# Supplementary Information (SI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_04092
_database_code_depnum_ccdc_archive 'CCDC 2378540'
loop_
_audit_author_name
_audit_author_address
'Josefina Perles'
;Universidad Autonoma de Madrid
Spain
;
_audit_update_record             
;
2024-08-19 deposited with the CCDC.	2024-11-11 downloaded from the CCDC.
;
_audit_creation_date             2024-04-08
_audit_creation_method           
;
Olex2 1.5-ac6-012
(compiled 2023.08.24 svn.re1ec1418 for Rigaku Oxford Diffraction, GUI svn.r6817)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        CSG.CRISTAL-MA
_chemical_formula_moiety         
'2(F6 Sb), 2(C27 H35 Cl2 O2 Rh2), 1.25(C H2 Cl2)'
_chemical_formula_sum            'C55.25 H72.50 Cl6.50 F12 O4 Rh4 Sb2'
_chemical_formula_weight         1914.19
_chemical_melting_point          ?
_chemical_oxdiff_formula         C27H35Cl2O2Rh2SbF6CH2Cl2
_chemical_oxdiff_usercomment     'CSG.CRISTAL-MA 200K'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.0562 5.8946 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.1103(2)
_cell_length_b                   19.9704(2)
_cell_length_c                   22.1424(2)
_cell_angle_alpha                77.4221(9)
_cell_angle_beta                 88.9106(17)
_cell_angle_gamma                88.3440(17)
_cell_volume                     3498.48(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    26096
_cell_measurement_temperature    200.00(10)
_cell_measurement_theta_max      68.1430
_cell_measurement_theta_min      2.6920
_shelx_estimated_absorpt_T_max   0.853
_shelx_estimated_absorpt_T_min   0.192
_exptl_absorpt_coefficient_mu    16.405
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.602
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.105a (Rigaku Oxford Diffraction, 2024)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear intense orange'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   intense
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    1.817
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       ribbon
_exptl_crystal_F_000             1873
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 -1 -1 0.0120
0 1 1 0.0065
-1 1 -1 0.0581
1 -1 1 0.0601
0 -1 1 0.0061
0 1 -1 0.0083

_exptl_crystal_recrystallization_method 
'obtained from a dichloromethane-hexane mixture'
_exptl_crystal_size_max          0.149
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.014
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.0017 -1.0028 -0.9981 -0.0029 -0.0089 0.0939
0.0017 1.0028 0.9981 0.0029 0.0089 -0.0939
-1.0016 0.9861 -1.0063 -0.0153 -0.2204 -0.0384
1.0016 -0.9861 1.0063 0.0153 0.2204 0.0384
0.0015 -0.9993 1.0019 -0.0949 0.0673 0.0161
-0.0015 0.9993 -1.0019 0.0949 -0.0673 -0.0161

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0656
_diffrn_reflns_av_unetI/netI     0.0416
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            65451
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         68.520
_diffrn_reflns_theta_min         2.703
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      200.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            'HyPix-Arc 100'
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     46.00 105.00   0.50    0.63    --  113.34 -95.00-180.00  118
  2  ω     38.00  65.00   0.50    0.63    --  105.89-125.00 -60.00   54
  3  ω     55.00 112.00   0.50    0.63    --  113.34-125.00   0.00  114
  4  ω     35.00 106.00   0.50    0.63    --  105.89 -95.00  60.00  142
  5  ω     25.00  54.00   0.50    0.63    --  105.89 -45.00  90.00   58
  6  ω     29.00  72.00   0.50    0.63    --  105.89 -59.00  68.00   86
  7  ω     36.00  72.00   0.50    0.63    --  113.34 -59.00  68.00   72
  8  ω     29.00  75.00   0.50    0.63    --  105.89 -61.00 -30.00   92
  9  ω     61.00 102.00   0.50    0.63    --  113.34 -77.00 -30.00   82
 10  ω     28.00  54.00   0.50    0.63    --  105.89 -45.00 120.00   52
 11  ω     25.00  54.00   0.50    0.63    --  105.89 -45.00 -60.00   58
 12  ω     28.00  53.00   0.50    0.63    --  105.89 -45.00-120.00   50
 13  ω     37.00  74.00   0.50    0.63    --  113.34 -61.00-150.00   74
 14  ω     25.00  54.00   0.50    0.63    --  105.89 -45.00-180.00   58
 15  ω     75.00 167.00   0.50    0.63    --  105.89  30.00 -60.00  184
 16  ω     82.00 178.00   0.50    0.63    --  105.89  59.00-151.00  192
 17  ω    112.00 178.00   0.50    0.63    --  113.34  77.00 -30.00  132
 18  ω     89.00 178.00   0.50    0.63    --  113.34  59.00-151.00  178
 19  ω     21.00 123.00   0.50    0.29    --   45.15  59.00-151.00  204
 20  ω    108.00 134.00   0.50    0.63    --  113.34  45.00-180.00   52
 21  ω    133.00 176.00   0.50    0.63    --  113.34  61.00 150.00   86
 22  ω     97.00 127.00   0.50    0.63    --  113.34  61.00 150.00   60
 23  ω     83.00 152.00   0.50    0.63    --  113.34  77.00 120.00  138
 24  ω    152.00 178.00   0.50    0.63    --  113.34  45.00  90.00   52
 25  ω    102.00 132.00   0.50    0.63    --  113.34  45.00  90.00   60
 26  ω     75.00 167.00   0.50    0.63    --  105.89  30.00 -60.00  184
 27  ω    136.00 176.00   0.50    0.63    --  113.34  45.00-180.00   80
 28  ω    -37.00  30.00   0.50    0.29    --   45.15 -19.00 -90.00  134
 29  ω    -37.00  30.00   0.50    0.29    --   45.15 -19.00 -90.00  134
 30  ω    -37.00  30.00   0.50    0.29    --   45.15 -19.00 -60.00  134
 31  ω    -37.00  30.00   0.50    0.29    --   45.15 -19.00 -60.00  134
 32  ω    -32.00  70.00   0.50    0.29    --   45.15 -59.00  68.00  204
 33  ω     80.00 169.00   0.50    0.63    --  105.89 125.00  60.00  178
 34  ω    -47.00  -7.00   0.50    0.63    --  -88.49  45.00  60.00   80
 35  ω    -68.00 -11.00   0.50    0.63    --  -88.49  61.00   0.00  114
 36  ω   -112.00 -13.00   0.50    0.63    --  -88.49 125.00 -30.00  198
 37  ω    -65.00  31.00   0.50    0.29    --  -46.03  59.00-151.00  192
 38  ω    -65.00 -11.00   0.50    0.63    --  -88.49  59.00-151.00  108
 39  ω   -123.00 -22.00   0.50    0.29    --  -46.03 -59.00  68.00  202
 40  ω   -159.00 -57.00   0.50    0.63    --  -88.49 -77.00 120.00  204
 41  ω   -159.00 -57.00   0.50    0.63    --  -88.49 -77.00 120.00  204
 42  ω   -159.00 -57.00   0.50    0.63    --  -88.49 -77.00 150.00  204
 43  ω   -159.00 -57.00   0.50    0.63    --  -88.49 -77.00 150.00  204
 44  ω   -117.00 -15.00   0.50    0.29    --  -46.03 -77.00 150.00  204
 45  ω   -169.00 -68.00   0.50    0.63    --  -88.49 -45.00 150.00  202
 46  ω   -166.00 -64.00   0.50    0.63    --  -88.49 -59.00  68.00  204
 47  ω   -117.00 -15.00   0.50    0.29    --  -46.03 -77.00-180.00  204
 48  ω   -122.00 -74.00   0.50    0.29    --  -46.03-125.00  60.00   96
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix-Arc 100'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.1098376000
_diffrn_orient_matrix_UB_12      0.0487936000
_diffrn_orient_matrix_UB_13      -0.0462687000
_diffrn_orient_matrix_UB_21      0.1533423000
_diffrn_orient_matrix_UB_22      -0.0291068000
_diffrn_orient_matrix_UB_23      0.0378719000
_diffrn_orient_matrix_UB_31      0.0232308000
_diffrn_orient_matrix_UB_32      -0.0549837000
_diffrn_orient_matrix_UB_33      -0.0388264000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'PhotonJet R (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10548
_reflns_number_total             12667
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.43.105a (Rigaku OD, 2024)'
_computing_data_collection       
'CrysAlisPro system (CCD 43.105a 64-bit (release 11-01-2024))'
_computing_data_reduction        'CrysAlisPro 1.171.43.105a (Rigaku OD, 2024)'
_computing_molecular_graphics    'Olex2 1.5-ac6-012 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-ac6-012 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         2.345
_refine_diff_density_min         -1.227
_refine_diff_density_rms         0.168
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     809
_refine_ls_number_reflns         12667
_refine_ls_number_restraints     508
_refine_ls_R_factor_all          0.0651
_refine_ls_R_factor_gt           0.0553
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1021P)²+8.3416P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1570
_refine_ls_wR_factor_ref         0.1639
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C55A-Cl5A = C55A-Cl6A
 1.7 with sigma of 0.02
 C55B-Cl5B = C55B-Cl6B
 1.7 with sigma of 0.02
 C56-Cl7 = C56-Cl8
 1.7 with sigma of 0.02
 C48-C49A = C48-C49B
 1.5 with sigma of 0.02
 Cl5A-Cl6A
 2.9 with sigma of 0.04
 Cl5B-Cl6B
 2.9 with sigma of 0.04
 Cl7-Cl8
 2.9 with sigma of 0.04
3. Rigid bond restraints
 C49A, C54A, C53A, C52A, C51A, C50A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C49B, C54B, C53B, C52B, C51B, C50B
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C49A \\sim C50A \\sim C51A \\sim C52A \\sim C53A \\sim C54A: within 1.7A with
sigma of 0.04 and sigma for terminal atoms of 0.08 within 1.7A
C49B \\sim C54B \\sim C53B \\sim C52B \\sim C51B \\sim C50B: within 1.7A with
sigma of 0.04 and sigma for terminal atoms of 0.08 within 1.7A
5. Rigid body (RIGU) restrains
 C48, Rh3, Cl3, Cl4, O57, C38, C39, C40, C41, C42, Rh4, C43, C44, C45, C46,
 C47, O58, C28, C29, C30, C31, C32, C49A, C49B, H43A, H43B, H43C, H44A, H44B,
 H44C, H45A, H45B, H45C, H46A, H46B, H46C, H47A, H47B, H47C, C33, C34, C35, C36,
  C37, C50A, C54A, C50B, C54B, H33A, H33B, H33C, H34A, H34B, H34C, H35A, H35B,
 H35C, H36A, H36B, H36C, H37A, H37B, H37C, H50A, C51A, C53A, H54A, H50B, C51B,
 C53B, H54B, H51A, C52A, H53A, H51B, C52B, H53B, H52A, H52B
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
6. Others
 Sof(C49B)=Sof(C50B)=Sof(H50B)=Sof(C51B)=Sof(H51B)=Sof(C52B)=Sof(H52B)=
 Sof(C53B)=Sof(H53B)=Sof(C54B)=Sof(H54B)=1-FVAR(1)
 Sof(C49A)=Sof(C50A)=Sof(H50A)=Sof(C51A)=Sof(H51A)=Sof(C52A)=Sof(H52A)=
 Sof(C53A)=Sof(H53A)=Sof(C54A)=Sof(H54A)=FVAR(1)
 Sof(Cl5A)=Sof(Cl6A)=Sof(C55A)=Sof(H55A)=Sof(H55B)=1-FVAR(2)
 Sof(Cl5B)=Sof(Cl6B)=Sof(C55B)=Sof(H55C)=Sof(H55D)=FVAR(2)
 Fixed Sof: Cl7(0.25) Cl8(0.25) C56(0.25) H56A(0.25) H56B(0.25)
7.a Secondary CH2 refined with riding coordinates:
 C55A(H55A,H55B), C55B(H55C,H55D), C56(H56A,H56B)
7.b Aromatic/amide H refined with riding coordinates:
 C23(H23), C24(H24), C25(H25), C26(H26), C27(H27), C50A(H50A), C51A(H51A),
 C52A(H52A), C53A(H53A), C54A(H54A), C50B(H50B), C51B(H51B), C52B(H52B),
 C53B(H53B), C54B(H54B)
7.c Fitted hexagon refined as free rotating group:
 C49A(C50A,C51A,C52A,C53A,C54A), C49B(C50B,C51B,C52B,C53B,C54B)
7.d Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,
 H10B,H10C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C18(H18A,H18B,H18C),
 C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C33(H33A,H33B,H33C), C34(H34A,H34B,
 H34C), C35(H35A,H35B,H35C), C36(H36A,H36B,H36C), C37(H37A,H37B,H37C), C43(H43A,
 H43B,H43C), C44(H44A,H44B,H44C), C45(H45A,H45B,H45C), C46(H46A,H46B,H46C),
 C47(H47A,H47B,H47C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 1.03939(7) 1.05538(3) 0.30335(3) 0.05329(16) Uani 1 1 d . . . . .
F1 F 0.9060(7) 1.0632(3) 0.3710(2) 0.0715(15) Uani 1 1 d . . . . .
F2 F 1.1702(10) 1.0469(4) 0.2349(4) 0.108(3) Uani 1 1 d . . . . .
F3 F 1.2091(8) 1.0974(4) 0.3341(3) 0.101(2) Uani 1 1 d . . . . .
F4 F 0.9643(8) 1.1415(3) 0.2599(3) 0.0776(16) Uani 1 1 d . . . . .
F5 F 0.8611(9) 1.0147(4) 0.2705(3) 0.095(2) Uani 1 1 d . . . . .
F6 F 1.1139(9) 0.9691(3) 0.3459(4) 0.109(3) Uani 1 1 d . . . . .
Sb2 Sb -0.01374(7) 0.55093(3) 0.79507(3) 0.05432(16) Uani 1 1 d . . . . .
F7 F -0.1963(9) 0.5906(4) 0.8249(4) 0.111(3) Uani 1 1 d . . . . .
F8 F 0.1722(11) 0.5113(5) 0.7659(4) 0.125(3) Uani 1 1 d . . . . .
F9 F 0.0524(9) 0.6383(3) 0.7547(3) 0.090(2) Uani 1 1 d . . . . .
F10 F -0.1229(10) 0.5438(3) 0.7229(3) 0.103(3) Uani 1 1 d . . . . .
F11 F -0.0798(10) 0.4641(3) 0.8343(4) 0.112(3) Uani 1 1 d . . . . .
F12 F 0.1014(8) 0.5572(3) 0.8657(3) 0.0783(17) Uani 1 1 d . . . . .
Rh1 Rh 0.61960(6) 0.82918(3) 0.43529(2) 0.03524(14) Uani 1 1 d . . . . .
Rh2 Rh 0.42453(6) 0.72653(3) 0.56310(2) 0.03479(14) Uani 1 1 d . . . . .
Cl1 Cl 0.3981(2) 0.84632(9) 0.50685(8) 0.0434(4) Uani 1 1 d . . . . .
Cl2 Cl 0.7035(2) 0.73290(9) 0.51861(7) 0.0427(4) Uani 1 1 d . . . . .
O55 O 0.4622(6) 0.7635(3) 0.4008(2) 0.0468(12) Uani 1 1 d . . . . .
O56 O 0.3443(7) 0.6946(3) 0.4838(2) 0.0488(13) Uani 1 1 d . . . . .
C1 C 0.3811(9) 0.7479(4) 0.6530(3) 0.0398(15) Uani 1 1 d . . . . .
C2 C 0.2312(9) 0.7247(4) 0.6300(3) 0.0418(16) Uani 1 1 d . . . . .
C3 C 0.2626(10) 0.6563(4) 0.6211(3) 0.0477(18) Uani 1 1 d . . . . .
C4 C 0.4317(11) 0.6372(4) 0.6363(3) 0.0497(19) Uani 1 1 d . . . . .
C5 C 0.5027(10) 0.6939(4) 0.6570(3) 0.0428(16) Uani 1 1 d . . . . .
C6 C 0.4016(10) 0.8148(4) 0.6692(4) 0.0472(17) Uani 1 1 d . . . . .
H6A H 0.519130 0.825235 0.668009 0.071 Uiso 1 1 calc R U . . .
H6B H 0.357033 0.813128 0.710937 0.071 Uiso 1 1 calc R U . . .
H6C H 0.342421 0.850518 0.639503 0.071 Uiso 1 1 calc R U . . .
C7 C 0.0736(9) 0.7655(5) 0.6216(4) 0.053(2) Uani 1 1 d . . . . .
H7A H 0.097327 0.814175 0.606501 0.080 Uiso 1 1 calc R U . . .
H7B H 0.014087 0.759245 0.661246 0.080 Uiso 1 1 calc R U . . .
H7C H 0.005728 0.749932 0.591399 0.080 Uiso 1 1 calc R U . . .
C8 C 0.1370(13) 0.6140(5) 0.5969(5) 0.068(3) Uani 1 1 d . . . . .
H8A H 0.066038 0.644384 0.566904 0.101 Uiso 1 1 calc R U . . .
H8B H 0.069456 0.589537 0.631451 0.101 Uiso 1 1 calc R U . . .
H8C H 0.194621 0.580754 0.576799 0.101 Uiso 1 1 calc R U . . .
C9 C 0.5133(17) 0.5701(5) 0.6352(5) 0.076(3) Uani 1 1 d . . . . .
H9A H 0.477657 0.554292 0.598721 0.114 Uiso 1 1 calc R U . . .
H9B H 0.482831 0.536456 0.672722 0.114 Uiso 1 1 calc R U . . .
H9C H 0.633204 0.575091 0.633436 0.114 Uiso 1 1 calc R U . . .
C10 C 0.6751(10) 0.6963(5) 0.6788(4) 0.054(2) Uani 1 1 d . . . . .
H10A H 0.749616 0.671518 0.655409 0.080 Uiso 1 1 calc R U . . .
H10B H 0.680638 0.674712 0.722947 0.080 Uiso 1 1 calc R U . . .
H10C H 0.708214 0.744157 0.672325 0.080 Uiso 1 1 calc R U . . .
C11 C 0.7897(10) 0.9074(4) 0.4350(3) 0.0465(18) Uani 1 1 d . . . . .
C12 C 0.8675(9) 0.8570(4) 0.4070(4) 0.0500(19) Uani 1 1 d . . . . .
C13 C 0.7748(10) 0.8513(4) 0.3549(4) 0.0515(19) Uani 1 1 d . . . . .
C14 C 0.6417(10) 0.9001(4) 0.3487(3) 0.0489(18) Uani 1 1 d . . . . .
C15 C 0.6513(9) 0.9367(4) 0.3974(4) 0.0464(18) Uani 1 1 d . . . . .
C16 C 0.8457(16) 0.9315(6) 0.4906(5) 0.085(4) Uani 1 1 d . . . . .
H16A H 0.762644 0.920512 0.523726 0.128 Uiso 1 1 calc R U . . .
H16B H 0.860271 0.981197 0.479585 0.128 Uiso 1 1 calc R U . . .
H16C H 0.950737 0.908436 0.504712 0.128 Uiso 1 1 calc R U . . .
C17 C 1.0197(11) 0.8156(6) 0.4299(5) 0.073(3) Uani 1 1 d . . . . .
H17A H 1.116756 0.837853 0.408214 0.110 Uiso 1 1 calc R U . . .
H17B H 1.011952 0.769381 0.421862 0.110 Uiso 1 1 calc R U . . .
H17C H 1.029967 0.812341 0.474434 0.110 Uiso 1 1 calc R U . . .
C18 C 0.8086(15) 0.8037(6) 0.3132(5) 0.075(3) Uani 1 1 d . . . . .
H18A H 0.861112 0.828505 0.274971 0.113 Uiso 1 1 calc R U . . .
H18B H 0.704796 0.784770 0.303430 0.113 Uiso 1 1 calc R U . . .
H18C H 0.882449 0.766231 0.333737 0.113 Uiso 1 1 calc R U . . .
C19 C 0.5136(14) 0.9127(6) 0.2997(4) 0.078(3) Uani 1 1 d . . . . .
H19A H 0.503266 0.871388 0.283077 0.118 Uiso 1 1 calc R U . . .
H19B H 0.546045 0.951086 0.266336 0.118 Uiso 1 1 calc R U . . .
H19C H 0.407457 0.923860 0.317500 0.118 Uiso 1 1 calc R U . . .
C20 C 0.5352(13) 0.9931(5) 0.4072(6) 0.073(3) Uani 1 1 d . . . . .
H20A H 0.426589 0.974186 0.419846 0.110 Uiso 1 1 calc R U . . .
H20B H 0.525210 1.027791 0.368553 0.110 Uiso 1 1 calc R U . . .
H20C H 0.577770 1.014182 0.439572 0.110 Uiso 1 1 calc R U . . .
C21 C 0.3719(9) 0.7148(4) 0.4263(3) 0.0435(16) Uani 1 1 d . . . . .
C22 C 0.2843(10) 0.6795(4) 0.3835(4) 0.0512(19) Uani 1 1 d . . . . .
C23 C 0.2666(11) 0.7087(6) 0.3234(4) 0.065(2) Uani 1 1 d . . . . .
H23 H 0.312204 0.752454 0.307414 0.078 Uiso 1 1 calc R U . . .
C24 C 0.1838(15) 0.6767(7) 0.2841(5) 0.080(3) Uani 1 1 d . . . . .
H24 H 0.163204 0.700219 0.242738 0.096 Uiso 1 1 calc R U . . .
C25 C 0.1314(13) 0.6114(7) 0.3049(5) 0.078(3) Uani 1 1 d . . . . .
H25 H 0.083390 0.587684 0.277049 0.094 Uiso 1 1 calc R U . . .
C26 C 0.1481(17) 0.5802(7) 0.3655(7) 0.095(4) Uani 1 1 d . . . . .
H26 H 0.106920 0.535469 0.380482 0.114 Uiso 1 1 calc R U . . .
C27 C 0.2266(14) 0.6141(6) 0.4062(5) 0.073(3) Uani 1 1 d . . . . .
H27 H 0.239586 0.592478 0.448558 0.088 Uiso 1 1 calc R U . . .
Rh3 Rh 0.40692(6) 0.32396(3) 0.93738(2) 0.03890(14) Uani 1 1 d . . . . .
Rh4 Rh 0.59881(7) 0.22833(3) 1.06928(2) 0.03818(14) Uani 1 1 d . . . . .
Cl3 Cl 0.3247(2) 0.23189(11) 1.02396(8) 0.0516(5) Uani 1 1 d . . . . .
Cl4 Cl 0.6180(2) 0.34485(9) 1.00762(8) 0.0485(4) Uani 1 1 d . . . . .
O57 O 0.5718(7) 0.2526(3) 0.9071(2) 0.0536(13) Uani 1 1 d . . . . .
O58 O 0.6957(8) 0.1917(3) 0.9931(2) 0.0575(14) Uani 1 1 d . . . . .
C28 C 0.6254(9) 0.2543(4) 1.1572(3) 0.0436(15) Uani 1 1 d . . . . .
C29 C 0.5129(10) 0.1999(4) 1.1628(3) 0.0464(15) Uani 1 1 d . . . . .
C30 C 0.5983(13) 0.1426(4) 1.1454(3) 0.0564(18) Uani 1 1 d . . . . .
C31 C 0.7652(12) 0.1622(4) 1.1294(3) 0.0535(17) Uani 1 1 d . . . . .
C32 C 0.7812(10) 0.2306(4) 1.1359(3) 0.0463(15) Uani 1 1 d . . . . .
C33 C 0.5921(11) 0.3223(4) 1.1710(4) 0.0523(18) Uani 1 1 d . . . . .
H33A H 0.477051 0.336376 1.161418 0.078 Uiso 1 1 calc R U . . .
H33B H 0.665498 0.355804 1.145867 0.078 Uiso 1 1 calc R U . . .
H33C H 0.611447 0.320006 1.214977 0.078 Uiso 1 1 calc R U . . .
C34 C 0.3372(11) 0.2013(5) 1.1839(4) 0.060(2) Uani 1 1 d . . . . .
H34A H 0.331614 0.188116 1.229159 0.090 Uiso 1 1 calc R U . . .
H34B H 0.274674 0.169075 1.166287 0.090 Uiso 1 1 calc R U . . .
H34C H 0.290051 0.247774 1.170037 0.090 Uiso 1 1 calc R U . . .
C35 C 0.525(2) 0.0738(5) 1.1460(5) 0.095(4) Uani 1 1 d . . . . .
H35A H 0.561052 0.040414 1.182939 0.143 Uiso 1 1 calc R U . . .
H35B H 0.561328 0.057957 1.108886 0.143 Uiso 1 1 calc R U . . .
H35C H 0.404091 0.078272 1.146493 0.143 Uiso 1 1 calc R U . . .
C36 C 0.8963(16) 0.1185(6) 1.1089(5) 0.081(3) Uani 1 1 d . . . . .
H36A H 0.956167 0.092767 1.145051 0.122 Uiso 1 1 calc R U . . .
H36B H 0.973140 0.147457 1.080785 0.122 Uiso 1 1 calc R U . . .
H36C H 0.846384 0.086255 1.087406 0.122 Uiso 1 1 calc R U . . .
C37 C 0.9350(10) 0.2726(6) 1.1256(4) 0.061(2) Uani 1 1 d . . . . .
H37A H 0.904447 0.321148 1.110937 0.091 Uiso 1 1 calc R U . . .
H37B H 1.005885 0.257337 1.094577 0.091 Uiso 1 1 calc R U . . .
H37C H 0.994586 0.266438 1.164590 0.091 Uiso 1 1 calc R U . . .
C38 C 0.2234(12) 0.4032(5) 0.9340(4) 0.0607(19) Uani 1 1 d . . . . .
C39 C 0.3671(11) 0.4308(4) 0.8976(4) 0.0535(17) Uani 1 1 d . . . . .
C40 C 0.3902(10) 0.3941(5) 0.8497(4) 0.0518(17) Uani 1 1 d . . . . .
C41 C 0.2617(11) 0.3455(5) 0.8559(4) 0.0568(18) Uani 1 1 d . . . . .
C42 C 0.1611(9) 0.3518(5) 0.9063(4) 0.0569(18) Uani 1 1 d . . . . .
C43 C 0.144(2) 0.4254(8) 0.9877(5) 0.129(7) Uani 1 1 d . . . . .
H43A H 0.228688 0.430298 1.017345 0.193 Uiso 1 1 calc R U . . .
H43B H 0.065254 0.390976 1.007818 0.193 Uiso 1 1 calc R U . . .
H43C H 0.085919 0.469549 0.973376 0.193 Uiso 1 1 calc R U . . .
C44 C 0.4737(16) 0.4871(5) 0.9060(6) 0.084(3) Uani 1 1 d . . . . .
H44A H 0.429844 0.506739 0.940104 0.127 Uiso 1 1 calc R U . . .
H44B H 0.475596 0.522821 0.867848 0.127 Uiso 1 1 calc R U . . .
H44C H 0.585941 0.468994 0.915636 0.127 Uiso 1 1 calc R U . . .
C45 C 0.5204(14) 0.4048(7) 0.8004(5) 0.088(4) Uani 1 1 d . . . . .
H45A H 0.475765 0.433961 0.762520 0.131 Uiso 1 1 calc R U . . .
H45B H 0.556600 0.360381 0.792202 0.131 Uiso 1 1 calc R U . . .
H45C H 0.614465 0.427169 0.814106 0.131 Uiso 1 1 calc R U . . .
C46 C 0.2365(18) 0.2953(7) 0.8143(6) 0.093(4) Uani 1 1 d . . . . .
H46A H 0.342872 0.274049 0.806357 0.139 Uiso 1 1 calc R U . . .
H46B H 0.189235 0.319848 0.775027 0.139 Uiso 1 1 calc R U . . .
H46C H 0.161158 0.259558 0.834747 0.139 Uiso 1 1 calc R U . . .
C47 C 0.0085(12) 0.3118(7) 0.9295(7) 0.108(5) Uani 1 1 d . . . . .
H47A H -0.008748 0.311081 0.973611 0.162 Uiso 1 1 calc R U . . .
H47B H 0.022855 0.264701 0.923790 0.162 Uiso 1 1 calc R U . . .
H47C H -0.087525 0.333728 0.906283 0.162 Uiso 1 1 calc R U . . .
C48 C 0.6671(11) 0.2064(4) 0.9354(4) 0.0529(18) Uani 1 1 d D . . . .
C49A C 0.742(3) 0.1599(12) 0.8986(11) 0.093(8) Uani 0.48(3) 1 d DG U P A 1
C50A C 0.737(3) 0.1782(13) 0.8344(11) 0.098(8) Uani 0.48(3) 1 d G U P A 1
H50A H 0.684394 0.220181 0.814513 0.117 Uiso 0.48(3) 1 calc R U P A 1
C51A C 0.808(3) 0.1350(15) 0.7992(9) 0.120(10) Uani 0.48(3) 1 d G U P A 1
H51A H 0.804884 0.147499 0.755348 0.144 Uiso 0.48(3) 1 calc R U P A 1
C52A C 0.885(4) 0.0736(14) 0.8283(11) 0.135(11) Uani 0.48(3) 1 d G U P A 1
H52A H 0.933750 0.044084 0.804292 0.162 Uiso 0.48(3) 1 calc R U P A 1
C53A C 0.890(5) 0.0553(14) 0.8925(11) 0.139(11) Uani 0.48(3) 1 d G U P A 1
H53A H 0.942127 0.013350 0.912403 0.167 Uiso 0.48(3) 1 calc R U P A 1
C54A C 0.818(4) 0.0985(14) 0.9277(9) 0.114(10) Uani 0.48(3) 1 d G U P A 1
H54A H 0.821638 0.086031 0.971569 0.137 Uiso 0.48(3) 1 calc R U P A 1
C49B C 0.777(2) 0.1637(7) 0.8991(7) 0.052(4) Uani 0.52(3) 1 d DG U P A 2
C50B C 0.733(2) 0.1615(10) 0.8392(8) 0.062(6) Uani 0.52(3) 1 d G U P A 2
H50B H 0.638069 0.186426 0.821274 0.074 Uiso 0.52(3) 1 calc R U P A 2
C51B C 0.828(3) 0.1230(10) 0.8056(6) 0.078(7) Uani 0.52(3) 1 d G U P A 2
H51B H 0.797772 0.121549 0.764671 0.093 Uiso 0.52(3) 1 calc R U P A 2
C52B C 0.967(3) 0.0866(9) 0.8319(6) 0.080(7) Uani 0.52(3) 1 d G U P A 2
H52B H 1.031894 0.060275 0.808877 0.097 Uiso 0.52(3) 1 calc R U P A 2
C53B C 1.011(3) 0.0888(11) 0.8917(7) 0.087(8) Uani 0.52(3) 1 d G U P A 2
H53B H 1.106314 0.063878 0.909685 0.104 Uiso 0.52(3) 1 calc R U P A 2
C54B C 0.916(3) 0.1273(10) 0.9254(5) 0.074(7) Uani 0.52(3) 1 d G U P A 2
H54B H 0.946612 0.128754 0.966288 0.089 Uiso 0.52(3) 1 calc R U P A 2
Cl5A Cl 0.6929(8) 0.5989(3) 0.3525(3) 0.058(2) Uiso 0.426(18) 1 d D . P B 1
Cl6A Cl 0.696(2) 0.5482(6) 0.4794(5) 0.127(5) Uiso 0.426(18) 1 d D . P B 1
C55A C 0.741(4) 0.6171(11) 0.4211(7) 0.067(8) Uiso 0.426(18) 1 d D . P B 1
H55A H 0.676428 0.658131 0.427141 0.081 Uiso 0.426(18) 1 calc R U P B 1
H55B H 0.859494 0.627152 0.421575 0.081 Uiso 0.426(18) 1 calc R U P B 1
Cl5B Cl 0.685(3) 0.5990(11) 0.3603(9) 0.230(10) Uiso 0.574(18) 1 d D . P B 2
Cl6B Cl 0.8068(13) 0.5500(4) 0.4844(3) 0.112(3) Uiso 0.574(18) 1 d D . P B 2
C55B C 0.773(8) 0.6166(16) 0.4232(15) 0.20(3) Uiso 0.574(18) 1 d D . P B 2
H55C H 0.702832 0.651390 0.437726 0.238 Uiso 0.574(18) 1 calc R U P B 2
H55D H 0.880564 0.637778 0.410162 0.238 Uiso 0.574(18) 1 calc R U P B 2
Cl7 Cl 1.3275(16) 0.0990(6) 0.8661(5) 0.087(3) Uiso 0.25 1 d D . P C 2
Cl8 Cl 1.2667(19) 0.0334(8) 0.9973(6) 0.103(4) Uiso 0.25 1 d D . P C 2
C56 C 1.380(6) 0.084(3) 0.9423(10) 0.12(2) Uiso 0.25 1 d D . P C 2
H56A H 1.494080 0.064142 0.945298 0.146 Uiso 0.25 1 calc R U P C 2
H56B H 1.385326 0.129113 0.953522 0.146 Uiso 0.25 1 calc R U P C 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 F1 1.863(5) . ?
Sb1 F2 1.868(6) . ?
Sb1 F3 1.848(7) . ?
Sb1 F4 1.870(5) . ?
Sb1 F5 1.909(6) . ?
Sb1 F6 1.864(6) . ?
Sb2 F7 1.839(7) . ?
Sb2 F8 1.853(8) . ?
Sb2 F9 1.868(6) . ?
Sb2 F10 1.875(6) . ?
Sb2 F11 1.852(6) . ?
Sb2 F12 1.866(5) . ?
Rh1 Cl1 2.4386(18) . ?
Rh1 Cl2 2.4476(16) . ?
Rh1 O55 2.122(5) . ?
Rh1 C11 2.112(7) . ?
Rh1 C12 2.146(7) . ?
Rh1 C13 2.134(7) . ?
Rh1 C14 2.128(7) . ?
Rh1 C15 2.148(7) . ?
Rh2 Cl1 2.4500(17) . ?
Rh2 Cl2 2.4461(17) . ?
Rh2 O56 2.114(5) . ?
Rh2 C1 2.145(7) . ?
Rh2 C2 2.132(7) . ?
Rh2 C3 2.145(7) . ?
Rh2 C4 2.134(7) . ?
Rh2 C5 2.142(6) . ?
O55 C21 1.260(9) . ?
O56 C21 1.266(9) . ?
C1 C2 1.453(10) . ?
C1 C5 1.429(11) . ?
C1 C6 1.471(11) . ?
C2 C3 1.436(12) . ?
C2 C7 1.488(11) . ?
C3 C4 1.439(13) . ?
C3 C8 1.518(12) . ?
C4 C5 1.449(12) . ?
C4 C9 1.483(13) . ?
C5 C10 1.493(11) . ?
C11 C12 1.419(13) . ?
C11 C15 1.443(11) . ?
C11 C16 1.497(12) . ?
C12 C13 1.416(12) . ?
C12 C17 1.499(12) . ?
C13 C14 1.422(12) . ?
C13 C18 1.479(13) . ?
C14 C15 1.432(12) . ?
C14 C19 1.493(12) . ?
C15 C20 1.496(13) . ?
C21 C22 1.499(11) . ?
C22 C23 1.341(13) . ?
C22 C27 1.384(14) . ?
C23 C24 1.379(14) . ?
C24 C25 1.364(17) . ?
C25 C26 1.358(18) . ?
C26 C27 1.411(14) . ?
Rh3 Cl3 2.4470(18) . ?
Rh3 Cl4 2.4387(19) . ?
Rh3 O57 2.130(6) . ?
Rh3 C38 2.131(9) . ?
Rh3 C39 2.141(8) . ?
Rh3 C40 2.137(7) . ?
Rh3 C41 2.130(8) . ?
Rh3 C42 2.140(7) . ?
Rh4 Cl3 2.4496(18) . ?
Rh4 Cl4 2.4356(18) . ?
Rh4 O58 2.110(6) . ?
Rh4 C28 2.136(7) . ?
Rh4 C29 2.134(7) . ?
Rh4 C30 2.125(7) . ?
Rh4 C31 2.130(8) . ?
Rh4 C32 2.117(8) . ?
O57 C48 1.252(10) . ?
O58 C48 1.270(9) . ?
C28 C29 1.422(11) . ?
C28 C32 1.443(11) . ?
C28 C33 1.472(12) . ?
C29 C30 1.441(13) . ?
C29 C34 1.492(12) . ?
C30 C31 1.437(14) . ?
C30 C35 1.512(14) . ?
C31 C32 1.415(12) . ?
C31 C36 1.482(13) . ?
C32 C37 1.509(12) . ?
C38 C39 1.455(13) . ?
C38 C42 1.413(14) . ?
C38 C43 1.487(14) . ?
C39 C40 1.420(13) . ?
C39 C44 1.484(14) . ?
C40 C41 1.430(13) . ?
C40 C45 1.490(12) . ?
C41 C42 1.396(13) . ?
C41 C46 1.523(15) . ?
C42 C47 1.513(13) . ?
C48 C49A 1.474(14) . ?
C48 C49B 1.550(12) . ?
C49A C50A 1.3900 . ?
C49A C54A 1.3900 . ?
C50A C51A 1.3900 . ?
C51A C52A 1.3900 . ?
C52A C53A 1.3900 . ?
C53A C54A 1.3900 . ?
C49B C50B 1.3900 . ?
C49B C54B 1.3900 . ?
C50B C51B 1.3900 . ?
C51B C52B 1.3900 . ?
C52B C53B 1.3900 . ?
C53B C54B 1.3900 . ?
Cl5A C55A 1.693(16) . ?
Cl6A C55A 1.712(17) . ?
Cl5B C55B 1.687(19) . ?
Cl6B C55B 1.698(19) . ?
Cl7 C56 1.71(2) . ?
Cl8 C56 1.68(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F1 Sb1 F2 179.0(4) . . ?
F1 Sb1 F4 90.6(3) . . ?
F1 Sb1 F5 89.2(3) . . ?
F1 Sb1 F6 89.8(3) . . ?
F2 Sb1 F4 89.3(3) . . ?
F2 Sb1 F5 89.9(4) . . ?
F3 Sb1 F1 90.6(3) . . ?
F3 Sb1 F2 90.4(4) . . ?
F3 Sb1 F4 89.2(3) . . ?
F3 Sb1 F5 178.2(3) . . ?
F3 Sb1 F6 91.3(4) . . ?
F4 Sb1 F5 89.1(3) . . ?
F6 Sb1 F2 90.2(3) . . ?
F6 Sb1 F4 179.4(4) . . ?
F6 Sb1 F5 90.5(4) . . ?
F7 Sb2 F8 179.2(4) . . ?
F7 Sb2 F9 88.9(4) . . ?
F7 Sb2 F10 92.2(4) . . ?
F7 Sb2 F11 91.3(4) . . ?
F7 Sb2 F12 89.6(4) . . ?
F8 Sb2 F9 90.9(4) . . ?
F8 Sb2 F10 88.6(4) . . ?
F8 Sb2 F12 89.5(3) . . ?
F9 Sb2 F10 88.7(3) . . ?
F11 Sb2 F8 88.9(5) . . ?
F11 Sb2 F9 179.4(3) . . ?
F11 Sb2 F10 90.7(3) . . ?
F11 Sb2 F12 89.6(3) . . ?
F12 Sb2 F9 91.0(3) . . ?
F12 Sb2 F10 178.1(4) . . ?
Cl1 Rh1 Cl2 84.41(6) . . ?
O55 Rh1 Cl1 88.17(15) . . ?
O55 Rh1 Cl2 89.70(15) . . ?
O55 Rh1 C12 128.6(3) . . ?
O55 Rh1 C13 95.4(3) . . ?
O55 Rh1 C14 94.1(3) . . ?
O55 Rh1 C15 126.2(3) . . ?
C11 Rh1 Cl1 106.2(2) . . ?
C11 Rh1 Cl2 106.2(2) . . ?
C11 Rh1 O55 159.3(2) . . ?
C11 Rh1 C12 38.9(3) . . ?
C11 Rh1 C13 65.6(3) . . ?
C11 Rh1 C14 66.0(3) . . ?
C11 Rh1 C15 39.6(3) . . ?
C12 Rh1 Cl1 143.3(3) . . ?
C12 Rh1 Cl2 94.5(2) . . ?
C12 Rh1 C15 65.2(3) . . ?
C13 Rh1 Cl1 157.9(2) . . ?
C13 Rh1 Cl2 117.3(2) . . ?
C13 Rh1 C12 38.6(3) . . ?
C13 Rh1 C15 65.5(3) . . ?
C14 Rh1 Cl1 119.1(2) . . ?
C14 Rh1 Cl2 156.2(2) . . ?
C14 Rh1 C12 65.0(3) . . ?
C14 Rh1 C13 39.0(3) . . ?
C14 Rh1 C15 39.1(3) . . ?
C15 Rh1 Cl1 94.9(2) . . ?
C15 Rh1 Cl2 144.1(2) . . ?
Cl2 Rh2 Cl1 84.20(6) . . ?
O56 Rh2 Cl1 89.56(15) . . ?
O56 Rh2 Cl2 88.26(16) . . ?
O56 Rh2 C1 151.7(3) . . ?
O56 Rh2 C2 112.0(3) . . ?
O56 Rh2 C3 90.9(3) . . ?
O56 Rh2 C4 106.5(3) . . ?
O56 Rh2 C5 145.6(3) . . ?
C1 Rh2 Cl1 95.3(2) . . ?
C1 Rh2 Cl2 120.0(2) . . ?
C1 Rh2 C3 66.0(3) . . ?
C2 Rh2 Cl1 99.8(2) . . ?
C2 Rh2 Cl2 159.3(2) . . ?
C2 Rh2 C1 39.7(3) . . ?
C2 Rh2 C3 39.2(3) . . ?
C2 Rh2 C4 66.4(3) . . ?
C2 Rh2 C5 65.8(3) . . ?
C3 Rh2 Cl1 134.5(2) . . ?
C3 Rh2 Cl2 141.3(2) . . ?
C4 Rh2 Cl1 161.7(2) . . ?
C4 Rh2 Cl2 104.6(2) . . ?
C4 Rh2 C1 66.4(3) . . ?
C4 Rh2 C3 39.3(3) . . ?
C4 Rh2 C5 39.6(3) . . ?
C5 Rh2 Cl1 124.9(2) . . ?
C5 Rh2 Cl2 95.1(2) . . ?
C5 Rh2 C1 38.9(3) . . ?
C5 Rh2 C3 65.6(3) . . ?
Rh1 Cl1 Rh2 91.23(6) . . ?
Rh2 Cl2 Rh1 91.11(6) . . ?
C21 O55 Rh1 133.4(5) . . ?
C21 O56 Rh2 133.7(5) . . ?
C2 C1 Rh2 69.7(4) . . ?
C2 C1 C6 125.7(7) . . ?
C5 C1 Rh2 70.4(4) . . ?
C5 C1 C2 107.4(7) . . ?
C5 C1 C6 126.9(7) . . ?
C6 C1 Rh2 125.5(5) . . ?
C1 C2 Rh2 70.6(4) . . ?
C1 C2 C7 123.9(7) . . ?
C3 C2 Rh2 70.9(4) . . ?
C3 C2 C1 107.9(7) . . ?
C3 C2 C7 128.1(7) . . ?
C7 C2 Rh2 126.7(5) . . ?
C2 C3 Rh2 69.9(4) . . ?
C2 C3 C4 108.6(7) . . ?
C2 C3 C8 124.4(8) . . ?
C4 C3 Rh2 69.9(4) . . ?
C4 C3 C8 127.0(8) . . ?
C8 C3 Rh2 124.0(6) . . ?
C3 C4 Rh2 70.7(4) . . ?
C3 C4 C5 107.0(7) . . ?
C3 C4 C9 126.1(9) . . ?
C5 C4 Rh2 70.5(4) . . ?
C5 C4 C9 126.7(9) . . ?
C9 C4 Rh2 127.1(6) . . ?
C1 C5 Rh2 70.7(4) . . ?
C1 C5 C4 109.0(7) . . ?
C1 C5 C10 125.1(7) . . ?
C4 C5 Rh2 69.9(4) . . ?
C4 C5 C10 125.8(8) . . ?
C10 C5 Rh2 125.3(5) . . ?
C12 C11 Rh1 71.8(4) . . ?
C12 C11 C15 107.9(7) . . ?
C12 C11 C16 127.4(9) . . ?
C15 C11 Rh1 71.6(4) . . ?
C15 C11 C16 124.5(9) . . ?
C16 C11 Rh1 126.0(6) . . ?
C11 C12 Rh1 69.2(4) . . ?
C11 C12 C17 125.6(9) . . ?
C13 C12 Rh1 70.2(4) . . ?
C13 C12 C11 108.5(7) . . ?
C13 C12 C17 125.9(9) . . ?
C17 C12 Rh1 125.2(6) . . ?
C12 C13 Rh1 71.2(4) . . ?
C12 C13 C14 108.1(8) . . ?
C12 C13 C18 126.8(9) . . ?
C14 C13 Rh1 70.3(4) . . ?
C14 C13 C18 125.1(9) . . ?
C18 C13 Rh1 124.4(6) . . ?
C13 C14 Rh1 70.7(4) . . ?
C13 C14 C15 108.5(7) . . ?
C13 C14 C19 126.5(9) . . ?
C15 C14 Rh1 71.2(4) . . ?
C15 C14 C19 125.0(9) . . ?
C19 C14 Rh1 124.6(6) . . ?
C11 C15 Rh1 68.9(4) . . ?
C11 C15 C20 127.6(9) . . ?
C14 C15 Rh1 69.7(4) . . ?
C14 C15 C11 106.9(7) . . ?
C14 C15 C20 125.5(8) . . ?
C20 C15 Rh1 125.3(6) . . ?
O55 C21 O56 126.7(7) . . ?
O55 C21 C22 115.8(7) . . ?
O56 C21 C22 117.5(7) . . ?
C23 C22 C21 121.4(8) . . ?
C23 C22 C27 119.5(9) . . ?
C27 C22 C21 119.0(8) . . ?
C22 C23 C24 121.4(11) . . ?
C25 C24 C23 119.9(11) . . ?
C26 C25 C24 119.8(9) . . ?
C25 C26 C27 120.0(12) . . ?
C22 C27 C26 119.0(11) . . ?
Cl4 Rh3 Cl3 84.54(6) . . ?
O57 Rh3 Cl3 88.58(17) . . ?
O57 Rh3 Cl4 89.22(16) . . ?
O57 Rh3 C39 128.5(3) . . ?
O57 Rh3 C40 95.9(3) . . ?
O57 Rh3 C42 127.2(3) . . ?
C38 Rh3 Cl3 105.3(2) . . ?
C38 Rh3 Cl4 106.3(3) . . ?
C38 Rh3 O57 159.8(3) . . ?
C38 Rh3 C39 39.8(3) . . ?
C38 Rh3 C40 65.9(3) . . ?
C38 Rh3 C42 38.6(4) . . ?
C39 Rh3 Cl3 142.9(3) . . ?
C39 Rh3 Cl4 93.6(2) . . ?
C40 Rh3 Cl3 157.9(2) . . ?
C40 Rh3 Cl4 117.0(2) . . ?
C40 Rh3 C39 38.8(3) . . ?
C40 Rh3 C42 65.0(3) . . ?
C41 Rh3 Cl3 119.0(3) . . ?
C41 Rh3 Cl4 156.0(3) . . ?
C41 Rh3 O57 95.6(3) . . ?
C41 Rh3 C38 65.0(4) . . ?
C41 Rh3 C39 65.1(3) . . ?
C41 Rh3 C40 39.2(3) . . ?
C41 Rh3 C42 38.1(4) . . ?
C42 Rh3 Cl3 95.2(2) . . ?
C42 Rh3 Cl4 143.6(3) . . ?
C42 Rh3 C39 65.2(3) . . ?
Cl4 Rh4 Cl3 84.55(6) . . ?
O58 Rh4 Cl3 88.52(18) . . ?
O58 Rh4 Cl4 88.76(17) . . ?
O58 Rh4 C28 151.6(3) . . ?
O58 Rh4 C29 145.1(3) . . ?
O58 Rh4 C30 106.2(3) . . ?
O58 Rh4 C31 90.3(3) . . ?
O58 Rh4 C32 111.9(3) . . ?
C28 Rh4 Cl3 119.8(2) . . ?
C28 Rh4 Cl4 96.3(2) . . ?
C29 Rh4 Cl3 95.0(2) . . ?
C29 Rh4 Cl4 126.1(2) . . ?
C29 Rh4 C28 38.9(3) . . ?
C30 Rh4 Cl3 105.2(3) . . ?
C30 Rh4 Cl4 162.1(2) . . ?
C30 Rh4 C28 66.0(3) . . ?
C30 Rh4 C29 39.6(3) . . ?
C30 Rh4 C31 39.5(4) . . ?
C31 Rh4 Cl3 142.1(3) . . ?
C31 Rh4 Cl4 133.3(3) . . ?
C31 Rh4 C28 66.0(3) . . ?
C31 Rh4 C29 66.1(3) . . ?
C32 Rh4 Cl3 159.1(2) . . ?
C32 Rh4 Cl4 99.8(2) . . ?
C32 Rh4 C28 39.7(3) . . ?
C32 Rh4 C29 65.8(3) . . ?
C32 Rh4 C30 65.8(3) . . ?
C32 Rh4 C31 38.9(3) . . ?
Rh3 Cl3 Rh4 90.87(6) . . ?
Rh4 Cl4 Rh3 91.41(6) . . ?
C48 O57 Rh3 132.6(5) . . ?
C48 O58 Rh4 133.7(5) . . ?
C29 C28 Rh4 70.5(4) . . ?
C29 C28 C32 107.4(7) . . ?
C29 C28 C33 127.0(7) . . ?
C32 C28 Rh4 69.4(4) . . ?
C32 C28 C33 125.6(7) . . ?
C33 C28 Rh4 126.0(5) . . ?
C28 C29 Rh4 70.6(4) . . ?
C28 C29 C30 108.2(7) . . ?
C28 C29 C34 126.1(8) . . ?
C30 C29 Rh4 69.9(4) . . ?
C30 C29 C34 125.7(8) . . ?
C34 C29 Rh4 125.7(5) . . ?
C29 C30 Rh4 70.6(4) . . ?
C29 C30 C35 125.5(10) . . ?
C31 C30 Rh4 70.5(4) . . ?
C31 C30 C29 107.8(7) . . ?
C31 C30 C35 126.7(10) . . ?
C35 C30 Rh4 125.8(7) . . ?
C30 C31 Rh4 70.1(5) . . ?
C30 C31 C36 125.8(10) . . ?
C32 C31 Rh4 70.0(4) . . ?
C32 C31 C30 107.8(8) . . ?
C32 C31 C36 126.3(10) . . ?
C36 C31 Rh4 124.9(6) . . ?
C28 C32 Rh4 70.9(4) . . ?
C28 C32 C37 124.1(8) . . ?
C31 C32 Rh4 71.0(5) . . ?
C31 C32 C28 108.8(7) . . ?
C31 C32 C37 127.1(8) . . ?
C37 C32 Rh4 126.1(5) . . ?
C39 C38 Rh3 70.5(5) . . ?
C39 C38 C43 128.9(12) . . ?
C42 C38 Rh3 71.1(5) . . ?
C42 C38 C39 107.1(8) . . ?
C42 C38 C43 124.0(12) . . ?
C43 C38 Rh3 126.7(7) . . ?
C38 C39 Rh3 69.7(5) . . ?
C38 C39 C44 128.5(10) . . ?
C40 C39 Rh3 70.4(5) . . ?
C40 C39 C38 107.5(8) . . ?
C40 C39 C44 124.0(9) . . ?
C44 C39 Rh3 125.7(6) . . ?
C39 C40 Rh3 70.8(4) . . ?
C39 C40 C41 107.5(8) . . ?
C39 C40 C45 127.1(10) . . ?
C41 C40 Rh3 70.2(4) . . ?
C41 C40 C45 125.4(10) . . ?
C45 C40 Rh3 125.7(6) . . ?
C40 C41 Rh3 70.7(4) . . ?
C40 C41 C46 126.0(10) . . ?
C42 C41 Rh3 71.3(4) . . ?
C42 C41 C40 108.8(8) . . ?
C42 C41 C46 125.2(10) . . ?
C46 C41 Rh3 124.5(7) . . ?
C38 C42 Rh3 70.3(5) . . ?
C38 C42 C47 123.5(11) . . ?
C41 C42 Rh3 70.5(4) . . ?
C41 C42 C38 109.1(8) . . ?
C41 C42 C47 127.4(11) . . ?
C47 C42 Rh3 125.4(6) . . ?
O57 C48 O58 127.3(7) . . ?
O57 C48 C49A 116.0(11) . . ?
O57 C48 C49B 120.1(8) . . ?
O58 C48 C49A 116.5(11) . . ?
O58 C48 C49B 112.4(9) . . ?
C50A C49A C48 119.6(15) . . ?
C50A C49A C54A 120.0 . . ?
C54A C49A C48 120.4(15) . . ?
C49A C50A C51A 120.0 . . ?
C52A C51A C50A 120.0 . . ?
C53A C52A C51A 120.0 . . ?
C52A C53A C54A 120.0 . . ?
C53A C54A C49A 120.0 . . ?
C50B C49B C48 118.5(10) . . ?
C50B C49B C54B 120.0 . . ?
C54B C49B C48 121.5(10) . . ?
C49B C50B C51B 120.0 . . ?
C52B C51B C50B 120.0 . . ?
C53B C52B C51B 120.0 . . ?
C52B C53B C54B 120.0 . . ?
C53B C54B C49B 120.0 . . ?
Cl5A C55A Cl6A 109.0(12) . . ?
Cl5B C55B Cl6B 117.4(19) . . ?
Cl8 C56 Cl7 121(2) . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C55A H55A Cl2 0.99 2.78 3.49(2) 129.4 . yes
C55B H55C Cl2 0.99 2.67 3.49(5) 140.6 . yes
C56 H56A Cl8 0.99 2.82 3.72(6) 151.5 2_857 yes
C56 H56B Cl3 0.99 2.86 3.80(6) 158.1 1_655 yes

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 O55 C21 O56 4.9(12) . . . . ?
Rh1 O55 C21 C22 -177.6(5) . . . . ?
Rh1 C11 C12 C13 59.4(5) . . . . ?
Rh1 C11 C12 C17 -119.2(8) . . . . ?
Rh1 C11 C15 C14 -59.6(5) . . . . ?
Rh1 C11 C15 C20 118.9(8) . . . . ?
Rh1 C12 C13 C14 60.9(5) . . . . ?
Rh1 C12 C13 C18 -119.4(9) . . . . ?
Rh1 C13 C14 C15 61.5(5) . . . . ?
Rh1 C13 C14 C19 -119.3(9) . . . . ?
Rh1 C14 C15 C11 59.1(5) . . . . ?
Rh1 C14 C15 C20 -119.5(8) . . . . ?
Rh2 O56 C21 O55 -0.2(13) . . . . ?
Rh2 O56 C21 C22 -177.7(5) . . . . ?
Rh2 C1 C2 C3 61.4(5) . . . . ?
Rh2 C1 C2 C7 -121.8(7) . . . . ?
Rh2 C1 C5 C4 -59.6(5) . . . . ?
Rh2 C1 C5 C10 120.1(7) . . . . ?
Rh2 C2 C3 C4 59.4(5) . . . . ?
Rh2 C2 C3 C8 -118.2(7) . . . . ?
Rh2 C3 C4 C5 61.5(5) . . . . ?
Rh2 C3 C4 C9 -122.5(8) . . . . ?
Rh2 C4 C5 C1 60.0(5) . . . . ?
Rh2 C4 C5 C10 -119.6(7) . . . . ?
O55 C21 C22 C23 -17.4(12) . . . . ?
O55 C21 C22 C27 159.9(8) . . . . ?
O56 C21 C22 C23 160.3(8) . . . . ?
O56 C21 C22 C27 -22.4(12) . . . . ?
C1 C2 C3 Rh2 -61.2(5) . . . . ?
C1 C2 C3 C4 -1.8(8) . . . . ?
C1 C2 C3 C8 -179.4(7) . . . . ?
C2 C1 C5 Rh2 60.1(5) . . . . ?
C2 C1 C5 C4 0.5(8) . . . . ?
C2 C1 C5 C10 -179.8(6) . . . . ?
C2 C3 C4 Rh2 -59.4(5) . . . . ?
C2 C3 C4 C5 2.1(8) . . . . ?
C2 C3 C4 C9 178.2(7) . . . . ?
C3 C4 C5 Rh2 -61.7(5) . . . . ?
C3 C4 C5 C1 -1.6(8) . . . . ?
C3 C4 C5 C10 178.7(7) . . . . ?
C5 C1 C2 Rh2 -60.6(5) . . . . ?
C5 C1 C2 C3 0.8(7) . . . . ?
C5 C1 C2 C7 177.6(7) . . . . ?
C6 C1 C2 Rh2 119.8(7) . . . . ?
C6 C1 C2 C3 -178.9(7) . . . . ?
C6 C1 C2 C7 -2.0(11) . . . . ?
C6 C1 C5 Rh2 -120.2(7) . . . . ?
C6 C1 C5 C4 -179.8(7) . . . . ?
C6 C1 C5 C10 -0.1(11) . . . . ?
C7 C2 C3 Rh2 122.1(8) . . . . ?
C7 C2 C3 C4 -178.5(7) . . . . ?
C7 C2 C3 C8 4.0(12) . . . . ?
C8 C3 C4 Rh2 118.1(8) . . . . ?
C8 C3 C4 C5 179.6(7) . . . . ?
C8 C3 C4 C9 -4.4(13) . . . . ?
C9 C4 C5 Rh2 122.3(8) . . . . ?
C9 C4 C5 C1 -177.6(7) . . . . ?
C9 C4 C5 C10 2.7(12) . . . . ?
C11 C12 C13 Rh1 -58.8(5) . . . . ?
C11 C12 C13 C14 2.1(8) . . . . ?
C11 C12 C13 C18 -178.2(8) . . . . ?
C12 C11 C15 Rh1 63.0(5) . . . . ?
C12 C11 C15 C14 3.5(8) . . . . ?
C12 C11 C15 C20 -178.0(7) . . . . ?
C12 C13 C14 Rh1 -61.5(5) . . . . ?
C12 C13 C14 C15 0.1(8) . . . . ?
C12 C13 C14 C19 179.2(8) . . . . ?
C13 C14 C15 Rh1 -61.2(5) . . . . ?
C13 C14 C15 C11 -2.2(8) . . . . ?
C13 C14 C15 C20 179.3(7) . . . . ?
C15 C11 C12 Rh1 -62.9(5) . . . . ?
C15 C11 C12 C13 -3.5(8) . . . . ?
C15 C11 C12 C17 178.0(7) . . . . ?
C16 C11 C12 Rh1 121.9(8) . . . . ?
C16 C11 C12 C13 -178.7(8) . . . . ?
C16 C11 C12 C17 2.7(13) . . . . ?
C16 C11 C15 Rh1 -121.6(8) . . . . ?
C16 C11 C15 C14 178.9(8) . . . . ?
C16 C11 C15 C20 -2.6(12) . . . . ?
C17 C12 C13 Rh1 119.8(8) . . . . ?
C17 C12 C13 C14 -179.3(7) . . . . ?
C17 C12 C13 C18 0.4(13) . . . . ?
C18 C13 C14 Rh1 118.8(8) . . . . ?
C18 C13 C14 C15 -179.6(8) . . . . ?
C18 C13 C14 C19 -0.5(13) . . . . ?
C19 C14 C15 Rh1 119.6(8) . . . . ?
C19 C14 C15 C11 178.6(8) . . . . ?
C19 C14 C15 C20 0.1(12) . . . . ?
C21 C22 C23 C24 -179.0(9) . . . . ?
C21 C22 C27 C26 -178.3(10) . . . . ?
C22 C23 C24 C25 -6.2(17) . . . . ?
C23 C22 C27 C26 -0.9(16) . . . . ?
C23 C24 C25 C26 5.8(18) . . . . ?
C24 C25 C26 C27 -3.0(19) . . . . ?
C25 C26 C27 C22 0.6(19) . . . . ?
C27 C22 C23 C24 3.7(15) . . . . ?
Rh3 O57 C48 O58 -3.4(15) . . . . ?
Rh3 O57 C48 C49A 170.2(14) . . . . ?
Rh3 O57 C48 C49B -178.1(9) . . . . ?
Rh3 C38 C39 C40 60.6(5) . . . . ?
Rh3 C38 C39 C44 -120.1(9) . . . . ?
Rh3 C38 C42 C41 -60.1(6) . . . . ?
Rh3 C38 C42 C47 120.0(8) . . . . ?
Rh3 C39 C40 C41 60.9(5) . . . . ?
Rh3 C39 C40 C45 -120.7(9) . . . . ?
Rh3 C40 C41 C42 61.4(5) . . . . ?
Rh3 C40 C41 C46 -119.2(9) . . . . ?
Rh3 C41 C42 C38 60.0(6) . . . . ?
Rh3 C41 C42 C47 -120.2(9) . . . . ?
Rh4 O58 C48 O57 4.1(15) . . . . ?
Rh4 O58 C48 C49A -169.5(14) . . . . ?
Rh4 O58 C48 C49B 179.2(9) . . . . ?
Rh4 C28 C29 C30 60.0(5) . . . . ?
Rh4 C28 C29 C34 -120.6(7) . . . . ?
Rh4 C28 C32 C31 -61.3(5) . . . . ?
Rh4 C28 C32 C37 121.2(7) . . . . ?
Rh4 C29 C30 C31 61.0(5) . . . . ?
Rh4 C29 C30 C35 -120.7(9) . . . . ?
Rh4 C30 C31 C32 60.1(5) . . . . ?
Rh4 C30 C31 C36 -119.2(8) . . . . ?
Rh4 C31 C32 C28 61.2(5) . . . . ?
Rh4 C31 C32 C37 -121.4(8) . . . . ?
O57 C48 C49A C50A 15(2) . . . . ?
O57 C48 C49A C54A -165.4(17) . . . . ?
O57 C48 C49B C50B -20.3(16) . . . . ?
O57 C48 C49B C54B 160.6(12) . . . . ?
O58 C48 C49A C50A -170.4(14) . . . . ?
O58 C48 C49A C54A 9(2) . . . . ?
O58 C48 C49B C50B 164.3(10) . . . . ?
O58 C48 C49B C54B -14.9(16) . . . . ?
C28 C29 C30 Rh4 -60.5(5) . . . . ?
C28 C29 C30 C31 0.5(8) . . . . ?
C28 C29 C30 C35 178.8(8) . . . . ?
C29 C28 C32 Rh4 60.5(5) . . . . ?
C29 C28 C32 C31 -0.7(8) . . . . ?
C29 C28 C32 C37 -178.3(7) . . . . ?
C29 C30 C31 Rh4 -61.0(5) . . . . ?
C29 C30 C31 C32 -0.9(8) . . . . ?
C29 C30 C31 C36 179.7(8) . . . . ?
C30 C31 C32 Rh4 -60.2(5) . . . . ?
C30 C31 C32 C28 1.0(8) . . . . ?
C30 C31 C32 C37 178.5(7) . . . . ?
C32 C28 C29 Rh4 -59.9(5) . . . . ?
C32 C28 C29 C30 0.2(8) . . . . ?
C32 C28 C29 C34 179.5(7) . . . . ?
C33 C28 C29 Rh4 120.9(7) . . . . ?
C33 C28 C29 C30 -179.0(7) . . . . ?
C33 C28 C29 C34 0.3(12) . . . . ?
C33 C28 C32 Rh4 -120.2(7) . . . . ?
C33 C28 C32 C31 178.5(7) . . . . ?
C33 C28 C32 C37 0.9(11) . . . . ?
C34 C29 C30 Rh4 120.1(7) . . . . ?
C34 C29 C30 C31 -178.9(7) . . . . ?
C34 C29 C30 C35 -0.6(13) . . . . ?
C35 C30 C31 Rh4 120.7(9) . . . . ?
C35 C30 C31 C32 -179.2(8) . . . . ?
C35 C30 C31 C36 1.4(13) . . . . ?
C36 C31 C32 Rh4 119.2(8) . . . . ?
C36 C31 C32 C28 -179.6(8) . . . . ?
C36 C31 C32 C37 -2.2(13) . . . . ?
C38 C39 C40 Rh3 -60.1(5) . . . . ?
C38 C39 C40 C41 0.8(9) . . . . ?
C38 C39 C40 C45 179.2(8) . . . . ?
C39 C38 C42 Rh3 61.6(5) . . . . ?
C39 C38 C42 C41 1.5(9) . . . . ?
C39 C38 C42 C47 -178.4(8) . . . . ?
C39 C40 C41 Rh3 -61.3(5) . . . . ?
C39 C40 C41 C42 0.2(9) . . . . ?
C39 C40 C41 C46 179.5(8) . . . . ?
C40 C41 C42 Rh3 -61.0(6) . . . . ?
C40 C41 C42 C38 -1.1(9) . . . . ?
C40 C41 C42 C47 178.8(8) . . . . ?
C42 C38 C39 Rh3 -62.0(5) . . . . ?
C42 C38 C39 C40 -1.4(9) . . . . ?
C42 C38 C39 C44 177.9(8) . . . . ?
C43 C38 C39 Rh3 121.8(10) . . . . ?
C43 C38 C39 C40 -177.6(9) . . . . ?
C43 C38 C39 C44 1.8(15) . . . . ?
C43 C38 C42 Rh3 -122.0(9) . . . . ?
C43 C38 C42 C41 177.9(9) . . . . ?
C43 C38 C42 C47 -2.0(14) . . . . ?
C44 C39 C40 Rh3 120.5(8) . . . . ?
C44 C39 C40 C41 -178.6(8) . . . . ?
C44 C39 C40 C45 -0.2(13) . . . . ?
C45 C40 C41 Rh3 120.3(9) . . . . ?
C45 C40 C41 C42 -178.3(8) . . . . ?
C45 C40 C41 C46 1.1(14) . . . . ?
C46 C41 C42 Rh3 119.6(9) . . . . ?
C46 C41 C42 C38 179.6(8) . . . . ?
C46 C41 C42 C47 -0.6(14) . . . . ?
C48 C49A C50A C51A 179(2) . . . . ?
C48 C49A C54A C53A -179(2) . . . . ?
C48 C49B C50B C51B -179.2(14) . . . . ?
C48 C49B C54B C53B 179.1(14) . . . . ?
C49A C50A C51A C52A 0.0 . . . . ?
C50A C49A C54A C53A 0.0 . . . . ?
C50A C51A C52A C53A 0.0 . . . . ?
C51A C52A C53A C54A 0.0 . . . . ?
C52A C53A C54A C49A 0.0 . . . . ?
C54A C49A C50A C51A 0.0 . . . . ?
C49B C50B C51B C52B 0.0 . . . . ?
C50B C49B C54B C53B 0.0 . . . . ?
C50B C51B C52B C53B 0.0 . . . . ?
C51B C52B C53B C54B 0.0 . . . . ?
C52B C53B C54B C49B 0.0 . . . . ?
C54B C49B C50B C51B 0.0 . . . . ?

_olex2_exptl_crystal_mounting_method 'placed on a MiTeGen micromount'
_olex2_submission_original_sample_id 04092
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.904
_oxdiff_exptl_absorpt_empirical_full_min 0.551
