# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aa886c
_database_code_depnum_ccdc_archive 'CCDC 2393281'
loop_
_audit_author_name
_audit_author_address
'Dimitris I. Alexandropoulos'
;university of patras
Greece
;
_audit_update_record             
;
2024-10-23 deposited with the CCDC.	2024-12-22 downloaded from the CCDC.
;
_audit_creation_date             2024-09-09
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C56 H52 Dy N6 O2 Si2, F6 P'
_chemical_formula_sum            'C56 H52 Dy F6 N6 O2 P Si2'
_chemical_formula_weight         1204.68
_chemical_absolute_configuration 'C56 H52 Dy N6 O2 Si2, F6 P'
_chemical_melting_point          ?
_chemical_oxdiff_formula         'Dy1 C56 N4 O2 Si2 P6 F1 '
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   15.49440(10)
_cell_length_b                   15.77890(10)
_cell_length_c                   26.1724(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     6398.75(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    37782
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      78.9160
_cell_measurement_theta_min      3.2500
_shelx_estimated_absorpt_T_max   0.595
_shelx_estimated_absorpt_T_min   0.207
_exptl_absorpt_coefficient_mu    7.328
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.518
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.49 (Rigaku Oxford Diffraction, 2022)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'light yellow'
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.251
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             2436
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 -1 17 0.0788
1 1 -17 0.1117
-10 0 0 0.1627
10 0 0 0.1516
0 -10 -1 0.0465
0 10 1 0.0321
1 -2 -17 0.1016
-1 7 -12 0.1031
0 -9 6 0.0609
-4 9 -6 0.0991
-3 5 13 0.1069
-4 -9 4 0.1037

_exptl_crystal_size_max          0.314
_exptl_crystal_size_mid          0.198
_exptl_crystal_size_min          0.079
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0.0098 -1.0132 16.9999 0.5174 -0.8612 -0.0375
0.9889 1.0121 -17.0018 -0.5207 0.8637 -0.0617
-9.9877 0.0115 0.0186 0.0323 -0.0240 0.9925
9.9877 -0.0115 -0.0186 -0.0323 0.0240 -0.9925
-0.0074 -9.9971 -0.9727 -0.8171 -0.5366 0.0135
0.0074 9.9971 0.9727 0.8171 0.5366 -0.0135
0.9869 -1.9873 -16.9936 -0.7553 0.6885 -0.0584
-1.0014 7.0092 -12.0151 0.1302 0.9730 0.1187
-0.0024 -9.0029 6.0234 -0.4936 -0.8088 -0.0035
-3.9927 9.0075 -6.0160 0.5065 0.7991 0.4005
-2.9849 4.9921 12.9899 0.8562 -0.3293 0.2626
-3.9987 -8.9967 4.0312 -0.5508 -0.7239 0.3980

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0533
_diffrn_reflns_av_unetI/netI     0.0326
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.969
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            56998
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.951
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         80.041
_diffrn_reflns_theta_min         3.270
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -81.00 -49.00   0.40    1.00    --  -47.19 137.00-111.00   80
  2  ω    -88.00 -18.00   0.40    1.00    --  -47.19 133.00  70.00  175
  3  ω     69.00  94.20   0.40    1.00    --   47.19 137.00-111.00   63
  4  ω     68.00 117.20   0.40    1.00    --   47.19 133.00  70.00  123
  5  ω    -97.00 -71.00   0.40    4.00    -- -106.00 133.00  70.00   65
  6  ω    -88.00 -62.00   0.40    4.00    -- -106.00 137.00-111.00   65
  7  ω    149.00 174.20   0.40    4.00    --  113.25 137.00-111.00   63
  8  ω     68.00 124.00   0.40    4.00    --  113.25 137.00-111.00  140
  9  ω     56.00  81.20   0.40    4.00    --  113.25-133.00   3.00   63
 10  ω    -29.00  24.20   0.40    1.00    --  -47.19  19.00 -90.00  133
 11  ω    -43.00  25.00   0.40    1.00    --  -47.19  38.00  30.00  170
 12  ω     81.00 117.00   0.40    1.00    --   47.19 126.00 -60.00   90
 13  ω     75.00 101.00   0.40    1.00    --   47.19 126.00-150.00   65
 14  ω     73.00  98.20   0.40    1.00    --   47.19 126.00  30.00   63
 15  ω    -71.00 -45.00   0.40    4.00    -- -106.00  61.00  60.00   65
 16  ω   -176.00-144.00   0.40    4.00    -- -106.00 -15.00  60.00   80
 17  ω   -103.00 -77.00   0.40    4.00    -- -106.00 114.00-151.14   65
 18  ω    -71.00 -33.00   0.40    4.00    -- -106.00  61.00 120.00   95
 19  ω    -72.00 -40.00   0.40    4.00    -- -106.00 114.00-151.14   80
 20  ω   -126.00 -34.00   0.40    4.00    -- -106.00 144.00 -93.08  230
 21  ω   -107.00 -37.00   0.40    4.00    -- -106.00 108.00 -17.68  175
 22  ω   -138.00 -94.00   0.40    4.00    -- -106.00 -15.00  60.00  110
 23  ω   -107.00 -61.00   0.40    4.00    -- -106.00 106.00  46.44  115
 24  ω   -163.00 -91.00   0.40    4.00    -- -106.00 -61.00 -90.00  180
 25  ω   -106.00 -42.80   0.40    4.00    -- -106.00 104.00 105.15  158
 26  ω     50.00 102.00   0.40    4.00    --  113.25 -95.00  30.00  130
 27  ω     42.00  67.20   0.40    4.00    --  113.25 -61.00-180.00   63
 28  ω     98.00 144.00   0.40    4.00    --  113.25  61.00 150.00  115
 29  ω     97.00 172.20   0.40    4.00    --  113.25  61.00 -30.00  188
 30  ω     44.00  70.00   0.40    4.00    --  113.25 -61.00 150.00   65
 31  ω     99.00 124.20   0.40    4.00    --  113.25 133.00  70.00   63
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  
'XtaLAB Synergy, Single source at home/near, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0030764000
_diffrn_orient_matrix_UB_12      0.0783183000
_diffrn_orient_matrix_UB_13      0.0351074000
_diffrn_orient_matrix_UB_21      0.0023875000
_diffrn_orient_matrix_UB_22      0.0582608000
_diffrn_orient_matrix_UB_23      -0.0471908000
_diffrn_orient_matrix_UB_31      -0.0993734000
_diffrn_orient_matrix_UB_32      -0.0010598000
_diffrn_orient_matrix_UB_33      -0.0022122000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.792
_reflns_Friedel_fraction_full    0.993
_reflns_Friedel_fraction_max     0.929
_reflns_number_gt                12856
_reflns_number_total             13278
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.617
_refine_diff_density_min         -2.199
_refine_diff_density_rms         0.119
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.504(6)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     650
_refine_ls_number_reflns         13278
_refine_ls_number_restraints     84
_refine_ls_R_factor_all          0.0616
_refine_ls_R_factor_gt           0.0606
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1152P)²+8.6992P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1675
_refine_ls_wR_factor_ref         0.1686
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.496(6)
 0.504(6)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
3. Rigid bond restraints
 C50, C49, C48, C47, C46, C45
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C45 \\sim C50 \\sim C49 \\sim C48 \\sim C47 \\sim C46: within 2A with sigma of
0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(F4) \\sim Ueq, Uanis(F2) \\sim Ueq, Uanis(F5) \\sim Ueq, Uanis(F6) \\sim
Ueq, Uanis(F1) \\sim Ueq, Uanis(F3) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(F1) = Uanis(F2)
Uanis(F4) = Uanis(F6)
Uanis(F5) = Uanis(F3)
5. Rigid body (RIGU) restrains
 F3, F4, F1, F6, F5, F2
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
6.a Ternary CH refined with riding coordinates:
 N5(H5), N6(H6)
6.b Secondary CH2 refined with riding coordinates:
 C16(H16A,H16B), C15(H15A,H15B), C17(H17A,H17B), C20(H20A,H20B), C19(H19A,
 H19B), C18(H18A,H18B)
6.c Aromatic/amide H refined with riding coordinates:
 C32(H32), C44(H44), C34(H34), C46(H46), C35(H35), C41(H41), C40(H40),
 C38(H38), C37(H37), C31(H31), C26(H26), C28(H28), C55(H55), C11(H11), C1(H1),
 C52(H52), C36(H36), C42(H42), C6(H6A), C43(H43), C24(H24), C47(H47), C30(H30),
 C50(H50), C56(H56), C7(H7), C25(H25), C23(H23), C14(H14), C48(H48), C54(H54),
 C29(H29), C12(H12), C22(H22), C3(H3), C49(H49), C4(H4), C53(H53)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.20988(2) 0.49049(2) 0.49534(2) 0.03782(14) Uani 1 1 d . . . . .
Si1 Si 0.27866(12) 0.27137(12) 0.52561(9) 0.0377(4) Uani 1 1 d . . . . .
Si2 Si 0.20554(13) 0.72296(12) 0.47394(8) 0.0391(4) Uani 1 1 d . . . . .
P1 P 0.3617(2) 0.3583(2) 0.25342(11) 0.0723(8) Uani 1 1 d . . . . .
O1 O 0.2350(3) 0.3576(3) 0.5083(2) 0.0402(12) Uani 1 1 d . . . . .
F2 F 0.3244(7) 0.4542(7) 0.2549(3) 0.121(2) Uani 1 1 d . U . . .
N5 N 0.0426(4) 0.5336(4) 0.5010(3) 0.0481(16) Uani 1 1 d . . . . .
H5 H 0.036408 0.583333 0.478802 0.058 Uiso 1 1 calc R U . . .
O2 O 0.2204(4) 0.6267(3) 0.4886(3) 0.0486(14) Uani 1 1 d . . . . .
N2 N 0.3721(4) 0.5024(4) 0.4737(3) 0.0408(14) Uani 1 1 d . . . . .
C32 C 0.2794(5) 0.1108(5) 0.4717(3) 0.0419(16) Uani 1 1 d . . . . .
H32 H 0.260474 0.086026 0.501952 0.050 Uiso 1 1 calc R U . . .
C33 C 0.3908(5) 0.2874(5) 0.5529(3) 0.0385(16) Uani 1 1 d . . . . .
C27 C 0.2914(5) 0.1982(5) 0.4702(3) 0.0398(15) Uani 1 1 d . . . . .
C39 C 0.2157(5) 0.7920(5) 0.5328(3) 0.0398(15) Uani 1 1 d . . . . .
C44 C 0.2616(5) 0.8679(5) 0.5322(4) 0.0419(17) Uani 1 1 d . . . . .
H44 H 0.287850 0.885908 0.502117 0.050 Uiso 1 1 calc R U . . .
C34 C 0.4642(5) 0.2874(5) 0.5222(4) 0.0475(19) Uani 1 1 d . . . . .
H34 H 0.458652 0.277198 0.487344 0.057 Uiso 1 1 calc R U . . .
C46 C 0.0224(5) 0.7648(5) 0.4717(4) 0.0501(18) Uani 1 1 d . U . . .
H46 H 0.028167 0.781187 0.505645 0.060 Uiso 1 1 calc R U . . .
C45 C 0.0956(5) 0.7363(5) 0.4454(4) 0.0454(17) Uani 1 1 d . U . . .
N3 N 0.3144(4) 0.5067(4) 0.5709(3) 0.0456(15) Uani 1 1 d . . . . .
C35 C 0.5446(5) 0.3022(5) 0.5423(4) 0.0467(19) Uani 1 1 d . . . . .
H35 H 0.592312 0.304911 0.520776 0.056 Uiso 1 1 calc R U . . .
N4 N 0.1437(5) 0.4988(5) 0.5857(3) 0.0517(17) Uani 1 1 d . . . . .
C10 C 0.4304(5) 0.5093(4) 0.5113(4) 0.049(2) Uani 1 1 d . . . . .
N1 N 0.2534(5) 0.4866(5) 0.4011(3) 0.0505(17) Uani 1 1 d . . . . .
F4 F 0.2870(8) 0.3340(6) 0.2954(4) 0.121(3) Uani 1 1 d . U . . .
C21 C 0.2115(6) 0.2189(5) 0.5769(4) 0.0468(18) Uani 1 1 d . . . . .
C9 C 0.4004(5) 0.5128(5) 0.5634(4) 0.046(2) Uani 1 1 d . . . . .
C16 C 0.0169(6) 0.5616(7) 0.5510(5) 0.060(3) Uani 1 1 d . . . . .
H16A H -0.045602 0.564341 0.552688 0.071 Uiso 1 1 calc R U . . .
H16B H 0.039403 0.618002 0.557151 0.071 Uiso 1 1 calc R U . . .
C15 C 0.0493(6) 0.5029(7) 0.5908(4) 0.057(2) Uani 1 1 d . . . . .
H15A H 0.033708 0.523529 0.624482 0.069 Uiso 1 1 calc R U . . .
H15B H 0.024333 0.447055 0.586242 0.069 Uiso 1 1 calc R U . . .
C2 C 0.4007(6) 0.4957(6) 0.4257(4) 0.053(2) Uani 1 1 d . . . . .
C41 C 0.1874(7) 0.8167(7) 0.6234(4) 0.057(2) Uani 1 1 d . . . . .
H41 H 0.162628 0.799113 0.653941 0.068 Uiso 1 1 calc R U . . .
C40 C 0.1796(6) 0.7663(5) 0.5782(4) 0.0471(19) Uani 1 1 d . . . . .
H40 H 0.149665 0.715267 0.579584 0.056 Uiso 1 1 calc R U . . .
C38 C 0.4022(6) 0.2989(6) 0.6063(4) 0.052(2) Uani 1 1 d . . . . .
H38 H 0.354881 0.297378 0.628176 0.063 Uiso 1 1 calc R U . . .
C5 C 0.5203(5) 0.5178(5) 0.5017(5) 0.060(3) Uani 1 1 d . . . . .
C37 C 0.4866(6) 0.3128(7) 0.6262(4) 0.057(2) Uani 1 1 d . . . . .
H37 H 0.494310 0.321571 0.661017 0.068 Uiso 1 1 calc R U . . .
F5 F 0.2949(8) 0.3373(7) 0.2106(4) 0.132(3) Uani 1 1 d . U . . .
C31 C 0.2945(5) 0.0597(5) 0.4300(3) 0.0439(16) Uani 1 1 d . . . . .
H31 H 0.284902 0.001682 0.432426 0.053 Uiso 1 1 calc R U . . .
N6 N 0.1011(5) 0.4089(5) 0.4318(4) 0.0536(19) Uani 1 1 d . . . . .
H6 H 0.094446 0.352297 0.446736 0.064 Uiso 1 1 calc R U . . .
C8 C 0.4600(6) 0.5244(6) 0.6030(5) 0.056(2) Uani 1 1 d . . . . .
C51 C 0.2851(6) 0.7583(5) 0.4252(3) 0.0447(17) Uani 1 1 d . . . . .
C26 C 0.1269(6) 0.2492(7) 0.5869(4) 0.059(2) Uani 1 1 d . . . . .
H26 H 0.104567 0.293585 0.567619 0.071 Uiso 1 1 calc R U . . .
C28 C 0.3204(6) 0.2323(5) 0.4234(3) 0.0458(19) Uani 1 1 d . . . . .
H28 H 0.330491 0.290151 0.420436 0.055 Uiso 1 1 calc R U . . .
C55 C 0.3284(9) 0.8509(7) 0.3560(4) 0.073(3) Uani 1 1 d . . . . .
H55 H 0.316146 0.897318 0.335306 0.088 Uiso 1 1 calc R U . . .
C11 C 0.4286(7) 0.5283(7) 0.6515(5) 0.067(3) Uani 1 1 d . . . . .
H11 H 0.466299 0.533632 0.678946 0.080 Uiso 1 1 calc R U . . .
C1 C 0.3319(6) 0.4901(7) 0.3875(4) 0.055(2) Uani 1 1 d . . . . .
H1 H 0.345870 0.489157 0.352928 0.066 Uiso 1 1 calc R U . . .
C13 C 0.2861(6) 0.5123(6) 0.6182(4) 0.056(2) Uani 1 1 d . . . . .
C17 C -0.0155(6) 0.4679(7) 0.4787(5) 0.066(3) Uani 1 1 d . . . . .
H17A H -0.073486 0.490676 0.475794 0.079 Uiso 1 1 calc R U . . .
H17B H -0.017696 0.419265 0.501357 0.079 Uiso 1 1 calc R U . . .
F3 F 0.4298(8) 0.3847(8) 0.2978(4) 0.132(3) Uani 1 1 d . U . . .
F6 F 0.4289(8) 0.3869(6) 0.2127(4) 0.121(3) Uani 1 1 d . U . . .
C52 C 0.3654(6) 0.7169(6) 0.4216(4) 0.055(2) Uani 1 1 d . . . . .
H52 H 0.379023 0.672394 0.443451 0.066 Uiso 1 1 calc R U . . .
C36 C 0.5553(6) 0.3131(6) 0.5946(4) 0.055(2) Uani 1 1 d . . . . .
H36 H 0.610385 0.320782 0.607934 0.066 Uiso 1 1 calc R U . . .
C20 C 0.1879(7) 0.4718(6) 0.3628(4) 0.059(2) Uani 1 1 d . . . . .
H20A H 0.213920 0.461283 0.329729 0.071 Uiso 1 1 calc R U . . .
H20B H 0.149512 0.520111 0.360095 0.071 Uiso 1 1 calc R U . . .
C42 C 0.2324(6) 0.8921(6) 0.6206(4) 0.053(2) Uani 1 1 d . . . . .
H42 H 0.237804 0.925780 0.649609 0.064 Uiso 1 1 calc R U . . .
C6 C 0.5792(6) 0.5280(7) 0.5417(5) 0.068(3) Uani 1 1 d . . . . .
H6A H 0.637912 0.531255 0.534564 0.082 Uiso 1 1 calc R U . . .
C43 C 0.2686(6) 0.9173(5) 0.5765(4) 0.051(2) Uani 1 1 d . . . . .
H43 H 0.298659 0.968260 0.575344 0.061 Uiso 1 1 calc R U . . .
C24 C 0.1149(8) 0.1491(8) 0.6540(5) 0.069(3) Uani 1 1 d . . . . .
H24 H 0.082219 0.125499 0.680215 0.083 Uiso 1 1 calc R U . . .
C47 C -0.0584(6) 0.7696(7) 0.4489(5) 0.058(2) Uani 1 1 d . U . . .
H47 H -0.105178 0.790711 0.467121 0.069 Uiso 1 1 calc R U . . .
F1 F 0.3873(7) 0.2618(7) 0.2529(3) 0.121(2) Uani 1 1 d . U . . .
C30 C 0.3230(6) 0.0931(6) 0.3858(4) 0.051(2) Uani 1 1 d . . . . .
H30 H 0.335233 0.057918 0.358293 0.062 Uiso 1 1 calc R U . . .
C50 C 0.0841(6) 0.7097(7) 0.3958(4) 0.058(2) Uani 1 1 d . U . . .
H50 H 0.131773 0.691992 0.377034 0.070 Uiso 1 1 calc R U . . .
C56 C 0.2686(6) 0.8257(5) 0.3902(4) 0.050(2) Uani 1 1 d . . . . .
H56 H 0.215409 0.852986 0.391101 0.061 Uiso 1 1 calc R U . . .
C19 C 0.1392(7) 0.3940(7) 0.3814(5) 0.065(3) Uani 1 1 d . . . . .
H19A H 0.093869 0.380079 0.357218 0.078 Uiso 1 1 calc R U . . .
H19B H 0.178365 0.346120 0.383227 0.078 Uiso 1 1 calc R U . . .
C7 C 0.5525(6) 0.5330(6) 0.5897(6) 0.066(3) Uani 1 1 d . . . . .
H7 H 0.592592 0.542090 0.615506 0.080 Uiso 1 1 calc R U . . .
C25 C 0.0786(7) 0.2136(8) 0.6242(5) 0.071(3) Uani 1 1 d . . . . .
H25 H 0.022289 0.231744 0.630037 0.086 Uiso 1 1 calc R U . . .
C18 C 0.0155(6) 0.4406(7) 0.4272(4) 0.057(2) Uani 1 1 d . . . . .
H18A H -0.022127 0.396746 0.413785 0.068 Uiso 1 1 calc R U . . .
H18B H 0.014469 0.488222 0.403842 0.068 Uiso 1 1 calc R U . . .
C23 C 0.1931(9) 0.1210(7) 0.6462(4) 0.070(3) Uani 1 1 d . . . . .
H23 H 0.215763 0.079163 0.667339 0.084 Uiso 1 1 calc R U . . .
C14 C 0.1909(6) 0.5086(6) 0.6242(4) 0.054(2) Uani 1 1 d . . . . .
H14 H 0.166264 0.513609 0.656432 0.064 Uiso 1 1 calc R U . . .
C48 C -0.0692(6) 0.7424(8) 0.3980(5) 0.064(2) Uani 1 1 d . U . . .
H48 H -0.122471 0.746840 0.381818 0.076 Uiso 1 1 calc R U . . .
C54 C 0.4069(7) 0.8108(7) 0.3503(5) 0.072(3) Uani 1 1 d . . . . .
H54 H 0.445645 0.827206 0.325004 0.087 Uiso 1 1 calc R U . . .
C29 C 0.3339(7) 0.1790(6) 0.3814(4) 0.054(2) Uani 1 1 d . . . . .
H29 H 0.350531 0.202040 0.350173 0.065 Uiso 1 1 calc R U . . .
C12 C 0.3410(7) 0.5243(7) 0.6600(4) 0.063(3) Uani 1 1 d . . . . .
H12 H 0.318851 0.529469 0.692868 0.076 Uiso 1 1 calc R U . . .
C22 C 0.2421(7) 0.1531(6) 0.6070(4) 0.056(2) Uani 1 1 d . . . . .
H22 H 0.296390 0.130342 0.600499 0.067 Uiso 1 1 calc R U . . .
C3 C 0.4869(6) 0.5040(7) 0.4130(5) 0.063(3) Uani 1 1 d . . . . .
H3 H 0.504025 0.503868 0.378988 0.076 Uiso 1 1 calc R U . . .
C49 C 0.0021(7) 0.7085(9) 0.3726(5) 0.068(2) Uani 1 1 d . U . . .
H49 H -0.004500 0.685161 0.340183 0.081 Uiso 1 1 calc R U . . .
C4 C 0.5457(6) 0.5122(7) 0.4504(5) 0.065(3) Uani 1 1 d . . . . .
H4 H 0.604044 0.514236 0.442162 0.078 Uiso 1 1 calc R U . . .
C53 C 0.4258(7) 0.7451(8) 0.3836(5) 0.075(4) Uani 1 1 d . . . . .
H53 H 0.479140 0.718390 0.381273 0.090 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.160(5) . ?
Dy1 N5 2.683(6) . ?
Dy1 O2 2.162(5) . ?
Dy1 N2 2.584(6) . ?
Dy1 N3 2.568(7) . ?
Dy1 N4 2.580(8) . ?
Dy1 N1 2.558(8) . ?
Dy1 N6 2.695(8) . ?
Si1 O1 1.585(5) . ?
Si1 C33 1.896(8) . ?
Si1 C27 1.865(8) . ?
Si1 C21 1.890(9) . ?
Si2 O2 1.583(5) . ?
Si2 C39 1.892(9) . ?
Si2 C45 1.872(9) . ?
Si2 C51 1.860(9) . ?
P1 F2 1.621(10) . ?
P1 F4 1.642(11) . ?
P1 F5 1.562(10) . ?
P1 F3 1.624(11) . ?
P1 F6 1.556(10) . ?
P1 F1 1.573(10) . ?
N5 H5 0.9800 . ?
N5 C16 1.438(14) . ?
N5 C17 1.492(12) . ?
N2 C10 1.340(12) . ?
N2 C2 1.336(12) . ?
C32 H32 0.9300 . ?
C32 C27 1.392(11) . ?
C32 C31 1.376(12) . ?
C33 C34 1.392(12) . ?
C33 C38 1.422(14) . ?
C27 C28 1.411(11) . ?
C39 C44 1.393(11) . ?
C39 C40 1.375(12) . ?
C44 H44 0.9300 . ?
C44 C43 1.402(12) . ?
C34 H34 0.9300 . ?
C34 C35 1.373(12) . ?
C46 H46 0.9300 . ?
C46 C45 1.401(12) . ?
C46 C47 1.389(13) . ?
C45 C50 1.376(14) . ?
N3 C9 1.350(10) . ?
N3 C13 1.317(13) . ?
C35 H35 0.9300 . ?
C35 C36 1.389(15) . ?
N4 C15 1.470(10) . ?
N4 C14 1.254(13) . ?
C10 C9 1.442(14) . ?
C10 C5 1.421(11) . ?
N1 C1 1.268(11) . ?
N1 C20 1.445(14) . ?
C21 C26 1.420(13) . ?
C21 C22 1.386(13) . ?
C9 C8 1.401(14) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C15 1.482(15) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C2 C1 1.465(15) . ?
C2 C3 1.383(12) . ?
C41 H41 0.9300 . ?
C41 C40 1.430(14) . ?
C41 C42 1.381(15) . ?
C40 H40 0.9300 . ?
C38 H38 0.9300 . ?
C38 C37 1.424(13) . ?
C5 C6 1.399(17) . ?
C5 C4 1.402(18) . ?
C37 H37 0.9300 . ?
C37 C36 1.348(15) . ?
C31 H31 0.9300 . ?
C31 C30 1.346(13) . ?
N6 H6 0.9800 . ?
N6 C19 1.464(14) . ?
N6 C18 1.423(12) . ?
C8 C11 1.360(17) . ?
C8 C7 1.480(14) . ?
C51 C52 1.407(12) . ?
C51 C56 1.426(13) . ?
C26 H26 0.9300 . ?
C26 C25 1.353(15) . ?
C28 H28 0.9300 . ?
C28 C29 1.400(13) . ?
C55 H55 0.9300 . ?
C55 C56 1.349(14) . ?
C55 C54 1.379(18) . ?
C11 H11 0.9300 . ?
C11 C12 1.376(15) . ?
C1 H1 0.9300 . ?
C13 C14 1.484(13) . ?
C13 C12 1.400(15) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 C18 1.495(17) . ?
C52 H52 0.9300 . ?
C52 C53 1.436(15) . ?
C36 H36 0.9300 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 C19 1.521(15) . ?
C42 H42 0.9300 . ?
C42 C43 1.343(14) . ?
C6 H6A 0.9300 . ?
C6 C7 1.324(18) . ?
C43 H43 0.9300 . ?
C24 H24 0.9300 . ?
C24 C25 1.400(19) . ?
C24 C23 1.308(18) . ?
C47 H47 0.9300 . ?
C47 C48 1.409(16) . ?
C30 H30 0.9300 . ?
C30 C29 1.370(14) . ?
C50 H50 0.9300 . ?
C50 C49 1.407(14) . ?
C56 H56 0.9300 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C7 H7 0.9300 . ?
C25 H25 0.9300 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C23 H23 0.9300 . ?
C23 C22 1.373(15) . ?
C14 H14 0.9300 . ?
C48 H48 0.9300 . ?
C48 C49 1.397(16) . ?
C54 H54 0.9300 . ?
C54 C53 1.39(2) . ?
C29 H29 0.9300 . ?
C12 H12 0.9300 . ?
C22 H22 0.9300 . ?
C3 H3 0.9300 . ?
C3 C4 1.343(17) . ?
C49 H49 0.9300 . ?
C4 H4 0.9300 . ?
C53 H53 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 N5 114.3(2) . . ?
O1 Dy1 O2 164.6(2) . . ?
O1 Dy1 N2 86.0(2) . . ?
O1 Dy1 N3 82.0(2) . . ?
O1 Dy1 N4 88.7(2) . . ?
O1 Dy1 N1 94.7(2) . . ?
O1 Dy1 N6 75.3(2) . . ?
N5 Dy1 N6 63.3(2) . . ?
O2 Dy1 N5 79.9(2) . . ?
O2 Dy1 N2 80.6(2) . . ?
O2 Dy1 N3 85.2(2) . . ?
O2 Dy1 N4 93.1(3) . . ?
O2 Dy1 N1 85.7(3) . . ?
O2 Dy1 N6 118.1(2) . . ?
N2 Dy1 N5 158.9(2) . . ?
N2 Dy1 N6 120.5(2) . . ?
N3 Dy1 N5 122.8(2) . . ?
N3 Dy1 N2 63.1(2) . . ?
N3 Dy1 N4 62.6(2) . . ?
N3 Dy1 N6 156.4(2) . . ?
N4 Dy1 N5 63.5(3) . . ?
N4 Dy1 N2 125.7(2) . . ?
N4 Dy1 N6 109.9(3) . . ?
N1 Dy1 N5 108.3(3) . . ?
N1 Dy1 N2 62.2(2) . . ?
N1 Dy1 N3 125.3(2) . . ?
N1 Dy1 N4 171.7(3) . . ?
N1 Dy1 N6 63.8(3) . . ?
O1 Si1 C33 112.6(3) . . ?
O1 Si1 C27 110.8(3) . . ?
O1 Si1 C21 110.1(3) . . ?
C27 Si1 C33 106.1(3) . . ?
C27 Si1 C21 109.9(3) . . ?
C21 Si1 C33 107.2(4) . . ?
O2 Si2 C39 110.1(3) . . ?
O2 Si2 C45 109.7(3) . . ?
O2 Si2 C51 110.9(4) . . ?
C45 Si2 C39 109.6(4) . . ?
C51 Si2 C39 109.3(4) . . ?
C51 Si2 C45 107.2(4) . . ?
F2 P1 F4 87.2(5) . . ?
F2 P1 F3 88.6(6) . . ?
F5 P1 F2 88.8(6) . . ?
F5 P1 F4 87.9(7) . . ?
F5 P1 F3 177.3(6) . . ?
F5 P1 F1 87.4(6) . . ?
F3 P1 F4 92.2(7) . . ?
F6 P1 F2 89.0(5) . . ?
F6 P1 F4 176.0(6) . . ?
F6 P1 F5 90.8(7) . . ?
F6 P1 F3 88.9(7) . . ?
F6 P1 F1 96.1(5) . . ?
F1 P1 F2 173.6(7) . . ?
F1 P1 F4 87.6(5) . . ?
F1 P1 F3 95.2(6) . . ?
Si1 O1 Dy1 162.8(3) . . ?
Dy1 N5 H5 105.4 . . ?
C16 N5 Dy1 113.3(6) . . ?
C16 N5 H5 105.4 . . ?
C16 N5 C17 113.6(8) . . ?
C17 N5 Dy1 112.7(6) . . ?
C17 N5 H5 105.4 . . ?
Si2 O2 Dy1 164.2(4) . . ?
C10 N2 Dy1 120.1(5) . . ?
C2 N2 Dy1 121.5(6) . . ?
C2 N2 C10 118.3(7) . . ?
C27 C32 H32 118.9 . . ?
C31 C32 H32 118.9 . . ?
C31 C32 C27 122.3(8) . . ?
C34 C33 Si1 122.1(7) . . ?
C34 C33 C38 117.8(8) . . ?
C38 C33 Si1 120.1(6) . . ?
C32 C27 Si1 125.2(6) . . ?
C32 C27 C28 116.4(8) . . ?
C28 C27 Si1 118.2(6) . . ?
C44 C39 Si2 121.9(6) . . ?
C40 C39 Si2 120.0(6) . . ?
C40 C39 C44 118.1(8) . . ?
C39 C44 H44 119.7 . . ?
C39 C44 C43 120.5(8) . . ?
C43 C44 H44 119.7 . . ?
C33 C34 H34 119.3 . . ?
C35 C34 C33 121.4(9) . . ?
C35 C34 H34 119.3 . . ?
C45 C46 H46 118.8 . . ?
C47 C46 H46 118.8 . . ?
C47 C46 C45 122.4(10) . . ?
C46 C45 Si2 125.2(8) . . ?
C50 C45 Si2 117.5(7) . . ?
C50 C45 C46 117.2(8) . . ?
C9 N3 Dy1 121.2(6) . . ?
C13 N3 Dy1 121.3(6) . . ?
C13 N3 C9 117.4(8) . . ?
C34 C35 H35 119.8 . . ?
C34 C35 C36 120.5(8) . . ?
C36 C35 H35 119.8 . . ?
C15 N4 Dy1 118.8(6) . . ?
C14 N4 Dy1 120.7(6) . . ?
C14 N4 C15 120.1(8) . . ?
N2 C10 C9 118.7(7) . . ?
N2 C10 C5 122.5(10) . . ?
C5 C10 C9 118.7(9) . . ?
C1 N1 Dy1 121.5(7) . . ?
C1 N1 C20 119.1(9) . . ?
C20 N1 Dy1 119.1(6) . . ?
C26 C21 Si1 119.4(7) . . ?
C22 C21 Si1 122.9(7) . . ?
C22 C21 C26 117.6(9) . . ?
N3 C9 C10 116.9(8) . . ?
N3 C9 C8 123.6(9) . . ?
C8 C9 C10 119.5(8) . . ?
N5 C16 H16A 109.5 . . ?
N5 C16 H16B 109.5 . . ?
N5 C16 C15 110.8(8) . . ?
H16A C16 H16B 108.1 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
N4 C15 C16 107.5(8) . . ?
N4 C15 H15A 110.2 . . ?
N4 C15 H15B 110.2 . . ?
C16 C15 H15A 110.2 . . ?
C16 C15 H15B 110.2 . . ?
H15A C15 H15B 108.5 . . ?
N2 C2 C1 114.0(7) . . ?
N2 C2 C3 122.5(10) . . ?
C3 C2 C1 123.0(10) . . ?
C40 C41 H41 120.7 . . ?
C42 C41 H41 120.7 . . ?
C42 C41 C40 118.6(9) . . ?
C39 C40 C41 121.1(8) . . ?
C39 C40 H40 119.4 . . ?
C41 C40 H40 119.4 . . ?
C33 C38 H38 120.3 . . ?
C33 C38 C37 119.5(9) . . ?
C37 C38 H38 120.3 . . ?
C6 C5 C10 121.2(11) . . ?
C6 C5 C4 122.7(9) . . ?
C4 C5 C10 116.0(10) . . ?
C38 C37 H37 119.9 . . ?
C36 C37 C38 120.2(10) . . ?
C36 C37 H37 119.9 . . ?
C32 C31 H31 119.7 . . ?
C30 C31 C32 120.5(8) . . ?
C30 C31 H31 119.7 . . ?
Dy1 N6 H6 104.8 . . ?
C19 N6 Dy1 112.4(6) . . ?
C19 N6 H6 104.8 . . ?
C18 N6 Dy1 117.9(6) . . ?
C18 N6 H6 104.8 . . ?
C18 N6 C19 110.9(9) . . ?
C9 C8 C7 118.4(11) . . ?
C11 C8 C9 117.4(9) . . ?
C11 C8 C7 124.3(10) . . ?
C52 C51 Si2 119.5(7) . . ?
C52 C51 C56 117.5(8) . . ?
C56 C51 Si2 123.0(7) . . ?
C21 C26 H26 119.9 . . ?
C25 C26 C21 120.3(10) . . ?
C25 C26 H26 119.9 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 C27 120.0(8) . . ?
C29 C28 H28 120.0 . . ?
C56 C55 H55 118.6 . . ?
C56 C55 C54 122.9(12) . . ?
C54 C55 H55 118.6 . . ?
C8 C11 H11 119.9 . . ?
C8 C11 C12 120.1(10) . . ?
C12 C11 H11 119.9 . . ?
N1 C1 C2 120.6(9) . . ?
N1 C1 H1 119.7 . . ?
C2 C1 H1 119.7 . . ?
N3 C13 C14 115.4(9) . . ?
N3 C13 C12 122.8(9) . . ?
C12 C13 C14 121.8(9) . . ?
N5 C17 H17A 109.4 . . ?
N5 C17 H17B 109.4 . . ?
N5 C17 C18 111.0(8) . . ?
H17A C17 H17B 108.0 . . ?
C18 C17 H17A 109.4 . . ?
C18 C17 H17B 109.4 . . ?
C51 C52 H52 120.7 . . ?
C51 C52 C53 118.6(10) . . ?
C53 C52 H52 120.7 . . ?
C35 C36 H36 119.7 . . ?
C37 C36 C35 120.6(9) . . ?
C37 C36 H36 119.7 . . ?
N1 C20 H20A 110.7 . . ?
N1 C20 H20B 110.7 . . ?
N1 C20 C19 105.0(9) . . ?
H20A C20 H20B 108.8 . . ?
C19 C20 H20A 110.7 . . ?
C19 C20 H20B 110.7 . . ?
C41 C42 H42 119.7 . . ?
C43 C42 C41 120.7(9) . . ?
C43 C42 H42 119.7 . . ?
C5 C6 H6A 119.6 . . ?
C7 C6 C5 120.8(9) . . ?
C7 C6 H6A 119.6 . . ?
C44 C43 H43 119.5 . . ?
C42 C43 C44 121.0(8) . . ?
C42 C43 H43 119.5 . . ?
C25 C24 H24 118.9 . . ?
C23 C24 H24 118.9 . . ?
C23 C24 C25 122.2(10) . . ?
C46 C47 H47 120.1 . . ?
C46 C47 C48 119.8(10) . . ?
C48 C47 H47 120.1 . . ?
C31 C30 H30 119.9 . . ?
C31 C30 C29 120.1(9) . . ?
C29 C30 H30 119.9 . . ?
C45 C50 H50 119.0 . . ?
C45 C50 C49 121.9(10) . . ?
C49 C50 H50 119.0 . . ?
C51 C56 H56 119.2 . . ?
C55 C56 C51 121.5(10) . . ?
C55 C56 H56 119.2 . . ?
N6 C19 C20 111.0(8) . . ?
N6 C19 H19A 109.4 . . ?
N6 C19 H19B 109.4 . . ?
C20 C19 H19A 109.4 . . ?
C20 C19 H19B 109.4 . . ?
H19A C19 H19B 108.0 . . ?
C8 C7 H7 119.3 . . ?
C6 C7 C8 121.5(10) . . ?
C6 C7 H7 119.3 . . ?
C26 C25 C24 118.8(10) . . ?
C26 C25 H25 120.6 . . ?
C24 C25 H25 120.6 . . ?
N6 C18 C17 109.0(9) . . ?
N6 C18 H18A 109.9 . . ?
N6 C18 H18B 109.9 . . ?
C17 C18 H18A 109.9 . . ?
C17 C18 H18B 109.9 . . ?
H18A C18 H18B 108.3 . . ?
C24 C23 H23 119.9 . . ?
C24 C23 C22 120.3(12) . . ?
C22 C23 H23 119.9 . . ?
N4 C14 C13 119.9(9) . . ?
N4 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C47 C48 H48 120.9 . . ?
C49 C48 C47 118.2(9) . . ?
C49 C48 H48 120.9 . . ?
C55 C54 H54 121.3 . . ?
C55 C54 C53 117.5(10) . . ?
C53 C54 H54 121.3 . . ?
C28 C29 H29 119.7 . . ?
C30 C29 C28 120.5(9) . . ?
C30 C29 H29 119.7 . . ?
C11 C12 C13 118.7(11) . . ?
C11 C12 H12 120.7 . . ?
C13 C12 H12 120.7 . . ?
C21 C22 H22 119.6 . . ?
C23 C22 C21 120.8(10) . . ?
C23 C22 H22 119.6 . . ?
C2 C3 H3 120.3 . . ?
C4 C3 C2 119.3(11) . . ?
C4 C3 H3 120.3 . . ?
C50 C49 H49 119.9 . . ?
C48 C49 C50 120.2(11) . . ?
C48 C49 H49 119.9 . . ?
C5 C4 H4 119.6 . . ?
C3 C4 C5 120.9(9) . . ?
C3 C4 H4 119.6 . . ?
C52 C53 H53 119.0 . . ?
C54 C53 C52 122.0(11) . . ?
C54 C53 H53 119.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 N5 C16 C15 -46.8(9) . . . . ?
Dy1 N5 C17 C18 -48.5(10) . . . . ?
Dy1 N2 C10 C9 -2.1(9) . . . . ?
Dy1 N2 C10 C5 -178.6(5) . . . . ?
Dy1 N2 C2 C1 5.9(11) . . . . ?
Dy1 N2 C2 C3 178.3(8) . . . . ?
Dy1 N3 C9 C10 -0.3(9) . . . . ?
Dy1 N3 C9 C8 177.9(6) . . . . ?
Dy1 N3 C13 C14 0.0(11) . . . . ?
Dy1 N3 C13 C12 -177.6(8) . . . . ?
Dy1 N4 C15 C16 -41.8(10) . . . . ?
Dy1 N4 C14 C13 -2.3(13) . . . . ?
Dy1 N1 C1 C2 0.6(14) . . . . ?
Dy1 N1 C20 C19 -49.7(9) . . . . ?
Dy1 N6 C19 C20 -42.6(10) . . . . ?
Dy1 N6 C18 C17 -39.5(10) . . . . ?
Si1 C33 C34 C35 177.6(7) . . . . ?
Si1 C33 C38 C37 -178.6(7) . . . . ?
Si1 C27 C28 C29 177.6(7) . . . . ?
Si1 C21 C26 C25 -178.5(8) . . . . ?
Si1 C21 C22 C23 175.3(8) . . . . ?
Si2 C39 C44 C43 -179.5(6) . . . . ?
Si2 C39 C40 C41 179.1(7) . . . . ?
Si2 C45 C50 C49 173.1(9) . . . . ?
Si2 C51 C52 C53 179.8(7) . . . . ?
Si2 C51 C56 C55 178.7(8) . . . . ?
O1 Si1 C33 C34 -88.5(7) . . . . ?
O1 Si1 C33 C38 92.3(7) . . . . ?
O1 Si1 C27 C32 -141.4(7) . . . . ?
O1 Si1 C27 C28 42.5(7) . . . . ?
O1 Si1 C21 C26 12.1(9) . . . . ?
O1 Si1 C21 C22 -165.6(8) . . . . ?
N5 C16 C15 N4 57.5(11) . . . . ?
N5 C17 C18 N6 57.9(12) . . . . ?
O2 Si2 C39 C44 135.8(6) . . . . ?
O2 Si2 C39 C40 -42.0(7) . . . . ?
O2 Si2 C45 C46 98.5(8) . . . . ?
O2 Si2 C45 C50 -76.1(8) . . . . ?
O2 Si2 C51 C52 -25.7(8) . . . . ?
O2 Si2 C51 C56 153.7(7) . . . . ?
N2 C10 C9 N3 1.6(11) . . . . ?
N2 C10 C9 C8 -176.7(8) . . . . ?
N2 C10 C5 C6 177.7(8) . . . . ?
N2 C10 C5 C4 -4.7(12) . . . . ?
N2 C2 C1 N1 -4.3(14) . . . . ?
N2 C2 C3 C4 5.5(16) . . . . ?
C32 C27 C28 C29 1.2(12) . . . . ?
C32 C31 C30 C29 -2.6(14) . . . . ?
C33 Si1 O1 Dy1 -6.4(14) . . . . ?
C33 Si1 C27 C32 96.1(7) . . . . ?
C33 Si1 C27 C28 -80.0(7) . . . . ?
C33 Si1 C21 C26 134.9(8) . . . . ?
C33 Si1 C21 C22 -42.8(9) . . . . ?
C33 C34 C35 C36 3.5(13) . . . . ?
C33 C38 C37 C36 -1.4(15) . . . . ?
C27 Si1 O1 Dy1 -125.1(13) . . . . ?
C27 Si1 C33 C34 32.9(8) . . . . ?
C27 Si1 C33 C38 -146.4(7) . . . . ?
C27 Si1 C21 C26 -110.2(8) . . . . ?
C27 Si1 C21 C22 72.1(9) . . . . ?
C27 C32 C31 C30 0.9(13) . . . . ?
C27 C28 C29 C30 -2.9(15) . . . . ?
C39 Si2 O2 Dy1 135.1(15) . . . . ?
C39 Si2 C45 C46 -22.5(9) . . . . ?
C39 Si2 C45 C50 162.9(7) . . . . ?
C39 Si2 C51 C52 95.9(7) . . . . ?
C39 Si2 C51 C56 -84.7(8) . . . . ?
C39 C44 C43 C42 1.0(13) . . . . ?
C44 C39 C40 C41 1.3(12) . . . . ?
C34 C33 C38 C37 2.1(13) . . . . ?
C34 C35 C36 C37 -2.6(14) . . . . ?
C46 C45 C50 C49 -1.9(16) . . . . ?
C46 C47 C48 C49 2.1(17) . . . . ?
C45 Si2 O2 Dy1 14.4(17) . . . . ?
C45 Si2 C39 C44 -103.5(7) . . . . ?
C45 Si2 C39 C40 78.8(7) . . . . ?
C45 Si2 C51 C52 -145.4(7) . . . . ?
C45 Si2 C51 C56 34.0(8) . . . . ?
C45 C46 C47 C48 2.2(15) . . . . ?
C45 C50 C49 C48 6.2(19) . . . . ?
N3 C9 C8 C11 1.1(14) . . . . ?
N3 C9 C8 C7 -178.0(8) . . . . ?
N3 C13 C14 N4 1.6(14) . . . . ?
N3 C13 C12 C11 -1.7(16) . . . . ?
C10 N2 C2 C1 -178.9(8) . . . . ?
C10 N2 C2 C3 -6.5(14) . . . . ?
C10 C9 C8 C11 179.2(8) . . . . ?
C10 C9 C8 C7 0.2(12) . . . . ?
C10 C5 C6 C7 -2.5(15) . . . . ?
C10 C5 C4 C3 3.6(14) . . . . ?
N1 C20 C19 N6 59.3(11) . . . . ?
C21 Si1 O1 Dy1 113.2(13) . . . . ?
C21 Si1 C33 C34 150.2(7) . . . . ?
C21 Si1 C33 C38 -29.0(8) . . . . ?
C21 Si1 C27 C32 -19.5(8) . . . . ?
C21 Si1 C27 C28 164.4(6) . . . . ?
C21 C26 C25 C24 2.5(17) . . . . ?
C9 N3 C13 C14 177.7(8) . . . . ?
C9 N3 C13 C12 0.1(14) . . . . ?
C9 C10 C5 C6 1.1(12) . . . . ?
C9 C10 C5 C4 178.7(8) . . . . ?
C9 C8 C11 C12 -2.6(15) . . . . ?
C9 C8 C7 C6 -1.5(15) . . . . ?
C16 N5 C17 C18 -179.1(9) . . . . ?
C15 N4 C14 C13 -174.4(9) . . . . ?
C2 N2 C10 C9 -177.3(7) . . . . ?
C2 N2 C10 C5 6.1(12) . . . . ?
C2 C3 C4 C5 -4.0(16) . . . . ?
C41 C42 C43 C44 0.0(14) . . . . ?
C40 C39 C44 C43 -1.6(12) . . . . ?
C40 C41 C42 C43 -0.3(15) . . . . ?
C38 C33 C34 C35 -3.2(13) . . . . ?
C38 C37 C36 C35 1.6(15) . . . . ?
C5 C10 C9 N3 178.3(7) . . . . ?
C5 C10 C9 C8 0.0(11) . . . . ?
C5 C6 C7 C8 2.7(17) . . . . ?
C31 C32 C27 Si1 -176.3(6) . . . . ?
C31 C32 C27 C28 -0.2(12) . . . . ?
C31 C30 C29 C28 3.6(16) . . . . ?
C8 C11 C12 C13 2.9(17) . . . . ?
C51 Si2 O2 Dy1 -103.8(15) . . . . ?
C51 Si2 C39 C44 13.7(7) . . . . ?
C51 Si2 C39 C40 -164.0(7) . . . . ?
C51 Si2 C45 C46 -141.1(7) . . . . ?
C51 Si2 C45 C50 44.4(8) . . . . ?
C51 C52 C53 C54 -0.6(16) . . . . ?
C26 C21 C22 C23 -2.5(15) . . . . ?
C55 C54 C53 C52 2.3(17) . . . . ?
C11 C8 C7 C6 179.5(11) . . . . ?
C1 N1 C20 C19 124.2(10) . . . . ?
C1 C2 C3 C4 177.3(10) . . . . ?
C13 N3 C9 C10 -178.0(7) . . . . ?
C13 N3 C9 C8 0.2(13) . . . . ?
C17 N5 C16 C15 83.5(10) . . . . ?
C52 C51 C56 C55 -1.9(14) . . . . ?
C20 N1 C1 C2 -173.2(9) . . . . ?
C42 C41 C40 C39 -0.3(14) . . . . ?
C6 C5 C4 C3 -178.8(10) . . . . ?
C24 C23 C22 C21 3.7(17) . . . . ?
C47 C46 C45 Si2 -176.9(7) . . . . ?
C47 C46 C45 C50 -2.3(14) . . . . ?
C47 C48 C49 C50 -6.1(18) . . . . ?
C56 C51 C52 C53 0.4(13) . . . . ?
C56 C55 C54 C53 -3.9(18) . . . . ?
C19 N6 C18 C17 -171.0(8) . . . . ?
C7 C8 C11 C12 176.4(10) . . . . ?
C25 C24 C23 C22 -1.7(19) . . . . ?
C18 N6 C19 C20 91.7(10) . . . . ?
C23 C24 C25 C26 -1.4(19) . . . . ?
C14 N4 C15 C16 130.4(10) . . . . ?
C14 C13 C12 C11 -179.1(10) . . . . ?
C54 C55 C56 C51 3.8(17) . . . . ?
C12 C13 C14 N4 179.1(10) . . . . ?
C22 C21 C26 C25 -0.6(15) . . . . ?
C3 C2 C1 N1 -176.6(10) . . . . ?
C4 C5 C6 C7 -180.0(10) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.508 -0.032 0.250 869.5 306.7 ?
2 -0.705 -0.790 0.750 869.5 306.7 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.458
_oxdiff_exptl_absorpt_empirical_full_min 0.586
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.496(6)
2 0.504(6)

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aa656b_plates_auto
_database_code_depnum_ccdc_archive 'CCDC 2393282'
loop_
_audit_author_name
_audit_author_address
'Dimitris I. Alexandropoulos'
;university of patras
Greece
;
_audit_update_record             
;
2024-10-23 deposited with the CCDC.	2024-12-22 downloaded from the CCDC.
;
_audit_creation_date             2024-10-03
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        plate
_chemical_formula_moiety         'C56 H50 Dy N4 O4 Si2, F6 P'
_chemical_formula_sum            'C56 H50 Dy F6 N4 O4 P Si2'
_chemical_formula_weight         1206.65
_chemical_melting_point          ?
_chemical_oxdiff_formula         'Dy Cl C N O Si P F'
_chemical_oxdiff_usercomment     C
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.6004(4)
_cell_length_b                   14.1007(4)
_cell_length_c                   15.7213(4)
_cell_angle_alpha                65.991(2)
_cell_angle_beta                 89.277(2)
_cell_angle_gamma                73.563(2)
_cell_volume                     2623.41(13)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    29163
_cell_measurement_temperature    190.1(5)
_cell_measurement_theta_max      76.3310
_cell_measurement_theta_min      3.0930
_shelx_estimated_absorpt_T_max   0.367
_shelx_estimated_absorpt_T_min   0.188
_exptl_absorpt_coefficient_mu    8.957
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.558
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.90a (Rigaku Oxford Diffraction, 2023)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'light yellow'
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.528
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1218
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-7 3 5 0.0805
3 -6 -7 0.0580
-8 -5 -3 0.1321
0 8 8 0.0965
8 -1 -2 0.0950
-5 0 8 0.0797
5 -1 -8 0.0543
-3 -8 2 0.0636
1 9 2 0.0759
4 0 8 0.0968
-5 -3 -8 0.1306

_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-6.6033 3.4191 4.9409 -0.0859 0.4817 0.8721
3.1874 -6.4791 -7.2387 0.0017 -0.0352 -0.9994
-8.3372 -4.8526 -2.9788 -0.1839 0.9829 0.0027
0.0637 7.9016 7.9281 0.0662 -0.3289 0.9420
8.2400 -0.5551 -2.4349 0.1377 -0.7528 -0.6437
-5.3038 0.0535 7.9133 -0.6992 0.2496 0.6699
5.1553 -1.1777 -8.1994 0.6133 -0.2198 -0.7586
-3.4118 -7.6163 1.6402 -0.9004 0.3156 -0.2994
1.2363 8.8427 2.1487 0.6846 -0.2376 0.6891
4.2189 0.3829 7.7259 -0.6829 -0.7214 0.1148
-5.0406 -2.5213 -8.1036 0.5063 0.8272 -0.2438

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0254
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.965
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            36242
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.965
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.952
_diffrn_reflns_theta_min         3.098
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      190.1(5)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -61.00  24.20   0.40    0.50    --  -47.34  91.00  79.00  213
  2  ω    -23.00  45.00   0.40    0.50    --   47.34 -91.00 -33.00  170
  3  ω   -177.00-111.00   0.40    1.00    -- -106.00 -91.00 -33.00  165
  4  ω    -99.00 -59.00   0.40    1.00    -- -106.00  91.00  79.00  100
  5  ω     81.00 176.20   0.40    1.00    --  106.10  91.00  79.00  238
  6  ω     45.00  70.20   0.40    1.00    --  106.10 -91.00 -33.00   63
  7  ω    -93.00 -39.00   0.40    0.50    --  -47.34 -38.00 -30.00  135
  8  ω     -1.00  28.20   0.40    0.50    --  -47.34  19.00   0.00   73
  9  ω    -26.00  28.00   0.40    0.50    --  -47.34  19.00-120.00  135
 10  ω     38.00 119.20   0.40    0.50    --   47.34  77.00  60.00  203
 11  ω    -20.00   5.20   0.40    0.50    --   47.34 -77.00-120.00   63
 12  ω     -9.00  15.80   0.40    0.50    --   47.34 -19.00 -60.00   62
 13  ω    -22.00  42.80   0.40    0.50    --   47.34 -38.00  30.00  162
 14  ω     23.00  68.20   0.40    0.50    --   47.34 -77.00-120.00  113
 15  ω   -176.00 -82.80   0.40    1.00    -- -106.00 -77.00 -60.00  233
 16  ω   -112.00 -86.00   0.40    1.00    -- -106.00 125.00-150.00   65
 17  ω   -176.00 -94.00   0.40    1.00    -- -106.00 -30.00   0.00  205
 18  ω    -77.00 -39.00   0.40    1.00    -- -106.00 125.00-150.00   95
 19  ω   -112.00 -58.00   0.40    1.00    -- -106.00 125.00 -60.00  135
 20  ω   -110.00 -60.00   0.40    1.00    -- -106.00 125.00  90.00  125
 21  ω   -164.00 -96.00   0.40    1.00    -- -106.00 -61.00   0.00  170
 22  ω   -168.00-116.00   0.40    1.00    -- -106.00 -61.00  60.00  130
 23  ω    -68.00 -36.00   0.40    1.00    -- -106.00  61.00 -60.00   80
 24  ω   -120.00 -50.00   0.40    1.00    -- -106.00 137.00  57.76  175
 25  ω   -100.00 -66.00   0.40    1.00    -- -106.00  77.00  90.00   85
 26  ω   -108.00 -74.80   0.40    1.00    -- -106.00 114.00 164.99   83
 27  ω   -107.00 -37.00   0.40    1.00    -- -106.00 108.00 -54.50  175
 28  ω   -112.00 -52.00   0.40    1.00    -- -106.00 125.00 -30.00  150
 29  ω    -76.00 -36.00   0.40    1.00    -- -106.00 125.00 120.00  100
 30  ω     49.00  75.00   0.40    1.00    --  106.10-125.00  90.00   65
 31  ω     38.00 106.00   0.40    1.00    --  106.10-125.00 -90.00  170
 32  ω     78.00 122.00   0.40    1.00    --  106.10 125.00 120.00  110
 33  ω     88.00 164.00   0.40    1.00    --  106.10  77.00   0.00  190
 34  ω     39.00  69.00   0.40    1.00    --  106.10 -95.00 -60.00   75
 35  ω     44.00 103.20   0.40    1.00    --  106.10-125.00-120.00  148
 36  ω     40.00  67.20   0.40    1.00    --  106.10 -61.00-120.00   68
 37  ω     36.00  65.20   0.40    1.00    --  106.10 -61.00 150.00   73
 38  ω    113.00 171.00   0.40    1.00    --  106.10  45.00  30.00  145
 39  ω     76.00 101.20   0.40    1.00    --  106.10 -77.00 120.00   63
 40  ω     34.00  60.80   0.40    1.00    --  106.10 -61.00 120.00   67
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  
'XtaLAB Synergy, Single source at home/near, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0035530000
_diffrn_orient_matrix_UB_12      0.1001279000
_diffrn_orient_matrix_UB_13      -0.0914191000
_diffrn_orient_matrix_UB_21      -0.1025804000
_diffrn_orient_matrix_UB_22      -0.0034901000
_diffrn_orient_matrix_UB_23      -0.0371850000
_diffrn_orient_matrix_UB_31      -0.0600512000
_diffrn_orient_matrix_UB_32      0.0756626000
_diffrn_orient_matrix_UB_33      0.0438954000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10437
_reflns_number_total             10691
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.90a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.90a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.90a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.748
_refine_diff_density_min         -0.621
_refine_diff_density_rms         0.057
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     722
_refine_ls_number_reflns         10691
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0267
_refine_ls_R_factor_gt           0.0261
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0455P)²+0.7954P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0708
_refine_ls_wR_factor_ref         0.0711
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 P1-F1 \\sim P1-F1A
 with sigma of 0.02
 P1-F2 \\sim P1-F2A
 with sigma of 0.02
 P1-F3 \\sim P1-F3A
 with sigma of 0.02
 P1-F4 \\sim P1-F4A
 with sigma of 0.02
 P1-F5 \\sim P1-F5A
 with sigma of 0.02
 P1-F6 \\sim P1-F6A
 with sigma of 0.02
3. Others
 Sof(F1A)=Sof(F2A)=Sof(F3A)=Sof(F4A)=Sof(F5A)=Sof(F6A)=1-FVAR(1)
 Sof(F1)=Sof(F2)=Sof(F3)=Sof(F4)=Sof(F5)=Sof(F6)=FVAR(1)
4.a Secondary CH2 refined with riding coordinates:
 C15(H15A,H15B), C16(H16A,H16B), C17(H17A,H17B), C18(H18A,H18B), C19(H19A,
 H19B), C20(H20A,H20B)
4.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C3(H3), C4(H4), C7(H7), C8(H8), C11(H11), C12(H12), C14(H14),
 C21(H21), C22(H22), C23(H23), C24(H24), C25(H25), C27(H27), C28(H28), C29(H29),
  C30(H30), C31(H31), C33(H33), C34(H34), C35(H35), C36(H36), C37(H37),
 C39(H39), C40(H40), C41(H41), C42(H42), C43(H43), C45(H45), C46(H46), C47(H47),
  C48(H48), C49(H49), C51(H51), C52(H52), C53(H53), C54(H54), C55(H55)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.30374(2) 0.65903(2) 0.76344(2) 0.02578(5) Uani 1 1 d . . . . .
Si1 Si 0.24205(4) 0.95829(4) 0.67376(4) 0.02825(11) Uani 1 1 d . . . . .
Si2 Si 0.35721(4) 0.36923(4) 0.83245(4) 0.03074(11) Uani 1 1 d . . . . .
O1 O 0.38628(12) 0.66552(13) 0.90865(11) 0.0384(3) Uani 1 1 d . . . . .
O2 O 0.19698(13) 0.66743(14) 0.89997(11) 0.0419(4) Uani 1 1 d . . . . .
O3 O 0.24834(11) 0.83313(11) 0.70991(10) 0.0318(3) Uani 1 1 d . . . . .
O4 O 0.35678(12) 0.48345(11) 0.83061(11) 0.0362(3) Uani 1 1 d . . . . .
N1 N 0.12547(14) 0.62953(14) 0.76657(14) 0.0375(4) Uani 1 1 d . . . . .
N2 N 0.20768(13) 0.69221(13) 0.60559(13) 0.0323(3) Uani 1 1 d . . . . .
N3 N 0.40124(13) 0.69952(13) 0.61339(11) 0.0297(3) Uani 1 1 d . . . . .
N4 N 0.49976(13) 0.63126(13) 0.78127(12) 0.0305(3) Uani 1 1 d . . . . .
C1 C 0.07247(17) 0.64610(18) 0.69332(18) 0.0425(5) Uani 1 1 d . . . . .
H1 H 0.007689 0.632393 0.697383 0.051 Uiso 1 1 calc R U . . .
C2 C 0.11174(17) 0.68644(18) 0.60257(18) 0.0397(5) Uani 1 1 d . . . . .
C3 C 0.0509(2) 0.7173(2) 0.5183(2) 0.0537(6) Uani 1 1 d . . . . .
H3 H -0.017307 0.712272 0.519295 0.064 Uiso 1 1 calc R U . . .
C4 C 0.0906(2) 0.7545(2) 0.4356(2) 0.0542(7) Uani 1 1 d . . . . .
H4 H 0.050576 0.775379 0.378181 0.065 Uiso 1 1 calc R U . . .
C5 C 0.19127(19) 0.7615(2) 0.43585(17) 0.0438(5) Uani 1 1 d . . . . .
C6 C 0.24678(17) 0.72839(16) 0.52388(14) 0.0344(4) Uani 1 1 d . . . . .
C7 C 0.2398(2) 0.7991(2) 0.35278(17) 0.0545(7) Uani 1 1 d . . . . .
H7 H 0.202456 0.821455 0.293722 0.065 Uiso 1 1 calc R U . . .
C8 C 0.3368(2) 0.8037(2) 0.35589(17) 0.0531(6) Uani 1 1 d . . . . .
H8 H 0.366868 0.828690 0.299192 0.064 Uiso 1 1 calc R U . . .
C9 C 0.39636(19) 0.77121(19) 0.44399(15) 0.0408(5) Uani 1 1 d . . . . .
C10 C 0.35061(16) 0.73354(16) 0.52740(14) 0.0328(4) Uani 1 1 d . . . . .
C11 C 0.4980(2) 0.7730(2) 0.45146(16) 0.0463(5) Uani 1 1 d . . . . .
H11 H 0.531041 0.798890 0.396760 0.056 Uiso 1 1 calc R U . . .
C12 C 0.54955(19) 0.7369(2) 0.53842(17) 0.0428(5) Uani 1 1 d . . . . .
H12 H 0.619186 0.736104 0.544838 0.051 Uiso 1 1 calc R U . . .
C13 C 0.49844(16) 0.70149(17) 0.61743(15) 0.0328(4) Uani 1 1 d . . . . .
C14 C 0.55021(16) 0.66152(17) 0.71232(15) 0.0331(4) Uani 1 1 d . . . . .
H14 H 0.620108 0.658475 0.721692 0.040 Uiso 1 1 calc R U . . .
C15 C 0.55144(17) 0.59238(18) 0.87491(15) 0.0373(4) Uani 1 1 d . . . . .
H15A H 0.623160 0.595837 0.871673 0.045 Uiso 1 1 calc R U . . .
H15B H 0.553422 0.515937 0.913057 0.045 Uiso 1 1 calc R U . . .
C16 C 0.49062(18) 0.6653(2) 0.91766(16) 0.0411(5) Uani 1 1 d . . . . .
H16A H 0.517002 0.637112 0.984514 0.049 Uiso 1 1 calc R U . . .
H16B H 0.495645 0.740034 0.884217 0.049 Uiso 1 1 calc R U . . .
C17 C 0.31784(19) 0.7387(2) 0.94015(16) 0.0454(5) Uani 1 1 d . . . . .
H17A H 0.293781 0.812890 0.888763 0.055 Uiso 1 1 calc R U . . .
H17B H 0.353196 0.741907 0.993110 0.055 Uiso 1 1 calc R U . . .
C18 C 0.2294(2) 0.6959(2) 0.97051(17) 0.0507(6) Uani 1 1 d . . . . .
H18A H 0.250258 0.630998 1.031303 0.061 Uiso 1 1 calc R U . . .
H18B H 0.171856 0.752047 0.978390 0.061 Uiso 1 1 calc R U . . .
C19 C 0.09721(19) 0.6521(2) 0.91008(19) 0.0510(6) Uani 1 1 d . . . . .
H19A H 0.042761 0.723515 0.884481 0.061 Uiso 1 1 calc R U . . .
H19B H 0.090261 0.612751 0.977166 0.061 Uiso 1 1 calc R U . . .
C20 C 0.08625(19) 0.5867(2) 0.85704(19) 0.0487(6) Uani 1 1 d . . . . .
H20A H 0.125779 0.509037 0.893417 0.058 Uiso 1 1 calc R U . . .
H20B H 0.012780 0.591974 0.847274 0.058 Uiso 1 1 calc R U . . .
C21 C 0.1407(2) 0.9915(2) 0.50207(18) 0.0494(6) Uani 1 1 d . . . . .
H21 H 0.123772 0.927206 0.539663 0.059 Uiso 1 1 calc R U . . .
C22 C 0.1079(3) 1.0426(2) 0.4062(2) 0.0679(9) Uani 1 1 d . . . . .
H22 H 0.068818 1.013539 0.379151 0.081 Uiso 1 1 calc R U . . .
C23 C 0.1324(3) 1.1350(3) 0.35104(19) 0.0689(10) Uani 1 1 d . . . . .
H23 H 0.111280 1.169419 0.285460 0.083 Uiso 1 1 calc R U . . .
C24 C 0.1876(2) 1.1781(2) 0.3906(2) 0.0664(9) Uani 1 1 d . . . . .
H24 H 0.203945 1.242535 0.352379 0.080 Uiso 1 1 calc R U . . .
C25 C 0.21958(19) 1.1273(2) 0.48660(19) 0.0500(6) Uani 1 1 d . . . . .
H25 H 0.257062 1.158066 0.513313 0.060 Uiso 1 1 calc R U . . .
C26 C 0.19743(16) 1.03206(16) 0.54417(15) 0.0346(4) Uani 1 1 d . . . . .
C27 C 0.08314(18) 0.96688(19) 0.79064(18) 0.0427(5) Uani 1 1 d . . . . .
H27 H 0.085980 0.898350 0.791596 0.051 Uiso 1 1 calc R U . . .
C28 C 0.0130(2) 1.0095(2) 0.8407(2) 0.0549(6) Uani 1 1 d . . . . .
H28 H -0.030890 0.969831 0.875797 0.066 Uiso 1 1 calc R U . . .
C29 C 0.0071(2) 1.1095(2) 0.8393(2) 0.0518(6) Uani 1 1 d . . . . .
H29 H -0.040696 1.138683 0.873650 0.062 Uiso 1 1 calc R U . . .
C30 C 0.07035(18) 1.1667(2) 0.78828(19) 0.0459(6) Uani 1 1 d . . . . .
H30 H 0.065731 1.235935 0.786566 0.055 Uiso 1 1 calc R U . . .
C31 C 0.14119(17) 1.12338(18) 0.73910(17) 0.0384(5) Uani 1 1 d . . . . .
H31 H 0.185190 1.163233 0.704566 0.046 Uiso 1 1 calc R U . . .
C32 C 0.14884(15) 1.02163(16) 0.73957(14) 0.0315(4) Uani 1 1 d . . . . .
C33 C 0.4077(2) 0.9816(2) 0.77107(19) 0.0489(6) Uani 1 1 d . . . . .
H33 H 0.359678 0.995736 0.812101 0.059 Uiso 1 1 calc R U . . .
C34 C 0.5108(2) 0.9725(3) 0.7897(2) 0.0626(8) Uani 1 1 d . . . . .
H34 H 0.532475 0.979986 0.843238 0.075 Uiso 1 1 calc R U . . .
C35 C 0.5809(2) 0.9527(2) 0.7310(2) 0.0616(8) Uani 1 1 d . . . . .
H35 H 0.651179 0.946207 0.743940 0.074 Uiso 1 1 calc R U . . .
C36 C 0.5496(2) 0.9423(2) 0.6533(2) 0.0576(7) Uani 1 1 d . . . . .
H36 H 0.598059 0.928976 0.612306 0.069 Uiso 1 1 calc R U . . .
C37 C 0.44685(18) 0.95140(19) 0.63470(19) 0.0448(5) Uani 1 1 d . . . . .
H37 H 0.426033 0.944474 0.580595 0.054 Uiso 1 1 calc R U . . .
C38 C 0.37375(16) 0.97034(16) 0.69325(16) 0.0360(4) Uani 1 1 d . . . . .
C39 C 0.1947(2) 0.3949(2) 0.70107(19) 0.0515(6) Uani 1 1 d . . . . .
H39 H 0.156022 0.378100 0.753032 0.062 Uiso 1 1 calc R U . . .
C40 C 0.1476(3) 0.4226(3) 0.6127(2) 0.0721(10) Uani 1 1 d . . . . .
H40 H 0.078310 0.423062 0.604757 0.086 Uiso 1 1 calc R U . . .
C41 C 0.2019(4) 0.4490(3) 0.5374(2) 0.0890(14) Uani 1 1 d . . . . .
H41 H 0.170119 0.467859 0.476903 0.107 Uiso 1 1 calc R U . . .
C42 C 0.3025(4) 0.4485(3) 0.5482(2) 0.0903(14) Uani 1 1 d . . . . .
H42 H 0.338979 0.468893 0.495000 0.108 Uiso 1 1 calc R U . . .
C43 C 0.3516(3) 0.4179(3) 0.6383(2) 0.0665(8) Uani 1 1 d . . . . .
H43 H 0.421479 0.415770 0.645722 0.080 Uiso 1 1 calc R U . . .
C44 C 0.2975(2) 0.39092(18) 0.71588(16) 0.0433(5) Uani 1 1 d . . . . .
C45 C 0.26652(17) 0.32989(19) 1.00275(16) 0.0386(4) Uani 1 1 d . . . . .
H45 H 0.291133 0.386298 1.003433 0.046 Uiso 1 1 calc R U . . .
C46 C 0.2153(2) 0.2792(2) 1.07620(18) 0.0501(6) Uani 1 1 d . . . . .
H46 H 0.205455 0.300320 1.126632 0.060 Uiso 1 1 calc R U . . .
C47 C 0.17848(19) 0.1974(2) 1.07543(19) 0.0512(6) Uani 1 1 d . . . . .
H47 H 0.144048 0.161664 1.125932 0.061 Uiso 1 1 calc R U . . .
C48 C 0.19161(18) 0.16787(19) 1.00190(19) 0.0460(5) Uani 1 1 d . . . . .
H48 H 0.164506 0.113192 1.000807 0.055 Uiso 1 1 calc R U . . .
C49 C 0.24447(17) 0.21777(17) 0.92909(17) 0.0379(4) Uani 1 1 d . . . . .
H49 H 0.254545 0.195286 0.879444 0.045 Uiso 1 1 calc R U . . .
C50 C 0.28312(15) 0.30039(15) 0.92743(14) 0.0316(4) Uani 1 1 d . . . . .
C51 C 0.57531(18) 0.31515(18) 0.82225(16) 0.0384(4) Uani 1 1 d . . . . .
H51 H 0.561079 0.390735 0.783490 0.046 Uiso 1 1 calc R U . . .
C52 C 0.67677(18) 0.2476(2) 0.84089(17) 0.0418(5) Uani 1 1 d . . . . .
H52 H 0.730574 0.277047 0.814708 0.050 Uiso 1 1 calc R U . . .
C53 C 0.69899(19) 0.1377(2) 0.89754(19) 0.0451(5) Uani 1 1 d . . . . .
H53 H 0.768075 0.091092 0.910599 0.054 Uiso 1 1 calc R U . . .
C54 C 0.6202(2) 0.09606(19) 0.9350(2) 0.0507(6) Uani 1 1 d . . . . .
H54 H 0.635184 0.020472 0.974111 0.061 Uiso 1 1 calc R U . . .
C55 C 0.51900(18) 0.16372(17) 0.91610(19) 0.0436(5) Uani 1 1 d . . . . .
H55 H 0.465787 0.133494 0.942741 0.052 Uiso 1 1 calc R U . . .
C56 C 0.49374(16) 0.27523(16) 0.85878(15) 0.0332(4) Uani 1 1 d . . . . .
P1 P 0.84913(5) 0.46710(5) 0.75745(4) 0.04465(13) Uani 1 1 d D . . . .
F1 F 0.7420(3) 0.4598(3) 0.8001(3) 0.0591(10) Uani 0.654(9) 1 d D . P A 1
F1A F 0.7407(5) 0.4738(8) 0.7356(14) 0.127(6) Uani 0.346(9) 1 d D . P A 2
F2 F 0.8414(4) 0.3874(4) 0.7126(4) 0.0662(11) Uani 0.654(9) 1 d D . P A 1
F2A F 0.8871(11) 0.3977(7) 0.6966(6) 0.086(3) Uani 0.346(9) 1 d D . P A 2
F3 F 0.9084(7) 0.3675(7) 0.8487(6) 0.103(3) Uani 0.654(9) 1 d D . P A 1
F3A F 0.8778(12) 0.3545(11) 0.8453(9) 0.076(4) Uani 0.346(9) 1 d D . P A 2
F4 F 0.8461(5) 0.5573(5) 0.7945(4) 0.0827(14) Uani 0.654(9) 1 d D . P A 1
F4A F 0.8308(12) 0.5225(9) 0.8292(7) 0.103(4) Uani 0.346(9) 1 d D . P A 2
F5 F 0.7795(4) 0.5688(3) 0.6640(2) 0.0793(16) Uani 0.654(9) 1 d D . P A 1
F5A F 0.8414(12) 0.5742(6) 0.6727(6) 0.117(4) Uani 0.346(9) 1 d D . P A 2
F6 F 0.9471(4) 0.4811(4) 0.7098(5) 0.0907(19) Uani 0.654(9) 1 d D . P A 1
F6A F 0.9727(5) 0.4535(6) 0.7806(10) 0.091(3) Uani 0.346(9) 1 d D . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.6025(15) . ?
Dy1 O2 2.6001(15) . ?
Dy1 O3 2.1426(13) . ?
Dy1 O4 2.1555(14) . ?
Dy1 N1 2.5701(18) . ?
Dy1 N2 2.6220(17) . ?
Dy1 N3 2.6273(17) . ?
Dy1 N4 2.5841(17) . ?
Si1 O3 1.5951(14) . ?
Si1 C26 1.884(2) . ?
Si1 C32 1.885(2) . ?
Si1 C38 1.887(2) . ?
Si2 O4 1.5973(15) . ?
Si2 C44 1.885(2) . ?
Si2 C50 1.877(2) . ?
Si2 C56 1.886(2) . ?
O1 C16 1.427(3) . ?
O1 C17 1.427(3) . ?
O2 C18 1.435(3) . ?
O2 C19 1.430(3) . ?
N1 C1 1.268(3) . ?
N1 C20 1.462(3) . ?
N2 C2 1.333(3) . ?
N2 C6 1.340(3) . ?
N3 C10 1.357(3) . ?
N3 C13 1.333(3) . ?
N4 C14 1.264(3) . ?
N4 C15 1.454(3) . ?
C1 H1 0.9500 . ?
C1 C2 1.462(4) . ?
C2 C3 1.408(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.358(4) . ?
C4 H4 0.9500 . ?
C4 C5 1.400(4) . ?
C5 C6 1.416(3) . ?
C5 C7 1.427(4) . ?
C6 C10 1.437(3) . ?
C7 H7 0.9500 . ?
C7 C8 1.342(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.444(3) . ?
C9 C10 1.410(3) . ?
C9 C11 1.397(4) . ?
C11 H11 0.9500 . ?
C11 C12 1.370(4) . ?
C12 H12 0.9500 . ?
C12 C13 1.395(3) . ?
C13 C14 1.468(3) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.504(3) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C18 1.483(4) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.508(4) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 H21 0.9500 . ?
C21 C22 1.393(4) . ?
C21 C26 1.390(4) . ?
C22 H22 0.9500 . ?
C22 C23 1.371(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.377(5) . ?
C24 H24 0.9500 . ?
C24 C25 1.393(4) . ?
C25 H25 0.9500 . ?
C25 C26 1.396(3) . ?
C27 H27 0.9500 . ?
C27 C28 1.390(3) . ?
C27 C32 1.381(3) . ?
C28 H28 0.9500 . ?
C28 C29 1.381(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.372(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.390(3) . ?
C31 H31 0.9500 . ?
C31 C32 1.406(3) . ?
C33 H33 0.9500 . ?
C33 C34 1.396(4) . ?
C33 C38 1.396(3) . ?
C34 H34 0.9500 . ?
C34 C35 1.369(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.375(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.390(4) . ?
C37 H37 0.9500 . ?
C37 C38 1.391(3) . ?
C39 H39 0.9500 . ?
C39 C40 1.391(4) . ?
C39 C44 1.402(4) . ?
C40 H40 0.9500 . ?
C40 C41 1.363(6) . ?
C41 H41 0.9500 . ?
C41 C42 1.379(7) . ?
C42 H42 0.9500 . ?
C42 C43 1.414(5) . ?
C43 H43 0.9500 . ?
C43 C44 1.390(4) . ?
C45 H45 0.9500 . ?
C45 C46 1.386(4) . ?
C45 C50 1.403(3) . ?
C46 H46 0.9500 . ?
C46 C47 1.385(4) . ?
C47 H47 0.9500 . ?
C47 C48 1.374(4) . ?
C48 H48 0.9500 . ?
C48 C49 1.390(3) . ?
C49 H49 0.9500 . ?
C49 C50 1.399(3) . ?
C51 H51 0.9500 . ?
C51 C52 1.392(3) . ?
C51 C56 1.397(3) . ?
C52 H52 0.9500 . ?
C52 C53 1.380(4) . ?
C53 H53 0.9500 . ?
C53 C54 1.378(4) . ?
C54 H54 0.9500 . ?
C54 C55 1.389(3) . ?
C55 H55 0.9500 . ?
C55 C56 1.397(3) . ?
P1 F1 1.608(3) . ?
P1 F1A 1.486(6) . ?
P1 F2 1.576(4) . ?
P1 F2A 1.613(7) . ?
P1 F3 1.559(7) . ?
P1 F3A 1.569(9) . ?
P1 F4 1.591(4) . ?
P1 F4A 1.595(9) . ?
P1 F5 1.633(3) . ?
P1 F5A 1.531(7) . ?
P1 F6 1.543(3) . ?
P1 F6A 1.665(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 N2 169.28(5) . . ?
O1 Dy1 N3 117.73(5) . . ?
O2 Dy1 O1 59.25(5) . . ?
O2 Dy1 N2 119.06(5) . . ?
O2 Dy1 N3 166.67(5) . . ?
O3 Dy1 O1 85.54(5) . . ?
O3 Dy1 O2 83.37(5) . . ?
O3 Dy1 O4 174.42(5) . . ?
O3 Dy1 N1 96.41(6) . . ?
O3 Dy1 N2 83.74(5) . . ?
O3 Dy1 N3 83.43(5) . . ?
O3 Dy1 N4 99.22(5) . . ?
O4 Dy1 O1 89.99(6) . . ?
O4 Dy1 O2 91.47(6) . . ?
O4 Dy1 N1 82.88(6) . . ?
O4 Dy1 N2 100.71(6) . . ?
O4 Dy1 N3 101.64(5) . . ?
O4 Dy1 N4 81.45(6) . . ?
N1 Dy1 O1 119.53(6) . . ?
N1 Dy1 O2 61.01(6) . . ?
N1 Dy1 N2 61.76(6) . . ?
N1 Dy1 N3 122.55(6) . . ?
N1 Dy1 N4 164.33(6) . . ?
N2 Dy1 N3 61.14(5) . . ?
N4 Dy1 O1 60.92(5) . . ?
N4 Dy1 O2 119.68(5) . . ?
N4 Dy1 N2 121.13(5) . . ?
N4 Dy1 N3 60.91(5) . . ?
O3 Si1 C26 109.85(9) . . ?
O3 Si1 C32 109.15(9) . . ?
O3 Si1 C38 110.02(9) . . ?
C26 Si1 C32 109.98(9) . . ?
C26 Si1 C38 107.96(10) . . ?
C32 Si1 C38 109.86(9) . . ?
O4 Si2 C44 109.89(9) . . ?
O4 Si2 C50 110.87(9) . . ?
O4 Si2 C56 109.86(9) . . ?
C44 Si2 C56 109.97(10) . . ?
C50 Si2 C44 109.17(11) . . ?
C50 Si2 C56 107.04(9) . . ?
C16 O1 Dy1 122.54(12) . . ?
C16 O1 C17 112.30(18) . . ?
C17 O1 Dy1 112.82(12) . . ?
C18 O2 Dy1 123.03(14) . . ?
C19 O2 Dy1 124.54(15) . . ?
C19 O2 C18 112.30(19) . . ?
Si1 O3 Dy1 163.32(9) . . ?
Si2 O4 Dy1 149.56(10) . . ?
C1 N1 Dy1 122.55(16) . . ?
C1 N1 C20 118.8(2) . . ?
C20 N1 Dy1 118.54(15) . . ?
C2 N2 Dy1 120.17(15) . . ?
C2 N2 C6 117.38(19) . . ?
C6 N2 Dy1 121.93(14) . . ?
C10 N3 Dy1 121.12(13) . . ?
C13 N3 Dy1 120.79(13) . . ?
C13 N3 C10 117.49(18) . . ?
C14 N4 Dy1 123.26(13) . . ?
C14 N4 C15 118.20(18) . . ?
C15 N4 Dy1 118.02(13) . . ?
N1 C1 H1 120.2 . . ?
N1 C1 C2 119.5(2) . . ?
C2 C1 H1 120.2 . . ?
N2 C2 C1 115.5(2) . . ?
N2 C2 C3 123.0(2) . . ?
C3 C2 C1 121.5(2) . . ?
C2 C3 H3 120.3 . . ?
C4 C3 C2 119.4(2) . . ?
C4 C3 H3 120.3 . . ?
C3 C4 H4 120.4 . . ?
C3 C4 C5 119.2(2) . . ?
C5 C4 H4 120.4 . . ?
C4 C5 C6 117.4(2) . . ?
C4 C5 C7 123.4(2) . . ?
C6 C5 C7 119.2(2) . . ?
N2 C6 C5 123.5(2) . . ?
N2 C6 C10 117.27(18) . . ?
C5 C6 C10 119.2(2) . . ?
C5 C7 H7 119.1 . . ?
C8 C7 C5 121.7(2) . . ?
C8 C7 H7 119.1 . . ?
C7 C8 H8 119.4 . . ?
C7 C8 C9 121.1(2) . . ?
C9 C8 H8 119.4 . . ?
C10 C9 C8 118.5(2) . . ?
C11 C9 C8 123.5(2) . . ?
C11 C9 C10 117.9(2) . . ?
N3 C10 C6 117.11(19) . . ?
N3 C10 C9 122.7(2) . . ?
C9 C10 C6 120.22(19) . . ?
C9 C11 H11 120.3 . . ?
C12 C11 C9 119.3(2) . . ?
C12 C11 H11 120.3 . . ?
C11 C12 H12 120.4 . . ?
C11 C12 C13 119.1(2) . . ?
C13 C12 H12 120.4 . . ?
N3 C13 C12 123.5(2) . . ?
N3 C13 C14 115.17(18) . . ?
C12 C13 C14 121.4(2) . . ?
N4 C14 C13 118.57(19) . . ?
N4 C14 H14 120.7 . . ?
C13 C14 H14 120.7 . . ?
N4 C15 H15A 110.4 . . ?
N4 C15 H15B 110.4 . . ?
N4 C15 C16 106.86(17) . . ?
H15A C15 H15B 108.6 . . ?
C16 C15 H15A 110.4 . . ?
C16 C15 H15B 110.4 . . ?
O1 C16 C15 106.20(18) . . ?
O1 C16 H16A 110.5 . . ?
O1 C16 H16B 110.5 . . ?
C15 C16 H16A 110.5 . . ?
C15 C16 H16B 110.5 . . ?
H16A C16 H16B 108.7 . . ?
O1 C17 H17A 110.4 . . ?
O1 C17 H17B 110.4 . . ?
O1 C17 C18 106.7(2) . . ?
H17A C17 H17B 108.6 . . ?
C18 C17 H17A 110.4 . . ?
C18 C17 H17B 110.4 . . ?
O2 C18 C17 108.13(18) . . ?
O2 C18 H18A 110.1 . . ?
O2 C18 H18B 110.1 . . ?
C17 C18 H18A 110.1 . . ?
C17 C18 H18B 110.1 . . ?
H18A C18 H18B 108.4 . . ?
O2 C19 H19A 110.1 . . ?
O2 C19 H19B 110.1 . . ?
O2 C19 C20 107.81(19) . . ?
H19A C19 H19B 108.5 . . ?
C20 C19 H19A 110.1 . . ?
C20 C19 H19B 110.1 . . ?
N1 C20 C19 108.8(2) . . ?
N1 C20 H20A 109.9 . . ?
N1 C20 H20B 109.9 . . ?
C19 C20 H20A 109.9 . . ?
C19 C20 H20B 109.9 . . ?
H20A C20 H20B 108.3 . . ?
C22 C21 H21 119.1 . . ?
C26 C21 H21 119.1 . . ?
C26 C21 C22 121.8(3) . . ?
C21 C22 H22 120.2 . . ?
C23 C22 C21 119.7(3) . . ?
C23 C22 H22 120.2 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.1(3) . . ?
C24 C23 H23 120.0 . . ?
C23 C24 H24 119.9 . . ?
C23 C24 C25 120.1(3) . . ?
C25 C24 H24 119.9 . . ?
C24 C25 H25 119.5 . . ?
C24 C25 C26 121.1(3) . . ?
C26 C25 H25 119.5 . . ?
C21 C26 Si1 120.06(17) . . ?
C21 C26 C25 117.3(2) . . ?
C25 C26 Si1 122.66(19) . . ?
C28 C27 H27 119.2 . . ?
C32 C27 H27 119.2 . . ?
C32 C27 C28 121.7(2) . . ?
C27 C28 H28 120.0 . . ?
C29 C28 C27 120.0(3) . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 120.1 . . ?
C30 C29 C28 119.8(2) . . ?
C30 C29 H29 120.1 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.1(2) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 119.4 . . ?
C30 C31 C32 121.1(2) . . ?
C32 C31 H31 119.4 . . ?
C27 C32 Si1 119.13(15) . . ?
C27 C32 C31 117.31(19) . . ?
C31 C32 Si1 123.56(17) . . ?
C34 C33 H33 119.4 . . ?
C34 C33 C38 121.2(3) . . ?
C38 C33 H33 119.4 . . ?
C33 C34 H34 119.9 . . ?
C35 C34 C33 120.1(3) . . ?
C35 C34 H34 119.9 . . ?
C34 C35 H35 120.0 . . ?
C34 C35 C36 120.0(3) . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 120.0 . . ?
C35 C36 C37 119.9(3) . . ?
C37 C36 H36 120.0 . . ?
C36 C37 H37 119.1 . . ?
C36 C37 C38 121.7(3) . . ?
C38 C37 H37 119.1 . . ?
C33 C38 Si1 123.80(18) . . ?
C37 C38 Si1 118.50(17) . . ?
C37 C38 C33 117.0(2) . . ?
C40 C39 H39 119.0 . . ?
C40 C39 C44 122.0(3) . . ?
C44 C39 H39 119.0 . . ?
C39 C40 H40 120.3 . . ?
C41 C40 C39 119.3(4) . . ?
C41 C40 H40 120.3 . . ?
C40 C41 H41 119.6 . . ?
C40 C41 C42 120.7(3) . . ?
C42 C41 H41 119.6 . . ?
C41 C42 H42 119.9 . . ?
C41 C42 C43 120.2(3) . . ?
C43 C42 H42 119.9 . . ?
C42 C43 H43 120.0 . . ?
C44 C43 C42 120.0(4) . . ?
C44 C43 H43 120.0 . . ?
C39 C44 Si2 122.24(19) . . ?
C43 C44 Si2 119.5(2) . . ?
C43 C44 C39 117.7(3) . . ?
C46 C45 H45 119.0 . . ?
C46 C45 C50 121.9(2) . . ?
C50 C45 H45 119.0 . . ?
C45 C46 H46 120.3 . . ?
C47 C46 C45 119.4(2) . . ?
C47 C46 H46 120.3 . . ?
C46 C47 H47 119.9 . . ?
C48 C47 C46 120.2(2) . . ?
C48 C47 H47 119.9 . . ?
C47 C48 H48 119.9 . . ?
C47 C48 C49 120.2(2) . . ?
C49 C48 H48 119.9 . . ?
C48 C49 H49 119.3 . . ?
C48 C49 C50 121.3(2) . . ?
C50 C49 H49 119.3 . . ?
C45 C50 Si2 119.62(16) . . ?
C49 C50 Si2 123.47(16) . . ?
C49 C50 C45 116.9(2) . . ?
C52 C51 H51 119.0 . . ?
C52 C51 C56 122.0(2) . . ?
C56 C51 H51 119.0 . . ?
C51 C52 H52 120.1 . . ?
C53 C52 C51 119.8(2) . . ?
C53 C52 H52 120.1 . . ?
C52 C53 H53 120.3 . . ?
C54 C53 C52 119.5(2) . . ?
C54 C53 H53 120.3 . . ?
C53 C54 H54 119.7 . . ?
C53 C54 C55 120.5(2) . . ?
C55 C54 H54 119.7 . . ?
C54 C55 H55 119.3 . . ?
C54 C55 C56 121.5(2) . . ?
C56 C55 H55 119.3 . . ?
C51 C56 Si2 120.89(16) . . ?
C55 C56 Si2 122.42(17) . . ?
C55 C56 C51 116.7(2) . . ?
F1 P1 F5 86.6(2) . . ?
F1A P1 F2A 89.8(6) . . ?
F1A P1 F3A 96.9(8) . . ?
F1A P1 F4A 98.8(7) . . ?
F1A P1 F5A 92.9(6) . . ?
F1A P1 F6A 176.8(4) . . ?
F2 P1 F1 90.08(18) . . ?
F2 P1 F4 173.6(3) . . ?
F2 P1 F5 88.8(3) . . ?
F2A P1 F6A 87.3(5) . . ?
F3 P1 F1 89.4(4) . . ?
F3 P1 F2 89.9(5) . . ?
F3 P1 F4 96.1(5) . . ?
F3 P1 F5 175.8(4) . . ?
F3A P1 F2A 86.2(8) . . ?
F3A P1 F4A 87.0(8) . . ?
F3A P1 F6A 81.8(6) . . ?
F4 P1 F1 87.6(2) . . ?
F4 P1 F5 85.1(3) . . ?
F4A P1 F2A 169.6(7) . . ?
F4A P1 F6A 84.0(7) . . ?
F5A P1 F2A 91.7(6) . . ?
F5A P1 F3A 170.0(7) . . ?
F5A P1 F4A 93.7(6) . . ?
F5A P1 F6A 88.4(5) . . ?
F6 P1 F1 175.7(3) . . ?
F6 P1 F2 89.74(19) . . ?
F6 P1 F3 94.8(4) . . ?
F6 P1 F4 92.2(3) . . ?
F6 P1 F5 89.1(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C16 C15 -36.1(2) . . . . ?
Dy1 O1 C17 C18 63.2(2) . . . . ?
Dy1 O2 C18 C17 10.9(3) . . . . ?
Dy1 O2 C19 C20 23.4(3) . . . . ?
Dy1 N1 C1 C2 -1.8(3) . . . . ?
Dy1 N1 C20 C19 49.4(2) . . . . ?
Dy1 N2 C2 C1 -8.3(2) . . . . ?
Dy1 N2 C2 C3 171.31(18) . . . . ?
Dy1 N2 C6 C5 -170.97(15) . . . . ?
Dy1 N2 C6 C10 8.8(2) . . . . ?
Dy1 N3 C10 C6 -10.4(2) . . . . ?
Dy1 N3 C10 C9 170.47(15) . . . . ?
Dy1 N3 C13 C12 -170.87(17) . . . . ?
Dy1 N3 C13 C14 10.1(2) . . . . ?
Dy1 N4 C14 C13 -8.2(3) . . . . ?
Dy1 N4 C15 C16 -51.3(2) . . . . ?
O1 C17 C18 O2 -46.0(2) . . . . ?
O2 C19 C20 N1 -43.7(3) . . . . ?
O3 Si1 C26 C21 23.7(2) . . . . ?
O3 Si1 C26 C25 -155.80(18) . . . . ?
O3 Si1 C32 C27 -14.3(2) . . . . ?
O3 Si1 C32 C31 166.36(17) . . . . ?
O3 Si1 C38 C33 -96.1(2) . . . . ?
O3 Si1 C38 C37 74.22(19) . . . . ?
O4 Si2 C44 C39 -99.0(2) . . . . ?
O4 Si2 C44 C43 72.5(2) . . . . ?
O4 Si2 C50 C45 -21.01(19) . . . . ?
O4 Si2 C50 C49 160.54(16) . . . . ?
O4 Si2 C56 C51 -37.6(2) . . . . ?
O4 Si2 C56 C55 141.47(19) . . . . ?
N1 C1 C2 N2 6.7(3) . . . . ?
N1 C1 C2 C3 -172.9(2) . . . . ?
N2 C2 C3 C4 0.3(4) . . . . ?
N2 C6 C10 N3 1.1(3) . . . . ?
N2 C6 C10 C9 -179.78(18) . . . . ?
N3 C13 C14 N4 -1.5(3) . . . . ?
N4 C15 C16 O1 52.9(2) . . . . ?
C1 N1 C20 C19 -133.7(2) . . . . ?
C1 C2 C3 C4 180.0(2) . . . . ?
C2 N2 C6 C5 0.8(3) . . . . ?
C2 N2 C6 C10 -179.41(18) . . . . ?
C2 C3 C4 C5 -0.2(4) . . . . ?
C3 C4 C5 C6 0.4(4) . . . . ?
C3 C4 C5 C7 179.8(3) . . . . ?
C4 C5 C6 N2 -0.7(3) . . . . ?
C4 C5 C6 C10 179.5(2) . . . . ?
C4 C5 C7 C8 -179.3(3) . . . . ?
C5 C6 C10 N3 -179.09(18) . . . . ?
C5 C6 C10 C9 0.0(3) . . . . ?
C5 C7 C8 C9 -0.4(4) . . . . ?
C6 N2 C2 C1 179.74(18) . . . . ?
C6 N2 C2 C3 -0.6(3) . . . . ?
C6 C5 C7 C8 0.1(4) . . . . ?
C7 C5 C6 N2 179.8(2) . . . . ?
C7 C5 C6 C10 0.1(3) . . . . ?
C7 C8 C9 C10 0.5(4) . . . . ?
C7 C8 C9 C11 179.1(3) . . . . ?
C8 C9 C10 N3 178.8(2) . . . . ?
C8 C9 C10 C6 -0.3(3) . . . . ?
C8 C9 C11 C12 -177.7(2) . . . . ?
C9 C11 C12 C13 -1.4(4) . . . . ?
C10 N3 C13 C12 0.3(3) . . . . ?
C10 N3 C13 C14 -178.69(17) . . . . ?
C10 C9 C11 C12 1.0(4) . . . . ?
C11 C9 C10 N3 0.0(3) . . . . ?
C11 C9 C10 C6 -179.0(2) . . . . ?
C11 C12 C13 N3 0.7(4) . . . . ?
C11 C12 C13 C14 179.7(2) . . . . ?
C12 C13 C14 N4 179.4(2) . . . . ?
C13 N3 C10 C6 178.38(17) . . . . ?
C13 N3 C10 C9 -0.7(3) . . . . ?
C14 N4 C15 C16 120.6(2) . . . . ?
C15 N4 C14 C13 -179.66(18) . . . . ?
C16 O1 C17 C18 -153.40(19) . . . . ?
C17 O1 C16 C15 -175.50(18) . . . . ?
C18 O2 C19 C20 -160.8(2) . . . . ?
C19 O2 C18 C17 -165.0(2) . . . . ?
C20 N1 C1 C2 -178.5(2) . . . . ?
C21 C22 C23 C24 -1.1(5) . . . . ?
C22 C21 C26 Si1 -178.8(2) . . . . ?
C22 C21 C26 C25 0.7(4) . . . . ?
C22 C23 C24 C25 0.6(4) . . . . ?
C23 C24 C25 C26 0.6(4) . . . . ?
C24 C25 C26 Si1 178.29(19) . . . . ?
C24 C25 C26 C21 -1.2(4) . . . . ?
C26 Si1 O3 Dy1 111.8(3) . . . . ?
C26 Si1 C32 C27 106.25(19) . . . . ?
C26 Si1 C32 C31 -73.1(2) . . . . ?
C26 Si1 C38 C33 144.02(19) . . . . ?
C26 Si1 C38 C37 -45.64(19) . . . . ?
C26 C21 C22 C23 0.4(5) . . . . ?
C27 C28 C29 C30 0.2(4) . . . . ?
C28 C27 C32 Si1 179.9(2) . . . . ?
C28 C27 C32 C31 -0.8(4) . . . . ?
C28 C29 C30 C31 -0.9(4) . . . . ?
C29 C30 C31 C32 0.7(4) . . . . ?
C30 C31 C32 Si1 179.42(18) . . . . ?
C30 C31 C32 C27 0.1(3) . . . . ?
C32 Si1 O3 Dy1 -127.6(3) . . . . ?
C32 Si1 C26 C21 -96.5(2) . . . . ?
C32 Si1 C26 C25 84.0(2) . . . . ?
C32 Si1 C38 C33 24.1(2) . . . . ?
C32 Si1 C38 C37 -165.58(17) . . . . ?
C32 C27 C28 C29 0.6(4) . . . . ?
C33 C34 C35 C36 0.3(5) . . . . ?
C34 C33 C38 Si1 169.5(2) . . . . ?
C34 C33 C38 C37 -1.0(4) . . . . ?
C34 C35 C36 C37 -0.3(4) . . . . ?
C35 C36 C37 C38 -0.4(4) . . . . ?
C36 C37 C38 Si1 -170.0(2) . . . . ?
C36 C37 C38 C33 1.0(4) . . . . ?
C38 Si1 O3 Dy1 -7.0(3) . . . . ?
C38 Si1 C26 C21 143.68(19) . . . . ?
C38 Si1 C26 C25 -35.8(2) . . . . ?
C38 Si1 C32 C27 -135.05(18) . . . . ?
C38 Si1 C32 C31 45.6(2) . . . . ?
C38 C33 C34 C35 0.4(4) . . . . ?
C39 C40 C41 C42 -0.1(5) . . . . ?
C40 C39 C44 Si2 172.9(2) . . . . ?
C40 C39 C44 C43 1.2(4) . . . . ?
C40 C41 C42 C43 1.6(6) . . . . ?
C41 C42 C43 C44 -1.7(5) . . . . ?
C42 C43 C44 Si2 -171.6(2) . . . . ?
C42 C43 C44 C39 0.3(4) . . . . ?
C44 Si2 O4 Dy1 12.6(2) . . . . ?
C44 Si2 C50 C45 -142.21(16) . . . . ?
C44 Si2 C50 C49 39.3(2) . . . . ?
C44 Si2 C56 C51 83.48(19) . . . . ?
C44 Si2 C56 C55 -97.5(2) . . . . ?
C44 C39 C40 C41 -1.4(5) . . . . ?
C45 C46 C47 C48 -0.8(4) . . . . ?
C46 C45 C50 Si2 -177.87(18) . . . . ?
C46 C45 C50 C49 0.7(3) . . . . ?
C46 C47 C48 C49 1.8(4) . . . . ?
C47 C48 C49 C50 -1.6(3) . . . . ?
C48 C49 C50 Si2 178.83(17) . . . . ?
C48 C49 C50 C45 0.3(3) . . . . ?
C50 Si2 O4 Dy1 -108.17(19) . . . . ?
C50 Si2 C44 C39 22.8(2) . . . . ?
C50 Si2 C44 C43 -165.7(2) . . . . ?
C50 Si2 C56 C51 -158.04(17) . . . . ?
C50 Si2 C56 C55 21.0(2) . . . . ?
C50 C45 C46 C47 -0.5(4) . . . . ?
C51 C52 C53 C54 0.0(4) . . . . ?
C52 C51 C56 Si2 179.75(17) . . . . ?
C52 C51 C56 C55 0.6(3) . . . . ?
C52 C53 C54 C55 0.1(4) . . . . ?
C53 C54 C55 C56 0.2(4) . . . . ?
C54 C55 C56 Si2 -179.6(2) . . . . ?
C54 C55 C56 C51 -0.5(4) . . . . ?
C56 Si2 O4 Dy1 133.72(18) . . . . ?
C56 Si2 C44 C39 139.94(19) . . . . ?
C56 Si2 C44 C43 -48.6(2) . . . . ?
C56 Si2 C50 C45 98.80(17) . . . . ?
C56 Si2 C50 C49 -79.65(19) . . . . ?
C56 C51 C52 C53 -0.4(3) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.786
_oxdiff_exptl_absorpt_empirical_full_min 0.612
