# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_0102_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2413055'
_audit_update_record             
;
2024-12-27 deposited with the CCDC.	2025-02-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'B3 Ca0 Eu2 Mg0 Na2 O9 P0 Rb'
_chemical_formula_weight         611.80

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           38
_space_group_name_H-M_alt        'A m m 2'
_space_group_name_Hall           'A 2 -2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x, -y, z'
'-x, y, z'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x, -y+1/2, z+1/2'
'-x, y+1/2, z+1/2'

_cell_length_a                   5.1228(2)
_cell_length_b                   11.1226(7)
_cell_length_c                   7.0441(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     401.36(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    1475
_cell_measurement_theta_min      3.42
_cell_measurement_theta_max      32.48

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    5.062
_exptl_crystal_F_000             544
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    21.648
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            1578
_diffrn_reflns_av_unetI/netI     0.0370
_diffrn_reflns_av_R_equivalents  0.0371
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       4
_diffrn_reflns_theta_min         3.423
_diffrn_reflns_theta_max         32.479
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.885
_diffrn_measured_fraction_theta_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.885
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.609
_diffrn_reflns_point_group_measured_fraction_full 0.748
_reflns_number_total             506
_reflns_number_gt                502
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.284
_reflns_Friedel_fraction_max     0.290
_reflns_Friedel_fraction_full    0.461

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0370P)²+23.2827P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.020(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.30(8)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         506
_refine_ls_number_parameters     45
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0348
_refine_ls_R_factor_gt           0.0346
_refine_ls_wR_factor_ref         0.0885
_refine_ls_wR_factor_gt          0.0884
_refine_ls_goodness_of_fit_ref   1.149
_refine_ls_restrained_S_all      1.142
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.500000 0.28661(6) 0.77467(17) 0.0068(3) Uani 1 2 d S T P . .
Na1 Na 0.000000 0.500000 0.8714(16) 0.0051(12) Uani 1 4 d S T P . .
Rb2 Rb 1.000000 0.500000 0.3821(6) 0.0252(8) Uani 1 4 d S T P . .
Na2 Na 0.500000 0.500000 0.1334(17) 0.0051(12) Uani 1 4 d S T P . .
O1 O -0.2372(17) 0.1596(9) 0.5642(15) 0.0078(17) Uani 1 1 d . . . . .
O2 O 0.500000 0.500000 0.748(4) 0.017(5) Uani 1 4 d S TU P . .
O3 O 0.500000 0.3923(12) 0.463(2) 0.0051(12) Uani 1 2 d S T P . .
O4 O 0.000000 0.3236(17) 0.695(3) 0.020(3) Uani 1 2 d S T P . .
B2 B 0.000000 0.2162(17) 0.600(3) 0.0051(12) Uani 1 2 d S T P . .
B1 B 0.500000 0.500000 0.549(5) 0.013(6) Uani 1 4 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.381(2) . ?
Eu1 O3 2.394(14) 6_655 ?
Eu1 O1 2.450(10) 4 ?
Eu1 O1 2.450(10) 1_655 ?
Eu1 O3 2.488(15) . ?
Eu1 O1 2.516(10) 7_655 ?
Eu1 O1 2.516(10) 6 ?
Eu1 O4 2.655(5) 1_655 ?
Eu1 O4 2.655(5) . ?
Eu1 B1 2.86(2) . ?
Eu1 B2 2.947(11) 1_655 ?
Eu1 B2 2.947(11) . ?
Na1 O4 2.323(19) . ?
Na1 O4 2.323(19) 2_565 ?
Na1 O1 2.544(12) 8 ?
Na1 O1 2.544(12) 5 ?
Na1 O1 2.544(12) 7 ?
Na1 O1 2.544(12) 6 ?
Na1 O2 2.706(10) . ?
Na1 O2 2.706(10) 1_455 ?
Na1 B2 2.89(2) 5 ?
Na1 B2 2.89(2) 6 ?
Na1 Na2 3.157(10) 1_556 ?
Na1 Na2 3.157(10) 1_456 ?
Rb2 B1 2.817(16) . ?
Rb2 B1 2.817(16) 1_655 ?
Rb2 O3 2.885(6) . ?
Rb2 O3 2.885(6) 2_765 ?
Rb2 O3 2.885(6) 1_655 ?
Rb2 O3 2.885(6) 2_665 ?
Rb2 O4 2.95(2) 2_665 ?
Rb2 O4 2.95(2) 1_655 ?
Rb2 Na2 3.103(7) 1_655 ?
Rb2 Na2 3.103(7) . ?
Rb2 O1 3.106(11) 7_654 ?
Rb2 O1 3.106(11) 6_654 ?
Na2 O1 2.281(10) 6_554 ?
Na2 O1 2.281(10) 5_654 ?
Na2 O1 2.281(10) 7_654 ?
Na2 O1 2.281(10) 8_554 ?
Na2 O3 2.615(19) . ?
Na2 O3 2.615(19) 2_665 ?
Na2 O2 2.72(3) 1_554 ?
Na2 B1 2.92(4) . ?
O1 B2 1.392(13) . ?
O2 B1 1.40(4) . ?
O3 B1 1.34(2) . ?
O4 B2 1.37(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O3 150.8(8) . 6_655 ?
O2 Eu1 O1 121.7(6) . 4 ?
O3 Eu1 O1 81.8(4) 6_655 4 ?
O2 Eu1 O1 121.7(6) . 1_655 ?
O3 Eu1 O1 81.8(4) 6_655 1_655 ?
O1 Eu1 O1 66.6(4) 4 1_655 ?
O2 Eu1 O3 57.2(7) . . ?
O3 Eu1 O3 152.0(5) 6_655 . ?
O1 Eu1 O3 74.9(4) 4 . ?
O1 Eu1 O3 74.9(4) 1_655 . ?
O2 Eu1 O1 80.1(6) . 7_655 ?
O3 Eu1 O1 75.4(4) 6_655 7_655 ?
O1 Eu1 O1 157.1(3) 4 7_655 ?
O1 Eu1 O1 109.5(3) 1_655 7_655 ?
O3 Eu1 O1 127.0(3) . 7_655 ?
O2 Eu1 O1 80.1(6) . 6 ?
O3 Eu1 O1 75.4(4) 6_655 6 ?
O1 Eu1 O1 109.5(3) 4 6 ?
O1 Eu1 O1 157.1(3) 1_655 6 ?
O3 Eu1 O1 127.0(3) . 6 ?
O1 Eu1 O1 64.7(4) 7_655 6 ?
O2 Eu1 O4 80.1(4) . 1_655 ?
O3 Eu1 O4 104.3(4) 6_655 1_655 ?
O1 Eu1 O4 119.4(4) 4 1_655 ?
O1 Eu1 O4 55.3(4) 1_655 1_655 ?
O3 Eu1 O4 74.9(4) . 1_655 ?
O1 Eu1 O4 67.6(4) 7_655 1_655 ?
O1 Eu1 O4 130.6(4) 6 1_655 ?
O2 Eu1 O4 80.1(4) . . ?
O3 Eu1 O4 104.3(4) 6_655 . ?
O1 Eu1 O4 55.3(4) 4 . ?
O1 Eu1 O4 119.4(4) 1_655 . ?
O3 Eu1 O4 74.9(4) . . ?
O1 Eu1 O4 130.6(4) 7_655 . ?
O1 Eu1 O4 67.6(4) 6 . ?
O4 Eu1 O4 149.6(8) 1_655 . ?
O2 Eu1 B1 29.3(8) . . ?
O3 Eu1 B1 179.9(7) 6_655 . ?
O1 Eu1 B1 98.1(6) 4 . ?
O1 Eu1 B1 98.1(6) 1_655 . ?
O3 Eu1 B1 27.9(7) . . ?
O1 Eu1 B1 104.7(6) 7_655 . ?
O1 Eu1 B1 104.7(6) 6 . ?
O4 Eu1 B1 75.7(4) 1_655 . ?
O4 Eu1 B1 75.7(4) . . ?
O2 Eu1 B2 103.4(5) . 1_655 ?
O3 Eu1 B2 90.6(4) 6_655 1_655 ?
O1 Eu1 B2 94.1(4) 4 1_655 ?
O1 Eu1 B2 28.0(4) 1_655 1_655 ?
O3 Eu1 B2 76.0(4) . 1_655 ?
O1 Eu1 B2 86.3(4) 7_655 1_655 ?
O1 Eu1 B2 150.0(5) 6 1_655 ?
O4 Eu1 B2 27.6(5) 1_655 1_655 ?
O4 Eu1 B2 142.3(6) . 1_655 ?
B1 Eu1 B2 89.3(5) . 1_655 ?
O2 Eu1 B2 103.4(5) . . ?
O3 Eu1 B2 90.6(4) 6_655 . ?
O1 Eu1 B2 28.0(4) 4 . ?
O1 Eu1 B2 94.1(4) 1_655 . ?
O3 Eu1 B2 76.0(4) . . ?
O1 Eu1 B2 150.0(5) 7_655 . ?
O1 Eu1 B2 86.3(4) 6 . ?
O4 Eu1 B2 142.3(6) 1_655 . ?
O4 Eu1 B2 27.6(5) . . ?
B1 Eu1 B2 89.3(5) . . ?
B2 Eu1 B2 120.7(8) 1_655 . ?
O4 Na1 O4 115.2(11) . 2_565 ?
O4 Na1 O1 151.1(2) . 8 ?
O4 Na1 O1 72.3(5) 2_565 8 ?
O4 Na1 O1 151.1(2) . 5 ?
O4 Na1 O1 72.3(5) 2_565 5 ?
O1 Na1 O1 57.1(4) 8 5 ?
O4 Na1 O1 72.3(5) . 7 ?
O4 Na1 O1 151.1(2) 2_565 7 ?
O1 Na1 O1 115.5(6) 8 7 ?
O1 Na1 O1 88.5(5) 5 7 ?
O4 Na1 O1 72.3(5) . 6 ?
O4 Na1 O1 151.1(2) 2_565 6 ?
O1 Na1 O1 88.5(5) 8 6 ?
O1 Na1 O1 115.5(6) 5 6 ?
O1 Na1 O1 57.1(4) 7 6 ?
O4 Na1 O2 80.1(4) . . ?
O4 Na1 O2 80.1(4) 2_565 . ?
O1 Na1 O2 73.7(4) 8 . ?
O1 Na1 O2 128.6(4) 5 . ?
O1 Na1 O2 128.6(4) 7 . ?
O1 Na1 O2 73.7(4) 6 . ?
O4 Na1 O2 80.1(4) . 1_455 ?
O4 Na1 O2 80.1(4) 2_565 1_455 ?
O1 Na1 O2 128.6(4) 8 1_455 ?
O1 Na1 O2 73.7(4) 5 1_455 ?
O1 Na1 O2 73.7(4) 7 1_455 ?
O1 Na1 O2 128.6(4) 6 1_455 ?
O2 Na1 O2 142.4(13) . 1_455 ?
O4 Na1 B2 178.6(8) . 5 ?
O4 Na1 B2 66.2(7) 2_565 5 ?
O1 Na1 B2 28.7(2) 8 5 ?
O1 Na1 B2 28.7(2) 5 5 ?
O1 Na1 B2 106.4(6) 7 5 ?
O1 Na1 B2 106.4(6) 6 5 ?
O2 Na1 B2 100.3(3) . 5 ?
O2 Na1 B2 100.3(3) 1_455 5 ?
O4 Na1 B2 66.2(7) . 6 ?
O4 Na1 B2 178.6(8) 2_565 6 ?
O1 Na1 B2 106.4(6) 8 6 ?
O1 Na1 B2 106.4(6) 5 6 ?
O1 Na1 B2 28.7(2) 7 6 ?
O1 Na1 B2 28.7(2) 6 6 ?
O2 Na1 B2 100.3(3) . 6 ?
O2 Na1 B2 100.3(3) 1_455 6 ?
B2 Na1 B2 112.4(10) 5 6 ?
O4 Na1 Na2 108.2(3) . 1_556 ?
O4 Na1 Na2 108.2(3) 2_565 1_556 ?
O1 Na1 Na2 45.6(2) 8 1_556 ?
O1 Na1 Na2 94.3(4) 5 1_556 ?
O1 Na1 Na2 94.3(4) 7 1_556 ?
O1 Na1 Na2 45.6(2) 6 1_556 ?
O2 Na1 Na2 54.6(6) . 1_556 ?
O2 Na1 Na2 163.0(8) 1_455 1_556 ?
B2 Na1 Na2 71.0(3) 5 1_556 ?
B2 Na1 Na2 71.0(3) 6 1_556 ?
O4 Na1 Na2 108.2(3) . 1_456 ?
O4 Na1 Na2 108.2(3) 2_565 1_456 ?
O1 Na1 Na2 94.3(4) 8 1_456 ?
O1 Na1 Na2 45.6(2) 5 1_456 ?
O1 Na1 Na2 45.6(2) 7 1_456 ?
O1 Na1 Na2 94.3(4) 6 1_456 ?
O2 Na1 Na2 163.0(8) . 1_456 ?
O2 Na1 Na2 54.6(6) 1_455 1_456 ?
B2 Na1 Na2 71.0(3) 5 1_456 ?
B2 Na1 Na2 71.0(3) 6 1_456 ?
Na2 Na1 Na2 108.5(5) 1_556 1_456 ?
B1 Rb2 B1 130.8(14) . 1_655 ?
B1 Rb2 O3 27.1(4) . . ?
B1 Rb2 O3 136.4(6) 1_655 . ?
B1 Rb2 O3 136.4(6) . 2_765 ?
B1 Rb2 O3 27.1(4) 1_655 2_765 ?
O3 Rb2 O3 157.1(6) . 2_765 ?
B1 Rb2 O3 136.4(6) . 1_655 ?
B1 Rb2 O3 27.1(4) 1_655 1_655 ?
O3 Rb2 O3 125.2(5) . 1_655 ?
O3 Rb2 O3 49.0(5) 2_765 1_655 ?
B1 Rb2 O3 27.1(4) . 2_665 ?
B1 Rb2 O3 136.4(6) 1_655 2_665 ?
O3 Rb2 O3 49.0(5) . 2_665 ?
O3 Rb2 O3 125.2(5) 2_765 2_665 ?
O3 Rb2 O3 157.1(6) 1_655 2_665 ?
B1 Rb2 O4 71.9(5) . 2_665 ?
B1 Rb2 O4 71.9(5) 1_655 2_665 ?
O3 Rb2 O4 97.3(3) . 2_665 ?
O3 Rb2 O4 64.9(3) 2_765 2_665 ?
O3 Rb2 O4 97.3(3) 1_655 2_665 ?
O3 Rb2 O4 64.9(3) 2_665 2_665 ?
B1 Rb2 O4 71.9(5) . 1_655 ?
B1 Rb2 O4 71.9(5) 1_655 1_655 ?
O3 Rb2 O4 64.9(3) . 1_655 ?
O3 Rb2 O4 97.3(3) 2_765 1_655 ?
O3 Rb2 O4 64.9(3) 1_655 1_655 ?
O3 Rb2 O4 97.3(3) 2_665 1_655 ?
O4 Rb2 O4 83.4(7) 2_665 1_655 ?
B1 Rb2 Na2 170.2(7) . 1_655 ?
B1 Rb2 Na2 59.0(7) 1_655 1_655 ?
O3 Rb2 Na2 147.7(3) . 1_655 ?
O3 Rb2 Na2 51.6(3) 2_765 1_655 ?
O3 Rb2 Na2 51.6(3) 1_655 1_655 ?
O3 Rb2 Na2 147.7(3) 2_665 1_655 ?
O4 Rb2 Na2 114.93(19) 2_665 1_655 ?
O4 Rb2 Na2 114.93(19) 1_655 1_655 ?
B1 Rb2 Na2 59.0(7) . . ?
B1 Rb2 Na2 170.2(7) 1_655 . ?
O3 Rb2 Na2 51.6(3) . . ?
O3 Rb2 Na2 147.7(3) 2_765 . ?
O3 Rb2 Na2 147.7(3) 1_655 . ?
O3 Rb2 Na2 51.6(3) 2_665 . ?
O4 Rb2 Na2 114.93(19) 2_665 . ?
O4 Rb2 Na2 114.93(19) 1_655 . ?
Na2 Rb2 Na2 111.3(4) 1_655 . ?
B1 Rb2 O1 86.8(6) . 7_654 ?
B1 Rb2 O1 131.0(5) 1_655 7_654 ?
O3 Rb2 O1 63.8(3) . 7_654 ?
O3 Rb2 O1 136.7(3) 2_765 7_654 ?
O3 Rb2 O1 104.7(3) 1_655 7_654 ?
O3 Rb2 O1 91.9(3) 2_665 7_654 ?
O4 Rb2 O1 156.74(17) 2_665 7_654 ?
O4 Rb2 O1 99.1(4) 1_655 7_654 ?
Na2 Rb2 O1 85.2(3) 1_655 7_654 ?
Na2 Rb2 O1 43.1(2) . 7_654 ?
B1 Rb2 O1 131.0(5) . 6_654 ?
B1 Rb2 O1 86.8(6) 1_655 6_654 ?
O3 Rb2 O1 104.7(3) . 6_654 ?
O3 Rb2 O1 91.9(3) 2_765 6_654 ?
O3 Rb2 O1 63.8(3) 1_655 6_654 ?
O3 Rb2 O1 136.7(3) 2_665 6_654 ?
O4 Rb2 O1 156.74(18) 2_665 6_654 ?
O4 Rb2 O1 99.1(4) 1_655 6_654 ?
Na2 Rb2 O1 43.1(2) 1_655 6_654 ?
Na2 Rb2 O1 85.2(3) . 6_654 ?
O1 Rb2 O1 46.1(3) 7_654 6_654 ?
O1 Na2 O1 155.3(8) 6_554 5_654 ?
O1 Na2 O1 72.3(5) 6_554 7_654 ?
O1 Na2 O1 102.2(5) 5_654 7_654 ?
O1 Na2 O1 102.2(5) 6_554 8_554 ?
O1 Na2 O1 72.3(5) 5_654 8_554 ?
O1 Na2 O1 155.3(8) 7_654 8_554 ?
O1 Na2 O3 80.4(4) 6_554 . ?
O1 Na2 O3 123.1(5) 5_654 . ?
O1 Na2 O3 80.4(4) 7_654 . ?
O1 Na2 O3 123.1(5) 8_554 . ?
O1 Na2 O3 123.1(5) 6_554 2_665 ?
O1 Na2 O3 80.4(4) 5_654 2_665 ?
O1 Na2 O3 123.1(5) 7_654 2_665 ?
O1 Na2 O3 80.4(4) 8_554 2_665 ?
O3 Na2 O3 54.5(6) . 2_665 ?
O1 Na2 O2 77.7(4) 6_554 1_554 ?
O1 Na2 O2 77.7(4) 5_654 1_554 ?
O1 Na2 O2 77.7(4) 7_654 1_554 ?
O1 Na2 O2 77.7(4) 8_554 1_554 ?
O3 Na2 O2 152.7(3) . 1_554 ?
O3 Na2 O2 152.7(3) 2_665 1_554 ?
O1 Na2 B1 102.3(4) 6_554 . ?
O1 Na2 B1 102.3(4) 5_654 . ?
O1 Na2 B1 102.3(4) 7_654 . ?
O1 Na2 B1 102.3(4) 8_554 . ?
O3 Na2 B1 27.3(3) . . ?
O3 Na2 B1 27.3(3) 2_665 . ?
O2 Na2 B1 180.0 1_554 . ?
O1 Na2 Rb2 68.5(3) 6_554 1_455 ?
O1 Na2 Rb2 127.4(3) 5_654 1_455 ?
O1 Na2 Rb2 127.4(3) 7_654 1_455 ?
O1 Na2 Rb2 68.5(3) 8_554 1_455 ?
O3 Na2 Rb2 59.9(2) . 1_455 ?
O3 Na2 Rb2 59.9(2) 2_665 1_455 ?
O2 Na2 Rb2 124.4(2) 1_554 1_455 ?
B1 Na2 Rb2 55.6(2) . 1_455 ?
O1 Na2 Rb2 127.4(3) 6_554 . ?
O1 Na2 Rb2 68.5(3) 5_654 . ?
O1 Na2 Rb2 68.5(3) 7_654 . ?
O1 Na2 Rb2 127.4(3) 8_554 . ?
O3 Na2 Rb2 59.9(2) . . ?
O3 Na2 Rb2 59.9(2) 2_665 . ?
O2 Na2 Rb2 124.4(2) 1_554 . ?
B1 Na2 Rb2 55.6(2) . . ?
Rb2 Na2 Rb2 111.3(4) 1_455 . ?
O1 Na2 Na1 52.9(3) 6_554 1_554 ?
O1 Na2 Na1 110.7(4) 5_654 1_554 ?
O1 Na2 Na1 110.7(4) 7_654 1_554 ?
O1 Na2 Na1 52.9(3) 8_554 1_554 ?
O3 Na2 Na1 121.3(2) . 1_554 ?
O3 Na2 Na1 121.3(2) 2_665 1_554 ?
O2 Na2 Na1 54.2(2) 1_554 1_554 ?
B1 Na2 Na1 125.8(2) . 1_554 ?
Rb2 Na2 Na1 70.14(18) 1_455 1_554 ?
Rb2 Na2 Na1 178.6(4) . 1_554 ?
O1 Na2 Na1 110.7(4) 6_554 1_654 ?
O1 Na2 Na1 52.9(3) 5_654 1_654 ?
O1 Na2 Na1 52.9(3) 7_654 1_654 ?
O1 Na2 Na1 110.7(4) 8_554 1_654 ?
O3 Na2 Na1 121.3(2) . 1_654 ?
O3 Na2 Na1 121.3(2) 2_665 1_654 ?
O2 Na2 Na1 54.2(2) 1_554 1_654 ?
B1 Na2 Na1 125.8(2) . 1_654 ?
Rb2 Na2 Na1 178.6(4) 1_455 1_654 ?
Rb2 Na2 Na1 70.14(18) . 1_654 ?
Na1 Na2 Na1 108.5(5) 1_554 1_654 ?
B2 O1 Na2 145.9(10) . 5_445 ?
B2 O1 Eu1 96.3(9) . 1_455 ?
Na2 O1 Eu1 89.7(4) 5_445 1_455 ?
B2 O1 Eu1 120.5(10) . 6_554 ?
Na2 O1 Eu1 92.4(4) 5_445 6_554 ?
Eu1 O1 Eu1 93.4(3) 1_455 6_554 ?
B2 O1 Na1 89.7(9) . 5_544 ?
Na2 O1 Na1 81.5(4) 5_445 5_544 ?
Eu1 O1 Na1 170.9(5) 1_455 5_544 ?
Eu1 O1 Na1 89.4(4) 6_554 5_544 ?
B2 O1 Rb2 77.6(9) . 5_445 ?
Na2 O1 Rb2 68.4(3) 5_445 5_445 ?
Eu1 O1 Rb2 96.2(3) 1_455 5_445 ?
Eu1 O1 Rb2 158.4(4) 6_554 5_445 ?
Na1 O1 Rb2 78.4(3) 5_544 5_445 ?
B1 O2 Eu1 94.6(7) . 2_665 ?
B1 O2 Eu1 94.6(7) . . ?
Eu1 O2 Eu1 170.8(13) 2_665 . ?
B1 O2 Na1 108.8(6) . . ?
Eu1 O2 Na1 88.5(3) 2_665 . ?
Eu1 O2 Na1 88.5(3) . . ?
B1 O2 Na1 108.8(6) . 1_655 ?
Eu1 O2 Na1 88.5(3) 2_665 1_655 ?
Eu1 O2 Na1 88.5(3) . 1_655 ?
Na1 O2 Na1 142.4(13) . 1_655 ?
B1 O2 Na2 180.0 . 1_556 ?
Eu1 O2 Na2 85.4(7) 2_665 1_556 ?
Eu1 O2 Na2 85.4(7) . 1_556 ?
Na1 O2 Na2 71.2(6) . 1_556 ?
Na1 O2 Na2 71.2(6) 1_655 1_556 ?
B1 O2 Rb2 44.8(3) . . ?
Eu1 O2 Rb2 93.2(4) 2_665 . ?
Eu1 O2 Rb2 93.2(5) . . ?
Na1 O2 Rb2 153.6(9) . . ?
Na1 O2 Rb2 63.9(4) 1_655 . ?
Na2 O2 Rb2 135.2(3) 1_556 . ?
B1 O2 Rb2 44.8(3) . 1_455 ?
Eu1 O2 Rb2 93.2(4) 2_665 1_455 ?
Eu1 O2 Rb2 93.2(4) . 1_455 ?
Na1 O2 Rb2 63.9(4) . 1_455 ?
Na1 O2 Rb2 153.6(9) 1_655 1_455 ?
Na2 O2 Rb2 135.2(3) 1_556 1_455 ?
Rb2 O2 Rb2 89.7(6) . 1_455 ?
B1 O3 Eu1 172.9(17) . 6_654 ?
B1 O3 Eu1 91.6(15) . . ?
Eu1 O3 Eu1 95.5(5) 6_654 . ?
B1 O3 Na2 89.4(15) . . ?
Eu1 O3 Na2 83.5(5) 6_654 . ?
Eu1 O3 Na2 179.0(6) . . ?
B1 O3 Rb2 73.6(6) . . ?
Eu1 O3 Rb2 103.6(3) 6_654 . ?
Eu1 O3 Rb2 111.8(3) . . ?
Na2 O3 Rb2 68.5(3) . . ?
B1 O3 Rb2 73.6(6) . 1_455 ?
Eu1 O3 Rb2 103.6(3) 6_654 1_455 ?
Eu1 O3 Rb2 111.8(3) . 1_455 ?
Na2 O3 Rb2 68.5(3) . 1_455 ?
Rb2 O3 Rb2 125.2(5) . 1_455 ?
B2 O4 Na1 176.8(16) . . ?
B2 O4 Eu1 88.2(5) . 1_455 ?
Na1 O4 Eu1 91.0(4) . 1_455 ?
B2 O4 Eu1 88.2(5) . . ?
Na1 O4 Eu1 91.0(4) . . ?
Eu1 O4 Eu1 149.6(8) 1_455 . ?
B2 O4 Rb2 102.5(13) . 1_455 ?
Na1 O4 Rb2 80.7(6) . 1_455 ?
Eu1 O4 Rb2 105.2(4) 1_455 1_455 ?
Eu1 O4 Rb2 105.2(4) . 1_455 ?
O4 B2 O1 118.9(9) . 4 ?
O4 B2 O1 118.9(9) . . ?
O1 B2 O1 121.7(16) 4 . ?
O4 B2 Na1 175.4(16) . 5_544 ?
O1 B2 Na1 61.5(8) 4 5_544 ?
O1 B2 Na1 61.5(8) . 5_544 ?
O4 B2 Eu1 64.2(5) . . ?
O1 B2 Eu1 55.7(6) 4 . ?
O1 B2 Eu1 162.7(13) . . ?
Na1 B2 Eu1 116.9(4) 5_544 . ?
O4 B2 Eu1 64.2(5) . 1_455 ?
O1 B2 Eu1 162.7(13) 4 1_455 ?
O1 B2 Eu1 55.7(6) . 1_455 ?
Na1 B2 Eu1 116.9(4) 5_544 1_455 ?
Eu1 B2 Eu1 120.7(8) . 1_455 ?
O4 B2 Rb2 111.3(15) . 5_445 ?
O1 B2 Rb2 76.5(9) 4 5_445 ?
O1 B2 Rb2 76.5(9) . 5_445 ?
Na1 B2 Rb2 73.4(5) 5_544 5_445 ?
Eu1 B2 Rb2 86.5(5) . 5_445 ?
Eu1 B2 Rb2 86.5(5) 1_455 5_445 ?
O4 B2 Rb2 55.1(11) . 1_455 ?
O1 B2 Rb2 109.1(9) 4 1_455 ?
O1 B2 Rb2 109.1(9) . 1_455 ?
Na1 B2 Rb2 120.2(8) 5_544 1_455 ?
Eu1 B2 Rb2 86.8(4) . 1_455 ?
Eu1 B2 Rb2 86.8(4) 1_455 1_455 ?
Rb2 B2 Rb2 166.4(8) 5_445 1_455 ?
O3 B1 O3 127(3) . 2_665 ?
O3 B1 O2 116.6(15) . . ?
O3 B1 O2 116.6(15) 2_665 . ?
O3 B1 Rb2 79.2(8) . . ?
O3 B1 Rb2 79.2(8) 2_665 . ?
O2 B1 Rb2 114.6(7) . . ?
O3 B1 Rb2 79.2(8) . 1_455 ?
O3 B1 Rb2 79.2(8) 2_665 1_455 ?
O2 B1 Rb2 114.6(7) . 1_455 ?
Rb2 B1 Rb2 130.8(14) . 1_455 ?
O3 B1 Eu1 173(2) . 2_665 ?
O3 B1 Eu1 60.5(10) 2_665 2_665 ?
O2 B1 Eu1 56.1(6) . 2_665 ?
Rb2 B1 Eu1 103.41(15) . 2_665 ?
Rb2 B1 Eu1 103.41(15) 1_455 2_665 ?
O3 B1 Eu1 60.5(10) . . ?
O3 B1 Eu1 173(2) 2_665 . ?
O2 B1 Eu1 56.1(6) . . ?
Rb2 B1 Eu1 103.41(15) . . ?
Rb2 B1 Eu1 103.41(15) 1_455 . ?
Eu1 B1 Eu1 112.3(12) 2_665 . ?
O3 B1 Na2 63.4(15) . . ?
O3 B1 Na2 63.4(15) 2_665 . ?
O2 B1 Na2 180.0 . . ?
Rb2 B1 Na2 65.4(7) . . ?
Rb2 B1 Na2 65.4(7) 1_455 . ?
Eu1 B1 Na2 123.9(6) 2_665 . ?
Eu1 B1 Na2 123.9(6) . . ?

_refine_diff_density_max         6.049
_refine_diff_density_min         -3.811
_refine_diff_density_rms         0.496



