# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
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# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
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# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_gv_sg_605_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2444264'
_audit_update_record             
;
2025-04-16 deposited with the CCDC.	2025-06-04 downloaded from the CCDC.
;
_audit_creation_date             2025-04-16
_audit_creation_method           
;
Olex2 1.5-beta
(compiled 2021.11.18 svn.ra9532c28 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
loop_
_audit_author_email
ganesh.v@chem.iitkgp.ac.in
?
_chemical_name_common            ?
_chemical_name_systematic        
(E)-4-(2-(4-methoxyphenyl)-1,4-diphenylbut-1-en-3-yn-1-yl)benzonitrile
_chemical_formula_moiety         'C30 H21 N O'
_chemical_formula_sum            'C30 H21 N O'
_chemical_formula_weight         411.48
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.762(2)
_cell_length_b                   19.290(4)
_cell_length_c                   13.150(3)
_cell_angle_alpha                90
_cell_angle_beta                 110.326(6)
_cell_angle_gamma                90
_cell_volume                     2322.0(8)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    6851
_cell_measurement_temperature    301(2)
_cell_measurement_theta_max      22.18
_cell_measurement_theta_min      2.22
_shelx_estimated_absorpt_T_max   0.986
_shelx_estimated_absorpt_T_min   0.972
_exptl_absorpt_coefficient_mu    0.071
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.6271
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1057 before and 0.0866 after correction.
The Ratio of minimum to maximum transmission is 0.8414.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear yellowish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.177
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             864
_exptl_crystal_preparation       'borylation reaction'
_exptl_crystal_recrystallization_method 'slow evaporation'
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0997
_diffrn_reflns_av_unetI/netI     0.0438
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            55386
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        24.992
_diffrn_reflns_theta_max         24.992
_diffrn_reflns_theta_min         1.960
_diffrn_ambient_temperature      301.40
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2581
_reflns_number_total             4088
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5-beta (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-beta (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.225
_refine_diff_density_min         -0.133
_refine_diff_density_rms         0.034
_refine_ls_extinction_coef       0.030(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     291
_refine_ls_number_reflns         4088
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0907
_refine_ls_R_factor_gt           0.0492
_refine_ls_restrained_S_all      1.080
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0769P)²+0.0794P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1320
_refine_ls_wR_factor_ref         0.1507
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C9(H9), C10(H10), C13(H13), C14(H14), C17(H17), C18(H18),
 C19(H19), C20(H20), C21(H21), C22(H22), C23(H23), C25(H25), C26(H26), C27(H27),
  C28(H28), C29(H29)
2.b Idealised Me refined as rotating group:
 C12(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O -0.11409(15) 0.49267(9) 0.31033(11) 0.0820(5) Uani 1 1 d . . . . .
N1 N 0.1817(3) 0.68662(12) -0.10782(17) 0.1075(8) Uani 1 1 d . . . . .
C30 C 0.5099(2) 0.60590(10) 0.61448(15) 0.0563(5) Uani 1 1 d . . . . .
C1 C 0.2377(3) 0.68123(12) -0.01586(18) 0.0750(6) Uani 1 1 d . . . . .
C2 C 0.3072(2) 0.67526(10) 0.09937(15) 0.0581(5) Uani 1 1 d . . . . .
C3 C 0.3433(2) 0.73453(10) 0.16315(16) 0.0615(5) Uani 1 1 d . . . . .
H3 H 0.323046 0.778113 0.131165 0.074 Uiso 1 1 calc R U . . .
C4 C 0.4091(2) 0.72859(10) 0.27378(15) 0.0584(5) Uani 1 1 d . . . . .
H4 H 0.435671 0.768414 0.315954 0.070 Uiso 1 1 calc R U . . .
C5 C 0.43650(19) 0.66375(9) 0.32356(14) 0.0525(5) Uani 1 1 d . . . . .
C6 C 0.50379(19) 0.65806(9) 0.44394(14) 0.0533(5) Uani 1 1 d . . . . .
C7 C 0.43927(19) 0.61911(9) 0.50117(14) 0.0515(5) Uani 1 1 d . . . . .
C8 C 0.29301(19) 0.58550(9) 0.45185(13) 0.0497(5) Uani 1 1 d . . . . .
C9 C 0.2742(2) 0.51631(10) 0.47123(15) 0.0572(5) Uani 1 1 d . . . . .
H9 H 0.353225 0.491313 0.516695 0.069 Uiso 1 1 calc R U . . .
C10 C 0.1412(2) 0.48317(10) 0.42499(16) 0.0618(5) Uani 1 1 d . . . . .
H10 H 0.132100 0.436311 0.437982 0.074 Uiso 1 1 calc R U . . .
C11 C 0.0230(2) 0.51993(11) 0.35984(14) 0.0591(5) Uani 1 1 d . . . . .
C12 C -0.1332(3) 0.42046(14) 0.3266(2) 0.0934(8) Uani 1 1 d . . . . .
H12A H -0.069307 0.393801 0.300333 0.140 Uiso 1 1 calc R U . . .
H12B H -0.232666 0.407544 0.287767 0.140 Uiso 1 1 calc R U . . .
H12C H -0.110320 0.411600 0.402521 0.140 Uiso 1 1 calc R U . . .
C13 C 0.1711(2) 0.62178(10) 0.38629(14) 0.0580(5) Uani 1 1 d . . . . .
H13 H 0.179761 0.668568 0.372548 0.070 Uiso 1 1 calc R U . . .
C14 C 0.0384(2) 0.58949(11) 0.34162(15) 0.0636(5) Uani 1 1 d . . . . .
H14 H -0.042071 0.614737 0.298635 0.076 Uiso 1 1 calc R U . . .
C15 C 0.5651(2) 0.59420(10) 0.70953(16) 0.0594(5) Uani 1 1 d . . . . .
C16 C 0.6445(2) 0.58386(10) 0.82255(15) 0.0644(6) Uani 1 1 d . . . . .
C17 C 0.7952(3) 0.58243(14) 0.8582(2) 0.0984(9) Uani 1 1 d . . . . .
H17 H 0.843893 0.588927 0.809379 0.118 Uiso 1 1 calc R U . . .
C18 C 0.8735(4) 0.57127(18) 0.9671(3) 0.1407(14) Uani 1 1 d . . . . .
H18 H 0.975084 0.570382 0.991517 0.169 Uiso 1 1 calc R U . . .
C19 C 0.8022(6) 0.56159(18) 1.0386(3) 0.1407(16) Uani 1 1 d . . . . .
H19 H 0.855315 0.553208 1.111268 0.169 Uiso 1 1 calc R U . . .
C20 C 0.6550(5) 0.56407(16) 1.0045(2) 0.1255(12) Uani 1 1 d . . . . .
H20 H 0.607010 0.558250 1.053886 0.151 Uiso 1 1 calc R U . . .
C21 C 0.5760(3) 0.57523(13) 0.89658(19) 0.0928(8) Uani 1 1 d . . . . .
H21 H 0.474554 0.576937 0.873603 0.111 Uiso 1 1 calc R U . . .
C22 C 0.3377(2) 0.61041(11) 0.14800(16) 0.0676(6) Uani 1 1 d . . . . .
H22 H 0.314855 0.570560 0.105609 0.081 Uiso 1 1 calc R U . . .
C23 C 0.4015(2) 0.60514(10) 0.25828(15) 0.0650(6) Uani 1 1 d . . . . .
H23 H 0.421846 0.561506 0.290060 0.078 Uiso 1 1 calc R U . . .
C24 C 0.6461(2) 0.69384(10) 0.49539(15) 0.0574(5) Uani 1 1 d . . . . .
C25 C 0.7485(2) 0.69449(12) 0.44390(19) 0.0764(6) Uani 1 1 d . . . . .
H25 H 0.725412 0.674505 0.375625 0.092 Uiso 1 1 calc R U . . .
C26 C 0.8843(3) 0.72438(15) 0.4926(2) 0.0970(8) Uani 1 1 d . . . . .
H26 H 0.951840 0.724112 0.457232 0.116 Uiso 1 1 calc R U . . .
C27 C 0.9196(3) 0.75431(15) 0.5926(2) 0.1013(9) Uani 1 1 d . . . . .
H27 H 1.011024 0.774385 0.625159 0.122 Uiso 1 1 calc R U . . .
C28 C 0.8212(3) 0.75476(14) 0.6444(2) 0.0967(8) Uani 1 1 d . . . . .
H28 H 0.845868 0.774489 0.712985 0.116 Uiso 1 1 calc R U . . .
C29 C 0.6840(2) 0.72589(11) 0.59540(18) 0.0768(7) Uani 1 1 d . . . . .
H29 H 0.616157 0.728117 0.630435 0.092 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C11 1.374(2) . ?
O1 C12 1.431(3) . ?
N1 C1 1.146(2) . ?
C30 C7 1.431(2) . ?
C30 C15 1.198(2) . ?
C1 C2 1.434(3) . ?
C2 C3 1.389(3) . ?
C2 C22 1.389(3) . ?
C3 H3 0.9300 . ?
C3 C4 1.376(3) . ?
C4 H4 0.9300 . ?
C4 C5 1.394(2) . ?
C5 C6 1.492(2) . ?
C5 C23 1.389(3) . ?
C6 C7 1.363(3) . ?
C6 C24 1.487(3) . ?
C7 C8 1.495(2) . ?
C8 C9 1.383(3) . ?
C8 C13 1.391(2) . ?
C9 H9 0.9300 . ?
C9 C10 1.384(3) . ?
C10 H10 0.9300 . ?
C10 C11 1.372(3) . ?
C11 C14 1.380(3) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 H13 0.9300 . ?
C13 C14 1.373(3) . ?
C14 H14 0.9300 . ?
C15 C16 1.432(3) . ?
C16 C17 1.380(3) . ?
C16 C21 1.370(3) . ?
C17 H17 0.9300 . ?
C17 C18 1.387(4) . ?
C18 H18 0.9300 . ?
C18 C19 1.363(5) . ?
C19 H19 0.9300 . ?
C19 C20 1.349(5) . ?
C20 H20 0.9300 . ?
C20 C21 1.377(4) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C22 C23 1.369(3) . ?
C23 H23 0.9300 . ?
C24 C25 1.389(3) . ?
C24 C29 1.382(3) . ?
C25 H25 0.9300 . ?
C25 C26 1.382(3) . ?
C26 H26 0.9300 . ?
C26 C27 1.366(4) . ?
C27 H27 0.9300 . ?
C27 C28 1.357(3) . ?
C28 H28 0.9300 . ?
C28 C29 1.385(3) . ?
C29 H29 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 O1 C12 117.24(17) . . ?
C15 C30 C7 178.0(2) . . ?
N1 C1 C2 179.3(3) . . ?
C3 C2 C1 119.98(18) . . ?
C3 C2 C22 119.62(17) . . ?
C22 C2 C1 120.39(18) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 C2 119.82(18) . . ?
C4 C3 H3 120.1 . . ?
C3 C4 H4 119.5 . . ?
C3 C4 C5 120.95(18) . . ?
C5 C4 H4 119.5 . . ?
C4 C5 C6 120.41(16) . . ?
C23 C5 C4 118.32(17) . . ?
C23 C5 C6 121.27(16) . . ?
C7 C6 C5 120.59(16) . . ?
C7 C6 C24 122.87(16) . . ?
C24 C6 C5 116.48(16) . . ?
C30 C7 C8 114.61(16) . . ?
C6 C7 C30 121.70(16) . . ?
C6 C7 C8 123.67(16) . . ?
C9 C8 C7 120.43(15) . . ?
C9 C8 C13 117.37(17) . . ?
C13 C8 C7 122.19(16) . . ?
C8 C9 H9 119.0 . . ?
C8 C9 C10 121.96(17) . . ?
C10 C9 H9 119.0 . . ?
C9 C10 H10 120.2 . . ?
C11 C10 C9 119.53(18) . . ?
C11 C10 H10 120.2 . . ?
O1 C11 C14 115.88(17) . . ?
C10 C11 O1 124.62(19) . . ?
C10 C11 C14 119.50(17) . . ?
O1 C12 H12A 109.5 . . ?
O1 C12 H12B 109.5 . . ?
O1 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C8 C13 H13 119.5 . . ?
C14 C13 C8 120.93(18) . . ?
C14 C13 H13 119.5 . . ?
C11 C14 H14 119.7 . . ?
C13 C14 C11 120.67(17) . . ?
C13 C14 H14 119.7 . . ?
C30 C15 C16 173.9(2) . . ?
C17 C16 C15 119.0(2) . . ?
C21 C16 C15 122.2(2) . . ?
C21 C16 C17 118.9(2) . . ?
C16 C17 H17 120.2 . . ?
C16 C17 C18 119.6(3) . . ?
C18 C17 H17 120.2 . . ?
C17 C18 H18 119.9 . . ?
C19 C18 C17 120.2(4) . . ?
C19 C18 H18 119.9 . . ?
C18 C19 H19 119.8 . . ?
C20 C19 C18 120.5(3) . . ?
C20 C19 H19 119.8 . . ?
C19 C20 H20 120.1 . . ?
C19 C20 C21 119.9(3) . . ?
C21 C20 H20 120.1 . . ?
C16 C21 C20 121.0(3) . . ?
C16 C21 H21 119.5 . . ?
C20 C21 H21 119.5 . . ?
C2 C22 H22 120.0 . . ?
C23 C22 C2 120.02(18) . . ?
C23 C22 H22 120.0 . . ?
C5 C23 H23 119.4 . . ?
C22 C23 C5 121.21(18) . . ?
C22 C23 H23 119.4 . . ?
C25 C24 C6 119.96(18) . . ?
C29 C24 C6 122.65(18) . . ?
C29 C24 C25 117.37(19) . . ?
C24 C25 H25 119.5 . . ?
C26 C25 C24 121.0(2) . . ?
C26 C25 H25 119.5 . . ?
C25 C26 H26 119.9 . . ?
C27 C26 C25 120.2(2) . . ?
C27 C26 H26 119.9 . . ?
C26 C27 H27 120.0 . . ?
C28 C27 C26 120.0(2) . . ?
C28 C27 H27 120.0 . . ?
C27 C28 H28 119.9 . . ?
C27 C28 C29 120.1(2) . . ?
C29 C28 H28 119.9 . . ?
C24 C29 C28 121.2(2) . . ?
C24 C29 H29 119.4 . . ?
C28 C29 H29 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C11 C14 C13 -179.30(18) . . . . ?
C30 C7 C8 C9 -47.7(2) . . . . ?
C30 C7 C8 C13 131.71(19) . . . . ?
C1 C2 C3 C4 179.58(18) . . . . ?
C1 C2 C22 C23 -178.7(2) . . . . ?
C2 C3 C4 C5 -1.9(3) . . . . ?
C2 C22 C23 C5 0.2(3) . . . . ?
C3 C2 C22 C23 0.8(3) . . . . ?
C3 C4 C5 C6 -178.12(17) . . . . ?
C3 C4 C5 C23 2.8(3) . . . . ?
C4 C5 C6 C7 127.0(2) . . . . ?
C4 C5 C6 C24 -56.0(2) . . . . ?
C4 C5 C23 C22 -1.9(3) . . . . ?
C5 C6 C7 C30 172.30(16) . . . . ?
C5 C6 C7 C8 -6.1(3) . . . . ?
C5 C6 C24 C25 -37.6(3) . . . . ?
C5 C6 C24 C29 144.0(2) . . . . ?
C6 C5 C23 C22 178.97(18) . . . . ?
C6 C7 C8 C9 130.9(2) . . . . ?
C6 C7 C8 C13 -49.7(3) . . . . ?
C6 C24 C25 C26 -176.7(2) . . . . ?
C6 C24 C29 C28 175.6(2) . . . . ?
C7 C6 C24 C25 139.4(2) . . . . ?
C7 C6 C24 C29 -39.1(3) . . . . ?
C7 C8 C9 C10 -178.53(18) . . . . ?
C7 C8 C13 C14 179.65(17) . . . . ?
C8 C9 C10 C11 -1.5(3) . . . . ?
C8 C13 C14 C11 -0.7(3) . . . . ?
C9 C8 C13 C14 -1.0(3) . . . . ?
C9 C10 C11 O1 -179.57(18) . . . . ?
C9 C10 C11 C14 -0.2(3) . . . . ?
C10 C11 C14 C13 1.3(3) . . . . ?
C12 O1 C11 C10 -1.3(3) . . . . ?
C12 O1 C11 C14 179.27(19) . . . . ?
C13 C8 C9 C10 2.1(3) . . . . ?
C15 C16 C17 C18 -178.9(2) . . . . ?
C15 C16 C21 C20 178.8(2) . . . . ?
C16 C17 C18 C19 0.2(5) . . . . ?
C17 C16 C21 C20 -1.1(4) . . . . ?
C17 C18 C19 C20 -1.3(6) . . . . ?
C18 C19 C20 C21 1.2(6) . . . . ?
C19 C20 C21 C16 0.1(5) . . . . ?
C21 C16 C17 C18 1.0(4) . . . . ?
C22 C2 C3 C4 0.1(3) . . . . ?
C23 C5 C6 C7 -53.9(3) . . . . ?
C23 C5 C6 C24 123.1(2) . . . . ?
C24 C6 C7 C30 -4.6(3) . . . . ?
C24 C6 C7 C8 177.00(16) . . . . ?
C24 C25 C26 C27 -0.4(4) . . . . ?
C25 C24 C29 C28 -2.8(3) . . . . ?
C25 C26 C27 C28 0.0(5) . . . . ?
C26 C27 C28 C29 -1.0(5) . . . . ?
C27 C28 C29 C24 2.5(4) . . . . ?
C29 C24 C25 C26 1.8(3) . . . . ?


_olex2_exptl_crystal_mounting_method 'loop mounting'
_olex2_submission_original_sample_id GV_SG-605
_olex2_submission_special_instructions 'No special instructions were received'
