# Supplementary Information (SI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2024

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_11tjw_auto
_database_code_depnum_ccdc_archive 'CCDC 2363301'
loop_
_audit_author_name
_audit_author_address
'Jinwen Tan'
;Sichuan Normal University
China
;
_audit_update_record             
;
2024-06-17 deposited with the CCDC.	2024-08-01 downloaded from the CCDC.
;
_audit_creation_date             2024-06-17
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'F H2 O6 P Rb S Sb'
_chemical_formula_sum            'F H2 O6 P Rb S Sb'
_chemical_formula_weight         387.27
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   15.1004(6)
_cell_length_b                   5.4481(2)
_cell_length_c                   8.8857(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     731.01(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4671
_cell_measurement_temperature    296.44(10)
_cell_measurement_theta_max      30.9020
_cell_measurement_theta_min      2.6260
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    10.894
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.48571
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.93a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic dark white'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    3.519
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             712
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_unetI/netI     0.0236
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.880
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            7757
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.880
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.792
_diffrn_reflns_theta_min         2.660
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      296.44(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.880
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -20.00  38.00   0.50    0.12    --    6.02 -99.00  90.00  116
  2  ω    -20.00  40.00   0.50    0.12    --    6.02 -99.00  60.00  120
  3  ω      0.00  80.00   0.50    0.12    --    6.02  37.00-180.00  160
  4  ω    -10.00  68.00   0.50    0.12    --    6.02  77.00-120.00  156
  5  ω     10.00  55.00   0.50    0.12    --    6.02  77.00 -60.00   90
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0238671000
_diffrn_orient_matrix_UB_12      0.0093571000
_diffrn_orient_matrix_UB_13      0.0685001000
_diffrn_orient_matrix_UB_21      0.0402163000
_diffrn_orient_matrix_UB_22      0.0088264000
_diffrn_orient_matrix_UB_23      -0.0408991000
_diffrn_orient_matrix_UB_31      -0.0044657000
_diffrn_orient_matrix_UB_32      0.1295618000
_diffrn_orient_matrix_UB_33      -0.0021702000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                980
_reflns_number_total             1101
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.43.93a (Rigaku OD, 2023)'
_computing_data_collection       
'CrysAlisPro system (CCD 43.93a 64-bit (release 17-10-2023))'
_computing_data_reduction        'CrysAlisPro 1.171.43.93a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.842
_refine_diff_density_min         -1.619
_refine_diff_density_rms         0.198
_refine_ls_extinction_coef       0.0468(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.126
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     68
_refine_ls_number_reflns         1101
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0233
_refine_ls_restrained_S_all      1.126
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0283P)²+0.2140P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0509
_refine_ls_wR_factor_ref         0.0520
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.63386(2) 0.750000 0.77258(3) 0.01659(11) Uani 1 2 d S T P . .
Rb1 Rb 0.42669(3) 0.250000 0.72077(4) 0.02979(13) Uani 1 2 d S T P . .
S1 S 0.65733(5) 0.250000 0.55792(9) 0.01697(18) Uani 1 2 d S T P . .
P1 P 0.65384(6) 1.250000 0.99696(9) 0.0177(2) Uani 1 2 d S T P . .
F1 F 0.50658(14) 0.750000 0.7708(2) 0.0255(5) Uani 1 2 d S T P . .
O1 O 0.60966(13) 1.0165(3) 0.9456(2) 0.0299(4) Uani 1 1 d . . . . .
O2 O 0.73081(17) 0.250000 0.6645(3) 0.0300(6) Uani 1 2 d S T P . .
O3 O 0.6860(2) 0.250000 0.4032(3) 0.0450(8) Uani 1 2 d S T P . .
O4 O 0.60013(13) 0.4681(4) 0.5858(2) 0.0349(5) Uani 1 1 d . . . . .
H1A H 0.660(3) 1.250000 1.151(5) 0.031(11) Uiso 1 2 d S . P . .
H1B H 0.737(3) 1.250000 0.966(5) 0.044(13) Uiso 1 2 d S . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Rb1 4.1736(4) 1_565 ?
Sb1 Rb1 4.1736(4) . ?
Sb1 F1 1.922(2) . ?
Sb1 O1 2.1462(18) 7_575 ?
Sb1 O1 2.1462(18) . ?
Sb1 O4 2.3179(19) 7_575 ?
Sb1 O4 2.3179(19) . ?
Rb1 F1 3.0121(10) 1_545 ?
Rb1 F1 3.0121(10) . ?
Rb1 O1 3.639(2) 7_575 ?
Rb1 O1 3.3462(19) 5_667 ?
Rb1 O1 3.3462(19) 3_647 ?
Rb1 O2 3.129(3) 6_557 ?
Rb1 O3 3.3952(18) 5_656 ?
Rb1 O3 3.3952(18) 5_666 ?
Rb1 O4 3.153(2) 3_646 ?
Rb1 O4 3.153(2) 5_666 ?
Rb1 O4 3.116(2) 7_565 ?
Rb1 O4 3.116(2) . ?
S1 O2 1.459(3) . ?
S1 O3 1.441(3) . ?
S1 O4 1.4897(19) . ?
S1 O4 1.4898(19) 7_565 ?
P1 O1 1.5071(19) . ?
P1 O1 1.5071(18) 7_585 ?
P1 H1A 1.38(4) . ?
P1 H1B 1.28(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Rb1 Sb1 Rb1 81.489(9) . 1_565 ?
F1 Sb1 Rb1 41.370(11) . 1_565 ?
F1 Sb1 Rb1 41.370(11) . . ?
F1 Sb1 O1 80.55(7) . 7_575 ?
F1 Sb1 O1 80.55(7) . . ?
F1 Sb1 O4 76.95(7) . . ?
F1 Sb1 O4 76.95(7) . 7_575 ?
O1 Sb1 Rb1 60.65(6) 7_575 . ?
O1 Sb1 Rb1 60.65(6) . 1_565 ?
O1 Sb1 Rb1 113.14(5) 7_575 1_565 ?
O1 Sb1 Rb1 113.14(5) . . ?
O1 Sb1 O1 85.15(10) 7_575 . ?
O1 Sb1 O4 157.49(8) . . ?
O1 Sb1 O4 157.49(8) 7_575 7_575 ?
O1 Sb1 O4 91.56(9) 7_575 . ?
O1 Sb1 O4 91.56(9) . 7_575 ?
O4 Sb1 Rb1 100.88(5) . 1_565 ?
O4 Sb1 Rb1 47.45(6) 7_575 1_565 ?
O4 Sb1 Rb1 47.45(6) . . ?
O4 Sb1 Rb1 100.88(5) 7_575 . ?
O4 Sb1 O4 83.00(10) . 7_575 ?
F1 Rb1 F1 129.48(8) 1_545 . ?
F1 Rb1 O1 45.48(5) . 7_575 ?
F1 Rb1 O1 109.12(5) 1_545 3_647 ?
F1 Rb1 O1 62.78(5) 1_545 5_667 ?
F1 Rb1 O1 86.05(5) 1_545 7_575 ?
F1 Rb1 O1 62.78(5) . 3_647 ?
F1 Rb1 O1 109.12(5) . 5_667 ?
F1 Rb1 O2 109.30(4) . 6_557 ?
F1 Rb1 O2 109.30(4) 1_545 6_557 ?
F1 Rb1 O3 61.50(6) . 5_666 ?
F1 Rb1 O3 166.93(6) . 5_656 ?
F1 Rb1 O3 166.93(6) 1_545 5_666 ?
F1 Rb1 O3 61.50(6) 1_545 5_656 ?
F1 Rb1 O4 51.34(5) . . ?
F1 Rb1 O4 74.83(5) 1_545 3_646 ?
F1 Rb1 O4 93.73(5) 1_545 . ?
F1 Rb1 O4 128.26(5) . 3_646 ?
F1 Rb1 O4 128.26(5) 1_545 5_666 ?
F1 Rb1 O4 51.34(5) 1_545 7_565 ?
F1 Rb1 O4 74.83(5) . 5_666 ?
F1 Rb1 O4 93.73(5) . 7_565 ?
O1 Rb1 O1 59.10(5) 3_647 7_575 ?
O1 Rb1 O1 51.43(6) 3_647 5_667 ?
O1 Rb1 O1 77.87(4) 5_667 7_575 ?
O1 Rb1 O3 123.60(6) 5_667 5_666 ?
O1 Rb1 O3 81.78(5) 3_647 5_666 ?
O1 Rb1 O3 81.78(5) 5_667 5_656 ?
O1 Rb1 O3 123.60(6) 3_647 5_656 ?
O2 Rb1 O1 63.66(6) 6_557 3_647 ?
O2 Rb1 O1 122.61(6) 6_557 7_575 ?
O2 Rb1 O1 63.66(6) 6_557 5_667 ?
O2 Rb1 O3 68.41(6) 6_557 5_656 ?
O2 Rb1 O3 68.41(6) 6_557 5_666 ?
O2 Rb1 O4 99.21(6) 6_557 3_646 ?
O2 Rb1 O4 99.21(6) 6_557 5_666 ?
O3 Rb1 O1 106.14(5) 5_666 7_575 ?
O3 Rb1 O1 147.03(5) 5_656 7_575 ?
O3 Rb1 O3 106.70(8) 5_656 5_666 ?
O4 Rb1 O1 137.90(5) 3_646 7_575 ?
O4 Rb1 O1 72.93(5) 7_565 7_575 ?
O4 Rb1 O1 108.26(5) . 3_647 ?
O4 Rb1 O1 122.20(5) 3_646 5_667 ?
O4 Rb1 O1 122.20(5) 5_666 3_647 ?
O4 Rb1 O1 162.86(6) 3_646 3_647 ?
O4 Rb1 O1 113.67(4) 5_666 7_575 ?
O4 Rb1 O1 55.94(5) . 7_575 ?
O4 Rb1 O1 108.26(5) 7_565 5_667 ?
O4 Rb1 O1 162.86(6) 5_666 5_667 ?
O4 Rb1 O1 130.11(5) 7_565 3_647 ?
O4 Rb1 O1 130.11(5) . 5_667 ?
O4 Rb1 O2 156.93(4) 7_565 6_557 ?
O4 Rb1 O2 156.93(4) . 6_557 ?
O4 Rb1 O3 92.65(6) 3_646 5_666 ?
O4 Rb1 O3 89.45(6) 7_565 5_656 ?
O4 Rb1 O3 42.66(6) 3_646 5_656 ?
O4 Rb1 O3 42.66(6) 5_666 5_666 ?
O4 Rb1 O3 127.03(6) . 5_656 ?
O4 Rb1 O3 89.45(6) . 5_666 ?
O4 Rb1 O3 127.03(6) 7_565 5_666 ?
O4 Rb1 O3 92.65(6) 5_666 5_656 ?
O4 Rb1 O4 65.78(6) 7_565 3_646 ?
O4 Rb1 O4 87.77(4) . 3_646 ?
O4 Rb1 O4 87.77(4) 7_565 5_666 ?
O4 Rb1 O4 65.78(6) . 5_666 ?
O4 Rb1 O4 58.29(7) 3_646 5_666 ?
O4 Rb1 O4 44.83(7) 7_565 . ?
Rb1 S1 Rb1 88.785(18) 5_656 5_666 ?
Rb1 S1 Rb1 86.741(16) . 5_656 ?
Rb1 S1 Rb1 86.741(16) . 5_666 ?
O2 S1 Rb1 131.35(5) . 5_666 ?
O2 S1 Rb1 131.35(5) . 5_656 ?
O2 S1 Rb1 116.95(12) . . ?
O2 S1 O4 109.45(10) . 7_565 ?
O2 S1 O4 109.45(10) . . ?
O3 S1 Rb1 59.41(7) . 5_666 ?
O3 S1 Rb1 130.02(13) . . ?
O3 S1 Rb1 59.41(7) . 5_656 ?
O3 S1 O2 113.03(17) . . ?
O3 S1 O4 109.43(11) . 7_565 ?
O3 S1 O4 109.43(11) . . ?
O4 S1 Rb1 118.35(8) . 5_656 ?
O4 S1 Rb1 53.18(9) . . ?
O4 S1 Rb1 50.13(8) 7_565 5_656 ?
O4 S1 Rb1 50.13(8) . 5_666 ?
O4 S1 Rb1 53.18(9) 7_565 . ?
O4 S1 Rb1 118.35(8) 7_565 5_666 ?
O4 S1 O4 105.80(18) . 7_565 ?
Rb1 P1 Rb1 88.682(19) 5_677 5_667 ?
Rb1 P1 H1A 51.7(8) 5_667 . ?
Rb1 P1 H1A 51.7(8) 5_677 . ?
Rb1 P1 H1B 116.3(14) 5_677 . ?
Rb1 P1 H1B 116.3(13) 5_667 . ?
O1 P1 Rb1 130.28(8) 7_585 5_667 ?
O1 P1 Rb1 130.28(8) . 5_677 ?
O1 P1 Rb1 57.77(8) . 5_667 ?
O1 P1 Rb1 57.77(8) 7_585 5_677 ?
O1 P1 O1 115.14(17) . 7_585 ?
O1 P1 H1A 109.4(8) 7_585 . ?
O1 P1 H1A 109.4(8) . . ?
O1 P1 H1B 111.6(9) 7_585 . ?
O1 P1 H1B 111.6(9) . . ?
H1A P1 H1B 98(3) . . ?
Sb1 F1 Rb1 113.68(4) . . ?
Sb1 F1 Rb1 113.68(4) . 1_565 ?
Rb1 F1 Rb1 129.48(8) . 1_565 ?
Sb1 O1 Rb1 111.66(7) . 5_667 ?
Sb1 O1 Rb1 88.42(6) . 1_565 ?
Rb1 O1 Rb1 120.90(5) 5_667 1_565 ?
P1 O1 Sb1 135.44(11) . . ?
P1 O1 Rb1 99.83(9) . 5_667 ?
P1 O1 Rb1 101.96(9) . 1_565 ?
S1 O2 Rb1 158.53(17) . 6_657 ?
Rb1 O3 Rb1 106.70(8) 5_656 5_666 ?
S1 O3 Rb1 99.15(9) . 5_666 ?
S1 O3 Rb1 99.15(9) . 5_656 ?
Sb1 O4 Rb1 108.91(7) . 5_666 ?
Sb1 O4 Rb1 99.31(7) . . ?
Rb1 O4 Rb1 114.22(6) . 5_666 ?
S1 O4 Sb1 121.35(11) . . ?
S1 O4 Rb1 104.31(10) . . ?
S1 O4 Rb1 108.61(10) . 5_666 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rb1 S1 O2 Rb1 180.000(1) . . . 6_657 ?
Rb1 S1 O2 Rb1 68.74(10) 5_656 . . 6_657 ?
Rb1 S1 O2 Rb1 -68.74(10) 5_666 . . 6_657 ?
Rb1 S1 O3 Rb1 -54.36(6) . . . 5_656 ?
Rb1 S1 O3 Rb1 108.71(12) 5_656 . . 5_666 ?
Rb1 S1 O3 Rb1 54.36(6) . . . 5_666 ?
Rb1 S1 O3 Rb1 -108.71(12) 5_666 . . 5_656 ?
Rb1 S1 O4 Sb1 171.56(7) 5_656 . . . ?
Rb1 S1 O4 Sb1 110.54(15) . . . . ?
Rb1 S1 O4 Sb1 -127.27(17) 5_666 . . . ?
Rb1 S1 O4 Rb1 -122.19(10) . . . 5_666 ?
Rb1 S1 O4 Rb1 122.19(10) 5_666 . . . ?
Rb1 S1 O4 Rb1 -61.17(11) 5_656 . . 5_666 ?
Rb1 S1 O4 Rb1 61.01(10) 5_656 . . . ?
Rb1 P1 O1 Sb1 169.53(9) 5_677 . . . ?
Rb1 P1 O1 Sb1 -135.2(2) 5_667 . . . ?
Rb1 P1 O1 Rb1 124.71(8) 5_667 . . 1_565 ?
Rb1 P1 O1 Rb1 -55.25(11) 5_677 . . 5_667 ?
Rb1 P1 O1 Rb1 69.46(10) 5_677 . . 1_565 ?
O1 P1 O1 Sb1 101.52(18) 7_585 . . . ?
O1 P1 O1 Rb1 -123.26(11) 7_585 . . 5_667 ?
O1 P1 O1 Rb1 1.45(16) 7_585 . . 1_565 ?
O2 S1 O3 Rb1 125.64(6) . . . 5_656 ?
O2 S1 O3 Rb1 -125.64(6) . . . 5_666 ?
O2 S1 O4 Sb1 0.91(19) . . . . ?
O2 S1 O4 Rb1 128.17(12) . . . 5_666 ?
O2 S1 O4 Rb1 -109.64(12) . . . . ?
O3 S1 O2 Rb1 0.000(1) . . . 6_657 ?
O3 S1 O4 Sb1 -123.46(16) . . . . ?
O3 S1 O4 Rb1 3.81(15) . . . 5_666 ?
O3 S1 O4 Rb1 126.00(13) . . . . ?
O4 S1 O2 Rb1 -122.24(11) . . . 6_657 ?
O4 S1 O2 Rb1 122.24(11) 7_565 . . 6_657 ?
O4 S1 O3 Rb1 -3.40(13) . . . 5_666 ?
O4 S1 O3 Rb1 112.11(9) 7_565 . . 5_666 ?
O4 S1 O3 Rb1 -112.11(9) . . . 5_656 ?
O4 S1 O3 Rb1 3.40(13) 7_565 . . 5_656 ?
O4 S1 O4 Sb1 118.74(11) 7_565 . . . ?
O4 S1 O4 Rb1 8.20(16) 7_565 . . . ?
O4 S1 O4 Rb1 -113.99(11) 7_565 . . 5_666 ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.792
_oxdiff_exptl_absorpt_empirical_full_min 0.726
