# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2390596'
loop_
_audit_author_name
_audit_author_address
'Mariappan Murali'
;National College (Autonomous)
India
;
_audit_update_record             
;
2024-10-13 deposited with the CCDC.	2025-03-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H21 Cl Cu N4 O5'
_chemical_formula_sum            'C26 H21 Cl Cu N4 O5'
_chemical_formula_weight         568.46

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   9.547(2)
_cell_length_b                   17.906(3)
_cell_length_c                   14.077(3)
_cell_angle_alpha                90
_cell_angle_beta                 107.131(5)
_cell_angle_gamma                90
_cell_volume                     2299.7(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    5199
_cell_measurement_theta_min      2.50
_cell_measurement_theta_max      31.40

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.642
_exptl_crystal_F_000             1164
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.290
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.220
_exptl_absorpt_coefficient_mu    1.115
_shelx_estimated_absorpt_T_min   0.738
_shelx_estimated_absorpt_T_max   0.791
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.666
_exptl_absorpt_correction_T_max  0.782
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 14.222
_diffrn_reflns_number            16803
_diffrn_reflns_av_unetI/netI     0.0206
_diffrn_reflns_av_R_equivalents  0.0233
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.733
_diffrn_reflns_theta_max         24.996
_diffrn_reflns_theta_full        24.996
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             4034
_reflns_number_gt                3897
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)'
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r15'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r15'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Diamond 3.2'
_computing_publication_material  'WinGX v2014.1'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0598P)²+0.9981P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4034
_refine_ls_number_parameters     334
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0281
_refine_ls_R_factor_gt           0.0272
_refine_ls_wR_factor_ref         0.0859
_refine_ls_wR_factor_gt          0.0850
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_restrained_S_all      1.007
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.60576(2) 0.04049(2) 0.75602(2) 0.01693(10) Uani 1 1 d . . . . .
Cl1 Cl 0.12635(5) 0.16830(3) 0.70627(4) 0.03028(14) Uani 1 1 d . . . . .
O1 O 0.69328(14) -0.05265(7) 0.81708(10) 0.0210(3) Uani 1 1 d . . . . .
O2 O 0.2269(2) 0.20215(15) 0.66273(16) 0.0785(8) Uani 1 1 d . . . . .
O3 O 0.15729(19) 0.08980(10) 0.72399(14) 0.0496(5) Uani 1 1 d . . . . .
O4 O -0.02183(17) 0.17626(10) 0.64243(13) 0.0439(4) Uani 1 1 d . . . . .
O5 O 0.1376(2) 0.20318(12) 0.79970(15) 0.0613(5) Uani 1 1 d . . . . .
N1 N 0.42282(16) -0.01782(9) 0.68968(11) 0.0180(3) Uani 1 1 d . . . . .
N2 N 0.54446(16) 0.09118(8) 0.61249(11) 0.0180(3) Uani 1 1 d . . . . .
N3 N 0.78590(16) 0.09795(8) 0.81400(11) 0.0188(3) Uani 1 1 d . . . . .
N4 N 0.50974(16) 0.10351(9) 0.85335(11) 0.0184(3) Uani 1 1 d . . . . .
C1 C 0.6116(2) 0.14231(10) 0.57281(14) 0.0210(4) Uani 1 1 d . . . . .
H1 H 0.7045 0.1604 0.6114 0.025 Uiso 1 1 calc R U . . .
C2 C 0.5512(2) 0.17077(11) 0.47644(14) 0.0237(4) Uani 1 1 d . . . . .
H2 H 0.6015 0.2081 0.4514 0.028 Uiso 1 1 calc R U . . .
C3 C 0.4188(2) 0.14402(11) 0.41889(13) 0.0234(4) Uani 1 1 d . . . . .
H3 H 0.3772 0.1624 0.3533 0.028 Uiso 1 1 calc R U . . .
C4 C 0.3449(2) 0.08940(10) 0.45738(13) 0.0206(4) Uani 1 1 d . . . . .
C5 C 0.2085(2) 0.05585(12) 0.40266(14) 0.0247(4) Uani 1 1 d . . . . .
H5 H 0.1594 0.0737 0.3378 0.030 Uiso 1 1 calc R U . . .
C6 C 0.1482(2) -0.00033(11) 0.44102(14) 0.0242(4) Uani 1 1 d . . . . .
H6 H 0.0586 -0.0219 0.4024 0.029 Uiso 1 1 calc R U . . .
C7 C 0.2178(2) -0.02812(11) 0.53988(14) 0.0207(4) Uani 1 1 d . . . . .
C8 C 0.1650(2) -0.08878(11) 0.58195(15) 0.0244(4) Uani 1 1 d . . . . .
H8 H 0.0770 -0.1132 0.5459 0.029 Uiso 1 1 calc R U . . .
C9 C 0.2414(2) -0.11291(11) 0.67599(14) 0.0242(4) Uani 1 1 d . . . . .
H9 H 0.2070 -0.1541 0.7053 0.029 Uiso 1 1 calc R U . . .
C10 C 0.3705(2) -0.07580(11) 0.72753(14) 0.0213(4) Uani 1 1 d . . . . .
H10 H 0.4228 -0.0927 0.7922 0.026 Uiso 1 1 calc R U . . .
C11 C 0.34825(19) 0.00569(10) 0.59676(13) 0.0173(4) Uani 1 1 d . . . . .
C12 C 0.41349(19) 0.06461(10) 0.55562(13) 0.0171(4) Uani 1 1 d . . . . .
C13 C 0.4387(2) 0.06936(11) 0.90980(14) 0.0221(4) Uani 1 1 d . . . . .
H13 H 0.4096 0.0189 0.8952 0.027 Uiso 1 1 calc R U . . .
C14 C 0.4053(2) 0.10374(12) 0.98866(14) 0.0256(4) Uani 1 1 d . . . . .
H14 H 0.3538 0.0776 1.0267 0.031 Uiso 1 1 calc R U . . .
C15 C 0.4486(2) 0.17672(12) 1.01063(14) 0.0280(4) Uani 1 1 d . . . . .
H15 H 0.4287 0.2017 1.0648 0.034 Uiso 1 1 calc R U . . .
C16 C 0.5217(2) 0.21306(11) 0.95235(14) 0.0252(4) Uani 1 1 d . . . . .
H16 H 0.5523 0.2634 0.9660 0.030 Uiso 1 1 calc R U . . .
C17 C 0.5498(2) 0.17530(10) 0.87395(13) 0.0203(4) Uani 1 1 d . . . . .
C18 C 0.6281(2) 0.21110(11) 0.80743(14) 0.0221(4) Uani 1 1 d . . . . .
H18A H 0.6343 0.2656 0.8200 0.027 Uiso 1 1 calc R U . . .
H18B H 0.5698 0.2033 0.7373 0.027 Uiso 1 1 calc R U . . .
C19 C 0.7822(2) 0.18067(10) 0.82228(14) 0.0227(4) Uani 1 1 d . . . . .
H19A H 0.8232 0.2032 0.7720 0.027 Uiso 1 1 calc R U . . .
H19B H 0.8453 0.1958 0.8887 0.027 Uiso 1 1 calc R U . . .
C20 C 0.91156(19) 0.06771(11) 0.85234(13) 0.0203(4) Uani 1 1 d . . . . .
H20 H 0.9920 0.1007 0.8768 0.024 Uiso 1 1 calc R U . . .
C21 C 0.9439(2) -0.01130(11) 0.86233(13) 0.0191(4) Uani 1 1 d . . . . .
C22 C 1.0926(2) -0.03180(11) 0.89347(15) 0.0257(4) Uani 1 1 d . . . . .
H22 H 1.1652 0.0061 0.9033 0.031 Uiso 1 1 calc R U . . .
C23 C 1.1361(2) -0.10498(12) 0.91008(15) 0.0280(4) Uani 1 1 d . . . . .
H23 H 1.2371 -0.1179 0.9293 0.034 Uiso 1 1 calc R U . . .
C24 C 1.0287(2) -0.15989(11) 0.89806(14) 0.0256(4) Uani 1 1 d . . . . .
H24 H 1.0571 -0.2107 0.9101 0.031 Uiso 1 1 calc R U . . .
C25 C 0.8821(2) -0.14161(11) 0.86907(13) 0.0226(4) Uani 1 1 d . . . . .
H25 H 0.8115 -0.1801 0.8629 0.027 Uiso 1 1 calc R U . . .
C26 C 0.83411(19) -0.06693(11) 0.84818(12) 0.0177(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 O1 1.9481(13) . ?
Cu1 N3 1.9634(15) . ?
Cu1 N1 2.0130(16) . ?
Cu1 N2 2.1335(15) . ?
Cu1 N4 2.1750(15) . ?
Cl1 O2 1.4183(19) . ?
Cl1 O5 1.431(2) . ?
Cl1 O4 1.4424(16) . ?
Cl1 O3 1.4428(18) . ?
O1 C26 1.311(2) . ?
N1 C10 1.330(2) . ?
N1 C11 1.359(2) . ?
N2 C1 1.331(2) . ?
N2 C12 1.357(2) . ?
N3 C20 1.282(2) . ?
N3 C19 1.487(2) . ?
N4 C13 1.335(2) . ?
N4 C17 1.348(2) . ?
C1 C2 1.404(3) . ?
C1 H1 0.9500 . ?
C2 C3 1.372(3) . ?
C2 H2 0.9500 . ?
C3 C4 1.404(3) . ?
C3 H3 0.9500 . ?
C4 C12 1.416(3) . ?
C4 C5 1.435(3) . ?
C5 C6 1.348(3) . ?
C5 H5 0.9500 . ?
C6 C7 1.443(3) . ?
C6 H6 0.9500 . ?
C7 C8 1.400(3) . ?
C7 C11 1.404(3) . ?
C8 C9 1.379(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.400(3) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C12 1.431(3) . ?
C13 C14 1.386(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.378(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.386(3) . ?
C15 H15 0.9500 . ?
C16 C17 1.386(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.503(3) . ?
C18 C19 1.524(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 C21 1.446(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.405(3) . ?
C21 C26 1.417(3) . ?
C22 C23 1.374(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.395(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.376(3) . ?
C24 H24 0.9500 . ?
C25 C26 1.416(3) . ?
C25 H25 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Cu1 N3 93.20(6) . . ?
O1 Cu1 N1 87.78(6) . . ?
N3 Cu1 N1 177.04(6) . . ?
O1 Cu1 N2 138.10(6) . . ?
N3 Cu1 N2 97.65(6) . . ?
N1 Cu1 N2 79.79(6) . . ?
O1 Cu1 N4 111.83(6) . . ?
N3 Cu1 N4 86.93(6) . . ?
N1 Cu1 N4 95.29(6) . . ?
N2 Cu1 N4 109.08(6) . . ?
O2 Cl1 O5 109.49(14) . . ?
O2 Cl1 O4 110.67(11) . . ?
O5 Cl1 O4 108.88(12) . . ?
O2 Cl1 O3 111.16(14) . . ?
O5 Cl1 O3 108.07(12) . . ?
O4 Cl1 O3 108.50(10) . . ?
C26 O1 Cu1 125.37(12) . . ?
C10 N1 C11 118.38(16) . . ?
C10 N1 Cu1 126.60(12) . . ?
C11 N1 Cu1 115.01(12) . . ?
C1 N2 C12 117.87(15) . . ?
C1 N2 Cu1 131.17(13) . . ?
C12 N2 Cu1 110.95(12) . . ?
C20 N3 C19 115.39(16) . . ?
C20 N3 Cu1 123.39(13) . . ?
C19 N3 Cu1 121.09(12) . . ?
C13 N4 C17 118.05(16) . . ?
C13 N4 Cu1 121.30(13) . . ?
C17 N4 Cu1 119.00(12) . . ?
N2 C1 C2 122.94(17) . . ?
N2 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
C3 C2 C1 119.24(18) . . ?
C3 C2 H2 120.4 . . ?
C1 C2 H2 120.4 . . ?
C2 C3 C4 119.71(17) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 H3 120.1 . . ?
C3 C4 C12 117.07(17) . . ?
C3 C4 C5 124.32(17) . . ?
C12 C4 C5 118.57(18) . . ?
C6 C5 C4 121.63(18) . . ?
C6 C5 H5 119.2 . . ?
C4 C5 H5 119.2 . . ?
C5 C6 C7 120.93(18) . . ?
C5 C6 H6 119.5 . . ?
C7 C6 H6 119.5 . . ?
C8 C7 C11 117.58(17) . . ?
C8 C7 C6 123.68(18) . . ?
C11 C7 C6 118.72(18) . . ?
C9 C8 C7 119.61(17) . . ?
C9 C8 H8 120.2 . . ?
C7 C8 H8 120.2 . . ?
C8 C9 C10 119.01(18) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
N1 C10 C9 122.70(17) . . ?
N1 C10 H10 118.6 . . ?
C9 C10 H10 118.6 . . ?
N1 C11 C7 122.71(17) . . ?
N1 C11 C12 116.80(15) . . ?
C7 C11 C12 120.38(16) . . ?
N2 C12 C4 123.15(17) . . ?
N2 C12 C11 117.06(15) . . ?
C4 C12 C11 119.68(17) . . ?
N4 C13 C14 123.38(18) . . ?
N4 C13 H13 118.3 . . ?
C14 C13 H13 118.3 . . ?
C15 C14 C13 118.44(19) . . ?
C15 C14 H14 120.8 . . ?
C13 C14 H14 120.8 . . ?
C14 C15 C16 118.85(18) . . ?
C14 C15 H15 120.6 . . ?
C16 C15 H15 120.6 . . ?
C15 C16 C17 119.43(19) . . ?
C15 C16 H16 120.3 . . ?
C17 C16 H16 120.3 . . ?
N4 C17 C16 121.83(18) . . ?
N4 C17 C18 115.73(16) . . ?
C16 C17 C18 122.43(17) . . ?
C17 C18 C19 113.53(16) . . ?
C17 C18 H18A 108.9 . . ?
C19 C18 H18A 108.9 . . ?
C17 C18 H18B 108.9 . . ?
C19 C18 H18B 108.9 . . ?
H18A C18 H18B 107.7 . . ?
N3 C19 C18 112.93(15) . . ?
N3 C19 H19A 109.0 . . ?
C18 C19 H19A 109.0 . . ?
N3 C19 H19B 109.0 . . ?
C18 C19 H19B 109.0 . . ?
H19A C19 H19B 107.8 . . ?
N3 C20 C21 126.95(17) . . ?
N3 C20 H20 116.5 . . ?
C21 C20 H20 116.5 . . ?
C22 C21 C26 119.85(18) . . ?
C22 C21 C20 116.96(17) . . ?
C26 C21 C20 123.08(17) . . ?
C23 C22 C21 121.96(19) . . ?
C23 C22 H22 119.0 . . ?
C21 C22 H22 119.0 . . ?
C22 C23 C24 118.50(18) . . ?
C22 C23 H23 120.7 . . ?
C24 C23 H23 120.7 . . ?
C25 C24 C23 121.01(19) . . ?
C25 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C24 C25 C26 121.66(18) . . ?
C24 C25 H25 119.2 . . ?
C26 C25 H25 119.2 . . ?
O1 C26 C25 119.42(17) . . ?
O1 C26 C21 123.61(17) . . ?
C25 C26 C21 116.98(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C12 N2 C1 C2 1.6(3) . . . . ?
Cu1 N2 C1 C2 -178.16(13) . . . . ?
N2 C1 C2 C3 -1.5(3) . . . . ?
C1 C2 C3 C4 0.7(3) . . . . ?
C2 C3 C4 C12 -0.1(3) . . . . ?
C2 C3 C4 C5 -177.87(17) . . . . ?
C3 C4 C5 C6 174.96(18) . . . . ?
C12 C4 C5 C6 -2.8(3) . . . . ?
C4 C5 C6 C7 1.1(3) . . . . ?
C5 C6 C7 C8 -176.51(18) . . . . ?
C5 C6 C7 C11 1.6(3) . . . . ?
C11 C7 C8 C9 -0.1(3) . . . . ?
C6 C7 C8 C9 178.00(17) . . . . ?
C7 C8 C9 C10 0.2(3) . . . . ?
C11 N1 C10 C9 -0.6(3) . . . . ?
Cu1 N1 C10 C9 179.68(14) . . . . ?
C8 C9 C10 N1 0.1(3) . . . . ?
C10 N1 C11 C7 0.8(3) . . . . ?
Cu1 N1 C11 C7 -179.51(13) . . . . ?
C10 N1 C11 C12 -175.52(16) . . . . ?
Cu1 N1 C11 C12 4.2(2) . . . . ?
C8 C7 C11 N1 -0.4(3) . . . . ?
C6 C7 C11 N1 -178.60(16) . . . . ?
C8 C7 C11 C12 175.74(16) . . . . ?
C6 C7 C11 C12 -2.5(3) . . . . ?
C1 N2 C12 C4 -0.9(3) . . . . ?
Cu1 N2 C12 C4 178.90(14) . . . . ?
C1 N2 C12 C11 175.44(16) . . . . ?
Cu1 N2 C12 C11 -4.79(19) . . . . ?
C3 C4 C12 N2 0.1(3) . . . . ?
C5 C4 C12 N2 178.07(16) . . . . ?
C3 C4 C12 C11 -176.07(16) . . . . ?
C5 C4 C12 C11 1.9(3) . . . . ?
N1 C11 C12 N2 0.7(2) . . . . ?
C7 C11 C12 N2 -175.70(16) . . . . ?
N1 C11 C12 C4 177.10(15) . . . . ?
C7 C11 C12 C4 0.7(3) . . . . ?
C17 N4 C13 C14 -0.5(3) . . . . ?
Cu1 N4 C13 C14 164.66(14) . . . . ?
N4 C13 C14 C15 -0.6(3) . . . . ?
C13 C14 C15 C16 0.9(3) . . . . ?
C14 C15 C16 C17 -0.2(3) . . . . ?
C13 N4 C17 C16 1.3(3) . . . . ?
Cu1 N4 C17 C16 -164.24(14) . . . . ?
C13 N4 C17 C18 -179.46(16) . . . . ?
Cu1 N4 C17 C18 15.0(2) . . . . ?
C15 C16 C17 N4 -1.0(3) . . . . ?
C15 C16 C17 C18 179.85(17) . . . . ?
N4 C17 C18 C19 -69.9(2) . . . . ?
C16 C17 C18 C19 109.3(2) . . . . ?
C20 N3 C19 C18 -161.20(16) . . . . ?
Cu1 N3 C19 C18 14.8(2) . . . . ?
C17 C18 C19 N3 53.4(2) . . . . ?
C19 N3 C20 C21 174.34(17) . . . . ?
Cu1 N3 C20 C21 -1.5(3) . . . . ?
N3 C20 C21 C22 170.93(18) . . . . ?
N3 C20 C21 C26 -13.0(3) . . . . ?
C26 C21 C22 C23 0.6(3) . . . . ?
C20 C21 C22 C23 176.81(18) . . . . ?
C21 C22 C23 C24 -1.8(3) . . . . ?
C22 C23 C24 C25 0.8(3) . . . . ?
C23 C24 C25 C26 1.4(3) . . . . ?
Cu1 O1 C26 C25 -165.05(13) . . . . ?
Cu1 O1 C26 C21 14.8(2) . . . . ?
C24 C25 C26 O1 177.35(17) . . . . ?
C24 C25 C26 C21 -2.5(3) . . . . ?
C22 C21 C26 O1 -178.35(17) . . . . ?
C20 C21 C26 O1 5.7(3) . . . . ?
C22 C21 C26 C25 1.5(3) . . . . ?
C20 C21 C26 C25 -174.47(16) . . . . ?

_refine_diff_density_max         0.474
_refine_diff_density_min         -0.313
_refine_diff_density_rms         0.053



