# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_4767_auto
_database_code_depnum_ccdc_archive 'CCDC 2426517'
loop_
_audit_author_name
_audit_author_address
'Cheng kai Ruan'
;China West Normal University
China
;
_audit_update_record             
;
2025-02-24 deposited with the CCDC.	2025-12-10 downloaded from the CCDC.
;
_audit_creation_date             2023-10-26
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C17 H18 N O3 P'
_chemical_formula_sum            'C17 H17 N O3 P'
_chemical_formula_weight         314.28
_chemical_melting_point          ?
_chemical_oxdiff_formula         CHPNO
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   21.4243(4)
_cell_length_b                   13.8932(2)
_cell_length_c                   11.1722(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.625(2)
_cell_angle_gamma                90
_cell_volume                     3287.82(10)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    7617
_cell_measurement_temperature    297.32(10)
_cell_measurement_theta_max      76.4760
_cell_measurement_theta_min      3.7680
_shelx_estimated_absorpt_T_max   0.786
_shelx_estimated_absorpt_T_min   0.743
_exptl_absorpt_coefficient_mu    1.583
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.82327
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.112a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.270
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0237
_diffrn_reflns_av_unetI/netI     0.0239
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.951
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10997
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.951
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.557
_diffrn_reflns_theta_min         3.805
_diffrn_ambient_environment      air
_diffrn_ambient_temperature      297.32(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.951
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     94.00 138.00   0.50    0.14    --  106.81  37.00   0.00   88
  2  ω    150.00 176.00   0.50    0.14    --  106.81  57.00   0.00   52
  3  ω    145.00 170.00   0.50    0.14    --  106.81  37.00   0.00   50
  4  ω     97.00 129.00   0.50    0.14    --  106.81  57.00   0.00   64
  5  ω     94.00 177.00   0.50    0.14    --  106.81  37.00 120.00  166
  6  ω     85.00 159.00   0.50    0.14    --  106.81  93.00  47.00  148
  7  ω     82.00 107.00   0.50    0.14    --  106.81 -77.00 -90.00   50
  8  ω     37.00  62.00   0.50    0.14    --  106.81 -57.00 -90.00   50
  9  ω     34.00  59.00   0.50    0.14    --  106.81 -57.00 -30.00   50
 10  ω     35.00  61.00   0.50    0.14    --  106.81 -57.00   0.00   52
 11  ω     38.00  63.00   0.50    0.14    --  106.81 -57.00 120.00   50
 12  ω    -12.00  71.00   0.50    0.05    --   47.63 -93.00 -64.00  166
 13  ω     50.00  89.00   0.50    0.14    --  106.81 -93.00 -64.00   78
 14  ω    -62.00 -33.00   0.50    0.14    -- -102.00  57.00 -90.00   58
 15  ω    -64.00 -39.00   0.50    0.14    -- -102.00  57.00-150.00   50
 16  ω    -64.00 -38.00   0.50    0.14    -- -102.00  57.00-180.00   52
 17  ω    -64.00 -39.00   0.50    0.14    -- -102.00  57.00-120.00   50
 18  ω    -63.00 -29.00   0.50    0.14    -- -102.00  57.00   0.00   68
 19  ω    -61.00 -29.00   0.50    0.14    -- -102.00  57.00 120.00   64
 20  ω   -152.00-127.00   0.50    0.14    -- -102.00 -93.00 -64.00   50
 21  ω   -116.00 -71.00   0.50    0.05    --  -47.63-125.00  60.00   90
 22  ω   -117.00 -71.00   0.50    0.05    --  -47.63-125.00   0.00   92
 23  ω   -118.00 -73.00   0.50    0.05    --  -47.63-125.00-180.00   90
 24  ω    -61.00  23.00   0.50    0.05    --  -47.63  93.00  47.00  168
 25  ω   -108.00 -38.00   0.50    0.14    -- -102.00  93.00  47.00  140
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0178527000
_diffrn_orient_matrix_UB_12      -0.1013948000
_diffrn_orient_matrix_UB_13      -0.0496258000
_diffrn_orient_matrix_UB_21      -0.0682113000
_diffrn_orient_matrix_UB_22      0.0155611000
_diffrn_orient_matrix_UB_23      0.0240511000
_diffrn_orient_matrix_UB_31      -0.0177605000
_diffrn_orient_matrix_UB_32      0.0421916000
_diffrn_orient_matrix_UB_33      -0.1280948000
_diffrn_oxdiff_digest_frames     
;
0108e115e54f6932d2423dba7962db12fc000579f26
;
_diffrn_oxdiff_digest_hkl        
;
01dbfbc6ff449313704d8ad8f146be5d9aa658
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2806
_reflns_number_total             3289
_reflns_odcompleteness_completeness 99.90
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.112a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.183
_refine_diff_density_min         -0.257
_refine_diff_density_rms         0.034
_refine_ls_extinction_coef       0.00035(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     202
_refine_ls_number_reflns         3289
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0420
_refine_ls_R_factor_gt           0.0368
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0594P)²+0.9339P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1071
_refine_ls_wR_factor_ref         0.1111
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C1(H1A)
2.b Aromatic/amide H refined with riding coordinates:
 N1(H1), C4(H4), C7(H7), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C13(H13), C14(H14), C15(H15)
2.c Idealised Me refined as rotating group:
 C16(H16A,H16B,H16C), C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.36252(2) 0.55676(3) 0.84750(3) 0.04425(15) Uani 1 1 d . . . . .
O1 O 0.34230(6) 0.56710(8) 0.96648(10) 0.0558(3) Uani 1 1 d . . . . .
O2 O 0.33783(6) 0.63887(9) 0.75613(10) 0.0615(3) Uani 1 1 d . . . . .
O3 O 0.43539(5) 0.55783(9) 0.84801(12) 0.0630(3) Uani 1 1 d . . . . .
N1 N 0.24657(5) 0.42469(9) 0.61162(10) 0.0454(3) Uani 1 1 d . . . . .
H1 H 0.2688 0.4188 0.5539 0.055 Uiso 1 1 calc R . . . .
C1 C 0.34081(6) 0.44599(10) 0.76766(12) 0.0414(3) Uani 1 1 d . . . . .
H1A H 0.3591 0.4490 0.6924 0.050 Uiso 1 1 calc R . . . .
C2 C 0.36579(6) 0.35370(11) 0.83188(12) 0.0439(3) Uani 1 1 d . . . . .
C3 C 0.27014(7) 0.44160(10) 0.73080(12) 0.0410(3) Uani 1 1 d . . . . .
C4 C 0.22152(7) 0.44709(10) 0.79649(13) 0.0449(3) Uani 1 1 d . . . . .
H4 H 0.2249 0.4580 0.8793 0.054 Uiso 1 1 calc R . . . .
C5 C 0.16446(7) 0.43289(10) 0.71410(13) 0.0440(3) Uani 1 1 d . . . . .
C6 C 0.18185(7) 0.41868(11) 0.59900(13) 0.0452(3) Uani 1 1 d . . . . .
C7 C 0.13796(8) 0.39982(13) 0.49699(14) 0.0570(4) Uani 1 1 d . . . . .
H7 H 0.1503 0.3903 0.4216 0.068 Uiso 1 1 calc R . . . .
C8 C 0.10024(7) 0.42881(13) 0.72581(16) 0.0546(4) Uani 1 1 d . . . . .
H8 H 0.0872 0.4383 0.8007 0.066 Uiso 1 1 calc R . . . .
C9 C 0.35433(8) 0.33087(12) 0.94689(14) 0.0555(4) Uani 1 1 d . . . . .
H9 H 0.3341 0.3752 0.9903 0.067 Uiso 1 1 calc R . . . .
C10 C 0.39685(9) 0.28745(14) 0.76991(15) 0.0627(4) Uani 1 1 d . . . . .
H10 H 0.4062 0.3025 0.6935 0.075 Uiso 1 1 calc R . . . .
C11 C 0.37263(9) 0.24248(14) 0.99833(16) 0.0650(5) Uani 1 1 d . . . . .
H11 H 0.3650 0.2281 1.0762 0.078 Uiso 1 1 calc R . . . .
C12 C 0.05699(7) 0.41055(15) 0.62479(17) 0.0632(5) Uani 1 1 d . . . . .
H12 H 0.0143 0.4080 0.6319 0.076 Uiso 1 1 calc R . . . .
C13 C 0.07534(8) 0.39586(15) 0.51213(16) 0.0635(5) Uani 1 1 d . . . . .
H13 H 0.0448 0.3831 0.4457 0.076 Uiso 1 1 calc R . . . .
C14 C 0.40200(9) 0.17603(14) 0.93447(17) 0.0659(5) Uani 1 1 d . . . . .
H14 H 0.4135 0.1163 0.9683 0.079 Uiso 1 1 calc R . . . .
C15 C 0.41419(10) 0.19813(15) 0.82131(18) 0.0742(5) Uani 1 1 d . . . . .
H15 H 0.4342 0.1534 0.7782 0.089 Uiso 1 1 calc R . . . .
C16 C 0.27846(10) 0.68696(15) 0.7589(2) 0.0835(6) Uani 1 1 d . . . . .
H16A H 0.2771 0.7452 0.7124 0.125 Uiso 1 1 calc GR . . . .
H16B H 0.2742 0.7022 0.8412 0.125 Uiso 1 1 calc GR . . . .
H16C H 0.2445 0.6455 0.7251 0.125 Uiso 1 1 calc GR . . . .
C17 C 0.47586(11) 0.6278(2) 0.9143(3) 0.1067(9) Uani 1 1 d . . . . .
H17A H 0.5181 0.6198 0.8971 0.160 Uiso 1 1 calc GR . . . .
H17B H 0.4754 0.6193 0.9994 0.160 Uiso 1 1 calc GR . . . .
H17C H 0.4611 0.6913 0.8907 0.160 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.4656(11) . ?
P1 O2 1.5688(12) . ?
P1 O3 1.5605(12) . ?
P1 C1 1.8044(14) . ?
O2 C16 1.441(2) . ?
O3 C17 1.433(2) . ?
N1 H1 0.8600 . ?
N1 C3 1.3717(18) . ?
N1 C6 1.3751(18) . ?
C1 H1A 0.9800 . ?
C1 C2 1.526(2) . ?
C1 C3 1.5096(18) . ?
C2 C9 1.381(2) . ?
C2 C10 1.381(2) . ?
C3 C4 1.363(2) . ?
C4 H4 0.9300 . ?
C4 C5 1.429(2) . ?
C5 C6 1.405(2) . ?
C5 C8 1.403(2) . ?
C6 C7 1.389(2) . ?
C7 H7 0.9300 . ?
C7 C13 1.378(2) . ?
C8 H8 0.9300 . ?
C8 C12 1.372(2) . ?
C9 H9 0.9300 . ?
C9 C11 1.387(2) . ?
C10 H10 0.9300 . ?
C10 C15 1.394(3) . ?
C11 H11 0.9300 . ?
C11 C14 1.375(3) . ?
C12 H12 0.9300 . ?
C12 C13 1.389(3) . ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C14 C15 1.364(3) . ?
C15 H15 0.9300 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 O2 113.72(7) . . ?
O1 P1 O3 115.29(7) . . ?
O1 P1 C1 116.28(7) . . ?
O2 P1 C1 105.18(7) . . ?
O3 P1 O2 103.58(7) . . ?
O3 P1 C1 101.16(6) . . ?
C16 O2 P1 122.37(12) . . ?
C17 O3 P1 122.40(14) . . ?
C3 N1 H1 125.4 . . ?
C3 N1 C6 109.18(12) . . ?
C6 N1 H1 125.4 . . ?
P1 C1 H1A 106.3 . . ?
C2 C1 P1 115.97(9) . . ?
C2 C1 H1A 106.3 . . ?
C3 C1 P1 110.05(9) . . ?
C3 C1 H1A 106.3 . . ?
C3 C1 C2 111.16(11) . . ?
C9 C2 C1 122.12(13) . . ?
C9 C2 C10 118.66(15) . . ?
C10 C2 C1 119.05(13) . . ?
N1 C3 C1 118.67(12) . . ?
C4 C3 N1 109.42(12) . . ?
C4 C3 C1 131.83(13) . . ?
C3 C4 H4 126.4 . . ?
C3 C4 C5 107.12(13) . . ?
C5 C4 H4 126.4 . . ?
C6 C5 C4 106.86(12) . . ?
C8 C5 C4 134.56(14) . . ?
C8 C5 C6 118.56(14) . . ?
N1 C6 C5 107.41(12) . . ?
N1 C6 C7 130.06(14) . . ?
C7 C6 C5 122.51(14) . . ?
C6 C7 H7 121.4 . . ?
C13 C7 C6 117.28(15) . . ?
C13 C7 H7 121.4 . . ?
C5 C8 H8 120.6 . . ?
C12 C8 C5 118.78(15) . . ?
C12 C8 H8 120.6 . . ?
C2 C9 H9 119.7 . . ?
C2 C9 C11 120.68(16) . . ?
C11 C9 H9 119.7 . . ?
C2 C10 H10 119.8 . . ?
C2 C10 C15 120.36(16) . . ?
C15 C10 H10 119.8 . . ?
C9 C11 H11 119.9 . . ?
C14 C11 C9 120.14(17) . . ?
C14 C11 H11 119.9 . . ?
C8 C12 H12 119.2 . . ?
C8 C12 C13 121.65(15) . . ?
C13 C12 H12 119.2 . . ?
C7 C13 C12 121.21(15) . . ?
C7 C13 H13 119.4 . . ?
C12 C13 H13 119.4 . . ?
C11 C14 H14 120.1 . . ?
C15 C14 C11 119.73(17) . . ?
C15 C14 H14 120.1 . . ?
C10 C15 H15 119.8 . . ?
C14 C15 C10 120.39(17) . . ?
C14 C15 H15 119.8 . . ?
O2 C16 H16A 109.5 . . ?
O2 C16 H16B 109.5 . . ?
O2 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O3 C17 H17A 109.5 . . ?
O3 C17 H17B 109.5 . . ?
O3 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 C2 C9 55.78(17) . . . . ?
P1 C1 C2 C10 -129.11(13) . . . . ?
P1 C1 C3 N1 126.60(12) . . . . ?
P1 C1 C3 C4 -56.98(19) . . . . ?
O1 P1 O2 C16 -31.06(17) . . . . ?
O1 P1 O3 C17 -46.4(2) . . . . ?
O1 P1 C1 C2 -59.65(12) . . . . ?
O1 P1 C1 C3 67.59(11) . . . . ?
O2 P1 O3 C17 78.4(2) . . . . ?
O2 P1 C1 C2 173.57(10) . . . . ?
O2 P1 C1 C3 -59.19(11) . . . . ?
O3 P1 O2 C16 -156.95(15) . . . . ?
O3 P1 C1 C2 66.02(11) . . . . ?
O3 P1 C1 C3 -166.74(10) . . . . ?
N1 C3 C4 C5 -0.02(17) . . . . ?
N1 C6 C7 C13 178.42(17) . . . . ?
C1 P1 O2 C16 97.27(16) . . . . ?
C1 P1 O3 C17 -172.75(19) . . . . ?
C1 C2 C9 C11 173.99(15) . . . . ?
C1 C2 C10 C15 -173.09(16) . . . . ?
C1 C3 C4 C5 -176.68(14) . . . . ?
C2 C1 C3 N1 -103.52(14) . . . . ?
C2 C1 C3 C4 72.89(19) . . . . ?
C2 C9 C11 C14 -0.6(3) . . . . ?
C2 C10 C15 C14 -1.5(3) . . . . ?
C3 N1 C6 C5 0.35(16) . . . . ?
C3 N1 C6 C7 -177.95(17) . . . . ?
C3 C1 C2 C9 -70.91(17) . . . . ?
C3 C1 C2 C10 104.20(16) . . . . ?
C3 C4 C5 C6 0.23(17) . . . . ?
C3 C4 C5 C8 178.73(17) . . . . ?
C4 C5 C6 N1 -0.35(16) . . . . ?
C4 C5 C6 C7 178.10(15) . . . . ?
C4 C5 C8 C12 -177.97(18) . . . . ?
C5 C6 C7 C13 0.3(3) . . . . ?
C5 C8 C12 C13 0.2(3) . . . . ?
C6 N1 C3 C1 176.96(12) . . . . ?
C6 N1 C3 C4 -0.21(17) . . . . ?
C6 C5 C8 C12 0.4(2) . . . . ?
C6 C7 C13 C12 0.3(3) . . . . ?
C8 C5 C6 N1 -179.14(13) . . . . ?
C8 C5 C6 C7 -0.7(2) . . . . ?
C8 C12 C13 C7 -0.5(3) . . . . ?
C9 C2 C10 C15 2.2(3) . . . . ?
C9 C11 C14 C15 1.3(3) . . . . ?
C10 C2 C9 C11 -1.1(2) . . . . ?
C11 C14 C15 C10 -0.3(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.539
_oxdiff_exptl_absorpt_empirical_full_min 0.830
