# Supplementary Information (SI) for Materials Advances.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2260170'
loop_
_audit_author_name
_audit_author_address
'Sammer Yousuf'
;University of Karachi
Pakistan
;
_audit_update_record             
;
2025-03-24 deposited with the CCDC.	2025-05-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H26 Ag2 Cl4 N8 O8'
_chemical_formula_sum            'C28 H26 Ag2 Cl4 N8 O8'
_chemical_formula_weight         960.11

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.9484(4)
_cell_length_b                   10.7265(4)
_cell_length_c                   19.5888(8)
_cell_angle_alpha                91.661(2)
_cell_angle_beta                 102.5380(10)
_cell_angle_gamma                107.355(2)
_cell_volume                     1742.94(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    9739
_cell_measurement_theta_min      4.34
_cell_measurement_theta_max      68.51

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            brown
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.829
_exptl_crystal_F_000             952
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    12.360
_shelx_estimated_absorpt_T_min   0.155
_shelx_estimated_absorpt_T_max   0.319
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1550
_exptl_absorpt_correction_T_max  0.3190
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            45047
_diffrn_reflns_av_unetI/netI     0.0322
_diffrn_reflns_av_R_equivalents  0.0626
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         4.340
_diffrn_reflns_theta_max         68.505
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             6375
_reflns_number_gt                5833
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1012P)²+2.3399P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0036(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         6375
_refine_ls_number_parameters     462
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0555
_refine_ls_R_factor_gt           0.0521
_refine_ls_wR_factor_ref         0.1566
_refine_ls_wR_factor_gt          0.1517
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_restrained_S_all      1.025
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.44913(4) 0.17776(4) -0.04057(2) 0.07031(19) Uani 1 1 d . . . . .
Ag2 Ag 0.23066(5) 0.16496(5) 0.18316(2) 0.0784(2) Uani 1 1 d . . . . .
Cl1 Cl 0.84534(15) 0.47103(12) 0.11188(8) 0.0677(3) Uani 1 1 d . . . . .
Cl2 Cl 0.65727(18) 0.85951(11) 0.21041(6) 0.0662(3) Uani 1 1 d . . . . .
Cl3 Cl 0.1457(2) 0.14780(19) 0.38483(10) 0.0951(5) Uani 1 1 d . . . . .
Cl4 Cl 0.6915(4) 0.1844(2) 0.58246(10) 0.1289(9) Uani 1 1 d . . . . .
O1 O 0.4448(3) 0.3635(3) 0.03696(14) 0.0427(6) Uani 1 1 d . . . . .
O2 O 0.6104(4) 0.0747(4) -0.0666(2) 0.0759(11) Uani 1 1 d . . . . .
O3 O 0.8506(4) 0.0789(3) -0.0637(2) 0.0603(8) Uani 1 1 d . . . . .
O4 O 0.8078(5) 0.2537(3) -0.0293(2) 0.0756(10) Uani 1 1 d . . . . .
O5 O 0.4079(4) 0.1211(4) 0.28255(16) 0.0596(8) Uani 1 1 d . . . . .
O6 O -0.0823(4) 0.1810(3) 0.20333(18) 0.0613(8) Uani 1 1 d . . . . .
O7 O -0.0202(4) 0.1014(4) 0.11487(19) 0.0634(9) Uani 1 1 d . . . . .
O8 O -0.2582(4) 0.1126(4) 0.1048(2) 0.0721(10) Uani 1 1 d . . . . .
N1 N 0.1769(4) 0.2591(3) 0.00460(17) 0.0406(7) Uani 1 1 d . . . . .
H1 H 0.081548 0.261813 0.004089 0.049 Uiso 1 1 calc R U . . .
N2 N 0.1974(4) 0.1479(3) -0.0272(2) 0.0470(8) Uani 1 1 d . . . . .
H2A H 0.129038 0.125318 -0.069266 0.056 Uiso 1 1 calc R U . . .
H2AB H 0.171943 0.081472 -0.001274 0.056 Uiso 1 1 calc R U . . .
N3 N 0.6045(4) 0.5970(3) 0.13781(16) 0.0404(7) Uani 1 1 d . . . . .
H3 H 0.568824 0.587397 0.092901 0.049 Uiso 1 1 calc R U . . .
N4 N 0.7584(4) 0.1384(3) -0.05353(19) 0.0480(8) Uani 1 1 d . . . . .
N5 N 0.5889(5) 0.1806(4) 0.21589(19) 0.0517(8) Uani 1 1 d . . . . .
H5A H 0.688323 0.200360 0.214073 0.062 Uiso 1 1 calc R U . . .
N6 N 0.4712(5) 0.1801(4) 0.15540(19) 0.0518(8) Uani 1 1 d . . . . .
H6A H 0.457998 0.112487 0.124831 0.062 Uiso 1 1 calc R U . . .
H6B H 0.503685 0.253578 0.135239 0.062 Uiso 1 1 calc R U . . .
N7 N -0.1209(4) 0.1326(3) 0.14145(19) 0.0468(8) Uani 1 1 d . . . . .
N8 N 0.4975(6) 0.1817(4) 0.4356(2) 0.0677(12) Uani 1 1 d . . . . .
H8 H 0.470440 0.116529 0.403960 0.081 Uiso 1 1 calc R U . . .
C1 C 0.3047(4) 0.3599(3) 0.03544(17) 0.0339(7) Uani 1 1 d . . . . .
C2 C 0.2703(5) 0.4719(4) 0.0714(2) 0.0398(8) Uani 1 1 d . . . . .
H2C H 0.320541 0.553805 0.053857 0.048 Uiso 1 1 calc R U . . .
H2D H 0.155010 0.457308 0.061063 0.048 Uiso 1 1 calc R U . . .
C3 C 0.3358(5) 0.4805(3) 0.15012(19) 0.0373(7) Uani 1 1 d . . . . .
C4 C 0.2312(5) 0.4253(4) 0.1921(2) 0.0494(9) Uani 1 1 d . . . . .
H4 H 0.122187 0.385909 0.171752 0.059 Uiso 1 1 calc R U . . .
C5 C 0.2883(7) 0.4286(5) 0.2642(3) 0.0600(12) Uani 1 1 d . . . . .
H5 H 0.217961 0.390819 0.291998 0.072 Uiso 1 1 calc R U . . .
C6 C 0.4504(7) 0.4883(5) 0.2946(2) 0.0649(13) Uani 1 1 d . . . . .
H6 H 0.489082 0.491369 0.342878 0.078 Uiso 1 1 calc R U . . .
C7 C 0.5537(6) 0.5429(4) 0.2535(2) 0.0507(10) Uani 1 1 d . . . . .
H7 H 0.662521 0.582369 0.274289 0.061 Uiso 1 1 calc R U . . .
C8 C 0.4990(5) 0.5405(3) 0.18127(19) 0.0379(8) Uani 1 1 d . . . . .
C9 C 0.7669(5) 0.6684(4) 0.16768(19) 0.0421(8) Uani 1 1 d . . . . .
C10 C 0.8928(5) 0.6231(4) 0.1599(2) 0.0488(9) Uani 1 1 d . . . . .
C11 C 1.0533(6) 0.6954(5) 0.1870(3) 0.0668(13) Uani 1 1 d . . . . .
H11 H 1.134943 0.663920 0.179080 0.080 Uiso 1 1 calc R U . . .
C12 C 1.0905(7) 0.8152(6) 0.2260(3) 0.0733(15) Uani 1 1 d . . . . .
H12 H 1.197272 0.862504 0.246662 0.088 Uiso 1 1 calc R U . . .
C13 C 0.9691(8) 0.8636(5) 0.2339(2) 0.0680(16) Uani 1 1 d . . . . .
H13 H 0.993957 0.944904 0.258978 0.082 Uiso 1 1 calc R U . . .
C14 C 0.8096(6) 0.7921(4) 0.2047(2) 0.0484(9) Uani 1 1 d . . . . .
C15 C 0.5477(5) 0.1508(4) 0.2758(2) 0.0476(9) Uani 1 1 d . . . . .
C16 C 0.6862(7) 0.1639(6) 0.3378(3) 0.0652(13) Uani 1 1 d . . . . .
H16A H 0.781710 0.165883 0.321505 0.078 Uiso 1 1 calc R U . . .
H16B H 0.660592 0.088805 0.364492 0.078 Uiso 1 1 calc R U . . .
C17 C 0.7187(6) 0.2896(5) 0.3845(3) 0.0641(13) Uani 1 1 d . . . . .
C18 C 0.8400(8) 0.4035(7) 0.3792(4) 0.0883(19) Uani 1 1 d . . . . .
H18 H 0.901874 0.403124 0.346735 0.106 Uiso 1 1 calc R U . . .
C19 C 0.8683(10) 0.5168(7) 0.4220(5) 0.104(3) Uani 1 1 d . . . . .
H19 H 0.948786 0.592557 0.417948 0.125 Uiso 1 1 calc R U . . .
C20 C 0.7812(12) 0.5183(6) 0.4691(4) 0.103(3) Uani 1 1 d . . . . .
H20 H 0.804248 0.594453 0.498651 0.124 Uiso 1 1 calc R U . . .
C21 C 0.6582(9) 0.4094(5) 0.4747(3) 0.0797(17) Uani 1 1 d . . . . .
H21 H 0.596990 0.412778 0.507110 0.096 Uiso 1 1 calc R U . . .
C22 C 0.6248(7) 0.2936(5) 0.4320(2) 0.0616(12) Uani 1 1 d . . . . .
C23 C 0.4138(9) 0.1717(5) 0.4876(3) 0.0716(16) Uani 1 1 d . . . . .
C24 C 0.2494(10) 0.1546(5) 0.4721(3) 0.084(2) Uani 1 1 d . . . . .
C28 C 0.4916(12) 0.1757(6) 0.5600(3) 0.094(2) Uani 1 1 d . . . . .
C25 C 0.1764(19) 0.1439(9) 0.5278(7) 0.078(4) Uani 0.76(3) 1 d . . P A 1
H25 H 0.065574 0.128005 0.518306 0.094 Uiso 0.76(3) 1 calc R U P A 1
C26 C 0.260(2) 0.1555(11) 0.5969(6) 0.089(6) Uani 0.76(3) 1 d . . P A 1
H26 H 0.205387 0.152714 0.632598 0.106 Uiso 0.76(3) 1 calc R U P A 1
C27 C 0.421(3) 0.1711(13) 0.6137(6) 0.098(5) Uani 0.76(3) 1 d . . P A 1
H27 H 0.479188 0.178194 0.660006 0.118 Uiso 0.76(3) 1 calc R U P A 1
C25A C 0.105(6) 0.152(4) 0.505(2) 0.078(4) Uani 0.24(3) 1 d . . P A 2
H25A H -0.000554 0.146407 0.482815 0.094 Uiso 0.24(3) 1 calc R U P A 2
C26A C 0.175(7) 0.160(4) 0.576(2) 0.089(6) Uani 0.24(3) 1 d . . P A 2
H26A H 0.114288 0.154540 0.609487 0.106 Uiso 0.24(3) 1 calc R U P A 2
C27A C 0.351(11) 0.177(6) 0.597(3) 0.098(5) Uani 0.24(3) 1 d . . P A 2
H27A H 0.389219 0.193217 0.645921 0.118 Uiso 0.24(3) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O2 2.192(3) . ?
Ag1 N2 2.253(4) . ?
Ag1 O1 2.485(3) . ?
Ag2 O7 2.242(3) . ?
Ag2 N6 2.293(4) . ?
Ag2 O5 2.384(3) . ?
Cl1 C10 1.746(4) . ?
Cl2 C14 1.744(5) . ?
Cl3 C24 1.747(8) . ?
Cl4 C28 1.720(10) . ?
O1 C1 1.236(5) . ?
O2 N4 1.261(5) . ?
O3 N4 1.227(5) . ?
O4 N4 1.225(5) . ?
O5 C15 1.233(6) . ?
O6 N7 1.238(5) . ?
O7 N7 1.252(5) . ?
O8 N7 1.234(5) . ?
N1 C1 1.329(5) . ?
N1 N2 1.408(5) . ?
N1 H1 0.8600 . ?
N2 H2A 0.8900 . ?
N2 H2AB 0.8900 . ?
N3 C9 1.408(5) . ?
N3 C8 1.422(5) . ?
N3 H3 0.8600 . ?
N5 C15 1.324(6) . ?
N5 N6 1.403(5) . ?
N5 H5A 0.8600 . ?
N6 H6A 0.8900 . ?
N6 H6B 0.8900 . ?
N8 C23 1.378(8) . ?
N8 C22 1.403(7) . ?
N8 H8 0.8600 . ?
C1 C2 1.516(5) . ?
C2 C3 1.516(5) . ?
C2 H2C 0.9700 . ?
C2 H2D 0.9700 . ?
C3 C4 1.391(6) . ?
C3 C8 1.396(5) . ?
C4 C5 1.390(7) . ?
C4 H4 0.9300 . ?
C5 C6 1.385(8) . ?
C5 H5 0.9300 . ?
C6 C7 1.368(7) . ?
C6 H6 0.9300 . ?
C7 C8 1.390(5) . ?
C7 H7 0.9300 . ?
C9 C10 1.388(6) . ?
C9 C14 1.398(6) . ?
C10 C11 1.388(6) . ?
C11 C12 1.387(9) . ?
C11 H11 0.9300 . ?
C12 C13 1.370(9) . ?
C12 H12 0.9300 . ?
C13 C14 1.385(7) . ?
C13 H13 0.9300 . ?
C15 C16 1.504(6) . ?
C16 C17 1.523(8) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C22 1.390(8) . ?
C17 C18 1.395(8) . ?
C18 C19 1.382(12) . ?
C18 H18 0.9300 . ?
C19 C20 1.334(13) . ?
C19 H19 0.9300 . ?
C20 C21 1.372(11) . ?
C20 H20 0.9300 . ?
C21 C22 1.393(7) . ?
C21 H21 0.9300 . ?
C23 C24 1.390(11) . ?
C23 C28 1.430(9) . ?
C24 C25 1.380(11) . ?
C24 C25A 1.56(4) . ?
C28 C27 1.332(18) . ?
C28 C27A 1.59(9) . ?
C25 C26 1.378(16) . ?
C25 H25 0.9300 . ?
C26 C27 1.37(2) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C25A C26A 1.39(5) . ?
C25A H25A 0.9300 . ?
C26A C27A 1.49(10) . ?
C26A H26A 0.9300 . ?
C27A H27A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Ag1 N2 143.38(13) . . ?
O2 Ag1 O1 142.25(11) . . ?
N2 Ag1 O1 69.88(10) . . ?
O7 Ag2 N6 130.13(13) . . ?
O7 Ag2 O5 145.54(13) . . ?
N6 Ag2 O5 71.18(12) . . ?
C1 O1 Ag1 110.8(2) . . ?
N4 O2 Ag1 117.0(3) . . ?
C15 O5 Ag2 111.9(3) . . ?
N7 O7 Ag2 114.3(3) . . ?
C1 N1 N2 120.1(3) . . ?
C1 N1 H1 120.0 . . ?
N2 N1 H1 120.0 . . ?
N1 N2 Ag1 114.0(2) . . ?
N1 N2 H2A 108.8 . . ?
Ag1 N2 H2A 108.8 . . ?
N1 N2 H2AB 108.8 . . ?
Ag1 N2 H2AB 108.8 . . ?
H2A N2 H2AB 107.6 . . ?
C9 N3 C8 120.5(3) . . ?
C9 N3 H3 119.7 . . ?
C8 N3 H3 119.7 . . ?
O4 N4 O3 121.7(4) . . ?
O4 N4 O2 120.9(4) . . ?
O3 N4 O2 117.3(4) . . ?
C15 N5 N6 120.4(4) . . ?
C15 N5 H5A 119.8 . . ?
N6 N5 H5A 119.8 . . ?
N5 N6 Ag2 110.6(2) . . ?
N5 N6 H6A 109.5 . . ?
Ag2 N6 H6A 109.5 . . ?
N5 N6 H6B 109.5 . . ?
Ag2 N6 H6B 109.5 . . ?
H6A N6 H6B 108.1 . . ?
O8 N7 O6 121.4(4) . . ?
O8 N7 O7 118.5(4) . . ?
O6 N7 O7 120.1(4) . . ?
C23 N8 C22 122.8(4) . . ?
C23 N8 H8 118.6 . . ?
C22 N8 H8 118.6 . . ?
O1 C1 N1 123.3(3) . . ?
O1 C1 C2 120.7(3) . . ?
N1 C1 C2 116.0(3) . . ?
C3 C2 C1 109.6(3) . . ?
C3 C2 H2C 109.7 . . ?
C1 C2 H2C 109.7 . . ?
C3 C2 H2D 109.7 . . ?
C1 C2 H2D 109.7 . . ?
H2C C2 H2D 108.2 . . ?
C4 C3 C8 119.3(4) . . ?
C4 C3 C2 119.2(4) . . ?
C8 C3 C2 121.5(3) . . ?
C5 C4 C3 120.6(4) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C6 C5 C4 119.7(4) . . ?
C6 C5 H5 120.2 . . ?
C4 C5 H5 120.2 . . ?
C7 C6 C5 120.0(4) . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C8 121.2(4) . . ?
C6 C7 H7 119.4 . . ?
C8 C7 H7 119.4 . . ?
C7 C8 C3 119.3(4) . . ?
C7 C8 N3 122.0(4) . . ?
C3 C8 N3 118.7(3) . . ?
C10 C9 C14 116.4(4) . . ?
C10 C9 N3 122.4(4) . . ?
C14 C9 N3 121.1(4) . . ?
C9 C10 C11 122.6(4) . . ?
C9 C10 Cl1 118.0(3) . . ?
C11 C10 Cl1 119.4(4) . . ?
C12 C11 C10 119.2(5) . . ?
C12 C11 H11 120.4 . . ?
C10 C11 H11 120.4 . . ?
C13 C12 C11 119.6(5) . . ?
C13 C12 H12 120.2 . . ?
C11 C12 H12 120.2 . . ?
C12 C13 C14 120.5(5) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C13 C14 C9 121.6(5) . . ?
C13 C14 Cl2 119.9(4) . . ?
C9 C14 Cl2 118.5(3) . . ?
O5 C15 N5 123.7(4) . . ?
O5 C15 C16 121.1(4) . . ?
N5 C15 C16 115.1(4) . . ?
C15 C16 C17 109.8(4) . . ?
C15 C16 H16A 109.7 . . ?
C17 C16 H16A 109.7 . . ?
C15 C16 H16B 109.7 . . ?
C17 C16 H16B 109.7 . . ?
H16A C16 H16B 108.2 . . ?
C22 C17 C18 118.8(6) . . ?
C22 C17 C16 120.4(5) . . ?
C18 C17 C16 120.8(6) . . ?
C19 C18 C17 120.1(8) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C20 C19 C18 120.5(7) . . ?
C20 C19 H19 119.7 . . ?
C18 C19 H19 119.7 . . ?
C19 C20 C21 121.1(7) . . ?
C19 C20 H20 119.5 . . ?
C21 C20 H20 119.5 . . ?
C20 C21 C22 120.1(7) . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C17 C22 C21 119.2(6) . . ?
C17 C22 N8 119.5(4) . . ?
C21 C22 N8 121.3(6) . . ?
N8 C23 C24 121.6(5) . . ?
N8 C23 C28 121.5(7) . . ?
C24 C23 C28 116.9(6) . . ?
C25 C24 C23 117.2(9) . . ?
C23 C24 C25A 144.1(19) . . ?
C25 C24 Cl3 123.3(9) . . ?
C23 C24 Cl3 119.5(4) . . ?
C25A C24 Cl3 95.9(19) . . ?
C27 C28 C23 125.5(11) . . ?
C23 C28 C27A 101(2) . . ?
C27 C28 Cl4 115.0(10) . . ?
C23 C28 Cl4 119.5(6) . . ?
C27A C28 Cl4 139(2) . . ?
C26 C25 C24 123.2(12) . . ?
C26 C25 H25 118.4 . . ?
C24 C25 H25 118.4 . . ?
C27 C26 C25 120.8(11) . . ?
C27 C26 H26 119.6 . . ?
C25 C26 H26 119.6 . . ?
C28 C27 C26 116.3(11) . . ?
C28 C27 H27 121.8 . . ?
C26 C27 H27 121.8 . . ?
C26A C25A C24 101(3) . . ?
C26A C25A H25A 129.4 . . ?
C24 C25A H25A 129.4 . . ?
C25A C26A C27A 118(4) . . ?
C25A C26A H26A 121.0 . . ?
C27A C26A H26A 121.0 . . ?
C26A C27A C28 138(4) . . ?
C26A C27A H27A 111.2 . . ?
C28 C27A H27A 111.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 N1 N2 Ag1 -12.5(4) . . . . ?
Ag1 O2 N4 O4 -2.1(6) . . . . ?
Ag1 O2 N4 O3 175.4(3) . . . . ?
C15 N5 N6 Ag2 11.5(5) . . . . ?
Ag2 O7 N7 O8 173.1(3) . . . . ?
Ag2 O7 N7 O6 -7.6(5) . . . . ?
Ag1 O1 C1 N1 9.2(4) . . . . ?
Ag1 O1 C1 C2 -172.5(3) . . . . ?
N2 N1 C1 O1 1.4(6) . . . . ?
N2 N1 C1 C2 -177.0(3) . . . . ?
O1 C1 C2 C3 -65.1(4) . . . . ?
N1 C1 C2 C3 113.3(4) . . . . ?
C1 C2 C3 C4 -99.1(4) . . . . ?
C1 C2 C3 C8 79.9(4) . . . . ?
C8 C3 C4 C5 -0.6(6) . . . . ?
C2 C3 C4 C5 178.3(4) . . . . ?
C3 C4 C5 C6 0.6(7) . . . . ?
C4 C5 C6 C7 -0.5(8) . . . . ?
C5 C6 C7 C8 0.4(8) . . . . ?
C6 C7 C8 C3 -0.4(6) . . . . ?
C6 C7 C8 N3 179.9(4) . . . . ?
C4 C3 C8 C7 0.5(5) . . . . ?
C2 C3 C8 C7 -178.4(3) . . . . ?
C4 C3 C8 N3 -179.8(3) . . . . ?
C2 C3 C8 N3 1.3(5) . . . . ?
C9 N3 C8 C7 -5.9(6) . . . . ?
C9 N3 C8 C3 174.4(3) . . . . ?
C8 N3 C9 C10 111.5(4) . . . . ?
C8 N3 C9 C14 -71.1(5) . . . . ?
C14 C9 C10 C11 0.0(6) . . . . ?
N3 C9 C10 C11 177.5(4) . . . . ?
C14 C9 C10 Cl1 -178.2(3) . . . . ?
N3 C9 C10 Cl1 -0.7(5) . . . . ?
C9 C10 C11 C12 2.8(8) . . . . ?
Cl1 C10 C11 C12 -179.0(4) . . . . ?
C10 C11 C12 C13 -3.6(8) . . . . ?
C11 C12 C13 C14 1.6(8) . . . . ?
C12 C13 C14 C9 1.2(7) . . . . ?
C12 C13 C14 Cl2 -175.9(4) . . . . ?
C10 C9 C14 C13 -2.0(6) . . . . ?
N3 C9 C14 C13 -179.6(4) . . . . ?
C10 C9 C14 Cl2 175.2(3) . . . . ?
N3 C9 C14 Cl2 -2.3(5) . . . . ?
Ag2 O5 C15 N5 -11.5(5) . . . . ?
Ag2 O5 C15 C16 164.6(3) . . . . ?
N6 N5 C15 O5 0.3(7) . . . . ?
N6 N5 C15 C16 -176.0(4) . . . . ?
O5 C15 C16 C17 -73.5(6) . . . . ?
N5 C15 C16 C17 102.9(5) . . . . ?
C15 C16 C17 C22 80.5(6) . . . . ?
C15 C16 C17 C18 -97.7(6) . . . . ?
C22 C17 C18 C19 1.8(9) . . . . ?
C16 C17 C18 C19 -179.9(6) . . . . ?
C17 C18 C19 C20 0.5(11) . . . . ?
C18 C19 C20 C21 -2.2(12) . . . . ?
C19 C20 C21 C22 1.5(11) . . . . ?
C18 C17 C22 C21 -2.5(7) . . . . ?
C16 C17 C22 C21 179.3(5) . . . . ?
C18 C17 C22 N8 177.0(5) . . . . ?
C16 C17 C22 N8 -1.3(7) . . . . ?
C20 C21 C22 C17 0.8(8) . . . . ?
C20 C21 C22 N8 -178.6(5) . . . . ?
C23 N8 C22 C17 170.6(5) . . . . ?
C23 N8 C22 C21 -10.0(8) . . . . ?
C22 N8 C23 C24 118.7(6) . . . . ?
C22 N8 C23 C28 -62.7(8) . . . . ?
N8 C23 C24 C25 179.1(6) . . . . ?
C28 C23 C24 C25 0.5(8) . . . . ?
N8 C23 C24 C25A -171(2) . . . . ?
C28 C23 C24 C25A 10(2) . . . . ?
N8 C23 C24 Cl3 -1.0(7) . . . . ?
C28 C23 C24 Cl3 -179.6(4) . . . . ?
N8 C23 C28 C27 177.6(8) . . . . ?
C24 C23 C28 C27 -3.7(11) . . . . ?
N8 C23 C28 C27A 174(2) . . . . ?
C24 C23 C28 C27A -8(2) . . . . ?
N8 C23 C28 Cl4 -3.5(7) . . . . ?
C24 C23 C28 Cl4 175.2(4) . . . . ?
C23 C24 C25 C26 3.1(12) . . . . ?
Cl3 C24 C25 C26 -176.8(8) . . . . ?
C24 C25 C26 C27 -3.9(16) . . . . ?
C23 C28 C27 C26 3.1(15) . . . . ?
Cl4 C28 C27 C26 -175.9(8) . . . . ?
C25 C26 C27 C28 0.7(17) . . . . ?
C23 C24 C25A C26A -7(4) . . . . ?
Cl3 C24 C25A C26A -179(2) . . . . ?
C24 C25A C26A C27A 4(5) . . . . ?
C25A C26A C27A C28 -8(8) . . . . ?
C23 C28 C27A C26A 9(6) . . . . ?
Cl4 C28 C27A C26A -174(4) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
N5 H5A O6 0.86 2.18 3.004(5) 161.2 1_655 yes
N5 H5A N7 0.86 2.68 3.397(5) 141.1 1_655 yes
N5 H5A O8 0.86 2.51 2.988(5) 116.2 1_655 yes
N1 H1 O3 0.86 2.47 2.973(5) 117.7 1_455 yes
N1 H1 O4 0.86 2.37 3.206(5) 164.9 1_455 yes
N2 H2A O3 0.89 2.42 2.885(5) 113.0 1_455 yes
N2 H2A O7 0.89 2.40 2.938(5) 119.5 2 yes
N2 H2AB O3 0.89 2.16 3.038(5) 170.9 2_655 yes
N3 H3 O1 0.86 2.44 2.927(4) 117.0 . yes
N3 H3 O1 0.86 2.60 3.411(4) 158.3 2_665 yes
C2 H2C O4 0.97 2.65 3.309(5) 125.1 2_665 yes
N6 H6A O2 0.89 2.13 3.002(5) 166.2 2_655 yes
N6 H6B O1 0.89 2.33 3.100(5) 144.6 . yes
N8 H8 O5 0.86 2.33 2.930(5) 127.3 . yes
N1 H1 O3 0.86 2.47 2.973(5) 117.7 1_455 yes
N1 H1 O4 0.86 2.37 3.206(5) 164.9 1_455 yes
N2 H2A O3 0.89 2.42 2.885(5) 113.0 1_455 yes
N2 H2A O7 0.89 2.40 2.938(5) 119.5 2 yes
N2 H2AB O3 0.89 2.16 3.038(5) 170.9 2_655 yes
N3 H3 O1 0.86 2.44 2.927(4) 117.0 . yes
N3 H3 O1 0.86 2.60 3.411(4) 158.3 2_665 yes
N5 H5A O6 0.86 2.18 3.004(5) 161.2 1_655 yes
N5 H5A O8 0.86 2.51 2.988(5) 116.2 1_655 yes
N5 H5A N7 0.86 2.68 3.397(5) 141.1 1_655 yes
N6 H6A O2 0.89 2.13 3.002(5) 166.2 2_655 yes
N6 H6B O1 0.89 2.33 3.100(5) 144.6 . yes
N8 H8 O5 0.86 2.33 2.930(5) 127.3 . yes
C2 H2C O4 0.97 2.65 3.309(5) 125.1 2_665 yes
C27A^b H27A^b Cl2 0.93 2.98 3.81(5) 149.8 2_666 yes

_refine_diff_density_max         1.476
_refine_diff_density_min         -1.322
_refine_diff_density_rms         0.101

