# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cu_20220531_yhj_gxmz_hb411_0m
_database_code_depnum_ccdc_archive 'CCDC 2285560'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2024-02-21 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2024-01-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'3(C74 H74 N10 Pt2), 2(C H4 O), 2[CH2Cl2], 1[CH3OH]'
_chemical_formula_sum            'C223 H226 N30 O Pt6'
_chemical_formula_weight         4512.86
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   35.0453(7)
_cell_length_b                   13.1591(2)
_cell_length_c                   46.5467(9)
_cell_angle_alpha                90
_cell_angle_beta                 109.6480(10)
_cell_angle_gamma                90
_cell_volume                     20215.9(7)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9992
_cell_measurement_temperature    193.00
_cell_measurement_theta_max      68.18
_cell_measurement_theta_min      3.51
_shelx_estimated_absorpt_T_max   0.446
_shelx_estimated_absorpt_T_min   0.379
_exptl_absorpt_coefficient_mu    8.035
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.6100
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0998 before and 0.0732 after correction.
The Ratio of minimum to maximum transmission is 0.8100.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    1.483
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             9000
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0874
_diffrn_reflns_av_unetI/netI     0.0694
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       41
_diffrn_reflns_limit_h_min       -41
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       55
_diffrn_reflns_limit_l_min       -53
_diffrn_reflns_number            147527
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        66.596
_diffrn_reflns_theta_max         66.596
_diffrn_reflns_theta_min         2.770
_diffrn_ambient_temperature      193.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           1.1
_diffrn_source_power             0.05500000000000001
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                27268
_reflns_number_total             35578
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (1, 2016)'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'SAINT V8.40B (1, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         1.382
_refine_diff_density_min         -1.050
_refine_diff_density_rms         0.136
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2499
_refine_ls_number_reflns         35578
_refine_ls_number_restraints     6186
_refine_ls_R_factor_all          0.0615
_refine_ls_R_factor_gt           0.0426
_refine_ls_restrained_S_all      0.997
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0421P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0943
_refine_ls_wR_factor_ref         0.1013
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Restrained distances
 C1A-C1B \\sim C1A-C1C \\sim C1B-C1C \\sim C162-C163 \\sim C162-C164 \\sim
C163-C164
 with sigma of 0.04
 C1D-C1E \\sim C1D-C1F \\sim C102-C103 \\sim C102-C104 \\sim C103-C104
 with sigma of 0.04
 C87-C88A \\sim C87-C89A \\sim C87-C90A \\sim C87-C88 \\sim C87-C89 \\sim
C87-C90
 with sigma of 0.02
 C161-C1A \\sim C161-C1B \\sim C161-C1C \\sim C161-C162 \\sim C161-C163 \\sim
C161-C164
 with sigma of 0.02
 C101-C1D \\sim C101-C1E \\sim C101-C1F \\sim C101-C102 \\sim C101-C103 \\sim
C101-C104
 with sigma of 0.02
 C88A-C89A \\sim C89A-C90A \\sim C88-C89 \\sim C88-C90 \\sim C89-C90
 with sigma of 0.04
 C111-C112 \\sim C111-C113 \\sim C111-C114 \\sim C111-C223 \\sim C111-C1G \\sim
C111-C1H
 with sigma of 0.02
 C112-C114 \\sim C113-C114 \\sim C223-C1H \\sim C1G-C1H
 with sigma of 0.04
3. Rigid bond restraints
 C225, O1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.002
4. Uiso/Uaniso restraints and constraints
C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6 \\sim C7 \\sim C8 \\sim C9
\\sim C10 \\sim C11 \\sim C12 \\sim C13 \\sim C14 \\sim C15 \\sim C16 \\sim C17
\\sim C18 \\sim C19 \\sim C20 \\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25
\\sim C26 \\sim C27 \\sim C28 \\sim C29 \\sim C30 \\sim C31 \\sim C32 \\sim C33
\\sim C34 \\sim C35 \\sim C36 \\sim C37 \\sim C38 \\sim C39 \\sim C40 \\sim C41
\\sim C42 \\sim C43 \\sim C44 \\sim C45 \\sim C46 \\sim C47 \\sim C48 \\sim C49
\\sim C50 \\sim C51 \\sim C52 \\sim C53 \\sim C54 \\sim C55 \\sim C56 \\sim C57
\\sim C58 \\sim C59 \\sim C60 \\sim C61 \\sim C62 \\sim C63 \\sim C64 \\sim C65
\\sim C66 \\sim C67 \\sim C68 \\sim C69 \\sim C70 \\sim C219 \\sim C220 \\sim
C221 \\sim C222 \\sim C71 \\sim C72 \\sim C73 \\sim C74 \\sim C75 \\sim C76
\\sim C77 \\sim C78 \\sim C79 \\sim C80 \\sim C81 \\sim C82 \\sim C83 \\sim C84
\\sim C85 \\sim C86 \\sim C87 \\sim C91 \\sim C92 \\sim C93 \\sim C94 \\sim C95
\\sim C96 \\sim C97 \\sim C98 \\sim C99 \\sim C100 \\sim C101 \\sim C105 \\sim
C106 \\sim C107 \\sim C108 \\sim C109 \\sim C110 \\sim C111 \\sim C112 \\sim
C113 \\sim C114 \\sim C115 \\sim C116 \\sim C117 \\sim C118 \\sim C119 \\sim
C120 \\sim C121 \\sim C122 \\sim C123 \\sim C124 \\sim C125 \\sim C126 \\sim
C127 \\sim C128 \\sim C129 \\sim C130 \\sim C131 \\sim C132 \\sim C133 \\sim
C134 \\sim C135 \\sim C136 \\sim C137 \\sim C138 \\sim C139 \\sim C140 \\sim
C141 \\sim C142 \\sim C143 \\sim C144 \\sim C1D \\sim C1E \\sim C1F \\sim C88A
\\sim C89A \\sim C90A \\sim C145 \\sim C146 \\sim C147 \\sim C148 \\sim C149
\\sim C150 \\sim C151 \\sim C152 \\sim C153 \\sim C154 \\sim C155 \\sim C156
\\sim C157 \\sim C158 \\sim C159 \\sim C160 \\sim C161 \\sim C165 \\sim C166
\\sim C167 \\sim C168 \\sim C169 \\sim C170 \\sim C171 \\sim C172 \\sim C173
\\sim C174 \\sim C175 \\sim C176 \\sim C177 \\sim C178 \\sim C179 \\sim C180
\\sim C181 \\sim C182 \\sim C183 \\sim C184 \\sim C185 \\sim C186 \\sim C187
\\sim C188 \\sim C189 \\sim C190 \\sim C191 \\sim C192 \\sim C193 \\sim C194
\\sim C195 \\sim C196 \\sim C197 \\sim C198 \\sim C199 \\sim C200 \\sim C201
\\sim C202 \\sim C203 \\sim C204 \\sim C205 \\sim C206 \\sim C207 \\sim C208
\\sim C209 \\sim C210 \\sim C211 \\sim C212 \\sim C213 \\sim C214 \\sim C215
\\sim C216 \\sim C217 \\sim C218 \\sim C1A \\sim C1B \\sim C1C \\sim C88 \\sim
C89 \\sim C90 \\sim C102 \\sim C103 \\sim C104 \\sim C162 \\sim C163 \\sim C164
\\sim C223 \\sim C1G \\sim C1H \\sim C225: within 3.8A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 3.8A
Uanis(O1) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C163) \\sim Ueq, Uanis(C164) \\sim Ueq, Uanis(C89A) \\sim Ueq, Uanis(C89)
\\sim Ueq, Uanis(C223) \\sim Ueq, Uanis(C1G) \\sim Ueq, Uanis(C114) \\sim Ueq,
Uanis(C1C) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C114) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
5. Others
 Sof(C1D)=Sof(H1DA)=Sof(H1DB)=Sof(H1DC)=Sof(C1E)=Sof(H1EA)=Sof(H1EB)=Sof(H1EC)=
 Sof(C1F)=Sof(H1FA)=Sof(H1FB)=Sof(H1FC)=Sof(C88A)=Sof(H88A)=Sof(H88B)=Sof(H88C)=
 Sof(C89A)=Sof(H89A)=Sof(H89B)=Sof(H89C)=Sof(C90A)=Sof(H90A)=Sof(H90B)=
 Sof(H90C)=Sof(C1A)=Sof(H1AA)=Sof(H1AB)=Sof(H1AC)=Sof(C1B)=Sof(H1BA)=Sof(H1BB)=
 Sof(H1BC)=Sof(C1C)=Sof(H1CA)=Sof(H1CB)=Sof(H1CC)=Sof(C223)=Sof(H22A)=Sof(H22B)=
 Sof(H22C)=Sof(C1G)=Sof(H1GA)=Sof(H1GB)=Sof(H1GC)=Sof(C1H)=Sof(H1HA)=Sof(H1HB)=
 Sof(H1HC)=1-FVAR(1)
 Sof(C112)=Sof(H11A)=Sof(H11B)=Sof(H11C)=Sof(C113)=Sof(H11D)=Sof(H11E)=
 Sof(H11F)=Sof(C114)=Sof(H11G)=Sof(H11H)=Sof(H11I)=Sof(C88)=Sof(H88D)=Sof(H88E)=
 Sof(H88F)=Sof(C89)=Sof(H89D)=Sof(H89E)=Sof(H89F)=Sof(C90)=Sof(H90D)=Sof(H90E)=
 Sof(H90F)=Sof(C102)=Sof(H10A)=Sof(H10B)=Sof(H10C)=Sof(C103)=Sof(H10D)=
 Sof(H10E)=Sof(H10F)=Sof(C104)=Sof(H10G)=Sof(H10H)=Sof(H10I)=Sof(C162)=
 Sof(H16A)=Sof(H16B)=Sof(H16C)=Sof(C163)=Sof(H16D)=Sof(H16E)=Sof(H16F)=
 Sof(C164)=Sof(H16G)=Sof(H16H)=Sof(H16I)=FVAR(1)
6.a Riding coordinates:
 O1(H1)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C12(H12), C14(H14), C15(H15), C22(H22), C23(H23), C24(H24),
 C32(H32), C33(H33), C35(H35), C42(H42), C43(H43), C44(H44), C46(H46), C47(H47),
  C48(H48), C49(H49), C50(H50), C51(H51), C53(H53), C54(H54), C55(H55),
 C56(H56), C57(H57), C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C64(H64),
  C66(H66), C67(H67), C68(H68), C69(H69), C70(H70), C220(H220), C222(H222),
 C72(H72), C78(H78), C83(H83), C84(H84), C86(H86), C92(H92), C93(H93), C94(H94),
  C96(H96), C98(H98), C107(H107), C108(H108), C110(H110), C116(H116),
 C117(H117), C118(H118), C120(H120), C121(H121), C122(H122), C123(H123),
 C124(H124), C125(H125), C127(H127), C128(H128), C129(H129), C130(H130),
 C131(H131), C133(H133), C134(H134), C135(H135), C136(H136), C137(H137),
 C138(H138), C140(H140), C141(H141), C142(H142), C143(H143), C144(H144),
 C146(H146), C152(H152), C156(H156), C157(H157), C159(H159), C166(H166),
 C167(H167), C168(H168), C170(H170), C172(H172), C181(H181), C182(H182),
 C184(H184), C190(H190), C191(H191), C192(H192), C194(H194), C195(H195),
 C196(H196), C197(H197), C198(H198), C199(H199), C201(H201), C202(H202),
 C203(H203), C204(H204), C205(H205), C207(H207), C208(H208), C209(H209),
 C210(H210), C211(H211), C212(H212), C214(H214), C215(H215), C216(H216),
 C217(H217), C218(H218)
6.c Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10J,H10K,H10L), C18(H18J,H18K,H18L),
 C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C28(H28A,H28B,H28C), C29(H29A,H29B,
 H29C), C30(H30A,H30B,H30C), C38(H38A,H38B,H38C), C39(H39A,H39B,H39C), C40(H40A,
 H40B,H40C), C75(H75A,H75B,H75C), C76(H76A,H76B,H76C), C77(H77A,H77B,H77C),
 C112(H11A,H11B,H11C), C113(H11D,H11E,H11F), C114(H11G,H11H,H11I), C1D(H1DA,
 H1DB,H1DC), C1E(H1EA,H1EB,H1EC), C1F(H1FA,H1FB,H1FC), C88A(H88A,H88B,H88C),
 C89A(H89A,H89B,H89C), C90A(H90A,H90B,H90C), C149(H14A,H14B,H14C), C150(H15A,
 H15B,H15C), C151(H15D,H15E,H15F), C176(H17A,H17B,H17C), C177(H17D,H17E,H17F),
 C178(H17G,H17H,H17I), C186(H18A,H18B,H18C), C187(H18D,H18E,H18F), C188(H18G,
 H18H,H18I), C1A(H1AA,H1AB,H1AC), C1B(H1BA,H1BB,H1BC), C1C(H1CA,H1CB,H1CC),
 C88(H88D,H88E,H88F), C89(H89D,H89E,H89F), C90(H90D,H90E,H90F), C102(H10A,H10B,
 H10C), C103(H10D,H10E,H10F), C104(H10G,H10H,H10I), C162(H16A,H16B,H16C),
 C163(H16D,H16E,H16F), C164(H16G,H16H,H16I), C223(H22A,H22B,H22C), C1G(H1GA,
 H1GB,H1GC), C1H(H1HA,H1HB,H1HC), C225(H22D,H22E,H22F)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.75217(2) 0.99114(2) 0.36548(2) 0.02218(6) Uani 1 1 d . . . . .
Pt2 Pt 0.74931(2) 0.94834(2) 0.42681(2) 0.02201(6) Uani 1 1 d . . . . .
N1 N 0.77513(16) 0.8556(4) 0.35904(12) 0.0265(12) Uani 1 1 d . . . . .
N2 N 0.83450(16) 0.8709(4) 0.40176(12) 0.0251(12) Uani 1 1 d . . . . .
N3 N 0.81931(17) 0.7148(4) 0.37837(13) 0.0313(13) Uani 1 1 d . . . . .
N4 N 0.80697(15) 0.9674(4) 0.45723(12) 0.0230(11) Uani 1 1 d . . . . .
N5 N 0.86111(18) 0.9246(4) 0.50315(14) 0.0350(14) Uani 1 1 d . . . . .
N6 N 0.81793(16) 0.7990(4) 0.47666(12) 0.0255(12) Uani 1 1 d . . . . .
N7 N 0.73872(16) 1.1091(4) 0.42411(12) 0.0280(12) Uani 1 1 d . . . . .
N8 N 0.72835(15) 1.1249(4) 0.37169(11) 0.0232(11) Uani 1 1 d . . . . .
N9 N 0.68980(15) 0.9366(4) 0.40161(12) 0.0265(12) Uani 1 1 d . . . . .
N10 N 0.69121(16) 0.9349(4) 0.35126(12) 0.0280(12) Uani 1 1 d . . . . .
C1 C 0.8084(2) 1.0447(5) 0.38263(15) 0.0278(12) Uani 1 1 d . U . . .
C2 C 0.8209(2) 1.1458(5) 0.38457(16) 0.0315(12) Uani 1 1 d . U . . .
H2 H 0.801854 1.195246 0.373467 0.038 Uiso 1 1 calc R U . . .
C3 C 0.8600(2) 1.1790(5) 0.40203(16) 0.0321(13) Uani 1 1 d . U . . .
C4 C 0.8880(2) 1.1103(5) 0.41981(16) 0.0326(12) Uani 1 1 d . U . . .
H4 H 0.914129 1.132209 0.432338 0.039 Uiso 1 1 calc R U . . .
C5 C 0.8767(2) 1.0065(5) 0.41889(15) 0.0287(11) Uani 1 1 d . U . . .
C6 C 0.83833(19) 0.9794(5) 0.39927(15) 0.0255(11) Uani 1 1 d . U . . .
C7 C 0.8701(2) 1.2930(6) 0.40188(19) 0.0448(17) Uani 1 1 d . U . . .
C8 C 0.9122(3) 1.3192(7) 0.4239(3) 0.076(3) Uani 1 1 d . U . . .
H8A H 0.913651 1.303069 0.444836 0.114 Uiso 1 1 calc R U . . .
H8B H 0.917399 1.391865 0.422443 0.114 Uiso 1 1 calc R U . . .
H8C H 0.932602 1.279555 0.418693 0.114 Uiso 1 1 calc R U . . .
C9 C 0.8397(3) 1.3565(7) 0.4127(3) 0.077(3) Uani 1 1 d . U . . .
H9A H 0.812687 1.353677 0.397055 0.115 Uiso 1 1 calc R U . . .
H9B H 0.848806 1.427326 0.415824 0.115 Uiso 1 1 calc R U . . .
H9C H 0.838431 1.328469 0.431822 0.115 Uiso 1 1 calc R U . . .
C10 C 0.8648(4) 1.3281(8) 0.3701(2) 0.078(3) Uani 1 1 d . U . . .
H10J H 0.885091 1.295087 0.363039 0.117 Uiso 1 1 calc R U . . .
H10K H 0.868325 1.401955 0.370106 0.117 Uiso 1 1 calc R U . . .
H10L H 0.837605 1.310135 0.356516 0.117 Uiso 1 1 calc R U . . .
C11 C 0.8964(2) 0.9172(5) 0.43561(15) 0.0278(11) Uani 1 1 d . U . . .
C12 C 0.9327(2) 0.9020(6) 0.45977(16) 0.0329(12) Uani 1 1 d . U . . .
H12 H 0.950709 0.957382 0.467195 0.039 Uiso 1 1 calc R U . . .
C13 C 0.9425(2) 0.8065(6) 0.47300(16) 0.0360(14) Uani 1 1 d . U . . .
C14 C 0.9149(2) 0.7273(6) 0.46211(16) 0.0338(13) Uani 1 1 d . U . . .
H14 H 0.921051 0.662161 0.471343 0.041 Uiso 1 1 calc R U . . .
C15 C 0.8787(2) 0.7407(5) 0.43818(15) 0.0288(11) Uani 1 1 d . U . . .
H15 H 0.860365 0.685776 0.431063 0.035 Uiso 1 1 calc R U . . .
C16 C 0.86997(19) 0.8353(5) 0.42503(15) 0.0272(11) Uani 1 1 d . U . . .
C17 C 0.9820(2) 0.7903(6) 0.50038(18) 0.0431(17) Uani 1 1 d . U . . .
C18 C 1.0183(3) 0.8222(8) 0.4911(2) 0.062(2) Uani 1 1 d . U . . .
H18J H 1.019337 0.780030 0.473973 0.093 Uiso 1 1 calc R U . . .
H18K H 1.043416 0.813177 0.508402 0.093 Uiso 1 1 calc R U . . .
H18L H 1.015493 0.893760 0.484868 0.093 Uiso 1 1 calc R U . . .
C19 C 0.9809(3) 0.8523(8) 0.5267(2) 0.068(3) Uani 1 1 d . U . . .
H19A H 0.979909 0.924515 0.521404 0.101 Uiso 1 1 calc R U . . .
H19B H 1.005206 0.838738 0.544308 0.101 Uiso 1 1 calc R U . . .
H19C H 0.956749 0.834485 0.531807 0.101 Uiso 1 1 calc R U . . .
C20 C 0.9877(3) 0.6799(7) 0.5107(2) 0.075(3) Uani 1 1 d . U . . .
H20A H 0.965482 0.659441 0.517767 0.112 Uiso 1 1 calc R U . . .
H20B H 1.013553 0.672501 0.527361 0.112 Uiso 1 1 calc R U . . .
H20C H 0.987737 0.636710 0.493538 0.112 Uiso 1 1 calc R U . . .
C21 C 0.8088(2) 0.8111(5) 0.37941(15) 0.0279(11) Uani 1 1 d . U . . .
C22 C 0.7970(2) 0.6585(6) 0.35507(17) 0.0359(15) Uani 1 1 d . U . . .
H22 H 0.803537 0.588705 0.354302 0.043 Uiso 1 1 calc R U . . .
C23 C 0.7646(2) 0.6985(6) 0.33204(17) 0.0345(15) Uani 1 1 d . U . . .
H23 H 0.749791 0.659161 0.314780 0.041 Uiso 1 1 calc R U . . .
C24 C 0.7550(2) 0.7969(5) 0.33517(16) 0.0310(13) Uani 1 1 d . U . . .
H24 H 0.732701 0.825840 0.319549 0.037 Uiso 1 1 calc R U . . .
C25 C 0.7933(2) 0.6465(5) 0.45419(15) 0.0304(12) Uani 1 1 d . U . . .
C26 C 0.7878(2) 0.7519(5) 0.45141(15) 0.0277(11) Uani 1 1 d . U . . .
C27 C 0.7054(3) 0.5534(6) 0.38670(19) 0.0485(18) Uani 1 1 d . U . . .
C28 C 0.6798(3) 0.6025(7) 0.3584(2) 0.064(2) Uani 1 1 d . U . . .
H28A H 0.696754 0.644979 0.350208 0.097 Uiso 1 1 calc R U . . .
H28B H 0.659415 0.644949 0.362689 0.097 Uiso 1 1 calc R U . . .
H28C H 0.666310 0.550375 0.343379 0.097 Uiso 1 1 calc R U . . .
C29 C 0.7295(3) 0.4712(7) 0.3727(2) 0.066(2) Uani 1 1 d . U . . .
H29A H 0.710182 0.421858 0.359947 0.100 Uiso 1 1 calc R U . . .
H29B H 0.749823 0.435550 0.389399 0.100 Uiso 1 1 calc R U . . .
H29C H 0.742955 0.506913 0.360250 0.100 Uiso 1 1 calc R U . . .
C30 C 0.6836(3) 0.4901(8) 0.4016(2) 0.069(2) Uani 1 1 d . U . . .
H30A H 0.663164 0.531164 0.406355 0.104 Uiso 1 1 calc R U . . .
H30B H 0.702649 0.462085 0.420448 0.104 Uiso 1 1 calc R U . . .
H30C H 0.670195 0.434397 0.387916 0.104 Uiso 1 1 calc R U . . .
C31 C 0.8407(2) 0.7209(5) 0.49545(15) 0.0300(12) Uani 1 1 d . U . . .
C32 C 0.8714(2) 0.7226(6) 0.52427(16) 0.0372(14) Uani 1 1 d . U . . .
H32 H 0.880746 0.785002 0.534502 0.045 Uiso 1 1 calc R U . . .
C33 C 0.8873(2) 0.6322(6) 0.53700(19) 0.0461(16) Uani 1 1 d . U . . .
H33 H 0.908278 0.633663 0.556283 0.055 Uiso 1 1 calc R U . . .
C34 C 0.8748(2) 0.5372(6) 0.52351(18) 0.0395(14) Uani 1 1 d . U . . .
C35 C 0.8440(2) 0.5348(6) 0.49550(17) 0.0365(13) Uani 1 1 d . U . . .
H35 H 0.834664 0.471922 0.485642 0.044 Uiso 1 1 calc R U . . .
C36 C 0.8270(2) 0.6267(5) 0.48190(15) 0.0303(12) Uani 1 1 d . U . . .
C37 C 0.8953(3) 0.4408(6) 0.5396(2) 0.0526(19) Uani 1 1 d . U . . .
C38 C 0.9395(3) 0.4441(8) 0.5456(3) 0.090(3) Uani 1 1 d . U . . .
H38A H 0.944599 0.447592 0.526158 0.134 Uiso 1 1 calc R U . . .
H38B H 0.952054 0.382628 0.556625 0.134 Uiso 1 1 calc R U . . .
H38C H 0.951002 0.504094 0.557884 0.134 Uiso 1 1 calc R U . . .
C39 C 0.8882(4) 0.4328(8) 0.5701(3) 0.091(3) Uani 1 1 d . U . . .
H39A H 0.899282 0.493194 0.582396 0.136 Uiso 1 1 calc R U . . .
H39B H 0.901819 0.371979 0.580911 0.136 Uiso 1 1 calc R U . . .
H39C H 0.859105 0.428145 0.566543 0.136 Uiso 1 1 calc R U . . .
C40 C 0.8786(3) 0.3432(7) 0.5219(2) 0.069(3) Uani 1 1 d . U . . .
H40A H 0.850260 0.334139 0.520473 0.103 Uiso 1 1 calc R U . . .
H40B H 0.894603 0.285034 0.532559 0.103 Uiso 1 1 calc R U . . .
H40C H 0.880256 0.348083 0.501343 0.103 Uiso 1 1 calc R U . . .
C41 C 0.82843(19) 0.8988(5) 0.47902(15) 0.0273(11) Uani 1 1 d . U . . .
C42 C 0.8748(2) 1.0186(6) 0.50396(17) 0.0361(15) Uani 1 1 d . U . . .
H42 H 0.897560 1.037863 0.520970 0.043 Uiso 1 1 calc R U . . .
C43 C 0.8582(2) 1.0905(6) 0.48174(16) 0.0330(14) Uani 1 1 d . U . . .
H43 H 0.869782 1.156099 0.482286 0.040 Uiso 1 1 calc R U . . .
C44 C 0.8237(2) 1.0609(5) 0.45871(16) 0.0304(12) Uani 1 1 d . U . . .
H44 H 0.810978 1.108372 0.443044 0.037 Uiso 1 1 calc R U . . .
C45 C 0.7414(2) 1.1667(6) 0.45071(16) 0.0330(13) Uani 1 1 d . U . . .
C46 C 0.7312(2) 1.1198(6) 0.47379(16) 0.0381(14) Uani 1 1 d . U . . .
H46 H 0.722811 1.050730 0.471812 0.046 Uiso 1 1 calc R U . . .
C47 C 0.7335(2) 1.1752(6) 0.50022(17) 0.0431(16) Uani 1 1 d . U . . .
H47 H 0.726754 1.142996 0.516164 0.052 Uiso 1 1 calc R U . . .
C48 C 0.7454(2) 1.2765(6) 0.50318(18) 0.0457(16) Uani 1 1 d . U . . .
H48 H 0.746310 1.314089 0.520830 0.055 Uiso 1 1 calc R U . . .
C49 C 0.7559(2) 1.3217(7) 0.48029(18) 0.0455(17) Uani 1 1 d . U . . .
H49 H 0.764265 1.390799 0.482142 0.055 Uiso 1 1 calc R U . . .
C50 C 0.7543(2) 1.2663(6) 0.45423(17) 0.0367(14) Uani 1 1 d . U . . .
H50 H 0.762126 1.297850 0.438729 0.044 Uiso 1 1 calc R U . . .
C51 C 0.72720(19) 1.1590(5) 0.39806(15) 0.0271(12) Uani 1 1 d . U . . .
H51 H 0.717118 1.225933 0.398269 0.032 Uiso 1 1 calc R U . . .
C52 C 0.7075(2) 1.1832(5) 0.34503(15) 0.0289(13) Uani 1 1 d . U . . .
C53 C 0.7248(2) 1.1950(5) 0.32226(16) 0.0333(13) Uani 1 1 d . U . . .
H53 H 0.750770 1.167125 0.325035 0.040 Uiso 1 1 calc R U . . .
C54 C 0.7045(2) 1.2464(6) 0.29590(17) 0.0392(15) Uani 1 1 d . U . . .
H54 H 0.716350 1.252659 0.280363 0.047 Uiso 1 1 calc R U . . .
C55 C 0.6667(2) 1.2896(6) 0.29180(18) 0.0432(16) Uani 1 1 d . U . . .
H55 H 0.653128 1.327286 0.273861 0.052 Uiso 1 1 calc R U . . .
C56 C 0.6490(2) 1.2770(6) 0.31403(18) 0.0429(16) Uani 1 1 d . U . . .
H56 H 0.622803 1.303911 0.311066 0.051 Uiso 1 1 calc R U . . .
C57 C 0.6695(2) 1.2253(5) 0.34054(16) 0.0338(14) Uani 1 1 d . U . . .
H57 H 0.657497 1.218315 0.355945 0.041 Uiso 1 1 calc R U . . .
C58 C 0.6673(2) 0.9102(5) 0.32073(15) 0.0289(13) Uani 1 1 d . U . . .
C59 C 0.6745(2) 0.9595(6) 0.29640(16) 0.0346(13) Uani 1 1 d . U . . .
H59 H 0.694640 1.010739 0.300312 0.042 Uiso 1 1 calc R U . . .
C60 C 0.6523(2) 0.9337(6) 0.26675(17) 0.0409(15) Uani 1 1 d . U . . .
H60 H 0.657873 0.967429 0.250570 0.049 Uiso 1 1 calc R U . . .
C61 C 0.6225(2) 0.8615(6) 0.25978(17) 0.0417(16) Uani 1 1 d . U . . .
H61 H 0.607566 0.845018 0.239185 0.050 Uiso 1 1 calc R U . . .
C62 C 0.6148(2) 0.8133(6) 0.28358(17) 0.0407(16) Uani 1 1 d . U . . .
H62 H 0.594019 0.763545 0.279222 0.049 Uiso 1 1 calc R U . . .
C63 C 0.6371(2) 0.8360(5) 0.31402(16) 0.0332(14) Uani 1 1 d . U . . .
H63 H 0.631586 0.801014 0.330066 0.040 Uiso 1 1 calc R U . . .
C64 C 0.67290(19) 0.9319(5) 0.37167(14) 0.0257(12) Uani 1 1 d . U . . .
H64 H 0.644226 0.925760 0.364002 0.031 Uiso 1 1 calc R U . . .
C65 C 0.6631(2) 0.9455(6) 0.41877(16) 0.0361(13) Uani 1 1 d . U . . .
C66 C 0.6379(2) 1.0298(7) 0.41485(18) 0.0432(15) Uani 1 1 d . U . . .
H66 H 0.638767 1.081873 0.400930 0.052 Uiso 1 1 calc R U . . .
C67 C 0.6112(3) 1.0378(7) 0.4316(2) 0.0532(17) Uani 1 1 d . U . . .
H67 H 0.594096 1.095419 0.429232 0.064 Uiso 1 1 calc R U . . .
C68 C 0.6101(3) 0.9613(8) 0.4515(2) 0.0529(17) Uani 1 1 d . U . . .
H68 H 0.591909 0.966188 0.462639 0.063 Uiso 1 1 calc R U . . .
C69 C 0.6353(3) 0.8770(8) 0.4555(2) 0.0542(17) Uani 1 1 d . U . . .
H69 H 0.634096 0.824208 0.469051 0.065 Uiso 1 1 calc R U . . .
C70 C 0.6622(2) 0.8707(7) 0.43949(18) 0.0441(15) Uani 1 1 d . U . . .
H70 H 0.680189 0.814507 0.442768 0.053 Uiso 1 1 calc R U . . .
C219 C 0.75697(19) 0.7994(5) 0.42827(14) 0.0260(11) Uani 1 1 d . U . . .
C220 C 0.7320(2) 0.7299(5) 0.40737(16) 0.0325(13) Uani 1 1 d . U . . .
H220 H 0.710621 0.757434 0.390731 0.039 Uiso 1 1 calc R U . . .
C221 C 0.7357(2) 0.6231(5) 0.40876(16) 0.0344(14) Uani 1 1 d . U . . .
C222 C 0.7673(2) 0.5827(6) 0.43272(16) 0.0343(13) Uani 1 1 d . U . . .
H222 H 0.771236 0.511163 0.434401 0.041 Uiso 1 1 calc R U . . .
Pt3 Pt 0.47320(2) 0.35054(2) 0.32650(2) 0.02029(6) Uani 1 1 d . . . . .
Pt4 Pt 0.49200(2) 0.40908(2) 0.39116(2) 0.02135(6) Uani 1 1 d . . . . .
N11 N 0.44508(15) 0.4815(4) 0.30720(12) 0.0244(12) Uani 1 1 d . . . . .
N12 N 0.39809(18) 0.6151(4) 0.30353(14) 0.0345(14) Uani 1 1 d . . . . .
N13 N 0.39383(15) 0.4669(4) 0.32940(12) 0.0245(12) Uani 1 1 d . . . . .
N14 N 0.43976(16) 0.3907(4) 0.40123(12) 0.0224(11) Uani 1 1 d . . . . .
N15 N 0.3916(2) 0.4353(5) 0.42469(17) 0.0460(18) Uani 1 1 d . . . . .
N16 N 0.43306(17) 0.5585(4) 0.41669(13) 0.0282(12) Uani 1 1 d . . . . .
N17 N 0.50502(16) 0.2512(4) 0.39629(12) 0.0270(12) Uani 1 1 d . . . . .
N18 N 0.50287(15) 0.2226(4) 0.34551(12) 0.0237(11) Uani 1 1 d . . . . .
N19 N 0.54776(15) 0.4230(4) 0.38655(12) 0.0250(12) Uani 1 1 d . . . . .
N20 N 0.53167(15) 0.4117(4) 0.33307(11) 0.0234(11) Uani 1 1 d . . . . .
C71 C 0.41965(19) 0.2931(5) 0.32408(15) 0.0255(11) Uani 1 1 d . U . . .
C72 C 0.4092(2) 0.1900(5) 0.32432(15) 0.0273(12) Uani 1 1 d . U . . .
H72 H 0.427560 0.140242 0.322005 0.033 Uiso 1 1 calc R U . . .
C73 C 0.3728(2) 0.1567(5) 0.32780(16) 0.0284(12) Uani 1 1 d . U . . .
C74 C 0.3668(2) 0.0419(5) 0.33026(17) 0.0336(14) Uani 1 1 d . U . . .
C75 C 0.3748(2) -0.0176(6) 0.30478(19) 0.0433(17) Uani 1 1 d . U . . .
H75A H 0.357080 0.007655 0.284982 0.065 Uiso 1 1 calc R U . . .
H75B H 0.369368 -0.089816 0.306716 0.065 Uiso 1 1 calc R U . . .
H75C H 0.403182 -0.008721 0.306245 0.065 Uiso 1 1 calc R U . . .
C76 C 0.3976(3) 0.0042(6) 0.36056(19) 0.0458(18) Uani 1 1 d . U . . .
H76A H 0.424971 0.024551 0.361698 0.069 Uiso 1 1 calc R U . . .
H76B H 0.396217 -0.070064 0.361553 0.069 Uiso 1 1 calc R U . . .
H76C H 0.391207 0.034084 0.377679 0.069 Uiso 1 1 calc R U . . .
C77 C 0.3241(2) 0.0140(6) 0.3294(2) 0.052(2) Uani 1 1 d . U . . .
H77A H 0.319397 0.041735 0.347479 0.078 Uiso 1 1 calc R U . . .
H77B H 0.321266 -0.060121 0.329214 0.078 Uiso 1 1 calc R U . . .
H77C H 0.304177 0.042513 0.310984 0.078 Uiso 1 1 calc R U . . .
C78 C 0.3456(2) 0.2279(5) 0.33195(16) 0.0282(11) Uani 1 1 d . U . . .
H78 H 0.321164 0.206617 0.334705 0.034 Uiso 1 1 calc R U . . .
C79 C 0.3551(2) 0.3313(5) 0.33196(16) 0.0282(11) Uani 1 1 d . U . . .
C80 C 0.39057(19) 0.3595(5) 0.32708(15) 0.0260(11) Uani 1 1 d . U . . .
C81 C 0.3373(2) 0.4233(5) 0.33985(17) 0.0311(11) Uani 1 1 d . U . . .
C82 C 0.3620(2) 0.5038(5) 0.33802(16) 0.0295(12) Uani 1 1 d . U . . .
C83 C 0.3560(2) 0.6012(5) 0.34781(17) 0.0332(12) Uani 1 1 d . U . . .
H83 H 0.373756 0.655512 0.347605 0.040 Uiso 1 1 calc R U . . .
C84 C 0.3237(2) 0.6157(6) 0.35773(18) 0.0375(13) Uani 1 1 d . U . . .
H84 H 0.319212 0.681442 0.364423 0.045 Uiso 1 1 calc R U . . .
C85 C 0.2968(2) 0.5360(6) 0.35831(18) 0.0360(13) Uani 1 1 d . U . . .
C86 C 0.3042(2) 0.4403(5) 0.34974(17) 0.0330(12) Uani 1 1 d . U . . .
H86 H 0.286944 0.385520 0.350516 0.040 Uiso 1 1 calc R U . . .
C87 C 0.2611(2) 0.5568(5) 0.36979(18) 0.0465(16) Uani 1 1 d D U . . .
C91 C 0.4132(2) 0.5224(5) 0.31291(15) 0.0275(12) Uani 1 1 d . U . . .
C92 C 0.4131(2) 0.6662(5) 0.28533(18) 0.0366(15) Uani 1 1 d . U . . .
H92 H 0.403075 0.732187 0.278603 0.044 Uiso 1 1 calc R U . . .
C93 C 0.4432(2) 0.6254(6) 0.27597(18) 0.0383(15) Uani 1 1 d . U . . .
H93 H 0.452870 0.660304 0.261943 0.046 Uiso 1 1 calc R U . . .
C94 C 0.4583(2) 0.5345(5) 0.28733(16) 0.0307(13) Uani 1 1 d . U . . .
H94 H 0.479173 0.505929 0.281164 0.037 Uiso 1 1 calc R U . . .
C95 C 0.4825(2) 0.5566(5) 0.38775(15) 0.0289(11) Uani 1 1 d . U . . .
C96 C 0.5017(2) 0.6252(5) 0.37333(16) 0.0283(12) Uani 1 1 d . U . . .
H96 H 0.518635 0.597357 0.363134 0.034 Uiso 1 1 calc R U . . .
C97 C 0.4973(2) 0.7330(5) 0.37309(16) 0.0314(13) Uani 1 1 d . U . . .
C98 C 0.4724(2) 0.7746(5) 0.38774(16) 0.0319(12) Uani 1 1 d . U . . .
H98 H 0.469211 0.846176 0.388278 0.038 Uiso 1 1 calc R U . . .
C99 C 0.4519(2) 0.7106(5) 0.40172(16) 0.0292(12) Uani 1 1 d . U . . .
C100 C 0.4571(2) 0.6053(5) 0.40086(16) 0.0278(11) Uani 1 1 d . U . . .
C101 C 0.5214(2) 0.8006(5) 0.35849(16) 0.0374(14) Uani 1 1 d D U . . .
C105 C 0.4248(2) 0.7315(5) 0.41865(16) 0.0313(12) Uani 1 1 d . U . . .
C106 C 0.4138(2) 0.6379(5) 0.42778(17) 0.0323(12) Uani 1 1 d . U . . .
C107 C 0.3888(2) 0.6338(6) 0.44556(17) 0.0368(13) Uani 1 1 d . U . . .
H107 H 0.382330 0.571010 0.452886 0.044 Uiso 1 1 calc R U . . .
C108 C 0.3740(2) 0.7246(6) 0.45206(18) 0.0394(14) Uani 1 1 d . U . . .
H108 H 0.356741 0.722430 0.464015 0.047 Uiso 1 1 calc R U . . .
C109 C 0.3826(2) 0.8207(6) 0.44224(18) 0.0388(14) Uani 1 1 d . U . . .
C110 C 0.4093(2) 0.8207(6) 0.42590(17) 0.0357(13) Uani 1 1 d . U . . .
H110 H 0.417163 0.883618 0.419577 0.043 Uiso 1 1 calc R U . . .
C111 C 0.3612(2) 0.9147(6) 0.44728(17) 0.0456(16) Uani 1 1 d D U . . .
C112 C 0.3154(4) 0.9067(12) 0.4282(3) 0.053(3) Uani 0.571(5) 1 d D U P A 1
H11A H 0.312107 0.903778 0.406464 0.080 Uiso 0.571(5) 1 calc R U P A 1
H11B H 0.301099 0.966255 0.432123 0.080 Uiso 0.571(5) 1 calc R U P A 1
H11C H 0.304133 0.844942 0.433999 0.080 Uiso 0.571(5) 1 calc R U P A 1
C113 C 0.3777(5) 1.0134(10) 0.4403(4) 0.055(3) Uani 0.571(5) 1 d D U P A 1
H11D H 0.406621 1.018253 0.452213 0.082 Uiso 0.571(5) 1 calc R U P A 1
H11E H 0.363193 1.070183 0.445491 0.082 Uiso 0.571(5) 1 calc R U P A 1
H11F H 0.374163 1.016183 0.418461 0.082 Uiso 0.571(5) 1 calc R U P A 1
C114 C 0.3634(5) 0.9166(11) 0.4812(3) 0.044(3) Uani 0.571(5) 1 d D U P A 1
H11G H 0.349458 0.856874 0.485383 0.065 Uiso 0.571(5) 1 calc R U P A 1
H11H H 0.350377 0.978450 0.485047 0.065 Uiso 0.571(5) 1 calc R U P A 1
H11I H 0.391853 0.915584 0.494412 0.065 Uiso 0.571(5) 1 calc R U P A 1
C115 C 0.4214(2) 0.4575(5) 0.41409(16) 0.0301(12) Uani 1 1 d . U . . .
C116 C 0.3778(2) 0.3406(6) 0.42157(19) 0.0417(15) Uani 1 1 d . U . . .
H116 H 0.357099 0.323152 0.429587 0.050 Uiso 1 1 calc R U . . .
C117 C 0.3925(2) 0.2668(6) 0.40718(17) 0.0347(14) Uani 1 1 d . U . . .
H117 H 0.381833 0.199703 0.404415 0.042 Uiso 1 1 calc R U . . .
C118 C 0.4234(2) 0.2952(5) 0.39703(15) 0.0284(11) Uani 1 1 d . U . . .
H118 H 0.433852 0.246453 0.386606 0.034 Uiso 1 1 calc R U . . .
C119 C 0.5480(2) 0.4273(5) 0.30927(15) 0.0285(12) Uani 1 1 d . U . . .
C120 C 0.5348(2) 0.3676(5) 0.28317(15) 0.0301(12) Uani 1 1 d . U . . .
H120 H 0.515037 0.316317 0.281361 0.036 Uiso 1 1 calc R U . . .
C121 C 0.5503(2) 0.3827(6) 0.25974(17) 0.0376(14) Uani 1 1 d . U . . .
H121 H 0.541056 0.341349 0.241997 0.045 Uiso 1 1 calc R U . . .
C122 C 0.5790(2) 0.4568(6) 0.26179(17) 0.0366(14) Uani 1 1 d . U . . .
H122 H 0.589726 0.466016 0.245716 0.044 Uiso 1 1 calc R U . . .
C123 C 0.5920(2) 0.5171(6) 0.28736(17) 0.0375(15) Uani 1 1 d . U . . .
H123 H 0.611577 0.568471 0.288788 0.045 Uiso 1 1 calc R U . . .
C124 C 0.5767(2) 0.5040(6) 0.31146(17) 0.0334(13) Uani 1 1 d . U . . .
H124 H 0.585658 0.546479 0.328968 0.040 Uiso 1 1 calc R U . . .
C125 C 0.5571(2) 0.4220(5) 0.36117(15) 0.0277(12) Uani 1 1 d . U . . .
H125 H 0.584923 0.429363 0.363485 0.033 Uiso 1 1 calc R U . . .
C126 C 0.5805(2) 0.4183(6) 0.41466(16) 0.0329(13) Uani 1 1 d . U . . .
C127 C 0.5843(2) 0.4930(7) 0.43674(19) 0.0468(15) Uani 1 1 d . U . . .
H127 H 0.565773 0.548126 0.433046 0.056 Uiso 1 1 calc R U . . .
C128 C 0.6160(3) 0.4843(8) 0.4643(2) 0.0576(19) Uani 1 1 d . U . . .
H128 H 0.618072 0.533344 0.479749 0.069 Uiso 1 1 calc R U . . .
C129 C 0.6439(3) 0.4101(7) 0.47027(19) 0.0516(17) Uani 1 1 d . U . . .
H129 H 0.665795 0.408952 0.489074 0.062 Uiso 1 1 calc R U . . .
C130 C 0.6404(3) 0.3348(7) 0.4485(2) 0.0521(17) Uani 1 1 d . U . . .
H130 H 0.659207 0.280303 0.452533 0.063 Uiso 1 1 calc R U . . .
C131 C 0.6082(2) 0.3409(6) 0.42028(17) 0.0407(15) Uani 1 1 d . U . . .
H131 H 0.605872 0.290804 0.405087 0.049 Uiso 1 1 calc R U . . .
C132 C 0.5203(2) 0.1610(5) 0.32809(15) 0.0271(12) Uani 1 1 d . U . . .
C133 C 0.4967(2) 0.1317(5) 0.29891(16) 0.0320(13) Uani 1 1 d . U . . .
H133 H 0.468997 0.151388 0.290904 0.038 Uiso 1 1 calc R U . . .
C134 C 0.5138(2) 0.0731(6) 0.28133(18) 0.0390(15) Uani 1 1 d . U . . .
H134 H 0.497893 0.053250 0.261254 0.047 Uiso 1 1 calc R U . . .
C135 C 0.5546(2) 0.0436(6) 0.29335(17) 0.0378(14) Uani 1 1 d . U . . .
H135 H 0.566259 0.001965 0.281807 0.045 Uiso 1 1 calc R U . . .
C136 C 0.5775(2) 0.0758(6) 0.32203(17) 0.0377(14) Uani 1 1 d . U . . .
H136 H 0.605225 0.057194 0.330215 0.045 Uiso 1 1 calc R U . . .
C137 C 0.5607(2) 0.1346(5) 0.33903(17) 0.0332(13) Uani 1 1 d . U . . .
H137 H 0.577181 0.157508 0.358631 0.040 Uiso 1 1 calc R U . . .
C138 C 0.51174(19) 0.1957(5) 0.37470(15) 0.0258(12) Uani 1 1 d . U . . .
H138 H 0.523939 0.131022 0.380521 0.031 Uiso 1 1 calc R U . . .
C139 C 0.5108(2) 0.2002(5) 0.42437(15) 0.0294(12) Uani 1 1 d . U . . .
C140 C 0.5277(2) 0.2536(6) 0.45197(17) 0.0382(13) Uani 1 1 d . U . . .
H140 H 0.535637 0.322533 0.451725 0.046 Uiso 1 1 calc R U . . .
C141 C 0.5327(3) 0.2058(7) 0.47929(18) 0.0452(16) Uani 1 1 d . U . . .
H141 H 0.544443 0.242121 0.497813 0.054 Uiso 1 1 calc R U . . .
C142 C 0.5213(3) 0.1081(7) 0.48027(18) 0.0468(16) Uani 1 1 d . U . . .
H142 H 0.524958 0.076698 0.499379 0.056 Uiso 1 1 calc R U . . .
C143 C 0.5044(2) 0.0537(6) 0.45358(17) 0.0403(15) Uani 1 1 d . U . . .
H143 H 0.496556 -0.015057 0.454311 0.048 Uiso 1 1 calc R U . . .
C144 C 0.4989(2) 0.1004(6) 0.42566(17) 0.0349(13) Uani 1 1 d . U . . .
H144 H 0.486840 0.063492 0.407295 0.042 Uiso 1 1 calc R U . . .
C1D C 0.5675(4) 0.7709(13) 0.3753(4) 0.044(3) Uani 0.429(5) 1 d D U P A 2
H1DA H 0.576237 0.795939 0.396374 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1DB H 0.584343 0.801699 0.364568 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1DC H 0.570442 0.696840 0.375406 0.066 Uiso 0.429(5) 1 calc R U P A 2
C1E C 0.5199(6) 0.9123(10) 0.3658(5) 0.044(3) Uani 0.429(5) 1 d D U P A 2
H1EA H 0.491773 0.936157 0.357909 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1EB H 0.536308 0.951061 0.356256 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1EC H 0.530589 0.922060 0.387951 0.066 Uiso 0.429(5) 1 calc R U P A 2
C1F C 0.5144(6) 0.7732(15) 0.3259(3) 0.049(3) Uani 0.429(5) 1 d D U P A 2
H1FA H 0.525224 0.705155 0.324874 0.073 Uiso 0.429(5) 1 calc R U P A 2
H1FB H 0.528036 0.822639 0.316928 0.073 Uiso 0.429(5) 1 calc R U P A 2
H1FC H 0.485216 0.773856 0.314457 0.073 Uiso 0.429(5) 1 calc R U P A 2
C88A C 0.2765(6) 0.6018(17) 0.4025(3) 0.059(3) Uani 0.429(5) 1 d D U P A 2
H88A H 0.293024 0.551152 0.416705 0.088 Uiso 0.429(5) 1 calc R U P A 2
H88B H 0.253260 0.620375 0.408666 0.088 Uiso 0.429(5) 1 calc R U P A 2
H88C H 0.292851 0.662435 0.402794 0.088 Uiso 0.429(5) 1 calc R U P A 2
C89A C 0.2367(6) 0.6509(13) 0.3509(5) 0.053(3) Uani 0.429(5) 1 d D U P A 2
H89A H 0.252285 0.713395 0.357960 0.080 Uiso 0.429(5) 1 calc R U P A 2
H89B H 0.210457 0.656489 0.353974 0.080 Uiso 0.429(5) 1 calc R U P A 2
H89C H 0.232392 0.640956 0.329181 0.080 Uiso 0.429(5) 1 calc R U P A 2
C90A C 0.2298(5) 0.4724(13) 0.3631(5) 0.051(3) Uani 0.429(5) 1 d D U P A 2
H90A H 0.220859 0.455808 0.341278 0.076 Uiso 0.429(5) 1 calc R U P A 2
H90B H 0.206501 0.494768 0.368581 0.076 Uiso 0.429(5) 1 calc R U P A 2
H90C H 0.241833 0.411960 0.375000 0.076 Uiso 0.429(5) 1 calc R U P A 2
Pt5 Pt 0.07901(2) 0.12791(2) 0.22584(2) 0.02099(6) Uani 1 1 d . . . . .
Pt6 Pt 0.16053(2) 0.20051(2) 0.26660(2) 0.02070(6) Uani 1 1 d . . . . .
N21 N 0.04656(16) 0.1621(4) 0.25342(12) 0.0234(11) Uani 1 1 d . . . . .
N22 N 0.04049(17) 0.1707(4) 0.30279(14) 0.0302(13) Uani 1 1 d . . . . .
N23 N 0.08661(16) 0.0611(4) 0.29349(12) 0.0259(12) Uani 1 1 d . . . . .
N24 N 0.18682(15) 0.0858(4) 0.29626(12) 0.0241(11) Uani 1 1 d . . . . .
N25 N 0.23178(17) 0.0273(5) 0.34434(14) 0.0337(14) Uani 1 1 d . . . . .
N26 N 0.20259(16) 0.1856(4) 0.34109(12) 0.0256(12) Uani 1 1 d . . . . .
N27 N 0.07517(15) 0.2794(4) 0.20999(12) 0.0264(12) Uani 1 1 d . . . . .
N28 N 0.14316(15) 0.3208(4) 0.23760(12) 0.0238(11) Uani 1 1 d . . . . .
N29 N 0.11040(16) 0.0956(4) 0.19761(12) 0.0243(11) Uani 1 1 d . . . . .
N30 N 0.17671(16) 0.1253(4) 0.23168(12) 0.0240(11) Uani 1 1 d . . . . .
C145 C 0.08828(19) -0.0099(5) 0.24362(15) 0.0271(11) Uani 1 1 d . U . . .
C146 C 0.0992(2) -0.0982(5) 0.23170(16) 0.0291(12) Uani 1 1 d . U . . .
H146 H 0.094771 -0.099506 0.210415 0.035 Uiso 1 1 calc R U . . .
C147 C 0.1162(2) -0.1854(5) 0.24855(17) 0.0310(12) Uani 1 1 d . U . . .
C148 C 0.1298(2) -0.2735(5) 0.23285(18) 0.0368(15) Uani 1 1 d . U . . .
C149 C 0.0941(3) -0.3196(7) 0.2074(2) 0.059(2) Uani 1 1 d . U . . .
H14A H 0.074654 -0.348316 0.216217 0.089 Uiso 1 1 calc R U . . .
H14B H 0.103935 -0.373424 0.197161 0.089 Uiso 1 1 calc R U . . .
H14C H 0.080781 -0.266679 0.192658 0.089 Uiso 1 1 calc R U . . .
C150 C 0.1615(3) -0.2328(6) 0.2190(2) 0.0480(19) Uani 1 1 d . U . . .
H15A H 0.149600 -0.177030 0.204840 0.072 Uiso 1 1 calc R U . . .
H15B H 0.169548 -0.287668 0.207971 0.072 Uiso 1 1 calc R U . . .
H15C H 0.185400 -0.207924 0.235383 0.072 Uiso 1 1 calc R U . . .
C151 C 0.1510(3) -0.3575(6) 0.2551(2) 0.056(2) Uani 1 1 d . U . . .
H15D H 0.175499 -0.330026 0.270414 0.083 Uiso 1 1 calc R U . . .
H15E H 0.158548 -0.412795 0.243985 0.083 Uiso 1 1 calc R U . . .
H15F H 0.132727 -0.383559 0.265350 0.083 Uiso 1 1 calc R U . . .
C152 C 0.1228(2) -0.1860(5) 0.28005(16) 0.0300(11) Uani 1 1 d . U . . .
H152 H 0.134654 -0.243300 0.292195 0.036 Uiso 1 1 calc R U . . .
C153 C 0.1115(2) -0.1002(5) 0.29312(16) 0.0277(11) Uani 1 1 d . U . . .
C154 C 0.09318(19) -0.0170(5) 0.27438(15) 0.0255(11) Uani 1 1 d . U . . .
C155 C 0.1045(2) 0.0312(5) 0.32410(15) 0.0275(11) Uani 1 1 d . U . . .
C156 C 0.1113(2) 0.0865(6) 0.35085(16) 0.0336(12) Uani 1 1 d . U . . .
H156 H 0.101378 0.153716 0.350651 0.040 Uiso 1 1 calc R U . . .
C157 C 0.1332(2) 0.0390(6) 0.37749(17) 0.0386(13) Uani 1 1 d . U . . .
H157 H 0.138271 0.076251 0.395879 0.046 Uiso 1 1 calc R U . . .
C158 C 0.1485(2) -0.0588(6) 0.37987(18) 0.0428(15) Uani 1 1 d . U . . .
C159 C 0.1419(2) -0.1127(6) 0.35269(17) 0.0369(13) Uani 1 1 d . U . . .
H159 H 0.151963 -0.179866 0.353162 0.044 Uiso 1 1 calc R U . . .
C160 C 0.1204(2) -0.0671(5) 0.32494(16) 0.0298(11) Uani 1 1 d . U . . .
C161 C 0.1726(2) -0.1015(6) 0.41075(19) 0.0546(18) Uani 1 1 d D U . . .
C165 C 0.0578(2) 0.1343(5) 0.28310(15) 0.0262(11) Uani 1 1 d . U . . .
C166 C 0.0089(2) 0.2328(6) 0.29184(18) 0.0373(15) Uani 1 1 d . U . . .
H166 H -0.003369 0.259752 0.305520 0.045 Uiso 1 1 calc R U . . .
C167 C -0.0066(2) 0.2596(5) 0.26162(17) 0.0339(14) Uani 1 1 d . U . . .
H167 H -0.029969 0.301142 0.253944 0.041 Uiso 1 1 calc R U . . .
C168 C 0.0135(2) 0.2230(5) 0.24316(17) 0.0303(13) Uani 1 1 d . U . . .
H168 H 0.003925 0.241208 0.222192 0.036 Uiso 1 1 calc R U . . .
C169 C 0.14700(19) 0.2719(5) 0.29970(15) 0.0250(11) Uani 1 1 d . U . . .
C170 C 0.11728(19) 0.3487(5) 0.29580(15) 0.0254(12) Uani 1 1 d . U . . .
H170 H 0.100796 0.365604 0.275597 0.030 Uiso 1 1 calc R U . . .
C171 C 0.1107(2) 0.4012(5) 0.31998(16) 0.0273(12) Uani 1 1 d . U . . .
C172 C 0.1348(2) 0.3788(5) 0.34953(16) 0.0282(12) Uani 1 1 d . U . . .
H172 H 0.131213 0.414002 0.366247 0.034 Uiso 1 1 calc R U . . .
C173 C 0.1645(2) 0.3041(5) 0.35452(15) 0.0265(11) Uani 1 1 d . U . . .
C174 C 0.1697(2) 0.2532(5) 0.33004(15) 0.0275(11) Uani 1 1 d . U . . .
C175 C 0.0797(2) 0.4891(5) 0.31442(17) 0.0327(14) Uani 1 1 d . U . . .
C176 C 0.0550(3) 0.5027(6) 0.28117(19) 0.0467(19) Uani 1 1 d . U . . .
H17A H 0.072659 0.525329 0.269993 0.070 Uiso 1 1 calc R U . . .
H17B H 0.033854 0.553702 0.279159 0.070 Uiso 1 1 calc R U . . .
H17C H 0.042350 0.437862 0.272748 0.070 Uiso 1 1 calc R U . . .
C177 C 0.0513(2) 0.4714(6) 0.3326(2) 0.0455(18) Uani 1 1 d . U . . .
H17D H 0.032568 0.415942 0.323234 0.068 Uiso 1 1 calc R U . . .
H17E H 0.035869 0.533546 0.332507 0.068 Uiso 1 1 calc R U . . .
H17F H 0.067218 0.453308 0.353612 0.068 Uiso 1 1 calc R U . . .
C178 C 0.1038(3) 0.5888(6) 0.3262(2) 0.0453(18) Uani 1 1 d . U . . .
H17G H 0.115844 0.586205 0.348450 0.068 Uiso 1 1 calc R U . . .
H17H H 0.085355 0.647081 0.320274 0.068 Uiso 1 1 calc R U . . .
H17I H 0.125218 0.595849 0.317201 0.068 Uiso 1 1 calc R U . . .
C179 C 0.1967(2) 0.2734(5) 0.38197(15) 0.0296(11) Uani 1 1 d . U . . .
C180 C 0.2203(2) 0.2015(5) 0.37324(16) 0.0318(12) Uani 1 1 d . U . . .
C181 C 0.2561(2) 0.1643(6) 0.39431(16) 0.0355(13) Uani 1 1 d . U . . .
H181 H 0.272254 0.116238 0.388405 0.043 Uiso 1 1 calc R U . . .
C182 C 0.2674(2) 0.1996(6) 0.42433(16) 0.0404(15) Uani 1 1 d . U . . .
H182 H 0.291675 0.174762 0.438910 0.048 Uiso 1 1 calc R U . . .
C183 C 0.2438(2) 0.2710(6) 0.43359(16) 0.0374(14) Uani 1 1 d . U . . .
C184 C 0.2089(2) 0.3057(6) 0.41231(16) 0.0340(12) Uani 1 1 d . U . . .
H184 H 0.192483 0.352991 0.418325 0.041 Uiso 1 1 calc R U . . .
C185 C 0.2586(3) 0.3031(7) 0.46740(17) 0.0468(17) Uani 1 1 d . U . . .
C186 C 0.2529(3) 0.2122(8) 0.48632(19) 0.059(2) Uani 1 1 d . U . . .
H18A H 0.224902 0.188094 0.478079 0.089 Uiso 1 1 calc R U . . .
H18B H 0.258945 0.233290 0.507581 0.089 Uiso 1 1 calc R U . . .
H18C H 0.271386 0.157326 0.485372 0.089 Uiso 1 1 calc R U . . .
C187 C 0.2341(3) 0.3967(8) 0.4725(2) 0.060(2) Uani 1 1 d . U . . .
H18D H 0.238975 0.455211 0.461157 0.091 Uiso 1 1 calc R U . . .
H18E H 0.242749 0.413022 0.494248 0.091 Uiso 1 1 calc R U . . .
H18F H 0.205087 0.380396 0.465121 0.091 Uiso 1 1 calc R U . . .
C188 C 0.3031(3) 0.3313(8) 0.4779(2) 0.062(2) Uani 1 1 d . U . . .
H18G H 0.319120 0.272056 0.476111 0.094 Uiso 1 1 calc R U . . .
H18H H 0.311756 0.353492 0.499243 0.094 Uiso 1 1 calc R U . . .
H18I H 0.307307 0.386618 0.465186 0.094 Uiso 1 1 calc R U . . .
C189 C 0.20732(19) 0.0966(5) 0.32674(15) 0.0247(11) Uani 1 1 d . U . . .
C190 C 0.2346(2) -0.0619(5) 0.33179(17) 0.0338(14) Uani 1 1 d . U . . .
H190 H 0.252187 -0.112204 0.343908 0.041 Uiso 1 1 calc R U . . .
C191 C 0.2130(2) -0.0834(5) 0.30195(16) 0.0302(13) Uani 1 1 d . U . . .
H191 H 0.214278 -0.148397 0.293406 0.036 Uiso 1 1 calc R U . . .
C192 C 0.18935(19) -0.0063(5) 0.28487(16) 0.0281(11) Uani 1 1 d . U . . .
H192 H 0.174153 -0.019210 0.264083 0.034 Uiso 1 1 calc R U . . .
C193 C 0.1760(2) 0.3842(5) 0.23702(16) 0.0278(12) Uani 1 1 d . U . . .
C194 C 0.2047(2) 0.4157(5) 0.26423(17) 0.0323(13) Uani 1 1 d . U . . .
H194 H 0.202120 0.395442 0.283081 0.039 Uiso 1 1 calc R U . . .
C195 C 0.2371(2) 0.4762(5) 0.26421(18) 0.0374(15) Uani 1 1 d . U . . .
H195 H 0.256829 0.496295 0.282949 0.045 Uiso 1 1 calc R U . . .
C196 C 0.2406(2) 0.5072(6) 0.23688(18) 0.0387(15) Uani 1 1 d . U . . .
H196 H 0.262795 0.548540 0.236808 0.046 Uiso 1 1 calc R U . . .
C197 C 0.2123(2) 0.4785(6) 0.20993(18) 0.0384(15) Uani 1 1 d . U . . .
H197 H 0.214504 0.501575 0.191228 0.046 Uiso 1 1 calc R U . . .
C198 C 0.1802(2) 0.4160(5) 0.20954(17) 0.0336(13) Uani 1 1 d . U . . .
H198 H 0.161105 0.394809 0.190653 0.040 Uiso 1 1 calc R U . . .
C199 C 0.1072(2) 0.3383(5) 0.21665(15) 0.0269(12) Uani 1 1 d . U . . .
H199 H 0.104373 0.399578 0.205343 0.032 Uiso 1 1 calc R U . . .
C200 C 0.0383(2) 0.3194(5) 0.18954(16) 0.0309(13) Uani 1 1 d . U . . .
C201 C 0.0261(2) 0.4186(5) 0.19100(17) 0.0331(13) Uani 1 1 d . U . . .
H201 H 0.043407 0.463856 0.205489 0.040 Uiso 1 1 calc R U . . .
C202 C -0.0108(2) 0.4528(6) 0.17175(18) 0.0390(15) Uani 1 1 d . U . . .
H202 H -0.018680 0.521233 0.173189 0.047 Uiso 1 1 calc R U . . .
C203 C -0.0366(2) 0.3887(6) 0.15035(18) 0.0397(15) Uani 1 1 d . U . . .
H203 H -0.061890 0.412940 0.136942 0.048 Uiso 1 1 calc R U . . .
C204 C -0.0252(2) 0.2891(6) 0.14877(18) 0.0398(15) Uani 1 1 d . U . . .
H204 H -0.042621 0.244128 0.134265 0.048 Uiso 1 1 calc R U . . .
C205 C 0.0120(2) 0.2545(6) 0.16842(17) 0.0346(13) Uani 1 1 d . U . . .
H205 H 0.019419 0.185519 0.167424 0.042 Uiso 1 1 calc R U . . .
C206 C 0.0879(2) 0.0823(6) 0.16596(16) 0.0326(13) Uani 1 1 d . U . . .
C207 C 0.0540(2) 0.0184(6) 0.15728(17) 0.0373(14) Uani 1 1 d . U . . .
H207 H 0.046260 -0.015897 0.172456 0.045 Uiso 1 1 calc R U . . .
C208 C 0.0314(2) 0.0047(7) 0.12666(18) 0.0465(16) Uani 1 1 d . U . . .
H208 H 0.008127 -0.037600 0.120928 0.056 Uiso 1 1 calc R U . . .
C209 C 0.0432(3) 0.0534(7) 0.10435(19) 0.0504(17) Uani 1 1 d . U . . .
H209 H 0.028061 0.043922 0.083375 0.060 Uiso 1 1 calc R U . . .
C210 C 0.0770(2) 0.1155(7) 0.11283(19) 0.0500(17) Uani 1 1 d . U . . .
H210 H 0.085321 0.148025 0.097703 0.060 Uiso 1 1 calc R U . . .
C211 C 0.0987(2) 0.1303(6) 0.14360(17) 0.0404(15) Uani 1 1 d . U . . .
H211 H 0.121498 0.174502 0.149280 0.048 Uiso 1 1 calc R U . . .
C212 C 0.14999(19) 0.0983(5) 0.20496(15) 0.0265(11) Uani 1 1 d . U . . .
H212 H 0.160687 0.078922 0.189530 0.032 Uiso 1 1 calc R U . . .
C213 C 0.2181(2) 0.1094(5) 0.23453(15) 0.0291(13) Uani 1 1 d . U . . .
C214 C 0.2310(2) 0.0213(6) 0.22378(17) 0.0355(14) Uani 1 1 d . U . . .
H214 H 0.212308 -0.032085 0.215402 0.043 Uiso 1 1 calc R U . . .
C215 C 0.2712(2) 0.0117(6) 0.22533(18) 0.0404(15) Uani 1 1 d . U . . .
H215 H 0.279593 -0.048077 0.217647 0.049 Uiso 1 1 calc R U . . .
C216 C 0.2985(2) 0.0853(6) 0.23747(18) 0.0408(15) Uani 1 1 d . U . . .
H216 H 0.325576 0.078423 0.237691 0.049 Uiso 1 1 calc R U . . .
C217 C 0.2869(2) 0.1722(6) 0.24978(18) 0.0424(15) Uani 1 1 d . U . . .
H217 H 0.306164 0.223446 0.259054 0.051 Uiso 1 1 calc R U . . .
C218 C 0.2468(2) 0.1826(6) 0.24828(17) 0.0363(13) Uani 1 1 d . U . . .
H218 H 0.238943 0.241169 0.256864 0.044 Uiso 1 1 calc R U . . .
C1A C 0.1739(7) -0.0434(17) 0.4386(4) 0.072(4) Uani 0.429(5) 1 d D U P A 2
H1AA H 0.201759 -0.042255 0.452939 0.108 Uiso 0.429(5) 1 calc R U P A 2
H1AB H 0.156192 -0.076075 0.448237 0.108 Uiso 0.429(5) 1 calc R U P A 2
H1AC H 0.164675 0.026366 0.432859 0.108 Uiso 0.429(5) 1 calc R U P A 2
C1B C 0.2177(4) -0.1118(16) 0.4120(4) 0.054(3) Uani 0.429(5) 1 d D U P A 2
H1BA H 0.218583 -0.149064 0.394036 0.080 Uiso 0.429(5) 1 calc R U P A 2
H1BB H 0.233271 -0.148645 0.430520 0.080 Uiso 0.429(5) 1 calc R U P A 2
H1BC H 0.229312 -0.043921 0.412265 0.080 Uiso 0.429(5) 1 calc R U P A 2
C1C C 0.1620(7) -0.2144(12) 0.4123(5) 0.070(4) Uani 0.429(5) 1 d D U P A 2
H1CA H 0.133943 -0.220417 0.411839 0.104 Uiso 0.429(5) 1 calc R U P A 2
H1CB H 0.180262 -0.244162 0.431203 0.104 Uiso 0.429(5) 1 calc R U P A 2
H1CC H 0.165066 -0.250403 0.394755 0.104 Uiso 0.429(5) 1 calc R U P A 2
C88 C 0.2707(4) 0.4972(11) 0.4002(3) 0.049(3) Uani 0.571(5) 1 d D U P A 1
H88D H 0.271209 0.424189 0.396152 0.074 Uiso 0.571(5) 1 calc R U P A 1
H88E H 0.249876 0.511431 0.409324 0.074 Uiso 0.571(5) 1 calc R U P A 1
H88F H 0.297250 0.518353 0.414253 0.074 Uiso 0.571(5) 1 calc R U P A 1
C89 C 0.2563(5) 0.6676(9) 0.3768(4) 0.061(3) Uani 0.571(5) 1 d D U P A 1
H89D H 0.281149 0.691596 0.392370 0.092 Uiso 0.571(5) 1 calc R U P A 1
H89E H 0.233457 0.674887 0.384321 0.092 Uiso 0.571(5) 1 calc R U P A 1
H89F H 0.251120 0.708060 0.358178 0.092 Uiso 0.571(5) 1 calc R U P A 1
C90 C 0.2223(4) 0.5138(11) 0.3464(3) 0.044(3) Uani 0.571(5) 1 d D U P A 1
H90D H 0.216268 0.550651 0.327131 0.066 Uiso 0.571(5) 1 calc R U P A 1
H90E H 0.199682 0.521758 0.354189 0.066 Uiso 0.571(5) 1 calc R U P A 1
H90F H 0.226130 0.441541 0.343106 0.066 Uiso 0.571(5) 1 calc R U P A 1
C102 C 0.4896(4) 0.8708(10) 0.3348(3) 0.047(3) Uani 0.571(5) 1 d D U P A 1
H10A H 0.469653 0.828496 0.319733 0.070 Uiso 0.571(5) 1 calc R U P A 1
H10B H 0.503665 0.914006 0.324335 0.070 Uiso 0.571(5) 1 calc R U P A 1
H10C H 0.475850 0.913637 0.345455 0.070 Uiso 0.571(5) 1 calc R U P A 1
C103 C 0.5478(4) 0.8712(10) 0.3810(3) 0.046(2) Uani 0.571(5) 1 d D U P A 1
H10D H 0.531203 0.914155 0.389379 0.068 Uiso 0.571(5) 1 calc R U P A 1
H10E H 0.562578 0.914008 0.371108 0.068 Uiso 0.571(5) 1 calc R U P A 1
H10F H 0.567084 0.832422 0.397544 0.068 Uiso 0.571(5) 1 calc R U P A 1
C104 C 0.5421(4) 0.7463(10) 0.3393(3) 0.042(3) Uani 0.571(5) 1 d D U P A 1
H10G H 0.565240 0.707853 0.352634 0.063 Uiso 0.571(5) 1 calc R U P A 1
H10H H 0.551551 0.796193 0.327625 0.063 Uiso 0.571(5) 1 calc R U P A 1
H10I H 0.522904 0.699645 0.325318 0.063 Uiso 0.571(5) 1 calc R U P A 1
C162 C 0.1439(5) -0.1174(13) 0.4291(4) 0.064(3) Uani 0.571(5) 1 d D U P A 1
H16A H 0.135913 -0.051262 0.434979 0.096 Uiso 0.571(5) 1 calc R U P A 1
H16B H 0.157720 -0.156992 0.447538 0.096 Uiso 0.571(5) 1 calc R U P A 1
H16C H 0.119650 -0.154165 0.416622 0.096 Uiso 0.571(5) 1 calc R U P A 1
C163 C 0.1935(5) -0.1994(11) 0.4111(4) 0.070(3) Uani 0.571(5) 1 d D U P A 1
H16D H 0.173515 -0.251538 0.401015 0.105 Uiso 0.571(5) 1 calc R U P A 1
H16E H 0.207846 -0.219628 0.432248 0.105 Uiso 0.571(5) 1 calc R U P A 1
H16F H 0.212935 -0.191755 0.400265 0.105 Uiso 0.571(5) 1 calc R U P A 1
C164 C 0.2030(5) -0.0212(12) 0.4295(4) 0.074(3) Uani 0.571(5) 1 d D U P A 1
H16G H 0.219517 0.003361 0.417565 0.111 Uiso 0.571(5) 1 calc R U P A 1
H16H H 0.220650 -0.051807 0.448481 0.111 Uiso 0.571(5) 1 calc R U P A 1
H16I H 0.188179 0.035927 0.434198 0.111 Uiso 0.571(5) 1 calc R U P A 1
C223 C 0.3412(7) 0.9056(17) 0.4716(4) 0.053(3) Uani 0.429(5) 1 d D U P A 2
H22A H 0.319463 0.854861 0.465167 0.080 Uiso 0.429(5) 1 calc R U P A 2
H22B H 0.329799 0.971463 0.474242 0.080 Uiso 0.429(5) 1 calc R U P A 2
H22C H 0.361395 0.884432 0.490888 0.080 Uiso 0.429(5) 1 calc R U P A 2
C1G C 0.3914(5) 1.0056(12) 0.4551(5) 0.044(3) Uani 0.429(5) 1 d D U P A 2
H1GA H 0.409658 0.999355 0.476213 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1GB H 0.376292 1.069516 0.452637 0.066 Uiso 0.429(5) 1 calc R U P A 2
H1GC H 0.407268 1.005055 0.441307 0.066 Uiso 0.429(5) 1 calc R U P A 2
C1H C 0.3286(5) 0.9420(16) 0.4162(3) 0.052(3) Uani 0.429(5) 1 d D U P A 2
H1HA H 0.337927 1.000233 0.407224 0.078 Uiso 0.429(5) 1 calc R U P A 2
H1HB H 0.303166 0.959234 0.419404 0.078 Uiso 0.429(5) 1 calc R U P A 2
H1HC H 0.324327 0.883603 0.402406 0.078 Uiso 0.429(5) 1 calc R U P A 2
O1 O 0.3225(4) 0.7267(9) 0.2801(3) 0.144(4) Uani 1 1 d . U . . .
H1 H 0.344730 0.697518 0.290746 0.216 Uiso 1 1 d R U . . .
C225 C 0.2852(4) 0.7516(10) 0.2855(3) 0.100(3) Uani 1 1 d . U . . .
H22D H 0.267386 0.692118 0.281107 0.150 Uiso 1 1 calc R U . . .
H22E H 0.271747 0.807879 0.272137 0.150 Uiso 1 1 calc R U . . .
H22F H 0.291360 0.771726 0.306838 0.150 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 2.9442(4) . ?
Pt1 N1 2.020(6) . ?
Pt1 N8 2.010(5) . ?
Pt1 N10 2.144(5) . ?
Pt1 C1 1.990(7) . ?
Pt2 N4 2.056(5) . ?
Pt2 N7 2.144(6) . ?
Pt2 N9 2.026(5) . ?
Pt2 C219 1.976(7) . ?
N1 C21 1.372(9) . ?
N1 C24 1.342(9) . ?
N2 C6 1.443(9) . ?
N2 C16 1.426(8) . ?
N2 C21 1.372(8) . ?
N3 C21 1.325(9) . ?
N3 C22 1.329(9) . ?
N4 C41 1.376(8) . ?
N4 C44 1.355(9) . ?
N5 C41 1.350(9) . ?
N5 C42 1.324(9) . ?
N6 C26 1.430(8) . ?
N6 C31 1.410(8) . ?
N6 C41 1.359(9) . ?
N7 C45 1.428(9) . ?
N7 C51 1.317(8) . ?
N8 C51 1.320(8) . ?
N8 C52 1.433(8) . ?
N9 C64 1.320(8) . ?
N9 C65 1.425(9) . ?
N10 C58 1.424(8) . ?
N10 C64 1.314(8) . ?
C1 C2 1.394(10) . ?
C1 C6 1.376(9) . ?
C2 H2 0.9500 . ?
C2 C3 1.408(10) . ?
C3 C4 1.385(10) . ?
C3 C7 1.541(10) . ?
C4 H4 0.9500 . ?
C4 C5 1.418(10) . ?
C5 C6 1.395(9) . ?
C5 C11 1.450(10) . ?
C7 C8 1.528(12) . ?
C7 C9 1.564(14) . ?
C7 C10 1.500(13) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10J 0.9800 . ?
C10 H10K 0.9800 . ?
C10 H10L 0.9800 . ?
C11 C12 1.399(10) . ?
C11 C16 1.399(10) . ?
C12 H12 0.9500 . ?
C12 C13 1.391(10) . ?
C13 C14 1.397(11) . ?
C13 C17 1.549(10) . ?
C14 H14 0.9500 . ?
C14 C15 1.390(10) . ?
C15 H15 0.9500 . ?
C15 C16 1.375(10) . ?
C17 C18 1.536(12) . ?
C17 C19 1.484(13) . ?
C17 C20 1.521(12) . ?
C18 H18J 0.9800 . ?
C18 H18K 0.9800 . ?
C18 H18L 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C22 H22 0.9500 . ?
C22 C23 1.376(10) . ?
C23 H23 0.9500 . ?
C23 C24 1.359(10) . ?
C24 H24 0.9500 . ?
C25 C26 1.401(10) . ?
C25 C36 1.449(9) . ?
C25 C222 1.385(10) . ?
C26 C219 1.391(9) . ?
C27 C28 1.471(11) . ?
C27 C29 1.638(14) . ?
C27 C30 1.453(12) . ?
C27 C221 1.513(10) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.410(10) . ?
C31 C36 1.400(10) . ?
C32 H32 0.9500 . ?
C32 C33 1.362(10) . ?
C33 H33 0.9500 . ?
C33 C34 1.402(11) . ?
C34 C35 1.384(10) . ?
C34 C37 1.524(10) . ?
C35 H35 0.9500 . ?
C35 C36 1.402(10) . ?
C37 C38 1.480(14) . ?
C37 C39 1.523(15) . ?
C37 C40 1.531(13) . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C42 H42 0.9500 . ?
C42 C43 1.378(10) . ?
C43 H43 0.9500 . ?
C43 C44 1.375(10) . ?
C44 H44 0.9500 . ?
C45 C46 1.386(10) . ?
C45 C50 1.378(11) . ?
C46 H46 0.9500 . ?
C46 C47 1.410(10) . ?
C47 H47 0.9500 . ?
C47 C48 1.391(12) . ?
C48 H48 0.9500 . ?
C48 C49 1.374(12) . ?
C49 H49 0.9500 . ?
C49 C50 1.400(10) . ?
C50 H50 0.9500 . ?
C51 H51 0.9500 . ?
C52 C53 1.395(10) . ?
C52 C57 1.391(10) . ?
C53 H53 0.9500 . ?
C53 C54 1.371(10) . ?
C54 H54 0.9500 . ?
C54 C55 1.397(11) . ?
C55 H55 0.9500 . ?
C55 C56 1.383(11) . ?
C56 H56 0.9500 . ?
C56 C57 1.381(10) . ?
C57 H57 0.9500 . ?
C58 C59 1.399(10) . ?
C58 C63 1.397(10) . ?
C59 H59 0.9500 . ?
C59 C60 1.379(10) . ?
C60 H60 0.9500 . ?
C60 C61 1.367(11) . ?
C61 H61 0.9500 . ?
C61 C62 1.379(11) . ?
C62 H62 0.9500 . ?
C62 C63 1.401(10) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 C66 1.390(11) . ?
C65 C70 1.386(11) . ?
C66 H66 0.9500 . ?
C66 C67 1.412(11) . ?
C67 H67 0.9500 . ?
C67 C68 1.375(13) . ?
C68 H68 0.9500 . ?
C68 C69 1.391(12) . ?
C69 H69 0.9500 . ?
C69 C70 1.385(11) . ?
C70 H70 0.9500 . ?
C219 C220 1.406(10) . ?
C220 H220 0.9500 . ?
C220 C221 1.410(10) . ?
C221 C222 1.389(10) . ?
C222 H222 0.9500 . ?
Pt3 Pt4 2.9586(4) . ?
Pt3 N11 2.037(5) . ?
Pt3 N18 2.020(5) . ?
Pt3 N20 2.125(5) . ?
Pt3 C71 1.991(6) . ?
Pt4 N14 2.051(5) . ?
Pt4 N17 2.123(6) . ?
Pt4 N19 2.044(5) . ?
Pt4 C95 1.967(7) . ?
N11 C91 1.346(8) . ?
N11 C94 1.358(8) . ?
N12 C91 1.343(9) . ?
N12 C92 1.322(9) . ?
N13 C80 1.419(8) . ?
N13 C82 1.394(8) . ?
N13 C91 1.390(8) . ?
N14 C115 1.343(8) . ?
N14 C118 1.368(8) . ?
N15 C115 1.330(9) . ?
N15 C116 1.326(10) . ?
N16 C100 1.431(8) . ?
N16 C106 1.431(8) . ?
N16 C115 1.384(9) . ?
N17 C138 1.326(8) . ?
N17 C139 1.423(8) . ?
N18 C132 1.421(8) . ?
N18 C138 1.336(8) . ?
N19 C125 1.328(8) . ?
N19 C126 1.423(9) . ?
N20 C119 1.422(8) . ?
N20 C125 1.319(8) . ?
C71 C72 1.406(9) . ?
C71 C80 1.385(9) . ?
C72 H72 0.9500 . ?
C72 C73 1.408(9) . ?
C73 C74 1.535(10) . ?
C73 C78 1.395(9) . ?
C74 C75 1.524(11) . ?
C74 C76 1.542(11) . ?
C74 C77 1.529(10) . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
C78 H78 0.9500 . ?
C78 C79 1.401(9) . ?
C79 C80 1.388(9) . ?
C79 C81 1.462(9) . ?
C81 C82 1.388(10) . ?
C81 C86 1.403(9) . ?
C82 C83 1.399(10) . ?
C83 H83 0.9500 . ?
C83 C84 1.373(10) . ?
C84 H84 0.9500 . ?
C84 C85 1.417(10) . ?
C85 C86 1.373(10) . ?
C85 C87 1.541(10) . ?
C86 H86 0.9500 . ?
C87 C88A 1.552(14) . ?
C87 C89A 1.591(13) . ?
C87 C90A 1.517(13) . ?
C87 C88 1.552(12) . ?
C87 C89 1.517(12) . ?
C87 C90 1.534(12) . ?
C92 H92 0.9500 . ?
C92 C93 1.376(10) . ?
C93 H93 0.9500 . ?
C93 C94 1.342(10) . ?
C94 H94 0.9500 . ?
C95 C96 1.422(9) . ?
C95 C100 1.394(9) . ?
C96 H96 0.9500 . ?
C96 C97 1.426(9) . ?
C97 C98 1.388(10) . ?
C97 C101 1.534(9) . ?
C98 H98 0.9500 . ?
C98 C99 1.399(9) . ?
C99 C100 1.401(9) . ?
C99 C105 1.451(9) . ?
C101 C1D 1.590(13) . ?
C101 C1E 1.514(13) . ?
C101 C1F 1.498(13) . ?
C101 C102 1.577(11) . ?
C101 C103 1.471(11) . ?
C101 C104 1.504(11) . ?
C105 C106 1.398(10) . ?
C105 C110 1.381(10) . ?
C106 C107 1.392(9) . ?
C107 H107 0.9500 . ?
C107 C108 1.377(10) . ?
C108 H108 0.9500 . ?
C108 C109 1.411(11) . ?
C109 C110 1.390(10) . ?
C109 C111 1.507(10) . ?
C110 H110 0.9500 . ?
C111 C112 1.554(12) . ?
C111 C113 1.503(12) . ?
C111 C114 1.552(11) . ?
C111 C223 1.521(13) . ?
C111 C1G 1.557(13) . ?
C111 C1H 1.552(13) . ?
C112 H11A 0.9800 . ?
C112 H11B 0.9800 . ?
C112 H11C 0.9800 . ?
C113 H11D 0.9800 . ?
C113 H11E 0.9800 . ?
C113 H11F 0.9800 . ?
C114 H11G 0.9800 . ?
C114 H11H 0.9800 . ?
C114 H11I 0.9800 . ?
C116 H116 0.9500 . ?
C116 C117 1.374(10) . ?
C117 H117 0.9500 . ?
C117 C118 1.370(9) . ?
C118 H118 0.9500 . ?
C119 C120 1.388(10) . ?
C119 C124 1.405(10) . ?
C120 H120 0.9500 . ?
C120 C121 1.387(10) . ?
C121 H121 0.9500 . ?
C121 C122 1.382(11) . ?
C122 H122 0.9500 . ?
C122 C123 1.374(11) . ?
C123 H123 0.9500 . ?
C123 C124 1.407(10) . ?
C124 H124 0.9500 . ?
C125 H125 0.9500 . ?
C126 C127 1.396(10) . ?
C126 C131 1.370(11) . ?
C127 H127 0.9500 . ?
C127 C128 1.393(12) . ?
C128 H128 0.9500 . ?
C128 C129 1.343(13) . ?
C129 H129 0.9500 . ?
C129 C130 1.391(12) . ?
C130 H130 0.9500 . ?
C130 C131 1.417(11) . ?
C131 H131 0.9500 . ?
C132 C133 1.386(10) . ?
C132 C137 1.379(10) . ?
C133 H133 0.9500 . ?
C133 C134 1.400(10) . ?
C134 H134 0.9500 . ?
C134 C135 1.403(11) . ?
C135 H135 0.9500 . ?
C135 C136 1.373(11) . ?
C136 H136 0.9500 . ?
C136 C137 1.372(10) . ?
C137 H137 0.9500 . ?
C138 H138 0.9500 . ?
C139 C140 1.408(10) . ?
C139 C144 1.385(10) . ?
C140 H140 0.9500 . ?
C140 C141 1.376(10) . ?
C141 H141 0.9500 . ?
C141 C142 1.351(12) . ?
C142 H142 0.9500 . ?
C142 C143 1.383(12) . ?
C143 H143 0.9500 . ?
C143 C144 1.391(10) . ?
C144 H144 0.9500 . ?
C1D H1DA 0.9800 . ?
C1D H1DB 0.9800 . ?
C1D H1DC 0.9800 . ?
C1E H1EA 0.9800 . ?
C1E H1EB 0.9800 . ?
C1E H1EC 0.9800 . ?
C1F H1FA 0.9800 . ?
C1F H1FB 0.9800 . ?
C1F H1FC 0.9800 . ?
C88A H88A 0.9800 . ?
C88A H88B 0.9800 . ?
C88A H88C 0.9800 . ?
C89A H89A 0.9800 . ?
C89A H89B 0.9800 . ?
C89A H89C 0.9800 . ?
C90A H90A 0.9800 . ?
C90A H90B 0.9800 . ?
C90A H90C 0.9800 . ?
Pt5 Pt6 3.0048(4) . ?
Pt5 N21 2.032(5) . ?
Pt5 N27 2.114(5) . ?
Pt5 N29 2.022(5) . ?
Pt5 C145 1.974(7) . ?
Pt6 N24 2.045(5) . ?
Pt6 N28 2.036(5) . ?
Pt6 N30 2.136(5) . ?
Pt6 C169 1.993(6) . ?
N21 C165 1.353(8) . ?
N21 C168 1.355(9) . ?
N22 C165 1.346(8) . ?
N22 C166 1.330(10) . ?
N23 C154 1.428(8) . ?
N23 C155 1.406(8) . ?
N23 C165 1.361(9) . ?
N24 C189 1.365(8) . ?
N24 C192 1.337(8) . ?
N25 C189 1.328(9) . ?
N25 C190 1.329(9) . ?
N26 C174 1.409(9) . ?
N26 C180 1.430(9) . ?
N26 C189 1.386(8) . ?
N27 C199 1.312(9) . ?
N27 C200 1.423(9) . ?
N28 C193 1.428(8) . ?
N28 C199 1.329(9) . ?
N29 C206 1.429(9) . ?
N29 C212 1.313(8) . ?
N30 C212 1.329(9) . ?
N30 C213 1.425(8) . ?
C145 C146 1.396(9) . ?
C145 C154 1.387(9) . ?
C146 H146 0.9500 . ?
C146 C147 1.404(10) . ?
C147 C148 1.530(10) . ?
C147 C152 1.405(10) . ?
C148 C149 1.529(12) . ?
C148 C150 1.557(10) . ?
C148 C151 1.528(11) . ?
C149 H14A 0.9800 . ?
C149 H14B 0.9800 . ?
C149 H14C 0.9800 . ?
C150 H15A 0.9800 . ?
C150 H15B 0.9800 . ?
C150 H15C 0.9800 . ?
C151 H15D 0.9800 . ?
C151 H15E 0.9800 . ?
C151 H15F 0.9800 . ?
C152 H152 0.9500 . ?
C152 C153 1.401(9) . ?
C153 C154 1.413(9) . ?
C153 C160 1.473(10) . ?
C155 C156 1.392(10) . ?
C155 C160 1.404(10) . ?
C156 H156 0.9500 . ?
C156 C157 1.370(10) . ?
C157 H157 0.9500 . ?
C157 C158 1.384(11) . ?
C158 C159 1.400(11) . ?
C158 C161 1.510(11) . ?
C159 H159 0.9500 . ?
C159 C160 1.393(10) . ?
C161 C1A 1.492(14) . ?
C161 C1B 1.567(13) . ?
C161 C1C 1.537(14) . ?
C161 C162 1.539(12) . ?
C161 C163 1.478(13) . ?
C161 C164 1.546(13) . ?
C166 H166 0.9500 . ?
C166 C167 1.372(11) . ?
C167 H167 0.9500 . ?
C167 C168 1.369(10) . ?
C168 H168 0.9500 . ?
C169 C170 1.418(9) . ?
C169 C174 1.390(9) . ?
C170 H170 0.9500 . ?
C170 C171 1.404(9) . ?
C171 C172 1.383(10) . ?
C171 C175 1.549(9) . ?
C172 H172 0.9500 . ?
C172 C173 1.393(9) . ?
C173 C174 1.385(9) . ?
C173 C179 1.449(9) . ?
C175 C176 1.509(11) . ?
C175 C177 1.523(10) . ?
C175 C178 1.556(11) . ?
C176 H17A 0.9800 . ?
C176 H17B 0.9800 . ?
C176 H17C 0.9800 . ?
C177 H17D 0.9800 . ?
C177 H17E 0.9800 . ?
C177 H17F 0.9800 . ?
C178 H17G 0.9800 . ?
C178 H17H 0.9800 . ?
C178 H17I 0.9800 . ?
C179 C180 1.404(10) . ?
C179 C184 1.397(9) . ?
C180 C181 1.395(10) . ?
C181 H181 0.9500 . ?
C181 C182 1.397(10) . ?
C182 H182 0.9500 . ?
C182 C183 1.411(11) . ?
C183 C184 1.370(10) . ?
C183 C185 1.541(10) . ?
C184 H184 0.9500 . ?
C185 C186 1.537(12) . ?
C185 C187 1.565(12) . ?
C185 C188 1.516(12) . ?
C186 H18A 0.9800 . ?
C186 H18B 0.9800 . ?
C186 H18C 0.9800 . ?
C187 H18D 0.9800 . ?
C187 H18E 0.9800 . ?
C187 H18F 0.9800 . ?
C188 H18G 0.9800 . ?
C188 H18H 0.9800 . ?
C188 H18I 0.9800 . ?
C190 H190 0.9500 . ?
C190 C191 1.370(10) . ?
C191 H191 0.9500 . ?
C191 C192 1.381(9) . ?
C192 H192 0.9500 . ?
C193 C194 1.390(10) . ?
C193 C198 1.400(9) . ?
C194 H194 0.9500 . ?
C194 C195 1.388(10) . ?
C195 H195 0.9500 . ?
C195 C196 1.380(11) . ?
C196 H196 0.9500 . ?
C196 C197 1.366(11) . ?
C197 H197 0.9500 . ?
C197 C198 1.388(10) . ?
C198 H198 0.9500 . ?
C199 H199 0.9500 . ?
C200 C201 1.382(10) . ?
C200 C205 1.393(10) . ?
C201 H201 0.9500 . ?
C201 C202 1.379(10) . ?
C202 H202 0.9500 . ?
C202 C203 1.384(11) . ?
C203 H203 0.9500 . ?
C203 C204 1.381(11) . ?
C204 H204 0.9500 . ?
C204 C205 1.391(10) . ?
C205 H205 0.9500 . ?
C206 C207 1.402(10) . ?
C206 C211 1.375(10) . ?
C207 H207 0.9500 . ?
C207 C208 1.389(11) . ?
C208 H208 0.9500 . ?
C208 C209 1.396(12) . ?
C209 H209 0.9500 . ?
C209 C210 1.382(12) . ?
C210 H210 0.9500 . ?
C210 C211 1.391(11) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 C214 1.397(10) . ?
C213 C218 1.385(10) . ?
C214 H214 0.9500 . ?
C214 C215 1.394(10) . ?
C215 H215 0.9500 . ?
C215 C216 1.344(11) . ?
C216 H216 0.9500 . ?
C216 C217 1.399(11) . ?
C217 H217 0.9500 . ?
C217 C218 1.390(10) . ?
C218 H218 0.9500 . ?
C1A H1AA 0.9800 . ?
C1A H1AB 0.9800 . ?
C1A H1AC 0.9800 . ?
C1B H1BA 0.9800 . ?
C1B H1BB 0.9800 . ?
C1B H1BC 0.9800 . ?
C1C H1CA 0.9800 . ?
C1C H1CB 0.9800 . ?
C1C H1CC 0.9800 . ?
C88 H88D 0.9800 . ?
C88 H88E 0.9800 . ?
C88 H88F 0.9800 . ?
C89 H89D 0.9800 . ?
C89 H89E 0.9800 . ?
C89 H89F 0.9800 . ?
C90 H90D 0.9800 . ?
C90 H90E 0.9800 . ?
C90 H90F 0.9800 . ?
C102 H10A 0.9800 . ?
C102 H10B 0.9800 . ?
C102 H10C 0.9800 . ?
C103 H10D 0.9800 . ?
C103 H10E 0.9800 . ?
C103 H10F 0.9800 . ?
C104 H10G 0.9800 . ?
C104 H10H 0.9800 . ?
C104 H10I 0.9800 . ?
C162 H16A 0.9800 . ?
C162 H16B 0.9800 . ?
C162 H16C 0.9800 . ?
C163 H16D 0.9800 . ?
C163 H16E 0.9800 . ?
C163 H16F 0.9800 . ?
C164 H16G 0.9800 . ?
C164 H16H 0.9800 . ?
C164 H16I 0.9800 . ?
C223 H22A 0.9800 . ?
C223 H22B 0.9800 . ?
C223 H22C 0.9800 . ?
C1G H1GA 0.9800 . ?
C1G H1GB 0.9800 . ?
C1G H1GC 0.9800 . ?
C1H H1HA 0.9800 . ?
C1H H1HB 0.9800 . ?
C1H H1HC 0.9800 . ?
O1 H1 0.8607 . ?
O1 C225 1.445(16) . ?
C225 H22D 0.9800 . ?
C225 H22E 0.9800 . ?
C225 H22F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 Pt2 96.90(14) . . ?
N1 Pt1 N10 93.1(2) . . ?
N8 Pt1 Pt2 82.93(14) . . ?
N8 Pt1 N1 179.0(2) . . ?
N8 Pt1 N10 85.9(2) . . ?
N10 Pt1 Pt2 83.00(14) . . ?
C1 Pt1 Pt2 91.77(19) . . ?
C1 Pt1 N1 89.0(2) . . ?
C1 Pt1 N8 92.0(2) . . ?
C1 Pt1 N10 174.6(2) . . ?
N4 Pt2 Pt1 107.36(14) . . ?
N4 Pt2 N7 91.8(2) . . ?
N7 Pt2 Pt1 79.40(14) . . ?
N9 Pt2 Pt1 79.47(15) . . ?
N9 Pt2 N4 172.0(2) . . ?
N9 Pt2 N7 85.3(2) . . ?
C219 Pt2 Pt1 100.05(18) . . ?
C219 Pt2 N4 90.4(2) . . ?
C219 Pt2 N7 177.9(2) . . ?
C219 Pt2 N9 92.6(2) . . ?
C21 N1 Pt1 124.6(4) . . ?
C24 N1 Pt1 120.4(5) . . ?
C24 N1 C21 114.6(6) . . ?
C16 N2 C6 107.8(5) . . ?
C21 N2 C6 124.2(6) . . ?
C21 N2 C16 124.8(6) . . ?
C21 N3 C22 117.9(6) . . ?
C41 N4 Pt2 126.5(4) . . ?
C44 N4 Pt2 117.0(4) . . ?
C44 N4 C41 115.9(6) . . ?
C42 N5 C41 117.1(6) . . ?
C31 N6 C26 107.5(5) . . ?
C41 N6 C26 126.2(5) . . ?
C41 N6 C31 125.0(6) . . ?
C45 N7 Pt2 120.9(4) . . ?
C51 N7 Pt2 122.7(5) . . ?
C51 N7 C45 116.4(6) . . ?
C51 N8 Pt1 125.1(4) . . ?
C51 N8 C52 117.2(6) . . ?
C52 N8 Pt1 117.4(4) . . ?
C64 N9 Pt2 128.6(4) . . ?
C64 N9 C65 116.7(5) . . ?
C65 N9 Pt2 114.3(4) . . ?
C58 N10 Pt1 125.3(4) . . ?
C64 N10 Pt1 117.7(4) . . ?
C64 N10 C58 116.6(6) . . ?
C2 C1 Pt1 127.6(5) . . ?
C6 C1 Pt1 118.0(5) . . ?
C6 C1 C2 113.4(6) . . ?
C1 C2 H2 118.1 . . ?
C1 C2 C3 123.8(6) . . ?
C3 C2 H2 118.1 . . ?
C2 C3 C7 118.6(6) . . ?
C4 C3 C2 120.0(7) . . ?
C4 C3 C7 121.4(6) . . ?
C3 C4 H4 120.8 . . ?
C3 C4 C5 118.5(6) . . ?
C5 C4 H4 120.8 . . ?
C4 C5 C11 133.4(6) . . ?
C6 C5 C4 117.6(6) . . ?
C6 C5 C11 108.9(6) . . ?
C1 C6 N2 126.1(6) . . ?
C1 C6 C5 126.5(7) . . ?
C5 C6 N2 107.2(6) . . ?
C3 C7 C9 109.8(7) . . ?
C8 C7 C3 112.8(7) . . ?
C8 C7 C9 105.8(8) . . ?
C10 C7 C3 110.6(7) . . ?
C10 C7 C8 111.3(8) . . ?
C10 C7 C9 106.3(8) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10J 109.5 . . ?
C7 C10 H10K 109.5 . . ?
C7 C10 H10L 109.5 . . ?
H10J C10 H10K 109.5 . . ?
H10J C10 H10L 109.5 . . ?
H10K C10 H10L 109.5 . . ?
C12 C11 C5 133.4(7) . . ?
C16 C11 C5 107.2(6) . . ?
C16 C11 C12 119.3(6) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 C11 120.5(7) . . ?
C13 C12 H12 119.8 . . ?
C12 C13 C14 118.4(6) . . ?
C12 C13 C17 120.6(7) . . ?
C14 C13 C17 120.9(7) . . ?
C13 C14 H14 119.0 . . ?
C15 C14 C13 122.0(7) . . ?
C15 C14 H14 119.0 . . ?
C14 C15 H15 120.7 . . ?
C16 C15 C14 118.6(7) . . ?
C16 C15 H15 120.7 . . ?
C11 C16 N2 108.7(6) . . ?
C15 C16 N2 129.9(6) . . ?
C15 C16 C11 121.2(6) . . ?
C18 C17 C13 109.1(7) . . ?
C19 C17 C13 109.8(7) . . ?
C19 C17 C18 109.7(8) . . ?
C19 C17 C20 107.6(8) . . ?
C20 C17 C13 112.2(7) . . ?
C20 C17 C18 108.4(8) . . ?
C17 C18 H18J 109.5 . . ?
C17 C18 H18K 109.5 . . ?
C17 C18 H18L 109.5 . . ?
H18J C18 H18K 109.5 . . ?
H18J C18 H18L 109.5 . . ?
H18K C18 H18L 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N1 C21 N2 118.2(6) . . ?
N3 C21 N1 124.6(6) . . ?
N3 C21 N2 117.1(6) . . ?
N3 C22 H22 119.1 . . ?
N3 C22 C23 121.8(7) . . ?
C23 C22 H22 119.1 . . ?
C22 C23 H23 121.6 . . ?
C24 C23 C22 116.8(7) . . ?
C24 C23 H23 121.6 . . ?
N1 C24 C23 123.9(7) . . ?
N1 C24 H24 118.1 . . ?
C23 C24 H24 118.1 . . ?
C26 C25 C36 107.8(6) . . ?
C222 C25 C26 119.8(6) . . ?
C222 C25 C36 132.4(7) . . ?
C25 C26 N6 108.2(6) . . ?
C219 C26 N6 127.5(6) . . ?
C219 C26 C25 124.3(6) . . ?
C28 C27 C29 100.0(8) . . ?
C28 C27 C221 114.7(7) . . ?
C30 C27 C28 114.8(8) . . ?
C30 C27 C29 103.7(8) . . ?
C30 C27 C221 112.7(8) . . ?
C221 C27 C29 109.4(7) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N6 C31 C32 132.0(7) . . ?
C36 C31 N6 109.2(6) . . ?
C36 C31 C32 118.7(6) . . ?
C31 C32 H32 121.0 . . ?
C33 C32 C31 118.0(7) . . ?
C33 C32 H32 121.0 . . ?
C32 C33 H33 117.8 . . ?
C32 C33 C34 124.3(7) . . ?
C34 C33 H33 117.8 . . ?
C33 C34 C37 119.8(7) . . ?
C35 C34 C33 118.0(7) . . ?
C35 C34 C37 122.2(7) . . ?
C34 C35 H35 120.5 . . ?
C34 C35 C36 119.0(7) . . ?
C36 C35 H35 120.5 . . ?
C31 C36 C25 107.2(6) . . ?
C31 C36 C35 122.0(6) . . ?
C35 C36 C25 130.7(7) . . ?
C34 C37 C40 113.7(7) . . ?
C38 C37 C34 111.0(8) . . ?
C38 C37 C39 108.3(9) . . ?
C38 C37 C40 108.1(9) . . ?
C39 C37 C34 108.6(8) . . ?
C39 C37 C40 106.9(8) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N5 C41 N4 123.3(6) . . ?
N5 C41 N6 116.2(6) . . ?
N6 C41 N4 120.5(6) . . ?
N5 C42 H42 117.9 . . ?
N5 C42 C43 124.3(7) . . ?
C43 C42 H42 117.9 . . ?
C42 C43 H43 122.3 . . ?
C44 C43 C42 115.4(7) . . ?
C44 C43 H43 122.3 . . ?
N4 C44 C43 123.3(7) . . ?
N4 C44 H44 118.3 . . ?
C43 C44 H44 118.3 . . ?
C46 C45 N7 118.5(7) . . ?
C50 C45 N7 122.1(6) . . ?
C50 C45 C46 119.4(7) . . ?
C45 C46 H46 120.2 . . ?
C45 C46 C47 119.5(8) . . ?
C47 C46 H46 120.2 . . ?
C46 C47 H47 119.7 . . ?
C48 C47 C46 120.6(8) . . ?
C48 C47 H47 119.7 . . ?
C47 C48 H48 120.4 . . ?
C49 C48 C47 119.2(7) . . ?
C49 C48 H48 120.4 . . ?
C48 C49 H49 119.9 . . ?
C48 C49 C50 120.2(8) . . ?
C50 C49 H49 119.9 . . ?
C45 C50 C49 121.0(7) . . ?
C45 C50 H50 119.5 . . ?
C49 C50 H50 119.5 . . ?
N7 C51 N8 126.2(6) . . ?
N7 C51 H51 116.9 . . ?
N8 C51 H51 116.9 . . ?
C53 C52 N8 119.5(6) . . ?
C57 C52 N8 121.8(6) . . ?
C57 C52 C53 118.6(6) . . ?
C52 C53 H53 119.7 . . ?
C54 C53 C52 120.6(7) . . ?
C54 C53 H53 119.7 . . ?
C53 C54 H54 119.9 . . ?
C53 C54 C55 120.3(7) . . ?
C55 C54 H54 119.9 . . ?
C54 C55 H55 120.2 . . ?
C56 C55 C54 119.5(7) . . ?
C56 C55 H55 120.2 . . ?
C55 C56 H56 120.1 . . ?
C57 C56 C55 119.9(7) . . ?
C57 C56 H56 120.1 . . ?
C52 C57 H57 119.5 . . ?
C56 C57 C52 121.0(7) . . ?
C56 C57 H57 119.5 . . ?
C59 C58 N10 119.8(6) . . ?
C63 C58 N10 122.0(6) . . ?
C63 C58 C59 118.2(6) . . ?
C58 C59 H59 119.9 . . ?
C60 C59 C58 120.1(7) . . ?
C60 C59 H59 119.9 . . ?
C59 C60 H60 118.8 . . ?
C61 C60 C59 122.5(8) . . ?
C61 C60 H60 118.8 . . ?
C60 C61 H61 121.0 . . ?
C60 C61 C62 117.9(7) . . ?
C62 C61 H61 121.0 . . ?
C61 C62 H62 119.2 . . ?
C61 C62 C63 121.5(7) . . ?
C63 C62 H62 119.2 . . ?
C58 C63 C62 119.8(7) . . ?
C58 C63 H63 120.1 . . ?
C62 C63 H63 120.1 . . ?
N9 C64 H64 116.3 . . ?
N10 C64 N9 127.4(6) . . ?
N10 C64 H64 116.3 . . ?
C66 C65 N9 119.9(7) . . ?
C70 C65 N9 120.3(7) . . ?
C70 C65 C66 119.8(7) . . ?
C65 C66 H66 120.1 . . ?
C65 C66 C67 119.7(8) . . ?
C67 C66 H66 120.1 . . ?
C66 C67 H67 120.3 . . ?
C68 C67 C66 119.5(8) . . ?
C68 C67 H67 120.3 . . ?
C67 C68 H68 119.6 . . ?
C67 C68 C69 120.9(8) . . ?
C69 C68 H68 119.6 . . ?
C68 C69 H69 120.2 . . ?
C70 C69 C68 119.5(8) . . ?
C70 C69 H69 120.2 . . ?
C65 C70 H70 119.7 . . ?
C69 C70 C65 120.6(8) . . ?
C69 C70 H70 119.7 . . ?
C26 C219 Pt2 122.2(5) . . ?
C26 C219 C220 112.6(6) . . ?
C220 C219 Pt2 125.2(5) . . ?
C219 C220 H220 116.9 . . ?
C219 C220 C221 126.2(6) . . ?
C221 C220 H220 116.9 . . ?
C220 C221 C27 122.7(7) . . ?
C222 C221 C27 120.1(7) . . ?
C222 C221 C220 117.0(6) . . ?
C25 C222 C221 120.1(7) . . ?
C25 C222 H222 120.0 . . ?
C221 C222 H222 120.0 . . ?
N11 Pt3 Pt4 97.91(15) . . ?
N11 Pt3 N20 92.5(2) . . ?
N18 Pt3 Pt4 82.27(15) . . ?
N18 Pt3 N11 178.0(2) . . ?
N18 Pt3 N20 85.6(2) . . ?
N20 Pt3 Pt4 83.16(14) . . ?
C71 Pt3 Pt4 92.28(19) . . ?
C71 Pt3 N11 89.4(2) . . ?
C71 Pt3 N18 92.6(2) . . ?
C71 Pt3 N20 175.3(2) . . ?
N14 Pt4 Pt3 106.92(15) . . ?
N14 Pt4 N17 91.9(2) . . ?
N17 Pt4 Pt3 79.95(15) . . ?
N19 Pt4 Pt3 79.07(15) . . ?
N19 Pt4 N14 173.0(2) . . ?
N19 Pt4 N17 85.6(2) . . ?
C95 Pt4 Pt3 101.6(2) . . ?
C95 Pt4 N14 89.7(2) . . ?
C95 Pt4 N17 177.3(3) . . ?
C95 Pt4 N19 92.5(2) . . ?
C91 N11 Pt3 124.2(4) . . ?
C91 N11 C94 115.1(6) . . ?
C94 N11 Pt3 120.7(4) . . ?
C92 N12 C91 118.2(6) . . ?
C82 N13 C80 108.5(5) . . ?
C91 N13 C80 121.5(5) . . ?
C91 N13 C82 124.2(6) . . ?
C115 N14 Pt4 128.5(4) . . ?
C115 N14 C118 115.1(5) . . ?
C118 N14 Pt4 116.1(4) . . ?
C116 N15 C115 117.9(6) . . ?
C100 N16 C106 107.6(5) . . ?
C115 N16 C100 125.1(5) . . ?
C115 N16 C106 124.9(5) . . ?
C138 N17 Pt4 122.7(4) . . ?
C138 N17 C139 115.4(6) . . ?
C139 N17 Pt4 121.6(4) . . ?
C132 N18 Pt3 118.8(4) . . ?
C138 N18 Pt3 125.2(4) . . ?
C138 N18 C132 115.6(5) . . ?
C125 N19 Pt4 128.5(5) . . ?
C125 N19 C126 117.0(5) . . ?
C126 N19 Pt4 113.8(4) . . ?
C119 N20 Pt3 124.3(4) . . ?
C125 N20 Pt3 118.6(4) . . ?
C125 N20 C119 116.3(5) . . ?
C72 C71 Pt3 127.6(5) . . ?
C80 C71 Pt3 117.8(5) . . ?
C80 C71 C72 113.9(6) . . ?
C71 C72 H72 118.3 . . ?
C71 C72 C73 123.4(6) . . ?
C73 C72 H72 118.3 . . ?
C72 C73 C74 117.8(6) . . ?
C78 C73 C72 119.6(6) . . ?
C78 C73 C74 122.2(6) . . ?
C73 C74 C76 108.3(6) . . ?
C75 C74 C73 112.4(6) . . ?
C75 C74 C76 106.9(6) . . ?
C75 C74 C77 107.0(7) . . ?
C77 C74 C73 113.1(6) . . ?
C77 C74 C76 109.0(6) . . ?
C74 C75 H75A 109.5 . . ?
C74 C75 H75B 109.5 . . ?
C74 C75 H75C 109.5 . . ?
H75A C75 H75B 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C74 C76 H76A 109.5 . . ?
C74 C76 H76B 109.5 . . ?
C74 C76 H76C 109.5 . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C74 C77 H77A 109.5 . . ?
C74 C77 H77B 109.5 . . ?
C74 C77 H77C 109.5 . . ?
H77A C77 H77B 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C73 C78 H78 120.7 . . ?
C73 C78 C79 118.7(6) . . ?
C79 C78 H78 120.7 . . ?
C78 C79 C81 133.1(6) . . ?
C80 C79 C78 119.0(6) . . ?
C80 C79 C81 107.5(6) . . ?
C71 C80 N13 126.4(6) . . ?
C71 C80 C79 125.3(6) . . ?
C79 C80 N13 107.9(5) . . ?
C82 C81 C79 106.9(6) . . ?
C82 C81 C86 119.9(6) . . ?
C86 C81 C79 133.1(6) . . ?
N13 C82 C83 129.4(6) . . ?
C81 C82 N13 109.1(6) . . ?
C81 C82 C83 121.0(6) . . ?
C82 C83 H83 121.0 . . ?
C84 C83 C82 117.9(7) . . ?
C84 C83 H83 121.0 . . ?
C83 C84 H84 118.9 . . ?
C83 C84 C85 122.2(7) . . ?
C85 C84 H84 118.9 . . ?
C84 C85 C87 119.9(6) . . ?
C86 C85 C84 118.7(6) . . ?
C86 C85 C87 121.3(6) . . ?
C81 C86 H86 119.9 . . ?
C85 C86 C81 120.1(7) . . ?
C85 C86 H86 119.9 . . ?
C85 C87 C88A 110.7(10) . . ?
C85 C87 C89A 107.1(9) . . ?
C85 C87 C88 105.8(7) . . ?
C88A C87 C89A 100.9(11) . . ?
C90A C87 C85 114.4(9) . . ?
C90A C87 C88A 118.1(13) . . ?
C90A C87 C89A 103.9(11) . . ?
C89 C87 C85 114.0(8) . . ?
C89 C87 C88 107.2(9) . . ?
C89 C87 C90 111.8(9) . . ?
C90 C87 C85 108.6(7) . . ?
C90 C87 C88 109.2(8) . . ?
N11 C91 N13 119.4(6) . . ?
N12 C91 N11 124.2(6) . . ?
N12 C91 N13 116.5(6) . . ?
N12 C92 H92 119.4 . . ?
N12 C92 C93 121.1(7) . . ?
C93 C92 H92 119.4 . . ?
C92 C93 H93 121.1 . . ?
C94 C93 C92 117.7(7) . . ?
C94 C93 H93 121.1 . . ?
N11 C94 H94 118.4 . . ?
C93 C94 N11 123.2(6) . . ?
C93 C94 H94 118.4 . . ?
C96 C95 Pt4 124.9(5) . . ?
C100 C95 Pt4 122.3(5) . . ?
C100 C95 C96 112.8(6) . . ?
C95 C96 H96 117.7 . . ?
C95 C96 C97 124.7(6) . . ?
C97 C96 H96 117.7 . . ?
C96 C97 C101 120.4(6) . . ?
C98 C97 C96 118.2(6) . . ?
C98 C97 C101 121.4(6) . . ?
C97 C98 H98 120.1 . . ?
C97 C98 C99 119.8(6) . . ?
C99 C98 H98 120.1 . . ?
C98 C99 C100 119.4(6) . . ?
C98 C99 C105 132.1(6) . . ?
C100 C99 C105 108.5(6) . . ?
C95 C100 N16 126.9(6) . . ?
C95 C100 C99 125.1(6) . . ?
C99 C100 N16 107.9(5) . . ?
C97 C101 C1D 105.1(8) . . ?
C97 C101 C102 106.6(7) . . ?
C1E C101 C97 113.4(8) . . ?
C1E C101 C1D 103.5(10) . . ?
C1F C101 C97 112.5(9) . . ?
C1F C101 C1D 103.5(10) . . ?
C1F C101 C1E 117.1(12) . . ?
C103 C101 C97 111.0(8) . . ?
C103 C101 C102 104.8(8) . . ?
C103 C101 C104 114.2(9) . . ?
C104 C101 C97 115.7(7) . . ?
C104 C101 C102 103.3(8) . . ?
C106 C105 C99 107.2(6) . . ?
C110 C105 C99 132.5(7) . . ?
C110 C105 C106 120.3(6) . . ?
C105 C106 N16 108.8(6) . . ?
C107 C106 N16 130.7(6) . . ?
C107 C106 C105 120.5(6) . . ?
C106 C107 H107 121.4 . . ?
C108 C107 C106 117.1(7) . . ?
C108 C107 H107 121.4 . . ?
C107 C108 H108 117.7 . . ?
C107 C108 C109 124.7(7) . . ?
C109 C108 H108 117.7 . . ?
C108 C109 C111 120.9(6) . . ?
C110 C109 C108 115.7(6) . . ?
C110 C109 C111 123.2(7) . . ?
C105 C110 C109 121.7(7) . . ?
C105 C110 H110 119.2 . . ?
C109 C110 H110 119.2 . . ?
C109 C111 C112 109.2(8) . . ?
C109 C111 C114 108.3(8) . . ?
C109 C111 C223 115.4(10) . . ?
C109 C111 C1G 109.3(9) . . ?
C109 C111 C1H 107.0(9) . . ?
C113 C111 C109 115.2(8) . . ?
C113 C111 C112 109.5(11) . . ?
C113 C111 C114 108.4(9) . . ?
C114 C111 C112 105.8(9) . . ?
C223 C111 C1G 109.6(13) . . ?
C223 C111 C1H 109.5(11) . . ?
C1H C111 C1G 105.6(11) . . ?
C111 C112 H11A 109.5 . . ?
C111 C112 H11B 109.5 . . ?
C111 C112 H11C 109.5 . . ?
H11A C112 H11B 109.5 . . ?
H11A C112 H11C 109.5 . . ?
H11B C112 H11C 109.5 . . ?
C111 C113 H11D 109.5 . . ?
C111 C113 H11E 109.5 . . ?
C111 C113 H11F 109.5 . . ?
H11D C113 H11E 109.5 . . ?
H11D C113 H11F 109.5 . . ?
H11E C113 H11F 109.5 . . ?
C111 C114 H11G 109.5 . . ?
C111 C114 H11H 109.5 . . ?
C111 C114 H11I 109.5 . . ?
H11G C114 H11H 109.5 . . ?
H11G C114 H11I 109.5 . . ?
H11H C114 H11I 109.5 . . ?
N14 C115 N16 119.8(6) . . ?
N15 C115 N14 125.1(6) . . ?
N15 C115 N16 115.1(6) . . ?
N15 C116 H116 118.8 . . ?
N15 C116 C117 122.4(7) . . ?
C117 C116 H116 118.8 . . ?
C116 C117 H117 121.9 . . ?
C118 C117 C116 116.3(7) . . ?
C118 C117 H117 121.9 . . ?
N14 C118 C117 123.0(6) . . ?
N14 C118 H118 118.5 . . ?
C117 C118 H118 118.5 . . ?
C120 C119 N20 119.8(6) . . ?
C120 C119 C124 119.4(6) . . ?
C124 C119 N20 120.9(6) . . ?
C119 C120 H120 119.9 . . ?
C121 C120 C119 120.2(7) . . ?
C121 C120 H120 119.9 . . ?
C120 C121 H121 119.5 . . ?
C122 C121 C120 121.0(7) . . ?
C122 C121 H121 119.5 . . ?
C121 C122 H122 120.4 . . ?
C123 C122 C121 119.2(7) . . ?
C123 C122 H122 120.4 . . ?
C122 C123 H123 119.4 . . ?
C122 C123 C124 121.1(7) . . ?
C124 C123 H123 119.4 . . ?
C119 C124 C123 119.0(7) . . ?
C119 C124 H124 120.5 . . ?
C123 C124 H124 120.5 . . ?
N19 C125 H125 116.6 . . ?
N20 C125 N19 126.7(6) . . ?
N20 C125 H125 116.6 . . ?
C127 C126 N19 119.5(7) . . ?
C131 C126 N19 120.6(7) . . ?
C131 C126 C127 119.8(7) . . ?
C126 C127 H127 121.0 . . ?
C128 C127 C126 118.0(8) . . ?
C128 C127 H127 121.0 . . ?
C127 C128 H128 118.3 . . ?
C129 C128 C127 123.4(9) . . ?
C129 C128 H128 118.3 . . ?
C128 C129 H129 120.4 . . ?
C128 C129 C130 119.1(8) . . ?
C130 C129 H129 120.4 . . ?
C129 C130 H130 120.5 . . ?
C129 C130 C131 118.9(8) . . ?
C131 C130 H130 120.5 . . ?
C126 C131 C130 120.7(8) . . ?
C126 C131 H131 119.7 . . ?
C130 C131 H131 119.7 . . ?
C133 C132 N18 119.2(6) . . ?
C137 C132 N18 121.2(6) . . ?
C137 C132 C133 119.5(6) . . ?
C132 C133 H133 120.2 . . ?
C132 C133 C134 119.6(7) . . ?
C134 C133 H133 120.2 . . ?
C133 C134 H134 120.0 . . ?
C133 C134 C135 120.0(7) . . ?
C135 C134 H134 120.0 . . ?
C134 C135 H135 120.5 . . ?
C136 C135 C134 119.0(7) . . ?
C136 C135 H135 120.5 . . ?
C135 C136 H136 119.6 . . ?
C137 C136 C135 120.8(7) . . ?
C137 C136 H136 119.6 . . ?
C132 C137 H137 119.5 . . ?
C136 C137 C132 121.0(7) . . ?
C136 C137 H137 119.5 . . ?
N17 C138 N18 125.8(6) . . ?
N17 C138 H138 117.1 . . ?
N18 C138 H138 117.1 . . ?
C140 C139 N17 119.2(6) . . ?
C144 C139 N17 122.4(6) . . ?
C144 C139 C140 118.3(6) . . ?
C139 C140 H140 120.0 . . ?
C141 C140 C139 119.9(7) . . ?
C141 C140 H140 120.0 . . ?
C140 C141 H141 119.4 . . ?
C142 C141 C140 121.2(8) . . ?
C142 C141 H141 119.4 . . ?
C141 C142 H142 119.8 . . ?
C141 C142 C143 120.3(7) . . ?
C143 C142 H142 119.8 . . ?
C142 C143 H143 120.2 . . ?
C142 C143 C144 119.6(8) . . ?
C144 C143 H143 120.2 . . ?
C139 C144 C143 120.7(7) . . ?
C139 C144 H144 119.7 . . ?
C143 C144 H144 119.7 . . ?
C101 C1D H1DA 109.5 . . ?
C101 C1D H1DB 109.5 . . ?
C101 C1D H1DC 109.5 . . ?
H1DA C1D H1DB 109.5 . . ?
H1DA C1D H1DC 109.5 . . ?
H1DB C1D H1DC 109.5 . . ?
C101 C1E H1EA 109.5 . . ?
C101 C1E H1EB 109.5 . . ?
C101 C1E H1EC 109.5 . . ?
H1EA C1E H1EB 109.5 . . ?
H1EA C1E H1EC 109.5 . . ?
H1EB C1E H1EC 109.5 . . ?
C101 C1F H1FA 109.5 . . ?
C101 C1F H1FB 109.5 . . ?
C101 C1F H1FC 109.5 . . ?
H1FA C1F H1FB 109.5 . . ?
H1FA C1F H1FC 109.5 . . ?
H1FB C1F H1FC 109.5 . . ?
C87 C88A H88A 109.5 . . ?
C87 C88A H88B 109.5 . . ?
C87 C88A H88C 109.5 . . ?
H88A C88A H88B 109.5 . . ?
H88A C88A H88C 109.5 . . ?
H88B C88A H88C 109.5 . . ?
C87 C89A H89A 109.5 . . ?
C87 C89A H89B 109.5 . . ?
C87 C89A H89C 109.5 . . ?
H89A C89A H89B 109.5 . . ?
H89A C89A H89C 109.5 . . ?
H89B C89A H89C 109.5 . . ?
C87 C90A H90A 109.5 . . ?
C87 C90A H90B 109.5 . . ?
C87 C90A H90C 109.5 . . ?
H90A C90A H90B 109.5 . . ?
H90A C90A H90C 109.5 . . ?
H90B C90A H90C 109.5 . . ?
N21 Pt5 Pt6 98.40(15) . . ?
N21 Pt5 N27 91.6(2) . . ?
N27 Pt5 Pt6 81.72(14) . . ?
N29 Pt5 Pt6 82.40(15) . . ?
N29 Pt5 N21 178.7(2) . . ?
N29 Pt5 N27 87.5(2) . . ?
C145 Pt5 Pt6 92.29(19) . . ?
C145 Pt5 N21 89.3(2) . . ?
C145 Pt5 N27 174.0(2) . . ?
C145 Pt5 N29 91.7(2) . . ?
N24 Pt6 Pt5 107.97(14) . . ?
N24 Pt6 N30 89.8(2) . . ?
N28 Pt6 Pt5 79.62(14) . . ?
N28 Pt6 N24 171.2(2) . . ?
N28 Pt6 N30 87.3(2) . . ?
N30 Pt6 Pt5 79.14(14) . . ?
C169 Pt6 Pt5 102.42(19) . . ?
C169 Pt6 N24 89.8(2) . . ?
C169 Pt6 N28 92.9(2) . . ?
C169 Pt6 N30 178.4(2) . . ?
C165 N21 Pt5 123.5(4) . . ?
C165 N21 C168 116.1(5) . . ?
C168 N21 Pt5 120.1(4) . . ?
C166 N22 C165 117.7(6) . . ?
C155 N23 C154 108.6(5) . . ?
C165 N23 C154 123.0(6) . . ?
C165 N23 C155 125.6(6) . . ?
C189 N24 Pt6 125.8(4) . . ?
C192 N24 Pt6 118.4(4) . . ?
C192 N24 C189 115.1(6) . . ?
C189 N25 C190 117.6(6) . . ?
C174 N26 C180 107.7(5) . . ?
C189 N26 C174 125.0(6) . . ?
C189 N26 C180 123.2(6) . . ?
C199 N27 Pt5 121.7(4) . . ?
C199 N27 C200 116.8(6) . . ?
C200 N27 Pt5 121.3(4) . . ?
C193 N28 Pt6 113.8(4) . . ?
C199 N28 Pt6 128.3(4) . . ?
C199 N28 C193 117.1(6) . . ?
C206 N29 Pt5 117.6(4) . . ?
C212 N29 Pt5 125.6(5) . . ?
C212 N29 C206 116.1(5) . . ?
C212 N30 Pt6 123.5(4) . . ?
C212 N30 C213 115.0(5) . . ?
C213 N30 Pt6 121.2(4) . . ?
C146 C145 Pt5 128.8(5) . . ?
C154 C145 Pt5 116.1(5) . . ?
C154 C145 C146 113.5(6) . . ?
C145 C146 H146 117.3 . . ?
C145 C146 C147 125.4(7) . . ?
C147 C146 H146 117.3 . . ?
C146 C147 C148 119.6(6) . . ?
C146 C147 C152 118.6(6) . . ?
C152 C147 C148 121.7(6) . . ?
C147 C148 C150 108.6(6) . . ?
C149 C148 C147 111.4(6) . . ?
C149 C148 C150 109.2(7) . . ?
C151 C148 C147 112.5(7) . . ?
C151 C148 C149 108.9(7) . . ?
C151 C148 C150 106.1(6) . . ?
C148 C149 H14A 109.5 . . ?
C148 C149 H14B 109.5 . . ?
C148 C149 H14C 109.5 . . ?
H14A C149 H14B 109.5 . . ?
H14A C149 H14C 109.5 . . ?
H14B C149 H14C 109.5 . . ?
C148 C150 H15A 109.5 . . ?
C148 C150 H15B 109.5 . . ?
C148 C150 H15C 109.5 . . ?
H15A C150 H15B 109.5 . . ?
H15A C150 H15C 109.5 . . ?
H15B C150 H15C 109.5 . . ?
C148 C151 H15D 109.5 . . ?
C148 C151 H15E 109.5 . . ?
C148 C151 H15F 109.5 . . ?
H15D C151 H15E 109.5 . . ?
H15D C151 H15F 109.5 . . ?
H15E C151 H15F 109.5 . . ?
C147 C152 H152 120.8 . . ?
C153 C152 C147 118.5(6) . . ?
C153 C152 H152 120.8 . . ?
C152 C153 C154 119.5(6) . . ?
C152 C153 C160 132.9(6) . . ?
C154 C153 C160 106.8(6) . . ?
C145 C154 N23 127.2(6) . . ?
C145 C154 C153 124.2(6) . . ?
C153 C154 N23 108.0(6) . . ?
C156 C155 N23 130.1(6) . . ?
C156 C155 C160 120.6(6) . . ?
C160 C155 N23 108.9(6) . . ?
C155 C156 H156 121.7 . . ?
C157 C156 C155 116.6(7) . . ?
C157 C156 H156 121.7 . . ?
C156 C157 H157 117.3 . . ?
C156 C157 C158 125.5(8) . . ?
C158 C157 H157 117.3 . . ?
C157 C158 C159 117.2(7) . . ?
C157 C158 C161 120.0(7) . . ?
C159 C158 C161 122.8(7) . . ?
C158 C159 H159 120.2 . . ?
C160 C159 C158 119.6(7) . . ?
C160 C159 H159 120.2 . . ?
C155 C160 C153 107.3(6) . . ?
C159 C160 C153 132.1(7) . . ?
C159 C160 C155 120.5(7) . . ?
C158 C161 C1B 107.6(9) . . ?
C158 C161 C1C 109.7(10) . . ?
C158 C161 C162 108.6(8) . . ?
C158 C161 C164 109.9(9) . . ?
C1A C161 C158 118.7(11) . . ?
C1A C161 C1B 105.9(12) . . ?
C1A C161 C1C 113.1(13) . . ?
C1C C161 C1B 99.9(11) . . ?
C162 C161 C164 103.6(10) . . ?
C163 C161 C158 116.8(10) . . ?
C163 C161 C162 106.9(10) . . ?
C163 C161 C164 110.1(10) . . ?
N21 C165 N23 118.7(6) . . ?
N22 C165 N21 123.8(6) . . ?
N22 C165 N23 117.4(6) . . ?
N22 C166 H166 118.6 . . ?
N22 C166 C167 122.8(7) . . ?
C167 C166 H166 118.6 . . ?
C166 C167 H167 121.9 . . ?
C168 C167 C166 116.3(7) . . ?
C168 C167 H167 121.9 . . ?
N21 C168 C167 123.0(7) . . ?
N21 C168 H168 118.5 . . ?
C167 C168 H168 118.5 . . ?
C170 C169 Pt6 126.3(5) . . ?
C174 C169 Pt6 119.9(5) . . ?
C174 C169 C170 113.6(6) . . ?
C169 C170 H170 118.0 . . ?
C171 C170 C169 124.0(6) . . ?
C171 C170 H170 118.0 . . ?
C170 C171 C175 121.9(6) . . ?
C172 C171 C170 118.8(6) . . ?
C172 C171 C175 119.0(6) . . ?
C171 C172 H172 120.4 . . ?
C171 C172 C173 119.3(6) . . ?
C173 C172 H172 120.4 . . ?
C172 C173 C179 131.3(6) . . ?
C174 C173 C172 120.1(6) . . ?
C174 C173 C179 108.2(6) . . ?
C169 C174 N26 127.0(6) . . ?
C173 C174 N26 108.8(6) . . ?
C173 C174 C169 124.1(6) . . ?
C171 C175 C178 107.7(6) . . ?
C176 C175 C171 112.9(6) . . ?
C176 C175 C177 109.3(6) . . ?
C176 C175 C178 108.5(6) . . ?
C177 C175 C171 110.2(6) . . ?
C177 C175 C178 108.2(6) . . ?
C175 C176 H17A 109.5 . . ?
C175 C176 H17B 109.5 . . ?
C175 C176 H17C 109.5 . . ?
H17A C176 H17B 109.5 . . ?
H17A C176 H17C 109.5 . . ?
H17B C176 H17C 109.5 . . ?
C175 C177 H17D 109.5 . . ?
C175 C177 H17E 109.5 . . ?
C175 C177 H17F 109.5 . . ?
H17D C177 H17E 109.5 . . ?
H17D C177 H17F 109.5 . . ?
H17E C177 H17F 109.5 . . ?
C175 C178 H17G 109.5 . . ?
C175 C178 H17H 109.5 . . ?
C175 C178 H17I 109.5 . . ?
H17G C178 H17H 109.5 . . ?
H17G C178 H17I 109.5 . . ?
H17H C178 H17I 109.5 . . ?
C180 C179 C173 107.0(6) . . ?
C184 C179 C173 133.5(6) . . ?
C184 C179 C180 119.3(6) . . ?
C179 C180 N26 108.1(6) . . ?
C181 C180 N26 131.0(6) . . ?
C181 C180 C179 120.7(6) . . ?
C180 C181 H181 120.9 . . ?
C180 C181 C182 118.2(7) . . ?
C182 C181 H181 120.9 . . ?
C181 C182 H182 119.1 . . ?
C181 C182 C183 121.9(7) . . ?
C183 C182 H182 119.1 . . ?
C182 C183 C185 117.7(7) . . ?
C184 C183 C182 118.3(7) . . ?
C184 C183 C185 124.0(7) . . ?
C179 C184 H184 119.2 . . ?
C183 C184 C179 121.6(7) . . ?
C183 C184 H184 119.2 . . ?
C183 C185 C187 110.9(7) . . ?
C186 C185 C183 107.9(7) . . ?
C186 C185 C187 110.0(7) . . ?
C188 C185 C183 110.7(7) . . ?
C188 C185 C186 108.8(8) . . ?
C188 C185 C187 108.5(8) . . ?
C185 C186 H18A 109.5 . . ?
C185 C186 H18B 109.5 . . ?
C185 C186 H18C 109.5 . . ?
H18A C186 H18B 109.5 . . ?
H18A C186 H18C 109.5 . . ?
H18B C186 H18C 109.5 . . ?
C185 C187 H18D 109.5 . . ?
C185 C187 H18E 109.5 . . ?
C185 C187 H18F 109.5 . . ?
H18D C187 H18E 109.5 . . ?
H18D C187 H18F 109.5 . . ?
H18E C187 H18F 109.5 . . ?
C185 C188 H18G 109.5 . . ?
C185 C188 H18H 109.5 . . ?
C185 C188 H18I 109.5 . . ?
H18G C188 H18H 109.5 . . ?
H18G C188 H18I 109.5 . . ?
H18H C188 H18I 109.5 . . ?
N24 C189 N26 118.9(6) . . ?
N25 C189 N24 125.1(6) . . ?
N25 C189 N26 116.1(6) . . ?
N25 C190 H190 119.0 . . ?
N25 C190 C191 122.1(6) . . ?
C191 C190 H190 119.0 . . ?
C190 C191 H191 121.6 . . ?
C190 C191 C192 116.8(7) . . ?
C192 C191 H191 121.6 . . ?
N24 C192 C191 123.0(7) . . ?
N24 C192 H192 118.5 . . ?
C191 C192 H192 118.5 . . ?
C194 C193 N28 119.9(6) . . ?
C194 C193 C198 118.5(6) . . ?
C198 C193 N28 121.7(6) . . ?
C193 C194 H194 119.6 . . ?
C195 C194 C193 120.9(7) . . ?
C195 C194 H194 119.6 . . ?
C194 C195 H195 120.1 . . ?
C196 C195 C194 119.8(7) . . ?
C196 C195 H195 120.1 . . ?
C195 C196 H196 119.9 . . ?
C197 C196 C195 120.2(7) . . ?
C197 C196 H196 119.9 . . ?
C196 C197 H197 119.6 . . ?
C196 C197 C198 120.8(7) . . ?
C198 C197 H197 119.6 . . ?
C193 C198 H198 120.0 . . ?
C197 C198 C193 119.9(7) . . ?
C197 C198 H198 120.0 . . ?
N27 C199 N28 126.6(6) . . ?
N27 C199 H199 116.7 . . ?
N28 C199 H199 116.7 . . ?
C201 C200 N27 122.9(7) . . ?
C201 C200 C205 118.1(7) . . ?
C205 C200 N27 118.9(6) . . ?
C200 C201 H201 119.5 . . ?
C202 C201 C200 121.0(7) . . ?
C202 C201 H201 119.5 . . ?
C201 C202 H202 119.6 . . ?
C201 C202 C203 120.8(7) . . ?
C203 C202 H202 119.6 . . ?
C202 C203 H203 120.5 . . ?
C204 C203 C202 119.1(7) . . ?
C204 C203 H203 120.5 . . ?
C203 C204 H204 120.0 . . ?
C203 C204 C205 120.0(7) . . ?
C205 C204 H204 120.0 . . ?
C200 C205 H205 119.5 . . ?
C204 C205 C200 121.0(7) . . ?
C204 C205 H205 119.5 . . ?
C207 C206 N29 119.4(6) . . ?
C211 C206 N29 121.8(6) . . ?
C211 C206 C207 118.8(7) . . ?
C206 C207 H207 119.8 . . ?
C208 C207 C206 120.5(7) . . ?
C208 C207 H207 119.8 . . ?
C207 C208 H208 120.1 . . ?
C207 C208 C209 119.7(8) . . ?
C209 C208 H208 120.1 . . ?
C208 C209 H209 120.1 . . ?
C210 C209 C208 119.9(8) . . ?
C210 C209 H209 120.1 . . ?
C209 C210 H210 120.1 . . ?
C209 C210 C211 119.8(8) . . ?
C211 C210 H210 120.1 . . ?
C206 C211 C210 121.3(8) . . ?
C206 C211 H211 119.3 . . ?
C210 C211 H211 119.3 . . ?
N29 C212 N30 127.0(6) . . ?
N29 C212 H212 116.5 . . ?
N30 C212 H212 116.5 . . ?
C214 C213 N30 122.0(6) . . ?
C218 C213 N30 120.0(6) . . ?
C218 C213 C214 118.0(6) . . ?
C213 C214 H214 120.0 . . ?
C215 C214 C213 120.1(7) . . ?
C215 C214 H214 120.0 . . ?
C214 C215 H215 119.3 . . ?
C216 C215 C214 121.3(7) . . ?
C216 C215 H215 119.3 . . ?
C215 C216 H216 120.1 . . ?
C215 C216 C217 119.8(7) . . ?
C217 C216 H216 120.1 . . ?
C216 C217 H217 120.4 . . ?
C218 C217 C216 119.3(7) . . ?
C218 C217 H217 120.4 . . ?
C213 C218 C217 121.3(7) . . ?
C213 C218 H218 119.3 . . ?
C217 C218 H218 119.3 . . ?
C161 C1A H1AA 109.5 . . ?
C161 C1A H1AB 109.5 . . ?
C161 C1A H1AC 109.5 . . ?
H1AA C1A H1AB 109.5 . . ?
H1AA C1A H1AC 109.5 . . ?
H1AB C1A H1AC 109.5 . . ?
C161 C1B H1BA 109.5 . . ?
C161 C1B H1BB 109.5 . . ?
C161 C1B H1BC 109.5 . . ?
H1BA C1B H1BB 109.5 . . ?
H1BA C1B H1BC 109.5 . . ?
H1BB C1B H1BC 109.5 . . ?
C161 C1C H1CA 109.5 . . ?
C161 C1C H1CB 109.5 . . ?
C161 C1C H1CC 109.5 . . ?
H1CA C1C H1CB 109.5 . . ?
H1CA C1C H1CC 109.5 . . ?
H1CB C1C H1CC 109.5 . . ?
C87 C88 H88D 109.5 . . ?
C87 C88 H88E 109.5 . . ?
C87 C88 H88F 109.5 . . ?
H88D C88 H88E 109.5 . . ?
H88D C88 H88F 109.5 . . ?
H88E C88 H88F 109.5 . . ?
C87 C89 H89D 109.5 . . ?
C87 C89 H89E 109.5 . . ?
C87 C89 H89F 109.5 . . ?
H89D C89 H89E 109.5 . . ?
H89D C89 H89F 109.5 . . ?
H89E C89 H89F 109.5 . . ?
C87 C90 H90D 109.5 . . ?
C87 C90 H90E 109.5 . . ?
C87 C90 H90F 109.5 . . ?
H90D C90 H90E 109.5 . . ?
H90D C90 H90F 109.5 . . ?
H90E C90 H90F 109.5 . . ?
C101 C102 H10A 109.5 . . ?
C101 C102 H10B 109.5 . . ?
C101 C102 H10C 109.5 . . ?
H10A C102 H10B 109.5 . . ?
H10A C102 H10C 109.5 . . ?
H10B C102 H10C 109.5 . . ?
C101 C103 H10D 109.5 . . ?
C101 C103 H10E 109.5 . . ?
C101 C103 H10F 109.5 . . ?
H10D C103 H10E 109.5 . . ?
H10D C103 H10F 109.5 . . ?
H10E C103 H10F 109.5 . . ?
C101 C104 H10G 109.5 . . ?
C101 C104 H10H 109.5 . . ?
C101 C104 H10I 109.5 . . ?
H10G C104 H10H 109.5 . . ?
H10G C104 H10I 109.5 . . ?
H10H C104 H10I 109.5 . . ?
C161 C162 H16A 109.5 . . ?
C161 C162 H16B 109.5 . . ?
C161 C162 H16C 109.5 . . ?
H16A C162 H16B 109.5 . . ?
H16A C162 H16C 109.5 . . ?
H16B C162 H16C 109.5 . . ?
C161 C163 H16D 109.5 . . ?
C161 C163 H16E 109.5 . . ?
C161 C163 H16F 109.5 . . ?
H16D C163 H16E 109.5 . . ?
H16D C163 H16F 109.5 . . ?
H16E C163 H16F 109.5 . . ?
C161 C164 H16G 109.5 . . ?
C161 C164 H16H 109.5 . . ?
C161 C164 H16I 109.5 . . ?
H16G C164 H16H 109.5 . . ?
H16G C164 H16I 109.5 . . ?
H16H C164 H16I 109.5 . . ?
C111 C223 H22A 109.5 . . ?
C111 C223 H22B 109.5 . . ?
C111 C223 H22C 109.5 . . ?
H22A C223 H22B 109.5 . . ?
H22A C223 H22C 109.5 . . ?
H22B C223 H22C 109.5 . . ?
C111 C1G H1GA 109.5 . . ?
C111 C1G H1GB 109.5 . . ?
C111 C1G H1GC 109.5 . . ?
H1GA C1G H1GB 109.5 . . ?
H1GA C1G H1GC 109.5 . . ?
H1GB C1G H1GC 109.5 . . ?
C111 C1H H1HA 109.5 . . ?
C111 C1H H1HB 109.5 . . ?
C111 C1H H1HC 109.5 . . ?
H1HA C1H H1HB 109.5 . . ?
H1HA C1H H1HC 109.5 . . ?
H1HB C1H H1HC 109.5 . . ?
C225 O1 H1 134.4 . . ?
O1 C225 H22D 109.5 . . ?
O1 C225 H22E 109.5 . . ?
O1 C225 H22F 109.5 . . ?
H22D C225 H22E 109.5 . . ?
H22D C225 H22F 109.5 . . ?
H22E C225 H22F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N1 C21 N2 -17.1(8) . . . . ?
Pt1 N1 C21 N3 165.8(5) . . . . ?
Pt1 N1 C24 C23 -168.4(5) . . . . ?
Pt1 N8 C51 N7 -5.0(10) . . . . ?
Pt1 N8 C52 C53 -45.1(8) . . . . ?
Pt1 N8 C52 C57 132.2(6) . . . . ?
Pt1 N10 C58 C59 -27.5(9) . . . . ?
Pt1 N10 C58 C63 151.1(5) . . . . ?
Pt1 N10 C64 N9 -17.4(9) . . . . ?
Pt1 C1 C2 C3 167.6(5) . . . . ?
Pt1 C1 C6 N2 10.3(9) . . . . ?
Pt1 C1 C6 C5 -163.7(5) . . . . ?
Pt2 N4 C41 N5 -162.1(5) . . . . ?
Pt2 N4 C41 N6 19.7(9) . . . . ?
Pt2 N4 C44 C43 166.8(5) . . . . ?
Pt2 N7 C45 C46 -31.2(8) . . . . ?
Pt2 N7 C45 C50 147.9(6) . . . . ?
Pt2 N7 C51 N8 -14.4(9) . . . . ?
Pt2 N9 C64 N10 -0.6(10) . . . . ?
Pt2 N9 C65 C66 111.8(7) . . . . ?
Pt2 N9 C65 C70 -67.8(8) . . . . ?
Pt2 C219 C220 C221 -176.7(6) . . . . ?
N3 C22 C23 C24 -4.0(11) . . . . ?
N5 C42 C43 C44 4.2(11) . . . . ?
N6 C26 C219 Pt2 -0.6(9) . . . . ?
N6 C26 C219 C220 -178.6(6) . . . . ?
N6 C31 C32 C33 178.8(7) . . . . ?
N6 C31 C36 C25 -2.3(8) . . . . ?
N6 C31 C36 C35 -180.0(6) . . . . ?
N7 C45 C46 C47 -179.7(6) . . . . ?
N7 C45 C50 C49 178.8(7) . . . . ?
N8 C52 C53 C54 176.9(7) . . . . ?
N8 C52 C57 C56 -176.8(7) . . . . ?
N9 C65 C66 C67 179.3(7) . . . . ?
N9 C65 C70 C69 -177.7(8) . . . . ?
N10 C58 C59 C60 178.0(6) . . . . ?
N10 C58 C63 C62 -178.9(6) . . . . ?
C1 C2 C3 C4 -3.4(11) . . . . ?
C1 C2 C3 C7 179.2(7) . . . . ?
C2 C1 C6 N2 179.8(6) . . . . ?
C2 C1 C6 C5 5.8(10) . . . . ?
C2 C3 C4 C5 2.6(10) . . . . ?
C2 C3 C7 C8 174.9(8) . . . . ?
C2 C3 C7 C9 57.2(10) . . . . ?
C2 C3 C7 C10 -59.7(10) . . . . ?
C3 C4 C5 C6 1.9(10) . . . . ?
C3 C4 C5 C11 -174.7(7) . . . . ?
C4 C3 C7 C8 -2.4(12) . . . . ?
C4 C3 C7 C9 -120.1(8) . . . . ?
C4 C3 C7 C10 122.9(9) . . . . ?
C4 C5 C6 N2 178.4(6) . . . . ?
C4 C5 C6 C1 -6.6(10) . . . . ?
C4 C5 C11 C12 4.0(13) . . . . ?
C4 C5 C11 C16 178.9(7) . . . . ?
C5 C11 C12 C13 174.9(7) . . . . ?
C5 C11 C16 N2 0.9(7) . . . . ?
C5 C11 C16 C15 -174.9(6) . . . . ?
C6 N2 C16 C11 -3.5(7) . . . . ?
C6 N2 C16 C15 171.9(6) . . . . ?
C6 N2 C21 N1 -24.9(9) . . . . ?
C6 N2 C21 N3 152.5(6) . . . . ?
C6 C1 C2 C3 -0.7(10) . . . . ?
C6 C5 C11 C12 -172.9(7) . . . . ?
C6 C5 C11 C16 2.1(7) . . . . ?
C7 C3 C4 C5 179.9(7) . . . . ?
C11 C5 C6 N2 -4.2(7) . . . . ?
C11 C5 C6 C1 170.8(6) . . . . ?
C11 C12 C13 C14 -1.6(11) . . . . ?
C11 C12 C13 C17 -178.2(7) . . . . ?
C12 C11 C16 N2 176.7(6) . . . . ?
C12 C11 C16 C15 0.8(10) . . . . ?
C12 C13 C14 C15 1.5(11) . . . . ?
C12 C13 C17 C18 -57.9(10) . . . . ?
C12 C13 C17 C19 62.4(10) . . . . ?
C12 C13 C17 C20 -178.0(8) . . . . ?
C13 C14 C15 C16 -0.2(10) . . . . ?
C14 C13 C17 C18 125.7(8) . . . . ?
C14 C13 C17 C19 -114.0(9) . . . . ?
C14 C13 C17 C20 5.5(11) . . . . ?
C14 C15 C16 N2 -175.9(6) . . . . ?
C14 C15 C16 C11 -1.0(10) . . . . ?
C16 N2 C6 C1 -170.3(6) . . . . ?
C16 N2 C6 C5 4.7(7) . . . . ?
C16 N2 C21 N1 178.1(6) . . . . ?
C16 N2 C21 N3 -4.5(9) . . . . ?
C16 C11 C12 C13 0.5(10) . . . . ?
C17 C13 C14 C15 178.0(7) . . . . ?
C21 N1 C24 C23 4.9(10) . . . . ?
C21 N2 C6 C1 29.4(10) . . . . ?
C21 N2 C6 C5 -155.6(6) . . . . ?
C21 N2 C16 C11 156.7(6) . . . . ?
C21 N2 C16 C15 -27.9(10) . . . . ?
C21 N3 C22 C23 2.0(10) . . . . ?
C22 N3 C21 N1 3.8(10) . . . . ?
C22 N3 C21 N2 -173.3(6) . . . . ?
C22 C23 C24 N1 0.2(11) . . . . ?
C24 N1 C21 N2 170.0(6) . . . . ?
C24 N1 C21 N3 -7.1(9) . . . . ?
C25 C26 C219 Pt2 177.0(5) . . . . ?
C25 C26 C219 C220 -1.0(10) . . . . ?
C26 N6 C31 C32 -173.7(8) . . . . ?
C26 N6 C31 C36 3.0(7) . . . . ?
C26 N6 C41 N4 6.3(10) . . . . ?
C26 N6 C41 N5 -172.0(6) . . . . ?
C26 C25 C36 C31 0.8(8) . . . . ?
C26 C25 C36 C35 178.2(7) . . . . ?
C26 C25 C222 C221 -0.8(11) . . . . ?
C26 C219 C220 C221 1.2(10) . . . . ?
C27 C221 C222 C25 -175.2(7) . . . . ?
C28 C27 C221 C220 18.7(13) . . . . ?
C28 C27 C221 C222 -165.3(8) . . . . ?
C29 C27 C221 C220 130.1(8) . . . . ?
C29 C27 C221 C222 -53.9(10) . . . . ?
C30 C27 C221 C220 -115.1(9) . . . . ?
C30 C27 C221 C222 60.8(11) . . . . ?
C31 N6 C26 C25 -2.5(7) . . . . ?
C31 N6 C26 C219 175.5(6) . . . . ?
C31 N6 C41 N4 171.7(6) . . . . ?
C31 N6 C41 N5 -6.7(10) . . . . ?
C31 C32 C33 C34 -0.9(13) . . . . ?
C32 C31 C36 C25 174.8(6) . . . . ?
C32 C31 C36 C35 -2.8(11) . . . . ?
C32 C33 C34 C35 -0.4(13) . . . . ?
C32 C33 C34 C37 178.9(8) . . . . ?
C33 C34 C35 C36 0.1(12) . . . . ?
C33 C34 C37 C38 -57.2(12) . . . . ?
C33 C34 C37 C39 61.7(11) . . . . ?
C33 C34 C37 C40 -179.4(9) . . . . ?
C34 C35 C36 C25 -175.5(7) . . . . ?
C34 C35 C36 C31 1.5(11) . . . . ?
C35 C34 C37 C38 122.2(10) . . . . ?
C35 C34 C37 C39 -118.9(10) . . . . ?
C35 C34 C37 C40 0.0(13) . . . . ?
C36 C25 C26 N6 1.0(8) . . . . ?
C36 C25 C26 C219 -176.9(6) . . . . ?
C36 C25 C222 C221 176.4(7) . . . . ?
C36 C31 C32 C33 2.4(11) . . . . ?
C37 C34 C35 C36 -179.2(8) . . . . ?
C41 N4 C44 C43 -5.2(9) . . . . ?
C41 N5 C42 C43 -0.8(11) . . . . ?
C41 N6 C26 C25 165.0(6) . . . . ?
C41 N6 C26 C219 -17.1(11) . . . . ?
C41 N6 C31 C32 18.7(12) . . . . ?
C41 N6 C31 C36 -164.7(6) . . . . ?
C42 N5 C41 N4 -6.2(10) . . . . ?
C42 N5 C41 N6 172.1(6) . . . . ?
C42 C43 C44 N4 -0.9(10) . . . . ?
C44 N4 C41 N5 9.0(9) . . . . ?
C44 N4 C41 N6 -169.2(6) . . . . ?
C45 N7 C51 N8 169.5(6) . . . . ?
C45 C46 C47 C48 0.6(12) . . . . ?
C46 C45 C50 C49 -2.1(11) . . . . ?
C46 C47 C48 C49 -1.4(12) . . . . ?
C47 C48 C49 C50 0.4(12) . . . . ?
C48 C49 C50 C45 1.3(12) . . . . ?
C50 C45 C46 C47 1.1(11) . . . . ?
C51 N7 C45 C46 145.0(7) . . . . ?
C51 N7 C45 C50 -35.9(9) . . . . ?
C51 N8 C52 C53 140.8(7) . . . . ?
C51 N8 C52 C57 -41.8(9) . . . . ?
C52 N8 C51 N7 168.5(6) . . . . ?
C52 C53 C54 C55 1.4(12) . . . . ?
C53 C52 C57 C56 0.6(11) . . . . ?
C53 C54 C55 C56 -2.3(12) . . . . ?
C54 C55 C56 C57 2.4(12) . . . . ?
C55 C56 C57 C52 -1.5(12) . . . . ?
C57 C52 C53 C54 -0.5(11) . . . . ?
C58 N10 C64 N9 169.0(7) . . . . ?
C58 C59 C60 C61 0.9(12) . . . . ?
C59 C58 C63 C62 -0.3(10) . . . . ?
C59 C60 C61 C62 -0.1(12) . . . . ?
C60 C61 C62 C63 -0.9(12) . . . . ?
C61 C62 C63 C58 1.1(11) . . . . ?
C63 C58 C59 C60 -0.7(10) . . . . ?
C64 N9 C65 C66 -61.8(9) . . . . ?
C64 N9 C65 C70 118.5(8) . . . . ?
C64 N10 C58 C59 145.7(7) . . . . ?
C64 N10 C58 C63 -35.8(9) . . . . ?
C65 N9 C64 N10 171.9(7) . . . . ?
C65 C66 C67 C68 -0.6(13) . . . . ?
C66 C65 C70 C69 2.6(12) . . . . ?
C66 C67 C68 C69 0.7(14) . . . . ?
C67 C68 C69 C70 0.8(14) . . . . ?
C68 C69 C70 C65 -2.5(14) . . . . ?
C70 C65 C66 C67 -1.1(12) . . . . ?
C219 C220 C221 C27 174.9(7) . . . . ?
C219 C220 C221 C222 -1.2(11) . . . . ?
C220 C221 C222 C25 1.0(11) . . . . ?
C222 C25 C26 N6 178.9(6) . . . . ?
C222 C25 C26 C219 0.9(11) . . . . ?
C222 C25 C36 C31 -176.7(8) . . . . ?
C222 C25 C36 C35 0.7(14) . . . . ?
Pt3 N11 C91 N12 170.6(5) . . . . ?
Pt3 N11 C91 N13 -9.7(9) . . . . ?
Pt3 N11 C94 C93 -174.1(6) . . . . ?
Pt3 N18 C132 C133 -50.9(8) . . . . ?
Pt3 N18 C132 C137 125.5(6) . . . . ?
Pt3 N18 C138 N17 -4.8(9) . . . . ?
Pt3 N20 C119 C120 -26.6(8) . . . . ?
Pt3 N20 C119 C124 151.9(5) . . . . ?
Pt3 N20 C125 N19 -18.5(9) . . . . ?
Pt3 C71 C72 C73 168.6(5) . . . . ?
Pt3 C71 C80 N13 5.3(9) . . . . ?
Pt3 C71 C80 C79 -166.6(6) . . . . ?
Pt4 N14 C115 N15 -167.9(6) . . . . ?
Pt4 N14 C115 N16 12.9(10) . . . . ?
Pt4 N14 C118 C117 169.4(6) . . . . ?
Pt4 N17 C138 N18 -15.6(9) . . . . ?
Pt4 N17 C139 C140 -31.6(8) . . . . ?
Pt4 N17 C139 C144 145.9(6) . . . . ?
Pt4 N19 C125 N20 0.2(10) . . . . ?
Pt4 N19 C126 C127 -63.4(8) . . . . ?
Pt4 N19 C126 C131 116.3(6) . . . . ?
Pt4 C95 C96 C97 -174.6(6) . . . . ?
Pt4 C95 C100 N16 -3.6(11) . . . . ?
Pt4 C95 C100 C99 173.8(6) . . . . ?
N12 C92 C93 C94 -3.8(12) . . . . ?
N13 C82 C83 C84 -174.1(7) . . . . ?
N15 C116 C117 C118 2.2(12) . . . . ?
N16 C106 C107 C108 -178.6(8) . . . . ?
N17 C139 C140 C141 178.8(7) . . . . ?
N17 C139 C144 C143 -178.8(6) . . . . ?
N18 C132 C133 C134 178.5(6) . . . . ?
N18 C132 C137 C136 -179.5(6) . . . . ?
N19 C126 C127 C128 178.1(7) . . . . ?
N19 C126 C131 C130 -178.6(7) . . . . ?
N20 C119 C120 C121 179.6(6) . . . . ?
N20 C119 C124 C123 -179.8(6) . . . . ?
C71 C72 C73 C74 -175.1(6) . . . . ?
C71 C72 C73 C78 -1.5(11) . . . . ?
C72 C71 C80 N13 176.0(6) . . . . ?
C72 C71 C80 C79 4.1(10) . . . . ?
C72 C73 C74 C75 -50.5(9) . . . . ?
C72 C73 C74 C76 67.3(8) . . . . ?
C72 C73 C74 C77 -171.8(7) . . . . ?
C72 C73 C78 C79 1.2(10) . . . . ?
C73 C78 C79 C80 1.6(10) . . . . ?
C73 C78 C79 C81 -169.6(7) . . . . ?
C74 C73 C78 C79 174.5(7) . . . . ?
C78 C73 C74 C75 136.0(7) . . . . ?
C78 C73 C74 C76 -106.1(8) . . . . ?
C78 C73 C74 C77 14.7(10) . . . . ?
C78 C79 C80 N13 -177.7(6) . . . . ?
C78 C79 C80 C71 -4.6(11) . . . . ?
C78 C79 C81 C82 174.7(8) . . . . ?
C78 C79 C81 C86 -1.2(14) . . . . ?
C79 C81 C82 N13 0.1(8) . . . . ?
C79 C81 C82 C83 -172.2(7) . . . . ?
C79 C81 C86 C85 173.8(8) . . . . ?
C80 N13 C82 C81 -2.8(8) . . . . ?
C80 N13 C82 C83 168.7(7) . . . . ?
C80 N13 C91 N11 -33.5(9) . . . . ?
C80 N13 C91 N12 146.2(6) . . . . ?
C80 C71 C72 C73 -1.0(10) . . . . ?
C80 C79 C81 C82 2.7(8) . . . . ?
C80 C79 C81 C86 -173.1(8) . . . . ?
C81 C79 C80 N13 -4.4(8) . . . . ?
C81 C79 C80 C71 168.8(7) . . . . ?
C81 C82 C83 C84 -3.5(11) . . . . ?
C82 N13 C80 C71 -168.5(7) . . . . ?
C82 N13 C80 C79 4.5(7) . . . . ?
C82 N13 C91 N11 176.4(6) . . . . ?
C82 N13 C91 N12 -3.9(10) . . . . ?
C82 C81 C86 C85 -1.6(11) . . . . ?
C82 C83 C84 C85 0.1(12) . . . . ?
C83 C84 C85 C86 2.5(12) . . . . ?
C83 C84 C85 C87 179.8(7) . . . . ?
C84 C85 C86 C81 -1.7(12) . . . . ?
C84 C85 C87 C88A -55.9(13) . . . . ?
C84 C85 C87 C89A 53.2(12) . . . . ?
C84 C85 C87 C90A 167.7(11) . . . . ?
C84 C85 C87 C88 -112.0(9) . . . . ?
C84 C85 C87 C89 5.6(12) . . . . ?
C84 C85 C87 C90 130.8(9) . . . . ?
C86 C81 C82 N13 176.6(6) . . . . ?
C86 C81 C82 C83 4.3(11) . . . . ?
C86 C85 C87 C88A 121.3(11) . . . . ?
C86 C85 C87 C89A -129.6(11) . . . . ?
C86 C85 C87 C90A -15.1(14) . . . . ?
C86 C85 C87 C88 65.2(10) . . . . ?
C86 C85 C87 C89 -177.2(10) . . . . ?
C86 C85 C87 C90 -52.0(11) . . . . ?
C87 C85 C86 C81 -179.0(7) . . . . ?
C91 N11 C94 C93 5.4(10) . . . . ?
C91 N12 C92 C93 0.6(12) . . . . ?
C91 N13 C80 C71 37.2(10) . . . . ?
C91 N13 C80 C79 -149.7(6) . . . . ?
C91 N13 C82 C81 150.6(6) . . . . ?
C91 N13 C82 C83 -38.0(11) . . . . ?
C92 N12 C91 N11 6.1(11) . . . . ?
C92 N12 C91 N13 -173.6(7) . . . . ?
C92 C93 C94 N11 0.6(12) . . . . ?
C94 N11 C91 N12 -8.9(10) . . . . ?
C94 N11 C91 N13 170.8(6) . . . . ?
C95 C96 C97 C98 -0.4(11) . . . . ?
C95 C96 C97 C101 176.3(7) . . . . ?
C96 C95 C100 N16 179.2(7) . . . . ?
C96 C95 C100 C99 -3.4(11) . . . . ?
C96 C97 C98 C99 -1.1(11) . . . . ?
C96 C97 C101 C1D -55.8(10) . . . . ?
C96 C97 C101 C1E -168.1(10) . . . . ?
C96 C97 C101 C1F 56.2(12) . . . . ?
C96 C97 C101 C102 126.6(9) . . . . ?
C96 C97 C101 C103 -119.8(9) . . . . ?
C96 C97 C101 C104 12.3(11) . . . . ?
C97 C98 C99 C100 0.3(11) . . . . ?
C97 C98 C99 C105 179.3(8) . . . . ?
C98 C97 C101 C1D 120.8(9) . . . . ?
C98 C97 C101 C1E 8.5(13) . . . . ?
C98 C97 C101 C1F -127.2(11) . . . . ?
C98 C97 C101 C102 -56.8(10) . . . . ?
C98 C97 C101 C103 56.8(11) . . . . ?
C98 C97 C101 C104 -171.1(9) . . . . ?
C98 C99 C100 N16 180.0(6) . . . . ?
C98 C99 C100 C95 2.2(12) . . . . ?
C98 C99 C105 C106 -179.1(8) . . . . ?
C98 C99 C105 C110 1.9(15) . . . . ?
C99 C105 C106 N16 -0.6(8) . . . . ?
C99 C105 C106 C107 177.6(7) . . . . ?
C99 C105 C110 C109 178.7(8) . . . . ?
C100 N16 C106 C105 1.1(8) . . . . ?
C100 N16 C106 C107 -176.9(8) . . . . ?
C100 N16 C115 N14 14.8(11) . . . . ?
C100 N16 C115 N15 -164.4(7) . . . . ?
C100 C95 C96 C97 2.6(10) . . . . ?
C100 C99 C105 C106 -0.1(8) . . . . ?
C100 C99 C105 C110 -179.1(8) . . . . ?
C101 C97 C98 C99 -177.8(7) . . . . ?
C105 C99 C100 N16 0.8(8) . . . . ?
C105 C99 C100 C95 -177.0(7) . . . . ?
C105 C106 C107 C108 3.5(12) . . . . ?
C106 N16 C100 C95 176.6(7) . . . . ?
C106 N16 C100 C99 -1.2(8) . . . . ?
C106 N16 C115 N14 175.0(6) . . . . ?
C106 N16 C115 N15 -4.3(11) . . . . ?
C106 C105 C110 C109 -0.2(12) . . . . ?
C106 C107 C108 C109 -0.6(13) . . . . ?
C107 C108 C109 C110 -2.6(13) . . . . ?
C107 C108 C109 C111 172.7(8) . . . . ?
C108 C109 C110 C105 2.9(12) . . . . ?
C108 C109 C111 C112 -65.5(11) . . . . ?
C108 C109 C111 C113 170.8(10) . . . . ?
C108 C109 C111 C114 49.2(11) . . . . ?
C108 C109 C111 C223 18.8(15) . . . . ?
C108 C109 C111 C1G 142.8(11) . . . . ?
C108 C109 C111 C1H -103.3(12) . . . . ?
C110 C105 C106 N16 178.5(7) . . . . ?
C110 C105 C106 C107 -3.2(12) . . . . ?
C110 C109 C111 C112 109.5(10) . . . . ?
C110 C109 C111 C113 -14.3(13) . . . . ?
C110 C109 C111 C114 -135.9(9) . . . . ?
C110 C109 C111 C223 -166.3(12) . . . . ?
C110 C109 C111 C1G -42.2(13) . . . . ?
C110 C109 C111 C1H 71.7(12) . . . . ?
C111 C109 C110 C105 -172.2(7) . . . . ?
C115 N14 C118 C117 -4.8(10) . . . . ?
C115 N15 C116 C117 -1.9(13) . . . . ?
C115 N16 C100 C95 -20.4(11) . . . . ?
C115 N16 C100 C99 161.8(7) . . . . ?
C115 N16 C106 C105 -161.9(7) . . . . ?
C115 N16 C106 C107 20.0(12) . . . . ?
C116 N15 C115 N14 -2.2(12) . . . . ?
C116 N15 C115 N16 177.0(7) . . . . ?
C116 C117 C118 N14 1.3(11) . . . . ?
C118 N14 C115 N15 5.3(10) . . . . ?
C118 N14 C115 N16 -173.8(6) . . . . ?
C119 N20 C125 N19 171.3(6) . . . . ?
C119 C120 C121 C122 0.0(11) . . . . ?
C120 C119 C124 C123 -1.3(10) . . . . ?
C120 C121 C122 C123 -0.7(11) . . . . ?
C121 C122 C123 C124 0.5(11) . . . . ?
C122 C123 C124 C119 0.6(11) . . . . ?
C124 C119 C120 C121 1.1(10) . . . . ?
C125 N19 C126 C127 125.3(7) . . . . ?
C125 N19 C126 C131 -55.0(9) . . . . ?
C125 N20 C119 C120 143.0(7) . . . . ?
C125 N20 C119 C124 -38.6(9) . . . . ?
C126 N19 C125 N20 169.9(7) . . . . ?
C126 C127 C128 C129 2.6(15) . . . . ?
C127 C126 C131 C130 1.1(12) . . . . ?
C127 C128 C129 C130 -3.0(15) . . . . ?
C128 C129 C130 C131 2.3(14) . . . . ?
C129 C130 C131 C126 -1.4(13) . . . . ?
C131 C126 C127 C128 -1.6(12) . . . . ?
C132 N18 C138 N17 167.4(6) . . . . ?
C132 C133 C134 C135 0.5(11) . . . . ?
C133 C132 C137 C136 -3.1(11) . . . . ?
C133 C134 C135 C136 -2.1(11) . . . . ?
C134 C135 C136 C137 1.1(12) . . . . ?
C135 C136 C137 C132 1.5(11) . . . . ?
C137 C132 C133 C134 2.1(10) . . . . ?
C138 N17 C139 C140 142.9(7) . . . . ?
C138 N17 C139 C144 -39.6(9) . . . . ?
C138 N18 C132 C133 136.4(6) . . . . ?
C138 N18 C132 C137 -47.2(9) . . . . ?
C139 N17 C138 N18 170.0(6) . . . . ?
C139 C140 C141 C142 -0.7(12) . . . . ?
C140 C139 C144 C143 -1.4(11) . . . . ?
C140 C141 C142 C143 0.3(13) . . . . ?
C141 C142 C143 C144 -0.5(12) . . . . ?
C142 C143 C144 C139 1.0(11) . . . . ?
C144 C139 C140 C141 1.2(11) . . . . ?
Pt5 N21 C165 N22 168.3(5) . . . . ?
Pt5 N21 C165 N23 -15.6(8) . . . . ?
Pt5 N21 C168 C167 -171.4(5) . . . . ?
Pt5 N27 C199 N28 -13.1(9) . . . . ?
Pt5 N27 C200 C201 143.3(6) . . . . ?
Pt5 N27 C200 C205 -32.1(8) . . . . ?
Pt5 N29 C206 C207 -48.7(8) . . . . ?
Pt5 N29 C206 C211 131.5(6) . . . . ?
Pt5 N29 C212 N30 -2.1(10) . . . . ?
Pt5 C145 C146 C147 161.0(5) . . . . ?
Pt5 C145 C154 N23 9.7(9) . . . . ?
Pt5 C145 C154 C153 -160.4(5) . . . . ?
Pt6 N24 C189 N25 -164.0(5) . . . . ?
Pt6 N24 C189 N26 16.6(8) . . . . ?
Pt6 N24 C192 C191 167.3(5) . . . . ?
Pt6 N28 C193 C194 -47.4(7) . . . . ?
Pt6 N28 C193 C198 132.5(6) . . . . ?
Pt6 N28 C199 N27 -1.1(10) . . . . ?
Pt6 N30 C212 N29 -13.2(9) . . . . ?
Pt6 N30 C213 C214 143.5(5) . . . . ?
Pt6 N30 C213 C218 -36.5(8) . . . . ?
Pt6 C169 C170 C171 -175.8(5) . . . . ?
Pt6 C169 C174 N26 -0.9(9) . . . . ?
Pt6 C169 C174 C173 175.4(5) . . . . ?
N22 C166 C167 C168 -3.3(11) . . . . ?
N23 C155 C156 C157 -173.7(7) . . . . ?
N23 C155 C160 C153 -0.5(7) . . . . ?
N23 C155 C160 C159 176.3(6) . . . . ?
N25 C190 C191 C192 2.9(10) . . . . ?
N26 C180 C181 C182 175.1(7) . . . . ?
N27 C200 C201 C202 -176.5(7) . . . . ?
N27 C200 C205 C204 177.4(7) . . . . ?
N28 C193 C194 C195 179.2(6) . . . . ?
N28 C193 C198 C197 179.3(6) . . . . ?
N29 C206 C207 C208 179.6(7) . . . . ?
N29 C206 C211 C210 179.0(7) . . . . ?
N30 C213 C214 C215 176.0(6) . . . . ?
N30 C213 C218 C217 -176.1(7) . . . . ?
C145 C146 C147 C148 -175.1(6) . . . . ?
C145 C146 C147 C152 0.5(10) . . . . ?
C146 C145 C154 N23 176.8(6) . . . . ?
C146 C145 C154 C153 6.7(10) . . . . ?
C146 C147 C148 C149 -62.7(9) . . . . ?
C146 C147 C148 C150 57.5(9) . . . . ?
C146 C147 C148 C151 174.7(7) . . . . ?
C146 C147 C152 C153 1.1(10) . . . . ?
C147 C152 C153 C154 1.3(9) . . . . ?
C147 C152 C153 C160 -167.1(7) . . . . ?
C148 C147 C152 C153 176.5(6) . . . . ?
C152 C147 C148 C149 121.9(8) . . . . ?
C152 C147 C148 C150 -117.9(8) . . . . ?
C152 C147 C148 C151 -0.7(10) . . . . ?
C152 C153 C154 N23 -177.3(6) . . . . ?
C152 C153 C154 C145 -5.6(10) . . . . ?
C152 C153 C160 C155 173.7(7) . . . . ?
C152 C153 C160 C159 -2.7(13) . . . . ?
C154 N23 C155 C156 169.5(7) . . . . ?
C154 N23 C155 C160 -3.3(7) . . . . ?
C154 N23 C165 N21 -28.0(9) . . . . ?
C154 N23 C165 N22 148.3(6) . . . . ?
C154 C145 C146 C147 -4.1(10) . . . . ?
C154 C153 C160 C155 4.2(7) . . . . ?
C154 C153 C160 C159 -172.1(7) . . . . ?
C155 N23 C154 C145 -165.4(6) . . . . ?
C155 N23 C154 C153 6.0(7) . . . . ?
C155 N23 C165 N21 173.1(6) . . . . ?
C155 N23 C165 N22 -10.5(9) . . . . ?
C155 C156 C157 C158 -0.6(11) . . . . ?
C156 C155 C160 C153 -174.2(6) . . . . ?
C156 C155 C160 C159 2.7(10) . . . . ?
C156 C157 C158 C159 1.6(12) . . . . ?
C156 C157 C158 C161 179.2(7) . . . . ?
C157 C158 C159 C160 -0.5(11) . . . . ?
C157 C158 C161 C1A 9.5(15) . . . . ?
C157 C158 C161 C1B -110.6(11) . . . . ?
C157 C158 C161 C1C 141.7(12) . . . . ?
C157 C158 C161 C162 68.8(11) . . . . ?
C157 C158 C161 C163 -170.3(10) . . . . ?
C157 C158 C161 C164 -43.9(12) . . . . ?
C158 C159 C160 C153 174.4(7) . . . . ?
C158 C159 C160 C155 -1.6(10) . . . . ?
C159 C158 C161 C1A -173.0(13) . . . . ?
C159 C158 C161 C1B 66.9(12) . . . . ?
C159 C158 C161 C1C -40.8(13) . . . . ?
C159 C158 C161 C162 -113.7(10) . . . . ?
C159 C158 C161 C163 7.1(13) . . . . ?
C159 C158 C161 C164 133.5(11) . . . . ?
C160 C153 C154 N23 -6.2(7) . . . . ?
C160 C153 C154 C145 165.5(6) . . . . ?
C160 C155 C156 C157 -1.6(10) . . . . ?
C161 C158 C159 C160 -178.0(7) . . . . ?
C165 N21 C168 C167 3.2(10) . . . . ?
C165 N22 C166 C167 0.8(10) . . . . ?
C165 N23 C154 C145 32.6(10) . . . . ?
C165 N23 C154 C153 -156.0(6) . . . . ?
C165 N23 C155 C156 -29.1(11) . . . . ?
C165 N23 C155 C160 158.1(6) . . . . ?
C166 N22 C165 N21 4.2(10) . . . . ?
C166 N22 C165 N23 -171.9(6) . . . . ?
C166 C167 C168 N21 1.2(11) . . . . ?
C168 N21 C165 N22 -6.1(9) . . . . ?
C168 N21 C165 N23 169.9(6) . . . . ?
C169 C170 C171 C172 1.1(10) . . . . ?
C169 C170 C171 C175 176.0(6) . . . . ?
C170 C169 C174 N26 -176.6(6) . . . . ?
C170 C169 C174 C173 -0.3(10) . . . . ?
C170 C171 C172 C173 -0.9(10) . . . . ?
C170 C171 C175 C176 6.4(9) . . . . ?
C170 C171 C175 C177 128.9(7) . . . . ?
C170 C171 C175 C178 -113.3(7) . . . . ?
C171 C172 C173 C174 0.2(10) . . . . ?
C171 C172 C173 C179 171.7(7) . . . . ?
C172 C171 C175 C176 -178.7(7) . . . . ?
C172 C171 C175 C177 -56.2(9) . . . . ?
C172 C171 C175 C178 61.6(8) . . . . ?
C172 C173 C174 N26 177.3(6) . . . . ?
C172 C173 C174 C169 0.4(10) . . . . ?
C172 C173 C179 C180 -173.8(7) . . . . ?
C172 C173 C179 C184 0.8(13) . . . . ?
C173 C179 C180 N26 -1.5(8) . . . . ?
C173 C179 C180 C181 174.0(7) . . . . ?
C173 C179 C184 C183 -172.4(8) . . . . ?
C174 N26 C180 C179 3.9(8) . . . . ?
C174 N26 C180 C181 -170.9(8) . . . . ?
C174 N26 C189 N24 20.9(9) . . . . ?
C174 N26 C189 N25 -158.7(6) . . . . ?
C174 C169 C170 C171 -0.5(9) . . . . ?
C174 C173 C179 C180 -1.5(8) . . . . ?
C174 C173 C179 C184 173.1(8) . . . . ?
C175 C171 C172 C173 -176.0(6) . . . . ?
C179 C173 C174 N26 4.0(8) . . . . ?
C179 C173 C174 C169 -172.9(6) . . . . ?
C179 C180 C181 C182 0.7(11) . . . . ?
C180 N26 C174 C169 171.9(7) . . . . ?
C180 N26 C174 C173 -4.9(7) . . . . ?
C180 N26 C189 N24 175.3(6) . . . . ?
C180 N26 C189 N25 -4.2(9) . . . . ?
C180 C179 C184 C183 1.7(11) . . . . ?
C180 C181 C182 C183 -0.1(12) . . . . ?
C181 C182 C183 C184 0.2(12) . . . . ?
C181 C182 C183 C185 178.7(7) . . . . ?
C182 C183 C184 C179 -1.0(12) . . . . ?
C182 C183 C185 C186 -70.3(9) . . . . ?
C182 C183 C185 C187 169.1(7) . . . . ?
C182 C183 C185 C188 48.7(11) . . . . ?
C184 C179 C180 N26 -177.0(6) . . . . ?
C184 C179 C180 C181 -1.5(11) . . . . ?
C184 C183 C185 C186 108.1(9) . . . . ?
C184 C183 C185 C187 -12.5(11) . . . . ?
C184 C183 C185 C188 -132.9(9) . . . . ?
C185 C183 C184 C179 -179.4(7) . . . . ?
C189 N24 C192 C191 -4.2(9) . . . . ?
C189 N25 C190 C191 -0.7(10) . . . . ?
C189 N26 C174 C169 -30.4(10) . . . . ?
C189 N26 C174 C173 152.9(6) . . . . ?
C189 N26 C180 C179 -154.3(6) . . . . ?
C189 N26 C180 C181 30.8(11) . . . . ?
C190 N25 C189 N24 -4.4(10) . . . . ?
C190 N25 C189 N26 175.1(6) . . . . ?
C190 C191 C192 N24 -0.3(10) . . . . ?
C192 N24 C189 N25 6.7(9) . . . . ?
C192 N24 C189 N26 -172.7(5) . . . . ?
C193 N28 C199 N27 167.9(6) . . . . ?
C193 C194 C195 C196 1.1(11) . . . . ?
C194 C193 C198 C197 -0.7(10) . . . . ?
C194 C195 C196 C197 0.1(11) . . . . ?
C195 C196 C197 C198 -1.6(12) . . . . ?
C196 C197 C198 C193 1.9(11) . . . . ?
C198 C193 C194 C195 -0.8(10) . . . . ?
C199 N27 C200 C201 -41.8(9) . . . . ?
C199 N27 C200 C205 142.9(7) . . . . ?
C199 N28 C193 C194 142.0(6) . . . . ?
C199 N28 C193 C198 -38.1(9) . . . . ?
C200 N27 C199 N28 172.0(6) . . . . ?
C200 C201 C202 C203 -0.2(12) . . . . ?
C201 C200 C205 C204 1.8(11) . . . . ?
C201 C202 C203 C204 0.9(12) . . . . ?
C202 C203 C204 C205 -0.3(12) . . . . ?
C203 C204 C205 C200 -1.1(12) . . . . ?
C205 C200 C201 C202 -1.2(11) . . . . ?
C206 N29 C212 N30 168.8(6) . . . . ?
C206 C207 C208 C209 1.3(12) . . . . ?
C207 C206 C211 C210 -0.8(12) . . . . ?
C207 C208 C209 C210 -0.5(13) . . . . ?
C208 C209 C210 C211 -0.9(13) . . . . ?
C209 C210 C211 C206 1.6(13) . . . . ?
C211 C206 C207 C208 -0.6(11) . . . . ?
C212 N29 C206 C207 139.6(7) . . . . ?
C212 N29 C206 C211 -40.2(10) . . . . ?
C212 N30 C213 C214 -42.2(9) . . . . ?
C212 N30 C213 C218 137.8(7) . . . . ?
C213 N30 C212 N29 172.7(6) . . . . ?
C213 C214 C215 C216 1.0(11) . . . . ?
C214 C213 C218 C217 3.8(11) . . . . ?
C214 C215 C216 C217 2.1(12) . . . . ?
C215 C216 C217 C218 -2.3(12) . . . . ?
C216 C217 C218 C213 -0.8(12) . . . . ?
C218 C213 C214 C215 -4.0(10) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 468 electrons were 
found in a volume of 2000Å³ in 7 voids per unit cell. 
This is consistent with the presence of 
2[CH2Cl2], 2.2[CH3OH] per Asymmetric Unit 
which account for 494 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.004 0.072 0.391 288.6 76.3 '2 CH2Cl2'
2 0.004 -0.072 0.609 288.6 79.7 '2 CH2Cl2'
3 -0.004 0.428 0.891 288.6 76.2 '2 CH2Cl2'
4 0.004 0.572 0.109 288.6 79.8 '2 CH2Cl2'
5 0.067 -0.012 0.032 22.4 0.0 ?
6 0.067 0.512 0.532 22.4 0.0 ?
7 0.189 0.578 0.408 7.4 0.0 ?
8 0.189 0.922 0.908 7.4 0.0 ?
9 0.224 0.598 0.667 11.6 0.0 ?
10 0.224 0.902 0.167 11.6 0.0 ?
11 0.254 0.234 0.810 8.8 0.0 ?
12 0.254 0.266 0.310 8.8 0.0 ?
13 0.336 0.147 0.057 14.9 0.0 ?
14 0.336 0.353 0.557 14.9 0.0 ?
15 0.500 0.500 0.500 290.1 82.0 '4.4 CH3OH'
16 0.500 0.000 1.000 290.1 82.0 '4.4 CH3OH'
17 0.475 0.219 0.231 9.6 0.3 ?
18 0.475 0.281 0.731 9.6 0.4 ?
19 0.525 0.719 0.269 9.6 0.0 ?
20 0.525 0.781 0.769 9.6 0.0 ?
21 0.664 0.647 0.443 14.9 0.0 ?
22 0.664 0.853 0.943 14.9 0.0 ?
23 0.746 0.734 0.690 8.8 0.0 ?
24 0.746 0.766 0.190 8.8 0.0 ?
25 0.776 0.098 0.833 11.6 0.4 ?
26 0.776 0.402 0.333 11.6 0.4 ?
27 0.811 0.078 0.092 7.4 0.0 ?
28 0.811 0.422 0.592 7.4 0.0 ?
29 0.933 0.012 0.968 22.4 0.0 ?
30 0.933 0.488 0.468 22.4 0.0 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cu_20220707_zh_gxmz_hb49_0m
_database_code_depnum_ccdc_archive 'CCDC 2285563'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2024-02-21 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2024-01-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H90 N10 Pt2'
_chemical_formula_sum            'C70 H90 N10 Pt2'
_chemical_formula_weight         1461.69
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.5525(3)
_cell_length_b                   17.1628(5)
_cell_length_c                   19.2112(6)
_cell_angle_alpha                86.287(2)
_cell_angle_beta                 74.490(2)
_cell_angle_gamma                70.632(2)
_cell_volume                     3761.07(19)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9835
_cell_measurement_temperature    193.00
_cell_measurement_theta_max      68.18
_cell_measurement_theta_min      5.05
_shelx_estimated_absorpt_T_max   0.480
_shelx_estimated_absorpt_T_min   0.393
_exptl_absorpt_coefficient_mu    7.173
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.4928
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1216 before and 0.0622 after correction.
The Ratio of minimum to maximum transmission is 0.6544.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.291
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1472
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0497
_diffrn_reflns_av_unetI/netI     0.0462
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            49578
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.525
_diffrn_reflns_theta_min         2.730
_diffrn_ambient_temperature      193.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           1.1
_diffrn_source_power             0.05500000000000001
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11715
_reflns_number_total             13729
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (1, 2016)'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'SAINT V8.40B (1, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         4.069
_refine_diff_density_min         -2.353
_refine_diff_density_rms         0.147
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     824
_refine_ls_number_reflns         13729
_refine_ls_number_restraints     75
_refine_ls_R_factor_all          0.0637
_refine_ls_R_factor_gt           0.0568
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0707P)²+24.5425P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1459
_refine_ls_wR_factor_ref         0.1504
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C42-C43 \\sim C42-C44 \\sim C43-C44
 with sigma of 0.04
 C41-C42 \\sim C41-C43 \\sim C41-C44
 with sigma of 0.02
 C43A-C42A \\sim C44A-C42A
 with sigma of 0.04
 C24-C21 \\sim C22-C21 \\sim C23-C21
 with sigma of 0.02
 C22-C23 \\sim C22-C24 \\sim C23-C24
 with sigma of 0.02
 C22-C21 \\sim C22A-C21 \\sim C23-C21 \\sim C23A-C21 \\sim C24A-C21 \\sim
C24-C21
 with sigma of 0.02
3. Rigid bond restraints
 C21, C22
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C41, C43
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Uiso/Uaniso restraints and constraints
Uanis(C22) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C23A) \\sim Ueq, Uanis(C22A) \\sim Ueq, Uanis(C24A) \\sim Ueq,
Uanis(C42A) \\sim Ueq, Uanis(C43A) \\sim Ueq, Uanis(C43) \\sim Ueq, Uanis(C44)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
5. Others
 Sof(C43A)=Sof(H43D)=Sof(H43E)=Sof(H43F)=Sof(C44A)=Sof(H44D)=Sof(H44E)=
 Sof(H44F)=Sof(C42A)=Sof(H42D)=Sof(H42E)=Sof(H42F)=Sof(C24A)=Sof(H24D)=
 Sof(H24E)=Sof(H24F)=Sof(C23A)=Sof(H23D)=Sof(H23E)=Sof(H23F)=Sof(C22A)=
 Sof(H22D)=Sof(H22E)=Sof(H22F)=1-FVAR(1)
 Sof(C22)=Sof(H22A)=Sof(H22B)=Sof(H22C)=Sof(C23)=Sof(H23A)=Sof(H23B)=Sof(H23C)=
 Sof(C24)=Sof(H24A)=Sof(H24B)=Sof(H24C)=Sof(C42)=Sof(H42A)=Sof(H42B)=Sof(H42C)=
 Sof(C43)=Sof(H43A)=Sof(H43B)=Sof(H43C)=Sof(C44)=Sof(H44A)=Sof(H44B)=Sof(H44C)=
 FVAR(1)
6.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20),
 C26(H26), C28(H28), C36(H36), C38(H38), C39(H39), C46(H46), C47(H47), C48(H48),
  C54(H54), C65(H65)
6.b Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C22(H22A,H22B,H22C),
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C), C32(H32A,H32B,H32C), C33(H33A,H33B,
 H33C), C34(H34A,H34B,H34C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C44(H44A,
 H44B,H44C), C51(H51A,H51B,H51C), C52(H52A,H52B,H52C), C53(H53A,H53B,H53C),
 C57(H57A,H57B,H57C), C58(H58A,H58B,H58C), C59(H59A,H59B,H59C), C62(H62A,H62B,
 H62C), C63(H63A,H63B,H63C), C64(H64A,H64B,H64C), C68(H68A,H68B,H68C), C69(H69A,
 H69B,H69C), C70(H70A,H70B,H70C), C43A(H43D,H43E,H43F), C44A(H44D,H44E,H44F),
 C42A(H42D,H42E,H42F), C24A(H24D,H24E,H24F), C23A(H23D,H23E,H23F), C22A(H22D,
 H22E,H22F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.61885(2) 0.17757(2) 0.39587(2) 0.03499(10) Uani 1 1 d . . . . .
Pt2 Pt 0.64598(3) 0.29362(2) 0.27254(2) 0.03812(10) Uani 1 1 d . . . . .
N1 N 0.7553(5) 0.1552(4) 0.4405(3) 0.0410(14) Uani 1 1 d . . . . .
N2 N 0.8515(6) 0.1147(5) 0.5351(4) 0.0532(17) Uani 1 1 d . . . . .
N3 N 0.6499(5) 0.1579(4) 0.5633(3) 0.0375(13) Uani 1 1 d . . . . .
N4 N 0.5975(5) 0.4087(4) 0.3184(3) 0.0422(14) Uani 1 1 d . . . . .
N5 N 0.7382(6) 0.4552(4) 0.2354(4) 0.0445(15) Uani 1 1 d . . . . .
N6 N 0.6031(7) 0.5449(5) 0.3251(5) 0.065(2) Uani 1 1 d . . . . .
N7 N 0.4851(5) 0.2089(4) 0.3485(3) 0.0390(13) Uani 1 1 d . . . . .
N8 N 0.4753(5) 0.2818(4) 0.3111(3) 0.0404(14) Uani 1 1 d . . . . .
N9 N 0.7252(5) 0.1192(4) 0.2929(3) 0.0407(14) Uani 1 1 d . . . . .
N10 N 0.6978(5) 0.1746(4) 0.2388(3) 0.0420(14) Uani 1 1 d . . . . .
C1 C 0.5089(6) 0.2286(5) 0.4889(4) 0.0372(15) Uani 1 1 d . . . . .
C2 C 0.3908(6) 0.2805(5) 0.4980(4) 0.0394(16) Uani 1 1 d . . . . .
H2 H 0.365784 0.300213 0.455753 0.047 Uiso 1 1 calc R U . . .
C3 C 0.3098(6) 0.3041(5) 0.5643(4) 0.0415(17) Uani 1 1 d . . . . .
C4 C 0.3435(6) 0.2745(5) 0.6266(4) 0.0451(18) Uani 1 1 d . . . . .
H4 H 0.288865 0.287317 0.672616 0.054 Uiso 1 1 calc R U . . .
C5 C 0.4588(6) 0.2256(5) 0.6204(4) 0.0405(16) Uani 1 1 d . . . . .
C6 C 0.5388(6) 0.2061(4) 0.5527(4) 0.0385(16) Uani 1 1 d . . . . .
C7 C 0.1836(7) 0.3595(6) 0.5668(5) 0.052(2) Uani 1 1 d . . . . .
C8 C 0.1886(9) 0.4406(7) 0.5277(8) 0.093(4) Uani 1 1 d . . . . .
H8A H 0.215563 0.472343 0.555710 0.139 Uiso 1 1 calc R U . . .
H8B H 0.110406 0.473316 0.523110 0.139 Uiso 1 1 calc R U . . .
H8C H 0.242900 0.427272 0.479511 0.139 Uiso 1 1 calc R U . . .
C9 C 0.1283(9) 0.3160(9) 0.5279(8) 0.099(4) Uani 1 1 d . . . . .
H9A H 0.179095 0.298620 0.479267 0.149 Uiso 1 1 calc R U . . .
H9B H 0.051909 0.353741 0.524469 0.149 Uiso 1 1 calc R U . . .
H9C H 0.118121 0.267341 0.554881 0.149 Uiso 1 1 calc R U . . .
C10 C 0.1094(10) 0.3839(10) 0.6433(6) 0.103(5) Uani 1 1 d . . . . .
H10A H 0.107305 0.334068 0.670815 0.155 Uiso 1 1 calc R U . . .
H10B H 0.029717 0.417630 0.642356 0.155 Uiso 1 1 calc R U . . .
H10C H 0.143183 0.415809 0.666328 0.155 Uiso 1 1 calc R U . . .
C11 C 0.5196(7) 0.1874(5) 0.6748(4) 0.0430(17) Uani 1 1 d . . . . .
C12 C 0.6358(7) 0.1472(5) 0.6390(4) 0.0415(16) Uani 1 1 d . . . . .
C13 C 0.7554(6) 0.1422(5) 0.5116(4) 0.0412(16) Uani 1 1 d . . . . .
C14 C 0.8591(7) 0.1499(6) 0.3945(5) 0.056(2) Uani 1 1 d . . . . .
H14 H 0.861927 0.163257 0.345415 0.067 Uiso 1 1 calc R U . . .
C15 C 0.9624(7) 0.1255(7) 0.4159(5) 0.065(3) Uani 1 1 d . . . . .
H15 H 1.035538 0.121307 0.382823 0.078 Uiso 1 1 calc R U . . .
C16 C 0.9530(7) 0.1077(7) 0.4877(5) 0.067(3) Uani 1 1 d . . . . .
H16 H 1.022082 0.089637 0.504089 0.081 Uiso 1 1 calc R U . . .
C17 C 0.7139(8) 0.1052(6) 0.6784(5) 0.052(2) Uani 1 1 d . . . . .
H17 H 0.794387 0.079531 0.655358 0.063 Uiso 1 1 calc R U . . .
C18 C 0.6710(9) 0.1015(6) 0.7530(5) 0.062(2) Uani 1 1 d . . . . .
H18 H 0.724039 0.072181 0.780354 0.075 Uiso 1 1 calc R U . . .
C19 C 0.5545(9) 0.1385(6) 0.7892(5) 0.063(3) Uani 1 1 d . . . . .
C20 C 0.4797(8) 0.1827(6) 0.7486(5) 0.057(2) Uani 1 1 d . . . . .
H20 H 0.399708 0.210136 0.771858 0.068 Uiso 1 1 calc R U . . .
C21 C 0.5055(11) 0.1282(7) 0.8706(6) 0.087(3) Uani 1 1 d D U . . .
C22 C 0.402(2) 0.0965(18) 0.8849(15) 0.104(9) Uani 0.46(2) 1 d D U P A 1
H22A H 0.423763 0.045983 0.855909 0.156 Uiso 0.46(2) 1 calc R U P A 1
H22B H 0.335817 0.138691 0.871766 0.156 Uiso 0.46(2) 1 calc R U P A 1
H22C H 0.378375 0.084597 0.936310 0.156 Uiso 0.46(2) 1 calc R U P A 1
C23 C 0.5911(18) 0.0724(15) 0.9069(10) 0.078(9) Uani 0.46(2) 1 d D . P A 1
H23A H 0.557731 0.077675 0.959322 0.117 Uiso 0.46(2) 1 calc R U P A 1
H23B H 0.662676 0.087369 0.894322 0.117 Uiso 0.46(2) 1 calc R U P A 1
H23C H 0.609632 0.015228 0.890927 0.117 Uiso 0.46(2) 1 calc R U P A 1
C24 C 0.459(3) 0.2127(11) 0.9062(15) 0.074(8) Uani 0.46(2) 1 d D . P A 1
H24A H 0.399655 0.249304 0.884120 0.112 Uiso 0.46(2) 1 calc R U P A 1
H24B H 0.523688 0.235045 0.899720 0.112 Uiso 0.46(2) 1 calc R U P A 1
H24C H 0.424802 0.208639 0.957905 0.112 Uiso 0.46(2) 1 calc R U P A 1
C25 C 0.8060(6) 0.2984(5) 0.2300(4) 0.0397(16) Uani 1 1 d . . . . .
C26 C 0.9066(7) 0.2310(5) 0.2047(4) 0.0426(17) Uani 1 1 d . . . . .
H26 H 0.901058 0.177307 0.214327 0.051 Uiso 1 1 calc R U . . .
C27 C 1.0156(7) 0.2371(5) 0.1661(4) 0.0461(18) Uani 1 1 d . . . . .
C28 C 1.0256(7) 0.3146(5) 0.1498(4) 0.0458(18) Uani 1 1 d . . . . .
H28 H 1.097588 0.320308 0.122350 0.055 Uiso 1 1 calc R U . . .
C29 C 0.9270(7) 0.3847(5) 0.1748(4) 0.0443(17) Uani 1 1 d . . . . .
C30 C 0.8221(7) 0.3752(5) 0.2152(4) 0.0411(16) Uani 1 1 d . . . . .
C31 C 1.1197(7) 0.1589(6) 0.1419(5) 0.053(2) Uani 1 1 d . . . . .
C32 C 1.2270(9) 0.1758(8) 0.0958(7) 0.087(4) Uani 1 1 d . . . . .
H32A H 1.210848 0.201621 0.051041 0.131 Uiso 1 1 calc R U . . .
H32B H 1.292024 0.123653 0.084008 0.131 Uiso 1 1 calc R U . . .
H32C H 1.247927 0.212958 0.122251 0.131 Uiso 1 1 calc R U . . .
C33 C 1.1490(11) 0.1166(9) 0.2091(6) 0.098(4) Uani 1 1 d . . . . .
H33A H 1.154047 0.156767 0.241039 0.147 Uiso 1 1 calc R U . . .
H33B H 1.224229 0.071968 0.195530 0.147 Uiso 1 1 calc R U . . .
H33C H 1.087725 0.093543 0.234372 0.147 Uiso 1 1 calc R U . . .
C34 C 1.0906(11) 0.1006(8) 0.0996(7) 0.092(4) Uani 1 1 d . . . . .
H34A H 1.032192 0.079292 0.131822 0.139 Uiso 1 1 calc R U . . .
H34B H 1.161649 0.054439 0.079245 0.139 Uiso 1 1 calc R U . . .
H34C H 1.059175 0.130348 0.060331 0.139 Uiso 1 1 calc R U . . .
C35 C 0.9085(7) 0.4720(5) 0.1679(4) 0.0466(18) Uani 1 1 d . . . . .
C36 C 0.9839(8) 0.5155(6) 0.1316(5) 0.053(2) Uani 1 1 d . . . . .
H36 H 1.062204 0.486279 0.106443 0.063 Uiso 1 1 calc R U . . .
C37 C 0.9429(8) 0.6012(6) 0.1330(5) 0.054(2) Uani 1 1 d . . . . .
C38 C 0.8286(9) 0.6406(6) 0.1696(5) 0.062(2) Uani 1 1 d . . . . .
H38 H 0.800894 0.699302 0.170334 0.075 Uiso 1 1 calc R U . . .
C39 C 0.7506(9) 0.6004(5) 0.2058(5) 0.057(2) Uani 1 1 d . . . . .
H39 H 0.671802 0.629923 0.229765 0.069 Uiso 1 1 calc R U . . .
C40 C 0.7941(7) 0.5156(5) 0.2047(4) 0.0437(17) Uani 1 1 d . . . . .
C41 C 1.0234(9) 0.6492(6) 0.0921(6) 0.071(3) Uani 1 1 d D U . . .
C42 C 0.955(3) 0.723(2) 0.054(2) 0.15(2) Uani 0.46(2) 1 d D . P A 1
H42A H 0.890983 0.709883 0.042640 0.219 Uiso 0.46(2) 1 calc R U P A 1
H42B H 1.007287 0.733521 0.009797 0.219 Uiso 0.46(2) 1 calc R U P A 1
H42C H 0.922300 0.771701 0.086533 0.219 Uiso 0.46(2) 1 calc R U P A 1
C43 C 1.063(4) 0.679(3) 0.1507(19) 0.137(13) Uani 0.46(2) 1 d D U P A 1
H43A H 1.014864 0.671490 0.198344 0.206 Uiso 0.46(2) 1 calc R U P A 1
H43B H 1.054402 0.737831 0.144479 0.206 Uiso 0.46(2) 1 calc R U P A 1
H43C H 1.145218 0.647309 0.147041 0.206 Uiso 0.46(2) 1 calc R U P A 1
C44 C 1.129(3) 0.594(2) 0.0361(18) 0.131(14) Uani 0.46(2) 1 d D U P A 1
H44A H 1.171781 0.627486 0.005982 0.197 Uiso 0.46(2) 1 calc R U P A 1
H44B H 1.101838 0.564754 0.005635 0.197 Uiso 0.46(2) 1 calc R U P A 1
H44C H 1.180772 0.552986 0.061083 0.197 Uiso 0.46(2) 1 calc R U P A 1
C45 C 0.6430(7) 0.4698(5) 0.2945(4) 0.0440(17) Uani 1 1 d . . . . .
C46 C 0.5149(10) 0.5603(6) 0.3840(6) 0.074(3) Uani 1 1 d . . . . .
H46 H 0.482350 0.614212 0.405482 0.088 Uiso 1 1 calc R U . . .
C47 C 0.4699(8) 0.5001(6) 0.4146(5) 0.064(2) Uani 1 1 d . . . . .
H47 H 0.409672 0.510883 0.458434 0.077 Uiso 1 1 calc R U . . .
C48 C 0.5128(7) 0.4248(5) 0.3812(5) 0.051(2) Uani 1 1 d . . . . .
H48 H 0.482591 0.382305 0.402418 0.062 Uiso 1 1 calc R U . . .
C49 C 0.7750(7) 0.0439(5) 0.2630(5) 0.0497(19) Uani 1 1 d . . . . .
C50 C 0.8247(8) -0.0370(6) 0.2999(5) 0.059(2) Uani 1 1 d . . . . .
C51 C 0.7767(13) -0.0338(7) 0.3800(6) 0.097(4) Uani 1 1 d . . . . .
H51A H 0.799969 0.006309 0.401423 0.145 Uiso 1 1 calc R U . . .
H51B H 0.807577 -0.088489 0.399358 0.145 Uiso 1 1 calc R U . . .
H51C H 0.691180 -0.016952 0.391957 0.145 Uiso 1 1 calc R U . . .
C52 C 0.8061(16) -0.1078(6) 0.2724(7) 0.111(6) Uani 1 1 d . . . . .
H52A H 0.742439 -0.088014 0.248493 0.167 Uiso 1 1 calc R U . . .
H52B H 0.785380 -0.142686 0.312667 0.167 Uiso 1 1 calc R U . . .
H52C H 0.877962 -0.139988 0.237649 0.167 Uiso 1 1 calc R U . . .
C53 C 0.9567(11) -0.0565(10) 0.2818(11) 0.137(7) Uani 1 1 d . . . . .
H53A H 0.987936 -0.055774 0.229336 0.205 Uiso 1 1 calc R U . . .
H53B H 0.992566 -0.111260 0.299399 0.205 Uiso 1 1 calc R U . . .
H53C H 0.974592 -0.014890 0.305067 0.205 Uiso 1 1 calc R U . . .
C54 C 0.7808(8) 0.0489(6) 0.1898(5) 0.055(2) Uani 1 1 d . . . . .
H54 H 0.812356 0.004251 0.155588 0.065 Uiso 1 1 calc R U . . .
C55 C 0.7307(7) 0.1331(6) 0.1760(4) 0.0479(19) Uani 1 1 d . . . . .
C56 C 0.7023(9) 0.1688(7) 0.1062(5) 0.061(2) Uani 1 1 d . . . . .
C57 C 0.5731(10) 0.1850(8) 0.1162(6) 0.079(3) Uani 1 1 d . . . . .
H57A H 0.557059 0.132458 0.122311 0.118 Uiso 1 1 calc R U . . .
H57B H 0.550120 0.212313 0.073567 0.118 Uiso 1 1 calc R U . . .
H57C H 0.528342 0.220639 0.159126 0.118 Uiso 1 1 calc R U . . .
C58 C 0.7707(12) 0.1072(8) 0.0434(6) 0.089(4) Uani 1 1 d . . . . .
H58A H 0.854587 0.091688 0.039582 0.133 Uiso 1 1 calc R U . . .
H58B H 0.754782 0.132499 -0.001570 0.133 Uiso 1 1 calc R U . . .
H58C H 0.746725 0.057821 0.051702 0.133 Uiso 1 1 calc R U . . .
C59 C 0.7290(12) 0.2480(8) 0.0872(6) 0.079(3) Uani 1 1 d . . . . .
H59A H 0.675464 0.291534 0.122629 0.118 Uiso 1 1 calc R U . . .
H59B H 0.718966 0.264284 0.038926 0.118 Uiso 1 1 calc R U . . .
H59C H 0.809820 0.239787 0.087770 0.118 Uiso 1 1 calc R U . . .
C60 C 0.3922(6) 0.1859(5) 0.3518(4) 0.0416(17) Uani 1 1 d . . . . .
C61 C 0.3825(6) 0.1030(5) 0.3783(4) 0.0422(17) Uani 1 1 d . . . . .
C62 C 0.4626(9) 0.0390(6) 0.3193(7) 0.074(3) Uani 1 1 d . . . . .
H62A H 0.433773 0.050171 0.275826 0.110 Uiso 1 1 calc R U . . .
H62B H 0.463698 -0.016294 0.336113 0.110 Uiso 1 1 calc R U . . .
H62C H 0.542026 0.042075 0.308011 0.110 Uiso 1 1 calc R U . . .
C63 C 0.4151(9) 0.0795(7) 0.4502(6) 0.069(3) Uani 1 1 d . . . . .
H63A H 0.494720 0.079873 0.445157 0.103 Uiso 1 1 calc R U . . .
H63B H 0.411243 0.024131 0.463156 0.103 Uiso 1 1 calc R U . . .
H63C H 0.360210 0.119477 0.488173 0.103 Uiso 1 1 calc R U . . .
C64 C 0.2570(7) 0.1045(6) 0.3907(5) 0.056(2) Uani 1 1 d . . . . .
H64A H 0.206255 0.143621 0.430373 0.085 Uiso 1 1 calc R U . . .
H64B H 0.252550 0.049190 0.403116 0.085 Uiso 1 1 calc R U . . .
H64C H 0.231235 0.121741 0.346578 0.085 Uiso 1 1 calc R U . . .
C65 C 0.3206(7) 0.2458(5) 0.3170(5) 0.0462(18) Uani 1 1 d . . . . .
H65 H 0.247354 0.246459 0.311402 0.055 Uiso 1 1 calc R U . . .
C66 C 0.3739(7) 0.3037(5) 0.2924(4) 0.0444(17) Uani 1 1 d . . . . .
C67 C 0.3246(8) 0.3835(6) 0.2540(5) 0.057(2) Uani 1 1 d . . . . .
C68 C 0.2481(11) 0.3668(8) 0.2092(7) 0.088(4) Uani 1 1 d . . . . .
H68A H 0.296352 0.322297 0.173472 0.133 Uiso 1 1 calc R U . . .
H68B H 0.215068 0.417102 0.184324 0.133 Uiso 1 1 calc R U . . .
H68C H 0.184549 0.350510 0.241466 0.133 Uiso 1 1 calc R U . . .
C69 C 0.2444(13) 0.4491(8) 0.3114(7) 0.100(4) Uani 1 1 d . . . . .
H69A H 0.181057 0.430234 0.340522 0.150 Uiso 1 1 calc R U . . .
H69B H 0.211219 0.500570 0.287959 0.150 Uiso 1 1 calc R U . . .
H69C H 0.289296 0.458812 0.342562 0.150 Uiso 1 1 calc R U . . .
C70 C 0.4169(10) 0.4136(7) 0.2047(7) 0.079(3) Uani 1 1 d . . . . .
H70A H 0.458113 0.432158 0.233437 0.118 Uiso 1 1 calc R U . . .
H70B H 0.380127 0.459689 0.176813 0.118 Uiso 1 1 calc R U . . .
H70C H 0.472736 0.368515 0.171501 0.118 Uiso 1 1 calc R U . . .
C43A C 0.971(2) 0.7407(12) 0.1063(15) 0.084(7) Uani 0.54(2) 1 d D U P A 2
H43D H 0.890867 0.759644 0.100685 0.126 Uiso 0.54(2) 1 calc R U P A 2
H43E H 1.018022 0.768798 0.071906 0.126 Uiso 0.54(2) 1 calc R U P A 2
H43F H 0.969013 0.753484 0.155688 0.126 Uiso 0.54(2) 1 calc R U P A 2
C44A C 1.1409(17) 0.6138(14) 0.1128(12) 0.075(7) Uani 0.54(2) 1 d D . P A 2
H44D H 1.125759 0.605003 0.164915 0.113 Uiso 0.54(2) 1 calc R U P A 2
H44E H 1.184512 0.652830 0.099711 0.113 Uiso 0.54(2) 1 calc R U P A 2
H44F H 1.186924 0.561022 0.086729 0.113 Uiso 0.54(2) 1 calc R U P A 2
C42A C 1.047(2) 0.6322(14) 0.0142(10) 0.075(6) Uani 0.54(2) 1 d D U P A 2
H42D H 1.093210 0.573871 0.003069 0.112 Uiso 0.54(2) 1 calc R U P A 2
H42E H 1.091343 0.666850 -0.013418 0.112 Uiso 0.54(2) 1 calc R U P A 2
H42F H 0.973146 0.644752 0.001108 0.112 Uiso 0.54(2) 1 calc R U P A 2
C24A C 0.405(3) 0.2027(18) 0.9037(19) 0.124(12) Uani 0.54(2) 1 d D U P A 2
H24D H 0.337276 0.205826 0.886395 0.186 Uiso 0.54(2) 1 calc R U P A 2
H24E H 0.427085 0.252466 0.889827 0.186 Uiso 0.54(2) 1 calc R U P A 2
H24F H 0.385733 0.198850 0.956396 0.186 Uiso 0.54(2) 1 calc R U P A 2
C23A C 0.596(3) 0.121(3) 0.910(2) 0.163(18) Uani 0.54(2) 1 d D U P A 2
H23D H 0.560866 0.122997 0.962080 0.244 Uiso 0.54(2) 1 calc R U P A 2
H23E H 0.626720 0.167400 0.897209 0.244 Uiso 0.54(2) 1 calc R U P A 2
H23F H 0.660022 0.068961 0.896041 0.244 Uiso 0.54(2) 1 calc R U P A 2
C22A C 0.490(4) 0.0441(18) 0.879(2) 0.160(15) Uani 0.54(2) 1 d D U P A 2
H22D H 0.485334 0.026965 0.929017 0.239 Uiso 0.54(2) 1 calc R U P A 2
H22E H 0.557548 0.003982 0.846587 0.239 Uiso 0.54(2) 1 calc R U P A 2
H22F H 0.418498 0.046729 0.866457 0.239 Uiso 0.54(2) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 3.0172(4) . ?
Pt1 N1 2.031(6) . ?
Pt1 N7 2.022(6) . ?
Pt1 N9 2.158(6) . ?
Pt1 C1 1.987(7) . ?
Pt2 N4 2.047(6) . ?
Pt2 N8 2.145(6) . ?
Pt2 N10 2.020(7) . ?
Pt2 C25 1.983(7) . ?
N1 C13 1.369(10) . ?
N1 C14 1.342(10) . ?
N2 C13 1.329(10) . ?
N2 C16 1.326(11) . ?
N3 C6 1.427(9) . ?
N3 C12 1.425(9) . ?
N3 C13 1.381(9) . ?
N4 C45 1.354(10) . ?
N4 C48 1.351(10) . ?
N5 C30 1.427(10) . ?
N5 C40 1.447(9) . ?
N5 C45 1.376(10) . ?
N6 C45 1.331(11) . ?
N6 C46 1.323(12) . ?
N7 N8 1.388(8) . ?
N7 C60 1.336(9) . ?
N8 C66 1.342(9) . ?
N9 N10 1.395(9) . ?
N9 C49 1.328(11) . ?
N10 C55 1.336(10) . ?
C1 C2 1.423(10) . ?
C1 C6 1.373(10) . ?
C2 H2 0.9500 . ?
C2 C3 1.386(11) . ?
C3 C4 1.385(11) . ?
C3 C7 1.544(10) . ?
C4 H4 0.9500 . ?
C4 C5 1.388(11) . ?
C5 C6 1.394(11) . ?
C5 C11 1.453(10) . ?
C7 C8 1.549(15) . ?
C7 C9 1.514(15) . ?
C7 C10 1.514(14) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.391(11) . ?
C11 C20 1.378(11) . ?
C12 C17 1.382(11) . ?
C14 H14 0.9500 . ?
C14 C15 1.390(12) . ?
C15 H15 0.9500 . ?
C15 C16 1.376(13) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C17 C18 1.396(13) . ?
C18 H18 0.9500 . ?
C18 C19 1.387(14) . ?
C19 C20 1.381(13) . ?
C19 C21 1.543(14) . ?
C20 H20 0.9500 . ?
C21 C22 1.527(16) . ?
C21 C23 1.479(15) . ?
C21 C24 1.504(15) . ?
C21 C24A 1.494(16) . ?
C21 C23A 1.494(17) . ?
C21 C22A 1.510(17) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.394(11) . ?
C25 C30 1.397(11) . ?
C26 H26 0.9500 . ?
C26 C27 1.406(10) . ?
C27 C28 1.385(11) . ?
C27 C31 1.522(12) . ?
C28 H28 0.9500 . ?
C28 C29 1.407(12) . ?
C29 C30 1.394(10) . ?
C29 C35 1.441(12) . ?
C31 C32 1.506(13) . ?
C31 C33 1.513(14) . ?
C31 C34 1.517(15) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.409(11) . ?
C35 C40 1.391(12) . ?
C36 H36 0.9500 . ?
C36 C37 1.388(13) . ?
C37 C38 1.375(14) . ?
C37 C41 1.536(12) . ?
C38 H38 0.9500 . ?
C38 C39 1.392(12) . ?
C39 H39 0.9500 . ?
C39 C40 1.374(12) . ?
C41 C42 1.53(2) . ?
C41 C43 1.52(2) . ?
C41 C44 1.53(2) . ?
C41 C43A 1.50(2) . ?
C41 C44A 1.55(2) . ?
C41 C42A 1.47(2) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C46 H46 0.9500 . ?
C46 C47 1.364(14) . ?
C47 H47 0.9500 . ?
C47 C48 1.355(13) . ?
C48 H48 0.9500 . ?
C49 C50 1.534(13) . ?
C49 C54 1.386(12) . ?
C50 C51 1.493(15) . ?
C50 C52 1.465(14) . ?
C50 C53 1.523(15) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54 0.9500 . ?
C54 C55 1.410(13) . ?
C55 C56 1.517(12) . ?
C56 C57 1.513(14) . ?
C56 C58 1.523(14) . ?
C56 C59 1.506(14) . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C60 C61 1.513(10) . ?
C60 C65 1.389(11) . ?
C61 C62 1.523(13) . ?
C61 C63 1.537(12) . ?
C61 C64 1.520(10) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 H65 0.9500 . ?
C65 C66 1.367(11) . ?
C66 C67 1.534(11) . ?
C67 C68 1.549(13) . ?
C67 C69 1.520(16) . ?
C67 C70 1.501(13) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C43A H43D 0.9800 . ?
C43A H43E 0.9800 . ?
C43A H43F 0.9800 . ?
C44A H44D 0.9800 . ?
C44A H44E 0.9800 . ?
C44A H44F 0.9800 . ?
C42A H42D 0.9800 . ?
C42A H42E 0.9800 . ?
C42A H42F 0.9800 . ?
C24A H24D 0.9800 . ?
C24A H24E 0.9800 . ?
C24A H24F 0.9800 . ?
C23A H23D 0.9800 . ?
C23A H23E 0.9800 . ?
C23A H23F 0.9800 . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 Pt2 108.69(17) . . ?
N1 Pt1 N9 94.9(2) . . ?
N7 Pt1 Pt2 66.96(16) . . ?
N7 Pt1 N1 175.2(2) . . ?
N7 Pt1 N9 85.2(2) . . ?
N9 Pt1 Pt2 64.63(17) . . ?
C1 Pt1 Pt2 116.1(2) . . ?
C1 Pt1 N1 89.9(3) . . ?
C1 Pt1 N7 90.4(3) . . ?
C1 Pt1 N9 174.7(3) . . ?
N4 Pt2 Pt1 106.31(18) . . ?
N4 Pt2 N8 94.5(2) . . ?
N8 Pt2 Pt1 64.62(16) . . ?
N10 Pt2 Pt1 67.27(18) . . ?
N10 Pt2 N4 173.0(3) . . ?
N10 Pt2 N8 85.3(2) . . ?
C25 Pt2 Pt1 116.3(2) . . ?
C25 Pt2 N4 89.6(3) . . ?
C25 Pt2 N8 175.3(3) . . ?
C25 Pt2 N10 90.9(3) . . ?
C13 N1 Pt1 128.0(5) . . ?
C14 N1 Pt1 116.1(5) . . ?
C14 N1 C13 115.9(6) . . ?
C16 N2 C13 117.7(7) . . ?
C12 N3 C6 107.7(6) . . ?
C13 N3 C6 125.0(6) . . ?
C13 N3 C12 125.6(6) . . ?
C45 N4 Pt2 127.6(5) . . ?
C48 N4 Pt2 116.3(5) . . ?
C48 N4 C45 116.0(7) . . ?
C30 N5 C40 107.7(6) . . ?
C45 N5 C30 123.2(6) . . ?
C45 N5 C40 124.6(7) . . ?
C46 N6 C45 117.8(8) . . ?
N8 N7 Pt1 112.4(4) . . ?
C60 N7 Pt1 137.2(5) . . ?
C60 N7 N8 109.4(6) . . ?
N7 N8 Pt2 108.5(4) . . ?
C66 N8 Pt2 139.3(5) . . ?
C66 N8 N7 107.2(6) . . ?
N10 N9 Pt1 108.1(4) . . ?
C49 N9 Pt1 138.8(5) . . ?
C49 N9 N10 108.0(6) . . ?
N9 N10 Pt2 112.5(5) . . ?
C55 N10 Pt2 137.2(6) . . ?
C55 N10 N9 109.4(7) . . ?
C2 C1 Pt1 125.5(5) . . ?
C6 C1 Pt1 120.2(5) . . ?
C6 C1 C2 113.7(7) . . ?
C1 C2 H2 117.7 . . ?
C3 C2 C1 124.5(7) . . ?
C3 C2 H2 117.7 . . ?
C2 C3 C7 119.4(7) . . ?
C4 C3 C2 118.8(7) . . ?
C4 C3 C7 121.8(7) . . ?
C3 C4 H4 120.7 . . ?
C3 C4 C5 118.7(7) . . ?
C5 C4 H4 120.7 . . ?
C4 C5 C6 120.7(7) . . ?
C4 C5 C11 131.3(7) . . ?
C6 C5 C11 108.1(7) . . ?
C1 C6 N3 128.5(7) . . ?
C1 C6 C5 123.4(7) . . ?
C5 C6 N3 108.1(6) . . ?
C3 C7 C8 108.4(7) . . ?
C9 C7 C3 109.6(8) . . ?
C9 C7 C8 109.0(10) . . ?
C9 C7 C10 110.7(10) . . ?
C10 C7 C3 112.3(8) . . ?
C10 C7 C8 106.8(10) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 C5 107.4(7) . . ?
C20 C11 C5 131.4(8) . . ?
C20 C11 C12 121.1(7) . . ?
C11 C12 N3 108.7(6) . . ?
C17 C12 N3 131.7(7) . . ?
C17 C12 C11 119.5(7) . . ?
N1 C13 N3 119.1(6) . . ?
N2 C13 N1 124.3(7) . . ?
N2 C13 N3 116.6(7) . . ?
N1 C14 H14 118.8 . . ?
N1 C14 C15 122.5(8) . . ?
C15 C14 H14 118.8 . . ?
C14 C15 H15 121.8 . . ?
C16 C15 C14 116.3(8) . . ?
C16 C15 H15 121.8 . . ?
N2 C16 C15 122.8(7) . . ?
N2 C16 H16 118.6 . . ?
C15 C16 H16 118.6 . . ?
C12 C17 H17 121.0 . . ?
C12 C17 C18 118.1(8) . . ?
C18 C17 H17 121.0 . . ?
C17 C18 H18 118.5 . . ?
C19 C18 C17 123.1(8) . . ?
C19 C18 H18 118.5 . . ?
C18 C19 C21 122.8(9) . . ?
C20 C19 C18 117.4(8) . . ?
C20 C19 C21 119.7(9) . . ?
C11 C20 C19 120.8(8) . . ?
C11 C20 H20 119.6 . . ?
C19 C20 H20 119.6 . . ?
C22 C21 C19 111.6(13) . . ?
C23 C21 C19 114.9(11) . . ?
C23 C21 C22 107.4(11) . . ?
C23 C21 C24 108.9(11) . . ?
C24 C21 C19 107.3(14) . . ?
C24 C21 C22 106.4(12) . . ?
C24A C21 C19 111.5(16) . . ?
C24A C21 C22A 120(2) . . ?
C23A C21 C19 110(2) . . ?
C23A C21 C24A 105(2) . . ?
C23A C21 C22A 103(3) . . ?
C22A C21 C19 106.8(16) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 Pt2 125.9(6) . . ?
C26 C25 C30 114.2(7) . . ?
C30 C25 Pt2 119.4(6) . . ?
C25 C26 H26 117.8 . . ?
C25 C26 C27 124.5(7) . . ?
C27 C26 H26 117.8 . . ?
C26 C27 C31 119.7(7) . . ?
C28 C27 C26 119.0(8) . . ?
C28 C27 C31 121.2(7) . . ?
C27 C28 H28 120.6 . . ?
C27 C28 C29 118.7(7) . . ?
C29 C28 H28 120.6 . . ?
C28 C29 C35 132.5(7) . . ?
C30 C29 C28 119.9(7) . . ?
C30 C29 C35 107.6(7) . . ?
C25 C30 N5 128.0(7) . . ?
C29 C30 N5 108.5(7) . . ?
C29 C30 C25 123.6(7) . . ?
C32 C31 C27 113.1(8) . . ?
C32 C31 C33 108.0(9) . . ?
C32 C31 C34 108.0(9) . . ?
C33 C31 C27 107.5(8) . . ?
C33 C31 C34 108.9(10) . . ?
C34 C31 C27 111.2(8) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 C29 131.2(8) . . ?
C40 C35 C29 109.2(7) . . ?
C40 C35 C36 119.6(8) . . ?
C35 C36 H36 120.2 . . ?
C37 C36 C35 119.5(9) . . ?
C37 C36 H36 120.2 . . ?
C36 C37 C41 120.0(9) . . ?
C38 C37 C36 118.1(8) . . ?
C38 C37 C41 121.9(9) . . ?
C37 C38 H38 117.8 . . ?
C37 C38 C39 124.4(9) . . ?
C39 C38 H38 117.8 . . ?
C38 C39 H39 121.9 . . ?
C40 C39 C38 116.3(9) . . ?
C40 C39 H39 121.9 . . ?
C35 C40 N5 107.0(7) . . ?
C39 C40 N5 130.9(8) . . ?
C39 C40 C35 122.0(7) . . ?
C37 C41 C44A 107.8(9) . . ?
C42 C41 C37 110.1(16) . . ?
C42 C41 C44 109.6(15) . . ?
C43 C41 C37 104.4(17) . . ?
C43 C41 C42 110.6(17) . . ?
C43 C41 C44 110.6(17) . . ?
C44 C41 C37 111.5(14) . . ?
C43A C41 C37 113.1(11) . . ?
C43A C41 C44A 111.5(15) . . ?
C42A C41 C37 107.8(10) . . ?
C42A C41 C43A 108.9(14) . . ?
C42A C41 C44A 107.5(13) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N4 C45 N5 119.6(7) . . ?
N6 C45 N4 124.5(7) . . ?
N6 C45 N5 116.0(7) . . ?
N6 C46 H46 119.4 . . ?
N6 C46 C47 121.3(9) . . ?
C47 C46 H46 119.4 . . ?
C46 C47 H47 120.6 . . ?
C48 C47 C46 118.7(8) . . ?
C48 C47 H47 120.6 . . ?
N4 C48 C47 121.4(8) . . ?
N4 C48 H48 119.3 . . ?
C47 C48 H48 119.3 . . ?
N9 C49 C50 127.4(8) . . ?
N9 C49 C54 108.9(8) . . ?
C54 C49 C50 123.7(8) . . ?
C51 C50 C49 114.1(8) . . ?
C51 C50 C53 109.3(12) . . ?
C52 C50 C49 113.1(9) . . ?
C52 C50 C51 106.9(10) . . ?
C52 C50 C53 106.0(12) . . ?
C53 C50 C49 107.2(8) . . ?
C50 C51 H51A 109.5 . . ?
C50 C51 H51B 109.5 . . ?
C50 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C50 C52 H52A 109.5 . . ?
C50 C52 H52B 109.5 . . ?
C50 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C50 C53 H53A 109.5 . . ?
C50 C53 H53B 109.5 . . ?
C50 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54 126.5 . . ?
C49 C54 C55 106.9(8) . . ?
C55 C54 H54 126.5 . . ?
N10 C55 C54 106.9(7) . . ?
N10 C55 C56 125.7(8) . . ?
C54 C55 C56 126.8(8) . . ?
C55 C56 C58 110.7(9) . . ?
C57 C56 C55 107.1(8) . . ?
C57 C56 C58 108.7(9) . . ?
C59 C56 C55 113.0(8) . . ?
C59 C56 C57 109.2(10) . . ?
C59 C56 C58 108.1(9) . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C56 C58 H58A 109.5 . . ?
C56 C58 H58B 109.5 . . ?
C56 C58 H58C 109.5 . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C56 C59 H59A 109.5 . . ?
C56 C59 H59B 109.5 . . ?
C56 C59 H59C 109.5 . . ?
H59A C59 H59B 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
N7 C60 C61 123.8(7) . . ?
N7 C60 C65 106.8(7) . . ?
C65 C60 C61 128.8(7) . . ?
C60 C61 C62 107.0(7) . . ?
C60 C61 C63 113.3(7) . . ?
C60 C61 C64 109.7(6) . . ?
C62 C61 C63 110.4(8) . . ?
C64 C61 C62 109.7(7) . . ?
C64 C61 C63 106.7(7) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C61 C63 H63A 109.5 . . ?
C61 C63 H63B 109.5 . . ?
C61 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C61 C64 H64A 109.5 . . ?
C61 C64 H64B 109.5 . . ?
C61 C64 H64C 109.5 . . ?
H64A C64 H64B 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C60 C65 H65 126.0 . . ?
C66 C65 C60 108.0(6) . . ?
C66 C65 H65 126.0 . . ?
N8 C66 C65 108.5(7) . . ?
N8 C66 C67 124.7(7) . . ?
C65 C66 C67 126.7(7) . . ?
C66 C67 C68 107.9(8) . . ?
C69 C67 C66 108.1(8) . . ?
C69 C67 C68 107.4(10) . . ?
C70 C67 C66 113.8(8) . . ?
C70 C67 C68 108.9(9) . . ?
C70 C67 C69 110.6(10) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C67 C69 H69A 109.5 . . ?
C67 C69 H69B 109.5 . . ?
C67 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C67 C70 H70A 109.5 . . ?
C67 C70 H70B 109.5 . . ?
C67 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C41 C43A H43D 109.5 . . ?
C41 C43A H43E 109.5 . . ?
C41 C43A H43F 109.5 . . ?
H43D C43A H43E 109.5 . . ?
H43D C43A H43F 109.5 . . ?
H43E C43A H43F 109.5 . . ?
C41 C44A H44D 109.5 . . ?
C41 C44A H44E 109.5 . . ?
C41 C44A H44F 109.5 . . ?
H44D C44A H44E 109.5 . . ?
H44D C44A H44F 109.5 . . ?
H44E C44A H44F 109.5 . . ?
C41 C42A H42D 109.5 . . ?
C41 C42A H42E 109.5 . . ?
C41 C42A H42F 109.5 . . ?
H42D C42A H42E 109.5 . . ?
H42D C42A H42F 109.5 . . ?
H42E C42A H42F 109.5 . . ?
C21 C24A H24D 109.5 . . ?
C21 C24A H24E 109.5 . . ?
C21 C24A H24F 109.5 . . ?
H24D C24A H24E 109.5 . . ?
H24D C24A H24F 109.5 . . ?
H24E C24A H24F 109.5 . . ?
C21 C23A H23D 109.5 . . ?
C21 C23A H23E 109.5 . . ?
C21 C23A H23F 109.5 . . ?
H23D C23A H23E 109.5 . . ?
H23D C23A H23F 109.5 . . ?
H23E C23A H23F 109.5 . . ?
C21 C22A H22D 109.5 . . ?
C21 C22A H22E 109.5 . . ?
C21 C22A H22F 109.5 . . ?
H22D C22A H22E 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N1 C13 N2 168.5(6) . . . . ?
Pt1 N1 C13 N3 -11.2(11) . . . . ?
Pt1 N1 C14 C15 -172.4(8) . . . . ?
Pt1 N7 N8 Pt2 29.9(5) . . . . ?
Pt1 N7 N8 C66 -170.0(5) . . . . ?
Pt1 N7 C60 C61 -22.3(13) . . . . ?
Pt1 N7 C60 C65 166.5(6) . . . . ?
Pt1 N9 N10 Pt2 29.8(5) . . . . ?
Pt1 N9 N10 C55 -159.6(5) . . . . ?
Pt1 N9 C49 C50 -32.6(13) . . . . ?
Pt1 N9 C49 C54 150.0(7) . . . . ?
Pt1 C1 C2 C3 168.5(6) . . . . ?
Pt1 C1 C6 N3 10.8(11) . . . . ?
Pt1 C1 C6 C5 -166.2(6) . . . . ?
Pt2 N4 C45 N5 -4.8(11) . . . . ?
Pt2 N4 C45 N6 176.3(7) . . . . ?
Pt2 N4 C48 C47 -176.8(8) . . . . ?
Pt2 N8 C66 C65 150.1(7) . . . . ?
Pt2 N8 C66 C67 -33.4(14) . . . . ?
Pt2 N10 C55 C54 167.0(6) . . . . ?
Pt2 N10 C55 C56 -21.4(13) . . . . ?
Pt2 C25 C26 C27 170.9(6) . . . . ?
Pt2 C25 C30 N5 9.1(11) . . . . ?
Pt2 C25 C30 C29 -169.0(6) . . . . ?
N1 C14 C15 C16 -0.7(16) . . . . ?
N3 C12 C17 C18 -175.6(8) . . . . ?
N6 C46 C47 C48 -3.7(18) . . . . ?
N7 N8 C66 C65 -0.3(9) . . . . ?
N7 N8 C66 C67 176.2(8) . . . . ?
N7 C60 C61 C62 -73.6(10) . . . . ?
N7 C60 C61 C63 48.3(11) . . . . ?
N7 C60 C61 C64 167.4(8) . . . . ?
N7 C60 C65 C66 0.9(10) . . . . ?
N8 N7 C60 C61 170.1(7) . . . . ?
N8 N7 C60 C65 -1.1(9) . . . . ?
N8 C66 C67 C68 151.8(9) . . . . ?
N8 C66 C67 C69 -92.5(11) . . . . ?
N8 C66 C67 C70 30.8(13) . . . . ?
N9 N10 C55 C54 -0.1(8) . . . . ?
N9 N10 C55 C56 171.5(7) . . . . ?
N9 C49 C50 C51 21.5(14) . . . . ?
N9 C49 C50 C52 144.1(11) . . . . ?
N9 C49 C50 C53 -99.5(13) . . . . ?
N9 C49 C54 C55 -0.1(10) . . . . ?
N10 N9 C49 C50 177.4(8) . . . . ?
N10 N9 C49 C54 0.0(9) . . . . ?
N10 C55 C56 C57 -71.0(11) . . . . ?
N10 C55 C56 C58 170.7(9) . . . . ?
N10 C55 C56 C59 49.3(12) . . . . ?
C1 C2 C3 C4 -1.5(12) . . . . ?
C1 C2 C3 C7 -179.0(7) . . . . ?
C2 C1 C6 N3 -177.3(7) . . . . ?
C2 C1 C6 C5 5.7(11) . . . . ?
C2 C3 C4 C5 3.2(11) . . . . ?
C2 C3 C7 C8 -58.4(11) . . . . ?
C2 C3 C7 C9 60.4(11) . . . . ?
C2 C3 C7 C10 -176.2(10) . . . . ?
C3 C4 C5 C6 -0.6(12) . . . . ?
C3 C4 C5 C11 178.8(8) . . . . ?
C4 C3 C7 C8 124.1(10) . . . . ?
C4 C3 C7 C9 -117.1(10) . . . . ?
C4 C3 C7 C10 6.4(13) . . . . ?
C4 C5 C6 N3 178.2(7) . . . . ?
C4 C5 C6 C1 -4.2(12) . . . . ?
C4 C5 C11 C12 -178.1(8) . . . . ?
C4 C5 C11 C20 5.7(15) . . . . ?
C5 C11 C12 N3 -0.9(9) . . . . ?
C5 C11 C12 C17 -179.9(7) . . . . ?
C5 C11 C20 C19 176.5(9) . . . . ?
C6 N3 C12 C11 0.1(8) . . . . ?
C6 N3 C12 C17 178.9(9) . . . . ?
C6 N3 C13 N1 -16.9(11) . . . . ?
C6 N3 C13 N2 163.4(7) . . . . ?
C6 C1 C2 C3 -2.9(11) . . . . ?
C6 C5 C11 C12 1.3(9) . . . . ?
C6 C5 C11 C20 -174.8(9) . . . . ?
C7 C3 C4 C5 -179.3(8) . . . . ?
C11 C5 C6 N3 -1.3(8) . . . . ?
C11 C5 C6 C1 176.3(7) . . . . ?
C11 C12 C17 C18 3.1(13) . . . . ?
C12 N3 C6 C1 -176.6(7) . . . . ?
C12 N3 C6 C5 0.7(8) . . . . ?
C12 N3 C13 N1 179.9(7) . . . . ?
C12 N3 C13 N2 0.2(11) . . . . ?
C12 C11 C20 C19 0.7(14) . . . . ?
C12 C17 C18 C19 -0.6(15) . . . . ?
C13 N1 C14 C15 5.6(14) . . . . ?
C13 N2 C16 C15 -1.8(16) . . . . ?
C13 N3 C6 C1 17.6(12) . . . . ?
C13 N3 C6 C5 -165.0(7) . . . . ?
C13 N3 C12 C11 165.7(7) . . . . ?
C13 N3 C12 C17 -15.5(13) . . . . ?
C14 N1 C13 N2 -9.2(12) . . . . ?
C14 N1 C13 N3 171.1(8) . . . . ?
C14 C15 C16 N2 -1.4(17) . . . . ?
C16 N2 C13 N1 7.4(13) . . . . ?
C16 N2 C13 N3 -172.9(8) . . . . ?
C17 C18 C19 C20 -1.8(16) . . . . ?
C17 C18 C19 C21 174.7(10) . . . . ?
C18 C19 C20 C11 1.7(16) . . . . ?
C18 C19 C21 C22 -125.3(15) . . . . ?
C18 C19 C21 C23 -2.7(18) . . . . ?
C18 C19 C21 C24 118.5(15) . . . . ?
C18 C19 C21 C24A 150(2) . . . . ?
C18 C19 C21 C23A 34(2) . . . . ?
C18 C19 C21 C22A -78(2) . . . . ?
C20 C11 C12 N3 175.8(8) . . . . ?
C20 C11 C12 C17 -3.2(13) . . . . ?
C20 C19 C21 C22 51.2(17) . . . . ?
C20 C19 C21 C23 173.7(14) . . . . ?
C20 C19 C21 C24 -65.0(16) . . . . ?
C20 C19 C21 C24A -34(2) . . . . ?
C20 C19 C21 C23A -150(2) . . . . ?
C20 C19 C21 C22A 99(2) . . . . ?
C21 C19 C20 C11 -174.9(9) . . . . ?
C25 C26 C27 C28 -1.5(12) . . . . ?
C25 C26 C27 C31 179.4(7) . . . . ?
C26 C25 C30 N5 -178.0(7) . . . . ?
C26 C25 C30 C29 3.8(11) . . . . ?
C26 C27 C28 C29 2.1(12) . . . . ?
C26 C27 C31 C32 175.1(9) . . . . ?
C26 C27 C31 C33 -65.8(11) . . . . ?
C26 C27 C31 C34 53.3(11) . . . . ?
C27 C28 C29 C30 0.1(12) . . . . ?
C27 C28 C29 C35 179.5(8) . . . . ?
C28 C27 C31 C32 -4.0(13) . . . . ?
C28 C27 C31 C33 115.2(10) . . . . ?
C28 C27 C31 C34 -125.8(10) . . . . ?
C28 C29 C30 N5 178.2(7) . . . . ?
C28 C29 C30 C25 -3.3(12) . . . . ?
C28 C29 C35 C36 2.1(15) . . . . ?
C28 C29 C35 C40 -178.4(8) . . . . ?
C29 C35 C36 C37 179.3(8) . . . . ?
C29 C35 C40 N5 -0.3(9) . . . . ?
C29 C35 C40 C39 -178.1(8) . . . . ?
C30 N5 C40 C35 -0.5(8) . . . . ?
C30 N5 C40 C39 177.1(9) . . . . ?
C30 N5 C45 N4 -27.1(11) . . . . ?
C30 N5 C45 N6 151.9(8) . . . . ?
C30 C25 C26 C27 -1.4(11) . . . . ?
C30 C29 C35 C36 -178.5(8) . . . . ?
C30 C29 C35 C40 1.0(9) . . . . ?
C31 C27 C28 C29 -178.8(7) . . . . ?
C35 C29 C30 N5 -1.3(8) . . . . ?
C35 C29 C30 C25 177.2(7) . . . . ?
C35 C36 C37 C38 -0.6(13) . . . . ?
C35 C36 C37 C41 -178.5(8) . . . . ?
C36 C35 C40 N5 179.3(7) . . . . ?
C36 C35 C40 C39 1.4(13) . . . . ?
C36 C37 C38 C39 0.1(15) . . . . ?
C36 C37 C41 C42 139(2) . . . . ?
C36 C37 C41 C43 -102.3(19) . . . . ?
C36 C37 C41 C44 17(2) . . . . ?
C36 C37 C41 C43A -173.0(15) . . . . ?
C36 C37 C41 C44A -49.2(15) . . . . ?
C36 C37 C41 C42A 66.5(15) . . . . ?
C37 C38 C39 C40 1.1(15) . . . . ?
C38 C37 C41 C42 -39(2) . . . . ?
C38 C37 C41 C43 80(2) . . . . ?
C38 C37 C41 C44 -160.8(19) . . . . ?
C38 C37 C41 C43A 9.1(19) . . . . ?
C38 C37 C41 C44A 132.9(13) . . . . ?
C38 C37 C41 C42A -111.3(14) . . . . ?
C38 C39 C40 N5 -179.1(9) . . . . ?
C38 C39 C40 C35 -1.9(13) . . . . ?
C40 N5 C30 C25 -177.2(7) . . . . ?
C40 N5 C30 C29 1.2(8) . . . . ?
C40 N5 C45 N4 179.8(7) . . . . ?
C40 N5 C45 N6 -1.3(12) . . . . ?
C40 C35 C36 C37 -0.1(12) . . . . ?
C41 C37 C38 C39 178.0(10) . . . . ?
C45 N4 C48 C47 5.2(13) . . . . ?
C45 N5 C30 C25 25.7(12) . . . . ?
C45 N5 C30 C29 -155.8(7) . . . . ?
C45 N5 C40 C35 156.1(7) . . . . ?
C45 N5 C40 C39 -26.3(14) . . . . ?
C45 N6 C46 C47 3.1(17) . . . . ?
C46 N6 C45 N4 1.9(15) . . . . ?
C46 N6 C45 N5 -177.1(9) . . . . ?
C46 C47 C48 N4 -0.7(16) . . . . ?
C48 N4 C45 N5 172.9(7) . . . . ?
C48 N4 C45 N6 -6.0(12) . . . . ?
C49 N9 N10 Pt2 -170.5(5) . . . . ?
C49 N9 N10 C55 0.1(8) . . . . ?
C49 C54 C55 N10 0.1(9) . . . . ?
C49 C54 C55 C56 -171.4(8) . . . . ?
C50 C49 C54 C55 -177.6(8) . . . . ?
C54 C49 C50 C51 -161.4(11) . . . . ?
C54 C49 C50 C52 -38.9(13) . . . . ?
C54 C49 C50 C53 77.5(13) . . . . ?
C54 C55 C56 C57 99.0(11) . . . . ?
C54 C55 C56 C58 -19.3(13) . . . . ?
C54 C55 C56 C59 -140.7(10) . . . . ?
C60 N7 N8 Pt2 -159.2(5) . . . . ?
C60 N7 N8 C66 0.9(9) . . . . ?
C60 C65 C66 N8 -0.4(10) . . . . ?
C60 C65 C66 C67 -176.8(8) . . . . ?
C61 C60 C65 C66 -169.7(8) . . . . ?
C65 C60 C61 C62 95.6(10) . . . . ?
C65 C60 C61 C63 -142.5(9) . . . . ?
C65 C60 C61 C64 -23.4(12) . . . . ?
C65 C66 C67 C68 -32.4(13) . . . . ?
C65 C66 C67 C69 83.4(12) . . . . ?
C65 C66 C67 C70 -153.3(10) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 219 electrons were 
found in a volume of 856Å³ in 1 void per unit cell. 
This is consistent with the presence of 
3[CH2Cl2] per Asymmetric Unit 
which account for 252 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.433 -0.433 0.000 855.9 219.0 '6 CH2Cl2'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_221212yhb
_database_code_depnum_ccdc_archive 'CCDC 2285561'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2024-02-22 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2024-02-22
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C74 H74 N10 Pt2, C7 H8, 3[C7H8]'
_chemical_formula_sum            'C102 H106 N10 Pt2'
_chemical_formula_weight         1862.14
_chemical_melting_point          ?
# end Validation Reply Form
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -5.3886 5.5592 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.5142(12)
_cell_length_b                   17.7460(14)
_cell_length_c                   21.0372(17)
_cell_angle_alpha                65.743(5)
_cell_angle_beta                 88.505(5)
_cell_angle_gamma                78.217(5)
_cell_volume                     4825.9(7)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9077
_cell_measurement_temperature    213.00
_cell_measurement_theta_max      55.176
_cell_measurement_theta_min      4.430
_shelx_estimated_absorpt_T_max   0.828
_shelx_estimated_absorpt_T_min   0.771
_exptl_absorpt_coefficient_mu    3.912
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.4504
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1370 before and 0.0856 after correction.
The Ratio of minimum to maximum transmission is 0.5999.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.281
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1888
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0737
_diffrn_reflns_av_unetI/netI     0.0752
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            66341
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         55.517
_diffrn_reflns_theta_min         2.711
_diffrn_ambient_temperature      213.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_source_current           2.86
_diffrn_source_power             0.1995708
_diffrn_source_voltage           69.78
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13361
_reflns_number_total             18298
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         6.130
_refine_diff_density_min         -3.235
_refine_diff_density_rms         0.202
_refine_ls_extinction_coef       0.00102(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.300
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     815
_refine_ls_number_reflns         18298
_refine_ls_number_restraints     82
_refine_ls_R_factor_all          0.1162
_refine_ls_R_factor_gt           0.1011
_refine_ls_restrained_S_all      1.305
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.2000P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3076
_refine_ls_wR_factor_ref         0.3308
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C48-C46
 2.44 with sigma of 0.01
 C23-C22 = C25-C22 = C24-C22
 1.53 with sigma of 0.01
 C24-C23
 2.44 with sigma of 0.01
 C46-C45
 1.53 with sigma of 0.01
 H32-H48C
 2.05 with sigma of 0.01
3. Rigid bond restraints
 C78, C79
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
 C33, C34, C76, C77
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
4. Uiso/Uaniso restraints and constraints
C45 \\sim C46 \\sim C47 \\sim C48: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
C22 \\sim C23 \\sim C24 \\sim C25: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
C30 \\sim C31 \\sim C32 \\sim C33 \\sim C34 \\sim C35: within 2A with sigma of
0.01 and sigma for terminal atoms of 0.02 within 2A
C45 \\sim C46 \\sim C48 \\sim C47: within 2A with sigma of 0.005 and sigma for
terminal atoms of 0.01 within 2A
5.a Me refined with riding coordinates:
 C24(H24A,H24B,H24C)
5.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C11(H11), C14(H14), C16(H16),
 C26(H26), C27(H27), C28(H28), C34(H34), C32(H32), C31(H31), C37(H37), C39(H39),
  C49(H49), C51(H51), C52(H52), C53(H53), C54(H54), C55(H55), C57(H57),
 C58(H58), C59(H59), C60(H60), C61(H61), C62(H62), C64(H64), C65(H65), C66(H66),
  C67(H67), C68(H68), C70(H70), C71(H71), C72(H72), C73(H73), C74(H74),
 C80(H80), C79(H79), C78(H78), C77(H77), C76(H76)
5.c Fitted hexagon refined as free rotating group:
 C35(C34,C33,C32,C31,C30), C40(C36,C37,C38,C39,C2), C75(C80,C79,C78,C77,C76)
5.d Idealised Me refined as rotating group:
 C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C21(H21A,H21B,H21C), C23(H23A,H23B,
 H23C), C25(H25A,H25B,H25C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C44(H44A,
 H44B,H44C), C46(H46A,H46B,H46C), C47(H47A,H47B,H47C), C48(H48A,H48B,H48C),
 C81(H81A,H81B,H81C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.83468(2) 0.51083(2) 0.31419(2) 0.05612(19) Uani 1 1 d . . . . .
Pt2 Pt 0.76883(2) 0.35674(2) 0.40909(2) 0.05988(19) Uani 1 1 d . . . . .
N1 N 0.8074(5) 0.5810(4) 0.3714(4) 0.0577(17) Uani 1 1 d . . . . .
N2 N 0.7335(5) 0.7078(4) 0.2806(4) 0.0590(17) Uani 1 1 d . . . . .
N3 N 0.7623(5) 0.7063(5) 0.3876(4) 0.0650(18) Uani 1 1 d . . . . .
N4 N 0.6935(5) 0.4068(5) 0.4697(4) 0.0642(19) Uani 1 1 d . . . . .
N5 N 0.5962(5) 0.5141(5) 0.3754(4) 0.0620(17) Uani 1 1 d . . . . .
N6 N 0.6033(5) 0.5298(5) 0.4800(4) 0.0660(19) Uani 1 1 d . . . . .
N7 N 0.8468(6) 0.3107(5) 0.3456(5) 0.069(2) Uani 1 1 d . . . . .
N8 N 0.8662(5) 0.4400(5) 0.2587(5) 0.068(2) Uani 1 1 d . . . . .
N9 N 0.9604(5) 0.4354(5) 0.3787(4) 0.0632(18) Uani 1 1 d . . . . .
N10 N 0.9016(5) 0.3301(5) 0.4675(4) 0.069(2) Uani 1 1 d . . . . .
C1 C 0.7299(6) 0.5918(5) 0.2426(5) 0.0560(19) Uani 1 1 d . . . . .
C3 C 0.8322(6) 0.5398(6) 0.4425(5) 0.067(2) Uani 1 1 d . . . . .
H3 H 0.854351 0.480814 0.461869 0.080 Uiso 1 1 calc R U . . .
C4 C 0.8263(6) 0.5792(6) 0.4848(5) 0.062(2) Uani 1 1 d . . . . .
H4 H 0.845970 0.550110 0.532477 0.074 Uiso 1 1 calc R U . . .
C5 C 0.7909(7) 0.6625(6) 0.4556(5) 0.069(2) Uani 1 1 d . . . . .
H5 H 0.785690 0.692024 0.484237 0.083 Uiso 1 1 calc R U . . .
C6 C 0.7681(6) 0.6641(6) 0.3475(4) 0.059(2) Uani 1 1 d . . . . .
C7 C 0.6950(6) 0.7969(5) 0.2490(5) 0.060(2) Uani 1 1 d . . . . .
C8 C 0.7105(7) 0.8614(6) 0.2648(5) 0.070(2) Uani 1 1 d . . . . .
H8 H 0.748468 0.849850 0.304558 0.084 Uiso 1 1 calc R U . . .
C9 C 0.6685(8) 0.9443(6) 0.2203(6) 0.081(3) Uani 1 1 d . . . . .
H9 H 0.677707 0.988536 0.231427 0.097 Uiso 1 1 calc R U . . .
C10 C 0.6138(8) 0.9640(6) 0.1606(6) 0.077(3) Uani 1 1 d . . . . .
C11 C 0.6037(7) 0.8975(6) 0.1448(5) 0.068(2) Uani 1 1 d . . . . .
H11 H 0.567884 0.909219 0.103930 0.081 Uiso 1 1 calc R U . . .
C12 C 0.6444(6) 0.8153(5) 0.1869(5) 0.062(2) Uani 1 1 d . . . . .
C13 C 0.6466(6) 0.7349(5) 0.1804(4) 0.063(2) Uani 1 1 d . . . . .
C14 C 0.6099(6) 0.7187(6) 0.1299(4) 0.060(2) Uani 1 1 d . . . . .
H14 H 0.572804 0.762268 0.091275 0.071 Uiso 1 1 calc R U . . .
C15 C 0.6292(7) 0.6347(6) 0.1371(5) 0.064(2) Uani 1 1 d . . . . .
C16 C 0.6873(6) 0.5758(5) 0.1924(5) 0.059(2) Uani 1 1 d . . . . .
H16 H 0.699666 0.519665 0.197053 0.071 Uiso 1 1 calc R U . . .
C17 C 0.7055(6) 0.6717(6) 0.2383(5) 0.058(2) Uani 1 1 d . . . . .
C18 C 0.5902(7) 0.6179(6) 0.0779(5) 0.068(2) Uani 1 1 d . . . . .
C19 C 0.6096(9) 0.5242(7) 0.0934(6) 0.090(3) Uani 1 1 d . . . . .
H19A H 0.676588 0.500413 0.104328 0.135 Uiso 1 1 calc R U . . .
H19B H 0.589492 0.517285 0.052894 0.135 Uiso 1 1 calc R U . . .
H19C H 0.575020 0.495151 0.132990 0.135 Uiso 1 1 calc R U . . .
C20 C 0.4820(8) 0.6485(8) 0.0681(7) 0.093(3) Uani 1 1 d . . . . .
H20A H 0.454504 0.622587 0.112305 0.139 Uiso 1 1 calc R U . . .
H20B H 0.457594 0.632551 0.033969 0.139 Uiso 1 1 calc R U . . .
H20C H 0.465913 0.709518 0.051736 0.139 Uiso 1 1 calc R U . . .
C21 C 0.6345(9) 0.6672(8) 0.0110(6) 0.090(3) Uani 1 1 d . . . . .
H21A H 0.615764 0.727272 -0.000584 0.135 Uiso 1 1 calc R U . . .
H21B H 0.613295 0.655849 -0.026870 0.135 Uiso 1 1 calc R U . . .
H21C H 0.702670 0.649826 0.017988 0.135 Uiso 1 1 calc R U . . .
C22 C 0.5721(11) 1.0563(7) 0.1147(7) 0.133(5) Uani 1 1 d D U . . .
C23 C 0.5098(13) 1.0964(9) 0.1570(8) 0.177(7) Uani 1 1 d D U . . .
H23A H 0.459387 1.140663 0.126387 0.265 Uiso 1 1 calc R U . . .
H23B H 0.547366 1.120406 0.178151 0.265 Uiso 1 1 calc R U . . .
H23C H 0.482920 1.053591 0.193329 0.265 Uiso 1 1 calc R U . . .
C24 C 0.6507(12) 1.1067(10) 0.0919(11) 0.226(10) Uani 1 1 d D U . . .
H24A H 0.689390 1.096591 0.132721 0.339 Uiso 1 1 calc R U . . .
H24B H 0.689534 1.088854 0.060338 0.339 Uiso 1 1 calc R U . . .
H24C H 0.622711 1.166609 0.068350 0.339 Uiso 1 1 calc R U . . .
C25 C 0.5070(15) 1.0673(9) 0.0550(10) 0.179(8) Uani 1 1 d D U . . .
H25A H 0.469320 1.024448 0.071385 0.269 Uiso 1 1 calc R U . . .
H25B H 0.544144 1.061646 0.017638 0.269 Uiso 1 1 calc R U . . .
H25C H 0.465724 1.122983 0.037819 0.269 Uiso 1 1 calc R U . . .
C26 C 0.7139(7) 0.3735(6) 0.5399(5) 0.067(2) Uani 1 1 d . . . . .
H26 H 0.752993 0.319362 0.561183 0.080 Uiso 1 1 calc R U . . .
C27 C 0.6812(7) 0.4137(6) 0.5808(5) 0.068(2) Uani 1 1 d . . . . .
H27 H 0.692957 0.387923 0.629574 0.082 Uiso 1 1 calc R U . . .
C28 C 0.6289(7) 0.4959(6) 0.5458(6) 0.074(3) Uani 1 1 d . . . . .
H28 H 0.611264 0.528526 0.571577 0.089 Uiso 1 1 calc R U . . .
C29 C 0.6315(6) 0.4845(5) 0.4421(5) 0.061(2) Uani 1 1 d . . . . .
C35 C 0.4777(4) 0.5797(3) 0.2909(3) 0.070(2) Uani 1 1 d G U . . .
C34 C 0.4093(4) 0.6471(4) 0.2467(3) 0.077(2) Uani 1 1 d G U . . .
H34 H 0.374100 0.640699 0.213045 0.093 Uiso 1 1 calc R U . . .
C33 C 0.3928(4) 0.7241(3) 0.2523(3) 0.081(2) Uani 1 1 d G U . . .
C32 C 0.4448(5) 0.7336(3) 0.3020(4) 0.075(2) Uani 1 1 d G U . . .
H32 H 0.433692 0.785612 0.305785 0.090 Uiso 1 1 calc DR U . . .
C31 C 0.5133(4) 0.6661(4) 0.3462(3) 0.069(2) Uani 1 1 d G U . . .
H31 H 0.548442 0.672564 0.379855 0.083 Uiso 1 1 calc R U . . .
C30 C 0.5297(4) 0.5892(3) 0.3406(3) 0.066(2) Uani 1 1 d G U . . .
C40 C 0.5883(4) 0.4634(4) 0.3409(3) 0.060(2) Uani 1 1 d G . . . .
C36 C 0.5093(4) 0.4968(3) 0.2942(3) 0.063(2) Uani 1 1 d G . . . .
C37 C 0.4866(4) 0.4522(4) 0.2580(3) 0.068(2) Uani 1 1 d G . . . .
H37 H 0.433213 0.474754 0.226454 0.082 Uiso 1 1 calc R U . . .
C38 C 0.5430(5) 0.3741(4) 0.2684(3) 0.079(3) Uani 1 1 d G . . . .
C39 C 0.6220(4) 0.3407(3) 0.3151(4) 0.078(3) Uani 1 1 d G . . . .
H39 H 0.660055 0.287929 0.322091 0.094 Uiso 1 1 calc R U . . .
C2 C 0.6446(4) 0.3853(4) 0.3513(3) 0.069(2) Uani 1 1 d G . . . .
C41 C 0.5127(9) 0.3190(8) 0.2379(7) 0.091(3) Uani 1 1 d . . . . .
C42 C 0.4325(14) 0.3606(13) 0.1831(11) 0.165(8) Uani 1 1 d . . . . .
H42A H 0.373245 0.355526 0.205216 0.248 Uiso 1 1 calc R U . . .
H42B H 0.438622 0.333154 0.151215 0.248 Uiso 1 1 calc R U . . .
H42C H 0.433766 0.419892 0.157341 0.248 Uiso 1 1 calc R U . . .
C43 C 0.5961(12) 0.2889(9) 0.2008(8) 0.123(5) Uani 1 1 d . . . . .
H43A H 0.611407 0.337461 0.162433 0.185 Uiso 1 1 calc R U . . .
H43B H 0.578688 0.250991 0.182965 0.185 Uiso 1 1 calc R U . . .
H43C H 0.650492 0.259484 0.233838 0.185 Uiso 1 1 calc R U . . .
C44 C 0.4903(15) 0.2362(11) 0.2976(9) 0.161(8) Uani 1 1 d . . . . .
H44A H 0.470597 0.201804 0.276856 0.241 Uiso 1 1 calc R U . . .
H44B H 0.440177 0.251634 0.324181 0.241 Uiso 1 1 calc R U . . .
H44C H 0.546436 0.204312 0.328352 0.241 Uiso 1 1 calc R U . . .
C45 C 0.3163(11) 0.8018(10) 0.2047(8) 0.158(6) Uani 1 1 d D U . . .
C46 C 0.3508(12) 0.8327(11) 0.1317(7) 0.195(7) Uani 1 1 d D U . . .
H46A H 0.383298 0.784672 0.123085 0.293 Uiso 1 1 calc R U . . .
H46B H 0.393743 0.869641 0.127321 0.293 Uiso 1 1 calc R U . . .
H46C H 0.297410 0.863627 0.097924 0.293 Uiso 1 1 calc R U . . .
C47 C 0.2275(11) 0.7928(11) 0.2280(11) 0.188(7) Uani 1 1 d . U . . .
H47A H 0.230811 0.735494 0.262655 0.283 Uiso 1 1 calc R U . . .
H47B H 0.184642 0.804311 0.188944 0.283 Uiso 1 1 calc R U . . .
H47C H 0.204724 0.832321 0.248780 0.283 Uiso 1 1 calc R U . . .
C48 C 0.3266(13) 0.8882(10) 0.2210(9) 0.177(7) Uani 1 1 d D U . . .
H48A H 0.307702 0.879343 0.267699 0.266 Uiso 1 1 calc R U . . .
H48B H 0.286174 0.938940 0.187125 0.266 Uiso 1 1 calc R U . . .
H48C H 0.391528 0.894621 0.217303 0.266 Uiso 1 1 calc DR U . . .
C49 C 0.8742(7) 0.3566(6) 0.2874(6) 0.069(2) Uani 1 1 d . . . . .
H49 H 0.904046 0.327940 0.261007 0.083 Uiso 1 1 calc R U . . .
C50 C 0.8772(8) 0.2214(6) 0.3718(7) 0.079(3) Uani 1 1 d . . . . .
C51 C 0.8199(9) 0.1664(7) 0.4072(6) 0.083(3) Uani 1 1 d . . . . .
H51 H 0.758452 0.187921 0.415677 0.100 Uiso 1 1 calc R U . . .
C52 C 0.8522(10) 0.0781(8) 0.4308(7) 0.099(4) Uani 1 1 d . . . . .
H52 H 0.810685 0.041492 0.450713 0.119 Uiso 1 1 calc R U . . .
C53 C 0.9412(12) 0.0472(9) 0.4248(11) 0.139(6) Uani 1 1 d . . . . .
H53 H 0.965915 -0.011311 0.447060 0.166 Uiso 1 1 calc R U . . .
C54 C 0.9980(11) 0.1012(8) 0.3857(10) 0.133(6) Uani 1 1 d . . . . .
H54 H 1.058193 0.078227 0.376109 0.159 Uiso 1 1 calc R U . . .
C55 C 0.9684(10) 0.1878(8) 0.3605(9) 0.128(6) Uani 1 1 d . . . . .
H55 H 1.009047 0.223519 0.336144 0.154 Uiso 1 1 calc R U . . .
C56 C 0.8927(7) 0.4768(7) 0.1882(5) 0.064(2) Uani 1 1 d . . . . .
C57 C 0.9357(8) 0.5447(7) 0.1652(6) 0.085(3) Uani 1 1 d . . . . .
H57 H 0.948483 0.564570 0.198446 0.103 Uiso 1 1 calc R U . . .
C58 C 0.9615(9) 0.5857(9) 0.1000(7) 0.098(4) Uani 1 1 d . . . . .
H58 H 0.992863 0.630631 0.088276 0.117 Uiso 1 1 calc R U . . .
C59 C 0.9393(12) 0.5580(10) 0.0530(8) 0.125(6) Uani 1 1 d . . . . .
H59 H 0.953531 0.586311 0.006428 0.150 Uiso 1 1 calc R U . . .
C60 C 0.8941(10) 0.4860(9) 0.0705(8) 0.109(4) Uani 1 1 d . . . . .
H60 H 0.881513 0.466332 0.037144 0.131 Uiso 1 1 calc R U . . .
C61 C 0.8711(8) 0.4490(7) 0.1386(6) 0.080(3) Uani 1 1 d . . . . .
H61 H 0.840024 0.403671 0.151993 0.096 Uiso 1 1 calc R U . . .
C62 C 0.9702(6) 0.3670(6) 0.4366(5) 0.063(2) Uani 1 1 d . . . . .
H62 H 1.031329 0.342119 0.458014 0.075 Uiso 1 1 calc R U . . .
C63 C 1.0461(6) 0.4611(6) 0.3534(5) 0.063(2) Uani 1 1 d . . . . .
C64 C 1.0508(7) 0.5455(7) 0.3279(5) 0.074(3) Uani 1 1 d . . . . .
H64 H 0.996698 0.586779 0.324501 0.088 Uiso 1 1 calc R U . . .
C65 C 1.1385(8) 0.5693(8) 0.3069(6) 0.090(3) Uani 1 1 d . . . . .
H65 H 1.142976 0.625841 0.293690 0.107 Uiso 1 1 calc R U . . .
C66 C 1.2156(8) 0.5125(9) 0.3054(6) 0.098(4) Uani 1 1 d . . . . .
H66 H 1.272377 0.528850 0.289060 0.118 Uiso 1 1 calc R U . . .
C67 C 1.2066(8) 0.4269(10) 0.3298(6) 0.095(4) Uani 1 1 d . . . . .
H67 H 1.259660 0.385860 0.330826 0.114 Uiso 1 1 calc R U . . .
C68 C 1.1254(7) 0.4025(7) 0.3515(6) 0.079(3) Uani 1 1 d . . . . .
H68 H 1.121875 0.345599 0.365553 0.095 Uiso 1 1 calc R U . . .
C69 C 0.9233(6) 0.2668(6) 0.5365(5) 0.062(2) Uani 1 1 d . . . . .
C70 C 0.9738(8) 0.2787(8) 0.5839(6) 0.087(3) Uani 1 1 d . . . . .
H70 H 0.992906 0.330296 0.571018 0.105 Uiso 1 1 calc R U . . .
C71 C 0.9975(10) 0.2162(9) 0.6509(7) 0.101(4) Uani 1 1 d . . . . .
H71 H 1.034384 0.225272 0.682057 0.121 Uiso 1 1 calc R U . . .
C72 C 0.9681(10) 0.1411(10) 0.6727(8) 0.115(5) Uani 1 1 d . . . . .
H72 H 0.985124 0.098606 0.717976 0.138 Uiso 1 1 calc R U . . .
C73 C 0.9125(11) 0.1297(8) 0.6257(7) 0.100(4) Uani 1 1 d . . . . .
H73 H 0.889318 0.079882 0.639851 0.120 Uiso 1 1 calc R U . . .
C74 C 0.8913(9) 0.1912(6) 0.5587(6) 0.084(3) Uani 1 1 d . . . . .
H74 H 0.854617 0.182281 0.527268 0.100 Uiso 1 1 calc R U . . .
C75 C 0.5137(8) 0.2094(5) 0.5358(5) 0.109(5) Uani 1 1 d G . . . .
C80 C 0.4728(6) 0.1624(6) 0.5956(5) 0.107(4) Uani 1 1 d G . . . .
H80 H 0.409301 0.181037 0.602211 0.128 Uiso 1 1 calc R U . . .
C79 C 0.5257(9) 0.0879(6) 0.6457(5) 0.140(6) Uani 1 1 d G U . . .
H79 H 0.498074 0.056126 0.686172 0.168 Uiso 1 1 calc R U . . .
C78 C 0.6196(8) 0.0603(7) 0.6360(7) 0.151(7) Uani 1 1 d G U . . .
H78 H 0.655382 0.009941 0.669844 0.181 Uiso 1 1 calc R U . . .
C77 C 0.6605(6) 0.1073(8) 0.5761(8) 0.172(9) Uani 1 1 d G U . . .
H77 H 0.723918 0.088668 0.569555 0.206 Uiso 1 1 calc R U . . .
C76 C 0.6075(8) 0.1818(8) 0.5261(6) 0.164(8) Uani 1 1 d G U . . .
H76 H 0.635147 0.213580 0.485592 0.196 Uiso 1 1 calc R U . . .
C81 C 0.4573(15) 0.2886(10) 0.4773(10) 0.162(8) Uani 1 1 d . . . . .
H81A H 0.499005 0.326295 0.453145 0.243 Uiso 1 1 calc R U . . .
H81B H 0.408240 0.317051 0.496855 0.243 Uiso 1 1 calc R U . . .
H81C H 0.428894 0.272934 0.444537 0.243 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 2.9763(5) . ?
Pt1 N1 2.039(7) . ?
Pt1 N8 2.023(9) . ?
Pt1 N9 2.145(7) . ?
Pt1 C1 2.024(9) . ?
Pt2 N4 2.017(8) . ?
Pt2 N7 2.042(8) . ?
Pt2 N10 2.172(8) . ?
Pt2 C2 2.054(4) . ?
N1 C3 1.387(12) . ?
N1 C6 1.348(11) . ?
N2 C6 1.348(11) . ?
N2 C7 1.432(11) . ?
N2 C17 1.401(11) . ?
N3 C5 1.346(11) . ?
N3 C6 1.329(11) . ?
N4 C26 1.363(12) . ?
N4 C29 1.381(11) . ?
N5 C29 1.353(11) . ?
N5 C30 1.397(8) . ?
N5 C40 1.391(8) . ?
N6 C28 1.292(12) . ?
N6 C29 1.350(12) . ?
N7 C49 1.269(13) . ?
N7 C50 1.420(12) . ?
N8 C49 1.330(12) . ?
N8 C56 1.432(13) . ?
N9 C62 1.304(12) . ?
N9 C63 1.427(11) . ?
N10 C62 1.313(12) . ?
N10 C69 1.418(12) . ?
C1 C16 1.387(12) . ?
C1 C17 1.355(12) . ?
C3 H3 0.9400 . ?
C3 C4 1.331(13) . ?
C4 H4 0.9400 . ?
C4 C5 1.336(13) . ?
C5 H5 0.9400 . ?
C7 C8 1.375(13) . ?
C7 C12 1.398(12) . ?
C8 H8 0.9400 . ?
C8 C9 1.394(13) . ?
C9 H9 0.9400 . ?
C9 C10 1.381(15) . ?
C10 C11 1.386(14) . ?
C10 C22 1.518(14) . ?
C11 H11 0.9400 . ?
C11 C12 1.370(12) . ?
C12 C13 1.481(13) . ?
C13 C14 1.357(12) . ?
C13 C17 1.418(12) . ?
C14 H14 0.9400 . ?
C14 C15 1.403(12) . ?
C15 C16 1.359(12) . ?
C15 C18 1.540(13) . ?
C16 H16 0.9400 . ?
C18 C19 1.524(14) . ?
C18 C20 1.542(14) . ?
C18 C21 1.527(14) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C21 H21C 0.9700 . ?
C22 C23 1.527(9) . ?
C22 C24 1.540(9) . ?
C22 C25 1.515(9) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C24 H24C 0.9700 . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C25 H25C 0.9700 . ?
C26 H26 0.9400 . ?
C26 C27 1.346(14) . ?
C27 H27 0.9400 . ?
C27 C28 1.394(13) . ?
C28 H28 0.9400 . ?
C35 C34 1.3900 . ?
C35 C30 1.3900 . ?
C35 C36 1.421(6) . ?
C34 H34 0.9400 . ?
C34 C33 1.3900 . ?
C33 C32 1.3900 . ?
C33 C45 1.561(13) . ?
C32 H32 0.9400 . ?
C32 C31 1.3900 . ?
C31 H31 0.9400 . ?
C31 C30 1.3900 . ?
C40 C36 1.3900 . ?
C40 C2 1.3900 . ?
C36 C37 1.3900 . ?
C37 H37 0.9400 . ?
C37 C38 1.3900 . ?
C38 C39 1.3900 . ?
C38 C41 1.506(12) . ?
C39 H39 0.9400 . ?
C39 C2 1.3900 . ?
C41 C42 1.500(19) . ?
C41 C43 1.545(19) . ?
C41 C44 1.58(2) . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C42 H42C 0.9700 . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C43 H43C 0.9700 . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C44 H44C 0.9700 . ?
C45 C46 1.513(9) . ?
C45 C47 1.38(2) . ?
C45 C48 1.74(3) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
C46 H46C 0.9700 . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C47 H47C 0.9700 . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C48 H48C 0.9700 . ?
C49 H49 0.9400 . ?
C50 C51 1.379(14) . ?
C50 C55 1.394(17) . ?
C51 H51 0.9400 . ?
C51 C52 1.412(15) . ?
C52 H52 0.9400 . ?
C52 C53 1.320(19) . ?
C53 H53 0.9400 . ?
C53 C54 1.38(2) . ?
C54 H54 0.9400 . ?
C54 C55 1.379(16) . ?
C55 H55 0.9400 . ?
C56 C57 1.373(15) . ?
C56 C61 1.392(15) . ?
C57 H57 0.9400 . ?
C57 C58 1.347(16) . ?
C58 H58 0.9400 . ?
C58 C59 1.34(2) . ?
C59 H59 0.9400 . ?
C59 C60 1.46(2) . ?
C60 H60 0.9400 . ?
C60 C61 1.373(17) . ?
C61 H61 0.9400 . ?
C62 H62 0.9400 . ?
C63 C64 1.384(13) . ?
C63 C68 1.397(13) . ?
C64 H64 0.9400 . ?
C64 C65 1.425(14) . ?
C65 H65 0.9400 . ?
C65 C66 1.353(17) . ?
C66 H66 0.9400 . ?
C66 C67 1.422(19) . ?
C67 H67 0.9400 . ?
C67 C68 1.344(15) . ?
C68 H68 0.9400 . ?
C69 C70 1.360(15) . ?
C69 C74 1.402(14) . ?
C70 H70 0.9400 . ?
C70 C71 1.386(16) . ?
C71 H71 0.9400 . ?
C71 C72 1.37(2) . ?
C72 H72 0.9400 . ?
C72 C73 1.39(2) . ?
C73 H73 0.9400 . ?
C73 C74 1.376(16) . ?
C74 H74 0.9400 . ?
C75 C80 1.3900 . ?
C75 C76 1.3900 . ?
C75 C81 1.524(19) . ?
C80 H80 0.9400 . ?
C80 C79 1.3900 . ?
C79 H79 0.9400 . ?
C79 C78 1.3900 . ?
C78 H78 0.9400 . ?
C78 C77 1.3900 . ?
C77 H77 0.9400 . ?
C77 C76 1.3900 . ?
C76 H76 0.9400 . ?
C81 H81A 0.9700 . ?
C81 H81B 0.9700 . ?
C81 H81C 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 Pt2 99.7(2) . . ?
N1 Pt1 N9 91.4(3) . . ?
N8 Pt1 Pt2 80.5(2) . . ?
N8 Pt1 N1 178.1(3) . . ?
N8 Pt1 N9 86.8(3) . . ?
N8 Pt1 C1 91.4(3) . . ?
N9 Pt1 Pt2 78.2(2) . . ?
C1 Pt1 Pt2 110.2(2) . . ?
C1 Pt1 N1 90.2(3) . . ?
C1 Pt1 N9 171.0(3) . . ?
N4 Pt2 Pt1 97.7(2) . . ?
N4 Pt2 N7 177.6(3) . . ?
N4 Pt2 N10 93.6(3) . . ?
N4 Pt2 C2 86.8(3) . . ?
N7 Pt2 Pt1 79.9(2) . . ?
N7 Pt2 N10 86.0(3) . . ?
N7 Pt2 C2 93.5(3) . . ?
N10 Pt2 Pt1 83.1(2) . . ?
C2 Pt2 Pt1 95.01(18) . . ?
C2 Pt2 N10 178.1(3) . . ?
C3 N1 Pt1 117.3(6) . . ?
C6 N1 Pt1 127.0(6) . . ?
C6 N1 C3 115.7(8) . . ?
C6 N2 C7 124.6(8) . . ?
C6 N2 C17 124.8(7) . . ?
C17 N2 C7 108.5(7) . . ?
C6 N3 C5 118.1(8) . . ?
C26 N4 Pt2 121.1(6) . . ?
C26 N4 C29 115.3(8) . . ?
C29 N4 Pt2 122.5(6) . . ?
C29 N5 C30 125.5(7) . . ?
C29 N5 C40 124.4(7) . . ?
C40 N5 C30 105.5(6) . . ?
C28 N6 C29 118.5(8) . . ?
C49 N7 Pt2 124.2(7) . . ?
C49 N7 C50 118.9(9) . . ?
C50 N7 Pt2 116.7(7) . . ?
C49 N8 Pt1 122.5(7) . . ?
C49 N8 C56 116.5(9) . . ?
C56 N8 Pt1 120.5(6) . . ?
C62 N9 Pt1 129.0(6) . . ?
C62 N9 C63 115.1(8) . . ?
C63 N9 Pt1 115.8(6) . . ?
C62 N10 Pt2 120.1(7) . . ?
C62 N10 C69 116.4(8) . . ?
C69 N10 Pt2 123.2(6) . . ?
C16 C1 Pt1 125.9(6) . . ?
C17 C1 Pt1 117.2(6) . . ?
C17 C1 C16 116.5(8) . . ?
N1 C3 H3 118.2 . . ?
C4 C3 N1 123.6(9) . . ?
C4 C3 H3 118.2 . . ?
C3 C4 H4 121.9 . . ?
C3 C4 C5 116.2(9) . . ?
C5 C4 H4 121.9 . . ?
N3 C5 H5 118.2 . . ?
C4 C5 N3 123.6(9) . . ?
C4 C5 H5 118.2 . . ?
N2 C6 N1 120.0(8) . . ?
N3 C6 N1 122.5(8) . . ?
N3 C6 N2 117.5(8) . . ?
C8 C7 N2 131.3(9) . . ?
C8 C7 C12 120.2(8) . . ?
C12 C7 N2 107.9(8) . . ?
C7 C8 H8 120.8 . . ?
C7 C8 C9 118.4(9) . . ?
C9 C8 H8 120.8 . . ?
C8 C9 H9 118.7 . . ?
C10 C9 C8 122.6(9) . . ?
C10 C9 H9 118.7 . . ?
C9 C10 C11 117.2(9) . . ?
C9 C10 C22 118.9(9) . . ?
C11 C10 C22 123.8(10) . . ?
C10 C11 H11 119.1 . . ?
C12 C11 C10 121.9(9) . . ?
C12 C11 H11 119.1 . . ?
C7 C12 C13 108.4(8) . . ?
C11 C12 C7 119.5(9) . . ?
C11 C12 C13 132.1(9) . . ?
C14 C13 C12 131.4(8) . . ?
C14 C13 C17 123.1(8) . . ?
C17 C13 C12 105.2(8) . . ?
C13 C14 H14 121.2 . . ?
C13 C14 C15 117.7(8) . . ?
C15 C14 H14 121.2 . . ?
C14 C15 C18 117.0(8) . . ?
C16 C15 C14 117.8(8) . . ?
C16 C15 C18 124.9(8) . . ?
C1 C16 H16 117.3 . . ?
C15 C16 C1 125.4(8) . . ?
C15 C16 H16 117.3 . . ?
N2 C17 C13 109.9(8) . . ?
C1 C17 N2 130.9(8) . . ?
C1 C17 C13 119.1(8) . . ?
C15 C18 C20 110.2(9) . . ?
C19 C18 C15 112.6(8) . . ?
C19 C18 C20 106.0(9) . . ?
C19 C18 C21 110.8(9) . . ?
C21 C18 C15 107.6(8) . . ?
C21 C18 C20 109.5(9) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C10 C22 C23 109.9(11) . . ?
C10 C22 C24 110.3(11) . . ?
C23 C22 C24 104.7(8) . . ?
C25 C22 C10 112.7(9) . . ?
C25 C22 C23 104.6(15) . . ?
C25 C22 C24 114.1(15) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N4 C26 H26 118.1 . . ?
C27 C26 N4 123.8(9) . . ?
C27 C26 H26 118.1 . . ?
C26 C27 H27 122.2 . . ?
C26 C27 C28 115.5(9) . . ?
C28 C27 H27 122.2 . . ?
N6 C28 C27 123.6(10) . . ?
N6 C28 H28 118.2 . . ?
C27 C28 H28 118.2 . . ?
N5 C29 N4 118.0(8) . . ?
N6 C29 N4 122.4(9) . . ?
N6 C29 N5 119.5(8) . . ?
C34 C35 C30 120.0 . . ?
C34 C35 C36 130.7(5) . . ?
C30 C35 C36 109.3(5) . . ?
C35 C34 H34 120.0 . . ?
C35 C34 C33 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C33 C45 122.4(10) . . ?
C32 C33 C34 120.0 . . ?
C32 C33 C45 117.6(10) . . ?
C33 C32 H32 120.0 . . ?
C33 C32 C31 120.0 . . ?
C31 C32 H32 120.0 . . ?
C32 C31 H31 120.0 . . ?
C30 C31 C32 120.0 . . ?
C30 C31 H31 120.0 . . ?
C35 C30 N5 108.5(5) . . ?
C31 C30 N5 131.5(5) . . ?
C31 C30 C35 120.0 . . ?
C36 C40 N5 111.8(5) . . ?
C36 C40 C2 120.0 . . ?
C2 C40 N5 128.1(5) . . ?
C40 C36 C35 103.8(4) . . ?
C37 C36 C35 135.7(5) . . ?
C37 C36 C40 120.0 . . ?
C36 C37 H37 120.0 . . ?
C36 C37 C38 120.0 . . ?
C38 C37 H37 120.0 . . ?
C37 C38 C41 121.0(6) . . ?
C39 C38 C37 120.0 . . ?
C39 C38 C41 118.5(6) . . ?
C38 C39 H39 120.0 . . ?
C2 C39 C38 120.0 . . ?
C2 C39 H39 120.0 . . ?
C40 C2 Pt2 113.7(3) . . ?
C39 C2 Pt2 125.5(3) . . ?
C39 C2 C40 120.0 . . ?
C38 C41 C43 108.5(9) . . ?
C38 C41 C44 110.8(9) . . ?
C42 C41 C38 116.2(11) . . ?
C42 C41 C43 104.8(12) . . ?
C42 C41 C44 109.9(14) . . ?
C43 C41 C44 106.0(12) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C33 C45 C48 108.3(14) . . ?
C46 C45 C33 106.9(10) . . ?
C46 C45 C48 97.2(12) . . ?
C47 C45 C33 110.5(11) . . ?
C47 C45 C46 131.1(19) . . ?
C47 C45 C48 99.6(16) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C45 C48 H48A 109.5 . . ?
C45 C48 H48B 109.5 . . ?
C45 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
N7 C49 N8 128.5(10) . . ?
N7 C49 H49 115.8 . . ?
N8 C49 H49 115.8 . . ?
C51 C50 N7 122.9(10) . . ?
C51 C50 C55 118.3(10) . . ?
C55 C50 N7 118.8(10) . . ?
C50 C51 H51 119.5 . . ?
C50 C51 C52 121.0(11) . . ?
C52 C51 H51 119.5 . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.5(13) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 H53 120.1 . . ?
C52 C53 C54 119.9(13) . . ?
C54 C53 H53 120.1 . . ?
C53 C54 H54 119.2 . . ?
C55 C54 C53 121.6(14) . . ?
C55 C54 H54 119.2 . . ?
C50 C55 H55 120.6 . . ?
C54 C55 C50 118.9(12) . . ?
C54 C55 H55 120.6 . . ?
C57 C56 N8 121.6(10) . . ?
C57 C56 C61 116.7(10) . . ?
C61 C56 N8 121.7(9) . . ?
C56 C57 H57 116.6 . . ?
C58 C57 C56 126.8(13) . . ?
C58 C57 H57 116.6 . . ?
C57 C58 H58 122.3 . . ?
C59 C58 C57 115.3(14) . . ?
C59 C58 H58 122.3 . . ?
C58 C59 H59 118.3 . . ?
C58 C59 C60 123.5(13) . . ?
C60 C59 H59 118.3 . . ?
C59 C60 H60 121.9 . . ?
C61 C60 C59 116.1(12) . . ?
C61 C60 H60 121.9 . . ?
C56 C61 H61 119.2 . . ?
C60 C61 C56 121.5(11) . . ?
C60 C61 H61 119.2 . . ?
N9 C62 N10 125.3(9) . . ?
N9 C62 H62 117.3 . . ?
N10 C62 H62 117.3 . . ?
C64 C63 N9 120.3(9) . . ?
C64 C63 C68 118.8(9) . . ?
C68 C63 N9 120.9(9) . . ?
C63 C64 H64 120.3 . . ?
C63 C64 C65 119.4(10) . . ?
C65 C64 H64 120.3 . . ?
C64 C65 H65 119.2 . . ?
C66 C65 C64 121.5(12) . . ?
C66 C65 H65 119.2 . . ?
C65 C66 H66 121.5 . . ?
C65 C66 C67 117.0(10) . . ?
C67 C66 H66 121.5 . . ?
C66 C67 H67 118.7 . . ?
C68 C67 C66 122.6(12) . . ?
C68 C67 H67 118.7 . . ?
C63 C68 H68 119.8 . . ?
C67 C68 C63 120.3(12) . . ?
C67 C68 H68 119.8 . . ?
C70 C69 N10 120.9(9) . . ?
C70 C69 C74 117.9(10) . . ?
C74 C69 N10 121.2(9) . . ?
C69 C70 H70 119.4 . . ?
C69 C70 C71 121.1(12) . . ?
C71 C70 H70 119.4 . . ?
C70 C71 H71 119.3 . . ?
C72 C71 C70 121.3(14) . . ?
C72 C71 H71 119.3 . . ?
C71 C72 H72 120.9 . . ?
C71 C72 C73 118.1(13) . . ?
C73 C72 H72 120.9 . . ?
C72 C73 H73 119.9 . . ?
C74 C73 C72 120.2(13) . . ?
C74 C73 H73 119.9 . . ?
C69 C74 H74 119.4 . . ?
C73 C74 C69 121.2(12) . . ?
C73 C74 H74 119.4 . . ?
C80 C75 C76 120.0 . . ?
C80 C75 C81 122.1(10) . . ?
C76 C75 C81 117.8(10) . . ?
C75 C80 H80 120.0 . . ?
C75 C80 C79 120.0 . . ?
C79 C80 H80 120.0 . . ?
C80 C79 H79 120.0 . . ?
C80 C79 C78 120.0 . . ?
C78 C79 H79 120.0 . . ?
C79 C78 H78 120.0 . . ?
C79 C78 C77 120.0 . . ?
C77 C78 H78 120.0 . . ?
C78 C77 H77 120.0 . . ?
C76 C77 C78 120.0 . . ?
C76 C77 H77 120.0 . . ?
C75 C76 H76 120.0 . . ?
C77 C76 C75 120.0 . . ?
C77 C76 H76 120.0 . . ?
C75 C81 H81A 109.5 . . ?
C75 C81 H81B 109.5 . . ?
C75 C81 H81C 109.5 . . ?
H81A C81 H81B 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N1 C3 C4 173.7(7) . . . . ?
Pt1 N1 C6 N2 6.9(12) . . . . ?
Pt1 N1 C6 N3 -172.6(6) . . . . ?
Pt1 N8 C49 N7 15.4(15) . . . . ?
Pt1 N8 C56 C57 28.0(13) . . . . ?
Pt1 N8 C56 C61 -148.1(8) . . . . ?
Pt1 N9 C62 N10 0.0(16) . . . . ?
Pt1 N9 C63 C64 45.7(11) . . . . ?
Pt1 N9 C63 C68 -132.0(8) . . . . ?
Pt1 C1 C16 C15 -167.8(7) . . . . ?
Pt1 C1 C17 N2 -7.8(12) . . . . ?
Pt1 C1 C17 C13 167.5(6) . . . . ?
Pt2 N4 C26 C27 164.9(8) . . . . ?
Pt2 N4 C29 N5 22.8(10) . . . . ?
Pt2 N4 C29 N6 -159.3(6) . . . . ?
Pt2 N7 C49 N8 6.3(16) . . . . ?
Pt2 N7 C50 C51 41.8(15) . . . . ?
Pt2 N7 C50 C55 -139.0(12) . . . . ?
Pt2 N10 C62 N9 19.0(14) . . . . ?
Pt2 N10 C69 C70 -143.5(9) . . . . ?
Pt2 N10 C69 C74 34.6(13) . . . . ?
N1 C3 C4 C5 2.6(14) . . . . ?
N2 C7 C8 C9 174.3(9) . . . . ?
N2 C7 C12 C11 -177.1(8) . . . . ?
N2 C7 C12 C13 2.9(10) . . . . ?
N4 C26 C27 C28 -4.2(15) . . . . ?
N5 C40 C36 C35 11.1(6) . . . . ?
N5 C40 C36 C37 -176.1(6) . . . . ?
N5 C40 C2 Pt2 -14.3(6) . . . . ?
N5 C40 C2 C39 175.4(7) . . . . ?
N7 C50 C51 C52 178.5(11) . . . . ?
N7 C50 C55 C54 -179.9(15) . . . . ?
N8 C56 C57 C58 -178.2(11) . . . . ?
N8 C56 C61 C60 178.0(10) . . . . ?
N9 C63 C64 C65 176.2(10) . . . . ?
N9 C63 C68 C67 -177.8(10) . . . . ?
N10 C69 C70 C71 -178.2(10) . . . . ?
N10 C69 C74 C73 180.0(10) . . . . ?
C3 N1 C6 N2 -173.7(8) . . . . ?
C3 N1 C6 N3 6.8(12) . . . . ?
C3 C4 C5 N3 -0.2(15) . . . . ?
C5 N3 C6 N1 -4.8(13) . . . . ?
C5 N3 C6 N2 175.7(8) . . . . ?
C6 N1 C3 C4 -5.7(12) . . . . ?
C6 N2 C7 C8 25.2(15) . . . . ?
C6 N2 C7 C12 -164.4(8) . . . . ?
C6 N2 C17 C1 -22.6(14) . . . . ?
C6 N2 C17 C13 161.8(8) . . . . ?
C6 N3 C5 C4 1.3(15) . . . . ?
C7 N2 C6 N1 -176.6(7) . . . . ?
C7 N2 C6 N3 2.9(13) . . . . ?
C7 N2 C17 C1 173.8(8) . . . . ?
C7 N2 C17 C13 -1.8(9) . . . . ?
C7 C8 C9 C10 -1.4(17) . . . . ?
C7 C12 C13 C14 -178.8(9) . . . . ?
C7 C12 C13 C17 -3.9(10) . . . . ?
C8 C7 C12 C11 -5.4(14) . . . . ?
C8 C7 C12 C13 174.6(8) . . . . ?
C8 C9 C10 C11 -1.7(18) . . . . ?
C8 C9 C10 C22 -179.1(11) . . . . ?
C9 C10 C11 C12 1.3(17) . . . . ?
C9 C10 C22 C23 -58.6(16) . . . . ?
C9 C10 C22 C24 56.3(17) . . . . ?
C9 C10 C22 C25 -174.8(15) . . . . ?
C10 C11 C12 C7 2.2(15) . . . . ?
C10 C11 C12 C13 -177.7(10) . . . . ?
C11 C10 C22 C23 124.3(13) . . . . ?
C11 C10 C22 C24 -120.8(14) . . . . ?
C11 C10 C22 C25 8(2) . . . . ?
C11 C12 C13 C14 1.1(17) . . . . ?
C11 C12 C13 C17 176.0(10) . . . . ?
C12 C7 C8 C9 4.9(15) . . . . ?
C12 C13 C14 C15 176.3(9) . . . . ?
C12 C13 C17 N2 3.5(9) . . . . ?
C12 C13 C17 C1 -172.7(7) . . . . ?
C13 C14 C15 C16 -3.3(13) . . . . ?
C13 C14 C15 C18 -177.7(8) . . . . ?
C14 C13 C17 N2 178.9(8) . . . . ?
C14 C13 C17 C1 2.7(13) . . . . ?
C14 C15 C16 C1 -0.3(14) . . . . ?
C14 C15 C18 C19 -176.2(9) . . . . ?
C14 C15 C18 C20 -58.0(12) . . . . ?
C14 C15 C18 C21 61.4(11) . . . . ?
C16 C1 C17 N2 178.7(8) . . . . ?
C16 C1 C17 C13 -6.0(12) . . . . ?
C16 C15 C18 C19 9.9(15) . . . . ?
C16 C15 C18 C20 128.0(11) . . . . ?
C16 C15 C18 C21 -112.6(11) . . . . ?
C17 N2 C6 N1 22.4(13) . . . . ?
C17 N2 C6 N3 -158.1(8) . . . . ?
C17 N2 C7 C8 -171.1(10) . . . . ?
C17 N2 C7 C12 -0.8(9) . . . . ?
C17 C1 C16 C15 5.1(14) . . . . ?
C17 C13 C14 C15 2.2(13) . . . . ?
C18 C15 C16 C1 173.7(9) . . . . ?
C22 C10 C11 C12 178.5(11) . . . . ?
C26 N4 C29 N5 -169.0(8) . . . . ?
C26 N4 C29 N6 8.9(12) . . . . ?
C26 C27 C28 N6 7.5(15) . . . . ?
C28 N6 C29 N4 -6.1(13) . . . . ?
C28 N6 C29 N5 171.8(8) . . . . ?
C29 N4 C26 C27 -3.5(14) . . . . ?
C29 N5 C30 C35 -151.1(7) . . . . ?
C29 N5 C30 C31 32.2(11) . . . . ?
C29 N5 C40 C36 146.3(7) . . . . ?
C29 N5 C40 C2 -29.4(10) . . . . ?
C29 N6 C28 C27 -2.6(14) . . . . ?
C35 C34 C33 C32 0.0 . . . . ?
C35 C34 C33 C45 -179.4(8) . . . . ?
C35 C36 C37 C38 170.0(7) . . . . ?
C34 C35 C30 N5 -177.1(6) . . . . ?
C34 C35 C30 C31 0.0 . . . . ?
C34 C35 C36 C40 170.8(4) . . . . ?
C34 C35 C36 C37 -0.3(9) . . . . ?
C34 C33 C32 C31 0.0 . . . . ?
C34 C33 C45 C46 -69.6(17) . . . . ?
C34 C33 C45 C47 78.4(19) . . . . ?
C34 C33 C45 C48 -173.5(8) . . . . ?
C33 C32 C31 C30 0.0 . . . . ?
C32 C33 C45 C46 111.0(15) . . . . ?
C32 C33 C45 C47 -101(2) . . . . ?
C32 C33 C45 C48 7.2(12) . . . . ?
C32 C31 C30 N5 176.4(7) . . . . ?
C32 C31 C30 C35 0.0 . . . . ?
C30 N5 C29 N4 176.9(7) . . . . ?
C30 N5 C29 N6 -1.0(12) . . . . ?
C30 N5 C40 C36 -10.6(7) . . . . ?
C30 N5 C40 C2 173.7(5) . . . . ?
C30 C35 C34 C33 0.0 . . . . ?
C30 C35 C36 C40 -7.3(4) . . . . ?
C30 C35 C36 C37 -178.4(5) . . . . ?
C40 N5 C29 N4 24.6(11) . . . . ?
C40 N5 C29 N6 -153.4(7) . . . . ?
C40 N5 C30 C35 5.5(6) . . . . ?
C40 N5 C30 C31 -171.2(5) . . . . ?
C40 C36 C37 C38 0.0 . . . . ?
C36 C35 C34 C33 -177.9(7) . . . . ?
C36 C35 C30 N5 1.2(5) . . . . ?
C36 C35 C30 C31 178.3(5) . . . . ?
C36 C40 C2 Pt2 170.3(4) . . . . ?
C36 C40 C2 C39 0.0 . . . . ?
C36 C37 C38 C39 0.0 . . . . ?
C36 C37 C38 C41 171.2(8) . . . . ?
C37 C38 C39 C2 0.0 . . . . ?
C37 C38 C41 C42 14.0(16) . . . . ?
C37 C38 C41 C43 131.7(9) . . . . ?
C37 C38 C41 C44 -112.3(11) . . . . ?
C38 C39 C2 Pt2 -169.1(5) . . . . ?
C38 C39 C2 C40 0.0 . . . . ?
C39 C38 C41 C42 -174.7(12) . . . . ?
C39 C38 C41 C43 -57.0(11) . . . . ?
C39 C38 C41 C44 59.0(13) . . . . ?
C2 C40 C36 C35 -172.8(5) . . . . ?
C2 C40 C36 C37 0.0 . . . . ?
C41 C38 C39 C2 -171.4(8) . . . . ?
C45 C33 C32 C31 179.4(8) . . . . ?
C49 N7 C50 C51 -142.6(12) . . . . ?
C49 N7 C50 C55 36.6(18) . . . . ?
C49 N8 C56 C57 -144.5(10) . . . . ?
C49 N8 C56 C61 39.4(13) . . . . ?
C50 N7 C49 N8 -169.0(11) . . . . ?
C50 C51 C52 C53 6(2) . . . . ?
C51 C50 C55 C54 -1(3) . . . . ?
C51 C52 C53 C54 -10(3) . . . . ?
C52 C53 C54 C55 9(3) . . . . ?
C53 C54 C55 C50 -3(3) . . . . ?
C55 C50 C51 C52 -1(2) . . . . ?
C56 N8 C49 N7 -172.3(10) . . . . ?
C56 C57 C58 C59 2(2) . . . . ?
C57 C56 C61 C60 1.7(16) . . . . ?
C57 C58 C59 C60 -3(2) . . . . ?
C58 C59 C60 C61 3(2) . . . . ?
C59 C60 C61 C56 -2.1(19) . . . . ?
C61 C56 C57 C58 -1.9(18) . . . . ?
C62 N9 C63 C64 -136.9(10) . . . . ?
C62 N9 C63 C68 45.4(13) . . . . ?
C62 N10 C69 C70 43.7(13) . . . . ?
C62 N10 C69 C74 -138.3(10) . . . . ?
C63 N9 C62 N10 -176.9(10) . . . . ?
C63 C64 C65 C66 5.8(18) . . . . ?
C64 C63 C68 C67 4.5(16) . . . . ?
C64 C65 C66 C67 -3.7(19) . . . . ?
C65 C66 C67 C68 2.0(19) . . . . ?
C66 C67 C68 C63 -2.5(18) . . . . ?
C68 C63 C64 C65 -6.1(16) . . . . ?
C69 N10 C62 N9 -167.9(10) . . . . ?
C69 C70 C71 C72 -2.3(19) . . . . ?
C70 C69 C74 C73 -1.9(16) . . . . ?
C70 C71 C72 C73 -1(2) . . . . ?
C71 C72 C73 C74 3(2) . . . . ?
C72 C73 C74 C69 -1.2(19) . . . . ?
C74 C69 C70 C71 3.7(16) . . . . ?
C75 C80 C79 C78 0.0 . . . . ?
C80 C75 C76 C77 0.0 . . . . ?
C80 C79 C78 C77 0.0 . . . . ?
C79 C78 C77 C76 0.0 . . . . ?
C78 C77 C76 C75 0.0 . . . . ?
C76 C75 C80 C79 0.0 . . . . ?
C81 C75 C80 C79 176.3(12) . . . . ?
C81 C75 C76 C77 -176.4(12) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 288 electrons were 
found in a volume of 1883Å³ in 1 void per unit cell. 
This is consistent with the presence of 
3[C7H8] per Formula Unit 
which account for 300 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.084 -0.054 -0.052 1883.2 288.3 '6 C7H8'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_platon_squeeze_special_details  
;
A solvent mask was calculated and 334 electrons were 
found in a volume of 1994Å³ in 1 void per unit cell. 
This is consistent with the presence of 
1[C7H8] per Formula Unit 
which account for 100 electrons 
per unit cell.
;
_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT971_221212yhb           
;
PROBLEM: Check Calcd Resid. Dens.  2.41Ang From C37             5.80 eA-3  
RESPONSE: Inadequate absorption correction of Pt which strongly absorbs X-rays
;
_vrf_PLAT972_221212yhb           
;
PROBLEM: Check Calcd Resid. Dens.  0.91Ang From Pt1            -3.29 eA-3  
RESPONSE: Inadequate absorption correction of Pt which strongly absorbs X-rays
;
_vrf_PLAT973_221212yhb           
;
PROBLEM: Check Calcd Positive Resid. Density on       Pt1       4.36 eA-3  
RESPONSE: Inadequate absorption correction of Pt which strongly absorbs X-rays
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1012-hb492-100k_autored
_database_code_depnum_ccdc_archive 'CCDC 2285564'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2023-07-31 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2023-07-11
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2019/2
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H90 N10 Pt2, 2(C H2 Cl2)'
_chemical_formula_sum            'C72 H94 Cl4 N10 Pt2'
_chemical_formula_weight         1631.55
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.0515(3)
_cell_length_b                   15.3733(3)
_cell_length_c                   18.5567(4)
_cell_angle_alpha                104.639(2)
_cell_angle_beta                 104.890(2)
_cell_angle_gamma                101.452(2)
_cell_volume                     3596.32(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    28168
_cell_measurement_temperature    99.99(10)
_cell_measurement_theta_max      29.4960
_cell_measurement_theta_min      1.5430
_shelx_estimated_absorpt_T_max   0.496
_shelx_estimated_absorpt_T_min   0.467
_exptl_absorpt_coefficient_mu    4.082
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.48724
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.123a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.507
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1640
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0475
_diffrn_reflns_av_unetI/netI     0.0614
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.824
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            46510
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.824
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.279
_diffrn_reflns_theta_min         1.541
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.99(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.824
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     37.00  63.00   0.50    0.17    --   10.52-113.00 128.00   52
  2  ω      2.00  53.00   0.50    0.17    --   10.52 -99.00  60.00  102
  3  ω      3.00  29.00   0.50    0.17    --   10.52 -99.00 -30.00   52
  4  ω    -20.00  33.00   0.50    0.17    --   10.52 -37.00-120.00  106
  5  ω    -66.00 -33.00   0.50    0.17    --   10.52 -37.00-120.00   66
  6  ω    -29.00  44.00   0.50    0.17    --  -11.30  19.00-150.00  146
  7  ω    -64.00 -34.00   0.50    0.17    --  -11.30 113.00-139.00   60
  8  ω    -24.00  64.00   0.50    0.17    --  -11.30  57.00-150.00  176
  9  ω     -9.00  33.00   0.50    0.17    --  -11.30 -99.00   0.00   84
 10  ω    -42.00  70.00   0.50    0.17    --  -11.30  37.00 120.00  224
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'ROD, Synergy Custom DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0218516000
_diffrn_orient_matrix_UB_12      -0.0251332000
_diffrn_orient_matrix_UB_13      -0.0408357000
_diffrn_orient_matrix_UB_21      -0.0493803000
_diffrn_orient_matrix_UB_22      -0.0101425000
_diffrn_orient_matrix_UB_23      0.0042270000
_diffrn_orient_matrix_UB_31      -0.0069033000
_diffrn_orient_matrix_UB_32      0.0416607000
_diffrn_orient_matrix_UB_33      -0.0076311000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12193
_reflns_number_total             16192
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/2 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.630
_refine_diff_density_min         -1.795
_refine_diff_density_rms         0.151
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1063
_refine_ls_number_reflns         16192
_refine_ls_number_restraints     936
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0409
_refine_ls_restrained_S_all      1.085
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0523P)²+1.2867P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0985
_refine_ls_wR_factor_ref         0.1064
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 C21-C13 = C21A-C13
 1.5 with sigma of 0.01
 Cl4-C72 = Cl4A-C72A = Cl3A-C72A = Cl3-C72
 1.79 with sigma of 0.01
 C24A-C21A = C23-C21 = C22A-C21A = C24-C21 = C23A-C21A = C22-C21
 1.54 with sigma of 0.01
 C67A-C62 = C67-C62
 1.5 with sigma of 0.01
 C69-C67 = C68A-C67A = C70-C67 = C69A-C67A = C68-C67 = C70A-C67A
 1.54 with sigma of 0.01
 C46A-C45A = C48-C45 = C47-C45 = C48A-C45A = C46-C45 = C47A-C45A
 1.54 with sigma of 0.01
 C45-C37 = C45A-C37
 1.5 with sigma of 0.01
 C56-C51 = C56A-C51
 1.5 with sigma of 0.01
 C58A-C56A = C58-C56 = C57A-C56A = C57-C56 = C59A-C56A = C59-C56
 1.54 with sigma of 0.01
 Cl2-C71 = C71-Cl1 = Cl2A-C71A = C71A-Cl1A
 1.79 with sigma of 0.01
 C43-C41 = C42A-C41 = C44-C41 = C44A-C41 = C43A-C41 = C42-C41
 1.54 with sigma of 0.01
 Cl4A-Cl3A = Cl4-Cl3
 2.924 with sigma of 0.02
 Cl2-Cl1 = Cl2A-Cl1A
 2.924 with sigma of 0.02
2. Uiso/Uaniso restraints and constraints
C72 \\sim Cl3 \\sim Cl4 \\sim C72A \\sim Cl3A \\sim Cl4A: within 2A with sigma
of 0.01 and sigma for terminal atoms of 0.02 within 2A
C21 \\sim C21A \\sim C22A \\sim C22 \\sim C24A \\sim C23 \\sim C23A \\sim C24:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C67 \\sim C68 \\sim C69 \\sim C70 \\sim C67A \\sim C70A \\sim C69A \\sim C68A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C45 \\sim C46 \\sim C47 \\sim C48 \\sim C48A \\sim C45A \\sim C46A \\sim C47A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C56 \\sim C57 \\sim C58 \\sim C59 \\sim C56A \\sim C58A \\sim C57A \\sim C59A:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
Cl1 \\sim Cl2 \\sim C71 \\sim Cl1A \\sim C71A \\sim Cl2A: within 2A with sigma
of 0.01 and sigma for terminal atoms of 0.02 within 2A
C43A \\sim C44A \\sim C44 \\sim C42A \\sim C42 \\sim C43: within 2A with sigma
of 0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(C67) \\sim Ueq, Uanis(C68) \\sim Ueq, Uanis(C69) \\sim Ueq, Uanis(C70)
\\sim Ueq, Uanis(C67A) \\sim Ueq, Uanis(C70A) \\sim Ueq, Uanis(C69A) \\sim Ueq,
Uanis(C68A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C45) \\sim Ueq, Uanis(C46) \\sim Ueq, Uanis(C47) \\sim Ueq, Uanis(C48)
\\sim Ueq, Uanis(C48A) \\sim Ueq, Uanis(C45A) \\sim Ueq, Uanis(C46A) \\sim Ueq,
Uanis(C47A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3. Rigid body (RIGU) restrains
 C21A, C22A, C23A, C24A, C13
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C21, C23, C24, C22, C13
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C72A, Cl3A, Cl4A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C62, C67, C70, C69, C68
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C68A, C67A, C69A, C70A, C62
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C37, C45, C46, C47, C48
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C37, C45A, C47A, C48A, C46A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C56A, C58A, C57A, C59A, C51
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C51, C56, C58, C59, C57
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 Cl1A, C71A, Cl2A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 Cl1, C71, Cl2
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C43A, C41, C44A, C42A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C72, Cl3, Cl4
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Others
 Sof(C21A)=Sof(C24A)=Sof(H24D)=Sof(H24E)=Sof(H24F)=Sof(C22A)=Sof(H22D)=
 Sof(H22E)=Sof(H22F)=Sof(C23A)=Sof(H23D)=Sof(H23E)=Sof(H23F)=1-FVAR(1)
 Sof(C21)=Sof(C22)=Sof(H22A)=Sof(H22B)=Sof(H22C)=Sof(C23)=Sof(H23A)=Sof(H23B)=
 Sof(H23C)=Sof(C24)=Sof(H24A)=Sof(H24B)=Sof(H24C)=FVAR(1)
 Sof(C67A)=Sof(C70A)=Sof(H70D)=Sof(H70E)=Sof(H70F)=Sof(C69A)=Sof(H69D)=
 Sof(H69E)=Sof(H69F)=Sof(C68A)=Sof(H68D)=Sof(H68E)=Sof(H68F)=1-FVAR(2)
 Sof(C67)=Sof(C68)=Sof(H68A)=Sof(H68B)=Sof(H68C)=Sof(C69)=Sof(H69A)=Sof(H69B)=
 Sof(H69C)=Sof(C70)=Sof(H70A)=Sof(H70B)=Sof(H70C)=FVAR(2)
 Sof(C48A)=Sof(H48D)=Sof(H48E)=Sof(H48F)=Sof(C45A)=Sof(C46A)=Sof(H46D)=
 Sof(H46E)=Sof(H46F)=Sof(C47A)=Sof(H47D)=Sof(H47E)=Sof(H47F)=1-FVAR(3)
 Sof(C45)=Sof(C46)=Sof(H46A)=Sof(H46B)=Sof(H46C)=Sof(C47)=Sof(H47A)=Sof(H47B)=
 Sof(H47C)=Sof(C48)=Sof(H48A)=Sof(H48B)=Sof(H48C)=FVAR(3)
 Sof(C56A)=Sof(C58A)=Sof(H58D)=Sof(H58E)=Sof(H58F)=Sof(C57A)=Sof(H57D)=
 Sof(H57E)=Sof(H57F)=Sof(C59A)=Sof(H59D)=Sof(H59E)=Sof(H59F)=1-FVAR(4)
 Sof(C56)=Sof(C57)=Sof(H57A)=Sof(H57B)=Sof(H57C)=Sof(C58)=Sof(H58A)=Sof(H58B)=
 Sof(H58C)=Sof(C59)=Sof(H59A)=Sof(H59B)=Sof(H59C)=FVAR(4)
 Sof(Cl1A)=Sof(C71A)=Sof(H71C)=Sof(H71D)=Sof(Cl2A)=1-FVAR(5)
 Sof(Cl1)=Sof(Cl2)=Sof(C71)=Sof(H71A)=Sof(H71B)=FVAR(5)
 Sof(C44A)=Sof(H44D)=Sof(H44E)=Sof(H44F)=Sof(C43A)=Sof(H43D)=Sof(H43E)=
 Sof(H43F)=Sof(C42A)=Sof(H42D)=Sof(H42E)=Sof(H42F)=1-FVAR(6)
 Sof(C42)=Sof(H42A)=Sof(H42B)=Sof(H42C)=Sof(C43)=Sof(H43A)=Sof(H43B)=Sof(H43C)=
 Sof(C44)=Sof(H44A)=Sof(H44B)=Sof(H44C)=FVAR(6)
 Sof(C72A)=Sof(H72C)=Sof(H72D)=Sof(Cl3A)=Sof(Cl4A)=1-FVAR(7)
 Sof(Cl3)=Sof(Cl4)=Sof(C72)=Sof(H72A)=Sof(H72B)=FVAR(7)
 Fixed Z: Cl3A(0.41798)
5.a Secondary CH2 refined with riding coordinates:
 C71(H71A,H71B), C72(H72A,H72B), C71A(H71C,H71D), C72A(H72C,H72D)
5.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C7(H7), C9(H9), C12(H12), C14(H14), C15(H15),
 C25(H25), C26(H26), C27(H27), C31(H31), C33(H33), C36(H36), C38(H38), C39(H39),
  C50(H50), C61(H61)
5.c Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C22(H22A,H22B,
 H22C), C23(H23A,H23B,H23C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C44(H44A,
 H44B,H44C), C46(H46A,H46B,H46C), C47(H47A,H47B,H47C), C48(H48A,H48B,H48C),
 C53(H53A,H53B,H53C), C54(H54A,H54B,H54C), C55(H55A,H55B,H55C), C57(H57A,H57B,
 H57C), C58(H58A,H58B,H58C), C59(H59A,H59B,H59C), C64(H64A,H64B,H64C), C65(H65A,
 H65B,H65C), C66(H66A,H66B,H66C), C68(H68A,H68B,H68C), C69(H69A,H69B,H69C),
 C70(H70A,H70B,H70C), C24(H24A,H24B,H24C), C24A(H24D,H24E,H24F), C22A(H22D,H22E,
 H22F), C23A(H23D,H23E,H23F), C70A(H70D,H70E,H70F), C69A(H69D,H69E,H69F),
 C68A(H68D,H68E,H68F), C48A(H48D,H48E,H48F), C46A(H46D,H46E,H46F), C47A(H47D,
 H47E,H47F), C58A(H58D,H58E,H58F), C57A(H57D,H57E,H57F), C59A(H59D,H59E,H59F),
 C44A(H44D,H44E,H44F), C43A(H43D,H43E,H43F), C42A(H42D,H42E,H42F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.57722(2) 0.74822(2) 0.76667(2) 0.02018(6) Uani 1 1 d . . . . .
Pt2 Pt 0.54552(2) 0.79028(2) 0.61260(2) 0.02462(6) Uani 1 1 d . . . . .
N1 N 0.4830(3) 0.6315(3) 0.7706(2) 0.0255(9) Uani 1 1 d . . . . .
N2 N 0.4479(4) 0.5301(3) 0.8454(3) 0.0308(10) Uani 1 1 d . . . . .
N3 N 0.6161(3) 0.5951(3) 0.8548(2) 0.0234(9) Uani 1 1 d . . . . .
N4 N 0.4827(3) 0.6694(3) 0.5215(2) 0.0323(10) Uani 1 1 d . . . . .
N5 N 0.4413(4) 0.5751(3) 0.3885(3) 0.0495(14) Uani 1 1 d . . . . .
N6 N 0.5581(4) 0.7213(3) 0.4357(2) 0.0315(10) Uani 1 1 d . . . . .
N7 N 0.6626(3) 0.8743(3) 0.7736(2) 0.0237(9) Uani 1 1 d . . . . .
N8 N 0.6186(3) 0.9013(3) 0.7101(2) 0.0235(9) Uani 1 1 d . . . . .
N9 N 0.4483(3) 0.7987(3) 0.7343(2) 0.0258(9) Uani 1 1 d . . . . .
N10 N 0.4158(4) 0.7819(3) 0.6539(2) 0.0306(10) Uani 1 1 d . . . . .
C1 C 0.3814(4) 0.6070(3) 0.7320(3) 0.0302(12) Uani 1 1 d . . . . .
H1 H 0.357725 0.633519 0.692186 0.036 Uiso 1 1 calc R U . . .
C2 C 0.3109(4) 0.5457(4) 0.7475(3) 0.0376(13) Uani 1 1 d . . . . .
H2 H 0.239779 0.527191 0.718473 0.045 Uiso 1 1 calc R U . . .
C3 C 0.3496(5) 0.5122(4) 0.8086(4) 0.0393(14) Uani 1 1 d . . . . .
H3 H 0.302333 0.474315 0.824570 0.047 Uiso 1 1 calc R U . . .
C4 C 0.5142(4) 0.5863(3) 0.8237(3) 0.0250(11) Uani 1 1 d . . . . .
C5 C 0.6897(4) 0.6236(3) 0.8191(3) 0.0231(10) Uani 1 1 d . . . . .
C6 C 0.6906(4) 0.6888(3) 0.7798(3) 0.0236(10) Uani 1 1 d . . . . .
C7 C 0.7708(4) 0.7008(3) 0.7484(3) 0.0251(11) Uani 1 1 d . . . . .
H7 H 0.774741 0.744463 0.720301 0.030 Uiso 1 1 calc R U . . .
C8 C 0.8455(4) 0.6528(4) 0.7555(3) 0.0316(12) Uani 1 1 d . . . . .
C9 C 0.8429(5) 0.5913(4) 0.7991(3) 0.0375(13) Uani 1 1 d . . . . .
H9 H 0.894034 0.559318 0.806582 0.045 Uiso 1 1 calc R U . . .
C10 C 0.7650(4) 0.5773(3) 0.8316(3) 0.0299(12) Uani 1 1 d . . . . .
C11 C 0.7420(5) 0.5225(4) 0.8823(3) 0.0343(13) Uani 1 1 d . . . . .
C12 C 0.7922(5) 0.4661(4) 0.9155(3) 0.0450(16) Uani 1 1 d . . . . .
H12 H 0.851021 0.454927 0.902965 0.054 Uiso 1 1 calc R U . . .
C13 C 0.7583(5) 0.4258(4) 0.9664(3) 0.0430(15) Uani 1 1 d D . . . .
C14 C 0.6715(5) 0.4452(4) 0.9834(3) 0.0372(14) Uani 1 1 d . . . . .
H14 H 0.648639 0.420144 1.019853 0.045 Uiso 1 1 calc R U . . .
C15 C 0.6172(4) 0.4993(3) 0.9496(3) 0.0304(12) Uani 1 1 d . . . . .
H15 H 0.557835 0.510175 0.961354 0.036 Uiso 1 1 calc R U . . .
C16 C 0.6537(4) 0.5366(3) 0.8978(3) 0.0276(11) Uani 1 1 d . . . . .
C17 C 0.9331(4) 0.6733(4) 0.7211(3) 0.0375(13) Uani 1 1 d . . . . .
C18 C 0.8935(5) 0.6858(6) 0.6408(4) 0.063(2) Uani 1 1 d . . . . .
H18A H 0.838514 0.629734 0.605325 0.094 Uiso 1 1 calc R U . . .
H18B H 0.949737 0.695047 0.618882 0.094 Uiso 1 1 calc R U . . .
H18C H 0.866862 0.740512 0.646707 0.094 Uiso 1 1 calc R U . . .
C19 C 1.0127(5) 0.7644(5) 0.7764(4) 0.064(2) Uani 1 1 d . . . . .
H19A H 0.980843 0.815949 0.780279 0.095 Uiso 1 1 calc R U . . .
H19B H 1.069634 0.777494 0.755791 0.095 Uiso 1 1 calc R U . . .
H19C H 1.038623 0.758444 0.828741 0.095 Uiso 1 1 calc R U . . .
C20 C 0.9858(6) 0.5964(6) 0.7132(5) 0.072(2) Uani 1 1 d . . . . .
H20A H 1.013128 0.589281 0.764868 0.109 Uiso 1 1 calc R U . . .
H20B H 1.042087 0.612695 0.692578 0.109 Uiso 1 1 calc R U . . .
H20C H 0.936224 0.537402 0.676914 0.109 Uiso 1 1 calc R U . . .
C21 C 0.8257(8) 0.3720(7) 1.0042(7) 0.045(3) Uani 0.516(8) 1 d D U P A 1
C22 C 0.9389(8) 0.4261(8) 1.0492(8) 0.050(3) Uani 0.516(8) 1 d D U P A 1
H22A H 0.969320 0.452513 1.014738 0.075 Uiso 0.516(8) 1 calc R U P A 1
H22B H 0.976086 0.383319 1.066235 0.075 Uiso 0.516(8) 1 calc R U P A 1
H22C H 0.943582 0.476789 1.095420 0.075 Uiso 0.516(8) 1 calc R U P A 1
C23 C 0.7775(13) 0.3313(11) 1.0579(10) 0.060(3) Uani 0.516(8) 1 d D U P A 1
H23A H 0.777967 0.382518 1.102125 0.090 Uiso 0.516(8) 1 calc R U P A 1
H23B H 0.816982 0.291763 1.078077 0.090 Uiso 0.516(8) 1 calc R U P A 1
H23C H 0.706556 0.293626 1.028048 0.090 Uiso 0.516(8) 1 calc R U P A 1
C25 C 0.4271(5) 0.5960(4) 0.5343(4) 0.0475(16) Uani 1 1 d . . . . .
H25 H 0.423002 0.602808 0.585706 0.057 Uiso 1 1 calc R U . . .
C26 C 0.3763(6) 0.5122(4) 0.4762(4) 0.0583(19) Uani 1 1 d . . . . .
H26 H 0.338804 0.460254 0.485854 0.070 Uiso 1 1 calc R U . . .
C27 C 0.3830(6) 0.5079(5) 0.4023(4) 0.0593(19) Uani 1 1 d . . . . .
H27 H 0.343180 0.453143 0.359294 0.071 Uiso 1 1 calc R U . . .
C28 C 0.4918(4) 0.6532(4) 0.4489(3) 0.0341(12) Uani 1 1 d . . . . .
C29 C 0.6491(4) 0.7868(3) 0.4956(3) 0.0295(12) Uani 1 1 d . . . . .
C30 C 0.6644(4) 0.8157(3) 0.5753(3) 0.0286(12) Uani 1 1 d . . . . .
C31 C 0.7623(4) 0.8776(3) 0.6198(3) 0.0253(11) Uani 1 1 d . . . . .
H31 H 0.780423 0.896005 0.675547 0.030 Uiso 1 1 calc R U . . .
C32 C 0.8345(4) 0.9140(3) 0.5879(3) 0.0275(11) Uani 1 1 d . . . . .
C33 C 0.8087(4) 0.8867(3) 0.5058(3) 0.0307(12) Uani 1 1 d . . . . .
H33 H 0.855290 0.912047 0.482231 0.037 Uiso 1 1 calc R U . . .
C34 C 0.7157(4) 0.8231(3) 0.4594(3) 0.0313(12) Uani 1 1 d . . . . .
C35 C 0.6636(5) 0.7829(3) 0.3742(3) 0.0336(13) Uani 1 1 d . . . . .
C36 C 0.6920(6) 0.8015(4) 0.3113(3) 0.0419(16) Uani 1 1 d . . . . .
H36 H 0.756915 0.843185 0.320616 0.050 Uiso 1 1 calc R U . . .
C37 C 0.6237(6) 0.7581(4) 0.2350(3) 0.0488(18) Uani 1 1 d D . . . .
C38 C 0.5294(6) 0.6953(4) 0.2241(3) 0.0499(18) Uani 1 1 d . . . . .
H38 H 0.482655 0.665627 0.172113 0.060 Uiso 1 1 calc R U . . .
C39 C 0.5017(5) 0.6748(4) 0.2858(3) 0.0429(15) Uani 1 1 d . . . . .
H39 H 0.438403 0.630840 0.276753 0.052 Uiso 1 1 calc R U . . .
C40 C 0.5700(5) 0.7209(4) 0.3612(3) 0.0355(14) Uani 1 1 d . . . . .
C41 C 0.9379(4) 0.9857(3) 0.6393(3) 0.0340(12) Uani 1 1 d D . . . .
C42 C 0.9521(6) 1.0078(5) 0.7270(4) 0.0399(19) Uani 0.771(7) 1 d D U P B 1
H42A H 1.020870 1.049985 0.757621 0.060 Uiso 0.771(7) 1 calc R U P B 1
H42B H 0.943988 0.949560 0.740201 0.060 Uiso 0.771(7) 1 calc R U P B 1
H42C H 0.900478 1.038057 0.739360 0.060 Uiso 0.771(7) 1 calc R U P B 1
C43 C 1.0224(6) 0.9414(5) 0.6228(5) 0.0428(19) Uani 0.771(7) 1 d D U P B 1
H43A H 1.015690 0.927395 0.566926 0.064 Uiso 0.771(7) 1 calc R U P B 1
H43B H 1.015355 0.883297 0.636322 0.064 Uiso 0.771(7) 1 calc R U P B 1
H43C H 1.089887 0.985198 0.654787 0.064 Uiso 0.771(7) 1 calc R U P B 1
C44 C 0.9461(7) 1.0745(5) 0.6171(5) 0.047(2) Uani 0.771(7) 1 d D U P B 1
H44A H 0.938377 1.059697 0.560983 0.071 Uiso 0.771(7) 1 calc R U P B 1
H44B H 1.013348 1.119302 0.648234 0.071 Uiso 0.771(7) 1 calc R U P B 1
H44C H 0.891943 1.102030 0.627755 0.071 Uiso 0.771(7) 1 calc R U P B 1
C45 C 0.6421(6) 0.7789(5) 0.1628(4) 0.047(2) Uani 0.793(9) 1 d D U P C 1
C46 C 0.7378(9) 0.8613(8) 0.1881(8) 0.078(4) Uani 0.793(9) 1 d D U P C 1
H46A H 0.733574 0.913436 0.229148 0.117 Uiso 0.793(9) 1 calc R U P C 1
H46B H 0.742282 0.881333 0.142621 0.117 Uiso 0.793(9) 1 calc R U P C 1
H46C H 0.798930 0.842066 0.208611 0.117 Uiso 0.793(9) 1 calc R U P C 1
C47 C 0.6614(8) 0.6906(5) 0.1152(5) 0.053(2) Uani 0.793(9) 1 d D U P C 1
H47A H 0.720819 0.678061 0.147663 0.080 Uiso 0.793(9) 1 calc R U P C 1
H47B H 0.675059 0.700317 0.068179 0.080 Uiso 0.793(9) 1 calc R U P C 1
H47C H 0.600779 0.637077 0.099357 0.080 Uiso 0.793(9) 1 calc R U P C 1
C48 C 0.5456(7) 0.7915(6) 0.1100(5) 0.076(3) Uani 0.793(9) 1 d D U P C 1
H48A H 0.489450 0.733648 0.091632 0.113 Uiso 0.793(9) 1 calc R U P C 1
H48B H 0.559865 0.805763 0.064579 0.113 Uiso 0.793(9) 1 calc R U P C 1
H48C H 0.525994 0.843189 0.140014 0.113 Uiso 0.793(9) 1 calc R U P C 1
C49 C 0.7245(4) 0.9513(3) 0.8333(3) 0.0274(11) Uani 1 1 d . . . . .
C50 C 0.7183(5) 1.0282(3) 0.8070(3) 0.0314(13) Uani 1 1 d . . . . .
H50 H 0.753542 1.091873 0.836631 0.038 Uiso 1 1 calc R U . . .
C51 C 0.6522(4) 0.9957(3) 0.7304(3) 0.0273(11) Uani 1 1 d D . . . .
C52 C 0.7902(4) 0.9522(3) 0.9120(3) 0.0296(12) Uani 1 1 d . . . . .
C53 C 0.8325(5) 1.0536(3) 0.9675(3) 0.0378(14) Uani 1 1 d . . . . .
H53A H 0.876645 1.090837 0.946539 0.057 Uiso 1 1 calc R U . . .
H53B H 0.872426 1.054787 1.019675 0.057 Uiso 1 1 calc R U . . .
H53C H 0.775341 1.079951 0.971771 0.057 Uiso 1 1 calc R U . . .
C54 C 0.8806(5) 0.9143(4) 0.9028(3) 0.0387(14) Uani 1 1 d . . . . .
H54A H 0.855122 0.847310 0.872733 0.058 Uiso 1 1 calc R U . . .
H54B H 0.927847 0.923448 0.954892 0.058 Uiso 1 1 calc R U . . .
H54C H 0.916667 0.947849 0.874773 0.058 Uiso 1 1 calc R U . . .
C55 C 0.7301(5) 0.8952(4) 0.9516(3) 0.0416(15) Uani 1 1 d . . . . .
H55A H 0.670413 0.917431 0.955713 0.062 Uiso 1 1 calc R U . . .
H55B H 0.774666 0.903002 1.004377 0.062 Uiso 1 1 calc R U . . .
H55C H 0.707030 0.828736 0.919950 0.062 Uiso 1 1 calc R U . . .
C56 C 0.6011(12) 1.0467(10) 0.6784(8) 0.034(3) Uani 0.57(3) 1 d D U P D 1
C57 C 0.6602(16) 1.1503(11) 0.7154(11) 0.041(4) Uani 0.57(3) 1 d D U P D 1
H57A H 0.648238 1.175648 0.765278 0.061 Uiso 0.57(3) 1 calc R U P D 1
H57B H 0.636675 1.184402 0.679520 0.061 Uiso 0.57(3) 1 calc R U P D 1
H57C H 0.733722 1.157357 0.725240 0.061 Uiso 0.57(3) 1 calc R U P D 1
C58 C 0.6090(19) 1.015(3) 0.5955(11) 0.031(4) Uani 0.57(3) 1 d D U P D 1
H58A H 0.680957 1.020354 0.599253 0.047 Uiso 0.57(3) 1 calc R U P D 1
H58B H 0.582835 1.053996 0.565688 0.047 Uiso 0.57(3) 1 calc R U P D 1
H58C H 0.568315 0.949194 0.568681 0.047 Uiso 0.57(3) 1 calc R U P D 1
C59 C 0.4882(13) 1.0365(12) 0.6745(11) 0.039(3) Uani 0.57(3) 1 d D U P D 1
H59A H 0.449502 0.970050 0.652673 0.059 Uiso 0.57(3) 1 calc R U P D 1
H59B H 0.458255 1.070583 0.640876 0.059 Uiso 0.57(3) 1 calc R U P D 1
H59C H 0.485283 1.062342 0.727650 0.059 Uiso 0.57(3) 1 calc R U P D 1
C60 C 0.3797(5) 0.8290(4) 0.7639(3) 0.0342(13) Uani 1 1 d . . . . .
C61 C 0.2980(5) 0.8277(4) 0.7020(3) 0.0426(15) Uani 1 1 d . . . . .
H61 H 0.237145 0.843676 0.705873 0.051 Uiso 1 1 calc R U . . .
C62 C 0.3223(4) 0.7986(4) 0.6336(3) 0.0411(14) Uani 1 1 d D . . . .
C63 C 0.3997(5) 0.8681(4) 0.8517(3) 0.0363(13) Uani 1 1 d . . . . .
C64 C 0.4381(5) 0.8047(4) 0.8967(3) 0.0344(13) Uani 1 1 d . . . . .
H64A H 0.386034 0.743988 0.877871 0.052 Uiso 1 1 calc R U . . .
H64B H 0.450975 0.833967 0.953037 0.052 Uiso 1 1 calc R U . . .
H64C H 0.501806 0.795387 0.888149 0.052 Uiso 1 1 calc R U . . .
C65 C 0.4812(6) 0.9631(4) 0.8806(3) 0.0471(17) Uani 1 1 d . . . . .
H65A H 0.544401 0.953748 0.871049 0.071 Uiso 1 1 calc R U . . .
H65B H 0.495309 0.992169 0.937179 0.071 Uiso 1 1 calc R U . . .
H65C H 0.455858 1.003988 0.852227 0.071 Uiso 1 1 calc R U . . .
C66 C 0.3018(5) 0.8839(5) 0.8675(4) 0.0545(18) Uani 1 1 d . . . . .
H66A H 0.277604 0.926179 0.840161 0.082 Uiso 1 1 calc R U . . .
H66B H 0.316353 0.911931 0.924218 0.082 Uiso 1 1 calc R U . . .
H66C H 0.248730 0.823803 0.848239 0.082 Uiso 1 1 calc R U . . .
C67 C 0.2529(7) 0.7706(6) 0.5490(5) 0.042(2) Uani 0.588(9) 1 d D U P E 1
C68 C 0.3113(10) 0.8108(9) 0.5001(8) 0.045(3) Uani 0.588(9) 1 d D U P E 1
H68A H 0.334234 0.879314 0.522052 0.067 Uiso 0.588(9) 1 calc R U P E 1
H68B H 0.266035 0.792036 0.445562 0.067 Uiso 0.588(9) 1 calc R U P E 1
H68C H 0.371071 0.786706 0.501297 0.067 Uiso 0.588(9) 1 calc R U P E 1
C69 C 0.2015(10) 0.6654(7) 0.5079(7) 0.070(4) Uani 0.588(9) 1 d D U P E 1
H69A H 0.253374 0.631275 0.514845 0.105 Uiso 0.588(9) 1 calc R U P E 1
H69B H 0.168732 0.653708 0.451596 0.105 Uiso 0.588(9) 1 calc R U P E 1
H69C H 0.149547 0.643874 0.530895 0.105 Uiso 0.588(9) 1 calc R U P E 1
C70 C 0.1642(9) 0.8152(10) 0.5494(7) 0.056(3) Uani 0.588(9) 1 d D U P E 1
H70A H 0.126701 0.792786 0.582019 0.083 Uiso 0.588(9) 1 calc R U P E 1
H70B H 0.117535 0.797562 0.495426 0.083 Uiso 0.588(9) 1 calc R U P E 1
H70C H 0.191785 0.883507 0.570866 0.083 Uiso 0.588(9) 1 calc R U P E 1
Cl1 Cl 0.9499(6) 0.6834(5) 1.1719(3) 0.204(3) Uani 0.747(6) 1 d D U P F 1
Cl2 Cl 0.9094(4) 0.7771(3) 1.0561(4) 0.162(2) Uani 0.747(6) 1 d D U P F 1
C71 C 0.8939(8) 0.6666(6) 1.0712(5) 0.073(3) Uani 0.747(6) 1 d D U P F 1
H71A H 0.819967 0.632974 1.053782 0.087 Uiso 0.747(6) 1 calc R U P F 1
H71B H 0.927177 0.628197 1.039894 0.087 Uiso 0.747(6) 1 calc R U P F 1
Cl3 Cl 0.8766(3) 0.55529(17) 0.44401(14) 0.0958(11) Uani 0.893(5) 1 d D U P G 1
Cl4 Cl 0.8997(2) 0.6809(2) 0.3537(2) 0.1214(14) Uani 0.893(5) 1 d D U P G 1
C72 C 0.8448(9) 0.6546(6) 0.4258(5) 0.096(3) Uani 0.893(5) 1 d D U P G 1
H72A H 0.872278 0.708481 0.475054 0.115 Uiso 0.893(5) 1 calc R U P G 1
H72B H 0.769325 0.641943 0.405987 0.115 Uiso 0.893(5) 1 calc R U P G 1
C24 C 0.8227(14) 0.2890(8) 0.9356(8) 0.060(3) Uani 0.516(8) 1 d D U P A 1
H24A H 0.752695 0.246979 0.911442 0.090 Uiso 0.516(8) 1 calc R U P A 1
H24B H 0.869472 0.254727 0.955662 0.090 Uiso 0.516(8) 1 calc R U P A 1
H24C H 0.843942 0.312696 0.896198 0.090 Uiso 0.516(8) 1 calc R U P A 1
C21A C 0.7922(10) 0.3491(8) 0.9961(8) 0.052(3) Uani 0.484(8) 1 d D U P A 2
C24A C 0.8196(15) 0.3816(12) 1.0860(8) 0.065(4) Uani 0.484(8) 1 d D U P A 2
H24D H 0.757202 0.383737 1.100024 0.098 Uiso 0.484(8) 1 calc R U P A 2
H24E H 0.868543 0.444210 1.108373 0.098 Uiso 0.484(8) 1 calc R U P A 2
H24F H 0.850393 0.337647 1.107113 0.098 Uiso 0.484(8) 1 calc R U P A 2
C22A C 0.7081(11) 0.2545(8) 0.9661(9) 0.057(3) Uani 0.484(8) 1 d D U P A 2
H22D H 0.735996 0.208871 0.986692 0.086 Uiso 0.484(8) 1 calc R U P A 2
H22E H 0.684972 0.231346 0.908397 0.086 Uiso 0.484(8) 1 calc R U P A 2
H22F H 0.649866 0.263340 0.984083 0.086 Uiso 0.484(8) 1 calc R U P A 2
C23A C 0.8857(12) 0.3327(12) 0.9716(11) 0.063(4) Uani 0.484(8) 1 d D U P A 2
H23D H 0.941523 0.391187 0.993743 0.094 Uiso 0.484(8) 1 calc R U P A 2
H23E H 0.866421 0.311947 0.914062 0.094 Uiso 0.484(8) 1 calc R U P A 2
H23F H 0.908612 0.284459 0.991452 0.094 Uiso 0.484(8) 1 calc R U P A 2
C67A C 0.2666(10) 0.8113(9) 0.5575(6) 0.043(3) Uani 0.412(9) 1 d D U P E 2
C70A C 0.3026(16) 0.7666(12) 0.4895(10) 0.043(4) Uani 0.412(9) 1 d D U P E 2
H70D H 0.255560 0.764872 0.439609 0.064 Uiso 0.412(9) 1 calc R U P E 2
H70E H 0.303378 0.702614 0.488208 0.064 Uiso 0.412(9) 1 calc R U P E 2
H70F H 0.371883 0.803650 0.497126 0.064 Uiso 0.412(9) 1 calc R U P E 2
C69A C 0.2665(13) 0.9123(9) 0.5603(9) 0.057(4) Uani 0.412(9) 1 d D U P E 2
H69D H 0.337145 0.950813 0.574314 0.085 Uiso 0.412(9) 1 calc R U P E 2
H69E H 0.236107 0.938243 0.599864 0.085 Uiso 0.412(9) 1 calc R U P E 2
H69F H 0.226144 0.912009 0.508597 0.085 Uiso 0.412(9) 1 calc R U P E 2
C68A C 0.1564(11) 0.7515(14) 0.5391(11) 0.059(4) Uani 0.412(9) 1 d D U P E 2
H68D H 0.157161 0.688056 0.539651 0.088 Uiso 0.412(9) 1 calc R U P E 2
H68E H 0.114264 0.748444 0.486916 0.088 Uiso 0.412(9) 1 calc R U P E 2
H68F H 0.127478 0.779762 0.578812 0.088 Uiso 0.412(9) 1 calc R U P E 2
C48A C 0.781(2) 0.754(2) 0.1731(19) 0.061(6) Uani 0.207(9) 1 d D U P C 2
H48D H 0.837130 0.802776 0.216247 0.092 Uiso 0.207(9) 1 calc R U P C 2
H48E H 0.790201 0.755259 0.122706 0.092 Uiso 0.207(9) 1 calc R U P C 2
H48F H 0.783048 0.692369 0.178981 0.092 Uiso 0.207(9) 1 calc R U P C 2
C45A C 0.677(2) 0.7706(19) 0.1754(13) 0.049(4) Uani 0.207(9) 1 d D U P C 2
C46A C 0.622(3) 0.713(2) 0.0878(15) 0.060(6) Uani 0.207(9) 1 d D U P C 2
H46D H 0.569001 0.658258 0.083365 0.090 Uiso 0.207(9) 1 calc R U P C 2
H46E H 0.671900 0.692897 0.064008 0.090 Uiso 0.207(9) 1 calc R U P C 2
H46F H 0.590200 0.752214 0.060435 0.090 Uiso 0.207(9) 1 calc R U P C 2
C47A C 0.701(3) 0.875(2) 0.182(3) 0.039(6) Uani 0.207(9) 1 d D U P C 2
H47D H 0.638765 0.895210 0.180229 0.058 Uiso 0.207(9) 1 calc R U P C 2
H47E H 0.723415 0.883509 0.137818 0.058 Uiso 0.207(9) 1 calc R U P C 2
H47F H 0.755165 0.911677 0.231645 0.058 Uiso 0.207(9) 1 calc R U P C 2
C56A C 0.6193(14) 1.0595(13) 0.6850(11) 0.032(3) Uani 0.43(3) 1 d D U P D 2
C58A C 0.588(3) 1.015(4) 0.5956(13) 0.029(5) Uani 0.43(3) 1 d D U P D 2
H58D H 0.562538 1.058160 0.569714 0.044 Uiso 0.43(3) 1 calc R U P D 2
H58E H 0.533379 0.956238 0.578620 0.044 Uiso 0.43(3) 1 calc R U P D 2
H58F H 0.647271 1.002512 0.581187 0.044 Uiso 0.43(3) 1 calc R U P D 2
C57A C 0.6979(17) 1.1552(14) 0.7118(14) 0.031(4) Uani 0.43(3) 1 d D U P D 2
H57D H 0.753054 1.149558 0.689169 0.047 Uiso 0.43(3) 1 calc R U P D 2
H57E H 0.726762 1.177682 0.769406 0.047 Uiso 0.43(3) 1 calc R U P D 2
H57F H 0.664365 1.199718 0.694160 0.047 Uiso 0.43(3) 1 calc R U P D 2
C59A C 0.5226(17) 1.0718(16) 0.7056(14) 0.037(4) Uani 0.43(3) 1 d D U P D 2
H59D H 0.493770 1.113093 0.679408 0.055 Uiso 0.43(3) 1 calc R U P D 2
H59E H 0.540539 1.099477 0.762706 0.055 Uiso 0.43(3) 1 calc R U P D 2
H59F H 0.471725 1.010524 0.687782 0.055 Uiso 0.43(3) 1 calc R U P D 2
Cl1A Cl 1.149(2) 0.6352(13) 1.2745(13) 0.274(10) Uani 0.253(6) 1 d D U P F 2
C71A C 1.032(2) 0.642(3) 1.213(4) 0.242(10) Uani 0.253(6) 1 d D U P F 2
H71C H 0.980762 0.644698 1.240942 0.290 Uiso 0.253(6) 1 calc R U P F 2
H71D H 1.002467 0.586596 1.164640 0.290 Uiso 0.253(6) 1 calc R U P F 2
Cl2A Cl 1.063(3) 0.748(2) 1.1875(16) 0.336(10) Uani 0.253(6) 1 d D U P F 2
C44A C 1.0175(17) 1.0267(18) 0.6043(15) 0.045(5) Uani 0.229(7) 1 d D U P B 2
H44D H 0.985692 1.055529 0.566525 0.068 Uiso 0.229(7) 1 calc R U P B 2
H44E H 1.041868 0.976532 0.577371 0.068 Uiso 0.229(7) 1 calc R U P B 2
H44F H 1.075541 1.074239 0.646620 0.068 Uiso 0.229(7) 1 calc R U P B 2
C43A C 1.0005(17) 0.9564(19) 0.7063(12) 0.043(5) Uani 0.229(7) 1 d D U P B 2
H43D H 1.028974 0.906788 0.683900 0.065 Uiso 0.229(7) 1 calc R U P B 2
H43E H 0.955505 0.933137 0.733949 0.065 Uiso 0.229(7) 1 calc R U P B 2
H43F H 1.056558 1.010629 0.743394 0.065 Uiso 0.229(7) 1 calc R U P B 2
C42A C 0.918(2) 1.0774(12) 0.6834(15) 0.046(5) Uani 0.229(7) 1 d D U P B 2
H42D H 0.983756 1.123144 0.717051 0.070 Uiso 0.229(7) 1 calc R U P B 2
H42E H 0.875941 1.063421 0.715963 0.070 Uiso 0.229(7) 1 calc R U P B 2
H42F H 0.882050 1.103278 0.645015 0.070 Uiso 0.229(7) 1 calc R U P B 2
C72A C 0.882(9) 0.594(3) 0.424(4) 0.116(6) Uani 0.107(5) 1 d D U P G 2
H72C H 0.816917 0.611244 0.421301 0.140 Uiso 0.107(5) 1 calc R U P G 2
H72D H 0.933609 0.634052 0.475364 0.140 Uiso 0.107(5) 1 calc R U P G 2
Cl3A Cl 0.862(3) 0.4731(18) 0.417980 0.159(9) Uani 0.107(5) 1 d D U P G 2
Cl4A Cl 0.925(3) 0.617(2) 0.346(2) 0.144(8) Uani 0.107(5) 1 d D U P G 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 3.0308(3) . ?
Pt1 N1 2.038(4) . ?
Pt1 N7 2.021(4) . ?
Pt1 N9 2.116(4) . ?
Pt1 C6 1.980(5) . ?
Pt2 N4 2.021(4) . ?
Pt2 N8 2.007(4) . ?
Pt2 N10 2.146(4) . ?
Pt2 C30 1.974(5) . ?
N1 C1 1.348(6) . ?
N1 C4 1.375(6) . ?
N2 C3 1.311(7) . ?
N2 C4 1.351(6) . ?
N3 C4 1.364(6) . ?
N3 C5 1.421(6) . ?
N3 C16 1.436(6) . ?
N4 C25 1.349(7) . ?
N4 C28 1.352(6) . ?
N5 C27 1.307(8) . ?
N5 C28 1.332(7) . ?
N6 C28 1.372(7) . ?
N6 C29 1.441(7) . ?
N6 C40 1.434(6) . ?
N7 N8 1.385(5) . ?
N7 C49 1.349(6) . ?
N8 C51 1.354(6) . ?
N9 N10 1.382(5) . ?
N9 C60 1.330(7) . ?
N10 C62 1.364(7) . ?
C1 H1 0.9500 . ?
C1 C2 1.365(7) . ?
C2 H2 0.9500 . ?
C2 C3 1.392(8) . ?
C3 H3 0.9500 . ?
C5 C6 1.380(6) . ?
C5 C10 1.391(7) . ?
C6 C7 1.399(7) . ?
C7 H7 0.9500 . ?
C7 C8 1.395(7) . ?
C8 C9 1.393(7) . ?
C8 C17 1.540(7) . ?
C9 H9 0.9500 . ?
C9 C10 1.385(7) . ?
C10 C11 1.466(7) . ?
C11 C12 1.383(7) . ?
C11 C16 1.388(7) . ?
C12 H12 0.9500 . ?
C12 C13 1.384(8) . ?
C13 C14 1.405(8) . ?
C13 C21 1.527(8) . ?
C13 C21A 1.529(9) . ?
C14 H14 0.9500 . ?
C14 C15 1.392(7) . ?
C15 H15 0.9500 . ?
C15 C16 1.389(7) . ?
C17 C18 1.526(8) . ?
C17 C19 1.526(9) . ?
C17 C20 1.510(8) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.537(9) . ?
C21 C23 1.530(9) . ?
C21 C24 1.542(9) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C25 H25 0.9500 . ?
C25 C26 1.367(8) . ?
C26 H26 0.9500 . ?
C26 C27 1.384(9) . ?
C27 H27 0.9500 . ?
C29 C30 1.376(7) . ?
C29 C34 1.395(7) . ?
C30 C31 1.407(7) . ?
C31 H31 0.9500 . ?
C31 C32 1.394(7) . ?
C32 C33 1.400(7) . ?
C32 C41 1.536(7) . ?
C33 H33 0.9500 . ?
C33 C34 1.377(8) . ?
C34 C35 1.466(7) . ?
C35 C36 1.402(7) . ?
C35 C40 1.385(8) . ?
C36 H36 0.9500 . ?
C36 C37 1.393(8) . ?
C37 C38 1.409(9) . ?
C37 C45 1.525(7) . ?
C37 C45A 1.517(10) . ?
C38 H38 0.9500 . ?
C38 C39 1.388(8) . ?
C39 H39 0.9500 . ?
C39 C40 1.386(8) . ?
C41 C42 1.527(6) . ?
C41 C43 1.539(7) . ?
C41 C44 1.513(7) . ?
C41 C44A 1.539(10) . ?
C41 C43A 1.550(10) . ?
C41 C42A 1.557(10) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.527(8) . ?
C45 C47 1.536(7) . ?
C45 C48 1.534(8) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C50 1.399(6) . ?
C49 C52 1.509(7) . ?
C50 H50 0.9500 . ?
C50 C51 1.382(7) . ?
C51 C56 1.521(8) . ?
C51 C56A 1.512(9) . ?
C52 C53 1.533(6) . ?
C52 C54 1.529(8) . ?
C52 C55 1.540(7) . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C57 1.525(9) . ?
C56 C58 1.531(9) . ?
C56 C59 1.544(9) . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C60 C61 1.392(8) . ?
C60 C63 1.516(8) . ?
C61 H61 0.9500 . ?
C61 C62 1.388(8) . ?
C62 C67 1.517(8) . ?
C62 C67A 1.508(9) . ?
C63 C64 1.526(7) . ?
C63 C65 1.534(8) . ?
C63 C66 1.531(8) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 C68 1.532(9) . ?
C67 C69 1.533(9) . ?
C67 C70 1.537(9) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
Cl1 C71 1.760(8) . ?
Cl2 C71 1.771(8) . ?
C71 H71A 0.9900 . ?
C71 H71B 0.9900 . ?
Cl3 C72 1.760(7) . ?
Cl4 C72 1.798(8) . ?
C72 H72A 0.9900 . ?
C72 H72B 0.9900 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C21A C24A 1.534(9) . ?
C21A C22A 1.547(9) . ?
C21A C23A 1.541(9) . ?
C24A H24D 0.9800 . ?
C24A H24E 0.9800 . ?
C24A H24F 0.9800 . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?
C23A H23D 0.9800 . ?
C23A H23E 0.9800 . ?
C23A H23F 0.9800 . ?
C67A C70A 1.534(10) . ?
C67A C69A 1.540(9) . ?
C67A C68A 1.538(10) . ?
C70A H70D 0.9800 . ?
C70A H70E 0.9800 . ?
C70A H70F 0.9800 . ?
C69A H69D 0.9800 . ?
C69A H69E 0.9800 . ?
C69A H69F 0.9800 . ?
C68A H68D 0.9800 . ?
C68A H68E 0.9800 . ?
C68A H68F 0.9800 . ?
C48A H48D 0.9800 . ?
C48A H48E 0.9800 . ?
C48A H48F 0.9800 . ?
C48A C45A 1.547(10) . ?
C45A C46A 1.541(10) . ?
C45A C47A 1.535(10) . ?
C46A H46D 0.9800 . ?
C46A H46E 0.9800 . ?
C46A H46F 0.9800 . ?
C47A H47D 0.9800 . ?
C47A H47E 0.9800 . ?
C47A H47F 0.9800 . ?
C56A C58A 1.531(10) . ?
C56A C57A 1.527(9) . ?
C56A C59A 1.537(10) . ?
C58A H58D 0.9800 . ?
C58A H58E 0.9800 . ?
C58A H58F 0.9800 . ?
C57A H57D 0.9800 . ?
C57A H57E 0.9800 . ?
C57A H57F 0.9800 . ?
C59A H59D 0.9800 . ?
C59A H59E 0.9800 . ?
C59A H59F 0.9800 . ?
Cl1A C71A 1.785(10) . ?
C71A H71C 0.9900 . ?
C71A H71D 0.9900 . ?
C71A Cl2A 1.812(10) . ?
C44A H44D 0.9800 . ?
C44A H44E 0.9800 . ?
C44A H44F 0.9800 . ?
C43A H43D 0.9800 . ?
C43A H43E 0.9800 . ?
C43A H43F 0.9800 . ?
C42A H42D 0.9800 . ?
C42A H42E 0.9800 . ?
C42A H42F 0.9800 . ?
C72A H72C 0.9900 . ?
C72A H72D 0.9900 . ?
C72A Cl3A 1.798(10) . ?
C72A Cl4A 1.791(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 Pt2 119.48(12) . . ?
N1 Pt1 N9 89.14(16) . . ?
N7 Pt1 Pt2 64.41(11) . . ?
N7 Pt1 N1 171.94(15) . . ?
N7 Pt1 N9 86.26(16) . . ?
N9 Pt1 Pt2 66.23(10) . . ?
C6 Pt1 Pt2 107.31(14) . . ?
C6 Pt1 N1 89.19(18) . . ?
C6 Pt1 N7 96.34(18) . . ?
C6 Pt1 N9 171.21(17) . . ?
N4 Pt2 Pt1 109.68(12) . . ?
N4 Pt2 N10 96.02(18) . . ?
N8 Pt2 Pt1 64.61(10) . . ?
N8 Pt2 N4 172.63(16) . . ?
N8 Pt2 N10 85.83(16) . . ?
N10 Pt2 Pt1 65.36(11) . . ?
C30 Pt2 Pt1 118.48(14) . . ?
C30 Pt2 N4 89.1(2) . . ?
C30 Pt2 N8 89.86(19) . . ?
C30 Pt2 N10 172.13(17) . . ?
C1 N1 Pt1 120.0(3) . . ?
C1 N1 C4 116.4(4) . . ?
C4 N1 Pt1 122.3(3) . . ?
C3 N2 C4 117.6(5) . . ?
C4 N3 C5 123.0(4) . . ?
C4 N3 C16 123.0(4) . . ?
C5 N3 C16 107.1(4) . . ?
C25 N4 Pt2 117.1(4) . . ?
C25 N4 C28 116.0(5) . . ?
C28 N4 Pt2 126.9(4) . . ?
C27 N5 C28 117.0(5) . . ?
C28 N6 C29 123.9(4) . . ?
C28 N6 C40 126.2(4) . . ?
C40 N6 C29 106.9(4) . . ?
N8 N7 Pt1 110.9(3) . . ?
C49 N7 Pt1 134.5(3) . . ?
C49 N7 N8 108.9(4) . . ?
N7 N8 Pt2 111.5(3) . . ?
C51 N8 Pt2 138.8(3) . . ?
C51 N8 N7 108.7(4) . . ?
N10 N9 Pt1 109.8(3) . . ?
C60 N9 Pt1 140.3(3) . . ?
C60 N9 N10 109.0(4) . . ?
N9 N10 Pt2 109.5(3) . . ?
C62 N10 Pt2 137.3(3) . . ?
C62 N10 N9 107.9(4) . . ?
N1 C1 H1 118.5 . . ?
N1 C1 C2 123.0(5) . . ?
C2 C1 H1 118.5 . . ?
C1 C2 H2 122.1 . . ?
C1 C2 C3 115.9(5) . . ?
C3 C2 H2 122.1 . . ?
N2 C3 C2 123.5(5) . . ?
N2 C3 H3 118.2 . . ?
C2 C3 H3 118.2 . . ?
N2 C4 N1 123.0(5) . . ?
N2 C4 N3 117.3(4) . . ?
N3 C4 N1 119.7(4) . . ?
C6 C5 N3 126.7(4) . . ?
C6 C5 C10 123.9(5) . . ?
C10 C5 N3 109.4(4) . . ?
C5 C6 Pt1 118.9(4) . . ?
C5 C6 C7 114.3(4) . . ?
C7 C6 Pt1 126.6(3) . . ?
C6 C7 H7 117.8 . . ?
C8 C7 C6 124.4(4) . . ?
C8 C7 H7 117.8 . . ?
C7 C8 C17 120.5(4) . . ?
C9 C8 C7 118.3(5) . . ?
C9 C8 C17 121.0(5) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 C8 119.4(5) . . ?
C10 C9 H9 120.3 . . ?
C5 C10 C11 106.8(4) . . ?
C9 C10 C5 119.6(4) . . ?
C9 C10 C11 133.6(5) . . ?
C12 C11 C10 132.1(5) . . ?
C12 C11 C16 119.8(5) . . ?
C16 C11 C10 108.0(4) . . ?
C11 C12 H12 119.3 . . ?
C11 C12 C13 121.3(5) . . ?
C13 C12 H12 119.3 . . ?
C12 C13 C14 117.0(5) . . ?
C12 C13 C21 116.0(6) . . ?
C12 C13 C21A 127.7(7) . . ?
C14 C13 C21 126.7(6) . . ?
C14 C13 C21A 114.4(7) . . ?
C13 C14 H14 118.3 . . ?
C15 C14 C13 123.3(5) . . ?
C15 C14 H14 118.3 . . ?
C14 C15 H15 121.5 . . ?
C16 C15 C14 117.0(5) . . ?
C16 C15 H15 121.5 . . ?
C11 C16 N3 108.3(4) . . ?
C11 C16 C15 121.3(5) . . ?
C15 C16 N3 130.3(5) . . ?
C18 C17 C8 111.0(5) . . ?
C18 C17 C19 107.9(5) . . ?
C19 C17 C8 108.7(5) . . ?
C20 C17 C8 111.8(5) . . ?
C20 C17 C18 109.1(5) . . ?
C20 C17 C19 108.2(6) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C13 C21 C22 116.5(8) . . ?
C13 C21 C23 109.5(9) . . ?
C13 C21 C24 105.6(8) . . ?
C22 C21 C24 107.5(11) . . ?
C23 C21 C22 109.7(11) . . ?
C23 C21 C24 107.5(11) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N4 C25 H25 118.8 . . ?
N4 C25 C26 122.5(6) . . ?
C26 C25 H25 118.8 . . ?
C25 C26 H26 122.1 . . ?
C25 C26 C27 115.8(6) . . ?
C27 C26 H26 122.1 . . ?
N5 C27 C26 123.5(6) . . ?
N5 C27 H27 118.2 . . ?
C26 C27 H27 118.2 . . ?
N4 C28 N6 118.3(5) . . ?
N5 C28 N4 124.7(5) . . ?
N5 C28 N6 117.0(5) . . ?
C30 C29 N6 125.9(5) . . ?
C30 C29 C34 125.0(5) . . ?
C34 C29 N6 108.8(4) . . ?
C29 C30 Pt2 119.0(4) . . ?
C29 C30 C31 113.2(5) . . ?
C31 C30 Pt2 126.4(4) . . ?
C30 C31 H31 117.7 . . ?
C32 C31 C30 124.5(5) . . ?
C32 C31 H31 117.7 . . ?
C31 C32 C33 118.1(5) . . ?
C31 C32 C41 122.3(4) . . ?
C33 C32 C41 119.5(4) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 C32 119.7(5) . . ?
C34 C33 H33 120.1 . . ?
C29 C34 C35 107.1(5) . . ?
C33 C34 C29 118.9(5) . . ?
C33 C34 C35 134.0(5) . . ?
C36 C35 C34 130.7(6) . . ?
C40 C35 C34 108.2(5) . . ?
C40 C35 C36 121.0(5) . . ?
C35 C36 H36 120.5 . . ?
C37 C36 C35 119.0(6) . . ?
C37 C36 H36 120.5 . . ?
C36 C37 C38 118.4(5) . . ?
C36 C37 C45 123.8(6) . . ?
C36 C37 C45A 110.4(12) . . ?
C38 C37 C45 117.7(6) . . ?
C38 C37 C45A 129.5(11) . . ?
C37 C38 H38 118.5 . . ?
C39 C38 C37 123.0(6) . . ?
C39 C38 H38 118.5 . . ?
C38 C39 H39 121.3 . . ?
C40 C39 C38 117.3(6) . . ?
C40 C39 H39 121.3 . . ?
C35 C40 N6 108.8(5) . . ?
C35 C40 C39 121.3(5) . . ?
C39 C40 N6 129.7(6) . . ?
C32 C41 C43 107.0(5) . . ?
C32 C41 C44A 122.6(11) . . ?
C32 C41 C43A 114.4(10) . . ?
C32 C41 C42A 109.0(11) . . ?
C42 C41 C32 112.1(4) . . ?
C42 C41 C43 107.8(5) . . ?
C44 C41 C32 109.4(5) . . ?
C44 C41 C42 110.2(5) . . ?
C44 C41 C43 110.2(5) . . ?
C44A C41 C43A 104.6(14) . . ?
C44A C41 C42A 100.0(14) . . ?
C43A C41 C42A 103.9(16) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C37 C45 C46 110.0(7) . . ?
C37 C45 C47 105.8(5) . . ?
C37 C45 C48 111.1(6) . . ?
C46 C45 C47 108.9(8) . . ?
C46 C45 C48 114.0(8) . . ?
C48 C45 C47 106.6(7) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C45 C48 H48A 109.5 . . ?
C45 C48 H48B 109.5 . . ?
C45 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
N7 C49 C50 106.8(4) . . ?
N7 C49 C52 125.8(4) . . ?
C50 C49 C52 127.3(4) . . ?
C49 C50 H50 125.8 . . ?
C51 C50 C49 108.4(4) . . ?
C51 C50 H50 125.8 . . ?
N8 C51 C50 107.2(4) . . ?
N8 C51 C56 120.2(7) . . ?
N8 C51 C56A 129.2(9) . . ?
C50 C51 C56 131.3(7) . . ?
C50 C51 C56A 123.3(9) . . ?
C49 C52 C53 108.7(4) . . ?
C49 C52 C54 110.2(4) . . ?
C49 C52 C55 113.0(5) . . ?
C53 C52 C55 107.2(4) . . ?
C54 C52 C53 108.5(5) . . ?
C54 C52 C55 109.1(4) . . ?
C52 C53 H53A 109.5 . . ?
C52 C53 H53B 109.5 . . ?
C52 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C52 C54 H54A 109.5 . . ?
C52 C54 H54B 109.5 . . ?
C52 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C52 C55 H55A 109.5 . . ?
C52 C55 H55B 109.5 . . ?
C52 C55 H55C 109.5 . . ?
H55A C55 H55B 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C51 C56 C57 106.8(11) . . ?
C51 C56 C58 111.7(18) . . ?
C51 C56 C59 111.9(10) . . ?
C57 C56 C58 107.2(18) . . ?
C57 C56 C59 108.3(10) . . ?
C58 C56 C59 110.7(13) . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C56 C58 H58A 109.5 . . ?
C56 C58 H58B 109.5 . . ?
C56 C58 H58C 109.5 . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C56 C59 H59A 109.5 . . ?
C56 C59 H59B 109.5 . . ?
C56 C59 H59C 109.5 . . ?
H59A C59 H59B 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
N9 C60 C61 108.5(5) . . ?
N9 C60 C63 122.4(5) . . ?
C61 C60 C63 128.8(5) . . ?
C60 C61 H61 126.5 . . ?
C62 C61 C60 107.0(5) . . ?
C62 C61 H61 126.5 . . ?
N10 C62 C61 107.6(4) . . ?
N10 C62 C67 123.3(6) . . ?
N10 C62 C67A 127.8(7) . . ?
C61 C62 C67 128.0(6) . . ?
C61 C62 C67A 122.5(7) . . ?
C60 C63 C64 113.1(4) . . ?
C60 C63 C65 106.4(4) . . ?
C60 C63 C66 110.1(5) . . ?
C64 C63 C65 109.7(5) . . ?
C64 C63 C66 108.7(4) . . ?
C66 C63 C65 108.8(5) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64B 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C63 C65 H65A 109.5 . . ?
C63 C65 H65B 109.5 . . ?
C63 C65 H65C 109.5 . . ?
H65A C65 H65B 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C63 C66 H66A 109.5 . . ?
C63 C66 H66B 109.5 . . ?
C63 C66 H66C 109.5 . . ?
H66A C66 H66B 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
C62 C67 C68 110.1(8) . . ?
C62 C67 C69 115.9(7) . . ?
C62 C67 C70 107.7(7) . . ?
C68 C67 C69 110.1(9) . . ?
C68 C67 C70 107.3(9) . . ?
C69 C67 C70 105.3(10) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C67 C69 H69A 109.5 . . ?
C67 C69 H69B 109.5 . . ?
C67 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C67 C70 H70A 109.5 . . ?
C67 C70 H70B 109.5 . . ?
C67 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
Cl1 C71 Cl2 109.1(5) . . ?
Cl1 C71 H71A 109.9 . . ?
Cl1 C71 H71B 109.9 . . ?
Cl2 C71 H71A 109.9 . . ?
Cl2 C71 H71B 109.9 . . ?
H71A C71 H71B 108.3 . . ?
Cl3 C72 Cl4 108.3(4) . . ?
Cl3 C72 H72A 110.0 . . ?
Cl3 C72 H72B 110.0 . . ?
Cl4 C72 H72A 110.0 . . ?
Cl4 C72 H72B 110.0 . . ?
H72A C72 H72B 108.4 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C13 C21A C24A 108.0(9) . . ?
C13 C21A C22A 114.4(9) . . ?
C13 C21A C23A 109.2(9) . . ?
C24A C21A C22A 105.6(12) . . ?
C24A C21A C23A 111.0(13) . . ?
C23A C21A C22A 108.7(11) . . ?
C21A C24A H24D 109.5 . . ?
C21A C24A H24E 109.5 . . ?
C21A C24A H24F 109.5 . . ?
H24D C24A H24E 109.5 . . ?
H24D C24A H24F 109.5 . . ?
H24E C24A H24F 109.5 . . ?
C21A C22A H22D 109.5 . . ?
C21A C22A H22E 109.5 . . ?
C21A C22A H22F 109.5 . . ?
H22D C22A H22E 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?
C21A C23A H23D 109.5 . . ?
C21A C23A H23E 109.5 . . ?
C21A C23A H23F 109.5 . . ?
H23D C23A H23E 109.5 . . ?
H23D C23A H23F 109.5 . . ?
H23E C23A H23F 109.5 . . ?
C62 C67A C70A 112.1(11) . . ?
C62 C67A C69A 116.4(10) . . ?
C62 C67A C68A 102.3(10) . . ?
C70A C67A C69A 109.6(12) . . ?
C70A C67A C68A 105.9(14) . . ?
C68A C67A C69A 109.7(13) . . ?
C67A C70A H70D 109.5 . . ?
C67A C70A H70E 109.5 . . ?
C67A C70A H70F 109.5 . . ?
H70D C70A H70E 109.5 . . ?
H70D C70A H70F 109.5 . . ?
H70E C70A H70F 109.5 . . ?
C67A C69A H69D 109.5 . . ?
C67A C69A H69E 109.5 . . ?
C67A C69A H69F 109.5 . . ?
H69D C69A H69E 109.5 . . ?
H69D C69A H69F 109.5 . . ?
H69E C69A H69F 109.5 . . ?
C67A C68A H68D 109.5 . . ?
C67A C68A H68E 109.5 . . ?
C67A C68A H68F 109.5 . . ?
H68D C68A H68E 109.5 . . ?
H68D C68A H68F 109.5 . . ?
H68E C68A H68F 109.5 . . ?
H48D C48A H48E 109.5 . . ?
H48D C48A H48F 109.5 . . ?
H48E C48A H48F 109.5 . . ?
C45A C48A H48D 109.5 . . ?
C45A C48A H48E 109.5 . . ?
C45A C48A H48F 109.5 . . ?
C37 C45A C48A 128(2) . . ?
C37 C45A C46A 119(2) . . ?
C37 C45A C47A 107(2) . . ?
C46A C45A C48A 93(2) . . ?
C47A C45A C48A 100(2) . . ?
C47A C45A C46A 108(3) . . ?
C45A C46A H46D 109.5 . . ?
C45A C46A H46E 109.5 . . ?
C45A C46A H46F 109.5 . . ?
H46D C46A H46E 109.5 . . ?
H46D C46A H46F 109.5 . . ?
H46E C46A H46F 109.5 . . ?
C45A C47A H47D 109.5 . . ?
C45A C47A H47E 109.5 . . ?
C45A C47A H47F 109.5 . . ?
H47D C47A H47E 109.5 . . ?
H47D C47A H47F 109.5 . . ?
H47E C47A H47F 109.5 . . ?
C51 C56A C58A 114(2) . . ?
C51 C56A C57A 113.5(14) . . ?
C51 C56A C59A 101.6(12) . . ?
C58A C56A C59A 107.8(18) . . ?
C57A C56A C58A 110(2) . . ?
C57A C56A C59A 109.4(13) . . ?
C56A C58A H58D 109.5 . . ?
C56A C58A H58E 109.5 . . ?
C56A C58A H58F 109.5 . . ?
H58D C58A H58E 109.5 . . ?
H58D C58A H58F 109.5 . . ?
H58E C58A H58F 109.5 . . ?
C56A C57A H57D 109.5 . . ?
C56A C57A H57E 109.5 . . ?
C56A C57A H57F 109.5 . . ?
H57D C57A H57E 109.5 . . ?
H57D C57A H57F 109.5 . . ?
H57E C57A H57F 109.5 . . ?
C56A C59A H59D 109.5 . . ?
C56A C59A H59E 109.5 . . ?
C56A C59A H59F 109.5 . . ?
H59D C59A H59E 109.5 . . ?
H59D C59A H59F 109.5 . . ?
H59E C59A H59F 109.5 . . ?
Cl1A C71A H71C 110.4 . . ?
Cl1A C71A H71D 110.4 . . ?
Cl1A C71A Cl2A 106.5(12) . . ?
H71C C71A H71D 108.6 . . ?
Cl2A C71A H71C 110.4 . . ?
Cl2A C71A H71D 110.4 . . ?
C41 C44A H44D 109.5 . . ?
C41 C44A H44E 109.5 . . ?
C41 C44A H44F 109.5 . . ?
H44D C44A H44E 109.5 . . ?
H44D C44A H44F 109.5 . . ?
H44E C44A H44F 109.5 . . ?
C41 C43A H43D 109.5 . . ?
C41 C43A H43E 109.5 . . ?
C41 C43A H43F 109.5 . . ?
H43D C43A H43E 109.5 . . ?
H43D C43A H43F 109.5 . . ?
H43E C43A H43F 109.5 . . ?
C41 C42A H42D 109.5 . . ?
C41 C42A H42E 109.5 . . ?
C41 C42A H42F 109.5 . . ?
H42D C42A H42E 109.5 . . ?
H42D C42A H42F 109.5 . . ?
H42E C42A H42F 109.5 . . ?
H72C C72A H72D 108.0 . . ?
Cl3A C72A H72C 109.4 . . ?
Cl3A C72A H72D 109.4 . . ?
Cl4A C72A H72C 109.4 . . ?
Cl4A C72A H72D 109.4 . . ?
Cl4A C72A Cl3A 111.1(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N1 C1 C2 -162.7(4) . . . . ?
Pt1 N1 C4 N2 157.7(4) . . . . ?
Pt1 N1 C4 N3 -24.4(6) . . . . ?
Pt1 N7 N8 Pt2 -32.8(3) . . . . ?
Pt1 N7 N8 C51 156.8(3) . . . . ?
Pt1 N7 C49 C50 -149.2(4) . . . . ?
Pt1 N7 C49 C52 32.9(8) . . . . ?
Pt1 N9 N10 Pt2 -32.5(3) . . . . ?
Pt1 N9 N10 C62 168.6(4) . . . . ?
Pt1 N9 C60 C61 -164.0(4) . . . . ?
Pt1 N9 C60 C63 22.5(9) . . . . ?
Pt1 C6 C7 C8 -175.9(4) . . . . ?
Pt2 N4 C25 C26 176.4(6) . . . . ?
Pt2 N4 C28 N5 -173.4(4) . . . . ?
Pt2 N4 C28 N6 6.9(7) . . . . ?
Pt2 N8 C51 C50 -166.0(4) . . . . ?
Pt2 N8 C51 C56 25.5(10) . . . . ?
Pt2 N8 C51 C56A 19.9(13) . . . . ?
Pt2 N10 C62 C61 -148.8(4) . . . . ?
Pt2 N10 C62 C67 41.9(9) . . . . ?
Pt2 N10 C62 C67A 15.1(11) . . . . ?
Pt2 C30 C31 C32 -161.0(4) . . . . ?
N1 C1 C2 C3 2.6(8) . . . . ?
N3 C5 C6 Pt1 -2.2(7) . . . . ?
N3 C5 C6 C7 -178.0(4) . . . . ?
N3 C5 C10 C9 177.4(5) . . . . ?
N3 C5 C10 C11 -4.3(6) . . . . ?
N4 C25 C26 C27 -1.8(11) . . . . ?
N6 C29 C30 Pt2 -14.4(7) . . . . ?
N6 C29 C30 C31 177.9(4) . . . . ?
N6 C29 C34 C33 -179.2(4) . . . . ?
N6 C29 C34 C35 2.5(5) . . . . ?
N7 N8 C51 C50 0.4(5) . . . . ?
N7 N8 C51 C56 -168.1(8) . . . . ?
N7 N8 C51 C56A -173.6(11) . . . . ?
N7 C49 C50 C51 -0.3(6) . . . . ?
N7 C49 C52 C53 -169.7(5) . . . . ?
N7 C49 C52 C54 71.5(6) . . . . ?
N7 C49 C52 C55 -50.9(7) . . . . ?
N8 N7 C49 C50 0.6(6) . . . . ?
N8 N7 C49 C52 -177.3(5) . . . . ?
N8 C51 C56 C57 -177.1(9) . . . . ?
N8 C51 C56 C58 -60.3(19) . . . . ?
N8 C51 C56 C59 64.5(13) . . . . ?
N8 C51 C56A C58A -32(2) . . . . ?
N8 C51 C56A C57A -159.5(12) . . . . ?
N8 C51 C56A C59A 83.2(16) . . . . ?
N9 N10 C62 C61 1.2(6) . . . . ?
N9 N10 C62 C67 -168.1(6) . . . . ?
N9 N10 C62 C67A 165.0(8) . . . . ?
N9 C60 C61 C62 -2.4(7) . . . . ?
N9 C60 C63 C64 -50.1(7) . . . . ?
N9 C60 C63 C65 70.4(6) . . . . ?
N9 C60 C63 C66 -171.9(5) . . . . ?
N10 N9 C60 C61 3.2(6) . . . . ?
N10 N9 C60 C63 -170.3(4) . . . . ?
N10 C62 C67 C68 -54.2(11) . . . . ?
N10 C62 C67 C69 71.5(11) . . . . ?
N10 C62 C67 C70 -170.9(7) . . . . ?
N10 C62 C67A C70A 22.7(15) . . . . ?
N10 C62 C67A C69A -104.6(13) . . . . ?
N10 C62 C67A C68A 135.8(11) . . . . ?
C1 N1 C4 N2 -9.1(7) . . . . ?
C1 N1 C4 N3 168.8(4) . . . . ?
C1 C2 C3 N2 -6.0(8) . . . . ?
C3 N2 C4 N1 6.0(7) . . . . ?
C3 N2 C4 N3 -171.9(5) . . . . ?
C4 N1 C1 C2 4.5(7) . . . . ?
C4 N2 C3 C2 1.9(8) . . . . ?
C4 N3 C5 C6 36.4(7) . . . . ?
C4 N3 C5 C10 -145.4(4) . . . . ?
C4 N3 C16 C11 145.9(5) . . . . ?
C4 N3 C16 C15 -36.4(7) . . . . ?
C5 N3 C4 N1 -20.2(6) . . . . ?
C5 N3 C4 N2 157.9(4) . . . . ?
C5 N3 C16 C11 -5.7(5) . . . . ?
C5 N3 C16 C15 172.1(5) . . . . ?
C5 C6 C7 C8 -0.5(7) . . . . ?
C5 C10 C11 C12 -177.5(6) . . . . ?
C5 C10 C11 C16 0.7(6) . . . . ?
C6 C5 C10 C9 -4.3(8) . . . . ?
C6 C5 C10 C11 174.0(5) . . . . ?
C6 C7 C8 C9 -2.5(8) . . . . ?
C6 C7 C8 C17 -177.9(5) . . . . ?
C7 C8 C9 C10 2.2(8) . . . . ?
C7 C8 C17 C18 -40.9(7) . . . . ?
C7 C8 C17 C19 77.7(7) . . . . ?
C7 C8 C17 C20 -163.0(6) . . . . ?
C8 C9 C10 C5 1.0(8) . . . . ?
C8 C9 C10 C11 -176.8(6) . . . . ?
C9 C8 C17 C18 143.8(6) . . . . ?
C9 C8 C17 C19 -97.6(6) . . . . ?
C9 C8 C17 C20 21.8(8) . . . . ?
C9 C10 C11 C12 0.5(11) . . . . ?
C9 C10 C11 C16 178.7(6) . . . . ?
C10 C5 C6 Pt1 179.8(4) . . . . ?
C10 C5 C6 C7 4.0(7) . . . . ?
C10 C11 C12 C13 175.7(6) . . . . ?
C10 C11 C16 N3 3.1(6) . . . . ?
C10 C11 C16 C15 -174.9(5) . . . . ?
C11 C12 C13 C14 -0.5(10) . . . . ?
C11 C12 C13 C21 -175.0(7) . . . . ?
C11 C12 C13 C21A 168.1(8) . . . . ?
C12 C11 C16 N3 -178.4(5) . . . . ?
C12 C11 C16 C15 3.6(8) . . . . ?
C12 C13 C14 C15 2.4(9) . . . . ?
C12 C13 C21 C22 55.2(12) . . . . ?
C12 C13 C21 C23 -179.5(9) . . . . ?
C12 C13 C21 C24 -64.0(11) . . . . ?
C12 C13 C21A C24A 130.2(11) . . . . ?
C12 C13 C21A C22A -112.6(11) . . . . ?
C12 C13 C21A C23A 9.5(15) . . . . ?
C13 C14 C15 C16 -1.3(8) . . . . ?
C14 C13 C21 C22 -118.7(10) . . . . ?
C14 C13 C21 C23 6.5(14) . . . . ?
C14 C13 C21 C24 122.0(10) . . . . ?
C14 C13 C21A C24A -60.9(13) . . . . ?
C14 C13 C21A C22A 56.3(12) . . . . ?
C14 C13 C21A C23A 178.3(10) . . . . ?
C14 C15 C16 N3 -179.2(5) . . . . ?
C14 C15 C16 C11 -1.7(8) . . . . ?
C16 N3 C4 N1 -167.3(4) . . . . ?
C16 N3 C4 N2 10.8(6) . . . . ?
C16 N3 C5 C6 -172.0(5) . . . . ?
C16 N3 C5 C10 6.2(5) . . . . ?
C16 C11 C12 C13 -2.4(9) . . . . ?
C17 C8 C9 C10 177.6(5) . . . . ?
C21 C13 C14 C15 176.3(7) . . . . ?
C25 N4 C28 N5 7.9(9) . . . . ?
C25 N4 C28 N6 -171.8(5) . . . . ?
C25 C26 C27 N5 6.3(12) . . . . ?
C27 N5 C28 N4 -3.8(9) . . . . ?
C27 N5 C28 N6 175.9(6) . . . . ?
C28 N4 C25 C26 -4.8(9) . . . . ?
C28 N5 C27 C26 -3.7(11) . . . . ?
C28 N6 C29 C30 -25.9(8) . . . . ?
C28 N6 C29 C34 159.7(5) . . . . ?
C28 N6 C40 C35 -160.8(5) . . . . ?
C28 N6 C40 C39 23.8(9) . . . . ?
C29 N6 C28 N4 29.1(8) . . . . ?
C29 N6 C28 N5 -150.5(5) . . . . ?
C29 N6 C40 C35 0.0(6) . . . . ?
C29 N6 C40 C39 -175.4(5) . . . . ?
C29 C30 C31 C32 5.6(7) . . . . ?
C29 C34 C35 C36 174.0(5) . . . . ?
C29 C34 C35 C40 -2.5(6) . . . . ?
C30 C29 C34 C33 6.3(8) . . . . ?
C30 C29 C34 C35 -171.9(5) . . . . ?
C30 C31 C32 C33 -0.5(7) . . . . ?
C30 C31 C32 C41 176.5(4) . . . . ?
C31 C32 C33 C34 -2.3(7) . . . . ?
C31 C32 C41 C42 2.4(7) . . . . ?
C31 C32 C41 C43 120.3(5) . . . . ?
C31 C32 C41 C44 -120.2(5) . . . . ?
C31 C32 C41 C44A -179.4(13) . . . . ?
C31 C32 C41 C43A 52.3(13) . . . . ?
C31 C32 C41 C42A -63.5(11) . . . . ?
C32 C33 C34 C29 -0.3(7) . . . . ?
C32 C33 C34 C35 177.3(5) . . . . ?
C33 C32 C41 C42 179.3(5) . . . . ?
C33 C32 C41 C43 -62.8(6) . . . . ?
C33 C32 C41 C44 56.7(6) . . . . ?
C33 C32 C41 C44A -2.5(14) . . . . ?
C33 C32 C41 C43A -130.8(13) . . . . ?
C33 C32 C41 C42A 113.4(11) . . . . ?
C33 C34 C35 C36 -3.9(10) . . . . ?
C33 C34 C35 C40 179.6(6) . . . . ?
C34 C29 C30 Pt2 159.1(4) . . . . ?
C34 C29 C30 C31 -8.6(7) . . . . ?
C34 C35 C36 C37 -174.9(5) . . . . ?
C34 C35 C40 N6 1.5(6) . . . . ?
C34 C35 C40 C39 177.4(5) . . . . ?
C35 C36 C37 C38 -1.4(8) . . . . ?
C35 C36 C37 C45 174.8(5) . . . . ?
C35 C36 C37 C45A -167.7(12) . . . . ?
C36 C35 C40 N6 -175.4(4) . . . . ?
C36 C35 C40 C39 0.5(8) . . . . ?
C36 C37 C38 C39 -0.1(9) . . . . ?
C36 C37 C45 C46 -7.1(10) . . . . ?
C36 C37 C45 C47 110.4(8) . . . . ?
C36 C37 C45 C48 -134.3(7) . . . . ?
C36 C37 C45A C48A 48(3) . . . . ?
C36 C37 C45A C46A 169(2) . . . . ?
C36 C37 C45A C47A -69(2) . . . . ?
C37 C38 C39 C40 1.7(9) . . . . ?
C38 C37 C45 C46 169.2(8) . . . . ?
C38 C37 C45 C47 -73.4(8) . . . . ?
C38 C37 C45 C48 42.0(8) . . . . ?
C38 C37 C45A C48A -116(2) . . . . ?
C38 C37 C45A C46A 5(3) . . . . ?
C38 C37 C45A C47A 126.6(19) . . . . ?
C38 C39 C40 N6 173.0(5) . . . . ?
C38 C39 C40 C35 -2.0(8) . . . . ?
C40 N6 C28 N4 -173.1(5) . . . . ?
C40 N6 C28 N5 7.2(8) . . . . ?
C40 N6 C29 C30 172.7(5) . . . . ?
C40 N6 C29 C34 -1.6(5) . . . . ?
C40 C35 C36 C37 1.2(8) . . . . ?
C41 C32 C33 C34 -179.3(4) . . . . ?
C45 C37 C38 C39 -176.5(5) . . . . ?
C49 N7 N8 Pt2 169.8(3) . . . . ?
C49 N7 N8 C51 -0.6(5) . . . . ?
C49 C50 C51 N8 -0.1(6) . . . . ?
C49 C50 C51 C56 166.7(9) . . . . ?
C49 C50 C51 C56A 174.4(10) . . . . ?
C50 C49 C52 C53 12.8(7) . . . . ?
C50 C49 C52 C54 -106.0(6) . . . . ?
C50 C49 C52 C55 131.7(6) . . . . ?
C50 C51 C56 C57 17.6(15) . . . . ?
C50 C51 C56 C58 134.5(16) . . . . ?
C50 C51 C56 C59 -100.8(11) . . . . ?
C50 C51 C56A C58A 154.4(18) . . . . ?
C50 C51 C56A C57A 27.3(19) . . . . ?
C50 C51 C56A C59A -90.0(13) . . . . ?
C52 C49 C50 C51 177.5(5) . . . . ?
C60 N9 N10 Pt2 156.2(3) . . . . ?
C60 N9 N10 C62 -2.7(6) . . . . ?
C60 C61 C62 N10 0.7(7) . . . . ?
C60 C61 C62 C67 169.3(7) . . . . ?
C60 C61 C62 C67A -164.2(8) . . . . ?
C61 C60 C63 C64 137.9(6) . . . . ?
C61 C60 C63 C65 -101.7(7) . . . . ?
C61 C60 C63 C66 16.0(8) . . . . ?
C61 C62 C67 C68 138.8(9) . . . . ?
C61 C62 C67 C69 -95.5(11) . . . . ?
C61 C62 C67 C70 22.1(11) . . . . ?
C61 C62 C67A C70A -175.6(11) . . . . ?
C61 C62 C67A C69A 57.0(14) . . . . ?
C61 C62 C67A C68A -62.5(13) . . . . ?
C63 C60 C61 C62 170.5(6) . . . . ?
C21A C13 C14 C15 -167.7(7) . . . . ?
C45A C37 C38 C39 163.2(15) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.621
_oxdiff_exptl_absorpt_empirical_full_min 0.634
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_20220714_zh_gxmz_hb50_y_0m
_database_code_depnum_ccdc_archive 'CCDC 2285565'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2024-02-21 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2024-01-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H66 N10 Pt2, C H2 Cl2, 3[CH2Cl2]'
_chemical_formula_sum            'C71 H68 Cl2 N10 Pt2'
_chemical_formula_weight         1522.43
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.0889(11)
_cell_length_b                   16.5091(11)
_cell_length_c                   16.9976(11)
_cell_angle_alpha                116.920(2)
_cell_angle_beta                 100.826(2)
_cell_angle_gamma                92.785(2)
_cell_volume                     3664.7(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9998
_cell_measurement_temperature    193.00
_cell_measurement_theta_max      27.31
_cell_measurement_theta_min      2.47
_shelx_estimated_absorpt_T_max   0.650
_shelx_estimated_absorpt_T_min   0.590
_exptl_absorpt_coefficient_mu    3.930
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6057
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1150 before and 0.0695 after correction.
The Ratio of minimum to maximum transmission is 0.8124.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.380
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1508
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0631
_diffrn_reflns_av_unetI/netI     0.0486
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            56449
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.027
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_min         2.118
_diffrn_ambient_temperature      193.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10326
_reflns_number_total             12797
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (1, 2016)'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'SAINT V8.40B (1, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         2.201
_refine_diff_density_min         -1.129
_refine_diff_density_rms         0.102
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     836
_refine_ls_number_reflns         12797
_refine_ls_number_restraints     2114
_refine_ls_R_factor_all          0.0445
_refine_ls_R_factor_gt           0.0343
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0409P)²+0.7636P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0800
_refine_ls_wR_factor_ref         0.0839
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C9-C7 \\sim C9A-C7 \\sim C7-C10A \\sim C7-C10 \\sim C8A-C7 \\sim C8-C7
 with sigma of 0.02
 C33-C31 \\sim C32A-C31 \\sim C32-C31 \\sim C34A-C31 \\sim C34-C31 \\sim
C33A-C31
 with sigma of 0.02
 C8A-C9A \\sim C8A-C10A \\sim C9A-C10A
 with sigma of 0.02
 C32A-C33A \\sim C32A-C34A \\sim C33A-C34A
 with sigma of 0.02
3. Rigid bond restraints
 C7, C10A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 C7, C8A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4. Uiso/Uaniso restraints and constraints
C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6 \\sim C7 \\sim C11 \\sim C12
\\sim C13 \\sim C14 \\sim C15 \\sim C16 \\sim C17 \\sim C18 \\sim C19 \\sim C20
\\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25 \\sim C26 \\sim C27 \\sim C28
\\sim C29 \\sim C30 \\sim C31 \\sim C35 \\sim C36 \\sim C37 \\sim C38 \\sim C39
\\sim C40 \\sim C41 \\sim C42 \\sim C43 \\sim C44 \\sim C45 \\sim C46 \\sim C47
\\sim C48 \\sim C49 \\sim C50 \\sim C51 \\sim C52 \\sim C53 \\sim C54 \\sim C55
\\sim C56 \\sim C57 \\sim C58 \\sim C59 \\sim C60 \\sim C61 \\sim C62 \\sim C63
\\sim C64 \\sim C65 \\sim C66 \\sim C67 \\sim C68 \\sim C69 \\sim C70 \\sim C8
\\sim C9 \\sim C10 \\sim C32 \\sim C33 \\sim C34 \\sim C8A \\sim C9A \\sim C10A
\\sim C32A \\sim C33A \\sim C34A \\sim C71: within 3.8A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 3.8A
Uanis(C32A) \\sim Ueq, Uanis(C33A) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
Uanis(C8A) \\sim Ueq, Uanis(C10A) \\sim Ueq, Uanis(C9A) \\sim Ueq, Uanis(C34A)
\\sim Ueq, Uanis(C33) \\sim Ueq, Uanis(C32) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(C10) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
5. Others
 Sof(C8A)=Sof(H8AA)=Sof(H8AB)=Sof(H8AC)=Sof(C9A)=Sof(H9AA)=Sof(H9AB)=Sof(H9AC)=
 Sof(C10A)=Sof(H10D)=Sof(H10E)=Sof(H10F)=Sof(C32A)=Sof(H32D)=Sof(H32E)=
 Sof(H32F)=Sof(C33A)=Sof(H33D)=Sof(H33E)=Sof(H33F)=Sof(C34A)=Sof(H34D)=
 Sof(H34E)=Sof(H34F)=1-FVAR(1)
 Sof(C8)=Sof(H8A)=Sof(H8B)=Sof(H8C)=Sof(C9)=Sof(H9A)=Sof(H9B)=Sof(H9C)=
 Sof(C10)=Sof(H10A)=Sof(H10B)=Sof(H10C)=Sof(C32)=Sof(H32A)=Sof(H32B)=Sof(H32C)=
 Sof(C33)=Sof(H33A)=Sof(H33B)=Sof(H33C)=Sof(C34)=Sof(H34A)=Sof(H34B)=Sof(H34C)=
 FVAR(1)
6.a Riding coordinates:
 C8A(H8AA,H8AB,H8AC), C9A(H9AA,H9AB,H9AC), C32A(H32D,H32E,H32F)
6.b Secondary CH2 refined with riding coordinates:
 C71(H71A,H71B)
6.c Aromatic/amide H refined with riding coordinates:
 C4(H4), C6(H6), C13(H13), C14(H14), C16(H16), C22(H22), C23(H23), C24(H24),
 C27(H27), C29(H29), C37(H37), C38(H38), C40(H40), C46(H46), C47(H47), C48(H48),
  C49(H49), C50(H50), C51(H51), C56(H56), C57(H57), C58(H58), C59(H59),
 C60(H60), C61(H61), C62(H62), C66(H66), C67(H67), C68(H68), C69(H69)
6.d Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C42(H42A,H42B,
 H42C), C43(H43A,H43B,H43C), C44(H44A,H44B,H44C), C8(H8A,H8B,H8C), C9(H9A,H9B,
 H9C), C10(H10A,H10B,H10C), C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C34(H34A,
 H34B,H34C), C10A(H10D,H10E,H10F), C33A(H33D,H33E,H33F), C34A(H34D,H34E,H34F)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.16706(2) 0.34081(2) 0.74954(2) 0.03105(7) Uani 1 1 d . . . . .
N1 N 0.2278(3) 0.2369(2) 0.6674(3) 0.0319(9) Uani 1 1 d . . . . .
C1 C 0.2191(3) 0.4254(3) 0.7098(3) 0.0321(9) Uani 1 1 d . U . . .
Pt2 Pt 0.28636(2) 0.38654(2) 0.93153(2) 0.03120(7) Uani 1 1 d . . . . .
N2 N 0.2576(3) 0.2989(2) 0.5718(3) 0.0329(9) Uani 1 1 d . . . . .
C2 C 0.2511(3) 0.3918(3) 0.6310(3) 0.0338(10) Uani 1 1 d . U . . .
N3 N 0.2849(3) 0.1524(3) 0.5357(3) 0.0429(11) Uani 1 1 d . . . . .
C3 C 0.2785(4) 0.4467(3) 0.5938(4) 0.0390(10) Uani 1 1 d . U . . .
N4 N 0.3750(3) 0.4778(2) 0.9247(3) 0.0318(9) Uani 1 1 d . . . . .
C4 C 0.2775(4) 0.5406(3) 0.6389(4) 0.0449(11) Uani 1 1 d . U . . .
H4 H 0.296298 0.578318 0.614426 0.054 Uiso 1 1 calc R U . . .
C5 C 0.2492(4) 0.5795(3) 0.7191(4) 0.0424(11) Uani 1 1 d . U . . .
N5 N 0.4746(3) 0.5200(3) 0.8507(3) 0.0404(11) Uani 1 1 d . . . . .
C6 C 0.2219(3) 0.5216(3) 0.7531(4) 0.0389(10) Uani 1 1 d . U . . .
H6 H 0.203946 0.549065 0.809056 0.047 Uiso 1 1 calc R U . . .
N6 N 0.4285(3) 0.3668(2) 0.8046(3) 0.0295(9) Uani 1 1 d . . . . .
C7 C 0.2461(4) 0.6835(3) 0.7697(4) 0.0520(13) Uani 1 1 d D U . . .
N7 N 0.0990(3) 0.4399(3) 0.8247(3) 0.0375(10) Uani 1 1 d . . . . .
N8 N 0.1957(3) 0.4805(3) 0.9701(3) 0.0351(10) Uani 1 1 d . . . . .
N9 N 0.1044(3) 0.2513(3) 0.7895(3) 0.0370(10) Uani 1 1 d . . . . .
N10 N 0.1952(3) 0.2985(3) 0.9389(3) 0.0348(10) Uani 1 1 d . . . . .
C11 C 0.3013(4) 0.3871(3) 0.5095(4) 0.0402(10) Uani 1 1 d . U . . .
C12 C 0.2870(4) 0.2967(3) 0.4959(4) 0.0395(10) Uani 1 1 d . U . . .
C13 C 0.3009(4) 0.2241(3) 0.4171(4) 0.0444(11) Uani 1 1 d . U . . .
H13 H 0.290584 0.162457 0.406729 0.053 Uiso 1 1 calc R U . . .
C14 C 0.3302(4) 0.2444(4) 0.3545(4) 0.0487(12) Uani 1 1 d . U . . .
H14 H 0.338316 0.194980 0.300188 0.058 Uiso 1 1 calc R U . . .
C15 C 0.3483(4) 0.3339(4) 0.3675(4) 0.0477(12) Uani 1 1 d . U . . .
C16 C 0.3324(4) 0.4056(4) 0.4475(4) 0.0479(11) Uani 1 1 d . U . . .
H16 H 0.343276 0.467352 0.458446 0.057 Uiso 1 1 calc R U . . .
C17 C 0.3868(5) 0.3556(4) 0.3008(4) 0.0576(14) Uani 1 1 d . U . . .
C18 C 0.3871(5) 0.2682(4) 0.2139(5) 0.0758(19) Uani 1 1 d . U . . .
H18A H 0.427911 0.230032 0.228607 0.114 Uiso 1 1 calc R U . . .
H18B H 0.408597 0.284706 0.171355 0.114 Uiso 1 1 calc R U . . .
H18C H 0.325121 0.233833 0.186100 0.114 Uiso 1 1 calc R U . . .
C19 C 0.3286(5) 0.4188(5) 0.2745(5) 0.0725(18) Uani 1 1 d . U . . .
H19A H 0.265576 0.387424 0.245364 0.109 Uiso 1 1 calc R U . . .
H19B H 0.354215 0.432682 0.232300 0.109 Uiso 1 1 calc R U . . .
H19C H 0.329274 0.476199 0.329259 0.109 Uiso 1 1 calc R U . . .
C20 C 0.4847(4) 0.4061(4) 0.3475(5) 0.0650(16) Uani 1 1 d . U . . .
H20A H 0.484159 0.464120 0.401000 0.098 Uiso 1 1 calc R U . . .
H20B H 0.511257 0.418764 0.305075 0.098 Uiso 1 1 calc R U . . .
H20C H 0.521330 0.367610 0.366150 0.098 Uiso 1 1 calc R U . . .
C21 C 0.2565(3) 0.2275(3) 0.5930(3) 0.0343(10) Uani 1 1 d . U . . .
C22 C 0.2896(4) 0.0838(3) 0.5550(4) 0.0423(12) Uani 1 1 d . U . . .
H22 H 0.309233 0.029765 0.514691 0.051 Uiso 1 1 calc R U . . .
C23 C 0.2673(3) 0.0868(3) 0.6309(4) 0.0381(11) Uani 1 1 d . U . . .
H23 H 0.272615 0.037178 0.644512 0.046 Uiso 1 1 calc R U . . .
C24 C 0.2370(3) 0.1646(3) 0.6856(4) 0.0362(10) Uani 1 1 d . U . . .
H24 H 0.221669 0.168821 0.738938 0.043 Uiso 1 1 calc R U . . .
C25 C 0.4190(3) 0.2952(3) 0.8288(3) 0.0309(9) Uani 1 1 d . U . . .
C26 C 0.3675(3) 0.2916(3) 0.8870(3) 0.0325(9) Uani 1 1 d . U . . .
C27 C 0.3712(3) 0.2140(3) 0.8992(3) 0.0351(10) Uani 1 1 d . U . . .
H27 H 0.338296 0.208185 0.939351 0.042 Uiso 1 1 calc R U . . .
C28 C 0.4211(3) 0.1434(3) 0.8554(4) 0.0382(10) Uani 1 1 d . U . . .
C29 C 0.4665(3) 0.1480(3) 0.7941(3) 0.0348(10) Uani 1 1 d . U . . .
H29 H 0.498652 0.099999 0.762540 0.042 Uiso 1 1 calc R U . . .
C30 C 0.4646(3) 0.2246(3) 0.7792(3) 0.0321(9) Uani 1 1 d . U . . .
C31 C 0.4202(4) 0.0611(3) 0.8763(4) 0.0490(12) Uani 1 1 d D U . . .
C35 C 0.4970(3) 0.2486(3) 0.7155(3) 0.0319(9) Uani 1 1 d . U . . .
C36 C 0.4740(3) 0.3353(3) 0.7319(3) 0.0317(9) Uani 1 1 d . U . . .
C37 C 0.4888(3) 0.3732(3) 0.6780(4) 0.0359(10) Uani 1 1 d . U . . .
H37 H 0.473272 0.432117 0.689919 0.043 Uiso 1 1 calc R U . . .
C38 C 0.5268(3) 0.3237(3) 0.6058(4) 0.0369(10) Uani 1 1 d . U . . .
H38 H 0.536509 0.349541 0.567659 0.044 Uiso 1 1 calc R U . . .
C39 C 0.5517(3) 0.2368(3) 0.5860(4) 0.0362(10) Uani 1 1 d . U . . .
C40 C 0.5360(3) 0.2005(3) 0.6428(3) 0.0331(10) Uani 1 1 d . U . . .
H40 H 0.552084 0.141975 0.631564 0.040 Uiso 1 1 calc R U . . .
C41 C 0.5936(4) 0.1822(3) 0.5058(4) 0.0402(11) Uani 1 1 d . U . . .
C42 C 0.6916(4) 0.1704(4) 0.5413(4) 0.0568(15) Uani 1 1 d . U . . .
H42A H 0.728817 0.231005 0.580024 0.085 Uiso 1 1 calc R U . . .
H42B H 0.718342 0.135441 0.489752 0.085 Uiso 1 1 calc R U . . .
H42C H 0.689736 0.137242 0.576482 0.085 Uiso 1 1 calc R U . . .
C43 C 0.5356(4) 0.0879(4) 0.4457(4) 0.0598(16) Uani 1 1 d . U . . .
H43A H 0.532577 0.055495 0.481516 0.090 Uiso 1 1 calc R U . . .
H43B H 0.563079 0.052209 0.395013 0.090 Uiso 1 1 calc R U . . .
H43C H 0.473836 0.095337 0.422074 0.090 Uiso 1 1 calc R U . . .
C44 C 0.5995(4) 0.2300(4) 0.4479(4) 0.0591(15) Uani 1 1 d . U . . .
H44A H 0.538587 0.241209 0.426767 0.089 Uiso 1 1 calc R U . . .
H44B H 0.623113 0.190770 0.395393 0.089 Uiso 1 1 calc R U . . .
H44C H 0.640571 0.288687 0.484208 0.089 Uiso 1 1 calc R U . . .
C45 C 0.4262(3) 0.4582(3) 0.8618(3) 0.0331(9) Uani 1 1 d . U . . .
C46 C 0.3805(3) 0.5682(3) 0.9836(4) 0.0366(11) Uani 1 1 d . U . . .
H46 H 0.348725 0.585075 1.030630 0.044 Uiso 1 1 calc R U . . .
C47 C 0.4298(4) 0.6352(3) 0.9777(4) 0.0421(12) Uani 1 1 d . U . . .
H47 H 0.432729 0.698288 1.019071 0.051 Uiso 1 1 calc R U . . .
C48 C 0.4753(4) 0.6078(3) 0.9095(4) 0.0441(12) Uani 1 1 d . U . . .
H48 H 0.509318 0.653890 0.903628 0.053 Uiso 1 1 calc R U . . .
C49 C 0.0249(4) 0.4604(4) 0.7824(4) 0.0450(12) Uani 1 1 d . U . . .
H49 H 0.006189 0.427004 0.718062 0.054 Uiso 1 1 calc R U . . .
C50 C -0.0247(4) 0.5271(4) 0.8277(4) 0.0489(13) Uani 1 1 d . U . . .
H50 H -0.075823 0.538556 0.794198 0.059 Uiso 1 1 calc R U . . .
C51 C -0.0013(4) 0.5772(4) 0.9207(4) 0.0479(12) Uani 1 1 d . U . . .
H51 H -0.035639 0.623002 0.952077 0.057 Uiso 1 1 calc R U . . .
C52 C 0.0730(3) 0.5592(3) 0.9667(4) 0.0384(10) Uani 1 1 d . U . . .
C53 C 0.1235(3) 0.4894(3) 0.9158(4) 0.0359(10) Uani 1 1 d . U . . .
C54 C 0.1934(3) 0.5421(3) 1.0592(4) 0.0377(10) Uani 1 1 d . U . . .
C55 C 0.1186(3) 0.5927(3) 1.0598(4) 0.0420(11) Uani 1 1 d . U . . .
C56 C 0.1047(4) 0.6558(4) 1.1427(4) 0.0517(13) Uani 1 1 d . U . . .
H56 H 0.054753 0.688955 1.144919 0.062 Uiso 1 1 calc R U . . .
C57 C 0.1629(4) 0.6701(4) 1.2212(4) 0.0565(15) Uani 1 1 d . U . . .
H57 H 0.152795 0.713679 1.277695 0.068 Uiso 1 1 calc R U . . .
C58 C 0.2368(4) 0.6224(4) 1.2207(4) 0.0548(14) Uani 1 1 d . U . . .
H58 H 0.276604 0.634331 1.276468 0.066 Uiso 1 1 calc R U . . .
C59 C 0.2524(4) 0.5579(4) 1.1394(4) 0.0449(12) Uani 1 1 d . U . . .
H59 H 0.302563 0.525057 1.138576 0.054 Uiso 1 1 calc R U . . .
C60 C 0.2032(4) 0.2872(4) 1.0141(4) 0.0445(12) Uani 1 1 d . U . . .
H60 H 0.251587 0.324841 1.065181 0.053 Uiso 1 1 calc R U . . .
C61 C 0.1462(4) 0.2254(4) 1.0208(4) 0.0507(13) Uani 1 1 d . U . . .
H61 H 0.154652 0.220784 1.075389 0.061 Uiso 1 1 calc R U . . .
C62 C 0.0748(4) 0.1687(4) 0.9460(4) 0.0502(12) Uani 1 1 d . U . . .
H62 H 0.035014 0.124219 0.948789 0.060 Uiso 1 1 calc R U . . .
C63 C 0.0630(4) 0.1780(3) 0.8687(4) 0.0428(11) Uani 1 1 d . U . . .
C64 C 0.1252(3) 0.2474(3) 0.8684(4) 0.0370(10) Uani 1 1 d . U . . .
C65 C 0.0316(4) 0.1821(4) 0.7351(4) 0.0453(12) Uani 1 1 d . U . . .
C66 C -0.0126(4) 0.1566(4) 0.6468(4) 0.0534(13) Uani 1 1 d . U . . .
H66 H 0.005181 0.188325 0.616189 0.064 Uiso 1 1 calc R U . . .
C67 C -0.0836(4) 0.0837(4) 0.6038(5) 0.0633(15) Uani 1 1 d . U . . .
H67 H -0.113438 0.064216 0.542379 0.076 Uiso 1 1 calc R U . . .
C68 C -0.1124(4) 0.0380(4) 0.6485(5) 0.0675(16) Uani 1 1 d . U . . .
H68 H -0.162150 -0.011019 0.617826 0.081 Uiso 1 1 calc R U . . .
C69 C -0.0687(4) 0.0638(4) 0.7372(5) 0.0603(14) Uani 1 1 d . U . . .
H69 H -0.088004 0.032733 0.767780 0.072 Uiso 1 1 calc R U . . .
C70 C 0.0033(4) 0.1355(4) 0.7809(4) 0.0470(12) Uani 1 1 d . U . . .
C8 C 0.2148(7) 0.7138(5) 0.8568(6) 0.068(2) Uani 0.729(6) 1 d D U P A 1
H8A H 0.153368 0.681415 0.843463 0.101 Uiso 0.729(6) 1 calc R U P A 1
H8B H 0.213816 0.780195 0.884955 0.101 Uiso 0.729(6) 1 calc R U P A 1
H8C H 0.257012 0.699392 0.898398 0.101 Uiso 0.729(6) 1 calc R U P A 1
C9 C 0.1860(7) 0.7106(6) 0.7060(7) 0.075(3) Uani 0.729(6) 1 d D U P A 1
H9A H 0.209302 0.692947 0.651320 0.112 Uiso 0.729(6) 1 calc R U P A 1
H9B H 0.186592 0.777271 0.736558 0.112 Uiso 0.729(6) 1 calc R U P A 1
H9C H 0.123411 0.679161 0.689129 0.112 Uiso 0.729(6) 1 calc R U P A 1
C10 C 0.3432(6) 0.7359(5) 0.7924(7) 0.072(2) Uani 0.729(6) 1 d D U P A 1
H10A H 0.385939 0.718074 0.830581 0.107 Uiso 0.729(6) 1 calc R U P A 1
H10B H 0.342358 0.802269 0.824861 0.107 Uiso 0.729(6) 1 calc R U P A 1
H10C H 0.362500 0.720588 0.735972 0.107 Uiso 0.729(6) 1 calc R U P A 1
C32 C 0.4729(7) -0.0110(5) 0.8243(7) 0.057(2) Uani 0.729(6) 1 d D U P A 1
H32A H 0.445423 -0.037652 0.759199 0.086 Uiso 0.729(6) 1 calc R U P A 1
H32B H 0.471558 -0.059379 0.842660 0.086 Uiso 0.729(6) 1 calc R U P A 1
H32C H 0.536267 0.016689 0.837143 0.086 Uiso 0.729(6) 1 calc R U P A 1
C33 C 0.4563(8) 0.0990(6) 0.9779(6) 0.071(2) Uani 0.729(6) 1 d D U P A 1
H33A H 0.520870 0.125210 0.994941 0.106 Uiso 0.729(6) 1 calc R U P A 1
H33B H 0.449813 0.049323 0.993876 0.106 Uiso 0.729(6) 1 calc R U P A 1
H33C H 0.421467 0.146916 1.010319 0.106 Uiso 0.729(6) 1 calc R U P A 1
C34 C 0.3217(6) 0.0151(6) 0.8547(8) 0.077(2) Uani 0.729(6) 1 d D U P A 1
H34A H 0.286543 0.060259 0.890733 0.115 Uiso 0.729(6) 1 calc R U P A 1
H34B H 0.321768 -0.035739 0.869565 0.115 Uiso 0.729(6) 1 calc R U P A 1
H34C H 0.293943 -0.008643 0.789942 0.115 Uiso 0.729(6) 1 calc R U P A 1
C8A C 0.3187(13) 0.7302(14) 0.8565(12) 0.069(4) Uani 0.271(6) 1 d D U P A 2
H8AA H 0.287630 0.737015 0.904378 0.103 Uiso 0.271(6) 1 d R U P A 2
H8AB H 0.349560 0.790415 0.870568 0.103 Uiso 0.271(6) 1 d R U P A 2
H8AC H 0.363840 0.688665 0.852838 0.103 Uiso 0.271(6) 1 d R U P A 2
C9A C 0.1538(12) 0.7008(16) 0.7953(17) 0.075(4) Uani 0.271(6) 1 d D U P A 2
H9AA H 0.113502 0.690470 0.738117 0.113 Uiso 0.271(6) 1 d R U P A 2
H9AB H 0.155782 0.764150 0.842017 0.113 Uiso 0.271(6) 1 d R U P A 2
H9AC H 0.130412 0.658050 0.814617 0.113 Uiso 0.271(6) 1 d R U P A 2
C10A C 0.2590(17) 0.7304(15) 0.7131(15) 0.066(4) Uani 0.271(6) 1 d D U P A 2
H10D H 0.324344 0.745795 0.719326 0.098 Uiso 0.271(6) 1 calc R U P A 2
H10E H 0.231318 0.786761 0.734024 0.098 Uiso 0.271(6) 1 calc R U P A 2
H10F H 0.229629 0.688966 0.649175 0.098 Uiso 0.271(6) 1 calc R U P A 2
C32A C 0.5034(12) 0.0141(18) 0.8586(16) 0.059(4) Uani 0.271(6) 1 d D U P A 2
H32D H 0.499423 -0.015594 0.793107 0.088 Uiso 0.271(6) 1 d R U P A 2
H32E H 0.499033 -0.032974 0.878317 0.088 Uiso 0.271(6) 1 d R U P A 2
H32F H 0.561843 0.054996 0.890977 0.088 Uiso 0.271(6) 1 d R U P A 2
C33A C 0.4002(14) 0.0758(16) 0.9642(11) 0.053(4) Uani 0.271(6) 1 d D U P A 2
H33D H 0.426863 0.031453 0.981350 0.080 Uiso 0.271(6) 1 calc R U P A 2
H33E H 0.333971 0.067193 0.957468 0.080 Uiso 0.271(6) 1 calc R U P A 2
H33F H 0.426664 0.138380 1.011466 0.080 Uiso 0.271(6) 1 calc R U P A 2
C34A C 0.3364(12) -0.0085(14) 0.8000(13) 0.063(4) Uani 0.271(6) 1 d D U P A 2
H34D H 0.342361 -0.015806 0.740828 0.095 Uiso 0.271(6) 1 calc R U P A 2
H34E H 0.279590 0.015426 0.812547 0.095 Uiso 0.271(6) 1 calc R U P A 2
H34F H 0.335183 -0.068146 0.799423 0.095 Uiso 0.271(6) 1 calc R U P A 2
Cl1 Cl 0.67816(13) 0.04225(13) 0.72267(16) 0.0902(6) Uani 1 1 d . . . . .
Cl2 Cl 0.7375(3) 0.1911(2) 0.9057(2) 0.1685(14) Uani 1 1 d . . . . .
C71 C 0.7268(6) 0.1568(5) 0.7941(6) 0.093(3) Uani 1 1 d . . . . .
H71A H 0.788050 0.166392 0.783797 0.112 Uiso 1 1 calc R U . . .
H71B H 0.688932 0.196305 0.777088 0.112 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 2.048(4) . ?
Pt1 C1 1.993(4) . ?
Pt1 Pt2 3.0067(3) . ?
Pt1 N7 2.031(4) . ?
Pt1 N9 2.134(4) . ?
N1 C21 1.358(6) . ?
N1 C24 1.371(6) . ?
C1 C2 1.390(7) . ?
C1 C6 1.411(6) . ?
Pt2 N4 2.024(4) . ?
Pt2 N8 2.081(4) . ?
Pt2 N10 2.014(4) . ?
Pt2 C26 1.997(4) . ?
N2 C2 1.424(6) . ?
N2 C12 1.428(6) . ?
N2 C21 1.379(6) . ?
C2 C3 1.404(7) . ?
N3 C21 1.336(6) . ?
N3 C22 1.316(6) . ?
C3 C4 1.386(7) . ?
C3 C11 1.443(7) . ?
N4 C45 1.366(6) . ?
N4 C46 1.356(6) . ?
C4 H4 0.9500 . ?
C4 C5 1.381(7) . ?
C5 C6 1.403(7) . ?
C5 C7 1.542(7) . ?
N5 C45 1.328(6) . ?
N5 C48 1.335(6) . ?
C6 H6 0.9500 . ?
N6 C25 1.427(5) . ?
N6 C36 1.429(6) . ?
N6 C45 1.383(6) . ?
C7 C8 1.510(9) . ?
C7 C9 1.516(8) . ?
C7 C10 1.551(9) . ?
C7 C8A 1.501(14) . ?
C7 C9A 1.538(14) . ?
C7 C10A 1.514(13) . ?
N7 C49 1.356(7) . ?
N7 C53 1.346(7) . ?
N8 C53 1.348(7) . ?
N8 C54 1.400(6) . ?
N9 C64 1.350(7) . ?
N9 C65 1.381(7) . ?
N10 C60 1.357(7) . ?
N10 C64 1.336(7) . ?
C11 C12 1.402(6) . ?
C11 C16 1.373(7) . ?
C12 C13 1.396(7) . ?
C13 H13 0.9500 . ?
C13 C14 1.388(7) . ?
C14 H14 0.9500 . ?
C14 C15 1.397(7) . ?
C15 C16 1.414(7) . ?
C15 C17 1.531(8) . ?
C16 H16 0.9500 . ?
C17 C18 1.529(8) . ?
C17 C19 1.557(8) . ?
C17 C20 1.532(9) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C22 H22 0.9500 . ?
C22 C23 1.373(7) . ?
C23 H23 0.9500 . ?
C23 C24 1.362(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.388(7) . ?
C25 C30 1.395(6) . ?
C26 C27 1.389(6) . ?
C27 H27 0.9500 . ?
C27 C28 1.412(6) . ?
C28 C29 1.376(7) . ?
C28 C31 1.553(6) . ?
C29 H29 0.9500 . ?
C29 C30 1.399(6) . ?
C30 C35 1.461(7) . ?
C31 C32 1.494(8) . ?
C31 C33 1.518(9) . ?
C31 C34 1.533(9) . ?
C31 C32A 1.515(14) . ?
C31 C33A 1.494(13) . ?
C31 C34A 1.578(14) . ?
C35 C36 1.404(6) . ?
C35 C40 1.391(6) . ?
C36 C37 1.364(7) . ?
C37 H37 0.9500 . ?
C37 C38 1.381(7) . ?
C38 H38 0.9500 . ?
C38 C39 1.405(6) . ?
C39 C40 1.394(7) . ?
C39 C41 1.529(7) . ?
C40 H40 0.9500 . ?
C41 C42 1.545(8) . ?
C41 C43 1.525(7) . ?
C41 C44 1.526(7) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C46 H46 0.9500 . ?
C46 C47 1.354(7) . ?
C47 H47 0.9500 . ?
C47 C48 1.369(7) . ?
C48 H48 0.9500 . ?
C49 H49 0.9500 . ?
C49 C50 1.376(7) . ?
C50 H50 0.9500 . ?
C50 C51 1.373(8) . ?
C51 H51 0.9500 . ?
C51 C52 1.367(8) . ?
C52 C53 1.445(6) . ?
C52 C55 1.430(8) . ?
C54 C55 1.435(7) . ?
C54 C59 1.385(8) . ?
C55 C56 1.385(7) . ?
C56 H56 0.9500 . ?
C56 C57 1.364(9) . ?
C57 H57 0.9500 . ?
C57 C58 1.395(8) . ?
C58 H58 0.9500 . ?
C58 C59 1.384(7) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C60 C61 1.361(7) . ?
C61 H61 0.9500 . ?
C61 C62 1.401(8) . ?
C62 H62 0.9500 . ?
C62 C63 1.370(8) . ?
C63 C64 1.449(7) . ?
C63 C70 1.420(8) . ?
C65 C66 1.378(8) . ?
C65 C70 1.420(8) . ?
C66 H66 0.9500 . ?
C66 C67 1.384(8) . ?
C67 H67 0.9500 . ?
C67 C68 1.394(9) . ?
C68 H68 0.9500 . ?
C68 C69 1.380(9) . ?
C69 H69 0.9500 . ?
C69 C70 1.382(8) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C8A H8AA 0.9799 . ?
C8A H8AB 0.9801 . ?
C8A H8AC 0.9800 . ?
C9A H9AA 0.9799 . ?
C9A H9AB 0.9799 . ?
C9A H9AC 0.9799 . ?
C10A H10D 0.9800 . ?
C10A H10E 0.9800 . ?
C10A H10F 0.9800 . ?
C32A H32D 0.9799 . ?
C32A H32E 0.9799 . ?
C32A H32F 0.9799 . ?
C33A H33D 0.9800 . ?
C33A H33E 0.9800 . ?
C33A H33F 0.9800 . ?
C34A H34D 0.9800 . ?
C34A H34E 0.9800 . ?
C34A H34F 0.9800 . ?
Cl1 C71 1.744(8) . ?
Cl2 C71 1.689(9) . ?
C71 H71A 0.9900 . ?
C71 H71B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 Pt2 99.64(11) . . ?
N1 Pt1 N9 90.85(15) . . ?
C1 Pt1 N1 90.64(17) . . ?
C1 Pt1 Pt2 106.74(15) . . ?
C1 Pt1 N7 90.09(17) . . ?
C1 Pt1 N9 177.04(17) . . ?
N7 Pt1 N1 176.21(16) . . ?
N7 Pt1 Pt2 83.70(13) . . ?
N7 Pt1 N9 88.26(15) . . ?
N9 Pt1 Pt2 75.52(12) . . ?
C21 N1 Pt1 128.3(3) . . ?
C21 N1 C24 114.6(4) . . ?
C24 N1 Pt1 117.0(3) . . ?
C2 C1 Pt1 121.2(3) . . ?
C2 C1 C6 113.8(4) . . ?
C6 C1 Pt1 124.9(4) . . ?
N4 Pt2 Pt1 91.87(12) . . ?
N4 Pt2 N8 91.77(15) . . ?
N8 Pt2 Pt1 79.18(12) . . ?
N10 Pt2 Pt1 87.55(13) . . ?
N10 Pt2 N4 178.16(14) . . ?
N10 Pt2 N8 86.41(15) . . ?
C26 Pt2 Pt1 97.38(15) . . ?
C26 Pt2 N4 89.64(17) . . ?
C26 Pt2 N8 176.32(18) . . ?
C26 Pt2 N10 92.16(17) . . ?
C2 N2 C12 107.9(4) . . ?
C21 N2 C2 125.9(4) . . ?
C21 N2 C12 124.6(4) . . ?
C1 C2 N2 127.9(4) . . ?
C1 C2 C3 123.8(4) . . ?
C3 C2 N2 108.2(4) . . ?
C22 N3 C21 117.5(5) . . ?
C2 C3 C11 107.8(4) . . ?
C4 C3 C2 119.3(5) . . ?
C4 C3 C11 132.9(5) . . ?
C45 N4 Pt2 126.2(3) . . ?
C46 N4 Pt2 117.9(3) . . ?
C46 N4 C45 115.7(4) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 C3 120.3(5) . . ?
C5 C4 H4 119.9 . . ?
C4 C5 C6 118.2(4) . . ?
C4 C5 C7 121.2(5) . . ?
C6 C5 C7 120.6(5) . . ?
C45 N5 C48 115.8(4) . . ?
C1 C6 H6 117.7 . . ?
C5 C6 C1 124.5(5) . . ?
C5 C6 H6 117.7 . . ?
C25 N6 C36 107.3(3) . . ?
C45 N6 C25 124.0(4) . . ?
C45 N6 C36 124.6(4) . . ?
C5 C7 C10 108.5(5) . . ?
C8 C7 C5 113.7(5) . . ?
C8 C7 C9 110.9(6) . . ?
C8 C7 C10 108.5(7) . . ?
C9 C7 C5 109.0(5) . . ?
C9 C7 C10 105.9(6) . . ?
C8A C7 C5 111.2(9) . . ?
C8A C7 C9A 106.9(10) . . ?
C8A C7 C10A 107.9(10) . . ?
C9A C7 C5 110.4(10) . . ?
C10A C7 C5 112.3(10) . . ?
C10A C7 C9A 107.9(10) . . ?
C49 N7 Pt1 119.5(4) . . ?
C53 N7 Pt1 124.2(3) . . ?
C53 N7 C49 116.3(4) . . ?
C53 N8 Pt2 127.4(3) . . ?
C53 N8 C54 106.3(4) . . ?
C54 N8 Pt2 126.1(3) . . ?
C64 N9 Pt1 129.8(3) . . ?
C64 N9 C65 105.6(4) . . ?
C65 N9 Pt1 124.7(4) . . ?
C60 N10 Pt2 121.8(4) . . ?
C64 N10 Pt2 120.6(3) . . ?
C64 N10 C60 117.6(4) . . ?
C12 C11 C3 108.0(4) . . ?
C16 C11 C3 131.5(5) . . ?
C16 C11 C12 120.5(5) . . ?
C11 C12 N2 108.1(4) . . ?
C13 C12 N2 131.9(4) . . ?
C13 C12 C11 120.1(5) . . ?
C12 C13 H13 120.9 . . ?
C14 C13 C12 118.3(5) . . ?
C14 C13 H13 120.9 . . ?
C13 C14 H14 118.4 . . ?
C13 C14 C15 123.1(5) . . ?
C15 C14 H14 118.4 . . ?
C14 C15 C16 117.0(5) . . ?
C14 C15 C17 122.5(5) . . ?
C16 C15 C17 120.5(5) . . ?
C11 C16 C15 121.0(5) . . ?
C11 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C15 C17 C19 110.3(5) . . ?
C15 C17 C20 108.3(5) . . ?
C18 C17 C15 111.6(5) . . ?
C18 C17 C19 108.4(6) . . ?
C18 C17 C20 109.4(5) . . ?
C20 C17 C19 108.9(5) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N1 C21 N2 120.0(4) . . ?
N3 C21 N1 125.1(4) . . ?
N3 C21 N2 115.0(4) . . ?
N3 C22 H22 118.5 . . ?
N3 C22 C23 123.0(5) . . ?
C23 C22 H22 118.5 . . ?
C22 C23 H23 121.7 . . ?
C24 C23 C22 116.6(5) . . ?
C24 C23 H23 121.7 . . ?
N1 C24 H24 118.5 . . ?
C23 C24 N1 123.1(5) . . ?
C23 C24 H24 118.5 . . ?
C26 C25 N6 126.2(4) . . ?
C26 C25 C30 124.5(4) . . ?
C30 C25 N6 109.1(4) . . ?
C25 C26 Pt2 118.4(3) . . ?
C25 C26 C27 114.1(4) . . ?
C27 C26 Pt2 127.0(4) . . ?
C26 C27 H27 118.2 . . ?
C26 C27 C28 123.7(5) . . ?
C28 C27 H27 118.2 . . ?
C27 C28 C31 118.2(4) . . ?
C29 C28 C27 119.6(4) . . ?
C29 C28 C31 122.3(4) . . ?
C28 C29 H29 120.5 . . ?
C28 C29 C30 119.0(4) . . ?
C30 C29 H29 120.5 . . ?
C25 C30 C29 118.9(4) . . ?
C25 C30 C35 107.2(4) . . ?
C29 C30 C35 133.8(4) . . ?
C28 C31 C34A 101.8(10) . . ?
C32 C31 C28 113.8(5) . . ?
C32 C31 C33 111.1(6) . . ?
C32 C31 C34 107.9(6) . . ?
C33 C31 C28 107.8(5) . . ?
C33 C31 C34 105.9(7) . . ?
C34 C31 C28 110.1(5) . . ?
C32A C31 C28 111.6(12) . . ?
C32A C31 C34A 106.1(10) . . ?
C33A C31 C28 118.0(10) . . ?
C33A C31 C32A 112.2(11) . . ?
C33A C31 C34A 105.6(10) . . ?
C36 C35 C30 107.7(4) . . ?
C40 C35 C30 133.0(4) . . ?
C40 C35 C36 119.1(4) . . ?
C35 C36 N6 108.4(4) . . ?
C37 C36 N6 129.8(4) . . ?
C37 C36 C35 121.6(4) . . ?
C36 C37 H37 120.9 . . ?
C36 C37 C38 118.2(4) . . ?
C38 C37 H37 120.9 . . ?
C37 C38 H38 118.5 . . ?
C37 C38 C39 123.0(5) . . ?
C39 C38 H38 118.5 . . ?
C38 C39 C41 122.8(4) . . ?
C40 C39 C38 117.1(4) . . ?
C40 C39 C41 120.1(4) . . ?
C35 C40 C39 121.0(4) . . ?
C35 C40 H40 119.5 . . ?
C39 C40 H40 119.5 . . ?
C39 C41 C42 109.6(5) . . ?
C43 C41 C39 109.3(4) . . ?
C43 C41 C42 109.5(4) . . ?
C43 C41 C44 108.4(5) . . ?
C44 C41 C39 112.4(4) . . ?
C44 C41 C42 107.6(5) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N4 C45 N6 118.0(4) . . ?
N5 C45 N4 125.3(4) . . ?
N5 C45 N6 116.7(4) . . ?
N4 C46 H46 118.9 . . ?
C47 C46 N4 122.3(5) . . ?
C47 C46 H46 118.9 . . ?
C46 C47 H47 121.5 . . ?
C46 C47 C48 117.0(5) . . ?
C48 C47 H47 121.5 . . ?
N5 C48 C47 123.8(5) . . ?
N5 C48 H48 118.1 . . ?
C47 C48 H48 118.1 . . ?
N7 C49 H49 118.3 . . ?
N7 C49 C50 123.5(6) . . ?
C50 C49 H49 118.3 . . ?
C49 C50 H50 119.6 . . ?
C51 C50 C49 120.9(5) . . ?
C51 C50 H50 119.6 . . ?
C50 C51 H51 121.0 . . ?
C52 C51 C50 118.0(5) . . ?
C52 C51 H51 121.0 . . ?
C51 C52 C53 118.9(5) . . ?
C51 C52 C55 136.1(5) . . ?
C55 C52 C53 105.0(4) . . ?
N7 C53 N8 125.4(4) . . ?
N7 C53 C52 122.4(5) . . ?
N8 C53 C52 112.2(5) . . ?
N8 C54 C55 110.5(5) . . ?
C59 C54 N8 128.4(4) . . ?
C59 C54 C55 121.1(5) . . ?
C52 C55 C54 105.9(4) . . ?
C56 C55 C52 135.6(5) . . ?
C56 C55 C54 118.4(5) . . ?
C55 C56 H56 120.0 . . ?
C57 C56 C55 119.9(5) . . ?
C57 C56 H56 120.0 . . ?
C56 C57 H57 119.1 . . ?
C56 C57 C58 121.7(5) . . ?
C58 C57 H57 119.1 . . ?
C57 C58 H58 119.9 . . ?
C59 C58 C57 120.3(6) . . ?
C59 C58 H58 119.9 . . ?
C54 C59 H59 120.7 . . ?
C58 C59 C54 118.6(5) . . ?
C58 C59 H59 120.7 . . ?
N10 C60 H60 118.0 . . ?
N10 C60 C61 124.1(6) . . ?
C61 C60 H60 118.0 . . ?
C60 C61 H61 120.6 . . ?
C60 C61 C62 118.9(6) . . ?
C62 C61 H61 120.6 . . ?
C61 C62 H62 120.3 . . ?
C63 C62 C61 119.4(5) . . ?
C63 C62 H62 120.3 . . ?
C62 C63 C64 118.0(5) . . ?
C62 C63 C70 137.2(5) . . ?
C70 C63 C64 104.7(5) . . ?
N9 C64 C63 112.0(5) . . ?
N10 C64 N9 126.1(5) . . ?
N10 C64 C63 121.9(5) . . ?
N9 C65 C70 111.8(5) . . ?
C66 C65 N9 127.7(5) . . ?
C66 C65 C70 120.5(5) . . ?
C65 C66 H66 120.8 . . ?
C65 C66 C67 118.4(6) . . ?
C67 C66 H66 120.8 . . ?
C66 C67 H67 119.2 . . ?
C66 C67 C68 121.6(7) . . ?
C68 C67 H67 119.2 . . ?
C67 C68 H68 119.9 . . ?
C69 C68 C67 120.2(6) . . ?
C69 C68 H68 119.9 . . ?
C68 C69 H69 120.4 . . ?
C68 C69 C70 119.2(6) . . ?
C70 C69 H69 120.4 . . ?
C65 C70 C63 105.8(5) . . ?
C69 C70 C63 134.0(6) . . ?
C69 C70 C65 120.2(6) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C7 C8A H8AA 105.3 . . ?
C7 C8A H8AB 115.5 . . ?
C7 C8A H8AC 107.5 . . ?
H8AA C8A H8AB 109.5 . . ?
H8AA C8A H8AC 109.5 . . ?
H8AB C8A H8AC 109.4 . . ?
C7 C9A H9AA 102.5 . . ?
C7 C9A H9AB 112.2 . . ?
C7 C9A H9AC 113.5 . . ?
H9AA C9A H9AB 109.5 . . ?
H9AA C9A H9AC 109.5 . . ?
H9AB C9A H9AC 109.5 . . ?
C7 C10A H10D 109.5 . . ?
C7 C10A H10E 109.5 . . ?
C7 C10A H10F 109.5 . . ?
H10D C10A H10E 109.5 . . ?
H10D C10A H10F 109.5 . . ?
H10E C10A H10F 109.5 . . ?
C31 C32A H32D 108.4 . . ?
C31 C32A H32E 105.4 . . ?
C31 C32A H32F 114.5 . . ?
H32D C32A H32E 109.4 . . ?
H32D C32A H32F 109.5 . . ?
H32E C32A H32F 109.5 . . ?
C31 C33A H33D 109.5 . . ?
C31 C33A H33E 109.5 . . ?
C31 C33A H33F 109.5 . . ?
H33D C33A H33E 109.5 . . ?
H33D C33A H33F 109.5 . . ?
H33E C33A H33F 109.5 . . ?
C31 C34A H34D 109.5 . . ?
C31 C34A H34E 109.5 . . ?
C31 C34A H34F 109.5 . . ?
H34D C34A H34E 109.5 . . ?
H34D C34A H34F 109.5 . . ?
H34E C34A H34F 109.5 . . ?
Cl1 C71 H71A 108.6 . . ?
Cl1 C71 H71B 108.6 . . ?
Cl2 C71 Cl1 114.5(5) . . ?
Cl2 C71 H71A 108.6 . . ?
Cl2 C71 H71B 108.6 . . ?
H71A C71 H71B 107.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N1 C21 N2 9.0(7) . . . . ?
Pt1 N1 C21 N3 -171.0(4) . . . . ?
Pt1 N1 C24 C23 172.9(4) . . . . ?
Pt1 C1 C2 N2 -4.0(7) . . . . ?
Pt1 C1 C2 C3 172.2(4) . . . . ?
Pt1 C1 C6 C5 -172.5(4) . . . . ?
Pt1 N7 C49 C50 -179.3(4) . . . . ?
Pt1 N7 C53 N8 -0.3(7) . . . . ?
Pt1 N7 C53 C52 -179.9(3) . . . . ?
Pt1 N9 C64 N10 -3.5(7) . . . . ?
Pt1 N9 C64 C63 177.9(3) . . . . ?
Pt1 N9 C65 C66 1.4(7) . . . . ?
Pt1 N9 C65 C70 -178.6(3) . . . . ?
C1 C2 C3 C4 2.6(8) . . . . ?
C1 C2 C3 C11 -176.2(5) . . . . ?
Pt2 N4 C45 N5 170.4(4) . . . . ?
Pt2 N4 C45 N6 -9.6(6) . . . . ?
Pt2 N4 C46 C47 -172.3(4) . . . . ?
Pt2 N8 C53 N7 -2.6(7) . . . . ?
Pt2 N8 C53 C52 177.1(3) . . . . ?
Pt2 N8 C54 C55 -176.9(3) . . . . ?
Pt2 N8 C54 C59 4.2(8) . . . . ?
Pt2 N10 C60 C61 -176.5(4) . . . . ?
Pt2 N10 C64 N9 -3.8(6) . . . . ?
Pt2 N10 C64 C63 174.7(3) . . . . ?
Pt2 C26 C27 C28 170.9(4) . . . . ?
N2 C2 C3 C4 179.5(5) . . . . ?
N2 C2 C3 C11 0.7(6) . . . . ?
N2 C12 C13 C14 179.9(5) . . . . ?
C2 C1 C6 C5 3.3(8) . . . . ?
C2 N2 C12 C11 1.9(6) . . . . ?
C2 N2 C12 C13 -177.2(6) . . . . ?
C2 N2 C21 N1 15.3(7) . . . . ?
C2 N2 C21 N3 -164.7(5) . . . . ?
C2 C3 C4 C5 -0.5(8) . . . . ?
C2 C3 C11 C12 0.5(6) . . . . ?
C2 C3 C11 C16 -179.3(6) . . . . ?
N3 C22 C23 C24 1.7(8) . . . . ?
C3 C4 C5 C6 0.0(8) . . . . ?
C3 C4 C5 C7 -179.0(5) . . . . ?
C3 C11 C12 N2 -1.4(6) . . . . ?
C3 C11 C12 C13 177.7(5) . . . . ?
C3 C11 C16 C15 -178.6(6) . . . . ?
N4 C46 C47 C48 -0.6(8) . . . . ?
C4 C3 C11 C12 -178.1(6) . . . . ?
C4 C3 C11 C16 2.2(11) . . . . ?
C4 C5 C6 C1 -1.5(8) . . . . ?
C4 C5 C7 C8 -179.1(7) . . . . ?
C4 C5 C7 C9 56.5(8) . . . . ?
C4 C5 C7 C10 -58.3(8) . . . . ?
C4 C5 C7 C8A -110.0(11) . . . . ?
C4 C5 C7 C9A 131.4(11) . . . . ?
C4 C5 C7 C10A 10.9(12) . . . . ?
C6 C1 C2 N2 180.0(5) . . . . ?
C6 C1 C2 C3 -3.8(7) . . . . ?
C6 C5 C7 C8 1.9(8) . . . . ?
C6 C5 C7 C9 -122.4(7) . . . . ?
C6 C5 C7 C10 122.7(7) . . . . ?
C6 C5 C7 C8A 71.0(11) . . . . ?
C6 C5 C7 C9A -47.5(12) . . . . ?
C6 C5 C7 C10A -168.0(11) . . . . ?
N6 C25 C26 Pt2 7.6(7) . . . . ?
N6 C25 C26 C27 -179.4(5) . . . . ?
N6 C25 C30 C29 178.2(4) . . . . ?
N6 C25 C30 C35 -5.1(6) . . . . ?
N6 C36 C37 C38 -173.4(5) . . . . ?
C7 C5 C6 C1 177.5(5) . . . . ?
N7 C49 C50 C51 -0.4(9) . . . . ?
N8 C54 C55 C52 0.9(6) . . . . ?
N8 C54 C55 C56 178.7(5) . . . . ?
N8 C54 C59 C58 -179.8(5) . . . . ?
N9 C65 C66 C67 178.8(5) . . . . ?
N9 C65 C70 C63 -0.6(6) . . . . ?
N9 C65 C70 C69 -179.9(5) . . . . ?
N10 C60 C61 C62 0.6(8) . . . . ?
C11 C3 C4 C5 177.9(6) . . . . ?
C11 C12 C13 C14 0.9(8) . . . . ?
C12 N2 C2 C1 175.1(5) . . . . ?
C12 N2 C2 C3 -1.6(6) . . . . ?
C12 N2 C21 N1 179.5(5) . . . . ?
C12 N2 C21 N3 -0.5(7) . . . . ?
C12 C11 C16 C15 1.7(9) . . . . ?
C12 C13 C14 C15 1.5(9) . . . . ?
C13 C14 C15 C16 -2.2(9) . . . . ?
C13 C14 C15 C17 175.7(6) . . . . ?
C14 C15 C16 C11 0.6(9) . . . . ?
C14 C15 C17 C18 9.4(9) . . . . ?
C14 C15 C17 C19 129.8(6) . . . . ?
C14 C15 C17 C20 -111.1(6) . . . . ?
C16 C11 C12 N2 178.3(5) . . . . ?
C16 C11 C12 C13 -2.5(8) . . . . ?
C16 C15 C17 C18 -172.7(6) . . . . ?
C16 C15 C17 C19 -52.3(8) . . . . ?
C16 C15 C17 C20 66.8(7) . . . . ?
C17 C15 C16 C11 -177.4(6) . . . . ?
C21 N1 C24 C23 -3.8(7) . . . . ?
C21 N2 C2 C1 -18.5(8) . . . . ?
C21 N2 C2 C3 164.8(5) . . . . ?
C21 N2 C12 C11 -164.7(5) . . . . ?
C21 N2 C12 C13 16.2(9) . . . . ?
C21 N3 C22 C23 -0.5(8) . . . . ?
C22 N3 C21 N1 -3.3(8) . . . . ?
C22 N3 C21 N2 176.7(5) . . . . ?
C22 C23 C24 N1 0.6(8) . . . . ?
C24 N1 C21 N2 -174.7(4) . . . . ?
C24 N1 C21 N3 5.3(7) . . . . ?
C25 N6 C36 C35 -3.5(5) . . . . ?
C25 N6 C36 C37 170.9(5) . . . . ?
C25 N6 C45 N4 -29.9(7) . . . . ?
C25 N6 C45 N5 150.1(5) . . . . ?
C25 C26 C27 C28 -1.3(8) . . . . ?
C25 C30 C35 C36 2.9(6) . . . . ?
C25 C30 C35 C40 -170.8(5) . . . . ?
C26 C25 C30 C29 -6.3(8) . . . . ?
C26 C25 C30 C35 170.4(5) . . . . ?
C26 C27 C28 C29 -2.6(8) . . . . ?
C26 C27 C28 C31 179.3(5) . . . . ?
C27 C28 C29 C30 2.2(8) . . . . ?
C27 C28 C31 C32 178.3(6) . . . . ?
C27 C28 C31 C33 -58.0(7) . . . . ?
C27 C28 C31 C34 57.1(8) . . . . ?
C27 C28 C31 C32A -156.0(10) . . . . ?
C27 C28 C31 C33A -23.8(12) . . . . ?
C27 C28 C31 C34A 91.2(10) . . . . ?
C28 C29 C30 C25 1.9(8) . . . . ?
C28 C29 C30 C35 -173.7(5) . . . . ?
C29 C28 C31 C32 0.2(9) . . . . ?
C29 C28 C31 C33 123.9(7) . . . . ?
C29 C28 C31 C34 -121.0(7) . . . . ?
C29 C28 C31 C32A 25.9(11) . . . . ?
C29 C28 C31 C33A 158.1(11) . . . . ?
C29 C28 C31 C34A -86.9(10) . . . . ?
C29 C30 C35 C36 179.0(6) . . . . ?
C29 C30 C35 C40 5.3(10) . . . . ?
C30 C25 C26 Pt2 -167.2(4) . . . . ?
C30 C25 C26 C27 5.8(8) . . . . ?
C30 C35 C36 N6 0.4(5) . . . . ?
C30 C35 C36 C37 -174.6(5) . . . . ?
C30 C35 C40 C39 172.7(5) . . . . ?
C31 C28 C29 C30 -179.7(5) . . . . ?
C35 C36 C37 C38 0.4(8) . . . . ?
C36 N6 C25 C26 -170.1(5) . . . . ?
C36 N6 C25 C30 5.4(5) . . . . ?
C36 N6 C45 N4 175.9(4) . . . . ?
C36 N6 C45 N5 -4.1(7) . . . . ?
C36 C35 C40 C39 -0.4(8) . . . . ?
C36 C37 C38 C39 -0.7(8) . . . . ?
C37 C38 C39 C40 0.4(8) . . . . ?
C37 C38 C39 C41 179.9(5) . . . . ?
C38 C39 C40 C35 0.1(8) . . . . ?
C38 C39 C41 C42 116.2(6) . . . . ?
C38 C39 C41 C43 -123.9(5) . . . . ?
C38 C39 C41 C44 -3.4(7) . . . . ?
C40 C35 C36 N6 175.1(4) . . . . ?
C40 C35 C36 C37 0.2(8) . . . . ?
C40 C39 C41 C42 -64.4(6) . . . . ?
C40 C39 C41 C43 55.6(7) . . . . ?
C40 C39 C41 C44 176.0(5) . . . . ?
C41 C39 C40 C35 -179.3(5) . . . . ?
C45 N4 C46 C47 3.3(7) . . . . ?
C45 N5 C48 C47 -0.1(8) . . . . ?
C45 N6 C25 C26 32.0(8) . . . . ?
C45 N6 C25 C30 -152.6(4) . . . . ?
C45 N6 C36 C35 154.3(4) . . . . ?
C45 N6 C36 C37 -31.3(8) . . . . ?
C46 N4 C45 N5 -4.8(7) . . . . ?
C46 N4 C45 N6 175.2(4) . . . . ?
C46 C47 C48 N5 -1.2(9) . . . . ?
C48 N5 C45 N4 3.2(8) . . . . ?
C48 N5 C45 N6 -176.8(5) . . . . ?
C49 N7 C53 N8 -178.9(5) . . . . ?
C49 N7 C53 C52 1.4(7) . . . . ?
C49 C50 C51 C52 0.4(9) . . . . ?
C50 C51 C52 C53 0.5(8) . . . . ?
C50 C51 C52 C55 -178.9(6) . . . . ?
C51 C52 C53 N7 -1.5(8) . . . . ?
C51 C52 C53 N8 178.8(5) . . . . ?
C51 C52 C55 C54 179.8(6) . . . . ?
C51 C52 C55 C56 2.6(12) . . . . ?
C52 C55 C56 C57 178.7(6) . . . . ?
C53 N7 C49 C50 -0.5(8) . . . . ?
C53 N8 C54 C55 -1.8(6) . . . . ?
C53 N8 C54 C59 179.2(5) . . . . ?
C53 C52 C55 C54 0.4(5) . . . . ?
C53 C52 C55 C56 -176.9(6) . . . . ?
C54 N8 C53 N7 -177.6(5) . . . . ?
C54 N8 C53 C52 2.1(6) . . . . ?
C54 C55 C56 C57 1.7(8) . . . . ?
C55 C52 C53 N7 178.1(5) . . . . ?
C55 C52 C53 N8 -1.6(6) . . . . ?
C55 C54 C59 C58 1.4(8) . . . . ?
C55 C56 C57 C58 -0.2(9) . . . . ?
C56 C57 C58 C59 -0.7(9) . . . . ?
C57 C58 C59 C54 0.1(9) . . . . ?
C59 C54 C55 C52 179.9(5) . . . . ?
C59 C54 C55 C56 -2.3(8) . . . . ?
C60 N10 C64 N9 177.6(4) . . . . ?
C60 N10 C64 C63 -3.9(7) . . . . ?
C60 C61 C62 C63 -1.3(8) . . . . ?
C61 C62 C63 C64 -0.5(8) . . . . ?
C61 C62 C63 C70 178.6(6) . . . . ?
C62 C63 C64 N9 -178.1(4) . . . . ?
C62 C63 C64 N10 3.2(7) . . . . ?
C62 C63 C70 C65 179.7(6) . . . . ?
C62 C63 C70 C69 -1.1(12) . . . . ?
C64 N9 C65 C66 -178.0(5) . . . . ?
C64 N9 C65 C70 2.1(5) . . . . ?
C64 N10 C60 C61 2.1(7) . . . . ?
C64 C63 C70 C65 -1.1(5) . . . . ?
C64 C63 C70 C69 178.1(6) . . . . ?
C65 N9 C64 N10 175.7(4) . . . . ?
C65 N9 C64 C63 -2.8(5) . . . . ?
C65 C66 C67 C68 1.9(9) . . . . ?
C66 C65 C70 C63 179.5(5) . . . . ?
C66 C65 C70 C69 0.2(8) . . . . ?
C66 C67 C68 C69 -1.4(10) . . . . ?
C67 C68 C69 C70 0.2(9) . . . . ?
C68 C69 C70 C63 -178.7(6) . . . . ?
C68 C69 C70 C65 0.3(9) . . . . ?
C70 C63 C64 N9 2.5(5) . . . . ?
C70 C63 C64 N10 -176.1(4) . . . . ?
C70 C65 C66 C67 -1.3(8) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 213 electrons were 
found in a volume of 869Å³ in 1 void per unit cell. 
This is consistent with the presence of 
3[CH2Cl2] per Asymmetric Unit 
which account for 252 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 -0.185 -0.185 869.4 212.9 '6 CH2Cl2'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_221009yhb_512
_database_code_depnum_ccdc_archive 'CCDC 2285566'
loop_
_audit_author_name
_audit_author_address
'Haibo Yao'
;Guangxi minzu university
China
;
_audit_update_record             
;
2024-02-07 deposited with the CCDC.	2024-02-25 downloaded from the CCDC.
;
_audit_creation_date             2024-02-06
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C70 H70 N10 Pt2, 14[CH3OH]'
_chemical_formula_sum            'C84 H126 N10 O14 Pt2'
_chemical_formula_weight         1890.12
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0412 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -5.3886 5.5592 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   16.6809(3)
_cell_length_b                   17.8405(3)
_cell_length_c                   28.5344(5)
_cell_angle_alpha                90
_cell_angle_beta                 97.0900(10)
_cell_angle_gamma                90
_cell_volume                     8426.8(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9822
_cell_measurement_temperature    213.00
_cell_measurement_theta_max      54.973
_cell_measurement_theta_min      3.333
_shelx_estimated_absorpt_T_max   0.804
_shelx_estimated_absorpt_T_min   0.741
_exptl_absorpt_coefficient_mu    4.561
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.4395
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1201 before and 0.0620 after correction.
The Ratio of minimum to maximum transmission is 0.5854.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.490
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3872
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0631
_diffrn_reflns_av_unetI/netI     0.0486
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            89782
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.988
_diffrn_reflns_theta_min         3.332
_diffrn_ambient_temperature      213.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_source_current           2.86
_diffrn_source_power             0.1995708
_diffrn_source_voltage           69.78
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11747
_reflns_number_total             15989
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.731
_refine_diff_density_min         -1.615
_refine_diff_density_rms         0.107
_refine_ls_extinction_coef       0.00044(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.135
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     752
_refine_ls_number_reflns         15989
_refine_ls_number_restraints     37
_refine_ls_R_factor_all          0.0652
_refine_ls_R_factor_gt           0.0510
_refine_ls_restrained_S_all      1.150
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0862P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1466
_refine_ls_wR_factor_ref         0.1540
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 N3, C22
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.005
3. Uiso/Uaniso restraints and constraints
C36 \\sim C39 \\sim C37 \\sim C38: within 2A with sigma of 0.005 and sigma for
terminal atoms of 0.01 within 2A
C64 \\sim C66 \\sim C67 \\sim C65: within 2A with sigma of 0.005 and sigma for
terminal atoms of 0.01 within 2A
4.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C15(H15), C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9), C10(H10),
 C11(H11), C14(H14), C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C21(H21),
  C22(H22), C26(H26), C28(H28), C32(H32), C33(H33), C35(H35), C44(H44),
 C45(H45), C46(H46), C50(H50), C52(H52), C56(H56), C57(H57), C59(H59), C68(H68),
  C69(H69), C70(H70)
4.b Idealised Me refined as rotating group:
 C37(H37A,H37B,H37C), C38(H38A,H38B,H38C), C39(H39A,H39B,H39C), C41(H41A,H41B,
 H41C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C61(H61A,H61B,H61C), C62(H62A,
 H62B,H62C), C63(H63A,H63B,H63C), C65(H65A,H65B,H65C), C66(H66A,H66B,H66C),
 C67(H67A,H67B,H67C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.76224(2) 0.45239(2) 0.35348(2) 0.05297(11) Uani 1 1 d . . . . .
Pt2 Pt 0.85834(2) 0.32356(2) 0.33101(2) 0.05377(11) Uani 1 1 d . . . . .
N1 N 0.9309(2) 0.3586(3) 0.38846(15) 0.0559(11) Uani 1 1 d . . . . .
N2 N 0.8844(3) 0.4807(3) 0.38258(16) 0.0584(11) Uani 1 1 d . . . . .
N3 N 0.7843(3) 0.2780(3) 0.38067(15) 0.0599(11) Uani 1 1 d . U . . .
N4 N 0.7593(2) 0.3937(3) 0.41448(15) 0.0557(11) Uani 1 1 d . . . . .
N5 N 0.7842(3) 0.2827(2) 0.27455(15) 0.0553(11) Uani 1 1 d . . . . .
N6 N 0.8840(3) 0.2588(2) 0.22474(15) 0.0534(11) Uani 1 1 d . . . . .
N7 N 0.7554(3) 0.2179(3) 0.20204(17) 0.0714(14) Uani 1 1 d . . . . .
N8 N 0.7713(2) 0.5088(2) 0.29172(15) 0.0531(11) Uani 1 1 d . . . . .
N9 N 0.6332(3) 0.5321(2) 0.26836(15) 0.0541(11) Uani 1 1 d . . . . .
N10 N 0.7256(3) 0.5756(3) 0.22137(17) 0.0651(12) Uani 1 1 d . . . . .
C1 C 0.9349(3) 0.4293(3) 0.40433(19) 0.0539(13) Uani 1 1 d . . . . .
C2 C 0.8998(4) 0.5566(3) 0.3920(2) 0.0630(15) Uani 1 1 d . . . . .
C3 C 0.8401(4) 0.6045(4) 0.4049(2) 0.0691(16) Uani 1 1 d . . . . .
H3 H 0.788306 0.585555 0.407640 0.083 Uiso 1 1 calc R U . . .
C15 C 0.8093(4) 0.4714(5) 0.5347(2) 0.089(2) Uani 1 1 d . . . . .
H15 H 0.847708 0.464843 0.561370 0.107 Uiso 1 1 calc R U . . .
C4 C 0.8567(5) 0.6812(4) 0.4139(3) 0.089(2) Uani 1 1 d . . . . .
H4 H 0.815289 0.712831 0.421567 0.107 Uiso 1 1 calc R U . . .
C5 C 0.9326(5) 0.7104(4) 0.4115(3) 0.092(2) Uani 1 1 d . . . . .
H5 H 0.944270 0.760764 0.419252 0.110 Uiso 1 1 calc R U . . .
C6 C 0.9901(5) 0.6643(4) 0.3976(3) 0.100(2) Uani 1 1 d . . . . .
H6 H 1.041581 0.684025 0.394909 0.119 Uiso 1 1 calc R U . . .
C7 C 0.9757(4) 0.5890(4) 0.3873(2) 0.0793(19) Uani 1 1 d . . . . .
H7 H 1.016730 0.559356 0.377030 0.095 Uiso 1 1 calc R U . . .
C8 C 0.9910(4) 0.4444(4) 0.4456(2) 0.0674(16) Uani 1 1 d . . . . .
H8 H 0.995108 0.493659 0.457358 0.081 Uiso 1 1 calc R U . . .
C9 C 1.0386(4) 0.3903(4) 0.4682(2) 0.0730(17) Uani 1 1 d . . . . .
H9 H 1.075163 0.401889 0.495025 0.088 Uiso 1 1 calc R U . . .
C10 C 1.0317(4) 0.3166(4) 0.4506(2) 0.0801(19) Uani 1 1 d . . . . .
H10 H 1.062966 0.277332 0.465267 0.096 Uiso 1 1 calc R U . . .
C11 C 0.9789(4) 0.3050(4) 0.4123(2) 0.0699(16) Uani 1 1 d . . . . .
H11 H 0.974107 0.255771 0.400535 0.084 Uiso 1 1 calc R U . . .
C12 C 0.7601(3) 0.3178(3) 0.4168(2) 0.0595(15) Uani 1 1 d . . . . .
C13 C 0.7542(3) 0.4356(4) 0.4553(2) 0.0650(16) Uani 1 1 d . . . . .
C14 C 0.8102(4) 0.4262(4) 0.4958(2) 0.0710(16) Uani 1 1 d . . . . .
H14 H 0.849159 0.388067 0.496325 0.085 Uiso 1 1 calc R U . . .
C16 C 0.7494(5) 0.5283(4) 0.5340(2) 0.0819(19) Uani 1 1 d . . . . .
H16 H 0.748430 0.560647 0.559939 0.098 Uiso 1 1 calc R U . . .
C17 C 0.6934(4) 0.5351(4) 0.4952(2) 0.0817(19) Uani 1 1 d . . . . .
H17 H 0.652409 0.571349 0.494974 0.098 Uiso 1 1 calc R U . . .
C18 C 0.6957(4) 0.4897(4) 0.4559(2) 0.0694(16) Uani 1 1 d . . . . .
H18 H 0.656856 0.495940 0.429452 0.083 Uiso 1 1 calc R U . . .
C19 C 0.7332(4) 0.2780(4) 0.4555(2) 0.0745(17) Uani 1 1 d . . . . .
H19 H 0.718497 0.304796 0.481497 0.089 Uiso 1 1 calc R U . . .
C20 C 0.7285(5) 0.2002(5) 0.4551(3) 0.096(2) Uani 1 1 d . . . . .
H20 H 0.710073 0.174243 0.480343 0.116 Uiso 1 1 calc R U . . .
C21 C 0.7518(5) 0.1614(4) 0.4165(2) 0.087(2) Uani 1 1 d . . . . .
H21 H 0.747227 0.108954 0.414502 0.104 Uiso 1 1 calc R U . . .
C22 C 0.7812(4) 0.2018(4) 0.3820(2) 0.0737(17) Uani 1 1 d . U . . .
H22 H 0.800721 0.175238 0.357285 0.088 Uiso 1 1 calc R U . . .
C23 C 0.8046(3) 0.2534(3) 0.23451(19) 0.0555(13) Uani 1 1 d . . . . .
C24 C 0.9435(3) 0.3086(3) 0.24692(18) 0.0524(13) Uani 1 1 d . . . . .
C25 C 0.9411(3) 0.3478(3) 0.28879(18) 0.0554(13) Uani 1 1 d . . . . .
C26 C 1.0084(3) 0.3952(3) 0.30083(19) 0.0598(14) Uani 1 1 d . . . . .
H26 H 1.009759 0.424086 0.328459 0.072 Uiso 1 1 calc R U . . .
C27 C 1.0732(3) 0.4017(3) 0.27417(19) 0.0592(14) Uani 1 1 d . . . . .
C28 C 1.0733(3) 0.3562(3) 0.2347(2) 0.0648(15) Uani 1 1 d . . . . .
H28 H 1.117461 0.356771 0.217233 0.078 Uiso 1 1 calc R U . . .
C30 C 0.9931(3) 0.2545(3) 0.18414(18) 0.0566(14) Uani 1 1 d . . . . .
C29 C 1.0086(3) 0.3105(3) 0.22160(19) 0.0564(14) Uani 1 1 d . . . . .
C31 C 0.9168(3) 0.2231(3) 0.18648(19) 0.0579(14) Uani 1 1 d . . . . .
C32 C 0.8879(4) 0.1667(3) 0.1558(2) 0.0644(15) Uani 1 1 d . . . . .
H32 H 0.835216 0.147783 0.155677 0.077 Uiso 1 1 calc R U . . .
C33 C 0.9390(4) 0.1388(4) 0.1252(2) 0.0701(16) Uani 1 1 d . . . . .
H33 H 0.920385 0.099352 0.104891 0.084 Uiso 1 1 calc R U . . .
C34 C 1.0164(4) 0.1662(4) 0.1230(2) 0.0721(17) Uani 1 1 d . . . . .
C35 C 1.0430(4) 0.2252(4) 0.1526(2) 0.0674(16) Uani 1 1 d . . . . .
H35 H 1.094686 0.245638 0.151483 0.081 Uiso 1 1 calc R U . . .
C36 C 1.0736(5) 0.1314(5) 0.0914(3) 0.109(2) Uani 1 1 d . U . . .
C37 C 1.1018(6) 0.1921(6) 0.0593(3) 0.152(3) Uani 1 1 d . U . . .
H37A H 1.139687 0.170631 0.039894 0.227 Uiso 1 1 calc R U . . .
H37B H 1.127986 0.232085 0.078536 0.227 Uiso 1 1 calc R U . . .
H37C H 1.055567 0.212051 0.039256 0.227 Uiso 1 1 calc R U . . .
C38 C 1.0314(6) 0.0698(6) 0.0600(4) 0.147(3) Uani 1 1 d . U . . .
H38A H 1.071688 0.038756 0.047621 0.221 Uiso 1 1 calc R U . . .
H38B H 0.996938 0.092596 0.033981 0.221 Uiso 1 1 calc R U . . .
H38C H 0.998930 0.039127 0.078427 0.221 Uiso 1 1 calc R U . . .
C39 C 1.1447(5) 0.0932(6) 0.1238(3) 0.137(3) Uani 1 1 d . U . . .
H39A H 1.122876 0.058117 0.144959 0.206 Uiso 1 1 calc R U . . .
H39B H 1.176023 0.131197 0.142217 0.206 Uiso 1 1 calc R U . . .
H39C H 1.179074 0.066596 0.104397 0.206 Uiso 1 1 calc R U . . .
C40 C 1.1416(3) 0.4566(3) 0.2894(2) 0.0666(16) Uani 1 1 d . . . . .
C41 C 1.1697(4) 0.4485(4) 0.3428(2) 0.086(2) Uani 1 1 d . . . . .
H41A H 1.124933 0.459443 0.360400 0.129 Uiso 1 1 calc R U . . .
H41B H 1.213454 0.483419 0.351961 0.129 Uiso 1 1 calc R U . . .
H41C H 1.188383 0.397739 0.349540 0.129 Uiso 1 1 calc R U . . .
C42 C 1.2159(4) 0.4420(4) 0.2642(2) 0.090(2) Uani 1 1 d . . . . .
H42A H 1.232867 0.390307 0.269041 0.135 Uiso 1 1 calc R U . . .
H42B H 1.259412 0.475074 0.276924 0.135 Uiso 1 1 calc R U . . .
H42C H 1.202591 0.451487 0.230663 0.135 Uiso 1 1 calc R U . . .
C43 C 1.1111(4) 0.5365(4) 0.2794(3) 0.096(2) Uani 1 1 d . . . . .
H43A H 1.095479 0.542724 0.245770 0.143 Uiso 1 1 calc R U . . .
H43B H 1.153633 0.571791 0.290131 0.143 Uiso 1 1 calc R U . . .
H43C H 1.064722 0.545600 0.296086 0.143 Uiso 1 1 calc R U . . .
C44 C 0.6771(4) 0.2162(4) 0.2082(2) 0.0777(19) Uani 1 1 d . . . . .
H44 H 0.640766 0.189898 0.186307 0.093 Uiso 1 1 calc R U . . .
C45 C 0.6483(4) 0.2514(4) 0.2454(2) 0.0676(16) Uani 1 1 d . . . . .
H45 H 0.592712 0.253650 0.248072 0.081 Uiso 1 1 calc R U . . .
C46 C 0.7043(3) 0.2830(3) 0.2781(2) 0.0600(14) Uani 1 1 d . . . . .
H46 H 0.686531 0.306218 0.304529 0.072 Uiso 1 1 calc R U . . .
C54 C 0.4943(3) 0.5347(3) 0.2533(2) 0.0592(14) Uani 1 1 d . . . . .
C47 C 0.7131(3) 0.5385(3) 0.2610(2) 0.0526(13) Uani 1 1 d . . . . .
C48 C 0.6024(3) 0.4783(3) 0.29877(19) 0.0516(13) Uani 1 1 d . . . . .
C49 C 0.6452(3) 0.4358(3) 0.33392(18) 0.0515(13) Uani 1 1 d . . . . .
C50 C 0.5940(3) 0.3878(3) 0.35538(19) 0.0562(13) Uani 1 1 d . . . . .
H50 H 0.619367 0.356596 0.379291 0.067 Uiso 1 1 calc R U . . .
C51 C 0.5123(3) 0.3806(3) 0.3461(2) 0.0594(14) Uani 1 1 d . . . . .
C58 C 0.4142(3) 0.6215(4) 0.2032(2) 0.0680(16) Uani 1 1 d . . . . .
C52 C 0.4732(3) 0.4274(3) 0.3125(2) 0.0640(15) Uani 1 1 d . . . . .
H52 H 0.416683 0.425696 0.305427 0.077 Uiso 1 1 calc R U . . .
C53 C 0.5187(3) 0.4778(3) 0.28875(19) 0.0559(13) Uani 1 1 d . . . . .
C55 C 0.5662(3) 0.5675(3) 0.2408(2) 0.0564(13) Uani 1 1 d . . . . .
C56 C 0.5615(3) 0.6266(3) 0.20859(19) 0.0569(14) Uani 1 1 d . . . . .
H56 H 0.608544 0.647682 0.199018 0.068 Uiso 1 1 calc R U . . .
C57 C 0.4864(3) 0.6531(3) 0.1912(2) 0.0646(15) Uani 1 1 d . . . . .
H57 H 0.482969 0.694203 0.170434 0.077 Uiso 1 1 calc R U . . .
C59 C 0.4199(3) 0.5617(3) 0.2341(2) 0.0650(16) Uani 1 1 d . . . . .
H59 H 0.372604 0.539169 0.242242 0.078 Uiso 1 1 calc R U . . .
C60 C 0.3310(4) 0.6531(4) 0.1839(3) 0.085(2) Uani 1 1 d . . . . .
C61 C 0.2802(5) 0.5919(5) 0.1594(4) 0.139(4) Uani 1 1 d . . . . .
H61A H 0.307495 0.570920 0.134356 0.209 Uiso 1 1 calc R U . . .
H61B H 0.228402 0.612336 0.146135 0.209 Uiso 1 1 calc R U . . .
H61C H 0.271675 0.552943 0.182006 0.209 Uiso 1 1 calc R U . . .
C62 C 0.3362(4) 0.7211(5) 0.1516(3) 0.117(3) Uani 1 1 d . . . . .
H62A H 0.366161 0.760859 0.169049 0.175 Uiso 1 1 calc R U . . .
H62B H 0.282204 0.738522 0.140312 0.175 Uiso 1 1 calc R U . . .
H62C H 0.363667 0.706844 0.124835 0.175 Uiso 1 1 calc R U . . .
C63 C 0.2896(5) 0.6836(5) 0.2271(3) 0.112(3) Uani 1 1 d . . . . .
H63A H 0.275315 0.641758 0.246113 0.168 Uiso 1 1 calc R U . . .
H63B H 0.241279 0.711393 0.215440 0.168 Uiso 1 1 calc R U . . .
H63C H 0.326938 0.716286 0.246174 0.168 Uiso 1 1 calc R U . . .
C64 C 0.4663(4) 0.3243(4) 0.3729(3) 0.0856(18) Uani 1 1 d . U . . .
C65 C 0.3774(5) 0.3320(5) 0.3635(3) 0.127(3) Uani 1 1 d . U . . .
H65A H 0.362712 0.384359 0.365576 0.191 Uiso 1 1 calc R U . . .
H65B H 0.352449 0.303338 0.386746 0.191 Uiso 1 1 calc R U . . .
H65C H 0.358864 0.313210 0.332166 0.191 Uiso 1 1 calc R U . . .
C66 C 0.4880(5) 0.3333(5) 0.4260(3) 0.114(3) Uani 1 1 d . U . . .
H66A H 0.545449 0.325079 0.434338 0.171 Uiso 1 1 calc R U . . .
H66B H 0.458049 0.297080 0.442328 0.171 Uiso 1 1 calc R U . . .
H66C H 0.474249 0.383594 0.435286 0.171 Uiso 1 1 calc R U . . .
C67 C 0.4921(6) 0.2470(5) 0.3574(4) 0.141(3) Uani 1 1 d . U . . .
H67A H 0.449187 0.225421 0.335456 0.212 Uiso 1 1 calc R U . . .
H67B H 0.502928 0.214724 0.384775 0.212 Uiso 1 1 calc R U . . .
H67C H 0.540579 0.251733 0.342005 0.212 Uiso 1 1 calc R U . . .
C68 C 0.8026(4) 0.5793(4) 0.2113(2) 0.0761(18) Uani 1 1 d . . . . .
H68 H 0.813791 0.605422 0.184264 0.091 Uiso 1 1 calc R U . . .
C69 C 0.8647(4) 0.5457(4) 0.2396(2) 0.0677(16) Uani 1 1 d . . . . .
H69 H 0.917663 0.545746 0.231589 0.081 Uiso 1 1 calc R U . . .
C70 C 0.8466(3) 0.5127(3) 0.2795(2) 0.0610(14) Uani 1 1 d . . . . .
H70 H 0.888958 0.491211 0.299899 0.073 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 2.9184(3) . ?
Pt1 N2 2.163(5) . ?
Pt1 N4 2.037(4) . ?
Pt1 N8 2.051(4) . ?
Pt1 C49 1.985(5) . ?
Pt2 N1 2.013(4) . ?
Pt2 N3 2.151(4) . ?
Pt2 N5 2.040(4) . ?
Pt2 C25 1.988(5) . ?
N1 C1 1.339(7) . ?
N1 C11 1.373(7) . ?
N2 C1 1.344(7) . ?
N2 C2 1.398(7) . ?
N3 C12 1.353(7) . ?
N3 C22 1.361(7) . ?
N4 C12 1.357(7) . ?
N4 C13 1.396(7) . ?
N5 C23 1.338(6) . ?
N5 C46 1.349(6) . ?
N6 C23 1.390(6) . ?
N6 C24 1.421(6) . ?
N6 C31 1.430(6) . ?
N7 C23 1.321(7) . ?
N7 C44 1.340(7) . ?
N8 C47 1.335(7) . ?
N8 C70 1.347(6) . ?
N9 C47 1.380(6) . ?
N9 C48 1.432(6) . ?
N9 C55 1.431(7) . ?
N10 C47 1.348(7) . ?
N10 C68 1.352(7) . ?
C1 C8 1.436(8) . ?
C2 C3 1.396(8) . ?
C2 C7 1.412(8) . ?
C3 H3 0.9400 . ?
C3 C4 1.413(9) . ?
C15 H15 0.9400 . ?
C15 C14 1.373(9) . ?
C15 C16 1.423(10) . ?
C4 H4 0.9400 . ?
C4 C5 1.378(10) . ?
C5 H5 0.9400 . ?
C5 C6 1.359(11) . ?
C6 H6 0.9400 . ?
C6 C7 1.390(9) . ?
C7 H7 0.9400 . ?
C8 H8 0.9400 . ?
C8 C9 1.362(8) . ?
C9 H9 0.9400 . ?
C9 C10 1.407(9) . ?
C10 H10 0.9400 . ?
C10 C11 1.334(8) . ?
C11 H11 0.9400 . ?
C12 C19 1.431(8) . ?
C13 C14 1.403(8) . ?
C13 C18 1.373(8) . ?
C14 H14 0.9400 . ?
C16 H16 0.9400 . ?
C16 C17 1.365(9) . ?
C17 H17 0.9400 . ?
C17 C18 1.387(9) . ?
C18 H18 0.9400 . ?
C19 H19 0.9400 . ?
C19 C20 1.390(9) . ?
C20 H20 0.9400 . ?
C20 C21 1.394(9) . ?
C21 H21 0.9400 . ?
C21 C22 1.362(8) . ?
C22 H22 0.9400 . ?
C24 C25 1.389(7) . ?
C24 C29 1.377(7) . ?
C25 C26 1.413(7) . ?
C26 H26 0.9400 . ?
C26 C27 1.401(7) . ?
C27 C28 1.388(7) . ?
C27 C40 1.525(8) . ?
C28 H28 0.9400 . ?
C28 C29 1.368(7) . ?
C30 C29 1.462(8) . ?
C30 C31 1.401(7) . ?
C30 C35 1.399(7) . ?
C31 C32 1.381(8) . ?
C32 H32 0.9400 . ?
C32 C33 1.386(8) . ?
C33 H33 0.9400 . ?
C33 C34 1.389(8) . ?
C34 C35 1.388(8) . ?
C34 C36 1.524(8) . ?
C35 H35 0.9400 . ?
C36 C37 1.529(12) . ?
C36 C38 1.534(11) . ?
C36 C39 1.566(12) . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C37 H37C 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C38 H38C 0.9700 . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C39 H39C 0.9700 . ?
C40 C41 1.545(9) . ?
C40 C42 1.529(8) . ?
C40 C43 1.528(9) . ?
C41 H41A 0.9700 . ?
C41 H41B 0.9700 . ?
C41 H41C 0.9700 . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C42 H42C 0.9700 . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C43 H43C 0.9700 . ?
C44 H44 0.9400 . ?
C44 C45 1.370(8) . ?
C45 H45 0.9400 . ?
C45 C46 1.360(8) . ?
C46 H46 0.9400 . ?
C54 C53 1.454(8) . ?
C54 C55 1.418(7) . ?
C54 C59 1.380(8) . ?
C48 C49 1.383(7) . ?
C48 C53 1.391(7) . ?
C49 C50 1.403(7) . ?
C50 H50 0.9400 . ?
C50 C51 1.362(7) . ?
C51 C52 1.375(8) . ?
C51 C64 1.526(8) . ?
C58 C57 1.409(8) . ?
C58 C59 1.381(8) . ?
C58 C60 1.536(8) . ?
C52 H52 0.9400 . ?
C52 C53 1.403(7) . ?
C55 C56 1.395(8) . ?
C56 H56 0.9400 . ?
C56 C57 1.374(7) . ?
C57 H57 0.9400 . ?
C59 H59 0.9400 . ?
C60 C61 1.500(10) . ?
C60 C62 1.532(9) . ?
C60 C63 1.582(10) . ?
C61 H61A 0.9700 . ?
C61 H61B 0.9700 . ?
C61 H61C 0.9700 . ?
C62 H62A 0.9700 . ?
C62 H62B 0.9700 . ?
C62 H62C 0.9700 . ?
C63 H63A 0.9700 . ?
C63 H63B 0.9700 . ?
C63 H63C 0.9700 . ?
C64 C65 1.479(10) . ?
C64 C66 1.523(10) . ?
C64 C67 1.527(12) . ?
C65 H65A 0.9700 . ?
C65 H65B 0.9700 . ?
C65 H65C 0.9700 . ?
C66 H66A 0.9700 . ?
C66 H66B 0.9700 . ?
C66 H66C 0.9700 . ?
C67 H67A 0.9700 . ?
C67 H67B 0.9700 . ?
C67 H67C 0.9700 . ?
C68 H68 0.9400 . ?
C68 C69 1.370(8) . ?
C69 H69 0.9400 . ?
C69 C70 1.348(8) . ?
C70 H70 0.9400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt1 Pt2 75.61(12) . . ?
N4 Pt1 Pt2 81.67(12) . . ?
N4 Pt1 N2 85.00(17) . . ?
N4 Pt1 N8 176.84(17) . . ?
N8 Pt1 Pt2 95.57(12) . . ?
N8 Pt1 N2 92.84(17) . . ?
C49 Pt1 Pt2 111.63(15) . . ?
C49 Pt1 N2 171.79(18) . . ?
C49 Pt1 N4 92.13(19) . . ?
C49 Pt1 N8 90.31(19) . . ?
N1 Pt2 Pt1 82.38(13) . . ?
N1 Pt2 N3 85.24(17) . . ?
N1 Pt2 N5 176.95(17) . . ?
N3 Pt2 Pt1 77.13(13) . . ?
N5 Pt2 Pt1 99.17(12) . . ?
N5 Pt2 N3 92.53(17) . . ?
C25 Pt2 Pt1 113.76(17) . . ?
C25 Pt2 N1 91.9(2) . . ?
C25 Pt2 N3 168.3(2) . . ?
C25 Pt2 N5 89.9(2) . . ?
C1 N1 Pt2 124.6(4) . . ?
C1 N1 C11 119.2(5) . . ?
C11 N1 Pt2 116.2(4) . . ?
C1 N2 Pt1 121.6(4) . . ?
C1 N2 C2 118.8(5) . . ?
C2 N2 Pt1 116.3(4) . . ?
C12 N3 Pt2 123.6(4) . . ?
C12 N3 C22 119.1(5) . . ?
C22 N3 Pt2 115.0(4) . . ?
C12 N4 Pt1 123.6(4) . . ?
C12 N4 C13 119.7(5) . . ?
C13 N4 Pt1 116.7(4) . . ?
C23 N5 Pt2 128.4(4) . . ?
C23 N5 C46 115.1(5) . . ?
C46 N5 Pt2 116.5(4) . . ?
C23 N6 C24 125.7(4) . . ?
C23 N6 C31 125.9(5) . . ?
C24 N6 C31 107.9(4) . . ?
C23 N7 C44 116.8(5) . . ?
C47 N8 Pt1 129.4(3) . . ?
C47 N8 C70 115.8(5) . . ?
C70 N8 Pt1 114.7(4) . . ?
C47 N9 C48 125.0(5) . . ?
C47 N9 C55 125.7(5) . . ?
C55 N9 C48 108.4(4) . . ?
C47 N10 C68 116.8(5) . . ?
N1 C1 N2 119.0(5) . . ?
N1 C1 C8 117.0(5) . . ?
N2 C1 C8 123.9(6) . . ?
N2 C2 C7 121.6(6) . . ?
C3 C2 N2 121.5(5) . . ?
C3 C2 C7 116.9(6) . . ?
C2 C3 H3 119.7 . . ?
C2 C3 C4 120.6(6) . . ?
C4 C3 H3 119.7 . . ?
C14 C15 H15 120.5 . . ?
C14 C15 C16 119.1(7) . . ?
C16 C15 H15 120.5 . . ?
C3 C4 H4 119.4 . . ?
C5 C4 C3 121.3(7) . . ?
C5 C4 H4 119.4 . . ?
C4 C5 H5 121.0 . . ?
C6 C5 C4 118.1(7) . . ?
C6 C5 H5 121.0 . . ?
C5 C6 H6 118.8 . . ?
C5 C6 C7 122.5(8) . . ?
C7 C6 H6 118.8 . . ?
C2 C7 H7 119.7 . . ?
C6 C7 C2 120.6(7) . . ?
C6 C7 H7 119.7 . . ?
C1 C8 H8 118.7 . . ?
C9 C8 C1 122.6(6) . . ?
C9 C8 H8 118.7 . . ?
C8 C9 H9 120.8 . . ?
C8 C9 C10 118.4(6) . . ?
C10 C9 H9 120.8 . . ?
C9 C10 H10 121.5 . . ?
C11 C10 C9 117.0(6) . . ?
C11 C10 H10 121.5 . . ?
N1 C11 H11 117.1 . . ?
C10 C11 N1 125.7(6) . . ?
C10 C11 H11 117.1 . . ?
N3 C12 N4 119.2(5) . . ?
N3 C12 C19 118.7(5) . . ?
N4 C12 C19 122.0(5) . . ?
N4 C13 C14 121.3(5) . . ?
C18 C13 N4 120.2(6) . . ?
C18 C13 C14 118.4(6) . . ?
C15 C14 C13 121.5(6) . . ?
C15 C14 H14 119.3 . . ?
C13 C14 H14 119.3 . . ?
C15 C16 H16 120.5 . . ?
C17 C16 C15 119.0(6) . . ?
C17 C16 H16 120.5 . . ?
C16 C17 H17 119.4 . . ?
C16 C17 C18 121.2(7) . . ?
C18 C17 H17 119.4 . . ?
C13 C18 C17 120.8(6) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C12 C19 H19 119.6 . . ?
C20 C19 C12 120.7(6) . . ?
C20 C19 H19 119.6 . . ?
C19 C20 H20 120.6 . . ?
C19 C20 C21 118.8(6) . . ?
C21 C20 H20 120.6 . . ?
C20 C21 H21 121.0 . . ?
C22 C21 C20 118.0(7) . . ?
C22 C21 H21 121.0 . . ?
N3 C22 C21 124.5(6) . . ?
N3 C22 H22 117.7 . . ?
C21 C22 H22 117.7 . . ?
N5 C23 N6 119.5(5) . . ?
N7 C23 N5 125.8(5) . . ?
N7 C23 N6 114.7(5) . . ?
C25 C24 N6 127.2(5) . . ?
C29 C24 N6 109.5(4) . . ?
C29 C24 C25 123.2(5) . . ?
C24 C25 Pt2 120.5(4) . . ?
C24 C25 C26 113.8(5) . . ?
C26 C25 Pt2 124.9(4) . . ?
C25 C26 H26 118.0 . . ?
C27 C26 C25 124.1(5) . . ?
C27 C26 H26 118.0 . . ?
C26 C27 C40 120.0(5) . . ?
C28 C27 C26 118.0(5) . . ?
C28 C27 C40 122.0(5) . . ?
C27 C28 H28 120.3 . . ?
C29 C28 C27 119.4(5) . . ?
C29 C28 H28 120.3 . . ?
C31 C30 C29 108.5(4) . . ?
C35 C30 C29 131.3(5) . . ?
C35 C30 C31 119.8(5) . . ?
C24 C29 C30 106.7(5) . . ?
C28 C29 C24 121.1(5) . . ?
C28 C29 C30 132.0(5) . . ?
C30 C31 N6 107.1(5) . . ?
C32 C31 N6 132.2(5) . . ?
C32 C31 C30 120.7(5) . . ?
C31 C32 H32 121.1 . . ?
C31 C32 C33 117.8(5) . . ?
C33 C32 H32 121.1 . . ?
C32 C33 H33 118.3 . . ?
C32 C33 C34 123.4(6) . . ?
C34 C33 H33 118.3 . . ?
C33 C34 C36 122.5(6) . . ?
C35 C34 C33 118.0(5) . . ?
C35 C34 C36 119.5(6) . . ?
C30 C35 H35 119.9 . . ?
C34 C35 C30 120.2(5) . . ?
C34 C35 H35 119.9 . . ?
C34 C36 C37 109.1(7) . . ?
C34 C36 C38 111.2(7) . . ?
C34 C36 C39 108.1(6) . . ?
C37 C36 C38 108.0(8) . . ?
C37 C36 C39 113.3(8) . . ?
C38 C36 C39 107.0(8) . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C36 C39 H39A 109.5 . . ?
C36 C39 H39B 109.5 . . ?
C36 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C27 C40 C41 110.2(5) . . ?
C27 C40 C42 112.3(5) . . ?
C27 C40 C43 109.0(5) . . ?
C42 C40 C41 106.4(5) . . ?
C43 C40 C41 108.8(6) . . ?
C43 C40 C42 110.0(6) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C40 C42 H42A 109.5 . . ?
C40 C42 H42B 109.5 . . ?
C40 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C40 C43 H43A 109.5 . . ?
C40 C43 H43B 109.5 . . ?
C40 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
N7 C44 H44 118.9 . . ?
N7 C44 C45 122.1(6) . . ?
C45 C44 H44 118.9 . . ?
C44 C45 H45 121.8 . . ?
C46 C45 C44 116.4(5) . . ?
C46 C45 H45 121.8 . . ?
N5 C46 C45 123.3(5) . . ?
N5 C46 H46 118.4 . . ?
C45 C46 H46 118.4 . . ?
C55 C54 C53 106.9(5) . . ?
C59 C54 C53 132.8(5) . . ?
C59 C54 C55 120.2(5) . . ?
N8 C47 N9 120.3(5) . . ?
N8 C47 N10 124.8(5) . . ?
N10 C47 N9 114.9(5) . . ?
C49 C48 N9 128.0(5) . . ?
C49 C48 C53 124.2(5) . . ?
C53 C48 N9 107.7(5) . . ?
C48 C49 Pt1 121.6(4) . . ?
C48 C49 C50 111.3(5) . . ?
C50 C49 Pt1 126.8(4) . . ?
C49 C50 H50 115.8 . . ?
C51 C50 C49 128.4(5) . . ?
C51 C50 H50 115.8 . . ?
C50 C51 C52 117.1(5) . . ?
C50 C51 C64 121.2(5) . . ?
C52 C51 C64 121.6(5) . . ?
C57 C58 C60 121.8(6) . . ?
C59 C58 C57 118.1(5) . . ?
C59 C58 C60 120.0(5) . . ?
C51 C52 H52 120.4 . . ?
C51 C52 C53 119.2(5) . . ?
C53 C52 H52 120.4 . . ?
C48 C53 C54 109.1(5) . . ?
C48 C53 C52 119.6(5) . . ?
C52 C53 C54 131.4(5) . . ?
C54 C55 N9 107.8(5) . . ?
C56 C55 N9 132.2(5) . . ?
C56 C55 C54 119.9(5) . . ?
C55 C56 H56 120.9 . . ?
C57 C56 C55 118.2(5) . . ?
C57 C56 H56 120.9 . . ?
C58 C57 H57 118.5 . . ?
C56 C57 C58 122.9(5) . . ?
C56 C57 H57 118.5 . . ?
C54 C59 C58 120.7(5) . . ?
C54 C59 H59 119.6 . . ?
C58 C59 H59 119.6 . . ?
C58 C60 C63 107.9(6) . . ?
C61 C60 C58 109.5(6) . . ?
C61 C60 C62 111.5(7) . . ?
C61 C60 C63 109.6(7) . . ?
C62 C60 C58 113.0(5) . . ?
C62 C60 C63 105.1(7) . . ?
C60 C61 H61A 109.5 . . ?
C60 C61 H61B 109.5 . . ?
C60 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C60 C62 H62A 109.5 . . ?
C60 C62 H62B 109.5 . . ?
C60 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C60 C63 H63A 109.5 . . ?
C60 C63 H63B 109.5 . . ?
C60 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C51 C64 C67 105.8(6) . . ?
C65 C64 C51 113.8(6) . . ?
C65 C64 C66 106.2(7) . . ?
C65 C64 C67 110.1(7) . . ?
C66 C64 C51 110.9(6) . . ?
C66 C64 C67 110.1(7) . . ?
C64 C65 H65A 109.5 . . ?
C64 C65 H65B 109.5 . . ?
C64 C65 H65C 109.5 . . ?
H65A C65 H65B 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C64 C66 H66A 109.5 . . ?
C64 C66 H66B 109.5 . . ?
C64 C66 H66C 109.5 . . ?
H66A C66 H66B 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
C64 C67 H67A 109.5 . . ?
C64 C67 H67B 109.5 . . ?
C64 C67 H67C 109.5 . . ?
H67A C67 H67B 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
N10 C68 H68 119.2 . . ?
N10 C68 C69 121.5(5) . . ?
C69 C68 H68 119.2 . . ?
C68 C69 H69 121.4 . . ?
C70 C69 C68 117.2(5) . . ?
C70 C69 H69 121.4 . . ?
N8 C70 C69 123.7(6) . . ?
N8 C70 H70 118.2 . . ?
C69 C70 H70 118.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N2 C1 N1 35.1(6) . . . . ?
Pt1 N2 C1 C8 -141.6(5) . . . . ?
Pt1 N2 C2 C3 30.8(7) . . . . ?
Pt1 N2 C2 C7 -146.8(5) . . . . ?
Pt1 N4 C12 N3 17.6(7) . . . . ?
Pt1 N4 C12 C19 -160.1(5) . . . . ?
Pt1 N4 C13 C14 -125.9(5) . . . . ?
Pt1 N4 C13 C18 51.2(6) . . . . ?
Pt1 N8 C47 N9 -1.3(7) . . . . ?
Pt1 N8 C47 N10 179.1(4) . . . . ?
Pt1 N8 C70 C69 178.3(5) . . . . ?
Pt1 C49 C50 C51 172.6(5) . . . . ?
Pt2 N1 C1 N2 3.9(7) . . . . ?
Pt2 N1 C1 C8 -179.1(4) . . . . ?
Pt2 N1 C11 C10 179.1(5) . . . . ?
Pt2 N3 C12 N4 21.3(7) . . . . ?
Pt2 N3 C12 C19 -161.0(4) . . . . ?
Pt2 N3 C22 C21 166.4(6) . . . . ?
Pt2 N5 C23 N6 -10.0(8) . . . . ?
Pt2 N5 C23 N7 169.5(4) . . . . ?
Pt2 N5 C46 C45 -173.8(5) . . . . ?
Pt2 C25 C26 C27 168.7(5) . . . . ?
N1 C1 C8 C9 -0.2(8) . . . . ?
N2 C1 C8 C9 176.6(5) . . . . ?
N2 C2 C3 C4 -179.4(6) . . . . ?
N2 C2 C7 C6 -178.9(6) . . . . ?
N3 C12 C19 C20 -2.9(9) . . . . ?
N4 C12 C19 C20 174.8(7) . . . . ?
N4 C13 C14 C15 174.6(6) . . . . ?
N4 C13 C18 C17 -175.6(6) . . . . ?
N6 C24 C25 Pt2 11.6(8) . . . . ?
N6 C24 C25 C26 -177.9(5) . . . . ?
N6 C24 C29 C28 177.9(5) . . . . ?
N6 C24 C29 C30 -5.1(6) . . . . ?
N6 C31 C32 C33 -173.3(6) . . . . ?
N7 C44 C45 C46 -5.5(10) . . . . ?
N9 C48 C49 Pt1 7.3(8) . . . . ?
N9 C48 C49 C50 -178.6(5) . . . . ?
N9 C48 C53 C54 -3.0(6) . . . . ?
N9 C48 C53 C52 177.5(5) . . . . ?
N9 C55 C56 C57 -173.3(6) . . . . ?
N10 C68 C69 C70 -3.9(10) . . . . ?
C1 N1 C11 C10 -0.9(9) . . . . ?
C1 N2 C2 C3 -129.1(6) . . . . ?
C1 N2 C2 C7 53.3(8) . . . . ?
C1 C8 C9 C10 -0.5(9) . . . . ?
C2 N2 C1 N1 -166.1(5) . . . . ?
C2 N2 C1 C8 17.1(8) . . . . ?
C2 C3 C4 C5 -1.9(11) . . . . ?
C3 C2 C7 C6 3.4(10) . . . . ?
C3 C4 C5 C6 3.7(12) . . . . ?
C15 C16 C17 C18 -2.4(10) . . . . ?
C4 C5 C6 C7 -2.0(13) . . . . ?
C5 C6 C7 C2 -1.6(12) . . . . ?
C7 C2 C3 C4 -1.7(9) . . . . ?
C8 C9 C10 C11 0.5(10) . . . . ?
C9 C10 C11 N1 0.2(10) . . . . ?
C11 N1 C1 N2 -176.1(5) . . . . ?
C11 N1 C1 C8 0.9(7) . . . . ?
C12 N3 C22 C21 3.0(10) . . . . ?
C12 N4 C13 C14 55.7(7) . . . . ?
C12 N4 C13 C18 -127.2(6) . . . . ?
C12 C19 C20 C21 1.0(11) . . . . ?
C13 N4 C12 N3 -164.2(5) . . . . ?
C13 N4 C12 C19 18.1(8) . . . . ?
C14 C15 C16 C17 1.5(10) . . . . ?
C14 C13 C18 C17 1.6(9) . . . . ?
C16 C15 C14 C13 0.9(10) . . . . ?
C16 C17 C18 C13 0.8(10) . . . . ?
C18 C13 C14 C15 -2.5(9) . . . . ?
C19 C20 C21 C22 2.7(12) . . . . ?
C20 C21 C22 N3 -4.9(11) . . . . ?
C22 N3 C12 N4 -176.8(5) . . . . ?
C22 N3 C12 C19 1.0(8) . . . . ?
C23 N5 C46 C45 4.5(8) . . . . ?
C23 N6 C24 C25 16.3(9) . . . . ?
C23 N6 C24 C29 -166.7(5) . . . . ?
C23 N6 C31 C30 168.7(5) . . . . ?
C23 N6 C31 C32 -13.2(9) . . . . ?
C23 N7 C44 C45 2.2(10) . . . . ?
C24 N6 C23 N5 -16.9(8) . . . . ?
C24 N6 C23 N7 163.5(5) . . . . ?
C24 N6 C31 C30 -3.4(6) . . . . ?
C24 N6 C31 C32 174.7(6) . . . . ?
C24 C25 C26 C27 -1.4(8) . . . . ?
C25 C24 C29 C28 -4.9(9) . . . . ?
C25 C24 C29 C30 172.0(5) . . . . ?
C25 C26 C27 C28 -3.3(9) . . . . ?
C25 C26 C27 C40 177.9(5) . . . . ?
C26 C27 C28 C29 4.1(9) . . . . ?
C26 C27 C40 C41 46.8(8) . . . . ?
C26 C27 C40 C42 165.3(6) . . . . ?
C26 C27 C40 C43 -72.5(7) . . . . ?
C27 C28 C29 C24 -0.3(9) . . . . ?
C27 C28 C29 C30 -176.3(6) . . . . ?
C28 C27 C40 C41 -131.9(6) . . . . ?
C28 C27 C40 C42 -13.4(9) . . . . ?
C28 C27 C40 C43 108.7(6) . . . . ?
C30 C31 C32 C33 4.6(9) . . . . ?
C29 C24 C25 Pt2 -165.0(4) . . . . ?
C29 C24 C25 C26 5.5(8) . . . . ?
C29 C30 C31 N6 0.3(6) . . . . ?
C29 C30 C31 C32 -178.1(5) . . . . ?
C29 C30 C35 C34 173.3(6) . . . . ?
C31 N6 C23 N5 172.3(5) . . . . ?
C31 N6 C23 N7 -7.2(8) . . . . ?
C31 N6 C24 C25 -171.6(5) . . . . ?
C31 N6 C24 C29 5.4(6) . . . . ?
C31 C30 C29 C24 3.0(6) . . . . ?
C31 C30 C29 C28 179.5(6) . . . . ?
C31 C30 C35 C34 1.3(9) . . . . ?
C31 C32 C33 C34 -1.9(10) . . . . ?
C32 C33 C34 C35 -1.0(10) . . . . ?
C32 C33 C34 C36 175.9(7) . . . . ?
C33 C34 C35 C30 1.3(9) . . . . ?
C33 C34 C36 C37 124.9(8) . . . . ?
C33 C34 C36 C38 5.8(11) . . . . ?
C33 C34 C36 C39 -111.5(8) . . . . ?
C35 C30 C29 C24 -169.7(6) . . . . ?
C35 C30 C29 C28 6.8(11) . . . . ?
C35 C30 C31 N6 174.0(5) . . . . ?
C35 C30 C31 C32 -4.3(8) . . . . ?
C35 C34 C36 C37 -58.2(10) . . . . ?
C35 C34 C36 C38 -177.3(8) . . . . ?
C35 C34 C36 C39 65.5(9) . . . . ?
C36 C34 C35 C30 -175.7(6) . . . . ?
C40 C27 C28 C29 -177.1(6) . . . . ?
C44 N7 C23 N5 5.3(9) . . . . ?
C44 N7 C23 N6 -175.2(5) . . . . ?
C44 C45 C46 N5 2.0(9) . . . . ?
C46 N5 C23 N6 172.0(5) . . . . ?
C46 N5 C23 N7 -8.5(8) . . . . ?
C54 C55 C56 C57 2.4(8) . . . . ?
C47 N8 C70 C69 1.6(8) . . . . ?
C47 N9 C48 C49 16.5(9) . . . . ?
C47 N9 C48 C53 -166.6(5) . . . . ?
C47 N9 C55 C54 167.9(5) . . . . ?
C47 N9 C55 C56 -16.0(9) . . . . ?
C47 N10 C68 C69 1.1(9) . . . . ?
C48 N9 C47 N8 -19.1(8) . . . . ?
C48 N9 C47 N10 160.5(5) . . . . ?
C48 N9 C55 C54 -1.2(6) . . . . ?
C48 N9 C55 C56 174.9(6) . . . . ?
C48 C49 C50 C51 -1.1(8) . . . . ?
C49 C48 C53 C54 174.0(5) . . . . ?
C49 C48 C53 C52 -5.5(9) . . . . ?
C49 C50 C51 C52 -2.2(9) . . . . ?
C49 C50 C51 C64 179.3(6) . . . . ?
C50 C51 C52 C53 1.9(9) . . . . ?
C50 C51 C64 C65 171.2(7) . . . . ?
C50 C51 C64 C66 51.5(9) . . . . ?
C50 C51 C64 C67 -67.9(8) . . . . ?
C51 C52 C53 C54 -177.7(6) . . . . ?
C51 C52 C53 C48 1.6(9) . . . . ?
C52 C51 C64 C65 -7.2(11) . . . . ?
C52 C51 C64 C66 -126.9(7) . . . . ?
C52 C51 C64 C67 113.8(7) . . . . ?
C53 C54 C55 N9 -0.6(6) . . . . ?
C53 C54 C55 C56 -177.3(5) . . . . ?
C53 C54 C59 C58 174.4(6) . . . . ?
C53 C48 C49 Pt1 -169.2(4) . . . . ?
C53 C48 C49 C50 5.0(8) . . . . ?
C55 N9 C47 N8 173.5(5) . . . . ?
C55 N9 C47 N10 -6.9(8) . . . . ?
C55 N9 C48 C49 -174.3(5) . . . . ?
C55 N9 C48 C53 2.6(6) . . . . ?
C55 C54 C53 C48 2.3(6) . . . . ?
C55 C54 C53 C52 -178.3(6) . . . . ?
C55 C54 C59 C58 -0.9(9) . . . . ?
C55 C56 C57 C58 -2.4(9) . . . . ?
C57 C58 C59 C54 1.0(9) . . . . ?
C57 C58 C60 C61 124.5(8) . . . . ?
C57 C58 C60 C62 -0.5(10) . . . . ?
C57 C58 C60 C63 -116.2(7) . . . . ?
C59 C54 C53 C48 -173.5(6) . . . . ?
C59 C54 C53 C52 5.9(11) . . . . ?
C59 C54 C55 N9 175.8(5) . . . . ?
C59 C54 C55 C56 -0.8(9) . . . . ?
C59 C58 C57 C56 0.7(9) . . . . ?
C59 C58 C60 C61 -57.2(9) . . . . ?
C59 C58 C60 C62 177.8(7) . . . . ?
C59 C58 C60 C63 62.1(8) . . . . ?
C60 C58 C57 C56 179.0(6) . . . . ?
C60 C58 C59 C54 -177.4(6) . . . . ?
C64 C51 C52 C53 -179.7(6) . . . . ?
C68 N10 C47 N8 3.5(8) . . . . ?
C68 N10 C47 N9 -176.1(5) . . . . ?
C68 C69 C70 N8 2.5(9) . . . . ?
C70 N8 C47 N9 174.8(5) . . . . ?
C70 N8 C47 N10 -4.8(8) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 1076 electrons were 
found in a volume of 3370Å³ in 1 void per unit cell. 
This is consistent with the presence of 
14[CH3OH] per Formula Unit 
which account for 72 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.896 -0.444 -0.542 3370.3 1075.8 '56 CH3OH'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
