# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_tb-mof-1
_database_code_depnum_ccdc_archive 'CCDC 2346454'
loop_
_audit_author_name
_audit_author_address
'Peng-Kun Wang'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2024-12-09 deposited with the CCDC.	2024-12-13 downloaded from the CCDC.
;
_audit_creation_date             2024-10-14
_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ' [Tb(HDOBPDC)(DMF)]n'
_chemical_formula_moiety         'C17 H14 N O7 Tb, H2O'
_chemical_formula_sum            'C17 H16 N O8 Tb'
_chemical_formula_weight         521.23
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   6.3736(2)
_cell_length_b                   15.8213(5)
_cell_length_c                   24.4175(6)
_cell_angle_alpha                90
_cell_angle_beta                 92.222(2)
_cell_angle_gamma                90
_cell_volume                     2460.38(13)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    11352
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      29.5280
_cell_measurement_theta_min      1.5420
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.908
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.78611
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.407
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rod
_exptl_crystal_F_000             1016
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_unetI/netI     0.0346
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            17403
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.027
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_min         2.816
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'ROD, Synergy Custom DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3723
_reflns_number_total             4354
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    ?
_computing_publication_material  ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.723
_refine_diff_density_min         -1.110
_refine_diff_density_rms         0.181
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     235
_refine_ls_number_reflns         4354
_refine_ls_number_restraints     19
_refine_ls_R_factor_all          0.0432
_refine_ls_R_factor_gt           0.0358
_refine_ls_restrained_S_all      1.115
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0727P)²+4.6044P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1180
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups, All O(H,H) groups
2. Rigid bond restraints
 C15, O3
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C17) \\sim Ueq, Uanis(C16) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(O8) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C15) = Uanis(C16) = Uanis(C17)
4.a Riding coordinates:
 O8(H8a,H8b)
4.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C6(H6), C12(H12), C9(H9), C13(H13), C4(H4), C15(H15)
4.c Idealised Me refined as rotating group:
 C16(H16a,H16b,H16c), C17(H17a,H17b,H17c)
4.d Idealised tetrahedral OH refined as rotating group:
 O5(H5)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb01 Tb 0.73668(3) 0.07096(2) 0.48449(2) 0.01501(13) Uani 1 1 d . . . . .
O4 O 0.0558(5) 0.0354(3) 0.44447(14) 0.0202(8) Uani 1 1 d . . . . .
O2 O 0.6264(6) 0.1647(3) 0.42252(16) 0.0271(9) Uani 1 1 d . . . . .
O6 O 0.3287(6) 0.4721(3) 0.08743(15) 0.0258(9) Uani 1 1 d . . . . .
O1 O 0.3728(6) 0.0609(2) 0.47664(15) 0.0176(8) Uani 1 1 d . . . . .
O7 O 0.6136(6) 0.3932(3) 0.07133(15) 0.0264(9) Uani 1 1 d . . . . .
O3 O 0.9667(7) 0.1773(3) 0.51342(18) 0.0381(11) Uani 1 1 d . U . . .
O5 O 0.0678(7) 0.4184(4) 0.1583(2) 0.0523(16) Uani 1 1 d . . . . .
H5 H 0.110549 0.463261 0.146089 0.078 Uiso 1 1 calc R U . . .
C1 C 0.2292(8) 0.0743(3) 0.4401(2) 0.0180(12) Uani 1 1 d . . . . .
C14 C 0.4581(9) 0.4136(4) 0.0996(2) 0.0242(13) Uani 1 1 d . . . . .
C7 C 0.4673(8) 0.1698(4) 0.3866(2) 0.0222(12) Uani 1 1 d . . . . .
C2 C 0.2680(8) 0.1300(4) 0.3935(2) 0.0241(13) Uani 1 1 d . . . . .
C11 C 0.4246(9) 0.3665(4) 0.1512(2) 0.0283(14) Uani 1 1 d . . . . .
C3 C 0.1062(9) 0.1417(5) 0.3537(2) 0.0361(16) Uani 1 1 d . . . . .
H3 H -0.022973 0.115959 0.358497 0.043 Uiso 1 1 calc R U . . .
C10 C 0.2327(9) 0.3718(4) 0.1774(2) 0.0321(15) Uani 1 1 d . . . . .
C6 C 0.4898(9) 0.2163(4) 0.3387(2) 0.0324(14) Uani 1 1 d . . . . .
H6 H 0.618440 0.241945 0.332979 0.039 Uiso 1 1 calc R U . . .
C12 C 0.5826(10) 0.3180(5) 0.1754(3) 0.0396(17) Uani 1 1 d . . . . .
H12 H 0.711522 0.315478 0.158872 0.048 Uiso 1 1 calc R U . . .
C5 C 0.3294(9) 0.2263(4) 0.2991(2) 0.0344(15) Uani 1 1 d . . . . .
C9 C 0.2047(10) 0.3250(5) 0.2249(3) 0.0393(17) Uani 1 1 d . . . . .
H9 H 0.075879 0.327323 0.241475 0.047 Uiso 1 1 calc R U . . .
C13 C 0.5567(10) 0.2734(5) 0.2226(3) 0.047(2) Uani 1 1 d . . . . .
H13 H 0.667284 0.241836 0.237923 0.056 Uiso 1 1 calc R U . . .
C8 C 0.3625(10) 0.2753(5) 0.2481(2) 0.0378(17) Uani 1 1 d . . . . .
C4 C 0.1331(10) 0.1903(5) 0.3077(3) 0.046(2) Uani 1 1 d . . . . .
H4 H 0.021701 0.199103 0.282616 0.055 Uiso 1 1 calc R U . . .
N1 N 1.1370(13) 0.2823(5) 0.5575(3) 0.066(2) Uani 1 1 d . . . . .
C15 C 0.991(2) 0.2273(7) 0.5501(5) 0.097(2) Uani 1 1 d . U . . .
H15 H 0.891047 0.225905 0.576766 0.116 Uiso 1 1 calc R U . . .
C16 C 1.309(2) 0.2869(8) 0.5198(5) 0.097(2) Uani 1 1 d . U . . .
H16A H 1.319113 0.234151 0.500593 0.145 Uiso 1 1 calc R U . . .
H16B H 1.437944 0.297867 0.539965 0.145 Uiso 1 1 calc R U . . .
H16C H 1.281661 0.331591 0.493854 0.145 Uiso 1 1 calc R U . . .
C17 C 1.1476(19) 0.3419(7) 0.6042(5) 0.097(2) Uani 1 1 d . U . . .
H17A H 1.129119 0.398566 0.590838 0.145 Uiso 1 1 calc R U . . .
H17B H 1.281919 0.337015 0.623093 0.145 Uiso 1 1 calc R U . . .
H17C H 1.038677 0.328707 0.628866 0.145 Uiso 1 1 calc R U . . .
O8 O 0.778(2) 0.3376(8) 0.4368(6) 0.203(6) Uani 1 1 d . U . A 1
H8A H 0.838354 0.297098 0.420706 0.305 Uiso 1 1 d R U . A 1
H8B H 0.672144 0.318988 0.452956 0.305 Uiso 1 1 d R U . A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb01 Tb01 3.8594(5) 3_656 ?
Tb01 O4 2.722(4) 3_656 ?
Tb01 O4 2.358(3) 1_655 ?
Tb01 O2 2.213(4) . ?
Tb01 O6 2.376(4) 2_645 ?
Tb01 O1 2.325(4) . ?
Tb01 O1 2.407(3) 3_656 ?
Tb01 O7 2.358(4) 4_566 ?
Tb01 O3 2.324(4) . ?
Tb01 C1 2.948(5) 3_656 ?
O4 C1 1.274(7) . ?
O2 C7 1.317(7) . ?
O6 C14 1.268(7) . ?
O1 C1 1.272(7) . ?
O7 C14 1.271(7) . ?
O3 C15 1.201(11) . ?
O5 H5 0.8200 . ?
O5 C10 1.352(7) . ?
C1 C2 1.467(7) . ?
C14 C11 1.486(8) . ?
C7 C2 1.434(8) . ?
C7 C6 1.394(8) . ?
C2 C3 1.402(8) . ?
C11 C10 1.405(8) . ?
C11 C12 1.380(8) . ?
C3 H3 0.9300 . ?
C3 C4 1.377(8) . ?
C10 C9 1.392(8) . ?
C6 H6 0.9300 . ?
C6 C5 1.388(8) . ?
C12 H12 0.9300 . ?
C12 C13 1.368(8) . ?
C5 C8 1.490(8) . ?
C5 C4 1.398(9) . ?
C9 H9 0.9300 . ?
C9 C8 1.381(9) . ?
C13 H13 0.9300 . ?
C13 C8 1.406(9) . ?
C4 H4 0.9300 . ?
N1 C15 1.280(12) . ?
N1 C16 1.460(13) . ?
N1 C17 1.477(12) . ?
C15 H15 0.9300 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
O8 H8A 0.8506 . ?
O8 H8B 0.8497 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Tb01 Tb01 129.47(10) 1_655 3_656 ?
O4 Tb01 Tb01 83.09(8) 3_656 3_656 ?
O4 Tb01 O4 73.20(13) 1_655 3_656 ?
O4 Tb01 O6 70.48(13) 1_655 2_645 ?
O4 Tb01 O1 102.97(13) 1_655 3_656 ?
O4 Tb01 C1 25.56(13) 3_656 3_656 ?
O4 Tb01 C1 91.66(14) 1_655 3_656 ?
O2 Tb01 Tb01 107.10(9) . 3_656 ?
O2 Tb01 O4 169.45(12) . 3_656 ?
O2 Tb01 O4 97.62(14) . 1_655 ?
O2 Tb01 O6 83.89(16) . 2_645 ?
O2 Tb01 O1 139.55(13) . 3_656 ?
O2 Tb01 O1 72.55(13) . . ?
O2 Tb01 O7 110.24(15) . 4_566 ?
O2 Tb01 O3 84.42(16) . . ?
O2 Tb01 C1 164.39(15) . 3_656 ?
O6 Tb01 Tb01 69.28(9) 2_645 3_656 ?
O6 Tb01 O4 97.53(13) 2_645 3_656 ?
O6 Tb01 O1 71.08(13) 2_645 3_656 ?
O6 Tb01 C1 87.44(15) 2_645 3_656 ?
O1 Tb01 Tb01 36.06(8) . 3_656 ?
O1 Tb01 Tb01 34.65(8) 3_656 3_656 ?
O1 Tb01 O4 145.38(13) . 1_655 ?
O1 Tb01 O4 49.77(12) 3_656 3_656 ?
O1 Tb01 O4 117.96(11) . 3_656 ?
O1 Tb01 O6 75.43(13) . 2_645 ?
O1 Tb01 O1 70.71(14) . 3_656 ?
O1 Tb01 O7 74.05(13) . 4_566 ?
O1 Tb01 C1 92.72(13) . 3_656 ?
O1 Tb01 C1 24.95(14) 3_656 3_656 ?
O7 Tb01 Tb01 70.95(10) 4_566 3_656 ?
O7 Tb01 O4 138.77(13) 4_566 1_655 ?
O7 Tb01 O4 75.28(13) 4_566 3_656 ?
O7 Tb01 O6 140.15(13) 4_566 2_645 ?
O7 Tb01 O1 75.05(14) 4_566 3_656 ?
O7 Tb01 C1 69.17(15) 4_566 3_656 ?
O3 Tb01 Tb01 148.26(10) . 3_656 ?
O3 Tb01 O4 88.19(15) . 3_656 ?
O3 Tb01 O4 75.81(15) . 1_655 ?
O3 Tb01 O6 142.34(14) . 2_645 ?
O3 Tb01 O1 133.64(15) . . ?
O3 Tb01 O1 134.19(15) . 3_656 ?
O3 Tb01 O7 77.33(14) . 4_566 ?
O3 Tb01 C1 110.13(16) . 3_656 ?
C1 Tb01 Tb01 57.53(11) 3_656 3_656 ?
Tb01 O4 Tb01 106.80(13) 1_455 3_656 ?
C1 O4 Tb01 87.2(3) . 3_656 ?
C1 O4 Tb01 133.2(3) . 1_455 ?
C7 O2 Tb01 135.5(3) . . ?
C14 O6 Tb01 138.4(3) . 2_655 ?
Tb01 O1 Tb01 109.29(14) . 3_656 ?
C1 O1 Tb01 137.3(3) . . ?
C1 O1 Tb01 102.1(3) . 3_656 ?
C14 O7 Tb01 136.1(4) . 4_565 ?
C15 O3 Tb01 140.1(7) . . ?
C10 O5 H5 109.5 . . ?
O4 C1 Tb01 67.3(3) . 3_656 ?
O4 C1 C2 121.9(5) . . ?
O1 C1 Tb01 53.0(2) . 3_656 ?
O1 C1 O4 117.6(5) . . ?
O1 C1 C2 120.4(5) . . ?
C2 C1 Tb01 160.4(4) . 3_656 ?
O6 C14 O7 124.9(5) . . ?
O6 C14 C11 116.8(5) . . ?
O7 C14 C11 118.3(5) . . ?
O2 C7 C2 123.8(5) . . ?
O2 C7 C6 119.3(5) . . ?
C6 C7 C2 116.8(5) . . ?
C7 C2 C1 122.2(5) . . ?
C3 C2 C1 118.4(5) . . ?
C3 C2 C7 119.4(5) . . ?
C10 C11 C14 120.9(5) . . ?
C12 C11 C14 121.0(5) . . ?
C12 C11 C10 118.1(5) . . ?
C2 C3 H3 119.1 . . ?
C4 C3 C2 121.9(6) . . ?
C4 C3 H3 119.1 . . ?
O5 C10 C11 123.6(5) . . ?
O5 C10 C9 117.1(5) . . ?
C9 C10 C11 119.3(5) . . ?
C7 C6 H6 118.4 . . ?
C5 C6 C7 123.2(5) . . ?
C5 C6 H6 118.4 . . ?
C11 C12 H12 118.7 . . ?
C13 C12 C11 122.5(6) . . ?
C13 C12 H12 118.7 . . ?
C6 C5 C8 121.1(5) . . ?
C6 C5 C4 119.3(5) . . ?
C4 C5 C8 119.6(5) . . ?
C10 C9 H9 119.0 . . ?
C8 C9 C10 121.9(6) . . ?
C8 C9 H9 119.0 . . ?
C12 C13 H13 120.1 . . ?
C12 C13 C8 119.9(6) . . ?
C8 C13 H13 120.1 . . ?
C9 C8 C5 121.0(5) . . ?
C9 C8 C13 118.1(5) . . ?
C13 C8 C5 120.9(6) . . ?
C3 C4 C5 119.3(6) . . ?
C3 C4 H4 120.3 . . ?
C5 C4 H4 120.3 . . ?
C15 N1 C16 120.1(9) . . ?
C15 N1 C17 123.6(10) . . ?
C16 N1 C17 116.3(8) . . ?
O3 C15 N1 128.8(12) . . ?
O3 C15 H15 115.6 . . ?
N1 C15 H15 115.6 . . ?
N1 C16 H16A 109.5 . . ?
N1 C16 H16B 109.5 . . ?
N1 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N1 C17 H17A 109.5 . . ?
N1 C17 H17B 109.5 . . ?
N1 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
H8A O8 H8B 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Tb01 O4 C1 Tb01 110.5(4) 1_455 . . 3_656 ?
Tb01 O4 C1 O1 93.5(5) 1_455 . . . ?
Tb01 O4 C1 O1 -17.0(4) 3_656 . . . ?
Tb01 O4 C1 C2 160.5(5) 3_656 . . . ?
Tb01 O4 C1 C2 -89.0(6) 1_455 . . . ?
Tb01 O2 C7 C2 28.4(9) . . . . ?
Tb01 O2 C7 C6 -151.6(5) . . . . ?
Tb01 O6 C14 O7 2.8(10) 2_655 . . . ?
Tb01 O6 C14 C11 -178.0(4) 2_655 . . . ?
Tb01 O1 C1 Tb01 136.9(5) . . . 3_656 ?
Tb01 O1 C1 O4 19.7(5) 3_656 . . . ?
Tb01 O1 C1 O4 156.7(4) . . . . ?
Tb01 O1 C1 C2 -20.9(8) . . . . ?
Tb01 O1 C1 C2 -157.8(4) 3_656 . . . ?
Tb01 O7 C14 O6 -8.5(10) 4_565 . . . ?
Tb01 O7 C14 C11 172.3(4) 4_565 . . . ?
Tb01 O3 C15 N1 -179.9(8) . . . . ?
Tb01 C1 C2 C7 -62.8(14) 3_656 . . . ?
Tb01 C1 C2 C3 114.7(11) 3_656 . . . ?
O4 C1 C2 C7 -176.0(5) . . . . ?
O4 C1 C2 C3 1.5(9) . . . . ?
O2 C7 C2 C1 -4.6(9) . . . . ?
O2 C7 C2 C3 177.9(6) . . . . ?
O2 C7 C6 C5 -178.9(6) . . . . ?
O6 C14 C11 C10 15.7(9) . . . . ?
O6 C14 C11 C12 -162.9(6) . . . . ?
O1 C1 C2 C7 1.4(8) . . . . ?
O1 C1 C2 C3 178.9(5) . . . . ?
O7 C14 C11 C10 -165.1(6) . . . . ?
O7 C14 C11 C12 16.3(9) . . . . ?
O5 C10 C9 C8 -179.9(7) . . . . ?
C1 C2 C3 C4 -177.3(7) . . . . ?
C14 C11 C10 O5 0.2(11) . . . . ?
C14 C11 C10 C9 178.2(6) . . . . ?
C14 C11 C12 C13 -179.5(7) . . . . ?
C7 C2 C3 C4 0.3(11) . . . . ?
C7 C6 C5 C8 -178.9(7) . . . . ?
C7 C6 C5 C4 1.8(11) . . . . ?
C2 C7 C6 C5 1.1(10) . . . . ?
C2 C3 C4 C5 2.7(12) . . . . ?
C11 C10 C9 C8 1.9(11) . . . . ?
C11 C12 C13 C8 0.7(12) . . . . ?
C10 C11 C12 C13 1.9(11) . . . . ?
C10 C9 C8 C5 179.6(7) . . . . ?
C10 C9 C8 C13 0.6(12) . . . . ?
C6 C7 C2 C1 175.4(6) . . . . ?
C6 C7 C2 C3 -2.1(9) . . . . ?
C6 C5 C8 C9 -143.4(7) . . . . ?
C6 C5 C8 C13 35.6(11) . . . . ?
C6 C5 C4 C3 -3.7(12) . . . . ?
C12 C11 C10 O5 178.8(7) . . . . ?
C12 C11 C10 C9 -3.1(10) . . . . ?
C12 C13 C8 C5 179.1(7) . . . . ?
C12 C13 C8 C9 -1.9(12) . . . . ?
C8 C5 C4 C3 177.0(7) . . . . ?
C4 C5 C8 C9 35.9(11) . . . . ?
C4 C5 C8 C13 -145.1(8) . . . . ?
C16 N1 C15 O3 -3(2) . . . . ?
C17 N1 C15 O3 178.7(12) . . . . ?

# end Validation Reply Form
# start Validation Reply Form
_vrf_PLAT602_tb-mof-1            
;
PROBLEM: Solvent Accessible VOID(S) in Structure ........  
RESPONSE: Due to the presence of large channels within this three-dimensional metal-organic framework structure, in which there are many voids occupied by disorder solvent molecules (DMF or H2O in this case), which is a relatively common phenomenon in porous MOFs.
;
