# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_navos
_database_code_depnum_ccdc_archive 'CCDC 2366824'
loop_
_audit_author_name
_audit_author_address
'Linfeng Dong'
;UCAS
China
;
_audit_update_record             
;
2024-07-01 deposited with the CCDC.	2024-07-04 downloaded from the CCDC.
;
_audit_creation_date             2021-04-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2016/4
_chemical_name_common            ?
_chemical_name_systematic        Na3VOS3
_chemical_formula_moiety         '0.17(Na12 O4 S12 V4)'
_chemical_formula_sum            'Na2 O0.67 S2 V0.67'
_chemical_formula_weight         154.73
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           36
_space_group_name_H-M_alt        'C m c 21'
_space_group_name_Hall           'C 2c -2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'x, -y, z+1/2'
'-x, y, z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z'

_cell_length_a                   9.5667(7)
_cell_length_b                   11.8659(9)
_cell_length_c                   5.8806(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     667.55(8)
_cell_formula_units_Z            6
_cell_measurement_reflns_used    ?
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      ?
_cell_measurement_theta_min      ?
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.503
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.50648
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    2.309
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             448
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0735
_diffrn_reflns_av_unetI/netI     0.0469
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            4073
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.725
_diffrn_reflns_theta_min         3.434
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.796
_reflns_Friedel_fraction_full    0.986
_reflns_Friedel_fraction_max     0.958
_reflns_number_gt                853
_reflns_number_total             878
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine (Bourhis et al., 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.870
_refine_diff_density_min         -0.591
_refine_diff_density_rms         0.123
_refine_ls_abs_structure_details 
;
 Flack x determined using 366 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.23(4)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         878
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0331
_refine_ls_restrained_S_all      1.102
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0480P)²+0.4270P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0842
_refine_ls_wR_factor_ref         0.0853
_refine_special_details          ?
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.75(6)
 0.25(6)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
V001 V 0.500000 0.79804(6) 0.34685(19) 0.0170(3) Uani 1 2 d S T P . .
S002 S 0.500000 0.61949(12) 0.2516(3) 0.0269(4) Uani 1 2 d S T P . .
S003 S 0.68991(12) 0.87708(10) 0.23031(17) 0.0293(3) Uani 1 1 d . . . . .
Na04 Na 0.500000 0.6187(2) 0.7692(5) 0.0306(6) Uani 1 2 d S T P . .
Na05 Na 0.7054(2) 0.88059(18) 0.7507(4) 0.0394(5) Uani 1 1 d . . . . .
O006 O 0.500000 0.8036(4) 0.6287(9) 0.0273(11) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
V001 S002 2.1914(16) . ?
V001 S003 2.1564(12) . ?
V001 S003 2.1565(12) 4_655 ?
V001 Na04 3.271(3) . ?
V001 Na05 3.235(2) 4_655 ?
V001 Na05 3.571(2) 7_464 ?
V001 Na05 3.235(2) . ?
V001 Na05 3.571(2) 6_664 ?
V001 O006 1.659(5) . ?
S002 Na04 2.837(3) 1_554 ?
S002 Na04 3.044(3) . ?
S002 Na04 2.828(3) 2_664 ?
S002 Na05 2.818(2) 7_464 ?
S002 Na05 2.818(2) 6_664 ?
S003 Na04 2.9758(12) 6_664 ?
S003 Na05 3.064(3) . ?
S003 Na05 2.882(2) 3_574 ?
S003 Na05 2.825(3) 1_554 ?
S003 Na05 3.220(2) 6_664 ?
Na04 S002 2.828(3) 2_665 ?
Na04 S002 2.837(3) 1_556 ?
Na04 S003 2.9758(12) 7_465 ?
Na04 S003 2.9758(12) 6_665 ?
Na04 Na05 3.992(3) 8_645 ?
Na04 Na05 3.992(3) 5_445 ?
Na04 Na05 3.679(3) 4_655 ?
Na04 Na05 3.679(3) . ?
Na04 Na05 3.995(3) 6_665 ?
Na04 O006 2.345(6) . ?
Na05 V001 3.571(2) 6_665 ?
Na05 S002 2.818(2) 6_665 ?
Na05 S003 2.882(2) 3_575 ?
Na05 S003 3.220(2) 6_665 ?
Na05 S003 2.825(3) 1_556 ?
Na05 Na04 3.995(3) 6_664 ?
Na05 Na04 3.992(3) 5 ?
Na05 Na05 3.931(5) 4_655 ?
Na05 O006 2.283(3) . ?
O006 Na05 2.283(3) 4_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S002 V001 Na04 64.22(7) . . ?
S002 V001 Na05 52.10(4) . 6_664 ?
S002 V001 Na05 118.72(6) . 4_655 ?
S002 V001 Na05 52.10(4) . 7_464 ?
S002 V001 Na05 118.71(6) . . ?
S003 V001 S002 109.83(5) . . ?
S003 V001 S002 109.83(5) 4_655 . ?
S003 V001 S003 114.81(8) . 4_655 ?
S003 V001 Na04 121.62(4) . . ?
S003 V001 Na04 121.62(4) 4_655 . ?
S003 V001 Na05 65.78(5) . . ?
S003 V001 Na05 65.78(5) 4_655 4_655 ?
S003 V001 Na05 150.77(7) . 7_464 ?
S003 V001 Na05 62.81(5) 4_655 7_464 ?
S003 V001 Na05 150.77(7) 4_655 6_664 ?
S003 V001 Na05 127.84(6) 4_655 . ?
S003 V001 Na05 127.84(6) . 4_655 ?
S003 V001 Na05 62.81(5) . 6_664 ?
Na04 V001 Na05 74.58(5) . 6_664 ?
Na04 V001 Na05 74.58(5) . 7_464 ?
Na05 V001 Na04 68.87(6) . . ?
Na05 V001 Na04 68.87(6) 4_655 . ?
Na05 V001 Na05 79.43(5) 4_655 7_464 ?
Na05 V001 Na05 140.85(8) . 7_464 ?
Na05 V001 Na05 104.20(7) 7_464 6_664 ?
Na05 V001 Na05 74.83(9) 4_655 . ?
Na05 V001 Na05 79.43(5) . 6_664 ?
Na05 V001 Na05 140.85(8) 4_655 6_664 ?
O006 V001 S002 107.10(17) . . ?
O006 V001 S003 107.47(9) . . ?
O006 V001 S003 107.47(9) . 4_655 ?
O006 V001 Na04 42.88(18) . . ?
O006 V001 Na05 100.48(11) . 6_664 ?
O006 V001 Na05 100.48(11) . 7_464 ?
O006 V001 Na05 41.78(8) . . ?
O006 V001 Na05 41.78(8) . 4_655 ?
V001 S002 Na04 105.01(9) . 1_554 ?
V001 S002 Na04 163.09(10) . 2_664 ?
V001 S002 Na04 75.37(8) . . ?
V001 S002 Na05 90.05(6) . 7_464 ?
V001 S002 Na05 90.05(6) . 6_664 ?
Na04 S002 Na04 91.90(10) 2_664 1_554 ?
Na04 S002 Na04 179.62(13) 1_554 . ?
Na04 S002 Na04 87.72(9) 2_664 . ?
Na05 S002 Na04 89.98(5) 6_664 2_664 ?
Na05 S002 Na04 89.98(5) 7_464 2_664 ?
Na05 S002 Na04 90.11(6) 6_664 . ?
Na05 S002 Na04 89.89(6) 6_664 1_554 ?
Na05 S002 Na04 89.89(6) 7_464 1_554 ?
Na05 S002 Na04 90.11(6) 7_464 . ?
Na05 S002 Na05 179.78(12) 7_464 6_664 ?
V001 S003 Na04 145.37(8) . 6_664 ?
V001 S003 Na05 74.30(6) . . ?
V001 S003 Na05 117.66(7) . 3_574 ?
V001 S003 Na05 111.60(7) . 1_554 ?
V001 S003 Na05 80.62(6) . 6_664 ?
Na04 S003 Na05 72.74(7) 6_664 6_664 ?
Na04 S003 Na05 82.80(8) 6_664 . ?
Na05 S003 Na04 85.90(7) 3_574 6_664 ?
Na05 S003 Na04 91.38(9) 1_554 6_664 ?
Na05 S003 Na05 91.38(7) 1_554 3_574 ?
Na05 S003 Na05 173.98(10) 1_554 . ?
Na05 S003 Na05 158.44(5) 3_574 6_664 ?
Na05 S003 Na05 92.00(7) 1_554 6_664 ?
Na05 S003 Na05 87.74(7) . 6_664 ?
Na05 S003 Na05 86.70(7) 3_574 . ?
V001 Na04 Na05 55.10(5) . . ?
V001 Na04 Na05 116.09(6) . 5_445 ?
V001 Na04 Na05 116.09(6) . 8_645 ?
V001 Na04 Na05 122.47(6) . 6_665 ?
V001 Na04 Na05 55.10(5) . 4_655 ?
S002 Na04 V001 40.41(5) . . ?
S002 Na04 V001 139.21(11) 1_556 . ?
S002 Na04 V001 128.49(11) 2_665 . ?
S002 Na04 S002 179.62(13) 1_556 . ?
S002 Na04 S002 88.08(10) 2_665 . ?
S002 Na04 S002 92.30(9) 2_665 1_556 ?
S002 Na04 S003 94.41(7) 1_556 6_665 ?
S002 Na04 S003 90.81(6) 2_665 7_465 ?
S002 Na04 S003 94.41(7) 1_556 7_465 ?
S002 Na04 S003 90.81(6) 2_665 6_665 ?
S002 Na04 Na05 44.91(4) 2_665 8_645 ?
S002 Na04 Na05 91.53(8) 1_556 . ?
S002 Na04 Na05 88.57(7) . 5_445 ?
S002 Na04 Na05 91.70(6) 1_556 5_445 ?
S002 Na04 Na05 88.57(7) . 8_645 ?
S002 Na04 Na05 88.15(7) . 4_655 ?
S002 Na04 Na05 91.61(7) 2_665 6_665 ?
S002 Na04 Na05 91.53(8) 1_556 4_655 ?
S002 Na04 Na05 135.13(4) . 6_665 ?
S002 Na04 Na05 44.86(4) 1_556 6_665 ?
S002 Na04 Na05 91.70(6) 1_556 8_645 ?
S002 Na04 Na05 147.48(5) 2_665 . ?
S002 Na04 Na05 44.91(4) 2_665 5_445 ?
S002 Na04 Na05 88.15(7) . . ?
S002 Na04 Na05 147.48(5) 2_665 4_655 ?
S003 Na04 V001 86.02(6) 6_665 . ?
S003 Na04 V001 86.02(6) 7_465 . ?
S003 Na04 S002 85.59(6) 6_665 . ?
S003 Na04 S002 85.59(6) 7_465 . ?
S003 Na04 S003 170.97(13) 7_465 6_665 ?
S003 Na04 Na05 56.69(5) 6_665 . ?
S003 Na04 Na05 135.53(9) 6_665 5_445 ?
S003 Na04 Na05 135.53(9) 7_465 8_645 ?
S003 Na04 Na05 121.06(9) 7_465 . ?
S003 Na04 Na05 121.06(9) 6_665 4_655 ?
S003 Na04 Na05 46.06(4) 7_465 5_445 ?
S003 Na04 Na05 49.55(5) 6_665 6_665 ?
S003 Na04 Na05 56.69(5) 7_465 4_655 ?
S003 Na04 Na05 139.26(10) 7_465 6_665 ?
S003 Na04 Na05 46.06(4) 6_665 8_645 ?
Na05 Na04 Na05 166.97(9) . 5_445 ?
Na05 Na04 Na05 121.26(8) 5_445 6_665 ?
Na05 Na04 Na05 102.705(11) 4_655 5_445 ?
Na05 Na04 Na05 64.58(9) . 4_655 ?
Na05 Na04 Na05 113.33(8) 4_655 6_665 ?
Na05 Na04 Na05 166.97(9) 4_655 8_645 ?
Na05 Na04 Na05 69.04(5) . 6_665 ?
Na05 Na04 Na05 61.50(5) 8_645 6_665 ?
Na05 Na04 Na05 102.705(11) . 8_645 ?
Na05 Na04 Na05 89.82(9) 5_445 8_645 ?
O006 Na04 V001 28.77(13) . . ?
O006 Na04 S002 157.26(19) . 2_665 ?
O006 Na04 S002 69.18(15) . . ?
O006 Na04 S002 110.44(18) . 1_556 ?
O006 Na04 S003 87.54(6) . 7_465 ?
O006 Na04 S003 87.54(6) . 6_665 ?
O006 Na04 Na05 130.74(8) . 8_645 ?
O006 Na04 Na05 104.35(12) . 6_665 ?
O006 Na04 Na05 36.77(8) . . ?
O006 Na04 Na05 36.77(8) . 4_655 ?
O006 Na04 Na05 130.74(8) . 5_445 ?
V001 Na05 V001 114.58(7) . 6_665 ?
V001 Na05 Na04 131.55(7) . 5 ?
V001 Na05 Na04 63.70(6) 6_665 6_664 ?
V001 Na05 Na04 85.15(5) 6_665 . ?
V001 Na05 Na04 81.88(5) 6_665 5 ?
V001 Na05 Na04 84.77(6) . 6_664 ?
V001 Na05 Na04 56.03(6) . . ?
V001 Na05 Na05 142.10(4) 6_665 4_655 ?
V001 Na05 Na05 52.58(5) . 4_655 ?
S002 Na05 V001 127.51(9) 6_665 . ?
S002 Na05 V001 37.85(4) 6_665 6_665 ?
S002 Na05 S003 71.87(7) 6_665 6_665 ?
S002 Na05 S003 92.91(8) 6_665 1_556 ?
S002 Na05 S003 92.89(8) 6_665 . ?
S002 Na05 S003 92.98(7) 6_665 3_575 ?
S002 Na05 Na04 122.27(9) 6_665 . ?
S002 Na05 Na04 45.11(5) 6_665 5 ?
S002 Na05 Na04 45.24(6) 6_665 6_664 ?
S002 Na05 Na05 179.89(7) 6_665 4_655 ?
S003 Na05 V001 82.76(5) 6_665 . ?
S003 Na05 V001 129.75(8) 3_575 6_665 ?
S003 Na05 V001 100.86(8) . 6_665 ?
S003 Na05 V001 39.93(4) . . ?
S003 Na05 V001 36.57(3) 6_665 6_665 ?
S003 Na05 V001 82.80(7) 1_556 6_665 ?
S003 Na05 V001 134.16(9) 1_556 . ?
S003 Na05 V001 103.90(8) 3_575 . ?
S003 Na05 S003 92.27(8) 1_556 6_665 ?
S003 Na05 S003 173.98(10) 1_556 . ?
S003 Na05 S003 93.07(8) 1_556 3_575 ?
S003 Na05 S003 87.99(7) . 6_665 ?
S003 Na05 S003 164.17(9) 3_575 6_665 ?
S003 Na05 S003 88.25(7) 3_575 . ?
S003 Na05 Na04 90.27(7) 3_575 6_664 ?
S003 Na05 Na04 47.65(5) . 6_664 ?
S003 Na05 Na04 116.98(7) 6_665 5 ?
S003 Na05 Na04 50.57(4) 6_665 . ?
S003 Na05 Na04 91.16(7) 1_556 5 ?
S003 Na05 Na04 75.90(6) 6_665 6_664 ?
S003 Na05 Na04 144.75(9) 3_575 . ?
S003 Na05 Na04 94.08(7) . 5 ?
S003 Na05 Na04 89.55(7) . . ?
S003 Na05 Na04 48.04(5) 3_575 5 ?
S003 Na05 Na04 138.15(9) 1_556 6_664 ?
S003 Na05 Na04 85.98(7) 1_556 . ?
S003 Na05 Na05 86.98(6) 1_556 4_655 ?
S003 Na05 Na05 87.22(5) . 4_655 ?
S003 Na05 Na05 87.04(6) 3_575 4_655 ?
S003 Na05 Na05 108.12(4) 6_665 4_655 ?
Na04 Na05 Na04 61.30(6) 5 6_664 ?
Na04 Na05 Na04 166.97(9) . 5 ?
Na04 Na05 Na04 113.56(7) . 6_664 ?
Na04 Na05 Na05 57.71(4) . 4_655 ?
Na05 Na05 Na04 134.91(4) 4_655 5 ?
Na05 Na05 Na04 134.86(4) 4_655 6_664 ?
O006 Na05 V001 28.95(12) . . ?
O006 Na05 V001 119.45(13) . 6_665 ?
O006 Na05 S002 149.47(14) . 6_665 ?
O006 Na05 S003 68.83(13) . . ?
O006 Na05 S003 105.23(15) . 1_556 ?
O006 Na05 S003 82.88(12) . 6_665 ?
O006 Na05 S003 109.98(14) . 3_575 ?
O006 Na05 Na04 112.67(13) . 6_664 ?
O006 Na05 Na04 37.94(12) . . ?
O006 Na05 Na04 154.09(14) . 5 ?
O006 Na05 Na05 30.59(12) . 4_655 ?
V001 O006 Na04 108.4(3) . . ?
V001 O006 Na05 109.27(15) . . ?
V001 O006 Na05 109.27(15) . 4_655 ?
Na05 O006 Na04 105.28(15) . . ?
Na05 O006 Na04 105.28(15) 4_655 . ?
Na05 O006 Na05 118.8(2) 4_655 . ?


_olex2_submission_original_sample_id Na3VOS3
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.75(6)
2 0.25(6)

