# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_99
_database_code_depnum_ccdc_archive 'CCDC 2409564'
loop_
_audit_author_name
_audit_author_address
'Zheng Wang'
;xian longzheng chemistry
China
;
_audit_update_record             
;
2024-12-12 deposited with the CCDC.	2026-01-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H35 Ag6 F9 N2 O6'
_chemical_formula_weight         1385.86

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.3257 6.8362 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   17.68875(19)
_cell_length_b                   17.4738(2)
_cell_length_c                   26.8601(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     8302.20(16)
_cell_formula_units_Z            8
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    10007
_cell_measurement_theta_min      4.1160
_cell_measurement_theta_max      73.8130

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.218
_exptl_crystal_F_000             5312
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.150
_exptl_absorpt_coefficient_mu    23.023
_shelx_estimated_absorpt_T_min   0.104
_shelx_estimated_absorpt_T_max   0.130
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  angilent
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            16455
_diffrn_reflns_av_unetI/netI     0.0584
_diffrn_reflns_av_R_equivalents  0.0617
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         3.918
_diffrn_reflns_theta_max         66.002
_diffrn_reflns_theta_full        66.002
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             7203
_reflns_number_gt                6543
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0001P)²+1085.2308P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7203
_refine_ls_number_parameters     550
_refine_ls_number_restraints     226
_refine_ls_R_factor_all          0.1167
_refine_ls_R_factor_gt           0.1115
_refine_ls_wR_factor_ref         0.2473
_refine_ls_wR_factor_gt          0.2448
_refine_ls_goodness_of_fit_ref   1.192
_refine_ls_restrained_S_all      1.218
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag4 Ag 0.93892(7) 0.39875(7) 0.49254(5) 0.0129(3) Uani 1 1 d . U . . .
Ag1 Ag 0.92226(8) 0.64780(8) 0.55794(5) 0.0179(3) Uani 1 1 d . . . . .
Ag6 Ag 0.94247(8) 0.65874(8) 0.44602(5) 0.0183(3) Uani 1 1 d . U . . .
Ag3 Ag 0.83583(8) 0.49751(8) 0.54561(5) 0.0197(3) Uani 1 1 d . . . . .
Ag5 Ag 0.85225(8) 0.50585(8) 0.43526(5) 0.0203(3) Uani 1 1 d . U . . .
Ag2 Ag 0.98585(9) 0.49424(9) 0.59752(6) 0.0278(4) Uani 1 1 d . . . . .
F6 F 1.0593(13) 0.9082(10) 0.4896(6) 0.073(6) Uani 1 1 d . . . . .
O6 O 0.8445(10) 0.6638(9) 0.6275(6) 0.034(4) Uani 1 1 d . . . . .
O1 O 0.8842(9) 0.5655(9) 0.3544(6) 0.032(4) Uani 1 1 d . U . . .
O2 O 0.8857(9) 0.6916(8) 0.3704(5) 0.024(3) Uani 1 1 d . . . . .
F5 F 1.0439(11) 0.9002(10) 0.5675(6) 0.061(5) Uani 1 1 d . . . . .
O3 O 0.9919(10) 0.7742(9) 0.4752(6) 0.037(4) Uani 1 1 d . . . . .
F4 F 0.9527(12) 0.9297(9) 0.5239(9) 0.074(6) Uani 1 1 d . . . . .
O4 O 0.9627(10) 0.7723(8) 0.5571(5) 0.033(4) Uani 1 1 d . . . . .
C7 C 0.9213(10) 0.3897(10) 0.5700(7) 0.010(3) Uani 1 1 d . U . . .
C13 C 0.9496(10) 0.3991(10) 0.4138(7) 0.010(3) Uani 1 1 d . U . . .
N2 N 0.2769(11) 0.5397(11) 0.4239(7) 0.029(4) Uani 1 1 d . U . . .
O5 O 0.8558(10) 0.5359(9) 0.6374(6) 0.036(4) Uani 1 1 d . . . . .
C1 C 0.8426(12) 0.5982(12) 0.4941(8) 0.022(4) Uani 1 1 d . U . . .
N1 N 0.7508(11) 0.4486(12) 0.4009(7) 0.034(5) Uani 1 1 d . . . . .
F8 F 0.7841(10) 0.6665(10) 0.7196(7) 0.058(3) Uani 1 1 d . U . . .
C2 C 0.8063(12) 0.6540(13) 0.4917(8) 0.027(5) Uani 1 1 d . U . . .
C8 C 0.9113(10) 0.3680(10) 0.6122(7) 0.011(4) Uani 1 1 d . U . . .
C33 C 0.3814(13) 0.5826(15) 0.3597(8) 0.033(5) Uani 1 1 d . . . . .
H33A H 0.4021 0.6323 0.3710 0.039 Uiso 1 1 calc R U . . .
H33B H 0.3571 0.5910 0.3269 0.039 Uiso 1 1 calc R U . . .
F9 F 0.7863(10) 0.5468(10) 0.7238(7) 0.059(3) Uani 1 1 d . U . . .
C30 C 0.4455(13) 0.5269(13) 0.3534(7) 0.026(5) Uani 1 1 d . . . . .
C4 C 0.7527(14) 0.7199(15) 0.4908(8) 0.034(6) Uani 1 1 d . . . . .
C25 C 0.7041(11) 0.4192(13) 0.3770(7) 0.022(4) Uani 1 1 d . . . . .
C11 C 0.9297(13) 0.3817(13) 0.7028(9) 0.029(5) Uani 1 1 d . U . . .
H11A H 0.9848 0.3765 0.7010 0.043 Uiso 1 1 calc R U . . .
H11B H 0.9118 0.3632 0.7352 0.043 Uiso 1 1 calc R U . . .
H11C H 0.9157 0.4356 0.6988 0.043 Uiso 1 1 calc R U . . .
C27 C 0.5736(11) 0.4333(11) 0.3473(7) 0.018(4) Uani 1 1 d . U . . .
C22 C 1.0100(16) 0.8843(14) 0.5223(10) 0.040(6) Uani 1 1 d . . . . .
C9 C 0.8927(11) 0.3336(11) 0.6605(7) 0.017(4) Uani 1 1 d . U . . .
C29 C 0.4501(13) 0.4574(12) 0.3797(8) 0.026(5) Uani 1 1 d . U . . .
H29 H 0.4088 0.4416 0.3998 0.031 Uiso 1 1 calc R U . . .
C28 C 0.5138(12) 0.4120(12) 0.3768(8) 0.022(4) Uani 1 1 d . . . . .
H28 H 0.5162 0.3657 0.3953 0.026 Uiso 1 1 calc R U . . .
F7 F 0.7074(10) 0.6042(10) 0.6791(7) 0.058(3) Uani 1 1 d . U . . .
C31 C 0.5059(11) 0.5460(12) 0.3231(8) 0.023(4) Uani 1 1 d . U . . .
H31 H 0.5031 0.5916 0.3039 0.027 Uiso 1 1 calc R U . . .
C21 C 0.9877(13) 0.8022(12) 0.5167(9) 0.027(5) Uani 1 1 d . . . . .
C34 C 0.3228(12) 0.5571(14) 0.3958(8) 0.028(5) Uani 1 1 d . . . . .
C10 C 0.8069(11) 0.3370(12) 0.6688(8) 0.023(4) Uani 1 1 d . U . . .
H10A H 0.7915 0.3902 0.6741 0.035 Uiso 1 1 calc R U . . .
H10B H 0.7935 0.3064 0.6980 0.035 Uiso 1 1 calc R U . . .
H10C H 0.7809 0.3166 0.6394 0.035 Uiso 1 1 calc R U . . .
C15 C 0.9393(11) 0.3506(11) 0.3207(8) 0.020(4) Uani 1 1 d . U . . .
C12 C 0.9227(11) 0.2523(12) 0.6605(8) 0.023(4) Uani 1 1 d . U . . .
H12A H 0.8966 0.2225 0.6347 0.034 Uiso 1 1 calc R U . . .
H12B H 0.9137 0.2288 0.6931 0.034 Uiso 1 1 calc R U . . .
H12C H 0.9770 0.2529 0.6535 0.034 Uiso 1 1 calc R U . . .
C19 C 0.8680(11) 0.6331(11) 0.3454(8) 0.019(4) Uani 1 1 d . U . . .
C14 C 0.9473(11) 0.3792(11) 0.3720(8) 0.020(4) Uani 1 1 d . U . . .
C23 C 0.8316(18) 0.6007(18) 0.6490(12) 0.053(3) Uani 1 1 d . U . . .
C3 C 0.7056(16) 0.7136(18) 0.4426(9) 0.047(7) Uani 1 1 d . . . . .
H3A H 0.7372 0.7268 0.4139 0.070 Uiso 1 1 calc R U . . .
H3B H 0.6626 0.7488 0.4444 0.070 Uiso 1 1 calc R U . . .
H3C H 0.6869 0.6610 0.4389 0.070 Uiso 1 1 calc R U . . .
C26 C 0.6454(12) 0.3855(13) 0.3459(9) 0.026(5) Uani 1 1 d . U . . .
H26A H 0.6342 0.3331 0.3577 0.032 Uiso 1 1 calc R U . . .
H26B H 0.6638 0.3819 0.3112 0.032 Uiso 1 1 calc R U . . .
C24 C 0.7752(18) 0.6039(19) 0.6935(12) 0.055(2) Uani 1 1 d . U . . .
C5 C 0.7921(17) 0.7967(15) 0.4931(15) 0.062(10) Uani 1 1 d . . . . .
H5A H 0.8234 0.7991 0.5231 0.093 Uiso 1 1 calc R U . . .
H5B H 0.7542 0.8376 0.4940 0.093 Uiso 1 1 calc R U . . .
H5C H 0.8241 0.8030 0.4636 0.093 Uiso 1 1 calc R U . . .
C32 C 0.5699(14) 0.5014(13) 0.3197(7) 0.028(5) Uani 1 1 d . . . . .
H32 H 0.6109 0.5165 0.2991 0.033 Uiso 1 1 calc R U . . .
C16 C 0.8570(17) 0.3396(18) 0.3088(12) 0.052(7) Uani 1 1 d . U . . .
H16A H 0.8334 0.3084 0.3348 0.078 Uiso 1 1 calc R U . . .
H16B H 0.8521 0.3137 0.2766 0.078 Uiso 1 1 calc R U . . .
H16C H 0.8320 0.3896 0.3072 0.078 Uiso 1 1 calc R U . . .
C18 C 0.9832(17) 0.2754(17) 0.3174(12) 0.052(7) Uani 1 1 d . U . . .
H18A H 1.0355 0.2838 0.3281 0.078 Uiso 1 1 calc R U . . .
H18B H 0.9828 0.2569 0.2830 0.078 Uiso 1 1 calc R U . . .
H18C H 0.9594 0.2372 0.3391 0.078 Uiso 1 1 calc R U . . .
C17 C 0.9774(15) 0.4074(16) 0.2844(10) 0.043(6) Uani 1 1 d . U . . .
H17A H 0.9499 0.4561 0.2848 0.064 Uiso 1 1 calc R U . . .
H17B H 0.9767 0.3860 0.2506 0.064 Uiso 1 1 calc R U . . .
H17C H 1.0299 0.4160 0.2947 0.064 Uiso 1 1 calc R U . . .
C6 C 0.7004(17) 0.709(2) 0.5378(10) 0.056(9) Uani 1 1 d . . . . .
H6A H 0.6762 0.6588 0.5364 0.084 Uiso 1 1 calc R U . . .
H6B H 0.6616 0.7492 0.5381 0.084 Uiso 1 1 calc R U . . .
H6C H 0.7311 0.7129 0.5681 0.084 Uiso 1 1 calc R U . . .
C20 C 0.8257(16) 0.6499(16) 0.2970(10) 0.043(6) Uani 1 1 d . U . . .
F1 F 0.765(3) 0.685(3) 0.3019(17) 0.066(13) Uani 0.5 1 d . U P A 1
F2 F 0.874(2) 0.691(2) 0.2660(12) 0.062(9) Uani 0.5 1 d . U P A 1
F3 F 0.816(2) 0.589(2) 0.2697(14) 0.054(8) Uani 0.5 1 d . U P A 1
F2A F 0.860(3) 0.627(3) 0.2597(14) 0.076(11) Uani 0.5 1 d . U P A 2
F3A F 0.767(3) 0.600(3) 0.2925(17) 0.081(12) Uani 0.5 1 d . U P A 2
F1A F 0.791(2) 0.713(2) 0.2963(15) 0.050(10) Uani 0.5 1 d . U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag4 C7 2.110(18) . ?
Ag4 C13 2.123(18) . ?
Ag4 Ag6 2.8520(19) 5_766 ?
Ag4 Ag5 2.8670(19) . ?
Ag4 Ag3 2.8871(19) . ?
Ag4 Ag1 2.9205(19) 5_766 ?
Ag4 Ag2 3.334(2) 5_766 ?
Ag1 O4 2.290(15) . ?
Ag1 O6 2.337(16) . ?
Ag1 C1 2.38(2) . ?
Ag1 C13 2.527(17) 5_766 ?
Ag1 Ag4 2.9205(19) 5_766 ?
Ag1 Ag6 3.0332(18) . ?
Ag1 Ag3 3.057(2) . ?
Ag1 Ag2 3.098(2) . ?
Ag6 O3 2.334(16) . ?
Ag6 O2 2.339(14) . ?
Ag6 C1 2.43(2) . ?
Ag6 C7 2.590(17) 5_766 ?
Ag6 C2 2.70(2) . ?
Ag6 Ag4 2.8520(19) 5_766 ?
Ag6 Ag5 3.125(2) . ?
Ag6 Ag2 3.181(2) 5_766 ?
Ag3 C1 2.24(2) . ?
Ag3 N2 2.251(19) 5_666 ?
Ag3 C7 2.503(17) . ?
Ag3 O5 2.580(16) . ?
Ag3 Ag5 2.9817(19) . ?
Ag3 Ag2 2.998(2) . ?
Ag5 N1 2.25(2) . ?
Ag5 C1 2.27(2) . ?
Ag5 O1 2.476(16) . ?
Ag5 C13 2.603(17) . ?
Ag5 Ag2 2.996(2) 5_766 ?
Ag2 C13 2.206(17) 5_766 ?
Ag2 C7 2.277(17) . ?
Ag2 C8 2.600(18) . ?
Ag2 C14 2.64(2) 5_766 ?
Ag2 Ag5 2.996(2) 5_766 ?
Ag2 Ag6 3.181(2) 5_766 ?
Ag2 Ag4 3.334(2) 5_766 ?
F6 C22 1.31(3) . ?
O6 C23 1.26(3) . ?
O1 C19 1.24(3) . ?
O2 C19 1.26(2) . ?
F5 C22 1.38(3) . ?
O3 C21 1.22(3) . ?
F4 C22 1.29(3) . ?
O4 C21 1.28(3) . ?
C7 C8 1.21(3) . ?
C7 Ag6 2.590(17) 5_766 ?
C13 C14 1.18(3) . ?
C13 Ag2 2.206(17) 5_766 ?
C13 Ag1 2.527(17) 5_766 ?
N2 C34 1.15(3) . ?
N2 Ag3 2.251(19) 5_666 ?
O5 C23 1.25(3) . ?
C1 C2 1.17(3) . ?
N1 C25 1.17(3) . ?
F8 C24 1.31(4) . ?
C2 C4 1.49(3) . ?
C8 C9 1.47(3) . ?
C33 C34 1.49(3) . ?
C33 C30 1.50(3) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
F9 C24 1.30(4) . ?
C30 C31 1.38(3) . ?
C30 C29 1.41(3) . ?
C4 C5 1.51(4) . ?
C4 C3 1.54(3) . ?
C4 C6 1.58(4) . ?
C25 C26 1.46(3) . ?
C11 C9 1.56(3) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C27 C28 1.37(3) . ?
C27 C32 1.40(3) . ?
C27 C26 1.52(3) . ?
C22 C21 1.50(3) . ?
C9 C12 1.52(3) . ?
C9 C10 1.53(3) . ?
C29 C28 1.38(3) . ?
C29 H29 0.9500 . ?
C28 H28 0.9500 . ?
F7 C24 1.26(4) . ?
C31 C32 1.38(3) . ?
C31 H31 0.9500 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C15 C14 1.47(3) . ?
C15 C16 1.50(3) . ?
C15 C18 1.53(3) . ?
C15 C17 1.55(3) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C19 C20 1.53(3) . ?
C14 Ag2 2.64(2) 5_766 ?
C23 C24 1.56(4) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C32 H32 0.9500 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C20 F2A 1.24(5) . ?
C20 F1 1.25(5) . ?
C20 F1A 1.27(5) . ?
C20 F3 1.30(4) . ?
C20 F3A 1.37(5) . ?
C20 F2 1.39(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Ag4 C13 174.7(7) . . ?
C7 Ag4 Ag6 60.8(5) . 5_766 ?
C13 Ag4 Ag6 120.8(5) . 5_766 ?
C7 Ag4 Ag5 119.9(5) . . ?
C13 Ag4 Ag5 60.7(5) . . ?
Ag6 Ag4 Ag5 159.03(6) 5_766 . ?
C7 Ag4 Ag3 57.6(5) . . ?
C13 Ag4 Ag3 123.1(5) . . ?
Ag6 Ag4 Ag3 112.92(6) 5_766 . ?
Ag5 Ag4 Ag3 62.42(5) . . ?
C7 Ag4 Ag1 124.1(5) . 5_766 ?
C13 Ag4 Ag1 57.6(5) . 5_766 ?
Ag6 Ag4 Ag1 63.38(5) 5_766 5_766 ?
Ag5 Ag4 Ag1 112.48(6) . 5_766 ?
Ag3 Ag4 Ag1 157.93(6) . 5_766 ?
C7 Ag4 Ag2 144.7(5) . 5_766 ?
C13 Ag4 Ag2 40.5(5) . 5_766 ?
Ag6 Ag4 Ag2 108.89(6) 5_766 5_766 ?
Ag5 Ag4 Ag2 57.19(5) . 5_766 ?
Ag3 Ag4 Ag2 105.97(5) . 5_766 ?
Ag1 Ag4 Ag2 58.93(5) 5_766 5_766 ?
O4 Ag1 O6 94.5(6) . . ?
O4 Ag1 C1 121.6(6) . . ?
O6 Ag1 C1 105.7(7) . . ?
O4 Ag1 C13 91.8(6) . 5_766 ?
O6 Ag1 C13 109.0(6) . 5_766 ?
C1 Ag1 C13 128.9(6) . 5_766 ?
O4 Ag1 Ag4 89.9(4) . 5_766 ?
O6 Ag1 Ag4 154.1(4) . 5_766 ?
C1 Ag1 Ag4 93.5(5) . 5_766 ?
C13 Ag1 Ag4 45.2(4) 5_766 5_766 ?
O4 Ag1 Ag6 83.9(4) . . ?
O6 Ag1 Ag6 148.7(4) . . ?
C1 Ag1 Ag6 51.7(5) . . ?
C13 Ag1 Ag6 102.3(4) 5_766 . ?
Ag4 Ag1 Ag6 57.21(4) 5_766 . ?
O4 Ag1 Ag3 166.2(4) . . ?
O6 Ag1 Ag3 84.0(4) . . ?
C1 Ag1 Ag3 46.6(5) . . ?
C13 Ag1 Ag3 101.7(4) 5_766 . ?
Ag4 Ag1 Ag3 97.52(5) 5_766 . ?
Ag6 Ag1 Ag3 90.33(5) . . ?
O4 Ag1 Ag2 135.5(4) . . ?
O6 Ag1 Ag2 92.4(4) . . ?
C1 Ag1 Ag2 98.4(5) . . ?
C13 Ag1 Ag2 44.8(4) 5_766 . ?
Ag4 Ag1 Ag2 67.22(5) 5_766 . ?
Ag6 Ag1 Ag2 110.61(6) . . ?
Ag3 Ag1 Ag2 58.30(5) . . ?
O3 Ag6 O2 103.9(6) . . ?
O3 Ag6 C1 118.1(6) . . ?
O2 Ag6 C1 104.9(6) . . ?
O3 Ag6 C7 89.4(6) . 5_766 ?
O2 Ag6 C7 109.6(5) . 5_766 ?
C1 Ag6 C7 128.4(6) . 5_766 ?
O3 Ag6 C2 102.0(6) . . ?
O2 Ag6 C2 91.1(6) . . ?
C1 Ag6 C2 25.6(7) . . ?
C7 Ag6 C2 153.4(6) 5_766 . ?
O3 Ag6 Ag4 80.5(5) . 5_766 ?
O2 Ag6 Ag4 154.9(4) . 5_766 ?
C1 Ag6 Ag4 94.2(5) . 5_766 ?
C7 Ag6 Ag4 45.3(4) 5_766 5_766 ?
C2 Ag6 Ag4 112.5(5) . 5_766 ?
O3 Ag6 Ag1 76.5(4) . . ?
O2 Ag6 Ag1 145.7(4) . . ?
C1 Ag6 Ag1 50.2(5) . . ?
C7 Ag6 Ag1 104.7(4) 5_766 . ?
C2 Ag6 Ag1 56.2(5) . . ?
Ag4 Ag6 Ag1 59.41(5) 5_766 . ?
O3 Ag6 Ag5 164.0(4) . . ?
O2 Ag6 Ag5 84.8(4) . . ?
C1 Ag6 Ag5 46.0(5) . . ?
C7 Ag6 Ag5 100.4(4) 5_766 . ?
C2 Ag6 Ag5 64.0(5) . . ?
Ag4 Ag6 Ag5 97.36(5) 5_766 . ?
Ag1 Ag6 Ag5 88.72(5) . . ?
O3 Ag6 Ag2 134.4(4) . 5_766 ?
O2 Ag6 Ag2 93.3(3) . 5_766 ?
C1 Ag6 Ag2 96.8(5) . 5_766 ?
C7 Ag6 Ag2 45.0(4) 5_766 5_766 ?
C2 Ag6 Ag2 119.7(5) . 5_766 ?
Ag4 Ag6 Ag2 67.89(5) 5_766 5_766 ?
Ag1 Ag6 Ag2 111.00(6) . 5_766 ?
Ag5 Ag6 Ag2 56.72(5) . 5_766 ?
C1 Ag3 N2 119.9(7) . 5_666 ?
C1 Ag3 C7 136.0(7) . . ?
N2 Ag3 C7 102.9(6) 5_666 . ?
C1 Ag3 O5 112.2(7) . . ?
N2 Ag3 O5 81.3(6) 5_666 . ?
C7 Ag3 O5 82.1(5) . . ?
C1 Ag3 Ag4 97.5(5) . . ?
N2 Ag3 Ag4 124.5(5) 5_666 . ?
C7 Ag3 Ag4 45.4(4) . . ?
O5 Ag3 Ag4 122.7(4) . . ?
C1 Ag3 Ag5 48.9(5) . . ?
N2 Ag3 Ag5 117.5(5) 5_666 . ?
C7 Ag3 Ag5 103.8(4) . . ?
O5 Ag3 Ag5 157.5(4) . . ?
Ag4 Ag3 Ag5 58.46(5) . . ?
C1 Ag3 Ag2 104.7(5) . . ?
N2 Ag3 Ag2 127.5(5) 5_666 . ?
C7 Ag3 Ag2 47.9(4) . . ?
O5 Ag3 Ag2 55.9(4) . . ?
Ag4 Ag3 Ag2 70.08(5) . . ?
Ag5 Ag3 Ag2 112.15(6) . . ?
C1 Ag3 Ag1 50.6(5) . . ?
N2 Ag3 Ag1 130.6(5) 5_666 . ?
C7 Ag3 Ag1 108.4(4) . . ?
O5 Ag3 Ag1 66.7(4) . . ?
Ag4 Ag3 Ag1 104.54(6) . . ?
Ag5 Ag3 Ag1 90.97(5) . . ?
Ag2 Ag3 Ag1 61.53(5) . . ?
N1 Ag5 C1 122.8(7) . . ?
N1 Ag5 O1 90.5(6) . . ?
C1 Ag5 O1 109.3(7) . . ?
N1 Ag5 C13 96.8(6) . . ?
C1 Ag5 C13 135.6(7) . . ?
O1 Ag5 C13 87.5(5) . . ?
N1 Ag5 Ag4 110.9(5) . . ?
C1 Ag5 Ag4 97.5(5) . . ?
O1 Ag5 Ag4 128.6(4) . . ?
C13 Ag5 Ag4 45.4(4) . . ?
N1 Ag5 Ag3 107.9(5) . . ?
C1 Ag5 Ag3 48.2(5) . . ?
O1 Ag5 Ag3 156.3(4) . . ?
C13 Ag5 Ag3 104.4(4) . . ?
Ag4 Ag5 Ag3 59.12(5) . . ?
N1 Ag5 Ag2 129.9(5) . 5_766 ?
C1 Ag5 Ag2 106.1(5) . 5_766 ?
O1 Ag5 Ag2 61.6(4) . 5_766 ?
C13 Ag5 Ag2 45.7(4) . 5_766 ?
Ag4 Ag5 Ag2 69.28(5) . 5_766 ?
Ag3 Ag5 Ag2 112.66(6) . 5_766 ?
N1 Ag5 Ag6 145.5(5) . . ?
C1 Ag5 Ag6 50.6(5) . . ?
O1 Ag5 Ag6 66.7(4) . . ?
C13 Ag5 Ag6 107.2(4) . . ?
Ag4 Ag5 Ag6 103.61(6) . . ?
Ag3 Ag5 Ag6 89.98(5) . . ?
Ag2 Ag5 Ag6 62.58(5) 5_766 . ?
C13 Ag2 C7 153.1(6) 5_766 . ?
C13 Ag2 C8 179.0(6) 5_766 . ?
C7 Ag2 C8 27.7(6) . . ?
C13 Ag2 C14 26.2(7) 5_766 5_766 ?
C7 Ag2 C14 176.2(6) . 5_766 ?
C8 Ag2 C14 153.1(6) . 5_766 ?
C13 Ag2 Ag5 57.7(4) 5_766 5_766 ?
C7 Ag2 Ag5 112.5(4) . 5_766 ?
C8 Ag2 Ag5 121.9(4) . 5_766 ?
C14 Ag2 Ag5 70.3(4) 5_766 5_766 ?
C13 Ag2 Ag3 112.2(5) 5_766 . ?
C7 Ag2 Ag3 54.6(4) . . ?
C8 Ag2 Ag3 68.8(4) . . ?
C14 Ag2 Ag3 121.7(4) 5_766 . ?
Ag5 Ag2 Ag3 135.18(7) 5_766 . ?
C13 Ag2 Ag1 53.8(5) 5_766 . ?
C7 Ag2 Ag1 113.7(4) . . ?
C8 Ag2 Ag1 127.1(4) . . ?
C14 Ag2 Ag1 62.8(4) 5_766 . ?
Ag5 Ag2 Ag1 104.28(6) 5_766 . ?
Ag3 Ag2 Ag1 60.16(5) . . ?
C13 Ag2 Ag6 116.9(5) 5_766 5_766 ?
C7 Ag2 Ag6 53.6(4) . 5_766 ?
C8 Ag2 Ag6 62.9(4) . 5_766 ?
C14 Ag2 Ag6 129.8(4) 5_766 5_766 ?
Ag5 Ag2 Ag6 60.70(5) 5_766 5_766 ?
Ag3 Ag2 Ag6 101.41(6) . 5_766 ?
Ag1 Ag2 Ag6 138.27(6) . 5_766 ?
C13 Ag2 Ag4 38.7(5) 5_766 5_766 ?
C7 Ag2 Ag4 114.5(4) . 5_766 ?
C8 Ag2 Ag4 142.0(4) . 5_766 ?
C14 Ag2 Ag4 64.9(4) 5_766 5_766 ?
Ag5 Ag2 Ag4 53.53(4) 5_766 5_766 ?
Ag3 Ag2 Ag4 90.29(5) . 5_766 ?
Ag1 Ag2 Ag4 53.85(4) . 5_766 ?
Ag6 Ag2 Ag4 92.60(5) 5_766 5_766 ?
C23 O6 Ag1 111.5(18) . . ?
C19 O1 Ag5 121.3(14) . . ?
C19 O2 Ag6 111.7(12) . . ?
C21 O3 Ag6 129.1(14) . . ?
C21 O4 Ag1 120.2(13) . . ?
C8 C7 Ag4 165.9(15) . . ?
C8 C7 Ag2 91.2(13) . . ?
Ag4 C7 Ag2 100.7(7) . . ?
C8 C7 Ag3 113.2(13) . . ?
Ag4 C7 Ag3 77.0(5) . . ?
Ag2 C7 Ag3 77.5(5) . . ?
C8 C7 Ag6 100.9(13) . 5_766 ?
Ag4 C7 Ag6 73.9(5) . 5_766 ?
Ag2 C7 Ag6 81.4(5) . 5_766 ?
Ag3 C7 Ag6 139.9(7) . 5_766 ?
C14 C13 Ag4 161.2(16) . . ?
C14 C13 Ag2 97.9(14) . 5_766 ?
Ag4 C13 Ag2 100.7(7) . 5_766 ?
C14 C13 Ag1 102.8(14) . 5_766 ?
Ag4 C13 Ag1 77.3(5) . 5_766 ?
Ag2 C13 Ag1 81.5(5) 5_766 5_766 ?
C14 C13 Ag5 113.6(15) . . ?
Ag4 C13 Ag5 73.9(5) . . ?
Ag2 C13 Ag5 76.6(5) 5_766 . ?
Ag1 C13 Ag5 139.4(7) 5_766 . ?
C34 N2 Ag3 160.2(17) . 5_666 ?
C23 O5 Ag3 115.2(18) . . ?
C2 C1 Ag3 131.3(18) . . ?
C2 C1 Ag5 126.6(18) . . ?
Ag3 C1 Ag5 82.9(7) . . ?
C2 C1 Ag1 93.5(16) . . ?
Ag3 C1 Ag1 82.7(7) . . ?
Ag5 C1 Ag1 135.8(9) . . ?
C2 C1 Ag6 90.4(16) . . ?
Ag3 C1 Ag6 135.1(9) . . ?
Ag5 C1 Ag6 83.4(7) . . ?
Ag1 C1 Ag6 78.1(6) . . ?
C25 N1 Ag5 170.4(17) . . ?
C1 C2 C4 174(3) . . ?
C1 C2 Ag6 64.0(14) . . ?
C4 C2 Ag6 122.3(16) . . ?
C7 C8 C9 172.3(19) . . ?
C7 C8 Ag2 61.1(11) . . ?
C9 C8 Ag2 126.5(12) . . ?
C34 C33 C30 114(2) . . ?
C34 C33 H33A 108.8 . . ?
C30 C33 H33A 108.8 . . ?
C34 C33 H33B 108.8 . . ?
C30 C33 H33B 108.8 . . ?
H33A C33 H33B 107.7 . . ?
C31 C30 C29 117(2) . . ?
C31 C30 C33 120(2) . . ?
C29 C30 C33 123(2) . . ?
C2 C4 C5 113(2) . . ?
C2 C4 C3 108(2) . . ?
C5 C4 C3 110(2) . . ?
C2 C4 C6 106(2) . . ?
C5 C4 C6 110(2) . . ?
C3 C4 C6 110(2) . . ?
N1 C25 C26 177(2) . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C28 C27 C32 119.9(19) . . ?
C28 C27 C26 120.6(18) . . ?
C32 C27 C26 119.4(19) . . ?
F4 C22 F6 110(2) . . ?
F4 C22 F5 101(2) . . ?
F6 C22 F5 104(2) . . ?
F4 C22 C21 113(2) . . ?
F6 C22 C21 115(2) . . ?
F5 C22 C21 113(2) . . ?
C8 C9 C12 107.7(16) . . ?
C8 C9 C10 109.5(16) . . ?
C12 C9 C10 112.5(17) . . ?
C8 C9 C11 109.2(16) . . ?
C12 C9 C11 111.1(17) . . ?
C10 C9 C11 106.8(17) . . ?
C28 C29 C30 121(2) . . ?
C28 C29 H29 119.5 . . ?
C30 C29 H29 119.5 . . ?
C27 C28 C29 120(2) . . ?
C27 C28 H28 119.8 . . ?
C29 C28 H28 119.8 . . ?
C32 C31 C30 122(2) . . ?
C32 C31 H31 118.8 . . ?
C30 C31 H31 118.8 . . ?
O3 C21 O4 129(2) . . ?
O3 C21 C22 117(2) . . ?
O4 C21 C22 113(2) . . ?
N2 C34 C33 178(3) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C14 C15 C16 109.6(19) . . ?
C14 C15 C18 107.3(19) . . ?
C16 C15 C18 112(2) . . ?
C14 C15 C17 109.3(18) . . ?
C16 C15 C17 112(2) . . ?
C18 C15 C17 107(2) . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
O1 C19 O2 127.7(19) . . ?
O1 C19 C20 117.5(19) . . ?
O2 C19 C20 114.7(19) . . ?
C13 C14 C15 176(2) . . ?
C13 C14 Ag2 55.9(12) . 5_766 ?
C15 C14 Ag2 128.2(14) . 5_766 ?
O5 C23 O6 128(3) . . ?
O5 C23 C24 116(3) . . ?
O6 C23 C24 116(3) . . ?
C4 C3 H3A 109.5 . . ?
C4 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C4 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C25 C26 C27 111.0(18) . . ?
C25 C26 H26A 109.4 . . ?
C27 C26 H26A 109.4 . . ?
C25 C26 H26B 109.4 . . ?
C27 C26 H26B 109.4 . . ?
H26A C26 H26B 108.0 . . ?
F7 C24 F9 110(3) . . ?
F7 C24 F8 106(3) . . ?
F9 C24 F8 107(3) . . ?
F7 C24 C23 112(3) . . ?
F9 C24 C23 111(3) . . ?
F8 C24 C23 111(3) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C31 C32 C27 119(2) . . ?
C31 C32 H32 120.5 . . ?
C27 C32 H32 120.5 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C4 C6 H6A 109.5 . . ?
C4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
F2A C20 F1A 120(4) . . ?
F1 C20 F3 110(4) . . ?
F2A C20 F3A 96(4) . . ?
F1A C20 F3A 101(3) . . ?
F1 C20 F2 110(4) . . ?
F3 C20 F2 99(3) . . ?
F2A C20 C19 113(3) . . ?
F1 C20 C19 115(3) . . ?
F1A C20 C19 115(3) . . ?
F3 C20 C19 113(3) . . ?
F3A C20 C19 109(3) . . ?
F2 C20 C19 108(2) . . ?

_refine_diff_density_max         4.654
_refine_diff_density_min         -4.167
_refine_diff_density_rms         0.558



