# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag14pd
_database_code_depnum_ccdc_archive 'CCDC 2352112'
loop_
_audit_author_name
_audit_author_address
'Xiao-Hong Ma'
;zhengzhou university
China
;
_audit_update_record             
;
2024-04-30 deposited with the CCDC.	2024-12-18 downloaded from the CCDC.
;
_audit_creation_date             2021-08-09
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/4
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'1(C180 H120 Ag14 F30 P8 Pd1 S6), 2(C18 H15 P1)'
_chemical_formula_sum            'C216 H150 Ag14 F30 P10 Pd S6'
_chemical_formula_weight         5433.88
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd 0.1215 3.9337 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           167
_space_group_name_H-M_alt        'R -3 c'
_space_group_name_Hall           '-R 3 2"c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'

_cell_length_a                   21.00820(10)
_cell_length_b                   21.00820(10)
_cell_length_c                   88.3377(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     33764.0(4)
_cell_formula_units_Z            6.00012
_cell_measurement_reflns_used    16568
_cell_measurement_temperature    200.00(10)
_cell_measurement_theta_max      72.3090
_cell_measurement_theta_min      3.1540
_shelx_estimated_absorpt_T_max   0.198
_shelx_estimated_absorpt_T_min   0.066
_exptl_absorpt_coefficient_mu    11.961
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.17892
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.27b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'reddish red'
_exptl_crystal_colour_modifier   reddish
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rhombohedral
_exptl_crystal_F_000             15996
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.5
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0364
_diffrn_reflns_av_unetI/netI     0.0282
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       54
_diffrn_reflns_limit_l_min       -106
_diffrn_reflns_number            36726
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.549
_diffrn_reflns_theta_min         3.147
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      200.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     71.00 106.72   0.38    0.38    --   45.50  57.00 -90.00   94
  2  ω    -41.00  83.26   0.38    0.38    --   45.50 -38.00  60.00  327
  3  ω     29.00 124.00   0.38    1.25    --  100.10 -61.00  30.00  250
  4  ω     45.00 131.64   0.38    1.25    --  100.10 -45.00  30.00  228
  5  ω     13.00 119.02   0.38    1.25    --  100.10 -61.00 -60.00  279
  6  ω     21.00 110.30   0.38    1.25    --  100.10 -82.00 -60.00  235
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0065202000
_diffrn_orient_matrix_UB_12      0.0635339000
_diffrn_orient_matrix_UB_13      0.0070482000
_diffrn_orient_matrix_UB_21      0.0781993000
_diffrn_orient_matrix_UB_22      0.0550710000
_diffrn_orient_matrix_UB_23      -0.0054925000
_diffrn_orient_matrix_UB_31      -0.0318161000
_diffrn_orient_matrix_UB_32      0.0097209000
_diffrn_orient_matrix_UB_33      -0.0149838000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6367
_reflns_number_total             7360
_reflns_odcompleteness_completeness 99.92
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.852
_refine_diff_density_min         -0.883
_refine_diff_density_rms         0.071
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         7360
_refine_ls_number_restraints     30
_refine_ls_R_factor_all          0.0304
_refine_ls_R_factor_gt           0.0270
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0459P)²+39.0166P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0782
_refine_ls_wR_factor_ref         0.0808
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 C3-C2 = C4-C3 = C5-C4 = C6-C5 = C6-C1 = C2-C1
 1.38 with sigma of 0.01
 C2-C1 = C6-C1 = C6-C5 = C5-C4 = C4-C3 = C3-C2
 1.38 with sigma of 0.005
3. Rigid bond restraints
 Ag2, Ag2, Ag2, Ag2, Ag2, Ag2
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
Uanis(C2) \\sim Ueq, Uanis(C3) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(Ag2) \\sim Ueq, Uanis(Ag2) \\sim Ueq, Uanis(Ag2) \\sim Ueq, Uanis(Ag2)
\\sim Ueq, Uanis(Ag2) \\sim Ueq, Uanis(Ag2) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
5.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C7(H7), C8(H8), C9(H9), C10(H10),
 C11(H11), C13(H13), C14(H14), C15(H15), C16(H16), C17(H17), C19(H19), C21(H21),
  C22(H22), C23(H23), C24(H24), C25(H25), C26(H26), C27(H27), C29(H29), C30(H30)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.666667 0.333333 0.63954(2) 0.03948(9) Uani 1 3 d S T P . .
Ag2 Ag 0.75755(2) 0.38000(2) 0.60815(2) 0.03208(7) Uani 1 1 d . U . . .
Pd1 Pd 0.666667 0.333333 0.583333 0.02517(9) Uani 1 6 d S T P . .
Ag4 Ag 0.59244(2) 0.40886(2) 0.57779(2) 0.03319(7) Uani 1 1 d . . . . .
S1 S 0.80512(3) 0.43469(3) 0.63316(2) 0.03885(13) Uani 1 1 d . . . . .
P1 P 0.51931(3) 0.47057(3) 0.57381(2) 0.04016(15) Uani 1 1 d . . . . .
P2 P 0.666667 0.333333 0.66810(2) 0.0441(3) Uani 1 3 d S T P . .
F1 F 0.91635(12) 0.50407(12) 0.65769(2) 0.0838(6) Uani 1 1 d . . . . .
F2 F 0.98967(13) 0.44940(15) 0.67242(2) 0.1079(8) Uani 1 1 d . . . . .
F3 F 0.97025(15) 0.31547(19) 0.66507(2) 0.1110(10) Uani 1 1 d . . . . .
F4 F 0.87253(15) 0.23565(14) 0.64301(2) 0.0959(7) Uani 1 1 d . . . . .
F5 F 0.80151(9) 0.28948(9) 0.62774(2) 0.0573(4) Uani 1 1 d . . . . .
C00D C 0.84804(14) 0.33139(16) 0.63868(3) 0.0475(6) Uani 1 1 d . . . . .
C00F C 0.85476(13) 0.39883(15) 0.64210(2) 0.0431(5) Uani 1 1 d . . . . .
C00L C 0.90474(18) 0.43808(18) 0.65367(3) 0.0573(7) Uani 1 1 d . . . . .
C00O C 0.88526(19) 0.3030(2) 0.64622(3) 0.0659(8) Uani 1 1 d . . . . .
C00X C 0.94317(18) 0.4100(2) 0.66117(3) 0.0723(10) Uani 1 1 d . . . . .
C1 C 0.77547(19) 0.3450(2) 0.68890(3) 0.0777(10) Uani 1 1 d D . . . .
H1 H 0.775668 0.385766 0.693075 0.093 Uiso 1 1 calc R . . . .
C2 C 0.8204(2) 0.3202(2) 0.69475(4) 0.0994(14) Uani 1 1 d D U . . .
H2 H 0.851242 0.344914 0.702860 0.119 Uiso 1 1 calc R . . . .
C3 C 0.8201(2) 0.2598(2) 0.68875(4) 0.0916(12) Uani 1 1 d D U . . .
H3 H 0.849867 0.243257 0.692899 0.110 Uiso 1 1 calc R . . . .
C4 C 0.77575(19) 0.2238(2) 0.67664(4) 0.0829(13) Uani 1 1 d D . . . .
H4 H 0.775691 0.183042 0.672521 0.099 Uiso 1 1 calc R . . . .
C5 C 0.73147(19) 0.24808(17) 0.67060(4) 0.0640(8) Uani 1 1 d D . . . .
H5 H 0.701932 0.223942 0.662305 0.077 Uiso 1 1 calc R . . . .
C6 C 0.73035(16) 0.30835(17) 0.67677(3) 0.0552(7) Uani 1 1 d D . . . .
C7 C 0.49720(17) 0.46803(18) 0.60476(3) 0.0525(6) Uani 1 1 d . . . . .
H7 H 0.512458 0.433414 0.604845 0.063 Uiso 1 1 calc R . . . .
C8 C 0.4793(2) 0.4888(2) 0.61827(3) 0.0647(8) Uani 1 1 d . . . . .
H8 H 0.483919 0.469104 0.627358 0.078 Uiso 1 1 calc R . . . .
C9 C 0.45467(18) 0.53810(19) 0.61828(4) 0.0684(10) Uani 1 1 d . . . . .
H9 H 0.441717 0.551168 0.627338 0.082 Uiso 1 1 calc R . . . .
C10 C 0.4492(2) 0.5680(2) 0.60501(4) 0.0783(11) Uani 1 1 d . . . . .
H10 H 0.432335 0.601317 0.605017 0.094 Uiso 1 1 calc R . . . .
C011 C 0.9339(2) 0.3433(2) 0.65760(4) 0.0753(10) Uani 1 1 d . . . . .
C11 C 0.4687(2) 0.5490(2) 0.59151(4) 0.0723(10) Uani 1 1 d . . . . .
H11 H 0.465741 0.570471 0.582533 0.087 Uiso 1 1 calc R . . . .
C12 C 0.49272(15) 0.49807(15) 0.59118(3) 0.0486(6) Uani 1 1 d . . . . .
C13 C 0.36461(16) 0.39788(19) 0.56892(4) 0.0650(8) Uani 1 1 d . . . . .
H13 H 0.359972 0.413377 0.578514 0.078 Uiso 1 1 calc R . . . .
C14 C 0.30289(19) 0.3576(2) 0.56015(5) 0.0837(11) Uani 1 1 d . . . . .
H14 H 0.256896 0.345829 0.563889 0.100 Uiso 1 1 calc R . . . .
C15 C 0.3089(2) 0.3345(2) 0.54588(5) 0.0803(10) Uani 1 1 d . . . . .
H15 H 0.267223 0.308387 0.539918 0.096 Uiso 1 1 calc R . . . .
C16 C 0.37624(19) 0.35010(19) 0.54048(4) 0.0686(8) Uani 1 1 d . . . . .
H16 H 0.380254 0.333595 0.530957 0.082 Uiso 1 1 calc R . . . .
C17 C 0.43864(16) 0.39068(16) 0.54929(3) 0.0542(6) Uani 1 1 d . . . . .
H17 H 0.484347 0.401336 0.545577 0.065 Uiso 1 1 calc R . . . .
C18 C 0.43357(15) 0.41551(14) 0.56356(3) 0.0458(6) Uani 1 1 d . . . . .
C19 C 0.63832(17) 0.59613(18) 0.56225(4) 0.0644(8) Uani 1 1 d . . . . .
H19 H 0.666440 0.580014 0.567329 0.077 Uiso 1 1 calc R . . . .
C20 C 0.56227(15) 0.55494(15) 0.56269(3) 0.0481(6) Uani 1 1 d . . . . .
C21 C 0.52107(18) 0.57931(16) 0.55480(3) 0.0584(7) Uani 1 1 d . . . . .
H21 H 0.470038 0.551319 0.554880 0.070 Uiso 1 1 calc R . . . .
C22 C 0.5553(2) 0.6446(2) 0.54686(4) 0.0824(10) Uani 1 1 d . . . . .
H22 H 0.527467 0.661147 0.541812 0.099 Uiso 1 1 calc R . . . .
C23 C 0.6310(3) 0.6851(2) 0.54647(5) 0.0954(13) Uani 1 1 d . . . . .
H23 H 0.654249 0.728587 0.540945 0.114 Uiso 1 1 calc R . . . .
C24 C 0.6724(2) 0.6618(2) 0.55416(5) 0.0925(12) Uani 1 1 d . . . . .
H24 H 0.723374 0.689972 0.553971 0.111 Uiso 1 1 calc R . . . .
P3 P 0.333333 0.666667 0.62744(2) 0.0595(4) Uani 1 3 d S T P . .
C25 C 0.55324(19) 0.7143(2) 0.64898(5) 0.0769(10) Uani 1 1 d . . . . .
H25 H 0.598106 0.724693 0.653134 0.092 Uiso 1 1 calc R . . . .
C26 C 0.48912(18) 0.65910(19) 0.65481(4) 0.0658(8) Uani 1 1 d . . . . .
H26 H 0.490279 0.631441 0.662915 0.079 Uiso 1 1 calc R . . . .
C27 C 0.42244(17) 0.64417(17) 0.64871(3) 0.0570(7) Uani 1 1 d . . . . .
H27 H 0.379181 0.606943 0.652915 0.068 Uiso 1 1 calc R . . . .
C28 C 0.41857(16) 0.68320(17) 0.63652(3) 0.0534(6) Uani 1 1 d . . . . .
C29 C 0.4844(2) 0.73862(19) 0.63060(5) 0.0751(11) Uani 1 1 d . . . . .
H29 H 0.483783 0.765496 0.622283 0.090 Uiso 1 1 calc R . . . .
C30 C 0.5509(2) 0.7542(2) 0.63699(6) 0.0866(12) Uani 1 1 d . . . . .
H30 H 0.594492 0.792184 0.633073 0.104 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.2284(3) 3_665 ?
Ag1 Ag2 3.2284(3) 2_655 ?
Ag1 Ag2 3.2281(3) . ?
Ag1 S1 2.6681(6) 2_655 ?
Ag1 S1 2.6681(6) . ?
Ag1 S1 2.6681(6) 3_665 ?
Ag1 P2 2.5230(12) . ?
Ag2 Ag2 2.8641(3) 2_655 ?
Ag2 Ag2 2.8642(3) 3_665 ?
Ag2 Pd1 2.74627(16) . ?
Ag2 Ag4 2.8884(2) 3_665 ?
Ag2 Ag4 2.9389(2) 16_545 ?
Ag2 Ag4 2.9106(2) 18_655 ?
Ag2 S1 2.4595(5) . ?
Pd1 Ag2 2.74599(16) 2_655 ?
Pd1 Ag2 2.74622(16) 18_655 ?
Pd1 Ag2 2.74622(16) 16_545 ?
Pd1 Ag2 2.74607(16) 3_665 ?
Pd1 Ag2 2.74622(16) 17 ?
Pd1 Ag4 2.76838(17) 2_655 ?
Pd1 Ag4 2.76834(17) . ?
Pd1 Ag4 2.76843(17) 16_545 ?
Pd1 Ag4 2.76830(17) 18_655 ?
Pd1 Ag4 2.76838(17) 3_665 ?
Pd1 Ag4 2.76830(17) 17 ?
Ag4 Ag2 2.8881(2) 2_655 ?
Ag4 Ag2 2.9105(2) 18_655 ?
Ag4 Ag2 2.9387(2) 16_545 ?
Ag4 Ag4 2.9175(3) 17 ?
Ag4 Ag4 2.8730(3) 18_655 ?
Ag4 P1 2.4811(7) . ?
S1 C00F 1.751(3) . ?
P1 C12 1.823(3) . ?
P1 C18 1.821(3) . ?
P1 C20 1.823(3) . ?
P2 C6 1.831(3) . ?
P2 C6 1.831(3) 3_665 ?
P2 C6 1.831(3) 2_655 ?
F1 C00L 1.330(4) . ?
F2 C00X 1.349(4) . ?
F3 C011 1.346(4) . ?
F4 C00O 1.332(4) . ?
F5 C00D 1.343(3) . ?
C00D C00F 1.385(4) . ?
C00D C00O 1.370(4) . ?
C00F C00L 1.400(4) . ?
C00L C00X 1.384(5) . ?
C00O C011 1.381(5) . ?
C00X C011 1.350(5) . ?
C1 H1 0.9300 . ?
C1 C2 1.386(3) . ?
C1 C6 1.382(3) . ?
C2 H2 0.9300 . ?
C2 C3 1.373(4) . ?
C3 H3 0.9300 . ?
C3 C4 1.371(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.372(3) . ?
C5 H5 0.9300 . ?
C5 C6 1.389(3) . ?
C7 H7 0.9300 . ?
C7 C8 1.385(4) . ?
C7 C12 1.381(4) . ?
C8 H8 0.9300 . ?
C8 C9 1.370(5) . ?
C9 H9 0.9300 . ?
C9 C10 1.361(6) . ?
C10 H10 0.9300 . ?
C10 C11 1.383(5) . ?
C11 H11 0.9300 . ?
C11 C12 1.392(4) . ?
C13 H13 0.9300 . ?
C13 C14 1.379(5) . ?
C13 C18 1.387(4) . ?
C14 H14 0.9300 . ?
C14 C15 1.379(6) . ?
C15 H15 0.9300 . ?
C15 C16 1.368(5) . ?
C16 H16 0.9300 . ?
C16 C17 1.390(4) . ?
C17 H17 0.9300 . ?
C17 C18 1.389(4) . ?
C19 H19 0.9300 . ?
C19 C20 1.386(4) . ?
C19 C24 1.392(5) . ?
C20 C21 1.393(4) . ?
C21 H21 0.9300 . ?
C21 C22 1.379(4) . ?
C22 H22 0.9300 . ?
C22 C23 1.380(6) . ?
C23 H23 0.9300 . ?
C23 C24 1.371(6) . ?
C24 H24 0.9300 . ?
P3 C28 1.830(3) 3_565 ?
P3 C28 1.830(3) . ?
P3 C28 1.829(3) 2_665 ?
C25 H25 0.9300 . ?
C25 C26 1.365(5) . ?
C25 C30 1.366(6) . ?
C26 H26 0.9300 . ?
C26 C27 1.383(4) . ?
C27 H27 0.9300 . ?
C27 C28 1.380(4) . ?
C28 C29 1.389(5) . ?
C29 H29 0.9300 . ?
C29 C30 1.387(6) . ?
C30 H30 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 52.667(7) 3_665 2_655 ?
Ag2 Ag1 Ag2 52.669(7) . 3_665 ?
Ag2 Ag1 Ag2 52.668(7) . 2_655 ?
S1 Ag1 Ag2 48.170(12) 2_655 2_655 ?
S1 Ag1 Ag2 99.619(14) 3_665 2_655 ?
S1 Ag1 Ag2 99.613(14) . 3_665 ?
S1 Ag1 Ag2 99.621(14) 2_655 . ?
S1 Ag1 Ag2 48.168(12) 3_665 3_665 ?
S1 Ag1 Ag2 87.463(13) 2_655 3_665 ?
S1 Ag1 Ag2 87.455(13) . 2_655 ?
S1 Ag1 Ag2 48.160(12) . . ?
S1 Ag1 Ag2 87.462(13) 3_665 . ?
S1 Ag1 S1 115.665(9) 3_665 2_655 ?
S1 Ag1 S1 115.662(9) 3_665 . ?
S1 Ag1 S1 115.663(9) . 2_655 ?
P2 Ag1 Ag2 149.186(4) . . ?
P2 Ag1 Ag2 149.190(4) . 2_655 ?
P2 Ag1 Ag2 149.188(4) . 3_665 ?
P2 Ag1 S1 102.192(13) . 3_665 ?
P2 Ag1 S1 102.192(12) . 2_655 ?
P2 Ag1 S1 102.198(13) . . ?
Ag2 Ag2 Ag1 63.671(3) 3_665 . ?
Ag2 Ag2 Ag1 63.670(3) 2_655 . ?
Ag2 Ag2 Ag2 60.0 2_655 3_665 ?
Ag2 Ag2 Ag4 60.187(6) 3_665 16_545 ?
Ag2 Ag2 Ag4 108.879(6) 3_665 18_655 ?
Ag2 Ag2 Ag4 61.174(6) 2_655 18_655 ?
Ag2 Ag2 Ag4 108.098(5) 2_655 16_545 ?
Ag2 Ag2 Ag4 108.130(5) 3_665 3_665 ?
Ag2 Ag2 Ag4 109.304(5) 2_655 3_665 ?
Pd1 Ag2 Ag1 112.162(6) . . ?
Pd1 Ag2 Ag2 58.564(3) . 3_665 ?
Pd1 Ag2 Ag2 58.563(3) . 2_655 ?
Pd1 Ag2 Ag4 58.512(4) . 18_655 ?
Pd1 Ag2 Ag4 58.788(4) . 3_665 ?
Pd1 Ag2 Ag4 58.163(4) . 16_545 ?
Ag4 Ag2 Ag1 117.111(6) 18_655 . ?
Ag4 Ag2 Ag1 170.877(8) 3_665 . ?
Ag4 Ag2 Ag1 116.271(6) 16_545 . ?
Ag4 Ag2 Ag4 107.569(8) 18_655 16_545 ?
Ag4 Ag2 Ag4 60.406(6) 3_665 18_655 ?
Ag4 Ag2 Ag4 59.073(6) 3_665 16_545 ?
S1 Ag2 Ag1 53.921(14) . . ?
S1 Ag2 Ag2 100.321(15) . 2_655 ?
S1 Ag2 Ag2 115.953(14) . 3_665 ?
S1 Ag2 Pd1 158.644(16) . . ?
S1 Ag2 Ag4 140.135(15) . 16_545 ?
S1 Ag2 Ag4 110.478(15) . 18_655 ?
S1 Ag2 Ag4 134.989(16) . 3_665 ?
Ag2 Pd1 Ag2 178.924(6) 16_545 3_665 ?
Ag2 Pd1 Ag2 178.926(6) 18_655 . ?
Ag2 Pd1 Ag2 62.863(6) 17 16_545 ?
Ag2 Pd1 Ag2 62.863(6) 2_655 . ?
Ag2 Pd1 Ag2 62.865(6) 3_665 . ?
Ag2 Pd1 Ag2 62.863(6) 18_655 16_545 ?
Ag2 Pd1 Ag2 116.511(7) 17 3_665 ?
Ag2 Pd1 Ag2 116.515(7) 16_545 . ?
Ag2 Pd1 Ag2 117.772(7) 18_655 3_665 ?
Ag2 Pd1 Ag2 117.772(7) 16_545 2_655 ?
Ag2 Pd1 Ag2 178.926(6) 17 2_655 ?
Ag2 Pd1 Ag2 117.774(7) 17 . ?
Ag2 Pd1 Ag2 62.863(6) 17 18_655 ?
Ag2 Pd1 Ag2 62.868(6) 3_665 2_655 ?
Ag2 Pd1 Ag2 116.514(7) 18_655 2_655 ?
Ag2 Pd1 Ag4 63.709(5) 17 2_655 ?
Ag2 Pd1 Ag4 64.405(5) . 16_545 ?
Ag2 Pd1 Ag4 116.612(4) 18_655 16_545 ?
Ag2 Pd1 Ag4 63.165(5) 18_655 17 ?
Ag2 Pd1 Ag4 63.170(5) . 3_665 ?
Ag2 Pd1 Ag4 116.837(5) 16_545 2_655 ?
Ag2 Pd1 Ag4 63.710(4) 3_665 16_545 ?
Ag2 Pd1 Ag4 116.844(5) 3_665 18_655 ?
Ag2 Pd1 Ag4 116.616(5) 2_655 3_665 ?
Ag2 Pd1 Ag4 63.166(5) 3_665 2_655 ?
Ag2 Pd1 Ag4 63.165(5) 17 16_545 ?
Ag2 Pd1 Ag4 116.840(5) . 17 ?
Ag2 Pd1 Ag4 115.267(4) 16_545 16_545 ?
Ag2 Pd1 Ag4 115.271(5) 2_655 2_655 ?
Ag2 Pd1 Ag4 116.843(5) 2_655 16_545 ?
Ag2 Pd1 Ag4 115.269(4) 18_655 18_655 ?
Ag2 Pd1 Ag4 64.401(5) 18_655 2_655 ?
Ag2 Pd1 Ag4 116.616(4) . 2_655 ?
Ag2 Pd1 Ag4 64.405(5) 2_655 18_655 ?
Ag2 Pd1 Ag4 63.712(5) . 18_655 ?
Ag2 Pd1 Ag4 115.267(5) 17 17 ?
Ag2 Pd1 Ag4 64.401(5) 17 3_665 ?
Ag2 Pd1 Ag4 116.613(4) 16_545 17 ?
Ag2 Pd1 Ag4 64.404(5) 3_665 17 ?
Ag2 Pd1 Ag4 63.713(5) 2_655 17 ?
Ag2 Pd1 Ag4 116.837(5) 18_655 3_665 ?
Ag2 Pd1 Ag4 116.838(5) 17 . ?
Ag2 Pd1 Ag4 63.711(4) 18_655 . ?
Ag2 Pd1 Ag4 64.401(4) 16_545 . ?
Ag2 Pd1 Ag4 63.709(5) 16_545 3_665 ?
Ag2 Pd1 Ag4 63.167(5) 2_655 . ?
Ag2 Pd1 Ag4 115.269(4) . . ?
Ag2 Pd1 Ag4 116.612(5) 17 18_655 ?
Ag2 Pd1 Ag4 115.271(4) 3_665 3_665 ?
Ag2 Pd1 Ag4 63.165(5) 16_545 18_655 ?
Ag2 Pd1 Ag4 116.618(4) 3_665 . ?
Ag4 Pd1 Ag4 62.516(6) 2_655 17 ?
Ag4 Pd1 Ag4 116.943(2) 16_545 18_655 ?
Ag4 Pd1 Ag4 62.518(6) 3_665 16_545 ?
Ag4 Pd1 Ag4 179.438(6) 2_655 18_655 ?
Ag4 Pd1 Ag4 63.596(6) 2_655 16_545 ?
Ag4 Pd1 Ag4 63.598(6) 17 . ?
Ag4 Pd1 Ag4 116.948(2) 18_655 17 ?
Ag4 Pd1 Ag4 179.435(6) 3_665 17 ?
Ag4 Pd1 Ag4 62.518(6) 18_655 . ?
Ag4 Pd1 Ag4 116.942(2) 3_665 . ?
Ag4 Pd1 Ag4 63.594(6) 3_665 18_655 ?
Ag4 Pd1 Ag4 116.943(2) 16_545 17 ?
Ag4 Pd1 Ag4 179.436(6) 16_545 . ?
Ag4 Pd1 Ag4 116.942(2) 2_655 3_665 ?
Ag4 Pd1 Ag4 116.943(2) 2_655 . ?
Ag2 Ag4 Ag2 107.600(7) 2_655 16_545 ?
Ag2 Ag4 Ag2 58.636(8) 18_655 16_545 ?
Ag2 Ag4 Ag2 107.311(7) 2_655 18_655 ?
Ag2 Ag4 Ag4 59.414(6) 18_655 17 ?
Ag2 Ag4 Ag4 60.173(6) 2_655 17 ?
Pd1 Ag4 Ag2 57.775(4) . 18_655 ?
Pd1 Ag4 Ag2 57.434(4) . 16_545 ?
Pd1 Ag4 Ag2 58.039(5) . 2_655 ?
Pd1 Ag4 Ag4 58.201(3) . 17 ?
Pd1 Ag4 Ag4 58.740(3) . 18_655 ?
Ag4 Ag4 Ag2 107.288(6) 18_655 18_655 ?
Ag4 Ag4 Ag2 106.496(6) 17 16_545 ?
Ag4 Ag4 Ag2 61.339(6) 18_655 2_655 ?
Ag4 Ag4 Ag2 59.585(6) 18_655 16_545 ?
Ag4 Ag4 Ag4 109.178(6) 18_655 17 ?
P1 Ag4 Ag2 125.973(16) . 16_545 ?
P1 Ag4 Ag2 122.030(16) . 18_655 ?
P1 Ag4 Ag2 119.856(16) . 2_655 ?
P1 Ag4 Pd1 176.339(16) . . ?
P1 Ag4 Ag4 123.539(15) . 18_655 ?
P1 Ag4 Ag4 118.285(15) . 17 ?
Ag2 S1 Ag1 77.919(17) . . ?
C00F S1 Ag1 101.97(8) . . ?
C00F S1 Ag2 113.25(9) . . ?
C12 P1 Ag4 114.46(10) . . ?
C18 P1 Ag4 114.38(9) . . ?
C18 P1 C12 104.90(13) . . ?
C18 P1 C20 101.62(12) . . ?
C20 P1 Ag4 116.72(9) . . ?
C20 P1 C12 103.10(12) . . ?
C6 P2 Ag1 114.72(9) . . ?
C6 P2 Ag1 114.73(9) 3_665 . ?
C6 P2 Ag1 114.73(9) 2_655 . ?
C6 P2 C6 103.75(10) . 3_665 ?
C6 P2 C6 103.74(10) 3_665 2_655 ?
C6 P2 C6 103.75(11) . 2_655 ?
F5 C00D C00F 119.7(2) . . ?
F5 C00D C00O 116.8(3) . . ?
C00O C00D C00F 123.4(3) . . ?
C00D C00F S1 124.30(18) . . ?
C00D C00F C00L 115.1(2) . . ?
C00L C00F S1 120.6(2) . . ?
F1 C00L C00F 120.1(3) . . ?
F1 C00L C00X 118.3(3) . . ?
C00X C00L C00F 121.6(3) . . ?
F4 C00O C00D 120.3(3) . . ?
F4 C00O C011 120.1(3) . . ?
C00D C00O C011 119.6(3) . . ?
F2 C00X C00L 119.3(4) . . ?
F2 C00X C011 119.6(3) . . ?
C011 C00X C00L 121.2(3) . . ?
C2 C1 H1 120.5 . . ?
C6 C1 H1 120.5 . . ?
C6 C1 C2 119.1(3) . . ?
C1 C2 H2 119.6 . . ?
C3 C2 C1 120.9(3) . . ?
C3 C2 H2 119.6 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0(3) . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.1 . . ?
C3 C4 C5 119.9(4) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 119.7 . . ?
C4 C5 C6 120.6(3) . . ?
C6 C5 H5 119.7 . . ?
C1 C6 P2 124.1(2) . . ?
C1 C6 C5 119.5(3) . . ?
C5 C6 P2 116.4(2) . . ?
C8 C7 H7 119.5 . . ?
C12 C7 H7 119.5 . . ?
C12 C7 C8 120.9(3) . . ?
C7 C8 H8 119.9 . . ?
C9 C8 C7 120.2(3) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 119.9(3) . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 119.9 . . ?
C9 C10 C11 120.3(3) . . ?
C11 C10 H10 119.9 . . ?
F3 C011 C00O 119.8(4) . . ?
F3 C011 C00X 121.2(3) . . ?
C00X C011 C00O 119.1(3) . . ?
C10 C11 H11 119.6 . . ?
C10 C11 C12 120.9(3) . . ?
C12 C11 H11 119.6 . . ?
C7 C12 P1 119.0(2) . . ?
C7 C12 C11 117.8(3) . . ?
C11 C12 P1 123.2(2) . . ?
C14 C13 H13 119.7 . . ?
C14 C13 C18 120.5(3) . . ?
C18 C13 H13 119.7 . . ?
C13 C14 H14 119.8 . . ?
C13 C14 C15 120.4(3) . . ?
C15 C14 H14 119.8 . . ?
C14 C15 H15 120.0 . . ?
C16 C15 C14 120.0(3) . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.1 . . ?
C15 C16 C17 119.8(3) . . ?
C17 C16 H16 120.1 . . ?
C16 C17 H17 119.6 . . ?
C18 C17 C16 120.8(3) . . ?
C18 C17 H17 119.6 . . ?
C13 C18 P1 124.7(2) . . ?
C13 C18 C17 118.4(3) . . ?
C17 C18 P1 116.9(2) . . ?
C20 C19 H19 120.2 . . ?
C20 C19 C24 119.6(3) . . ?
C24 C19 H19 120.2 . . ?
C19 C20 P1 118.5(2) . . ?
C19 C20 C21 119.4(3) . . ?
C21 C20 P1 122.0(2) . . ?
C20 C21 H21 119.7 . . ?
C22 C21 C20 120.6(3) . . ?
C22 C21 H21 119.7 . . ?
C21 C22 H22 120.2 . . ?
C21 C22 C23 119.5(4) . . ?
C23 C22 H22 120.2 . . ?
C22 C23 H23 119.7 . . ?
C24 C23 C22 120.5(3) . . ?
C24 C23 H23 119.7 . . ?
C19 C24 H24 119.8 . . ?
C23 C24 C19 120.3(4) . . ?
C23 C24 H24 119.8 . . ?
C28 P3 C28 102.25(11) 2_665 3_565 ?
C28 P3 C28 102.24(11) 3_565 . ?
C28 P3 C28 102.25(11) 2_665 . ?
C26 C25 H25 120.3 . . ?
C26 C25 C30 119.4(4) . . ?
C30 C25 H25 120.3 . . ?
C25 C26 H26 119.9 . . ?
C25 C26 C27 120.2(3) . . ?
C27 C26 H26 119.9 . . ?
C26 C27 H27 119.2 . . ?
C28 C27 C26 121.6(3) . . ?
C28 C27 H27 119.2 . . ?
C27 C28 P3 124.9(2) . . ?
C27 C28 C29 117.5(3) . . ?
C29 C28 P3 117.6(3) . . ?
C28 C29 H29 119.8 . . ?
C30 C29 C28 120.5(4) . . ?
C30 C29 H29 119.8 . . ?
C25 C30 C29 120.8(4) . . ?
C25 C30 H30 119.6 . . ?
C29 C30 H30 119.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S1 C00F C00D 60.3(2) . . . . ?
Ag1 S1 C00F C00L -118.9(2) . . . . ?
Ag1 P2 C6 C1 136.0(3) . . . . ?
Ag1 P2 C6 C5 -44.7(3) . . . . ?
Ag2 S1 C00F C00D -21.5(2) . . . . ?
Ag2 S1 C00F C00L 159.2(2) . . . . ?
Ag4 P1 C12 C7 -16.2(3) . . . . ?
Ag4 P1 C12 C11 163.0(2) . . . . ?
Ag4 P1 C18 C13 123.6(2) . . . . ?
Ag4 P1 C18 C17 -57.4(2) . . . . ?
Ag4 P1 C20 C19 -25.8(3) . . . . ?
Ag4 P1 C20 C21 154.8(2) . . . . ?
S1 C00F C00L F1 -1.8(4) . . . . ?
S1 C00F C00L C00X 178.3(3) . . . . ?
P1 C20 C21 C22 178.0(3) . . . . ?
F1 C00L C00X F2 1.3(5) . . . . ?
F1 C00L C00X C011 -179.9(3) . . . . ?
F2 C00X C011 F3 -0.1(5) . . . . ?
F2 C00X C011 C00O 179.0(3) . . . . ?
F4 C00O C011 F3 2.3(5) . . . . ?
F4 C00O C011 C00X -176.7(3) . . . . ?
F5 C00D C00F S1 0.7(3) . . . . ?
F5 C00D C00F C00L -180.0(2) . . . . ?
F5 C00D C00O F4 -2.6(4) . . . . ?
F5 C00D C00O C011 -179.9(3) . . . . ?
C00D C00F C00L F1 178.9(3) . . . . ?
C00D C00F C00L C00X -1.0(4) . . . . ?
C00D C00O C011 F3 179.7(3) . . . . ?
C00D C00O C011 C00X 0.6(5) . . . . ?
C00F C00D C00O F4 175.5(3) . . . . ?
C00F C00D C00O C011 -1.8(5) . . . . ?
C00F C00L C00X F2 -178.8(3) . . . . ?
C00F C00L C00X C011 0.0(5) . . . . ?
C00L C00X C011 F3 -178.8(3) . . . . ?
C00L C00X C011 C00O 0.2(6) . . . . ?
C00O C00D C00F S1 -177.4(2) . . . . ?
C00O C00D C00F C00L 2.0(4) . . . . ?
C1 C2 C3 C4 1.1(7) . . . . ?
C2 C1 C6 P2 178.6(3) . . . . ?
C2 C1 C6 C5 -0.7(5) . . . . ?
C2 C3 C4 C5 -0.4(6) . . . . ?
C3 C4 C5 C6 -0.8(6) . . . . ?
C4 C5 C6 P2 -178.0(3) . . . . ?
C4 C5 C6 C1 1.4(5) . . . . ?
C6 P2 C6 C1 10.1(3) 2_655 . . . ?
C6 P2 C6 C1 -98.1(2) 3_665 . . . ?
C6 P2 C6 C5 -170.6(2) 2_655 . . . ?
C6 P2 C6 C5 81.2(3) 3_665 . . . ?
C6 C1 C2 C3 -0.6(6) . . . . ?
C7 C8 C9 C10 -1.3(5) . . . . ?
C8 C7 C12 P1 178.4(3) . . . . ?
C8 C7 C12 C11 -0.8(5) . . . . ?
C8 C9 C10 C11 -0.3(6) . . . . ?
C9 C10 C11 C12 1.3(6) . . . . ?
C10 C11 C12 P1 -180.0(3) . . . . ?
C10 C11 C12 C7 -0.7(5) . . . . ?
C12 P1 C18 C13 -2.7(3) . . . . ?
C12 P1 C18 C17 176.4(2) . . . . ?
C12 P1 C20 C19 100.6(2) . . . . ?
C12 P1 C20 C21 -78.8(3) . . . . ?
C12 C7 C8 C9 1.9(5) . . . . ?
C13 C14 C15 C16 1.6(6) . . . . ?
C14 C13 C18 P1 178.1(3) . . . . ?
C14 C13 C18 C17 -0.9(5) . . . . ?
C14 C15 C16 C17 -1.5(6) . . . . ?
C15 C16 C17 C18 0.2(5) . . . . ?
C16 C17 C18 P1 -178.1(2) . . . . ?
C16 C17 C18 C13 1.0(4) . . . . ?
C18 P1 C12 C7 110.0(2) . . . . ?
C18 P1 C12 C11 -70.8(3) . . . . ?
C18 P1 C20 C19 -150.9(2) . . . . ?
C18 P1 C20 C21 29.7(3) . . . . ?
C18 C13 C14 C15 -0.4(6) . . . . ?
C19 C20 C21 C22 -1.4(5) . . . . ?
C20 P1 C12 C7 -144.0(2) . . . . ?
C20 P1 C12 C11 35.2(3) . . . . ?
C20 P1 C18 C13 -109.8(3) . . . . ?
C20 P1 C18 C17 69.3(2) . . . . ?
C20 C19 C24 C23 -1.0(6) . . . . ?
C20 C21 C22 C23 1.5(6) . . . . ?
C21 C22 C23 C24 -1.4(7) . . . . ?
C22 C23 C24 C19 1.2(7) . . . . ?
C24 C19 C20 P1 -178.3(3) . . . . ?
C24 C19 C20 C21 1.1(5) . . . . ?
P3 C28 C29 C30 179.7(3) . . . . ?
C25 C26 C27 C28 1.1(5) . . . . ?
C26 C25 C30 C29 -0.7(6) . . . . ?
C26 C27 C28 P3 178.9(2) . . . . ?
C26 C27 C28 C29 -0.3(4) . . . . ?
C27 C28 C29 C30 -1.0(5) . . . . ?
C28 P3 C28 C27 -8.7(3) 3_565 . . . ?
C28 P3 C28 C27 96.90(19) 2_665 . . . ?
C28 P3 C28 C29 -83.9(3) 2_665 . . . ?
C28 P3 C28 C29 170.5(3) 3_565 . . . ?
C28 C29 C30 C25 1.5(6) . . . . ?
C30 C25 C26 C27 -0.6(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 3.782
_oxdiff_exptl_absorpt_empirical_full_min 0.591
