# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_s142_1_s
_audit_block_doi                 10.25505/fiz.icsd.cc2pzjfn
_database_code_depnum_ccdc_archive 'CCDC 2501992'
loop_
_audit_author_name
_audit_author_address
'Jia Wang'
;XinJiang Technical Institute of Physics and Chemistry Chinese Academy of Sciences
China
;
_audit_update_record             
;
2025-11-11 deposited with the CCDC.	2025-12-22 downloaded from the CCDC.
;
_audit_creation_date             2025-06-12
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'F2 Na2 O4 S Sn'
_chemical_formula_sum            'F2 Na2 O4 S Sn'
_chemical_formula_weight         298.73
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   7.0381(17)
_cell_length_b                   5.5378(12)
_cell_length_c                   14.505(3)
_cell_angle_alpha                90
_cell_angle_beta                 92.650(9)
_cell_angle_gamma                90
_cell_volume                     564.7(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4290
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      27.52
_cell_measurement_theta_min      2.90
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.034
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6844
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1005 before and 0.0665 after correction.
The Ratio of minimum to maximum transmission is 0.9179.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.514
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             552
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0684
_diffrn_reflns_av_unetI/netI     0.0241
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            18036
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.520
_diffrn_reflns_theta_min         2.812
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1128
_reflns_number_total             1307
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.41 (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.41 (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.869
_refine_diff_density_min         -0.654
_refine_diff_density_rms         0.133
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     91
_refine_ls_number_reflns         1307
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0249
_refine_ls_R_factor_gt           0.0202
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0277P)²+0.1422P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0495
_refine_ls_wR_factor_ref         0.0520
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.40690(3) 0.73436(3) 0.32637(2) 0.01910(9) Uani 1 1 d . . . . .
S1 S 0.28677(10) 0.72557(11) 0.55844(5) 0.01525(15) Uani 1 1 d . . . . .
Na2 Na 0.08757(17) 1.25504(17) 0.18751(8) 0.0206(3) Uani 1 1 d . . . . .
Na1 Na 0.1798(2) 0.22042(19) 0.43083(9) 0.0266(3) Uani 1 1 d . . . . .
F1 F 0.1929(2) 0.9798(3) 0.29550(11) 0.0216(3) Uani 1 1 d . . . . .
F2 F 0.1818(2) 0.5000(3) 0.31459(11) 0.0241(4) Uani 1 1 d . . . . .
O3 O 0.2083(3) 0.4814(3) 0.55915(13) 0.0286(5) Uani 1 1 d . . . . .
O4 O 0.3046(5) 0.8044(4) 0.46166(16) 0.0466(7) Uani 1 1 d . . . . .
O2 O 0.4737(4) 0.7314(4) 0.6057(2) 0.0481(8) Uani 1 1 d . . . . .
O1 O 0.1586(4) 0.8948(4) 0.5986(2) 0.0500(7) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 Na2 3.4786(15) 2_545 ?
Sn1 Na2 3.5747(15) 2_645 ?
Sn1 Na1 3.5100(13) 1_565 ?
Sn1 Na1 3.6298(13) . ?
Sn1 F1 2.0624(16) . ?
Sn1 F2 2.0491(16) . ?
Sn1 O4 2.156(2) . ?
S1 Na1 3.3725(14) 1_565 ?
S1 Na1 3.3080(18) 3_566 ?
S1 O3 1.461(2) . ?
S1 O4 1.481(2) . ?
S1 O2 1.455(3) . ?
S1 O1 1.442(2) . ?
Na2 Na2 3.5609(16) 2_545 ?
Na2 Na2 3.5609(16) 2 ?
Na2 Na1 3.5819(17) 2_565 ?
Na2 Na1 3.564(2) 1_565 ?
Na2 F1 2.2847(19) . ?
Na2 F1 2.356(2) 2 ?
Na2 F2 2.363(2) 2 ?
Na2 F2 2.359(2) 1_565 ?
Na2 O3 2.459(2) 4_575 ?
Na2 O1 2.394(2) 4_585 ?
Na1 F1 2.378(2) 1_545 ?
Na1 F2 2.290(2) . ?
Na1 O3 2.358(2) . ?
Na1 O4 2.499(3) 1_545 ?
Na1 O2 2.534(3) 3_666 ?
Na1 O1 2.483(3) 3_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Na2 Sn1 Na2 172.48(4) 2_545 2_645 ?
Na2 Sn1 Na1 65.87(3) 2_545 . ?
Na2 Sn1 Na1 61.66(3) 2_545 1_565 ?
Na2 Sn1 Na1 120.48(3) 2_645 . ?
Na1 Sn1 Na2 118.30(3) 1_565 2_645 ?
Na1 Sn1 Na1 101.71(4) 1_565 . ?
F1 Sn1 Na2 133.27(5) . 2_645 ?
F1 Sn1 Na2 41.16(5) . 2_545 ?
F1 Sn1 Na1 41.04(5) . 1_565 ?
F1 Sn1 Na1 106.02(5) . . ?
F1 Sn1 O4 78.92(9) . . ?
F2 Sn1 Na2 41.27(5) . 2_545 ?
F2 Sn1 Na2 141.57(5) . 2_645 ?
F2 Sn1 Na1 35.36(5) . . ?
F2 Sn1 Na1 98.97(5) . 1_565 ?
F2 Sn1 F1 81.10(7) . . ?
F2 Sn1 O4 84.29(9) . . ?
O4 Sn1 Na2 114.86(9) . 2_645 ?
O4 Sn1 Na2 70.83(9) . 2_545 ?
O4 Sn1 Na1 44.88(7) . 1_565 ?
O4 Sn1 Na1 65.74(7) . . ?
Na1 S1 Na1 75.84(4) 3_566 1_565 ?
O3 S1 Na1 132.93(9) . 1_565 ?
O3 S1 Na1 72.96(9) . 3_566 ?
O3 S1 O4 109.16(13) . . ?
O4 S1 Na1 98.39(13) . 3_566 ?
O4 S1 Na1 42.85(10) . 1_565 ?
O2 S1 Na1 148.56(14) . 3_566 ?
O2 S1 Na1 114.50(10) . 1_565 ?
O2 S1 O3 110.54(13) . . ?
O2 S1 O4 109.02(17) . . ?
O1 S1 Na1 64.25(12) . 1_565 ?
O1 S1 Na1 44.06(11) . 3_566 ?
O1 S1 O3 110.79(13) . . ?
O1 S1 O4 105.85(16) . . ?
O1 S1 O2 111.34(18) . . ?
Sn1 Na2 Sn1 172.48(4) 2 2_655 ?
Sn1 Na2 Na2 71.70(4) 2 2 ?
Sn1 Na2 Na2 68.59(4) 2 2_545 ?
Sn1 Na2 Na1 119.88(4) 2_655 2_565 ?
Sn1 Na2 Na1 59.60(3) 2 2_565 ?
Sn1 Na2 Na1 101.03(4) 2 1_565 ?
Na2 Na2 Sn1 114.99(4) 2 2_655 ?
Na2 Na2 Sn1 111.88(4) 2_545 2_655 ?
Na2 Na2 Na2 102.08(6) 2_545 2 ?
Na2 Na2 Na1 59.87(3) 2 2_565 ?
Na2 Na2 Na1 128.09(6) 2_545 2_565 ?
Na2 Na2 Na1 65.74(4) 2 1_565 ?
Na2 Na2 Na1 60.36(4) 2_545 1_565 ?
Na1 Na2 Sn1 85.29(4) 1_565 2_655 ?
Na1 Na2 Na1 125.51(4) 1_565 2_565 ?
F1 Na2 Sn1 108.04(5) . 2 ?
F1 Na2 Sn1 74.04(5) . 2_655 ?
F1 Na2 Sn1 35.18(4) 2 2 ?
F1 Na2 Sn1 149.73(5) 2 2_655 ?
F1 Na2 Na2 40.63(5) . 2_545 ?
F1 Na2 Na2 39.16(4) 2 2 ?
F1 Na2 Na2 106.18(7) . 2 ?
F1 Na2 Na2 92.64(6) 2 2_545 ?
F1 Na2 Na1 162.79(6) . 2_565 ?
F1 Na2 Na1 92.29(6) 2 1_565 ?
F1 Na2 Na1 41.06(5) 2 2_565 ?
F1 Na2 Na1 41.12(5) . 1_565 ?
F1 Na2 F1 121.84(6) . 2 ?
F1 Na2 F2 77.13(7) . 1_565 ?
F1 Na2 F2 81.07(7) . 2 ?
F1 Na2 F2 79.70(6) 2 1_565 ?
F1 Na2 F2 68.99(7) 2 2 ?
F1 Na2 O3 92.95(7) . 4_575 ?
F1 Na2 O3 132.90(8) 2 4_575 ?
F1 Na2 O1 79.94(8) 2 4_585 ?
F1 Na2 O1 147.19(10) . 4_585 ?
F2 Na2 Sn1 34.89(4) 2 2 ?
F2 Na2 Sn1 107.97(5) 1_565 2 ?
F2 Na2 Sn1 79.50(5) 1_565 2_655 ?
F2 Na2 Sn1 141.27(5) 2 2_655 ?
F2 Na2 Na2 41.10(5) 1_565 2 ?
F2 Na2 Na2 100.07(7) 2 2 ?
F2 Na2 Na2 98.09(7) 1_565 2_545 ?
F2 Na2 Na2 41.01(5) 2 2_545 ?
F2 Na2 Na1 39.23(5) 1_565 1_565 ?
F2 Na2 Na1 95.15(6) 2 1_565 ?
F2 Na2 Na1 94.77(5) 1_565 2_565 ?
F2 Na2 Na1 91.17(6) 2 2_565 ?
F2 Na2 F2 123.37(6) 1_565 2 ?
F2 Na2 O3 88.69(7) 2 4_575 ?
F2 Na2 O3 143.44(8) 1_565 4_575 ?
F2 Na2 O1 131.63(9) 2 4_585 ?
F2 Na2 O1 84.10(9) 1_565 4_585 ?
O3 Na2 Sn1 63.95(6) 4_575 2_655 ?
O3 Na2 Sn1 108.56(7) 4_575 2 ?
O3 Na2 Na2 159.92(7) 4_575 2 ?
O3 Na2 Na2 96.39(5) 4_575 2_545 ?
O3 Na2 Na1 131.88(6) 4_575 1_565 ?
O3 Na2 Na1 102.26(6) 4_575 2_565 ?
O1 Na2 Sn1 76.26(7) 4_585 2_655 ?
O1 Na2 Sn1 103.22(7) 4_585 2 ?
O1 Na2 Na2 74.36(7) 4_585 2 ?
O1 Na2 Na2 171.80(9) 4_585 2_545 ?
O1 Na2 Na1 122.96(8) 4_585 1_565 ?
O1 Na2 Na1 43.72(7) 4_585 2_565 ?
O1 Na2 O3 86.29(9) 4_585 4_575 ?
Sn1 Na1 Sn1 101.71(4) 1_545 . ?
Sn1 Na1 Na2 58.74(3) 1_545 2_535 ?
Sn1 Na1 Na2 71.30(3) 1_545 1_545 ?
S1 Na1 Sn1 113.95(4) 3_566 . ?
S1 Na1 Sn1 61.26(3) 1_545 1_545 ?
S1 Na1 Sn1 140.78(5) 1_545 . ?
S1 Na1 Sn1 124.23(4) 3_566 1_545 ?
S1 Na1 S1 104.16(4) 3_566 1_545 ?
S1 Na1 Na2 65.61(3) 3_566 2_535 ?
S1 Na1 Na2 77.14(3) 1_545 2_535 ?
S1 Na1 Na2 84.61(4) 3_566 1_545 ?
S1 Na1 Na2 127.81(4) 1_545 1_545 ?
Na2 Na1 Sn1 126.57(4) 2_535 . ?
Na2 Na1 Sn1 66.92(3) 1_545 . ?
Na2 Na1 Na2 59.78(3) 1_545 2_535 ?
F1 Na1 Sn1 93.45(5) 1_545 . ?
F1 Na1 Sn1 34.72(4) 1_545 1_545 ?
F1 Na1 S1 99.56(6) 1_545 3_566 ?
F1 Na1 S1 88.94(5) 1_545 1_545 ?
F1 Na1 Na2 39.19(5) 1_545 1_545 ?
F1 Na1 Na2 40.61(5) 1_545 2_535 ?
F1 Na1 O4 66.69(7) 1_545 1_545 ?
F1 Na1 O2 79.15(9) 1_545 3_666 ?
F1 Na1 O1 77.74(8) 1_545 3_566 ?
F2 Na1 Sn1 100.50(6) . 1_545 ?
F2 Na1 Sn1 31.19(4) . . ?
F2 Na1 S1 90.77(6) . 3_566 ?
F2 Na1 S1 160.87(7) . 1_545 ?
F2 Na1 Na2 40.66(5) . 1_545 ?
F2 Na1 Na2 98.90(6) . 2_535 ?
F2 Na1 F1 76.66(7) . 1_545 ?
F2 Na1 O3 99.42(7) . . ?
F2 Na1 O4 137.83(9) . 1_545 ?
F2 Na1 O2 74.68(8) . 3_666 ?
F2 Na1 O1 94.92(9) . 3_566 ?
O3 Na1 Sn1 79.98(6) . . ?
O3 Na1 Sn1 141.91(8) . 1_545 ?
O3 Na1 S1 93.21(7) . 1_545 ?
O3 Na1 S1 87.47(7) . 3_566 ?
O3 Na1 Na2 147.45(7) . 2_535 ?
O3 Na1 Na2 138.92(7) . 1_545 ?
O3 Na1 F1 171.93(9) . 1_545 ?
O3 Na1 O4 114.05(9) . 1_545 ?
O3 Na1 O2 93.05(10) . 3_666 ?
O3 Na1 O1 109.82(9) . 3_566 ?
O4 Na1 Sn1 129.77(8) 1_545 . ?
O4 Na1 Sn1 37.51(6) 1_545 1_545 ?
O4 Na1 S1 23.77(6) 1_545 1_545 ?
O4 Na1 S1 114.62(8) 1_545 3_566 ?
O4 Na1 Na2 66.11(8) 1_545 2_535 ?
O4 Na1 Na2 105.86(7) 1_545 1_545 ?
O4 Na1 O2 78.50(9) 1_545 3_666 ?
O2 Na1 Sn1 51.92(6) 3_666 . ?
O2 Na1 Sn1 61.87(6) 3_666 1_545 ?
O2 Na1 S1 90.45(7) 3_666 1_545 ?
O2 Na1 S1 165.34(7) 3_666 3_566 ?
O2 Na1 Na2 117.70(8) 3_666 2_535 ?
O2 Na1 Na2 85.41(8) 3_666 1_545 ?
O1 Na1 Sn1 100.43(6) 3_566 1_545 ?
O1 Na1 Sn1 124.55(8) 3_566 . ?
O1 Na1 S1 94.21(7) 3_566 1_545 ?
O1 Na1 S1 23.82(5) 3_566 3_566 ?
O1 Na1 Na2 41.79(6) 3_566 2_535 ?
O1 Na1 Na2 73.41(8) 3_566 1_545 ?
O1 Na1 O4 96.91(10) 3_566 1_545 ?
O1 Na1 O2 156.32(11) 3_566 3_666 ?
Sn1 F1 Na2 103.66(7) . 2_545 ?
Sn1 F1 Na2 143.04(8) . . ?
Sn1 F1 Na1 104.24(7) . 1_565 ?
Na2 F1 Na2 100.21(7) . 2_545 ?
Na2 F1 Na1 98.33(7) 2_545 1_565 ?
Na2 F1 Na1 99.69(7) . 1_565 ?
Sn1 F2 Na2 128.15(8) . 1_545 ?
Sn1 F2 Na2 103.84(7) . 2_545 ?
Sn1 F2 Na1 113.45(8) . . ?
Na2 F2 Na2 97.89(6) 1_545 2_545 ?
Na1 F2 Na2 112.42(8) . 2_545 ?
Na1 F2 Na2 100.11(7) . 1_545 ?
S1 O3 Na2 129.94(12) . 4_576 ?
S1 O3 Na1 125.46(12) . . ?
Na1 O3 Na2 104.57(8) . 4_576 ?
Sn1 O4 Na1 97.61(9) . 1_565 ?
S1 O4 Sn1 148.88(16) . . ?
S1 O4 Na1 113.38(13) . 1_565 ?
S1 O2 Na1 139.58(19) . 3_666 ?
S1 O1 Na2 153.36(17) . 4_586 ?
S1 O1 Na1 112.12(14) . 3_566 ?
Na2 O1 Na1 94.49(9) 4_586 3_566 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Na1 S1 O3 Na2 -126.59(12) 1_565 . . 4_576 ?
Na1 S1 O3 Na2 -75.97(15) 3_566 . . 4_576 ?
Na1 S1 O3 Na1 55.4(2) 1_565 . . . ?
Na1 S1 O3 Na1 105.97(14) 3_566 . . . ?
Na1 S1 O4 Sn1 -127.0(3) 3_566 . . . ?
Na1 S1 O4 Sn1 174.5(5) 1_565 . . . ?
Na1 S1 O4 Na1 58.50(14) 3_566 . . 1_565 ?
Na1 S1 O2 Na1 -160.06(12) 3_566 . . 3_666 ?
Na1 S1 O2 Na1 -56.7(2) 1_565 . . 3_666 ?
Na1 S1 O1 Na2 176.8(5) 3_566 . . 4_586 ?
Na1 S1 O1 Na2 -87.0(4) 1_565 . . 4_586 ?
Na1 S1 O1 Na1 96.20(15) 1_565 . . 3_566 ?
O3 S1 O4 Sn1 -52.3(4) . . . . ?
O3 S1 O4 Na1 133.29(14) . . . 1_565 ?
O3 S1 O2 Na1 109.2(2) . . . 3_666 ?
O3 S1 O1 Na2 144.2(4) . . . 4_586 ?
O3 S1 O1 Na1 -32.5(2) . . . 3_566 ?
O4 S1 O3 Na2 -169.13(17) . . . 4_576 ?
O4 S1 O3 Na1 12.8(2) . . . . ?
O4 S1 O2 Na1 -10.8(3) . . . 3_666 ?
O4 S1 O1 Na2 -97.6(4) . . . 4_586 ?
O4 S1 O1 Na1 85.68(18) . . . 3_566 ?
O2 S1 O3 Na2 71.0(2) . . . 4_576 ?
O2 S1 O3 Na1 -107.1(2) . . . . ?
O2 S1 O4 Sn1 68.6(4) . . . . ?
O2 S1 O4 Na1 -105.88(17) . . . 1_565 ?
O2 S1 O1 Na2 20.8(5) . . . 4_586 ?
O2 S1 O1 Na1 -155.99(14) . . . 3_566 ?
O1 S1 O3 Na2 -52.9(2) . . . 4_576 ?
O1 S1 O3 Na1 129.00(17) . . . . ?
O1 S1 O4 Sn1 -171.5(3) . . . . ?
O1 S1 O4 Na1 14.0(2) . . . 1_565 ?
O1 S1 O2 Na1 -127.2(2) . . . 3_666 ?

_olex2_submission_special_instructions 'No special instructions were received'
