d . . . . .
Eu4 Eu -0.14672(3) 0.67285(3) 0.66712(2) 0.01132(9) Uani 1 1 d . . . . .
Eu5 Eu 0.17846(3) 0.66791(3) 0.52348(2) 0.01200(9) Uani 1 1 d . . . . .
Eu6 Eu 0.17730(3) 0.83257(3) 0.99938(2) 0.01091(9) Uani 1 1 d . . . . .
Ge1 Ge 0.000000 1.000000 0.33595(7) 0.0071(3) Uani 1 3 d S T P . .
Ge2 Ge 0.333333 0.666667 0.32439(7) 0.0079(3) Uani 1 3 d S T P . .
Ge3 Ge 0.32636(5) 0.98281(5) 0.54163(4) 0.00678(17) Uani 1 1 d . . . . .
Ge4 Ge 0.00041(5) 0.65401(5) 0.79725(4) 0.00617(17) Uani 1 1 d . . . . .
Ge5 Ge 0.333333 0.666667 0.67204(8) 0.0069(3) Uani 1 3 d S T P . .
S1 S 0.333333 0.666667 0.44694(17) 0.0134(7) Uani 1 3 d S T P . .
S2 S 0.33128(12) 0.78995(12) 0.63308(10) 0.0112(4) Uani 1 1 d . . . . .
S3 S 0.31674(12) 0.99341(12) 0.66403(9) 0.0100(4) Uani 1 1 d . . . . .
S4 S -0.12610(12) 0.53271(13) 0.75739(10) 0.0091(4) Uani 1 1 d . . . . .
S5 S 0.19937(12) 0.88038(13) 0.83858(10) 0.0095(4) Uani 1 1 d . . . . .
S6 S 0.12537(12) 0.65817(12) 0.75215(10) 0.0099(4) Uani 1 1 d . . . . .
S7 S 0.32950(13) 1.10841(12) 0.50155(9) 0.0096(4) Uani 1 1 d . . . . .
S8 S 0.34146(13) 0.79799(13) 0.97135(11) 0.0125(4) Uani 1 1 d . . . . .
S9 S 0.20173(12) 0.86041(12) 0.50417(10) 0.0103(4) Uani 1 1 d . . . . .
S10 S 0.00995(13) 0.67866(13) 0.91833(10) 0.0090(4) Uani 1 1 d . . . . .
S11 S -0.00686(13) 0.87573(12) 0.61023(10) 0.0117(4) Uani 1 1 d . . . . .
O1 O 0.000000 1.000000 0.4354(4) 0.0087(18) Uani 1 3 d S T P . .
O2 O 0.333333 0.666667 0.7724(4) 0.0066(17) Uani 1 3 d S T P . .
O3 O -0.0019(3) 0.7482(3) 0.7535(2) 0.0083(10) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu3 4.3920(6) . ?
Eu1 Eu5 4.1538(6) 5_565 ?
Eu1 S3 2.9752(18) . ?
Eu1 S5 3.1863(18) . ?
Eu1 S6 3.0883(19) . ?
Eu1 S9 3.1611(19) . ?
Eu1 S10 3.0031(19) 9_454 ?
Eu1 S11 3.1110(19) . ?
Eu1 O3 2.482(4) . ?
Eu2 Eu2 4.1729(7) 3_565 ?
Eu2 Eu2 4.1729(7) 2_665 ?
Eu2 Eu6 4.0957(6) 8_664 ?
Eu2 Eu6 4.4485(6) . ?
Eu2 Ge3 3.6378(9) 6_465 ?
Eu2 S2 3.1127(18) . ?
Eu2 S5 3.0237(18) . ?
Eu2 S6 3.1729(19) . ?
Eu2 S6 3.2258(19) 3_565 ?
Eu2 S7 2.9640(19) 6_465 ?
Eu2 S8 3.011(2) . ?
Eu2 O2 2.4802(18) . ?
Eu3 Eu3 3.8949(6) 3_465 ?
Eu3 Eu3 3.8949(6) 2_675 ?
Eu3 Eu4 4.2112(6) 9_454 ?
Eu3 Eu6 4.1096(6) 6_464 ?
Eu3 S4 3.1498(18) 9_454 ?
Eu3 S4 3.2744(18) 7_554 ?
Eu3 S7 2.9649(19) . ?
Eu3 S8 3.254(2) 6_464 ?
Eu3 S9 3.0223(19) . ?
Eu3 S11 3.1276(19) 2_675 ?
Eu3 S11 3.0910(19) . ?
Eu3 O1 2.423(3) . ?
Eu4 Eu5 4.3473(6) 5_565 ?
Eu4 S3 3.0679(18) 3_465 ?
Eu4 S4 3.0256(18) . ?
Eu4 S7 3.2246(17) 3_465 ?
Eu4 S8 3.3280(19) 7_444 ?
Eu4 S9 3.1704(19) 5_565 ?
Eu4 S10 3.0367(19) 9_454 ?
Eu4 S11 3.1986(19) . ?
Eu4 O3 2.623(5) . ?
Eu5 Eu6 4.0298(6) 9_454 ?
Eu5 Ge4 3.3871(9) 9_454 ?
Eu5 S1 2.9600(15) . ?
Eu5 S2 3.1395(19) 2_665 ?
Eu5 S2 3.0745(19) . ?
Eu5 S5 3.1358(18) 9_454 ?
Eu5 S9 3.0860(19) . ?
Eu5 S10 3.0880(19) 9_454 ?
Eu5 O3 2.457(5) 9_454 ?
Eu6 Ge3 3.5303(9) 6_465 ?
Eu6 Ge4 3.5716(9) 5_565 ?
Eu6 S2 3.4314(19) 6_465 ?
Eu6 S3 2.9610(19) 6_465 ?
Eu6 S4 2.8952(18) 5_565 ?
Eu6 S5 2.9763(18) . ?
Eu6 S6 3.0407(18) 5_565 ?
Eu6 S7 3.1607(17) 8_665 ?
Eu6 S8 3.1397(19) . ?
Eu6 S10 3.0807(19) . ?
Ge1 Ge1 0.0000 3_465 ?
Ge1 Ge1 0.0000 2_675 ?
Ge1 S8 2.2200(19) 5_564 ?
Ge1 S8 2.2200(18) 4_454 ?
Ge1 S8 2.2199(19) 6_464 ?
Ge1 O1 1.789(7) . ?
Ge2 S1 2.205(3) . ?
Ge2 S11 2.2104(19) 9_454 ?
Ge2 S11 2.2106(19) 7_544 ?
Ge2 S11 2.2105(19) 8_664 ?
Ge3 S3 2.2219(19) . ?
Ge3 S5 2.2089(19) 8_664 ?
Ge3 S7 2.2112(19) . ?
Ge3 S9 2.1878(19) . ?
Ge4 S4 2.209(2) . ?
Ge4 S6 2.225(2) . ?
Ge4 S10 2.2086(19) . ?
Ge4 O3 1.789(5) . ?
Ge5 Ge5 0.0000 3_565 ?
Ge5 Ge5 0.0000 2_665 ?
Ge5 S2 2.2090(19) 3_565 ?
Ge5 S2 2.2089(19) . ?
Ge5 S2 2.2089(19) 2_665 ?
Ge5 O2 1.806(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag

Eu5 Eu1 Eu3 111.822(12) 5_565 . ?
S3 Eu1 Eu3 72.39(4) . . ?
S3 Eu1 Eu5 107.62(4) . 5_565 ?
S3 Eu1 S5 73.55(5) . . ?
S3 Eu1 S6 116.55(5) . . ?
S3 Eu1 S9 70.96(5) . . ?
S3 Eu1 S10 143.53(5) . 9_454 ?
S3 Eu1 S11 106.50(5) . . ?
S5 Eu1 Eu3 130.03(4) . . ?
S5 Eu1 Eu5 48.40(3) . 5_565 ?
S6 Eu1 Eu3 158.43(3) . . ?
S6 Eu1 Eu5 85.02(3) . 5_565 ?
S6 Eu1 S5 71.13(5) . . ?
S6 Eu1 S9 118.32(5) . . ?
S6 Eu1 S11 136.22(5) . . ?
S9 Eu1 Eu3 43.48(3) . . ?
S9 Eu1 Eu5 155.18(4) . 5_565 ?
S9 Eu1 S5 143.47(5) . . ?
S10 Eu1 Eu3 87.93(4) 9_454 . ?
S10 Eu1 Eu5 108.15(4) 9_454 5_565 ?
S10 Eu1 S5 138.69(5) 9_454 . ?
S10 Eu1 S6 73.58(5) 9_454 . ?
S10 Eu1 S9 73.65(5) 9_454 . ?
S10 Eu1 S11 76.71(5) 9_454 . ?
S11 Eu1 Eu3 44.73(4) . . ?
S11 Eu1 Eu5 74.52(4) . 5_565 ?
S11 Eu1 S5 116.54(5) . . ?
S11 Eu1 S9 82.10(5) . . ?
O3 Eu1 Eu3 118.22(11) . . ?
O3 Eu1 Eu5 32.56(11) . 5_565 ?
O3 Eu1 S3 139.91(11) . . ?
O3 Eu1 S5 71.35(11) . . ?
O3 Eu1 S6 68.81(11) . . ?
O3 Eu1 S9 144.90(11) . . ?
O3 Eu1 S10 76.42(11) . 9_454 ?
O3 Eu1 S11 73.49(11) . . ?
Eu2 Eu2 Eu2 60.0 3_565 2_665 ?
Eu2 Eu2 Eu6 125.798(7) 3_565 . ?
Eu2 Eu2 Eu6 96.774(11) 2_665 . ?
Eu6 Eu2 Eu2 135.913(9) 8_664 2_665 ?
Eu6 Eu2 Eu2 94.071(13) 8_664 3_565 ?
Eu6 Eu2 Eu6 126.684(12) 8_664 . ?
Ge3 Eu2 Eu2 146.100(17) 6_465 2_665 ?
Ge3 Eu2 Eu2 142.586(18) 6_465 3_565 ?
Ge3 Eu2 Eu6 50.563(14) 6_465 . ?
Ge3 Eu2 Eu6 76.147(16) 6_465 8_664 ?
S2 Eu2 Eu2 85.61(3) . 2_665 ?
S2 Eu2 Eu2 84.31(3) . 3_565 ?
S2 Eu2 Eu6 146.42(4) . . ?
S2 Eu2 Eu6 54.82(3) . 8_664 ?
S2 Eu2 Ge3 115.97(4) . 6_465 ?
S2 Eu2 S6 72.61(5) . . ?
S2 Eu2 S6 70.25(5) . 3_565 ?
S5 Eu2 Eu2 113.86(4) . 2_665 ?
S5 Eu2 Eu2 167.23(4) . 3_565 ?
S5 Eu2 Eu6 41.74(3) . . ?
S5 Eu2 Eu6 97.36(4) . 8_664 ?
S5 Eu2 Ge3 37.31(4) . 6_465 ?
S5 Eu2 S2 106.96(5) . . ?
S5 Eu2 S6 72.14(5) . . ?
S5 Eu2 S6 140.20(5) . 3_565 ?
S6 Eu2 Eu2 105.60(3) 3_565 2_665 ?
S6 Eu2 Eu2 106.63(3) . 3_565 ?
S6 Eu2 Eu2 49.85(3) . 2_665 ?
S6 Eu2 Eu2 48.75(3) 3_565 3_565 ?
S6 Eu2 Eu6 139.22(3) 3_565 . ?
S6 Eu2 Eu6 83.42(3) . . ?
S6 Eu2 Eu6 120.89(3) . 8_664 ?
S6 Eu2 Eu6 47.25(3) 3_565 8_664 ?
S6 Eu2 Ge3 106.28(4) 3_565 6_465 ?
S6 Eu2 Ge3 109.34(4) . 6_465 ?
S6 Eu2 S6 136.79(6) . 3_565 ?
S7 Eu2 Eu2 165.80(4) 6_465 2_665 ?
S7 Eu2 Eu2 109.94(4) 6_465 3_565 ?
S7 Eu2 Eu6 81.06(3) 6_465 . ?
S7 Eu2 Eu6 50.11(3) 6_465 8_664 ?
S7 Eu2 Ge3 37.41(4) 6_465 6_465 ?
S7 Eu2 S2 104.01(5) 6_465 . ?
S7 Eu2 S5 73.75(5) 6_465 . ?
S7 Eu2 S6 142.75(5) 6_465 . ?
S7 Eu2 S6 68.93(5) 6_465 3_565 ?
S7 Eu2 S8 80.97(5) 6_465 . ?
S8 Eu2 Eu2 87.60(4) . 2_665 ?
S8 Eu2 Eu2 83.38(4) . 3_565 ?
S8 Eu2 Eu6 44.83(4) . . ?
S8 Eu2 Eu6 126.91(4) . 8_664 ?
S8 Eu2 Ge3 74.89(4) . 6_465 ?
S8 Eu2 S2 167.67(5) . . ?
S8 Eu2 S5 85.21(5) . . ?
S8 Eu2 S6 110.37(5) . . ?
S8 Eu2 S6 101.82(5) . 3_565 ?
O2 Eu2 Eu2 32.73(7) . 2_665 ?
O2 Eu2 Eu2 32.73(7) . 3_565 ?
O2 Eu2 Eu6 107.31(13) . 8_664 ?
O2 Eu2 Eu6 125.51(14) . . ?
O2 Eu2 Ge3 173.21(16) . 6_465 ?
O2 Eu2 S2 70.44(17) . . ?
O2 Eu2 S5 145.19(4) . . ?
O2 Eu2 S6 73.19(5) . 3_565 ?
O2 Eu2 S6 74.19(6) . . ?
O2 Eu2 S7 141.06(4) . 6_465 ?
O2 Eu2 S8 98.50(17) . . ?
Eu3 Eu3 Eu3 60.0 2_675 3_465 ?
Eu3 Eu3 Eu4 135.721(8) 2_675 9_454 ?
Eu3 Eu3 Eu4 97.646(12) 3_465 9_454 ?
Eu3 Eu3 Eu6 92.975(12) 2_675 6_464 ?
Eu3 Eu3 Eu6 131.932(8) 3_465 6_464 ?
Eu6 Eu3 Eu4 73.864(10) 6_464 9_454 ?
S4 Eu3 Eu3 51.24(3) 7_554 2_675 ?
S4 Eu3 Eu3 107.20(3) 7_554 3_465 ?
S4 Eu3 Eu3 109.88(3) 9_454 2_675 ?
S4 Eu3 Eu3 54.15(3) 9_454 3_465 ?
S4 Eu3 Eu4 114.34(3) 7_554 9_454 ?
S4 Eu3 Eu4 45.78(3) 9_454 9_454 ?
S4 Eu3 Eu6 44.40(3) 7_554 6_464 ?
S4 Eu3 Eu6 113.26(3) 9_454 6_464 ?
S4 Eu3 S4 135.06(7) 9_454 7_554 ?
S4 Eu3 S8 69.51(5) 9_454 6_464 ?
S7 Eu3 Eu3 110.50(4) . 2_675 ?
S7 Eu3 Eu3 169.07(4) . 3_465 ?
S7 Eu3 Eu4 93.12(4) . 9_454 ?
S7 Eu3 Eu6 49.92(3) . 6_464 ?
S7 Eu3 S4 136.72(5) . 9_454 ?
S7 Eu3 S4 66.26(5) . 7_554 ?
S7 Eu3 S8 96.78(5) . 6_464 ?
S7 Eu3 S9 74.39(5) . . ?
S7 Eu3 S11 83.05(5) . 2_675 ?
S7 Eu3 S11 125.91(5) . . ?
S8 Eu3 Eu3 88.30(3) 6_464 2_675 ?
S8 Eu3 Eu3 88.61(3) 6_464 3_465 ?
S8 Eu3 Eu4 51.00(3) 6_464 9_454 ?
S8 Eu3 Eu6 48.79(3) 6_464 6_464 ?
S8 Eu3 S4 69.62(5) 6_464 7_554 ?
S9 Eu3 Eu3 114.37(4) . 3_465 ?
S9 Eu3 Eu3 171.60(4) . 2_675 ?
S9 Eu3 Eu4 48.65(4) . 9_454 ?
S9 Eu3 Eu6 95.36(4) . 6_464 ?
S9 Eu3 S4 136.35(5) . 7_554 ?
S9 Eu3 S4 67.67(5) . 9_454 ?
S9 Eu3 S8 98.03(5) . 6_464 ?
S9 Eu3 S11 84.71(5) . . ?
S9 Eu3 S11 124.96(5) . 2_675 ?
S11 Eu3 Eu3 86.89(3) . 2_675 ?
S11 Eu3 Eu3 51.64(4) . 3_465 ?
S11 Eu3 Eu3 50.80(4) 2_675 2_675 ?
S11 Eu3 Eu3 86.39(3) 2_675 3_465 ?
S11 Eu3 Eu4 109.36(4) . 9_454 ?
S11 Eu3 Eu4 173.48(4) 2_675 9_454 ?
S11 Eu3 Eu6 107.22(4) 2_675 6_464 ?
S11 Eu3 Eu6 175.39(4) . 6_464 ?
S11 Eu3 S4 136.19(5) 2_675 9_454 ?
S11 Eu3 S4 71.05(5) . 9_454 ?
S11 Eu3 S4 133.86(5) . 7_554 ?
S11 Eu3 S4 68.97(5) 2_675 7_554 ?
S11 Eu3 S8 135.79(5) . 6_464 ?
S11 Eu3 S8 134.57(5) 2_675 6_464 ?
S11 Eu3 S11 69.19(7) . 2_675 ?
O1 Eu3 Eu3 36.50(9) . 2_675 ?
O1 Eu3 Eu3 36.50(9) . 3_465 ?
O1 Eu3 Eu4 102.35(13) . 9_454 ?
O1 Eu3 Eu6 97.88(13) . 6_464 ?
O1 Eu3 S4 74.80(6) . 9_454 ?
O1 Eu3 S4 72.38(5) . 7_554 ?
O1 Eu3 S7 138.61(6) . . ?
O1 Eu3 S8 66.37(17) . 6_464 ?
O1 Eu3 S9 142.44(6) . . ?
O1 Eu3 S11 84.76(14) . . ?
O1 Eu3 S11 83.95(14) . 2_675 ?
Eu3 Eu4 Eu5 87.863(10) 5_565 5_565 ?
S3 Eu4 Eu3 75.06(4) 3_465 5_565 ?
S3 Eu4 Eu5 102.59(3) 3_465 5_565 ?
S3 Eu4 S7 66.53(5) 3_465 3_465 ?
S3 Eu4 S8 70.50(5) 3_465 7_444 ?
S3 Eu4 S9 76.28(5) 3_465 5_565 ?
S3 Eu4 S11 98.66(5) 3_465 . ?
S4 Eu4 Eu3 48.25(3) . 5_565 ?
S4 Eu4 Eu5 81.33(4) . 5_565 ?
S4 Eu4 S3 123.20(5) . 3_465 ?
S4 Eu4 S7 132.99(5) . 3_465 ?
S4 Eu4 S8 69.98(5) . 7_444 ?
S4 Eu4 S9 67.37(5) . 5_565 ?
S4 Eu4 S10 76.67(5) . 9_454 ?
S4 Eu4 S11 134.04(5) . . ?
S7 Eu4 Eu3 118.35(3) 3_465 5_565 ?
S7 Eu4 Eu5 145.12(4) 3_465 5_565 ?
S7 Eu4 S8 72.59(5) 3_465 7_444 ?
S8 Eu4 Eu3 49.46(3) 7_444 5_565 ?
S8 Eu4 Eu5 137.32(4) 7_444 5_565 ?
S9 Eu4 Eu3 45.70(3) 5_565 5_565 ?
S9 Eu4 Eu5 45.19(3) 5_565 5_565 ?
S9 Eu4 S7 142.75(5) 5_565 3_465 ?
S9 Eu4 S8 93.66(5) 5_565 7_444 ?
S9 Eu4 S11 110.69(5) 5_565 . ?
S10 Eu4 Eu3 121.75(4) 9_454 5_565 ?
S10 Eu4 Eu5 102.96(4) 9_454 5_565 ?
S10 Eu4 S3 149.76(5) 9_454 3_465 ?
S10 Eu4 S7 83.25(5) 9_454 3_465 ?
S10 Eu4 S8 100.39(5) 9_454 7_444 ?
S10 Eu4 S9 133.86(5) 9_454 5_565 ?
S10 Eu4 S11 74.92(5) 9_454 . ?
S11 Eu4 Eu3 156.22(4) . 5_565 ?
S11 Eu4 Eu5 70.91(3) . 5_565 ?
S11 Eu4 S7 77.97(5) . 3_465 ?
S11 Eu4 S8 150.55(5) . 7_444 ?
O3 Eu4 Eu3 96.79(10) . 5_565 ?
O3 Eu4 Eu5 30.05(10) . 5_565 ?
O3 Eu4 S3 132.62(11) . 3_465 ?
O3 Eu4 S4 67.53(11) . . ?
O3 Eu4 S7 144.59(10) . 3_465 ?
O3 Eu4 S8 137.30(11) . 7_444 ?
O3 Eu4 S9 66.36(10) . 5_565 ?
O3 Eu4 S10 73.86(10) . 9_454 ?
O3 Eu4 S11 70.27(10) . . ?
Eu1 Eu5 Eu4 57.661(9) 9_454 9_454 ?
Eu6 Eu5 Eu1 93.163(11) 9_454 9_454 ?
Eu6 Eu5 Eu4 130.940(13) 9_454 9_454 ?
Ge4 Eu5 Eu1 53.470(15) 9_454 9_454 ?
Ge4 Eu5 Eu4 52.677(16) 9_454 9_454 ?
Ge4 Eu5 Eu6 78.340(16) 9_454 9_454 ?
S1 Eu5 Eu1 86.41(5) . 9_454 ?
S1 Eu5 Eu4 88.56(5) . 9_454 ?
S1 Eu5 Eu6 131.64(3) . 9_454 ?
S1 Eu5 Ge4 133.82(5) . 9_454 ?
S1 Eu5 S2 81.76(6) . . ?
S1 Eu5 S2 80.67(5) . 2_665 ?
S1 Eu5 S5 104.42(4) . 9_454 ?
S1 Eu5 S9 107.81(4) . . ?
S1 Eu5 S10 172.50(6) . 9_454 ?
S2 Eu5 Eu1 113.99(3) 2_665 9_454 ?
S2 Eu5 Eu1 166.03(4) . 9_454 ?
S2 Eu5 Eu4 114.36(4) . 9_454 ?
S2 Eu5 Eu4 167.02(4) 2_665 9_454 ?
S2 Eu5 Eu6 100.24(4) . 9_454 ?
S2 Eu5 Eu6 55.53(3) 2_665 9_454 ?
S2 Eu5 Ge4 133.18(4) . 9_454 ?
S2 Eu5 Ge4 132.66(4) 2_665 9_454 ?
S2 Eu5 S2 71.44(7) . 2_665 ?
S2 Eu5 S5 141.29(5) . 9_454 ?
S2 Eu5 S9 75.25(5) . . ?
S2 Eu5 S10 105.65(5) . 9_454 ?
S5 Eu5 Eu1 49.45(3) 9_454 9_454 ?
S5 Eu5 Eu4 104.07(3) 9_454 9_454 ?
S5 Eu5 Eu6 47.07(3) 9_454 9_454 ?
S5 Eu5 Ge4 68.59(4) 9_454 9_454 ?
S5 Eu5 S2 72.00(5) 9_454 2_665 ?
S9 Eu5 Eu1 101.58(4) . 9_454 ?
S9 Eu5 Eu4 46.79(3) . 9_454 ?
S9 Eu5 Eu6 119.51(4) . 9_454 ?
S9 Eu5 Ge4 65.98(4) . 9_454 ?
S9 Eu5 S2 144.01(5) . 2_665 ?
S9 Eu5 S5 134.54(5) . 9_454 ?
S9 Eu5 S10 73.57(5) . 9_454 ?
S10 Eu5 Eu1 86.09(4) 9_454 9_454 ?
S10 Eu5 Eu4 87.26(4) 9_454 9_454 ?
S10 Eu5 Eu6 49.13(3) 9_454 9_454 ?
S10 Eu5 Ge4 39.55(4) 9_454 9_454 ?
S10 Eu5 S2 102.62(5) 9_454 2_665 ?
S10 Eu5 S5 70.65(5) 9_454 9_454 ?
O3 Eu5 Eu1 32.93(10) 9_454 9_454 ?
O3 Eu5 Eu4 32.32(11) 9_454 9_454 ?
O3 Eu5 Eu6 102.08(11) 9_454 9_454 ?
O3 Eu5 Ge4 30.73(11) 9_454 9_454 ?
O3 Eu5 S1 103.11(12) 9_454 . ?
O3 Eu5 S2 144.29(11) 9_454 . ?
O3 Eu5 S2 144.15(11) 9_454 2_665 ?
O3 Eu5 S5 72.56(11) 9_454 9_454 ?
O3 Eu5 S9 69.55(11) 9_454 . ?
O3 Eu5 S10 70.24(11) 9_454 9_454 ?
Eu5 Eu6 Eu2 89.361(11) 5_565 6_465 ?
Ge3 Eu6 Eu2 94.193(17) 6_465 6_465 ?
Ge3 Eu6 Eu5 77.428(15) 6_465 5_565 ?
Ge3 Eu6 Ge4 170.29(2) 6_465 5_565 ?
Ge4 Eu6 Eu2 77.519(16) 5_565 6_465 ?
Ge4 Eu6 Eu5 97.225(17) 5_565 5_565 ?
S2 Eu6 Eu2 47.85(3) 6_465 6_465 ?
S2 Eu6 Eu5 48.96(3) 6_465 5_565 ?
S2 Eu6 Ge3 63.81(3) 6_465 6_465 ?
S2 Eu6 Ge4 106.56(3) 6_465 5_565 ?
S3 Eu6 Eu2 69.25(4) 6_465 6_465 ?
S3 Eu6 Eu5 106.23(4) 6_465 5_565 ?
S3 Eu6 Ge3 38.80(4) 6_465 6_465 ?
S3 Eu6 Ge4 138.56(4) 6_465 5_565 ?
S3 Eu6 S2 68.10(5) 6_465 6_465 ?
S3 Eu6 S5 77.28(5) 6_465 . ?
S3 Eu6 S6 120.15(5) 6_465 5_565 ?
S3 Eu6 S7 74.68(5) 6_465 8_665 ?
S3 Eu6 S8 74.55(5) 6_465 . ?
S3 Eu6 S10 149.72(5) 6_465 . ?
S4 Eu6 Eu2 104.58(4) 5_565 6_465 ?
S4 Eu6 Eu5 123.64(4) 5_565 5_565 ?
S4 Eu6 Ge3 151.18(4) 5_565 6_465 ?
S4 Eu6 Ge4 38.17(4) 5_565 5_565 ?
S4 Eu6 S2 144.27(5) 5_565 6_465 ?
S4 Eu6 S3 129.93(5) 5_565 6_465 ?
S4 Eu6 S5 137.79(5) 5_565 . ?
S4 Eu6 S6 76.36(5) 5_565 5_565 ?
S4 Eu6 S7 68.61(5) 5_565 8_665 ?
S4 Eu6 S8 76.17(5) 5_565 . ?
S4 Eu6 S10 77.91(5) 5_565 . ?
S5 Eu6 Eu2 116.26(4) . 6_465 ?
S5 Eu6 Eu5 50.48(3) . 5_565 ?
S5 Eu6 Ge3 38.52(4) . 6_465 ?
S5 Eu6 Ge4 141.68(4) . 5_565 ?
S5 Eu6 S2 69.88(5) . 6_465 ?
S5 Eu6 S6 121.50(5) . 5_565 ?
S5 Eu6 S7 151.12(5) . 8_665 ?
S5 Eu6 S8 83.78(5) . . ?
S5 Eu6 S10 72.88(5) . . ?
S6 Eu6 Eu2 51.18(4) 5_565 6_465 ?
S6 Eu6 Eu5 71.25(4) 5_565 5_565 ?
S6 Eu6 Ge3 132.12(4) 5_565 6_465 ?
S6 Eu6 Ge4 38.27(4) 5_565 5_565 ?
S6 Eu6 S2 68.32(5) 5_565 6_465 ?
S6 Eu6 S7 68.90(5) 5_565 8_665 ?
S6 Eu6 S8 151.84(5) 5_565 . ?
S6 Eu6 S10 73.17(5) 5_565 . ?
S7 Eu6 Eu2 46.02(3) 8_665 6_465 ?
S7 Eu6 Eu5 133.13(4) 8_665 5_565 ?
S7 Eu6 Ge3 113.32(4) 8_665 6_465 ?
S7 Eu6 Ge4 64.43(4) 8_665 5_565 ?
S7 Eu6 S2 93.11(5) 8_665 6_465 ?
S8 Eu6 Eu2 132.23(4) . 6_465 ?
S8 Eu6 Eu5 130.87(4) . 5_565 ?
S8 Eu6 Ge3 75.02(4) . 6_465 ?
S8 Eu6 Ge4 114.28(4) . 5_565 ?
S8 Eu6 S2 137.88(5) . 6_465 ?
S8 Eu6 S7 95.24(5) . 8_665 ?
S10 Eu6 Eu2 120.28(4) . 6_465 ?
S10 Eu6 Eu5 49.29(4) . 5_565 ?
S10 Eu6 Ge3 111.33(4) . 6_465 ?
S10 Eu6 Ge4 69.63(4) . 5_565 ?
S10 Eu6 S2 96.42(5) . 6_465 ?
S10 Eu6 S7 133.91(5) . 8_665 ?
S10 Eu6 S8 106.75(5) . . ?
Eu3 Ge1 Eu3 67.48(2) 2_675 3_465 ?
Ge1 Ge1 Eu3 0(10) 3_465 2_675 ?
Ge1 Ge1 Eu3 0(10) 3_465 3_465 ?
Ge1 Ge1 Eu3 0(10) 2_675 2_675 ?
Ge1 Ge1 Eu3 0(10) 2_675 3_465 ?
Ge1 Ge1 Ge1 0(10) 3_465 2_675 ?
Ge1 Ge1 S8 0(10) 3_465 5_564 ?
Ge1 Ge1 S8 0(10) 2_675 4_454 ?
Ge1 Ge1 S8 0(10) 3_465 4_454 ?
Ge1 Ge1 S8 0(10) 2_675 6_464 ?
Ge1 Ge1 S8 0(10) 3_465 6_464 ?
Ge1 Ge1 S8 0(10) 2_675 5_564 ?
Ge1 Ge1 O1 0(10) 2_675 . ?
Ge1 Ge1 O1 0(10) 3_465 . ?
S8 Ge1 Eu3 120.60(6) 5_564 2_675 ?
S8 Ge1 Eu3 64.79(5) 4_454 2_675 ?
S8 Ge1 Eu3 64.79(5) 5_564 3_465 ?
S8 Ge1 Eu3 120.60(6) 6_464 3_465 ?
S8 Ge1 Eu3 120.02(6) 4_454 3_465 ?
S8 Ge1 Eu3 120.02(6) 6_464 2_675 ?
S8 Ge1 S8 113.81(5) 6_464 4_454 ?
S8 Ge1 S8 113.81(5) 6_464 5_564 ?
S8 Ge1 S8 113.80(5) 5_564 4_454 ?
O1 Ge1 Eu3 39.891(16) . 2_675 ?
O1 Ge1 Eu3 39.891(16) . 3_465 ?
O1 Ge1 S8 104.68(6) . 5_564 ?
O1 Ge1 S8 104.68(6) . 4_454 ?
O1 Ge1 S8 104.68(6) . 6_464 ?
S1 Ge2 S11 112.74(6) . 8_664 ?
S1 Ge2 S11 112.74(6) . 7_544 ?
S1 Ge2 S11 112.75(6) . 9_454 ?
S11 Ge2 S11 106.01(6) 8_664 7_544 ?
S11 Ge2 S11 106.01(6) 9_454 8_664 ?
S11 Ge2 S11 106.01(6) 9_454 7_544 ?
Eu6 Ge3 Eu2 76.703(18) 8_664 8_664 ?
S3 Ge3 Eu2 109.73(5) . 8_664 ?
S3 Ge3 Eu6 56.62(5) . 8_664 ?
S5 Ge3 Eu2 56.07(5) 8_664 8_664 ?
S5 Ge3 Eu6 57.04(5) 8_664 8_664 ?
S5 Ge3 S3 113.61(8) 8_664 . ?
S5 Ge3 S7 108.77(7) 8_664 . ?
S7 Ge3 Eu2 54.52(5) . 8_664 ?
S7 Ge3 Eu6 117.15(5) . 8_664 ?
S7 Ge3 S3 102.37(7) . . ?
S9 Ge3 Eu2 141.82(6) . 8_664 ?
S9 Ge3 Eu6 131.69(6) . 8_664 ?
S9 Ge3 S3 107.87(7) . . ?
S9 Ge3 S5 112.98(8) . 8_664 ?
S9 Ge3 S7 110.74(7) . . ?
Eu5 Ge4 Eu6 156.81(3) 5_565 9_454 ?
S4 Ge4 Eu5 121.12(5) . 5_565 ?
S4 Ge4 Eu6 54.09(5) . 9_454 ?
S4 Ge4 S6 111.78(7) . . ?
S6 Ge4 Eu5 122.70(5) . 5_565 ?
S6 Ge4 Eu6 57.83(5) . 9_454 ?
S10 Ge4 Eu5 62.90(5) . 5_565 ?
S10 Ge4 Eu6 140.23(6) . 9_454 ?
S10 Ge4 S4 116.11(8) . . ?
S10 Ge4 S6 112.04(7) . . ?
O3 Ge4 Eu5 44.55(14) . 5_565 ?
O3 Ge4 Eu6 112.38(15) . 9_454 ?
O3 Ge4 S4 103.82(16) . . ?
O3 Ge4 S6 104.58(16) . . ?
O3 Ge4 S10 107.40(16) . . ?
Eu2 Ge5 Eu2 75.79(3) 2_665 3_565 ?
Ge5 Ge5 Eu2 73(2) 3_565 3_565 ?
Ge5 Ge5 Eu2 92(6) 2_665 3_565 ?
Ge5 Ge5 Eu2 51(10) 2_665 2_665 ?
Ge5 Ge5 Eu2 65(10) 3_565 2_665 ?
Ge5 Ge5 S2 145(10) 2_665 . ?
Ge5 Ge5 S2 161(10) 3_565 . ?
Ge5 Ge5 S2 91(10) 2_665 3_565 ?
Ge5 Ge5 S2 34(10) 2_665 2_665 ?
Ge5 Ge5 S2 66(10) 3_565 3_565 ?
Ge5 Ge5 S2 58(10) 3_565 2_665 ?
Ge5 Ge5 O2 90(6) 3_565 . ?
Ge5 Ge5 O2 90(6) 2_665 . ?
S2 Ge5 Eu2 122.70(5) . 3_565 ?
S2 Ge5 Eu2 63.35(5) 3_565 3_565 ?
S2 Ge5 Eu2 125.41(6) 2_665 3_565 ?
S2 Ge5 Eu2 125.41(6) . 2_665 ?
S2 Ge5 Eu2 63.35(5) 2_665 2_665 ?
S2 Ge5 Eu2 122.70(5) 3_565 2_665 ?
S2 Ge5 S2 110.42(6) . 3_565 ?
S2 Ge5 S2 110.42(6) . 2_665 ?
S2 Ge5 S2 110.42(6) 2_665 3_565 ?
O2 Ge5 Eu2 45.172(18) . 2_665 ?
O2 Ge5 Eu2 45.172(18) . 3_565 ?
O2 Ge5 S2 108.50(6) . 3_565 ?
O2 Ge5 S2 108.50(6) . 2_665 ?
O2 Ge5 S2 108.50(6) . . ?
Eu5 S1 Eu5 100.10(7) 3_565 2_665 ?
Eu5 S1 Eu5 100.10(7) . 3_565 ?
Eu5 S1 Eu5 100.10(7) . 2_665 ?
Ge2 S1 Eu5 117.73(5) . . ?
Ge2 S1 Eu5 117.73(5) . 2_665 ?
Ge2 S1 Eu5 117.73(5) . 3_565 ?
Eu2 S2 Eu5 132.10(6) . 3_565 ?
Eu2 S2 Eu6 77.32(4) . 8_664 ?
Eu5 S2 Eu2 130.02(6) . . ?
Eu5 S2 Eu5 93.82(5) . 3_565 ?
Eu5 S2 Eu6 143.28(6) . 8_664 ?
Eu5 S2 Eu6 75.51(4) 3_565 8_664 ?
Ge5 S2 Eu2 77.28(6) 3_565 . ?
Ge5 S2 Eu2 77.28(6) 2_665 . ?
Ge5 S2 Eu2 77.28(6) . . ?
Ge5 S2 Eu5 87.00(6) . 3_565 ?
Ge5 S2 Eu5 88.64(6) 2_665 . ?
Ge5 S2 Eu5 87.00(6) 2_665 3_565 ?
Ge5 S2 Eu5 88.64(6) 3_565 . ?
Ge5 S2 Eu5 88.64(6) . . ?
Ge5 S2 Eu5 87.00(6) 3_565 3_565 ?
Ge5 S2 Eu6 124.88(7) 3_565 8_664 ?
Ge5 S2 Eu6 124.88(7) . 8_664 ?
Ge5 S2 Eu6 124.88(7) 2_665 8_664 ?
Ge5 S2 Ge5 0.00(7) . 3_565 ?
Ge5 S2 Ge5 0.00(7) . 2_665 ?
Ge5 S2 Ge5 0.00(7) 3_565 2_665 ?
Eu1 S3 Eu4 119.06(6) . 2_675 ?
Eu6 S3 Eu1 128.69(6) 8_664 . ?
Eu6 S3 Eu4 112.06(6) 8_664 2_675 ?
Ge3 S3 Eu1 92.70(6) . . ?
Ge3 S3 Eu4 97.56(6) . 2_675 ?
Ge3 S3 Eu6 84.59(6) . 8_664 ?
Eu3 S4 Eu3 74.62(4) 5_565 4_445 ?
Eu4 S4 Eu3 85.96(4) . 5_565 ?
Eu4 S4 Eu3 151.37(7) . 4_445 ?
Eu6 S4 Eu3 147.72(7) 9_454 5_565 ?
Eu6 S4 Eu3 83.29(5) 9_454 4_445 ?
Eu6 S4 Eu4 104.11(6) 9_454 . ?
Ge4 S4 Eu3 124.82(7) . 4_445 ?
Ge4 S4 Eu3 124.19(7) . 5_565 ?
Ge4 S4 Eu4 83.48(6) . . ?
Ge4 S4 Eu6 87.74(6) . 9_454 ?
Eu2 S5 Eu1 84.06(4) . . ?
Eu2 S5 Eu5 148.45(7) . 5_565 ?
Eu5 S5 Eu1 82.15(4) 5_565 . ?
Eu6 S5 Eu1 149.43(7) . . ?
Eu6 S5 Eu2 95.70(5) . . ?
Eu6 S5 Eu5 82.45(4) . 5_565 ?
Ge3 S5 Eu1 125.94(7) 6_465 . ?
Ge3 S5 Eu2 86.62(6) 6_465 . ?
Ge3 S5 Eu5 124.26(7) 6_465 5_565 ?
Ge3 S5 Eu6 84.44(6) 6_465 . ?
Eu1 S6 Eu2 157.14(6) . 2_665 ?
Eu1 S6 Eu2 83.25(4) . . ?
Eu2 S6 Eu2 81.40(5) . 2_665 ?
Eu6 S6 Eu1 106.05(5) 9_454 . ?
Eu6 S6 Eu2 153.75(6) 9_454 . ?
Eu6 S6 Eu2 81.57(4) 9_454 2_665 ?
Ge4 S6 Eu1 79.48(6) . . ?
Ge4 S6 Eu2 123.17(7) . 2_665 ?
Ge4 S6 Eu2 122.24(7) . . ?
Ge4 S6 Eu6 83.90(6) . 9_454 ?
Eu2 S7 Eu3 159.58(7) 8_664 . ?
Eu2 S7 Eu4 102.88(5) 8_664 2_675 ?
Eu2 S7 Eu6 83.87(5) 8_664 6_464 ?
Eu3 S7 Eu4 96.77(5) . 2_675 ?
Eu3 S7 Eu6 84.21(4) . 6_464 ?
Eu6 S7 Eu4 141.51(6) 6_464 2_675 ?
Ge3 S7 Eu2 88.07(6) . 8_664 ?
Ge3 S7 Eu3 85.23(6) . . ?
Ge3 S7 Eu4 93.44(6) . 2_675 ?
Ge3 S7 Eu6 124.87(7) . 6_464 ?
Eu2 S8 Eu3 172.12(7) . 8_665 ?
Eu2 S8 Eu4 99.48(5) . 4 ?
Eu2 S8 Eu6 92.62(5) . . ?
Eu3 S8 Eu4 79.54(4) 8_665 4 ?
Eu6 S8 Eu3 79.97(5) . 8_665 ?
Eu6 S8 Eu4 101.23(5) . 4 ?
Ge1 S8 Eu2 109.37(8) 7_545 . ?
Ge1 S8 Eu3 77.10(6) 7_545 8_665 ?
Ge1 S8 Eu4 125.71(7) 7_545 4 ?
Ge1 S8 Eu6 121.55(7) 7_545 . ?
Eu1 S9 Eu4 147.86(6) . 9_454 ?
Eu3 S9 Eu1 90.49(5) . . ?
Eu3 S9 Eu4 85.66(5) . 9_454 ?
Eu3 S9 Eu5 152.92(6) . . ?
Eu5 S9 Eu1 81.05(4) . . ?
Eu5 S9 Eu4 88.02(5) . 9_454 ?
Ge3 S9 Eu1 88.47(6) . . ?
Ge3 S9 Eu3 84.23(6) . . ?
Ge3 S9 Eu4 122.71(7) . 9_454 ?
Ge3 S9 Eu5 120.91(7) . . ?
Eu1 S10 Eu4 85.57(5) 5_565 5_565 ?
Eu1 S10 Eu5 83.58(5) 5_565 5_565 ?
Eu1 S10 Eu6 107.18(6) 5_565 . ?
Eu4 S10 Eu5 168.92(7) 5_565 5_565 ?
Eu4 S10 Eu6 99.52(5) 5_565 . ?
Eu6 S10 Eu5 81.58(5) . 5_565 ?
Ge4 S10 Eu1 119.92(7) . 5_565 ?
Ge4 S10 Eu4 110.07(7) . 5_565 ?
Ge4 S10 Eu5 77.55(6) . 5_565 ?
Ge4 S10 Eu6 125.11(7) . . ?
Eu1 S11 Eu3 151.30(7) . 3_465 ?
Eu1 S11 Eu4 81.11(4) . . ?
Eu3 S11 Eu1 90.17(5) . . ?
Eu3 S11 Eu3 77.56(5) . 3_465 ?
Eu3 S11 Eu4 94.09(5) 3_465 . ?
Eu3 S11 Eu4 144.95(7) . . ?
Ge2 S11 Eu1 116.38(7) 4_455 . ?
Ge2 S11 Eu3 89.98(6) 4_455 3_465 ?
Ge2 S11 Eu3 90.93(6) 4_455 . ?
Ge2 S11 Eu4 123.38(8) 4_455 . ?
Eu3 O1 Eu3 107.00(18) 2_675 . ?
Eu3 O1 Eu3 107.00(18) 2_675 3_465 ?
Eu3 O1 Eu3 107.00(17) . 3_465 ?
Ge1 O1 Eu3 111.84(16) 2_675 . ?
Ge1 O1 Eu3 111.84(16) 3_465 . ?
Ge1 O1 Eu3 111.85(16) . 2_675 ?
Ge1 O1 Eu3 111.85(16) 2_675 3_465 ?
Ge1 O1 Eu3 111.84(16) . . ?
Ge1 O1 Eu3 111.85(16) 3_465 3_465 ?
Ge1 O1 Eu3 111.85(16) 2_675 2_675 ?
Ge1 O1 Eu3 111.85(16) 3_465 2_675 ?
Ge1 O1 Eu3 111.85(16) . 3_465 ?
Ge1 O1 Ge1 0.0 3_465 2_675 ?
Ge1 O1 Ge1 0.0 3_465 . ?
Ge1 O1 Ge1 0.0 2_675 . ?
Eu2 O2 Eu2 114.54(13) . 3_565 ?
Eu2 O2 Eu2 114.54(13) . 2_665 ?
Eu2 O2 Eu2 114.54(13) 2_665 3_565 ?
Ge5 O2 Eu2 103.74(17) . 3_565 ?
Ge5 O2 Eu2 103.74(17) . 2_665 ?
Ge5 O2 Eu2 103.74(17) 3_565 . ?
Ge5 O2 Eu2 103.74(17) . . ?
Ge5 O2 Eu2 103.74(17) 3_565 3_565 ?
Ge5 O2 Eu2 103.74(17) 3_565 2_665 ?
Ge5 O2 Eu2 103.74(17) 2_665 3_565 ?
Ge5 O2 Eu2 103.74(17) 2_665 2_665 ?
Ge5 O2 Eu2 103.74(17) 2_665 . ?
Ge5 O2 Ge5 0.0 2_665 . ?
Ge5 O2 Ge5 0.0 3_565 2_665 ?
Ge5 O2 Ge5 0.0 3_565 . ?
Eu1 O3 Eu4 106.93(16) . . ?
Eu5 O3 Eu1 114.51(18) 5_565 . ?
Eu5 O3 Eu4 117.63(18) 5_565 . ?
Ge4 O3 Eu1 107.1(2) . . ?
Ge4 O3 Eu4 105.0(2) . . ?
Ge4 O3 Eu5 104.7(2) . 5_565 ?


_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2329238'
loop_
_audit_author_name
_audit_author_address
'Sheng-Ping Guo'
;Yangzhou University
China
;
_audit_update_record             
;
2024-06-28 deposited with the CCDC.	2024-07-04 downloaded from the CCDC.
;
_audit_creation_date             2024-06-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Ca3.319 Eu14.681 Ge9 O5 S31'
_chemical_formula_sum            'Ca3.32 Eu14.68 Ge9 O5 S31'
_chemical_formula_weight         4091.01
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_H-M_alt        'R 3'
_space_group_name_Hall           'R 3'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'

_cell_length_a                   16.7573(8)
_cell_length_b                   16.7573(8)
_cell_length_c                   17.9107(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     4355.6(5)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    9928
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      30.50
_cell_measurement_theta_min      2.43
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    21.588
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.3848
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1462 before and 0.0491 after correction.
The Ratio of minimum to maximum transmission is 0.5157.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    4.679
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5446
_exptl_crystal_size_max          0.02
_exptl_crystal_size_mid          0.015
_exptl_crystal_size_min          0.01
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0438
_diffrn_reflns_av_unetI/netI     0.0479
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            16950
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.516
_diffrn_reflns_theta_min         2.431
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.978
_reflns_Friedel_fraction_full    0.989
_reflns_Friedel_fraction_max     0.975
_reflns_number_gt                5592
_reflns_number_total             5845
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS  (Sheldrick, 2008)'
_refine_diff_density_max         0.956
_refine_diff_density_min         -2.388
_refine_diff_density_rms         0.385
_refine_ls_abs_structure_details 
;
 Flack x determined using 2608 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.009(8)
_refine_ls_extinction_coef       0.000533(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     196
_refine_ls_number_reflns         5845
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0291
_refine_ls_R_factor_gt           0.0265
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0167P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0510
_refine_ls_wR_factor_ref         0.0516
_refine_special_details          ?
_olex2_refinement_description    
;
1. Shared sites
{Eu1, Ca1}
{Eu2, Ca2}
{Eu5, Ca5}
{Eu6, Ca6}
{Eu3, Ca3}
2. Uiso/Uaniso restraints and constraints
Uanis(Eu1) = Uanis(Ca1)
Uanis(Eu2) = Uanis(Ca2)
Uanis(Eu5) = Uanis(Ca5)
Uanis(Eu6) = Uanis(Ca6)
Uanis(Eu3) = Uanis(Ca3)
3. Others
 Sof(Ca1)=1-FVAR(1)
 Sof(Eu1)=FVAR(1)
 Sof(Ca2)=1-FVAR(2)
 Sof(Eu2)=FVAR(2)
 Sof(Ca5)=1-FVAR(3)
 Sof(Eu5)=FVAR(3)
 Sof(Ca6)=1-FVAR(4)
 Sof(Eu6)=FVAR(4)
 Sof(Ca3)=1-FVAR(5)
 Sof(Eu3)=FVAR(5)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.13535(3) 0.82434(4) 0.67120(3) 0.01359(15) Uani 0.848(2) 1 d . . P A 1
Eu2 Eu 0.32618(4) 0.80587(4) 0.80499(3) 0.01297(18) Uani 0.750(3) 1 d . . P A 3
Eu3 Eu 0.12834(4) 0.99055(4) 0.48481(3) 0.01118(17) Uani 0.762(3) 1 d . . P A 9
Eu4 Eu -0.14663(3) 0.67347(3) 0.66685(2) 0.01233(12) Uani 1 1 d . . . . .
Eu5 Eu 0.17878(4) 0.66784(4) 0.52328(4) 0.01328(19) Uani 0.705(3) 1 d . . P A 5
Eu6 Eu 0.17673(4) 0.83292(4) 0.99947(3) 0.01176(15) Uani 0.829(3) 1 d . . P A 7
Ge1 Ge 0.000000 1.000000 0.33580(8) 0.0074(3) Uani 1 3 d S T P A .
Ge2 Ge 0.333333 0.666667 0.32505(8) 0.0086(3) Uani 1 3 d S T P A .
Ge3 Ge 0.32640(6) 0.98320(6) 0.54199(5) 0.00771(19) Uani 1 1 d . . . . .
Ge4 Ge 0.00076(6) 0.65488(6) 0.79767(5) 0.00660(18) Uani 1 1 d . . . . .
Ge5 Ge 0.333333 0.666667 0.67238(9) 0.0084(3) Uani 1 3 d S T P A .
S1 S 0.333333 0.666667 0.4475(2) 0.0181(8) Uani 1 3 d S T P . .
S2 S 0.33097(15) 0.79037(14) 0.63303(12) 0.0135(4) Uani 1 1 d . . . . .
S3 S 0.31688(15) 0.99317(14) 0.66495(12) 0.0127(4) Uani 1 1 d . . . . .
S4 S -0.12588(14) 0.53302(14) 0.75677(11) 0.0088(4) Uani 1 1 d . . . . .
S5 S 0.19976(14) 0.87957(14) 0.83898(11) 0.0109(4) Uani 1 1 d . . . . .
S6 S 0.12587(14) 0.65844(14) 0.75230(12) 0.0109(4) Uani 1 1 d . . . . .
S7 S 0.32888(15) 1.10884(14) 0.50158(11) 0.0116(4) Uani 1 1 d . . . . .
S8 S 0.34101(14) 0.79801(14) 0.97067(12) 0.0126(4) Uani 1 1 d . . . . .
S9 S 0.20078(13) 0.86041(14) 0.50431(12) 0.0113(4) Uani 1 1 d . . . . .
S10 S 0.00946(14) 0.67953(14) 0.91911(11) 0.0093(4) Uani 1 1 d . . . . .
S11 S -0.00592(15) 0.87612(14) 0.60970(12) 0.0136(4) Uani 1 1 d . . . . .
O1 O 0.000000 1.000000 0.4352(5) 0.008(2) Uani 1 3 d S T P . .
O2 O 0.333333 0.666667 0.7740(5) 0.010(2) Uani 1 3 d S T P . .
O3 O -0.0007(4) 0.7506(4) 0.7536(3) 0.0085(11) Uani 1 1 d . . . . .
Ca1 Ca 0.13535(3) 0.82434(4) 0.67120(3) 0.01359(15) Uani 0.152(2) 1 d . . P A 2
Ca2 Ca 0.32618(4) 0.80587(4) 0.80499(3) 0.01297(18) Uani 0.250(3) 1 d . . P A 4
Ca5 Ca 0.17878(4) 0.66784(4) 0.52328(4) 0.01328(19) Uani 0.295(3) 1 d . . P A 6
Ca6 Ca 0.17673(4) 0.83292(4) 0.99947(3) 0.01176(15) Uani 0.171(3) 1 d . . P A 8
Ca3 Ca 0.12834(4) 0.99055(4) 0.48481(3) 0.01118(17) Uani 0.238(3) 1 d . . P A
10


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 S3 2.943(2) . ?
Eu1 S5 3.171(2) . ?
Eu1 S6 3.070(2) . ?
Eu1 S9 3.137(2) . ?
Eu1 S10 2.980(2) 9_454 ?
Eu1 S11 3.102(2) . ?
Eu1 O3 2.467(5) . ?
Eu2 Ge3 3.6186(10) 6_465 ?
Eu2 S2 3.095(2) . ?
Eu2 S5 3.000(2) . ?
Eu2 S6 3.157(2) . ?
Eu2 S6 3.194(2) 3_565 ?
Eu2 S7 2.953(2) 6_465 ?
Eu2 S8 2.986(2) . ?
Eu2 O2 2.458(2) . ?
Eu3 Eu4 4.1944(7) 9_454 ?
Eu3 S4 3.139(2) 9_454 ?
Eu3 S4 3.256(2) 7_554 ?
Eu3 S7 2.941(2) . ?
Eu3 S8 3.240(2) 6_464 ?
Eu3 S9 3.000(2) . ?
Eu3 S11 3.070(2) . ?
Eu3 S11 3.119(2) 2_675 ?
Eu3 O1 2.404(3) . ?
Eu4 Eu5 4.3254(8) 5_565 ?
Eu4 S3 3.051(2) 3_465 ?
Eu4 S4 3.012(2) . ?
Eu4 S7 3.198(2) 3_465 ?
Eu4 S8 3.320(2) 7_444 ?
Eu4 S9 3.160(2) 5_565 ?
Eu4 S10 3.031(2) 9_454 ?
Eu4 S11 3.183(2) . ?
Eu4 O3 2.627(5) . ?
Eu5 Ge4 3.3602(10) 9_454 ?
Eu5 S1 2.9324(18) . ?
Eu5 S2 3.057(2) . ?
Eu5 S2 3.127(2) 2_665 ?
Eu5 S5 3.130(2) 9_454 ?
Eu5 S9 3.078(2) . ?
Eu5 S10 3.066(2) 9_454 ?
Eu5 O3 2.425(6) 9_454 ?
Eu6 Ge3 3.5105(10) 6_465 ?
Eu6 Ge4 3.5643(10) 5_565 ?
Eu6 S2 3.398(2) 6_465 ?
Eu6 S3 2.941(2) 6_465 ?
Eu6 S4 2.880(2) 5_565 ?
Eu6 S5 2.953(2) . ?
Eu6 S6 3.021(2) 5_565 ?
Eu6 S7 3.141(2) 8_665 ?
Eu6 S8 3.130(2) . ?
Eu6 S10 3.055(2) . ?
Ge1 Ge1 0.0000 2_675 ?
Ge1 Ge1 0.0000 3_465 ?
Ge1 S8 2.214(2) 6_464 ?
Ge1 S8 2.214(2) 4_454 ?
Ge1 S8 2.214(2) 5_564 ?
Ge1 O1 1.781(9) . ?
Ge2 S1 2.194(4) . ?
Ge2 S11 2.208(2) 8_664 ?
Ge2 S11 2.208(2) 7_544 ?
Ge2 S11 2.208(2) 9_454 ?
Ge3 S3 2.220(2) . ?
Ge3 S5 2.203(2) 8_664 ?
Ge3 S7 2.207(2) . ?
Ge3 S9 2.188(2) . ?
Ge4 S4 2.208(2) . ?
Ge4 S6 2.221(2) . ?
Ge4 S10 2.205(2) . ?
Ge4 O3 1.798(6) . ?
Ge5 Ge5 0.0000 2_665 ?
Ge5 Ge5 0.0000 3_565 ?
Ge5 S2 2.208(2) 2_665 ?
Ge5 S2 2.208(2) 3_565 ?
Ge5 S2 2.208(2) . ?
Ge5 O2 1.820(10) . ?
S1 Ca5 2.9324(18) . ?
S2 Ca2 3.095(2) . ?
S2 Ca5 3.057(2) . ?
S3 Ca1 2.943(2) . ?
S5 Ca1 3.171(2) . ?
S5 Ca2 3.000(2) . ?
S5 Ca6 2.953(2) . ?
S6 Ca1 3.070(2) . ?
S6 Ca2 3.194(2) 2_665 ?
S6 Ca2 3.157(2) . ?
S7 Ca3 2.941(2) . ?
S8 Ca2 2.986(2) . ?
S8 Ca6 3.130(2) . ?
S9 Ca1 3.137(2) . ?
S9 Ca5 3.078(2) . ?
S9 Ca3 3.000(2) . ?
S10 Ca6 3.055(2) . ?
S11 Ca1 3.102(2) . ?
S11 Ca3 3.119(2) 3_465 ?
S11 Ca3 3.070(2) . ?
O1 Ca3 2.404(3) . ?
O1 Ca3 2.404(3) 3_465 ?
O1 Ca3 2.404(3) 2_675 ?
O2 Ca2 2.458(2) 3_565 ?
O2 Ca2 2.458(2) 2_665 ?
O2 Ca2 2.458(2) . ?
O3 Ca1 2.467(5) . ?
Ca2 Ca2 4.1481(10) 2_665 ?
Ca2 Ca2 4.1481(10) 3_565 ?
Ca3 Ca3 3.8694(9) 3_465 ?
Ca3 Ca3 3.8694(9) 2_675 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag

S3 Eu1 S5 73.63(6) . . ?
S3 Eu1 S6 116.69(6) . . ?
S3 Eu1 S9 71.63(6) . . ?
S3 Eu1 S10 143.94(6) . 9_454 ?
S3 Eu1 S11 106.50(6) . . ?
S6 Eu1 S5 70.84(6) . . ?
S6 Eu1 S9 118.71(6) . . ?
S6 Eu1 S11 136.07(6) . . ?
S9 Eu1 S5 144.27(6) . . ?
S10 Eu1 S5 138.18(6) 9_454 . ?
S10 Eu1 S6 73.36(5) 9_454 . ?
S10 Eu1 S9 73.47(5) 9_454 . ?
S10 Eu1 S11 76.66(6) 9_454 . ?
S11 Eu1 S5 116.80(6) . . ?
S11 Eu1 S9 81.36(6) . . ?
O3 Eu1 S3 139.15(13) . . ?
O3 Eu1 S5 70.96(12) . . ?
O3 Eu1 S6 69.31(13) . . ?
O3 Eu1 S9 144.39(12) . . ?
O3 Eu1 S10 76.74(13) . 9_454 ?
O3 Eu1 S11 73.10(13) . . ?
S2 Eu2 Ge3 115.94(4) . 6_465 ?
S2 Eu2 S6 72.48(6) . . ?
S2 Eu2 S6 70.56(6) . 3_565 ?
S5 Eu2 Ge3 37.42(4) . 6_465 ?
S5 Eu2 S2 106.84(6) . . ?
S5 Eu2 S6 140.67(6) . 3_565 ?
S5 Eu2 S6 71.91(5) . . ?
S6 Eu2 Ge3 109.22(4) . 6_465 ?
S6 Eu2 Ge3 106.55(4) 3_565 6_465 ?
S6 Eu2 S6 136.80(7) . 3_565 ?
S7 Eu2 Ge3 37.55(4) 6_465 6_465 ?
S7 Eu2 S2 104.09(6) 6_465 . ?
S7 Eu2 S5 74.02(6) 6_465 . ?
S7 Eu2 S6 142.78(6) 6_465 . ?
S7 Eu2 S6 69.05(6) 6_465 3_565 ?
S7 Eu2 S8 81.04(6) 6_465 . ?
S8 Eu2 Ge3 74.65(4) . 6_465 ?
S8 Eu2 S2 168.19(6) . . ?
S8 Eu2 S5 84.72(6) . . ?
S8 Eu2 S6 109.99(6) . . ?
S8 Eu2 S6 102.14(6) . 3_565 ?
O2 Eu2 Ge3 172.5(2) . 6_465 ?
O2 Eu2 S2 71.3(2) . . ?
O2 Eu2 S5 144.68(5) . . ?
O2 Eu2 S6 73.46(7) . 3_565 ?
O2 Eu2 S6 74.17(7) . . ?
O2 Eu2 S7 141.28(5) . 6_465 ?
O2 Eu2 S8 97.9(2) . . ?
S4 Eu3 Eu4 45.75(4) 9_454 9_454 ?
S4 Eu3 Eu4 114.40(4) 7_554 9_454 ?
S4 Eu3 S4 135.17(8) 9_454 7_554 ?
S4 Eu3 S8 69.60(5) 9_454 6_464 ?
S7 Eu3 Eu4 93.32(4) . 9_454 ?
S7 Eu3 S4 66.17(5) . 7_554 ?
S7 Eu3 S4 136.85(6) . 9_454 ?
S7 Eu3 S8 96.93(6) . 6_464 ?
S7 Eu3 S9 74.74(6) . . ?
S7 Eu3 S11 125.45(6) . . ?
S7 Eu3 S11 82.87(6) . 2_675 ?
S8 Eu3 Eu4 51.11(4) 6_464 9_454 ?
S8 Eu3 S4 69.60(5) 6_464 7_554 ?
S9 Eu3 Eu4 48.70(4) . 9_454 ?
S9 Eu3 S4 67.45(5) . 9_454 ?
S9 Eu3 S4 136.62(5) . 7_554 ?
S9 Eu3 S8 98.25(6) . 6_464 ?
S9 Eu3 S11 84.13(6) . . ?
S9 Eu3 S11 124.83(6) . 2_675 ?
S11 Eu3 Eu4 173.40(4) 2_675 9_454 ?
S11 Eu3 Eu4 109.27(4) . 9_454 ?
S11 Eu3 S4 71.14(6) . 9_454 ?
S11 Eu3 S4 69.00(5) 2_675 7_554 ?
S11 Eu3 S4 134.03(5) . 7_554 ?
S11 Eu3 S4 136.17(6) 2_675 9_454 ?
S11 Eu3 S8 136.08(6) . 6_464 ?
S11 Eu3 S8 134.56(6) 2_675 6_464 ?
S11 Eu3 S11 69.15(8) . 2_675 ?
O1 Eu3 Eu4 102.57(16) . 9_454 ?
O1 Eu3 S4 72.58(6) . 7_554 ?
O1 Eu3 S4 74.88(7) . 9_454 ?
O1 Eu3 S7 138.73(7) . . ?
O1 Eu3 S8 66.6(2) . 6_464 ?
O1 Eu3 S9 142.31(7) . . ?
O1 Eu3 S11 83.77(17) . 2_675 ?
O1 Eu3 S11 84.84(17) . . ?
Eu3 Eu4 Eu5 87.953(14) 5_565 5_565 ?
S3 Eu4 Eu3 74.68(4) 3_465 5_565 ?
S3 Eu4 Eu5 102.41(4) 3_465 5_565 ?
S3 Eu4 S7 67.18(5) 3_465 3_465 ?
S3 Eu4 S8 70.36(6) 3_465 7_444 ?
S3 Eu4 S9 76.15(5) 3_465 5_565 ?
S3 Eu4 S11 99.27(6) 3_465 . ?
S4 Eu4 Eu3 48.29(4) . 5_565 ?
S4 Eu4 Eu5 81.37(4) . 5_565 ?
S4 Eu4 S3 122.86(6) . 3_465 ?
S4 Eu4 S7 132.78(6) . 3_465 ?
S4 Eu4 S8 70.01(5) . 7_444 ?
S4 Eu4 S9 67.04(5) . 5_565 ?
S4 Eu4 S10 76.17(5) . 9_454 ?
S4 Eu4 S11 133.80(6) . . ?
S7 Eu4 Eu3 118.39(4) 3_465 5_565 ?
S7 Eu4 Eu5 145.23(4) 3_465 5_565 ?
S7 Eu4 S8 72.56(5) 3_465 7_444 ?
S8 Eu4 Eu3 49.42(4) 7_444 5_565 ?
S8 Eu4 Eu5 137.37(4) 7_444 5_565 ?
S9 Eu4 Eu3 45.50(4) 5_565 5_565 ?
S9 Eu4 Eu5 45.33(4) 5_565 5_565 ?
S9 Eu4 S7 143.25(5) 5_565 3_465 ?
S9 Eu4 S8 93.49(6) 5_565 7_444 ?
S9 Eu4 S11 111.24(6) 5_565 . ?
S10 Eu4 Eu3 121.38(4) 9_454 5_565 ?
S10 Eu4 Eu5 102.57(4) 9_454 5_565 ?
S10 Eu4 S3 150.64(6) 9_454 3_465 ?
S10 Eu4 S7 83.49(5) 9_454 3_465 ?
S10 Eu4 S8 100.48(6) 9_454 7_444 ?
S10 Eu4 S9 133.07(5) 9_454 5_565 ?
S10 Eu4 S11 74.73(5) 9_454 . ?
S11 Eu4 Eu3 156.58(4) . 5_565 ?
S11 Eu4 Eu5 71.03(4) . 5_565 ?
S11 Eu4 S7 77.92(6) . 3_465 ?
S11 Eu4 S8 150.46(6) . 7_444 ?
O3 Eu4 Eu3 97.14(12) . 5_565 ?
O3 Eu4 Eu5 29.77(12) . 5_565 ?
O3 Eu4 S3 132.16(13) . 3_465 ?
O3 Eu4 S4 68.00(13) . . ?
O3 Eu4 S7 144.20(12) . 3_465 ?
O3 Eu4 S8 137.79(13) . 7_444 ?
O3 Eu4 S9 66.34(12) . 5_565 ?
O3 Eu4 S10 73.60(12) . 9_454 ?
O3 Eu4 S11 69.80(12) . . ?
Ge4 Eu5 Eu4 52.878(19) 9_454 9_454 ?
S1 Eu5 Eu4 88.63(6) . 9_454 ?
S1 Eu5 Ge4 134.12(7) . 9_454 ?
S1 Eu5 S2 80.71(7) . 2_665 ?
S1 Eu5 S2 81.89(7) . . ?
S1 Eu5 S5 104.91(5) . 9_454 ?
S1 Eu5 S9 108.22(5) . . ?
S1 Eu5 S10 173.10(7) . 9_454 ?
S2 Eu5 Eu4 114.25(4) . 9_454 ?
S2 Eu5 Eu4 167.01(4) 2_665 9_454 ?
S2 Eu5 Ge4 132.31(5) 2_665 9_454 ?
S2 Eu5 Ge4 132.84(5) . 9_454 ?
S2 Eu5 S2 71.76(8) . 2_665 ?
S2 Eu5 S5 71.94(5) 2_665 9_454 ?
S2 Eu5 S5 141.32(6) . 9_454 ?
S2 Eu5 S9 75.19(6) . . ?
S2 Eu5 S10 104.94(6) . 9_454 ?
S5 Eu5 Eu4 104.05(4) 9_454 9_454 ?
S5 Eu5 Ge4 68.24(4) 9_454 9_454 ?
S9 Eu5 Eu4 46.88(4) . 9_454 ?
S9 Eu5 Ge4 65.73(4) . 9_454 ?
S9 Eu5 S2 144.11(6) . 2_665 ?
S9 Eu5 S5 133.92(6) . 9_454 ?
S10 Eu5 Eu4 87.61(4) 9_454 9_454 ?
S10 Eu5 Ge4 39.81(4) 9_454 9_454 ?
S10 Eu5 S2 102.20(6) 9_454 2_665 ?
S10 Eu5 S5 70.46(6) 9_454 9_454 ?
S10 Eu5 S9 73.15(5) 9_454 . ?
O3 Eu5 Eu4 32.54(12) 9_454 9_454 ?
O3 Eu5 Ge4 31.22(13) 9_454 9_454 ?
O3 Eu5 S1 102.91(14) 9_454 . ?
O3 Eu5 S2 143.62(13) 9_454 2_665 ?
O3 Eu5 S2 144.50(13) 9_454 . ?
O3 Eu5 S5 72.19(13) 9_454 9_454 ?
O3 Eu5 S9 69.88(13) 9_454 . ?
O3 Eu5 S10 70.99(13) 9_454 9_454 ?
Ge3 Eu6 Ge4 170.72(3) 6_465 5_565 ?
S2 Eu6 Ge3 63.85(4) 6_465 6_465 ?
S2 Eu6 Ge4 106.96(4) 6_465 5_565 ?
S3 Eu6 Ge3 39.02(4) 6_465 6_465 ?
S3 Eu6 Ge4 138.35(5) 6_465 5_565 ?
S3 Eu6 S2 68.08(5) 6_465 6_465 ?
S3 Eu6 S5 77.65(6) 6_465 . ?
S3 Eu6 S6 120.15(6) 6_465 5_565 ?
S3 Eu6 S7 74.62(6) 6_465 8_665 ?
S3 Eu6 S8 74.49(6) 6_465 . ?
S3 Eu6 S10 150.14(6) 6_465 . ?
S4 Eu6 Ge3 150.65(5) 5_565 6_465 ?
S4 Eu6 Ge4 38.25(4) 5_565 5_565 ?
S4 Eu6 S2 144.77(6) 5_565 6_465 ?
S4 Eu6 S3 129.65(6) 5_565 6_465 ?
S4 Eu6 S5 137.07(6) 5_565 . ?
S4 Eu6 S6 76.50(6) 5_565 5_565 ?
S4 Eu6 S7 68.44(6) 5_565 8_665 ?
S4 Eu6 S8 76.05(6) 5_565 . ?
S4 Eu6 S10 77.77(6) 5_565 . ?
S5 Eu6 Ge3 38.65(4) . 6_465 ?
S5 Eu6 Ge4 141.82(5) . 5_565 ?
S5 Eu6 S2 70.31(6) . 6_465 ?
S5 Eu6 S6 122.09(6) . 5_565 ?
S5 Eu6 S7 151.62(6) . 8_665 ?
S5 Eu6 S8 83.01(6) . . ?
S5 Eu6 S10 73.00(6) . . ?
S6 Eu6 Ge3 132.52(4) 5_565 6_465 ?
S6 Eu6 Ge4 38.32(4) 5_565 5_565 ?
S6 Eu6 S2 68.68(5) 5_565 6_465 ?
S6 Eu6 S7 68.96(6) 5_565 8_665 ?
S6 Eu6 S8 151.88(6) 5_565 . ?
S6 Eu6 S10 73.02(6) 5_565 . ?
S7 Eu6 Ge3 113.52(4) 8_665 6_465 ?
S7 Eu6 Ge4 64.25(4) 8_665 5_565 ?
S7 Eu6 S2 93.58(6) 8_665 6_465 ?
S8 Eu6 Ge3 74.61(4) . 6_465 ?
S8 Eu6 Ge4 114.24(4) . 5_565 ?
S8 Eu6 S2 137.56(6) . 6_465 ?
S8 Eu6 S7 95.19(6) . 8_665 ?
S10 Eu6 Ge3 111.56(4) . 6_465 ?
S10 Eu6 Ge4 69.49(4) . 5_565 ?
S10 Eu6 S2 96.51(6) . 6_465 ?
S10 Eu6 S7 133.61(6) . 8_665 ?
S10 Eu6 S8 106.73(6) . . ?
Ge1 Ge1 Ge1 0(10) 2_675 3_465 ?
Ge1 Ge1 S8 0(10) 3_465 6_464 ?
Ge1 Ge1 S8 0(10) 3_465 4_454 ?
Ge1 Ge1 S8 0(10) 2_675 5_564 ?
Ge1 Ge1 S8 0(10) 2_675 6_464 ?
Ge1 Ge1 S8 0(10) 2_675 4_454 ?
Ge1 Ge1 S8 0(10) 3_465 5_564 ?
Ge1 Ge1 O1 0(10) 3_465 . ?
Ge1 Ge1 O1 0(10) 2_675 . ?
S8 Ge1 S8 113.62(6) 5_564 4_454 ?
S8 Ge1 S8 113.63(6) 6_464 5_564 ?
S8 Ge1 S8 113.63(6) 6_464 4_454 ?
O1 Ge1 S8 104.90(7) . 6_464 ?
O1 Ge1 S8 104.90(7) . 5_564 ?
O1 Ge1 S8 104.90(7) . 4_454 ?
S1 Ge2 S11 113.27(7) . 8_664 ?
S1 Ge2 S11 113.27(7) . 9_454 ?
S1 Ge2 S11 113.27(7) . 7_544 ?
S11 Ge2 S11 105.42(8) 8_664 7_544 ?
S11 Ge2 S11 105.42(8) 9_454 7_544 ?
S11 Ge2 S11 105.43(8) 9_454 8_664 ?
S3 Ge3 Eu2 110.01(6) . 8_664 ?
S3 Ge3 Eu6 56.51(6) . 8_664 ?
S5 Ge3 Eu2 55.86(6) 8_664 8_664 ?
S5 Ge3 Eu6 56.86(6) 8_664 8_664 ?
S5 Ge3 S3 113.33(9) 8_664 . ?
S5 Ge3 S7 108.71(8) 8_664 . ?
S7 Ge3 Eu2 54.63(6) . 8_664 ?
S7 Ge3 Eu6 117.73(6) . 8_664 ?
S7 Ge3 S3 102.78(8) . . ?
S9 Ge3 Eu2 141.63(7) . 8_664 ?
S9 Ge3 Eu6 131.58(6) . 8_664 ?
S9 Ge3 S3 107.77(9) . . ?
S9 Ge3 S5 113.46(9) . 8_664 ?
S9 Ge3 S7 110.26(8) . . ?
S4 Ge4 Eu5 121.26(6) . 5_565 ?
S4 Ge4 Eu6 53.84(5) . 9_454 ?
S4 Ge4 S6 111.18(8) . . ?
S6 Ge4 Eu5 122.97(6) . 5_565 ?
S6 Ge4 Eu6 57.47(6) . 9_454 ?
S10 Ge4 Eu5 62.88(6) . 5_565 ?
S10 Ge4 Eu6 140.36(7) . 9_454 ?
S10 Ge4 S4 116.32(8) . . ?
S10 Ge4 S6 112.50(8) . . ?
O3 Ge4 Eu5 44.35(17) . 5_565 ?
O3 Ge4 Eu6 112.47(17) . 9_454 ?
O3 Ge4 S4 104.10(18) . . ?
O3 Ge4 S6 104.42(18) . . ?
O3 Ge4 S10 107.17(18) . . ?
Ge5 Ge5 S2 161(10) 3_565 . ?
Ge5 Ge5 S2 58(10) 3_565 2_665 ?
Ge5 Ge5 S2 144(10) 2_665 . ?
Ge5 Ge5 S2 66(10) 3_565 3_565 ?
Ge5 Ge5 S2 91(10) 2_665 3_565 ?
Ge5 Ge5 S2 34(10) 2_665 2_665 ?
Ge5 Ge5 O2 90(8) 3_565 . ?
Ge5 Ge5 O2 90(8) 2_665 . ?
S2 Ge5 S2 110.31(7) . 2_665 ?
S2 Ge5 S2 110.31(7) 2_665 3_565 ?
S2 Ge5 S2 110.32(7) . 3_565 ?
O2 Ge5 S2 108.61(7) . 3_565 ?
O2 Ge5 S2 108.61(7) . 2_665 ?
O2 Ge5 S2 108.61(7) . . ?
Ge2 S1 Eu5 117.56(6) . 2_665 ?
Ge2 S1 Eu5 117.56(6) . 3_565 ?
Ge2 S1 Eu5 117.56(6) . . ?
Ge2 S1 Ca5 117.56(6) . . ?
Eu2 S2 Eu6 77.17(5) . 8_664 ?
Eu5 S2 Eu6 75.60(5) 3_565 8_664 ?
Eu5 S2 Eu6 143.61(7) . 8_664 ?
Ge5 S2 Eu2 76.97(7) 3_565 . ?
Ge5 S2 Eu2 76.97(7) . . ?
Ge5 S2 Eu2 76.97(7) 2_665 . ?
Ge5 S2 Eu5 86.82(7) 3_565 3_565 ?
Ge5 S2 Eu5 86.82(7) . 3_565 ?
Ge5 S2 Eu5 88.58(7) 3_565 . ?
Ge5 S2 Eu5 88.58(7) . . ?
Ge5 S2 Eu5 86.82(7) 2_665 3_565 ?
Ge5 S2 Eu5 88.58(7) 2_665 . ?
Ge5 S2 Eu6 124.45(8) 3_565 8_664 ?
Ge5 S2 Eu6 124.45(8) 2_665 8_664 ?
Ge5 S2 Eu6 124.45(8) . 8_664 ?
Ge5 S2 Ge5 0.00(8) 3_565 2_665 ?
Ge5 S2 Ge5 0.00(8) . 2_665 ?
Ge5 S2 Ge5 0.00(8) . 3_565 ?
Ge5 S2 Ca2 76.97(7) 3_565 . ?
Ge5 S2 Ca2 76.97(7) 2_665 . ?
Ge5 S2 Ca2 76.97(7) . . ?
Ge5 S2 Ca5 88.58(7) . . ?
Ge5 S2 Ca5 88.58(7) 3_565 . ?
Ge5 S2 Ca5 88.58(7) 2_665 . ?
Ca2 S2 Eu6 77.17(5) . 8_664 ?
Ca5 S2 Eu6 143.61(7) . 8_664 ?
Eu1 S3 Eu4 118.99(7) . 2_675 ?
Ge3 S3 Eu1 92.52(7) . . ?
Ge3 S3 Eu4 96.85(8) . 2_675 ?
Ge3 S3 Eu6 84.47(7) . 8_664 ?
Ge3 S3 Ca1 92.52(7) . . ?
Eu4 S4 Eu3 151.35(7) . 4_445 ?
Eu4 S4 Eu3 85.96(5) . 5_565 ?
Eu6 S4 Eu4 104.41(6) 9_454 . ?
Ge4 S4 Eu3 123.90(8) . 5_565 ?
Ge4 S4 Eu3 124.69(8) . 4_445 ?
Ge4 S4 Eu4 83.56(6) . . ?
Ge4 S4 Eu6 87.91(7) . 9_454 ?
Eu2 S5 Eu5 148.99(8) . 5_565 ?
Eu6 S5 Eu5 82.29(5) . 5_565 ?
Ge3 S5 Eu1 125.52(8) 6_465 . ?
Ge3 S5 Eu2 86.71(7) 6_465 . ?
Ge3 S5 Eu5 123.75(9) 6_465 5_565 ?
Ge3 S5 Eu6 84.49(7) 6_465 . ?
Ge3 S5 Ca1 125.52(8) 6_465 . ?
Ge3 S5 Ca2 86.71(7) 6_465 . ?
Ge3 S5 Ca6 84.49(7) 6_465 . ?
Ca2 S5 Eu5 148.99(8) . 5_565 ?
Ca6 S5 Eu5 82.29(5) . 5_565 ?
Eu1 S6 Ca2 157.06(7) . 2_665 ?
Eu2 S6 Ca2 81.54(5) . 2_665 ?
Eu6 S6 Ca2 81.44(5) 9_454 2_665 ?
Ge4 S6 Eu1 79.53(6) . . ?
Ge4 S6 Eu2 122.11(8) . . ?
Ge4 S6 Eu6 84.21(7) . 9_454 ?
Ge4 S6 Ca1 79.53(6) . . ?
Ge4 S6 Ca2 123.20(8) . 2_665 ?
Ge4 S6 Ca2 122.11(8) . . ?
Ca1 S6 Ca2 157.06(7) . 2_665 ?
Ca2 S6 Ca2 81.54(5) . 2_665 ?
Eu2 S7 Eu6 83.40(5) 8_664 6_464 ?
Eu3 S7 Eu6 84.38(5) . 6_464 ?
Ge3 S7 Eu2 87.82(7) . 8_664 ?
Ge3 S7 Eu3 85.43(7) . . ?
Ge3 S7 Eu4 93.08(7) . 2_675 ?
Ge3 S7 Eu6 124.82(8) . 6_464 ?
Ge3 S7 Ca3 85.43(7) . . ?
Ca3 S7 Eu6 84.38(5) . 6_464 ?
Ge1 S8 Eu2 109.56(9) 7_545 . ?
Ge1 S8 Eu3 76.76(7) 7_545 8_665 ?
Ge1 S8 Eu4 125.41(8) 7_545 4 ?
Ge1 S8 Eu6 121.60(8) 7_545 . ?
Ge1 S8 Ca2 109.56(9) 7_545 . ?
Ge1 S8 Ca6 121.60(8) 7_545 . ?
Eu1 S9 Eu4 148.70(7) . 9_454 ?
Ge3 S9 Eu1 88.08(7) . . ?
Ge3 S9 Eu3 84.32(7) . . ?
Ge3 S9 Eu4 122.47(8) . 9_454 ?
Ge3 S9 Eu5 120.42(8) . . ?
Ge3 S9 Ca1 88.08(7) . . ?
Ge3 S9 Ca5 120.42(8) . . ?
Ge3 S9 Ca3 84.32(7) . . ?
Eu1 S10 Eu4 85.91(5) 5_565 5_565 ?
Eu1 S10 Eu5 83.89(6) 5_565 5_565 ?
Eu4 S10 Eu5 169.66(8) 5_565 5_565 ?
Eu4 S10 Eu6 99.83(6) 5_565 . ?
Eu4 S10 Ca6 99.83(6) 5_565 . ?
Eu6 S10 Eu5 81.74(5) . 5_565 ?
Ge4 S10 Eu1 120.11(8) . 5_565 ?
Ge4 S10 Eu4 109.46(8) . 5_565 ?
Ge4 S10 Eu5 77.31(7) . 5_565 ?
Ge4 S10 Eu6 124.70(8) . . ?
Ge4 S10 Ca6 124.70(8) . . ?
Ca6 S10 Eu5 81.74(5) . 5_565 ?
Eu1 S11 Eu4 81.33(5) . . ?
Eu1 S11 Ca3 151.47(8) . 3_465 ?
Eu3 S11 Eu4 145.20(8) . . ?
Ge2 S11 Eu1 116.17(9) 4_455 . ?
Ge2 S11 Eu3 91.50(7) 4_455 . ?
Ge2 S11 Eu4 122.49(9) 4_455 . ?
Ge2 S11 Ca1 116.17(9) 4_455 . ?
Ge2 S11 Ca3 90.23(7) 4_455 3_465 ?
Ge2 S11 Ca3 91.50(7) 4_455 . ?
Ca1 S11 Eu4 81.33(5) . . ?
Ca3 S11 Eu4 93.84(6) 3_465 . ?
Ca3 S11 Eu4 145.20(8) . . ?
Ge1 O1 Eu3 111.68(19) 2_675 . ?
Ge1 O1 Eu3 111.68(19) . . ?
Ge1 O1 Eu3 111.68(19) 3_465 . ?
Ge1 O1 Ge1 0.0 3_465 2_675 ?
Ge1 O1 Ge1 0.0 3_465 . ?
Ge1 O1 Ge1 0.0 2_675 . ?
Ge1 O1 Ca3 111.68(19) 2_675 3_465 ?
Ge1 O1 Ca3 111.68(19) 3_465 3_465 ?
Ge1 O1 Ca3 111.68(19) 3_465 2_675 ?
Ge1 O1 Ca3 111.68(19) 3_465 . ?
Ge1 O1 Ca3 111.68(19) 2_675 2_675 ?
Ge1 O1 Ca3 111.68(19) 2_675 . ?
Ge1 O1 Ca3 111.68(19) . . ?
Ge1 O1 Ca3 111.68(19) . 3_465 ?
Ge1 O1 Ca3 111.68(19) . 2_675 ?
Ca3 O1 Ca3 107.2(2) 2_675 . ?
Eu2 O2 Ca2 115.06(16) . 2_665 ?
Ge5 O2 Eu2 103.0(2) 3_565 . ?
Ge5 O2 Eu2 103.0(2) . . ?
Ge5 O2 Eu2 103.0(2) 2_665 . ?
Ge5 O2 Ge5 0.0 2_665 . ?
Ge5 O2 Ge5 0.0 3_565 . ?
Ge5 O2 Ge5 0.0 3_565 2_665 ?
Ge5 O2 Ca2 103.0(2) 3_565 3_565 ?
Ge5 O2 Ca2 103.0(2) 3_565 . ?
Ge5 O2 Ca2 103.0(2) 2_665 . ?
Ge5 O2 Ca2 103.0(2) . 3_565 ?
Ge5 O2 Ca2 103.0(2) 2_665 2_665 ?
Ge5 O2 Ca2 103.0(2) . . ?
Ge5 O2 Ca2 103.0(2) . 2_665 ?
Ge5 O2 Ca2 103.0(2) 2_665 3_565 ?
Ge5 O2 Ca2 103.0(2) 3_565 2_665 ?
Ca2 O2 Ca2 115.06(16) . 2_665 ?
Eu1 O3 Eu4 107.01(19) . . ?
Eu5 O3 Eu4 117.7(2) 5_565 . ?
Ge4 O3 Eu1 106.7(2) . . ?
Ge4 O3 Eu4 104.2(2) . . ?
Ge4 O3 Eu5 104.4(2) . 5_565 ?
Ge4 O3 Ca1 106.7(2) . . ?
Ca1 O3 Eu4 107.01(19) . . ?
S3 Ca1 S5 73.63(6) . . ?
S3 Ca1 S6 116.69(6) . . ?
S3 Ca1 S9 71.63(6) . . ?
S3 Ca1 S10 143.94(6) . 9_454 ?
S3 Ca1 S11 106.50(6) . . ?
S6 Ca1 S5 70.84(6) . . ?
S6 Ca1 S9 118.71(6) . . ?
S6 Ca1 S11 136.07(6) . . ?
S9 Ca1 S5 144.27(6) . . ?
S10 Ca1 S5 138.18(6) 9_454 . ?
S10 Ca1 S6 73.36(5) 9_454 . ?
S10 Ca1 S9 73.47(5) 9_454 . ?
S10 Ca1 S11 76.66(6) 9_454 . ?
S11 Ca1 S5 116.80(6) . . ?
S11 Ca1 S9 81.36(6) . . ?
O3 Ca1 S3 139.15(13) . . ?
O3 Ca1 S5 70.96(12) . . ?
O3 Ca1 S6 69.31(13) . . ?
O3 Ca1 S9 144.39(12) . . ?
O3 Ca1 S10 76.74(13) . 9_454 ?
O3 Ca1 S11 73.10(13) . . ?
Ge3 Ca2 Ca2 142.80(2) 6_465 3_565 ?
Ge3 Ca2 Ca2 145.72(2) 6_465 2_665 ?
Ge5 Ca2 Ge3 155.56(3) 3_565 6_465 ?
Ge5 Ca2 Ge3 155.56(3) 2_665 6_465 ?
Ge5 Ca2 Ge5 0.0 3_565 2_665 ?
Ge5 Ca2 Ca2 52.055(17) 2_665 3_565 ?
Ge5 Ca2 Ca2 52.055(17) 2_665 2_665 ?
Ge5 Ca2 Ca2 52.055(16) 3_565 3_565 ?
Ge5 Ca2 Ca2 52.055(17) 3_565 2_665 ?
S2 Ca2 Ge3 115.94(4) . 6_465 ?
S2 Ca2 Ge5 39.64(4) . 3_565 ?
S2 Ca2 Ge5 39.64(4) . 2_665 ?
S2 Ca2 S6 70.56(6) . 3_565 ?
S2 Ca2 S6 72.48(6) . . ?
S2 Ca2 Ca2 84.62(4) . 3_565 ?
S2 Ca2 Ca2 85.67(4) . 2_665 ?
S5 Ca2 Ge3 37.42(4) . 6_465 ?
S5 Ca2 Ge5 134.76(5) . 3_565 ?
S5 Ca2 Ge5 134.76(5) . 2_665 ?
S5 Ca2 S2 106.84(6) . . ?
S5 Ca2 S6 71.91(5) . . ?
S5 Ca2 S6 140.67(6) . 3_565 ?
S5 Ca2 Ca2 166.79(4) . 3_565 ?
S5 Ca2 Ca2 113.31(5) . 2_665 ?
S6 Ca2 Ge3 109.22(4) . 6_465 ?
S6 Ca2 Ge3 106.55(4) 3_565 6_465 ?
S6 Ca2 Ge5 68.89(4) . 3_565 ?
S6 Ca2 Ge5 68.89(4) . 2_665 ?
S6 Ca2 Ge5 68.48(4) 3_565 2_665 ?
S6 Ca2 Ge5 68.48(4) 3_565 3_565 ?
S6 Ca2 S6 136.80(7) . 3_565 ?
S6 Ca2 Ca2 49.62(4) . 2_665 ?
S6 Ca2 Ca2 48.84(4) 3_565 3_565 ?
S6 Ca2 Ca2 106.43(4) . 3_565 ?
S6 Ca2 Ca2 105.70(4) 3_565 2_665 ?
S7 Ca2 Ge3 37.55(4) 6_465 6_465 ?
S7 Ca2 Ge5 131.81(4) 6_465 2_665 ?
S7 Ca2 Ge5 131.81(4) 6_465 3_565 ?
S7 Ca2 S2 104.09(6) 6_465 . ?
S7 Ca2 S5 74.02(6) 6_465 . ?
S7 Ca2 S6 142.78(6) 6_465 . ?
S7 Ca2 S6 69.05(6) 6_465 3_565 ?
S7 Ca2 S8 81.04(6) 6_465 . ?
S7 Ca2 Ca2 165.91(4) 6_465 2_665 ?
S7 Ca2 Ca2 110.15(5) 6_465 3_565 ?
S8 Ca2 Ge3 74.65(4) . 6_465 ?
S8 Ca2 Ge5 129.55(5) . 2_665 ?
S8 Ca2 Ge5 129.55(5) . 3_565 ?
S8 Ca2 S2 168.19(6) . . ?
S8 Ca2 S5 84.72(6) . . ?
S8 Ca2 S6 109.99(6) . . ?
S8 Ca2 S6 102.14(6) . 3_565 ?
S8 Ca2 Ca2 83.62(4) . 3_565 ?
S8 Ca2 Ca2 87.55(4) . 2_665 ?
O2 Ca2 Ge3 172.5(2) . 6_465 ?
O2 Ca2 Ge5 31.7(2) . 3_565 ?
O2 Ca2 Ge5 31.7(2) . 2_665 ?
O2 Ca2 S2 71.3(2) . . ?
O2 Ca2 S5 144.68(5) . . ?
O2 Ca2 S6 73.46(7) . 3_565 ?
O2 Ca2 S6 74.17(7) . . ?
O2 Ca2 S7 141.28(5) . 6_465 ?
O2 Ca2 S8 97.9(2) . . ?
O2 Ca2 Ca2 32.47(8) . 3_565 ?
O2 Ca2 Ca2 32.47(8) . 2_665 ?
Ge4 Ca5 Eu4 52.878(19) 9_454 9_454 ?
S1 Ca5 Eu4 88.63(6) . 9_454 ?
S1 Ca5 Ge4 134.12(7) . 9_454 ?
S1 Ca5 S2 81.89(7) . . ?
S1 Ca5 S2 80.71(7) . 2_665 ?
S1 Ca5 S5 104.91(5) . 9_454 ?
S1 Ca5 S9 108.22(5) . . ?
S1 Ca5 S10 173.10(7) . 9_454 ?
S2 Ca5 Eu4 114.25(4) . 9_454 ?
S2 Ca5 Eu4 167.01(4) 2_665 9_454 ?
S2 Ca5 Ge4 132.31(5) 2_665 9_454 ?
S2 Ca5 Ge4 132.84(5) . 9_454 ?
S2 Ca5 S2 71.76(8) . 2_665 ?
S2 Ca5 S5 71.94(5) 2_665 9_454 ?
S2 Ca5 S5 141.32(6) . 9_454 ?
S2 Ca5 S9 75.19(6) . . ?
S2 Ca5 S10 104.94(6) . 9_454 ?
S5 Ca5 Eu4 104.05(4) 9_454 9_454 ?
S5 Ca5 Ge4 68.24(4) 9_454 9_454 ?
S9 Ca5 Eu4 46.88(4) . 9_454 ?
S9 Ca5 Ge4 65.73(4) . 9_454 ?
S9 Ca5 S2 144.11(6) . 2_665 ?
S9 Ca5 S5 133.92(6) . 9_454 ?
S10 Ca5 Eu4 87.61(4) 9_454 9_454 ?
S10 Ca5 Ge4 39.81(4) 9_454 9_454 ?
S10 Ca5 S2 102.20(6) 9_454 2_665 ?
S10 Ca5 S5 70.46(6) 9_454 9_454 ?
S10 Ca5 S9 73.15(5) 9_454 . ?
O3 Ca5 Eu4 32.54(12) 9_454 9_454 ?
O3 Ca5 Ge4 31.22(13) 9_454 9_454 ?
O3 Ca5 S1 102.91(14) 9_454 . ?
O3 Ca5 S2 144.50(13) 9_454 . ?
O3 Ca5 S2 143.62(13) 9_454 2_665 ?
O3 Ca5 S5 72.19(13) 9_454 9_454 ?
O3 Ca5 S9 69.88(13) 9_454 . ?
O3 Ca5 S10 70.99(13) 9_454 9_454 ?
Ge3 Ca6 Ge4 170.72(3) 6_465 5_565 ?
S2 Ca6 Ge3 63.85(4) 6_465 6_465 ?
S2 Ca6 Ge4 106.96(4) 6_465 5_565 ?
S3 Ca6 Ge3 39.02(4) 6_465 6_465 ?
S3 Ca6 Ge4 138.35(5) 6_465 5_565 ?
S3 Ca6 S2 68.08(5) 6_465 6_465 ?
S3 Ca6 S5 77.65(6) 6_465 . ?
S3 Ca6 S6 120.15(6) 6_465 5_565 ?
S3 Ca6 S7 74.62(6) 6_465 8_665 ?
S3 Ca6 S8 74.49(6) 6_465 . ?
S3 Ca6 S10 150.14(6) 6_465 . ?
S4 Ca6 Ge3 150.65(5) 5_565 6_465 ?
S4 Ca6 Ge4 38.25(4) 5_565 5_565 ?
S4 Ca6 S2 144.77(6) 5_565 6_465 ?
S4 Ca6 S3 129.65(6) 5_565 6_465 ?
S4 Ca6 S5 137.07(6) 5_565 . ?
S4 Ca6 S6 76.50(6) 5_565 5_565 ?
S4 Ca6 S7 68.44(6) 5_565 8_665 ?
S4 Ca6 S8 76.05(6) 5_565 . ?
S4 Ca6 S10 77.77(6) 5_565 . ?
S5 Ca6 Ge3 38.65(4) . 6_465 ?
S5 Ca6 Ge4 141.82(5) . 5_565 ?
S5 Ca6 S2 70.31(6) . 6_465 ?
S5 Ca6 S6 122.09(6) . 5_565 ?
S5 Ca6 S7 151.62(6) . 8_665 ?
S5 Ca6 S8 83.01(6) . . ?
S5 Ca6 S10 73.00(6) . . ?
S6 Ca6 Ge3 132.52(4) 5_565 6_465 ?
S6 Ca6 Ge4 38.32(4) 5_565 5_565 ?
S6 Ca6 S2 68.68(5) 5_565 6_465 ?
S6 Ca6 S7 68.96(6) 5_565 8_665 ?
S6 Ca6 S8 151.88(6) 5_565 . ?
S6 Ca6 S10 73.02(6) 5_565 . ?
S7 Ca6 Ge3 113.52(4) 8_665 6_465 ?
S7 Ca6 Ge4 64.25(4) 8_665 5_565 ?
S7 Ca6 S2 93.58(6) 8_665 6_465 ?
S8 Ca6 Ge3 74.61(4) . 6_465 ?
S8 Ca6 Ge4 114.24(4) . 5_565 ?
S8 Ca6 S2 137.56(6) . 6_465 ?
S8 Ca6 S7 95.19(6) . 8_665 ?
S10 Ca6 Ge3 111.56(4) . 6_465 ?
S10 Ca6 Ge4 69.49(4) . 5_565 ?
S10 Ca6 S2 96.51(6) . 6_465 ?
S10 Ca6 S7 133.61(6) . 8_665 ?
S10 Ca6 S8 106.73(6) . . ?
Ge1 Ca3 Ge1 0.0 3_465 2_675 ?
Ge1 Ca3 Ca3 56.229(15) 3_465 2_675 ?
Ge1 Ca3 Ca3 56.229(15) 3_465 3_465 ?
Ge1 Ca3 Ca3 56.229(15) 2_675 2_675 ?
Ge1 Ca3 Ca3 56.229(15) 2_675 3_465 ?
S4 Ca3 Ge1 67.70(4) 7_554 3_465 ?
S4 Ca3 Ge1 68.94(4) 9_454 3_465 ?
S4 Ca3 Ge1 68.94(4) 9_454 2_675 ?
S4 Ca3 Ge1 67.70(4) 7_554 2_675 ?
S4 Ca3 S4 135.17(8) 9_454 7_554 ?
S4 Ca3 S8 69.60(5) 9_454 6_464 ?
S4 Ca3 Ca3 54.16(4) 9_454 3_465 ?
S4 Ca3 Ca3 51.40(4) 7_554 2_675 ?
S4 Ca3 Ca3 109.90(4) 9_454 2_675 ?
S4 Ca3 Ca3 107.36(4) 7_554 3_465 ?
S7 Ca3 Ge1 124.85(4) . 3_465 ?
S7 Ca3 Ge1 124.85(4) . 2_675 ?
S7 Ca3 S4 136.85(6) . 9_454 ?
S7 Ca3 S4 66.17(5) . 7_554 ?
S7 Ca3 S8 96.93(6) . 6_464 ?
S7 Ca3 S9 74.74(6) . . ?
S7 Ca3 S11 82.87(6) . 2_675 ?
S7 Ca3 S11 125.45(6) . . ?
S7 Ca3 Ca3 110.45(5) . 2_675 ?
S7 Ca3 Ca3 168.90(4) . 3_465 ?
S8 Ca3 Ge1 38.26(4) 6_464 2_675 ?
S8 Ca3 Ge1 38.26(4) 6_464 3_465 ?
S8 Ca3 S4 69.60(5) 6_464 7_554 ?
S8 Ca3 Ca3 88.37(4) 6_464 2_675 ?
S8 Ca3 Ca3 88.73(4) 6_464 3_465 ?
S9 Ca3 Ge1 127.31(4) . 2_675 ?
S9 Ca3 Ge1 127.31(4) . 3_465 ?
S9 Ca3 S4 136.62(5) . 7_554 ?
S9 Ca3 S4 67.45(5) . 9_454 ?
S9 Ca3 S8 98.25(6) . 6_464 ?
S9 Ca3 S11 124.83(6) . 2_675 ?
S9 Ca3 S11 84.13(6) . . ?
S9 Ca3 Ca3 171.15(4) . 2_675 ?
S9 Ca3 Ca3 114.00(4) . 3_465 ?
S11 Ca3 Ge1 108.09(5) . 3_465 ?
S11 Ca3 Ge1 106.98(5) 2_675 2_675 ?
S11 Ca3 Ge1 106.98(5) 2_675 3_465 ?
S11 Ca3 Ge1 108.09(5) . 2_675 ?
S11 Ca3 S4 136.17(6) 2_675 9_454 ?
S11 Ca3 S4 69.00(5) 2_675 7_554 ?
S11 Ca3 S4 134.03(5) . 7_554 ?
S11 Ca3 S4 71.14(6) . 9_454 ?
S11 Ca3 S8 136.08(6) . 6_464 ?
S11 Ca3 S8 134.56(6) 2_675 6_464 ?
S11 Ca3 S11 69.15(8) . 2_675 ?
S11 Ca3 Ca3 51.86(4) . 3_465 ?
S11 Ca3 Ca3 86.36(4) 2_675 3_465 ?
S11 Ca3 Ca3 87.02(4) . 2_675 ?
S11 Ca3 Ca3 50.75(4) 2_675 2_675 ?
O1 Ca3 Ge1 28.4(2) . 2_675 ?
O1 Ca3 Ge1 28.4(2) . 3_465 ?
O1 Ca3 S4 74.88(7) . 9_454 ?
O1 Ca3 S4 72.58(6) . 7_554 ?
O1 Ca3 S7 138.73(7) . . ?
O1 Ca3 S8 66.6(2) . 6_464 ?
O1 Ca3 S9 142.31(7) . . ?
O1 Ca3 S11 83.77(17) . 2_675 ?
O1 Ca3 S11 84.84(17) . . ?
O1 Ca3 Ca3 36.41(11) . 2_675 ?
O1 Ca3 Ca3 36.41(11) . 3_465 ?


_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC2
_database_code_depnum_ccdc_archive 'CCDC 2329239'
loop_
_audit_author_name
_audit_author_address
'Sheng-Ping Guo'
;Yangzhou University
China
;
_audit_update_record             
;
2024-06-28 deposited with the CCDC.	2024-07-04 downloaded from the CCDC.
;
_audit_creation_date             2024-06-26
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Ba3 Eu15 Ge9 O5 S31'
_chemical_formula_sum            'Ba3 Eu15 Ge9 O5 S31'
_chemical_formula_weight         4418.59
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ba Ba -0.3244 2.2819 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_H-M_alt        'R 3'
_space_group_name_Hall           'R 3'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'

_cell_length_a                   16.8834(7)
_cell_length_b                   16.8834(7)
_cell_length_c                   18.0091(8)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     4445.7(4)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    9950
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.41
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    23.148
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5452
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1234 before and 0.0603 after correction.
The Ratio of minimum to maximum transmission is 0.7312.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    4.951
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5811
_exptl_crystal_size_max          0.02
_exptl_crystal_size_mid          0.015
_exptl_crystal_size_min          0.01
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0379
_diffrn_reflns_av_unetI/netI     0.0285
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            19013
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.018
_diffrn_reflns_theta_max         25.018
_diffrn_reflns_theta_min         1.794
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.999
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.999
_reflns_number_gt                3449
_reflns_number_total             3514
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS  (Sheldrick, 2008)'
_refine_diff_density_max         2.286
_refine_diff_density_min         -2.548
_refine_diff_density_rms         0.384
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.09(3)
_refine_ls_extinction_coef       0.000545(18)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.187
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     192
_refine_ls_number_reflns         3514
_refine_ls_number_restraints     13
_refine_ls_R_factor_all          0.0291
_refine_ls_R_factor_gt           0.0283
_refine_ls_restrained_S_all      1.186
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0253P)²+245.8606P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0693
_refine_ls_wR_factor_ref         0.0701
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.91(3)
 0.09(3)
2. Uiso/Uaniso restraints and constraints
Uanis(O2) \\sim Ueq, Uanis(S10) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ba1 Ba 0.84525(7) 0.84432(7) 0.53097(7) 0.0055(3) Uani 1 1 d . . . . .
Eu1 Eu 0.68864(8) 0.82373(7) 0.34536(5) 0.0143(3) Uani 1 1 d . . . . .
Eu2 Eu 0.47977(7) 0.80539(7) 0.47984(6) 0.0136(3) Uani 1 1 d . . . . .
Eu3 Eu 0.81967(8) 0.67266(9) 0.34137(6) 0.0136(3) Uani 1 1 d . . . . .
Eu4 Eu 0.79530(7) 0.47147(7) 0.49286(6) 0.0120(3) Uani 1 1 d . . . . .
Eu5 Eu 0.98930(7) 0.49864(8) 0.34063(6) 0.0135(3) Uani 1 1 d . . . . .
Ge1 Ge 0.333333 0.666667 0.67766(19) 0.0070(7) Uani 1 3 d S T P . .
Ge2 Ge 1.000000 1.000000 0.3329(2) 0.0091(8) Uani 1 3 d S T P . .
Ge3 Ge 0.65418(14) 0.65472(14) 0.47214(12) 0.0063(4) Uani 1 1 d . . . . .
Ge4 Ge 0.99330(14) 0.67695(14) 0.54941(12) 0.0093(5) Uani 1 1 d . . . . .
Ge5 Ge 1.000000 1.000000 0.6804(2) 0.0070(7) Uani 1 3 d S T P . .
S1 S 1.000000 1.000000 0.4542(5) 0.0157(18) Uani 1 3 d S T P . .
S2 S 0.6584(3) 0.5330(3) 0.4323(3) 0.0106(10) Uani 1 1 d . . . . .
S3 S 0.3419(3) 0.8748(3) 0.4274(3) 0.0111(10) Uani 1 1 d . . . . .
S4 S 0.8824(3) 0.8767(4) 0.2845(3) 0.0158(11) Uani 1 1 d . . . . .
S5 S 0.9980(3) 0.8748(3) 0.6411(3) 0.0117(10) Uani 1 1 d . . . . .
S6 S 0.8683(3) 0.6744(3) 0.5121(3) 0.0120(10) Uani 1 1 d . . . . .
S7 S 0.9960(3) 0.5545(3) 0.5088(3) 0.0114(10) Uani 1 1 d . . . . .
S8 S 0.4570(3) 0.7968(3) 0.6454(3) 0.0135(10) Uani 1 1 d . . . . .
S9 S 0.6807(3) 0.8806(3) 0.5128(3) 0.0114(10) Uani 1 1 d . . . . .
S10 S 0.6696(3) 0.6790(3) 0.5927(3) 0.0095(10) Uani 1 1 d . U . . .
S11 S 0.9843(3) 0.6584(3) 0.6718(3) 0.0122(10) Uani 1 1 d . . . . .
O1 O 0.7508(10) 0.7502(9) 0.4272(7) 0.013(3) Uani 1 1 d . . . . .
O2 O 0.333333 0.666667 0.7778(12) 0.0078(18) Uani 1 3 d S TU P . .
O3 O 1.000000 1.000000 0.7823(12) 0.009(5) Uani 1 3 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ba1 Ba1 4.5389(19) 3_675 ?
Ba1 Ba1 4.5390(19) 2_765 ?
Ba1 Eu1 4.0622(16) 6_565 ?
Ba1 Eu5 4.0278(16) 4_455 ?
Ba1 S1 2.963(4) . ?
Ba1 S5 3.086(5) . ?
Ba1 S5 3.145(5) 3_675 ?
Ba1 S6 3.101(5) . ?
Ba1 S9 3.147(5) . ?
Ba1 S10 3.089(5) . ?
Ba1 O1 2.455(14) . ?
Eu1 Eu4 4.4098(15) 8_654 ?
Eu1 S3 3.093(5) 3_565 ?
Eu1 S4 3.127(5) . ?
Eu1 S6 3.154(5) 8_654 ?
Eu1 S9 3.188(5) . ?
Eu1 S10 3.000(5) 8_654 ?
Eu1 S11 2.975(5) 8_654 ?
Eu1 O1 2.473(13) . ?
Eu2 Eu2 4.1740(19) 3_565 ?
Eu2 Eu2 4.1741(19) 2_665 ?
Eu2 Eu5 4.1012(16) 3_675 ?
Eu2 Ge4 3.643(2) 3_675 ?
Eu2 Ge5 3.395(3) 7_444 ?
Eu2 S3 3.226(5) . ?
Eu2 S3 3.179(5) 3_565 ?
Eu2 S5 3.116(5) 8_654 ?
Eu2 S7 2.971(5) 3_675 ?
Eu2 S8 3.001(5) . ?
Eu2 S9 3.028(5) . ?
Eu2 O3 2.473(5) 7_444 ?
Eu3 S2 3.039(5) . ?
Eu3 S4 3.224(5) . ?
Eu3 S6 3.179(5) . ?
Eu3 S7 3.234(5) 9_664 ?
Eu3 S8 3.353(5) 7_544 ?
Eu3 S10 3.052(5) 8_654 ?
Eu3 S11 3.092(5) 9_664 ?
Eu3 O1 2.641(13) . ?
Eu4 Eu4 3.9079(17) 2_655 ?
Eu4 Eu4 3.9079(17) 3_665 ?
Eu4 Ge1 3.500(3) 7_544 ?
Eu4 S2 3.274(5) 3_665 ?
Eu4 S2 3.163(5) . ?
Eu4 S4 3.142(5) 5_655 ?
Eu4 S4 3.089(5) 6_565 ?
Eu4 S6 3.026(5) . ?
Eu4 S7 2.963(5) . ?
Eu4 S8 3.258(5) 7_544 ?
Eu4 O2 2.419(8) 7_544 ?
Eu5 Ge3 3.577(2) 3_665 ?
Eu5 Ge4 3.546(2) 9_664 ?
Eu5 S2 2.894(5) 3_665 ?
Eu5 S3 3.035(5) 2_765 ?
Eu5 S5 3.433(5) 9_664 ?
Eu5 S7 3.157(5) . ?
Eu5 S8 3.148(5) 7_544 ?
Eu5 S9 2.988(5) 7_544 ?
Eu5 S10 3.076(5) 7_544 ?
Eu5 S11 2.962(5) 9_664 ?
Ge1 S8 2.222(5) 2_665 ?
Ge1 S8 2.222(5) . ?
Ge1 S8 2.222(5) 3_565 ?
Ge1 O2 1.80(2) . ?
Ge2 S1 2.184(9) . ?
Ge2 S4 2.213(5) . ?
Ge2 S4 2.213(5) 2_765 ?
Ge2 S4 2.213(5) 3_675 ?
Ge3 S2 2.212(5) . ?
Ge3 S3 2.229(5) 3_565 ?
Ge3 S10 2.202(5) . ?
Ge3 O1 1.813(14) . ?
Ge4 S6 2.194(5) . ?
Ge4 S7 2.215(5) . ?
Ge4 S9 2.205(5) 2_765 ?
Ge4 S11 2.220(5) . ?
Ge5 Ge5 0.000(8) 3_675 ?
Ge5 Ge5 0.000(8) 2_765 ?
Ge5 S5 2.214(5) 2_765 ?
Ge5 S5 2.214(5) 3_675 ?
Ge5 S5 2.214(5) . ?
Ge5 O3 1.83(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ba1 Ba1 Ba1 60.0 3_675 2_765 ?
Eu1 Ba1 Ba1 136.03(2) 6_565 3_675 ?
Eu1 Ba1 Ba1 99.23(3) 6_565 2_765 ?
Eu5 Ba1 Ba1 133.27(2) 4_455 2_765 ?
Eu5 Ba1 Ba1 92.34(3) 4_455 3_675 ?
Eu5 Ba1 Eu1 74.26(3) 4_455 6_565 ?
S1 Ba1 Ba1 40.01(9) . 3_675 ?
S1 Ba1 Ba1 40.01(9) . 2_765 ?
S1 Ba1 Eu1 139.03(8) . 6_565 ?
S1 Ba1 Eu5 132.01(8) . 4_455 ?
S1 Ba1 S5 81.92(15) . . ?
S1 Ba1 S5 80.94(15) . 3_675 ?
S1 Ba1 S6 107.86(11) . . ?
S1 Ba1 S9 104.57(11) . . ?
S1 Ba1 S10 172.65(16) . . ?
S5 Ba1 Ba1 43.75(10) . 2_765 ?
S5 Ba1 Ba1 81.93(9) . 3_675 ?
S5 Ba1 Ba1 81.34(9) 3_675 2_765 ?
S5 Ba1 Ba1 42.73(9) 3_675 3_675 ?
S5 Ba1 Eu1 60.43(10) . 6_565 ?
S5 Ba1 Eu1 99.98(9) 3_675 6_565 ?
S5 Ba1 Eu5 99.97(10) . 4_455 ?
S5 Ba1 Eu5 55.57(9) 3_675 4_455 ?
S5 Ba1 S5 71.34(18) . 3_675 ?
S5 Ba1 S6 75.13(13) . . ?
S5 Ba1 S9 72.11(12) 3_675 . ?
S5 Ba1 S9 141.25(13) . . ?
S5 Ba1 S10 105.28(13) . . ?
S6 Ba1 Ba1 143.54(9) . 3_675 ?
S6 Ba1 Ba1 84.05(9) . 2_765 ?
S6 Ba1 Eu1 50.08(10) . 6_565 ?
S6 Ba1 Eu5 119.05(10) . 4_455 ?
S6 Ba1 S5 143.71(13) . 3_675 ?
S6 Ba1 S9 134.46(13) . . ?
S9 Ba1 Ba1 79.99(10) . 3_675 ?
S9 Ba1 Ba1 139.57(10) . 2_765 ?
S9 Ba1 Eu1 114.75(10) . 6_565 ?
S9 Ba1 Eu5 47.28(10) . 4_455 ?
S10 Ba1 Ba1 141.24(10) . 3_675 ?
S10 Ba1 Ba1 146.45(10) . 2_765 ?
S10 Ba1 Eu1 47.22(9) . 6_565 ?
S10 Ba1 Eu5 49.06(9) . 4_455 ?
S10 Ba1 S5 102.56(13) . 3_675 ?
S10 Ba1 S6 73.22(13) . . ?
S10 Ba1 S9 70.82(13) . . ?
O1 Ba1 Ba1 124.3(3) . 2_765 ?
O1 Ba1 Ba1 124.0(3) . 3_675 ?
O1 Ba1 Eu1 99.9(3) . 6_565 ?
O1 Ba1 Eu5 102.2(3) . 4_455 ?
O1 Ba1 S1 102.6(4) . . ?
O1 Ba1 S5 144.6(3) . . ?
O1 Ba1 S5 143.9(3) . 3_675 ?
O1 Ba1 S6 70.1(3) . . ?
O1 Ba1 S9 72.3(3) . . ?
O1 Ba1 S10 70.7(3) . . ?
Ba1 Eu1 Eu4 89.28(3) 8_654 8_654 ?
S3 Eu1 Ba1 70.82(9) 3_565 8_654 ?
S3 Eu1 Eu4 158.82(10) 3_565 8_654 ?
S3 Eu1 S4 136.16(13) 3_565 . ?
S3 Eu1 S6 119.03(13) 3_565 8_654 ?
S3 Eu1 S9 71.09(13) 3_565 . ?
S4 Eu1 Ba1 111.48(11) . 8_654 ?
S4 Eu1 Eu4 44.46(10) . 8_654 ?
S4 Eu1 S6 81.78(13) . 8_654 ?
S4 Eu1 S9 116.15(14) . . ?
S6 Eu1 Ba1 48.92(9) 8_654 8_654 ?
S6 Eu1 Eu4 43.32(9) 8_654 8_654 ?
S6 Eu1 S9 143.65(13) 8_654 . ?
S9 Eu1 Ba1 131.98(10) . 8_654 ?
S9 Eu1 Eu4 129.78(10) . 8_654 ?
S10 Eu1 Ba1 49.10(10) 8_654 8_654 ?
S10 Eu1 Eu4 87.84(10) 8_654 8_654 ?
S10 Eu1 S3 73.79(13) 8_654 3_565 ?
S10 Eu1 S4 76.80(14) 8_654 . ?
S10 Eu1 S6 73.66(13) 8_654 8_654 ?
S10 Eu1 S9 138.83(13) 8_654 . ?
S11 Eu1 Ba1 99.07(10) 8_654 8_654 ?
S11 Eu1 Eu4 72.60(10) 8_654 8_654 ?
S11 Eu1 S3 116.62(14) 8_654 3_565 ?
S11 Eu1 S4 106.40(14) 8_654 . ?
S11 Eu1 S6 71.04(13) 8_654 8_654 ?
S11 Eu1 S9 73.50(13) 8_654 . ?
S11 Eu1 S10 143.58(14) 8_654 8_654 ?
O1 Eu1 Ba1 119.2(3) . 8_654 ?
O1 Eu1 Eu4 117.4(3) . 8_654 ?
O1 Eu1 S3 69.2(3) . 3_565 ?
O1 Eu1 S4 72.9(3) . . ?
O1 Eu1 S6 144.6(3) . 8_654 ?
O1 Eu1 S9 71.3(3) . . ?
O1 Eu1 S10 76.6(3) . 8_654 ?
O1 Eu1 S11 139.6(3) . 8_654 ?
Eu2 Eu2 Eu2 60.0 3_565 2_665 ?
Eu5 Eu2 Eu2 93.93(4) 3_675 2_665 ?
Eu5 Eu2 Eu2 135.81(2) 3_675 3_565 ?
Ge4 Eu2 Eu2 142.73(5) 3_675 2_665 ?
Ge4 Eu2 Eu2 146.05(5) 3_675 3_565 ?
Ge4 Eu2 Eu5 76.28(4) 3_675 3_675 ?
Ge5 Eu2 Eu2 52.06(4) 7_444 3_565 ?
Ge5 Eu2 Eu2 52.06(4) 7_444 2_665 ?
Ge5 Eu2 Eu5 83.77(5) 7_444 3_675 ?
Ge5 Eu2 Ge4 155.29(7) 7_444 3_675 ?
S3 Eu2 Eu2 48.85(9) . 2_665 ?
S3 Eu2 Eu2 106.68(9) 3_565 2_665 ?
S3 Eu2 Eu2 49.82(9) 3_565 3_565 ?
S3 Eu2 Eu2 105.77(9) . 3_565 ?
S3 Eu2 Eu5 121.11(10) 3_565 3_675 ?
S3 Eu2 Eu5 47.09(9) . 3_675 ?
S3 Eu2 Ge4 109.13(10) 3_565 3_675 ?
S3 Eu2 Ge4 106.18(9) . 3_675 ?
S3 Eu2 Ge5 68.62(9) . 7_444 ?
S3 Eu2 Ge5 69.14(9) 3_565 7_444 ?
S3 Eu2 S3 137.19(17) 3_565 . ?
S5 Eu2 Eu2 84.37(9) 8_654 2_665 ?
S5 Eu2 Eu2 85.64(9) 8_654 3_565 ?
S5 Eu2 Eu5 54.78(9) 8_654 3_675 ?
S5 Eu2 Ge4 115.83(10) 8_654 3_675 ?
S5 Eu2 Ge5 39.47(10) 8_654 7_444 ?
S5 Eu2 S3 70.47(13) 8_654 . ?
S5 Eu2 S3 72.79(13) 8_654 3_565 ?
S7 Eu2 Eu2 110.17(11) 3_675 2_665 ?
S7 Eu2 Eu2 166.16(10) 3_675 3_565 ?
S7 Eu2 Eu5 49.96(9) 3_675 3_675 ?
S7 Eu2 Ge4 37.41(10) 3_675 3_675 ?
S7 Eu2 Ge5 131.52(10) 3_675 7_444 ?
S7 Eu2 S3 68.81(13) 3_675 . ?
S7 Eu2 S3 142.47(14) 3_675 3_565 ?
S7 Eu2 S5 103.72(13) 3_675 8_654 ?
S7 Eu2 S8 81.61(13) 3_675 . ?
S7 Eu2 S9 73.55(14) 3_675 . ?
S8 Eu2 Eu2 83.59(10) . 2_665 ?
S8 Eu2 Eu2 87.33(10) . 3_565 ?
S8 Eu2 Eu5 127.34(10) . 3_675 ?
S8 Eu2 Ge4 75.03(10) . 3_675 ?
S8 Eu2 Ge5 129.42(11) . 7_444 ?
S8 Eu2 S3 109.70(14) . 3_565 ?
S8 Eu2 S3 102.13(13) . . ?
S8 Eu2 S5 167.90(14) . 8_654 ?
S8 Eu2 S9 85.12(14) . . ?
S9 Eu2 Eu2 113.93(10) . 3_565 ?
S9 Eu2 Eu2 167.40(10) . 2_665 ?
S9 Eu2 Eu5 97.36(10) . 3_675 ?
S9 Eu2 Ge4 37.18(10) . 3_675 ?
S9 Eu2 Ge5 134.78(10) . 7_444 ?
S9 Eu2 S3 72.04(13) . 3_565 ?
S9 Eu2 S3 139.96(13) . . ?
S9 Eu2 S5 106.74(13) . 8_654 ?
O3 Eu2 Eu2 32.46(18) 7_444 2_665 ?
O3 Eu2 Eu2 32.45(18) 7_444 3_565 ?
O3 Eu2 Eu5 107.7(4) 7_444 3_675 ?
O3 Eu2 Ge4 172.6(5) 7_444 3_675 ?
O3 Eu2 Ge5 31.8(5) 7_444 7_444 ?
O3 Eu2 S3 74.43(15) 7_444 3_565 ?
O3 Eu2 S3 73.55(15) 7_444 . ?
O3 Eu2 S5 71.2(5) 7_444 8_654 ?
O3 Eu2 S7 141.23(11) 7_444 3_675 ?
O3 Eu2 S8 97.7(5) 7_444 . ?
O3 Eu2 S9 145.22(10) 7_444 . ?
S2 Eu3 S4 133.54(13) . . ?
S2 Eu3 S6 67.22(13) . . ?
S2 Eu3 S7 133.32(13) . 9_664 ?
S2 Eu3 S8 70.38(13) . 7_544 ?
S2 Eu3 S10 76.62(13) . 8_654 ?
S2 Eu3 S11 123.17(13) . 9_664 ?
S4 Eu3 S7 78.09(13) . 9_664 ?
S4 Eu3 S8 150.72(14) . 7_544 ?
S6 Eu3 S4 110.61(14) . . ?
S6 Eu3 S7 142.84(13) . 9_664 ?
S6 Eu3 S8 93.63(13) . 7_544 ?
S7 Eu3 S8 72.64(12) 9_664 7_544 ?
S10 Eu3 S4 74.64(13) 8_654 . ?
S10 Eu3 S6 133.60(13) 8_654 . ?
S10 Eu3 S7 83.43(13) 8_654 9_664 ?
S10 Eu3 S8 100.79(13) 8_654 7_544 ?
S10 Eu3 S11 150.03(13) 8_654 9_664 ?
S11 Eu3 S4 99.06(14) 9_664 . ?
S11 Eu3 S6 76.27(12) 9_664 . ?
S11 Eu3 S7 66.61(12) 9_664 9_664 ?
S11 Eu3 S8 70.18(13) 9_664 7_544 ?
O1 Eu3 S2 67.9(3) . . ?
O1 Eu3 S4 69.3(3) . . ?
O1 Eu3 S6 66.8(3) . . ?
O1 Eu3 S7 143.8(3) . 9_664 ?
O1 Eu3 S8 138.1(3) . 7_544 ?
O1 Eu3 S10 73.4(3) . 8_654 ?
O1 Eu3 S11 132.6(3) . 9_664 ?
Eu4 Eu4 Eu1 93.52(3) 2_655 6_565 ?
Eu4 Eu4 Eu1 126.31(2) 3_665 6_565 ?
Eu4 Eu4 Eu4 60.0 2_655 3_665 ?
Ge1 Eu4 Eu1 145.43(3) 7_544 6_565 ?
Ge1 Eu4 Eu4 56.06(3) 7_544 3_665 ?
Ge1 Eu4 Eu4 56.06(3) 7_544 2_655 ?
S2 Eu4 Eu1 79.84(9) . 6_565 ?
S2 Eu4 Eu1 144.48(9) 3_665 6_565 ?
S2 Eu4 Eu4 53.93(9) . 2_655 ?
S2 Eu4 Eu4 107.41(9) 3_665 2_655 ?
S2 Eu4 Eu4 51.33(9) 3_665 3_665 ?
S2 Eu4 Eu4 109.81(9) . 3_665 ?
S2 Eu4 Ge1 69.12(9) . 7_544 ?
S2 Eu4 Ge1 67.94(9) 3_665 7_544 ?
S2 Eu4 S2 135.67(17) . 3_665 ?
S2 Eu4 S8 70.20(13) . 7_544 ?
S4 Eu4 Eu1 84.88(10) 5_655 6_565 ?
S4 Eu4 Eu1 45.15(10) 6_565 6_565 ?
S4 Eu4 Eu4 50.56(10) 5_655 3_665 ?
S4 Eu4 Eu4 51.77(10) 6_565 2_655 ?
S4 Eu4 Eu4 86.83(10) 6_565 3_665 ?
S4 Eu4 Eu4 86.11(10) 5_655 2_655 ?
S4 Eu4 Ge1 107.83(11) 6_565 7_544 ?
S4 Eu4 Ge1 106.61(11) 5_655 7_544 ?
S4 Eu4 S2 70.87(13) 6_565 . ?
S4 Eu4 S2 135.61(14) 5_655 . ?
S4 Eu4 S2 133.64(13) 6_565 3_665 ?
S4 Eu4 S2 68.76(13) 5_655 3_665 ?
S4 Eu4 S4 68.88(19) 6_565 5_655 ?
S4 Eu4 S8 136.16(14) 6_565 7_544 ?
S4 Eu4 S8 134.07(13) 5_655 7_544 ?
S6 Eu4 Eu1 45.66(10) . 6_565 ?
S6 Eu4 Eu4 114.17(10) . 2_655 ?
S6 Eu4 Eu4 171.33(10) . 3_665 ?
S6 Eu4 Ge1 127.44(10) . 7_544 ?
S6 Eu4 S2 67.58(12) . . ?
S6 Eu4 S2 136.47(13) . 3_665 ?
S6 Eu4 S4 84.51(14) . 6_565 ?
S6 Eu4 S4 125.05(14) . 5_655 ?
S6 Eu4 S8 98.56(13) . 7_544 ?
S7 Eu4 Eu1 88.25(10) . 6_565 ?
S7 Eu4 Eu4 169.25(10) . 2_655 ?
S7 Eu4 Eu4 110.68(11) . 3_665 ?
S7 Eu4 Ge1 124.83(10) . 7_544 ?
S7 Eu4 S2 136.75(14) . . ?
S7 Eu4 S2 66.15(13) . 3_665 ?
S7 Eu4 S4 83.49(14) . 5_655 ?
S7 Eu4 S4 125.74(14) . 6_565 ?
S7 Eu4 S6 74.40(13) . . ?
S7 Eu4 S8 96.66(13) . 7_544 ?
S8 Eu4 Eu1 141.02(9) 7_544 6_565 ?
S8 Eu4 Eu4 88.62(9) 7_544 2_655 ?
S8 Eu4 Eu4 87.97(9) 7_544 3_665 ?
S8 Eu4 Ge1 38.18(10) 7_544 7_544 ?
S8 Eu4 S2 69.54(12) 7_544 3_665 ?
O2 Eu4 Eu1 128.7(3) 7_544 6_565 ?
O2 Eu4 Eu4 36.1(2) 7_544 2_655 ?
O2 Eu4 Eu4 36.1(2) 7_544 3_665 ?
O2 Eu4 Ge1 28.7(5) 7_544 7_544 ?
O2 Eu4 S2 75.00(16) 7_544 . ?
O2 Eu4 S2 72.82(15) 7_544 3_665 ?
O2 Eu4 S4 83.1(4) 7_544 5_655 ?
O2 Eu4 S4 84.2(4) 7_544 6_565 ?
O2 Eu4 S6 142.57(17) 7_544 . ?
O2 Eu4 S7 138.95(17) 7_544 . ?
O2 Eu4 S8 66.9(5) 7_544 7_544 ?
Ba1 Eu5 Eu2 89.52(3) 7_544 2_765 ?
Ge3 Eu5 Ba1 97.69(4) 3_665 7_544 ?
Ge3 Eu5 Eu2 77.68(4) 3_665 2_765 ?
Ge4 Eu5 Ba1 77.37(4) 9_664 7_544 ?
Ge4 Eu5 Eu2 94.17(5) 9_664 2_765 ?
Ge4 Eu5 Ge3 170.60(6) 9_664 3_665 ?
S2 Eu5 Ba1 124.24(10) 3_665 7_544 ?
S2 Eu5 Eu2 104.51(10) 3_665 2_765 ?
S2 Eu5 Ge3 38.17(10) 3_665 3_665 ?
S2 Eu5 Ge4 150.77(11) 3_665 9_664 ?
S2 Eu5 S3 76.36(14) 3_665 2_765 ?
S2 Eu5 S5 144.50(13) 3_665 9_664 ?
S2 Eu5 S7 68.53(13) 3_665 . ?
S2 Eu5 S8 76.00(13) 3_665 7_544 ?
S2 Eu5 S9 138.05(14) 3_665 7_544 ?
S2 Eu5 S10 78.40(13) 3_665 7_544 ?
S2 Eu5 S11 129.69(14) 3_665 9_664 ?
S3 Eu5 Ba1 71.83(10) 2_765 7_544 ?
S3 Eu5 Eu2 51.13(10) 2_765 2_765 ?
S3 Eu5 Ge3 38.30(10) 2_765 3_665 ?
S3 Eu5 Ge4 132.43(10) 2_765 9_664 ?
S3 Eu5 S5 68.60(12) 2_765 9_664 ?
S3 Eu5 S7 68.98(13) 2_765 . ?
S3 Eu5 S8 151.68(14) 2_765 7_544 ?
S3 Eu5 S10 73.55(14) 2_765 7_544 ?
S5 Eu5 Ba1 49.06(9) 9_664 7_544 ?
S5 Eu5 Eu2 47.84(9) 9_664 2_765 ?
S5 Eu5 Ge3 106.87(9) 9_664 3_665 ?
S5 Eu5 Ge4 63.83(9) 9_664 9_664 ?
S7 Eu5 Ba1 133.54(9) . 7_544 ?
S7 Eu5 Eu2 46.08(9) . 2_765 ?
S7 Eu5 Ge3 64.75(10) . 3_665 ?
S7 Eu5 Ge4 112.84(10) . 9_664 ?
S7 Eu5 S5 93.08(13) . 9_664 ?
S8 Eu5 Ba1 130.53(10) 7_544 7_544 ?
S8 Eu5 Eu2 132.26(10) 7_544 2_765 ?
S8 Eu5 Ge3 114.12(10) 7_544 3_665 ?
S8 Eu5 Ge4 74.80(10) 7_544 9_664 ?
S8 Eu5 S5 137.71(13) 7_544 9_664 ?
S8 Eu5 S7 95.07(13) 7_544 . ?
S9 Eu5 Ba1 50.69(10) 7_544 7_544 ?
S9 Eu5 Eu2 116.32(10) 7_544 2_765 ?
S9 Eu5 Ge3 142.27(11) 7_544 3_665 ?
S9 Eu5 Ge4 38.26(10) 7_544 9_664 ?
S9 Eu5 S3 122.28(14) 7_544 2_765 ?
S9 Eu5 S5 70.03(13) 7_544 9_664 ?
S9 Eu5 S7 150.50(14) 7_544 . ?
S9 Eu5 S8 83.26(14) 7_544 7_544 ?
S9 Eu5 S10 73.15(13) 7_544 7_544 ?
S10 Eu5 Ba1 49.35(10) 7_544 7_544 ?
S10 Eu5 Eu2 120.47(10) 7_544 2_765 ?
S10 Eu5 Ge3 69.87(10) 7_544 3_665 ?
S10 Eu5 Ge4 111.33(10) 7_544 9_664 ?
S10 Eu5 S5 96.55(13) 7_544 9_664 ?
S10 Eu5 S7 134.47(13) 7_544 . ?
S10 Eu5 S8 106.57(14) 7_544 7_544 ?
S11 Eu5 Ba1 105.88(10) 9_664 7_544 ?
S11 Eu5 Eu2 69.08(10) 9_664 2_765 ?
S11 Eu5 Ge3 138.55(10) 9_664 3_665 ?
S11 Eu5 Ge4 38.60(10) 9_664 9_664 ?
S11 Eu5 S3 119.95(14) 9_664 2_765 ?
S11 Eu5 S5 67.76(13) 9_664 9_664 ?
S11 Eu5 S7 74.35(13) 9_664 . ?
S11 Eu5 S8 74.74(14) 9_664 7_544 ?
S11 Eu5 S9 76.83(13) 9_664 7_544 ?
S11 Eu5 S10 149.49(14) 9_664 7_544 ?
Eu4 Ge1 Eu4 67.88(7) 6_565 5 ?
Eu4 Ge1 Eu4 67.88(7) 4_455 5 ?
Eu4 Ge1 Eu4 67.89(7) 6_565 4_455 ?
S8 Ge1 Eu4 120.11(16) 3_565 5 ?
S8 Ge1 Eu4 121.34(16) 3_565 4_455 ?
S8 Ge1 Eu4 121.34(16) 2_665 6_565 ?
S8 Ge1 Eu4 120.10(16) . 6_565 ?
S8 Ge1 Eu4 121.34(16) . 5 ?
S8 Ge1 Eu4 120.10(16) 2_665 4_455 ?
S8 Ge1 Eu4 65.01(15) 2_665 5 ?
S8 Ge1 Eu4 65.01(15) 3_565 6_565 ?
S8 Ge1 Eu4 65.00(15) . 4_455 ?
S8 Ge1 S8 113.43(14) . 3_565 ?
S8 Ge1 S8 113.43(14) 2_665 3_565 ?
S8 Ge1 S8 113.43(14) 2_665 . ?
O2 Ge1 Eu4 40.15(4) . 5 ?
O2 Ge1 Eu4 40.14(4) . 6_565 ?
O2 Ge1 Eu4 40.15(4) . 4_455 ?
O2 Ge1 S8 105.14(16) . . ?
O2 Ge1 S8 105.15(16) . 3_565 ?
O2 Ge1 S8 105.15(16) . 2_665 ?
S1 Ge2 S4 113.17(17) . . ?
S1 Ge2 S4 113.17(16) . 2_765 ?
S1 Ge2 S4 113.17(16) . 3_675 ?
S4 Ge2 S4 105.53(19) 2_765 3_675 ?
S4 Ge2 S4 105.53(18) . 2_765 ?
S4 Ge2 S4 105.53(19) . 3_675 ?
S2 Ge3 Eu5 53.97(13) . 2_655 ?
S2 Ge3 S3 111.3(2) . 3_565 ?
S3 Ge3 Eu5 57.57(13) 3_565 2_655 ?
S10 Ge3 Eu5 140.35(16) . 2_655 ?
S10 Ge3 S2 115.9(2) . . ?
S10 Ge3 S3 112.1(2) . 3_565 ?
O1 Ge3 Eu5 111.9(4) . 2_655 ?
O1 Ge3 S2 104.4(4) . . ?
O1 Ge3 S3 104.2(4) . 3_565 ?
O1 Ge3 S10 107.8(4) . . ?
Eu5 Ge4 Eu2 76.78(5) 5_655 2_765 ?
S6 Ge4 Eu2 142.03(16) . 2_765 ?
S6 Ge4 Eu5 131.50(15) . 5_655 ?
S6 Ge4 S7 110.43(19) . . ?
S6 Ge4 S9 113.1(2) . 2_765 ?
S6 Ge4 S11 107.7(2) . . ?
S7 Ge4 Eu2 54.58(13) . 2_765 ?
S7 Ge4 Eu5 117.66(14) . 5_655 ?
S7 Ge4 S11 103.2(2) . . ?
S9 Ge4 Eu2 56.07(13) 2_765 2_765 ?
S9 Ge4 Eu5 57.03(14) 2_765 5_655 ?
S9 Ge4 S7 108.70(19) 2_765 . ?
S9 Ge4 S11 113.3(2) 2_765 . ?
S11 Ge4 Eu2 109.77(15) . 2_765 ?
S11 Ge4 Eu5 56.32(14) . 5_655 ?
Ba1 Ge5 Ba1 74.33(7) 2_765 3_675 ?
Eu2 Ge5 Ba1 103.59(2) 5_665 3_675 ?
Eu2 Ge5 Ba1 106.24(2) 6_565 2_765 ?
Eu2 Ge5 Ba1 177.68(5) 6_565 3_675 ?
Eu2 Ge5 Ba1 106.24(2) 4 3_675 ?
Eu2 Ge5 Ba1 177.68(5) 5_665 2_765 ?
Eu2 Ge5 Ba1 103.60(2) 4 2_765 ?
Eu2 Ge5 Eu2 75.87(8) 4 5_665 ?
Eu2 Ge5 Eu2 75.87(8) 6_565 5_665 ?
Eu2 Ge5 Eu2 75.88(8) 6_565 4 ?
Ge5 Ge5 Ba1 0(10) 2_765 2_765 ?
Ge5 Ge5 Ba1 0(10) 3_675 3_675 ?
Ge5 Ge5 Ba1 0(10) 3_675 2_765 ?
Ge5 Ge5 Ba1 0(10) 2_765 3_675 ?
Ge5 Ge5 Eu2 0(10) 2_765 6_565 ?
Ge5 Ge5 Eu2 0(10) 2_765 5_665 ?
Ge5 Ge5 Eu2 0(10) 2_765 4 ?
Ge5 Ge5 Eu2 0(10) 3_675 6_565 ?
Ge5 Ge5 Eu2 0(10) 3_675 4 ?
Ge5 Ge5 Eu2 0(10) 3_675 5_665 ?
Ge5 Ge5 Ge5 0(10) 3_675 2_765 ?
Ge5 Ge5 S5 0(10) 3_675 3_675 ?
Ge5 Ge5 S5 0(10) 2_765 . ?
Ge5 Ge5 S5 0(10) 2_765 2_765 ?
Ge5 Ge5 S5 0(10) 2_765 3_675 ?
Ge5 Ge5 S5 0(10) 3_675 . ?
Ge5 Ge5 S5 0(10) 3_675 2_765 ?
Ge5 Ge5 O3 0(10) 2_765 . ?
Ge5 Ge5 O3 0(10) 3_675 . ?
S5 Ge5 Ba1 56.73(15) 2_765 3_675 ?
S5 Ge5 Ba1 56.73(15) . 2_765 ?
S5 Ge5 Ba1 55.21(14) 2_765 2_765 ?
S5 Ge5 Ba1 115.57(19) 3_675 2_765 ?
S5 Ge5 Ba1 115.57(19) . 3_675 ?
S5 Ge5 Ba1 55.21(14) 3_675 3_675 ?
S5 Ge5 Eu2 125.49(15) . 5_665 ?
S5 Ge5 Eu2 122.84(14) 3_675 6_565 ?
S5 Ge5 Eu2 122.84(14) . 4 ?
S5 Ge5 Eu2 125.48(15) 2_765 6_565 ?
S5 Ge5 Eu2 63.45(14) 3_675 5_665 ?
S5 Ge5 Eu2 122.84(14) 2_765 5_665 ?
S5 Ge5 Eu2 125.49(15) 3_675 4 ?
S5 Ge5 Eu2 63.45(14) . 6_565 ?
S5 Ge5 Eu2 63.45(14) 2_765 4 ?
S5 Ge5 S5 110.27(16) . 2_765 ?
S5 Ge5 S5 110.28(16) 3_675 2_765 ?
S5 Ge5 S5 110.27(16) 3_675 . ?
O3 Ge5 Ba1 135.77(5) . 3_675 ?
O3 Ge5 Ba1 135.77(5) . 2_765 ?
O3 Ge5 Eu2 45.23(5) . 4 ?
O3 Ge5 Eu2 45.23(5) . 5_665 ?
O3 Ge5 Eu2 45.23(5) . 6_565 ?
O3 Ge5 S5 108.65(16) . . ?
O3 Ge5 S5 108.66(16) . 3_675 ?
O3 Ge5 S5 108.65(16) . 2_765 ?
Ba1 S1 Ba1 99.98(18) 3_675 . ?
Ba1 S1 Ba1 99.98(18) 3_675 2_765 ?
Ba1 S1 Ba1 99.98(18) 2_765 . ?
Ge2 S1 Ba1 117.82(14) . 3_675 ?
Ge2 S1 Ba1 117.82(14) . 2_765 ?
Ge2 S1 Ba1 117.82(14) . . ?
Eu3 S2 Eu4 150.86(17) . 2_655 ?
Eu3 S2 Eu4 85.57(12) . . ?
Eu4 S2 Eu4 74.73(11) . 2_655 ?
Eu5 S2 Eu3 103.80(15) 2_655 . ?
Eu5 S2 Eu4 147.70(18) 2_655 . ?
Eu5 S2 Eu4 83.49(12) 2_655 2_655 ?
Ge3 S2 Eu3 83.47(15) . . ?
Ge3 S2 Eu4 125.37(19) . 2_655 ?
Ge3 S2 Eu4 124.2(2) . . ?
Ge3 S2 Eu5 87.86(16) . 2_655 ?
Eu1 S3 Eu2 156.56(17) 2_665 . ?
Eu1 S3 Eu2 83.08(12) 2_665 2_665 ?
Eu2 S3 Eu2 81.32(12) 2_665 . ?
Eu5 S3 Eu1 105.67(15) 3_675 2_665 ?
Eu5 S3 Eu2 153.49(17) 3_675 2_665 ?
Eu5 S3 Eu2 81.78(12) 3_675 . ?
Ge3 S3 Eu1 79.56(15) 2_665 2_665 ?
Ge3 S3 Eu2 122.32(19) 2_665 2_665 ?
Ge3 S3 Eu2 123.70(19) 2_665 . ?
Ge3 S3 Eu5 84.13(15) 2_665 3_675 ?
Eu1 S4 Eu3 81.09(12) . . ?
Eu1 S4 Eu4 151.00(19) . 9_664 ?
Eu4 S4 Eu1 90.38(14) 8_654 . ?
Eu4 S4 Eu3 144.77(19) 8_654 . ?
Eu4 S4 Eu3 93.49(14) 9_664 . ?
Eu4 S4 Eu4 77.67(13) 8_654 9_664 ?
Ge2 S4 Eu1 116.7(2) . . ?
Ge2 S4 Eu3 122.7(2) . . ?
Ge2 S4 Eu4 90.26(18) . 9_664 ?
Ge2 S4 Eu4 91.66(18) . 8_654 ?
Ba1 S5 Ba1 93.52(14) . 2_765 ?
Ba1 S5 Eu2 130.16(16) . 6_565 ?
Ba1 S5 Eu5 75.37(11) 2_765 5_655 ?
Ba1 S5 Eu5 143.39(16) . 5_655 ?
Eu2 S5 Ba1 132.24(16) 6_565 2_765 ?
Eu2 S5 Eu5 77.38(11) 6_565 5_655 ?
Ge5 S5 Ba1 88.69(16) 2_765 . ?
Ge5 S5 Ba1 87.21(17) 3_675 2_765 ?
Ge5 S5 Ba1 87.21(17) 2_765 2_765 ?
Ge5 S5 Ba1 88.69(16) 3_675 . ?
Ge5 S5 Ba1 88.69(16) . . ?
Ge5 S5 Ba1 87.21(17) . 2_765 ?
Ge5 S5 Eu2 77.08(17) . 6_565 ?
Ge5 S5 Eu2 77.08(17) 3_675 6_565 ?
Ge5 S5 Eu2 77.08(17) 2_765 6_565 ?
Ge5 S5 Eu5 124.60(19) . 5_655 ?
Ge5 S5 Eu5 124.60(19) 2_765 5_655 ?
Ge5 S5 Eu5 124.60(19) 3_675 5_655 ?
Ge5 S5 Ge5 0.00(19) 2_765 . ?
Ge5 S5 Ge5 0.00(19) 3_675 2_765 ?
Ge5 S5 Ge5 0.00(19) 3_675 . ?
Ba1 S6 Eu1 80.99(12) . 6_565 ?
Ba1 S6 Eu3 87.89(13) . . ?
Eu1 S6 Eu3 148.05(16) 6_565 . ?
Eu4 S6 Ba1 153.08(17) . . ?
Eu4 S6 Eu1 91.02(14) . 6_565 ?
Eu4 S6 Eu3 85.50(13) . . ?
Ge4 S6 Ba1 120.85(19) . . ?
Ge4 S6 Eu1 88.55(17) . 6_565 ?
Ge4 S6 Eu3 122.5(2) . . ?
Ge4 S6 Eu4 84.29(16) . . ?
Eu2 S7 Eu3 102.46(14) 2_765 5_655 ?
Eu2 S7 Eu5 83.97(12) 2_765 . ?
Eu4 S7 Eu2 159.99(19) . 2_765 ?
Eu4 S7 Eu3 96.78(14) . 5_655 ?
Eu4 S7 Eu5 84.49(12) . . ?
Eu5 S7 Eu3 141.15(17) . 5_655 ?
Ge4 S7 Eu2 88.01(16) . 2_765 ?
Ge4 S7 Eu3 93.16(16) . 5_655 ?
Ge4 S7 Eu4 85.48(16) . . ?
Ge4 S7 Eu5 125.5(2) . . ?
Eu2 S8 Eu3 99.08(14) . 4_455 ?
Eu2 S8 Eu4 172.31(19) . 4_455 ?
Eu2 S8 Eu5 93.10(14) . 4_455 ?
Eu4 S8 Eu3 79.17(12) 4_455 4_455 ?
Eu5 S8 Eu3 101.19(14) 4_455 4_455 ?
Eu5 S8 Eu4 79.98(12) 4_455 4_455 ?
Ge1 S8 Eu2 110.0(2) . . ?
Ge1 S8 Eu3 124.9(2) . 4_455 ?
Ge1 S8 Eu4 76.81(17) . 4_455 ?
Ge1 S8 Eu5 122.0(2) . 4_455 ?
Ba1 S9 Eu1 82.26(12) . . ?
Eu2 S9 Ba1 148.41(18) . . ?
Eu2 S9 Eu1 83.97(12) . . ?
Eu5 S9 Ba1 82.04(12) 4_455 . ?
Eu5 S9 Eu1 149.00(18) 4_455 . ?
Eu5 S9 Eu2 95.85(15) 4_455 . ?
Ge4 S9 Ba1 124.1(2) 3_675 . ?
Ge4 S9 Eu1 126.1(2) 3_675 . ?
Ge4 S9 Eu2 86.75(16) 3_675 . ?
Ge4 S9 Eu5 84.71(16) 3_675 4_455 ?
Eu1 S10 Ba1 83.68(13) 6_565 . ?
Eu1 S10 Eu3 86.03(13) 6_565 6_565 ?
Eu1 S10 Eu5 106.98(15) 6_565 4_455 ?
Eu3 S10 Ba1 169.46(18) 6_565 . ?
Eu3 S10 Eu5 99.31(14) 6_565 4_455 ?
Eu5 S10 Ba1 81.59(12) 4_455 . ?
Ge3 S10 Ba1 77.51(15) . . ?
Ge3 S10 Eu1 120.2(2) . 6_565 ?
Ge3 S10 Eu3 109.87(19) . 6_565 ?
Ge3 S10 Eu5 125.0(2) . 4_455 ?
Eu1 S11 Eu3 118.71(17) 6_565 5_655 ?
Eu5 S11 Eu1 128.90(18) 5_655 6_565 ?
Eu5 S11 Eu3 112.21(16) 5_655 5_655 ?
Ge4 S11 Eu1 92.74(17) . 6_565 ?
Ge4 S11 Eu3 96.96(17) . 5_655 ?
Ge4 S11 Eu5 85.08(16) . 5_655 ?
Ba1 O1 Eu1 115.5(5) . . ?
Ba1 O1 Eu3 117.5(5) . . ?
Eu1 O1 Eu3 107.6(5) . . ?
Ge3 O1 Ba1 103.9(6) . . ?
Ge3 O1 Eu1 107.1(6) . . ?
Ge3 O1 Eu3 104.1(6) . . ?
Eu4 O2 Eu4 107.8(5) 6_565 4_455 ?
Eu4 O2 Eu4 107.8(5) 6_565 5 ?
Eu4 O2 Eu4 107.8(5) 4_455 5 ?
Ge1 O2 Eu4 111.1(5) . 5 ?
Ge1 O2 Eu4 111.1(5) . 4_455 ?
Ge1 O2 Eu4 111.1(5) . 6_565 ?
Eu2 O3 Eu2 115.1(4) 6_565 5_665 ?
Eu2 O3 Eu2 115.1(4) 6_565 4 ?
Eu2 O3 Eu2 115.1(4) 4 5_665 ?
Ge5 O3 Eu2 103.0(5) 2_765 5_665 ?
Ge5 O3 Eu2 103.0(5) . 4 ?
Ge5 O3 Eu2 103.0(5) . 6_565 ?
Ge5 O3 Eu2 103.0(5) 3_675 6_565 ?
Ge5 O3 Eu2 103.0(5) 3_675 4 ?
Ge5 O3 Eu2 103.0(5) 2_765 4 ?
Ge5 O3 Eu2 103.0(5) 3_675 5_665 ?
Ge5 O3 Eu2 103.0(5) 2_765 6_565 ?
Ge5 O3 Eu2 103.0(5) . 5_665 ?
Ge5 O3 Ge5 0.000(1) 3_675 . ?
Ge5 O3 Ge5 0.000(1) 3_675 2_765 ?
Ge5 O3 Ge5 0.000(1) . 2_765 ?


_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.91(3)
2 0.09(3)

