# Supplementary Information (SI) for Journal of Materials Chemistry A.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_SYUCT-111
_database_code_depnum_ccdc_archive 'CCDC 2412395'
loop_
_audit_author_name
_audit_author_address
'ZHOU XUE'
;Shenyang University of Chemical Technology
China
;
_audit_update_record             
;
2024-12-23 deposited with the CCDC.	2025-03-16 downloaded from the CCDC.
;
_audit_creation_date             2024-09-28
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H26 Co2 N4 O8'
_chemical_formula_sum            'C32 H26 Co2 N4 O8'
_chemical_formula_weight         712.43
_chemical_melting_point          ?
_chemical_oxdiff_usercomment     'C H O N Co'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co -2.3653 3.6143 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.9236(2)
_cell_length_b                   15.6606(2)
_cell_length_c                   15.1309(2)
_cell_angle_alpha                90
_cell_angle_beta                 100.4290(10)
_cell_angle_gamma                90
_cell_volume                     3943.95(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9585
_cell_measurement_temperature    298.2(5)
_cell_measurement_theta_max      67.9670
_cell_measurement_theta_min      2.6760
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    6.980
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.31162
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.105a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            blue
_exptl_crystal_colour_primary    blue
_exptl_crystal_density_diffrn    1.200
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1456
_exptl_crystal_size_max          0.005
_exptl_crystal_size_mid          0.003
_exptl_crystal_size_min          0.002
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0374
_diffrn_reflns_av_unetI/netI     0.0407
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            21430
_diffrn_reflns_point_group_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         68.232
_diffrn_reflns_theta_min         2.655
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      298.2(5)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -26.00   0.00   0.50    1.50    --   41.90 -82.00-180.00   52
  2  ω      8.00  66.00   0.50    1.50    --   41.90 -82.00 -30.00  116
  3  ω     17.00  60.00   0.50    1.50    --   41.90  65.00 -30.00   86
  4  ω     42.00  69.00   0.50    1.50    --   41.90 -82.00-180.00   54
  5  ω     11.00  55.00   0.50    1.50    --   41.90 -77.00  90.00   88
  6  ω    -44.00 -14.00   0.50    1.50    --   41.90 -77.00  90.00   60
  7  ω     24.00  67.00   0.50    1.50    --   41.90 -77.00-120.00   86
  8  ω     67.00 131.00   0.50    1.50    --   41.90  65.00 -30.00  128
  9  ω    -46.00  66.00   0.50    1.50    --   41.90 -82.00 150.00  224
 10  ω     17.00  64.00   0.50    1.50    --   41.90  65.00  90.00   94
 11  ω     27.00  91.00   0.50    1.50    --   41.90  77.00-120.00  128
 12  ω    105.00 130.00   0.50    1.50    --   41.90  65.00  90.00   50
 13  ω    -43.00   0.00   0.50    1.50    --   41.90 -77.00-120.00   86
 14  ω    -47.00 -17.00   0.50    1.50    --   41.90 -82.00 -30.00   60
 15  ω      5.00 127.00   0.50    5.98    --   94.40 -42.00 -60.00  244
 16  ω    127.00 184.00   0.50    5.98    --   94.40  68.00-120.00  114
 17  ω     51.00 102.00   0.50    5.98    --   94.40 -82.00 120.00  102
 18  ω      5.00  55.00   0.50    5.98    --   94.40 -82.00 150.00  100
 19  ω     45.00  74.00   0.50    5.98    --   94.40 -82.00-120.00   58
 20  ω      7.00 120.00   0.50    5.98    --   94.40 -82.00-150.00  226
 21  ω     66.00  96.00   0.50    5.98    --   94.40 -82.00-180.00   60
 22  ω     90.00 121.00   0.50    5.98    --   94.40 -82.00-120.00   62
 23  ω      5.00 107.00   0.50    5.98    --   94.40 -50.00-150.00  204
 24  ω     68.00  96.00   0.50    5.98    --   94.40 -82.00 150.00   56
 25  ω      9.00  59.00   0.50    5.98    --   94.40 -77.00-180.00  100
 26  ω     20.00 146.00   0.50    5.98    --   94.40   0.00 -30.00  252
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  
'XtaLAB Pro II AFC12 (RINC): Kappa dual home/near'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0667094000
_diffrn_orient_matrix_UB_12      0.0681780000
_diffrn_orient_matrix_UB_13      -0.0112017000
_diffrn_orient_matrix_UB_21      0.0636173000
_diffrn_orient_matrix_UB_22      0.0697860000
_diffrn_orient_matrix_UB_23      0.0284904000
_diffrn_orient_matrix_UB_31      0.0084203000
_diffrn_orient_matrix_UB_32      0.0124135000
_diffrn_orient_matrix_UB_33      -0.0988998000
_diffrn_oxdiff_digest_frames     
;
0162fcb729a49021e45f56a58008452b4700026d9ba
;
_diffrn_oxdiff_digest_hkl        
;
01284d327fb8b4631e403be2b73deb75a41870
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5836
_reflns_number_total             7071
_reflns_odcompleteness_completeness 98.60
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.105a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.105a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.105a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.473
_refine_diff_density_min         -0.647
_refine_diff_density_rms         0.053
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         7071
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0477
_refine_ls_R_factor_gt           0.0399
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0567P)²+1.7301P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1122
_refine_ls_wR_factor_ref         0.1166
_refine_special_details          ?
_olex2_refinement_description    
;
1.a Secondary CH2 refined with riding coordinates:
 C018(H01D,H01E), C01B(H01G,H01H)
1.b Aromatic/amide H refined with riding coordinates:
 C00F(H00F), C00G(H00G), C00I(H00I), C00K(H00K), C00S(H00S), C00T(H00T),
 C00U(H00U), C00W(H00W), C00X(H00X), C011(H011), C012(H012), C014(H014),
 C015(H015), C017(H017), C019(H019), C01A(H01F)
1.c Idealised Me refined as rotating group:
 C00Y(H00A,H00B,H00C), C016(H01A,H01B,H01C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co01 Co 0.19534(2) 0.50058(2) 0.21079(2) 0.02470(11) Uani 1 1 d . . . . .
Co02 Co 0.36844(2) 1.00394(2) 0.73826(2) 0.02499(11) Uani 1 1 d . . . . .
O003 O 0.21328(10) 0.09978(11) 0.63216(11) 0.0423(4) Uani 1 1 d . . . . .
O004 O 0.23601(11) 0.91965(11) 0.61531(11) 0.0461(4) Uani 1 1 d . . . . .
O005 O 0.34674(10) 0.09956(11) 0.64851(12) 0.0469(4) Uani 1 1 d . . . . .
O006 O 0.22153(10) 0.60015(11) 0.29700(12) 0.0442(4) Uani 1 1 d . . . . .
O007 O 0.35570(10) 0.59539(11) 0.32229(12) 0.0476(4) Uani 1 1 d . . . . .
O008 O 0.19053(12) 0.42086(11) 0.31476(11) 0.0485(4) Uani 1 1 d . . . . .
O009 O 0.36948(11) 0.91759(12) 0.63972(12) 0.0507(5) Uani 1 1 d . . . . .
N00A N 0.48541(12) 1.02559(15) 0.79044(13) 0.0409(5) Uani 1 1 d . . . . .
O00B O 0.32348(12) 0.41965(12) 0.32916(13) 0.0560(5) Uani 1 1 d . . . . .
N00C N 1.07928(11) 0.97066(14) 0.65608(13) 0.0390(5) Uani 1 1 d . . . . .
C00D C 0.29316(14) 0.69540(15) 0.40233(15) 0.0348(5) Uani 1 1 d . . . . .
C00E C 0.26443(15) 0.32940(15) 0.42298(16) 0.0388(5) Uani 1 1 d . . . . .
C00F C 0.19764(14) 0.30662(15) 0.45819(16) 0.0383(5) Uani 1 1 d . . . . .
H00F H 0.148958 0.334213 0.438593 0.046 Uiso 1 1 calc R . . . .
C00G C 0.22331(15) 0.72474(17) 0.42780(17) 0.0441(6) Uani 1 1 d . . . . .
H00G H 0.174006 0.701886 0.401193 0.053 Uiso 1 1 calc R . . . .
C00H C 0.27841(14) 0.12823(14) 0.61590(15) 0.0349(5) Uani 1 1 d . . . . .
C00I C 0.36638(15) 0.73145(17) 0.44152(17) 0.0444(6) Uani 1 1 d . . . . .
H00I H 0.413700 0.712740 0.424759 0.053 Uiso 1 1 calc R . . . .
C00J C 0.30131(15) 0.89220(14) 0.60055(15) 0.0363(5) Uani 1 1 d . . . . .
C00K C 0.20264(14) 0.24322(15) 0.52224(15) 0.0364(5) Uani 1 1 d . . . . .
H00K H 0.157425 0.228801 0.545958 0.044 Uiso 1 1 calc R . . . .
C00L C 0.27446(14) 0.20086(15) 0.55152(15) 0.0366(5) Uani 1 1 d . . . . .
N00M N 0.61039(13) 1.06766(19) 0.81133(19) 0.0683(8) Uani 1 1 d . . . . .
C00N C 0.29930(14) 0.82342(14) 0.53129(15) 0.0348(5) Uani 1 1 d . . . . .
N00O N 0.95049(13) 0.9697(2) 0.60148(16) 0.0598(7) Uani 1 1 d . . . . .
C00P C 0.29028(14) 0.62518(14) 0.33517(15) 0.0352(5) Uani 1 1 d . . . . .
C00Q C 0.54452(14) 1.04869(18) 0.74980(18) 0.0463(6) Uani 1 1 d . . . . .
C00R C 0.25929(16) 0.39487(15) 0.35041(16) 0.0403(6) Uani 1 1 d . . . . .
C00S C 0.22628(15) 0.78756(16) 0.49228(17) 0.0443(6) Uani 1 1 d . . . . .
H00S H 0.179130 0.805947 0.509673 0.053 Uiso 1 1 calc R . . . .
C00T C 0.36874(15) 0.79502(17) 0.50529(17) 0.0442(6) Uani 1 1 d . . . . .
H00T H 0.417820 0.818962 0.531005 0.053 Uiso 1 1 calc R . . . .
C00U C 0.33706(17) 0.2885(2) 0.4543(2) 0.0592(8) Uani 1 1 d . . . . .
H00U H 0.382770 0.304485 0.432282 0.071 Uiso 1 1 calc R . . . .
C00W C 0.77768(15) 1.0387(3) 0.6893(2) 0.0661(9) Uani 1 1 d . . . . .
H00W H 0.779203 1.093737 0.666702 0.079 Uiso 1 1 calc R . . . .
C00X C 1.05800(17) 0.8909(2) 0.6176(2) 0.0567(7) Uani 1 1 d . . . . .
H00X H 1.093233 0.845670 0.615484 0.068 Uiso 1 1 calc R . . . .
C00Y C 1.0074(2) 1.1047(2) 0.6737(2) 0.0676(9) Uani 1 1 d . . . . .
H00A H 1.056881 1.121082 0.711470 0.101 Uiso 1 1 calc GR . . . .
H00B H 0.964063 1.110387 0.706369 0.101 Uiso 1 1 calc GR . . . .
H00C H 0.997583 1.140869 0.621616 0.101 Uiso 1 1 calc GR . . . .
C00Z C 0.73322(17) 1.0237(3) 0.7560(3) 0.0702(9) Uani 1 1 d . . . . .
C010 C 0.82007(17) 0.9747(3) 0.6549(2) 0.0624(8) Uani 1 1 d . . . . .
C011 C 0.98011(18) 0.8895(2) 0.5846(2) 0.0710(10) Uani 1 1 d . . . . .
H011 H 0.950884 0.844016 0.555740 0.085 Uiso 1 1 calc R . . . .
C012 C 0.51470(18) 1.0299(3) 0.8806(2) 0.0767(11) Uani 1 1 d . . . . .
H012 H 0.485688 1.017266 0.925646 0.092 Uiso 1 1 calc R . . . .
C013 C 1.01293(15) 1.01498(18) 0.64525(17) 0.0447(6) Uani 1 1 d . . . . .
C014 C 0.34187(16) 0.2248(2) 0.5175(2) 0.0584(8) Uani 1 1 d . . . . .
H014 H 0.390655 0.197532 0.537541 0.070 Uiso 1 1 calc R . . . .
C015 C 0.8181(2) 0.8933(3) 0.6884(2) 0.0782(10) Uani 1 1 d . . . . .
H015 H 0.846116 0.849542 0.666210 0.094 Uiso 1 1 calc R . . . .
C016 C 0.5407(2) 1.0548(3) 0.6519(2) 0.0762(10) Uani 1 1 d . . . . .
H01A H 0.584866 1.024009 0.635439 0.114 Uiso 1 1 calc GR . . . .
H01B H 0.543630 1.113673 0.635119 0.114 Uiso 1 1 calc GR . . . .
H01C H 0.490998 1.030710 0.621396 0.114 Uiso 1 1 calc GR . . . .
C017 C 0.59140(19) 1.0550(3) 0.8943(2) 0.0983(15) Uani 1 1 d . . . . .
H017 H 0.625221 1.062397 0.949434 0.118 Uiso 1 1 calc R . . . .
C018 C 0.86553(18) 0.9941(3) 0.5802(2) 0.0737(11) Uani 1 1 d . . . . .
H01D H 0.840231 0.964173 0.526391 0.088 Uiso 1 1 calc R . . . .
H01E H 0.861885 1.054850 0.567490 0.088 Uiso 1 1 calc R . . . .
C019 C 0.7325(2) 0.9410(3) 0.7888(3) 0.0842(12) Uani 1 1 d . . . . .
H019 H 0.703473 0.928700 0.833878 0.101 Uiso 1 1 calc R . . . .
C01A C 0.7744(2) 0.8769(3) 0.7553(3) 0.0929(12) Uani 1 1 d . . . . .
H01F H 0.773186 0.821760 0.777959 0.111 Uiso 1 1 calc R . . . .
C01B C 0.68829(19) 1.0947(3) 0.7915(3) 0.0965(14) Uani 1 1 d . . . . .
H01G H 0.720873 1.117159 0.845943 0.116 Uiso 1 1 calc R . . . .
H01H H 0.679727 1.140509 0.747636 0.116 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co01 Co02 2.8841(5) 4_575 ?
Co01 O003 2.0270(16) 4_565 ?
Co01 O004 2.1168(16) 4_575 ?
Co01 O006 2.0299(16) . ?
Co01 O008 2.0216(17) . ?
Co01 N00C 2.0390(19) 4_475 ?
Co02 O005 2.0102(16) 1_565 ?
Co02 O007 2.0449(17) 4_576 ?
Co02 O009 2.0154(17) . ?
Co02 N00A 2.023(2) . ?
Co02 O00B 2.0692(18) 4_576 ?
O003 C00H 1.254(3) . ?
O004 C00J 1.243(3) . ?
O005 C00H 1.255(3) . ?
O006 C00P 1.264(3) . ?
O007 C00P 1.249(3) . ?
O008 C00R 1.258(3) . ?
O009 C00J 1.262(3) . ?
N00A C00Q 1.316(3) . ?
N00A C012 1.367(3) . ?
O00B C00R 1.249(3) . ?
N00C C00X 1.398(3) . ?
N00C C013 1.305(3) . ?
C00D C00G 1.386(3) . ?
C00D C00I 1.393(3) . ?
C00D C00P 1.492(3) . ?
C00E C00F 1.381(3) . ?
C00E C00R 1.493(3) . ?
C00E C00U 1.391(4) . ?
C00F H00F 0.9300 . ?
C00F C00K 1.379(3) . ?
C00G H00G 0.9300 . ?
C00G C00S 1.380(3) . ?
C00H C00L 1.491(3) . ?
C00I H00I 0.9300 . ?
C00I C00T 1.382(3) . ?
C00J C00N 1.499(3) . ?
C00K H00K 0.9300 . ?
C00K C00L 1.385(3) . ?
C00L C014 1.385(3) . ?
N00M C00Q 1.350(3) . ?
N00M C017 1.365(5) . ?
N00M C01B 1.466(4) . ?
C00N C00S 1.388(3) . ?
C00N C00T 1.379(3) . ?
N00O C011 1.392(4) . ?
N00O C013 1.343(4) . ?
N00O C018 1.466(4) . ?
C00Q C016 1.474(4) . ?
C00S H00S 0.9300 . ?
C00T H00T 0.9300 . ?
C00U H00U 0.9300 . ?
C00U C014 1.375(4) . ?
C00W H00W 0.9300 . ?
C00W C00Z 1.383(5) . ?
C00W C010 1.388(5) . ?
C00X H00X 0.9300 . ?
C00X C011 1.323(4) . ?
C00Y H00A 0.9600 . ?
C00Y H00B 0.9600 . ?
C00Y H00C 0.9600 . ?
C00Y C013 1.477(4) . ?
C00Z C019 1.388(6) . ?
C00Z C01B 1.501(5) . ?
C010 C015 1.374(5) . ?
C010 C018 1.509(5) . ?
C011 H011 0.9300 . ?
C012 H012 0.9300 . ?
C012 C017 1.336(5) . ?
C014 H014 0.9300 . ?
C015 H015 0.9300 . ?
C015 C01A 1.382(5) . ?
C016 H01A 0.9600 . ?
C016 H01B 0.9600 . ?
C016 H01C 0.9600 . ?
C017 H017 0.9300 . ?
C018 H01D 0.9700 . ?
C018 H01E 0.9700 . ?
C019 H019 0.9300 . ?
C019 C01A 1.377(6) . ?
C01A H01F 0.9300 . ?
C01B H01G 0.9700 . ?
C01B H01H 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O003 Co01 Co02 79.02(5) 4_565 4_575 ?
O003 Co01 O004 87.44(7) 4_565 4_575 ?
O003 Co01 O006 159.13(7) 4_565 . ?
O003 Co01 N00C 99.71(8) 4_565 4_475 ?
O004 Co01 Co02 70.47(5) 4_575 4_575 ?
O006 Co01 Co02 80.12(5) . 4_575 ?
O006 Co01 O004 85.71(7) . 4_575 ?
O006 Co01 N00C 99.98(8) . 4_475 ?
O008 Co01 Co02 93.19(6) . 4_575 ?
O008 Co01 O003 90.53(7) . 4_565 ?
O008 Co01 O004 163.62(8) . 4_575 ?
O008 Co01 O006 90.53(8) . . ?
O008 Co01 N00C 106.31(8) . 4_475 ?
N00C Co01 Co02 160.49(6) 4_475 4_575 ?
N00C Co01 O004 90.05(8) 4_475 4_575 ?
O005 Co02 Co01 82.21(5) 1_565 4_576 ?
O005 Co02 O007 163.69(7) 1_565 4_576 ?
O005 Co02 O009 91.43(8) 1_565 . ?
O005 Co02 N00A 100.66(8) 1_565 . ?
O005 Co02 O00B 88.51(8) 1_565 4_576 ?
O007 Co02 Co01 81.51(5) 4_576 4_576 ?
O007 Co02 O00B 86.21(8) 4_576 4_576 ?
O009 Co02 Co01 91.24(5) . 4_576 ?
O009 Co02 O007 88.03(8) . 4_576 ?
O009 Co02 N00A 105.20(8) . . ?
O009 Co02 O00B 158.96(8) . 4_576 ?
N00A Co02 Co01 163.16(6) . 4_576 ?
N00A Co02 O007 95.21(8) . 4_576 ?
N00A Co02 O00B 95.47(8) . 4_576 ?
O00B Co02 Co01 67.91(6) 4_576 4_576 ?
C00H O003 Co01 128.39(15) . 4_566 ?
C00J O004 Co01 137.40(16) . 4_576 ?
C00H O005 Co02 125.07(16) . 1_545 ?
C00P O006 Co01 127.42(16) . . ?
C00P O007 Co02 125.27(15) . 4_575 ?
C00R O008 Co01 111.65(16) . . ?
C00J O009 Co02 115.42(16) . . ?
C00Q N00A Co02 129.54(18) . . ?
C00Q N00A C012 106.5(2) . . ?
C012 N00A Co02 123.40(19) . . ?
C00R O00B Co02 142.40(18) . 4_575 ?
C00X N00C Co01 121.55(18) . 4_676 ?
C013 N00C Co01 132.63(19) . 4_676 ?
C013 N00C C00X 105.8(2) . . ?
C00G C00D C00I 119.0(2) . . ?
C00G C00D C00P 120.6(2) . . ?
C00I C00D C00P 120.4(2) . . ?
C00F C00E C00R 121.2(2) . . ?
C00F C00E C00U 119.0(2) . . ?
C00U C00E C00R 119.8(2) . . ?
C00E C00F H00F 119.8 . . ?
C00K C00F C00E 120.4(2) . . ?
C00K C00F H00F 119.8 . . ?
C00D C00G H00G 119.7 . . ?
C00S C00G C00D 120.6(2) . . ?
C00S C00G H00G 119.7 . . ?
O003 C00H O005 125.2(2) . . ?
O003 C00H C00L 117.5(2) . . ?
O005 C00H C00L 117.3(2) . . ?
C00D C00I H00I 120.0 . . ?
C00T C00I C00D 120.0(2) . . ?
C00T C00I H00I 120.0 . . ?
O004 C00J O009 125.0(2) . . ?
O004 C00J C00N 117.8(2) . . ?
O009 C00J C00N 117.3(2) . . ?
C00F C00K H00K 119.7 . . ?
C00F C00K C00L 120.6(2) . . ?
C00L C00K H00K 119.7 . . ?
C00K C00L C00H 120.5(2) . . ?
C00K C00L C014 119.0(2) . . ?
C014 C00L C00H 120.4(2) . . ?
C00Q N00M C017 107.4(2) . . ?
C00Q N00M C01B 125.7(3) . . ?
C017 N00M C01B 126.9(3) . . ?
C00S C00N C00J 119.6(2) . . ?
C00T C00N C00J 121.2(2) . . ?
C00T C00N C00S 119.2(2) . . ?
C011 N00O C018 124.5(3) . . ?
C013 N00O C011 106.8(2) . . ?
C013 N00O C018 128.5(3) . . ?
O006 C00P C00D 117.0(2) . . ?
O007 C00P O006 125.6(2) . . ?
O007 C00P C00D 117.5(2) . . ?
N00A C00Q N00M 109.9(2) . . ?
N00A C00Q C016 126.0(2) . . ?
N00M C00Q C016 124.0(3) . . ?
O008 C00R C00E 117.6(2) . . ?
O00B C00R O008 124.7(2) . . ?
O00B C00R C00E 117.7(2) . . ?
C00G C00S C00N 120.3(2) . . ?
C00G C00S H00S 119.8 . . ?
C00N C00S H00S 119.8 . . ?
C00I C00T H00T 119.6 . . ?
C00N C00T C00I 120.9(2) . . ?
C00N C00T H00T 119.6 . . ?
C00E C00U H00U 119.7 . . ?
C014 C00U C00E 120.6(2) . . ?
C014 C00U H00U 119.7 . . ?
C00Z C00W H00W 118.7 . . ?
C00Z C00W C010 122.5(4) . . ?
C010 C00W H00W 118.7 . . ?
N00C C00X H00X 125.2 . . ?
C011 C00X N00C 109.6(3) . . ?
C011 C00X H00X 125.2 . . ?
H00A C00Y H00B 109.5 . . ?
H00A C00Y H00C 109.5 . . ?
H00B C00Y H00C 109.5 . . ?
C013 C00Y H00A 109.5 . . ?
C013 C00Y H00B 109.5 . . ?
C013 C00Y H00C 109.5 . . ?
C00W C00Z C019 117.4(4) . . ?
C00W C00Z C01B 120.9(4) . . ?
C019 C00Z C01B 121.7(4) . . ?
C00W C010 C018 120.2(4) . . ?
C015 C010 C00W 118.9(3) . . ?
C015 C010 C018 120.9(3) . . ?
N00O C011 H011 126.8 . . ?
C00X C011 N00O 106.5(3) . . ?
C00X C011 H011 126.8 . . ?
N00A C012 H012 125.2 . . ?
C017 C012 N00A 109.6(3) . . ?
C017 C012 H012 125.2 . . ?
N00C C013 N00O 111.3(3) . . ?
N00C C013 C00Y 124.6(3) . . ?
N00O C013 C00Y 124.0(3) . . ?
C00L C014 H014 119.8 . . ?
C00U C014 C00L 120.4(2) . . ?
C00U C014 H014 119.8 . . ?
C010 C015 H015 120.2 . . ?
C010 C015 C01A 119.7(4) . . ?
C01A C015 H015 120.2 . . ?
C00Q C016 H01A 109.5 . . ?
C00Q C016 H01B 109.5 . . ?
C00Q C016 H01C 109.5 . . ?
H01A C016 H01B 109.5 . . ?
H01A C016 H01C 109.5 . . ?
H01B C016 H01C 109.5 . . ?
N00M C017 H017 126.7 . . ?
C012 C017 N00M 106.5(3) . . ?
C012 C017 H017 126.7 . . ?
N00O C018 C010 113.3(2) . . ?
N00O C018 H01D 108.9 . . ?
N00O C018 H01E 108.9 . . ?
C010 C018 H01D 108.9 . . ?
C010 C018 H01E 108.9 . . ?
H01D C018 H01E 107.7 . . ?
C00Z C019 H019 119.7 . . ?
C01A C019 C00Z 120.7(4) . . ?
C01A C019 H019 119.7 . . ?
C015 C01A H01F 119.6 . . ?
C019 C01A C015 120.9(4) . . ?
C019 C01A H01F 119.6 . . ?
N00M C01B C00Z 113.0(3) . . ?
N00M C01B H01G 109.0 . . ?
N00M C01B H01H 109.0 . . ?
C00Z C01B H01G 109.0 . . ?
C00Z C01B H01H 109.0 . . ?
H01G C01B H01H 107.8 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 3.322
_oxdiff_exptl_absorpt_empirical_full_min 0.529
