# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_Bi_MOF720_1
_database_code_depnum_ccdc_archive 'CCDC 2495072'
loop_
_audit_author_name
_audit_author_address
'Feize Li'
;Sichuan University
China
;
_audit_update_record             
;
2026-02-06 deposited with the CCDC.	2026-02-09 downloaded from the CCDC.
;
_audit_creation_date             2026-02-06
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H33 Bi1 N3 O9'
_chemical_formula_sum            'C33 H33 Bi N3 O9'
_chemical_formula_weight         824.60
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           148
_space_group_name_H-M_alt        'R -3'
_space_group_name_Hall           '-R 3'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'

_cell_length_a                   17.337(2)
_cell_length_b                   17.337(2)
_cell_length_c                   18.389(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     4786.8(16)
_cell_formula_units_Z            6
_cell_measurement_reflns_used    6551
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      23.492
_cell_measurement_theta_min      2.349
_shelx_estimated_absorpt_T_max   0.488
_shelx_estimated_absorpt_T_min   0.268
_exptl_absorpt_coefficient_mu    5.584
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.4238
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1535 before and 0.0896 after correction.
The Ratio of minimum to maximum transmission is 0.5684.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_density_diffrn    1.716
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2442
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1491
_diffrn_reflns_av_unetI/netI     0.0575
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            33792
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.502
_diffrn_reflns_theta_min         2.349
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  Bruker
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1791
_reflns_number_total             2447
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.41 (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.41 (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2016/6 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.892
_refine_diff_density_min         -1.275
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       0.00046(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     160
_refine_ls_number_reflns         2447
_refine_ls_number_restraints     61
_refine_ls_R_factor_all          0.0797
_refine_ls_R_factor_gt           0.0452
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0486P)²+42.8334P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0991
_refine_ls_wR_factor_ref         0.1183
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N1-C11 = N1A-C11A = N1-C10 = N1A-C10A
 1.45 with sigma of 0.01
 O3A-C9A = O3-C9
 1.23 with sigma of 0.01
 N1-C9 = N1A-C9A
 1.32 with sigma of 0.01
 Bi1-O3A \\sim Bi1-O3
 with sigma of 0.01
3. Restrained planarity
 O3, C9, N1, C11, C10
 with sigma of 0.01
 O3A, C9A, N1A, C10A, C11A
 with sigma of 0.01
4. Uiso/Uaniso restraints and constraints
Uanis(O3) \\sim Ueq, Uanis(O3A) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C9A)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C11A) \\sim Ueq, Uanis(C11) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C10A) \\sim Ueq, Uanis(C10) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(N1) = Uanis(N1A)
Uanis(C9) = Uanis(C9A)
Uanis(O3) = Uanis(O3A)
Uanis(C10A) = Uanis(C10)
Uanis(C11) = Uanis(C11A)
5. Others
 Sof(O3A)=Sof(C9A)=Sof(H9A)=Sof(N1A)=Sof(C10A)=Sof(H10D)=Sof(H10E)=Sof(H10F)=
 Sof(C11A)=Sof(H11D)=Sof(H11E)=Sof(H11F)=1-FVAR(1)
 Sof(O3)=Sof(N1)=Sof(C9)=Sof(H9)=Sof(C11)=Sof(H11A)=Sof(H11B)=Sof(H11C)=
 Sof(C10)=Sof(H10A)=Sof(H10B)=Sof(H10C)=FVAR(1)
6.a Aromatic/amide H refined with riding coordinates:
 C8(H8), C5(H5), C7(H7), C6(H6), C9(H9), C9A(H9A)
6.b Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C10(H10A,H10B,H10C), C10A(H10D,H10E,H10F), C11A(H11D,
 H11E,H11F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.333333 0.666667 0.48348(3) 0.0450(2) Uani 1 3 d DS T P . .
O1 O 0.3248(3) 0.5633(3) 0.3959(3) 0.0518(12) Uani 1 1 d . . . . .
O4 O 0.2065(3) 0.5057(3) 0.4654(3) 0.0570(13) Uani 1 1 d . . . . .
C1 C 0.2493(4) 0.4996(4) 0.4139(4) 0.0438(16) Uani 1 1 d . . . . .
C4 C 0.2082(4) 0.3397(4) 0.4008(4) 0.0429(15) Uani 1 1 d . . . . .
C2 C 0.2089(4) 0.4145(4) 0.3710(4) 0.0426(15) Uani 1 1 d . . . . .
C3 C 0.1691(4) 0.4100(4) 0.3040(4) 0.0434(16) Uani 1 1 d . . . . .
C8 C 0.1641(5) 0.1811(5) 0.3948(4) 0.0498(17) Uani 1 1 d . . . . .
H8 H 0.133892 0.124857 0.371180 0.060 Uiso 1 1 calc R U . . .
O3 O 0.3585(16) 0.5497(13) 0.5588(12) 0.069(3) Uani 0.43(2) 1 d D U P A 1
C5 C 0.2513(5) 0.3429(5) 0.4680(4) 0.0537(18) Uani 1 1 d . . . . .
H5 H 0.280696 0.397270 0.494305 0.064 Uiso 1 1 calc R U . . .
C7 C 0.2064(5) 0.1891(5) 0.4581(4) 0.0560(19) Uani 1 1 d . . . . .
H7 H 0.205824 0.138399 0.478328 0.067 Uiso 1 1 calc R U . . .
C6 C 0.2512(5) 0.2704(5) 0.4948(5) 0.058(2) Uani 1 1 d . . . . .
H6 H 0.281737 0.274659 0.538854 0.069 Uiso 1 1 calc R U . . .
N1 N 0.4602(18) 0.5238(16) 0.6296(15) 0.073(4) Uani 0.43(2) 1 d D . P A 1
C9 C 0.424(2) 0.5459(17) 0.576(2) 0.107(4) Uani 0.43(2) 1 d D U P A 1
H9 H 0.464853 0.566632 0.536696 0.128 Uiso 0.43(2) 1 calc R U P A 1
C11 C 0.545(2) 0.527(3) 0.634(2) 0.136(9) Uani 0.43(2) 1 d D U P A 1
H11A H 0.581089 0.567806 0.673105 0.204 Uiso 0.43(2) 1 calc R U P A 1
H11B H 0.577134 0.548810 0.587630 0.204 Uiso 0.43(2) 1 calc R U P A 1
H11C H 0.535746 0.467539 0.643933 0.204 Uiso 0.43(2) 1 calc R U P A 1
C10 C 0.419(3) 0.490(3) 0.6996(18) 0.122(8) Uani 0.43(2) 1 d D U P A 1
H10A H 0.376648 0.509815 0.710149 0.184 Uiso 0.43(2) 1 calc R U P A 1
H10B H 0.465114 0.511403 0.737343 0.184 Uiso 0.43(2) 1 calc R U P A 1
H10C H 0.387689 0.424344 0.698619 0.184 Uiso 0.43(2) 1 calc R U P A 1
O3A O 0.3666(12) 0.5725(11) 0.5808(9) 0.069(3) Uani 0.57(2) 1 d D U P A 2
C9A C 0.4286(14) 0.5597(14) 0.5714(13) 0.107(4) Uani 0.57(2) 1 d D U P A 2
H9A H 0.469808 0.591527 0.533672 0.128 Uiso 0.57(2) 1 calc R U P A 2
N1A N 0.4419(14) 0.5037(12) 0.6110(11) 0.073(4) Uani 0.57(2) 1 d D . P A 2
C10A C 0.3802(19) 0.455(2) 0.6685(15) 0.122(8) Uani 0.57(2) 1 d D U P A 2
H10D H 0.409559 0.476509 0.715632 0.184 Uiso 0.57(2) 1 calc R U P A 2
H10E H 0.360334 0.391363 0.663659 0.184 Uiso 0.57(2) 1 calc R U P A 2
H10F H 0.328631 0.463622 0.665318 0.184 Uiso 0.57(2) 1 calc R U P A 2
C11A C 0.5148(19) 0.486(2) 0.6012(17) 0.136(9) Uani 0.57(2) 1 d D U P A 2
H11D H 0.550311 0.519558 0.558950 0.204 Uiso 0.57(2) 1 calc R U P A 2
H11E H 0.490923 0.422460 0.593358 0.204 Uiso 0.57(2) 1 calc R U P A 2
H11F H 0.552453 0.505282 0.644748 0.204 Uiso 0.57(2) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 O1 2.358(5) 3_565 ?
Bi1 O1 2.358(5) 2_665 ?
Bi1 O1 2.358(5) . ?
Bi1 O4 2.568(5) 3_565 ?
Bi1 O4 2.568(5) 2_665 ?
Bi1 O4 2.568(5) . ?
Bi1 O3 2.665(9) 3_565 ?
Bi1 O3 2.665(9) 2_665 ?
Bi1 O3 2.665(9) . ?
Bi1 O3A 2.672(8) 3_565 ?
Bi1 O3A 2.672(8) 2_665 ?
Bi1 O3A 2.672(8) . ?
O1 C1 1.264(8) . ?
O4 C1 1.239(8) . ?
C1 C2 1.503(9) . ?
C4 C2 1.402(9) . ?
C4 C3 1.431(9) 16 ?
C4 C5 1.431(10) . ?
C2 C3 1.394(10) . ?
C3 C8 1.437(9) 16 ?
C8 H8 0.9500 . ?
C8 C7 1.345(11) . ?
O3 C9 1.218(10) . ?
C5 H5 0.9500 . ?
C5 C6 1.349(10) . ?
C7 H7 0.9500 . ?
C7 C6 1.396(11) . ?
C6 H6 0.9500 . ?
N1 C9 1.316(10) . ?
N1 C11 1.452(10) . ?
N1 C10 1.446(10) . ?
C9 H9 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
O3A C9A 1.215(10) . ?
C9A H9A 0.9500 . ?
C9A N1A 1.322(10) . ?
N1A C10A 1.440(10) . ?
N1A C11A 1.448(10) . ?
C10A H10D 0.9800 . ?
C10A H10E 0.9800 . ?
C10A H10F 0.9800 . ?
C11A H11D 0.9800 . ?
C11A H11E 0.9800 . ?
C11A H11F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Bi1 O1 78.49(19) 3_565 2_665 ?
O1 Bi1 O1 78.49(19) 3_565 . ?
O1 Bi1 O1 78.49(19) 2_665 . ?
O1 Bi1 O4 127.46(17) 3_565 2_665 ?
O1 Bi1 O4 52.52(16) . . ?
O1 Bi1 O4 74.61(17) . 2_665 ?
O1 Bi1 O4 52.52(16) 2_665 2_665 ?
O1 Bi1 O4 52.52(16) 3_565 3_565 ?
O1 Bi1 O4 127.46(17) 2_665 . ?
O1 Bi1 O4 74.61(17) 2_665 3_565 ?
O1 Bi1 O4 127.46(17) . 3_565 ?
O1 Bi1 O4 74.60(17) 3_565 . ?
O1 Bi1 O3 75.4(6) 3_565 3_565 ?
O1 Bi1 O3 75.4(6) 2_665 2_665 ?
O1 Bi1 O3 121.9(5) 2_665 . ?
O1 Bi1 O3 141.9(5) 2_665 3_565 ?
O1 Bi1 O3 141.9(5) 3_565 . ?
O1 Bi1 O3 121.9(6) . 3_565 ?
O1 Bi1 O3 75.4(6) . . ?
O1 Bi1 O3 121.9(5) 3_565 2_665 ?
O1 Bi1 O3 141.9(5) . 2_665 ?
O1 Bi1 O3A 124.2(4) 2_665 . ?
O1 Bi1 O3A 150.0(4) 3_565 . ?
O1 Bi1 O3A 150.0(4) 2_665 3_565 ?
O1 Bi1 O3A 124.2(4) 3_565 2_665 ?
O1 Bi1 O3A 86.8(4) 3_565 3_565 ?
O1 Bi1 O3A 150.0(4) . 2_665 ?
O1 Bi1 O3A 124.2(4) . 3_565 ?
O1 Bi1 O3A 86.8(4) . . ?
O1 Bi1 O3A 86.8(4) 2_665 2_665 ?
O4 Bi1 O4 118.34(6) 3_565 . ?
O4 Bi1 O4 118.35(5) 2_665 . ?
O4 Bi1 O4 118.34(6) 3_565 2_665 ?
O4 Bi1 O3 67.5(5) . . ?
O4 Bi1 O3 70.8(5) 2_665 . ?
O4 Bi1 O3 156.1(6) . 2_665 ?
O4 Bi1 O3 67.5(5) 3_565 3_565 ?
O4 Bi1 O3 70.8(5) 3_565 2_665 ?
O4 Bi1 O3 156.1(6) 2_665 3_565 ?
O4 Bi1 O3 67.5(5) 2_665 2_665 ?
O4 Bi1 O3 70.8(5) . 3_565 ?
O4 Bi1 O3 156.1(6) 3_565 . ?
O4 Bi1 O3A 71.7(4) 3_565 2_665 ?
O4 Bi1 O3A 71.7(4) . 3_565 ?
O4 Bi1 O3A 75.7(4) 3_565 3_565 ?
O4 Bi1 O3A 75.7(4) 2_665 2_665 ?
O4 Bi1 O3A 71.7(4) 2_665 . ?
O4 Bi1 O3A 145.3(4) 3_565 . ?
O4 Bi1 O3A 145.3(4) 2_665 3_565 ?
O4 Bi1 O3A 75.7(4) . . ?
O4 Bi1 O3A 145.3(4) . 2_665 ?
O3 Bi1 O3 95.4(8) 3_565 2_665 ?
O3 Bi1 O3 95.4(8) 2_665 . ?
O3 Bi1 O3 95.4(8) 3_565 . ?
O3 Bi1 O3A 90.9(8) 2_665 3_565 ?
O3 Bi1 O3A 11.5(6) 3_565 3_565 ?
O3 Bi1 O3A 85.4(8) . 3_565 ?
O3 Bi1 O3A 90.9(8) . 2_665 ?
O3 Bi1 O3A 85.4(8) 3_565 2_665 ?
O3 Bi1 O3A 11.5(6) 2_665 2_665 ?
O3A Bi1 O3A 80.1(6) 3_565 2_665 ?
O3A Bi1 O3A 80.1(6) 2_665 . ?
O3A Bi1 O3A 80.1(6) 3_565 . ?
C1 O1 Bi1 97.4(4) . . ?
C1 O4 Bi1 88.2(4) . . ?
O1 C1 Bi1 56.1(3) . . ?
O1 C1 C2 119.4(6) . . ?
O4 C1 Bi1 65.7(4) . . ?
O4 C1 O1 121.9(6) . . ?
O4 C1 C2 118.7(6) . . ?
C2 C1 Bi1 175.1(5) . . ?
C2 C4 C3 119.5(6) . 16 ?
C2 C4 C5 122.6(6) . . ?
C5 C4 C3 117.9(6) . 16 ?
C4 C2 C1 119.2(6) . . ?
C3 C2 C1 119.5(6) . . ?
C3 C2 C4 121.2(6) . . ?
C4 C3 C8 118.2(7) 16 16 ?
C2 C3 C4 119.3(6) . 16 ?
C2 C3 C8 122.6(6) . 16 ?
C3 C8 H8 119.7 16 . ?
C7 C8 C3 120.6(7) . 16 ?
C7 C8 H8 119.7 . . ?
C9 O3 Bi1 133.8(19) . . ?
C4 C5 H5 119.3 . . ?
C6 C5 C4 121.5(7) . . ?
C6 C5 H5 119.3 . . ?
C8 C7 H7 119.3 . . ?
C8 C7 C6 121.5(7) . . ?
C6 C7 H7 119.3 . . ?
C5 C6 C7 120.3(8) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
C9 N1 C11 130(3) . . ?
C9 N1 C10 125(3) . . ?
C10 N1 C11 105(3) . . ?
O3 C9 N1 144(4) . . ?
O3 C9 H9 108.2 . . ?
N1 C9 H9 108.2 . . ?
N1 C11 H11A 109.5 . . ?
N1 C11 H11B 109.5 . . ?
N1 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N1 C10 H10A 109.5 . . ?
N1 C10 H10B 109.5 . . ?
N1 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9A O3A Bi1 119.9(14) . . ?
O3A C9A H9A 118.2 . . ?
O3A C9A N1A 124(2) . . ?
N1A C9A H9A 118.2 . . ?
C9A N1A C10A 119(2) . . ?
C9A N1A C11A 125(2) . . ?
C10A N1A C11A 116(2) . . ?
N1A C10A H10D 109.5 . . ?
N1A C10A H10E 109.5 . . ?
N1A C10A H10F 109.5 . . ?
H10D C10A H10E 109.5 . . ?
H10D C10A H10F 109.5 . . ?
H10E C10A H10F 109.5 . . ?
N1A C11A H11D 109.5 . . ?
N1A C11A H11E 109.5 . . ?
N1A C11A H11F 109.5 . . ?
H11D C11A H11E 109.5 . . ?
H11D C11A H11F 109.5 . . ?
H11E C11A H11F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Bi1 O1 C1 O4 -1.3(8) . . . . ?
Bi1 O1 C1 C2 177.5(5) . . . . ?
Bi1 O4 C1 O1 1.2(7) . . . . ?
Bi1 O4 C1 C2 -177.6(6) . . . . ?
Bi1 O3 C9 N1 141(3) . . . . ?
Bi1 O3A C9A N1A -169.9(15) . . . . ?
O1 C1 C2 C4 105.1(8) . . . . ?
O1 C1 C2 C3 -78.1(8) . . . . ?
O4 C1 C2 C4 -76.2(9) . . . . ?
O4 C1 C2 C3 100.7(8) . . . . ?
C1 C2 C3 C4 -175.5(6) . . . 16 ?
C1 C2 C3 C8 3.6(10) . . . 16 ?
C4 C2 C3 C4 1.3(10) . . . 16 ?
C4 C2 C3 C8 -179.6(6) . . . 16 ?
C4 C5 C6 C7 -1.7(12) . . . . ?
C2 C4 C5 C6 -178.6(7) . . . . ?
C3 C4 C2 C1 175.6(6) 16 . . . ?
C3 C4 C2 C3 -1.3(10) 16 . . . ?
C3 C4 C5 C6 0.2(10) 16 . . . ?
C3 C8 C7 C6 0.4(11) 16 . . . ?
C8 C7 C6 C5 1.5(12) . . . . ?
C5 C4 C2 C1 -5.7(10) . . . . ?
C5 C4 C2 C3 177.5(6) . . . . ?
C11 N1 C9 O3 180.0(6) . . . . ?
C10 N1 C9 O3 -0.3(5) . . . . ?
O3A C9A N1A C10A -0.1(4) . . . . ?
O3A C9A N1A C11A 179.7(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
