# Supplementary Information (SI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_La
_database_code_depnum_ccdc_archive 'CCDC 2206527'
loop_
_audit_author_name
_audit_author_address
XuFei
;Qingdao University
China
;
_audit_update_record             
;
2024-05-14 deposited with the CCDC.	2024-10-02 downloaded from the CCDC.
;
_audit_creation_date             2024-05-14
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelxl_version_number           2013-2
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         
'C10 H29 La2 Li O35 P10, 2(C12 H11 N4), 3(O H2)'
_chemical_formula_sum            'C34 H57 La2 Li N8 O38 P10'
_chemical_formula_weight         1780.28
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.2018(2)
_cell_length_b                   16.4476(2)
_cell_length_c                   16.9585(3)
_cell_angle_alpha                68.4420(10)
_cell_angle_beta                 69.632(2)
_cell_angle_gamma                79.1400(10)
_cell_volume                     2960.26(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    22808
_cell_measurement_temperature    293
_cell_measurement_theta_max      30.6900
_cell_measurement_theta_min      1.9620
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.805
_exptl_absorpt_correction_T_max  0.965
_exptl_absorpt_correction_T_min  0.897
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.110a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_lustre     ?
_exptl_crystal_colour_modifier   ?
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.991
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       stick
_exptl_crystal_F_000             1764
_exptl_crystal_preparation       ?
_exptl_crystal_recrystallization_method ?
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0547
_diffrn_reflns_av_unetI/netI     0.0444
_diffrn_reflns_Laue_measured_fraction_full 0.973
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            42386
_diffrn_reflns_point_group_measured_fraction_full 0.973
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.010
_diffrn_reflns_theta_min         1.952
_diffrn_ambient_temperature      293
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_special_details          ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9106
_reflns_number_total             10440
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2013/2 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.648
_refine_diff_density_min         -0.613
_refine_diff_density_rms         0.096
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     843
_refine_ls_number_reflns         10440
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0356
_refine_ls_R_factor_gt           0.0297
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0370P)²+1.3612P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0757
_refine_ls_wR_factor_ref         0.0785
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C14(H14), C16(H16A), C17(H17), C18(H18A), C19(H19A), C20(H20),
 N4(H4A), C22(H22), C24(H24), C26(H26), C28(H28), C29(H29A), C30(H30), C31(H31),
  C32(H32), C33(H33), C34(H34), N2(H2D), C21(H21), N6(H6D), N8(H8)
2.b Tetrahedral OH refined with riding coordinates:
 O2(H2), O4(H4), O6(H6), O9(H9), O11(H11), O13(H13), O16(H16), O18(H18),
 O19(H19), O23(H23), O25(H25), O27(H27), O29(H29), O35(H35)
2.c Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C0AA(H0AA,H0AB,H0AC), C6(H6A,H6B,H6C), C8(H8A,H8B,H8C),
 C10(H10A,H10B,H10C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
La1 La 0.87234(2) 0.40503(2) 0.11546(2) 0.01473(6) Uani 1 1 d . . . . .
La2 La 0.59383(2) 0.13689(2) 0.37965(2) 0.01630(6) Uani 1 1 d . . . . .
Li1 Li 0.6244(6) 0.5024(4) 0.1301(4) 0.0289(15) Uani 1 1 d . . . . .
C1 C 0.8963(3) 0.6637(2) 0.0966(2) 0.0163(7) Uani 1 1 d . . . . .
C2 C 0.8054(3) 0.6758(2) 0.1799(2) 0.0249(8) Uani 1 1 d . . . . .
H2A H 0.8440 0.6816 0.2179 0.037 Uiso 1 1 calc R U . . .
H2B H 0.7591 0.6258 0.2107 0.037 Uiso 1 1 calc R U . . .
H2C H 0.7555 0.7276 0.1637 0.037 Uiso 1 1 calc R U . . .
C3 C 0.7326(3) 0.3465(2) 0.3900(2) 0.0202(8) Uani 1 1 d . . . . .
C0AA C 0.6778(4) 0.3121(3) 0.4901(2) 0.0351(10) Uani 1 1 d . . . . .
H0AA H 0.7363 0.3048 0.5186 0.053 Uiso 1 1 calc R U . . .
H0AB H 0.6468 0.2566 0.5067 0.053 Uiso 1 1 calc R U . . .
H0AC H 0.6157 0.3530 0.5085 0.053 Uiso 1 1 calc R U . . .
C5 C 0.6237(3) 0.2511(2) 0.1212(2) 0.0217(8) Uani 1 1 d . . . . .
C6 C 0.5522(4) 0.1952(3) 0.1059(3) 0.0347(10) Uani 1 1 d . . . . .
H6A H 0.5408 0.1405 0.1539 0.052 Uiso 1 1 calc R U . . .
H6B H 0.5932 0.1844 0.0507 0.052 Uiso 1 1 calc R U . . .
H6C H 0.4774 0.2255 0.1035 0.052 Uiso 1 1 calc R U . . .
C7 C 0.2702(3) 0.0355(2) 0.4180(2) 0.0192(7) Uani 1 1 d . . . . .
C8 C 0.2356(4) 0.1048(2) 0.3395(3) 0.0306(9) Uani 1 1 d . . . . .
H8A H 0.2326 0.0773 0.2992 0.046 Uiso 1 1 calc R U . . .
H8B H 0.2924 0.1481 0.3089 0.046 Uiso 1 1 calc R U . . .
H8C H 0.1599 0.1324 0.3611 0.046 Uiso 1 1 calc R U . . .
C9 C 0.3296(3) 0.6683(2) 0.2526(2) 0.0230(8) Uani 1 1 d . . . . .
C10 C 0.2966(4) 0.6052(3) 0.3485(3) 0.0399(11) Uani 1 1 d . . . . .
H10A H 0.2163 0.6182 0.3789 0.060 Uiso 1 1 calc R U . . .
H10B H 0.3463 0.6117 0.3787 0.060 Uiso 1 1 calc R U . . .
H10C H 0.3065 0.5460 0.3480 0.060 Uiso 1 1 calc R U . . .
C11 C 0.5613(3) 0.9845(2) 0.0002(2) 0.0249(8) Uani 1 1 d . . . . .
C12 C 0.5952(3) 0.9675(2) 0.0758(2) 0.0266(9) Uani 1 1 d . . . . .
H12 H 0.5392 0.9725 0.1278 0.032 Uiso 1 1 calc R U . . .
C13 C 0.7110(4) 0.9432(2) 0.0749(2) 0.0260(9) Uani 1 1 d . . . . .
C14 C 0.7964(4) 0.9341(2) -0.0012(3) 0.0286(9) Uani 1 1 d . . . . .
H14 H 0.8745 0.9196 -0.0030 0.034 Uiso 1 1 calc R U . . .
C15 C 0.7608(4) 0.9475(2) -0.0738(2) 0.0261(9) Uani 1 1 d . . . . .
C16 C 0.6483(4) 0.9726(2) -0.0758(2) 0.0267(9) Uani 1 1 d . . . . .
H16A H 0.6292 0.9817 -0.1271 0.032 Uiso 1 1 calc R U . . .
C17 C 0.9105(4) 0.9967(3) -0.2270(3) 0.0404(11) Uani 1 1 d . . . . .
H17 H 0.8927 1.0569 -0.2426 0.048 Uiso 1 1 calc R U . . .
C18 C 0.9986(4) 0.9544(3) -0.2743(3) 0.0440(12) Uani 1 1 d . . . . .
H18A H 1.0534 0.9796 -0.3287 0.053 Uiso 1 1 calc R U . . .
C19 C 0.9036(5) 0.8575(3) -0.1544(3) 0.0444(13) Uani 1 1 d . . . . .
H19A H 0.8808 0.8039 -0.1114 0.053 Uiso 1 1 calc R U . . .
C20 C 0.8440(4) 0.8789(3) 0.1703(3) 0.0370(10) Uani 1 1 d . . . . .
H20 H 0.8987 0.8472 0.1368 0.044 Uiso 1 1 calc R U . . .
N4 N 0.7502(3) 0.9393(2) 0.2728(2) 0.0308(8) Uani 1 1 d . . . . .
H4A H 0.7316 0.9541 0.3197 0.037 Uiso 1 1 calc R U . . .
C22 C 0.6918(4) 0.9647(2) 0.2148(2) 0.0274(9) Uani 1 1 d . . . . .
H22 H 0.6240 1.0019 0.2176 0.033 Uiso 1 1 calc R U . . .
C23 C 0.0525(3) 0.4725(2) 0.4831(2) 0.0246(8) Uani 1 1 d . . . . .
C24 C 0.1312(3) 0.4343(2) 0.5308(2) 0.0264(8) Uani 1 1 d . . . . .
H24 H 0.1177 0.4426 0.5849 0.032 Uiso 1 1 calc R U . . .
C25 C 0.2293(3) 0.3843(2) 0.4996(2) 0.0237(8) Uani 1 1 d . . . . .
C26 C 0.2545(3) 0.3694(2) 0.4199(2) 0.0234(8) Uani 1 1 d . . . . .
H26 H 0.3206 0.3353 0.3994 0.028 Uiso 1 1 calc R U . . .
C27 C 0.1761(3) 0.4079(2) 0.3726(2) 0.0232(8) Uani 1 1 d . . . . .
C28 C 0.0774(3) 0.4585(2) 0.4021(2) 0.0248(8) Uani 1 1 d . . . . .
H28 H 0.0271 0.4836 0.3677 0.030 Uiso 1 1 calc R U . . .
C29 C 0.3366(4) 0.3856(3) 0.5976(3) 0.0282(9) Uani 1 1 d . . . . .
H29A H 0.3153 0.4432 0.5966 0.034 Uiso 1 1 calc R U . . .
C30 C 0.4145(4) 0.2513(2) 0.6274(3) 0.0286(9) Uani 1 1 d . . . . .
H30 H 0.4568 0.2007 0.6519 0.034 Uiso 1 1 calc R U . . .
C31 C 0.3561(4) 0.2610(2) 0.5709(3) 0.0283(9) Uani 1 1 d . . . . .
H31 H 0.3500 0.2190 0.5482 0.034 Uiso 1 1 calc R U . . .
C32 C 0.1308(4) 0.3696(3) 0.2605(2) 0.0290(9) Uani 1 1 d . . . . .
H32 H 0.0567 0.3504 0.2953 0.035 Uiso 1 1 calc R U . . .
C33 C 0.2882(4) 0.4073(3) 0.1477(3) 0.0453(12) Uani 1 1 d . . . . .
H33 H 0.3413 0.4174 0.0909 0.054 Uiso 1 1 calc R U . . .
C34 C 0.3019(4) 0.4242(3) 0.2148(3) 0.0454(12) Uani 1 1 d . . . . .
H34 H 0.3656 0.4483 0.2137 0.055 Uiso 1 1 calc R U . . .
N1 N 0.8524(3) 0.93440(18) -0.15185(19) 0.0239(7) Uani 1 1 d . . . . .
N2 N 0.9920(3) 0.8686(2) -0.2274(2) 0.0393(9) Uani 1 1 d . . . . .
H2D H 1.0389 0.8273 -0.2431 0.047 Uiso 1 1 calc R U . . .
N3 N 0.7454(3) 0.92871(19) 0.1513(2) 0.0254(7) Uani 1 1 d . . . . .
C21 C 0.8449(4) 0.8856(3) 0.2468(3) 0.0384(10) Uani 1 1 d . . . . .
H21 H 0.9002 0.8586 0.2765 0.046 Uiso 1 1 calc R U . . .
N5 N 0.3064(3) 0.34575(19) 0.5529(2) 0.0238(7) Uani 1 1 d . . . . .
N6 N 0.4015(3) 0.3287(2) 0.6431(2) 0.0287(7) Uani 1 1 d . . . . .
H6D H 0.4313 0.3386 0.6775 0.034 Uiso 1 1 calc R U . . .
N7 N 0.2018(3) 0.39851(19) 0.2867(2) 0.0228(7) Uani 1 1 d . . . . .
N8 N 0.1819(3) 0.3724(2) 0.1777(2) 0.0307(8) Uani 1 1 d . . . . .
H8 H 0.1533 0.3552 0.1472 0.037 Uiso 1 1 calc R U . . .
O1 O 0.9186(2) 0.49087(15) 0.19748(16) 0.0229(6) Uani 1 1 d . . . . .
O2 O 1.0771(2) 0.58615(16) 0.16642(16) 0.0243(6) Uani 1 1 d . . . . .
H2 H 1.1141 0.6278 0.1292 0.036 Uiso 1 1 calc R U . . .
O3 O 1.0556(2) 0.54051(15) 0.04508(15) 0.0227(6) Uani 1 1 d . . . . .
O4 O 0.9628(2) 0.74037(15) 0.05097(17) 0.0251(6) Uani 1 1 d . . . . .
H4 H 1.0127 0.7349 0.0057 0.038 Uiso 1 1 calc R U . . .
O5 O 0.9158(2) 0.65726(14) -0.06589(14) 0.0173(5) Uani 1 1 d . . . . .
O6 O 0.7293(2) 0.72412(15) 0.00926(16) 0.0239(6) Uani 1 1 d . . . . .
H6 H 0.6826 0.7251 0.0574 0.036 Uiso 1 1 calc R U . . .
O7 O 0.7724(2) 0.55961(14) 0.07251(15) 0.0181(5) Uani 1 1 d . . . . .
O8 O 0.6777(2) 0.40926(15) 0.23443(15) 0.0225(5) Uani 1 1 d . . . . .
O9 O 0.5333(2) 0.44427(16) 0.36768(17) 0.0292(6) Uani 1 1 d . . . . .
H9 H 0.5672 0.4888 0.3517 0.044 Uiso 1 1 calc R U . . .
O10 O 0.5573(2) 0.29133(15) 0.36385(17) 0.0252(6) Uani 1 1 d . . . . .
O11 O 0.7895(3) 0.42553(16) 0.36923(18) 0.0329(7) Uani 1 1 d . . . . .
H11 H 0.8200 0.4457 0.3153 0.049 Uiso 1 1 calc R U . . .
O12 O 0.7814(2) 0.17756(15) 0.38756(16) 0.0241(6) Uani 1 1 d . . . . .
O13 O 0.9379(2) 0.24838(16) 0.40284(16) 0.0259(6) Uani 1 1 d . . . . .
H13 H 0.9086 0.2297 0.4571 0.039 Uiso 1 1 calc R U . . .
O14 O 0.9029(2) 0.29533(14) 0.25815(15) 0.0203(5) Uani 1 1 d . . . . .
O15 O 0.8520(2) 0.26103(14) 0.10815(16) 0.0207(5) Uani 1 1 d . . . . .
O16 O 0.8083(2) 0.12783(15) 0.08513(17) 0.0274(6) Uani 1 1 d . . . . .
H16 H 0.8246 0.1552 0.0317 0.041 Uiso 1 1 calc R U . . .
O17 O 0.7356(2) 0.13937(15) 0.23553(16) 0.0250(6) Uani 1 1 d . . . . .
O18 O 0.5548(2) 0.26656(17) 0.20451(17) 0.0326(7) Uani 1 1 d . . . . .
H18 H 0.5903 0.2967 0.2154 0.049 Uiso 1 1 calc R U . . .
O19 O 0.5354(2) 0.39395(17) 0.00933(18) 0.0301(6) Uani 1 1 d . . . . .
H19 H 0.5113 0.3580 -0.0026 0.045 Uiso 1 1 calc R U . . .
O20 O 0.6854(2) 0.41533(15) 0.06842(16) 0.0227(5) Uani 1 1 d . . . . .
O21 O 0.7434(2) 0.33787(16) -0.04921(16) 0.0237(6) Uani 1 1 d . . . . .
O22 O 0.5055(2) 0.03978(16) 0.33964(17) 0.0263(6) Uani 1 1 d . . . . .
O23 O 0.4047(3) -0.05425(16) 0.30523(17) 0.0285(6) Uani 1 1 d . . . . .
H23 H 0.3478 -0.0833 0.3239 0.043 Uiso 1 1 calc R U . . .
O24 O 0.4243(2) -0.10000(15) 0.46092(16) 0.0262(6) Uani 1 1 d . . . . .
O25 O 0.1787(2) -0.02578(16) 0.46464(17) 0.0258(6) Uani 1 1 d . . . . .
H25 H 0.1949 -0.0637 0.5072 0.039 Uiso 1 1 calc R U . . .
O26 O 0.2872(3) 0.01036(15) 0.57923(16) 0.0272(6) Uani 1 1 d . . . . .
O27 O 0.1668(2) 0.14675(16) 0.51691(19) 0.0317(6) Uani 1 1 d . . . . .
H27 H 0.1093 0.1176 0.5416 0.047 Uiso 1 1 calc R U . . .
O28 O 0.3791(2) 0.14366(15) 0.45143(16) 0.0235(6) Uani 1 1 d . . . . .
O29 O 0.2500(3) 0.6595(2) 0.2118(2) 0.0429(8) Uani 1 1 d . . . . .
H29 H 0.1828 0.6719 0.2395 0.064 Uiso 1 1 calc R U . . .
O30 O 0.4809(2) 0.57452(16) 0.14839(17) 0.0267(6) Uani 1 1 d . . . . .
O31 O 0.5472(2) 0.60204(15) 0.25972(18) 0.0280(6) Uani 1 1 d . . . . .
O32 O 0.5303(2) 0.72725(16) 0.12065(17) 0.0313(6) Uani 1 1 d . . . . .
O34 O 0.3836(3) 0.79957(17) 0.2955(2) 0.0379(7) Uani 1 1 d . . . . .
O35 O 0.3412(3) 0.83671(18) 0.14996(19) 0.0413(7) Uani 1 1 d . . . . .
H35 H 0.2975 0.8273 0.1274 0.062 Uiso 1 1 calc R U . . .
O36 O 0.1758(3) 0.80288(17) 0.29288(19) 0.0348(7) Uani 1 1 d . . . . .
O37 O 0.0074(4) 0.7146(3) 0.2724(4) 0.0920(16) Uani 1 1 d . . . . .
O38 O 0.0697(2) 0.85980(17) 0.43420(17) 0.0295(6) Uani 1 1 d . . . . .
O39 O 0.8589(3) 0.1581(2) 0.9150(2) 0.0565(10) Uani 1 1 d . . . . .
P1 P 0.99187(8) 0.56424(5) 0.12804(6) 0.01592(19) Uani 1 1 d . . . . .
P2 P 0.82437(8) 0.64743(5) 0.02488(6) 0.01508(18) Uani 1 1 d . . . . .
P3 P 0.62059(8) 0.37312(5) 0.33396(6) 0.01665(19) Uani 1 1 d . . . . .
P4 P 0.84089(8) 0.26123(5) 0.35648(6) 0.01636(19) Uani 1 1 d . . . . .
P5 P 0.65376(8) 0.35644(6) 0.03019(6) 0.01844(19) Uani 1 1 d . . . . .
P6 P 0.76344(8) 0.19363(5) 0.13903(6) 0.01716(19) Uani 1 1 d . . . . .
P7 P 0.41156(8) -0.02448(6) 0.38103(6) 0.01748(19) Uani 1 1 d . . . . .
P8 P 0.28057(8) 0.08484(5) 0.49577(6) 0.01729(19) Uani 1 1 d . . . . .
P9 P 0.48206(9) 0.64191(6) 0.19084(6) 0.0204(2) Uani 1 1 d . . . . .
P10 P 0.30428(9) 0.78223(6) 0.25418(7) 0.0251(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
La1 O1 2.556(2) . ?
La1 O3 2.414(2) 2_765 ?
La1 O5 2.561(2) 2_765 ?
La1 O7 2.563(2) . ?
La1 O8 2.534(2) . ?
La1 O14 2.533(2) . ?
La1 O15 2.479(2) . ?
La1 O20 2.625(3) . ?
La2 O10 2.425(2) . ?
La2 O12 2.561(3) . ?
La2 O17 2.445(2) . ?
La2 O22 2.475(2) . ?
La2 O24 2.481(2) 2_656 ?
La2 O26 2.569(2) 2_656 ?
La2 O28 2.476(3) . ?
Li1 O7 1.959(7) . ?
Li1 O8 2.082(7) . ?
Li1 O20 1.964(7) . ?
Li1 O30 1.918(7) . ?
C1 C2 1.516(5) . ?
C1 O4 1.443(4) . ?
C1 P1 1.842(4) . ?
C1 P2 1.840(4) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 C0AA 1.516(5) . ?
C3 O11 1.459(4) . ?
C3 P3 1.826(4) . ?
C3 P4 1.844(4) . ?
C0AA H0AA 0.9600 . ?
C0AA H0AB 0.9600 . ?
C0AA H0AC 0.9600 . ?
C5 C6 1.520(5) . ?
C5 O18 1.457(4) . ?
C5 P5 1.843(4) . ?
C5 P6 1.853(4) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 C8 1.531(5) . ?
C7 O25 1.454(4) . ?
C7 P7 1.845(4) . ?
C7 P8 1.832(4) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C10 1.531(5) . ?
C9 O29 1.427(5) . ?
C9 P9 1.850(4) . ?
C9 P10 1.849(3) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 C11 1.488(8) 2_675 ?
C11 C12 1.398(6) . ?
C11 C16 1.408(5) . ?
C12 H12 0.9300 . ?
C12 C13 1.390(6) . ?
C13 C14 1.384(5) . ?
C13 N3 1.424(5) . ?
C14 H14 0.9300 . ?
C14 C15 1.376(6) . ?
C15 C16 1.365(6) . ?
C15 N1 1.461(5) . ?
C16 H16A 0.9300 . ?
C17 H17 0.9300 . ?
C17 C18 1.346(6) . ?
C17 N1 1.365(5) . ?
C18 H18A 0.9300 . ?
C18 N2 1.342(6) . ?
C19 H19A 0.9300 . ?
C19 N1 1.310(5) . ?
C19 N2 1.307(6) . ?
C20 H20 0.9300 . ?
C20 N3 1.388(5) . ?
C20 C21 1.345(6) . ?
N4 H4A 0.8600 . ?
N4 C22 1.312(5) . ?
N4 C21 1.362(5) . ?
C22 H22 0.9300 . ?
C22 N3 1.330(5) . ?
C23 C23 1.491(7) 2_566 ?
C23 C24 1.383(6) . ?
C23 C28 1.395(5) . ?
C24 H24 0.9300 . ?
C24 C25 1.377(5) . ?
C25 C26 1.381(5) . ?
C25 N5 1.433(5) . ?
C26 H26 0.9300 . ?
C26 C27 1.375(5) . ?
C27 C28 1.379(5) . ?
C27 N7 1.440(5) . ?
C28 H28 0.9300 . ?
C29 H29A 0.9300 . ?
C29 N5 1.337(5) . ?
C29 N6 1.309(5) . ?
C30 H30 0.9300 . ?
C30 C31 1.331(6) . ?
C30 N6 1.363(5) . ?
C31 H31 0.9300 . ?
C31 N5 1.379(5) . ?
C32 H32 0.9300 . ?
C32 N7 1.323(5) . ?
C32 N8 1.310(5) . ?
C33 H33 0.9300 . ?
C33 C34 1.334(6) . ?
C33 N8 1.371(6) . ?
C34 H34 0.9300 . ?
C34 N7 1.391(5) . ?
N2 H2D 0.8600 . ?
C21 H21 0.9300 . ?
N6 H6D 0.8600 . ?
N8 H8 0.8600 . ?
O1 P1 1.507(2) . ?
O2 H2 0.8200 . ?
O2 P1 1.556(3) . ?
O3 La1 2.414(2) 2_765 ?
O3 P1 1.505(2) . ?
O4 H4 0.8200 . ?
O5 La1 2.561(2) 2_765 ?
O5 P2 1.526(2) . ?
O6 H6 0.8200 . ?
O6 P2 1.557(2) . ?
O7 P2 1.507(2) . ?
O8 P3 1.513(2) . ?
O9 H9 0.8200 . ?
O9 P3 1.559(3) . ?
O10 P3 1.511(2) . ?
O11 H11 0.8200 . ?
O12 P4 1.509(2) . ?
O13 H13 0.8200 . ?
O13 P4 1.580(3) . ?
O14 P4 1.504(2) . ?
O15 P6 1.518(2) . ?
O16 H16 0.8200 . ?
O16 P6 1.569(2) . ?
O17 P6 1.498(2) . ?
O18 H18 0.8200 . ?
O19 H19 0.8200 . ?
O19 P5 1.565(3) . ?
O20 P5 1.511(2) . ?
O21 P5 1.501(3) . ?
O22 P7 1.509(3) . ?
O23 H23 0.8200 . ?
O23 P7 1.566(3) . ?
O24 La2 2.481(2) 2_656 ?
O24 P7 1.497(3) . ?
O25 H25 0.8200 . ?
O26 La2 2.569(2) 2_656 ?
O26 P8 1.510(3) . ?
O27 H27 0.8200 . ?
O27 P8 1.575(3) . ?
O28 P8 1.490(3) . ?
O29 H29 0.8200 . ?
O30 P9 1.532(3) . ?
O31 P9 1.521(3) . ?
O32 P9 1.526(3) . ?
O34 P10 1.493(3) . ?
O35 H35 0.8200 . ?
O35 P10 1.601(3) . ?
O36 P10 1.500(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 La1 O5 93.96(8) . 2_765 ?
O1 La1 O7 72.02(8) . . ?
O1 La1 O20 130.23(8) . . ?
O3 La1 O1 116.58(8) 2_765 . ?
O3 La1 O5 71.60(8) 2_765 2_765 ?
O3 La1 O7 75.46(7) 2_765 . ?
O3 La1 O8 136.62(8) 2_765 . ?
O3 La1 O14 146.93(8) 2_765 . ?
O3 La1 O15 89.14(8) 2_765 . ?
O3 La1 O20 76.80(8) 2_765 . ?
O5 La1 O7 133.03(7) 2_765 . ?
O5 La1 O20 134.11(7) 2_765 . ?
O7 La1 O20 65.52(7) . . ?
O8 La1 O1 78.70(8) . . ?
O8 La1 O5 151.15(7) . 2_765 ?
O8 La1 O7 71.49(7) . . ?
O8 La1 O20 64.37(8) . . ?
O14 La1 O1 72.70(7) . . ?
O14 La1 O5 76.25(7) . 2_765 ?
O14 La1 O7 134.98(7) . . ?
O14 La1 O8 74.93(8) . . ?
O14 La1 O20 123.24(8) . . ?
O15 La1 O1 148.32(8) . . ?
O15 La1 O5 76.12(8) . 2_765 ?
O15 La1 O7 135.99(8) . . ?
O15 La1 O8 95.49(8) . . ?
O15 La1 O14 75.71(8) . . ?
O15 La1 O20 70.93(8) . . ?
O10 La2 O12 75.97(8) . . ?
O10 La2 O17 102.23(8) . . ?
O10 La2 O22 132.39(9) . . ?
O10 La2 O24 90.36(8) . 2_656 ?
O10 La2 O26 150.92(9) . 2_656 ?
O10 La2 O28 79.99(8) . . ?
O12 La2 O26 75.84(8) . 2_656 ?
O17 La2 O12 76.81(8) . . ?
O17 La2 O22 79.21(8) . . ?
O17 La2 O24 142.53(9) . 2_656 ?
O17 La2 O26 78.06(8) . 2_656 ?
O17 La2 O28 139.55(9) . . ?
O22 La2 O12 146.50(8) . . ?
O22 La2 O24 117.48(8) . 2_656 ?
O22 La2 O26 76.57(9) . 2_656 ?
O22 La2 O28 70.89(8) . . ?
O24 La2 O12 72.25(8) 2_656 . ?
O24 La2 O26 74.35(8) 2_656 2_656 ?
O28 La2 O12 140.45(8) . . ?
O28 La2 O24 77.02(9) . 2_656 ?
O28 La2 O26 118.90(8) . 2_656 ?
O7 Li1 O8 94.9(3) . . ?
O7 Li1 O20 91.4(3) . . ?
O20 Li1 O8 85.6(3) . . ?
O30 Li1 O7 118.4(3) . . ?
O30 Li1 O8 122.9(3) . . ?
O30 Li1 O20 133.4(4) . . ?
C2 C1 P1 109.3(2) . . ?
C2 C1 P2 110.2(3) . . ?
O4 C1 C2 108.0(3) . . ?
O4 C1 P1 111.0(2) . . ?
O4 C1 P2 111.0(2) . . ?
P2 C1 P1 107.21(16) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C0AA C3 P3 110.6(3) . . ?
C0AA C3 P4 108.0(3) . . ?
O11 C3 C0AA 107.3(3) . . ?
O11 C3 P3 109.6(2) . . ?
O11 C3 P4 110.8(2) . . ?
P3 C3 P4 110.48(18) . . ?
C3 C0AA H0AA 109.5 . . ?
C3 C0AA H0AB 109.5 . . ?
C3 C0AA H0AC 109.5 . . ?
H0AA C0AA H0AB 109.5 . . ?
H0AA C0AA H0AC 109.5 . . ?
H0AB C0AA H0AC 109.5 . . ?
C6 C5 P5 112.4(3) . . ?
C6 C5 P6 112.9(3) . . ?
O18 C5 C6 106.2(3) . . ?
O18 C5 P5 110.0(2) . . ?
O18 C5 P6 105.7(2) . . ?
P5 C5 P6 109.44(19) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 P7 112.0(3) . . ?
C8 C7 P8 111.3(2) . . ?
O25 C7 C8 107.4(3) . . ?
O25 C7 P7 109.2(2) . . ?
O25 C7 P8 108.4(2) . . ?
P8 C7 P7 108.46(19) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C10 C9 P9 110.5(3) . . ?
C10 C9 P10 109.2(3) . . ?
O29 C9 C10 107.5(3) . . ?
O29 C9 P9 110.3(2) . . ?
O29 C9 P10 106.2(2) . . ?
P10 C9 P9 112.89(19) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 C11 121.3(4) . 2_675 ?
C12 C11 C16 117.2(4) . . ?
C16 C11 C11 121.5(4) . 2_675 ?
C11 C12 H12 119.3 . . ?
C13 C12 C11 121.4(3) . . ?
C13 C12 H12 119.3 . . ?
C12 C13 N3 121.0(3) . . ?
C14 C13 C12 120.7(4) . . ?
C14 C13 N3 118.3(4) . . ?
C13 C14 H14 121.4 . . ?
C15 C14 C13 117.2(4) . . ?
C15 C14 H14 121.4 . . ?
C14 C15 N1 115.7(4) . . ?
C16 C15 C14 123.7(3) . . ?
C16 C15 N1 120.6(3) . . ?
C11 C16 H16A 120.2 . . ?
C15 C16 C11 119.7(4) . . ?
C15 C16 H16A 120.2 . . ?
C18 C17 H17 126.5 . . ?
C18 C17 N1 106.9(3) . . ?
N1 C17 H17 126.5 . . ?
C17 C18 H18A 126.7 . . ?
N2 C18 C17 106.6(4) . . ?
N2 C18 H18A 126.7 . . ?
N1 C19 H19A 125.7 . . ?
N2 C19 H19A 125.7 . . ?
N2 C19 N1 108.6(3) . . ?
N3 C20 H20 126.7 . . ?
C21 C20 H20 126.7 . . ?
C21 C20 N3 106.6(4) . . ?
C22 N4 H4A 125.4 . . ?
C22 N4 C21 109.1(3) . . ?
C21 N4 H4A 125.4 . . ?
N4 C22 H22 125.5 . . ?
N4 C22 N3 109.0(4) . . ?
N3 C22 H22 125.5 . . ?
C24 C23 C23 120.6(4) . 2_566 ?
C24 C23 C28 117.1(3) . . ?
C28 C23 C23 122.3(4) . 2_566 ?
C23 C24 H24 119.5 . . ?
C25 C24 C23 121.1(3) . . ?
C25 C24 H24 119.5 . . ?
C24 C25 C26 122.4(4) . . ?
C24 C25 N5 118.2(3) . . ?
C26 C25 N5 119.4(3) . . ?
C25 C26 H26 121.9 . . ?
C27 C26 C25 116.2(3) . . ?
C27 C26 H26 121.9 . . ?
C26 C27 C28 122.7(3) . . ?
C26 C27 N7 118.3(3) . . ?
C28 C27 N7 118.9(3) . . ?
C23 C28 H28 119.7 . . ?
C27 C28 C23 120.5(4) . . ?
C27 C28 H28 119.7 . . ?
N5 C29 H29A 126.2 . . ?
N6 C29 H29A 126.2 . . ?
N6 C29 N5 107.6(3) . . ?
C31 C30 H30 126.0 . . ?
C31 C30 N6 108.0(3) . . ?
N6 C30 H30 126.0 . . ?
C30 C31 H31 126.9 . . ?
C30 C31 N5 106.1(3) . . ?
N5 C31 H31 126.9 . . ?
N7 C32 H32 125.5 . . ?
N8 C32 H32 125.5 . . ?
N8 C32 N7 109.0(4) . . ?
C34 C33 H33 126.2 . . ?
C34 C33 N8 107.7(4) . . ?
N8 C33 H33 126.2 . . ?
C33 C34 H34 126.8 . . ?
C33 C34 N7 106.4(4) . . ?
N7 C34 H34 126.8 . . ?
C17 N1 C15 127.9(3) . . ?
C19 N1 C15 123.3(3) . . ?
C19 N1 C17 108.2(3) . . ?
C18 N2 H2D 125.2 . . ?
C19 N2 C18 109.6(3) . . ?
C19 N2 H2D 125.2 . . ?
C20 N3 C13 126.3(3) . . ?
C22 N3 C13 125.8(3) . . ?
C22 N3 C20 107.8(3) . . ?
C20 C21 N4 107.5(4) . . ?
C20 C21 H21 126.2 . . ?
N4 C21 H21 126.2 . . ?
C29 N5 C25 124.8(3) . . ?
C29 N5 C31 108.9(3) . . ?
C31 N5 C25 126.2(3) . . ?
C29 N6 C30 109.5(3) . . ?
C29 N6 H6D 125.3 . . ?
C30 N6 H6D 125.3 . . ?
C32 N7 C27 125.8(3) . . ?
C32 N7 C34 108.1(3) . . ?
C34 N7 C27 125.9(3) . . ?
C32 N8 C33 108.8(3) . . ?
C32 N8 H8 125.6 . . ?
C33 N8 H8 125.6 . . ?
P1 O1 La1 107.28(12) . . ?
P1 O2 H2 109.5 . . ?
P1 O3 La1 145.44(14) . 2_765 ?
C1 O4 H4 109.5 . . ?
P2 O5 La1 133.55(13) . 2_765 ?
P2 O6 H6 109.5 . . ?
Li1 O7 La1 86.1(2) . . ?
P2 O7 La1 130.32(14) . . ?
P2 O7 Li1 143.6(2) . . ?
Li1 O8 La1 84.4(2) . . ?
P3 O8 La1 141.36(15) . . ?
P3 O8 Li1 134.0(2) . . ?
P3 O9 H9 109.5 . . ?
P3 O10 La2 141.48(16) . . ?
C3 O11 H11 109.5 . . ?
P4 O12 La2 135.34(14) . . ?
P4 O13 H13 109.5 . . ?
P4 O14 La1 140.91(15) . . ?
P6 O15 La1 141.87(14) . . ?
P6 O16 H16 109.5 . . ?
P6 O17 La2 140.29(16) . . ?
C5 O18 H18 109.5 . . ?
P5 O19 H19 109.5 . . ?
Li1 O20 La1 84.3(2) . . ?
P5 O20 La1 129.10(14) . . ?
P5 O20 Li1 145.1(3) . . ?
P7 O22 La2 140.14(15) . . ?
P7 O23 H23 109.5 . . ?
P7 O24 La2 141.90(14) . 2_656 ?
C7 O25 H25 109.5 . . ?
P8 O26 La2 137.55(15) . 2_656 ?
P8 O27 H27 109.5 . . ?
P8 O28 La2 139.67(14) . . ?
C9 O29 H29 109.5 . . ?
P9 O30 Li1 113.1(3) . . ?
P10 O35 H35 109.5 . . ?
O1 P1 C1 109.71(15) . . ?
O1 P1 O2 110.08(14) . . ?
O2 P1 C1 107.62(15) . . ?
O3 P1 C1 107.01(14) . . ?
O3 P1 O1 110.13(14) . . ?
O3 P1 O2 112.18(15) . . ?
O5 P2 C1 107.47(15) . . ?
O5 P2 O6 106.21(13) . . ?
O6 P2 C1 108.04(15) . . ?
O7 P2 C1 107.15(14) . . ?
O7 P2 O5 115.46(13) . . ?
O7 P2 O6 112.22(14) . . ?
O8 P3 C3 109.21(16) . . ?
O8 P3 O9 110.20(14) . . ?
O9 P3 C3 106.32(16) . . ?
O10 P3 C3 107.60(15) . . ?
O10 P3 O8 114.16(15) . . ?
O10 P3 O9 109.03(15) . . ?
O12 P4 C3 109.37(15) . . ?
O12 P4 O13 110.95(14) . . ?
O13 P4 C3 106.24(16) . . ?
O14 P4 C3 109.51(14) . . ?
O14 P4 O12 115.06(14) . . ?
O14 P4 O13 105.30(14) . . ?
O19 P5 C5 106.36(16) . . ?
O20 P5 C5 105.61(15) . . ?
O20 P5 O19 108.72(15) . . ?
O21 P5 C5 107.75(15) . . ?
O21 P5 O19 110.03(15) . . ?
O21 P5 O20 117.73(15) . . ?
O15 P6 C5 108.84(15) . . ?
O15 P6 O16 110.74(14) . . ?
O16 P6 C5 109.04(16) . . ?
O17 P6 C5 106.75(16) . . ?
O17 P6 O15 114.72(15) . . ?
O17 P6 O16 106.57(14) . . ?
O22 P7 C7 107.66(15) . . ?
O22 P7 O23 107.21(15) . . ?
O23 P7 C7 106.63(16) . . ?
O24 P7 C7 106.57(15) . . ?
O24 P7 O22 115.54(16) . . ?
O24 P7 O23 112.78(14) . . ?
O26 P8 C7 106.70(15) . . ?
O26 P8 O27 110.22(15) . . ?
O27 P8 C7 108.48(16) . . ?
O28 P8 C7 109.59(15) . . ?
O28 P8 O26 116.45(16) . . ?
O28 P8 O27 105.21(14) . . ?
O30 P9 C9 108.60(16) . . ?
O31 P9 C9 106.03(16) . . ?
O31 P9 O30 109.99(14) . . ?
O31 P9 O32 112.98(16) . . ?
O32 P9 C9 107.33(15) . . ?
O32 P9 O30 111.63(15) . . ?
O34 P10 C9 111.17(17) . . ?
O34 P10 O35 109.52(18) . . ?
O34 P10 O36 116.15(17) . . ?
O35 P10 C9 101.42(16) . . ?
O36 P10 C9 109.70(16) . . ?
O36 P10 O35 107.81(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
La1 O1 P1 C1 92.55(15) . . . . ?
La1 O1 P1 O2 -149.19(12) . . . . ?
La1 O1 P1 O3 -24.99(17) . . . . ?
La1 O3 P1 C1 25.9(3) 2_765 . . . ?
La1 O3 P1 O1 145.1(3) 2_765 . . . ?
La1 O3 P1 O2 -91.9(3) 2_765 . . . ?
La1 O5 P2 C1 47.4(2) 2_765 . . . ?
La1 O5 P2 O6 162.86(16) 2_765 . . . ?
La1 O5 P2 O7 -72.1(2) 2_765 . . . ?
La1 O7 P2 C1 -64.3(2) . . . . ?
La1 O7 P2 O5 55.4(2) . . . . ?
La1 O7 P2 O6 177.29(15) . . . . ?
La1 O8 P3 C3 25.6(3) . . . . ?
La1 O8 P3 O9 142.0(2) . . . . ?
La1 O8 P3 O10 -94.9(2) . . . . ?
La1 O14 P4 C3 -26.7(3) . . . . ?
La1 O14 P4 O12 97.0(2) . . . . ?
La1 O14 P4 O13 -140.5(2) . . . . ?
La1 O15 P6 C5 44.6(3) . . . . ?
La1 O15 P6 O16 164.5(2) . . . . ?
La1 O15 P6 O17 -74.9(3) . . . . ?
La1 O20 P5 C5 69.0(2) . . . . ?
La1 O20 P5 O19 -177.23(15) . . . . ?
La1 O20 P5 O21 -51.3(2) . . . . ?
La2 O10 P3 C3 -50.3(3) . . . . ?
La2 O10 P3 O8 71.1(3) . . . . ?
La2 O10 P3 O9 -165.2(2) . . . . ?
La2 O12 P4 C3 48.2(2) . . . . ?
La2 O12 P4 O13 165.12(17) . . . . ?
La2 O12 P4 O14 -75.5(2) . . . . ?
La2 O17 P6 C5 -27.1(3) . . . . ?
La2 O17 P6 O15 93.5(3) . . . . ?
La2 O17 P6 O16 -143.5(2) . . . . ?
La2 O22 P7 C7 61.5(3) . . . . ?
La2 O22 P7 O23 175.9(2) . . . . ?
La2 O22 P7 O24 -57.4(3) . . . . ?
La2 O24 P7 C7 -47.4(3) 2_656 . . . ?
La2 O24 P7 O22 72.1(3) 2_656 . . . ?
La2 O24 P7 O23 -164.1(2) 2_656 . . . ?
La2 O26 P8 C7 49.8(3) 2_656 . . . ?
La2 O26 P8 O27 167.4(2) 2_656 . . . ?
La2 O26 P8 O28 -72.9(2) 2_656 . . . ?
La2 O28 P8 C7 -59.7(3) . . . . ?
La2 O28 P8 O26 61.4(3) . . . . ?
La2 O28 P8 O27 -176.2(2) . . . . ?
Li1 O7 P2 C1 113.9(4) . . . . ?
Li1 O7 P2 O5 -126.4(4) . . . . ?
Li1 O7 P2 O6 -4.5(5) . . . . ?
Li1 O8 P3 C3 -146.8(3) . . . . ?
Li1 O8 P3 O9 -30.3(4) . . . . ?
Li1 O8 P3 O10 92.7(3) . . . . ?
Li1 O20 P5 C5 -91.1(4) . . . . ?
Li1 O20 P5 O19 22.7(4) . . . . ?
Li1 O20 P5 O21 148.7(4) . . . . ?
Li1 O30 P9 C9 -153.2(3) . . . . ?
Li1 O30 P9 O31 -37.6(3) . . . . ?
Li1 O30 P9 O32 88.6(3) . . . . ?
C2 C1 P1 O1 44.3(3) . . . . ?
C2 C1 P1 O2 -75.5(3) . . . . ?
C2 C1 P1 O3 163.8(2) . . . . ?
C2 C1 P2 O5 166.9(2) . . . . ?
C2 C1 P2 O6 52.7(3) . . . . ?
C2 C1 P2 O7 -68.4(3) . . . . ?
C0AA C3 P3 O8 178.6(3) . . . . ?
C0AA C3 P3 O9 59.8(3) . . . . ?
C0AA C3 P3 O10 -56.9(3) . . . . ?
C0AA C3 P4 O12 56.8(3) . . . . ?
C0AA C3 P4 O13 -63.0(3) . . . . ?
C0AA C3 P4 O14 -176.3(3) . . . . ?
C6 C5 P5 O19 45.2(3) . . . . ?
C6 C5 P5 O20 160.6(3) . . . . ?
C6 C5 P5 O21 -72.7(3) . . . . ?
C6 C5 P6 O15 151.9(3) . . . . ?
C6 C5 P6 O16 31.0(3) . . . . ?
C6 C5 P6 O17 -83.7(3) . . . . ?
C8 C7 P7 O22 65.7(3) . . . . ?
C8 C7 P7 O23 -49.1(3) . . . . ?
C8 C7 P7 O24 -169.8(2) . . . . ?
C8 C7 P8 O26 167.3(3) . . . . ?
C8 C7 P8 O27 48.5(3) . . . . ?
C8 C7 P8 O28 -65.8(3) . . . . ?
C10 C9 P9 O30 88.9(3) . . . . ?
C10 C9 P9 O31 -29.3(3) . . . . ?
C10 C9 P9 O32 -150.3(3) . . . . ?
C10 C9 P10 O34 64.6(3) . . . . ?
C10 C9 P10 O35 -179.1(3) . . . . ?
C10 C9 P10 O36 -65.3(3) . . . . ?
C11 C11 C12 C13 -176.3(4) 2_675 . . . ?
C11 C11 C16 C15 177.2(4) 2_675 . . . ?
C11 C12 C13 C14 -0.8(6) . . . . ?
C11 C12 C13 N3 178.0(3) . . . . ?
C12 C11 C16 C15 -1.6(5) . . . . ?
C12 C13 C14 C15 -1.9(5) . . . . ?
C12 C13 N3 C20 157.8(4) . . . . ?
C12 C13 N3 C22 -26.2(5) . . . . ?
C13 C14 C15 C16 2.9(6) . . . . ?
C13 C14 C15 N1 -177.9(3) . . . . ?
C14 C13 N3 C20 -23.4(5) . . . . ?
C14 C13 N3 C22 152.6(4) . . . . ?
C14 C15 C16 C11 -1.1(6) . . . . ?
C14 C15 N1 C17 -101.0(5) . . . . ?
C14 C15 N1 C19 68.9(5) . . . . ?
C16 C11 C12 C13 2.5(5) . . . . ?
C16 C15 N1 C17 78.2(6) . . . . ?
C16 C15 N1 C19 -111.9(5) . . . . ?
C17 C18 N2 C19 0.3(6) . . . . ?
C18 C17 N1 C15 170.8(4) . . . . ?
C18 C17 N1 C19 -0.4(6) . . . . ?
N4 C22 N3 C13 -177.5(3) . . . . ?
N4 C22 N3 C20 -0.9(4) . . . . ?
C22 N4 C21 C20 0.4(5) . . . . ?
C23 C23 C24 C25 -179.1(4) 2_566 . . . ?
C23 C23 C28 C27 179.4(4) 2_566 . . . ?
C23 C24 C25 C26 -0.1(6) . . . . ?
C23 C24 C25 N5 -179.2(3) . . . . ?
C24 C23 C28 C27 0.7(6) . . . . ?
C24 C25 C26 C27 0.4(6) . . . . ?
C24 C25 N5 C29 -40.4(5) . . . . ?
C24 C25 N5 C31 135.7(4) . . . . ?
C25 C26 C27 C28 -0.1(5) . . . . ?
C25 C26 C27 N7 176.5(3) . . . . ?
C26 C25 N5 C29 140.5(4) . . . . ?
C26 C25 N5 C31 -43.5(5) . . . . ?
C26 C27 C28 C23 -0.4(6) . . . . ?
C26 C27 N7 C32 127.3(4) . . . . ?
C26 C27 N7 C34 -57.7(5) . . . . ?
C28 C23 C24 C25 -0.4(6) . . . . ?
C28 C27 N7 C32 -56.0(5) . . . . ?
C28 C27 N7 C34 119.0(5) . . . . ?
C30 C31 N5 C25 -175.8(4) . . . . ?
C30 C31 N5 C29 0.7(5) . . . . ?
C31 C30 N6 C29 0.0(5) . . . . ?
C33 C34 N7 C27 -177.3(4) . . . . ?
C33 C34 N7 C32 -1.6(5) . . . . ?
C34 C33 N8 C32 1.1(6) . . . . ?
N1 C15 C16 C11 179.7(3) . . . . ?
N1 C17 C18 N2 0.0(6) . . . . ?
N1 C19 N2 C18 -0.6(6) . . . . ?
N2 C19 N1 C15 -171.1(4) . . . . ?
N2 C19 N1 C17 0.6(6) . . . . ?
N3 C13 C14 C15 179.3(3) . . . . ?
N3 C20 C21 N4 -0.9(5) . . . . ?
C21 C20 N3 C13 177.7(4) . . . . ?
C21 C20 N3 C22 1.1(5) . . . . ?
C21 N4 C22 N3 0.4(5) . . . . ?
N5 C25 C26 C27 179.5(3) . . . . ?
N5 C29 N6 C30 0.4(5) . . . . ?
N6 C29 N5 C25 175.9(3) . . . . ?
N6 C29 N5 C31 -0.7(5) . . . . ?
N6 C30 C31 N5 -0.4(5) . . . . ?
N7 C27 C28 C23 -177.0(3) . . . . ?
N7 C32 N8 C33 -2.2(5) . . . . ?
N8 C32 N7 C27 178.1(3) . . . . ?
N8 C32 N7 C34 2.3(5) . . . . ?
N8 C33 C34 N7 0.3(6) . . . . ?
O4 C1 P1 O1 163.4(2) . . . . ?
O4 C1 P1 O2 43.6(3) . . . . ?
O4 C1 P1 O3 -77.1(2) . . . . ?
O4 C1 P2 O5 47.2(3) . . . . ?
O4 C1 P2 O6 -67.0(3) . . . . ?
O4 C1 P2 O7 171.8(2) . . . . ?
O11 C3 P3 O8 60.5(3) . . . . ?
O11 C3 P3 O9 -58.4(3) . . . . ?
O11 C3 P3 O10 -175.1(2) . . . . ?
O11 C3 P4 O12 174.1(2) . . . . ?
O11 C3 P4 O13 54.2(3) . . . . ?
O11 C3 P4 O14 -59.0(3) . . . . ?
O18 C5 P5 O19 -72.9(3) . . . . ?
O18 C5 P5 O20 42.6(3) . . . . ?
O18 C5 P5 O21 169.2(2) . . . . ?
O18 C5 P6 O15 -92.5(2) . . . . ?
O18 C5 P6 O16 146.6(2) . . . . ?
O18 C5 P6 O17 31.8(3) . . . . ?
O25 C7 P7 O22 -175.5(2) . . . . ?
O25 C7 P7 O23 69.7(3) . . . . ?
O25 C7 P7 O24 -51.0(3) . . . . ?
O25 C7 P8 O26 49.4(3) . . . . ?
O25 C7 P8 O27 -69.3(3) . . . . ?
O25 C7 P8 O28 176.3(2) . . . . ?
O29 C9 P9 O30 -29.9(3) . . . . ?
O29 C9 P9 O31 -148.1(2) . . . . ?
O29 C9 P9 O32 90.9(3) . . . . ?
O29 C9 P10 O34 -179.8(2) . . . . ?
O29 C9 P10 O35 -63.5(3) . . . . ?
O29 C9 P10 O36 50.4(3) . . . . ?
P1 C1 P2 O5 -74.24(18) . . . . ?
P1 C1 P2 O6 171.53(15) . . . . ?
P1 C1 P2 O7 50.42(19) . . . . ?
P2 C1 P1 O1 -75.16(19) . . . . ?
P2 C1 P1 O2 165.07(15) . . . . ?
P2 C1 P1 O3 44.3(2) . . . . ?
P3 C3 P4 O12 -64.2(2) . . . . ?
P3 C3 P4 O13 175.94(16) . . . . ?
P3 C3 P4 O14 62.7(2) . . . . ?
P4 C3 P3 O8 -61.9(2) . . . . ?
P4 C3 P3 O9 179.23(16) . . . . ?
P4 C3 P3 O10 62.5(2) . . . . ?
P5 C5 P6 O15 25.9(2) . . . . ?
P5 C5 P6 O16 -94.96(19) . . . . ?
P5 C5 P6 O17 150.28(16) . . . . ?
P6 C5 P5 O19 171.44(16) . . . . ?
P6 C5 P5 O20 -73.1(2) . . . . ?
P6 C5 P5 O21 53.5(2) . . . . ?
P7 C7 P8 O26 -69.1(2) . . . . ?
P7 C7 P8 O27 172.17(15) . . . . ?
P7 C7 P8 O28 57.8(2) . . . . ?
P8 C7 P7 O22 -57.5(2) . . . . ?
P8 C7 P7 O23 -172.31(15) . . . . ?
P8 C7 P7 O24 67.0(2) . . . . ?
P9 C9 P10 O34 -58.8(2) . . . . ?
P9 C9 P10 O35 57.6(2) . . . . ?
P9 C9 P10 O36 171.38(19) . . . . ?
P10 C9 P9 O30 -148.54(18) . . . . ?
P10 C9 P9 O31 93.3(2) . . . . ?
P10 C9 P9 O32 -27.7(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Laa
_database_code_depnum_ccdc_archive 'CCDC 2206528'
loop_
_audit_author_name
_audit_author_address
XuFei
;Qingdao University
China
;
_audit_update_record             
;
2024-05-14 deposited with the CCDC.	2024-10-02 downloaded from the CCDC.
;
_audit_creation_date             2024-05-14
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C34 H57 La2 Li N8 O38 P10'
_chemical_formula_sum            'C34 H57 La2 Li N8 O38 P10'
_chemical_formula_weight         1780.28
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1985(2)
_cell_length_b                   16.4328(3)
_cell_length_c                   16.9643(4)
_cell_angle_alpha                68.463(2)
_cell_angle_beta                 69.625(2)
_cell_angle_gamma                79.152(2)
_cell_volume                     2958.14(12)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    22808
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.6900
_cell_measurement_theta_min      1.9620
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.806
_exptl_absorpt_correction_T_max  0.965
_exptl_absorpt_correction_T_min  0.897
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.110a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.992
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       stick
_exptl_crystal_F_000             1764
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0453
_diffrn_reflns_av_unetI/netI     0.0359
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            44686
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.010
_diffrn_reflns_theta_max         25.010
_diffrn_reflns_theta_min         1.883
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9218
_reflns_number_total             10438
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.680
_refine_diff_density_min         -0.784
_refine_diff_density_rms         0.108
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     843
_refine_ls_number_reflns         10438
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0387
_refine_ls_R_factor_gt           0.0334
_refine_ls_restrained_S_all      1.118
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0334P)²+7.1813P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0838
_refine_ls_wR_factor_ref         0.0859
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C12(H12A), C14(H14), C17(H17), C18(H18A), C20(H20A), N4(H4A), C22(H22),
 C24(H24), C26(H26), C28(H28), C29(H29A), C30(H30), C31(H31), C32(H32A),
 C33(H33), C34(H34), C19A(H19A), C16C(H16C), N2(H2D), C4(H4B), N6(H6), N8(H8)
2.b Tetrahedral OH refined with riding coordinates:
 O2(H2), O4(H4), O5(H5), O9(H9), O11(H11), O12(H12), O16(H16), O18(H18),
 O20(H20), O23(H23), O25(H25), O27(H27), O29(H29), O32(H32)
2.c Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C1AA(H1AA,H1AB,H1AC), C2AA(H2AA,H2AB,H2AC), C0AA(H0AA,H0AB,
 H0AC), C10B(H10A,H10B,H10C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1037(3) 0.3365(3) 0.9034(3) 0.0177(8) Uani 1 1 d . . . . .
C2 C 0.1949(4) 0.3237(3) 0.8204(3) 0.0275(10) Uani 1 1 d . . . . .
H2A H 0.245334 0.272373 0.837028 0.041 Uiso 1 1 calc GR . . . .
H2B H 0.240561 0.374049 0.788760 0.041 Uiso 1 1 calc GR . . . .
H2C H 0.156364 0.316701 0.782880 0.041 Uiso 1 1 calc GR . . . .
C3 C 0.2668(4) 0.6526(3) 0.6105(3) 0.0210(9) Uani 1 1 d . . . . .
C1AA C 0.3220(4) 0.6865(4) 0.5103(3) 0.0327(11) Uani 1 1 d . . . . .
H1AA H 0.378497 0.642712 0.491621 0.049 Uiso 1 1 calc GR . . . .
H1AB H 0.360188 0.738886 0.494038 0.049 Uiso 1 1 calc GR . . . .
H1AC H 0.262240 0.699295 0.481829 0.049 Uiso 1 1 calc GR . . . .
C5 C 0.3766(4) 0.7486(3) 0.8787(3) 0.0231(9) Uani 1 1 d . . . . .
C2AA C 0.4487(4) 0.8049(3) 0.8936(4) 0.0362(12) Uani 1 1 d . . . . .
H2AA H 0.522925 0.774171 0.897081 0.054 Uiso 1 1 calc GR . . . .
H2AB H 0.407269 0.816920 0.948170 0.054 Uiso 1 1 calc GR . . . .
H2AC H 0.461308 0.859147 0.844972 0.054 Uiso 1 1 calc GR . . . .
C7 C 0.7295(4) 0.9642(3) 0.5822(3) 0.0199(9) Uani 1 1 d . . . . .
C0AA C 0.7639(4) 0.8952(3) 0.6604(3) 0.0334(11) Uani 1 1 d . . . . .
H0AA H 0.838312 0.866093 0.638736 0.050 Uiso 1 1 calc GR . . . .
H0AB H 0.705529 0.852996 0.692213 0.050 Uiso 1 1 calc GR . . . .
H0AC H 0.769365 0.923007 0.699633 0.050 Uiso 1 1 calc GR . . . .
C9 C 0.6710(4) 0.3315(3) 0.7474(3) 0.0254(10) Uani 1 1 d . . . . .
C11 C 0.0522(4) 0.4728(3) 0.4830(3) 0.0266(10) Uani 1 1 d . . . . .
C12 C 0.0774(4) 0.4587(3) 0.4018(3) 0.0283(10) Uani 1 1 d . . . . .
H12A H 0.027527 0.484038 0.367066 0.034 Uiso 1 1 calc R . . . .
C13 C 0.1759(4) 0.4073(3) 0.3729(3) 0.0258(10) Uani 1 1 d . . . . .
C14 C 0.2540(4) 0.3693(3) 0.4201(3) 0.0262(10) Uani 1 1 d . . . . .
H14 H 0.320131 0.335157 0.399618 0.031 Uiso 1 1 calc R . . . .
C15 C 0.2296(4) 0.3844(3) 0.4997(3) 0.0254(9) Uani 1 1 d . . . . .
C17 C 0.1298(4) 0.3697(3) 0.2612(3) 0.0304(11) Uani 1 1 d . . . . .
H17 H 0.055383 0.351065 0.295869 0.037 Uiso 1 1 calc R . . . .
C18 C 0.2883(5) 0.4061(4) 0.1478(4) 0.0475(14) Uani 1 1 d . . . . .
H18A H 0.341527 0.415085 0.091153 0.057 Uiso 1 1 calc R . . . .
C20 C 0.3560(4) 0.2619(3) 0.5709(3) 0.0291(10) Uani 1 1 d . . . . .
H20A H 0.349690 0.219853 0.548217 0.035 Uiso 1 1 calc R . . . .
N4 N 0.4152(4) 0.2519(3) 0.6281(3) 0.0487(12) Uani 1 1 d . . . . .
H4A H 0.454512 0.205150 0.650691 0.058 Uiso 1 1 calc R . . . .
C22 C 0.3372(4) 0.3859(3) 0.5976(3) 0.0297(10) Uani 1 1 d . . . . .
H22 H 0.316151 0.443718 0.596323 0.036 Uiso 1 1 calc R . . . .
C23 C 0.5618(4) 0.9849(3) -0.0001(3) 0.0257(10) Uani 1 1 d . . . . .
C24 C 0.6483(4) 0.9720(3) -0.0755(3) 0.0286(10) Uani 1 1 d . . . . .
H24 H 0.628371 0.980053 -0.126145 0.034 Uiso 1 1 calc R . . . .
C25 C 0.7615(4) 0.9477(3) -0.0748(3) 0.0266(10) Uani 1 1 d . . . . .
C26 C 0.7963(4) 0.9346(3) -0.0016(3) 0.0296(10) Uani 1 1 d . . . . .
H26 H 0.874299 0.919971 -0.003099 0.036 Uiso 1 1 calc R . . . .
C27 C 0.7111(4) 0.9440(3) 0.0740(3) 0.0262(10) Uani 1 1 d . . . . .
C28 C 0.5947(4) 0.9672(3) 0.0759(3) 0.0296(10) Uani 1 1 d . . . . .
H28 H 0.538249 0.970857 0.128290 0.036 Uiso 1 1 calc R . . . .
C29 C 0.9045(6) 0.8574(3) -0.1549(3) 0.0487(15) Uani 1 1 d . . . . .
H29A H 0.882233 0.803686 -0.111880 0.058 Uiso 1 1 calc R . . . .
C30 C 0.9976(5) 0.9549(4) -0.2742(4) 0.0464(14) Uani 1 1 d . . . . .
H30 H 1.051779 0.980550 -0.328827 0.056 Uiso 1 1 calc R . . . .
C31 C 0.9104(5) 0.9968(3) -0.2270(3) 0.0426(13) Uani 1 1 d . . . . .
H31 H 0.892699 1.057074 -0.242536 0.051 Uiso 1 1 calc R . . . .
C32 C 0.8438(5) 0.8789(3) 0.1710(4) 0.0384(12) Uani 1 1 d . . . . .
H32A H 0.898639 0.847138 0.137537 0.046 Uiso 1 1 calc R . . . .
C33 C 0.8444(5) 0.8855(3) 0.2471(4) 0.0399(12) Uani 1 1 d . . . . .
H33 H 0.899385 0.858291 0.277065 0.048 Uiso 1 1 calc R . . . .
C34 C 0.6910(4) 0.9650(3) 0.2147(3) 0.0297(10) Uani 1 1 d . . . . .
H34 H 0.623127 1.002263 0.217460 0.036 Uiso 1 1 calc R . . . .
C19A C 0.3020(4) 0.4238(4) 0.2151(4) 0.0478(15) Uani 1 1 d . . . . .
H19A H 0.365643 0.448255 0.213945 0.057 Uiso 1 1 calc R . . . .
C10B C 0.7046(5) 0.3954(3) 0.6520(3) 0.0393(12) Uani 1 1 d . . . . .
H10A H 0.690117 0.454525 0.653041 0.059 Uiso 1 1 calc GR . . . .
H10B H 0.658542 0.386933 0.620190 0.059 Uiso 1 1 calc GR . . . .
H10C H 0.786245 0.384769 0.622884 0.059 Uiso 1 1 calc GR . . . .
C16C C 0.1312(4) 0.4345(3) 0.5313(3) 0.0287(10) Uani 1 1 d . . . . .
H16C H 0.117624 0.442665 0.585442 0.034 Uiso 1 1 calc R . . . .
La1 La 0.12762(2) 0.59492(2) 0.88464(2) 0.01554(7) Uani 1 1 d . . . . .
La2 La 0.40614(2) 0.86303(2) 0.62015(2) 0.01728(7) Uani 1 1 d . . . . .
Li1 Li 0.3758(6) 0.4973(5) 0.8705(5) 0.0275(16) Uani 1 1 d . . . . .
N1 N 0.2019(3) 0.3980(2) 0.2867(2) 0.0240(8) Uani 1 1 d . . . . .
N2 N 0.1814(3) 0.3723(3) 0.1784(3) 0.0318(9) Uani 1 1 d . . . . .
H2D H 0.152350 0.355419 0.147941 0.038 Uiso 1 1 calc R . . . .
N3 N 0.3068(3) 0.3462(2) 0.5528(2) 0.0241(8) Uani 1 1 d . . . . .
C4 C 0.4013(3) 0.3294(3) 0.6435(3) 0.0168(8) Uani 1 1 d . . . . .
H4B H 0.432823 0.340359 0.680961 0.020 Uiso 1 1 calc R . . . .
N5 N 0.8522(3) 0.9347(2) -0.1519(2) 0.0259(8) Uani 1 1 d . . . . .
N6 N 0.9924(4) 0.8686(3) -0.2277(3) 0.0407(11) Uani 1 1 d . . . . .
H6 H 1.039477 0.827442 -0.243687 0.049 Uiso 1 1 calc R . . . .
N7 N 0.7452(3) 0.9288(2) 0.1517(2) 0.0276(8) Uani 1 1 d . . . . .
N8 N 0.7497(4) 0.9393(3) 0.2726(3) 0.0336(9) Uani 1 1 d . . . . .
H8 H 0.731116 0.954184 0.319496 0.040 Uiso 1 1 calc R . . . .
O1 O 0.0818(3) 0.50903(19) 0.80216(19) 0.0236(6) Uani 1 1 d . . . . .
O2 O -0.0769(3) 0.4139(2) 0.8337(2) 0.0260(7) Uani 1 1 d . . . . .
H2 H -0.114027 0.372273 0.870847 0.039 Uiso 1 1 calc R . . . .
O3 O -0.0555(3) 0.45991(19) 0.95501(19) 0.0244(6) Uani 1 1 d . . . . .
O4 O 0.0379(3) 0.25917(19) 0.9493(2) 0.0254(7) Uani 1 1 d . . . . .
H4 H -0.011897 0.264404 0.994704 0.038 Uiso 1 1 calc R . . . .
O5 O 0.2707(3) 0.27597(19) 0.9909(2) 0.0259(7) Uani 1 1 d . . . . .
H5 H 0.317318 0.274957 0.942815 0.039 Uiso 1 1 calc R . . . .
O6 O 0.0842(2) 0.34271(18) 1.06588(18) 0.0181(6) Uani 1 1 d . . . . .
O7 O 0.2276(2) 0.44035(18) 0.92764(18) 0.0189(6) Uani 1 1 d . . . . .
O8 O 0.3224(2) 0.5902(2) 0.76586(19) 0.0240(6) Uani 1 1 d . . . . .
O9 O 0.4667(3) 0.5552(2) 0.6329(2) 0.0299(7) Uani 1 1 d . . . . .
H9 H 0.432555 0.510634 0.648964 0.045 Uiso 1 1 calc R . . . .
O10 O 0.4425(2) 0.70824(19) 0.6363(2) 0.0255(7) Uani 1 1 d . . . . .
O11 O 0.2099(3) 0.5743(2) 0.6314(2) 0.0322(7) Uani 1 1 d . . . . .
H11 H 0.179259 0.554355 0.685309 0.048 Uiso 1 1 calc R . . . .
O12 O 0.0628(2) 0.7512(2) 0.59720(19) 0.0262(7) Uani 1 1 d . . . . .
H12 H 0.093520 0.765113 0.543152 0.039 Uiso 1 1 calc R . . . .
O13 O 0.0972(2) 0.70415(18) 0.74244(18) 0.0206(6) Uani 1 1 d . . . . .
O14 O 0.2187(2) 0.82206(18) 0.61248(19) 0.0228(6) Uani 1 1 d . . . . .
O15 O 0.3146(3) 0.58467(19) 0.9315(2) 0.0240(6) Uani 1 1 d . . . . .
O16 O 0.4645(3) 0.6062(2) 0.9903(2) 0.0307(7) Uani 1 1 d . . . . .
H16 H 0.488680 0.642172 1.002220 0.046 Uiso 1 1 calc R . . . .
O17 O 0.2562(3) 0.6623(2) 1.04910(19) 0.0253(7) Uani 1 1 d . . . . .
O18 O 0.4448(3) 0.7331(2) 0.7956(2) 0.0340(8) Uani 1 1 d . . . . .
H18 H 0.408970 0.702855 0.784943 0.051 Uiso 1 1 calc R . . . .
O19 O 0.1481(2) 0.73894(19) 0.89184(19) 0.0225(6) Uani 1 1 d . . . . .
O20 O 0.1922(3) 0.8718(2) 0.9148(2) 0.0299(7) Uani 1 1 d . . . . .
H20 H 0.175681 0.844225 0.968159 0.045 Uiso 1 1 calc R . . . .
O21 O 0.2648(3) 0.8607(2) 0.76397(19) 0.0268(7) Uani 1 1 d . . . . .
O22 O 0.6208(2) 0.85611(19) 0.5485(2) 0.0244(7) Uani 1 1 d . . . . .
O23 O 0.8329(3) 0.8532(2) 0.4828(2) 0.0335(8) Uani 1 1 d . . . . .
H23 H 0.890507 0.882302 0.458121 0.050 Uiso 1 1 calc R . . . .
O24 O 0.7116(3) 0.98973(19) 0.4210(2) 0.0279(7) Uani 1 1 d . . . . .
O25 O 0.8209(3) 1.0258(2) 0.5352(2) 0.0267(7) Uani 1 1 d . . . . .
H25 H 0.804163 1.063807 0.492853 0.040 Uiso 1 1 calc R . . . .
O26 O 0.5757(3) 1.1000(2) 0.5389(2) 0.0272(7) Uani 1 1 d . . . . .
O27 O 0.5954(3) 1.0541(2) 0.6946(2) 0.0295(7) Uani 1 1 d . . . . .
H27 H 0.652514 1.083035 0.675975 0.044 Uiso 1 1 calc R . . . .
O28 O 0.4944(3) 0.9598(2) 0.6605(2) 0.0263(7) Uani 1 1 d . . . . .
O29 O 0.6592(3) 0.1634(2) 0.8498(2) 0.0444(9) Uani 1 1 d . . . . .
H29 H 0.703037 0.172931 0.872231 0.067 Uiso 1 1 calc R . . . .
O30 O 0.6165(3) 0.2007(2) 0.7042(2) 0.0393(8) Uani 1 1 d . . . . .
O31 O 0.8242(3) 0.1970(2) 0.7071(2) 0.0376(8) Uani 1 1 d . . . . .
O32 O 0.7513(3) 0.3408(3) 0.7872(3) 0.0441(9) Uani 1 1 d . . . . .
H32 H 0.736549 0.307281 0.838666 0.066 Uiso 1 1 calc R . . . .
O33 O 0.4700(3) 0.2724(2) 0.8798(2) 0.0308(7) Uani 1 1 d . . . . .
O34 O 0.5190(3) 0.4253(2) 0.8517(2) 0.0290(7) Uani 1 1 d . . . . .
O35 O 0.4529(3) 0.3979(2) 0.7406(2) 0.0303(7) Uani 1 1 d . . . . .
P1 P 0.00838(9) 0.43562(7) 0.87199(7) 0.0168(2) Uani 1 1 d . . . . .
P2 P 0.17570(9) 0.35258(7) 0.97529(7) 0.0158(2) Uani 1 1 d . . . . .
P3 P 0.15935(9) 0.73833(7) 0.64368(7) 0.0168(2) Uani 1 1 d . . . . .
P4 P 0.37947(9) 0.62669(7) 0.66630(7) 0.0178(2) Uani 1 1 d . . . . .
P5 P 0.23634(9) 0.80634(7) 0.86084(7) 0.0181(2) Uani 1 1 d . . . . .
P6 P 0.34625(9) 0.64353(7) 0.96976(7) 0.0192(2) Uani 1 1 d . . . . .
P7 P 0.71946(9) 0.91501(7) 0.50398(7) 0.0183(2) Uani 1 1 d . . . . .
P8 P 0.58824(9) 1.02438(7) 0.61893(7) 0.0188(2) Uani 1 1 d . . . . .
P9 P 0.51815(9) 0.35791(7) 0.80950(7) 0.0216(2) Uani 1 1 d . . . . .
P10 P 0.69570(11) 0.21784(8) 0.74566(8) 0.0272(3) Uani 1 1 d . . . . .
O36 O 0.0701(3) 0.8594(2) 0.4347(2) 0.0323(7) Uani 1 1 d . . . . .
O37 O 0.1410(4) 0.8416(3) 0.0846(3) 0.0584(11) Uani 1 1 d . . . . .
O38 O 0.0071(4) 0.7152(4) 0.2724(5) 0.100(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.518(6) . ?
C1 O4 1.446(5) . ?
C1 P1 1.835(4) . ?
C1 P2 1.843(4) . ?
C3 C1AA 1.517(6) . ?
C3 O11 1.448(5) . ?
C3 P3 1.841(4) . ?
C3 P4 1.832(4) . ?
C5 C2AA 1.526(6) . ?
C5 O18 1.453(5) . ?
C5 P5 1.859(4) . ?
C5 P6 1.841(4) . ?
C7 C0AA 1.526(6) . ?
C7 O25 1.455(5) . ?
C7 P7 1.834(4) . ?
C7 P8 1.844(4) . ?
C9 C10B 1.531(7) . ?
C9 O32 1.425(5) . ?
C9 P9 1.853(4) . ?
C9 P10 1.845(5) . ?
C11 C11 1.480(9) 2_566 ?
C11 C12 1.399(6) . ?
C11 C16C 1.393(6) . ?
C12 C13 1.382(6) . ?
C13 C14 1.370(6) . ?
C13 N1 1.444(5) . ?
C14 C15 1.382(6) . ?
C15 C16C 1.381(6) . ?
C15 N3 1.430(6) . ?
C17 N1 1.322(6) . ?
C17 N2 1.311(6) . ?
C18 C19A 1.347(8) . ?
C18 N2 1.366(7) . ?
C20 N4 1.349(6) . ?
C20 N3 1.371(6) . ?
N4 C4 1.360(6) . ?
C22 N3 1.339(6) . ?
C22 C4 1.304(6) . ?
C23 C23 1.496(9) 2_675 ?
C23 C24 1.403(6) . ?
C23 C28 1.395(6) . ?
C24 C25 1.366(6) . ?
C25 C26 1.381(7) . ?
C25 N5 1.445(6) . ?
C26 C27 1.381(6) . ?
C27 C28 1.391(6) . ?
C27 N7 1.439(6) . ?
C29 N5 1.321(6) . ?
C29 N6 1.302(7) . ?
C30 C31 1.334(7) . ?
C30 N6 1.348(7) . ?
C31 N5 1.362(6) . ?
C32 C33 1.337(7) . ?
C32 N7 1.390(6) . ?
C33 N8 1.361(6) . ?
C34 N7 1.328(6) . ?
C34 N8 1.314(6) . ?
C19A N1 1.389(6) . ?
La1 O1 2.560(3) . ?
La1 O3 2.412(3) 2_567 ?
La1 O6 2.560(3) 2_567 ?
La1 O7 2.562(3) . ?
La1 O8 2.534(3) . ?
La1 O13 2.524(3) . ?
La1 O15 2.623(3) . ?
La1 O19 2.477(3) . ?
La2 O10 2.427(3) . ?
La2 O14 2.559(3) . ?
La2 O21 2.440(3) . ?
La2 O22 2.473(3) . ?
La2 O24 2.560(3) 2_676 ?
La2 O26 2.476(3) 2_676 ?
La2 O28 2.473(3) . ?
Li1 O7 1.957(8) . ?
Li1 O8 2.085(8) . ?
Li1 O15 1.960(8) . ?
Li1 O34 1.914(8) . ?
O1 P1 1.510(3) . ?
O2 P1 1.553(3) . ?
O3 P1 1.511(3) . ?
O5 P2 1.555(3) . ?
O6 P2 1.525(3) . ?
O7 P2 1.505(3) . ?
O8 P4 1.514(3) . ?
O9 P4 1.560(3) . ?
O10 P4 1.503(3) . ?
O12 P3 1.576(3) . ?
O13 P3 1.511(3) . ?
O14 P3 1.507(3) . ?
O15 P6 1.510(3) . ?
O16 P6 1.562(3) . ?
O17 P6 1.504(3) . ?
O19 P5 1.512(3) . ?
O20 P5 1.563(3) . ?
O21 P5 1.504(3) . ?
O22 P7 1.492(3) . ?
O23 P7 1.572(3) . ?
O24 P7 1.510(3) . ?
O26 P8 1.498(3) . ?
O27 P8 1.565(3) . ?
O28 P8 1.510(3) . ?
O29 P10 1.600(4) . ?
O30 P10 1.493(3) . ?
O31 P10 1.501(3) . ?
O33 P9 1.528(3) . ?
O34 P9 1.527(3) . ?
O35 P9 1.522(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 P1 109.6(3) . . ?
C2 C1 P2 110.2(3) . . ?
O4 C1 C2 107.6(3) . . ?
O4 C1 P1 111.5(3) . . ?
O4 C1 P2 110.6(3) . . ?
P1 C1 P2 107.4(2) . . ?
C1AA C3 P3 108.2(3) . . ?
C1AA C3 P4 110.3(3) . . ?
O11 C3 C1AA 107.3(3) . . ?
O11 C3 P3 110.9(3) . . ?
O11 C3 P4 110.1(3) . . ?
P4 C3 P3 110.1(2) . . ?
C2AA C5 P5 112.9(3) . . ?
C2AA C5 P6 112.5(3) . . ?
O18 C5 C2AA 106.2(4) . . ?
O18 C5 P5 105.4(3) . . ?
O18 C5 P6 110.1(3) . . ?
P6 C5 P5 109.4(2) . . ?
C0AA C7 P7 111.5(3) . . ?
C0AA C7 P8 112.0(3) . . ?
O25 C7 C0AA 107.7(3) . . ?
O25 C7 P7 108.1(3) . . ?
O25 C7 P8 109.1(3) . . ?
P7 C7 P8 108.5(2) . . ?
C10B C9 P9 110.6(3) . . ?
C10B C9 P10 109.6(3) . . ?
O32 C9 C10B 106.3(4) . . ?
O32 C9 P9 110.8(3) . . ?
O32 C9 P10 106.5(3) . . ?
P10 C9 P9 112.7(2) . . ?
C12 C11 C11 122.6(5) . 2_566 ?
C16C C11 C11 120.2(5) . 2_566 ?
C16C C11 C12 117.2(4) . . ?
C13 C12 C11 120.4(4) . . ?
C12 C13 N1 118.6(4) . . ?
C14 C13 C12 122.7(4) . . ?
C14 C13 N1 118.5(4) . . ?
C13 C14 C15 116.7(4) . . ?
C14 C15 N3 119.7(4) . . ?
C16C C15 C14 122.3(4) . . ?
C16C C15 N3 118.0(4) . . ?
N2 C17 N1 108.2(4) . . ?
C19A C18 N2 107.1(5) . . ?
N4 C20 N3 106.3(4) . . ?
C20 N4 C4 107.4(4) . . ?
C4 C22 N3 108.1(4) . . ?
C24 C23 C23 121.6(5) . 2_675 ?
C28 C23 C23 120.8(5) . 2_675 ?
C28 C23 C24 117.6(4) . . ?
C25 C24 C23 120.3(4) . . ?
C24 C25 C26 122.5(4) . . ?
C24 C25 N5 121.3(4) . . ?
C26 C25 N5 116.2(4) . . ?
C27 C26 C25 117.5(4) . . ?
C26 C27 C28 121.2(4) . . ?
C26 C27 N7 118.4(4) . . ?
C28 C27 N7 120.4(4) . . ?
C27 C28 C23 120.6(4) . . ?
N6 C29 N5 109.0(5) . . ?
C31 C30 N6 107.1(5) . . ?
C30 C31 N5 107.2(5) . . ?
C33 C32 N7 106.7(4) . . ?
C32 C33 N8 107.3(5) . . ?
N8 C34 N7 108.3(4) . . ?
C18 C19A N1 106.0(5) . . ?
C15 C16C C11 120.7(4) . . ?
O1 La1 O6 94.06(9) . 2_567 ?
O1 La1 O7 72.10(9) . . ?
O1 La1 O15 130.14(9) . . ?
O3 La1 O1 116.57(10) 2_567 . ?
O3 La1 O6 71.67(9) 2_567 2_567 ?
O3 La1 O7 75.30(9) 2_567 . ?
O3 La1 O8 136.51(10) 2_567 . ?
O3 La1 O13 147.06(9) 2_567 . ?
O3 La1 O15 76.89(10) 2_567 . ?
O3 La1 O19 89.35(10) 2_567 . ?
O6 La1 O7 133.07(9) 2_567 . ?
O6 La1 O15 134.14(9) 2_567 . ?
O7 La1 O15 65.47(9) . . ?
O8 La1 O1 78.49(9) . . ?
O8 La1 O6 151.24(9) . 2_567 ?
O8 La1 O7 71.35(9) . . ?
O8 La1 O15 64.32(9) . . ?
O13 La1 O1 72.56(9) . . ?
O13 La1 O6 76.25(9) . 2_567 ?
O13 La1 O7 134.96(9) . . ?
O13 La1 O8 75.01(9) . . ?
O13 La1 O15 123.24(9) . . ?
O19 La1 O1 148.23(9) . . ?
O19 La1 O6 76.16(9) . 2_567 ?
O19 La1 O7 135.91(9) . . ?
O19 La1 O8 95.56(10) . . ?
O19 La1 O13 75.76(9) . . ?
O19 La1 O15 70.89(9) . . ?
O10 La2 O14 75.86(9) . . ?
O10 La2 O21 102.13(10) . . ?
O10 La2 O22 80.03(10) . . ?
O10 La2 O24 151.16(10) . 2_676 ?
O10 La2 O26 90.55(10) . 2_676 ?
O10 La2 O28 132.24(10) . . ?
O14 La2 O24 76.19(10) . 2_676 ?
O21 La2 O14 76.85(10) . . ?
O21 La2 O22 139.49(10) . . ?
O21 La2 O24 78.16(10) . 2_676 ?
O21 La2 O26 142.57(10) . 2_676 ?
O21 La2 O28 79.03(10) . . ?
O22 La2 O14 140.42(9) . . ?
O22 La2 O24 118.72(10) . 2_676 ?
O22 La2 O26 77.03(10) . 2_676 ?
O26 La2 O14 72.35(10) 2_676 . ?
O26 La2 O24 74.30(9) 2_676 2_676 ?
O28 La2 O14 146.57(10) . . ?
O28 La2 O22 70.96(9) . . ?
O28 La2 O24 76.47(10) . 2_676 ?
O28 La2 O26 117.58(10) . 2_676 ?
O7 Li1 O8 94.6(3) . . ?
O7 Li1 O15 91.4(3) . . ?
O15 Li1 O8 85.5(3) . . ?
O34 Li1 O7 118.5(4) . . ?
O34 Li1 O8 122.5(4) . . ?
O34 Li1 O15 133.8(4) . . ?
C17 N1 C13 125.1(4) . . ?
C17 N1 C19A 108.9(4) . . ?
C19A N1 C13 125.8(4) . . ?
C17 N2 C18 109.7(4) . . ?
C20 N3 C15 126.1(4) . . ?
C22 N3 C15 125.2(4) . . ?
C22 N3 C20 108.6(4) . . ?
C22 C4 N4 109.6(4) . . ?
C29 N5 C25 123.6(4) . . ?
C29 N5 C31 107.7(4) . . ?
C31 N5 C25 128.1(4) . . ?
C29 N6 C30 109.0(4) . . ?
C32 N7 C27 126.5(4) . . ?
C34 N7 C27 125.3(4) . . ?
C34 N7 C32 108.1(4) . . ?
C34 N8 C33 109.6(4) . . ?
P1 O1 La1 106.88(15) . . ?
P1 O3 La1 145.05(18) . 2_567 ?
P2 O6 La1 133.58(15) . 2_567 ?
Li1 O7 La1 86.3(2) . . ?
P2 O7 La1 130.31(15) . . ?
P2 O7 Li1 143.4(3) . . ?
Li1 O8 La1 84.4(2) . . ?
P4 O8 La1 141.17(17) . . ?
P4 O8 Li1 134.2(3) . . ?
P4 O10 La2 141.59(17) . . ?
P3 O13 La1 141.01(16) . . ?
P3 O14 La2 135.35(16) . . ?
Li1 O15 La1 84.5(2) . . ?
P6 O15 La1 129.14(16) . . ?
P6 O15 Li1 144.9(3) . . ?
P5 O19 La1 141.95(17) . . ?
P5 O21 La2 140.49(19) . . ?
P7 O22 La2 139.67(17) . . ?
P7 O24 La2 138.11(18) . 2_676 ?
P8 O26 La2 142.03(18) . 2_676 ?
P8 O28 La2 139.94(17) . . ?
P9 O34 Li1 113.4(3) . . ?
O1 P1 C1 109.70(18) . . ?
O1 P1 O2 109.79(17) . . ?
O1 P1 O3 110.10(17) . . ?
O2 P1 C1 107.81(18) . . ?
O3 P1 C1 107.15(17) . . ?
O3 P1 O2 112.20(17) . . ?
O5 P2 C1 108.14(18) . . ?
O6 P2 C1 107.40(17) . . ?
O6 P2 O5 106.22(16) . . ?
O7 P2 C1 106.97(17) . . ?
O7 P2 O5 112.24(16) . . ?
O7 P2 O6 115.58(16) . . ?
O12 P3 C3 105.93(18) . . ?
O13 P3 C3 109.32(18) . . ?
O13 P3 O12 105.58(16) . . ?
O14 P3 C3 109.74(18) . . ?
O14 P3 O12 110.78(16) . . ?
O14 P3 O13 115.05(17) . . ?
O8 P4 C3 109.03(18) . . ?
O8 P4 O9 109.85(17) . . ?
O9 P4 C3 106.17(19) . . ?
O10 P4 C3 107.85(18) . . ?
O10 P4 O8 114.42(18) . . ?
O10 P4 O9 109.18(18) . . ?
O19 P5 C5 108.69(18) . . ?
O19 P5 O20 110.86(17) . . ?
O20 P5 C5 108.72(19) . . ?
O21 P5 C5 106.54(19) . . ?
O21 P5 O19 114.98(17) . . ?
O21 P5 O20 106.83(18) . . ?
O15 P6 C5 105.47(18) . . ?
O15 P6 O16 108.74(18) . . ?
O16 P6 C5 106.17(19) . . ?
O17 P6 C5 107.83(19) . . ?
O17 P6 O15 117.62(17) . . ?
O17 P6 O16 110.33(18) . . ?
O22 P7 C7 109.31(18) . . ?
O22 P7 O23 105.22(17) . . ?
O22 P7 O24 116.12(18) . . ?
O23 P7 C7 108.56(19) . . ?
O24 P7 C7 106.74(18) . . ?
O24 P7 O23 110.73(19) . . ?
O26 P8 C7 106.56(18) . . ?
O26 P8 O27 112.87(18) . . ?
O26 P8 O28 115.78(19) . . ?
O27 P8 C7 106.46(18) . . ?
O28 P8 C7 107.48(18) . . ?
O28 P8 O27 107.20(17) . . ?
O33 P9 C9 107.32(19) . . ?
O34 P9 C9 108.71(18) . . ?
O34 P9 O33 111.67(19) . . ?
O35 P9 C9 106.0(2) . . ?
O35 P9 O33 113.05(19) . . ?
O35 P9 O34 109.82(18) . . ?
O29 P10 C9 101.3(2) . . ?
O30 P10 C9 111.3(2) . . ?
O30 P10 O29 109.8(2) . . ?
O30 P10 O31 116.1(2) . . ?
O31 P10 C9 109.6(2) . . ?
O31 P10 O29 107.5(2) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
