# Supplementary Information (SI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2027758'
loop_
_audit_author_name
_audit_author_address
'Onur Sahin'
;Sinop University
T?rkiye
;
_audit_update_record             
;
2020-09-07 deposited with the CCDC.	2025-12-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C27 H24 Cl2 N2 O2 Pt S'
_chemical_formula_sum            'C27 H24 Cl2 N2 O2 Pt S'
_chemical_formula_weight         706.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.000(4)
_cell_length_b                   11.709(6)
_cell_length_c                   13.983(7)
_cell_angle_alpha                111.08(2)
_cell_angle_beta                 90.57(3)
_cell_angle_gamma                105.13(2)
_cell_volume                     1318.5(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    110
_cell_measurement_reflns_used    6629
_cell_measurement_theta_min      2.79
_cell_measurement_theta_max      27.99

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_min          0.10
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_max          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.780
_exptl_crystal_F_000             688
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_absorpt_coefficient_mu    5.630
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6114
_exptl_absorpt_correction_T_max  0.7413
_exptl_absorpt_process_details   Bruker

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      110
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_reflns_number            31584
_diffrn_reflns_av_unetI/netI     0.0720
_diffrn_reflns_av_R_equivalents  0.0830
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.789
_diffrn_reflns_theta_max         28.676
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             6622
_reflns_number_gt                5014
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2013)'
_computing_cell_refinement       'SAINT(Bruker, 2013)'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2015)'
_computing_molecular_graphics    'Mercury (Macrae, 2008)'
_computing_publication_material  'WinGX (Farrugia, 2012)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0384P)²+5.7009P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6622
_refine_ls_number_parameters     318
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0806
_refine_ls_R_factor_gt           0.0520
_refine_ls_wR_factor_ref         0.1171
_refine_ls_wR_factor_gt          0.1066
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1285(7) 0.3533(6) 0.4653(5) 0.0347(14) Uani 1 1 d . . . . .
C2 C 0.0799(9) 0.3386(8) 0.5553(5) 0.0459(18) Uani 1 1 d . . . . .
H2 H 0.0244 0.2597 0.5555 0.055 Uiso 1 1 calc R U . . .
C3 C 0.1182(10) 0.4462(9) 0.6434(6) 0.057(2) Uani 1 1 d . . . . .
H3 H 0.0893 0.4398 0.7054 0.068 Uiso 1 1 calc R U . . .
C4 C 0.1991(11) 0.5650(9) 0.6430(6) 0.059(2) Uani 1 1 d . . . . .
H4 H 0.2198 0.6360 0.7043 0.071 Uiso 1 1 calc R U . . .
C5 C 0.2498(9) 0.5807(7) 0.5542(6) 0.0459(18) Uani 1 1 d . . . . .
H5 H 0.3046 0.6597 0.5538 0.055 Uiso 1 1 calc R U . . .
C6 C 0.2130(8) 0.4701(6) 0.4655(5) 0.0355(15) Uani 1 1 d . . . . .
C7 C 0.1797(7) 0.3242(6) 0.3062(5) 0.0319(14) Uani 1 1 d . . . . .
C8 C 0.1908(8) 0.2623(6) 0.1949(5) 0.0331(14) Uani 1 1 d . . . . .
C9 C 0.0565(8) 0.2009(7) 0.1261(5) 0.0427(17) Uani 1 1 d . . . . .
H9 H -0.0400 0.1958 0.1502 0.051 Uiso 1 1 calc R U . . .
C10 C 0.0673(9) 0.1469(7) 0.0211(5) 0.0471(18) Uani 1 1 d . . . . .
H10 H -0.0224 0.1070 -0.0252 0.056 Uiso 1 1 calc R U . . .
C11 C 0.2093(9) 0.1521(7) -0.0147(6) 0.0448(18) Uani 1 1 d . . . . .
H11 H 0.2156 0.1153 -0.0850 0.054 Uiso 1 1 calc R U . . .
C12 C 0.3417(8) 0.2116(7) 0.0533(5) 0.0420(17) Uani 1 1 d . . . . .
C13 C 0.3338(8) 0.2684(6) 0.1579(5) 0.0402(16) Uani 1 1 d . . . . .
H13 H 0.4243 0.3106 0.2033 0.048 Uiso 1 1 calc R U . . .
C14 C 0.6040(9) 0.3147(8) 0.0444(6) 0.0480(19) Uani 1 1 d . . . . .
C15 C 0.5877(9) 0.4359(8) 0.0726(6) 0.0512(19) Uani 1 1 d . . . . .
H15 H 0.4898 0.4487 0.0756 0.061 Uiso 1 1 calc R U . . .
C16 C 0.7187(10) 0.5378(9) 0.0962(6) 0.055(2) Uani 1 1 d . . . . .
H16 H 0.7087 0.6200 0.1156 0.066 Uiso 1 1 calc R U . . .
C17 C 0.8621(10) 0.5204(8) 0.0915(6) 0.056(2) Uani 1 1 d . . . . .
H17 H 0.9495 0.5900 0.1069 0.067 Uiso 1 1 calc R U . . .
C18 C 0.8772(9) 0.3978(9) 0.0635(6) 0.056(2) Uani 1 1 d . . . . .
H18 H 0.9751 0.3851 0.0604 0.067 Uiso 1 1 calc R U . . .
C19 C 0.7479(9) 0.2954(8) 0.0406(6) 0.0490(19) Uani 1 1 d . . . . .
H19 H 0.7579 0.2134 0.0225 0.059 Uiso 1 1 calc R U . . .
C20 C 0.3290(8) 0.5451(6) 0.3264(5) 0.0342(15) Uani 1 1 d . . . . .
C21 C 0.4789(8) 0.6129(7) 0.3691(6) 0.0457(18) Uani 1 1 d . . . . .
H21 H 0.5253 0.5986 0.4218 0.055 Uiso 1 1 calc R U . . .
C22 C 0.5591(9) 0.7033(8) 0.3315(7) 0.056(2) Uani 1 1 d . . . . .
H22 H 0.6607 0.7499 0.3595 0.068 Uiso 1 1 calc R U . . .
C23 C 0.4921(10) 0.7250(7) 0.2547(7) 0.052(2) Uani 1 1 d . . . . .
H23 H 0.5475 0.7863 0.2308 0.062 Uiso 1 1 calc R U . . .
C24 C 0.3413(9) 0.6558(7) 0.2120(6) 0.0490(19) Uani 1 1 d . . . . .
H24 H 0.2961 0.6694 0.1584 0.059 Uiso 1 1 calc R U . . .
C25 C 0.2573(9) 0.5658(7) 0.2492(6) 0.0433(17) Uani 1 1 d . . . . .
H25 H 0.1549 0.5207 0.2225 0.052 Uiso 1 1 calc R U . . .
C26 C 0.3150(13) -0.0084(10) 0.4165(8) 0.082(3) Uani 1 1 d . . . . .
H26A H 0.4215 -0.0089 0.4195 0.123 Uiso 1 1 calc R U . . .
H26B H 0.2494 -0.0946 0.3874 0.123 Uiso 1 1 calc R U . . .
H26C H 0.2908 0.0328 0.4849 0.123 Uiso 1 1 calc R U . . .
C27 C 0.3369(11) -0.0173(9) 0.2179(7) 0.067(2) Uani 1 1 d . . . . .
H27A H 0.3283 0.0207 0.1684 0.101 Uiso 1 1 calc R U . . .
H27B H 0.2687 -0.1026 0.1935 0.101 Uiso 1 1 calc R U . . .
H27C H 0.4417 -0.0195 0.2273 0.101 Uiso 1 1 calc R U . . .
Cl1 Cl -0.2145(2) 0.0730(2) 0.3095(2) 0.0665(6) Uani 1 1 d . . . . .
Cl2 Cl -0.0354(3) -0.14678(19) 0.27233(19) 0.0670(6) Uani 1 1 d . . . . .
N1 N 0.1077(6) 0.2625(5) 0.3637(4) 0.0317(12) Uani 1 1 d . . . . .
N2 N 0.2446(6) 0.4500(5) 0.3638(4) 0.0333(12) Uani 1 1 d . . . . .
O1 O 0.4798(7) 0.2056(5) 0.0130(4) 0.0620(16) Uani 1 1 d . . . . .
O2 O 0.3984(6) 0.2006(5) 0.3775(5) 0.0685(18) Uani 1 1 d . . . . .
Pt1 Pt 0.04014(3) 0.07110(2) 0.32215(2) 0.03699(10) Uani 1 1 d . . . . .
S1 S 0.2845(2) 0.07541(18) 0.33850(16) 0.0480(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.379(9) . ?
C1 C2 1.390(9) . ?
C1 N1 1.410(8) . ?
C2 C3 1.369(11) . ?
C2 H2 0.9300 . ?
C3 C4 1.394(12) . ?
C3 H3 0.9300 . ?
C4 C5 1.384(11) . ?
C4 H4 0.9300 . ?
C5 C6 1.391(9) . ?
C5 H5 0.9300 . ?
C6 N2 1.401(8) . ?
C7 N1 1.330(8) . ?
C7 N2 1.359(8) . ?
C7 C8 1.479(9) . ?
C8 C13 1.386(9) . ?
C8 C9 1.389(9) . ?
C9 C10 1.390(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.371(10) . ?
C10 H10 0.9300 . ?
C11 C12 1.370(10) . ?
C11 H11 0.9300 . ?
C12 O1 1.377(9) . ?
C12 C13 1.384(9) . ?
C13 H13 0.9300 . ?
C14 C19 1.370(11) . ?
C14 C15 1.378(11) . ?
C14 O1 1.384(9) . ?
C15 C16 1.378(11) . ?
C15 H15 0.9300 . ?
C16 C17 1.357(12) . ?
C16 H16 0.9300 . ?
C17 C18 1.390(12) . ?
C17 H17 0.9300 . ?
C18 C19 1.371(11) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.376(9) . ?
C20 C25 1.377(10) . ?
C20 N2 1.440(8) . ?
C21 C22 1.388(11) . ?
C21 H21 0.9300 . ?
C22 C23 1.359(12) . ?
C22 H22 0.9300 . ?
C23 C24 1.385(11) . ?
C23 H23 0.9300 . ?
C24 C25 1.392(10) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 S1 1.770(10) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 S1 1.791(9) . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
Cl1 Pt1 2.303(2) . ?
Cl2 Pt1 2.294(2) . ?
N1 Pt1 2.019(5) . ?
O2 S1 1.458(6) . ?
Pt1 S1 2.194(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 121.5(6) . . ?
C6 C1 N1 108.4(5) . . ?
C2 C1 N1 130.1(6) . . ?
C3 C2 C1 116.6(7) . . ?
C3 C2 H2 121.7 . . ?
C1 C2 H2 121.7 . . ?
C2 C3 C4 121.9(7) . . ?
C2 C3 H3 119.1 . . ?
C4 C3 H3 119.1 . . ?
C5 C4 C3 122.1(8) . . ?
C5 C4 H4 118.9 . . ?
C3 C4 H4 118.9 . . ?
C4 C5 C6 115.4(7) . . ?
C4 C5 H5 122.3 . . ?
C6 C5 H5 122.3 . . ?
C1 C6 C5 122.5(6) . . ?
C1 C6 N2 106.4(5) . . ?
C5 C6 N2 131.1(6) . . ?
N1 C7 N2 111.2(5) . . ?
N1 C7 C8 124.1(6) . . ?
N2 C7 C8 124.8(5) . . ?
C13 C8 C9 119.5(6) . . ?
C13 C8 C7 120.8(6) . . ?
C9 C8 C7 119.7(6) . . ?
C8 C9 C10 119.6(7) . . ?
C8 C9 H9 120.2 . . ?
C10 C9 H9 120.2 . . ?
C11 C10 C9 120.4(7) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C12 C11 C10 120.0(7) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C11 C12 O1 116.9(6) . . ?
C11 C12 C13 120.5(7) . . ?
O1 C12 C13 122.5(7) . . ?
C12 C13 C8 119.9(6) . . ?
C12 C13 H13 120.0 . . ?
C8 C13 H13 120.0 . . ?
C19 C14 C15 120.8(8) . . ?
C19 C14 O1 115.8(7) . . ?
C15 C14 O1 123.3(7) . . ?
C16 C15 C14 118.9(8) . . ?
C16 C15 H15 120.5 . . ?
C14 C15 H15 120.5 . . ?
C17 C16 C15 121.1(9) . . ?
C17 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C16 C17 C18 119.5(8) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C19 C18 C17 120.1(8) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C14 C19 C18 119.6(8) . . ?
C14 C19 H19 120.2 . . ?
C18 C19 H19 120.2 . . ?
C21 C20 C25 121.9(6) . . ?
C21 C20 N2 119.0(6) . . ?
C25 C20 N2 119.2(6) . . ?
C20 C21 C22 118.2(7) . . ?
C20 C21 H21 120.9 . . ?
C22 C21 H21 120.9 . . ?
C23 C22 C21 121.3(7) . . ?
C23 C22 H22 119.4 . . ?
C21 C22 H22 119.4 . . ?
C22 C23 C24 120.0(7) . . ?
C22 C23 H23 120.0 . . ?
C24 C23 H23 120.0 . . ?
C23 C24 C25 120.0(7) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C20 C25 C24 118.6(7) . . ?
C20 C25 H25 120.7 . . ?
C24 C25 H25 120.7 . . ?
S1 C26 H26A 109.5 . . ?
S1 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
S1 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
S1 C27 H27A 109.5 . . ?
S1 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
S1 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C7 N1 C1 106.6(5) . . ?
C7 N1 Pt1 125.2(4) . . ?
C1 N1 Pt1 125.8(4) . . ?
C7 N2 C6 107.4(5) . . ?
C7 N2 C20 126.1(5) . . ?
C6 N2 C20 126.5(5) . . ?
C12 O1 C14 119.1(6) . . ?
N1 Pt1 S1 88.97(16) . . ?
N1 Pt1 Cl2 179.06(15) . . ?
S1 Pt1 Cl2 90.80(8) . . ?
N1 Pt1 Cl1 89.48(16) . . ?
S1 Pt1 Cl1 178.11(8) . . ?
Cl2 Pt1 Cl1 90.77(9) . . ?
O2 S1 C26 108.1(4) . . ?
O2 S1 C27 107.8(4) . . ?
C26 S1 C27 101.2(5) . . ?
O2 S1 Pt1 117.0(3) . . ?
C26 S1 Pt1 111.1(4) . . ?
C27 S1 Pt1 110.4(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 1.0(11) . . . . ?
N1 C1 C2 C3 -180.0(7) . . . . ?
C1 C2 C3 C4 1.1(12) . . . . ?
C2 C3 C4 C5 -2.0(14) . . . . ?
C3 C4 C5 C6 0.6(12) . . . . ?
C2 C1 C6 C5 -2.5(11) . . . . ?
N1 C1 C6 C5 178.3(6) . . . . ?
C2 C1 C6 N2 178.8(6) . . . . ?
N1 C1 C6 N2 -0.4(7) . . . . ?
C4 C5 C6 C1 1.6(11) . . . . ?
C4 C5 C6 N2 179.9(7) . . . . ?
N1 C7 C8 C13 -121.5(7) . . . . ?
N2 C7 C8 C13 56.7(10) . . . . ?
N1 C7 C8 C9 60.5(9) . . . . ?
N2 C7 C8 C9 -121.3(7) . . . . ?
C13 C8 C9 C10 -0.3(11) . . . . ?
C7 C8 C9 C10 177.6(7) . . . . ?
C8 C9 C10 C11 1.1(11) . . . . ?
C9 C10 C11 C12 -0.5(12) . . . . ?
C10 C11 C12 O1 175.6(7) . . . . ?
C10 C11 C12 C13 -1.0(12) . . . . ?
C11 C12 C13 C8 1.7(11) . . . . ?
O1 C12 C13 C8 -174.6(7) . . . . ?
C9 C8 C13 C12 -1.1(11) . . . . ?
C7 C8 C13 C12 -179.0(6) . . . . ?
C19 C14 C15 C16 0.5(12) . . . . ?
O1 C14 C15 C16 -175.7(7) . . . . ?
C14 C15 C16 C17 0.4(12) . . . . ?
C15 C16 C17 C18 -0.7(12) . . . . ?
C16 C17 C18 C19 0.2(12) . . . . ?
C15 C14 C19 C18 -1.0(12) . . . . ?
O1 C14 C19 C18 175.5(7) . . . . ?
C17 C18 C19 C14 0.6(12) . . . . ?
C25 C20 C21 C22 -0.8(11) . . . . ?
N2 C20 C21 C22 179.4(7) . . . . ?
C20 C21 C22 C23 0.1(12) . . . . ?
C21 C22 C23 C24 -0.4(13) . . . . ?
C22 C23 C24 C25 1.3(12) . . . . ?
C21 C20 C25 C24 1.7(11) . . . . ?
N2 C20 C25 C24 -178.5(6) . . . . ?
C23 C24 C25 C20 -1.9(12) . . . . ?
N2 C7 N1 C1 -0.8(7) . . . . ?
C8 C7 N1 C1 177.6(6) . . . . ?
N2 C7 N1 Pt1 -164.4(4) . . . . ?
C8 C7 N1 Pt1 14.0(9) . . . . ?
C6 C1 N1 C7 0.7(7) . . . . ?
C2 C1 N1 C7 -178.4(7) . . . . ?
C6 C1 N1 Pt1 164.2(5) . . . . ?
C2 C1 N1 Pt1 -14.9(10) . . . . ?
N1 C7 N2 C6 0.6(8) . . . . ?
C8 C7 N2 C6 -177.8(6) . . . . ?
N1 C7 N2 C20 -178.9(6) . . . . ?
C8 C7 N2 C20 2.7(11) . . . . ?
C1 C6 N2 C7 -0.1(7) . . . . ?
C5 C6 N2 C7 -178.6(7) . . . . ?
C1 C6 N2 C20 179.4(6) . . . . ?
C5 C6 N2 C20 0.9(12) . . . . ?
C21 C20 N2 C7 -122.2(8) . . . . ?
C25 C20 N2 C7 58.0(10) . . . . ?
C21 C20 N2 C6 58.4(10) . . . . ?
C25 C20 N2 C6 -121.4(8) . . . . ?
C11 C12 O1 C14 135.8(8) . . . . ?
C13 C12 O1 C14 -47.7(11) . . . . ?
C19 C14 O1 C12 152.3(7) . . . . ?
C15 C14 O1 C12 -31.3(11) . . . . ?

_refine_diff_density_max         1.180
_refine_diff_density_min         -1.968
_refine_diff_density_rms         0.185

_shelxl_version_number           2013-4

