# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Ag8-1
_database_code_depnum_ccdc_archive 'CCDC 2511975'
loop_
_audit_author_name
_audit_author_address
'Jiankang Chen'
;Anhui University
China
;
_audit_update_record             
;
2025-12-17 deposited with the CCDC.	2025-12-22 downloaded from the CCDC.
;
_audit_creation_date             2025-12-15
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C40 H68 Ag4 S4)'
_chemical_formula_sum            'C80 H136 Ag8 S8'
_chemical_formula_weight         2217.32
_chemical_absolute_configuration rm
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           5
_space_group_name_H-M_alt        'I 1 2 1'
_space_group_name_Hall           'I 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'

_cell_length_a                   16.9196(2)
_cell_length_b                   12.7575(2)
_cell_length_c                   20.1848(3)
_cell_angle_alpha                90
_cell_angle_beta                 91.2890(10)
_cell_angle_gamma                90
_cell_volume                     4355.82(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    26900
_cell_measurement_temperature    120.0(4)
_cell_measurement_theta_max      76.4580
_cell_measurement_theta_min      3.3510
_shelx_estimated_absorpt_T_max   0.738
_shelx_estimated_absorpt_T_min   0.564
_exptl_absorpt_coefficient_mu    16.192
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.00261
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.143a (Rigaku Oxford Diffraction, 2024)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.691
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2240
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1316
_diffrn_reflns_av_unetI/netI     0.0663
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            42202
_diffrn_reflns_point_group_measured_fraction_full 0.947
_diffrn_reflns_point_group_measured_fraction_max 0.910
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.700
_diffrn_reflns_theta_min         3.371
_diffrn_ambient_temperature      120.15
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -82.00 -42.00   0.50    0.05    --  -48.07 -19.00 -30.00   80
  2  ω    -93.00 -41.00   0.50    0.05    --  -48.07 -38.00 -30.00  104
  3  ω   -109.00 -80.00   0.50    0.05    --  -48.07 -14.00  64.00   58
  4  ω    -66.00 -41.00   0.50    0.05    --  -48.07 -14.00  64.00   50
  5  ω    -73.00 -47.00   0.50    0.09    -- -103.74  77.00  60.00   52
  6  ω     -6.00  20.00   0.50    0.05    --  -48.07  14.00-124.00   52
  7  ω     30.00 101.00   0.50    0.05    --   48.07  77.00   0.00  142
  8  ω     56.00  83.00   0.50    0.05    --   48.07  77.00  30.00   54
  9  ω     29.00  54.00   0.50    0.05    --   48.07  77.00 -30.00   50
 10  ω     38.00 100.00   0.50    0.05    --   48.07  57.00   0.00  124
 11  ω     37.00  97.00   0.50    0.05    --   48.07  57.00 -60.00  120
 12  ω     29.00  60.00   0.50    0.05    --   48.07  77.00 -60.00   62
 13  ω     28.00  74.00   0.50    0.05    --   48.07  77.00 -90.00   92
 14  ω     67.00 115.00   0.50    0.05    --   48.07  14.00-124.00   96
 15  ω    101.00 137.00   0.50    0.09    --  103.74  14.00-124.00   72
 16  ω    151.00 176.00   0.50    0.09    --  103.74  77.00 -90.00   50
 17  ω     86.00 171.00   0.50    0.09    --  103.74  77.00   0.00  170
 18  ω     84.00 109.00   0.50    0.09    --  103.74  77.00 -30.00   50
 19  ω     85.00 112.00   0.50    0.09    --  103.74  77.00 -60.00   54
 20  ω     91.00 117.00   0.50    0.09    --  103.74  57.00 -60.00   52
 21  ω     83.00 110.00   0.50    0.09    --  103.74  77.00 -90.00   54
 22  ω     95.00 173.00   0.50    0.09    --  103.74  57.00 -90.00  156
 23  ω     99.00 124.00   0.50    0.09    --  103.74  57.00  30.00   50
 24  ω     20.00  70.00   0.50    0.05    --   48.07-125.00-180.00  100
 25  ω     35.00 105.00   0.50    0.09    --  103.74 -99.00 -90.00  140
 26  ω     34.00  71.00   0.50    0.09    --  103.74 -99.00 -60.00   74
 27  ω     74.00 104.00   0.50    0.09    --  103.74 -99.00 -60.00   60
 28  ω     64.00 103.00   0.50    0.09    --  103.74-125.00  30.00   78
 29  ω     19.00  92.00   0.50    0.05    --   48.07-125.00 -30.00  146
 30  ω     63.00  89.00   0.50    0.09    --  103.74 -99.00-180.00   52
 31  ω     37.00  62.00   0.50    0.09    --  103.74 -99.00-180.00   50
 32  ω     34.00 106.00   0.50    0.09    --  103.74 -99.00-150.00  144
 33  ω     33.00  68.00   0.50    0.09    --  103.74 -57.00 -60.00   70
 34  ω     40.00  67.00   0.50    0.09    --  103.74 -57.00 -90.00   54
 35  ω    -22.00  26.00   0.50    0.05    --   48.07 -14.00  64.00   96
 36  ω   -109.00 -82.00   0.50    0.09    -- -103.74 -79.00  28.21   54
 37  ω   -109.00 -84.00   0.50    0.09    -- -103.74 -77.00  30.00   50
 38  ω   -118.00 -84.00   0.50    0.09    -- -103.74 -77.00  22.17   68
 39  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -77.00   0.00   50
 40  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -77.00  60.00   50
 41  ω   -173.00-147.00   0.50    0.09    -- -103.74 -77.00  60.00   52
 42  ω   -172.00-146.00   0.50    0.09    -- -103.74 -77.00   0.00   52
 43  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -77.00 -60.00   50
 44  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -77.00 -37.59   50
 45  ω   -109.00 -84.00   0.50    0.09    -- -103.74 -75.00 -30.24   50
 46  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -68.00 -59.44   50
 47  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -76.00 -71.03   50
 48  ω   -108.00 -83.00   0.50    0.09    -- -103.74 -77.00 -90.00   50
 49  ω   -173.00 -88.00   0.50    0.09    -- -103.74 -67.00 -91.85  170
 50  ω   -163.00-137.00   0.50    0.09    -- -103.74 -68.00 -59.44   52
 51  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -66.00 -20.26   50
 52  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -67.00  -3.17   50
 53  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -67.00   2.26   50
 54  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -68.00  60.10   50
 55  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -66.00  37.79   50
 56  ω   -121.00 -87.00   0.50    0.09    -- -103.74 -66.00  30.14   68
 57  ω   -171.00-129.00   0.50    0.09    -- -103.74 -66.00  30.14   84
 58  ω   -173.00-147.00   0.50    0.09    -- -103.74 -65.00 -27.81   52
 59  ω   -118.00 -89.00   0.50    0.09    -- -103.74 -64.00 -68.31   58
 60  ω   -112.00 -87.00   0.50    0.09    -- -103.74 -66.00 -87.83   50
 61  ω   -119.00 -88.00   0.50    0.09    -- -103.74 -65.00 -27.81   62
 62  ω   -132.00 -89.00   0.50    0.09    -- -103.74 -63.00 -38.66   86
 63  ω   -114.00 -88.00   0.50    0.09    -- -103.74 -64.00  31.32   52
 64  ω   -115.00 -90.00   0.50    0.09    -- -103.74 -63.00  19.02   50
 65  ω   -174.00 -92.00   0.50    0.09    -- -103.74 -60.00 -14.03  164
 66  ω   -171.00-145.00   0.50    0.09    -- -103.74 -63.00 -38.66   52
 67  ω   -150.00-125.00   0.50    0.09    -- -103.74 -61.00 -86.87   50
 68  ω   -115.00 -89.00   0.50    0.09    -- -103.74 -61.00 -86.87   52
 69  ω   -115.00 -90.00   0.50    0.09    -- -103.74 -58.00 -56.35   50
 70  ω   -116.00 -91.00   0.50    0.09    -- -103.74 -57.00 -60.00   50
 71  ω   -130.00 -92.00   0.50    0.09    -- -103.74 -54.00 -70.24   76
 72  ω   -168.00-138.00   0.50    0.09    -- -103.74 -54.00 -70.24   60
 73  ω   -174.00 -93.00   0.50    0.09    -- -103.74 -54.00  12.47  162
 74  ω   -149.00 -93.00   0.50    0.09    -- -103.74 -51.00 -10.38  112
 75  ω   -139.00 -93.00   0.50    0.09    -- -103.74 -51.00  44.58   92
 76  ω   -119.00 -93.00   0.50    0.09    -- -103.74 -51.00  36.00   52
 77  ω   -120.00 -95.00   0.50    0.09    -- -103.74 -47.00  44.89   50
 78  ω   -135.00 -98.00   0.50    0.09    -- -103.74 -14.00  64.00   74
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.773
_reflns_Friedel_fraction_full    0.890
_reflns_Friedel_fraction_max     0.832
_reflns_number_gt                7773
_reflns_number_total             8370
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.43.143a (Rigaku OD, 2024)'
_computing_data_collection       'CrysAlisPro 1.171.43.143a (Rigaku OD, 2024)'
_computing_data_reduction        'CrysAlisPro 1.171.43.143a (Rigaku OD, 2024)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.966
_refine_diff_density_min         -1.696
_refine_diff_density_rms         0.191
_refine_ls_abs_structure_details 
;
 Flack x determined using 3092 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.044(18)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     444
_refine_ls_number_reflns         8370
_refine_ls_number_restraints     61
_refine_ls_R_factor_all          0.0670
_refine_ls_R_factor_gt           0.0634
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1301P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1684
_refine_ls_wR_factor_ref         0.1714
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(C15) \\sim Ueq, Uanis(C015) \\sim Ueq, Uanis(C017) \\sim Ueq, Uanis(C13)
\\sim Ueq, Uanis(C013) \\sim Ueq, Uanis(C019) \\sim Ueq, Uanis(C018) \\sim Ueq,
Uanis(C011) \\sim Ueq, Uanis(C00X) \\sim Ueq, Uanis(C00V) \\sim Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
2.a Riding coordinates:
 C011(H01D,H01E,H01F)
2.b Ternary CH refined with riding coordinates:
 C00C(H00E), C00D(H00F), C00H(H00O), C00I(H00P), C00M(H2), C00X(H6), C00Z(H7),
 C013(H013)
2.c Secondary CH2 refined with riding coordinates:
 C00A(H00A,H00B), C00B(H00C,H00D), C00G(H00M,H00N), C00J(H00Q,H00R), C13(H13A,
 H13B), C00Q(H00Y,H), C00R(H00Z,HA), C00W(H5,HJ), C012(H01G,H01H), C014(H01I,
 H01J), C017(H01K,H01L), C019(H01M,H01N)
2.d Idealised Me refined as rotating group:
 C6(H6A,H6B,H6C), C00E(H00G,H00H,H00I), C00F(H00J,H00K,H00L), C00L(H00S,H00T,
 H00U), C15(H15A,H15B,H15C), C00P(H00V,H00W,H00X), C00S(H00,HB,HC), C00T(H1,HD,
 HE), C00U(H3,HF,HG), C00V(H4,HH,HI), C010(H01A,H01B,H01C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag01 Ag 0.42125(4) -0.73600(8) 0.07954(3) 0.0301(2) Uani 1 1 d . . . . .
Ag02 Ag 0.59742(4) -0.73524(7) 0.06360(3) 0.0285(2) Uani 1 1 d . . . . .
Ag03 Ag 0.39682(6) -0.40179(8) -0.05885(5) 0.0410(3) Uani 1 1 d . . . . .
Ag04 Ag 0.43451(6) -0.43045(9) 0.08685(5) 0.0437(3) Uani 1 1 d . . . . .
S1 S 0.34463(14) -0.8529(2) 0.01258(13) 0.0287(6) Uani 1 1 d . . . . .
S007 S 0.32487(19) -0.4959(3) 0.02182(17) 0.0398(7) Uani 1 1 d . . . . .
S2 S 0.51875(15) -0.6284(2) 0.13186(12) 0.0280(5) Uani 1 1 d . . . . .
S008 S 0.4685(2) -0.3299(3) -0.14807(15) 0.0379(7) Uani 1 1 d . . . . .
C009 C 0.4664(7) -0.6505(11) 0.2643(5) 0.033(3) Uani 1 1 d . . . . .
C00A C 0.4632(7) -0.5326(11) 0.2725(5) 0.032(3) Uani 1 1 d . . . . .
H00A H 0.414840 -0.511146 0.295692 0.039 Uiso 1 1 calc R U . . .
H00B H 0.464208 -0.496964 0.228918 0.039 Uiso 1 1 calc R U . . .
C00B C 0.5079(8) -0.6825(13) 0.3299(6) 0.041(3) Uani 1 1 d . . . . .
H00C H 0.476964 -0.663414 0.369160 0.049 Uiso 1 1 calc R U . . .
H00D H 0.521738 -0.757825 0.331282 0.049 Uiso 1 1 calc R U . . .
C00C C 0.5794(7) -0.6125(11) 0.3212(5) 0.036(3) Uani 1 1 d . . . . .
H00E H 0.618777 -0.617060 0.358828 0.043 Uiso 1 1 calc R U . . .
C00D C 0.2409(6) -0.8128(11) 0.0195(5) 0.031(2) Uani 1 1 d . . . . .
H00F H 0.240439 -0.735354 0.027011 0.037 Uiso 1 1 calc R U . . .
C6 C 0.1812(19) -0.258(3) -0.019(2) 0.128(13) Uani 1 1 d . . . . .
H6A H 0.185848 -0.216550 0.021393 0.191 Uiso 1 1 calc R U . . .
H6B H 0.133011 -0.238300 -0.043917 0.191 Uiso 1 1 calc R U . . .
H6C H 0.227301 -0.245664 -0.046677 0.191 Uiso 1 1 calc R U . . .
C00E C 0.1644(9) -0.7350(15) -0.0794(7) 0.051(3) Uani 1 1 d . . . . .
H00G H 0.132673 -0.751052 -0.119385 0.077 Uiso 1 1 calc R U . . .
H00H H 0.212598 -0.698038 -0.091858 0.077 Uiso 1 1 calc R U . . .
H00I H 0.133645 -0.690543 -0.049921 0.077 Uiso 1 1 calc R U . . .
C00F C 0.6604(7) -0.5660(12) 0.2187(6) 0.035(3) Uani 1 1 d . . . . .
H00J H 0.704727 -0.543515 0.247383 0.053 Uiso 1 1 calc R U . . .
H00K H 0.626440 -0.505652 0.208369 0.053 Uiso 1 1 calc R U . . .
H00L H 0.680663 -0.595287 0.177586 0.053 Uiso 1 1 calc R U . . .
C00G C 0.5397(7) -0.5062(10) 0.3153(6) 0.034(3) Uani 1 1 d . . . . .
H00M H 0.573727 -0.455050 0.292521 0.041 Uiso 1 1 calc R U . . .
H00N H 0.526084 -0.478160 0.359361 0.041 Uiso 1 1 calc R U . . .
C00H C 0.5325(6) -0.6823(10) 0.2168(5) 0.027(2) Uani 1 1 d . . . . .
H00O H 0.532135 -0.760443 0.213280 0.032 Uiso 1 1 calc R U . . .
C00I C 0.1117(7) -0.8830(13) -0.0103(6) 0.042(3) Uani 1 1 d . . . . .
H00P H 0.061327 -0.873011 -0.036386 0.050 Uiso 1 1 calc R U . . .
C00J C 0.1124(7) -0.8293(14) 0.0586(6) 0.041(3) Uani 1 1 d . . . . .
H00Q H 0.106566 -0.752208 0.055708 0.050 Uiso 1 1 calc R U . . .
H00R H 0.072594 -0.858888 0.088540 0.050 Uiso 1 1 calc R U . . .
C00K C 0.6126(7) -0.6492(11) 0.2543(5) 0.034(3) Uani 1 1 d . . . . .
C13 C 0.416(3) -0.066(4) -0.234(2) 0.140(12) Uani 1 1 d . U . . .
H13A H 0.387962 -0.002503 -0.249568 0.168 Uiso 1 1 calc R U . . .
H13B H 0.420475 -0.116089 -0.271135 0.168 Uiso 1 1 calc R U . . .
C00L C 0.6636(8) -0.7481(15) 0.2626(7) 0.052(4) Uani 1 1 d . . . . .
H00S H 0.712652 -0.730502 0.286861 0.079 Uiso 1 1 calc R U . . .
H00T H 0.676355 -0.775894 0.218814 0.079 Uiso 1 1 calc R U . . .
H00U H 0.634457 -0.801052 0.287308 0.079 Uiso 1 1 calc R U . . .
C00M C 0.2479(8) -0.4016(11) 0.0483(7) 0.039(3) Uani 1 1 d . . . . .
H2 H 0.275158 -0.333717 0.058574 0.047 Uiso 1 1 calc R U . . .
C15 C 0.391(2) -0.129(3) -0.0509(15) 0.116(11) Uani 1 1 d . U . . .
H15A H 0.355338 -0.069348 -0.043270 0.174 Uiso 1 1 calc R U . . .
H15B H 0.432242 -0.130075 -0.016142 0.174 Uiso 1 1 calc R U . . .
H15C H 0.360706 -0.194129 -0.049943 0.174 Uiso 1 1 calc R U . . .
C00N C 0.1862(6) -0.8358(11) -0.0442(6) 0.034(3) Uani 1 1 d . . . . .
C00O C 0.1975(6) -0.8636(12) 0.0771(6) 0.034(3) Uani 1 1 d . . . . .
C00P C 0.2215(7) -0.9102(13) -0.0944(6) 0.045(3) Uani 1 1 d . . . . .
H00V H 0.237451 -0.975380 -0.072153 0.068 Uiso 1 1 calc R U . . .
H00W H 0.267829 -0.877379 -0.114022 0.068 Uiso 1 1 calc R U . . .
H00X H 0.182031 -0.925658 -0.129246 0.068 Uiso 1 1 calc R U . . .
C00Q C 0.1264(8) -0.9950(14) 0.0115(8) 0.048(3) Uani 1 1 d . . . . .
H00Y H 0.144588 -1.038573 -0.025822 0.057 Uiso 1 1 calc R U . . .
H H 0.078110 -1.026670 0.029714 0.057 Uiso 1 1 calc R U . . .
C00R C 0.1923(8) -0.9834(14) 0.0659(7) 0.047(3) Uani 1 1 d . . . . .
H00Z H 0.177630 -1.020167 0.107024 0.057 Uiso 1 1 calc R U . . .
HA H 0.243166 -1.011723 0.050516 0.057 Uiso 1 1 calc R U . . .
C00S C 0.3874(8) -0.6998(14) 0.2485(7) 0.047(3) Uani 1 1 d . . . . .
H00 H 0.350830 -0.684645 0.284263 0.071 Uiso 1 1 calc R U . . .
HB H 0.393740 -0.775880 0.244235 0.071 Uiso 1 1 calc R U . . .
HC H 0.366079 -0.671122 0.206772 0.071 Uiso 1 1 calc R U . . .
C00T C 0.2296(8) -0.8336(13) 0.1456(6) 0.044(3) Uani 1 1 d . . . . .
H1 H 0.238340 -0.757664 0.147362 0.066 Uiso 1 1 calc R U . . .
HD H 0.279667 -0.870082 0.154312 0.066 Uiso 1 1 calc R U . . .
HE H 0.191344 -0.853547 0.179070 0.066 Uiso 1 1 calc R U . . .
C00U C 0.2573(11) -0.440(2) 0.1721(9) 0.072(5) Uani 1 1 d . . . . .
H3 H 0.297394 -0.494792 0.166832 0.107 Uiso 1 1 calc R U . . .
HF H 0.225170 -0.456288 0.210530 0.107 Uiso 1 1 calc R U . . .
HG H 0.283414 -0.372232 0.178747 0.107 Uiso 1 1 calc R U . . .
C00V C 0.6300(18) -0.130(3) -0.158(2) 0.122(10) Uani 1 1 d . U . . .
H4 H 0.667497 -0.113890 -0.193117 0.182 Uiso 1 1 calc R U . . .
HH H 0.646174 -0.194725 -0.135584 0.182 Uiso 1 1 calc R U . . .
HI H 0.629146 -0.072270 -0.126304 0.182 Uiso 1 1 calc R U . . .
C00W C 0.1604(10) -0.5416(16) 0.0965(9) 0.060(5) Uani 1 1 d . . . . .
H5 H 0.193947 -0.591028 0.071797 0.073 Uiso 1 1 calc R U . . .
HJ H 0.143744 -0.575358 0.138071 0.073 Uiso 1 1 calc R U . . .
C00X C 0.4960(9) -0.1914(13) -0.1339(8) 0.049(3) Uani 1 1 d . U . . .
H6 H 0.528785 -0.192230 -0.092003 0.059 Uiso 1 1 calc R U . . .
C00Y C 0.2053(9) -0.4356(17) 0.1110(8) 0.058(4) Uani 1 1 d . . . . .
C00Z C 0.1058(11) -0.391(2) 0.0416(13) 0.084(7) Uani 1 1 d . . . . .
H7 H 0.058391 -0.350173 0.026095 0.100 Uiso 1 1 calc R U . . .
C010 C 0.1754(16) -0.442(2) -0.0649(10) 0.085(7) Uani 1 1 d . . . . .
H01A H 0.125454 -0.429919 -0.089210 0.128 Uiso 1 1 calc R U . . .
H01B H 0.179949 -0.516774 -0.053732 0.128 Uiso 1 1 calc R U . . .
H01C H 0.219658 -0.421761 -0.092637 0.128 Uiso 1 1 calc R U . . .
C011 C 0.547(2) -0.211(2) -0.2551(13) 0.113(10) Uani 1 1 d . U . . .
H01D H 0.500313 -0.256685 -0.254882 0.170 Uiso 1 1 d R U . . .
H01E H 0.594743 -0.254445 -0.257732 0.170 Uiso 1 1 d R U . . .
H01F H 0.543713 -0.164255 -0.293432 0.170 Uiso 1 1 d R U . . .
C012 C 0.1369(12) -0.359(2) 0.1103(12) 0.079(6) Uani 1 1 d . . . . .
H01G H 0.154290 -0.285437 0.112391 0.094 Uiso 1 1 calc R U . . .
H01H H 0.098661 -0.373954 0.145527 0.094 Uiso 1 1 calc R U . . .
C013 C 0.5074(18) -0.036(2) -0.2005(13) 0.092(7) Uani 1 1 d . U . . .
H013 H 0.537734 0.021103 -0.222759 0.110 Uiso 1 1 calc R U . . .
C014 C 0.0891(11) -0.507(2) 0.0545(12) 0.075(6) Uani 1 1 d . . . . .
H01I H 0.085411 -0.546415 0.012468 0.090 Uiso 1 1 calc R U . . .
H01J H 0.039453 -0.515585 0.078820 0.090 Uiso 1 1 calc R U . . .
C015 C 0.4298(12) -0.1161(18) -0.1203(11) 0.070(5) Uani 1 1 d . U . . .
C016 C 0.1772(11) -0.3768(15) -0.0010(9) 0.063(5) Uani 1 1 d . . . . .
C017 C 0.377(2) -0.113(2) -0.1788(15) 0.102(8) Uani 1 1 d . U . . .
H01K H 0.360062 -0.185459 -0.190620 0.122 Uiso 1 1 calc R U . . .
H01L H 0.328700 -0.072368 -0.168627 0.122 Uiso 1 1 calc R U . . .
C018 C 0.5521(13) -0.1436(18) -0.1875(11) 0.069(5) Uani 1 1 d . U . . .
C019 C 0.4744(15) -0.011(2) -0.1304(13) 0.082(6) Uani 1 1 d . U . . .
H01M H 0.517112 0.000290 -0.096728 0.098 Uiso 1 1 calc R U . . .
H01N H 0.438272 0.050391 -0.131093 0.098 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag01 Ag02 3.0053(9) . ?
Ag01 Ag02 2.8994(9) 2_655 ?
Ag01 S1 2.377(3) . ?
Ag01 S2 2.376(3) . ?
Ag02 S1 2.376(3) 2_655 ?
Ag02 S2 2.369(3) . ?
Ag03 Ag04 3.0175(14) . ?
Ag03 Ag04 2.9444(13) 2_655 ?
Ag03 S007 2.380(3) . ?
Ag03 S008 2.378(3) . ?
Ag04 S007 2.399(4) . ?
Ag04 S008 2.403(4) 2_655 ?
S1 C00D 1.836(11) . ?
S007 C00M 1.861(13) . ?
S2 C00H 1.858(11) . ?
S008 C00X 1.848(16) . ?
C009 C00A 1.51(2) . ?
C009 C00B 1.539(16) . ?
C009 C00H 1.544(16) . ?
C009 C00S 1.505(17) . ?
C00A H00A 0.9900 . ?
C00A H00B 0.9900 . ?
C00A C00G 1.578(16) . ?
C00B H00C 0.9900 . ?
C00B H00D 0.9900 . ?
C00B C00C 1.518(18) . ?
C00C H00E 1.0000 . ?
C00C C00G 1.517(19) . ?
C00C C00K 1.547(16) . ?
C00D H00F 1.0000 . ?
C00D C00N 1.594(14) . ?
C00D C00O 1.533(16) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C6 C016 1.56(4) . ?
C00E H00G 0.9800 . ?
C00E H00H 0.9800 . ?
C00E H00I 0.9800 . ?
C00E C00N 1.51(2) . ?
C00F H00J 0.9800 . ?
C00F H00K 0.9800 . ?
C00F H00L 0.9800 . ?
C00F C00K 1.523(18) . ?
C00G H00M 0.9900 . ?
C00G H00N 0.9900 . ?
C00H H00O 1.0000 . ?
C00H C00K 1.594(15) . ?
C00I H00P 1.0000 . ?
C00I C00J 1.550(17) . ?
C00I C00N 1.568(16) . ?
C00I C00Q 1.51(2) . ?
C00J H00Q 0.9900 . ?
C00J H00R 0.9900 . ?
C00J C00O 1.542(17) . ?
C00K C00L 1.54(2) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C13 C013 1.72(5) . ?
C13 C017 1.44(5) . ?
C00L H00S 0.9800 . ?
C00L H00T 0.9800 . ?
C00L H00U 0.9800 . ?
C00M H2 1.0000 . ?
C00M C00Y 1.53(2) . ?
C00M C016 1.572(18) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C15 C015 1.57(3) . ?
C00N C00P 1.520(19) . ?
C00O C00R 1.55(2) . ?
C00O C00T 1.522(16) . ?
C00P H00V 0.9800 . ?
C00P H00W 0.9800 . ?
C00P H00X 0.9800 . ?
C00Q H00Y 0.9900 . ?
C00Q H 0.9900 . ?
C00Q C00R 1.55(2) . ?
C00R H00Z 0.9900 . ?
C00R HA 0.9900 . ?
C00S H00 0.9800 . ?
C00S HB 0.9800 . ?
C00S HC 0.9800 . ?
C00T H1 0.9800 . ?
C00T HD 0.9800 . ?
C00T HE 0.9800 . ?
C00U H3 0.9800 . ?
C00U HF 0.9800 . ?
C00U HG 0.9800 . ?
C00U C00Y 1.50(3) . ?
C00V H4 0.9800 . ?
C00V HH 0.9800 . ?
C00V HI 0.9800 . ?
C00V C018 1.44(4) . ?
C00W H5 0.9900 . ?
C00W HJ 0.9900 . ?
C00W C00Y 1.58(3) . ?
C00W C014 1.53(3) . ?
C00X H6 1.0000 . ?
C00X C015 1.51(3) . ?
C00X C018 1.58(3) . ?
C00Y C012 1.51(2) . ?
C00Z H7 1.0000 . ?
C00Z C012 1.53(3) . ?
C00Z C014 1.52(4) . ?
C00Z C016 1.51(3) . ?
C010 H01A 0.9800 . ?
C010 H01B 0.9800 . ?
C010 H01C 0.9800 . ?
C010 C016 1.54(3) . ?
C011 H01D 0.9801 . ?
C011 H01E 0.9799 . ?
C011 H01F 0.9798 . ?
C011 C018 1.62(3) . ?
C012 H01G 0.9900 . ?
C012 H01H 0.9900 . ?
C013 H013 1.0000 . ?
C013 C018 1.59(4) . ?
C013 C019 1.57(4) . ?
C014 H01I 0.9900 . ?
C014 H01J 0.9900 . ?
C015 C017 1.47(4) . ?
C015 C019 1.56(3) . ?
C017 H01K 0.9900 . ?
C017 H01L 0.9900 . ?
C019 H01M 0.9900 . ?
C019 H01N 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag02 Ag01 Ag02 88.81(3) 2_655 . ?
S1 Ag01 Ag02 118.07(7) . . ?
S1 Ag01 Ag02 52.39(7) . 2_655 ?
S2 Ag01 Ag02 120.00(7) . 2_655 ?
S2 Ag01 Ag02 50.60(7) . . ?
S2 Ag01 S1 168.39(9) . . ?
Ag01 Ag02 Ag01 91.18(3) 2_655 . ?
S1 Ag02 Ag01 52.43(6) 2_655 2_655 ?
S1 Ag02 Ag01 119.47(7) 2_655 . ?
S2 Ag02 Ag01 50.80(7) . . ?
S2 Ag02 Ag01 122.11(7) . 2_655 ?
S2 Ag02 S1 170.19(9) . 2_655 ?
Ag04 Ag03 Ag04 89.29(4) 2_655 . ?
S007 Ag03 Ag04 51.12(9) . . ?
S007 Ag03 Ag04 125.56(10) . 2_655 ?
S008 Ag03 Ag04 52.36(9) . 2_655 ?
S008 Ag03 Ag04 133.21(9) . . ?
S008 Ag03 S007 171.99(12) . . ?
Ag03 Ag04 Ag03 88.99(4) 2_655 . ?
S007 Ag04 Ag03 132.78(9) . 2_655 ?
S007 Ag04 Ag03 50.57(8) . . ?
S007 Ag04 S008 168.02(13) . 2_655 ?
S008 Ag04 Ag03 124.29(8) 2_655 . ?
S008 Ag04 Ag03 51.60(8) 2_655 2_655 ?
Ag02 S1 Ag01 75.18(9) 2_655 . ?
C00D S1 Ag01 107.0(4) . . ?
C00D S1 Ag02 106.4(4) . 2_655 ?
Ag03 S007 Ag04 78.31(10) . . ?
C00M S007 Ag03 104.0(5) . . ?
C00M S007 Ag04 98.9(4) . . ?
Ag02 S2 Ag01 78.61(9) . . ?
C00H S2 Ag01 105.5(4) . . ?
C00H S2 Ag02 105.3(4) . . ?
Ag03 S008 Ag04 76.04(11) . 2_655 ?
C00X S008 Ag03 112.5(5) . . ?
C00X S008 Ag04 105.3(5) . 2_655 ?
C00A C009 C00B 100.7(10) . . ?
C00A C009 C00H 110.9(10) . . ?
C00B C009 C00H 98.1(10) . . ?
C00S C009 C00A 113.8(12) . . ?
C00S C009 C00B 117.2(11) . . ?
C00S C009 C00H 114.3(11) . . ?
C009 C00A H00A 111.0 . . ?
C009 C00A H00B 111.0 . . ?
C009 C00A C00G 103.9(10) . . ?
H00A C00A H00B 109.0 . . ?
C00G C00A H00A 111.0 . . ?
C00G C00A H00B 111.0 . . ?
C009 C00B H00C 112.7 . . ?
C009 C00B H00D 112.7 . . ?
H00C C00B H00D 110.1 . . ?
C00C C00B C009 95.5(10) . . ?
C00C C00B H00C 112.7 . . ?
C00C C00B H00D 112.7 . . ?
C00B C00C H00E 113.4 . . ?
C00B C00C C00K 103.2(10) . . ?
C00G C00C C00B 100.5(11) . . ?
C00G C00C H00E 113.4 . . ?
C00G C00C C00K 111.8(10) . . ?
C00K C00C H00E 113.4 . . ?
S1 C00D H00F 107.3 . . ?
C00N C00D S1 115.2(8) . . ?
C00N C00D H00F 107.3 . . ?
C00O C00D S1 114.6(9) . . ?
C00O C00D H00F 107.3 . . ?
C00O C00D C00N 104.7(9) . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C016 C6 H6A 109.5 . . ?
C016 C6 H6B 109.5 . . ?
C016 C6 H6C 109.5 . . ?
H00G C00E H00H 109.5 . . ?
H00G C00E H00I 109.5 . . ?
H00H C00E H00I 109.5 . . ?
C00N C00E H00G 109.5 . . ?
C00N C00E H00H 109.5 . . ?
C00N C00E H00I 109.5 . . ?
H00J C00F H00K 109.5 . . ?
H00J C00F H00L 109.5 . . ?
H00K C00F H00L 109.5 . . ?
C00K C00F H00J 109.5 . . ?
C00K C00F H00K 109.5 . . ?
C00K C00F H00L 109.5 . . ?
C00A C00G H00M 111.4 . . ?
C00A C00G H00N 111.4 . . ?
C00C C00G C00A 102.1(10) . . ?
C00C C00G H00M 111.4 . . ?
C00C C00G H00N 111.4 . . ?
H00M C00G H00N 109.2 . . ?
S2 C00H H00O 107.6 . . ?
C009 C00H S2 113.5(8) . . ?
C009 C00H H00O 107.6 . . ?
C009 C00H C00K 104.9(9) . . ?
C00K C00H S2 115.3(8) . . ?
C00K C00H H00O 107.6 . . ?
C00J C00I H00P 113.9 . . ?
C00J C00I C00N 103.4(10) . . ?
C00N C00I H00P 113.9 . . ?
C00Q C00I H00P 113.9 . . ?
C00Q C00I C00J 99.2(11) . . ?
C00Q C00I C00N 111.1(12) . . ?
C00I C00J H00Q 112.8 . . ?
C00I C00J H00R 112.8 . . ?
H00Q C00J H00R 110.3 . . ?
C00O C00J C00I 94.6(10) . . ?
C00O C00J H00Q 112.8 . . ?
C00O C00J H00R 112.8 . . ?
C00C C00K C00H 100.0(9) . . ?
C00F C00K C00C 114.0(11) . . ?
C00F C00K C00H 114.6(9) . . ?
C00F C00K C00L 108.7(11) . . ?
C00L C00K C00C 111.6(10) . . ?
C00L C00K C00H 107.7(11) . . ?
H13A C13 H13B 109.1 . . ?
C013 C13 H13A 111.2 . . ?
C013 C13 H13B 111.2 . . ?
C017 C13 H13A 111.2 . . ?
C017 C13 H13B 111.2 . . ?
C017 C13 C013 103(3) . . ?
C00K C00L H00S 109.5 . . ?
C00K C00L H00T 109.5 . . ?
C00K C00L H00U 109.5 . . ?
H00S C00L H00T 109.5 . . ?
H00S C00L H00U 109.5 . . ?
H00T C00L H00U 109.5 . . ?
S007 C00M H2 107.3 . . ?
C00Y C00M S007 113.5(10) . . ?
C00Y C00M H2 107.3 . . ?
C00Y C00M C016 102.4(13) . . ?
C016 C00M S007 118.4(11) . . ?
C016 C00M H2 107.3 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C015 C15 H15A 109.5 . . ?
C015 C15 H15B 109.5 . . ?
C015 C15 H15C 109.5 . . ?
C00E C00N C00D 110.8(11) . . ?
C00E C00N C00I 110.0(11) . . ?
C00E C00N C00P 108.2(11) . . ?
C00I C00N C00D 100.2(9) . . ?
C00P C00N C00D 115.0(10) . . ?
C00P C00N C00I 112.5(11) . . ?
C00D C00O C00J 99.0(10) . . ?
C00D C00O C00R 109.4(10) . . ?
C00J C00O C00R 101.3(11) . . ?
C00T C00O C00D 114.5(10) . . ?
C00T C00O C00J 117.4(11) . . ?
C00T C00O C00R 113.6(12) . . ?
C00N C00P H00V 109.5 . . ?
C00N C00P H00W 109.5 . . ?
C00N C00P H00X 109.5 . . ?
H00V C00P H00W 109.5 . . ?
H00V C00P H00X 109.5 . . ?
H00W C00P H00X 109.5 . . ?
C00I C00Q H00Y 111.2 . . ?
C00I C00Q H 111.2 . . ?
C00I C00Q C00R 103.0(11) . . ?
H00Y C00Q H 109.1 . . ?
C00R C00Q H00Y 111.2 . . ?
C00R C00Q H 111.2 . . ?
C00O C00R C00Q 103.6(12) . . ?
C00O C00R H00Z 111.0 . . ?
C00O C00R HA 111.0 . . ?
C00Q C00R H00Z 111.0 . . ?
C00Q C00R HA 111.0 . . ?
H00Z C00R HA 109.0 . . ?
C009 C00S H00 109.5 . . ?
C009 C00S HB 109.5 . . ?
C009 C00S HC 109.5 . . ?
H00 C00S HB 109.5 . . ?
H00 C00S HC 109.5 . . ?
HB C00S HC 109.5 . . ?
C00O C00T H1 109.5 . . ?
C00O C00T HD 109.5 . . ?
C00O C00T HE 109.5 . . ?
H1 C00T HD 109.5 . . ?
H1 C00T HE 109.5 . . ?
HD C00T HE 109.5 . . ?
H3 C00U HF 109.5 . . ?
H3 C00U HG 109.5 . . ?
HF C00U HG 109.5 . . ?
C00Y C00U H3 109.5 . . ?
C00Y C00U HF 109.5 . . ?
C00Y C00U HG 109.5 . . ?
H4 C00V HH 109.5 . . ?
H4 C00V HI 109.5 . . ?
HH C00V HI 109.5 . . ?
C018 C00V H4 109.5 . . ?
C018 C00V HH 109.5 . . ?
C018 C00V HI 109.5 . . ?
H5 C00W HJ 109.1 . . ?
C00Y C00W H5 111.2 . . ?
C00Y C00W HJ 111.2 . . ?
C014 C00W H5 111.2 . . ?
C014 C00W HJ 111.2 . . ?
C014 C00W C00Y 102.9(16) . . ?
S008 C00X H6 104.7 . . ?
C015 C00X S008 116.9(12) . . ?
C015 C00X H6 104.7 . . ?
C015 C00X C018 109.9(16) . . ?
C018 C00X S008 114.6(12) . . ?
C018 C00X H6 104.7 . . ?
C00M C00Y C00W 108.9(13) . . ?
C00U C00Y C00M 114.3(14) . . ?
C00U C00Y C00W 113.0(18) . . ?
C00U C00Y C012 117.9(16) . . ?
C012 C00Y C00M 100.6(16) . . ?
C012 C00Y C00W 100.6(15) . . ?
C012 C00Z H7 114.0 . . ?
C014 C00Z H7 114.0 . . ?
C014 C00Z C012 99(2) . . ?
C016 C00Z H7 114.0 . . ?
C016 C00Z C012 102.8(16) . . ?
C016 C00Z C014 111.4(18) . . ?
H01A C010 H01B 109.5 . . ?
H01A C010 H01C 109.5 . . ?
H01B C010 H01C 109.5 . . ?
C016 C010 H01A 109.5 . . ?
C016 C010 H01B 109.5 . . ?
C016 C010 H01C 109.5 . . ?
H01D C011 H01E 109.5 . . ?
H01D C011 H01F 109.5 . . ?
H01E C011 H01F 109.5 . . ?
C018 C011 H01D 109.9 . . ?
C018 C011 H01E 108.6 . . ?
C018 C011 H01F 110.0 . . ?
C00Y C012 C00Z 95.1(14) . . ?
C00Y C012 H01G 112.7 . . ?
C00Y C012 H01H 112.7 . . ?
C00Z C012 H01G 112.7 . . ?
C00Z C012 H01H 112.7 . . ?
H01G C012 H01H 110.2 . . ?
C13 C013 H013 117.1 . . ?
C018 C013 C13 107(2) . . ?
C018 C013 H013 117.1 . . ?
C019 C013 C13 94(2) . . ?
C019 C013 H013 117.1 . . ?
C019 C013 C018 101.8(19) . . ?
C00W C014 H01I 111.1 . . ?
C00W C014 H01J 111.1 . . ?
C00Z C014 C00W 103.4(17) . . ?
C00Z C014 H01I 111.1 . . ?
C00Z C014 H01J 111.1 . . ?
H01I C014 H01J 109.0 . . ?
C00X C015 C15 115(2) . . ?
C00X C015 C019 99.4(16) . . ?
C017 C015 C15 117(2) . . ?
C017 C015 C00X 108.3(19) . . ?
C017 C015 C019 99(2) . . ?
C019 C015 C15 115(2) . . ?
C6 C016 C00M 108.0(17) . . ?
C00Z C016 C6 107(2) . . ?
C00Z C016 C00M 102.9(15) . . ?
C00Z C016 C010 114.4(19) . . ?
C010 C016 C6 109(2) . . ?
C010 C016 C00M 115.0(15) . . ?
C13 C017 C015 110(3) . . ?
C13 C017 H01K 109.6 . . ?
C13 C017 H01L 109.6 . . ?
C015 C017 H01K 109.6 . . ?
C015 C017 H01L 109.6 . . ?
H01K C017 H01L 108.1 . . ?
C00V C018 C00X 109(2) . . ?
C00V C018 C011 116(2) . . ?
C00V C018 C013 113(2) . . ?
C00X C018 C011 110.6(16) . . ?
C00X C018 C013 99.1(17) . . ?
C013 C018 C011 108(2) . . ?
C013 C019 H01M 112.3 . . ?
C013 C019 H01N 112.3 . . ?
C015 C019 C013 97.2(19) . . ?
C015 C019 H01M 112.3 . . ?
C015 C019 H01N 112.3 . . ?
H01M C019 H01N 109.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag01 S1 C00D C00N 149.9(8) . . . . ?
Ag01 S1 C00D C00O -88.5(9) . . . . ?
Ag01 S2 C00H C009 -77.9(9) . . . . ?
Ag01 S2 C00H C00K 161.1(8) . . . . ?
Ag02 S1 C00D C00N 70.8(10) 2_655 . . . ?
Ag02 S1 C00D C00O -167.6(8) 2_655 . . . ?
Ag02 S2 C00H C009 -160.1(8) . . . . ?
Ag02 S2 C00H C00K 78.9(9) . . . . ?
Ag03 S007 C00M C00Y -167.4(10) . . . . ?
Ag03 S007 C00M C016 72.5(13) . . . . ?
Ag03 S008 C00X C015 -56.2(15) . . . . ?
Ag03 S008 C00X C018 173.2(12) . . . . ?
Ag04 S007 C00M C00Y -87.3(11) . . . . ?
Ag04 S007 C00M C016 152.6(12) . . . . ?
Ag04 S008 C00X C015 -137.1(13) 2_655 . . . ?
Ag04 S008 C00X C018 92.3(14) 2_655 . . . ?
S1 C00D C00N C00E -108.9(11) . . . . ?
S1 C00D C00N C00I 135.1(10) . . . . ?
S1 C00D C00N C00P 14.2(15) . . . . ?
S1 C00D C00O C00J -169.6(9) . . . . ?
S1 C00D C00O C00R -64.2(11) . . . . ?
S1 C00D C00O C00T 64.6(14) . . . . ?
S007 C00M C00Y C00U 64.9(19) . . . . ?
S007 C00M C00Y C00W -62.5(13) . . . . ?
S007 C00M C00Y C012 -167.7(12) . . . . ?
S007 C00M C016 C6 -117(2) . . . . ?
S007 C00M C016 C00Z 130.3(15) . . . . ?
S007 C00M C016 C010 5(2) . . . . ?
S2 C00H C00K C00C 130.7(9) . . . . ?
S2 C00H C00K C00F 8.3(14) . . . . ?
S2 C00H C00K C00L -112.8(10) . . . . ?
S008 C00X C015 C15 71(2) . . . . ?
S008 C00X C015 C017 -62(2) . . . . ?
S008 C00X C015 C019 -165.7(14) . . . . ?
S008 C00X C018 C00V -108(2) . . . . ?
S008 C00X C018 C011 21(2) . . . . ?
S008 C00X C018 C013 133.6(15) . . . . ?
C009 C00A C00G C00C 4.2(11) . . . . ?
C009 C00B C00C C00G 58.3(12) . . . . ?
C009 C00B C00C C00K -57.2(12) . . . . ?
C009 C00H C00K C00C 5.1(12) . . . . ?
C009 C00H C00K C00F -117.3(12) . . . . ?
C009 C00H C00K C00L 121.7(11) . . . . ?
C00A C009 C00B C00C -55.2(11) . . . . ?
C00A C009 C00H S2 -61.1(11) . . . . ?
C00A C009 C00H C00K 65.6(11) . . . . ?
C00B C009 C00A C00G 31.5(11) . . . . ?
C00B C009 C00H S2 -166.0(9) . . . . ?
C00B C009 C00H C00K -39.3(12) . . . . ?
C00B C00C C00G C00A -39.0(11) . . . . ?
C00B C00C C00K C00F 154.7(10) . . . . ?
C00B C00C C00K C00H 32.0(12) . . . . ?
C00B C00C C00K C00L -81.6(13) . . . . ?
C00D C00O C00R C00Q -75.8(12) . . . . ?
C00G C00C C00K C00F 47.6(13) . . . . ?
C00G C00C C00K C00H -75.1(12) . . . . ?
C00G C00C C00K C00L 171.2(11) . . . . ?
C00H C009 C00A C00G -71.6(11) . . . . ?
C00H C009 C00B C00C 58.0(12) . . . . ?
C00I C00J C00O C00D 58.7(12) . . . . ?
C00I C00J C00O C00R -53.4(12) . . . . ?
C00I C00J C00O C00T -177.6(12) . . . . ?
C00I C00Q C00R C00O 9.3(13) . . . . ?
C00J C00I C00N C00D 28.9(14) . . . . ?
C00J C00I C00N C00E -87.8(13) . . . . ?
C00J C00I C00N C00P 151.5(12) . . . . ?
C00J C00I C00Q C00R -43.0(12) . . . . ?
C00J C00O C00R C00Q 28.1(12) . . . . ?
C00K C00C C00G C00A 69.9(11) . . . . ?
C13 C013 C018 C00V -179(3) . . . . ?
C13 C013 C018 C00X -64(2) . . . . ?
C13 C013 C018 C011 51(3) . . . . ?
C13 C013 C019 C015 54(2) . . . . ?
C00M C00Y C012 C00Z 57(2) . . . . ?
C15 C015 C017 C13 160(3) . . . . ?
C15 C015 C019 C013 176(2) . . . . ?
C00N C00D C00O C00J -42.4(13) . . . . ?
C00N C00D C00O C00R 63.0(12) . . . . ?
C00N C00D C00O C00T -168.2(12) . . . . ?
C00N C00I C00J C00O -54.8(13) . . . . ?
C00N C00I C00Q C00R 65.2(13) . . . . ?
C00O C00D C00N C00E 124.3(12) . . . . ?
C00O C00D C00N C00I 8.3(13) . . . . ?
C00O C00D C00N C00P -112.6(13) . . . . ?
C00Q C00I C00J C00O 59.6(11) . . . . ?
C00Q C00I C00N C00D -76.6(12) . . . . ?
C00Q C00I C00N C00E 166.7(11) . . . . ?
C00Q C00I C00N C00P 46.0(14) . . . . ?
C00S C009 C00A C00G 157.9(10) . . . . ?
C00S C009 C00B C00C -179.2(13) . . . . ?
C00S C009 C00H S2 69.2(14) . . . . ?
C00S C009 C00H C00K -164.1(11) . . . . ?
C00T C00O C00R C00Q 154.9(10) . . . . ?
C00U C00Y C012 C00Z -178(2) . . . . ?
C00W C00Y C012 C00Z -55(2) . . . . ?
C00X C015 C017 C13 -67(3) . . . . ?
C00X C015 C019 C013 52(2) . . . . ?
C00Y C00M C016 C6 117(2) . . . . ?
C00Y C00M C016 C00Z 4.6(19) . . . . ?
C00Y C00M C016 C010 -120.4(19) . . . . ?
C00Y C00W C014 C00Z 7(2) . . . . ?
C012 C00Z C014 C00W -41.6(19) . . . . ?
C012 C00Z C016 C6 -83(2) . . . . ?
C012 C00Z C016 C00M 31(2) . . . . ?
C012 C00Z C016 C010 156.5(18) . . . . ?
C013 C13 C017 C015 -1(4) . . . . ?
C014 C00W C00Y C00M -75.3(15) . . . . ?
C014 C00W C00Y C00U 156.5(15) . . . . ?
C014 C00W C00Y C012 29.8(18) . . . . ?
C014 C00Z C012 C00Y 60(2) . . . . ?
C014 C00Z C016 C6 172(2) . . . . ?
C014 C00Z C016 C00M -74(2) . . . . ?
C014 C00Z C016 C010 51(2) . . . . ?
C015 C00X C018 C00V 118(2) . . . . ?
C015 C00X C018 C011 -113(2) . . . . ?
C015 C00X C018 C013 0(2) . . . . ?
C016 C00M C00Y C00U -166.3(18) . . . . ?
C016 C00M C00Y C00W 66.3(15) . . . . ?
C016 C00M C00Y C012 -38.9(17) . . . . ?
C016 C00Z C012 C00Y -55(2) . . . . ?
C016 C00Z C014 C00W 66(2) . . . . ?
C017 C13 C013 C018 70(3) . . . . ?
C017 C13 C013 C019 -34(3) . . . . ?
C017 C015 C019 C013 -58(2) . . . . ?
C018 C00X C015 C15 -156(2) . . . . ?
C018 C00X C015 C017 70(2) . . . . ?
C018 C00X C015 C019 -33(2) . . . . ?
C018 C013 C019 C015 -54(2) . . . . ?
C019 C013 C018 C00V -82(3) . . . . ?
C019 C013 C018 C00X 34(2) . . . . ?
C019 C013 C018 C011 149(2) . . . . ?
C019 C015 C017 C13 36(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
# Ag8-1 RESULTS (APPEND TO CIF)
_vrf_PLAT342_Ag8-1               
;
PROBLEM: ALERT: Low Bond Precision on  C-C Bonds
RESPONSE: Caused by the large number of C-C bonds in the structure.
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_r-ag8
_database_code_depnum_ccdc_archive 'CCDC 2511976'
loop_
_audit_author_name
_audit_author_address
'Jiankang Chen'
;Anhui University
China
;
_audit_update_record             
;
2025-12-17 deposited with the CCDC.	2025-12-22 downloaded from the CCDC.
;
_audit_creation_date             2025-12-15
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C40 H68 Ag4 S4)'
_chemical_formula_sum            'C80 H136 Ag8 S8'
_chemical_formula_weight         2217.32
_chemical_absolute_configuration rm
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           5
_space_group_name_H-M_alt        'I 1 2 1'
_space_group_name_Hall           'I 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'

_cell_length_a                   16.90380(10)
_cell_length_b                   12.78060(10)
_cell_length_c                   20.16090(10)
_cell_angle_alpha                90
_cell_angle_beta                 91.3310(10)
_cell_angle_gamma                90
_cell_volume                     4354.40(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    35589
_cell_measurement_temperature    120.0(4)
_cell_measurement_theta_max      76.6810
_cell_measurement_theta_min      3.3610
_shelx_estimated_absorpt_T_max   0.443
_shelx_estimated_absorpt_T_min   0.034
_exptl_absorpt_coefficient_mu    16.197
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.33168
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.143a (Rigaku Oxford Diffraction, 2024)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.691
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2240
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.65
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0408
_diffrn_reflns_av_unetI/netI     0.0285
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.977
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            42035
_diffrn_reflns_point_group_measured_fraction_full 0.958
_diffrn_reflns_point_group_measured_fraction_max 0.917
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.920
_diffrn_reflns_theta_min         3.452
_diffrn_ambient_temperature      120.15
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -106.00 -36.00   0.50    0.05    -- -103.74 125.00-150.00  140
  2  ω    -62.00 -37.00   0.50    0.05    -- -103.74  57.00-120.00   50
  3  ω    -62.00 -33.00   0.50    0.05    -- -103.74  57.00 120.00   58
  4  ω    -12.00  13.00   0.50    0.05    --  -48.32   9.00  38.00   50
  5  ω     29.00  65.00   0.50    0.05    --   48.32  77.00 150.00   72
  6  ω     30.00  58.00   0.50    0.05    --   48.32  77.00 120.00   56
  7  ω     38.00  64.00   0.50    0.05    --   48.32  57.00 120.00   52
  8  ω     41.00 115.00   0.50    0.05    --   48.32  38.00 150.00  148
  9  ω     28.00  75.00   0.50    0.05    --   48.32  77.00  90.00   94
 10  ω     39.00  89.00   0.50    0.05    --   48.32  57.00  60.00  100
 11  ω     44.00  72.00   0.50    0.05    --   48.32  38.00 120.00   56
 12  ω     47.00  94.00   0.50    0.05    --   48.32  19.00 120.00   94
 13  ω     62.00  88.00   0.50    0.05    --   48.32   9.00  38.00   52
 14  ω     28.00  78.00   0.50    0.05    --   48.32  77.00-150.00  100
 15  ω     31.00  98.00   0.50    0.05    --   48.32  77.00-180.00  134
 16  ω     83.00 110.00   0.50    0.05    --  103.74  77.00  60.00   54
 17  ω     83.00 109.00   0.50    0.05    --  103.74  77.00  90.00   52
 18  ω     83.00 109.00   0.50    0.05    --  103.74  77.00 120.00   52
 19  ω     92.00 119.00   0.50    0.05    --  103.74  57.00  60.00   54
 20  ω     83.00 110.00   0.50    0.05    --  103.74  77.00  30.00   54
 21  ω    136.00 161.00   0.50    0.05    --  103.74   9.00  38.00   50
 22  ω     91.00 117.00   0.50    0.05    --  103.74  57.00-150.00   52
 23  ω     83.00 110.00   0.50    0.05    --  103.74  77.00-150.00   54
 24  ω     83.00 109.00   0.50    0.05    --  103.74  77.00-180.00   52
 25  ω    -21.00  18.00   0.50    0.05    --   48.32  -9.00-135.00   78
 26  ω     35.00  69.00   0.50    0.05    --  103.74 -57.00-180.00   68
 27  ω     34.00 106.00   0.50    0.05    --  103.74 -99.00 120.00  144
 28  ω     77.00 103.00   0.50    0.05    --  103.74 -99.00 150.00   52
 29  ω     34.00  70.00   0.50    0.05    --  103.74 -99.00 150.00   72
 30  ω     19.00  91.00   0.50    0.05    --   48.32-125.00 150.00  144
 31  ω     45.00  70.00   0.50    0.05    --  103.74 -99.00 -60.00   50
 32  ω     35.00 105.00   0.50    0.05    --  103.74 -99.00-180.00  140
 33  ω    -86.00 -59.00   0.50    0.05    --  -48.32  -9.00-135.00   54
 34  ω   -109.00 -82.00   0.50    0.05    -- -103.74 -80.00-167.77   54
 35  ω   -108.00 -83.00   0.50    0.05    -- -103.74 -79.00-129.91   50
 36  ω   -173.00-130.00   0.50    0.05    -- -103.74 -79.00-129.91   86
 37  ω   -172.00-146.00   0.50    0.05    -- -103.74 -80.00-167.77   52
 38  ω   -107.00 -82.00   0.50    0.05    -- -103.74 -79.00  68.65   50
 39  ω   -107.00 -82.00   0.50    0.05    -- -103.74 -79.00 113.29   50
 40  ω   -108.00 -83.00   0.50    0.05    -- -103.74 -78.00 173.49   50
 41  ω   -107.00 -82.00   0.50    0.05    -- -103.74 -80.00 164.34   50
 42  ω   -108.00 -83.00   0.50    0.05    -- -103.74 -78.00 158.25   50
 43  ω   -108.00 -83.00   0.50    0.05    -- -103.74 -77.00  90.00   50
 44  ω   -109.00 -84.00   0.50    0.05    -- -103.74 -77.00 150.00   50
 45  ω   -174.00-116.00   0.50    0.05    -- -103.74 -77.00  90.00  116
 46  ω   -171.00-123.00   0.50    0.05    -- -103.74 -77.00-120.00   96
 47  ω   -109.00 -83.00   0.50    0.05    -- -103.74 -77.00-180.00   52
 48  ω   -110.00 -85.00   0.50    0.05    -- -103.74 -71.00-171.96   50
 49  ω   -108.00 -83.00   0.50    0.05    -- -103.74 -77.00-150.00   50
 50  ω   -109.00 -83.00   0.50    0.05    -- -103.74 -77.00-141.34   52
 51  ω   -111.00 -86.00   0.50    0.05    -- -103.74 -77.00-120.00   50
 52  ω   -112.00 -86.00   0.50    0.05    -- -103.74 -69.00 111.62   52
 53  ω   -112.00 -87.00   0.50    0.05    -- -103.74 -68.00 143.34   50
 54  ω   -112.00 -86.00   0.50    0.05    -- -103.74 -69.00 179.27   52
 55  ω   -114.00 -87.00   0.50    0.05    -- -103.74 -67.00 163.69   54
 56  ω   -147.00-122.00   0.50    0.05    -- -103.74 -69.00 179.27   50
 57  ω   -173.00-147.00   0.50    0.05    -- -103.74 -69.00 111.62   52
 58  ω   -113.00 -88.00   0.50    0.05    -- -103.74 -65.00  87.56   50
 59  ω   -115.00 -88.00   0.50    0.05    -- -103.74 -66.00  80.44   54
 60  ω   -115.00 -89.00   0.50    0.05    -- -103.74 -63.00  79.95   52
 61  ω   -113.00 -88.00   0.50    0.05    -- -103.74 -64.00  90.73   50
 62  ω   -119.00 -92.00   0.50    0.05    -- -103.74 -62.00 152.62   54
 63  ω   -114.00 -89.00   0.50    0.05    -- -103.74 -62.00 122.89   50
 64  ω   -116.00 -89.00   0.50    0.05    -- -103.74 -61.00 116.45   54
 65  ω   -116.00 -87.00   0.50    0.05    -- -103.74 -67.00-166.61   58
 66  ω   -116.00 -88.00   0.50    0.05    -- -103.74 -64.00-175.33   56
 67  ω   -122.00 -90.00   0.50    0.05    -- -103.74 -58.00-166.88   64
 68  ω   -118.00 -91.00   0.50    0.05    -- -103.74 -57.00-150.00   54
 69  ω   -168.00-119.00   0.50    0.05    -- -103.74 -64.00-175.33   98
 70  ω   -116.00 -91.00   0.50    0.05    -- -103.74 -58.00  96.59   50
 71  ω   -118.00 -93.00   0.50    0.05    -- -103.74 -56.00 105.30   50
 72  ω   -164.00 -95.00   0.50    0.05    -- -103.74 -48.00 114.56  138
 73  ω   -171.00 -95.00   0.50    0.05    -- -103.74 -48.00 146.83  152
 74  ω   -173.00 -94.00   0.50    0.05    -- -103.74 -49.00 160.16  158
 75  ω   -173.00 -94.00   0.50    0.05    -- -103.74 -47.00 132.82  158
 76  ω   -124.00 -94.00   0.50    0.05    -- -103.74 -47.00  55.51   60
 77  ω   -137.00 -96.00   0.50    0.05    -- -103.74  -9.00-135.00   82
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.794
_reflns_Friedel_fraction_full    0.912
_reflns_Friedel_fraction_max     0.851
_reflns_number_gt                8367
_reflns_number_total             8460
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.43.143a (Rigaku OD, 2024)'
_computing_data_collection       
'CrysAlisPro system (CCD 43.143a 64-bit (release 25-10-2024))'
_computing_data_reduction        'CrysAlisPro 1.171.43.143a (Rigaku OD, 2024)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2017/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.085
_refine_diff_density_min         -1.080
_refine_diff_density_rms         0.123
_refine_ls_abs_structure_details 
;
 Flack x determined using 3622 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.018(6)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     445
_refine_ls_number_reflns         8460
_refine_ls_number_restraints     121
_refine_ls_R_factor_all          0.0328
_refine_ls_R_factor_gt           0.0325
_refine_ls_restrained_S_all      1.096
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0543P)²+14.2184P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0880
_refine_ls_wR_factor_ref         0.0887
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(C00R) \\sim Ueq, Uanis(C00X) \\sim Ueq, Uanis(C010) \\sim Ueq,
Uanis(C011) \\sim Ueq, Uanis(C016) \\sim Ueq, Uanis(C018) \\sim Ueq,
Uanis(C019) \\sim Ueq, Uanis(C01B) \\sim Ueq, Uanis(C1) \\sim Ueq, Uanis(C2)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C01A) \\sim Ueq, Uanis(C00U) \\sim Ueq, Uanis(C012) \\sim Ueq,
Uanis(C00V) \\sim Ueq, Uanis(C00T) \\sim Ueq, Uanis(C00W) \\sim Ueq,
Uanis(C017) \\sim Ueq, Uanis(C00Y) \\sim Ueq, Uanis(C014) \\sim Ueq,
Uanis(C015) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
2.a Ternary CH refined with riding coordinates:
 C00B(H00C), C00G(H00K), C00M(H00Z), C00N(H00), C00R(H4), C00V(H7), C00Y(H8),
 C016(H016)
2.b Secondary CH2 refined with riding coordinates:
 C00A(H00A,H00B), C00C(H00D,H00E), C00D(H00F,H00G), C00L(H00X,H00Y), C00Q(H2,
 HB), C00Z(H3,HG), C014(H01D,H01E), C015(H01F,H01G), C017(H01H,H01I), C018(H01K,
 H01J), C019(H01L,H01M), C01B(H01Q,H01R)
2.c Idealised Me refined as rotating group:
 C00E(H00H,H00J,H00I), C00H(H00L,H00M,H00N), C00I(H00O,H00P,H00Q), C00J(H00T,
 H00R,H00S), C00K(H00U,H00V,H00W), C00P(H1,H,HA), C00T(H5,HC,HD), C00U(H6,HE,
 HF), C011(H01A,H01B,H01C), C01A(H01N,H01O,H01P), C1(H1A,H1B,H1C), C2(H2C,H2A,
 H2B)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag01 Ag 0.59730(2) 0.73152(4) 0.56391(2) 0.02137(11) Uani 1 1 d . . . . .
Ag02 Ag 0.57893(2) 0.73249(4) 0.42059(2) 0.02250(12) Uani 1 1 d . . . . .
Ag03 Ag 0.43479(3) 0.42729(5) 0.58701(3) 0.03495(14) Uani 1 1 d . . . . .
Ag04 Ag 0.39654(3) 0.39727(4) 0.44137(3) 0.03304(16) Uani 1 1 d . . . . .
S005 S 0.51849(9) 0.62419(13) 0.63198(7) 0.0204(3) Uani 1 1 d . . . . .
S006 S 0.65540(8) 0.84905(13) 0.48785(8) 0.0214(3) Uani 1 1 d . . . . .
S007 S 0.32438(11) 0.49153(15) 0.52188(10) 0.0310(4) Uani 1 1 d . . . . .
S008 S 0.46847(11) 0.32563(15) 0.35194(9) 0.0296(4) Uani 1 1 d . . . . .
C009 C 0.4654(4) 0.6472(6) 0.7643(3) 0.0242(14) Uani 1 1 d . . . . .
C00A C 0.5066(5) 0.6791(7) 0.8306(3) 0.0323(16) Uani 1 1 d . . . . .
H00A H 0.520507 0.754326 0.832277 0.039 Uiso 1 1 calc R U . . .
H00B H 0.475703 0.659599 0.869804 0.039 Uiso 1 1 calc R U . . .
C00B C 0.5789(4) 0.6084(6) 0.8212(3) 0.0259(14) Uani 1 1 d . . . . .
H00C H 0.618647 0.612502 0.858612 0.031 Uiso 1 1 calc R U . . .
C00C C 0.4627(4) 0.5275(6) 0.7724(3) 0.0257(14) Uani 1 1 d . . . . .
H00D H 0.463946 0.492278 0.728698 0.031 Uiso 1 1 calc R U . . .
H00E H 0.414466 0.505592 0.795539 0.031 Uiso 1 1 calc R U . . .
C00D C 0.8874(4) 0.8241(7) 0.4418(4) 0.0301(16) Uani 1 1 d . . . . .
H00F H 0.927563 0.852977 0.411894 0.036 Uiso 1 1 calc R U . . .
H00G H 0.892471 0.747083 0.444700 0.036 Uiso 1 1 calc R U . . .
C00E C 0.6601(4) 0.5611(7) 0.7195(3) 0.0286(15) Uani 1 1 d . . . . .
H00H H 0.705871 0.542453 0.747829 0.043 Uiso 1 1 calc R U . . .
H00J H 0.678353 0.587878 0.677011 0.043 Uiso 1 1 calc R U . . .
H00I H 0.627197 0.498902 0.711802 0.043 Uiso 1 1 calc R U . . .
C00F C 0.6116(4) 0.6450(6) 0.7537(3) 0.0226(13) Uani 1 1 d . . . . .
C00G C 0.8886(4) 0.8776(7) 0.5107(4) 0.0330(17) Uani 1 1 d . . . . .
H00K H 0.938916 0.867105 0.536899 0.040 Uiso 1 1 calc R U . . .
C00H C 0.8355(5) 0.7305(8) 0.5801(4) 0.0396(17) Uani 1 1 d . . . . .
H00L H 0.864516 0.684736 0.550234 0.059 Uiso 1 1 calc R U . . .
H00M H 0.787008 0.695257 0.593841 0.059 Uiso 1 1 calc R U . . .
H00N H 0.868646 0.746262 0.619362 0.059 Uiso 1 1 calc R U . . .
C00I C 0.7788(4) 0.9057(7) 0.5948(4) 0.0369(19) Uani 1 1 d . . . . .
H00O H 0.819599 0.925321 0.627782 0.055 Uiso 1 1 calc R U . . .
H00P H 0.735069 0.870788 0.616898 0.055 Uiso 1 1 calc R U . . .
H00Q H 0.759013 0.968712 0.572149 0.055 Uiso 1 1 calc R U . . .
C00J C 0.6638(5) 0.7426(7) 0.7627(4) 0.0386(18) Uani 1 1 d . . . . .
H00T H 0.635054 0.795759 0.787527 0.058 Uiso 1 1 calc R U . . .
H00R H 0.677089 0.770462 0.719048 0.058 Uiso 1 1 calc R U . . .
H00S H 0.712492 0.723747 0.787141 0.058 Uiso 1 1 calc R U . . .
C00K C 0.7706(5) 0.8291(8) 0.3550(3) 0.0365(18) Uani 1 1 d . . . . .
H00U H 0.806340 0.854795 0.321035 0.055 Uiso 1 1 calc R U . . .
H00V H 0.718007 0.859944 0.347738 0.055 Uiso 1 1 calc R U . . .
H00W H 0.766761 0.752734 0.352111 0.055 Uiso 1 1 calc R U . . .
C00L C 0.5386(4) 0.5015(6) 0.8148(3) 0.0295(15) Uani 1 1 d . . . . .
H00X H 0.525001 0.473274 0.858834 0.035 Uiso 1 1 calc R U . . .
H00Y H 0.572696 0.450659 0.791911 0.035 Uiso 1 1 calc R U . . .
C00M C 0.7592(3) 0.8085(6) 0.4815(3) 0.0209(13) Uani 1 1 d . . . . .
H00Z H 0.759686 0.731124 0.474094 0.025 Uiso 1 1 calc R U . . .
C00N C 0.5318(4) 0.6777(5) 0.7164(3) 0.0218(13) Uani 1 1 d . . . . .
H00 H 0.531699 0.755694 0.712632 0.026 Uiso 1 1 calc R U . . .
C00O C 0.8140(4) 0.8319(6) 0.5443(3) 0.0258(14) Uani 1 1 d . . . . .
C00P C 0.3863(4) 0.6956(7) 0.7476(4) 0.0368(18) Uani 1 1 d . . . . .
H1 H 0.348967 0.678877 0.782504 0.055 Uiso 1 1 calc R U . . .
H H 0.366342 0.667702 0.705135 0.055 Uiso 1 1 calc R U . . .
HA H 0.392149 0.771671 0.744225 0.055 Uiso 1 1 calc R U . . .
C00Q C 0.8742(5) 0.9908(7) 0.4889(4) 0.0381(18) Uani 1 1 d . . . . .
H2 H 0.922455 1.021846 0.470170 0.046 Uiso 1 1 calc R U . . .
HB H 0.856709 1.034463 0.526343 0.046 Uiso 1 1 calc R U . . .
C00R C 0.4971(5) 0.1891(7) 0.3668(4) 0.0374(18) Uani 1 1 d . U . A 1
H4 H 0.530585 0.190083 0.408399 0.045 Uiso 1 1 calc R U . A 1
C00S C 0.8026(4) 0.8599(6) 0.4232(3) 0.0254(14) Uani 1 1 d . . . . .
C00T C 0.2564(7) 0.4372(12) 0.6732(5) 0.065(3) Uani 1 1 d . U . . .
H5 H 0.281577 0.368960 0.680510 0.098 Uiso 1 1 calc R U . . .
HC H 0.223683 0.454415 0.711183 0.098 Uiso 1 1 calc R U . . .
HD H 0.297306 0.490864 0.668360 0.098 Uiso 1 1 calc R U . . .
C00U C 0.1752(8) 0.4374(11) 0.4358(5) 0.065(3) Uani 1 1 d . U . . .
H6 H 0.219953 0.417560 0.408340 0.098 Uiso 1 1 calc R U . . .
HE H 0.179046 0.511877 0.446917 0.098 Uiso 1 1 calc R U . . .
HF H 0.125553 0.424272 0.411146 0.098 Uiso 1 1 calc R U . . .
C00V C 0.2484(5) 0.3978(7) 0.5488(4) 0.0334(17) Uani 1 1 d . U . . .
H7 H 0.275622 0.330099 0.559202 0.040 Uiso 1 1 calc R U . . .
C00W C 0.2057(5) 0.4333(8) 0.6117(4) 0.0407(19) Uani 1 1 d . U . . .
C00X C 0.5504(7) 0.1410(8) 0.3126(6) 0.056(3) Uani 1 1 d . U . A 1
C00Y C 0.1056(6) 0.3874(11) 0.5430(7) 0.065(3) Uani 1 1 d . U . . .
H8 H 0.057933 0.346737 0.527849 0.078 Uiso 1 1 calc R U . . .
C00Z C 0.8075(5) 0.9797(7) 0.4349(4) 0.0347(17) Uani 1 1 d . . . . .
H3 H 0.756674 1.007464 0.450911 0.042 Uiso 1 1 calc R U . . .
HG H 0.821427 1.016904 0.393735 0.042 Uiso 1 1 calc R U . . .
C010 C 0.4307(6) 0.1120(8) 0.3800(6) 0.054(2) Uani 1 1 d . U . A 1
C011 C 0.6318(8) 0.1216(14) 0.3416(11) 0.104(6) Uani 1 1 d . U . A 1
H01A H 0.656182 0.188504 0.354206 0.156 Uiso 1 1 calc R U . A 1
H01B H 0.664259 0.086732 0.308618 0.156 Uiso 1 1 calc R U . A 1
H01C H 0.627888 0.077029 0.380941 0.156 Uiso 1 1 calc R U . A 1
C012 C 0.1770(6) 0.3733(9) 0.4988(5) 0.051(2) Uani 1 1 d . U . . .
C014 C 0.0892(6) 0.5039(11) 0.5544(6) 0.062(3) Uani 1 1 d . U . . .
H01D H 0.039105 0.514356 0.578082 0.074 Uiso 1 1 calc R U . . .
H01E H 0.086714 0.542923 0.512019 0.074 Uiso 1 1 calc R U . . .
C015 C 0.1609(5) 0.5375(8) 0.5974(5) 0.050(2) Uani 1 1 d . U . . .
H01F H 0.143858 0.570539 0.639099 0.060 Uiso 1 1 calc R U . . .
H01G H 0.194546 0.587271 0.573205 0.060 Uiso 1 1 calc R U . . .
C016 C 0.5075(10) 0.0351(10) 0.3002(7) 0.077(4) Uani 1 1 d . U . A 1
H016 H 0.540189 -0.020594 0.279380 0.093 Uiso 1 1 calc R U . A 1
C017 C 0.1365(6) 0.3568(10) 0.6109(6) 0.062(3) Uani 1 1 d . U . . .
H01H H 0.153872 0.282860 0.613125 0.075 Uiso 1 1 calc R U . . .
H01I H 0.098310 0.371398 0.646171 0.075 Uiso 1 1 calc R U . . .
C018 C 0.3753(10) 0.1122(12) 0.3205(8) 0.087(4) Uani 1 1 d . U . A 1
H01K H 0.362562 0.184619 0.306364 0.105 Uiso 1 1 calc R U . A 1
H01J H 0.325542 0.074980 0.330106 0.105 Uiso 1 1 calc R U . A 1
C019 C 0.4763(8) 0.0085(9) 0.3703(7) 0.067(3) Uani 1 1 d . U . A 1
H01L H 0.441107 -0.053332 0.369825 0.081 Uiso 1 1 calc R U . A 1
H01M H 0.519650 -0.001029 0.403615 0.081 Uiso 1 1 calc R U . A 1
C01A C 0.1825(10) 0.2574(11) 0.4793(9) 0.093(5) Uani 1 1 d . U . . .
H01N H 0.135922 0.237962 0.452258 0.140 Uiso 1 1 calc R U . . .
H01O H 0.184800 0.214205 0.519508 0.140 Uiso 1 1 calc R U . . .
H01P H 0.230428 0.245919 0.453810 0.140 Uiso 1 1 calc R U . . .
C01B C 0.4225(13) 0.0538(17) 0.2663(9) 0.115(6) Uani 1 1 d . U . A 1
H01Q H 0.426562 0.097071 0.225806 0.139 Uiso 1 1 calc R U . A 1
H01R H 0.396867 -0.013503 0.254497 0.139 Uiso 1 1 calc R U . A 1
C1 C 0.3911(10) 0.1275(13) 0.4482(8) 0.088(5) Uani 1 1 d . U . A 1
H1A H 0.431355 0.121885 0.483851 0.133 Uiso 1 1 calc R U . A 1
H1B H 0.350699 0.073582 0.454129 0.133 Uiso 1 1 calc R U . A 1
H1C H 0.366457 0.196821 0.449649 0.133 Uiso 1 1 calc R U . A 1
C2 C 0.5497(13) 0.2071(11) 0.2470(7) 0.106(6) Uani 1 1 d . U . . .
H2C H 0.495476 0.211941 0.229046 0.159 Uiso 1 1 calc R U . A 1
H2A H 0.583383 0.173181 0.214401 0.159 Uiso 1 1 calc R U . A 1
H2B H 0.569920 0.277565 0.256504 0.159 Uiso 1 1 calc R U . A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag01 Ag02 2.8991(6) . ?
Ag01 Ag02 3.0026(5) 2_656 ?
Ag01 S005 2.3716(16) . ?
Ag01 S006 2.3753(16) . ?
Ag02 S005 2.3812(16) 2_656 ?
Ag02 S006 2.3764(16) . ?
Ag03 Ag04 2.9461(8) 2_656 ?
Ag03 Ag04 3.0163(8) . ?
Ag03 S007 2.402(2) . ?
Ag03 S008 2.405(2) 2_656 ?
Ag04 S007 2.3802(18) . ?
Ag04 S008 2.3810(18) . ?
S005 C00N 1.844(7) . ?
S006 C00M 1.837(6) . ?
S007 C00V 1.847(8) . ?
S008 C00R 1.834(8) . ?
C009 C00A 1.547(9) . ?
C009 C00C 1.539(11) . ?
C009 C00N 1.548(9) . ?
C009 C00P 1.504(10) . ?
C00A H00A 0.9900 . ?
C00A H00B 0.9900 . ?
C00A C00B 1.534(10) . ?
C00B H00C 1.0000 . ?
C00B C00F 1.552(10) . ?
C00B C00L 1.530(11) . ?
C00C H00D 0.9900 . ?
C00C H00E 0.9900 . ?
C00C C00L 1.561(10) . ?
C00D H00F 0.9900 . ?
C00D H00G 0.9900 . ?
C00D C00G 1.548(10) . ?
C00D C00S 1.543(10) . ?
C00E H00H 0.9800 . ?
C00E H00J 0.9800 . ?
C00E H00I 0.9800 . ?
C00E C00F 1.524(10) . ?
C00F C00J 1.536(10) . ?
C00F C00N 1.585(8) . ?
C00G H00K 1.0000 . ?
C00G C00O 1.559(9) . ?
C00G C00Q 1.530(13) . ?
C00H H00L 0.9800 . ?
C00H H00M 0.9800 . ?
C00H H00N 0.9800 . ?
C00H C00O 1.524(12) . ?
C00I H00O 0.9800 . ?
C00I H00P 0.9800 . ?
C00I H00Q 0.9800 . ?
C00I C00O 1.519(10) . ?
C00J H00T 0.9800 . ?
C00J H00R 0.9800 . ?
C00J H00S 0.9800 . ?
C00K H00U 0.9800 . ?
C00K H00V 0.9800 . ?
C00K H00W 0.9800 . ?
C00K C00S 1.519(10) . ?
C00L H00X 0.9900 . ?
C00L H00Y 0.9900 . ?
C00M H00Z 1.0000 . ?
C00M C00O 1.579(8) . ?
C00M C00S 1.546(9) . ?
C00N H00 1.0000 . ?
C00P H1 0.9800 . ?
C00P H 0.9800 . ?
C00P HA 0.9800 . ?
C00Q H2 0.9900 . ?
C00Q HB 0.9900 . ?
C00Q C00Z 1.555(11) . ?
C00R H4 1.0000 . ?
C00R C00X 1.559(13) . ?
C00R C010 1.521(13) . ?
C00S C00Z 1.550(12) . ?
C00T H5 0.9800 . ?
C00T HC 0.9800 . ?
C00T HD 0.9800 . ?
C00T C00W 1.492(14) . ?
C00U H6 0.9800 . ?
C00U HE 0.9800 . ?
C00U HF 0.9800 . ?
C00U C012 1.511(16) . ?
C00V H7 1.0000 . ?
C00V C00W 1.542(12) . ?
C00V C012 1.585(11) . ?
C00W C015 1.556(15) . ?
C00W C017 1.524(13) . ?
C00X C011 1.502(19) . ?
C00X C016 1.553(18) . ?
C00X C2 1.570(18) . ?
C00Y H8 1.0000 . ?
C00Y C012 1.528(17) . ?
C00Y C014 1.533(19) . ?
C00Y C017 1.506(16) . ?
C00Z H3 0.9900 . ?
C00Z HG 0.9900 . ?
C010 C018 1.505(19) . ?
C010 C019 1.545(16) . ?
C010 C1 1.556(18) . ?
C011 H01A 0.9800 . ?
C011 H01B 0.9800 . ?
C011 H01C 0.9800 . ?
C012 C01A 1.537(17) . ?
C014 H01D 0.9900 . ?
C014 H01E 0.9900 . ?
C014 C015 1.534(15) . ?
C015 H01F 0.9900 . ?
C015 H01G 0.9900 . ?
C016 H016 1.0000 . ?
C016 C019 1.556(19) . ?
C016 C01B 1.60(3) . ?
C017 H01H 0.9900 . ?
C017 H01I 0.9900 . ?
C018 H01K 0.9900 . ?
C018 H01J 0.9900 . ?
C018 C01B 1.56(2) . ?
C019 H01L 0.9900 . ?
C019 H01M 0.9900 . ?
C01A H01N 0.9800 . ?
C01A H01O 0.9800 . ?
C01A H01P 0.9800 . ?
C01B H01Q 0.9900 . ?
C01B H01R 0.9900 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag02 Ag01 Ag02 91.160(15) . 2_656 ?
S005 Ag01 Ag02 50.96(4) . 2_656 ?
S005 Ag01 Ag02 122.05(4) . . ?
S005 Ag01 S006 170.25(6) . . ?
S006 Ag01 Ag02 119.39(4) . 2_656 ?
S006 Ag01 Ag02 52.42(4) . . ?
Ag01 Ag02 Ag01 88.839(15) . 2_656 ?
S005 Ag02 Ag01 50.68(4) 2_656 2_656 ?
S005 Ag02 Ag01 119.87(4) 2_656 . ?
S006 Ag02 Ag01 118.10(4) . 2_656 ?
S006 Ag02 Ag01 52.39(4) . . ?
S006 Ag02 S005 168.44(5) . 2_656 ?
Ag04 Ag03 Ag04 88.91(2) 2_656 . ?
S007 Ag03 Ag04 132.97(5) . 2_656 ?
S007 Ag03 Ag04 50.58(5) . . ?
S007 Ag03 S008 167.18(7) . 2_656 ?
S008 Ag03 Ag04 51.64(4) 2_656 2_656 ?
S008 Ag03 Ag04 123.87(5) 2_656 . ?
Ag03 Ag04 Ag03 89.20(2) 2_656 . ?
S007 Ag04 Ag03 51.21(5) . . ?
S007 Ag04 Ag03 125.46(5) . 2_656 ?
S007 Ag04 S008 171.80(7) . . ?
S008 Ag04 Ag03 52.37(5) . 2_656 ?
S008 Ag04 Ag03 133.18(5) . . ?
Ag01 S005 Ag02 78.36(5) . 2_656 ?
C00N S005 Ag01 105.2(2) . . ?
C00N S005 Ag02 105.3(2) . 2_656 ?
Ag01 S006 Ag02 75.19(5) . . ?
C00M S006 Ag01 106.0(2) . . ?
C00M S006 Ag02 106.9(2) . . ?
Ag04 S007 Ag03 78.22(6) . . ?
C00V S007 Ag03 98.9(3) . . ?
C00V S007 Ag04 104.0(3) . . ?
Ag04 S008 Ag03 75.99(6) . 2_656 ?
C00R S008 Ag03 104.9(3) . 2_656 ?
C00R S008 Ag04 112.3(3) . . ?
C00A C009 C00N 98.8(5) . . ?
C00C C009 C00A 100.6(6) . . ?
C00C C009 C00N 109.8(6) . . ?
C00P C009 C00A 117.8(6) . . ?
C00P C009 C00C 113.9(7) . . ?
C00P C009 C00N 114.2(6) . . ?
C009 C00A H00A 112.8 . . ?
C009 C00A H00B 112.8 . . ?
H00A C00A H00B 110.2 . . ?
C00B C00A C009 94.7(5) . . ?
C00B C00A H00A 112.8 . . ?
C00B C00A H00B 112.8 . . ?
C00A C00B H00C 113.5 . . ?
C00A C00B C00F 103.4(5) . . ?
C00F C00B H00C 113.5 . . ?
C00L C00B C00A 100.5(6) . . ?
C00L C00B H00C 113.5 . . ?
C00L C00B C00F 111.2(5) . . ?
C009 C00C H00D 110.9 . . ?
C009 C00C H00E 110.9 . . ?
C009 C00C C00L 104.1(6) . . ?
H00D C00C H00E 109.0 . . ?
C00L C00C H00D 110.9 . . ?
C00L C00C H00E 110.9 . . ?
H00F C00D H00G 110.3 . . ?
C00G C00D H00F 112.8 . . ?
C00G C00D H00G 112.8 . . ?
C00S C00D H00F 112.8 . . ?
C00S C00D H00G 112.8 . . ?
C00S C00D C00G 94.5(6) . . ?
H00H C00E H00J 109.5 . . ?
H00H C00E H00I 109.5 . . ?
H00J C00E H00I 109.5 . . ?
C00F C00E H00H 109.5 . . ?
C00F C00E H00J 109.5 . . ?
C00F C00E H00I 109.5 . . ?
C00B C00F C00N 100.3(5) . . ?
C00E C00F C00B 113.0(6) . . ?
C00E C00F C00J 108.1(6) . . ?
C00E C00F C00N 115.6(5) . . ?
C00J C00F C00B 110.9(6) . . ?
C00J C00F C00N 108.8(6) . . ?
C00D C00G H00K 114.0 . . ?
C00D C00G C00O 103.3(6) . . ?
C00O C00G H00K 114.0 . . ?
C00Q C00G C00D 99.2(6) . . ?
C00Q C00G H00K 114.0 . . ?
C00Q C00G C00O 110.8(7) . . ?
H00L C00H H00M 109.5 . . ?
H00L C00H H00N 109.5 . . ?
H00M C00H H00N 109.5 . . ?
C00O C00H H00L 109.5 . . ?
C00O C00H H00M 109.5 . . ?
C00O C00H H00N 109.5 . . ?
H00O C00I H00P 109.5 . . ?
H00O C00I H00Q 109.5 . . ?
H00P C00I H00Q 109.5 . . ?
C00O C00I H00O 109.5 . . ?
C00O C00I H00P 109.5 . . ?
C00O C00I H00Q 109.5 . . ?
C00F C00J H00T 109.5 . . ?
C00F C00J H00R 109.5 . . ?
C00F C00J H00S 109.5 . . ?
H00T C00J H00R 109.5 . . ?
H00T C00J H00S 109.5 . . ?
H00R C00J H00S 109.5 . . ?
H00U C00K H00V 109.5 . . ?
H00U C00K H00W 109.5 . . ?
H00V C00K H00W 109.5 . . ?
C00S C00K H00U 109.5 . . ?
C00S C00K H00V 109.5 . . ?
C00S C00K H00W 109.5 . . ?
C00B C00L C00C 102.4(6) . . ?
C00B C00L H00X 111.3 . . ?
C00B C00L H00Y 111.3 . . ?
C00C C00L H00X 111.3 . . ?
C00C C00L H00Y 111.3 . . ?
H00X C00L H00Y 109.2 . . ?
S006 C00M H00Z 107.5 . . ?
C00O C00M S006 115.7(4) . . ?
C00O C00M H00Z 107.5 . . ?
C00S C00M S006 113.8(5) . . ?
C00S C00M H00Z 107.5 . . ?
C00S C00M C00O 104.4(5) . . ?
S005 C00N H00 107.4 . . ?
C009 C00N S005 114.1(5) . . ?
C009 C00N C00F 105.0(5) . . ?
C009 C00N H00 107.4 . . ?
C00F C00N S005 115.1(5) . . ?
C00F C00N H00 107.4 . . ?
C00G C00O C00M 100.9(5) . . ?
C00H C00O C00G 109.8(6) . . ?
C00H C00O C00M 110.3(6) . . ?
C00I C00O C00G 113.0(6) . . ?
C00I C00O C00H 107.7(6) . . ?
C00I C00O C00M 115.0(6) . . ?
C009 C00P H1 109.5 . . ?
C009 C00P H 109.5 . . ?
C009 C00P HA 109.5 . . ?
H1 C00P H 109.5 . . ?
H1 C00P HA 109.5 . . ?
H C00P HA 109.5 . . ?
C00G C00Q H2 111.2 . . ?
C00G C00Q HB 111.2 . . ?
C00G C00Q C00Z 102.9(6) . . ?
H2 C00Q HB 109.1 . . ?
C00Z C00Q H2 111.2 . . ?
C00Z C00Q HB 111.2 . . ?
S008 C00R H4 105.5 . . ?
C00X C00R S008 114.5(6) . . ?
C00X C00R H4 105.5 . . ?
C010 C00R S008 116.9(6) . . ?
C010 C00R H4 105.5 . . ?
C010 C00R C00X 107.9(8) . . ?
C00D C00S C00M 98.3(6) . . ?
C00D C00S C00Z 102.1(6) . . ?
C00K C00S C00D 116.9(6) . . ?
C00K C00S C00M 114.4(6) . . ?
C00K C00S C00Z 114.2(7) . . ?
C00M C00S C00Z 109.2(6) . . ?
H5 C00T HC 109.5 . . ?
H5 C00T HD 109.5 . . ?
HC C00T HD 109.5 . . ?
C00W C00T H5 109.5 . . ?
C00W C00T HC 109.5 . . ?
C00W C00T HD 109.5 . . ?
H6 C00U HE 109.5 . . ?
H6 C00U HF 109.5 . . ?
HE C00U HF 109.5 . . ?
C012 C00U H6 109.5 . . ?
C012 C00U HE 109.5 . . ?
C012 C00U HF 109.5 . . ?
S007 C00V H7 107.6 . . ?
C00W C00V S007 113.1(6) . . ?
C00W C00V H7 107.6 . . ?
C00W C00V C012 102.6(7) . . ?
C012 C00V S007 117.7(6) . . ?
C012 C00V H7 107.6 . . ?
C00T C00W C00V 115.1(8) . . ?
C00T C00W C015 113.1(10) . . ?
C00T C00W C017 117.1(9) . . ?
C00V C00W C015 109.5(7) . . ?
C017 C00W C00V 100.2(8) . . ?
C017 C00W C015 100.1(8) . . ?
C00R C00X C2 112.7(8) . . ?
C011 C00X C00R 109.3(11) . . ?
C011 C00X C016 109.8(11) . . ?
C011 C00X C2 114.0(13) . . ?
C016 C00X C00R 100.4(9) . . ?
C016 C00X C2 109.8(12) . . ?
C012 C00Y H8 113.8 . . ?
C012 C00Y C014 110.5(9) . . ?
C014 C00Y H8 113.8 . . ?
C017 C00Y H8 113.8 . . ?
C017 C00Y C012 103.7(9) . . ?
C017 C00Y C014 100.1(11) . . ?
C00Q C00Z H3 111.1 . . ?
C00Q C00Z HG 111.1 . . ?
C00S C00Z C00Q 103.4(7) . . ?
C00S C00Z H3 111.1 . . ?
C00S C00Z HG 111.1 . . ?
H3 C00Z HG 109.1 . . ?
C00R C010 C019 99.2(8) . . ?
C00R C010 C1 113.9(10) . . ?
C018 C010 C00R 107.9(10) . . ?
C018 C010 C019 101.7(11) . . ?
C018 C010 C1 115.6(12) . . ?
C019 C010 C1 116.6(10) . . ?
C00X C011 H01A 109.5 . . ?
C00X C011 H01B 109.5 . . ?
C00X C011 H01C 109.5 . . ?
H01A C011 H01B 109.5 . . ?
H01A C011 H01C 109.5 . . ?
H01B C011 H01C 109.5 . . ?
C00U C012 C00V 115.3(8) . . ?
C00U C012 C00Y 115.2(10) . . ?
C00U C012 C01A 108.0(11) . . ?
C00Y C012 C00V 101.9(8) . . ?
C00Y C012 C01A 108.4(11) . . ?
C01A C012 C00V 107.6(9) . . ?
C00Y C014 H01D 111.3 . . ?
C00Y C014 H01E 111.3 . . ?
C00Y C014 C015 102.3(9) . . ?
H01D C014 H01E 109.2 . . ?
C015 C014 H01D 111.3 . . ?
C015 C014 H01E 111.3 . . ?
C00W C015 H01F 111.0 . . ?
C00W C015 H01G 111.0 . . ?
C014 C015 C00W 103.9(9) . . ?
C014 C015 H01F 111.0 . . ?
C014 C015 H01G 111.0 . . ?
H01F C015 H01G 109.0 . . ?
C00X C016 H016 115.3 . . ?
C00X C016 C019 102.2(10) . . ?
C00X C016 C01B 110.6(12) . . ?
C019 C016 H016 115.3 . . ?
C019 C016 C01B 95.8(13) . . ?
C01B C016 H016 115.3 . . ?
C00W C017 H01H 112.7 . . ?
C00W C017 H01I 112.7 . . ?
C00Y C017 C00W 95.4(8) . . ?
C00Y C017 H01H 112.7 . . ?
C00Y C017 H01I 112.7 . . ?
H01H C017 H01I 110.2 . . ?
C010 C018 H01K 111.0 . . ?
C010 C018 H01J 111.0 . . ?
C010 C018 C01B 103.8(13) . . ?
H01K C018 H01J 109.0 . . ?
C01B C018 H01K 111.0 . . ?
C01B C018 H01J 111.0 . . ?
C010 C019 C016 96.3(9) . . ?
C010 C019 H01L 112.5 . . ?
C010 C019 H01M 112.5 . . ?
C016 C019 H01L 112.5 . . ?
C016 C019 H01M 112.5 . . ?
H01L C019 H01M 110.0 . . ?
C012 C01A H01N 109.5 . . ?
C012 C01A H01O 109.5 . . ?
C012 C01A H01P 109.5 . . ?
H01N C01A H01O 109.5 . . ?
H01N C01A H01P 109.5 . . ?
H01O C01A H01P 109.5 . . ?
C016 C01B H01Q 111.0 . . ?
C016 C01B H01R 111.0 . . ?
C018 C01B C016 104.0(12) . . ?
C018 C01B H01Q 111.0 . . ?
C018 C01B H01R 111.0 . . ?
H01Q C01B H01R 109.0 . . ?
C010 C1 H1A 109.5 . . ?
C010 C1 H1B 109.5 . . ?
C010 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C00X C2 H2C 109.5 . . ?
C00X C2 H2A 109.5 . . ?
C00X C2 H2B 109.5 . . ?
H2C C2 H2A 109.5 . . ?
H2C C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag01 S005 C00N C009 159.5(4) . . . . ?
Ag01 S005 C00N C00F -79.0(5) . . . . ?
Ag01 S006 C00M C00O -71.6(5) . . . . ?
Ag01 S006 C00M C00S 167.5(4) . . . . ?
Ag02 S005 C00N C009 77.7(5) 2_656 . . . ?
Ag02 S005 C00N C00F -160.8(4) 2_656 . . . ?
Ag02 S006 C00M C00O -150.6(4) . . . . ?
Ag02 S006 C00M C00S 88.5(5) . . . . ?
Ag03 S007 C00V C00W 87.6(6) . . . . ?
Ag03 S007 C00V C012 -152.9(7) . . . . ?
Ag03 S008 C00R C00X -94.4(8) 2_656 . . . ?
Ag03 S008 C00R C010 138.0(7) 2_656 . . . ?
Ag04 S007 C00V C00W 167.6(5) . . . . ?
Ag04 S007 C00V C012 -72.9(7) . . . . ?
Ag04 S008 C00R C00X -175.1(7) . . . . ?
Ag04 S008 C00R C010 57.3(8) . . . . ?
S006 C00M C00O C00G -135.1(5) . . . . ?
S006 C00M C00O C00H 108.9(6) . . . . ?
S006 C00M C00O C00I -13.1(8) . . . . ?
S006 C00M C00S C00D 170.3(5) . . . . ?
S006 C00M C00S C00K -65.1(8) . . . . ?
S006 C00M C00S C00Z 64.3(6) . . . . ?
S007 C00V C00W C00T -66.4(11) . . . . ?
S007 C00V C00W C015 62.4(8) . . . . ?
S007 C00V C00W C017 167.1(6) . . . . ?
S007 C00V C012 C00U -5.0(13) . . . . ?
S007 C00V C012 C00Y -130.6(8) . . . . ?
S007 C00V C012 C01A 115.5(11) . . . . ?
S008 C00R C00X C011 111.8(11) . . . . ?
S008 C00R C00X C016 -132.7(8) . . . . ?
S008 C00R C00X C2 -16.0(14) . . . . ?
S008 C00R C010 C018 59.7(12) . . . . ?
S008 C00R C010 C019 165.3(8) . . . . ?
S008 C00R C010 C1 -70.1(12) . . . . ?
C009 C00A C00B C00F 56.6(7) . . . . ?
C009 C00A C00B C00L -58.4(6) . . . . ?
C009 C00C C00L C00B -4.4(7) . . . . ?
C00A C009 C00C C00L -31.8(6) . . . . ?
C00A C009 C00N S005 166.0(5) . . . . ?
C00A C009 C00N C00F 39.0(7) . . . . ?
C00A C00B C00F C00E -155.9(6) . . . . ?
C00A C00B C00F C00J 82.5(7) . . . . ?
C00A C00B C00F C00N -32.3(7) . . . . ?
C00A C00B C00L C00C 39.3(6) . . . . ?
C00B C00F C00N S005 -130.9(5) . . . . ?
C00B C00F C00N C009 -4.6(7) . . . . ?
C00C C009 C00A C00B 55.0(6) . . . . ?
C00C C009 C00N S005 61.2(6) . . . . ?
C00C C009 C00N C00F -65.7(7) . . . . ?
C00D C00G C00O C00H 88.1(7) . . . . ?
C00D C00G C00O C00I -151.7(7) . . . . ?
C00D C00G C00O C00M -28.3(8) . . . . ?
C00D C00G C00Q C00Z 43.5(7) . . . . ?
C00D C00S C00Z C00Q -27.2(7) . . . . ?
C00E C00F C00N S005 -9.1(8) . . . . ?
C00E C00F C00N C009 117.2(7) . . . . ?
C00F C00B C00L C00C -69.6(7) . . . . ?
C00G C00D C00S C00K 178.3(7) . . . . ?
C00G C00D C00S C00M -59.0(6) . . . . ?
C00G C00D C00S C00Z 52.9(7) . . . . ?
C00G C00Q C00Z C00S -10.1(7) . . . . ?
C00J C00F C00N S005 112.7(6) . . . . ?
C00J C00F C00N C009 -121.0(6) . . . . ?
C00K C00S C00Z C00Q -154.3(6) . . . . ?
C00L C00B C00F C00E -48.8(7) . . . . ?
C00L C00B C00F C00J -170.4(6) . . . . ?
C00L C00B C00F C00N 74.8(6) . . . . ?
C00M C00S C00Z C00Q 76.2(7) . . . . ?
C00N C009 C00A C00B -57.3(6) . . . . ?
C00N C009 C00C C00L 71.8(6) . . . . ?
C00O C00G C00Q C00Z -64.6(7) . . . . ?
C00O C00M C00S C00D 43.2(7) . . . . ?
C00O C00M C00S C00K 167.8(6) . . . . ?
C00O C00M C00S C00Z -62.8(7) . . . . ?
C00P C009 C00A C00B 179.3(7) . . . . ?
C00P C009 C00C C00L -158.8(6) . . . . ?
C00P C009 C00N S005 -68.0(8) . . . . ?
C00P C009 C00N C00F 165.0(6) . . . . ?
C00Q C00G C00O C00H -166.5(6) . . . . ?
C00Q C00G C00O C00I -46.2(8) . . . . ?
C00Q C00G C00O C00M 77.1(7) . . . . ?
C00R C00X C016 C019 -33.5(12) . . . . ?
C00R C00X C016 C01B 67.5(14) . . . . ?
C00R C010 C018 C01B 72.6(13) . . . . ?
C00R C010 C019 C016 -53.5(11) . . . . ?
C00S C00D C00G C00O 54.9(7) . . . . ?
C00S C00D C00G C00Q -59.2(6) . . . . ?
C00S C00M C00O C00G -9.2(7) . . . . ?
C00S C00M C00O C00H -125.2(6) . . . . ?
C00S C00M C00O C00I 112.8(7) . . . . ?
C00T C00W C015 C014 -155.9(8) . . . . ?
C00T C00W C017 C00Y 177.5(11) . . . . ?
C00V C00W C015 C014 74.2(9) . . . . ?
C00V C00W C017 C00Y -57.3(10) . . . . ?
C00W C00V C012 C00U 119.8(10) . . . . ?
C00W C00V C012 C00Y -5.7(10) . . . . ?
C00W C00V C012 C01A -119.6(11) . . . . ?
C00X C00R C010 C018 -71.1(12) . . . . ?
C00X C00R C010 C019 34.5(11) . . . . ?
C00X C00R C010 C1 159.1(11) . . . . ?
C00X C016 C019 C010 55.1(12) . . . . ?
C00X C016 C01B C018 -65.9(16) . . . . ?
C00Y C014 C015 C00W -5.7(10) . . . . ?
C010 C00R C00X C011 -116.1(11) . . . . ?
C010 C00R C00X C016 -0.7(11) . . . . ?
C010 C00R C00X C2 116.1(12) . . . . ?
C010 C018 C01B C016 -5.6(16) . . . . ?
C011 C00X C016 C019 81.6(14) . . . . ?
C011 C00X C016 C01B -177.4(14) . . . . ?
C012 C00V C00W C00T 165.8(10) . . . . ?
C012 C00V C00W C015 -65.4(8) . . . . ?
C012 C00V C00W C017 39.2(9) . . . . ?
C012 C00Y C014 C015 -68.4(11) . . . . ?
C012 C00Y C017 C00W 54.8(11) . . . . ?
C014 C00Y C012 C00U -49.6(12) . . . . ?
C014 C00Y C012 C00V 76.0(10) . . . . ?
C014 C00Y C012 C01A -170.7(10) . . . . ?
C014 C00Y C017 C00W -59.4(10) . . . . ?
C015 C00W C017 C00Y 54.8(10) . . . . ?
C017 C00W C015 C014 -30.5(10) . . . . ?
C017 C00Y C012 C00U -156.1(9) . . . . ?
C017 C00Y C012 C00V -30.5(11) . . . . ?
C017 C00Y C012 C01A 82.8(11) . . . . ?
C017 C00Y C014 C015 40.5(10) . . . . ?
C018 C010 C019 C016 57.1(12) . . . . ?
C019 C010 C018 C01B -31.2(13) . . . . ?
C019 C016 C01B C018 39.4(14) . . . . ?
C01B C016 C019 C010 -57.5(12) . . . . ?
C1 C010 C018 C01B -158.6(13) . . . . ?
C1 C010 C019 C016 -176.2(11) . . . . ?
C2 C00X C016 C019 -152.4(11) . . . . ?
C2 C00X C016 C01B -51.4(15) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
