# Supplementary Information (SI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ccobl_rt_sq
_database_code_depnum_ccdc_archive 'CCDC 2482991'
loop_
_audit_author_name
_audit_author_address
'Jan Janczak'
;Institute of Low Temperature and Structure Research Polish Academy of Sciences
Poland
;
_audit_update_record             
;
2025-08-26 deposited with the CCDC.	2026-01-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C18 H17 Co N2 O6 P'
_chemical_formula_sum            'C18 H17 Co N2 O6 P'
_chemical_formula_weight         447.23

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.4129(4)
_cell_length_b                   12.0896(4)
_cell_length_c                   16.1295(5)
_cell_angle_alpha                90
_cell_angle_beta                 94.285(3)
_cell_angle_gamma                90
_cell_volume                     2219.29(13)
_cell_formula_units_Z            4
_cell_measurement_temperature    295(2)
_cell_measurement_reflns_used    6463
_cell_measurement_theta_min      2.8190
_cell_measurement_theta_max      27.3000

_exptl_crystal_description       parallelepiped
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.339
_exptl_crystal_F_000             916
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.264
_exptl_crystal_size_mid          0.102
_exptl_crystal_size_min          0.096
_exptl_absorpt_coefficient_mu    0.878
_shelx_estimated_absorpt_T_min   0.801
_shelx_estimated_absorpt_T_max   0.920
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8973
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.93a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_diffrn_ambient_temperature      295(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Atlas'
_diffrn_detector                 'CCD plate'
_diffrn_measurement_method       ω-scan
_diffrn_detector_area_resol_mean 10.6249
_diffrn_reflns_number            31181
_diffrn_reflns_av_unetI/netI     0.0431
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         2.458
_diffrn_reflns_theta_max         29.273
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.922
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.922
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.922
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             5581
_reflns_number_gt                4151
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlis CCD 1.171.38.43 (Rigaku Oxford Diffraction, 2015
;
_computing_cell_refinement       
;
CrysAlis Red 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
;
_computing_data_reduction        
;
CrysAlis Red 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
;
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    
;
Brandenburg & Putz (2006). Diamond 3.0. Crystal and Molecular
Structure Visualisation, University of Bonn, Germany
;
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0403P)²+0.8345P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5581
_refine_ls_number_parameters     260
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0621
_refine_ls_R_factor_gt           0.0385
_refine_ls_wR_factor_ref         0.0913
_refine_ls_wR_factor_gt          0.0820
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_restrained_S_all      1.001
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co Co 0.70586(2) 0.29136(2) 0.23354(2) 0.02057(8) Uani 1 1 d . . . . .
C1 C 0.86844(18) 0.38396(17) 0.49616(13) 0.0292(5) Uani 1 1 d . . . . .
C2 C 0.85997(17) 0.46636(17) 0.43603(12) 0.0256(4) Uani 1 1 d . . . . .
H2 H 0.874752 0.448987 0.381617 0.031 Uiso 1 1 calc R U . . .
C3 C 0.83005(18) 0.57363(17) 0.45528(13) 0.0272(5) Uani 1 1 d . . . . .
C4 C 0.8078(2) 0.59988(19) 0.53632(14) 0.0391(6) Uani 1 1 d . . . . .
H4 H 0.788236 0.671882 0.550193 0.047 Uiso 1 1 calc R U . . .
C5 C 0.8148(3) 0.5183(2) 0.59605(16) 0.0511(7) Uani 1 1 d . . . . .
H5 H 0.799316 0.535279 0.650380 0.061 Uiso 1 1 calc R U . . .
C6 C 0.8446(2) 0.4119(2) 0.57615(15) 0.0441(6) Uani 1 1 d . . . . .
H6 H 0.848807 0.357873 0.617281 0.053 Uiso 1 1 calc R U . . .
C7 C 0.8982(2) 0.26687(18) 0.47349(15) 0.0343(5) Uani 1 1 d . . . . .
H7A H 0.929963 0.228789 0.523135 0.041 Uiso 1 1 calc R U . . .
H7B H 0.958983 0.268549 0.434540 0.041 Uiso 1 1 calc R U . . .
P1 P 0.77456(5) 0.18952(4) 0.42796(3) 0.02820(14) Uani 1 1 d . . . . .
O1 O 0.72051(12) 0.25247(13) 0.35472(9) 0.0304(3) Uani 1 1 d . . . . .
O2 O 0.81445(15) 0.07382(13) 0.41168(10) 0.0430(4) Uani 1 1 d . . . . .
O3 O 0.68777(16) 0.18605(16) 0.49909(10) 0.0480(5) Uani 1 1 d . . . . .
H3 H 0.620203 0.179348 0.478590 0.072 Uiso 1 1 calc R U . . .
C8 C 0.81990(17) 0.65887(17) 0.38848(13) 0.0249(4) Uani 1 1 d . . . . .
O4 O 0.81937(13) 0.76019(12) 0.40453(10) 0.0334(4) Uani 1 1 d . . . . .
O5 O 0.81009(13) 0.62698(12) 0.31326(9) 0.0312(3) Uani 1 1 d . . . . .
N1 N 0.51795(14) 0.30020(14) 0.23561(11) 0.0247(4) Uani 1 1 d . . . . .
C9 C 0.45268(17) 0.36971(18) 0.18705(13) 0.0284(5) Uani 1 1 d . . . . .
H9 H 0.490810 0.419395 0.154222 0.034 Uiso 1 1 calc R U . . .
C10 C 0.33170(17) 0.37133(18) 0.18325(13) 0.0280(5) Uani 1 1 d . . . . .
H10 H 0.290269 0.421029 0.148170 0.034 Uiso 1 1 calc R U . . .
C11 C 0.27151(17) 0.29904(17) 0.23161(12) 0.0239(4) Uani 1 1 d . . . . .
C12 C 0.34008(18) 0.22875(19) 0.28381(14) 0.0312(5) Uani 1 1 d . . . . .
H12 H 0.304349 0.179986 0.318708 0.037 Uiso 1 1 calc R U . . .
C13 C 0.46082(18) 0.23156(19) 0.28369(14) 0.0310(5) Uani 1 1 d . . . . .
H13 H 0.504653 0.183459 0.318688 0.037 Uiso 1 1 calc R U . . .
C14 C 0.14123(17) 0.29527(17) 0.22753(12) 0.0249(4) Uani 1 1 d . . . . .
C15 C 0.07213(18) 0.3760(2) 0.18776(15) 0.0377(6) Uani 1 1 d . . . . .
H15 H 0.107023 0.434259 0.161066 0.045 Uiso 1 1 calc R U . . .
C16 C -0.04849(19) 0.3703(2) 0.18770(16) 0.0401(6) Uani 1 1 d . . . . .
H16 H -0.092706 0.425911 0.160622 0.048 Uiso 1 1 calc R U . . .
N2 N -0.10549(14) 0.28962(15) 0.22418(11) 0.0284(4) Uani 1 1 d . . . . .
C17 C -0.03905(19) 0.21052(19) 0.25997(17) 0.0383(6) Uani 1 1 d . . . . .
H17 H -0.076445 0.151835 0.284322 0.046 Uiso 1 1 calc R U . . .
C18 C 0.08174(19) 0.20981(19) 0.26336(16) 0.0388(6) Uani 1 1 d . . . . .
H18 H 0.123461 0.152012 0.289679 0.047 Uiso 1 1 calc R U . . .
O1W O 0.70552(13) 0.46077(12) 0.22616(10) 0.0315(3) Uani 1 1 d D . . . .
H1A H 0.703(2) 0.4946(19) 0.1797(8) 0.047 Uiso 1 1 d D U . . .
H1B H 0.737(2) 0.5050(17) 0.2622(12) 0.047 Uiso 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co O1 2.0052(15) . ?
Co O1W 2.0515(15) . ?
Co O5 2.1287(14) 2_645 ?
Co N1 2.1500(16) . ?
Co N2 2.1697(16) 1_655 ?
Co O4 2.2558(16) 2_645 ?
C1 C6 1.380(3) . ?
C1 C2 1.389(3) . ?
C1 C7 1.507(3) . ?
C2 C3 1.382(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.387(3) . ?
C3 C8 1.489(3) . ?
C4 C5 1.377(3) . ?
C4 H4 0.9300 . ?
C5 C6 1.374(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 P1 1.803(2) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
P1 O1 1.4987(15) . ?
P1 O2 1.5001(16) . ?
P1 O3 1.5713(17) . ?
O3 H3 0.8200 . ?
C8 O4 1.252(2) . ?
C8 O5 1.270(2) . ?
N1 C9 1.337(3) . ?
N1 C13 1.338(3) . ?
C9 C10 1.378(3) . ?
C9 H9 0.9300 . ?
C10 C11 1.387(3) . ?
C10 H10 0.9300 . ?
C11 C12 1.395(3) . ?
C11 C14 1.484(3) . ?
C12 C13 1.379(3) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C15 1.383(3) . ?
C14 C18 1.386(3) . ?
C15 C16 1.378(3) . ?
C15 H15 0.9300 . ?
C16 N2 1.333(3) . ?
C16 H16 0.9300 . ?
N2 C17 1.326(3) . ?
C17 C18 1.376(3) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
O1W H1A 0.851(5) . ?
O1W H1B 0.849(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Co O1W 106.87(6) . . ?
O1 Co O5 97.20(6) . 2_645 ?
O1W Co O5 155.74(6) . 2_645 ?
O1 Co N1 90.41(6) . . ?
O1W Co N1 87.35(6) . . ?
O5 Co N1 89.59(6) 2_645 . ?
O1 Co N2 93.13(6) . 1_655 ?
O1W Co N2 90.19(6) . 1_655 ?
O5 Co N2 91.45(6) 2_645 1_655 ?
N1 Co N2 176.15(7) . 1_655 ?
O1 Co O4 156.69(6) . 2_645 ?
O1W Co O4 96.31(6) . 2_645 ?
O5 Co O4 59.52(5) 2_645 2_645 ?
N1 Co O4 88.26(6) . 2_645 ?
N2 Co O4 89.08(6) 1_655 2_645 ?
C6 C1 C2 118.0(2) . . ?
C6 C1 C7 121.4(2) . . ?
C2 C1 C7 120.6(2) . . ?
C3 C2 C1 121.44(19) . . ?
C3 C2 H2 119.3 . . ?
C1 C2 H2 119.3 . . ?
C2 C3 C4 119.5(2) . . ?
C2 C3 C8 119.60(19) . . ?
C4 C3 C8 120.91(19) . . ?
C5 C4 C3 119.3(2) . . ?
C5 C4 H4 120.3 . . ?
C3 C4 H4 120.3 . . ?
C6 C5 C4 120.6(2) . . ?
C6 C5 H5 119.7 . . ?
C4 C5 H5 119.7 . . ?
C5 C6 C1 121.1(2) . . ?
C5 C6 H6 119.4 . . ?
C1 C6 H6 119.4 . . ?
C1 C7 P1 113.70(15) . . ?
C1 C7 H7A 108.8 . . ?
P1 C7 H7A 108.8 . . ?
C1 C7 H7B 108.8 . . ?
P1 C7 H7B 108.8 . . ?
H7A C7 H7B 107.7 . . ?
O1 P1 O2 116.61(9) . . ?
O1 P1 O3 110.14(10) . . ?
O2 P1 O3 108.60(10) . . ?
O1 P1 C7 108.74(10) . . ?
O2 P1 C7 108.44(10) . . ?
O3 P1 C7 103.50(11) . . ?
P1 O1 Co 152.48(10) . . ?
P1 O3 H3 109.5 . . ?
O4 C8 O5 119.55(19) . . ?
O4 C8 C3 121.92(19) . . ?
O5 C8 C3 118.53(18) . . ?
C8 O4 Co 87.79(12) . 2_655 ?
C8 O5 Co 93.12(12) . 2_655 ?
C9 N1 C13 117.06(17) . . ?
C9 N1 Co 122.34(14) . . ?
C13 N1 Co 120.53(14) . . ?
N1 C9 C10 123.2(2) . . ?
N1 C9 H9 118.4 . . ?
C10 C9 H9 118.4 . . ?
C9 C10 C11 120.19(19) . . ?
C9 C10 H10 119.9 . . ?
C11 C10 H10 119.9 . . ?
C10 C11 C12 116.38(18) . . ?
C10 C11 C14 122.07(18) . . ?
C12 C11 C14 121.54(18) . . ?
C13 C12 C11 120.0(2) . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
N1 C13 C12 123.1(2) . . ?
N1 C13 H13 118.4 . . ?
C12 C13 H13 118.4 . . ?
C15 C14 C18 116.09(19) . . ?
C15 C14 C11 122.26(19) . . ?
C18 C14 C11 121.65(19) . . ?
C16 C15 C14 120.0(2) . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
N2 C16 C15 123.8(2) . . ?
N2 C16 H16 118.1 . . ?
C15 C16 H16 118.1 . . ?
C17 N2 C16 115.96(18) . . ?
C17 N2 Co 121.00(15) . 1_455 ?
C16 N2 Co 122.89(15) . 1_455 ?
N2 C17 C18 124.1(2) . . ?
N2 C17 H17 117.9 . . ?
C18 C17 H17 117.9 . . ?
C17 C18 C14 120.0(2) . . ?
C17 C18 H18 120.0 . . ?
C14 C18 H18 120.0 . . ?
Co O1W H1A 122.0(18) . . ?
Co O1W H1B 126.2(18) . . ?
H1A O1W H1B 107(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 0.8(3) . . . . ?
C7 C1 C2 C3 178.47(19) . . . . ?
C1 C2 C3 C4 -0.1(3) . . . . ?
C1 C2 C3 C8 -178.91(18) . . . . ?
C2 C3 C4 C5 -0.6(3) . . . . ?
C8 C3 C4 C5 178.2(2) . . . . ?
C3 C4 C5 C6 0.6(4) . . . . ?
C4 C5 C6 C1 0.1(4) . . . . ?
C2 C1 C6 C5 -0.8(4) . . . . ?
C7 C1 C6 C5 -178.5(2) . . . . ?
C6 C1 C7 P1 97.0(2) . . . . ?
C2 C1 C7 P1 -80.6(2) . . . . ?
C1 C7 P1 O1 54.6(2) . . . . ?
C1 C7 P1 O2 -177.65(16) . . . . ?
C1 C7 P1 O3 -62.45(19) . . . . ?
O2 P1 O1 Co -33.4(2) . . . . ?
O3 P1 O1 Co -157.72(19) . . . . ?
C7 P1 O1 Co 89.5(2) . . . . ?
C2 C3 C8 O4 -163.66(19) . . . . ?
C4 C3 C8 O4 17.5(3) . . . . ?
C2 C3 C8 O5 17.2(3) . . . . ?
C4 C3 C8 O5 -161.6(2) . . . . ?
O5 C8 O4 Co 1.37(18) . . . 2_655 ?
C3 C8 O4 Co -177.74(17) . . . 2_655 ?
O4 C8 O5 Co -1.46(19) . . . 2_655 ?
C3 C8 O5 Co 177.69(15) . . . 2_655 ?
C13 N1 C9 C10 -1.6(3) . . . . ?
Co N1 C9 C10 175.38(16) . . . . ?
N1 C9 C10 C11 0.4(3) . . . . ?
C9 C10 C11 C12 1.3(3) . . . . ?
C9 C10 C11 C14 -177.95(19) . . . . ?
C10 C11 C12 C13 -1.7(3) . . . . ?
C14 C11 C12 C13 177.5(2) . . . . ?
C9 N1 C13 C12 1.1(3) . . . . ?
Co N1 C13 C12 -175.92(17) . . . . ?
C11 C12 C13 N1 0.5(4) . . . . ?
C10 C11 C14 C15 -12.3(3) . . . . ?
C12 C11 C14 C15 168.5(2) . . . . ?
C10 C11 C14 C18 167.4(2) . . . . ?
C12 C11 C14 C18 -11.8(3) . . . . ?
C18 C14 C15 C16 2.0(3) . . . . ?
C11 C14 C15 C16 -178.2(2) . . . . ?
C14 C15 C16 N2 -0.2(4) . . . . ?
C15 C16 N2 C17 -1.8(4) . . . . ?
C15 C16 N2 Co 173.75(19) . . . 1_455 ?
C16 N2 C17 C18 2.1(4) . . . . ?
Co N2 C17 C18 -173.6(2) 1_455 . . . ?
N2 C17 C18 C14 -0.3(4) . . . . ?
C15 C14 C18 C17 -1.7(4) . . . . ?
C11 C14 C18 C17 178.5(2) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O1W H1A O2 0.851(5) 1.757(6) 2.605(2) 174(3) 2_655 yes
O1W H1B O5 0.849(5) 1.857(9) 2.681(2) 163(3) . yes

_refine_diff_density_max         0.410
_refine_diff_density_min         -0.353
_refine_diff_density_rms         0.064



