# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_240222c_yzq_xy_5c_0m
_database_code_depnum_ccdc_archive 'CCDC 2481584'
loop_
_audit_author_name
_audit_author_address
'yao xiao'
;Shenzhen University
China
;
_audit_update_record             
;
2025-08-20 deposited with the CCDC.	2025-10-03 downloaded from the CCDC.
;
_audit_creation_date             2024-03-13
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H31 N O2'
_chemical_formula_sum            'C25 H31 N O2'
_chemical_formula_weight         377.51
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_H-M_alt        'C 1 c 1'
_space_group_name_Hall           'C -2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'

_cell_length_a                   45.525(5)
_cell_length_b                   7.0641(7)
_cell_length_c                   6.6022(7)
_cell_angle_alpha                90
_cell_angle_beta                 94.133(4)
_cell_angle_gamma                90
_cell_volume                     2117.7(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4590
_cell_measurement_temperature    144.00
_cell_measurement_theta_max      26.15
_cell_measurement_theta_min      2.69
_shelx_estimated_absorpt_T_max   0.994
_shelx_estimated_absorpt_T_min   0.991
_exptl_absorpt_coefficient_mu    0.074
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6775
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1381 before and 0.0892 after correction.
The Ratio of minimum to maximum transmission is 0.9087.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.184
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1088
_diffrn_reflns_av_unetI/netI     0.0667
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       58
_diffrn_reflns_limit_h_min       -58
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            33984
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.541
_diffrn_reflns_theta_min         2.691
_diffrn_ambient_temperature      144.00
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON II'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE TXS PHOTON II'
_diffrn_measurement_method       'ω and φ shutterless scans'
_diffrn_measurement_specimen_support 'nylon loop'
_diffrn_radiation_monochromator  'Helios Multi-layer Optic'
_diffrn_radiation_probe          X-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   TXS
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_type              'Rotaing Anode'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.995
_reflns_Friedel_fraction_full    0.998
_reflns_Friedel_fraction_max     0.991
_reflns_number_gt                3454
_reflns_number_total             4874
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (Bruker, 2019)'
_computing_data_collection       'APEX5 V2023.9-2 (Bruker, 2023)'
_computing_data_reduction        'SAINT V8.40B (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.252
_refine_diff_density_min         -0.248
_refine_diff_density_rms         0.054
_refine_ls_abs_structure_details 
;
 Flack x determined using 1327 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.5(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         4874
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0932
_refine_ls_R_factor_gt           0.0642
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0703P)²+2.0335P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1498
_refine_ls_wR_factor_ref         0.1680
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C5(H5A,H5B), C4(H4A,H4B), C2(H2A,H2B), C24(H24A,H24B), C21(H21A,
 H21B), C22(H22A,H22B), C23(H23A,H23B)
2.b Aromatic/amide H refined with riding coordinates:
 C10(H10), C8(H8), C16(H16), C7(H7), C17(H17), C20(H20), C14(H14), C19(H19),
 C11(H11)
2.c Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C25(H25A,H25B,H25C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.63054(7) 0.7732(5) 0.7776(4) 0.0260(8) Uani 1 1 d . . . . .
O2 O 0.37211(7) 0.7798(6) 0.2092(5) 0.0303(9) Uani 1 1 d . . . . .
C12 C 0.51441(11) 0.7536(6) 0.4187(6) 0.0192(10) Uani 1 1 d . . . . .
N1 N 0.50882(9) 0.7964(6) 0.0296(6) 0.0312(9) Uani 1 1 d . . . . .
C10 C 0.55178(10) 0.6603(6) 0.6949(6) 0.0191(10) Uani 1 1 d . . . . .
H10 H 0.536683 0.595242 0.758722 0.023 Uiso 1 1 calc R U . . .
C8 C 0.56779(10) 0.8359(6) 0.4143(6) 0.0210(11) Uani 1 1 d . . . . .
H8 H 0.563908 0.892655 0.284682 0.025 Uiso 1 1 calc R U . . .
C16 C 0.45050(11) 0.6503(7) 0.2620(7) 0.0250(11) Uani 1 1 d . . . . .
H16 H 0.464634 0.581368 0.192651 0.030 Uiso 1 1 calc R U . . .
C15 C 0.45940(11) 0.7452(7) 0.4427(6) 0.0219(11) Uani 1 1 d . . . . .
C7 C 0.59596(11) 0.8387(7) 0.5053(7) 0.0239(11) Uani 1 1 d . . . . .
H7 H 0.611325 0.897454 0.438141 0.029 Uiso 1 1 calc R U . . .
C9 C 0.54480(10) 0.7505(6) 0.5103(6) 0.0201(11) Uani 1 1 d . . . . .
C17 C 0.42153(11) 0.6551(7) 0.1828(7) 0.0263(11) Uani 1 1 d . . . . .
H17 H 0.415829 0.588400 0.061307 0.032 Uiso 1 1 calc R U . . .
C13 C 0.51106(10) 0.7785(6) 0.2015(7) 0.0242(9) Uani 1 1 d . . . . .
C6 C 0.60207(10) 0.7561(7) 0.6952(7) 0.0222(12) Uani 1 1 d . . . . .
C20 C 0.43768(10) 0.8376(7) 0.5456(7) 0.0232(11) Uani 1 1 d . . . . .
H20 H 0.442918 0.897482 0.671897 0.028 Uiso 1 1 calc R U . . .
C3 C 0.67817(10) 0.7116(7) 1.2602(7) 0.0249(10) Uani 1 1 d . . . . .
H3A H 0.664455 0.752967 1.361172 0.030 Uiso 1 1 calc R U . . .
H3B H 0.678334 0.571459 1.258807 0.030 Uiso 1 1 calc R U . . .
C14 C 0.49029(11) 0.7472(7) 0.5243(7) 0.0222(10) Uani 1 1 d . . . . .
H14 H 0.493567 0.743610 0.667968 0.027 Uiso 1 1 calc R U . . .
C5 C 0.63696(11) 0.7095(8) 0.9823(7) 0.0258(11) Uani 1 1 d . . . . .
H5A H 0.636711 0.569490 0.987857 0.031 Uiso 1 1 calc R U . . .
H5B H 0.622061 0.758530 1.071067 0.031 Uiso 1 1 calc R U . . .
C4 C 0.66712(11) 0.7832(7) 1.0520(7) 0.0265(11) Uani 1 1 d . . . . .
H4A H 0.666496 0.923284 1.055003 0.032 Uiso 1 1 calc R U . . .
H4B H 0.681243 0.745306 0.952260 0.032 Uiso 1 1 calc R U . . .
C18 C 0.40075(11) 0.7581(7) 0.2819(7) 0.0256(12) Uani 1 1 d . . . . .
C19 C 0.40884(11) 0.8430(7) 0.4665(7) 0.0259(11) Uani 1 1 d . . . . .
H19 H 0.394408 0.905490 0.539201 0.031 Uiso 1 1 calc R U . . .
C11 C 0.57994(11) 0.6622(7) 0.7888(7) 0.0221(10) Uani 1 1 d . . . . .
H11 H 0.584075 0.600151 0.915298 0.027 Uiso 1 1 calc R U . . .
C2 C 0.70883(11) 0.7829(8) 1.3239(7) 0.0294(12) Uani 1 1 d . . . . .
H2A H 0.722238 0.747253 1.218677 0.035 Uiso 1 1 calc R U . . .
H2B H 0.708358 0.922881 1.330984 0.035 Uiso 1 1 calc R U . . .
C24 C 0.29158(11) 0.7872(9) -0.3227(7) 0.0358(14) Uani 1 1 d . . . . .
H24A H 0.292160 0.926938 -0.333673 0.043 Uiso 1 1 calc R U . . .
H24B H 0.278301 0.754578 -0.215629 0.043 Uiso 1 1 calc R U . . .
C21 C 0.36421(11) 0.7116(8) 0.0077(7) 0.0297(12) Uani 1 1 d . . . . .
H21A H 0.364074 0.571462 0.005975 0.036 Uiso 1 1 calc R U . . .
H21B H 0.378524 0.756738 -0.087444 0.036 Uiso 1 1 calc R U . . .
C22 C 0.33398(11) 0.7873(9) -0.0530(7) 0.0314(12) Uani 1 1 d . . . . .
H22A H 0.334713 0.927368 -0.055723 0.038 Uiso 1 1 calc R U . . .
H22B H 0.320316 0.749301 0.049744 0.038 Uiso 1 1 calc R U . . .
C23 C 0.32225(11) 0.7152(9) -0.2603(7) 0.0306(11) Uani 1 1 d . . . . .
H23A H 0.335805 0.755070 -0.362991 0.037 Uiso 1 1 calc R U . . .
H23B H 0.321936 0.575105 -0.257938 0.037 Uiso 1 1 calc R U . . .
C1 C 0.72107(14) 0.7068(9) 1.5259(8) 0.0391(14) Uani 1 1 d . . . . .
H1A H 0.722462 0.568519 1.518581 0.059 Uiso 1 1 calc R U . . .
H1B H 0.708006 0.742056 1.631373 0.059 Uiso 1 1 calc R U . . .
H1C H 0.740694 0.760157 1.559075 0.059 Uiso 1 1 calc R U . . .
C25 C 0.27910(13) 0.7057(11) -0.5232(8) 0.0493(17) Uani 1 1 d . . . . .
H25A H 0.292810 0.729792 -0.628087 0.074 Uiso 1 1 calc R U . . .
H25B H 0.260120 0.765639 -0.562259 0.074 Uiso 1 1 calc R U . . .
H25C H 0.276306 0.568917 -0.508844 0.074 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C6 1.374(6) . ?
O1 C5 1.434(5) . ?
O2 C18 1.365(6) . ?
O2 C21 1.436(5) . ?
C12 C9 1.470(6) . ?
C12 C13 1.442(6) . ?
C12 C14 1.343(5) . ?
N1 C13 1.139(5) . ?
C10 H10 0.9500 . ?
C10 C9 1.392(6) . ?
C10 C11 1.383(6) . ?
C8 H8 0.9500 . ?
C8 C7 1.377(7) . ?
C8 C9 1.399(6) . ?
C16 H16 0.9500 . ?
C16 C15 1.403(6) . ?
C16 C17 1.384(7) . ?
C15 C20 1.401(7) . ?
C15 C14 1.469(6) . ?
C7 H7 0.9500 . ?
C7 C6 1.393(7) . ?
C17 H17 0.9500 . ?
C17 C18 1.393(7) . ?
C6 C11 1.388(6) . ?
C20 H20 0.9500 . ?
C20 C19 1.378(7) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C3 C4 1.516(6) . ?
C3 C2 1.515(6) . ?
C14 H14 0.9500 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C5 C4 1.509(7) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C18 C19 1.384(7) . ?
C19 H19 0.9500 . ?
C11 H11 0.9500 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C2 C1 1.507(7) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C24 C23 1.515(7) . ?
C24 C25 1.516(7) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.504(7) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.520(6) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 O1 C5 117.9(4) . . ?
C18 O2 C21 117.2(4) . . ?
C13 C12 C9 116.1(4) . . ?
C14 C12 C9 124.5(3) . . ?
C14 C12 C13 119.2(4) . . ?
C9 C10 H10 118.9 . . ?
C11 C10 H10 118.9 . . ?
C11 C10 C9 122.3(4) . . ?
C7 C8 H8 119.6 . . ?
C7 C8 C9 120.8(4) . . ?
C9 C8 H8 119.6 . . ?
C15 C16 H16 119.4 . . ?
C17 C16 H16 119.4 . . ?
C17 C16 C15 121.2(5) . . ?
C16 C15 C14 121.8(4) . . ?
C20 C15 C16 117.7(4) . . ?
C20 C15 C14 120.5(4) . . ?
C8 C7 H7 119.8 . . ?
C8 C7 C6 120.4(4) . . ?
C6 C7 H7 119.8 . . ?
C10 C9 C12 121.1(4) . . ?
C10 C9 C8 117.6(4) . . ?
C8 C9 C12 121.3(4) . . ?
C16 C17 H17 120.1 . . ?
C16 C17 C18 119.8(4) . . ?
C18 C17 H17 120.1 . . ?
N1 C13 C12 178.8(5) . . ?
O1 C6 C7 116.2(4) . . ?
O1 C6 C11 124.0(4) . . ?
C11 C6 C7 119.8(4) . . ?
C15 C20 H20 119.5 . . ?
C19 C20 C15 121.0(4) . . ?
C19 C20 H20 119.5 . . ?
H3A C3 H3B 107.9 . . ?
C4 C3 H3A 109.1 . . ?
C4 C3 H3B 109.1 . . ?
C2 C3 H3A 109.1 . . ?
C2 C3 H3B 109.1 . . ?
C2 C3 C4 112.3(4) . . ?
C12 C14 C15 127.3(4) . . ?
C12 C14 H14 116.3 . . ?
C15 C14 H14 116.3 . . ?
O1 C5 H5A 110.2 . . ?
O1 C5 H5B 110.2 . . ?
O1 C5 C4 107.4(4) . . ?
H5A C5 H5B 108.5 . . ?
C4 C5 H5A 110.2 . . ?
C4 C5 H5B 110.2 . . ?
C3 C4 H4A 108.9 . . ?
C3 C4 H4B 108.9 . . ?
C5 C4 C3 113.4(4) . . ?
C5 C4 H4A 108.9 . . ?
C5 C4 H4B 108.9 . . ?
H4A C4 H4B 107.7 . . ?
O2 C18 C17 123.9(4) . . ?
O2 C18 C19 116.6(5) . . ?
C19 C18 C17 119.6(5) . . ?
C20 C19 C18 120.5(5) . . ?
C20 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
C10 C11 C6 119.0(4) . . ?
C10 C11 H11 120.5 . . ?
C6 C11 H11 120.5 . . ?
C3 C2 H2A 108.8 . . ?
C3 C2 H2B 108.8 . . ?
H2A C2 H2B 107.7 . . ?
C1 C2 C3 113.7(5) . . ?
C1 C2 H2A 108.8 . . ?
C1 C2 H2B 108.8 . . ?
H24A C24 H24B 107.8 . . ?
C23 C24 H24A 109.0 . . ?
C23 C24 H24B 109.0 . . ?
C23 C24 C25 113.0(5) . . ?
C25 C24 H24A 109.0 . . ?
C25 C24 H24B 109.0 . . ?
O2 C21 H21A 110.3 . . ?
O2 C21 H21B 110.3 . . ?
O2 C21 C22 106.9(4) . . ?
H21A C21 H21B 108.6 . . ?
C22 C21 H21A 110.3 . . ?
C22 C21 H21B 110.3 . . ?
C21 C22 H22A 109.2 . . ?
C21 C22 H22B 109.2 . . ?
C21 C22 C23 112.1(4) . . ?
H22A C22 H22B 107.9 . . ?
C23 C22 H22A 109.2 . . ?
C23 C22 H22B 109.2 . . ?
C24 C23 C22 112.9(5) . . ?
C24 C23 H23A 109.0 . . ?
C24 C23 H23B 109.0 . . ?
C22 C23 H23A 109.0 . . ?
C22 C23 H23B 109.0 . . ?
H23A C23 H23B 107.8 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C6 C11 C10 177.5(4) . . . . ?
O1 C5 C4 C3 -174.6(4) . . . . ?
O2 C18 C19 C20 -176.2(5) . . . . ?
O2 C21 C22 C23 -176.6(4) . . . . ?
C8 C7 C6 O1 -177.3(4) . . . . ?
C8 C7 C6 C11 3.2(7) . . . . ?
C16 C15 C20 C19 -3.2(7) . . . . ?
C16 C15 C14 C12 35.8(8) . . . . ?
C16 C17 C18 O2 176.1(4) . . . . ?
C16 C17 C18 C19 -4.8(8) . . . . ?
C15 C16 C17 C18 0.9(8) . . . . ?
C15 C20 C19 C18 -0.5(7) . . . . ?
C7 C8 C9 C12 177.4(4) . . . . ?
C7 C8 C9 C10 -3.4(6) . . . . ?
C7 C6 C11 C10 -3.0(7) . . . . ?
C9 C12 C14 C15 -178.4(3) . . . . ?
C9 C10 C11 C6 -0.4(7) . . . . ?
C9 C8 C7 C6 0.1(7) . . . . ?
C17 C16 C15 C20 3.0(7) . . . . ?
C17 C16 C15 C14 -177.7(5) . . . . ?
C17 C18 C19 C20 4.6(7) . . . . ?
C13 C12 C9 C10 -155.7(4) . . . . ?
C13 C12 C9 C8 23.5(6) . . . . ?
C13 C12 C14 C15 6.2(8) . . . . ?
C6 O1 C5 C4 -167.3(4) . . . . ?
C20 C15 C14 C12 -144.9(6) . . . . ?
C14 C12 C9 C10 28.8(7) . . . . ?
C14 C12 C9 C8 -152.0(5) . . . . ?
C14 C15 C20 C19 177.4(4) . . . . ?
C5 O1 C6 C7 172.9(4) . . . . ?
C5 O1 C6 C11 -7.5(7) . . . . ?
C4 C3 C2 C1 -177.2(5) . . . . ?
C18 O2 C21 C22 -168.3(4) . . . . ?
C11 C10 C9 C12 -177.2(4) . . . . ?
C11 C10 C9 C8 3.6(6) . . . . ?
C2 C3 C4 C5 178.3(4) . . . . ?
C21 O2 C18 C17 -7.9(8) . . . . ?
C21 O2 C18 C19 173.0(4) . . . . ?
C21 C22 C23 C24 179.0(5) . . . . ?
C25 C24 C23 C22 -176.4(5) . . . . ?

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