# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_jy115_0m
_database_code_depnum_ccdc_archive 'CCDC 2359733'
loop_
_audit_author_name
_audit_author_address
'Leoni A. Barrios Moreno'
;UNIVERSITY OF BARCELONA
Spain
;
_audit_update_record             
;
2024-05-31 deposited with the CCDC.	2024-07-29 downloaded from the CCDC.
;
_audit_creation_date             2023-06-12
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        C32H36ClF6N3O2PRh
_chemical_formula_moiety         'C32 H36 Cl N3 O2 Rh, C H2 Cl2, F6 P'
_chemical_formula_sum            'C33 H38 Cl3 F6 N3 O2 P Rh'
_chemical_formula_weight         862.89
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.8922(13)
_cell_length_b                   12.5691(15)
_cell_length_c                   13.0059(15)
_cell_angle_alpha                105.907(4)
_cell_angle_beta                 92.694(4)
_cell_angle_gamma                97.271(4)
_cell_volume                     1847.8(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9970
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.570
_cell_measurement_theta_min      2.247
_shelx_estimated_absorpt_T_max   0.905
_shelx_estimated_absorpt_T_min   0.798
_exptl_absorpt_coefficient_mu    0.787
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6977
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0978 before and 0.0611 after correction.
The Ratio of minimum to maximum transmission is 0.9351.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.551
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             876
_exptl_crystal_recrystallization_method 'SLOW DIFUSSION IN A DCM/C6 MIXTURE'
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0438
_diffrn_reflns_av_unetI/netI     0.0143
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            303095
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.642
_diffrn_reflns_theta_min         1.999
_diffrn_ambient_temperature      100.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10389
_reflns_number_total             11362
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_refine_diff_density_max         1.763
_refine_diff_density_min         -1.421
_refine_diff_density_rms         0.105
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     449
_refine_ls_number_reflns         11362
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0429
_refine_ls_R_factor_gt           0.0384
_refine_ls_restrained_S_all      1.067
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0431P)²+3.9416P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0964
_refine_ls_wR_factor_ref         0.0993
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B), C1A(H1AA,H1AB)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C7(H7), C8(H8), C13(H13), C15(H15), C16(H16)
2.c Idealised Me refined as rotating group:
 C21(H21A,H21B,H21C), C23(H23A,H23B,H23C), C29(H29A,H29B,H29C), C30(H30A,H30B,
 H30C), C31(H31A,H31B,H31C), C32(H32A,H32B,H32C), C33(H33A,H33B,H33C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.86568(2) 0.14649(2) 0.33364(2) 0.01305(5) Uani 1 1 d . . . . .
Cl1 Cl 0.92325(4) 0.16076(4) 0.51658(4) 0.01660(9) Uani 1 1 d . . . . .
O1 O 0.55794(17) 0.60969(17) 0.61214(17) 0.0347(4) Uani 1 1 d . . . . .
O2 O 0.59450(17) 0.44839(18) 0.64001(16) 0.0337(4) Uani 1 1 d . . . . .
N1 N 1.03839(14) 0.19468(14) 0.29790(13) 0.0133(3) Uani 1 1 d . . . . .
N2 N 0.97818(15) 0.47789(14) 0.34115(13) 0.0139(3) Uani 1 1 d . . . . .
N3 N 0.88347(15) 0.32131(14) 0.36345(13) 0.0139(3) Uani 1 1 d . . . . .
C1 C 1.12116(17) 0.12731(16) 0.27682(15) 0.0144(3) Uani 1 1 d . . . . .
C2 C 1.11848(18) 0.03586(17) 0.32118(17) 0.0169(4) Uani 1 1 d . . . . .
H2 H 1.058746 0.020419 0.363308 0.020 Uiso 1 1 calc R U . . .
C3 C 1.2032(2) -0.03011(18) 0.30255(18) 0.0203(4) Uani 1 1 d . . . . .
H3 H 1.202987 -0.089758 0.334334 0.024 Uiso 1 1 calc R U . . .
C4 C 1.2908(2) -0.0111(2) 0.23698(19) 0.0228(4) Uani 1 1 d . . . . .
H4 H 1.346613 -0.059747 0.222697 0.027 Uiso 1 1 calc R U . . .
C5 C 1.29538(19) 0.07717(19) 0.19405(18) 0.0214(4) Uani 1 1 d . . . . .
H5 H 1.354256 0.089392 0.149904 0.026 Uiso 1 1 calc R U . . .
C6 C 1.21236(18) 0.15060(17) 0.21530(16) 0.0167(4) Uani 1 1 d . . . . .
C7 C 1.21685(19) 0.24647(18) 0.17855(17) 0.0195(4) Uani 1 1 d . . . . .
H7 H 1.272994 0.260904 0.132579 0.023 Uiso 1 1 calc R U . . .
C8 C 1.13943(19) 0.31884(17) 0.20971(17) 0.0181(4) Uani 1 1 d . . . . .
H8 H 1.144099 0.386134 0.189221 0.022 Uiso 1 1 calc R U . . .
C9 C 1.05296(17) 0.29177(16) 0.27254(15) 0.0139(3) Uani 1 1 d . . . . .
C10 C 0.97123(17) 0.36475(16) 0.32084(15) 0.0137(3) Uani 1 1 d . . . . .
C12 C 0.82943(17) 0.40990(16) 0.41503(15) 0.0139(3) Uani 1 1 d . . . . .
C13 C 0.73699(17) 0.41338(18) 0.47783(16) 0.0164(4) Uani 1 1 d . . . . .
H13 H 0.698019 0.347594 0.489740 0.020 Uiso 1 1 calc R U . . .
C14 C 0.70497(18) 0.51756(19) 0.52189(17) 0.0179(4) Uani 1 1 d . . . . .
C15 C 0.76184(19) 0.61550(18) 0.50358(17) 0.0197(4) Uani 1 1 d . . . . .
H15 H 0.735225 0.684724 0.533051 0.024 Uiso 1 1 calc R U . . .
C16 C 0.85505(18) 0.61341(17) 0.44404(17) 0.0180(4) Uani 1 1 d . . . . .
H16 H 0.894591 0.679524 0.433257 0.022 Uiso 1 1 calc R U . . .
C17 C 0.88795(17) 0.50852(17) 0.40051(15) 0.0144(3) Uani 1 1 d . . . . .
C18 C 1.06782(17) 0.55778(16) 0.31788(16) 0.0150(3) Uani 1 1 d . . . . .
H18A H 1.140468 0.526828 0.315909 0.018 Uiso 1 1 calc R U . . .
H18B H 1.077559 0.628125 0.377056 0.018 Uiso 1 1 calc R U . . .
C19 C 1.04341(18) 0.58447(17) 0.21240(17) 0.0172(4) Uani 1 1 d . . . . .
H19A H 0.976863 0.625056 0.216869 0.021 Uiso 1 1 calc R U . . .
H19B H 1.025351 0.514196 0.153395 0.021 Uiso 1 1 calc R U . . .
C20 C 1.1471(2) 0.65617(19) 0.18939(18) 0.0223(4) Uani 1 1 d . . . . .
H20A H 1.211240 0.612219 0.178551 0.027 Uiso 1 1 calc R U . . .
H20B H 1.169747 0.721922 0.252495 0.027 Uiso 1 1 calc R U . . .
C21 C 1.1254(2) 0.6964(2) 0.0906(2) 0.0286(5) Uani 1 1 d . . . . .
H21A H 1.103712 0.631650 0.027695 0.043 Uiso 1 1 calc R U . . .
H21B H 1.194714 0.741110 0.078958 0.043 Uiso 1 1 calc R U . . .
H21C H 1.063753 0.742149 0.101862 0.043 Uiso 1 1 calc R U . . .
C22 C 0.61074(19) 0.5312(2) 0.59426(19) 0.0235(4) Uani 1 1 d . . . . .
C23 C 0.5039(3) 0.4553(3) 0.7118(3) 0.0448(8) Uani 1 1 d . . . . .
H23A H 0.431141 0.451000 0.671194 0.067 Uiso 1 1 calc R U . . .
H23B H 0.519112 0.526410 0.768482 0.067 Uiso 1 1 calc R U . . .
H23C H 0.500484 0.393206 0.744050 0.067 Uiso 1 1 calc R U . . .
C24 C 0.77763(19) 0.08224(19) 0.17745(17) 0.0193(4) Uani 1 1 d . . . . .
C25 C 0.69617(18) 0.1147(2) 0.25364(18) 0.0211(4) Uani 1 1 d . . . . .
C26 C 0.7010(2) 0.0527(2) 0.3295(2) 0.0298(5) Uani 1 1 d . . . . .
C27 C 0.7820(3) -0.0239(2) 0.2971(2) 0.0356(7) Uani 1 1 d . . . . .
C28 C 0.8270(2) -0.0070(2) 0.2026(2) 0.0294(5) Uani 1 1 d . . . . .
C29 C 0.7973(3) 0.1265(3) 0.0830(2) 0.0382(7) Uani 1 1 d . . . . .
H29A H 0.785212 0.204909 0.101160 0.057 Uiso 1 1 calc R U . . .
H29B H 0.744120 0.082531 0.021874 0.057 Uiso 1 1 calc R U . . .
H29C H 0.875597 0.120871 0.063996 0.057 Uiso 1 1 calc R U . . .
C30 C 0.6184(2) 0.1981(3) 0.2502(3) 0.0384(7) Uani 1 1 d . . . . .
H30A H 0.586122 0.221176 0.319518 0.058 Uiso 1 1 calc R U . . .
H30B H 0.556781 0.164374 0.193458 0.058 Uiso 1 1 calc R U . . .
H30C H 0.661068 0.263496 0.235514 0.058 Uiso 1 1 calc R U . . .
C31 C 0.6275(3) 0.0578(4) 0.4207(3) 0.0600(12) Uani 1 1 d . . . . .
H31A H 0.670639 0.044292 0.480844 0.090 Uiso 1 1 calc R U . . .
H31B H 0.560285 0.000542 0.397300 0.090 Uiso 1 1 calc R U . . .
H31C H 0.603437 0.131828 0.443657 0.090 Uiso 1 1 calc R U . . .
C32 C 0.8071(4) -0.1109(3) 0.3504(4) 0.0724(16) Uani 1 1 d . . . . .
H32A H 0.879791 -0.135390 0.329303 0.109 Uiso 1 1 calc R U . . .
H32B H 0.746320 -0.174970 0.328177 0.109 Uiso 1 1 calc R U . . .
H32C H 0.811680 -0.079193 0.428434 0.109 Uiso 1 1 calc R U . . .
C33 C 0.9065(3) -0.0728(3) 0.1353(3) 0.0635(13) Uani 1 1 d . . . . .
H33A H 0.964102 -0.021896 0.113933 0.095 Uiso 1 1 calc R U . . .
H33B H 0.863821 -0.124942 0.071122 0.095 Uiso 1 1 calc R U . . .
H33C H 0.943937 -0.114894 0.176711 0.095 Uiso 1 1 calc R U . . .
Cl1A Cl 0.73754(5) 0.46734(6) 0.16732(5) 0.03178(13) Uani 1 1 d . . . . .
Cl2A Cl 0.80526(5) 0.59410(5) 0.01795(5) 0.02822(12) Uani 1 1 d . . . . .
C1A C 0.6942(2) 0.5054(2) 0.0523(2) 0.0251(4) Uani 1 1 d . . . . .
H1AA H 0.626827 0.544417 0.066194 0.030 Uiso 1 1 calc R U . . .
H1AB H 0.672342 0.437270 -0.008535 0.030 Uiso 1 1 calc R U . . .
P1 P 0.46976(5) 0.21132(5) -0.07376(5) 0.02090(11) Uani 1 1 d . . . . .
F1 F 0.3811(3) 0.2477(2) -0.1499(2) 0.0758(8) Uani 1 1 d . . . . .
F2 F 0.3632(3) 0.1549(2) -0.0322(2) 0.0827(10) Uani 1 1 d . . . . .
F3 F 0.5628(3) 0.1805(3) -0.0073(3) 0.1258(18) Uani 1 1 d . . . . .
F4 F 0.5732(3) 0.2702(3) -0.1220(3) 0.1063(14) Uani 1 1 d . . . . .
F5 F 0.46694(18) 0.32421(19) 0.01819(19) 0.0598(7) Uani 1 1 d . . . . .
F6 F 0.47077(16) 0.10163(18) -0.16967(18) 0.0571(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Cl1 2.3966(6) . ?
Rh1 N1 2.1750(17) . ?
Rh1 N3 2.1049(17) . ?
Rh1 C24 2.136(2) . ?
Rh1 C25 2.163(2) . ?
Rh1 C26 2.145(2) . ?
Rh1 C27 2.159(2) . ?
Rh1 C28 2.177(2) . ?
O1 C22 1.211(3) . ?
O2 C22 1.332(3) . ?
O2 C23 1.454(3) . ?
N1 C1 1.368(3) . ?
N1 C9 1.342(2) . ?
N2 C10 1.364(2) . ?
N2 C17 1.384(3) . ?
N2 C18 1.470(2) . ?
N3 C10 1.331(2) . ?
N3 C12 1.384(3) . ?
C1 C2 1.418(3) . ?
C1 C6 1.426(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.373(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.415(3) . ?
C4 H4 0.9500 . ?
C4 C5 1.368(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.421(3) . ?
C6 C7 1.409(3) . ?
C7 H7 0.9500 . ?
C7 C8 1.373(3) . ?
C8 H8 0.9500 . ?
C8 C9 1.408(3) . ?
C9 C10 1.466(3) . ?
C12 C13 1.398(3) . ?
C12 C17 1.407(3) . ?
C13 H13 0.9500 . ?
C13 C14 1.387(3) . ?
C14 C15 1.412(3) . ?
C14 C22 1.493(3) . ?
C15 H15 0.9500 . ?
C15 C16 1.381(3) . ?
C16 H16 0.9500 . ?
C16 C17 1.398(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C19 1.523(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.525(3) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C20 C21 1.526(3) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 C25 1.434(3) . ?
C24 C28 1.435(3) . ?
C24 C29 1.498(3) . ?
C25 C26 1.419(3) . ?
C25 C30 1.491(4) . ?
C26 C27 1.442(5) . ?
C26 C31 1.498(4) . ?
C27 C28 1.422(5) . ?
C27 C32 1.497(4) . ?
C28 C33 1.491(4) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
Cl1A C1A 1.765(2) . ?
Cl2A C1A 1.772(2) . ?
C1A H1AA 0.9900 . ?
C1A H1AB 0.9900 . ?
P1 F1 1.604(2) . ?
P1 F2 1.564(2) . ?
P1 F3 1.524(2) . ?
P1 F4 1.598(3) . ?
P1 F5 1.5907(19) . ?
P1 F6 1.5874(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Rh1 Cl1 93.05(5) . . ?
N1 Rh1 C28 97.18(9) . . ?
N3 Rh1 Cl1 92.52(5) . . ?
N3 Rh1 N1 75.06(6) . . ?
N3 Rh1 C24 104.45(8) . . ?
N3 Rh1 C25 95.31(8) . . ?
N3 Rh1 C26 119.99(10) . . ?
N3 Rh1 C27 158.55(10) . . ?
N3 Rh1 C28 140.99(9) . . ?
C24 Rh1 Cl1 159.42(6) . . ?
C24 Rh1 N1 102.40(7) . . ?
C24 Rh1 C25 38.96(8) . . ?
C24 Rh1 C26 65.54(9) . . ?
C24 Rh1 C27 65.19(9) . . ?
C24 Rh1 C28 38.85(9) . . ?
C25 Rh1 Cl1 129.20(6) . . ?
C25 Rh1 N1 137.40(8) . . ?
C25 Rh1 C28 64.38(9) . . ?
C26 Rh1 Cl1 96.03(7) . . ?
C26 Rh1 N1 161.90(9) . . ?
C26 Rh1 C25 38.47(9) . . ?
C26 Rh1 C27 39.16(12) . . ?
C26 Rh1 C28 64.87(11) . . ?
C27 Rh1 Cl1 94.89(7) . . ?
C27 Rh1 N1 124.47(11) . . ?
C27 Rh1 C25 64.58(10) . . ?
C27 Rh1 C28 38.28(12) . . ?
C28 Rh1 Cl1 126.34(8) . . ?
C22 O2 C23 115.2(2) . . ?
C1 N1 Rh1 126.43(13) . . ?
C9 N1 Rh1 113.50(13) . . ?
C9 N1 C1 118.42(17) . . ?
C10 N2 C17 106.41(16) . . ?
C10 N2 C18 129.17(17) . . ?
C17 N2 C18 124.10(17) . . ?
C10 N3 Rh1 114.54(13) . . ?
C10 N3 C12 106.34(16) . . ?
C12 N3 Rh1 139.12(14) . . ?
N1 C1 C2 119.13(18) . . ?
N1 C1 C6 121.07(18) . . ?
C2 C1 C6 119.74(18) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 C1 119.26(19) . . ?
C3 C2 H2 120.4 . . ?
C2 C3 H3 119.3 . . ?
C2 C3 C4 121.3(2) . . ?
C4 C3 H3 119.3 . . ?
C3 C4 H4 119.8 . . ?
C5 C4 C3 120.3(2) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.2(2) . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C1 119.02(19) . . ?
C7 C6 C1 118.39(19) . . ?
C7 C6 C5 122.59(19) . . ?
C6 C7 H7 120.3 . . ?
C8 C7 C6 119.46(19) . . ?
C8 C7 H7 120.3 . . ?
C7 C8 H8 120.5 . . ?
C7 C8 C9 118.96(19) . . ?
C9 C8 H8 120.5 . . ?
N1 C9 C8 122.79(18) . . ?
N1 C9 C10 111.68(17) . . ?
C8 C9 C10 125.51(18) . . ?
N2 C10 C9 128.83(18) . . ?
N3 C10 N2 112.29(17) . . ?
N3 C10 C9 118.36(17) . . ?
N3 C12 C13 130.77(18) . . ?
N3 C12 C17 108.30(17) . . ?
C13 C12 C17 120.84(19) . . ?
C12 C13 H13 121.6 . . ?
C14 C13 C12 116.74(19) . . ?
C14 C13 H13 121.6 . . ?
C13 C14 C15 121.89(19) . . ?
C13 C14 C22 121.0(2) . . ?
C15 C14 C22 117.1(2) . . ?
C14 C15 H15 119.1 . . ?
C16 C15 C14 121.8(2) . . ?
C16 C15 H15 119.1 . . ?
C15 C16 H16 121.9 . . ?
C15 C16 C17 116.23(19) . . ?
C17 C16 H16 121.9 . . ?
N2 C17 C12 106.65(17) . . ?
N2 C17 C16 130.91(19) . . ?
C16 C17 C12 122.42(19) . . ?
N2 C18 H18A 108.8 . . ?
N2 C18 H18B 108.8 . . ?
N2 C18 C19 113.81(16) . . ?
H18A C18 H18B 107.7 . . ?
C19 C18 H18A 108.8 . . ?
C19 C18 H18B 108.8 . . ?
C18 C19 H19A 109.8 . . ?
C18 C19 H19B 109.8 . . ?
C18 C19 C20 109.56(18) . . ?
H19A C19 H19B 108.2 . . ?
C20 C19 H19A 109.8 . . ?
C20 C19 H19B 109.8 . . ?
C19 C20 H20A 109.0 . . ?
C19 C20 H20B 109.0 . . ?
C19 C20 C21 112.8(2) . . ?
H20A C20 H20B 107.8 . . ?
C21 C20 H20A 109.0 . . ?
C21 C20 H20B 109.0 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
O1 C22 O2 123.9(2) . . ?
O1 C22 C14 124.3(2) . . ?
O2 C22 C14 111.7(2) . . ?
O2 C23 H23A 109.5 . . ?
O2 C23 H23B 109.5 . . ?
O2 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C24 Rh1 71.53(12) . . ?
C25 C24 C28 107.4(2) . . ?
C25 C24 C29 125.4(2) . . ?
C28 C24 Rh1 72.12(13) . . ?
C28 C24 C29 127.0(2) . . ?
C29 C24 Rh1 126.42(17) . . ?
C24 C25 Rh1 69.51(12) . . ?
C24 C25 C30 124.7(2) . . ?
C26 C25 Rh1 70.08(13) . . ?
C26 C25 C24 108.6(2) . . ?
C26 C25 C30 126.7(2) . . ?
C30 C25 Rh1 127.37(17) . . ?
C25 C26 Rh1 71.45(13) . . ?
C25 C26 C27 107.6(2) . . ?
C25 C26 C31 126.2(3) . . ?
C27 C26 Rh1 70.97(14) . . ?
C27 C26 C31 125.9(3) . . ?
C31 C26 Rh1 127.4(2) . . ?
C26 C27 Rh1 69.87(13) . . ?
C26 C27 C32 125.3(4) . . ?
C28 C27 Rh1 71.53(14) . . ?
C28 C27 C26 108.1(2) . . ?
C28 C27 C32 126.5(4) . . ?
C32 C27 Rh1 127.34(19) . . ?
C24 C28 Rh1 69.03(12) . . ?
C24 C28 C33 124.4(3) . . ?
C27 C28 Rh1 70.19(14) . . ?
C27 C28 C24 108.2(2) . . ?
C27 C28 C33 127.3(3) . . ?
C33 C28 Rh1 129.01(19) . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C25 C30 H30A 109.5 . . ?
C25 C30 H30B 109.5 . . ?
C25 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C26 C31 H31A 109.5 . . ?
C26 C31 H31B 109.5 . . ?
C26 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C27 C32 H32A 109.5 . . ?
C27 C32 H32B 109.5 . . ?
C27 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C28 C33 H33A 109.5 . . ?
C28 C33 H33B 109.5 . . ?
C28 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
Cl1A C1A Cl2A 110.83(13) . . ?
Cl1A C1A H1AA 109.5 . . ?
Cl1A C1A H1AB 109.5 . . ?
Cl2A C1A H1AA 109.5 . . ?
Cl2A C1A H1AB 109.5 . . ?
H1AA C1A H1AB 108.1 . . ?
F2 P1 F1 86.29(19) . . ?
F2 P1 F4 176.3(2) . . ?
F2 P1 F5 89.95(13) . . ?
F2 P1 F6 91.04(12) . . ?
F3 P1 F1 174.6(2) . . ?
F3 P1 F2 99.0(3) . . ?
F3 P1 F4 84.6(3) . . ?
F3 P1 F5 90.56(15) . . ?
F3 P1 F6 91.85(15) . . ?
F4 P1 F1 90.1(2) . . ?
F5 P1 F1 90.35(13) . . ?
F5 P1 F4 90.65(14) . . ?
F6 P1 F1 87.12(13) . . ?
F6 P1 F4 88.20(13) . . ?
F6 P1 F5 177.22(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 N1 C1 C2 -27.7(3) . . . . ?
Rh1 N1 C1 C6 155.14(15) . . . . ?
Rh1 N1 C9 C8 -155.53(16) . . . . ?
Rh1 N1 C9 C10 26.3(2) . . . . ?
Rh1 N3 C10 N2 179.18(12) . . . . ?
Rh1 N3 C10 C9 -8.3(2) . . . . ?
Rh1 N3 C12 C13 4.9(4) . . . . ?
Rh1 N3 C12 C17 -178.49(15) . . . . ?
Rh1 C24 C25 C26 -59.36(16) . . . . ?
Rh1 C24 C25 C30 122.0(2) . . . . ?
Rh1 C24 C28 C27 59.48(16) . . . . ?
Rh1 C24 C28 C33 -123.7(3) . . . . ?
Rh1 C25 C26 C27 -62.15(16) . . . . ?
Rh1 C25 C26 C31 123.2(3) . . . . ?
Rh1 C26 C27 C28 -61.68(17) . . . . ?
Rh1 C26 C27 C32 122.1(3) . . . . ?
Rh1 C27 C28 C24 -58.76(16) . . . . ?
Rh1 C27 C28 C33 124.5(3) . . . . ?
N1 C1 C2 C3 -178.25(19) . . . . ?
N1 C1 C6 C5 -179.01(19) . . . . ?
N1 C1 C6 C7 1.4(3) . . . . ?
N1 C9 C10 N2 158.62(19) . . . . ?
N1 C9 C10 N3 -12.5(3) . . . . ?
N2 C18 C19 C20 -173.11(17) . . . . ?
N3 C12 C13 C14 177.8(2) . . . . ?
N3 C12 C17 N2 -0.8(2) . . . . ?
N3 C12 C17 C16 -179.34(18) . . . . ?
C1 N1 C9 C8 10.8(3) . . . . ?
C1 N1 C9 C10 -167.40(17) . . . . ?
C1 C2 C3 C4 -2.2(3) . . . . ?
C1 C6 C7 C8 5.1(3) . . . . ?
C2 C1 C6 C5 3.9(3) . . . . ?
C2 C1 C6 C7 -175.69(19) . . . . ?
C2 C3 C4 C5 2.7(4) . . . . ?
C3 C4 C5 C6 0.2(4) . . . . ?
C4 C5 C6 C1 -3.4(3) . . . . ?
C4 C5 C6 C7 176.1(2) . . . . ?
C5 C6 C7 C8 -174.4(2) . . . . ?
C6 C1 C2 C3 -1.1(3) . . . . ?
C6 C7 C8 C9 -3.8(3) . . . . ?
C7 C8 C9 N1 -4.3(3) . . . . ?
C7 C8 C9 C10 173.6(2) . . . . ?
C8 C9 C10 N2 -19.5(3) . . . . ?
C8 C9 C10 N3 169.4(2) . . . . ?
C9 N1 C1 C2 167.94(18) . . . . ?
C9 N1 C1 C6 -9.2(3) . . . . ?
C10 N2 C17 C12 0.7(2) . . . . ?
C10 N2 C17 C16 179.0(2) . . . . ?
C10 N2 C18 C19 95.0(2) . . . . ?
C10 N3 C12 C13 -175.9(2) . . . . ?
C10 N3 C12 C17 0.6(2) . . . . ?
C12 N3 C10 N2 -0.2(2) . . . . ?
C12 N3 C10 C9 172.31(17) . . . . ?
C12 C13 C14 C15 0.7(3) . . . . ?
C12 C13 C14 C22 -177.20(19) . . . . ?
C13 C12 C17 N2 176.14(18) . . . . ?
C13 C12 C17 C16 -2.4(3) . . . . ?
C13 C14 C15 C16 -2.4(3) . . . . ?
C13 C14 C22 O1 -159.1(2) . . . . ?
C13 C14 C22 O2 23.2(3) . . . . ?
C14 C15 C16 C17 1.7(3) . . . . ?
C15 C14 C22 O1 22.9(3) . . . . ?
C15 C14 C22 O2 -154.8(2) . . . . ?
C15 C16 C17 N2 -177.5(2) . . . . ?
C15 C16 C17 C12 0.6(3) . . . . ?
C17 N2 C10 N3 -0.3(2) . . . . ?
C17 N2 C10 C9 -171.85(19) . . . . ?
C17 N2 C18 C19 -92.4(2) . . . . ?
C17 C12 C13 C14 1.6(3) . . . . ?
C18 N2 C10 N3 173.28(18) . . . . ?
C18 N2 C10 C9 1.8(3) . . . . ?
C18 N2 C17 C12 -173.32(17) . . . . ?
C18 N2 C17 C16 5.0(3) . . . . ?
C18 C19 C20 C21 -174.23(19) . . . . ?
C22 C14 C15 C16 175.5(2) . . . . ?
C23 O2 C22 O1 2.4(4) . . . . ?
C23 O2 C22 C14 -179.9(2) . . . . ?
C24 C25 C26 Rh1 59.01(15) . . . . ?
C24 C25 C26 C27 -3.1(3) . . . . ?
C24 C25 C26 C31 -177.8(2) . . . . ?
C25 C24 C28 Rh1 -63.26(15) . . . . ?
C25 C24 C28 C27 -3.8(2) . . . . ?
C25 C24 C28 C33 173.1(2) . . . . ?
C25 C26 C27 Rh1 62.47(16) . . . . ?
C25 C26 C27 C28 0.8(3) . . . . ?
C25 C26 C27 C32 -175.4(2) . . . . ?
C26 C27 C28 Rh1 60.63(16) . . . . ?
C26 C27 C28 C24 1.9(3) . . . . ?
C26 C27 C28 C33 -174.8(2) . . . . ?
C28 C24 C25 Rh1 63.65(15) . . . . ?
C28 C24 C25 C26 4.3(2) . . . . ?
C28 C24 C25 C30 -174.4(2) . . . . ?
C29 C24 C25 Rh1 -122.0(2) . . . . ?
C29 C24 C25 C26 178.6(2) . . . . ?
C29 C24 C25 C30 -0.1(4) . . . . ?
C29 C24 C28 Rh1 122.5(2) . . . . ?
C29 C24 C28 C27 -178.0(2) . . . . ?
C29 C24 C28 C33 -1.1(4) . . . . ?
C30 C25 C26 Rh1 -122.3(2) . . . . ?
C30 C25 C26 C27 175.5(2) . . . . ?
C30 C25 C26 C31 0.9(4) . . . . ?
C31 C26 C27 Rh1 -122.9(3) . . . . ?
C31 C26 C27 C28 175.4(2) . . . . ?
C31 C26 C27 C32 -0.7(4) . . . . ?
C32 C27 C28 Rh1 -123.3(3) . . . . ?
C32 C27 C28 C24 178.0(2) . . . . ?
C32 C27 C28 C33 1.3(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
