# Supplementary Information (SI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2512227'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H19 Ag N4 O9'
_chemical_formula_weight         663.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.4392(8)
_cell_length_b                   10.4331(9)
_cell_length_c                   14.5148(13)
_cell_angle_alpha                76.969(2)
_cell_angle_beta                 85.423(2)
_cell_angle_gamma                66.140(2)
_cell_volume                     1273.48(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    5817
_cell_measurement_theta_min      2.18
_cell_measurement_theta_max      27.18

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_F_000             668
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.858
_shelx_estimated_absorpt_T_min   0.783
_shelx_estimated_absorpt_T_max   0.919
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.5777
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            25240
_diffrn_reflns_av_unetI/netI     0.0809
_diffrn_reflns_av_R_equivalents  0.0790
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.440
_diffrn_reflns_theta_max         25.989
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5009
_reflns_number_gt                2847
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0391P)²+3.1802P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5009
_refine_ls_number_parameters     386
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1253
_refine_ls_R_factor_gt           0.0592
_refine_ls_wR_factor_ref         0.1325
_refine_ls_wR_factor_gt          0.1095
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_restrained_S_all      1.010
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.000000 0.000000 1.000000 0.0572(3) Uani 1 2 d S . P . .
Ag2 Ag 0.500000 0.000000 0.000000 0.1121(5) Uani 1 2 d S . P . .
O1 O 0.9241(4) -0.2111(5) 0.6000(3) 0.0506(11) Uani 1 1 d . . . . .
O2 O 0.6453(4) 0.0411(4) 0.4341(2) 0.0387(9) Uani 1 1 d . . . . .
O3 O 0.8378(4) 0.3003(4) 0.9140(3) 0.0465(10) Uani 1 1 d . . . . .
O4 O 0.6489(4) 0.5188(4) 0.9102(3) 0.0376(9) Uani 1 1 d . . . . .
O5 O 0.4950(5) 0.3104(4) 0.9010(3) 0.0453(10) Uani 1 1 d . . . . .
O6 O 0.3101(4) 0.5218(4) 0.9181(3) 0.0458(10) Uani 1 1 d . . . . .
O7 O 0.7842(5) 0.6407(5) 0.4263(3) 0.0560(12) Uani 1 1 d . . . . .
O8 O 0.5306(4) 0.7089(4) 0.4327(2) 0.0401(10) Uani 1 1 d . . . . .
O9 O 0.2772(5) 0.7762(4) 0.4321(3) 0.0465(10) Uani 1 1 d . . . . .
N1 N 0.8793(5) -0.0604(5) 0.9094(3) 0.0365(11) Uani 1 1 d . . . . .
N2 N 0.6659(4) -0.1074(5) 0.6161(3) 0.0302(10) Uani 1 1 d . . . . .
H2A H 0.579765 -0.046874 0.588885 0.036 Uiso 1 1 calc R U . . .
N3 N 0.9045(5) -0.0683(5) 0.4179(3) 0.0361(11) Uani 1 1 d . . . . .
H3A H 0.988281 -0.135743 0.443726 0.043 Uiso 1 1 calc R U . . .
N4 N 0.6367(6) 0.0032(7) 0.1073(3) 0.0512(14) Uani 1 1 d . . . . .
C1 C 0.9101(8) -0.1966(7) 0.9111(5) 0.0578(19) Uani 1 1 d . . . . .
H1A H 0.979982 -0.267099 0.956328 0.069 Uiso 1 1 calc R U . . .
C2 C 0.8432(7) -0.2383(6) 0.8489(4) 0.0496(17) Uani 1 1 d . . . . .
H2B H 0.868556 -0.335149 0.852251 0.059 Uiso 1 1 calc R U . . .
C3 C 0.7386(5) -0.1361(6) 0.7817(3) 0.0270(12) Uani 1 1 d . . . . .
C4 C 0.7061(6) 0.0043(6) 0.7811(4) 0.0346(13) Uani 1 1 d . . . . .
H4A H 0.635736 0.076943 0.737074 0.042 Uiso 1 1 calc R U . . .
C5 C 0.7775(6) 0.0383(6) 0.8454(4) 0.0360(14) Uani 1 1 d . . . . .
H5A H 0.753381 0.134461 0.843918 0.043 Uiso 1 1 calc R U . . .
C6 C 0.6639(6) -0.1811(6) 0.7139(3) 0.0316(13) Uani 1 1 d . . . . .
H6A H 0.717607 -0.283602 0.718408 0.038 Uiso 1 1 calc R U . . .
H6B H 0.557347 -0.161792 0.732344 0.038 Uiso 1 1 calc R U . . .
C7 C 0.7955(6) -0.1304(6) 0.5678(4) 0.0321(13) Uani 1 1 d . . . . .
C8 C 0.7739(6) -0.0438(6) 0.4654(4) 0.0306(13) Uani 1 1 d . . . . .
C9 C 0.9121(6) 0.0138(7) 0.3241(4) 0.0424(15) Uani 1 1 d . . . . .
H9A H 1.018970 -0.021540 0.303776 0.051 Uiso 1 1 calc R U . . .
H9B H 0.882308 0.112926 0.328224 0.051 Uiso 1 1 calc R U . . .
C10 C 0.8126(6) 0.0103(6) 0.2493(4) 0.0311(13) Uani 1 1 d . . . . .
C11 C 0.7520(7) 0.1253(6) 0.1754(4) 0.0426(15) Uani 1 1 d . . . . .
H11A H 0.769555 0.207768 0.171994 0.051 Uiso 1 1 calc R U . . .
C12 C 0.6649(7) 0.1184(8) 0.1063(4) 0.0509(17) Uani 1 1 d . . . . .
H12A H 0.624187 0.197702 0.056928 0.061 Uiso 1 1 calc R U . . .
C13 C 0.6947(7) -0.1073(7) 0.1785(4) 0.0480(16) Uani 1 1 d . . . . .
H13A H 0.676192 -0.188867 0.180179 0.058 Uiso 1 1 calc R U . . .
C14 C 0.7810(6) -0.1075(6) 0.2502(4) 0.0377(14) Uani 1 1 d . . . . .
H14A H 0.818161 -0.187448 0.299493 0.045 Uiso 1 1 calc R U . . .
C15 C 0.7358(6) 0.4102(6) 0.8741(4) 0.0299(12) Uani 1 1 d . . . . .
C16 C 0.7090(5) 0.4430(5) 0.7678(3) 0.0266(12) Uani 1 1 d . . . . .
C17 C 0.5599(5) 0.5026(5) 0.7231(3) 0.0232(11) Uani 1 1 d . . . . .
C18 C 0.5514(5) 0.5654(5) 0.6248(3) 0.0246(11) Uani 1 1 d . . . . .
C19 C 0.4070(6) 0.6324(5) 0.5767(3) 0.0279(12) Uani 1 1 d . . . . .
C20 C 0.3955(7) 0.7100(6) 0.4777(4) 0.0356(13) Uani 1 1 d . . . . .
C21 C 0.4110(6) 0.4375(6) 0.8717(4) 0.0309(13) Uani 1 1 d . . . . .
C22 C 0.4195(6) 0.5047(5) 0.7693(3) 0.0289(12) Uani 1 1 d . . . . .
C23 C 0.2830(6) 0.5664(6) 0.7178(4) 0.0347(13) Uani 1 1 d . . . . .
H23A H 0.192570 0.565505 0.747863 0.042 Uiso 1 1 calc R U . . .
C24 C 0.2763(6) 0.6298(6) 0.6224(4) 0.0355(13) Uani 1 1 d . . . . .
H24A H 0.182238 0.670705 0.589665 0.043 Uiso 1 1 calc R U . . .
C25 C 0.6761(7) 0.6360(6) 0.4750(4) 0.0353(13) Uani 1 1 d . . . . .
C26 C 0.6866(6) 0.5621(5) 0.5741(3) 0.0269(12) Uani 1 1 d . . . . .
C27 C 0.8290(6) 0.4905(6) 0.6175(4) 0.0367(14) Uani 1 1 d . . . . .
H27A H 0.918679 0.481341 0.582970 0.044 Uiso 1 1 calc R U . . .
C28 C 0.8378(6) 0.4313(6) 0.7148(4) 0.0366(14) Uani 1 1 d . . . . .
H28A H 0.934696 0.382450 0.744094 0.044 Uiso 1 1 calc R U . . .
H4C H 0.650(9) 0.512(8) 0.995(6) 0.11(3) Uiso 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.149(4) . ?
Ag1 N1 2.149(4) 2_757 ?
Ag2 N4 2.114(5) . ?
Ag2 N4 2.114(5) 2_655 ?
O1 C7 1.220(6) . ?
O2 C8 1.225(6) . ?
O3 C15 1.214(6) . ?
O4 C15 1.295(6) . ?
O4 H4C 1.21(8) . ?
O5 C21 1.232(6) . ?
O6 C21 1.274(6) . ?
O7 C25 1.205(6) . ?
O8 C20 1.382(6) . ?
O8 C25 1.386(6) . ?
O9 C20 1.204(6) . ?
N1 C1 1.325(7) . ?
N1 C5 1.326(7) . ?
N2 C7 1.322(6) . ?
N2 C6 1.456(6) . ?
N2 H2A 0.8600 . ?
N3 C8 1.322(6) . ?
N3 C9 1.449(6) . ?
N3 H3A 0.8600 . ?
N4 C13 1.319(8) . ?
N4 C12 1.329(8) . ?
C1 C2 1.376(8) . ?
C1 H1A 0.9300 . ?
C2 C3 1.377(7) . ?
C2 H2B 0.9300 . ?
C3 C4 1.369(7) . ?
C3 C6 1.507(6) . ?
C4 C5 1.377(7) . ?
C4 H4A 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.536(7) . ?
C9 C10 1.508(7) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.371(7) . ?
C10 C14 1.375(7) . ?
C11 C12 1.378(8) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.371(7) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.522(7) . ?
C16 C28 1.363(7) . ?
C16 C17 1.430(6) . ?
C17 C18 1.423(6) . ?
C17 C22 1.431(7) . ?
C18 C26 1.413(7) . ?
C18 C19 1.413(7) . ?
C19 C24 1.360(7) . ?
C19 C20 1.470(7) . ?
C21 C22 1.504(7) . ?
C22 C23 1.378(7) . ?
C23 C24 1.387(7) . ?
C23 H23A 0.9300 . ?
C24 H24A 0.9300 . ?
C25 C26 1.461(7) . ?
C26 C27 1.368(7) . ?
C27 C28 1.402(7) . ?
C27 H27A 0.9300 . ?
C28 H28A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N1 180.0 . 2_757 ?
N4 Ag2 N4 180.0 . 2_655 ?
C15 O4 H4C 121(4) . . ?
C20 O8 C25 123.7(4) . . ?
C1 N1 C5 117.6(5) . . ?
C1 N1 Ag1 121.7(4) . . ?
C5 N1 Ag1 120.6(4) . . ?
C7 N2 C6 122.3(4) . . ?
C7 N2 H2A 118.8 . . ?
C6 N2 H2A 118.8 . . ?
C8 N3 C9 122.7(5) . . ?
C8 N3 H3A 118.6 . . ?
C9 N3 H3A 118.6 . . ?
C13 N4 C12 117.4(5) . . ?
C13 N4 Ag2 121.6(5) . . ?
C12 N4 Ag2 121.0(4) . . ?
N1 C1 C2 122.8(5) . . ?
N1 C1 H1A 118.6 . . ?
C2 C1 H1A 118.6 . . ?
C1 C2 C3 119.8(5) . . ?
C1 C2 H2B 120.1 . . ?
C3 C2 H2B 120.1 . . ?
C4 C3 C2 117.0(5) . . ?
C4 C3 C6 122.9(5) . . ?
C2 C3 C6 120.1(5) . . ?
C3 C4 C5 120.1(5) . . ?
C3 C4 H4A 120.0 . . ?
C5 C4 H4A 120.0 . . ?
N1 C5 C4 122.7(5) . . ?
N1 C5 H5A 118.6 . . ?
C4 C5 H5A 118.6 . . ?
N2 C6 C3 113.0(4) . . ?
N2 C6 H6A 109.0 . . ?
C3 C6 H6A 109.0 . . ?
N2 C6 H6B 109.0 . . ?
C3 C6 H6B 109.0 . . ?
H6A C6 H6B 107.8 . . ?
O1 C7 N2 124.4(5) . . ?
O1 C7 C8 121.0(5) . . ?
N2 C7 C8 114.7(4) . . ?
O2 C8 N3 125.1(5) . . ?
O2 C8 C7 121.0(5) . . ?
N3 C8 C7 113.9(4) . . ?
N3 C9 C10 115.7(4) . . ?
N3 C9 H9A 108.3 . . ?
C10 C9 H9A 108.3 . . ?
N3 C9 H9B 108.3 . . ?
C10 C9 H9B 108.3 . . ?
H9A C9 H9B 107.4 . . ?
C11 C10 C14 116.9(5) . . ?
C11 C10 C9 120.7(5) . . ?
C14 C10 C9 122.4(5) . . ?
C10 C11 C12 119.8(6) . . ?
C10 C11 H11A 120.1 . . ?
C12 C11 H11A 120.1 . . ?
N4 C12 C11 122.7(6) . . ?
N4 C12 H12A 118.6 . . ?
C11 C12 H12A 118.6 . . ?
N4 C13 C14 123.0(6) . . ?
N4 C13 H13A 118.5 . . ?
C14 C13 H13A 118.5 . . ?
C13 C14 C10 120.1(5) . . ?
C13 C14 H14A 120.0 . . ?
C10 C14 H14A 120.0 . . ?
O3 C15 O4 127.1(5) . . ?
O3 C15 C16 121.5(5) . . ?
O4 C15 C16 111.0(5) . . ?
C28 C16 C17 120.2(5) . . ?
C28 C16 C15 114.8(4) . . ?
C17 C16 C15 124.4(4) . . ?
C18 C17 C16 116.9(4) . . ?
C18 C17 C22 117.8(4) . . ?
C16 C17 C22 125.3(4) . . ?
C26 C18 C19 119.1(5) . . ?
C26 C18 C17 120.7(4) . . ?
C19 C18 C17 120.2(4) . . ?
C24 C19 C18 120.4(5) . . ?
C24 C19 C20 119.3(5) . . ?
C18 C19 C20 120.3(5) . . ?
O9 C20 O8 116.7(5) . . ?
O9 C20 C19 125.4(5) . . ?
O8 C20 C19 118.0(5) . . ?
O5 C21 O6 127.2(5) . . ?
O5 C21 C22 118.9(5) . . ?
O6 C21 C22 113.9(5) . . ?
C23 C22 C17 119.4(5) . . ?
C23 C22 C21 116.6(5) . . ?
C17 C22 C21 124.0(4) . . ?
C22 C23 C24 122.1(5) . . ?
C22 C23 H23A 119.0 . . ?
C24 C23 H23A 119.0 . . ?
C19 C24 C23 120.1(5) . . ?
C19 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
O7 C25 O8 116.5(5) . . ?
O7 C25 C26 125.4(5) . . ?
O8 C25 C26 118.2(5) . . ?
C27 C26 C18 120.4(5) . . ?
C27 C26 C25 119.1(5) . . ?
C18 C26 C25 120.5(5) . . ?
C26 C27 C28 119.0(5) . . ?
C26 C27 H27A 120.5 . . ?
C28 C27 H27A 120.5 . . ?
C16 C28 C27 122.2(5) . . ?
C16 C28 H28A 118.9 . . ?
C27 C28 H28A 118.9 . . ?

_refine_diff_density_max         1.137
_refine_diff_density_min         -1.570
_refine_diff_density_rms         0.088

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 2512229'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C12 H9 Ag N2 O5'
_chemical_formula_weight         369.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.779(2)
_cell_length_b                   7.1294(14)
_cell_length_c                   13.218(2)
_cell_angle_alpha                90
_cell_angle_beta                 93.331(4)
_cell_angle_gamma                90
_cell_volume                     1202.2(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9867
_cell_measurement_theta_min      2.28
_cell_measurement_theta_max      28.31

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.039
_exptl_crystal_F_000             728
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.699
_shelx_estimated_absorpt_T_min   0.550
_shelx_estimated_absorpt_T_max   0.728
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.5382
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            16417
_diffrn_reflns_av_unetI/netI     0.0261
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.155
_diffrn_reflns_theta_max         28.384
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             2981
_reflns_number_gt                2782
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0193P)²+7.5031P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2019/1 (Sheldrick 2019)'
_refine_ls_extinction_coef       0.0279(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         2981
_refine_ls_number_parameters     182
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0441
_refine_ls_R_factor_gt           0.0415
_refine_ls_wR_factor_ref         0.1087
_refine_ls_wR_factor_gt          0.1077
_refine_ls_goodness_of_fit_ref   1.163
_refine_ls_restrained_S_all      1.163
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.43382(3) 0.46323(6) 0.10950(3) 0.03233(16) Uani 1 1 d . . . . .
O1 O 0.9717(3) 0.7401(5) 0.5036(3) 0.0319(7) Uani 1 1 d . . . . .
O2 O 0.2859(2) 0.4247(5) 0.0155(2) 0.0293(7) Uani 1 1 d . . . . .
O3 O 0.2135(3) 0.2749(6) 0.1428(3) 0.0379(9) Uani 1 1 d . . . . .
O4 O 0.0282(3) 0.5695(7) 0.2781(3) 0.0461(10) Uani 1 1 d . . . . .
O5 O 0.1687(3) 0.6719(6) 0.2036(3) 0.0414(9) Uani 1 1 d . . . . .
H5C H 0.181610 0.733651 0.257882 0.050 Uiso 1 1 d R U . . .
N1 N 0.5498(3) 0.5199(6) 0.2330(3) 0.0318(9) Uani 1 1 d . . . . .
N2 N 0.8617(3) 0.4904(5) 0.4893(3) 0.0242(7) Uani 1 1 d . . . . .
H2A H 0.858071 0.370820 0.481104 0.029 Uiso 1 1 calc R U . . .
C1 C 0.5188(4) 0.5761(8) 0.3224(4) 0.0352(11) Uani 1 1 d . . . . .
H1A H 0.448028 0.601151 0.328507 0.042 Uiso 1 1 calc R U . . .
C2 C 0.5867(4) 0.5993(7) 0.4069(4) 0.0312(10) Uani 1 1 d . . . . .
H2B H 0.561440 0.638337 0.467994 0.037 Uiso 1 1 calc R U . . .
C3 C 0.6928(3) 0.5637(6) 0.3997(3) 0.0233(8) Uani 1 1 d . . . . .
C4 C 0.7248(4) 0.5059(8) 0.3069(4) 0.0339(11) Uani 1 1 d . . . . .
H4A H 0.795165 0.479863 0.299005 0.041 Uiso 1 1 calc R U . . .
C5 C 0.6525(4) 0.4866(9) 0.2254(4) 0.0374(12) Uani 1 1 d . . . . .
H5A H 0.675876 0.449320 0.163137 0.045 Uiso 1 1 calc R U . . .
C6 C 0.7652(3) 0.5964(7) 0.4923(3) 0.0272(9) Uani 1 1 d . . . . .
H6A H 0.781722 0.728986 0.497379 0.033 Uiso 1 1 calc R U . . .
H6B H 0.729514 0.561146 0.552245 0.033 Uiso 1 1 calc R U . . .
C7 C 0.9548(3) 0.5704(6) 0.4987(3) 0.0208(8) Uani 1 1 d . . . . .
C8 C 0.2101(3) 0.3771(6) 0.0669(3) 0.0200(8) Uani 1 1 d . . . . .
C9 C 0.1023(3) 0.4493(5) 0.0316(3) 0.0171(7) Uani 1 1 d . . . . .
C10 C 0.0377(3) 0.5349(6) 0.0992(3) 0.0177(7) Uani 1 1 d . . . . .
C11 C -0.0646(3) 0.5845(6) 0.0678(3) 0.0186(7) Uani 1 1 d . . . . .
H11A H -0.107843 0.640239 0.113408 0.022 Uiso 1 1 calc R U . . .
C12 C 0.0769(3) 0.5888(6) 0.2048(3) 0.0233(8) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N1 2.178(4) . ?
Ag O2 2.218(3) . ?
Ag O1 2.536(3) 2_645 ?
Ag O1 2.597(3) 4_575 ?
O1 C7 1.231(5) . ?
O2 C8 1.262(5) . ?
O3 C8 1.239(5) . ?
O4 C12 1.189(6) . ?
O5 C12 1.316(6) . ?
O5 H5C 0.8500 . ?
N1 C1 1.330(7) . ?
N1 C5 1.344(6) . ?
N2 C7 1.319(5) . ?
N2 C6 1.449(6) . ?
N2 H2A 0.8600 . ?
C1 C2 1.383(6) . ?
C1 H1A 0.9300 . ?
C2 C3 1.388(6) . ?
C2 H2B 0.9300 . ?
C3 C4 1.378(7) . ?
C3 C6 1.509(6) . ?
C4 C5 1.385(7) . ?
C4 H4A 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C7 1.529(8) 3_766 ?
C8 C9 1.518(5) . ?
C9 C10 1.393(5) . ?
C9 C11 1.395(5) 3_565 ?
C10 C11 1.393(5) . ?
C10 C12 1.506(5) . ?
C11 H11A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag O2 164.46(14) . . ?
N1 Ag O1 103.41(14) . 2_645 ?
O2 Ag O1 90.65(12) . 2_645 ?
N1 Ag O1 96.48(14) . 4_575 ?
O2 Ag O1 88.77(12) . 4_575 ?
O1 Ag O1 94.76(10) 2_645 4_575 ?
C7 O1 Ag 132.4(3) . 2_655 ?
C7 O1 Ag 142.3(3) . 4_676 ?
Ag O1 Ag 85.24(10) 2_655 4_676 ?
C8 O2 Ag 112.8(3) . . ?
C12 O5 H5C 110.6 . . ?
C1 N1 C5 117.5(4) . . ?
C1 N1 Ag 119.9(3) . . ?
C5 N1 Ag 122.4(3) . . ?
C7 N2 C6 122.4(4) . . ?
C7 N2 H2A 118.8 . . ?
C6 N2 H2A 118.8 . . ?
N1 C1 C2 123.2(4) . . ?
N1 C1 H1A 118.4 . . ?
C2 C1 H1A 118.4 . . ?
C1 C2 C3 119.5(4) . . ?
C1 C2 H2B 120.3 . . ?
C3 C2 H2B 120.3 . . ?
C4 C3 C2 117.2(4) . . ?
C4 C3 C6 124.7(4) . . ?
C2 C3 C6 118.1(4) . . ?
C3 C4 C5 120.2(4) . . ?
C3 C4 H4A 119.9 . . ?
C5 C4 H4A 119.9 . . ?
N1 C5 C4 122.3(5) . . ?
N1 C5 H5A 118.9 . . ?
C4 C5 H5A 118.9 . . ?
N2 C6 C3 112.3(4) . . ?
N2 C6 H6A 109.1 . . ?
C3 C6 H6A 109.1 . . ?
N2 C6 H6B 109.1 . . ?
C3 C6 H6B 109.1 . . ?
H6A C6 H6B 107.9 . . ?
O1 C7 N2 125.8(4) . . ?
O1 C7 C7 120.9(5) . 3_766 ?
N2 C7 C7 113.3(4) . 3_766 ?
O3 C8 O2 127.1(4) . . ?
O3 C8 C9 115.9(4) . . ?
O2 C8 C9 117.0(3) . . ?
C10 C9 C11 119.6(3) . 3_565 ?
C10 C9 C8 120.9(3) . . ?
C11 C9 C8 119.3(3) 3_565 . ?
C9 C10 C11 120.1(3) . . ?
C9 C10 C12 121.9(3) . . ?
C11 C10 C12 117.9(4) . . ?
C10 C11 C9 120.2(4) . 3_565 ?
C10 C11 H11A 119.9 . . ?
C9 C11 H11A 119.9 3_565 . ?
O4 C12 O5 124.9(4) . . ?
O4 C12 C10 124.3(4) . . ?
O5 C12 C10 110.6(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 -0.8(8) . . . . ?
Ag N1 C1 C2 174.2(4) . . . . ?
N1 C1 C2 C3 0.3(9) . . . . ?
C1 C2 C3 C4 -0.1(7) . . . . ?
C1 C2 C3 C6 178.0(5) . . . . ?
C2 C3 C4 C5 0.4(8) . . . . ?
C6 C3 C4 C5 -177.6(5) . . . . ?
C1 N1 C5 C4 1.1(8) . . . . ?
Ag N1 C5 C4 -173.8(4) . . . . ?
C3 C4 C5 N1 -1.0(9) . . . . ?
C7 N2 C6 C3 124.9(4) . . . . ?
C4 C3 C6 N2 -24.4(7) . . . . ?
C2 C3 C6 N2 157.6(4) . . . . ?
Ag O1 C7 N2 -117.8(4) 2_655 . . . ?
Ag O1 C7 N2 58.8(7) 4_676 . . . ?
Ag O1 C7 C7 61.2(7) 2_655 . . 3_766 ?
Ag O1 C7 C7 -122.2(5) 4_676 . . 3_766 ?
C6 N2 C7 O1 -5.4(7) . . . . ?
C6 N2 C7 C7 175.6(4) . . . 3_766 ?
Ag O2 C8 O3 -34.9(6) . . . . ?
Ag O2 C8 C9 146.2(3) . . . . ?
O3 C8 C9 C10 50.4(6) . . . . ?
O2 C8 C9 C10 -130.6(4) . . . . ?
O3 C8 C9 C11 -124.3(4) . . . 3_565 ?
O2 C8 C9 C11 54.7(5) . . . 3_565 ?
C11 C9 C10 C11 0.8(7) 3_565 . . . ?
C8 C9 C10 C11 -173.9(4) . . . . ?
C11 C9 C10 C12 -175.0(4) 3_565 . . . ?
C8 C9 C10 C12 10.3(6) . . . . ?
C9 C10 C11 C9 -0.8(7) . . . 3_565 ?
C12 C10 C11 C9 175.2(4) . . . 3_565 ?
C9 C10 C12 O4 -139.3(5) . . . . ?
C11 C10 C12 O4 44.8(7) . . . . ?
C9 C10 C12 O5 45.2(6) . . . . ?
C11 C10 C12 O5 -130.7(4) . . . . ?

_refine_diff_density_max         1.959
_refine_diff_density_min         -1.079
_refine_diff_density_rms         0.134

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2512228'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C26 H25 Ag N4 O8'
_chemical_formula_weight         629.37

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.096(2)
_cell_length_b                   9.557(2)
_cell_length_c                   15.651(4)
_cell_angle_alpha                76.424(8)
_cell_angle_beta                 80.583(8)
_cell_angle_gamma                84.483(8)
_cell_volume                     1302.3(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9920
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      27.54

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.605
_exptl_crystal_F_000             640
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.831
_shelx_estimated_absorpt_T_min   0.789
_shelx_estimated_absorpt_T_max   0.921
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.6202
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            24902
_diffrn_reflns_av_unetI/netI     0.0667
_diffrn_reflns_av_R_equivalents  0.0837
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.353
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5111
_reflns_number_gt                3904
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0478P)²+0.3900P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5111
_refine_ls_number_parameters     352
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0669
_refine_ls_R_factor_gt           0.0440
_refine_ls_wR_factor_ref         0.1150
_refine_ls_wR_factor_gt          0.1037
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.51327(3) 0.34921(3) 0.95405(2) 0.04898(14) Uani 1 1 d . . . . .
O1 O 0.4116(4) 0.6348(3) 0.4437(2) 0.0622(8) Uani 1 1 d . . . . .
O2 O 0.5981(4) 0.9508(3) 0.4066(2) 0.0633(9) Uani 1 1 d . . . . .
O3 O 0.2849(3) 0.4700(3) 1.04076(19) 0.0500(7) Uani 1 1 d . . . . .
O4 O 0.0694(3) 0.4945(3) 1.1256(2) 0.0643(9) Uani 1 1 d . . . . .
O5 O 0.0714(3) -0.2407(2) 1.10643(19) 0.0496(7) Uani 1 1 d . . . . .
H5C H 0.088017 -0.330888 1.110426 0.059 Uiso 1 1 d R U . . .
O6 O 0.1994(4) -0.2873(3) 1.2177(2) 0.0776(11) Uani 1 1 d . . . . .
N1 N 0.4331(3) 0.4641(3) 0.8310(2) 0.0416(7) Uani 1 1 d . . . . .
N2 N 0.3895(4) 0.7995(3) 0.52947(19) 0.0410(7) Uani 1 1 d . . . . .
H2A H 0.422106 0.878714 0.533779 0.049 Uiso 1 1 calc R U . . .
N3 N 0.6335(4) 0.7759(3) 0.33039(19) 0.0414(7) Uani 1 1 d . . . . .
H3A H 0.605880 0.694134 0.326904 0.050 Uiso 1 1 calc R U . . .
N4 N 0.5928(3) 1.1832(3) 0.06020(19) 0.0369(7) Uani 1 1 d . . . . .
C1 C 0.5278(5) 0.5229(5) 0.7596(3) 0.0552(11) Uani 1 1 d . . . . .
H1A H 0.629587 0.503330 0.761060 0.066 Uiso 1 1 calc R U . . .
C2 C 0.4834(4) 0.6099(4) 0.6846(3) 0.0491(10) Uani 1 1 d . . . . .
H2B H 0.554283 0.649960 0.637461 0.059 Uiso 1 1 calc R U . . .
C3 C 0.3348(4) 0.6382(4) 0.6788(2) 0.0331(8) Uani 1 1 d . . . . .
C4 C 0.2358(4) 0.5757(4) 0.7513(2) 0.0396(9) Uani 1 1 d . . . . .
H4B H 0.133510 0.589838 0.749891 0.048 Uiso 1 1 calc R U . . .
C5 C 0.2887(4) 0.4926(4) 0.8251(2) 0.0414(9) Uani 1 1 d . . . . .
H5A H 0.219824 0.454132 0.873851 0.050 Uiso 1 1 calc R U . . .
C6 C 0.2752(4) 0.7331(4) 0.5985(2) 0.0424(9) Uani 1 1 d . . . . .
H6A H 0.218117 0.675568 0.573890 0.051 Uiso 1 1 calc R U . . .
H6B H 0.207571 0.808430 0.617592 0.051 Uiso 1 1 calc R U . . .
C7 C 0.4470(4) 0.7451(4) 0.4599(2) 0.0416(9) Uani 1 1 d . . . . .
C8 C 0.5681(4) 0.8358(4) 0.3959(2) 0.0421(9) Uani 1 1 d . . . . .
C9 C 0.7512(4) 0.8452(4) 0.2640(2) 0.0424(9) Uani 1 1 d . . . . .
H9A H 0.807325 0.773479 0.234874 0.051 Uiso 1 1 calc R U . . .
H9B H 0.819157 0.883159 0.293458 0.051 Uiso 1 1 calc R U . . .
C10 C 0.6929(4) 0.9660(4) 0.1947(2) 0.0334(8) Uani 1 1 d . . . . .
C11 C 0.5655(4) 0.9532(4) 0.1601(3) 0.0447(9) Uani 1 1 d . . . . .
H11A H 0.511277 0.871239 0.181288 0.054 Uiso 1 1 calc R U . . .
C12 C 0.5203(4) 1.0620(4) 0.0944(3) 0.0443(9) Uani 1 1 d . . . . .
H12A H 0.434262 1.051743 0.072054 0.053 Uiso 1 1 calc R U . . .
C13 C 0.7138(4) 1.1962(4) 0.0941(2) 0.0379(8) Uani 1 1 d . . . . .
H13A H 0.766121 1.279069 0.071636 0.045 Uiso 1 1 calc R U . . .
C14 C 0.7651(4) 1.0918(4) 0.1612(2) 0.0357(8) Uani 1 1 d . . . . .
H14A H 0.849130 1.106433 0.184008 0.043 Uiso 1 1 calc R U . . .
C15 C 0.1749(4) 0.4211(3) 1.0917(2) 0.0323(8) Uani 1 1 d . . . . .
C16 C 0.1613(4) 0.2588(3) 1.1152(2) 0.0298(7) Uani 1 1 d . . . . .
C17 C 0.1568(4) 0.1766(3) 1.2042(2) 0.0302(7) Uani 1 1 d . . . . .
C18 C 0.1606(4) 0.2414(4) 1.2763(3) 0.0459(10) Uani 1 1 d . . . . .
H18A H 0.165300 0.340910 1.265568 0.055 Uiso 1 1 calc R U . . .
C19 C 0.1576(5) 0.1619(5) 1.3611(3) 0.0619(12) Uani 1 1 d . . . . .
H19A H 0.160704 0.207105 1.407235 0.074 Uiso 1 1 calc R U . . .
C20 C 0.1498(5) 0.0125(5) 1.3785(3) 0.0595(12) Uani 1 1 d . . . . .
H20A H 0.145252 -0.041115 1.436656 0.071 Uiso 1 1 calc R U . . .
C21 C 0.1489(5) -0.0559(4) 1.3111(3) 0.0460(10) Uani 1 1 d . . . . .
H21A H 0.146194 -0.155753 1.323817 0.055 Uiso 1 1 calc R U . . .
C22 C 0.1519(4) 0.0233(3) 1.2215(2) 0.0294(7) Uani 1 1 d . . . . .
C23 C 0.1439(3) -0.0415(3) 1.1493(2) 0.0274(7) Uani 1 1 d . . . . .
C24 C 0.1409(4) 0.0425(3) 1.0655(2) 0.0303(7) Uani 1 1 d . . . . .
H24A H 0.131187 -0.000498 1.019411 0.036 Uiso 1 1 calc R U . . .
C25 C 0.1521(4) 0.1911(3) 1.0482(2) 0.0316(8) Uani 1 1 d . . . . .
H25A H 0.153286 0.245257 0.990362 0.038 Uiso 1 1 calc R U . . .
C26 C 0.1405(4) -0.2025(3) 1.1614(2) 0.0335(8) Uani 1 1 d . . . . .
O7 O -0.0086(4) 0.4618(4) 0.6295(2) 0.0831(11) Uani 1 1 d . . . . .
H7C H -0.053815 0.409884 0.676297 0.100 Uiso 1 1 d R U . . .
H7D H -0.069615 0.489854 0.592247 0.100 Uiso 1 1 d R U . . .
O8 O 0.2131(4) 0.4120(3) 0.4887(2) 0.0696(9) Uani 1 1 d . . . . .
H8A H 0.276306 0.475226 0.481681 0.083 Uiso 1 1 d R U . . .
H8B H 0.162686 0.400976 0.540341 0.083 Uiso 1 1 d R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N4 2.176(3) 1_546 ?
Ag N1 2.182(3) . ?
O1 C7 1.224(5) . ?
O2 C8 1.212(5) . ?
O3 C15 1.229(4) . ?
O4 C15 1.255(4) . ?
O5 C26 1.279(4) . ?
O5 H5C 0.8500 . ?
O6 C26 1.207(4) . ?
N1 C5 1.329(5) . ?
N1 C1 1.338(5) . ?
N2 C7 1.325(5) . ?
N2 C6 1.445(4) . ?
N2 H2A 0.8600 . ?
N3 C8 1.321(5) . ?
N3 C9 1.454(5) . ?
N3 H3A 0.8600 . ?
N4 C13 1.325(5) . ?
N4 C12 1.343(5) . ?
C1 C2 1.365(5) . ?
C1 H1A 0.9300 . ?
C2 C3 1.366(5) . ?
C2 H2B 0.9300 . ?
C3 C4 1.380(5) . ?
C3 C6 1.514(5) . ?
C4 C5 1.370(5) . ?
C4 H4B 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.543(5) . ?
C9 C10 1.508(5) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C14 1.377(5) . ?
C10 C11 1.384(5) . ?
C11 C12 1.364(5) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.376(5) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.521(4) . ?
C16 C25 1.372(5) . ?
C16 C17 1.426(5) . ?
C17 C18 1.415(5) . ?
C17 C22 1.430(4) . ?
C18 C19 1.363(6) . ?
C18 H18A 0.9300 . ?
C19 C20 1.396(6) . ?
C19 H19A 0.9300 . ?
C20 C21 1.368(6) . ?
C20 H20A 0.9300 . ?
C21 C22 1.425(5) . ?
C21 H21A 0.9300 . ?
C22 C23 1.425(5) . ?
C23 C24 1.370(5) . ?
C23 C26 1.509(4) . ?
C24 C25 1.392(4) . ?
C24 H24A 0.9300 . ?
C25 H25A 0.9300 . ?
O7 H7C 0.8499 . ?
O7 H7D 0.8500 . ?
O8 H8A 0.8499 . ?
O8 H8B 0.8499 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag N1 163.94(12) 1_546 . ?
C26 O5 H5C 109.0 . . ?
C5 N1 C1 116.0(3) . . ?
C5 N1 Ag 122.4(2) . . ?
C1 N1 Ag 121.2(3) . . ?
C7 N2 C6 123.7(3) . . ?
C7 N2 H2A 118.1 . . ?
C6 N2 H2A 118.1 . . ?
C8 N3 C9 121.5(3) . . ?
C8 N3 H3A 119.3 . . ?
C9 N3 H3A 119.3 . . ?
C13 N4 C12 116.9(3) . . ?
C13 N4 Ag 122.2(2) . 1_564 ?
C12 N4 Ag 120.9(2) . 1_564 ?
N1 C1 C2 123.7(4) . . ?
N1 C1 H1A 118.1 . . ?
C2 C1 H1A 118.1 . . ?
C1 C2 C3 119.9(3) . . ?
C1 C2 H2B 120.0 . . ?
C3 C2 H2B 120.0 . . ?
C2 C3 C4 117.0(3) . . ?
C2 C3 C6 123.7(3) . . ?
C4 C3 C6 119.3(3) . . ?
C5 C4 C3 119.7(3) . . ?
C5 C4 H4B 120.1 . . ?
C3 C4 H4B 120.1 . . ?
N1 C5 C4 123.5(3) . . ?
N1 C5 H5A 118.2 . . ?
C4 C5 H5A 118.2 . . ?
N2 C6 C3 114.1(3) . . ?
N2 C6 H6A 108.7 . . ?
C3 C6 H6A 108.7 . . ?
N2 C6 H6B 108.7 . . ?
C3 C6 H6B 108.7 . . ?
H6A C6 H6B 107.6 . . ?
O1 C7 N2 126.0(4) . . ?
O1 C7 C8 120.2(3) . . ?
N2 C7 C8 113.8(3) . . ?
O2 C8 N3 124.5(4) . . ?
O2 C8 C7 121.8(3) . . ?
N3 C8 C7 113.7(3) . . ?
N3 C9 C10 113.0(3) . . ?
N3 C9 H9A 109.0 . . ?
C10 C9 H9A 109.0 . . ?
N3 C9 H9B 109.0 . . ?
C10 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
C14 C10 C11 116.9(3) . . ?
C14 C10 C9 122.0(3) . . ?
C11 C10 C9 121.0(3) . . ?
C12 C11 C10 119.3(3) . . ?
C12 C11 H11A 120.4 . . ?
C10 C11 H11A 120.4 . . ?
N4 C12 C11 123.8(3) . . ?
N4 C12 H12A 118.1 . . ?
C11 C12 H12A 118.1 . . ?
N4 C13 C14 122.6(3) . . ?
N4 C13 H13A 118.7 . . ?
C14 C13 H13A 118.7 . . ?
C13 C14 C10 120.5(3) . . ?
C13 C14 H14A 119.8 . . ?
C10 C14 H14A 119.8 . . ?
O3 C15 O4 125.4(3) . . ?
O3 C15 C16 118.5(3) . . ?
O4 C15 C16 116.1(3) . . ?
C25 C16 C17 119.8(3) . . ?
C25 C16 C15 118.4(3) . . ?
C17 C16 C15 121.9(3) . . ?
C18 C17 C16 122.2(3) . . ?
C18 C17 C22 118.5(3) . . ?
C16 C17 C22 119.3(3) . . ?
C19 C18 C17 121.8(4) . . ?
C19 C18 H18A 119.1 . . ?
C17 C18 H18A 119.1 . . ?
C18 C19 C20 119.9(4) . . ?
C18 C19 H19A 120.0 . . ?
C20 C19 H19A 120.0 . . ?
C21 C20 C19 120.7(4) . . ?
C21 C20 H20A 119.6 . . ?
C19 C20 H20A 119.6 . . ?
C20 C21 C22 121.1(4) . . ?
C20 C21 H21A 119.4 . . ?
C22 C21 H21A 119.4 . . ?
C21 C22 C23 123.5(3) . . ?
C21 C22 C17 118.0(3) . . ?
C23 C22 C17 118.5(3) . . ?
C24 C23 C22 120.2(3) . . ?
C24 C23 C26 117.9(3) . . ?
C22 C23 C26 121.9(3) . . ?
C23 C24 C25 121.2(3) . . ?
C23 C24 H24A 119.4 . . ?
C25 C24 H24A 119.4 . . ?
C16 C25 C24 120.9(3) . . ?
C16 C25 H25A 119.5 . . ?
C24 C25 H25A 119.5 . . ?
O6 C26 O5 123.3(3) . . ?
O6 C26 C23 122.5(3) . . ?
O5 C26 C23 114.2(3) . . ?
H7C O7 H7D 108.5 . . ?
H8A O8 H8B 110.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 1.3(7) . . . . ?
Ag N1 C1 C2 -172.1(4) . . . . ?
N1 C1 C2 C3 -1.7(7) . . . . ?
C1 C2 C3 C4 0.2(6) . . . . ?
C1 C2 C3 C6 -180.0(4) . . . . ?
C2 C3 C4 C5 1.6(6) . . . . ?
C6 C3 C4 C5 -178.3(4) . . . . ?
C1 N1 C5 C4 0.6(6) . . . . ?
Ag N1 C5 C4 173.9(3) . . . . ?
C3 C4 C5 N1 -2.0(6) . . . . ?
C7 N2 C6 C3 95.4(4) . . . . ?
C2 C3 C6 N2 -3.6(5) . . . . ?
C4 C3 C6 N2 176.3(3) . . . . ?
C6 N2 C7 O1 0.9(6) . . . . ?
C6 N2 C7 C8 -179.7(3) . . . . ?
C9 N3 C8 O2 0.4(6) . . . . ?
C9 N3 C8 C7 -179.5(3) . . . . ?
O1 C7 C8 O2 174.6(4) . . . . ?
N2 C7 C8 O2 -4.9(5) . . . . ?
O1 C7 C8 N3 -5.5(5) . . . . ?
N2 C7 C8 N3 175.0(3) . . . . ?
C8 N3 C9 C10 -78.0(4) . . . . ?
N3 C9 C10 C14 141.2(3) . . . . ?
N3 C9 C10 C11 -40.7(5) . . . . ?
C14 C10 C11 C12 1.4(5) . . . . ?
C9 C10 C11 C12 -176.9(4) . . . . ?
C13 N4 C12 C11 -1.0(6) . . . . ?
Ag N4 C12 C11 179.1(3) 1_564 . . . ?
C10 C11 C12 N4 0.2(6) . . . . ?
C12 N4 C13 C14 0.1(5) . . . . ?
Ag N4 C13 C14 -180.0(3) 1_564 . . . ?
N4 C13 C14 C10 1.6(5) . . . . ?
C11 C10 C14 C13 -2.2(5) . . . . ?
C9 C10 C14 C13 176.0(3) . . . . ?
O3 C15 C16 C25 -62.1(5) . . . . ?
O4 C15 C16 C25 116.7(4) . . . . ?
O3 C15 C16 C17 118.4(4) . . . . ?
O4 C15 C16 C17 -62.9(5) . . . . ?
C25 C16 C17 C18 -177.7(3) . . . . ?
C15 C16 C17 C18 1.8(5) . . . . ?
C25 C16 C17 C22 3.7(5) . . . . ?
C15 C16 C17 C22 -176.7(3) . . . . ?
C16 C17 C18 C19 -179.4(4) . . . . ?
C22 C17 C18 C19 -0.9(6) . . . . ?
C17 C18 C19 C20 -0.3(7) . . . . ?
C18 C19 C20 C21 1.6(8) . . . . ?
C19 C20 C21 C22 -1.6(7) . . . . ?
C20 C21 C22 C23 -176.9(4) . . . . ?
C20 C21 C22 C17 0.4(6) . . . . ?
C18 C17 C22 C21 0.9(5) . . . . ?
C16 C17 C22 C21 179.4(3) . . . . ?
C18 C17 C22 C23 178.3(3) . . . . ?
C16 C17 C22 C23 -3.1(5) . . . . ?
C21 C22 C23 C24 177.2(3) . . . . ?
C17 C22 C23 C24 -0.1(5) . . . . ?
C21 C22 C23 C26 -3.6(5) . . . . ?
C17 C22 C23 C26 179.1(3) . . . . ?
C22 C23 C24 C25 2.9(5) . . . . ?
C26 C23 C24 C25 -176.4(3) . . . . ?
C17 C16 C25 C24 -1.1(5) . . . . ?
C15 C16 C25 C24 179.4(3) . . . . ?
C23 C24 C25 C16 -2.3(5) . . . . ?
C24 C23 C26 O6 149.8(4) . . . . ?
C22 C23 C26 O6 -29.4(5) . . . . ?
C24 C23 C26 O5 -29.5(4) . . . . ?
C22 C23 C26 O5 151.2(3) . . . . ?

_refine_diff_density_max         0.371
_refine_diff_density_min         -0.700
_refine_diff_density_rms         0.082

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_6
_database_code_depnum_ccdc_archive 'CCDC 2512232'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C37 H36 Ag2 N8 O12'
_chemical_formula_weight         1000.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.4624(19)
_cell_length_b                   11.7312(19)
_cell_length_c                   19.160(3)
_cell_angle_alpha                95.359(6)
_cell_angle_beta                 95.325(7)
_cell_angle_gamma                106.993(7)
_cell_volume                     2008.9(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5841
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      26.65

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.654
_exptl_crystal_F_000             1008
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    1.047
_shelx_estimated_absorpt_T_min   0.744
_shelx_estimated_absorpt_T_max   0.903
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.5869
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            32451
_diffrn_reflns_av_unetI/netI     0.1223
_diffrn_reflns_av_R_equivalents  0.1393
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.076
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7913
_reflns_number_gt                3860
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0538P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7913
_refine_ls_number_parameters     542
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1473
_refine_ls_R_factor_gt           0.0596
_refine_ls_wR_factor_ref         0.1557
_refine_ls_wR_factor_gt          0.1241
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_restrained_S_all      1.003
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.95054(7) -0.06965(5) 0.07559(3) 0.0614(2) Uani 1 1 d . . . . .
Ag2 Ag 0.51433(7) 0.97148(5) 0.57739(3) 0.0615(2) Uani 1 1 d . . . . .
O1 O 1.3473(6) -0.4220(4) -0.1630(2) 0.0552(13) Uani 1 1 d . . . . .
O2 O 1.2405(5) -0.7015(4) -0.0983(2) 0.0465(12) Uani 1 1 d . . . . .
O3 O 0.7163(5) 0.2665(4) 0.3999(2) 0.0485(12) Uani 1 1 d . . . . .
O4 O 0.7991(7) 0.5378(4) 0.3287(3) 0.0722(17) Uani 1 1 d . . . . .
O5 O 0.7898(6) 0.3172(5) 0.6567(3) 0.0726(17) Uani 1 1 d . . . . .
O6 O 0.7979(7) 0.4376(5) 0.5727(3) 0.0808(18) Uani 1 1 d . . . . .
O7 O 0.8071(7) 0.9100(6) 0.8184(3) 0.093(2) Uani 1 1 d . . . . .
O8 O 0.7804(7) 0.8072(6) 0.9090(3) 0.093(2) Uani 1 1 d . . . . .
H8B H 0.698421 0.757017 0.914897 0.111 Uiso 1 1 d R U . . .
O9 O 0.7089(6) 0.6052(6) 0.9311(3) 0.0797(18) Uani 1 1 d . . . . .
O10 O 0.6174(9) 0.4219(7) 0.8700(3) 0.098(2) Uani 1 1 d . . . . .
N1 N 1.1056(6) -0.1555(5) 0.0380(3) 0.0452(15) Uani 1 1 d . . . . .
N2 N 1.3570(5) -0.4603(4) -0.0505(3) 0.0370(13) Uani 1 1 d . . . . .
H2A H 1.340245 -0.514735 -0.022517 0.044 Uiso 1 1 calc R U . . .
N3 N 1.1928(6) -0.6527(4) -0.2093(3) 0.0393(13) Uani 1 1 d . . . . .
H3A H 1.204258 -0.593377 -0.233646 0.047 Uiso 1 1 calc R U . . .
N4 N 1.3752(6) -0.9405(5) -0.3676(3) 0.0398(14) Uani 1 1 d . . . . .
N5 N 0.8043(6) 0.0138(5) 0.1244(3) 0.0415(14) Uani 1 1 d . . . . .
N6 N 0.6438(6) 0.3052(4) 0.2909(3) 0.0419(14) Uani 1 1 d . . . . .
H6A H 0.646507 0.361374 0.264827 0.050 Uiso 1 1 calc R U . . .
N7 N 0.8278(5) 0.5104(4) 0.4427(3) 0.0366(13) Uani 1 1 d . . . . .
H7A H 0.811477 0.460005 0.473104 0.044 Uiso 1 1 calc R U . . .
N8 N 0.6358(6) 0.8540(5) 0.5355(3) 0.0438(15) Uani 1 1 d . . . . .
C1 C 1.2502(8) -0.0963(6) 0.0410(4) 0.0486(19) Uani 1 1 d . . . . .
H1A H 1.283023 -0.014436 0.056749 0.058 Uiso 1 1 calc R U . . .
C2 C 1.3533(7) -0.1523(6) 0.0215(3) 0.0387(16) Uani 1 1 d . . . . .
H2B H 1.452902 -0.107681 0.023551 0.046 Uiso 1 1 calc R U . . .
C3 C 1.3081(7) -0.2747(6) -0.0011(3) 0.0350(16) Uani 1 1 d . . . . .
C4 C 1.1593(8) -0.3336(6) -0.0039(4) 0.0482(19) Uani 1 1 d . . . . .
H4B H 1.123599 -0.415524 -0.019404 0.058 Uiso 1 1 calc R U . . .
C5 C 1.0617(8) -0.2732(6) 0.0158(4) 0.051(2) Uani 1 1 d . . . . .
H5A H 0.961409 -0.316043 0.013558 0.061 Uiso 1 1 calc R U . . .
C6 C 1.4209(7) -0.3361(5) -0.0205(3) 0.0368(16) Uani 1 1 d . . . . .
H6B H 1.478832 -0.292581 -0.054140 0.044 Uiso 1 1 calc R U . . .
H6D H 1.488677 -0.331935 0.021577 0.044 Uiso 1 1 calc R U . . .
C7 C 1.3232(7) -0.4934(6) -0.1193(4) 0.0368(16) Uani 1 1 d . . . . .
C8 C 1.2477(7) -0.6285(5) -0.1414(3) 0.0331(15) Uani 1 1 d . . . . .
C9 C 1.1137(7) -0.7736(5) -0.2456(3) 0.0405(17) Uani 1 1 d . . . . .
H9A H 1.028702 -0.769587 -0.276683 0.049 Uiso 1 1 calc R U . . .
H9B H 1.075940 -0.825604 -0.210704 0.049 Uiso 1 1 calc R U . . .
C10 C 1.2073(7) -0.8287(6) -0.2882(3) 0.0338(15) Uani 1 1 d . . . . .
C11 C 1.3524(7) -0.7709(6) -0.2961(4) 0.0471(19) Uani 1 1 d . . . . .
H11A H 1.397252 -0.692414 -0.274637 0.056 Uiso 1 1 calc R U . . .
C12 C 1.4321(8) -0.8279(6) -0.3354(4) 0.0489(19) Uani 1 1 d . . . . .
H12A H 1.530229 -0.786141 -0.339813 0.059 Uiso 1 1 calc R U . . .
C13 C 1.2342(8) -0.9968(6) -0.3599(4) 0.0512(19) Uani 1 1 d . . . . .
H13A H 1.191968 -1.075456 -0.381516 0.061 Uiso 1 1 calc R U . . .
C14 C 1.1481(7) -0.9453(6) -0.3218(3) 0.0420(17) Uani 1 1 d . . . . .
H14A H 1.050037 -0.988606 -0.318560 0.050 Uiso 1 1 calc R U . . .
C15 C 0.6763(7) -0.0483(6) 0.1460(3) 0.0429(17) Uani 1 1 d . . . . .
H15A H 0.639944 -0.130650 0.131848 0.051 Uiso 1 1 calc R U . . .
C16 C 0.5967(7) 0.0038(5) 0.1880(3) 0.0375(16) Uani 1 1 d . . . . .
H16A H 0.507669 -0.042424 0.201141 0.045 Uiso 1 1 calc R U . . .
C17 C 0.6505(7) 0.1265(5) 0.2108(3) 0.0318(15) Uani 1 1 d . . . . .
C18 C 0.7797(7) 0.1917(6) 0.1878(3) 0.0419(17) Uani 1 1 d . . . . .
H18A H 0.818104 0.274167 0.201345 0.050 Uiso 1 1 calc R U . . .
C19 C 0.8514(7) 0.1332(6) 0.1442(4) 0.0461(18) Uani 1 1 d . . . . .
H19A H 0.936821 0.178565 0.127583 0.055 Uiso 1 1 calc R U . . .
C20 C 0.5654(7) 0.1824(6) 0.2601(3) 0.0405(17) Uani 1 1 d . . . . .
H20A H 0.471798 0.180903 0.234078 0.049 Uiso 1 1 calc R U . . .
H20B H 0.542308 0.133326 0.297991 0.049 Uiso 1 1 calc R U . . .
C21 C 0.7115(7) 0.3364(6) 0.3568(3) 0.0340(15) Uani 1 1 d . . . . .
C22 C 0.7833(7) 0.4725(6) 0.3756(4) 0.0374(16) Uani 1 1 d . . . . .
C23 C 0.9047(7) 0.6372(6) 0.4666(3) 0.0421(17) Uani 1 1 d . . . . .
H23A H 0.956627 0.672461 0.428813 0.051 Uiso 1 1 calc R U . . .
H23B H 0.979092 0.642941 0.506286 0.051 Uiso 1 1 calc R U . . .
C24 C 0.8061(7) 0.7095(6) 0.4885(3) 0.0339(15) Uani 1 1 d . . . . .
C25 C 0.6544(7) 0.6655(6) 0.4840(4) 0.0469(19) Uani 1 1 d . . . . .
H25A H 0.605238 0.586417 0.464733 0.056 Uiso 1 1 calc R U . . .
C26 C 0.5752(8) 0.7392(6) 0.5080(4) 0.0489(19) Uani 1 1 d . . . . .
H26A H 0.472277 0.706781 0.504968 0.059 Uiso 1 1 calc R U . . .
C27 C 0.7846(9) 0.8974(6) 0.5387(4) 0.055(2) Uani 1 1 d . . . . .
H27A H 0.831426 0.976990 0.557746 0.066 Uiso 1 1 calc R U . . .
C28 C 0.8703(7) 0.8295(6) 0.5151(3) 0.0432(18) Uani 1 1 d . . . . .
H28A H 0.972591 0.864320 0.517007 0.052 Uiso 1 1 calc R U . . .
C29 C 0.7923(8) 0.4147(8) 0.6352(4) 0.056(2) Uani 1 1 d . . . . .
C30 C 0.7845(8) 0.5165(7) 0.6891(4) 0.054(2) Uani 1 1 d . . . . .
C31 C 0.8180(10) 0.6327(8) 0.6752(4) 0.078(3) Uani 1 1 d . . . . .
H31A H 0.842379 0.651412 0.630830 0.093 Uiso 1 1 calc R U . . .
C32 C 0.8160(10) 0.7232(8) 0.7267(4) 0.078(3) Uani 1 1 d . . . . .
H32A H 0.843722 0.801854 0.716173 0.094 Uiso 1 1 calc R U . . .
C33 C 0.7750(8) 0.7028(8) 0.7927(4) 0.059(2) Uani 1 1 d . . . . .
C34 C 0.7838(9) 0.8137(9) 0.8435(5) 0.068(2) Uani 1 1 d . . . . .
C35 C 0.7342(8) 0.5839(8) 0.8059(4) 0.057(2) Uani 1 1 d . . . . .
C36 C 0.6834(10) 0.5306(10) 0.8729(4) 0.071(3) Uani 1 1 d . . . . .
C37 C 0.7407(7) 0.4936(7) 0.7539(3) 0.060(2) Uani 1 1 d . . . . .
H37A H 0.714067 0.414611 0.763885 0.072 Uiso 1 1 calc R U . . .
O11 O 0.7490(5) 0.1598(4) 0.5341(3) 0.0607(14) Uani 1 1 d . . . . .
H11B H 0.757873 0.227727 0.519819 0.073 Uiso 1 1 d R U . . .
H11C H 0.756663 0.170588 0.578999 0.073 Uiso 1 1 d R U . . .
O12 O 0.7364(8) 1.0421(7) 0.7032(4) 0.077(3) Uani 0.666(8) 1 d . . P A 1
H12B H 0.797827 1.009697 0.721422 0.092 Uiso 0.666(8) 1 d R U P A 1
H12C H 0.746547 1.108807 0.727812 0.092 Uiso 0.666(8) 1 d R U P A 1
O12' O 0.7787(19) 1.2434(14) 0.7895(8) 0.080(6) Uani 0.334(8) 1 d . . P A 2
H12D H 0.723802 1.279289 0.809084 0.096 Uiso 0.334(8) 1 d R U P A 2
H12E H 0.765912 1.176559 0.805622 0.096 Uiso 0.334(8) 1 d R U P A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N5 2.146(5) . ?
Ag1 N1 2.146(5) . ?
Ag2 N8 2.181(5) . ?
Ag2 N4 2.181(5) 1_476 ?
Ag2 Ag2 3.1055(13) 2_676 ?
O1 C7 1.229(7) . ?
O2 C8 1.236(7) . ?
O3 C21 1.225(7) . ?
O4 C22 1.226(7) . ?
O5 C29 1.247(9) . ?
O6 C29 1.255(9) . ?
O7 C34 1.237(10) . ?
O8 C34 1.269(10) . ?
O8 H8B 0.8500 . ?
O9 C36 1.309(9) . ?
O10 C36 1.239(10) . ?
N1 C1 1.334(8) . ?
N1 C5 1.336(8) . ?
N2 C7 1.322(7) . ?
N2 C6 1.443(7) . ?
N2 H2A 0.8600 . ?
N3 C8 1.327(8) . ?
N3 C9 1.468(7) . ?
N3 H3A 0.8600 . ?
N4 C13 1.333(8) . ?
N4 C12 1.337(8) . ?
N5 C15 1.343(8) . ?
N5 C19 1.345(8) . ?
N6 C21 1.328(8) . ?
N6 C20 1.452(7) . ?
N6 H6A 0.8600 . ?
N7 C22 1.308(8) . ?
N7 C23 1.460(8) . ?
N7 H7A 0.8600 . ?
N8 C26 1.334(8) . ?
N8 C27 1.344(8) . ?
C1 C2 1.385(8) . ?
C1 H1A 0.9300 . ?
C2 C3 1.387(8) . ?
C2 H2B 0.9300 . ?
C3 C4 1.369(9) . ?
C3 C6 1.507(7) . ?
C4 C5 1.376(8) . ?
C4 H4B 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6B 0.9700 . ?
C6 H6D 0.9700 . ?
C7 C8 1.536(9) . ?
C9 C10 1.496(7) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.372(8) . ?
C10 C14 1.386(8) . ?
C11 C12 1.375(8) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.369(8) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.370(8) . ?
C15 H15A 0.9300 . ?
C16 C17 1.391(8) . ?
C16 H16A 0.9300 . ?
C17 C18 1.375(8) . ?
C17 C20 1.518(7) . ?
C18 C19 1.379(8) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.534(9) . ?
C23 C24 1.494(8) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 C25 1.368(8) . ?
C24 C28 1.386(8) . ?
C25 C26 1.375(8) . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9300 . ?
C27 C28 1.369(8) . ?
C27 H27A 0.9300 . ?
C28 H28A 0.9300 . ?
C29 C30 1.527(9) . ?
C30 C31 1.364(11) . ?
C30 C37 1.371(8) . ?
C31 C32 1.385(10) . ?
C31 H31A 0.9300 . ?
C32 C33 1.377(10) . ?
C32 H32A 0.9300 . ?
C33 C35 1.389(10) . ?
C33 C34 1.527(11) . ?
C35 C37 1.404(9) . ?
C35 C36 1.536(11) . ?
C37 H37A 0.9300 . ?
O11 H11B 0.8501 . ?
O11 H11C 0.8500 . ?
O12 H12B 0.8499 . ?
O12 H12C 0.8500 . ?
O12' H12D 0.8500 . ?
O12' H12E 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Ag1 N1 173.9(2) . . ?
N8 Ag2 N4 168.2(2) . 1_476 ?
N8 Ag2 Ag2 83.41(15) . 2_676 ?
N4 Ag2 Ag2 105.86(14) 1_476 2_676 ?
C34 O8 H8B 108.8 . . ?
C1 N1 C5 117.5(5) . . ?
C1 N1 Ag1 121.8(4) . . ?
C5 N1 Ag1 120.5(4) . . ?
C7 N2 C6 122.4(5) . . ?
C7 N2 H2A 118.8 . . ?
C6 N2 H2A 118.8 . . ?
C8 N3 C9 124.5(5) . . ?
C8 N3 H3A 117.7 . . ?
C9 N3 H3A 117.7 . . ?
C13 N4 C12 116.4(5) . . ?
C13 N4 Ag2 122.9(4) . 1_634 ?
C12 N4 Ag2 120.6(4) . 1_634 ?
C15 N5 C19 116.8(5) . . ?
C15 N5 Ag1 123.4(4) . . ?
C19 N5 Ag1 119.0(4) . . ?
C21 N6 C20 124.3(6) . . ?
C21 N6 H6A 117.8 . . ?
C20 N6 H6A 117.8 . . ?
C22 N7 C23 120.8(5) . . ?
C22 N7 H7A 119.6 . . ?
C23 N7 H7A 119.6 . . ?
C26 N8 C27 115.9(5) . . ?
C26 N8 Ag2 125.4(4) . . ?
C27 N8 Ag2 118.7(4) . . ?
N1 C1 C2 122.5(6) . . ?
N1 C1 H1A 118.7 . . ?
C2 C1 H1A 118.7 . . ?
C1 C2 C3 120.1(6) . . ?
C1 C2 H2B 120.0 . . ?
C3 C2 H2B 120.0 . . ?
C4 C3 C2 116.5(6) . . ?
C4 C3 C6 123.5(6) . . ?
C2 C3 C6 120.1(6) . . ?
C3 C4 C5 120.9(6) . . ?
C3 C4 H4B 119.5 . . ?
C5 C4 H4B 119.5 . . ?
N1 C5 C4 122.5(6) . . ?
N1 C5 H5A 118.7 . . ?
C4 C5 H5A 118.7 . . ?
N2 C6 C3 114.2(5) . . ?
N2 C6 H6B 108.7 . . ?
C3 C6 H6B 108.7 . . ?
N2 C6 H6D 108.7 . . ?
C3 C6 H6D 108.7 . . ?
H6B C6 H6D 107.6 . . ?
O1 C7 N2 123.1(6) . . ?
O1 C7 C8 121.7(6) . . ?
N2 C7 C8 115.2(6) . . ?
O2 C8 N3 126.8(6) . . ?
O2 C8 C7 121.3(6) . . ?
N3 C8 C7 111.9(6) . . ?
N3 C9 C10 114.2(5) . . ?
N3 C9 H9A 108.7 . . ?
C10 C9 H9A 108.7 . . ?
N3 C9 H9B 108.7 . . ?
C10 C9 H9B 108.7 . . ?
H9A C9 H9B 107.6 . . ?
C11 C10 C14 116.3(5) . . ?
C11 C10 C9 123.9(6) . . ?
C14 C10 C9 119.8(6) . . ?
C10 C11 C12 120.6(6) . . ?
C10 C11 H11A 119.7 . . ?
C12 C11 H11A 119.7 . . ?
N4 C12 C11 123.0(6) . . ?
N4 C12 H12A 118.5 . . ?
C11 C12 H12A 118.5 . . ?
N4 C13 C14 123.7(6) . . ?
N4 C13 H13A 118.2 . . ?
C14 C13 H13A 118.2 . . ?
C13 C14 C10 120.0(6) . . ?
C13 C14 H14A 120.0 . . ?
C10 C14 H14A 120.0 . . ?
N5 C15 C16 123.2(6) . . ?
N5 C15 H15A 118.4 . . ?
C16 C15 H15A 118.4 . . ?
C15 C16 C17 119.3(6) . . ?
C15 C16 H16A 120.3 . . ?
C17 C16 H16A 120.3 . . ?
C18 C17 C16 118.1(5) . . ?
C18 C17 C20 122.9(5) . . ?
C16 C17 C20 119.0(5) . . ?
C17 C18 C19 119.1(6) . . ?
C17 C18 H18A 120.5 . . ?
C19 C18 H18A 120.5 . . ?
N5 C19 C18 123.4(6) . . ?
N5 C19 H19A 118.3 . . ?
C18 C19 H19A 118.3 . . ?
N6 C20 C17 114.6(5) . . ?
N6 C20 H20A 108.6 . . ?
C17 C20 H20A 108.6 . . ?
N6 C20 H20B 108.6 . . ?
C17 C20 H20B 108.6 . . ?
H20A C20 H20B 107.6 . . ?
O3 C21 N6 125.1(6) . . ?
O3 C21 C22 121.8(6) . . ?
N6 C21 C22 113.2(6) . . ?
O4 C22 N7 124.2(6) . . ?
O4 C22 C21 120.0(6) . . ?
N7 C22 C21 115.8(6) . . ?
N7 C23 C24 114.9(5) . . ?
N7 C23 H23A 108.6 . . ?
C24 C23 H23A 108.6 . . ?
N7 C23 H23B 108.6 . . ?
C24 C23 H23B 108.6 . . ?
H23A C23 H23B 107.5 . . ?
C25 C24 C28 116.7(6) . . ?
C25 C24 C23 124.4(6) . . ?
C28 C24 C23 118.9(6) . . ?
C24 C25 C26 119.4(6) . . ?
C24 C25 H25A 120.3 . . ?
C26 C25 H25A 120.3 . . ?
N8 C26 C25 124.5(6) . . ?
N8 C26 H26A 117.8 . . ?
C25 C26 H26A 117.8 . . ?
N8 C27 C28 122.8(6) . . ?
N8 C27 H27A 118.6 . . ?
C28 C27 H27A 118.6 . . ?
C27 C28 C24 120.7(6) . . ?
C27 C28 H28A 119.7 . . ?
C24 C28 H28A 119.7 . . ?
O5 C29 O6 126.3(7) . . ?
O5 C29 C30 117.7(7) . . ?
O6 C29 C30 115.9(8) . . ?
C31 C30 C37 117.0(7) . . ?
C31 C30 C29 122.4(7) . . ?
C37 C30 C29 120.6(7) . . ?
C30 C31 C32 120.5(8) . . ?
C30 C31 H31A 119.8 . . ?
C32 C31 H31A 119.8 . . ?
C33 C32 C31 123.5(8) . . ?
C33 C32 H32A 118.2 . . ?
C31 C32 H32A 118.2 . . ?
C32 C33 C35 116.2(7) . . ?
C32 C33 C34 116.4(8) . . ?
C35 C33 C34 127.4(8) . . ?
O7 C34 O8 122.5(9) . . ?
O7 C34 C33 116.7(9) . . ?
O8 C34 C33 120.5(9) . . ?
C33 C35 C37 119.6(7) . . ?
C33 C35 C36 129.5(7) . . ?
C37 C35 C36 110.9(8) . . ?
O10 C36 O9 122.7(8) . . ?
O10 C36 C35 120.1(8) . . ?
O9 C36 C35 117.2(9) . . ?
C30 C37 C35 123.1(8) . . ?
C30 C37 H37A 118.5 . . ?
C35 C37 H37A 118.5 . . ?
H11B O11 H11C 107.3 . . ?
H12B O12 H12C 109.1 . . ?
H12D O12' H12E 107.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.6(10) . . . . ?
Ag1 N1 C1 C2 175.5(5) . . . . ?
N1 C1 C2 C3 -1.1(10) . . . . ?
C1 C2 C3 C4 1.1(10) . . . . ?
C1 C2 C3 C6 -178.3(6) . . . . ?
C2 C3 C4 C5 -0.8(10) . . . . ?
C6 C3 C4 C5 178.6(6) . . . . ?
C1 N1 C5 C4 -0.3(11) . . . . ?
Ag1 N1 C5 C4 -175.2(5) . . . . ?
C3 C4 C5 N1 0.5(11) . . . . ?
C7 N2 C6 C3 92.3(7) . . . . ?
C4 C3 C6 N2 7.1(9) . . . . ?
C2 C3 C6 N2 -173.5(6) . . . . ?
C6 N2 C7 O1 2.1(9) . . . . ?
C6 N2 C7 C8 -176.6(5) . . . . ?
C9 N3 C8 O2 -0.8(10) . . . . ?
C9 N3 C8 C7 -179.7(5) . . . . ?
O1 C7 C8 O2 170.9(6) . . . . ?
N2 C7 C8 O2 -10.4(8) . . . . ?
O1 C7 C8 N3 -10.2(8) . . . . ?
N2 C7 C8 N3 168.5(5) . . . . ?
C8 N3 C9 C10 -100.2(7) . . . . ?
N3 C9 C10 C11 -2.9(9) . . . . ?
N3 C9 C10 C14 176.3(6) . . . . ?
C14 C10 C11 C12 -0.1(10) . . . . ?
C9 C10 C11 C12 179.2(6) . . . . ?
C13 N4 C12 C11 0.0(10) . . . . ?
Ag2 N4 C12 C11 -175.5(5) 1_634 . . . ?
C10 C11 C12 N4 -0.1(11) . . . . ?
C12 N4 C13 C14 0.4(10) . . . . ?
Ag2 N4 C13 C14 175.8(5) 1_634 . . . ?
N4 C13 C14 C10 -0.6(11) . . . . ?
C11 C10 C14 C13 0.4(10) . . . . ?
C9 C10 C14 C13 -178.9(6) . . . . ?
C19 N5 C15 C16 -1.9(10) . . . . ?
Ag1 N5 C15 C16 168.1(5) . . . . ?
N5 C15 C16 C17 -1.1(10) . . . . ?
C15 C16 C17 C18 2.5(9) . . . . ?
C15 C16 C17 C20 -177.2(6) . . . . ?
C16 C17 C18 C19 -1.0(9) . . . . ?
C20 C17 C18 C19 178.7(6) . . . . ?
C15 N5 C19 C18 3.5(10) . . . . ?
Ag1 N5 C19 C18 -166.9(5) . . . . ?
C17 C18 C19 N5 -2.1(10) . . . . ?
C21 N6 C20 C17 -102.7(7) . . . . ?
C18 C17 C20 N6 -10.4(9) . . . . ?
C16 C17 C20 N6 169.3(6) . . . . ?
C20 N6 C21 O3 -0.3(10) . . . . ?
C20 N6 C21 C22 -179.1(5) . . . . ?
C23 N7 C22 O4 -1.4(10) . . . . ?
C23 N7 C22 C21 176.8(5) . . . . ?
O3 C21 C22 O4 167.5(6) . . . . ?
N6 C21 C22 O4 -13.6(9) . . . . ?
O3 C21 C22 N7 -10.8(9) . . . . ?
N6 C21 C22 N7 168.1(5) . . . . ?
C22 N7 C23 C24 93.6(7) . . . . ?
N7 C23 C24 C25 -3.3(9) . . . . ?
N7 C23 C24 C28 177.0(6) . . . . ?
C28 C24 C25 C26 -2.6(10) . . . . ?
C23 C24 C25 C26 177.7(6) . . . . ?
C27 N8 C26 C25 0.3(11) . . . . ?
Ag2 N8 C26 C25 -177.8(5) . . . . ?
C24 C25 C26 N8 0.9(11) . . . . ?
C26 N8 C27 C28 0.4(10) . . . . ?
Ag2 N8 C27 C28 178.6(5) . . . . ?
N8 C27 C28 C24 -2.2(11) . . . . ?
C25 C24 C28 C27 3.2(10) . . . . ?
C23 C24 C28 C27 -177.1(6) . . . . ?
O5 C29 C30 C31 165.7(8) . . . . ?
O6 C29 C30 C31 -15.6(11) . . . . ?
O5 C29 C30 C37 -15.3(11) . . . . ?
O6 C29 C30 C37 163.4(7) . . . . ?
C37 C30 C31 C32 3.9(13) . . . . ?
C29 C30 C31 C32 -177.1(8) . . . . ?
C30 C31 C32 C33 -2.9(15) . . . . ?
C31 C32 C33 C35 -0.1(13) . . . . ?
C31 C32 C33 C34 178.2(8) . . . . ?
C32 C33 C34 O7 9.5(11) . . . . ?
C35 C33 C34 O7 -172.3(8) . . . . ?
C32 C33 C34 O8 -164.4(8) . . . . ?
C35 C33 C34 O8 13.7(12) . . . . ?
C32 C33 C35 C37 1.8(11) . . . . ?
C34 C33 C35 C37 -176.3(7) . . . . ?
C32 C33 C35 C36 179.9(8) . . . . ?
C34 C33 C35 C36 1.8(13) . . . . ?
C33 C35 C36 O10 162.3(9) . . . . ?
C37 C35 C36 O10 -19.4(11) . . . . ?
C33 C35 C36 O9 -15.5(12) . . . . ?
C37 C35 C36 O9 162.7(7) . . . . ?
C31 C30 C37 C35 -2.2(12) . . . . ?
C29 C30 C37 C35 178.8(7) . . . . ?
C33 C35 C37 C30 -0.7(11) . . . . ?
C36 C35 C37 C30 -179.2(7) . . . . ?

_refine_diff_density_max         0.674
_refine_diff_density_min         -0.741
_refine_diff_density_rms         0.098

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 2512231'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H19 Ag N4 O7'
_chemical_formula_weight         583.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.5629(16)
_cell_length_b                   25.199(5)
_cell_length_c                   10.864(2)
_cell_angle_alpha                90
_cell_angle_beta                 93.170(6)
_cell_angle_gamma                90
_cell_volume                     2340.6(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9883
_cell_measurement_theta_min      2.48
_cell_measurement_theta_max      28.08

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.655
_exptl_crystal_F_000             1176
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          1.000
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.915
_shelx_estimated_absorpt_T_min   0.461
_shelx_estimated_absorpt_T_max   0.914
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.6667
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            45242
_diffrn_reflns_av_unetI/netI     0.0493
_diffrn_reflns_av_R_equivalents  0.0805
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.616
_diffrn_reflns_theta_max         25.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4616
_reflns_number_gt                3265
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0256P)²+1.0625P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4616
_refine_ls_number_parameters     325
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0701
_refine_ls_R_factor_gt           0.0367
_refine_ls_wR_factor_ref         0.0699
_refine_ls_wR_factor_gt          0.0618
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_restrained_S_all      1.020
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag -0.75372(3) 0.02652(2) 1.53029(2) 0.03621(9) Uani 1 1 d . . . . .
O1 O -0.3274(3) 0.08248(9) 0.9820(2) 0.0432(6) Uani 1 1 d . . . . .
O2 O -0.2209(3) -0.04971(10) 1.0347(2) 0.0486(7) Uani 1 1 d . . . . .
O3 O -0.8253(2) 0.11190(8) 1.65537(19) 0.0339(5) Uani 1 1 d . . . . .
O4 O -0.6017(2) 0.07644(8) 1.72802(18) 0.0301(5) Uani 1 1 d . . . . .
O5 O -0.6677(3) 0.32915(10) 2.0706(3) 0.0619(8) Uani 1 1 d . . . . .
O6 O -0.4253(3) 0.29990(10) 2.0711(2) 0.0593(8) Uani 1 1 d . . . . .
H6C H -0.399728 0.331287 2.092605 0.071 Uiso 1 1 d R U . . .
O7 O -0.7753(3) 0.42104(9) 2.1796(2) 0.0588(8) Uani 1 1 d . . . . .
H7C H -0.742446 0.391535 2.153373 0.071 Uiso 1 1 d R U . . .
H7D H -0.870626 0.417345 2.195972 0.071 Uiso 1 1 d R U . . .
N1 N -0.6213(3) 0.06805(10) 1.3940(2) 0.0322(6) Uani 1 1 d . . . . .
N2 N -0.3953(3) 0.02685(10) 1.1366(2) 0.0285(6) Uani 1 1 d . . . . .
H2A H -0.391462 -0.005917 1.158733 0.034 Uiso 1 1 calc R U . . .
N3 N -0.1666(3) 0.00558(10) 0.8760(2) 0.0295(6) Uani 1 1 d . . . . .
H3A H -0.185242 0.037124 0.848723 0.035 Uiso 1 1 calc R U . . .
N4 N 0.1034(3) -0.02575(11) 0.6392(2) 0.0305(6) Uani 1 1 d . . . . .
C1 C -0.5455(3) 0.03949(12) 1.3122(3) 0.0255(7) Uani 1 1 d . . . . .
H1A H -0.539849 0.002908 1.322732 0.031 Uiso 1 1 calc R U . . .
C2 C -0.4751(3) 0.06175(12) 1.2123(3) 0.0259(7) Uani 1 1 d . . . . .
C3 C -0.4862(4) 0.11623(14) 1.1960(3) 0.0472(10) Uani 1 1 d . . . . .
H3B H -0.443960 0.132556 1.128593 0.057 Uiso 1 1 calc R U . . .
C4 C -0.5616(5) 0.14570(14) 1.2821(4) 0.0566(11) Uani 1 1 d . . . . .
H4B H -0.568179 0.182385 1.274139 0.068 Uiso 1 1 calc R U . . .
C5 C -0.6269(4) 0.12088(14) 1.3796(3) 0.0468(10) Uani 1 1 d . . . . .
H5A H -0.676327 0.141304 1.437208 0.056 Uiso 1 1 calc R U . . .
C6 C -0.3240(3) 0.03951(12) 1.0328(3) 0.0271(7) Uani 1 1 d . . . . .
C7 C -0.2316(3) -0.00747(13) 0.9817(3) 0.0279(7) Uani 1 1 d . . . . .
C8 C -0.0712(3) -0.02653(13) 0.8044(3) 0.0258(7) Uani 1 1 d . . . . .
C9 C -0.0543(4) -0.08071(13) 0.8175(3) 0.0378(8) Uani 1 1 d . . . . .
H9A H -0.104964 -0.099182 0.877759 0.045 Uiso 1 1 calc R U . . .
C10 C 0.0410(4) -0.10668(13) 0.7377(3) 0.0428(9) Uani 1 1 d . . . . .
H10A H 0.053925 -0.143249 0.743538 0.051 Uiso 1 1 calc R U . . .
C11 C 0.1162(4) -0.07868(14) 0.6502(3) 0.0379(8) Uani 1 1 d . . . . .
H11A H 0.178172 -0.096975 0.596822 0.046 Uiso 1 1 calc R U . . .
C12 C 0.0108(3) -0.00052(13) 0.7151(3) 0.0285(7) Uani 1 1 d . . . . .
H12A H 0.000723 0.036114 0.708069 0.034 Uiso 1 1 calc R U . . .
C13 C -0.7050(3) 0.11168(11) 1.7289(3) 0.0251(7) Uani 1 1 d . . . . .
C14 C -0.6811(3) 0.15751(11) 1.8177(3) 0.0251(7) Uani 1 1 d . . . . .
C15 C -0.5346(4) 0.17877(13) 1.8324(3) 0.0367(8) Uani 1 1 d . . . . .
H15A H -0.453348 0.163093 1.792101 0.044 Uiso 1 1 calc R U . . .
C16 C -0.5031(4) 0.22316(13) 1.9057(3) 0.0393(9) Uani 1 1 d . . . . .
H16A H -0.402508 0.237206 1.910836 0.047 Uiso 1 1 calc R U . . .
C17 C -0.6175(3) 0.24666(12) 1.9706(3) 0.0307(8) Uani 1 1 d . . . . .
C18 C -0.5754(4) 0.29562(13) 2.0437(3) 0.0352(8) Uani 1 1 d . . . . .
C19 C -0.7730(3) 0.22522(12) 1.9630(3) 0.0286(7) Uani 1 1 d . . . . .
C20 C -0.8959(4) 0.24549(14) 2.0320(3) 0.0431(9) Uani 1 1 d . . . . .
H20A H -0.876343 0.274056 2.084834 0.052 Uiso 1 1 calc R U . . .
C21 C -1.0415(4) 0.22395(14) 2.0223(4) 0.0497(10) Uani 1 1 d . . . . .
H21A H -1.120647 0.238315 2.067280 0.060 Uiso 1 1 calc R U . . .
C22 C -1.0736(4) 0.18016(14) 1.9450(3) 0.0421(9) Uani 1 1 d . . . . .
H22A H -1.173612 0.165633 1.939159 0.051 Uiso 1 1 calc R U . . .
C23 C -0.9590(3) 0.15896(12) 1.8786(3) 0.0336(8) Uani 1 1 d . . . . .
H23A H -0.981575 0.129755 1.828357 0.040 Uiso 1 1 calc R U . . .
C24 C -0.8054(3) 0.18050(11) 1.8843(3) 0.0250(7) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N1 2.182(3) . ?
Ag N4 2.189(3) 1_456 ?
O1 C6 1.215(3) . ?
O2 C7 1.212(4) . ?
O3 C13 1.268(3) . ?
O4 C13 1.254(3) . ?
O5 C18 1.204(4) . ?
O6 C18 1.307(4) . ?
O6 H6C 0.8501 . ?
O7 H7C 0.8500 . ?
O7 H7D 0.8499 . ?
N1 C1 1.339(4) . ?
N1 C5 1.341(4) . ?
N2 C6 1.350(4) . ?
N2 C2 1.407(4) . ?
N2 H2A 0.8600 . ?
N3 C7 1.344(4) . ?
N3 C8 1.413(4) . ?
N3 H3A 0.8600 . ?
N4 C12 1.336(4) . ?
N4 C11 1.343(4) . ?
C1 C2 1.388(4) . ?
C1 H1A 0.9300 . ?
C2 C3 1.387(4) . ?
C3 C4 1.383(5) . ?
C3 H3B 0.9300 . ?
C4 C5 1.375(5) . ?
C4 H4B 0.9300 . ?
C5 H5A 0.9300 . ?
C6 C7 1.544(4) . ?
C8 C9 1.379(4) . ?
C8 C12 1.393(4) . ?
C9 C10 1.386(4) . ?
C9 H9A 0.9300 . ?
C10 C11 1.373(4) . ?
C10 H10A 0.9300 . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.511(4) . ?
C14 C15 1.365(4) . ?
C14 C24 1.441(4) . ?
C15 C16 1.391(4) . ?
C15 H15A 0.9300 . ?
C16 C17 1.373(4) . ?
C16 H16A 0.9300 . ?
C17 C19 1.435(4) . ?
C17 C18 1.500(4) . ?
C19 C20 1.420(4) . ?
C19 C24 1.433(4) . ?
C20 C21 1.359(4) . ?
C20 H20A 0.9300 . ?
C21 C22 1.405(5) . ?
C21 H21A 0.9300 . ?
C22 C23 1.359(4) . ?
C22 H22A 0.9300 . ?
C23 C24 1.421(4) . ?
C23 H23A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag N4 169.27(9) . 1_456 ?
C18 O6 H6C 112.0 . . ?
H7C O7 H7D 108.3 . . ?
C1 N1 C5 118.2(3) . . ?
C1 N1 Ag 118.8(2) . . ?
C5 N1 Ag 122.6(2) . . ?
C6 N2 C2 126.7(3) . . ?
C6 N2 H2A 116.7 . . ?
C2 N2 H2A 116.7 . . ?
C7 N3 C8 127.5(3) . . ?
C7 N3 H3A 116.2 . . ?
C8 N3 H3A 116.2 . . ?
C12 N4 C11 117.7(3) . . ?
C12 N4 Ag 114.6(2) . 1_654 ?
C11 N4 Ag 126.9(2) . 1_654 ?
N1 C1 C2 123.3(3) . . ?
N1 C1 H1A 118.4 . . ?
C2 C1 H1A 118.4 . . ?
C3 C2 C1 118.0(3) . . ?
C3 C2 N2 125.2(3) . . ?
C1 C2 N2 116.8(3) . . ?
C4 C3 C2 118.4(3) . . ?
C4 C3 H3B 120.8 . . ?
C2 C3 H3B 120.8 . . ?
C5 C4 C3 120.1(3) . . ?
C5 C4 H4B 119.9 . . ?
C3 C4 H4B 119.9 . . ?
N1 C5 C4 121.9(3) . . ?
N1 C5 H5A 119.1 . . ?
C4 C5 H5A 119.1 . . ?
O1 C6 N2 126.2(3) . . ?
O1 C6 C7 121.3(3) . . ?
N2 C6 C7 112.6(3) . . ?
O2 C7 N3 126.7(3) . . ?
O2 C7 C6 121.9(3) . . ?
N3 C7 C6 111.4(3) . . ?
C9 C8 C12 118.9(3) . . ?
C9 C8 N3 124.8(3) . . ?
C12 C8 N3 116.3(3) . . ?
C8 C9 C10 117.7(3) . . ?
C8 C9 H9A 121.2 . . ?
C10 C9 H9A 121.2 . . ?
C11 C10 C9 120.3(3) . . ?
C11 C10 H10A 119.8 . . ?
C9 C10 H10A 119.8 . . ?
N4 C11 C10 122.2(3) . . ?
N4 C11 H11A 118.9 . . ?
C10 C11 H11A 118.9 . . ?
N4 C12 C8 123.1(3) . . ?
N4 C12 H12A 118.5 . . ?
C8 C12 H12A 118.5 . . ?
O4 C13 O3 123.2(3) . . ?
O4 C13 C14 118.4(3) . . ?
O3 C13 C14 118.4(3) . . ?
C15 C14 C24 118.9(3) . . ?
C15 C14 C13 117.8(3) . . ?
C24 C14 C13 123.3(3) . . ?
C14 C15 C16 122.0(3) . . ?
C14 C15 H15A 119.0 . . ?
C16 C15 H15A 119.0 . . ?
C17 C16 C15 121.3(3) . . ?
C17 C16 H16A 119.3 . . ?
C15 C16 H16A 119.3 . . ?
C16 C17 C19 119.6(3) . . ?
C16 C17 C18 118.0(3) . . ?
C19 C17 C18 122.4(3) . . ?
O5 C18 O6 122.5(3) . . ?
O5 C18 C17 124.3(3) . . ?
O6 C18 C17 113.1(3) . . ?
C20 C19 C24 118.3(3) . . ?
C20 C19 C17 123.1(3) . . ?
C24 C19 C17 118.6(3) . . ?
C21 C20 C19 121.3(3) . . ?
C21 C20 H20A 119.4 . . ?
C19 C20 H20A 119.4 . . ?
C20 C21 C22 120.6(3) . . ?
C20 C21 H21A 119.7 . . ?
C22 C21 H21A 119.7 . . ?
C23 C22 C21 120.2(3) . . ?
C23 C22 H22A 119.9 . . ?
C21 C22 H22A 119.9 . . ?
C22 C23 C24 121.4(3) . . ?
C22 C23 H23A 119.3 . . ?
C24 C23 H23A 119.3 . . ?
C23 C24 C19 118.3(3) . . ?
C23 C24 C14 122.1(3) . . ?
C19 C24 C14 119.5(3) . . ?

_refine_diff_density_max         0.507
_refine_diff_density_min         -0.838
_refine_diff_density_rms         0.078

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_8
_database_code_depnum_ccdc_archive 'CCDC 2512234'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C16 H12 Ag N2 O7'
_chemical_formula_weight         452.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.6861(19)
_cell_length_b                   8.914(2)
_cell_length_c                   11.391(3)
_cell_angle_alpha                84.881(7)
_cell_angle_beta                 70.317(5)
_cell_angle_gamma                70.793(5)
_cell_volume                     784.0(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9970
_cell_measurement_theta_min      2.44
_cell_measurement_theta_max      28.58

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.915
_exptl_crystal_F_000             450
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.800
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.331
_shelx_estimated_absorpt_T_min   0.416
_shelx_estimated_absorpt_T_max   0.777
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.4098
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14352
_diffrn_reflns_av_unetI/netI     0.0362
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.899
_diffrn_reflns_theta_max         28.368
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             3905
_reflns_number_gt                3552
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0353P)²+0.5672P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2019/1 (Sheldrick 2019)'
_refine_ls_extinction_coef       0.0282(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         3905
_refine_ls_number_parameters     236
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0344
_refine_ls_R_factor_gt           0.0305
_refine_ls_wR_factor_ref         0.0792
_refine_ls_wR_factor_gt          0.0767
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_restrained_S_all      1.071
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.50980(2) 0.57615(2) 0.12976(2) 0.03446(9) Uani 1 1 d . . . . .
O1 O 1.3955(2) 0.20728(18) 0.01467(15) 0.0279(3) Uani 1 1 d . . . . .
O2 O 0.2649(2) 0.67500(19) 0.27446(16) 0.0282(3) Uani 1 1 d . . . . .
O3 O 0.2278(3) 0.9154(2) 0.1887(2) 0.0478(6) Uani 1 1 d . . . . .
O4 O -0.5086(2) 1.32396(18) 0.55695(16) 0.0301(4) Uani 1 1 d . . . . .
O5 O -0.2887(2) 1.37141(18) 0.40318(17) 0.0338(4) Uani 1 1 d . . . . .
H5C H -0.358004 1.465898 0.415792 0.041 Uiso 1 1 d R U . . .
O6 O -0.4536(2) 0.7568(2) 0.70305(16) 0.0307(4) Uani 1 1 d . . . . .
O7 O -0.1999(3) 0.5740(2) 0.6094(2) 0.0590(7) Uani 1 1 d . . . . .
H7C H -0.249717 0.508528 0.649525 0.071 Uiso 1 1 d R U . . .
N1 N 0.7659(2) 0.4199(2) 0.02670(19) 0.0264(4) Uani 1 1 d . . . . .
N2 N 1.3872(2) 0.0246(2) -0.10951(17) 0.0240(4) Uani 1 1 d . . . . .
H2A H 1.412681 -0.074969 -0.124761 0.029 Uiso 1 1 calc R U . . .
C1 C 0.8567(3) 0.4667(3) -0.0831(2) 0.0268(4) Uani 1 1 d . . . . .
H1A H 0.804366 0.561202 -0.116206 0.032 Uiso 1 1 calc R U . . .
C2 C 1.0252(3) 0.3793(3) -0.1485(2) 0.0247(4) Uani 1 1 d . . . . .
H2B H 1.083743 0.414955 -0.224170 0.030 Uiso 1 1 calc R U . . .
C3 C 1.1067(3) 0.2371(2) -0.10001(19) 0.0208(4) Uani 1 1 d . . . . .
C4 C 1.2882(3) 0.1410(3) -0.1772(2) 0.0265(4) Uani 1 1 d . . . . .
H4A H 1.280749 0.085705 -0.243694 0.032 Uiso 1 1 calc R U . . .
H4B H 1.351342 0.214136 -0.215824 0.032 Uiso 1 1 calc R U . . .
C5 C 1.4391(3) 0.0690(2) -0.02466(19) 0.0200(4) Uani 1 1 d . . . . .
C6 C 1.0146(3) 0.1893(3) 0.0149(2) 0.0258(4) Uani 1 1 d . . . . .
H6A H 1.065352 0.096927 0.050965 0.031 Uiso 1 1 calc R U . . .
C7 C 0.8452(3) 0.2828(3) 0.0742(2) 0.0278(5) Uani 1 1 d . . . . .
H7A H 0.783554 0.249625 0.149890 0.033 Uiso 1 1 calc R U . . .
C8 C 0.1771(3) 0.8232(2) 0.26765(19) 0.0212(4) Uani 1 1 d . . . . .
C9 C -0.0005(3) 0.8835(2) 0.36556(18) 0.0186(4) Uani 1 1 d . . . . .
C10 C -0.0714(3) 0.7791(2) 0.44877(19) 0.0212(4) Uani 1 1 d . . . . .
H10A H -0.008907 0.671415 0.443940 0.025 Uiso 1 1 calc R U . . .
C11 C -0.2350(3) 0.8347(2) 0.53905(19) 0.0201(4) Uani 1 1 d . . . . .
C12 C -0.3097(3) 0.7201(2) 0.6267(2) 0.0249(4) Uani 1 1 d . . . . .
C13 C -0.3285(3) 0.9972(2) 0.54660(19) 0.0213(4) Uani 1 1 d . . . . .
H13A H -0.437213 1.034959 0.606178 0.026 Uiso 1 1 calc R U . . .
C14 C -0.2589(3) 1.1029(2) 0.46472(19) 0.0191(4) Uani 1 1 d . . . . .
C15 C -0.0954(3) 1.0470(2) 0.37405(18) 0.0192(4) Uani 1 1 d . . . . .
H15A H -0.049694 1.117446 0.319666 0.023 Uiso 1 1 calc R U . . .
C16 C -0.3628(3) 1.2768(2) 0.47868(19) 0.0210(4) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag O2 2.1640(16) . ?
Ag N1 2.1819(19) . ?
Ag O1 2.5840(17) 2_765 ?
O1 C5 1.242(3) . ?
O2 C8 1.301(3) . ?
O3 C8 1.231(3) . ?
O4 C16 1.238(3) . ?
O5 C16 1.311(3) . ?
O5 H5C 0.8499 . ?
O6 C12 1.215(3) . ?
O7 C12 1.322(3) . ?
O7 H7C 0.8500 . ?
N1 C1 1.349(3) . ?
N1 C7 1.357(3) . ?
N2 C5 1.331(3) . ?
N2 C4 1.459(3) . ?
N2 H2A 0.8600 . ?
C1 C2 1.386(3) . ?
C1 H1A 0.9300 . ?
C2 C3 1.401(3) . ?
C2 H2B 0.9300 . ?
C3 C6 1.398(3) . ?
C3 C4 1.518(3) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C5 1.539(4) 2_855 ?
C6 C7 1.393(3) . ?
C6 H6A 0.9300 . ?
C7 H7A 0.9300 . ?
C8 C9 1.521(3) . ?
C9 C10 1.404(3) . ?
C9 C15 1.412(3) . ?
C10 C11 1.402(3) . ?
C10 H10A 0.9300 . ?
C11 C13 1.403(3) . ?
C11 C12 1.510(3) . ?
C13 C14 1.401(3) . ?
C13 H13A 0.9300 . ?
C14 C15 1.403(3) . ?
C14 C16 1.507(3) . ?
C15 H15A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ag N1 162.23(7) . . ?
O2 Ag O1 111.88(6) . 2_765 ?
N1 Ag O1 84.37(7) . 2_765 ?
C5 O1 Ag 121.05(14) . 2_765 ?
C8 O2 Ag 118.27(14) . . ?
C16 O5 H5C 108.9 . . ?
C12 O7 H7C 110.4 . . ?
C1 N1 C7 117.90(19) . . ?
C1 N1 Ag 119.49(15) . . ?
C7 N1 Ag 122.32(16) . . ?
C5 N2 C4 121.54(18) . . ?
C5 N2 H2A 119.2 . . ?
C4 N2 H2A 119.2 . . ?
N1 C1 C2 122.5(2) . . ?
N1 C1 H1A 118.8 . . ?
C2 C1 H1A 118.8 . . ?
C1 C2 C3 119.7(2) . . ?
C1 C2 H2B 120.2 . . ?
C3 C2 H2B 120.2 . . ?
C6 C3 C2 118.18(19) . . ?
C6 C3 C4 123.73(19) . . ?
C2 C3 C4 118.07(19) . . ?
N2 C4 C3 115.77(18) . . ?
N2 C4 H4A 108.3 . . ?
C3 C4 H4A 108.3 . . ?
N2 C4 H4B 108.3 . . ?
C3 C4 H4B 108.3 . . ?
H4A C4 H4B 107.4 . . ?
O1 C5 N2 125.09(19) . . ?
O1 C5 C5 120.9(2) . 2_855 ?
N2 C5 C5 114.0(2) . 2_855 ?
C7 C6 C3 118.7(2) . . ?
C7 C6 H6A 120.6 . . ?
C3 C6 H6A 120.6 . . ?
N1 C7 C6 123.0(2) . . ?
N1 C7 H7A 118.5 . . ?
C6 C7 H7A 118.5 . . ?
O3 C8 O2 124.7(2) . . ?
O3 C8 C9 119.01(19) . . ?
O2 C8 C9 116.26(18) . . ?
C10 C9 C15 119.22(18) . . ?
C10 C9 C8 120.99(18) . . ?
C15 C9 C8 119.79(18) . . ?
C11 C10 C9 120.97(18) . . ?
C11 C10 H10A 119.5 . . ?
C9 C10 H10A 119.5 . . ?
C10 C11 C13 119.42(19) . . ?
C10 C11 C12 120.12(18) . . ?
C13 C11 C12 120.46(18) . . ?
O6 C12 O7 123.9(2) . . ?
O6 C12 C11 124.39(19) . . ?
O7 C12 C11 111.69(19) . . ?
C14 C13 C11 120.22(19) . . ?
C14 C13 H13A 119.9 . . ?
C11 C13 H13A 119.9 . . ?
C13 C14 C15 120.30(18) . . ?
C13 C14 C16 118.13(18) . . ?
C15 C14 C16 121.56(18) . . ?
C14 C15 C9 119.87(18) . . ?
C14 C15 H15A 120.1 . . ?
C9 C15 H15A 120.1 . . ?
O4 C16 O5 123.48(18) . . ?
O4 C16 C14 120.85(19) . . ?
O5 C16 C14 115.67(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C1 C2 0.8(3) . . . . ?
Ag N1 C1 C2 174.73(17) . . . . ?
N1 C1 C2 C3 -0.3(3) . . . . ?
C1 C2 C3 C6 -0.9(3) . . . . ?
C1 C2 C3 C4 177.2(2) . . . . ?
C5 N2 C4 C3 -67.8(3) . . . . ?
C6 C3 C4 N2 -20.8(3) . . . . ?
C2 C3 C4 N2 161.3(2) . . . . ?
Ag O1 C5 N2 -66.6(3) 2_765 . . . ?
Ag O1 C5 C5 114.0(2) 2_765 . . 2_855 ?
C4 N2 C5 O1 7.9(3) . . . . ?
C4 N2 C5 C5 -172.6(2) . . . 2_855 ?
C2 C3 C6 C7 1.5(3) . . . . ?
C4 C3 C6 C7 -176.4(2) . . . . ?
C1 N1 C7 C6 0.0(3) . . . . ?
Ag N1 C7 C6 -173.81(18) . . . . ?
C3 C6 C7 N1 -1.1(4) . . . . ?
Ag O2 C8 O3 -4.7(3) . . . . ?
Ag O2 C8 C9 175.25(13) . . . . ?
O3 C8 C9 C10 173.0(2) . . . . ?
O2 C8 C9 C10 -7.0(3) . . . . ?
O3 C8 C9 C15 -7.5(3) . . . . ?
O2 C8 C9 C15 172.46(19) . . . . ?
C15 C9 C10 C11 0.5(3) . . . . ?
C8 C9 C10 C11 179.95(19) . . . . ?
C9 C10 C11 C13 -0.3(3) . . . . ?
C9 C10 C11 C12 179.34(19) . . . . ?
C10 C11 C12 O6 -176.0(2) . . . . ?
C13 C11 C12 O6 3.7(3) . . . . ?
C10 C11 C12 O7 3.3(3) . . . . ?
C13 C11 C12 O7 -177.0(2) . . . . ?
C10 C11 C13 C14 -0.1(3) . . . . ?
C12 C11 C13 C14 -179.8(2) . . . . ?
C11 C13 C14 C15 0.4(3) . . . . ?
C11 C13 C14 C16 -178.59(19) . . . . ?
C13 C14 C15 C9 -0.2(3) . . . . ?
C16 C14 C15 C9 178.71(18) . . . . ?
C10 C9 C15 C14 -0.2(3) . . . . ?
C8 C9 C15 C14 -179.68(18) . . . . ?
C13 C14 C16 O4 -2.9(3) . . . . ?
C15 C14 C16 O4 178.2(2) . . . . ?
C13 C14 C16 O5 177.26(19) . . . . ?
C15 C14 C16 O5 -1.7(3) . . . . ?

_refine_diff_density_max         0.764
_refine_diff_density_min         -0.638
_refine_diff_density_rms         0.097

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_7
_database_code_depnum_ccdc_archive 'CCDC 2512233'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H31 Ag2 N6 O12'
_chemical_formula_weight         883.35

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.8579(15)
_cell_length_b                   12.1551(15)
_cell_length_c                   13.0789(16)
_cell_angle_alpha                78.820(4)
_cell_angle_beta                 85.334(5)
_cell_angle_gamma                78.078(5)
_cell_volume                     1655.3(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9913
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      28.23

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.772
_exptl_crystal_F_000             886
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.256
_shelx_estimated_absorpt_T_min   0.704
_shelx_estimated_absorpt_T_max   0.787
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.5626
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            25318
_diffrn_reflns_av_unetI/netI     0.0609
_diffrn_reflns_av_R_equivalents  0.0708
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.589
_diffrn_reflns_theta_max         25.999
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6483
_reflns_number_gt                4381
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0376P)²+8.4310P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6483
_refine_ls_number_parameters     451
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0974
_refine_ls_R_factor_gt           0.0591
_refine_ls_wR_factor_ref         0.1446
_refine_ls_wR_factor_gt          0.1201
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.12980(5) 0.35610(6) 0.39233(4) 0.0550(2) Uani 1 1 d . . . . .
Ag2 Ag 0.72867(5) 0.51874(5) 0.78583(4) 0.04883(18) Uani 1 1 d . . . . .
O1 O -0.3538(5) 0.3891(4) -0.0363(4) 0.0574(14) Uani 1 1 d . . . . .
O2 O -0.4504(5) 0.1326(4) 0.0613(4) 0.0515(12) Uani 1 1 d . . . . .
O3 O 1.0937(5) 0.8741(4) 0.9704(4) 0.0604(14) Uani 1 1 d . . . . .
O4 O 0.3132(4) 0.3140(5) 0.4613(3) 0.0535(13) Uani 1 1 d . . . . .
O5 O 0.4059(4) 0.2726(4) 0.3113(3) 0.0488(12) Uani 1 1 d . . . . .
O6 O 0.8583(4) 0.0585(4) 0.3397(4) 0.0529(13) Uani 1 1 d . . . . .
O7 O 0.9767(4) 0.1231(4) 0.4371(3) 0.0420(11) Uani 1 1 d . . . . .
H7C H 1.035875 0.080055 0.408685 0.050 Uiso 1 1 d R U . . .
O8 O 0.7919(4) 0.3999(5) 0.6638(4) 0.0563(13) Uani 1 1 d . . . . .
O9 O 0.5902(5) 0.4139(4) 0.7069(4) 0.0548(13) Uani 1 1 d . . . . .
O10 O 0.0337(5) 0.3525(5) 0.5758(4) 0.0714(16) Uani 1 1 d . . . . .
H10A H -0.044233 0.382783 0.576104 0.086 Uiso 1 1 d R U . . .
H10C H 0.047517 0.282713 0.605614 0.086 Uiso 1 1 d R U . . .
O11 O 0.2623(6) 0.2363(5) 0.6719(4) 0.0812(18) Uani 1 1 d . . . . .
H11C H 0.286517 0.261691 0.609941 0.097 Uiso 1 1 d R U . . .
H11D H 0.288407 0.164301 0.684452 0.097 Uiso 1 1 d R U . . .
O12 O 0.7105(5) -0.0077(4) 0.2140(4) 0.0598(14) Uani 1 1 d . . . . .
H12C H 0.665931 0.028221 0.162967 0.072 Uiso 1 1 d R U . . .
H12D H 0.724471 0.041211 0.247877 0.072 Uiso 1 1 d R U . . .
N1 N -0.0414(5) 0.3857(5) 0.3072(4) 0.0397(13) Uani 1 1 d . . . . .
N2 N -0.4169(4) 0.3257(4) 0.1285(4) 0.0349(12) Uani 1 1 d . . . . .
H2A H -0.443801 0.270935 0.170215 0.042 Uiso 1 1 calc R U . . .
N3 N -0.4468(5) 0.2310(4) -0.1055(4) 0.0365(12) Uani 1 1 d . . . . .
H3A H -0.435868 0.294764 -0.143349 0.044 Uiso 1 1 calc R U . . .
N4 N -0.1652(5) -0.0220(4) -0.3305(4) 0.0415(13) Uani 1 1 d . . . . .
N5 N 0.7681(5) 0.6154(4) 0.9003(4) 0.0363(12) Uani 1 1 d . . . . .
N6 N 0.9221(6) 0.8968(5) 1.0798(4) 0.0496(15) Uani 1 1 d . . . . .
H6A H 0.864185 0.945450 1.104790 0.060 Uiso 1 1 calc R U . . .
C1 C -0.1426(6) 0.4588(6) 0.3337(5) 0.0434(16) Uani 1 1 d . . . . .
H1A H -0.136213 0.502869 0.383058 0.052 Uiso 1 1 calc R U . . .
C2 C -0.2567(6) 0.4707(6) 0.2897(5) 0.0405(15) Uani 1 1 d . . . . .
H2B H -0.325361 0.523732 0.308421 0.049 Uiso 1 1 calc R U . . .
C3 C -0.2704(5) 0.4047(5) 0.2179(5) 0.0314(13) Uani 1 1 d . . . . .
C4 C -0.1653(5) 0.3284(5) 0.1912(5) 0.0340(14) Uani 1 1 d . . . . .
H4B H -0.169674 0.282157 0.143175 0.041 Uiso 1 1 calc R U . . .
C5 C -0.0530(6) 0.3223(5) 0.2375(5) 0.0383(15) Uani 1 1 d . . . . .
H5A H 0.017831 0.271381 0.218809 0.046 Uiso 1 1 calc R U . . .
C6 C -0.3959(6) 0.4217(6) 0.1702(5) 0.0414(16) Uani 1 1 d . . . . .
H6B H -0.461853 0.438462 0.222741 0.050 Uiso 1 1 calc R U . . .
H6C H -0.403599 0.487961 0.114478 0.050 Uiso 1 1 calc R U . . .
C7 C -0.3963(6) 0.3186(5) 0.0287(5) 0.0353(14) Uani 1 1 d . . . . .
C8 C -0.4357(6) 0.2164(5) -0.0032(5) 0.0358(14) Uani 1 1 d . . . . .
C9 C -0.4764(6) 0.1445(6) -0.1562(5) 0.0418(16) Uani 1 1 d . . . . .
H9A H -0.543768 0.179570 -0.203436 0.050 Uiso 1 1 calc R U . . .
H9B H -0.506823 0.087015 -0.103800 0.050 Uiso 1 1 calc R U . . .
C10 C -0.3658(6) 0.0870(5) -0.2165(5) 0.0350(14) Uani 1 1 d . . . . .
C11 C -0.2427(6) 0.0956(6) -0.2045(5) 0.0435(16) Uani 1 1 d . . . . .
H11A H -0.224910 0.138772 -0.158165 0.052 Uiso 1 1 calc R U . . .
C12 C -0.1468(6) 0.0391(6) -0.2623(5) 0.0464(17) Uani 1 1 d . . . . .
H12A H -0.064522 0.044489 -0.252449 0.056 Uiso 1 1 calc R U . . .
C13 C -0.2835(6) -0.0297(6) -0.3428(5) 0.0448(16) Uani 1 1 d . . . . .
H13A H -0.298089 -0.072331 -0.390830 0.054 Uiso 1 1 calc R U . . .
C14 C -0.3851(6) 0.0223(6) -0.2880(5) 0.0444(16) Uani 1 1 d . . . . .
H14A H -0.466141 0.014073 -0.298673 0.053 Uiso 1 1 calc R U . . .
C15 C 0.7485(6) 0.7285(5) 0.8882(5) 0.0390(15) Uani 1 1 d . . . . .
H15A H 0.702319 0.771671 0.832270 0.047 Uiso 1 1 calc R U . . .
C16 C 0.7936(6) 0.7857(6) 0.9551(5) 0.0406(15) Uani 1 1 d . . . . .
H16A H 0.776575 0.865174 0.944075 0.049 Uiso 1 1 calc R U . . .
C17 C 0.8633(6) 0.7239(5) 1.0375(5) 0.0370(14) Uani 1 1 d . . . . .
C18 C 0.8798(7) 0.6071(6) 1.0526(5) 0.0443(16) Uani 1 1 d . . . . .
H18A H 0.923757 0.562236 1.109114 0.053 Uiso 1 1 calc R U . . .
C19 C 0.8310(6) 0.5565(6) 0.9840(5) 0.0435(16) Uani 1 1 d . . . . .
H19A H 0.842354 0.477182 0.996344 0.052 Uiso 1 1 calc R U . . .
C20 C 0.9228(8) 0.7764(6) 1.1127(5) 0.0502(18) Uani 1 1 d . . . . .
H20A H 0.878217 0.764920 1.180108 0.060 Uiso 1 1 calc R U . . .
H20B H 1.009295 0.736142 1.121773 0.060 Uiso 1 1 calc R U . . .
C21 C 1.0080(6) 0.9345(6) 1.0122(5) 0.0418(16) Uani 1 1 d . . . . .
C22 C 0.4090(6) 0.2857(5) 0.4018(5) 0.0366(14) Uani 1 1 d . . . . .
C23 C 0.5348(5) 0.2696(5) 0.4496(4) 0.0323(13) Uani 1 1 d . . . . .
C24 C 0.6389(6) 0.2006(5) 0.4115(5) 0.0351(14) Uani 1 1 d . . . . .
H24A H 0.629332 0.160542 0.359802 0.042 Uiso 1 1 calc R U . . .
C25 C 0.7579(5) 0.1902(5) 0.4490(4) 0.0293(12) Uani 1 1 d . . . . .
C26 C 0.8685(5) 0.1161(5) 0.4028(5) 0.0343(14) Uani 1 1 d . . . . .
C27 C 0.7733(5) 0.2498(5) 0.5254(4) 0.0298(13) Uani 1 1 d . . . . .
H27A H 0.853182 0.244229 0.549229 0.036 Uiso 1 1 calc R U . . .
C28 C 0.6698(5) 0.3181(5) 0.5667(4) 0.0296(13) Uani 1 1 d . . . . .
C29 C 0.6836(6) 0.3825(5) 0.6515(5) 0.0356(14) Uani 1 1 d . . . . .
C30 C 0.5507(5) 0.3257(5) 0.5294(5) 0.0337(14) Uani 1 1 d . . . . .
H30A H 0.480735 0.369168 0.558411 0.040 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.174(5) . ?
Ag1 O4 2.175(4) . ?
Ag1 O10 2.534(5) . ?
Ag1 Ag2 3.0189(8) 2_666 ?
Ag2 N5 2.191(5) . ?
Ag2 O8 2.326(5) . ?
Ag2 O9 2.550(5) . ?
O1 C7 1.219(7) . ?
O2 C8 1.219(7) . ?
O3 C21 1.223(8) . ?
O4 C22 1.277(7) . ?
O5 C22 1.228(7) . ?
O6 C26 1.205(7) . ?
O7 C26 1.316(7) . ?
O7 H7C 0.8499 . ?
O8 C29 1.266(8) . ?
O9 C29 1.236(7) . ?
O10 H10A 0.8501 . ?
O10 H10C 0.8500 . ?
O11 H11C 0.8500 . ?
O11 H11D 0.8500 . ?
O12 H12C 0.8499 . ?
O12 H12D 0.8500 . ?
N1 C5 1.332(8) . ?
N1 C1 1.332(8) . ?
N2 C7 1.322(7) . ?
N2 C6 1.445(8) . ?
N2 H2A 0.8600 . ?
N3 C8 1.327(8) . ?
N3 C9 1.446(8) . ?
N3 H3A 0.8600 . ?
N4 C12 1.318(8) . ?
N4 C13 1.332(8) . ?
N5 C15 1.326(8) . ?
N5 C19 1.339(8) . ?
N6 C21 1.322(8) . ?
N6 C20 1.442(9) . ?
N6 H6A 0.8600 . ?
C1 C2 1.377(9) . ?
C1 H1A 0.9300 . ?
C2 C3 1.382(8) . ?
C2 H2B 0.9300 . ?
C3 C4 1.382(8) . ?
C3 C6 1.504(8) . ?
C4 C5 1.387(8) . ?
C4 H4B 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6B 0.9700 . ?
C6 H6C 0.9700 . ?
C7 C8 1.534(9) . ?
C9 C10 1.505(8) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.385(9) . ?
C10 C14 1.386(9) . ?
C11 C12 1.379(9) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.375(9) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.391(9) . ?
C15 H15A 0.9300 . ?
C16 C17 1.372(9) . ?
C16 H16A 0.9300 . ?
C17 C18 1.371(9) . ?
C17 C20 1.519(9) . ?
C18 C19 1.375(9) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C21 1.538(13) 2_777 ?
C22 C23 1.508(8) . ?
C23 C24 1.381(8) . ?
C23 C30 1.393(8) . ?
C24 C25 1.392(8) . ?
C24 H24A 0.9300 . ?
C25 C27 1.382(8) . ?
C25 C26 1.504(8) . ?
C27 C28 1.391(8) . ?
C27 H27A 0.9300 . ?
C28 C30 1.398(8) . ?
C28 C29 1.509(8) . ?
C30 H30A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 O4 172.3(2) . . ?
N1 Ag1 O10 99.40(18) . . ?
O4 Ag1 O10 87.21(17) . . ?
N1 Ag1 Ag2 94.05(14) . 2_666 ?
O4 Ag1 Ag2 82.33(13) . 2_666 ?
O10 Ag1 Ag2 146.49(14) . 2_666 ?
N5 Ag2 O8 152.20(18) . . ?
N5 Ag2 O9 153.22(17) . . ?
O8 Ag2 O9 53.34(15) . . ?
N5 Ag2 Ag1 94.49(13) . 2_666 ?
O8 Ag2 Ag1 71.86(14) . 2_666 ?
O9 Ag2 Ag1 107.34(12) . 2_666 ?
C22 O4 Ag1 117.0(4) . . ?
C26 O7 H7C 109.0 . . ?
C29 O8 Ag2 96.5(4) . . ?
C29 O9 Ag2 86.7(4) . . ?
Ag1 O10 H10A 112.1 . . ?
Ag1 O10 H10C 106.0 . . ?
H10A O10 H10C 112.6 . . ?
H11C O11 H11D 108.2 . . ?
H12C O12 H12D 107.8 . . ?
C5 N1 C1 118.3(5) . . ?
C5 N1 Ag1 121.5(4) . . ?
C1 N1 Ag1 119.7(4) . . ?
C7 N2 C6 122.6(5) . . ?
C7 N2 H2A 118.7 . . ?
C6 N2 H2A 118.7 . . ?
C8 N3 C9 123.0(6) . . ?
C8 N3 H3A 118.5 . . ?
C9 N3 H3A 118.5 . . ?
C12 N4 C13 117.3(5) . . ?
C15 N5 C19 116.4(5) . . ?
C15 N5 Ag2 125.5(4) . . ?
C19 N5 Ag2 117.5(4) . . ?
C21 N6 C20 121.8(6) . . ?
C21 N6 H6A 119.1 . . ?
C20 N6 H6A 119.1 . . ?
N1 C1 C2 121.5(6) . . ?
N1 C1 H1A 119.3 . . ?
C2 C1 H1A 119.3 . . ?
C1 C2 C3 120.8(6) . . ?
C1 C2 H2B 119.6 . . ?
C3 C2 H2B 119.6 . . ?
C2 C3 C4 117.5(5) . . ?
C2 C3 C6 119.2(5) . . ?
C4 C3 C6 123.3(5) . . ?
C3 C4 C5 118.5(6) . . ?
C3 C4 H4B 120.7 . . ?
C5 C4 H4B 120.7 . . ?
N1 C5 C4 123.3(6) . . ?
N1 C5 H5A 118.3 . . ?
C4 C5 H5A 118.3 . . ?
N2 C6 C3 115.0(5) . . ?
N2 C6 H6B 108.5 . . ?
C3 C6 H6B 108.5 . . ?
N2 C6 H6C 108.5 . . ?
C3 C6 H6C 108.5 . . ?
H6B C6 H6C 107.5 . . ?
O1 C7 N2 124.1(6) . . ?
O1 C7 C8 120.6(6) . . ?
N2 C7 C8 115.2(5) . . ?
O2 C8 N3 126.8(6) . . ?
O2 C8 C7 121.2(6) . . ?
N3 C8 C7 112.0(5) . . ?
N3 C9 C10 113.4(5) . . ?
N3 C9 H9A 108.9 . . ?
C10 C9 H9A 108.9 . . ?
N3 C9 H9B 108.9 . . ?
C10 C9 H9B 108.9 . . ?
H9A C9 H9B 107.7 . . ?
C11 C10 C14 117.2(6) . . ?
C11 C10 C9 122.9(6) . . ?
C14 C10 C9 119.8(6) . . ?
C12 C11 C10 119.1(6) . . ?
C12 C11 H11A 120.4 . . ?
C10 C11 H11A 120.4 . . ?
N4 C12 C11 123.7(6) . . ?
N4 C12 H12A 118.1 . . ?
C11 C12 H12A 118.1 . . ?
N4 C13 C14 123.3(6) . . ?
N4 C13 H13A 118.4 . . ?
C14 C13 H13A 118.4 . . ?
C13 C14 C10 119.4(6) . . ?
C13 C14 H14A 120.3 . . ?
C10 C14 H14A 120.3 . . ?
N5 C15 C16 123.3(6) . . ?
N5 C15 H15A 118.4 . . ?
C16 C15 H15A 118.4 . . ?
C17 C16 C15 119.5(6) . . ?
C17 C16 H16A 120.3 . . ?
C15 C16 H16A 120.3 . . ?
C18 C17 C16 117.4(6) . . ?
C18 C17 C20 118.2(6) . . ?
C16 C17 C20 124.4(6) . . ?
C17 C18 C19 119.8(6) . . ?
C17 C18 H18A 120.1 . . ?
C19 C18 H18A 120.1 . . ?
N5 C19 C18 123.5(6) . . ?
N5 C19 H19A 118.3 . . ?
C18 C19 H19A 118.3 . . ?
N6 C20 C17 114.3(6) . . ?
N6 C20 H20A 108.7 . . ?
C17 C20 H20A 108.7 . . ?
N6 C20 H20B 108.7 . . ?
C17 C20 H20B 108.7 . . ?
H20A C20 H20B 107.6 . . ?
O3 C21 N6 125.2(7) . . ?
O3 C21 C21 120.8(8) . 2_777 ?
N6 C21 C21 114.0(7) . 2_777 ?
O5 C22 O4 125.6(6) . . ?
O5 C22 C23 119.3(5) . . ?
O4 C22 C23 115.1(5) . . ?
C24 C23 C30 118.4(5) . . ?
C24 C23 C22 119.7(5) . . ?
C30 C23 C22 121.9(5) . . ?
C23 C24 C25 121.1(5) . . ?
C23 C24 H24A 119.4 . . ?
C25 C24 H24A 119.4 . . ?
C27 C25 C24 119.9(5) . . ?
C27 C25 C26 121.2(5) . . ?
C24 C25 C26 118.9(5) . . ?
O6 C26 O7 124.1(5) . . ?
O6 C26 C25 123.2(5) . . ?
O7 C26 C25 112.7(5) . . ?
C25 C27 C28 120.2(5) . . ?
C25 C27 H27A 119.9 . . ?
C28 C27 H27A 119.9 . . ?
C27 C28 C30 119.0(5) . . ?
C27 C28 C29 121.3(5) . . ?
C30 C28 C29 119.7(5) . . ?
O9 C29 O8 122.8(6) . . ?
O9 C29 C28 119.1(6) . . ?
O8 C29 C28 118.0(5) . . ?
C23 C30 C28 121.3(5) . . ?
C23 C30 H30A 119.4 . . ?
C28 C30 H30A 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 -0.9(10) . . . . ?
Ag1 N1 C1 C2 -172.8(5) . . . . ?
N1 C1 C2 C3 1.5(11) . . . . ?
C1 C2 C3 C4 -1.1(10) . . . . ?
C1 C2 C3 C6 -178.9(6) . . . . ?
C2 C3 C4 C5 0.1(9) . . . . ?
C6 C3 C4 C5 177.8(6) . . . . ?
C1 N1 C5 C4 -0.2(9) . . . . ?
Ag1 N1 C5 C4 171.6(5) . . . . ?
C3 C4 C5 N1 0.6(10) . . . . ?
C7 N2 C6 C3 -96.2(7) . . . . ?
C2 C3 C6 N2 -158.0(6) . . . . ?
C4 C3 C6 N2 24.3(9) . . . . ?
C6 N2 C7 O1 2.8(9) . . . . ?
C6 N2 C7 C8 -174.4(5) . . . . ?
C9 N3 C8 O2 -1.4(10) . . . . ?
C9 N3 C8 C7 176.6(5) . . . . ?
O1 C7 C8 O2 162.8(6) . . . . ?
N2 C7 C8 O2 -19.9(8) . . . . ?
O1 C7 C8 N3 -15.3(8) . . . . ?
N2 C7 C8 N3 162.0(5) . . . . ?
C8 N3 C9 C10 -106.9(7) . . . . ?
N3 C9 C10 C11 14.7(9) . . . . ?
N3 C9 C10 C14 -165.2(6) . . . . ?
C14 C10 C11 C12 -0.7(10) . . . . ?
C9 C10 C11 C12 179.4(6) . . . . ?
C13 N4 C12 C11 -0.6(10) . . . . ?
C10 C11 C12 N4 1.1(11) . . . . ?
C12 N4 C13 C14 -0.2(10) . . . . ?
N4 C13 C14 C10 0.5(11) . . . . ?
C11 C10 C14 C13 0.0(10) . . . . ?
C9 C10 C14 C13 179.9(6) . . . . ?
C19 N5 C15 C16 2.4(9) . . . . ?
Ag2 N5 C15 C16 -169.2(5) . . . . ?
N5 C15 C16 C17 0.8(10) . . . . ?
C15 C16 C17 C18 -3.2(10) . . . . ?
C15 C16 C17 C20 176.9(6) . . . . ?
C16 C17 C18 C19 2.4(10) . . . . ?
C20 C17 C18 C19 -177.7(6) . . . . ?
C15 N5 C19 C18 -3.2(10) . . . . ?
Ag2 N5 C19 C18 169.0(5) . . . . ?
C17 C18 C19 N5 0.9(11) . . . . ?
C21 N6 C20 C17 -81.9(8) . . . . ?
C18 C17 C20 N6 168.5(6) . . . . ?
C16 C17 C20 N6 -11.6(10) . . . . ?
C20 N6 C21 O3 1.0(11) . . . . ?
C20 N6 C21 C21 -179.4(6) . . . 2_777 ?
Ag1 O4 C22 O5 -5.3(9) . . . . ?
Ag1 O4 C22 C23 173.7(4) . . . . ?
O5 C22 C23 C24 -24.9(9) . . . . ?
O4 C22 C23 C24 156.0(6) . . . . ?
O5 C22 C23 C30 152.8(6) . . . . ?
O4 C22 C23 C30 -26.3(9) . . . . ?
C30 C23 C24 C25 -2.2(9) . . . . ?
C22 C23 C24 C25 175.6(5) . . . . ?
C23 C24 C25 C27 -0.3(9) . . . . ?
C23 C24 C25 C26 -178.5(6) . . . . ?
C27 C25 C26 O6 176.3(6) . . . . ?
C24 C25 C26 O6 -5.5(9) . . . . ?
C27 C25 C26 O7 -5.0(8) . . . . ?
C24 C25 C26 O7 173.2(5) . . . . ?
C24 C25 C27 C28 1.6(9) . . . . ?
C26 C25 C27 C28 179.8(5) . . . . ?
C25 C27 C28 C30 -0.3(9) . . . . ?
C25 C27 C28 C29 178.9(5) . . . . ?
Ag2 O9 C29 O8 7.7(6) . . . . ?
Ag2 O9 C29 C28 -173.7(5) . . . . ?
Ag2 O8 C29 O9 -8.5(7) . . . . ?
Ag2 O8 C29 C28 172.9(4) . . . . ?
C27 C28 C29 O9 -158.9(6) . . . . ?
C30 C28 C29 O9 20.3(9) . . . . ?
C27 C28 C29 O8 19.7(9) . . . . ?
C30 C28 C29 O8 -161.1(6) . . . . ?
C24 C23 C30 C28 3.4(9) . . . . ?
C22 C23 C30 C28 -174.3(6) . . . . ?
C27 C28 C30 C23 -2.2(9) . . . . ?
C29 C28 C30 C23 178.5(6) . . . . ?

_refine_diff_density_max         1.249
_refine_diff_density_min         -1.007
_refine_diff_density_rms         0.122

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_9
_database_code_depnum_ccdc_archive 'CCDC 2512235'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C46 H45 Ag5 N8 O21'
_chemical_formula_weight         1585.25

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.627(6)
_cell_length_b                   10.094(7)
_cell_length_c                   31.171(18)
_cell_angle_alpha                85.529(16)
_cell_angle_beta                 85.355(17)
_cell_angle_gamma                63.937(16)
_cell_volume                     2709(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9469
_cell_measurement_theta_min      2.28
_cell_measurement_theta_max      28.47

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.943
_exptl_crystal_F_000             1560
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.860
_shelx_estimated_absorpt_T_min   0.605
_shelx_estimated_absorpt_T_max   0.707
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.5783
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            58955
_diffrn_reflns_av_unetI/netI     0.0196
_diffrn_reflns_av_R_equivalents  0.0249
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_theta_min         1.312
_diffrn_reflns_theta_max         28.225
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             13236
_reflns_number_gt                11427
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0428P)²+4.4862P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         13236
_refine_ls_number_parameters     752
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0432
_refine_ls_R_factor_gt           0.0364
_refine_ls_wR_factor_ref         0.0984
_refine_ls_wR_factor_gt          0.0949
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -2.09164(3) 2.05584(4) 0.69745(2) 0.04875(8) Uani 1 1 d . . . . .
Ag2 Ag -0.97998(3) 1.28173(4) 0.25846(2) 0.05870(10) Uani 1 1 d . . . . .
Ag3 Ag -0.500000 1.000000 0.000000 0.04141(9) Uani 1 2 d S . P . .
Ag4 Ag 0.24080(3) 0.93590(3) 0.21765(2) 0.04394(8) Uani 1 1 d . . . . .
Ag5 Ag 1.32654(3) 0.61139(4) 0.22085(2) 0.05344(9) Uani 1 1 d . . . . .
Ag6 Ag 3.000000 -0.500000 0.000000 0.05262(11) Uani 1 2 d S . P . .
O1 O -1.6851(4) 1.9035(3) 0.43899(10) 0.0609(8) Uani 1 1 d . . . . .
O2 O -1.5962(5) 1.5256(4) 0.45770(10) 0.0713(10) Uani 1 1 d . . . . .
O3 O 2.0857(4) 0.2200(3) 0.03783(9) 0.0580(8) Uani 1 1 d . . . . .
O4 O 2.1455(4) -0.1189(3) 0.09208(10) 0.0686(10) Uani 1 1 d . . . . .
O5 O -0.7884(3) 1.2026(3) 0.21226(8) 0.0436(6) Uani 1 1 d . . . . .
O6 O -0.6665(4) 1.2700(4) 0.25836(10) 0.0717(10) Uani 1 1 d . . . . .
O7 O -0.5113(3) 1.0176(3) 0.06988(7) 0.0416(5) Uani 1 1 d . . . . .
O8 O -0.2574(3) 0.9534(3) 0.06071(7) 0.0520(7) Uani 1 1 d . . . . .
O9 O 0.0321(3) 0.9726(3) 0.18599(7) 0.0449(6) Uani 1 1 d . . . . .
O10 O -0.0943(3) 1.0252(3) 0.25105(7) 0.0426(6) Uani 1 1 d . . . . .
O11 O 0.4465(3) 0.8488(3) 0.25475(8) 0.0442(6) Uani 1 1 d . . . . .
O12 O 0.3394(3) 0.8874(3) 0.32244(8) 0.0439(6) Uani 1 1 d . . . . .
O13 O 1.0116(3) 0.6405(4) 0.22487(9) 0.0626(9) Uani 1 1 d . . . . .
O14 O 1.1512(2) 0.6725(3) 0.27397(8) 0.0407(5) Uani 1 1 d . . . . .
O15 O 0.9589(4) 0.6792(5) 0.42642(10) 0.0854(12) Uani 1 1 d . . . . .
H15C H 0.970802 0.664915 0.453385 0.102 Uiso 1 1 d R U . . .
O16 O 0.730(3) 0.681(6) 0.4434(3) 0.082(8) Uani 0.61(8) 1 d . . P A 1
O16' O 0.7019(19) 0.766(6) 0.4446(4) 0.064(8) Uani 0.39(8) 1 d . . P A 2
N1 N -1.9180(3) 1.9717(3) 0.63869(9) 0.0406(6) Uani 1 1 d . . . . .
N2 N -1.6017(4) 1.7528(4) 0.50021(10) 0.0530(8) Uani 1 1 d . . . . .
H2A H -1.580427 1.665702 0.511300 0.064 Uiso 1 1 calc R U . . .
N3 N -1.6516(3) 1.6644(4) 0.39487(9) 0.0417(7) Uani 1 1 d . . . . .
H3A H -1.677381 1.751108 0.382939 0.050 Uiso 1 1 calc R U . . .
N4 N -1.1886(3) 1.3523(3) 0.29844(10) 0.0402(6) Uani 1 1 d . . . . .
N5 N 1.5386(3) 0.5385(4) 0.18037(10) 0.0439(7) Uani 1 1 d . . . . .
N6 N 2.0485(4) 0.1708(3) 0.10952(10) 0.0441(7) Uani 1 1 d . . . . .
H6A H 2.048052 0.104248 0.128431 0.053 Uiso 1 1 calc R U . . .
N7 N 2.1802(3) -0.0664(3) 0.02045(10) 0.0396(6) Uani 1 1 d . . . . .
H7A H 2.169402 0.003083 0.001297 0.048 Uiso 1 1 calc R U . . .
N8 N 2.7443(3) -0.4210(3) 0.00218(11) 0.0422(7) Uani 1 1 d . . . . .
C1 C -1.7680(4) 1.9405(4) 0.64239(11) 0.0379(7) Uani 1 1 d . . . . .
H1A H -1.735403 1.945089 0.669284 0.046 Uiso 1 1 calc R U . . .
C2 C -1.6598(4) 1.9015(4) 0.60751(11) 0.0406(7) Uani 1 1 d . . . . .
H2B H -1.557469 1.881064 0.611381 0.049 Uiso 1 1 calc R U . . .
C3 C -1.7051(5) 1.8932(4) 0.56682(11) 0.0432(8) Uani 1 1 d . . . . .
C4 C -1.8596(5) 1.9210(5) 0.56342(12) 0.0540(10) Uani 1 1 d . . . . .
H4A H -1.894307 1.913982 0.537084 0.065 Uiso 1 1 calc R U . . .
C5 C -1.9607(5) 1.9590(5) 0.59952(13) 0.0518(10) Uani 1 1 d . . . . .
H5A H -2.062835 1.976693 0.596646 0.062 Uiso 1 1 calc R U . . .
C6 C -1.5915(6) 1.8601(5) 0.52745(13) 0.0573(11) Uani 1 1 d . . . . .
H6B H -1.612905 1.951121 0.510525 0.069 Uiso 1 1 calc R U . . .
H6C H -1.486944 1.821818 0.537015 0.069 Uiso 1 1 calc R U . . .
C7 C -1.6418(4) 1.7817(4) 0.45931(12) 0.0443(8) Uani 1 1 d . . . . .
C8 C -1.6278(4) 1.6435(4) 0.43694(12) 0.0448(8) Uani 1 1 d . . . . .
C9 C -1.6353(4) 1.5442(5) 0.36837(12) 0.0453(8) Uani 1 1 d . . . . .
H9A H -1.713743 1.582715 0.347180 0.054 Uiso 1 1 calc R U . . .
H9B H -1.652785 1.470006 0.386565 0.054 Uiso 1 1 calc R U . . .
C10 C -1.4756(4) 1.4720(4) 0.34515(10) 0.0339(6) Uani 1 1 d . . . . .
C11 C -1.3395(4) 1.4548(4) 0.36346(11) 0.0374(7) Uani 1 1 d . . . . .
H11A H -1.342767 1.482938 0.391374 0.045 Uiso 1 1 calc R U . . .
C12 C -1.2000(4) 1.3954(4) 0.33923(12) 0.0385(7) Uani 1 1 d . . . . .
H12A H -1.110579 1.384598 0.351537 0.046 Uiso 1 1 calc R U . . .
C13 C -1.3179(4) 1.3626(4) 0.28176(12) 0.0436(8) Uani 1 1 d . . . . .
H13A H -1.310713 1.329925 0.254223 0.052 Uiso 1 1 calc R U . . .
C14 C -1.4620(4) 1.4200(4) 0.30405(11) 0.0403(7) Uani 1 1 d . . . . .
H14A H -1.548356 1.423763 0.291651 0.048 Uiso 1 1 calc R U . . .
C15 C -0.6680(4) 1.2092(4) 0.22520(11) 0.0375(7) Uani 1 1 d . . . . .
C16 C -0.5196(3) 1.1350(4) 0.19764(9) 0.0313(6) Uani 1 1 d . . . . .
C17 C -0.5200(3) 1.0990(4) 0.15500(9) 0.0318(6) Uani 1 1 d . . . . .
H17A H -0.613405 1.120446 0.143060 0.038 Uiso 1 1 calc R U . . .
C18 C -0.3801(3) 1.0308(3) 0.13021(9) 0.0288(6) Uani 1 1 d . . . . .
C19 C -0.3815(4) 0.9969(3) 0.08319(9) 0.0326(6) Uani 1 1 d . . . . .
C20 C -0.2391(3) 0.9992(3) 0.14843(9) 0.0281(6) Uani 1 1 d . . . . .
H20A H -0.146432 0.955338 0.132128 0.034 Uiso 1 1 calc R U . . .
C21 C -0.2380(3) 1.0340(3) 0.19128(9) 0.0284(6) Uani 1 1 d . . . . .
C22 C -0.3780(3) 1.1015(4) 0.21548(9) 0.0299(6) Uani 1 1 d . . . . .
H22A H -0.377159 1.124523 0.243740 0.036 Uiso 1 1 calc R U . . .
C23 C -0.0884(3) 1.0077(3) 0.21127(9) 0.0301(6) Uani 1 1 d . . . . .
C24 C 0.4541(3) 0.8497(3) 0.29485(10) 0.0304(6) Uani 1 1 d . . . . .
C25 C 0.6152(3) 0.7977(3) 0.31151(10) 0.0291(6) Uani 1 1 d . . . . .
C26 C 0.7429(3) 0.7589(3) 0.28138(10) 0.0305(6) Uani 1 1 d . . . . .
H26A H 0.726683 0.767817 0.252069 0.037 Uiso 1 1 calc R U . . .
C27 C 0.8939(3) 0.7070(3) 0.29515(10) 0.0302(6) Uani 1 1 d . . . . .
C28 C 1.0287(4) 0.6689(4) 0.26178(11) 0.0354(7) Uani 1 1 d . . . . .
C29 C 0.9177(4) 0.6920(4) 0.33947(11) 0.0343(7) Uani 1 1 d . . . . .
H29A H 1.017550 0.657638 0.348793 0.041 Uiso 1 1 calc R U . . .
C30 C 0.7924(4) 0.7284(4) 0.36977(10) 0.0363(7) Uani 1 1 d . . . . .
C31 C 0.8207(5) 0.7058(6) 0.41713(13) 0.0587(11) Uani 1 1 d . . . . .
C32 C 0.6411(4) 0.7829(4) 0.35568(10) 0.0332(6) Uani 1 1 d . . . . .
H32A H 0.557609 0.809374 0.375769 0.040 Uiso 1 1 calc R U . . .
C33 C 1.5760(4) 0.4316(4) 0.15254(12) 0.0410(7) Uani 1 1 d . . . . .
H33A H 1.499496 0.405361 0.145627 0.049 Uiso 1 1 calc R U . . .
C34 C 1.7248(4) 0.3579(4) 0.13347(11) 0.0381(7) Uani 1 1 d . . . . .
H34A H 1.745852 0.283913 0.114512 0.046 Uiso 1 1 calc R U . . .
C35 C 1.8417(4) 0.3957(4) 0.14293(10) 0.0334(6) Uani 1 1 d . . . . .
C36 C 1.8007(4) 0.5104(5) 0.17102(13) 0.0482(9) Uani 1 1 d . . . . .
H36A H 1.873995 0.541368 0.177649 0.058 Uiso 1 1 calc R U . . .
C37 C 1.6508(5) 0.5777(5) 0.18890(15) 0.0561(11) Uani 1 1 d . . . . .
H37A H 1.626185 0.653172 0.207604 0.067 Uiso 1 1 calc R U . . .
C38 C 2.0053(4) 0.3202(4) 0.12338(12) 0.0411(8) Uani 1 1 d . . . . .
H38A H 2.016369 0.380278 0.098717 0.049 Uiso 1 1 calc R U . . .
H38B H 2.076825 0.314788 0.144391 0.049 Uiso 1 1 calc R U . . .
C39 C 2.0883(4) 0.1351(4) 0.06870(11) 0.0379(7) Uani 1 1 d . . . . .
C40 C 2.1412(4) -0.0316(4) 0.06137(12) 0.0417(8) Uani 1 1 d . . . . .
C41 C 2.2410(4) -0.2181(4) 0.00662(15) 0.0482(9) Uani 1 1 d . . . . .
H41A H 2.205407 -0.217231 -0.021683 0.058 Uiso 1 1 calc R U . . .
H41B H 2.201988 -0.274198 0.026541 0.058 Uiso 1 1 calc R U . . .
C42 C 2.4185(4) -0.2925(3) 0.00498(12) 0.0367(7) Uani 1 1 d . . . . .
C43 C 2.4989(4) -0.3142(4) 0.04227(13) 0.0467(8) Uani 1 1 d . . . . .
H43A H 2.445089 -0.286652 0.068706 0.056 Uiso 1 1 calc R U . . .
C44 C 2.6603(4) -0.3773(4) 0.03958(13) 0.0469(8) Uani 1 1 d . . . . .
H44A H 2.712199 -0.389760 0.064576 0.056 Uiso 1 1 calc R U . . .
C45 C 2.6662(4) -0.4009(4) -0.03359(13) 0.0448(8) Uani 1 1 d . . . . .
H45A H 2.722543 -0.430550 -0.059601 0.054 Uiso 1 1 calc R U . . .
C46 C 2.5050(4) -0.3379(4) -0.03349(12) 0.0416(8) Uani 1 1 d . . . . .
H46A H 2.455791 -0.326356 -0.058939 0.050 Uiso 1 1 calc R U . . .
O17 O 1.1636(4) 0.6240(4) 0.14279(11) 0.0694(9) Uani 1 1 d . . . . .
H17C H 1.107720 0.636600 0.166053 0.083 Uiso 1 1 d R U . . .
H17D H 1.171991 0.703350 0.135863 0.083 Uiso 1 1 d R U . . .
O18 O 3.0374(4) -0.6483(4) -0.07548(11) 0.0682(9) Uani 1 1 d . . . . .
H18C H 2.972807 -0.642304 -0.093441 0.082 Uiso 1 1 d R U . . .
H18D H 3.099777 -0.738844 -0.071581 0.082 Uiso 1 1 d R U . . .
O19 O 0.3763(9) 0.8574(9) 0.1407(2) 0.082(2) Uani 0.5 1 d . . P . .
H19B H 0.362867 0.784837 0.133218 0.099 Uiso 0.5 1 d R U P . .
H19C H 0.336257 0.929877 0.122618 0.099 Uiso 0.5 1 d R U P . .
O20 O 1.2333(7) 0.2090(6) 0.34113(16) 0.127(2) Uani 1 1 d . . . . .
H20B H 1.236387 0.167804 0.318065 0.152 Uiso 1 1 d R U . . .
H20E H 1.178835 0.185674 0.360265 0.152 Uiso 1 1 d R U . . .
O21 O 1.2140(9) 0.2204(7) 0.4305(2) 0.0707(19) Uani 0.5 1 d . . P B 1
O22 O 1.1639(10) 0.4336(11) 0.4832(2) 0.096(3) Uani 0.5 1 d . . P C 2
O23 O 1.0454(9) 0.6495(9) 0.50613(19) 0.076(2) Uani 0.5 1 d . . P . .
H23A H 1.048106 0.575237 0.521574 0.092 Uiso 0.5 1 d R U P . .
H23C H 0.973999 0.728507 0.515854 0.092 Uiso 0.5 1 d R U P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.317(3) . ?
Ag1 O12 2.320(3) 2_386 ?
Ag1 O10 2.329(2) 2_386 ?
Ag1 Ag4 2.8959(15) 2_386 ?
Ag1 Ag2 3.367(2) 2_286 ?
Ag2 O5 2.137(3) . ?
Ag2 N4 2.138(3) . ?
Ag3 O7 2.189(3) . ?
Ag3 O7 2.190(3) 2_475 ?
Ag4 O11 2.171(3) . ?
Ag4 O9 2.181(3) . ?
Ag4 O5 2.574(3) 1_655 ?
Ag4 Ag5 3.001(2) 1_455 ?
Ag5 N5 2.170(3) . ?
Ag5 O14 2.183(3) . ?
Ag6 N8 2.226(3) 2_;45 ?
Ag6 N8 2.226(3) . ?
O1 C7 1.248(5) . ?
O2 C8 1.233(5) . ?
O3 C39 1.232(4) . ?
O4 C40 1.240(4) . ?
O5 C15 1.288(4) . ?
O6 C15 1.247(4) . ?
O7 C19 1.272(4) . ?
O8 C19 1.250(4) . ?
O9 C23 1.275(4) . ?
O10 C23 1.260(4) . ?
O11 C24 1.259(4) . ?
O12 C24 1.278(4) . ?
O13 C28 1.248(4) . ?
O14 C28 1.284(4) . ?
O15 C31 1.290(5) . ?
O15 H15C 0.8502 . ?
O16 C31 1.239(12) . ?
O16' C31 1.31(2) . ?
N1 C1 1.349(5) . ?
N1 C5 1.352(5) . ?
N2 C7 1.335(5) . ?
N2 C6 1.468(5) . ?
N2 H2A 0.8600 . ?
N3 C8 1.334(5) . ?
N3 C9 1.465(5) . ?
N3 H3A 0.8600 . ?
N4 C13 1.347(5) . ?
N4 C12 1.356(5) . ?
N5 C33 1.342(5) . ?
N5 C37 1.354(5) . ?
N6 C39 1.329(4) . ?
N6 C38 1.468(5) . ?
N6 H6A 0.8600 . ?
N7 C40 1.329(5) . ?
N7 C41 1.466(5) . ?
N7 H7A 0.8600 . ?
N8 C45 1.348(5) . ?
N8 C44 1.350(5) . ?
C1 C2 1.395(5) . ?
C1 H1A 0.9300 . ?
C2 C3 1.394(5) . ?
C2 H2B 0.9300 . ?
C3 C4 1.398(6) . ?
C3 C6 1.529(5) . ?
C4 C5 1.387(5) . ?
C4 H4A 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6B 0.9700 . ?
C6 H6C 0.9700 . ?
C7 C8 1.555(5) . ?
C9 C10 1.528(5) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C14 1.396(5) . ?
C10 C11 1.407(5) . ?
C11 C12 1.390(5) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.394(5) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.517(4) . ?
C16 C22 1.404(4) . ?
C16 C17 1.406(4) . ?
C17 C18 1.409(4) . ?
C17 H17A 0.9300 . ?
C18 C20 1.408(4) . ?
C18 C19 1.533(4) . ?
C20 C21 1.409(4) . ?
C20 H20A 0.9300 . ?
C21 C22 1.399(4) . ?
C21 C23 1.522(4) . ?
C22 H22A 0.9300 . ?
C24 C25 1.524(4) . ?
C25 C32 1.404(4) . ?
C25 C26 1.412(4) . ?
C26 C27 1.404(4) . ?
C26 H26A 0.9300 . ?
C27 C29 1.404(5) . ?
C27 C28 1.523(4) . ?
C29 C30 1.401(5) . ?
C29 H29A 0.9300 . ?
C30 C32 1.407(5) . ?
C30 C31 1.504(5) . ?
C32 H32A 0.9300 . ?
C33 C34 1.398(5) . ?
C33 H33A 0.9300 . ?
C34 C35 1.395(5) . ?
C34 H34A 0.9300 . ?
C35 C36 1.402(5) . ?
C35 C38 1.515(4) . ?
C36 C37 1.387(5) . ?
C36 H36A 0.9300 . ?
C37 H37A 0.9300 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C39 C40 1.559(5) . ?
C41 C42 1.534(5) . ?
C41 H41A 0.9700 . ?
C41 H41B 0.9700 . ?
C42 C46 1.389(5) . ?
C42 C43 1.398(5) . ?
C43 C44 1.394(5) . ?
C43 H43A 0.9300 . ?
C44 H44A 0.9300 . ?
C45 C46 1.395(5) . ?
C45 H45A 0.9300 . ?
C46 H46A 0.9300 . ?
O17 H17C 0.8499 . ?
O17 H17D 0.8500 . ?
O18 H18C 0.8497 . ?
O18 H18D 0.8500 . ?
O19 H19B 0.8500 . ?
O19 H19C 0.8501 . ?
O20 H20B 0.8504 . ?
O20 H20E 0.8498 . ?
O23 H23A 0.8501 . ?
O23 H23C 0.8501 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 O12 109.53(10) . 2_386 ?
N1 Ag1 O10 95.96(11) . 2_386 ?
O12 Ag1 O10 150.72(9) 2_386 2_386 ?
N1 Ag1 Ag4 160.80(8) . 2_386 ?
O12 Ag1 Ag4 80.94(7) 2_386 2_386 ?
O10 Ag1 Ag4 70.69(8) 2_386 2_386 ?
N1 Ag1 Ag2 95.53(9) . 2_286 ?
O12 Ag1 Ag2 95.71(7) 2_386 2_286 ?
O10 Ag1 Ag2 66.90(7) 2_386 2_286 ?
Ag4 Ag1 Ag2 66.85(3) 2_386 2_286 ?
O5 Ag2 N4 171.86(11) . . ?
O5 Ag2 Ag1 94.53(8) . 2_286 ?
N4 Ag2 Ag1 84.30(9) . 2_286 ?
O7 Ag3 O7 180.0 . 2_475 ?
O11 Ag4 O9 165.87(11) . . ?
O11 Ag4 O5 94.77(10) . 1_655 ?
O9 Ag4 O5 98.77(10) . 1_655 ?
O11 Ag4 Ag1 81.89(8) . 2_386 ?
O9 Ag4 Ag1 92.26(7) . 2_386 ?
O5 Ag4 Ag1 97.79(6) 1_655 2_386 ?
O11 Ag4 Ag5 78.94(8) . 1_455 ?
O9 Ag4 Ag5 87.99(8) . 1_455 ?
O5 Ag4 Ag5 171.25(5) 1_655 1_455 ?
Ag1 Ag4 Ag5 87.41(2) 2_386 1_455 ?
N5 Ag5 O14 166.23(11) . . ?
N5 Ag5 Ag4 98.96(9) . 1_655 ?
O14 Ag5 Ag4 81.95(7) . 1_655 ?
C15 O5 Ag2 112.3(2) . . ?
C15 O5 Ag4 111.3(2) . 1_455 ?
Ag2 O5 Ag4 94.49(10) . 1_455 ?
C19 O7 Ag3 111.6(2) . . ?
C23 O9 Ag4 114.3(2) . . ?
C23 O10 Ag1 133.5(2) . 2_386 ?
C24 O11 Ag4 128.0(2) . . ?
C24 O12 Ag1 121.6(2) . 2_386 ?
C28 O14 Ag5 109.1(2) . . ?
C31 O15 H15C 111.9 . . ?
C1 N1 C5 117.3(3) . . ?
C1 N1 Ag1 119.5(2) . . ?
C5 N1 Ag1 123.2(3) . . ?
C7 N2 C6 124.2(4) . . ?
C7 N2 H2A 117.9 . . ?
C6 N2 H2A 117.9 . . ?
C8 N3 C9 122.1(3) . . ?
C8 N3 H3A 119.0 . . ?
C9 N3 H3A 119.0 . . ?
C13 N4 C12 117.8(3) . . ?
C13 N4 Ag2 118.7(2) . . ?
C12 N4 Ag2 123.3(2) . . ?
C33 N5 C37 117.4(3) . . ?
C33 N5 Ag5 121.4(2) . . ?
C37 N5 Ag5 119.9(2) . . ?
C39 N6 C38 122.2(3) . . ?
C39 N6 H6A 118.9 . . ?
C38 N6 H6A 118.9 . . ?
C40 N7 C41 122.8(3) . . ?
C40 N7 H7A 118.6 . . ?
C41 N7 H7A 118.6 . . ?
C45 N8 C44 117.4(3) . . ?
C45 N8 Ag6 122.3(2) . . ?
C44 N8 Ag6 119.9(3) . . ?
N1 C1 C2 122.6(3) . . ?
N1 C1 H1A 118.7 . . ?
C2 C1 H1A 118.7 . . ?
C3 C2 C1 120.0(3) . . ?
C3 C2 H2B 120.0 . . ?
C1 C2 H2B 120.0 . . ?
C2 C3 C4 117.2(3) . . ?
C2 C3 C6 121.2(4) . . ?
C4 C3 C6 121.6(4) . . ?
C5 C4 C3 119.6(3) . . ?
C5 C4 H4A 120.2 . . ?
C3 C4 H4A 120.2 . . ?
N1 C5 C4 123.2(4) . . ?
N1 C5 H5A 118.4 . . ?
C4 C5 H5A 118.4 . . ?
N2 C6 C3 112.3(3) . . ?
N2 C6 H6B 109.1 . . ?
C3 C6 H6B 109.1 . . ?
N2 C6 H6C 109.1 . . ?
C3 C6 H6C 109.1 . . ?
H6B C6 H6C 107.9 . . ?
O1 C7 N2 126.5(4) . . ?
O1 C7 C8 120.4(3) . . ?
N2 C7 C8 113.1(3) . . ?
O2 C8 N3 124.5(4) . . ?
O2 C8 C7 120.6(3) . . ?
N3 C8 C7 114.9(3) . . ?
N3 C9 C10 112.5(3) . . ?
N3 C9 H9A 109.1 . . ?
C10 C9 H9A 109.1 . . ?
N3 C9 H9B 109.1 . . ?
C10 C9 H9B 109.1 . . ?
H9A C9 H9B 107.8 . . ?
C14 C10 C11 117.8(3) . . ?
C14 C10 C9 119.5(3) . . ?
C11 C10 C9 122.7(3) . . ?
C12 C11 C10 119.1(3) . . ?
C12 C11 H11A 120.5 . . ?
C10 C11 H11A 120.5 . . ?
N4 C12 C11 122.9(3) . . ?
N4 C12 H12A 118.6 . . ?
C11 C12 H12A 118.6 . . ?
N4 C13 C14 122.8(3) . . ?
N4 C13 H13A 118.6 . . ?
C14 C13 H13A 118.6 . . ?
C13 C14 C10 119.5(3) . . ?
C13 C14 H14A 120.3 . . ?
C10 C14 H14A 120.3 . . ?
O6 C15 O5 124.5(3) . . ?
O6 C15 C16 119.4(3) . . ?
O5 C15 C16 116.1(3) . . ?
C22 C16 C17 119.3(3) . . ?
C22 C16 C15 118.7(3) . . ?
C17 C16 C15 122.0(3) . . ?
C16 C17 C18 120.6(3) . . ?
C16 C17 H17A 119.7 . . ?
C18 C17 H17A 119.7 . . ?
C20 C18 C17 119.4(3) . . ?
C20 C18 C19 120.1(3) . . ?
C17 C18 C19 120.4(3) . . ?
O8 C19 O7 124.9(3) . . ?
O8 C19 C18 118.4(3) . . ?
O7 C19 C18 116.7(3) . . ?
C18 C20 C21 120.2(3) . . ?
C18 C20 H20A 119.9 . . ?
C21 C20 H20A 119.9 . . ?
C22 C21 C20 119.6(3) . . ?
C22 C21 C23 118.8(3) . . ?
C20 C21 C23 121.5(3) . . ?
C21 C22 C16 120.8(3) . . ?
C21 C22 H22A 119.6 . . ?
C16 C22 H22A 119.6 . . ?
O10 C23 O9 125.5(3) . . ?
O10 C23 C21 117.6(3) . . ?
O9 C23 C21 117.0(3) . . ?
O11 C24 O12 125.6(3) . . ?
O11 C24 C25 116.5(3) . . ?
O12 C24 C25 117.9(3) . . ?
C32 C25 C26 119.1(3) . . ?
C32 C25 C24 122.3(3) . . ?
C26 C25 C24 118.6(3) . . ?
C27 C26 C25 120.8(3) . . ?
C27 C26 H26A 119.6 . . ?
C25 C26 H26A 119.6 . . ?
C26 C27 C29 119.3(3) . . ?
C26 C27 C28 119.4(3) . . ?
C29 C27 C28 121.3(3) . . ?
O13 C28 O14 125.0(3) . . ?
O13 C28 C27 118.6(3) . . ?
O14 C28 C27 116.4(3) . . ?
C30 C29 C27 120.6(3) . . ?
C30 C29 H29A 119.7 . . ?
C27 C29 H29A 119.7 . . ?
C29 C30 C32 119.7(3) . . ?
C29 C30 C31 119.8(3) . . ?
C32 C30 C31 120.4(3) . . ?
O16 C31 O15 122.2(9) . . ?
O15 C31 O16' 121.6(11) . . ?
O16 C31 C30 120.9(6) . . ?
O15 C31 C30 114.8(4) . . ?
O16' C31 C30 118.4(8) . . ?
C25 C32 C30 120.5(3) . . ?
C25 C32 H32A 119.8 . . ?
C30 C32 H32A 119.8 . . ?
N5 C33 C34 122.9(3) . . ?
N5 C33 H33A 118.5 . . ?
C34 C33 H33A 118.5 . . ?
C35 C34 C33 119.9(3) . . ?
C35 C34 H34A 120.1 . . ?
C33 C34 H34A 120.1 . . ?
C34 C35 C36 116.9(3) . . ?
C34 C35 C38 122.5(3) . . ?
C36 C35 C38 120.6(3) . . ?
C37 C36 C35 119.9(3) . . ?
C37 C36 H36A 120.1 . . ?
C35 C36 H36A 120.1 . . ?
N5 C37 C36 123.0(3) . . ?
N5 C37 H37A 118.5 . . ?
C36 C37 H37A 118.5 . . ?
N6 C38 C35 114.0(3) . . ?
N6 C38 H38A 108.7 . . ?
C35 C38 H38A 108.7 . . ?
N6 C38 H38B 108.7 . . ?
C35 C38 H38B 108.7 . . ?
H38A C38 H38B 107.6 . . ?
O3 C39 N6 126.3(3) . . ?
O3 C39 C40 119.8(3) . . ?
N6 C39 C40 114.0(3) . . ?
O4 C40 N7 125.7(3) . . ?
O4 C40 C39 120.7(3) . . ?
N7 C40 C39 113.6(3) . . ?
N7 C41 C42 110.8(3) . . ?
N7 C41 H41A 109.5 . . ?
C42 C41 H41A 109.5 . . ?
N7 C41 H41B 109.5 . . ?
C42 C41 H41B 109.5 . . ?
H41A C41 H41B 108.1 . . ?
C46 C42 C43 117.7(3) . . ?
C46 C42 C41 121.5(3) . . ?
C43 C42 C41 120.8(3) . . ?
C44 C43 C42 119.6(3) . . ?
C44 C43 H43A 120.2 . . ?
C42 C43 H43A 120.2 . . ?
N8 C44 C43 122.7(4) . . ?
N8 C44 H44A 118.7 . . ?
C43 C44 H44A 118.7 . . ?
N8 C45 C46 123.2(3) . . ?
N8 C45 H45A 118.4 . . ?
C46 C45 H45A 118.4 . . ?
C42 C46 C45 119.4(4) . . ?
C42 C46 H46A 120.3 . . ?
C45 C46 H46A 120.3 . . ?
H17C O17 H17D 108.2 . . ?
H18C O18 H18D 108.1 . . ?
H19B O19 H19C 109.5 . . ?
H20B O20 H20E 108.4 . . ?
H23A O23 H23C 110.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 2.2(6) . . . . ?
Ag1 N1 C1 C2 -174.4(3) . . . . ?
N1 C1 C2 C3 -0.2(6) . . . . ?
C1 C2 C3 C4 -1.9(6) . . . . ?
C1 C2 C3 C6 176.2(4) . . . . ?
C2 C3 C4 C5 1.8(6) . . . . ?
C6 C3 C4 C5 -176.2(4) . . . . ?
C1 N1 C5 C4 -2.3(6) . . . . ?
Ag1 N1 C5 C4 174.2(3) . . . . ?
C3 C4 C5 N1 0.2(7) . . . . ?
C7 N2 C6 C3 118.1(4) . . . . ?
C2 C3 C6 N2 136.3(4) . . . . ?
C4 C3 C6 N2 -45.7(6) . . . . ?
C6 N2 C7 O1 -4.6(6) . . . . ?
C6 N2 C7 C8 174.5(3) . . . . ?
C9 N3 C8 O2 -2.8(6) . . . . ?
C9 N3 C8 C7 176.9(3) . . . . ?
O1 C7 C8 O2 -174.6(4) . . . . ?
N2 C7 C8 O2 6.2(5) . . . . ?
O1 C7 C8 N3 5.7(5) . . . . ?
N2 C7 C8 N3 -173.5(3) . . . . ?
C8 N3 C9 C10 -95.6(4) . . . . ?
N3 C9 C10 C14 -145.3(3) . . . . ?
N3 C9 C10 C11 34.7(5) . . . . ?
C14 C10 C11 C12 3.6(5) . . . . ?
C9 C10 C11 C12 -176.4(3) . . . . ?
C13 N4 C12 C11 -2.9(5) . . . . ?
Ag2 N4 C12 C11 173.4(3) . . . . ?
C10 C11 C12 N4 -0.1(5) . . . . ?
C12 N4 C13 C14 2.4(6) . . . . ?
Ag2 N4 C13 C14 -174.1(3) . . . . ?
N4 C13 C14 C10 1.1(6) . . . . ?
C11 C10 C14 C13 -4.0(5) . . . . ?
C9 C10 C14 C13 176.0(4) . . . . ?
Ag2 O5 C15 O6 -7.9(5) . . . . ?
Ag4 O5 C15 O6 -112.4(4) 1_455 . . . ?
Ag2 O5 C15 C16 171.3(2) . . . . ?
Ag4 O5 C15 C16 66.8(3) 1_455 . . . ?
O6 C15 C16 C22 16.9(5) . . . . ?
O5 C15 C16 C22 -162.4(3) . . . . ?
O6 C15 C16 C17 -163.1(4) . . . . ?
O5 C15 C16 C17 17.6(5) . . . . ?
C22 C16 C17 C18 -0.3(5) . . . . ?
C15 C16 C17 C18 179.7(3) . . . . ?
C16 C17 C18 C20 -0.3(5) . . . . ?
C16 C17 C18 C19 -177.8(3) . . . . ?
Ag3 O7 C19 O8 -8.5(4) . . . . ?
Ag3 O7 C19 C18 170.4(2) . . . . ?
C20 C18 C19 O8 -6.2(5) . . . . ?
C17 C18 C19 O8 171.2(3) . . . . ?
C20 C18 C19 O7 174.7(3) . . . . ?
C17 C18 C19 O7 -7.8(5) . . . . ?
C17 C18 C20 C21 0.8(5) . . . . ?
C19 C18 C20 C21 178.3(3) . . . . ?
C18 C20 C21 C22 -0.7(5) . . . . ?
C18 C20 C21 C23 -177.2(3) . . . . ?
C20 C21 C22 C16 0.1(5) . . . . ?
C23 C21 C22 C16 176.7(3) . . . . ?
C17 C16 C22 C21 0.4(5) . . . . ?
C15 C16 C22 C21 -179.6(3) . . . . ?
Ag1 O10 C23 O9 -21.4(5) 2_386 . . . ?
Ag1 O10 C23 C21 160.1(2) 2_386 . . . ?
Ag4 O9 C23 O10 1.9(5) . . . . ?
Ag4 O9 C23 C21 -179.6(2) . . . . ?
C22 C21 C23 O10 11.6(5) . . . . ?
C20 C21 C23 O10 -171.9(3) . . . . ?
C22 C21 C23 O9 -167.0(3) . . . . ?
C20 C21 C23 O9 9.5(5) . . . . ?
Ag4 O11 C24 O12 8.8(5) . . . . ?
Ag4 O11 C24 C25 -172.6(2) . . . . ?
Ag1 O12 C24 O11 5.3(5) 2_386 . . . ?
Ag1 O12 C24 C25 -173.2(2) 2_386 . . . ?
O11 C24 C25 C32 -175.2(3) . . . . ?
O12 C24 C25 C32 3.4(5) . . . . ?
O11 C24 C25 C26 2.8(4) . . . . ?
O12 C24 C25 C26 -178.5(3) . . . . ?
C32 C25 C26 C27 -0.4(5) . . . . ?
C24 C25 C26 C27 -178.5(3) . . . . ?
C25 C26 C27 C29 0.8(5) . . . . ?
C25 C26 C27 C28 -178.9(3) . . . . ?
Ag5 O14 C28 O13 -2.6(5) . . . . ?
Ag5 O14 C28 C27 179.3(2) . . . . ?
C26 C27 C28 O13 -21.8(5) . . . . ?
C29 C27 C28 O13 158.5(4) . . . . ?
C26 C27 C28 O14 156.4(3) . . . . ?
C29 C27 C28 O14 -23.2(5) . . . . ?
C26 C27 C29 C30 0.0(5) . . . . ?
C28 C27 C29 C30 179.6(3) . . . . ?
C27 C29 C30 C32 -1.1(5) . . . . ?
C27 C29 C30 C31 177.5(3) . . . . ?
C29 C30 C31 O16 -152(3) . . . . ?
C32 C30 C31 O16 27(3) . . . . ?
C29 C30 C31 O15 12.3(6) . . . . ?
C32 C30 C31 O15 -169.0(4) . . . . ?
C29 C30 C31 O16' 167(3) . . . . ?
C32 C30 C31 O16' -14(3) . . . . ?
C26 C25 C32 C30 -0.8(5) . . . . ?
C24 C25 C32 C30 177.2(3) . . . . ?
C29 C30 C32 C25 1.6(5) . . . . ?
C31 C30 C32 C25 -177.1(4) . . . . ?
C37 N5 C33 C34 1.9(6) . . . . ?
Ag5 N5 C33 C34 -164.6(3) . . . . ?
N5 C33 C34 C35 -0.5(6) . . . . ?
C33 C34 C35 C36 -1.4(5) . . . . ?
C33 C34 C35 C38 180.0(3) . . . . ?
C34 C35 C36 C37 1.8(6) . . . . ?
C38 C35 C36 C37 -179.5(4) . . . . ?
C33 N5 C37 C36 -1.5(7) . . . . ?
Ag5 N5 C37 C36 165.3(4) . . . . ?
C35 C36 C37 N5 -0.4(7) . . . . ?
C39 N6 C38 C35 118.8(4) . . . . ?
C34 C35 C38 N6 -24.5(5) . . . . ?
C36 C35 C38 N6 156.9(3) . . . . ?
C38 N6 C39 O3 -4.5(6) . . . . ?
C38 N6 C39 C40 175.9(3) . . . . ?
C41 N7 C40 O4 -2.6(6) . . . . ?
C41 N7 C40 C39 176.7(3) . . . . ?
O3 C39 C40 O4 179.5(4) . . . . ?
N6 C39 C40 O4 -0.8(5) . . . . ?
O3 C39 C40 N7 0.1(5) . . . . ?
N6 C39 C40 N7 179.8(3) . . . . ?
C40 N7 C41 C42 -93.2(4) . . . . ?
N7 C41 C42 C46 -116.4(4) . . . . ?
N7 C41 C42 C43 62.2(5) . . . . ?
C46 C42 C43 C44 1.0(5) . . . . ?
C41 C42 C43 C44 -177.7(3) . . . . ?
C45 N8 C44 C43 0.4(6) . . . . ?
Ag6 N8 C44 C43 174.0(3) . . . . ?
C42 C43 C44 N8 -0.9(6) . . . . ?
C44 N8 C45 C46 0.0(5) . . . . ?
Ag6 N8 C45 C46 -173.5(3) . . . . ?
C43 C42 C46 C45 -0.7(5) . . . . ?
C41 C42 C46 C45 178.0(3) . . . . ?
N8 C45 C46 C42 0.2(6) . . . . ?

_refine_diff_density_max         1.387
_refine_diff_density_min         -0.922
_refine_diff_density_rms         0.091

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 2512230'
loop_
_audit_author_name
_audit_author_address
'Jhy-Der Chen'
;Chung Yuan Christian University
Taiwan
;
_audit_update_record             
;
2025-12-01 deposited with the CCDC.	2026-01-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2019/1
_shelx_SHELXL_version_number     2019/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H29 Ag N4 O12'
_chemical_formula_weight         673.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.277(2)
_cell_length_b                   11.398(2)
_cell_length_c                   21.089(4)
_cell_angle_alpha                90
_cell_angle_beta                 91.707(5)
_cell_angle_gamma                90
_cell_volume                     2709.5(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    9845
_cell_measurement_theta_min      2.61
_cell_measurement_theta_max      28.28

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_F_000             1376
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.815
_shelx_estimated_absorpt_T_min   0.736
_shelx_estimated_absorpt_T_max   0.923
_exptl_absorpt_correction_type   multi_scan
_exptl_absorpt_correction_T_min  0.6862
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   'sadabs v2008/1(bruker axs, 2008)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            60929
_diffrn_reflns_av_unetI/netI     0.0136
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         1.807
_diffrn_reflns_theta_max         28.440
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             6787
_reflns_number_gt                6005
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0407P)²+1.4676P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6787
_refine_ls_number_parameters     370
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0306
_refine_ls_wR_factor_ref         0.0849
_refine_ls_wR_factor_gt          0.0819
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_restrained_S_all      1.048
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.61654(2) 0.41991(2) 0.50014(2) 0.05239(7) Uani 1 1 d . . . . .
O1 O 0.11142(16) 0.03126(14) 0.54504(10) 0.0710(5) Uani 1 1 d . . . . .
O2 O 0.24477(17) -0.24331(16) 0.53798(10) 0.0720(5) Uani 1 1 d . . . . .
O3 O 0.42826(15) 0.49273(14) 0.72414(7) 0.0556(4) Uani 1 1 d . . . . .
O4 O 0.48894(14) 0.39200(14) 0.80881(7) 0.0517(4) Uani 1 1 d . . . . .
H4C H 0.527116 0.352966 0.781796 0.062 Uiso 1 1 d R U . . .
O5 O 0.25570(11) 0.72840(12) 0.69290(6) 0.0422(3) Uani 1 1 d . . . . .
O6 O 0.39918(14) 0.75908(14) 0.76471(7) 0.0549(4) Uani 1 1 d . . . . .
O7 O -0.04270(11) 0.31629(12) 0.82926(7) 0.0433(3) Uani 1 1 d . . . . .
H7C H -0.106364 0.283446 0.815928 0.052 Uiso 1 1 d R U . . .
O8 O -0.06334(14) 0.41837(15) 0.73917(8) 0.0585(4) Uani 1 1 d . . . . .
O9 O 0.19613(15) 0.26706(14) 0.75924(7) 0.0531(4) Uani 1 1 d . . . . .
O10 O 0.27829(16) 0.20707(13) 0.85040(8) 0.0577(4) Uani 1 1 d . . . . .
H10A H 0.317896 0.160131 0.827945 0.069 Uiso 1 1 d R U . . .
O11 O 0.54062(19) 0.3498(2) 0.38971(8) 0.0802(6) Uani 1 1 d . . . . .
H11A H 0.592770 0.365825 0.362744 0.096 Uiso 1 1 d R U . . .
H11C H 0.476430 0.384935 0.379354 0.096 Uiso 1 1 d R U . . .
O12 O 0.28863(19) -0.01563(17) 0.81606(11) 0.0819(6) Uani 1 1 d . . . . .
H12B H 0.241221 -0.000725 0.785024 0.098 Uiso 1 1 d R U . . .
H12C H 0.333381 -0.072825 0.806944 0.098 Uiso 1 1 d R U . . .
N1 N 0.49712(15) 0.30644(16) 0.54781(8) 0.0463(4) Uani 1 1 d . . . . .
N2 N 0.25393(14) -0.04720(15) 0.60837(9) 0.0457(4) Uani 1 1 d . . . . .
H2A H 0.293116 -0.109430 0.618652 0.055 Uiso 1 1 calc R U . . .
N3 N 0.09323(15) -0.16903(15) 0.47684(10) 0.0502(4) Uani 1 1 d . . . . .
H3A H 0.049594 -0.108070 0.470346 0.060 Uiso 1 1 calc R U . . .
N4 N -0.23448(16) -0.47285(15) 0.47585(8) 0.0466(4) Uani 1 1 d . . . . .
C1 C 0.4727(2) 0.2007(2) 0.52224(10) 0.0554(6) Uani 1 1 d . . . . .
H1A H 0.505020 0.182194 0.483437 0.066 Uiso 1 1 calc R U . . .
C2 C 0.4023(2) 0.1187(2) 0.55072(10) 0.0514(5) Uani 1 1 d . . . . .
H2B H 0.388426 0.046258 0.531578 0.062 Uiso 1 1 calc R U . . .
C3 C 0.35217(15) 0.14513(17) 0.60824(8) 0.0377(4) Uani 1 1 d . . . . .
C4 C 0.37817(18) 0.25305(19) 0.63488(9) 0.0445(4) Uani 1 1 d . . . . .
H4B H 0.346874 0.273789 0.673615 0.053 Uiso 1 1 calc R U . . .
C5 C 0.45070(19) 0.32993(19) 0.60380(9) 0.0466(4) Uani 1 1 d . . . . .
H5A H 0.468130 0.401744 0.622826 0.056 Uiso 1 1 calc R U . . .
C6 C 0.27504(18) 0.05995(19) 0.64333(10) 0.0469(4) Uani 1 1 d . . . . .
H6A H 0.313076 0.041274 0.683941 0.056 Uiso 1 1 calc R U . . .
H6B H 0.199590 0.097046 0.651478 0.056 Uiso 1 1 calc R U . . .
C7 C 0.17497(17) -0.05095(17) 0.56064(11) 0.0443(4) Uani 1 1 d . . . . .
C8 C 0.17371(17) -0.16622(17) 0.52396(11) 0.0459(4) Uani 1 1 d . . . . .
C9 C 0.0752(2) -0.26967(19) 0.43578(11) 0.0526(5) Uani 1 1 d . . . . .
H9A H 0.144456 -0.319970 0.439442 0.063 Uiso 1 1 calc R U . . .
H9B H 0.068309 -0.242786 0.392190 0.063 Uiso 1 1 calc R U . . .
C10 C -0.03348(17) -0.34086(16) 0.45055(9) 0.0396(4) Uani 1 1 d . . . . .
C11 C -0.0800(2) -0.4198(2) 0.40723(10) 0.0555(6) Uani 1 1 d . . . . .
H11B H -0.044625 -0.429474 0.368300 0.067 Uiso 1 1 calc R U . . .
C12 C -0.1792(2) -0.4847(2) 0.42144(11) 0.0571(6) Uani 1 1 d . . . . .
H12A H -0.208415 -0.538695 0.391821 0.069 Uiso 1 1 calc R U . . .
C13 C -0.1892(3) -0.3976(2) 0.51719(13) 0.0752(9) Uani 1 1 d . . . . .
H13A H -0.226867 -0.388368 0.555513 0.090 Uiso 1 1 calc R U . . .
C14 C -0.0892(3) -0.3318(3) 0.50691(12) 0.0740(9) Uani 1 1 d . . . . .
H14A H -0.059818 -0.281281 0.538251 0.089 Uiso 1 1 calc R U . . .
C15 C 0.42504(15) 0.47263(15) 0.78034(8) 0.0335(3) Uani 1 1 d . . . . .
C16 C 0.34862(14) 0.54249(15) 0.82513(7) 0.0314(3) Uani 1 1 d . . . . .
H16A H 0.401987 0.597034 0.847820 0.038 Uiso 1 1 calc R U . . .
C17 C 0.25382(14) 0.61806(15) 0.79056(8) 0.0311(3) Uani 1 1 d . . . . .
H17A H 0.217393 0.664910 0.823734 0.037 Uiso 1 1 calc R U . . .
C18 C 0.30661(15) 0.70693(14) 0.74502(8) 0.0335(3) Uani 1 1 d . . . . .
C19 C 0.15347(15) 0.54257(16) 0.76197(8) 0.0350(3) Uani 1 1 d . . . . .
H19A H 0.094063 0.592815 0.741794 0.042 Uiso 1 1 calc R U . . .
H19B H 0.184798 0.491283 0.729808 0.042 Uiso 1 1 calc R U . . .
C20 C 0.09603(14) 0.46869(15) 0.81332(8) 0.0341(3) Uani 1 1 d . . . . .
H20A H 0.064846 0.524892 0.843790 0.041 Uiso 1 1 calc R U . . .
C21 C -0.01040(15) 0.39847(16) 0.78881(9) 0.0382(4) Uani 1 1 d . . . . .
C22 C 0.18530(15) 0.39240(16) 0.85114(8) 0.0342(3) Uani 1 1 d . . . . .
H22A H 0.144364 0.364328 0.888577 0.041 Uiso 1 1 calc R U . . .
C23 C 0.29140(16) 0.46623(17) 0.87582(8) 0.0365(4) Uani 1 1 d . . . . .
H23A H 0.264985 0.516767 0.909607 0.044 Uiso 1 1 calc R U . . .
H23B H 0.351193 0.413840 0.893862 0.044 Uiso 1 1 calc R U . . .
C24 C 0.22053(15) 0.28396(16) 0.81397(8) 0.0361(4) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N1 2.1395(16) . ?
Ag N4 2.1519(16) 1_665 ?
Ag O11 2.5838(18) . ?
Ag Ag 3.2003(6) 3_666 ?
O1 C7 1.219(2) . ?
O2 C8 1.220(3) . ?
O3 C15 1.209(2) . ?
O4 C15 1.303(2) . ?
O4 H4C 0.8499 . ?
O5 C18 1.249(2) . ?
O6 C18 1.261(2) . ?
O7 C21 1.325(2) . ?
O7 H7C 0.8500 . ?
O8 C21 1.211(3) . ?
O9 C24 1.194(2) . ?
O10 C24 1.324(2) . ?
O10 H10A 0.8500 . ?
O11 H11A 0.8500 . ?
O11 H11C 0.8500 . ?
O12 H12B 0.8499 . ?
O12 H12C 0.8500 . ?
N1 C5 1.333(2) . ?
N1 C1 1.345(3) . ?
N2 C7 1.325(3) . ?
N2 C6 1.443(3) . ?
N2 H2A 0.8600 . ?
N3 C8 1.326(3) . ?
N3 C9 1.448(3) . ?
N3 H3A 0.8600 . ?
N4 C13 1.315(3) . ?
N4 C12 1.329(3) . ?
C1 C2 1.377(3) . ?
C1 H1A 0.9300 . ?
C2 C3 1.387(3) . ?
C2 H2B 0.9300 . ?
C3 C4 1.380(3) . ?
C3 C6 1.512(3) . ?
C4 C5 1.378(3) . ?
C4 H4B 0.9300 . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.524(3) . ?
C9 C10 1.510(3) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C14 1.365(3) . ?
C10 C11 1.375(3) . ?
C11 C12 1.382(3) . ?
C11 H11B 0.9300 . ?
C12 H12A 0.9300 . ?
C13 C14 1.377(3) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.522(2) . ?
C16 C23 1.535(2) . ?
C16 C17 1.539(2) . ?
C16 H16A 0.9800 . ?
C17 C18 1.529(2) . ?
C17 C19 1.531(2) . ?
C17 H17A 0.9800 . ?
C19 C20 1.531(2) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C21 1.520(2) . ?
C20 C22 1.536(3) . ?
C20 H20A 0.9800 . ?
C22 C24 1.523(2) . ?
C22 C23 1.541(2) . ?
C22 H22A 0.9800 . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag N4 164.18(7) . 1_665 ?
N1 Ag O11 92.31(7) . . ?
N4 Ag O11 101.60(7) 1_665 . ?
N1 Ag Ag 79.47(5) . 3_666 ?
N4 Ag Ag 108.81(5) 1_665 3_666 ?
O11 Ag Ag 85.67(5) . 3_666 ?
C15 O4 H4C 110.2 . . ?
C21 O7 H7C 110.1 . . ?
C24 O10 H10A 110.6 . . ?
Ag O11 H11A 108.6 . . ?
Ag O11 H11C 110.1 . . ?
H11A O11 H11C 109.1 . . ?
H12B O12 H12C 110.1 . . ?
C5 N1 C1 117.00(17) . . ?
C5 N1 Ag 124.34(14) . . ?
C1 N1 Ag 118.51(13) . . ?
C7 N2 C6 120.83(18) . . ?
C7 N2 H2A 119.6 . . ?
C6 N2 H2A 119.6 . . ?
C8 N3 C9 123.23(19) . . ?
C8 N3 H3A 118.4 . . ?
C9 N3 H3A 118.4 . . ?
C13 N4 C12 117.14(18) . . ?
C13 N4 Ag 120.18(14) . 1_445 ?
C12 N4 Ag 122.51(14) . 1_445 ?
N1 C1 C2 123.20(19) . . ?
N1 C1 H1A 118.4 . . ?
C2 C1 H1A 118.4 . . ?
C1 C2 C3 119.30(19) . . ?
C1 C2 H2B 120.3 . . ?
C3 C2 H2B 120.3 . . ?
C4 C3 C2 117.56(17) . . ?
C4 C3 C6 119.44(17) . . ?
C2 C3 C6 122.96(18) . . ?
C5 C4 C3 119.68(17) . . ?
C5 C4 H4B 120.2 . . ?
C3 C4 H4B 120.2 . . ?
N1 C5 C4 123.23(18) . . ?
N1 C5 H5A 118.4 . . ?
C4 C5 H5A 118.4 . . ?
N2 C6 C3 112.46(17) . . ?
N2 C6 H6A 109.1 . . ?
C3 C6 H6A 109.1 . . ?
N2 C6 H6B 109.1 . . ?
C3 C6 H6B 109.1 . . ?
H6A C6 H6B 107.8 . . ?
O1 C7 N2 123.8(2) . . ?
O1 C7 C8 121.94(19) . . ?
N2 C7 C8 114.15(18) . . ?
O2 C8 N3 126.5(2) . . ?
O2 C8 C7 120.1(2) . . ?
N3 C8 C7 113.38(17) . . ?
N3 C9 C10 113.75(17) . . ?
N3 C9 H9A 108.8 . . ?
C10 C9 H9A 108.8 . . ?
N3 C9 H9B 108.8 . . ?
C10 C9 H9B 108.8 . . ?
H9A C9 H9B 107.7 . . ?
C14 C10 C11 116.86(18) . . ?
C14 C10 C9 122.44(19) . . ?
C11 C10 C9 120.70(18) . . ?
C10 C11 C12 120.11(19) . . ?
C10 C11 H11B 119.9 . . ?
C12 C11 H11B 119.9 . . ?
N4 C12 C11 122.4(2) . . ?
N4 C12 H12A 118.8 . . ?
C11 C12 H12A 118.8 . . ?
N4 C13 C14 123.7(2) . . ?
N4 C13 H13A 118.2 . . ?
C14 C13 H13A 118.2 . . ?
C10 C14 C13 119.7(2) . . ?
C10 C14 H14A 120.1 . . ?
C13 C14 H14A 120.1 . . ?
O3 C15 O4 123.57(16) . . ?
O3 C15 C16 122.92(16) . . ?
O4 C15 C16 113.48(15) . . ?
C15 C16 C23 113.17(14) . . ?
C15 C16 C17 113.38(13) . . ?
C23 C16 C17 110.25(14) . . ?
C15 C16 H16A 106.5 . . ?
C23 C16 H16A 106.5 . . ?
C17 C16 H16A 106.5 . . ?
C18 C17 C19 114.96(14) . . ?
C18 C17 C16 112.97(13) . . ?
C19 C17 C16 111.52(14) . . ?
C18 C17 H17A 105.5 . . ?
C19 C17 H17A 105.5 . . ?
C16 C17 H17A 105.5 . . ?
O5 C18 O6 123.50(16) . . ?
O5 C18 C17 120.35(15) . . ?
O6 C18 C17 116.07(16) . . ?
C20 C19 C17 110.73(14) . . ?
C20 C19 H19A 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C20 C19 H19B 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 108.1 . . ?
C21 C20 C19 113.30(15) . . ?
C21 C20 C22 112.16(15) . . ?
C19 C20 C22 113.22(13) . . ?
C21 C20 H20A 105.8 . . ?
C19 C20 H20A 105.8 . . ?
C22 C20 H20A 105.8 . . ?
O8 C21 O7 123.43(17) . . ?
O8 C21 C20 124.00(17) . . ?
O7 C21 C20 112.49(16) . . ?
C24 C22 C20 111.67(14) . . ?
C24 C22 C23 113.91(15) . . ?
C20 C22 C23 110.90(15) . . ?
C24 C22 H22A 106.6 . . ?
C20 C22 H22A 106.6 . . ?
C23 C22 H22A 106.6 . . ?
C16 C23 C22 114.37(13) . . ?
C16 C23 H23A 108.7 . . ?
C22 C23 H23A 108.7 . . ?
C16 C23 H23B 108.7 . . ?
C22 C23 H23B 108.7 . . ?
H23A C23 H23B 107.6 . . ?
O9 C24 O10 123.31(18) . . ?
O9 C24 C22 124.92(17) . . ?
O10 C24 C22 111.72(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.8(4) . . . . ?
Ag N1 C1 C2 176.4(2) . . . . ?
N1 C1 C2 C3 0.7(4) . . . . ?
C1 C2 C3 C4 -1.4(3) . . . . ?
C1 C2 C3 C6 -179.2(2) . . . . ?
C2 C3 C4 C5 0.6(3) . . . . ?
C6 C3 C4 C5 178.48(19) . . . . ?
C1 N1 C5 C4 -1.6(3) . . . . ?
Ag N1 C5 C4 -176.98(16) . . . . ?
C3 C4 C5 N1 1.0(3) . . . . ?
C7 N2 C6 C3 -78.1(2) . . . . ?
C4 C3 C6 N2 178.49(17) . . . . ?
C2 C3 C6 N2 -3.7(3) . . . . ?
C6 N2 C7 O1 -3.9(3) . . . . ?
C6 N2 C7 C8 173.24(16) . . . . ?
C9 N3 C8 O2 2.6(3) . . . . ?
C9 N3 C8 C7 -179.56(17) . . . . ?
O1 C7 C8 O2 174.4(2) . . . . ?
N2 C7 C8 O2 -2.8(3) . . . . ?
O1 C7 C8 N3 -3.6(3) . . . . ?
N2 C7 C8 N3 179.24(18) . . . . ?
C8 N3 C9 C10 103.5(2) . . . . ?
N3 C9 C10 C14 -17.5(3) . . . . ?
N3 C9 C10 C11 163.3(2) . . . . ?
C14 C10 C11 C12 0.5(4) . . . . ?
C9 C10 C11 C12 179.7(2) . . . . ?
C13 N4 C12 C11 -1.5(4) . . . . ?
Ag N4 C12 C11 -176.7(2) 1_445 . . . ?
C10 C11 C12 N4 1.2(4) . . . . ?
C12 N4 C13 C14 0.0(5) . . . . ?
Ag N4 C13 C14 175.4(3) 1_445 . . . ?
C11 C10 C14 C13 -1.9(5) . . . . ?
C9 C10 C14 C13 178.9(3) . . . . ?
N4 C13 C14 C10 1.7(6) . . . . ?
O3 C15 C16 C23 141.25(18) . . . . ?
O4 C15 C16 C23 -40.8(2) . . . . ?
O3 C15 C16 C17 14.7(2) . . . . ?
O4 C15 C16 C17 -167.28(15) . . . . ?
C15 C16 C17 C18 -58.91(18) . . . . ?
C23 C16 C17 C18 173.03(13) . . . . ?
C15 C16 C17 C19 72.38(17) . . . . ?
C23 C16 C17 C19 -55.67(18) . . . . ?
C19 C17 C18 O5 12.2(2) . . . . ?
C16 C17 C18 O5 141.72(16) . . . . ?
C19 C17 C18 O6 -170.96(16) . . . . ?
C16 C17 C18 O6 -41.4(2) . . . . ?
C18 C17 C19 C20 -172.44(14) . . . . ?
C16 C17 C19 C20 57.30(18) . . . . ?
C17 C19 C20 C21 175.70(14) . . . . ?
C17 C19 C20 C22 -55.13(19) . . . . ?
C19 C20 C21 O8 -17.1(3) . . . . ?
C22 C20 C21 O8 -146.86(19) . . . . ?
C19 C20 C21 O7 165.93(15) . . . . ?
C22 C20 C21 O7 36.2(2) . . . . ?
C21 C20 C22 C24 52.31(18) . . . . ?
C19 C20 C22 C24 -77.44(18) . . . . ?
C21 C20 C22 C23 -179.48(14) . . . . ?
C19 C20 C22 C23 50.77(19) . . . . ?
C15 C16 C23 C22 -75.52(19) . . . . ?
C17 C16 C23 C22 52.64(19) . . . . ?
C24 C22 C23 C16 76.98(19) . . . . ?
C20 C22 C23 C16 -50.01(19) . . . . ?
C20 C22 C24 O9 9.9(2) . . . . ?
C23 C22 C24 O9 -116.7(2) . . . . ?
C20 C22 C24 O10 -167.61(15) . . . . ?
C23 C22 C24 O10 65.81(19) . . . . ?

_refine_diff_density_max         0.467
_refine_diff_density_min         -0.370
_refine_diff_density_rms         0.053

