# Supplementary Information (SI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_gs_jr_p4
_database_code_depnum_ccdc_archive 'CCDC 2466394'
loop_
_audit_author_name
_audit_author_address
Ramanababu
;IITH
India
;
_audit_update_record             
;
2025-06-23 deposited with the CCDC.	2025-08-20 downloaded from the CCDC.
;
_audit_creation_date             2025-06-09
_audit_creation_method           
;
Olex2 1.5-alpha
(compiled 2025.05.31 svn.r86d253d1 for OlexSys, GUI svn.r7254)
;
_shelx_SHELXL_version_number     2019/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C28 H24 N O2 P'
_chemical_formula_sum            'C28 H24 N O2 P'
_chemical_formula_weight         437.45
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           7
_space_group_name_H-M_alt        'P 1 n 1'
_space_group_name_Hall           'P -2yac'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y, z+1/2'

_cell_length_a                   6.0125(10)
_cell_length_b                   12.501(2)
_cell_length_c                   15.039(3)
_cell_angle_alpha                90
_cell_angle_beta                 96.181(6)
_cell_angle_gamma                90
_cell_volume                     1123.8(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    5137
_cell_measurement_temperature    298
_cell_measurement_theta_max      21.333
_cell_measurement_theta_min      2.724
_shelx_estimated_absorpt_T_max   0.978
_shelx_estimated_absorpt_T_min   0.960
_exptl_absorpt_coefficient_mu    0.148
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.6103
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1291 before and 0.0781 after correction.
The Ratio of minimum to maximum transmission is 0.8186.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.293
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             460
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0825
_diffrn_reflns_av_unetI/netI     0.0621
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            25702
_diffrn_reflns_point_group_measured_fraction_full 0.965
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.105
_diffrn_reflns_theta_min         2.123
_diffrn_ambient_temperature      298
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-V Photon II'
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.893
_reflns_Friedel_fraction_full    0.931
_reflns_Friedel_fraction_max     0.897
_reflns_number_gt                3487
_reflns_number_total             4708
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.125
_refine_diff_density_min         -0.188
_refine_diff_density_rms         0.034
_refine_ls_abs_structure_details 
;
 Flack x determined using 1317 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.20(7)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         4708
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0717
_refine_ls_R_factor_gt           0.0431
_refine_ls_restrained_S_all      1.019
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0389P)²+0.0195P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0840
_refine_ls_wR_factor_ref         0.0937
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C13(H13A,H13B), C22(H22A,H22B)
2.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C3(H3), C2(H2), C28(H28), C27(H27), C26(H26), C10(H10), C11(H11),
 C12(H12), C5(H5), C6(H6), C24(H24), C25(H25), C18(H18), C19(H19), C14(H14),
 C15(H15), C16(H16), C8(H8), C9(H9)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.37655(13) 0.32528(7) 0.53341(6) 0.0406(2) Uani 1 1 d . . . . .
O2 O 0.5564(4) 0.62588(17) 0.45894(15) 0.0415(6) Uani 1 1 d . . . . .
O1 O 0.1281(4) 0.3348(2) 0.52933(17) 0.0518(6) Uani 1 1 d . . . . .
C1 C 0.4557(6) 0.2329(3) 0.4503(2) 0.0429(8) Uani 1 1 d . . . . .
C7 C 0.4929(6) 0.2754(2) 0.6411(2) 0.0411(8) Uani 1 1 d . . . . .
N1 N 0.2443(6) 0.6754(2) 0.5198(2) 0.0512(8) Uani 1 1 d . . . . .
C4 C 0.5372(10) 0.0921(4) 0.3154(3) 0.0848(16) Uani 1 1 d . . . . .
H4 H 0.564462 0.044555 0.270310 0.102 Uiso 1 1 calc R U . . .
C3 C 0.6959(8) 0.1657(4) 0.3448(3) 0.0743(13) Uani 1 1 d . . . . .
H3 H 0.829503 0.169090 0.319037 0.089 Uiso 1 1 calc R U . . .
C2 C 0.6573(7) 0.2361(3) 0.4140(3) 0.0561(10) Uani 1 1 d . . . . .
H2 H 0.766979 0.284924 0.435423 0.067 Uiso 1 1 calc R U . . .
C13 C 0.5198(5) 0.4514(2) 0.5216(2) 0.0384(8) Uani 1 1 d . . . . .
H13A H 0.531575 0.487785 0.578848 0.046 Uiso 1 1 calc R U . . .
H13B H 0.670764 0.435811 0.508254 0.046 Uiso 1 1 calc R U . . .
C20 C 0.4134(5) 0.5292(3) 0.4499(2) 0.0388(8) Uani 1 1 d . . . . .
C21 C 0.4429(6) 0.6980(3) 0.5056(2) 0.0425(9) Uani 1 1 d . . . . .
C23 C 0.5613(7) 0.7980(3) 0.5319(2) 0.0502(9) Uani 1 1 d . . . . .
C28 C 0.4613(9) 0.8696(4) 0.5866(3) 0.0765(14) Uani 1 1 d . . . . .
H28 H 0.327230 0.852938 0.608909 0.092 Uiso 1 1 calc R U . . .
C27 C 0.5687(13) 0.9675(4) 0.6069(4) 0.0975(18) Uani 1 1 d . . . . .
H27 H 0.505675 1.015700 0.644046 0.117 Uiso 1 1 calc R U . . .
C26 C 0.7618(12) 0.9936(4) 0.5736(4) 0.0928(18) Uani 1 1 d . . . . .
H26 H 0.825843 1.060410 0.585745 0.111 Uiso 1 1 calc R U . . .
C10 C 0.6428(8) 0.1956(3) 0.8088(3) 0.0576(11) Uani 1 1 d . . . . .
H10 H 0.692456 0.169450 0.865374 0.069 Uiso 1 1 calc R U . . .
C11 C 0.4253(8) 0.1806(3) 0.7742(3) 0.0623(11) Uani 1 1 d . . . . .
H11 H 0.328502 0.142683 0.806799 0.075 Uiso 1 1 calc R U . . .
C12 C 0.3484(7) 0.2210(3) 0.6913(3) 0.0525(10) Uani 1 1 d . . . . .
H12 H 0.199294 0.211942 0.668942 0.063 Uiso 1 1 calc R U . . .
C5 C 0.3375(10) 0.0878(4) 0.3519(4) 0.0837(15) Uani 1 1 d . . . . .
H5 H 0.230111 0.037446 0.331395 0.100 Uiso 1 1 calc R U . . .
C6 C 0.2964(8) 0.1577(3) 0.4186(3) 0.0650(12) Uani 1 1 d . . . . .
H6 H 0.160628 0.154638 0.442778 0.078 Uiso 1 1 calc R U . . .
C22 C 0.1885(6) 0.5746(3) 0.4738(2) 0.0479(9) Uani 1 1 d . . . . .
H22A H 0.086843 0.586681 0.420177 0.058 Uiso 1 1 calc R U . . .
H22B H 0.118796 0.525658 0.512462 0.058 Uiso 1 1 calc R U . . .
C24 C 0.7615(7) 0.8240(3) 0.5018(3) 0.0577(10) Uani 1 1 d . . . . .
H24 H 0.830545 0.775212 0.467078 0.069 Uiso 1 1 calc R U . . .
C25 C 0.8633(10) 0.9222(3) 0.5223(4) 0.0787(13) Uani 1 1 d . . . . .
H25 H 0.998980 0.939042 0.501359 0.094 Uiso 1 1 calc R U . . .
C17 C 0.4137(6) 0.4854(3) 0.3565(2) 0.0387(8) Uani 1 1 d . . . . .
C18 C 0.2343(6) 0.4241(3) 0.3190(2) 0.0469(9) Uani 1 1 d . . . . .
H18 H 0.108758 0.415482 0.349396 0.056 Uiso 1 1 calc R U . . .
C19 C 0.2420(7) 0.3760(3) 0.2368(3) 0.0553(10) Uani 1 1 d . . . . .
H19 H 0.122299 0.334290 0.212732 0.066 Uiso 1 1 calc R U . . .
C14 C 0.4226(7) 0.3890(3) 0.1902(3) 0.0605(11) Uani 1 1 d . . . . .
H14 H 0.427013 0.356057 0.135003 0.073 Uiso 1 1 calc R U . . .
C15 C 0.5979(7) 0.4512(3) 0.2261(3) 0.0606(11) Uani 1 1 d . . . . .
H15 H 0.720585 0.461237 0.194261 0.073 Uiso 1 1 calc R U . . .
C16 C 0.5946(6) 0.4989(3) 0.3084(2) 0.0485(9) Uani 1 1 d . . . . .
H16 H 0.715127 0.540643 0.331707 0.058 Uiso 1 1 calc R U . . .
C8 C 0.7135(6) 0.2889(3) 0.6766(3) 0.0524(9) Uani 1 1 d . . . . .
H8 H 0.812766 0.324967 0.643914 0.063 Uiso 1 1 calc R U . . .
C9 C 0.7869(7) 0.2489(3) 0.7605(3) 0.0591(10) Uani 1 1 d . . . . .
H9 H 0.935034 0.258515 0.784055 0.071 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.493(2) . ?
P1 C1 1.803(4) . ?
P1 C7 1.805(3) . ?
P1 C13 1.815(3) . ?
O2 C20 1.481(4) . ?
O2 C21 1.369(4) . ?
C1 C2 1.382(5) . ?
C1 C6 1.390(5) . ?
C7 C12 1.389(5) . ?
C7 C8 1.386(5) . ?
N1 C21 1.267(4) . ?
N1 C22 1.458(5) . ?
C4 H4 0.9300 . ?
C4 C3 1.364(7) . ?
C4 C5 1.374(8) . ?
C3 H3 0.9300 . ?
C3 C2 1.401(6) . ?
C2 H2 0.9300 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 C20 1.539(4) . ?
C20 C22 1.544(5) . ?
C20 C17 1.508(5) . ?
C21 C23 1.472(5) . ?
C23 C28 1.395(5) . ?
C23 C24 1.370(5) . ?
C28 H28 0.9300 . ?
C28 C27 1.402(8) . ?
C27 H27 0.9300 . ?
C27 C26 1.352(8) . ?
C26 H26 0.9300 . ?
C26 C25 1.365(8) . ?
C10 H10 0.9300 . ?
C10 C11 1.368(5) . ?
C10 C9 1.363(6) . ?
C11 H11 0.9300 . ?
C11 C12 1.378(5) . ?
C12 H12 0.9300 . ?
C5 H5 0.9300 . ?
C5 C6 1.372(7) . ?
C6 H6 0.9300 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C24 H24 0.9300 . ?
C24 C25 1.391(6) . ?
C25 H25 0.9300 . ?
C17 C18 1.393(5) . ?
C17 C16 1.381(5) . ?
C18 H18 0.9300 . ?
C18 C19 1.380(5) . ?
C19 H19 0.9300 . ?
C19 C14 1.363(5) . ?
C14 H14 0.9300 . ?
C14 C15 1.372(6) . ?
C15 H15 0.9300 . ?
C15 C16 1.376(5) . ?
C16 H16 0.9300 . ?
C8 H8 0.9300 . ?
C8 C9 1.385(5) . ?
C9 H9 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 C1 111.12(15) . . ?
O1 P1 C7 110.72(15) . . ?
O1 P1 C13 114.20(15) . . ?
C1 P1 C7 107.17(15) . . ?
C1 P1 C13 108.96(16) . . ?
C7 P1 C13 104.24(15) . . ?
C21 O2 C20 105.5(3) . . ?
C2 C1 P1 124.3(3) . . ?
C2 C1 C6 119.0(4) . . ?
C6 C1 P1 116.6(3) . . ?
C12 C7 P1 116.9(3) . . ?
C8 C7 P1 124.5(3) . . ?
C8 C7 C12 118.6(3) . . ?
C21 N1 C22 106.6(3) . . ?
C3 C4 H4 119.7 . . ?
C3 C4 C5 120.5(4) . . ?
C5 C4 H4 119.7 . . ?
C4 C3 H3 120.0 . . ?
C4 C3 C2 119.9(5) . . ?
C2 C3 H3 120.0 . . ?
C1 C2 C3 119.8(4) . . ?
C1 C2 H2 120.1 . . ?
C3 C2 H2 120.1 . . ?
P1 C13 H13A 108.1 . . ?
P1 C13 H13B 108.1 . . ?
H13A C13 H13B 107.3 . . ?
C20 C13 P1 116.9(2) . . ?
C20 C13 H13A 108.1 . . ?
C20 C13 H13B 108.1 . . ?
O2 C20 C13 105.0(2) . . ?
O2 C20 C22 101.1(3) . . ?
O2 C20 C17 108.8(2) . . ?
C13 C20 C22 112.2(3) . . ?
C17 C20 C13 112.3(3) . . ?
C17 C20 C22 116.1(3) . . ?
O2 C21 C23 116.3(3) . . ?
N1 C21 O2 118.1(3) . . ?
N1 C21 C23 125.5(3) . . ?
C28 C23 C21 118.5(4) . . ?
C24 C23 C21 122.0(3) . . ?
C24 C23 C28 119.4(4) . . ?
C23 C28 H28 120.9 . . ?
C23 C28 C27 118.1(5) . . ?
C27 C28 H28 120.9 . . ?
C28 C27 H27 119.2 . . ?
C26 C27 C28 121.5(5) . . ?
C26 C27 H27 119.2 . . ?
C27 C26 H26 119.8 . . ?
C27 C26 C25 120.3(5) . . ?
C25 C26 H26 119.8 . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.1(4) . . ?
C10 C11 H11 119.7 . . ?
C10 C11 C12 120.5(4) . . ?
C12 C11 H11 119.7 . . ?
C7 C12 H12 119.9 . . ?
C11 C12 C7 120.2(4) . . ?
C11 C12 H12 119.9 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 C4 120.0(4) . . ?
C6 C5 H5 120.0 . . ?
C1 C6 H6 119.7 . . ?
C5 C6 C1 120.7(5) . . ?
C5 C6 H6 119.7 . . ?
N1 C22 C20 105.4(3) . . ?
N1 C22 H22A 110.7 . . ?
N1 C22 H22B 110.7 . . ?
C20 C22 H22A 110.7 . . ?
C20 C22 H22B 110.7 . . ?
H22A C22 H22B 108.8 . . ?
C23 C24 H24 119.4 . . ?
C23 C24 C25 121.2(4) . . ?
C25 C24 H24 119.4 . . ?
C26 C25 C24 119.3(5) . . ?
C26 C25 H25 120.4 . . ?
C24 C25 H25 120.4 . . ?
C18 C17 C20 120.0(3) . . ?
C16 C17 C20 121.6(3) . . ?
C16 C17 C18 118.3(3) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 C17 120.2(3) . . ?
C19 C18 H18 119.9 . . ?
C18 C19 H19 119.5 . . ?
C14 C19 C18 120.9(4) . . ?
C14 C19 H19 119.5 . . ?
C19 C14 H14 120.5 . . ?
C19 C14 C15 119.1(4) . . ?
C15 C14 H14 120.5 . . ?
C14 C15 H15 119.5 . . ?
C14 C15 C16 121.0(4) . . ?
C16 C15 H15 119.5 . . ?
C17 C16 H16 119.8 . . ?
C15 C16 C17 120.4(4) . . ?
C15 C16 H16 119.8 . . ?
C7 C8 H8 119.8 . . ?
C9 C8 C7 120.4(4) . . ?
C9 C8 H8 119.8 . . ?
C10 C9 C8 120.2(4) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 C2 C3 -175.2(3) . . . . ?
P1 C1 C6 C5 176.6(4) . . . . ?
P1 C7 C12 C11 179.9(3) . . . . ?
P1 C7 C8 C9 179.1(3) . . . . ?
P1 C13 C20 O2 176.8(2) . . . . ?
P1 C13 C20 C22 67.9(3) . . . . ?
P1 C13 C20 C17 -65.0(3) . . . . ?
O2 C20 C22 N1 -17.8(3) . . . . ?
O2 C20 C17 C18 -154.8(3) . . . . ?
O2 C20 C17 C16 29.1(4) . . . . ?
O2 C21 C23 C28 -174.2(3) . . . . ?
O2 C21 C23 C24 8.2(5) . . . . ?
O1 P1 C1 C2 154.3(3) . . . . ?
O1 P1 C1 C6 -22.5(3) . . . . ?
O1 P1 C7 C12 20.7(3) . . . . ?
O1 P1 C7 C8 -158.6(3) . . . . ?
O1 P1 C13 C20 -42.1(3) . . . . ?
C1 P1 C7 C12 -100.6(3) . . . . ?
C1 P1 C7 C8 80.1(3) . . . . ?
C1 P1 C13 C20 82.8(3) . . . . ?
C7 P1 C1 C2 -84.6(3) . . . . ?
C7 P1 C1 C6 98.6(3) . . . . ?
C7 P1 C13 C20 -163.1(2) . . . . ?
C7 C8 C9 C10 0.2(6) . . . . ?
N1 C21 C23 C28 8.4(5) . . . . ?
N1 C21 C23 C24 -169.3(4) . . . . ?
C4 C3 C2 C1 -1.9(6) . . . . ?
C4 C5 C6 C1 -0.4(7) . . . . ?
C3 C4 C5 C6 -0.1(8) . . . . ?
C2 C1 C6 C5 -0.3(6) . . . . ?
C13 P1 C1 C2 27.6(3) . . . . ?
C13 P1 C1 C6 -149.1(3) . . . . ?
C13 P1 C7 C12 143.9(3) . . . . ?
C13 P1 C7 C8 -35.3(3) . . . . ?
C13 C20 C22 N1 93.6(3) . . . . ?
C13 C20 C17 C18 89.4(4) . . . . ?
C13 C20 C17 C16 -86.7(4) . . . . ?
C20 O2 C21 N1 -8.6(4) . . . . ?
C20 O2 C21 C23 173.8(3) . . . . ?
C20 C17 C18 C19 -174.4(3) . . . . ?
C20 C17 C16 C15 175.0(4) . . . . ?
C21 O2 C20 C13 -101.2(3) . . . . ?
C21 O2 C20 C22 15.6(3) . . . . ?
C21 O2 C20 C17 138.3(3) . . . . ?
C21 N1 C22 C20 13.8(4) . . . . ?
C21 C23 C28 C27 -176.2(4) . . . . ?
C21 C23 C24 C25 175.5(4) . . . . ?
C23 C28 C27 C26 1.1(8) . . . . ?
C23 C24 C25 C26 0.2(7) . . . . ?
C28 C23 C24 C25 -2.2(6) . . . . ?
C28 C27 C26 C25 -3.1(9) . . . . ?
C27 C26 C25 C24 2.4(8) . . . . ?
C10 C11 C12 C7 1.6(6) . . . . ?
C11 C10 C9 C8 0.6(6) . . . . ?
C12 C7 C8 C9 -0.1(5) . . . . ?
C5 C4 C3 C2 1.2(7) . . . . ?
C6 C1 C2 C3 1.5(6) . . . . ?
C22 N1 C21 O2 -3.7(4) . . . . ?
C22 N1 C21 C23 173.7(3) . . . . ?
C22 C20 C17 C18 -41.6(4) . . . . ?
C22 C20 C17 C16 142.3(3) . . . . ?
C24 C23 C28 C27 1.5(6) . . . . ?
C17 C20 C22 N1 -135.3(3) . . . . ?
C17 C18 C19 C14 -1.1(6) . . . . ?
C18 C17 C16 C15 -1.2(5) . . . . ?
C18 C19 C14 C15 -0.3(6) . . . . ?
C19 C14 C15 C16 1.0(6) . . . . ?
C14 C15 C16 C17 -0.2(6) . . . . ?
C16 C17 C18 C19 1.8(5) . . . . ?
C8 C7 C12 C11 -0.8(5) . . . . ?
C9 C10 C11 C12 -1.5(6) . . . . ?

_olex2_exptl_crystal_mounting_method 'Nylon loop used'
_olex2_submission_special_instructions 'No special instructions were received'
