# Supplementary Information (SI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_si-1117
_database_code_depnum_ccdc_archive 'CCDC 2264465'
loop_
_audit_author_name
_audit_author_address
'Liao silane'
;Gannan Medical University
China
;
_audit_update_record             
;
2023-05-22 deposited with the CCDC.	2024-09-30 downloaded from the CCDC.
;
_audit_creation_date             2021-11-17
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C20 H23 N Si'
_chemical_formula_sum            'C20 H23 N Si'
_chemical_formula_weight         305.48
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.1994(8)
_cell_length_b                   12.6675(10)
_cell_length_c                   13.4020(11)
_cell_angle_alpha                90
_cell_angle_beta                 98.481(7)
_cell_angle_gamma                90
_cell_volume                     1712.6(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    3827
_cell_measurement_temperature    149.99(10)
_cell_measurement_theta_max      29.0470
_cell_measurement_theta_min      2.2110
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.134
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.30968
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.185
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             656
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0244
_diffrn_reflns_av_unetI/netI     0.0326
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8031
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.019
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      149.99(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.2684
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     -1.00  28.00   1.00    4.00    --  -11.43 -99.00  30.00   29
  2  ω    -18.00  50.00   1.00    4.00    --   11.90 -99.00-180.00   68
  3  ω    -87.00   6.00   1.00    4.00    --  -11.43 -77.00 -90.00   93
  4  ω    -61.00 -36.00   1.00    4.00    --  -11.43 114.00  63.00   25
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0176892000
_diffrn_orient_matrix_UB_12      0.0522077000
_diffrn_orient_matrix_UB_13      0.0118269000
_diffrn_orient_matrix_UB_21      0.0147121000
_diffrn_orient_matrix_UB_22      0.0175952000
_diffrn_orient_matrix_UB_23      -0.0473759000
_diffrn_orient_matrix_UB_31      -0.0664066000
_diffrn_orient_matrix_UB_32      -0.0099399000
_diffrn_orient_matrix_UB_33      -0.0219567000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2526
_reflns_number_total             3013
_reflns_odcompleteness_completeness 99.92
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.277
_refine_diff_density_min         -0.263
_refine_diff_density_rms         0.042
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     201
_refine_ls_number_reflns         3013
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0521
_refine_ls_R_factor_gt           0.0418
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0474P)²+0.6000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1011
_refine_ls_wR_factor_ref         0.1077
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9)
2.b Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C8(H8A,H8B), C12(H12A,H12B)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C11(H11), C16(H16), C17(H17), C18(H18),
 C19(H19), C20(H20)
2.d Idealised Me refined as rotating group:
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.49596(5) 0.74704(4) 0.73569(4) 0.02814(17) Uani 1 1 d . . . . .
N1 N 0.17520(14) 0.46703(11) 0.56408(11) 0.0275(3) Uani 1 1 d . . . . .
C1 C 0.07232(16) 0.36715(14) 0.66654(13) 0.0285(4) Uani 1 1 d . . . . .
C2 C -0.00643(18) 0.28205(15) 0.68793(15) 0.0364(5) Uani 1 1 d . . . . .
H2 H -0.023944 0.270818 0.753258 0.044 Uiso 1 1 calc R U . . .
C3 C -0.05759(19) 0.21528(15) 0.61112(17) 0.0407(5) Uani 1 1 d . . . . .
H3 H -0.110501 0.159028 0.625242 0.049 Uiso 1 1 calc R U . . .
C4 C -0.03223(19) 0.22964(15) 0.51245(17) 0.0389(5) Uani 1 1 d . . . . .
H4 H -0.068567 0.183011 0.462281 0.047 Uiso 1 1 calc R U . . .
C5 C 0.04557(18) 0.31160(14) 0.48833(14) 0.0328(4) Uani 1 1 d . . . . .
H5 H 0.063341 0.321056 0.422826 0.039 Uiso 1 1 calc R U . . .
C6 C 0.09654(16) 0.37964(13) 0.56539(13) 0.0267(4) Uani 1 1 d . . . . .
C7 C 0.23538(17) 0.52207(15) 0.48769(13) 0.0306(4) Uani 1 1 d . . . . .
H7A H 0.170468 0.562864 0.443460 0.037 Uiso 1 1 calc R U . . .
H7B H 0.279613 0.473541 0.447641 0.037 Uiso 1 1 calc R U . . .
C8 C 0.33493(18) 0.59378(15) 0.55262(13) 0.0332(4) Uani 1 1 d . . . . .
H8A H 0.341246 0.661481 0.519854 0.040 Uiso 1 1 calc R U . . .
H8B H 0.422082 0.561444 0.563324 0.040 Uiso 1 1 calc R U . . .
C9 C 0.28252(18) 0.60808(14) 0.65369(13) 0.0304(4) Uani 1 1 d . . . . .
H9 H 0.222732 0.669057 0.647282 0.036 Uiso 1 1 calc R U . . .
C10 C 0.19998(17) 0.51021(14) 0.65855(13) 0.0286(4) Uani 1 1 d . . . . .
C11 C 0.13927(17) 0.45219(15) 0.72379(14) 0.0319(4) Uani 1 1 d . . . . .
H11 H 0.140817 0.465083 0.792272 0.038 Uiso 1 1 calc R U . . .
C12 C 0.38925(18) 0.62700(15) 0.74401(14) 0.0345(4) Uani 1 1 d . . . . .
H12A H 0.446282 0.565401 0.752784 0.041 Uiso 1 1 calc R U . . .
H12B H 0.346669 0.633332 0.803842 0.041 Uiso 1 1 calc R U . . .
C13 C 0.63518(18) 0.72316(16) 0.66330(14) 0.0364(5) Uani 1 1 d . . . . .
H13A H 0.600484 0.701347 0.595974 0.055 Uiso 1 1 calc R U . . .
H13B H 0.691656 0.668806 0.695801 0.055 Uiso 1 1 calc R U . . .
H13C H 0.685300 0.786999 0.660745 0.055 Uiso 1 1 calc R U . . .
C14 C 0.5654(2) 0.78461(18) 0.86693(14) 0.0418(5) Uani 1 1 d . . . . .
H14A H 0.622941 0.844403 0.865611 0.063 Uiso 1 1 calc R U . . .
H14B H 0.614722 0.726401 0.899394 0.063 Uiso 1 1 calc R U . . .
H14C H 0.494377 0.802432 0.903566 0.063 Uiso 1 1 calc R U . . .
C15 C 0.38852(17) 0.85700(13) 0.67519(13) 0.0286(4) Uani 1 1 d . . . . .
C16 C 0.29087(19) 0.90096(15) 0.72534(16) 0.0382(5) Uani 1 1 d . . . . .
H16 H 0.280231 0.875386 0.788692 0.046 Uiso 1 1 calc R U . . .
C17 C 0.2098(2) 0.98139(16) 0.68317(18) 0.0471(6) Uani 1 1 d . . . . .
H17 H 0.145380 1.009263 0.717981 0.056 Uiso 1 1 calc R U . . .
C18 C 0.2243(2) 1.02037(16) 0.5896(2) 0.0508(6) Uani 1 1 d . . . . .
H18 H 0.170114 1.074908 0.561299 0.061 Uiso 1 1 calc R U . . .
C19 C 0.3194(2) 0.97849(16) 0.53779(17) 0.0473(6) Uani 1 1 d . . . . .
H19 H 0.329289 1.004563 0.474464 0.057 Uiso 1 1 calc R U . . .
C20 C 0.39994(19) 0.89748(15) 0.58042(15) 0.0366(5) Uani 1 1 d . . . . .
H20 H 0.463356 0.869391 0.544741 0.044 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C12 1.8827(19) . ?
Si1 C13 1.8589(19) . ?
Si1 C14 1.858(2) . ?
Si1 C15 1.8806(19) . ?
N1 C6 1.369(2) . ?
N1 C7 1.448(2) . ?
N1 C10 1.368(2) . ?
C1 C2 1.399(3) . ?
C1 C6 1.422(2) . ?
C1 C11 1.436(3) . ?
C2 H2 0.9300 . ?
C2 C3 1.374(3) . ?
C3 H3 0.9300 . ?
C3 C4 1.396(3) . ?
C4 H4 0.9300 . ?
C4 C5 1.374(3) . ?
C5 H5 0.9300 . ?
C5 C6 1.386(3) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 C8 1.534(2) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C9 1.538(2) . ?
C9 H9 0.9800 . ?
C9 C10 1.505(2) . ?
C9 C12 1.523(2) . ?
C10 C11 1.359(3) . ?
C11 H11 0.9300 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C16 1.397(3) . ?
C15 C20 1.390(3) . ?
C16 H16 0.9300 . ?
C16 C17 1.379(3) . ?
C17 H17 0.9300 . ?
C17 C18 1.376(3) . ?
C18 H18 0.9300 . ?
C18 C19 1.379(3) . ?
C19 H19 0.9300 . ?
C19 C20 1.384(3) . ?
C20 H20 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 Si1 C12 113.09(9) . . ?
C13 Si1 C15 109.69(8) . . ?
C14 Si1 C12 107.08(9) . . ?
C14 Si1 C13 108.77(9) . . ?
C14 Si1 C15 109.56(9) . . ?
C15 Si1 C12 108.58(8) . . ?
C6 N1 C7 135.15(15) . . ?
C10 N1 C6 109.89(14) . . ?
C10 N1 C7 114.96(14) . . ?
C2 C1 C6 117.82(17) . . ?
C2 C1 C11 135.31(18) . . ?
C6 C1 C11 106.87(15) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 C1 119.13(19) . . ?
C3 C2 H2 120.4 . . ?
C2 C3 H3 119.1 . . ?
C2 C3 C4 121.75(18) . . ?
C4 C3 H3 119.1 . . ?
C3 C4 H4 119.5 . . ?
C5 C4 C3 121.02(19) . . ?
C5 C4 H4 119.5 . . ?
C4 C5 H5 121.3 . . ?
C4 C5 C6 117.44(18) . . ?
C6 C5 H5 121.3 . . ?
N1 C6 C1 106.66(15) . . ?
N1 C6 C5 130.51(17) . . ?
C5 C6 C1 122.83(16) . . ?
N1 C7 H7A 111.5 . . ?
N1 C7 H7B 111.5 . . ?
N1 C7 C8 101.43(13) . . ?
H7A C7 H7B 109.3 . . ?
C8 C7 H7A 111.5 . . ?
C8 C7 H7B 111.5 . . ?
C7 C8 H8A 110.4 . . ?
C7 C8 H8B 110.4 . . ?
C7 C8 C9 106.40(14) . . ?
H8A C8 H8B 108.6 . . ?
C9 C8 H8A 110.4 . . ?
C9 C8 H8B 110.4 . . ?
C8 C9 H9 108.0 . . ?
C10 C9 C8 102.13(14) . . ?
C10 C9 H9 108.0 . . ?
C10 C9 C12 115.72(15) . . ?
C12 C9 C8 114.70(15) . . ?
C12 C9 H9 108.0 . . ?
N1 C10 C9 108.51(15) . . ?
C11 C10 N1 109.85(15) . . ?
C11 C10 C9 141.61(17) . . ?
C1 C11 H11 126.6 . . ?
C10 C11 C1 106.72(16) . . ?
C10 C11 H11 126.6 . . ?
Si1 C12 H12A 108.4 . . ?
Si1 C12 H12B 108.4 . . ?
C9 C12 Si1 115.58(13) . . ?
C9 C12 H12A 108.4 . . ?
C9 C12 H12B 108.4 . . ?
H12A C12 H12B 107.4 . . ?
Si1 C13 H13A 109.5 . . ?
Si1 C13 H13B 109.5 . . ?
Si1 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si1 C14 H14A 109.5 . . ?
Si1 C14 H14B 109.5 . . ?
Si1 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 Si1 119.95(14) . . ?
C20 C15 Si1 123.03(13) . . ?
C20 C15 C16 117.01(17) . . ?
C15 C16 H16 119.2 . . ?
C17 C16 C15 121.6(2) . . ?
C17 C16 H16 119.2 . . ?
C16 C17 H17 120.0 . . ?
C18 C17 C16 120.00(19) . . ?
C18 C17 H17 120.0 . . ?
C17 C18 H18 120.0 . . ?
C17 C18 C19 119.9(2) . . ?
C19 C18 H18 120.0 . . ?
C18 C19 H19 120.1 . . ?
C18 C19 C20 119.7(2) . . ?
C20 C19 H19 120.1 . . ?
C15 C20 H20 119.1 . . ?
C19 C20 C15 121.72(19) . . ?
C19 C20 H20 119.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Si1 C15 C16 C17 -179.72(15) . . . . ?
Si1 C15 C20 C19 179.98(15) . . . . ?
N1 C7 C8 C9 -23.79(18) . . . . ?
N1 C10 C11 C1 0.1(2) . . . . ?
C1 C2 C3 C4 0.5(3) . . . . ?
C2 C1 C6 N1 -179.84(15) . . . . ?
C2 C1 C6 C5 0.1(3) . . . . ?
C2 C1 C11 C10 -179.80(19) . . . . ?
C2 C3 C4 C5 0.1(3) . . . . ?
C3 C4 C5 C6 -0.6(3) . . . . ?
C4 C5 C6 N1 -179.61(17) . . . . ?
C4 C5 C6 C1 0.5(3) . . . . ?
C6 N1 C7 C8 -166.21(18) . . . . ?
C6 N1 C10 C9 -178.03(14) . . . . ?
C6 N1 C10 C11 0.4(2) . . . . ?
C6 C1 C2 C3 -0.6(3) . . . . ?
C6 C1 C11 C10 -0.48(19) . . . . ?
C7 N1 C6 C1 179.58(17) . . . . ?
C7 N1 C6 C5 -0.3(3) . . . . ?
C7 N1 C10 C9 1.8(2) . . . . ?
C7 N1 C10 C11 -179.81(15) . . . . ?
C7 C8 C9 C10 24.98(19) . . . . ?
C7 C8 C9 C12 150.96(15) . . . . ?
C8 C9 C10 N1 -16.73(18) . . . . ?
C8 C9 C10 C11 165.7(2) . . . . ?
C8 C9 C12 Si1 59.5(2) . . . . ?
C9 C10 C11 C1 177.7(2) . . . . ?
C10 N1 C6 C1 -0.67(18) . . . . ?
C10 N1 C6 C5 179.43(17) . . . . ?
C10 N1 C7 C8 14.05(19) . . . . ?
C10 C9 C12 Si1 178.05(12) . . . . ?
C11 C1 C2 C3 178.71(19) . . . . ?
C11 C1 C6 N1 0.70(18) . . . . ?
C11 C1 C6 C5 -179.39(16) . . . . ?
C12 Si1 C15 C16 66.69(16) . . . . ?
C12 Si1 C15 C20 -112.58(16) . . . . ?
C12 C9 C10 N1 -142.04(16) . . . . ?
C12 C9 C10 C11 40.4(3) . . . . ?
C13 Si1 C12 C9 -83.20(16) . . . . ?
C13 Si1 C15 C16 -169.28(14) . . . . ?
C13 Si1 C15 C20 11.45(18) . . . . ?
C14 Si1 C12 C9 157.00(14) . . . . ?
C14 Si1 C15 C16 -49.95(17) . . . . ?
C14 Si1 C15 C20 130.78(16) . . . . ?
C15 Si1 C12 C9 38.78(16) . . . . ?
C15 C16 C17 C18 -0.1(3) . . . . ?
C16 C15 C20 C19 0.7(3) . . . . ?
C16 C17 C18 C19 0.4(3) . . . . ?
C17 C18 C19 C20 -0.1(3) . . . . ?
C18 C19 C20 C15 -0.4(3) . . . . ?
C20 C15 C16 C17 -0.4(3) . . . . ?

_olex2_date_sample_data_collection 2021-11-17
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.722
_oxdiff_exptl_absorpt_empirical_full_min 0.356
