# Supplementary Information (SI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_lhc-32
_database_code_depnum_ccdc_archive 'CCDC 2393119'
loop_
_audit_author_name
_audit_author_address
'Haichao Liu'
;Jilin University
China
;
_audit_update_record             
;
2024-10-23 deposited with the CCDC.	2024-12-29 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        9-(3-(anthracen-9-yl)phenyl)-9H-carbazole
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H21 N'
_chemical_formula_sum            'C32 H21 N'
_chemical_formula_weight         419.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   8.9902(18)
_cell_length_b                   12.532(3)
_cell_length_c                   19.733(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     2223.2(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    14415
_cell_measurement_theta_min      2.98
_cell_measurement_theta_max      27.56

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.253
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             880
_exptl_absorpt_coefficient_mu    0.072
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9907
_exptl_absorpt_correction_T_max  0.9928
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21652
_diffrn_reflns_av_R_equivalents  0.0919
_diffrn_reflns_av_sigmaI/netI    0.0820
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.97
_diffrn_reflns_theta_max         27.48
_reflns_number_total             5091
_reflns_number_gt                2942
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID-AUTO (Rigaku Corporation, 1998)'
_computing_cell_refinement       RAPID-AUTO
_computing_data_reduction        
'CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2002)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0501P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -4(5)
_refine_ls_number_reflns         5091
_refine_ls_number_parameters     298
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.1074
_refine_ls_R_factor_gt           0.0549
_refine_ls_wR_factor_ref         0.1282
_refine_ls_wR_factor_gt          0.1080
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_restrained_S_all      1.000
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2169(3) 0.38236(19) 0.13248(13) 0.0498(6) Uani 1 1 d . . .
C2 C 0.0669(3) 0.3836(2) 0.10879(14) 0.0575(7) Uani 1 1 d . . .
H2 H 0.0052 0.4398 0.1214 0.069 Uiso 1 1 calc R . .
C3 C 0.0119(4) 0.3059(2) 0.06868(16) 0.0742(9) Uani 1 1 d . . .
H3 H -0.0855 0.3099 0.0530 0.089 Uiso 1 1 calc R . .
C4 C 0.1018(5) 0.2190(3) 0.05066(16) 0.0826(10) Uani 1 1 d . . .
H4 H 0.0634 0.1664 0.0224 0.099 Uiso 1 1 calc R . .
C5 C 0.2422(5) 0.2102(2) 0.07325(17) 0.0776(10) Uani 1 1 d . . .
H5 H 0.2983 0.1505 0.0619 0.093 Uiso 1 1 calc R . .
C6 C 0.3065(4) 0.2922(2) 0.11468(15) 0.0615(8) Uani 1 1 d . . .
C7 C 0.4511(4) 0.2859(2) 0.13866(16) 0.0709(9) Uani 1 1 d U . .
H7 H 0.5080 0.2261 0.1283 0.085 Uiso 1 1 calc R . .
C8 C 0.5134(3) 0.3668(2) 0.17782(15) 0.0607(7) Uani 1 1 d U . .
C9 C 0.6638(3) 0.3609(3) 0.20178(19) 0.0797(10) Uani 1 1 d . . .
H9 H 0.7205 0.3005 0.1926 0.096 Uiso 1 1 calc R . .
C10 C 0.7238(4) 0.4416(3) 0.2374(2) 0.0853(11) Uani 1 1 d . . .
H10 H 0.8216 0.4364 0.2524 0.102 Uiso 1 1 calc R . .
C11 C 0.6411(3) 0.5335(3) 0.25236(17) 0.0743(9) Uani 1 1 d . . .
H11 H 0.6846 0.5888 0.2767 0.089 Uiso 1 1 calc R . .
C12 C 0.4975(3) 0.5419(2) 0.23141(15) 0.0588(7) Uani 1 1 d . . .
H12 H 0.4442 0.6035 0.2415 0.071 Uiso 1 1 calc R . .
C13 C 0.4268(3) 0.4589(2) 0.19449(14) 0.0509(6) Uani 1 1 d . . .
C14 C 0.2770(3) 0.46460(19) 0.17234(13) 0.0454(6) Uani 1 1 d . . .
C15 C 0.1824(2) 0.55618(18) 0.19329(13) 0.0424(6) Uani 1 1 d . . .
C16 C 0.1323(3) 0.62982(18) 0.14556(12) 0.0430(6) Uani 1 1 d . . .
H16 H 0.1583 0.6216 0.1002 0.052 Uiso 1 1 calc R . .
C17 C 0.0440(2) 0.71544(18) 0.16504(13) 0.0422(6) Uani 1 1 d . . .
C18 C 0.0021(3) 0.7264(2) 0.23254(13) 0.0481(6) Uani 1 1 d . . .
H18 H -0.0560 0.7839 0.2461 0.058 Uiso 1 1 calc R . .
C19 C 0.0473(3) 0.6511(2) 0.27937(14) 0.0521(7) Uani 1 1 d . . .
H19 H 0.0169 0.6571 0.3243 0.063 Uiso 1 1 calc R . .
C20 C 0.1371(3) 0.5669(2) 0.26009(13) 0.0488(6) Uani 1 1 d . . .
H20 H 0.1674 0.5171 0.2922 0.059 Uiso 1 1 calc R . .
C21 C 0.0839(3) 0.83738(18) 0.06445(13) 0.0461(6) Uani 1 1 d . . .
C22 C 0.2330(3) 0.8198(2) 0.04847(15) 0.0569(7) Uani 1 1 d . . .
H22 H 0.2923 0.7744 0.0742 0.068 Uiso 1 1 calc R . .
C23 C 0.2885(4) 0.8734(3) -0.00772(17) 0.0719(9) Uani 1 1 d . . .
H23 H 0.3872 0.8631 -0.0203 0.086 Uiso 1 1 calc R . .
C24 C 0.1997(5) 0.9424(2) -0.04581(17) 0.0776(10) Uani 1 1 d . . .
H24 H 0.2392 0.9758 -0.0839 0.093 Uiso 1 1 calc R . .
C25 C 0.0556(4) 0.9613(2) -0.02775(17) 0.0715(9) Uani 1 1 d . . .
H25 H -0.0022 1.0085 -0.0528 0.086 Uiso 1 1 calc R . .
C26 C -0.0036(3) 0.91002(19) 0.02775(14) 0.0550(7) Uani 1 1 d . . .
C27 C -0.1494(3) 0.91180(19) 0.06008(15) 0.0577(7) Uani 1 1 d . . .
C28 C -0.2792(4) 0.9686(2) 0.04785(19) 0.0763(10) Uani 1 1 d . . .
H28 H -0.2819 1.0201 0.0139 0.092 Uiso 1 1 calc R . .
C29 C -0.4025(4) 0.9485(3) 0.0858(2) 0.0856(12) Uani 1 1 d . . .
H29 H -0.4887 0.9879 0.0784 0.103 Uiso 1 1 calc R . .
C30 C -0.4012(3) 0.8696(3) 0.13547(18) 0.0750(10) Uani 1 1 d . . .
H30 H -0.4881 0.8548 0.1593 0.090 Uiso 1 1 calc R . .
C31 C -0.2728(3) 0.8125(2) 0.15016(16) 0.0580(7) Uani 1 1 d . . .
H31 H -0.2715 0.7601 0.1835 0.070 Uiso 1 1 calc R . .
C32 C -0.1469(3) 0.83733(18) 0.11297(14) 0.0482(6) Uani 1 1 d . . .
N1 N -0.0024(2) 0.79248(15) 0.11650(11) 0.0466(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C14 1.404(3) . ?
C1 C2 1.427(4) . ?
C1 C6 1.431(4) . ?
C2 C3 1.349(4) . ?
C2 H2 0.9300 . ?
C3 C4 1.402(5) . ?
C3 H3 0.9300 . ?
C4 C5 1.343(5) . ?
C4 H4 0.9300 . ?
C5 C6 1.434(4) . ?
C5 H5 0.9300 . ?
C6 C7 1.385(4) . ?
C7 C8 1.392(4) . ?
C7 H7 0.9300 . ?
C8 C13 1.430(4) . ?
C8 C9 1.435(4) . ?
C9 C10 1.345(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.402(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.360(4) . ?
C11 H11 0.9300 . ?
C12 C13 1.420(4) . ?
C12 H12 0.9300 . ?
C13 C14 1.418(3) . ?
C14 C15 1.487(3) . ?
C15 C20 1.386(3) . ?
C15 C16 1.393(3) . ?
C16 C17 1.389(3) . ?
C16 H16 0.9300 . ?
C17 C18 1.391(3) . ?
C17 N1 1.423(3) . ?
C18 C19 1.382(4) . ?
C18 H18 0.9300 . ?
C19 C20 1.382(3) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 C22 1.394(4) . ?
C21 C26 1.405(3) . ?
C21 N1 1.405(3) . ?
C22 C23 1.389(4) . ?
C22 H22 0.9300 . ?
C23 C24 1.396(5) . ?
C23 H23 0.9300 . ?
C24 C25 1.364(5) . ?
C24 H24 0.9300 . ?
C25 C26 1.377(4) . ?
C25 H25 0.9300 . ?
C26 C27 1.458(4) . ?
C27 C28 1.388(4) . ?
C27 C32 1.400(4) . ?
C28 C29 1.361(5) . ?
C28 H28 0.9300 . ?
C29 C30 1.392(5) . ?
C29 H29 0.9300 . ?
C30 C31 1.388(4) . ?
C30 H30 0.9300 . ?
C31 C32 1.385(4) . ?
C31 H31 0.9300 . ?
C32 N1 1.417(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C14 C1 C2 122.6(2) . . ?
C14 C1 C6 120.0(3) . . ?
C2 C1 C6 117.4(3) . . ?
C3 C2 C1 122.0(3) . . ?
C3 C2 H2 119.0 . . ?
C1 C2 H2 119.0 . . ?
C2 C3 C4 119.9(3) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 H3 120.1 . . ?
C5 C4 C3 121.4(3) . . ?
C5 C4 H4 119.3 . . ?
C3 C4 H4 119.3 . . ?
C4 C5 C6 120.6(3) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C7 C6 C1 119.3(3) . . ?
C7 C6 C5 122.1(3) . . ?
C1 C6 C5 118.6(3) . . ?
C6 C7 C8 121.7(3) . . ?
C6 C7 H7 119.1 . . ?
C8 C7 H7 119.1 . . ?
C7 C8 C13 119.7(3) . . ?
C7 C8 C9 121.6(3) . . ?
C13 C8 C9 118.6(3) . . ?
C10 C9 C8 120.7(3) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C9 C10 C11 121.0(3) . . ?
C9 C10 H10 119.5 . . ?
C11 C10 H10 119.5 . . ?
C12 C11 C10 120.2(3) . . ?
C12 C11 H11 119.9 . . ?
C10 C11 H11 119.9 . . ?
C11 C12 C13 121.6(3) . . ?
C11 C12 H12 119.2 . . ?
C13 C12 H12 119.2 . . ?
C14 C13 C12 123.1(2) . . ?
C14 C13 C8 119.1(3) . . ?
C12 C13 C8 117.8(2) . . ?
C1 C14 C13 120.1(2) . . ?
C1 C14 C15 120.2(2) . . ?
C13 C14 C15 119.8(2) . . ?
C20 C15 C16 118.9(2) . . ?
C20 C15 C14 120.5(2) . . ?
C16 C15 C14 120.5(2) . . ?
C17 C16 C15 120.6(2) . . ?
C17 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
C16 C17 C18 119.7(2) . . ?
C16 C17 N1 120.4(2) . . ?
C18 C17 N1 119.9(2) . . ?
C19 C18 C17 119.6(2) . . ?
C19 C18 H18 120.2 . . ?
C17 C18 H18 120.2 . . ?
C18 C19 C20 120.6(2) . . ?
C18 C19 H19 119.7 . . ?
C20 C19 H19 119.7 . . ?
C19 C20 C15 120.5(2) . . ?
C19 C20 H20 119.7 . . ?
C15 C20 H20 119.7 . . ?
C22 C21 C26 121.6(3) . . ?
C22 C21 N1 129.3(2) . . ?
C26 C21 N1 109.1(2) . . ?
C23 C22 C21 116.7(3) . . ?
C23 C22 H22 121.6 . . ?
C21 C22 H22 121.6 . . ?
C22 C23 C24 121.6(3) . . ?
C22 C23 H23 119.2 . . ?
C24 C23 H23 119.2 . . ?
C25 C24 C23 120.6(3) . . ?
C25 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C24 C25 C26 119.6(3) . . ?
C24 C25 H25 120.2 . . ?
C26 C25 H25 120.2 . . ?
C25 C26 C21 119.7(3) . . ?
C25 C26 C27 133.5(3) . . ?
C21 C26 C27 106.7(2) . . ?
C28 C27 C32 119.0(3) . . ?
C28 C27 C26 133.4(3) . . ?
C32 C27 C26 107.6(2) . . ?
C29 C28 C27 119.6(3) . . ?
C29 C28 H28 120.2 . . ?
C27 C28 H28 120.2 . . ?
C28 C29 C30 120.8(3) . . ?
C28 C29 H29 119.6 . . ?
C30 C29 H29 119.6 . . ?
C31 C30 C29 121.3(3) . . ?
C31 C30 H30 119.3 . . ?
C29 C30 H30 119.3 . . ?
C32 C31 C30 117.0(3) . . ?
C32 C31 H31 121.5 . . ?
C30 C31 H31 121.5 . . ?
C31 C32 C27 122.1(2) . . ?
C31 C32 N1 129.4(2) . . ?
C27 C32 N1 108.4(2) . . ?
C21 N1 C32 108.1(2) . . ?
C21 N1 C17 127.03(19) . . ?
C32 N1 C17 124.8(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C14 C1 C2 C3 177.8(3) . . . . ?
C6 C1 C2 C3 -2.8(4) . . . . ?
C1 C2 C3 C4 1.8(4) . . . . ?
C2 C3 C4 C5 0.9(5) . . . . ?
C3 C4 C5 C6 -2.4(5) . . . . ?
C14 C1 C6 C7 1.7(4) . . . . ?
C2 C1 C6 C7 -177.7(2) . . . . ?
C14 C1 C6 C5 -179.3(2) . . . . ?
C2 C1 C6 C5 1.3(4) . . . . ?
C4 C5 C6 C7 -179.8(3) . . . . ?
C4 C5 C6 C1 1.2(4) . . . . ?
C1 C6 C7 C8 -2.2(4) . . . . ?
C5 C6 C7 C8 178.8(3) . . . . ?
C6 C7 C8 C13 0.5(4) . . . . ?
C6 C7 C8 C9 -179.1(3) . . . . ?
C7 C8 C9 C10 177.5(3) . . . . ?
C13 C8 C9 C10 -2.0(5) . . . . ?
C8 C9 C10 C11 0.2(5) . . . . ?
C9 C10 C11 C12 0.6(5) . . . . ?
C10 C11 C12 C13 0.4(5) . . . . ?
C11 C12 C13 C14 179.5(3) . . . . ?
C11 C12 C13 C8 -2.1(4) . . . . ?
C7 C8 C13 C14 1.8(4) . . . . ?
C9 C8 C13 C14 -178.6(3) . . . . ?
C7 C8 C13 C12 -176.7(3) . . . . ?
C9 C8 C13 C12 2.9(4) . . . . ?
C2 C1 C14 C13 179.9(2) . . . . ?
C6 C1 C14 C13 0.5(4) . . . . ?
C2 C1 C14 C15 1.9(4) . . . . ?
C6 C1 C14 C15 -177.5(2) . . . . ?
C12 C13 C14 C1 176.1(2) . . . . ?
C8 C13 C14 C1 -2.3(4) . . . . ?
C12 C13 C14 C15 -5.8(4) . . . . ?
C8 C13 C14 C15 175.8(2) . . . . ?
C1 C14 C15 C20 108.5(3) . . . . ?
C13 C14 C15 C20 -69.6(3) . . . . ?
C1 C14 C15 C16 -68.6(3) . . . . ?
C13 C14 C15 C16 113.4(3) . . . . ?
C20 C15 C16 C17 2.9(3) . . . . ?
C14 C15 C16 C17 180.0(2) . . . . ?
C15 C16 C17 C18 -1.6(3) . . . . ?
C15 C16 C17 N1 177.7(2) . . . . ?
C16 C17 C18 C19 -0.8(3) . . . . ?
N1 C17 C18 C19 179.9(2) . . . . ?
C17 C18 C19 C20 1.9(4) . . . . ?
C18 C19 C20 C15 -0.5(4) . . . . ?
C16 C15 C20 C19 -1.9(4) . . . . ?
C14 C15 C20 C19 -178.9(2) . . . . ?
C26 C21 C22 C23 -3.3(4) . . . . ?
N1 C21 C22 C23 178.1(2) . . . . ?
C21 C22 C23 C24 0.7(4) . . . . ?
C22 C23 C24 C25 1.7(5) . . . . ?
C23 C24 C25 C26 -1.4(5) . . . . ?
C24 C25 C26 C21 -1.2(4) . . . . ?
C24 C25 C26 C27 -180.0(3) . . . . ?
C22 C21 C26 C25 3.6(4) . . . . ?
N1 C21 C26 C25 -177.5(2) . . . . ?
C22 C21 C26 C27 -177.3(2) . . . . ?
N1 C21 C26 C27 1.6(3) . . . . ?
C25 C26 C27 C28 -2.6(5) . . . . ?
C21 C26 C27 C28 178.5(3) . . . . ?
C25 C26 C27 C32 176.4(3) . . . . ?
C21 C26 C27 C32 -2.5(3) . . . . ?
C32 C27 C28 C29 -2.2(4) . . . . ?
C26 C27 C28 C29 176.8(3) . . . . ?
C27 C28 C29 C30 -1.8(5) . . . . ?
C28 C29 C30 C31 3.1(5) . . . . ?
C29 C30 C31 C32 -0.3(4) . . . . ?
C30 C31 C32 C27 -3.7(4) . . . . ?
C30 C31 C32 N1 -179.6(3) . . . . ?
C28 C27 C32 C31 5.0(4) . . . . ?
C26 C27 C32 C31 -174.2(2) . . . . ?
C28 C27 C32 N1 -178.4(2) . . . . ?
C26 C27 C32 N1 2.5(3) . . . . ?
C22 C21 N1 C32 178.7(2) . . . . ?
C26 C21 N1 C32 -0.1(3) . . . . ?
C22 C21 N1 C17 -1.3(4) . . . . ?
C26 C21 N1 C17 179.9(2) . . . . ?
C31 C32 N1 C21 174.8(2) . . . . ?
C27 C32 N1 C21 -1.5(3) . . . . ?
C31 C32 N1 C17 -5.3(4) . . . . ?
C27 C32 N1 C17 178.5(2) . . . . ?
C16 C17 N1 C21 -41.9(3) . . . . ?
C18 C17 N1 C21 137.5(2) . . . . ?
C16 C17 N1 C32 138.2(2) . . . . ?
C18 C17 N1 C32 -42.5(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.166
_refine_diff_density_min         -0.171
_refine_diff_density_rms         0.039
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: dichloromethane and methanol'
_exptl_crystal_preparation       Luminescent
